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  • American Institute of Physics  (172,003)
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  • 1
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    National Academy of Sciences
    In:  EPIC3PNAS, National Academy of Sciences, 111(34), pp. E3501-E3505, ISSN: 0027-8424
    Publication Date: 2016-12-09
    Description: A recent temperature reconstruction of global annual temperature shows Early Holocene warmth followed by a cooling trend through the Middle to Late Holocene [Marcott SA, et al., 2013, Science 339(6124):1198–1201]. This global cooling is puzzling because it is opposite from the expected and simulated global warming trend due to the retreating ice sheets and rising atmospheric greenhouse gases. Our critical reexamination of this contradiction between the reconstructed cooling and the simulated warming points to potentially significant biases in both the seasonality of the proxy reconstruction and the climate sensitivity of current climate models.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
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  • 2
    Publication Date: 2014-10-14
    Description: The composition and abundance of algal pigments provide information on characteristics of a phytoplankton community in respect to its photoacclimation, overall biomass, and taxonomic composition. Particularly, these pigments play a major role in photoprotection and in the light-driven part of photosynthesis. Most phytoplankton pigments can be measured by High Performance Liquid Chromatography (HPLC) techniques to filtered water samples. This method, like others when water samples have to be analysed in the laboratory, is time consuming and therefore only a limited number of data points can be obtained. In order to receive information on phytoplankton pigment composition with a higher temporal and spatial resolution, we have developed a method to assess pigment concentrations from continuous optical measurements. The method applies an Empirical Orthogonal Function (EOF) analysis to remote sensing reflectance data derived from ship-based hyper-spectral underwater radiometric and from multispectral satellite data (using the MERIS Polymer product developed by Steinmetz et al., 2011) measured in the Eastern Tropical Atlantic. Subsequently we developed statistically linear models with measured (collocated) pigment concentrations as the response variable and EOF loadings as predictor variables. The model results, show that surface concentrations of a suite of pigments and pigment groups can be well predicted from the ship-based reflectance measurements, even when only a multi-spectral resolution is chosen (i.e. eight bands similar to those used by MERIS). Based on the MERIS reflectance data, concentrations of total and monovinyl chlorophyll a and the groups of photoprotective and photosynthetic carotenoids can be predicted with high quality. The fitted statistical model constructed on the satellite reflectance data as input was applied to one month of MERIS Polymer data to predict the concentration of those pigment groups for the whole Eastern Tropical Atlantic area. Bootstrapping explorations of cross-validation error indicate that the method can produce reliable predictions with relatively small data sets (e.g., 〈 50 collocated values of reflectance and pigment concentration). The method allows for the derivation of time series from continuous reflectance data of various pigment groups at various regions, which can be used to study variability and change of phytoplankton composition and photo-physiology.
    Repository Name: EPIC Alfred Wegener Institut
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  • 3
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    National Academy of Sciences
    In:  EPIC3Proceedings of the National Academy of Sciences, National Academy of Sciences, ISSN: 0027-8424
    Publication Date: 2017-02-08
    Description: The variability of sea surface temperatures (SSTs) at multidecadal and longer timescales is poorly constrained, primarily because instrumental records are short and proxy records are noisy. Through applying a new noise filtering technique to a global network of late Holocene SST proxies, we estimate SST variability between annual and millennial timescales. Filtered estimates of SST variability obtained from coral, foraminifer, and alkenone records are shown to be consistent with one another and with instrumental records in the frequency bands at which they overlap. General circulation models, however, simulate SST variability that is systematically smaller than instrumental and proxy-based estimates. Discrepancies in variability are largest at low latitudes and increase with timescale, reaching two orders of magnitude for tropical variability at millennial timescales. This result implies major deficiencies in observational estimates or model simulations, or both, and has implications for the attribution of past variations and prediction of future change.
    Repository Name: EPIC Alfred Wegener Institut
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  • 4
    Publication Date: 2017-04-04
    Description: Methane plays an important role in the Earth’s atmospheric chemistry and radiative balance being the second most important greenhouse gas after carbon dioxide. Methane is released to the atmosphere by a wide number of sources, both natural and anthropogenic, with the latter being twice as large as the former (IPCC, 2007). It has recently been established that significant amounts of geological methane, produced within the Earth’s crust, are currently released naturally into the atmosphere (Etiope, 2004). Active or recent volcanic/geothermal areas represent one of these sources of geological methane. But due to the fact that methane flux measurements are laboratory intensive, very few data have been collected until now and the contribution of this source has been generally indirectly estimated (Etiope et al., 2007). The Greek territory is geodynamically very active and has many volcanic and geothermal areas. Here we report on methane flux measurements made at two volcanic/geothermal systems along the South Aegean volcanic arc: Sousaki and Nisyros. The former is an extinct volcanic area of Plio-Pleistocene age hosting nowadays a low enthalpy geothermal field. The latter is a currently quiescent active volcanic system with strong fumarolic activity due to the presence of a high enthalpy geothermal system. Both systems have gas manifestations that emit significant amounts of hydrothermal methane and display important diffuse carbon dioxide emissions from the soils. New data on methane isotopic composition and higher hydrocarbon contents point to an abiogenic origin of the hydrothermal methane in the studied systems. Measured methane flux values range from –48 to 29,000 (38 sites) and from –20 to 1100 mg/mˆ2/d (35 sites) at Sousaki and Nisyros respectively. At Sousaki measurement sites covered almost all the degassing area and the diffuse methane output can be estimated in about 20 t/a from a surface of about 10,000 mˆ2. At Nisyros measurements covered the Stephanos and Kaminakia areas, which represent only a part of the entire degassing area. The two areas show very different methane degassing pattern with latter showing much higher flux values. Methane output can be estimated in about 0.25 t/a from an area of about 30,000 mˆ2 at Stephanos and about 1 t/a from an area of about 20,000 mˆ2 at Kaminakia. The total output from the entire geothermal system of Nisyros probably should not exceed 2 t/a.
    Description: Published
    Description: Vienna, Austria
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: open
    Keywords: methane output ; diffuse degassing ; volcanic/hydrothermal systems ; Greece ; 01. Atmosphere::01.01. Atmosphere::01.01.03. Pollution ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.08. Risk::05.08.01. Environmental risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Poster session
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  • 5
    Publication Date: 2017-04-04
    Description: A biomonitoring survey, above tree line level, using two endemic species (Senecio aethnensis and Rumex aethnensis) was performed on Mt. Etna, in order to evaluate the dispersion and the impact of volcanic atmospheric emissions. Samples of leaves were collected in summer 2008 from 30 sites in the upper part of the volcano (1500- 3000 m a.s.l). Acid digestion of samples was carried out with a microwave oven, and 44 elements were analyzed by using plasma spectrometry (ICP-MS and ICP-OES). The highest concentrations of all investigated elements were found in the samples collected closest to the degassing craters, and in the downwind sector, confirming that the eastern flank of Mt. Etna is the most impacted by volcanic emissions. Leaves collected along two radial transects from the active vents on the eastern flank, highlight that the levels of metals decrease one or two orders of magnitude with increasing distance from the source. This variability is higher for volatile elements (As, Bi, Cd, Cs, Pb, Sb, Tl) than for more refractory elements (Al, Ba, Sc, Si, Sr, Th, U). The two different species of plants do not show significant differences in the bioaccumulation of most of the analyzed elements, except for lanthanides, which are systematically enriched in Rumex leaves. The high concentrations of many toxic elements in the leaves allow us to consider these plants as highly tolerant species to the volcanic emissions, and suitable for biomonitoring researches in the Mt. Etna area.
    Description: Published
    Description: Vienna, Austria
    Description: 4.4. Scenari e mitigazione del rischio ambientale
    Description: open
    Keywords: Mt. Etna ; biomonitoring ; Trace elements ; 01. Atmosphere::01.01. Atmosphere::01.01.03. Pollution ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.08. Risk::05.08.01. Environmental risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 6
    Publication Date: 2017-04-04
    Description: Etna volcano, Italy, hosts one of the major groundwater systems of the island of Sicily. Waters circulate within highly permeable fractured, mainly hawaiitic, volcanic rocks. Aquifers are limited downwards by the underlying impermeable sedimentary terrains. Thickness of the volcanic rocks generally does not exceed some 300 m, preventing the waters to reach great depths. This is faced by short travel times (years to tens of years) and low thermalisation of the Etnean groundwaters. Measured temperatures are, in fact, generally lower than 25 °C. But the huge annual meteoric recharge (about 0.97 kmˆ3) with a high actual infiltration coefficient (0.75) implies a great underground circulation. During their travel from the summit area to the periphery of the volcano, waters acquire magmatic heat together with volcanic gases and solutes through water-rock interaction processes. In the last 20 years the Etnean aquifers has been extensively studied. Their waters were analysed for dissolved major, minor and trace element, O, H, C, S, B, Sr and He isotopes, and dissolved gas composition. These data have been published in several articles. Here, after a summary of the obtained results, the estimation of the magmatic heat flux through the aquifer will be discussed. To calculate heat uptake during subsurface circulation, for each sampling point (spring, well or drainage gallery) the following data have been considered: flow rate, water temperature, and oxygen isotopic composition. The latter was used to calculate the mean recharge altitude through the measured local isotopic lapse rate. Mean recharge temperatures, weighted for rain amount throughout the year, were obtained from the local weather station network. Calculations were made for a representative number of sampling points (216) including all major issues and corresponding to a total water flow of about 0.315 kmˆ3/a, which is 40% of the effective meteoric recharge. Results gave a total energy output of about 140 MW/a the half of which is ascribable to only 13 sampling points. These correspond to the highest flow drainage galleries with fluxes ranging from 50 to 1000 l/s and wells with pumping rates from 70 to 250 l/s. Geographical distribution indicates that, like magmatic gas leakage, heat flow is influenced by structural features of the volcanic edifice. The major heat discharge through groundwater are all tightly connected either to the major regional tectonic systems or to the major volcanic rift zones along which the most important flank eruptions take place. But rift zones are much more important for heat upraise due to the frequent dikes injection than for gas escape because generally when dikes have been emplaced the structure is no more permeable to gases because it becomes sealed by the cooling magma.
    Description: Published
    Description: Vienna, Austria
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: open
    Keywords: groundwaters ; volcanic surveillance ; water chemistry ; dissolved gases ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Oral presentation
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  • 7
    Publication Date: 2017-04-04
    Description: During the 2007-2008 antarctic campaign, the Italian PNRA installed a Low Power Magnetometer within the framework of the AIMNet (Antarctic International Magnetometer Network) project, proposed and coordinated by BAS. The magnetometer is situated at Talos Dome, around 300 km geographically North-West from Mario Zucchelli Station (MZS), and approximately at the same geomagnetic latitude as MZS. In this work we present a preliminary analysis of the geomagnetic field 1-min data, and a comparison with simultaneous data from different Antarctic stations.
    Description: Published
    Description: Vienna, Austria
    Description: 1.6. Osservazioni di geomagnetismo
    Description: open
    Keywords: daily variation ; AIMNet project ; Antarctica ; 04. Solid Earth::04.05. Geomagnetism::04.05.02. Geomagnetic field variations and reversals
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 8
    Publication Date: 2019-07-17
    Description: In this study temporal variations of coccolithophore blooms are investigated using satellite data. Eight years, from 2003 to 2010, of data of SCIAMACHY, a hyper-spectral satellite sensor on-board ENVISAT, were processed by the PhytoDOAS method to 5 monitor the biomass of coccolithophores in three selected regions. These regions are characterized by frequent occurrence of large coccolithophore blooms. The retrieval results, shown as monthly mean time-series, were compared to related satellite products, including the total surface phytoplankton, i.e., total chlorophyll-a (from GlobColour merged data) and the particulate inorganic carbon (from MODIS-Aqua). The 10 inter-annual variations of the phytoplankton bloom cycles and their maximum monthly mean values have been compared in the three selected regions to the variations of the geophysical parameters: sea-surface temperature (SST), mixed-layer depth (MLD) and surface wind speed, which are known to affect phytoplankton dynamics. For each region the anomalies and linear trends of the monitored parameters over the period of this 15 study have been computed. The patterns of total phytoplankton biomass and specific dynamics of coccolithophores chlorophyll-a in the selected regions are discussed in relation to other studies. The PhytoDOAS results are consistent with the two other ocean color products and support the reported dependencies of coccolithophore biomass’ dynamics to the compared geophysical variables. This suggests, that PhytoDOAS 20 is a valid method for retrieving coccolithophore biomass and for monitoring its bloom developments in the global oceans. Future applications of time-series studies using the PhytoDOAS data set are proposed, also using the new upcoming generations of hyper-spectral satellite sensors with improved spatial resolution.
    Repository Name: EPIC Alfred Wegener Institut
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  • 9
    Publication Date: 2019-07-17
    Description: The gradual cooling of the climate during the Cenozoic has generally been attributed to a decrease in CO2 concentration in the atmosphere. The lack of transient climate models and in particular the lack of high-resolution proxy records of CO2, beyond the ice-core record prohibit however a full understanding of for example the inception of the Northern Hemisphere glaciation and mid-Pleistocene transition. Here we elaborate on an inverse modelling technique to reconstruct a continuous CO2 series over the past 20 million year (Myr), by decomposing the global deep-sea benthic d18O record into a mutually consistent temperature and sea level record, using a set of 1-D models of the major Northern and Southern Hemisphere ice sheets. We subsequently compared the modelled temperature record with ice core and proxy-derived CO2 data to create a continuous CO2 reconstruction over the past 20 Myr. Results show a gradual decline from 450 ppmv around 15 Myr ago to 225 ppmv for mean conditions of the glacial-interglacial cycles of the last 1 Myr, coinciding with a gradual cooling of the global surface temperature of 10 K. Between 13 to 3 Myr ago there is no long-term sea level variation caused by ice-volume changes. We find no evidence for a change in the long-term relation between temperature change and CO2, other than the effect following from the saturation of the absorption bands for CO2. The reconstructed CO2 record shows that the Northern Hemisphere glaciation starts once the long-term average CO2 concentration drops below 265 ppmv after a period of strong decrease in CO2. Finally, only a small long-term decline of 23 ppmv is found during the mid-Pleistocene transition, constraining theories on this major transition in the climate system. The approach is not accurate enough to revise current ideas about climate sensitivity.
    Repository Name: EPIC Alfred Wegener Institut
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  • 10
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    National Academy of Sciences
    In:  EPIC3Proc. of the National Academy of Sciences of the United States of America (PNAS), National Academy of Sciences, 109(16), pp. 5967-5971
    Publication Date: 2019-07-17
    Description: Understanding the temporal variation of cosmic radiation and solar activity during the Holocene is essential for studies of the solar-terrestrial relationship. Cosmic-ray produced radionuclides, such as 10Be and 14C which are stored in polar ice cores and tree rings, offer the unique opportunity to reconstruct the history of cosmic radiation and solar activity over many millennia. Although records from different archives basically agree, they also show some deviations during certain periods. So far most reconstructions were based on only one single radionuclide record, which makes detection and correction of these deviations impossible. Here we combine different 10Be ice core records from Greenland and Antarctica with the global 14C tree ring record using principal component analysis. This approach is only possible due to a new high-resolution 10Be record from Dronning Maud Land obtained within the European Project for Ice Coring in Antarctica in Antarctica. The new cosmic radiation record enables us to derive total solar irradiance, which is then used as a proxy of solar activity to identify the solar imprint in an Asian climate record. Though generally the agreement between solar forcing and Asian climate is good, there are also periods without any coherence, pointing to other forcings like volcanoes and greenhouse gases and their corresponding feedbacks. The newly derived records have the potential to improve our understanding of the solar dynamics and to quantify the solar influence on climate.
    Repository Name: EPIC Alfred Wegener Institut
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  • 11
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    Copernicus
    In:  EPIC3The Cryosphere, Copernicus, 6(5), pp. 973-984, ISSN: 1994-0416
    Publication Date: 2019-07-17
    Description: The ongoing disintegration of large ice shelf parts in Antarctica raise the need for a better understanding of the physical processes that trigger critical crack growth in ice shelves. Finite elements in combination with configurational forces facilitate the analysis of single surface fractures in ice under various boundary conditions and material parameters. The principles of linear elastic fracture mechanics are applied to show the strong influence of different depth dependent functions for the density and the Young’s modulus on the stress intensity factor KI at the crack tip. Ice, for this purpose, is treated as an elastically compressible solid and the conse- quences of this choice in comparison to the predominant in- compressible approaches are discussed. The computed stress intensity factors KI for dry and water filled cracks are com- pared to critical values KIc from measurements that can be found in literature.
    Repository Name: EPIC Alfred Wegener Institut
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  • 12
    Publication Date: 2014-11-28
    Description: The reconstruction of the stable carbon isotope evolution in atmospheric CO2 (δ13Catm), as archived in Antarctic ice cores, bears the potential to disentangle the contributions of the different carbon cycle fluxes causing past CO2 variations. Here we present a new record of δ13Catm before, during and after the Marine Isotope Stage 5.5 (155 000 to 105 000 yr BP). The dataset is archived on the data repository PANGEA® (www.pangea.de) under 10.1594/PANGAEA.817041. The record was derived with a well established sublimation method using ice from the EPICA Dome C (EDC) and the Talos Dome ice cores in East Antarctica. We find a 0.4‰ shift to heavier values between the mean δ13Catm level in the Penultimate (~ 140 000 yr BP) and Last Glacial Maximum (~ 22 000 yr BP), which can be explained by either (i) changes in the isotopic composition or (ii) intensity of the carbon input fluxes to the combined ocean/atmosphere carbon reservoir or (iii) by long-term peat buildup. Our isotopic data suggest that the carbon cycle evolution along Termination II and the subsequent interglacial was controlled by essentially the same processes as during the last 24 000 yr, but with different phasing and magnitudes. Furthermore, a 5000 yr lag in the CO2 decline relative to EDC temperatures is confirmed during the glacial inception at the end of MIS5.5 (120 000 yr BP). Based on our isotopic data this lag can be explained by terrestrial carbon release and carbonate compensation.
    Repository Name: EPIC Alfred Wegener Institut
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  • 13
    Publication Date: 2019-07-17
    Description: Stable carbon isotope analysis of methane (δ13C of CH4) on atmospheric samples is one key method to constrain the current and past atmospheric CH4 budget. A frequently applied measurement technique is gas chromatography (GC) isotope ratio mass spectrometry (IRMS) coupled to a combustion-preconcentration unit. This report shows that the atmospheric trace gas krypton (Kr) can severely interfere during the mass spectrometric measurement, leading to significant biases in δ13C of CH4, if krypton is not sufficiently separated during the analysis. According to our experiments, the krypton interference is likely composed of two individual effects, with the lateral tailing of the doubly charged 86Kr peak affecting the neighbouring m/z 44 and partially the m/z 45 Faraday cups. Additionally, a broad signal affecting m/z 45 and especially m/z 46 is assumed to result from scattered ions of singly charged krypton. The introduced bias in the measured isotope ratios is dependent on the chromatographic separation, the krypton-to-CH4 mixing ratio in the sample, the focusing of the mass spectrometer as well as the detector configuration and can amount to up to several per mil in δ13C. Apart from technical solutions to avoid this interference, we present correction routines to a posteriori remove the bias.
    Repository Name: EPIC Alfred Wegener Institut
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  • 14
    Publication Date: 2019-07-16
    Description: Permafrost is one of the essential climate variables addressed by the Global Terrestrial Observing System (GCOS). Remote sensing data provide area-wide monitoring of e.g. surface temperatures or soil surface status (frozen or thawed state) in the Arctic and Subarctic, where ground data collection is difficult and restricted to local measurements at few monitoring sites. The task of the ESA Data User Element (DUE) Permafrost project is to build-up an Earth observation service for northern high-latitudinal permafrost applications with extensive involvement of the international permafrost research community (www.ipf.tuwien.ac.at/permafrost). The satellite-derived DUE Permafrost products are Land Surface Temperature, Surface Soil Moisture, Surface Frozen and Thawed State, Digital Elevation Model (locally as remote sensing product and circumpolar as non-remote sensing product) and Subsidence, and Land Cover. Land Surface Temperature, Surface Soil Moisture, and Surface Frozen and Thawed State will be provided for the circumpolar permafrost area north of 55° N with 25 km spatial resolution. In addition, regional products with higher spatial resolution were developed for five case study regions in different permafrost zones of the tundra and taiga (Laptev Sea [RU], Central Yakutia [RU], Western Siberia [RU], Alaska N-S transect, [US] Mackenzie River and Valley [CA]). This study shows the evaluation of two DUE Permafrost regional products, Land Surface Temperature and Surface Frozen and Thawed State, using freely available ground truth data from the Global Terrestrial Network of Permafrost (GTN-P) and monitoring data from the Russian-German Samoylov research station in the Lena River Delta (Central Siberia, RU). The GTN-P permafrost monitoring sites with their position in different permafrost zones are highly qualified for the validation of DUE Permafrost remote sensing products. Air and surface temperatures with high-temporal resolution from eleven GTN-P sites in Alaska and four sites in Siberia were used to match up LST products. Daily average GTN-P borehole- and air temperature data for three Alaskan and six Western Siberian sites were used to evaluate surface frozen and thawed. First results are promising and demonstrate the great benefit of freely available ground truth databases for remote sensing products.
    Repository Name: EPIC Alfred Wegener Institut
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  • 15
    Publication Date: 2019-07-17
    Description: The Toba eruption that occurred some 74 ka ago in Sumatra, Indonesia, is among the largest volcanic events on Earth over the last 2 million years. Tephra from this eruption has been spread over vast areas in Asia, where it constitutes a major time marker close to the Marine Isotope Stage 4/5 boundary. As yet, no tephra associated with Toba has been identified in Greenland or Antarctic ice cores. Based on new accurate dating of Toba tephra and on accurately dated European stalagmites, the Toba event is known to occur between the onsets of Greenland interstadials (GI) 19 and 20. Furthermore, the existing linking of Greenland and Antarctic ice cores by gas records and by the bipolar seesaw hypothesis suggests that the Antarctic counterpart is situated between Antarctic Isotope Maxima (AIM) 19 and 20. In this work we suggest a direct synchronization of Greenland (NGRIP) and Antarctic (EDML) ice cores at the Toba eruption based on matching of a pattern of bipolar volcanic spikes. Annual layer counting between volcanic spikes in both cores allows for a unique match. We first demonstrate this bipolar matching technique at the already synchronized Laschamp geomagnetic excursion (41 ka BP) before we apply it to the suggested Toba interval. The Toba synchronization pattern covers some 2000 yr in GI-20 and AIM-19/20 and includes nine acidity peaks that are recognized in both ice cores. The suggested bipolar Toba synchronization has decadal precision. It thus allows a determination of the exact phasing of inter-hemispheric climate in a time interval of poorly constrained ice core records, and it allows for a discussion of the climatic impact of the Toba eruption in a global perspective. The bipolar linking gives no support for a long-term global cooling caused by the Toba eruption as Antarctica experiences a major warming shortly after the event. Furthermore, our bipolar match provides a way to place palaeo-environmental records other than ice cores into a precise climatic context.
    Repository Name: EPIC Alfred Wegener Institut
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  • 16
    Publication Date: 2019-07-17
    Description: Here we present results of the first comprehensive study of sulphur compounds and methane in the oligotrophic tropical West Pacific Ocean. The concentrations of dimethylsuphide (DMS), dimethylsulphoniopropionate (DMSP), dimethylsulphoxide (DMSO), and methane (CH4), as well as various phytoplankton marker pigments in the surface ocean were measured along a north-south transit from Japan to Australia in October 2009. DMS (0.9 nmol l−1), dissolved DMSP (DMSPd, 1.6 nmol l−1) and particulate DMSP (DMSPp, 2 nmol l−1) concentrations were generally low, while dissolved DMSO (DMSOd, 4.4 nmol l−1) and particulate DMSO (DMSOp, 11.5 nmol l−1) concentrations were comparably enhanced. Positive correlations were found between DMSO and DMSP as well as DMSP and DMSO with chlorophyll a, which suggests a similar source for both compounds. Similar phytoplankton groups were identified as being important for the DMSO and DMSP pool, thus, the same algae taxa might produce both DMSP and DMSO. In contrast, phytoplankton seemed to play only a minor role for the DMS distribution in the western Pacific Ocean. The observed DMSPp : DMSOp ratios were very low and seem to be characteristic of oligotrophic tropical waters representing the extreme endpoint of the global DMSPp : DMSOp ratio vs. SST relationship. It is most likely that nutrient limitation and oxidative stress in the tropical West Pacific Ocean triggered enhanced DMSO production leading to an accumulation of DMSO in the sea surface. Positive correlations between DMSPd and CH4, as well as between DMSO (particulate and total) and CH4, were found along the transit. We conclude that both DMSP and DMSO serve as substrates for methanogenic bacteria in the western Pacific Ocean.
    Repository Name: EPIC Alfred Wegener Institut
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  • 17
    Publication Date: 2018-02-16
    Description: The Lena Delta in Northern Siberia is one of the largest river deltas in the world. During peak discharge, after the ice melt in spring, it delivers between 60–8000 m3 s−1 of water and sediment into the Arctic Ocean. The Lena Delta and the Laptev Sea coast also constitute a continuous permafrost region. Ongoing climate change, which is particularly pronounced in the Arctic, is leading to increased rates of permafrost thaw. This has already profoundly altered the discharge rates of the Lena River. But the chemistry of the river waters which are discharged into the coastal Laptev Sea have also been hypothesized to undergo considerable compositional changes, e.g. by increasing concentrations of inorganic nutrients such as dissolved organic carbon (DOC) and methane. These physical and chemical changes will also affect the composition of the phytoplankton communities. However, before potential consequences of climate change for coastal arctic phytoplankton communities can be judged, the inherent status of the diversity and food web interactions within the delta have to be established. In 2010, as part of the AWI Lena Delta programme, the phyto- and microzooplankton community in three river channels of the delta (Trofimov, Bykov and Olenek) as well as four coastal transects were investigated to capture the typical river phytoplankton communities and the transitional zone of brackish/marine conditions. Most CTD profiles from 23 coastal stations showed very strong stratification. The only exception to this was a small, shallow and mixed area running from the outflow of Bykov channel in a northerly direction parallel to the shore. Of the five stations in this area, three had a salinity of close to zero. Two further stations had salinities of around 2 and 5 throughout the water column. In the remaining transects, on the other hand, salinities varied between 5 and 30 with depth. Phytoplankton counts from the outflow from the Lena were dominated by diatoms (Aulacoseira species) cyanobacteria (Aphanizomenon, Pseudanabaena) and chlorophytes. In contrast, in the stratified stations the plankton was mostly dominated by dinoflagellates, ciliates and nanoflagellates, with only an insignificant diatom component from the genera Chaetoceros and Thalassiosira (brackish as opposed to freshwater species). Ciliate abundance was significantly coupled with the abundance of total flagellates. A pronounced partitioning in the phytoplankton community was also discernible with depth, with a different community composition and abundance above and below the thermocline in the stratified sites. This work is a first analysis of the phytoplankton community structure in the region where Lena River discharge enters the Laptev Sea.
    Repository Name: EPIC Alfred Wegener Institut
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  • 18
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    Copernicus
    In:  EPIC3Climate of the Past Discussions, Copernicus, 9, pp. 3103-3123, ISSN: 1814-9324
    Publication Date: 2019-07-17
    Description: There are a number of clear examples in the instrumental period where positive El Niño events were coincident with a severely weakened summer monsoon over India (ISM). ENSO's influence on the Indian Monsoon has therefore remained the centerpiece of various predictive schemes of ISM rainfall for over a century. The teleconnection between the monsoon and ENSO has undergone a protracted weakening since the late 1980's suggesting the strength of ENSO's influence on the monsoon may vary considerably on multidecadal timescales. The recent weakening has specifically prompted questions as to whether this shift represents a natural mode of climate variability or a fundamental change in ENSO and/or ISM dynamics due to anthropogenic warming. The brevity of empirical observations and large systematic errors in the representation of these two systems in state-of-the-art general circulation models hamper efforts to reliably assess the low frequency nature of this dynamical coupling under varying climate forcings. Here we place the 20th century ENSO-Monsoon relationship in a millennial context by assessing the phase angle between the two systems across the time spectrum using a continuous tree-ring ENSO reconstruction from North America and a speleothem oxygen isotope (δ18O) based reconstruction of the ISM. The results suggest that in the high-frequency domain (≤ 15 yr), El Niño (La Niña) events persistently lead to a weakened (strengthened) monsoon consistent with the observed relationship between the two systems during the instrumental period. However, in the low frequency domain (≥ 60 yr), periods of strong monsoon are, in general, coincident with periods of enhanced ENSO variance. This relationship is opposite to which would be predicted dynamically and leads us to conclude that ENSO is not pacing the prominent multidecadal variability that has characterized the ISM over the last millennium.
    Repository Name: EPIC Alfred Wegener Institut
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  • 19
    Publication Date: 2019-07-17
    Description: Sea ice thickness information is important for sea ice modelling and ship operations. Here a method to detect the thickness of sea ice up to 50 cm during the freeze-up season based on high incidence angle observations of the Soil Moisture and Ocean Salinity (SMOS) satellite working at 1.4 GHz is suggested. By comparison of thermodynamic ice growth data with SMOS brightness temperatures, a high correlation to intensity and an anticorrelation to the difference between vertically and horizontally polarised brightness temperatures at incidence angles between 40 and 50° are found and used to develop an empirical retrieval algorithm sensitive to thin sea ice up to 50 cm thickness. The algorithm shows high correlation with ice thickness data from airborne measurements and reasonable ice thickness patterns for the Arctic freeze-up period.
    Repository Name: EPIC Alfred Wegener Institut
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  • 20
    Publication Date: 2014-06-02
    Description: Following the launch of ESA's Soil Moisture and Ocean Salinity (SMOS) mission, it has been shown that brightness temperatures at a low microwave frequency of 1.4 GHz (L-band) are sensitive to sea ice properties. In the first demonstration study, sea ice thickness up to 50 cm has been derived using a semi-empirical algorithm with constant tie-points. Here, we introduce a novel iterative retrieval algorithm that is based on a thermodynamic sea ice model and a three-layer radiative transfer model, which explicitly takes variations of ice temperature and ice salinity into account. In addition, ice thickness variations within the SMOS spatial resolution are considered through a statistical thickness distribution function derived from high-resolution ice thickness measurements from NASA's Operation IceBridge campaign. This new algorithm has been used for the continuous operational production of a SMOS-based sea ice thickness data set from 2010 on. The data set is compared to and validated with estimates from assimilation systems, remote sensing data, and airborne electromagnetic sounding data. The comparisons show that the new retrieval algorithm has a considerably better agreement with the validation data and delivers a more realistic Arctic-wide ice thickness distribution than the algorithm used in the previous study (Kaleschke et al., 2012).
    Repository Name: EPIC Alfred Wegener Institut
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  • 21
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    Copernicus
    In:  EPIC3The Cryosphere Discussions, Copernicus, 8(1), pp. 919-951, ISSN: 1994-0440
    Publication Date: 2019-07-16
    Description: The ice shelf caverns around Antarctica are sources of cold and fresh water which contributes to the formation of Antarctic bottom water and thus to the ventilation of the deep basins of the World Ocean. While a realistic simulation of the cavern circulation requires high resolution, because of the complicated bottom topography and ice shelf morphology, the physics of melting and freezing at the ice shelf base is relatively simple. We have developed an analytically solvable box model of the cavern thermohaline state, using the formulation of melting and freezing as in Olbers and Hellmer (2010). There is high resolution along the cavern's path of the overturning circulation whereas the cross-path resolution is fairly coarse. The circulation in the cavern is prescribed and used as a tuning parameter to constrain the solution by attempting to match observed ranges for outflow temperature and salinity at the ice shelf front as well as of the mean basal melt rate. The method, tested for six Antarctic ice shelves, can be used for a quick estimate of melt/freeze rates and the overturning rate in particular caverns, given the temperature and salinity of the inflow and the above mentioned constrains for outflow and melting. In turn, the model can also be used for testing the compatibility of remotely sensed basal mass loss with observed cavern inflow characteristics.
    Repository Name: EPIC Alfred Wegener Institut
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  • 22
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    Copernicus
    In:  EPIC3Biogeosciences, Copernicus, 10(11), pp. 7081-7094, ISSN: 1726-4189
    Publication Date: 2018-02-16
    Description: Bio-optical measurements and sampling were carried out in the delta of the Lena River (northern Siberia, Russia) between 26 June and 4 July 2011. The aim of this study was to determine the inherent optical properties of the Lena water, i.e., absorption, attenuation, and scattering coefficients, during the period of maximum runoff. This aimed to contribute to the development of a bio-optical model for use as the basis for optical remote sensing of coastal water of the Arctic. In this context the absorption by CDOM (colored dissolved organic matter) and particles, and the concentrations of total suspended matter, phytoplankton-pigments, and carbon were measured. CDOM was found to be the most dominant parameter affecting the optical properties of the river, with an absorption coefficient of 4.5–5 m−1 at 442 nm, which was almost four times higher than total particle absorption values at visible wavelength range. The wavelenght-dependence of absorption of the different water constituents was chracterized by determining the semi logarithmic spectral slope. Mean CDOM, and detritus slopes were 0.0149 nm−1(standard deviation (stdev) = 0.0003, n = 18), and 0.0057 nm−1 (stdev = 0.0017, n = 19), respectively, values which are typical for water bodies with high concentrations of dissolved and particulate carbon. Mean chlorophyll a and total suspended matter were 1.8 mg m−3 (stdev = 0.734 n = 18) and 31.9 g m−3 (stdev = 19.94, n = 27), respectively. DOC (dissolved organic carbon) was in the range 8–10 g m−3 and the total particulate carbon (PC) in the range 0.25–1.5 g m−3. The light penetration depth (Secchi disc depth) was in the range 30–90 cm and was highly correlated with the suspended matter concentration. The period of maximum river runoff in June was chosen to obtain bio-optical data when maximum water constituents are transported into the Laptev Sea. However, we are aware that more data from other seasons and other years need to be collected to establish a general bio-optical model of the Lena water and conclusively characterize the light climate with respect to primary production.
    Repository Name: EPIC Alfred Wegener Institut
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  • 23
    Publication Date: 2015-03-19
    Description: The Surface Ocean CO2 Atlas (SOCAT), an activity of the international marine carbon research community, provides access to synthesis and gridded fCO2 (fugacity of carbon dioxide) products for the surface oceans. Version 2 of SOCAT is an update of the previous release (version 1) with more data (increased from 6.3 million to 10.1 million surface water fCO2 values) and extended data coverage (from 1968–2007 to 1968–2011). The quality control criteria, while identical in both versions, have been applied more strictly in version 2 than in version 1. The SOCAT website (http://www.socat.info/) has links to quality control comments, metadata, individual data set files, and synthesis and gridded data products. Interactive online tools allow visitors to explore the richness of the data. Applications of SOCAT include process studies, quantification of the ocean carbon sink and its spatial, seasonal, year-to-year and longerterm variation, as well as initialisation or validation of ocean carbon models and coupled climate-carbon models.
    Repository Name: EPIC Alfred Wegener Institut
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  • 24
    Publication Date: 2019-07-17
    Repository Name: EPIC Alfred Wegener Institut
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  • 25
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    Copernicus
    In:  EPIC3Geoscientific Model Development, Copernicus, 7(1), pp. 419-432, ISSN: 1991-9603
    Publication Date: 2019-07-17
    Description: In a feasibility study, the potential of proxy data for the temperature and salinity during the Last Glacial Maximum (LGM, about 19 000 to 23 000 years before present) in constraining the strength of the Atlantic meridional overturning circulation (AMOC) with a general ocean circulation model was explored. The proxy data were simulated by drawing data from four different model simulations at the ocean sediment core locations of the Multiproxy Approach for the Reconstruction of the Glacial Ocean surface (MARGO) project, and perturbing these data with realistic noise estimates. The results suggest that our method has the potential to provide estimates of the past strength of the AMOC even from sparse data, but in general, paleo-sea-surface temperature data without additional prior knowledge about the ocean state during the LGM is not adequate to constrain the model. On the one hand, additional data in the deep-ocean and salinity data are shown to be highly important in estimating the LGM circulation. On the other hand, increasing the amount of surface data alone does not appear to be enough for better estimates. Finally, better initial guesses to start the state estimation procedure would greatly improve the performance of the method. Indeed, with a sufficiently good first guess, just the sea-surface temperature data from the MARGO project promise to be sufficient for reliable estimates of the strength of the AMOC.
    Repository Name: EPIC Alfred Wegener Institut
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  • 26
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    Copernicus
    In:  EPIC3EGU General Assembly 2013, Vienna, 2013-04Geophysical Research Abstracts, Copernicus
    Publication Date: 2015-07-22
    Repository Name: EPIC Alfred Wegener Institut
    Type: Conference , notRev
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  • 27
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    Copernicus
    In:  EPIC3EGU General Assembly 2012, Vienna, 2012-04Geophysical Research Abstracts, Copernicus
    Publication Date: 2015-07-22
    Repository Name: EPIC Alfred Wegener Institut
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  • 28
    Publication Date: 2016-04-22
    Description: Citation only. Published in Proceedings of the National Academy of Sciences of the United States of America 109 (2012): 5984-5988, doi: 10.1073/pnas.1120794109
    Description: Funding was provided primarily from the Gordon and Betty Moore Foundation, and also the Chemical Oceanography Program of the US National Science Foundation, and WHOI.
    Repository Name: Woods Hole Open Access Server
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  • 29
    Publication Date: 2017-04-04
    Description: The effect of pressure on melt viscosity was investigated for five compositions along the join An(CaAl2Si2O8)–Di(CaMgSi2O6) and four alkali silicates containing lithium, sodium, and potassium in constant ratio of ∼ 1:1:1, but alkali-silica ratios are varying. The experiments were performed in an internally heated gas pressure vessel at pressures from 50 to 400 MPa in the viscosity range from 108 to 1011.5 Pa⋅s using parallel plate viscometry. The polymerized An composition shows a negative pressure dependence of viscosity while the other, more depolymerized compositions of the join An–Di have neutral to positive pressure coefficients. The alkali silicates display neutral to slightly positive pressure coefficients for melt viscosity. These findings in the high viscosity range of 108–1011 Pa⋅s, where pressure appears to be more efficient than in low viscous melts at high temperature, are consistent with previous results on the viscosity of polymerized to depolymerized melts in the system NaAlSi3O8–CaMgSi2O6 by Behrens and Schulze [ H. Behrens and F. Schulze, Am. Mineral. 88, 1351 (2003) ]. Thus we confirm that the sign of the pressure coefficient for viscosity is mainly related to the degree of melt polymerization in silicate and aluminosilicate melts.
    Description: DFG Grant n.°BE1720/9
    Description: Published
    Description: 044504-14
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: JCR Journal
    Description: open
    Keywords: viscosity ; polymerisation ; anorthite ; diopside ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 30
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    Copernicus
    In:  EPIC3Atmospheric Chemistry and Physics, Copernicus, 12(11), pp. 4817-4823
    Publication Date: 2019-07-16
    Description: Dynamical processes during the formation phase of the Arctic stratospheric vortex in autumn (from September to December) can introduce considerable interannual variability in the amount of ozone that is incorporated into the vortex. Chemistry in autumn tends to remove part of this variability because ozone relaxes towards equilibrium. As a quantitative measure of how important dynamical variability during vortex formation is for the winter ozone abundances above the Arctic we analyze which fraction of an ozone anomaly induced during vortex formation persists until early winter (3 January). The work is based on the Lagrangian Chemistry Transport Model ATLAS. In a case study, model runs for the winter 1999–2000 are used to assess the fate of an ozone anomaly artificially introduced during the vortex formation phase on 16 September. The runs provide information about the persistence of the induced ozone anomaly as a function of time, potential temperature and latitude. The induced ozone anomaly survives longer inside the polar vortex compared to outside the vortex. Half of the initial perturbation survives until 3 January at 540 K inside the polar vortex, with a rapid fall off towards higher levels, mainly due to NOx induced chemistry. Above 750 K the signal falls to values below 0.5%. Hence, dynamically induced ozone variability from the early vortex formation phase cannot significantly contribute to early winter variability above 750 K. At lower levels increasingly larger fractions of the initial perturbation survive, reaching 90% at 450 K. In this vertical range dynamical processes during the vortex formation phase are crucial for the ozone abundance in early winter.
    Repository Name: EPIC Alfred Wegener Institut
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  • 31
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    Copernicus
    In:  EPIC3Geoscientific Model Development, Copernicus, 7(5), pp. 2003-2013, ISSN: 1991-9603
    Publication Date: 2016-12-09
    Description: We present first results from a coupled model setup, consisting of the state-of-the-art ice sheet model RIMBAY (Revised Ice Model Based on frAnk pattYn), and the community earth system model COSMOS. We show that special care has to be provided in order to ensure physical distributions of the forcings as well as numeric stability of the involved models. We demonstrate that a suitable statistical downscaling is crucial for ice sheet stability, especially for southern Greenland where surface temperatures are close to the melting point. The downscaling of net snow accumulation is based on an empirical relationship between surface slope and rainfall. The simulated ice sheet does not show dramatic loss of ice volume for pre-industrial conditions and is comparable with present-day ice orography. A sensitivity study with high CO2 level is used to demonstrate the effects of dynamic ice sheets onto climate compared to the standard setup with prescribed ice sheets.
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  • 32
    Publication Date: 2021-12-06
    Description: Marked changes in human dispersal and development during the Middle to Upper Paleolithic transition have been attributed to massive volcanic eruption and/or severe climatic deterioration. We test this concept using records of volcanic ash layers of the Campanian Ignimbrite eruption dated to ca. 40,000 y ago (40 ka B.P.). The distribution of the Campanian Ignimbrite has been enhanced by the discovery of cryptotephra deposits (volcanic ash layers that are not visible to the naked eye) in archaeological cave sequences. They enable us to synchronize archaeological and paleoclimatic records through the period of transition from Neanderthal to the earliest anatomically modern human populations in Europe. Our results con!rm that the combined effects of a major volcanic eruption and severe climatic cooling failed to have lasting impacts on Neanderthals or early modern humans in Europe. We infer that modern humans proved a greater competitive threat to indigenous populations than natural disasters.
    Description: funded by the United Kingdom Natural Environment Research Council through a Response of Humans to Abrupt Environmental Transitions (RESET) Consortium Grant
    Description: Published
    Description: 13532–13537
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: JCR Journal
    Description: restricted
    Keywords: Neanderthals ; modern humans ; cryptotephra deposits ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 33
    Publication Date: 2024-04-23
    Description: 〈jats:p〉Abstract. The spatial and temporal variability of a low-centred polygon on the eastern floodplain area of the lower Anabar River (72.070° N, 113.921° E, northern Yakutia, Siberia) has been investigated using a multi-method approach. The present-day vegetation in each square metre was analysed revealing a community of Larix shrubby Betula and Salix on the polygon rim, a dominance of Carex and Andromeda polifolia in the rim-to-pond transition zone, and a predominantly monospecific Scorpidium scorpioides coverage within the pond. The TOC content, TOC/TN ratio, grain-size, vascular plant macrofossils, moss remains, diatoms, and pollen were analysed for two vertical sections and a sediment core from a transect across the polygon. Radiocarbon dating indicates that the formation of the polygon started at least 1500 yr ago; the general positions of the pond and rim have not changed since that time. Two types of pond vegetation were identified, indicating two contrasting development stages of the polygon. The first was a well-established moss association dominated by submerged or floating Scorpidium scorpioides and/or Drepanocladus spp. and overgrown by epiphytic diatoms such as Tabellaria flocculosa and Eunotia taxa. This stage coincides temporally with a period in which the polygon was only drained by lateral subsurface water flow, as indicated by mixed grain sizes. A different moss association occurred during times of repeated river flooding (indicated by homogeneous medium-grained sand that probably accumulated during the annual spring snow melt), characterized by an abundance of Meesia triquetra and a dominance of benthic diatoms (e.g. Navicula vulpina), indicative of a relatively high pH and a high tolerance of disturbance. A comparison of the local polygon vegetation (inferred from moss and macrofossil spectra) with the regional vegetation (inferred from pollen spectra) indicated that the moss association with Scorpidium scorpioides became established during relatively favourable climatic conditions while the association dominated by Meesia triquetra occurred during periods of harsh climatic conditions. Our study revealed a strong riverine influence (in addition to climatic influences) on polygon development and the type of peat accumulated. 〈/jats:p〉
    Repository Name: EPIC Alfred Wegener Institut
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  • 34
    Publication Date: 2024-04-11
    Description: Sea urchins as broadcasting spawners, release their gametes into open water for fertilization, thus being particularly vulnerable to ocean acidification. In this study, we assessed the effects of different pH scenarios on fertilization success of Strongylocen- 5 trotus droebachiensis, collected at Spitsbergen, Arctic. We achieved acidification by bubbling CO2 into filtered seawater using partial pressures (pCO2) of 180, 380, 980, 1400 and 3000 μatm. Untreated filtered seawater was used as control. We recorded fertilization rates and diagnosed morphological aberrations after post-fertilization periods of 1 h and 3 h under different exposure conditions in experiments with and without 10 pre-incubation of the eggs prior to fertilization. In parallel, we conducted measurements of intracellular pH changes using BCECF/AM in unfertilized eggs exposed to a range of acidified seawater. We observed increasing rates of polyspermy in relation to higher seawater pCO2, which might be due to failures in the formation of the fertilization envelope. In addition, our experiments showed anomalies in fertilized eggs: incomplete 15 lifting-off of the fertilization envelope and blebs of the hyaline layer. Other drastic malformations consisted of constriction, extrusion, vacuolization or degeneration (observed as a gradient from the cortex to the central region of the cell) of the egg cytoplasm, and irregular cell divisions until 2- to 4-cell stages. The intracellular pH (pHi) decreased significantly from 1400 μatm on. All results indicate a decreasing fertilization success 20 at CO2 concentrations from 1400 μatm upwards. Exposure time to low pH might be a threatening factor for the cellular buffer capacity, viability, and development after fertilization.
    Repository Name: EPIC Alfred Wegener Institut
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  • 35
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 86 (1999), S. 4902-4907 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Grain boundary diffusion of titanium through platinum thin films has been carried out in the temperature range from 200 to 600 °C. Five different platinum/titanium bilayer thicknesses, from 35 to 800 Å Pt, were annealed in 5% O2/95% N2. The accumulation of titanium at the platinum surface layer was measured by x-ray photoelectron spectroscopy (XPS) to determine the grain boundary diffusion coefficient (Db). Diffusivity values were calculated based on two different analysis methods assuming type C kinetics. For Pt layers thicker than 200 Å, the activation energy (Qb) for titanium diffusion was found to be 118±15 kJ/mol (1.22±0.16 eV). For Pt layers thinner than 200 Å, there was a thickness dependence on the diffusion kinetics, resulting in activation energies as low as 20±4 kJ/mol (0.21±0.04 eV). XPS results gave no evidence for any Pt-Ti alloy formation in these layers. The suppression of alloy formation may be attributed to the presence of oxygen at the Pt/Ti interface during layer deposition. The quantitative analysis of titanium interdiffusion in platinum provides valuable information regarding Pt/Ti surface concentrations in thin-film chemical sensors, and for understanding changes in operational characteristics of platinum electrodes. © 1999 American Institute of Physics.
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  • 36
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 86 (1999), S. 4922-4929 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Mechanical properties of sputtered AlCu(0.5 wt %) thin films, 0.2–2.0 μm thick, were determined by tensile testing. For comparison, tensile tests were also performed on bulk samples of the same composition. The films were deposited on thin polyimide foils. They were characterized with respect to the surface, microstructure, residual stress, and concentration of copper and oxygen. Stress-strain curves of the films were obtained by separating the force working on the polyimide foil from that working on the metal-polyimide compound. Young's modulus of the films almost corresponded to the bulk value. Films with a thickness 〉1.5 μm broke by formation of macrocracks while thinner films showed formation of microcracks. The Hall–Petch model, additional strengthening by small grain size, and the role of grain boundary sliding for crack formation are discussed. © 1999 American Institute of Physics.
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  • 37
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 86 (1999), S. 4943-4948 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We investigated the effect of C49-to-C54 conversion behavior on the agglomeration of Ti-silicide fabricated on subquarter micron polycrystalline Si lines by comparing pre-amorphized samples with conventional ones. Pre-amorphization of polycrystalline Si enhances the C49-to-C54 transformation on subquarter micron linewidths, however, it results in the early development of macroscopic grooves during the second rapid thermal annealing. From these results, we suggest the existence of an extra thermal budget during the second rapid thermal annealing of the pre-amorphized samples, which deteriorates the thermal stability of the C54-TiSi2 featured line. It is also shown that C49-to-C54 transformation on a 0.2 μm linewidth in the conventional samples has two kinds of competing factors when postannealing is added. One is the tendency of C54 transformation and the other is agglomeration of C49-TiSi2 grains. During high temperature annealing (〉850 °C), C49-TiSi2 has been agglomerated by a thinning mechanism instead of transformation into the C54 phase. © 1999 American Institute of Physics.
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  • 38
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 86 (1999), S. 5109-5115 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Recently published data on the variation with applied bias and temperature of steady-state photoluminescence and photoconductivity from a series of GaAs/AlGaAs single quantum well p-i-n structures are subjected to detailed theoretical analysis, using phenomenological variables introduced in connection with these results. The data are interpreted as revealing the presence in the well of a space charge, which causes band bending and hence indirectly modifies carrier escape lifetimes. It is shown that the thermionic escape of holes can affect the electron tunneling escape lifetime so that the latter displays a thermal activation energy which is quantitatively similar to the hole well depth. © 1999 American Institute of Physics.
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  • 39
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 86 (1999), S. 5116-5130 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Detailed experimental and theoretical analysis of the pulsed excitation of polymer light emitting diodes is presented. We find a set of universal transient features for a variety of device configurations (different polymers/cathodes) which can be reproduced using our phenomenological numerical model. We find that the temporal evolution of the electroluminescence in response to a step voltage pulse is characterized by: (i) a delay followed by; (ii) a fast initial rise at turn-on followed by; (iii) a slow rise (slower by at least one order of magnitude). The large mobility mismatch between holes and electrons in conjugated polymers allows us to separately time resolve the motion of holes and electrons. We suggest a method for extracting mobility values that takes into account the possible field-induced broadening of carrier fronts, and which is found to be compatible with mobilities determined from constant wave measurements. By using appropriate device configurations it is possible to determine the mobilities of both holes and electrons from a single device. Mobilities for holes and electrons are extracted for a poly(p-phenylenevinylene) copolymer and poly(di-octyl fluorene). © 1999 American Institute of Physics.
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  • 40
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 86 (1999), S. 5141-5145 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We have produced arrays of Co nanowires in anodic porous alumina filters by means of electrodeposition. The structure and magnetization behavior of the wires was investigated with nuclear magnetic resonance (NMR) and magnetization measurements. NMR shows that the wires consist of a mixture of fcc and hcp texture with the (0001) texture of the hcp fraction oriented preferentially perpendicular to the wires. The magnetization direction is determined by a competition of demagnetizing fields and dipole–dipole fields and can be tuned parallel or perpendicular to the wires by changing the length of the wires. © 1999 American Institute of Physics.
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    Journal of Applied Physics 86 (1999), S. 5164-5168 
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    Topics: Physics
    Notes: The effects of Fe doping on the magnetic, transport, and magnetoresistance properties are studied for La0.7Sr0.3Mn1−yFeyO3 (y=0–0.18) and La1−xSrxMn0.88Fe0.12O3 (x=0.1–0.50). For increasing y, a peak in the thermal dependence of the resistivity appears and develops at the temperature TPl lower than TC, while the another peak near TC becomes smaller and then disappears. At 78 K the La1−xSrxMn0.88Fe0.12O3 oxides are insulators for x〈0.2 and x〉0.5 and only the lower-temperature metal–insulator transition peak appears for 0.25〈x〈0.45. With increase of x from 0.25, TPl increases, becomes maximum at x=0.4 and then decreases. The temperature dependence of resistivity for the doped samples is quite different from that of the undoped La1−xSrxMnO3 series. © 1999 American Institute of Physics.
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 86 (1999), S. 5293-5295 
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    Topics: Physics
    Notes: Abnormal junction leakage characteristics in titanium-capped cobalt disilicide were investigated. The cobalt silicide n+-p junctions, fabricated with different capping layers, were characterized by current–voltage measurements and transmission electron microscopy. The reverse junction leakage currents of Ti-capped 13.5-nm-thick cobalt disilicide (CT) are higher than those of TiN-capped samples. The activation energy of CT at temperatures below 80 °C is 0.41 eV, and its dominant leakage mechanism is consistent with phonon-assisted tunneling. Transmission electron microscopy analysis indicates the existence of island phases and precipitates located at the silicide/Si interface, which are titanium disilicide and CoxTi1−xSi2 phases, as evidenced by energy dispersive spectroscopy. As a result, for the case of CT, the reasons for higher junction leakage currents and their field dependence appear to be the result of the diffusion of Ti atoms into CoSi2 grain boundaries and the resulting formation of TiSi2 and CoxTi1−xSi2 phases, which gives rise to a rougher silicide interface and a close spacing between silicide and the junction. © 1999 American Institute of Physics.
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 86 (1999), S. 4100-4106 
    ISSN: 1089-7550
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    Topics: Physics
    Notes: A swept frequency absorbance plasma diagnostic technique for measurement of self-resonance frequency, intrinsic plasma-tool distributed capacitance, radiative energy loss, and effective plasma capacitance is described. The ex situ probe measures the plasma properties independently of all contributions from the plasma-tool and transmission line connection to the rf supply. The technique employs a swept frequency source and a balanced equal ratio arm bridge to measure the frequency response of the plasma tool after the plasma has been extinguished under plasma conjugate matching conditions. The resonant frequency of the combination of capacitances due to plasma-tool geometry (intrinsic capacitance, Ci) and the matching network (Cm) exhibits a shift from the excitation frequency (13.56 MHz) that is dependent on the effective plasma capacitance. Resonance frequency shift data are given for He, Ne, Ar, O2, N2, and N2O as a function of both pressure (0.02–0.8 mbar) and incident power (50 and 100 W). This technique allows the differentiation between dissociation and ionization processes within the plasma through a simple noninvasive rf measurement. © 1999 American Institute of Physics.
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    Journal of Applied Physics 86 (1999), S. 4118-4123 
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    Topics: Physics
    Notes: The charge distribution function (CDF) of dust particles in low temperature plasmas is obtained as a function of both negative and positive discrete charges Z=(minus-plus)1,(minus-plus)2;,..., and various plasma parameters. Positively charged grains can be formed when secondary electron emission, that is, ionization of the grains by electron impact, is sufficiently important to change their charge. An expression for the CDF is derived from steady-state master equations for the densities of monodispersed, negatively or positively charged dust particles, with Z=(minus-plus)1,(minus-plus)2,... discrete elementary charges and radius R, taking into account single and double elementary charge changes in collisions of the particle with plasma electrons or ions. © 1999 American Institute of Physics.
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 86 (1999), S. 4124-4133 
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    Topics: Physics
    Notes: A two-dimensional model has been developed for calculating the behavior of Ar2+ and Ar2+ ions in a direct current argon glow discharge, by the use of balance equations describing the various production and loss processes for these species, as well as their transport by diffusion and migration. These balance equations are coupled to the equations for the Ar+ ions and electrons and solved simultaneously with Poisson's equation, to obtain a self-consistent description of the charged particles behavior and the electrical characteristics in the glow discharge. Moreover, this model is combined with the other models that we have developed previously for the Ar atoms in various excited levels and the Cu atomic and ionic species, to obtain an overall description of the direct current argon glow discharge. The model is applied to typical conditions used for glow discharge mass spectrometry (pressure of 50–100 Pa, voltage of 600–1400 V, and current of 0.4–15 mA). Typical calculation results include the densities and fluxes of these ionic species, as well as the relative contributions of their production and loss processes. The Ar2+ ions are almost exclusively formed by two-electron ionization from Ar0 atoms, and they become primarily lost by diffusion and subsequent recombination at the cell walls. The Ar2+ ions are mainly created by Hornbeck–Molnar and metastable-metastable associative ionization, whereas atom to molecule conversion seems to play only a minor role at the discharge conditions under study. Loss of these Ar2+ ions is caused primarily by diffusion and recombination at the cell walls, but dissociative recombination in the plasma plays also a significant role. We found that the ratios of Ar2+/Ar+ and Ar2+/Ar+ ion densities and fluxes were in the order of 1%–10%, which is in good agreement with experimental observations. © 1999 American Institute of Physics.
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    Journal of Applied Physics 86 (1999), S. 4192-4198 
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    Topics: Physics
    Notes: In the present work, we study the sensitivity of the near-edge x-ray absorption fine structure (NEXAFS) spectroscopy to ion induced defects in polycrystalline diamond films. The ion bombardment of hydrogenated films is performed using 30 keV Xe+ ions at room temperature for doses ranging from 2×1013 ions/cm2, producing local point defects, to 2×1015 ions/cm2, which results in almost complete amorphization of the diamond surface. Auger electron spectroscopy measurements are not sensitive to the modifications induced by the lowest implantation dose. Whereas partial electron yield (PEY) NEXAFS measurements, applied in surface and bulk-sensitive modes, using 35, 15, and 8 eV secondary electrons, respectively, reveals the formation of a defective structure and gradual deterioration of diamond in the near-surface region. From PEY NEXAFS spectra measured using 15 eV secondary electrons, the position of C(1s) binding energy is measured. The x-ray photoelectron spectra of the samples were measured using an incident photon energy of 450 eV. It is found that the C(1s) binding energy in the implanted samples has a positive shift of 0.6–1 eV, which is indicative of transformation of diamond to disordered carbon. The high sensitivity of NEXAFS spectroscopy to point defects induced by the low dose ion implantation was reflected by a sharp reduction in the intensity of the diamond core exciton peak and by the appearance of a new spectral feature in the pre-edge region, below the C(1s)−π* transition. Analysis of the NEXAFS spectra of ion implanted films is performed on the basis of the electronic structure of diamond. © 1999 American Institute of Physics.
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    Journal of Applied Physics 86 (1999), S. 4199-4213 
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    Topics: Physics
    Notes: We analyze the high-electric-field technique designed by Yokoyama and van Sprang [J. Appl. Phys. 57, 4520 (1985)] to determine the polar anchoring coefficient W of a nematic liquid crystal-solid substrate. The technique implies simultaneous measurement of the optical phase retardation and capacitance as functions of the applied voltage well above the threshold of the Frederiks transition. We develop a generalized model that allows for the determination of W for tilted director orientation. Furthermore, the model results in a new high-field technique, (referred to as the RV technique), based on the measurement of retardation versus applied voltage. W is determined from a simple linear fit over a well-specified voltage window. No capacitance measurements are needed to determine W when the dielectric constants of the liquid crystal are known. We analyze the validity of the Yokoyama–van Sprang (YvS) and RV techniques and show that experimental data in real cells often do not follow the theoretical curves. The reason is that the director distribution is inhomogeneous in the plane of the bounding plates, while the theory assumes that the director is not distorted in this plane. This discrepancy can greatly modify the fitted value of 1/W, and even change its sign, thus making the determination of W meaningless. We suggest a protocol that allows one to check if the cell can be used to measure W by the YvS or RV techniques. The protocol establishes new criteria that were absent in the original YvS procedure. The results are compared with other data on W, obtained by a threshold-field technique for the same nematic-substrate pair. © 1999 American Institute of Physics.
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    Journal of Applied Physics 86 (1999), S. 4214-4219 
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    Topics: Physics
    Notes: Microcavities formed by H+ and He+ implantation and subsequent annealing are effective gettering sites for transition metal impurities in silicon. However, gettering in silicon-on-insulator (SOI) materials is quite different from that in silicon. In this work, we investigate the gettering of Cu to these microcavities in silicon, separation by implantation of oxygen (SIMOX) and bonded/ion-cut SOI wafers. Our data indicate that He+ implantation in the high dose regime (0.2–1×1017 cm−2) creates a wide band of microcavities near the projected range without causing blistering on the sample surface. On the other hand, the implantation dose of H+ needed for stable microcavity formation is relatively narrow (3–4×1016 cm−2), and this value is related to the projected range. The different behavior of H and He in silicon is discussed and He implantation is more desirable with regard to impurity gettering. Cu is implanted into the surface region of the Si and SOI samples, followed by annealing at 700 and 1000 °C. Our results indicate that the microcavities can effectively getter a high dose of Cu (2.5×1015 cm−2) at 700 °C in bulk Si wafer, but higher temperature annealing is needed for the effective gettering in SIMOX. Gettering of Cu by the intrinsic defects at or beneath the buried oxide interface of the SIMOX is observed at 700 °C, but no trapped impurities are observed after 1000 °C annealing in the samples in the presence of microcavities. Almost all of the 1×1014 cm−2 Cu implanted into the Si overlayer of the bonded/ion-cut SOI diffuse through the thermally grown oxide layer and are captured by the cavities in the substrate after annealing at 1000 °C. © 1999 American Institute of Physics.
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    Journal of Applied Physics 86 (1999), S. 4232-4241 
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    Topics: Physics
    Notes: Closing cracks in viscoelastic materials are analyzed using a cohesive zone model. The analysis is relevant to the bonding of surfaces of viscoelastic materials, and in particular to the Johnson–Kendall–Roberts (JKR) experiment. A crack bonding theory due to Schapery is extended to include the case of the standard linear solid material, and some consequences of this material's finite long time compliance are illustrated. The stress field behind a steadily closing crack in a standard linear solid is also investigated in detail. Finally, a method for applying Schapery's crack bonding theory to the analysis of a JKR-type experiment involving viscoelastic cylinders is given explicitly. © 1999 American Institute of Physics.
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    Journal of Applied Physics 86 (1999), S. 4225-4231 
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    Topics: Physics
    Notes: Early hydration (up to four weeks) of five ordinary Portland cement pastes with different water-to-cement ratios (0.3, 0.4, 0.5, 0.6, and 1.0 wt) was investigated through positron annihilation lifetime spectroscopy. Measurements were performed at four different hydration times (1 day and 1, 2, and 4 weeks) and compared with results obtained from thermogravimetric analyses. Deconvolution of positron spectra allowed us to separate orthopositronium annihilations in the evacuated gel pores from those in the pores containing water, and therefore, to monitor the pores' evolution with aging time. It is found that the concentration of gel pores increases with aging time, as well as by increasing the content of water in the paste; on the other hand, the typical sizes of the pores do not show significant variations, either with aging time or with the water-to-cement ratio.© 1999 American Institute of Physics.
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    Journal of Applied Physics 86 (1999), S. 4734-4739 
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    Topics: Physics
    Notes: Spin-polarized intersubband lasers based on optically pumped type-II antimonide quantum wells in a magnetic field are proposed. Complete discretization of the electron energy spectrum is predicted to extend the electron lifetime considerably. Continuous-wave room-temperature operation is projected for both interband and intersubband pumping configurations lasing at λ=16–24 μm. Furthermore, the parasitic capacitances associated with electrical injection are eliminated, and the large differential gain and fast intrinsic time scale should give modulation bandwidths in excess of 100 GHz. © 1999 American Institute of Physics.
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    Journal of Applied Physics 86 (1999), S. 4772-4779 
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    Topics: Physics
    Notes: This article deals with ion behavior in small open-ended magnetic devices, the electron cyclotron resonance ion sources (ECRIS) that were developed for multicharged ion production. The ECRIS are basically ECR-heated plasma confinement machines with hot electrons and cold ions. The main parameters of the ion population in ECRIS plasmas are successively analyzed: temperature, collisions, losses, confinement times, followed by the gas mixing effect, a specific technique to improve the performance as an ion source. A series of experiments is described for the systematic analysis of this effect. It is experimentally shown that high charge state optimization by gas mixing results from an ion confinement time improvement due to ion cooling, and relies on a compromise between three criteria, ion losses, mass effect, and ionization rates. © 1999 American Institute of Physics.
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    Journal of Applied Physics 86 (1999), S. 4786-4791 
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    Topics: Physics
    Notes: An axial profile of the quasineutral plasma jet exhaust from a Hall thruster is studied. The plasma jet expansion is modeled using the sourceless steady-state hydrodynamic equations. It is considered that the plasma jet has a conical shape with a half angle of about 40°. The magnetic field surrounding the Hall thruster exit is included in the calculation. It is found that a magnetic field may significantly affect the axial profile of the plasma potential. For instance, in the case of zero magnetic field, the plasma potential is about −10 V at 1 m from the thruster exit, while in the case of a 0.1 T magnetic field, the plasma has a potential of about +25 V. Results predicted by the model are found to be in good agreement with experimental data for three different Hall thruster designs. © 1999 American Institute of Physics.
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    Journal of Applied Physics 86 (1999), S. 4322-4325 
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    Topics: Physics
    Notes: The kinetics changes in the growth of GaN induced by the presence of In segregated on the surface have been investigated in situ by using reflection high energy electron diffraction intensity oscillations. Two types of surfaces have been studied, namely, Ga-polar (0001) wurtzite, and (001) zinc blende. It has been found that In influenced both Ga and N surface kinetics, leading to a change in the growth rate associated with a change in the amount of Ga and N effectively available for the GaN growth. © 1999 American Institute of Physics.
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    Journal of Applied Physics 86 (1999), S. 4316-4321 
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    Topics: Physics
    Notes: Silicon dioxide (SiO2)/silicon carbide (SiC) structures annealed in nitric oxide (NO) and argon gas ambiences were investigated using x-ray photoelectron spectroscopy (XPS). The XPS depth profile analysis shows a nitrogen pileup of 1.6 at. % close to the NO annealed SiO2/SiC interface. The results of Si 2p, C 1s, O 1s, and N 1s core-level spectra are presented in detail to demonstrate significant differences between NO and Ar annealed samples. A SiO2/SiC interface with complex intermediate oxide/carbon states is found in the case of the Ar annealed sample, while the NO annealed SiO2/SiC interface is free of these compounds. The Si 2p spectrum of the Ar annealed sample is much broader than that of the NO annealed sample and can be fitted with three peaks compared with the two peaks in the NO annealed sample, indicating a more complex interface in the Ar annealed sample. Also the O 1s spectrum of the NO annealed samples is narrow and symmetrical and can be fitted with only one peak whereas that of the Ar annealed sample is broad and asymmetrical and is fitted with two peaks. It is evident that the Ar annealed sample contains some structural defects at the interface, which have been removed from the interface by NO annealing as shown by O 1s spectra. The C 1s spectra at the interface reveal the subtle difference between NO and Ar annealed samples. An additional peak representing the interface oxide/carbon species is observed in the Ar annealed sample. At the interface, the N 1s spectrum is symmetrical and can be fitted with one peak, representing the strong Si(Triple Bond)N bond. However, the N 1s and C 1s XPS spectra acquired in the bulk of the dielectric showed not only the Si(Triple Bond)N bond but also a trace amount of the N–C bond. © 1999 American Institute of Physics.
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    Journal of Applied Physics 86 (1999), S. 4333-4340 
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    Topics: Physics
    Notes: The sheet carrier concentration (Ns) of channel layers in modulation-doped InAlAs/InGaAs heterostructure field-effect transistor (HFET) structures with n+InGaAs contact layers has been successfully and nondestructively determined using the room-temperature photoluminescence (PL) method. It is found that the spectral energy width between the maximum position of the main PL peak around 0.8 eV and the half-maximum position on the higher energy side has a good positive linear correlation with the Ns of the channel measured by the van der Pauw method. The scattering of the data is less than ±3×1011 cm−2. The determination of Ns is effective even if the HFET structures have not only n+InGaAs contact layers but also layers for InAlAs Schottky level-shift diodes. From a comparison with low-temperature PL spectra, the main PL peak is attributed to the e2h transition in the quantum well of the channel. It is considered that the slope of the peak stretches further to the high energy as the Fermi energy in the channel become higher, i.e., as the Ns becomes larger. © 1999 American Institute of Physics.
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    Journal of Applied Physics 86 (1999), S. 4348-4353 
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    Topics: Physics
    Notes: Photoluminescence (PL) and Zeeman effect measurements in near-infrared luminescence bands in Cr-doped 4H and 6H SiC are presented. The PL spectrum consists of two no-phonon lines (NPLs) at 1.1583 and 1.1898 eV in 4H SiC and three NPLs at 1.1556, 1.1797, and 1.1886 eV in 6H SiC. The observed Zeeman splittings and temperature dependence studies reveal the spin triplet of the ground state and the orbital doublet structure of the excited state of the Cr-related center. All the triplets have almost isotropic g values close to 2 with trigonal symmetry and small zero-field splitting values D. In contrast, the effective g values of the excited state of the center are very anisotropic with g(parallel) in the range of 0.22–0.64 and g⊥=0 for different NPLs in both polytypes. Based on the Zeeman results, the PL is attributed to the internal transition 1E(D)→3A2(F) within the d shell of a substitutional, neutral chromium (Cr4+) in the 3d2 electronic configuration. © 1999 American Institute of Physics.
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    Journal of Applied Physics 86 (1999), S. 4341-4347 
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    Topics: Physics
    Notes: We report the results of a series of synchrotron characterizations of two epitaxial GaAs detectors of active areas 2.22 mm2 and thicknesses 40 and 400 μm. In spite of an order of magnitude difference in depletion depths, the detectors were found to have comparable performances at ∼−40 °C, with energy resolutions of ∼1 keV full width at half maximum (FWHM) at 7 keV rising to ∼2 keV FWHM at 200 keV and noise floors in the range of 1–1.5 keV. At the lower energies, the energy resolution was dominated by leakage current and electromagnetic pickup. At the highest energies, however, the measured resolutions appear to approach the expected Fano limit; e.g., ∼950 eV at 200 keV. Both detectors were remarkably linear, with average rms nonlinearities of 0.2% over the energy range of 10–60 keV. By raster scanning the active areas with 20×20 μm2 monoenergetic photon beams, it was found that the nonuniformity in the spatial response of both detectors was less than 1% and independent of energy. The material used to fabricate the detector is extremely pure. For example, low temperature photoluminescence measurements indicate that the density of the As antisite defect (EL2) is of the order of 1012 cm−3, which is ∼2–3 orders of magnitude lower than that generally reported. This indirect measurement of material purity is confirmed by Monte Carlo simulations of the detector x-ray response, which show that in order to reproduce the observed energy-loss spectra, electron and hole trapping cross-section/density products must be (very-much-less-than)1 cm−1. © 1999 American Institute of Physics.
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    Journal of Applied Physics 86 (1999), S. 4354-4359 
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    Topics: Physics
    Notes: CuInSe2 (CIS) films with Cu/In ratios of γ=0.82–1.79 have been grown on a GaAs (001) substrate by molecular beam epitaxy. Piezoelectric photoacoustic (PPA) measurements were carried out from liquid helium to room temperature to investigate nonradiative carrier recombination processes in comparison with photoluminescence (PL) measurements which directly detected radiative carrier recombination processes. Three PPA signal peaks which corresponded to band gap energies of the CIS (AB and C bands) and the GaAs substrate, were clearly obtained between liquid helium and room temperatures. A free-exciton emission line was observed up to 200 K in the PL spectra. Two additional peaks on intrinsic defects which are Cu vacancy (VCu) and interstitial In (Ini) were observed in the In-rich CIS samples. The PPA measurements were useful in investigating the defect levels and the band gap energy in the CIS/GaAs thin films. © 1999 American Institute of Physics.
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    Journal of Applied Physics 86 (1999), S. 4360-4364 
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    Topics: Physics
    Notes: The electro-optical properties of (Zn,Cd)Se/Zn(S,Se) quantum well structures grown on GaAs substrates have been studied with differential electroabsorption spectroscopy at room temperature and compared to model calculations. (Zn,Cd)Se wells of 20, 10, and 4×5 nm are investigated, corresponding to well widths of four, two, and one times the exciton Bohr radius in this material system, respectively. We observe the quantum confined Stark effect for the 4×5 nm sample and find a Stark shift of 18 meV in the heavy-hole exciton peak for an electric field change from 82 to 175 kV/cm. In contrast, the 10 nm sample shows a rather weak and more Franz–Keldysh-like signal. We show that the 20-nm-thick quantum-well sample behaves like bulk material, i.e., the electro-absorption signal is well described by Franz–Keldysh oscillations. © 1999 American Institute of Physics.
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    Journal of Applied Physics 86 (1999), S. 4365-4368 
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    Topics: Physics
    Notes: The noncollinear interaction between guided optical waves and magnetostatic waves under inclined bias magnetic field is studied in detail. The diffraction efficiency (DE) and the mode-conversion efficiency (MCE) of guided optical waves with magnetostatic forward volume waves in the bismuth-doped yttrium–iron–garnet (Bi-doped YIG) waveguide are calculated numerically. The calculation results indicate that the DE and the MCE are different in physical conception and the DE is not equal to the MCE in magnitude under inclined bias magnetic field. The DE may be greatly increased by using an appropriately inclined bias magnetic field, which has been experimentally confirmed in a pure YIG waveguide. By using an inclined bias magnetic field and the Bi-doped YIG waveguide, under the phase-matching conditions, the maximum DE can come up to 79.5% or more. © 1999 American Institute of Physics.
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    Journal of Applied Physics 86 (1999), S. 4387-4389 
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    Topics: Physics
    Notes: The topology of self-assembled InAs/GaAs quantum dots was studied by resonant Raman scattering caused by the interface modes localized near the edges of the dots. Evidences were found that on both sides of the InAs layer containing the dots, their topologies show some resemblances. In addition, in the multilayered systems the evidence of the coalescence of the dots (which form vertical columns) in neighbor layers separated by the distance smaller than 25 monolayers was obtained. © 1999 American Institute of Physics.
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    Journal of Applied Physics 86 (1999), S. 5157-5163 
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    Topics: Physics
    Notes: Hysteresis loops in SmCo5−xCux as-cast and annealed magnets (1〈x≤3) were measured at room temperature using a pulsed-field magnetometer and a static vibrating sample magnetometer. At field sweeps between 2 and 17 (GA/m)/s a giant—in this field range nearly constant—magnetic viscosity Sv was obtained. The viscosity is approximately proportional to the Cu concentration and to the coercive field. A heat treatment at 1273 K for three weeks changes the microstructure and enhances strongly the intensity and the time dependence of the coercivity. The decay of the inverse of the coercive field Hc with time follows a simple ln(t) relation between 10−5 and 10 s. Data analysis allows a density of stacking faults N to be extracted for each sample. Sv (and Hc) increases with N which increases with x. © 1999 American Institute of Physics.
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    Journal of Applied Physics 86 (1999), S. 5169-5174 
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    Topics: Physics
    Notes: We have investigated the unidirectional exchange anisotropy between a ferromagnetic (FM) Ni81Fe19 film and a disordered antiferromagnetic (AF) CrMnPtx (x=3, 6, or 9) film. The angular dependence of the exchange coupling in these FM/AF bilayers has been measured. We show that the complex angular dependence of this exchange coupling can be understood by a simple Stoner–Wohlfarth model involving only a uniaxial anisotropy and a unidirectional exchange coupling. Numerical results are in excellent agreement with the experimental data. © 1999 American Institute of Physics.
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    Journal of Applied Physics 86 (1999), S. 5203-5206 
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    Topics: Physics
    Notes: Degradation mechanisms contributing to increased 1/f noise of n-channel metaloxide-semiconductor field-effect transistors (n-MOSFETs) after different hot-carrier stresses are investigated. It is demonstrated that for any hot-carrier stress, the stress-induced enhancement of 1/f noise is mainly attributed to increased carrier-number fluctuation arising from created oxide traps, while enhanced surface-mobility fluctuation associated with electron trapping at preexisting and generated fast interface states and near-interface oxide traps is also responsible under maximum substrate- and gate-current stresses. Besides thermal-oxide n-MOSFETs, nitrided-oxide devices are also used to further support the above analysis. © 1999 American Institute of Physics.
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    Journal of Applied Physics 86 (1999), S. 5215-5231 
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    Topics: Physics
    Notes: A detailed dynamical analysis of an all solid-state THz source is given. This is based on the polarization-induced autonomous oscillation in resonant tunneling heterostructure with staggered band-gap alignment. The physical model consists of the following processes: (a) Generation by Zener tunneling of holes trapped in the barrier and electrons drifting in the depletion layer of the drain, whose rate decreases with the polarization between the barrier and quantum well. (b) Stimulated generation of barrier-well polarization. (c) Nonradiative decay of barrier-well polarization through barrier-hole recombination and quantum-well electron discharge. It is shown that a limit cycle oscillation of the barrier-well polarization and trapped-hole charge in the barrier can occur which induce THz oscillations in the resonant tunneling current across the device. The time-averaged results agree with the measured current–voltage characteristic of AlGaSb/InAs/AlGaSb staggered band-gap double-barrier structure. In particular, the measured smaller current offset at forward bias compared to that of reverse bias in the current–voltage hysteresis loop is predicted by our physical model and limit cycle analysis. Thus, we have experimental evidence indicating the correctness of our approach and the promising potential of this device as a novel all solid-state THz source. © 1999 American Institute of Physics.
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    Journal of Applied Physics 86 (1999), S. 5245-5248 
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    Topics: Physics
    Notes: In this article we show that in the atomic force microscopy experiments performed on a metallic surface, there is always a long range electrostatic force in addition to the van der Waals forces. This capacitive force is due to the contact potential between the tip and the surface and exists even without external applied potential. We have calculated this capacitive force for a real geometry of the tip–sample system and compared it to the van der Waals force calculated for the same geometry. We conclude that the electrostatic force is always dominant for a tip–surface distance larger than half of the tip radius of curvature. © 1999 American Institute of Physics.
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    Journal of Applied Physics 86 (1999), S. 5256-5262 
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    Topics: Physics
    Notes: Ion channeling in the low-keV energy range is demonstrated by means of the technique of time-of-flight scattering and recoiling spectrometry. The predictions of the Lindhard string model of ion channeling are compared with the experimental findings. Qualitative agreement was obtained between the experimentally measured critical angles and the predictions of the model. The technique of low-energy ion channeling is shown to be capable of quantitatively probing the positions of light elements on heavy substrates with analysis by simple geometrical constructs. Classical ion trajectory simulations using the scattering and recoiling imaging code were used to observe the details of the ion trajectories. Quantitative analysis of the Pt(111)-(1×1)-H surface using 5 keV Ne+ shows that the hydrogen atoms preferentially populate the threefold fcc sites with a height of 0.9±0.1 Å above the first-layer Pt atoms and a corresponding Pt–H bond length of 1.9±0.1 Å. © 1999 American Institute of Physics.
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    Journal of Applied Physics 86 (1999), S. 5270-5273 
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    Topics: Physics
    Notes: Thermal annealing effects on optical and structural properties of Ge-doped SiO2 thin films prepared by the chemical vapor deposition and flame hydrolysis deposition methods were investigated. The thin film prepared by the former method showed inhomogeneous Ge distribution, and Ge oxygen-deficient centers were observed. When it was thermally annealed at temperatures higher than 800 °C, the Ge distribution became uniform. The concentration of oxygen deficient centers was found to decrease with the thermal annealing in an O2 atmosphere, while it increased with the thermal annealing at 1000 °C in N2. This suggests that improvement of the film quality can be achieved by thermal annealing. On the other hand, neither inhomogeneity of Ge distribution nor the appearance of oxygen deficient centers was observed in the film prepared by the latter method, and its film quality was scarcely affected by the thermal annealing. © 1999 American Institute of Physics.
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    Journal of Applied Physics 86 (1999), S. 5279-5285 
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    Topics: Physics
    Notes: Synthesis of ultrafine nanosize powders by ion beam evaporation (IBE) has been studied numerically and experimentally. Theoretical models have been developed, which involve such physical processes as beam-target interaction, plasma expansion, and the synthesis of powders. The macroscopic properties of the ultrafine powders have been predicted. As an application of our models, the macroscopic properties of AlN powders synthesized by IBE with an AlN target have been predicted. The energy density, pulse width, and spot size of the ion beam are 20 J/cm2, 70 ns, and 1 cm2, respectively. The main results have shown that the particle size distribution is log normal and that 70% of all particles exist between 20 and 40 nm. The average diameter and the specific surface area are ∼30 nm and ∼50 m2/g, respectively. Experimentally, the ultrafine AlN powders have been successfully synthesized by IBE, which has been verified by x-ray diffraction and transmission electron diffraction. Furthermore, particle size distributions have been obtained by transmission electron microscopy. The experimental results are found to be in a reasonable agreement with the numerical studies. © 1999 American Institute of Physics.
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    Journal of Applied Physics 86 (1999), S. 4711-4712 
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    Topics: Physics
    Notes: This response recalls the bases of the Monte Carlo methods of gas flow simulations. Basic points and explicit parameters used in both the DSMC method and the method of random trajectories are underlined. Some clarifications are made on the confusion made by the author of the comment on this subject. The justification of the validity of the method is recalled, as already made in the original article. © 1999 American Institute of Physics.
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    Journal of Applied Physics 86 (1999), S. 3512-3515 
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    Topics: Physics
    Notes: A solid state broad band amplifier of terahertz radiation (1.5–4 THz), based on intersubband transitions of hot holes in p-Ge is demonstrated. The gain is investigated as a function of applied magnetic and electric fields by transmission measurements using a laser system with two p-Ge active crystals, when one operates as an oscillator and one as an amplifier. A peak gain higher than usually reported for p-Ge lasers has been achieved using time separated excitation of the oscillator and amplifier. Distinct differences in gain dependence on applied fields are noted between low- and high-frequency modes of p-Ge laser operation. © 1999 American Institute of Physics.
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    Journal of Applied Physics 86 (1999), S. 3525-3529 
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    Topics: Physics
    Notes: The use of low-energy ((approximate)15 keV) electron beams for pumping laser systems in dense gases with high specific power deposition is described. Thin (300 nm) SiNx ceramic foils used as entrance window in a transverse geometry for the electron beam allows pressure differentials of several atmospheres with low percentage energy loss in transmission. The 1.73 μm XeI (5d[3/2]1–6p[5/2]2) infrared laser was used for a first demonstration of this concept. The laser operated between 130 and 650 mbar. A threshold pumping power of 5.3 W and a maximum output power of 6 mW were observed. The system can be scaled to high pumping power ((approximate)MW/cm3) and short wavelength. © 1999 American Institute of Physics.
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    Journal of Applied Physics 86 (1999), S. 3543-3549 
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    Topics: Physics
    Notes: Growth processes of particles in a cluster-size range below a few nm in size in low pressure and low power SiH4 rf discharges are studied using the new method, in which the threshold photoemission method is coupled with the microwave interferometry, for measurements of their size and density. The density of particles is above 1010 cm−3 and much exceeds that of positive ions, the result of which shows that most of them are neutral. The particles grow mainly around the plasma/sheath boundary near the powered electrode and their size growth rate is 3.4–4.4 nm/s, being much higher than a film growth rate of 0.064–0.12 nm/s. These features strongly indicate that their growth is due to deposition of polymerized species, originated from short lifetime SiH2 radicals, on them, while coagulation between particles becomes appreciable after a time when their density reaches about 1011 cm−3. Moreover, the pulse modulation of rf discharge is found to be effective in reducing the density of cluster-size particles. The reduction can be explained by a model taking account of diffusion of the polymerized species through the radical production region, where the particles nucleate and grow. © 1999 American Institute of Physics.
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    Notes: Molybdenum (Mo) doped vanadium dioxide thin films were synthesized using a Mo striped vanadium (V) target during pulsed laser ablation process. The film structure was characterized by high resolution x-ray diffraction, x-ray rocking curve and Rutherford backscattering/channeling measurements. The results show that the full width at half magnitude of the x-ray rocking curve is as narrow as 0.0074°, comparable to that of the (0001) sapphire substrate, 0.0042°, in this study. The ratio of the aligned-to-random backscattered yield reaches 5%, implying that the growth is that of the single crystalline epitaxy. The result of angular scans for both V and Mo atomic channelings reveals that Mo atoms successfully take sites of the V sublattice as a substitutional dopant. It has been noted that the degradation of the phase transition properties of the film upon doping is closely related to the conductivity in the semiconductor phase. © 1999 American Institute of Physics.
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    Journal of Applied Physics 86 (1999), S. 4091-4095 
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    Topics: Physics
    Notes: We have modeled the switching behavior of a twisted nematic cell using the one-dimensional Ericksen–Leslie equations of nematodynamics. We compare the modeling results with experimental data on transmission versus time. Excellent agreement between experiment and model is achieved at all voltages and viewing angles. To achieve this agreement, only two viscosity parameters are required; these are combinations of the Leslie viscosity coefficients, namely, α3−α2 (the rotational viscosity) and α4+α5. A fast and stable adaptive numerical algorithm, based on an effective viscosity parameter, is developed for solving the equations of motion. The viscosity parameters obtained from fitting the flow experiments are in good agreement with those obtained from dynamic light-scattering measurements. © 1999 American Institute of Physics.
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    Journal of Applied Physics 86 (1999), S. 4076-4084 
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    Topics: Physics
    Notes: Vertical stacking of organic light emitting devices (OLEDs) that emit the three primary colors is shown to be a means for achieving efficient and bright full-color displays. In Paper I, we addressed stacked OLED (SOLED) design and fabrication principles to optimize emission colors, operating voltage, and efficiency. Here, we present results on two different (metal-containing and metal-free cathode) SOLED structures that exhibit performance suitable for many full-color display applications. The operating voltages at 10 mA/cm2 (corresponding to video display brightnesses) are 6.8, 8.5, and 12.1 V for the red (R), green (G), and blue (B) elements of the metal-containing SOLED, respectively. The respective subpixel luminous efficiencies are 0.53, 1.44, and 1.52 cd/A, and the Commission Internationale de L'Éclairage (CIE) chromaticity coordinates are (0.72, 0.28), (0.42, 0.56), and (0.20, 0.22). In the high transparency metal-free SOLED, an insulating layer was inserted between the two upper subpixels to allow for independent grounding of all color emitters in the stack. At operating voltages of 12–14 V, video display brightnesses were achieved with luminous efficiencies of 0.35, 1.36, and 1.05 cd/A for the R, G, and B subpixels, respectively. The respective CIE coordinates for R, G, and B emissions are (0.72, 0.28), (0.26, 0.63), and (0.17, 0.28) in the normal viewing direction, shifting inperceptibly as the viewing angle is increased to as large as 60°. Finally, we discuss addressing schemes of SOLED displays, and compare them with other strategies for achieving full-color, OLED-based displays. © 1999 American Institute of Physics.
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    Journal of Applied Physics 86 (1999), S. 4096-4099 
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    Topics: Physics
    Notes: The polarization state of a vertical cavity surface emitting laser (VCSEL) output was driven by means of optical injection from another VCSEL. The bistability inherent to polarization locking allowed us to generate a memory effect. The control parameter was the modulated bias current of the maser laser and effects were shown to exist at frequencies up to 1 GHz. © 1999 American Institute of Physics.
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    Journal of Applied Physics 86 (1999), S. 4107-4117 
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    Topics: Physics
    Notes: We present a detailed study of the recently discovered modulation at frequencies of hundreds of MHz of an electron beam produced by a plasma cathode. The plasma cathode consists of a ferroelectric disk sample [BaTiO3 or Pb(Zr, Ti)O3] that is placed in a cylindrical metal box having an output window covered by a grid. The plasma is prepared by an incomplete discharge that was ignited by a few kV driving pulse applied across the ferroelectric disk. It was shown that the current modulation appears only when the driving pulse is applied to the front gridded electrode of the ferroelectric sample and the solid rear electrode is grounded. The modulation spectrum is quite narrow (≤3%), with harmonics at frequencies up to a few GHz. The basic frequency of modulation was found to be dependent on the length of the feed cable to the sample. Investigation of the plasma and the beam modulation properties and their dependence on the experimental parameters is presented. The results indicate the formation of a plasma at the vicinity of the front electrode of the ferroelectric sample during the modulation. The results are discussed within the frame of electrons oscillating in the potential well created by the positively charged plasma having feedback coupling with the input cable. © 1999 American Institute of Physics.
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    Journal of Applied Physics 86 (1999), S. 4861-4864 
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    Topics: Physics
    Notes: Migration of vacancies in crystalline, n-type silicon at room temperature from Ge+-implanted (150 keV, 5×109–1×1011 cm−2) surface layers was studied by tracing the presence of P–V pairs (E centers) in the underlying layer using deep level transient spectroscopy (DLTS). Under the conditions we have examined, the vacancies migrate to a maximum depth of about 1 μm and at least one vacancy per implanted Ge ion migrates into the silicon crystal. The annealing of the E centers is accompanied, in an almost one-to-one fashion, by the appearance of a new DLTS line corresponding to a level at EC−Et(approximate)0.15 eV that has donor character. It is argued that the center associated with this line is most probably the P2–V complex; it anneals at about 550 K. A lower limit of the RT-diffusion coefficient of the doubly charged, negative vacancy is estimated to be 4×10−11 cm2/s. © 1999 American Institute of Physics.
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    Journal of Applied Physics 86 (1999), S. 3751-3757 
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    Topics: Physics
    Notes: Two different types of structure called X1 and X2 are existing in Y2SiO5 at normal conditions. In X1 type, Y3+ ions occupy two sites where they are surrounded respectively by nine and seven oxygen ions, while in X2 structure, only six and seven oxygen ions are involved. Nanometric scale X1-Y2SiO5 crystals were prepared by sol-gel method with particle size around 50 nm. Site selective excitation at low temperature has shown four different luminescent centers. Two of them belong to Eu3+ embedded in X1-Y2SiO5, the other two are attributed to Y2O3:Eu phase and to a particular site on the surface. The occurrence of the latter site may be related to the nanometric size of the sample. A pronounced excitation energy transfer from site 2 to site 1 was also observed on excitation spectra. The energy transfer rate increases rapidly with increasing Eu3+ concentration and for x=0.7 in Y2−xSiO5:Eux, no fluorescence takes place in site 2 at 15 K. The lifetimes of the 5D0 levels of Eu3+ in the two sites were measured as a function of Eu3+ concentration. The results have shown that the lifetime of the 5D0 level of Eu3+ in site 2 decreases with increasing Eu3+ concentration. The energy transfer rate dependence upon temperature was studied in detail and compared to a theoretical simulation. © 1999 American Institute of Physics.
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    Journal of Applied Physics 86 (1999), S. 3787-3791 
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    Topics: Physics
    Notes: We report on the observation of quantized jumps due to single-carrier trapping and detrapping at defect states in silicon photoconductors of 103 μm3 in volume. A specifically designed electrical test structure in a low-doped (2×1014 cm−3) silicon crystal was fabricated. It consists in four substrate resistances connected in a Wheatstone bridge. After the exposure to light, the bridge offset voltage recovers its equilibrium value with steps of 5–10 μV, corresponding to the emission or capture of a single carrier. Such structures also display random telegraph signals in the dark, with steps of similar amplitude. This behavior is observed with structures processed on Czochralski-grown substrates and not with those processed on float-zone substrates. Simple calculations based on quantized free carrier concentration variations corroborate the above measurements. © 1999 American Institute of Physics.
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    Journal of Applied Physics 86 (1999), S. 3822-3825 
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    Topics: Physics
    Notes: Electroabsorption has been investigated in semi-insulating asymmetric GaAs/AlGaAs double quantum wells presenting high linear Stark responses, adequate for photorefractive applications. We have used the envelope function approximation to calculate the linear Stark shifts of the energy levels and select a suitable structure for the experimental study. The experimental data indicate that the response to the applied field critically depends on a complicated interplay of effects that compete or cooperate to suppress or enhance the electroabsorption. For positive field polarity, the competing contributions of the overlapping e1–hh1 and e1–hh2 transitions partially cancel the electroabsorption despite large linear Stark shifts. On the other hand, small negative fields induce large electroabsorption because the Stark shifts of the two transitions have opposite signs. © 1999 American Institute of Physics.
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    Journal of Applied Physics 86 (1999), S. 3833-3843 
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    Topics: Physics
    Notes: A self-consistent, two-dimensional, time-dependent, drift-diffusion model is developed to simulate the response of high power photoconductive switches. Effects of spatial inhomogeneities associated with the contact barrier potential are incorporated and shown to foster filamentation. Results of the dark current match the available experiment data. Persistent photoconductivity is shown to arise at a high bias even under the conditions of spatial uniformity. Filamentary currents require an inherent spatial inhomogeneity, and are more likely to occur for low optical excitation. Under strong uniform illumination, the spatial nonuniformities were quenched as a result of a polarization-induced collapse in the internal fields. However, strong electric fields resulting at the contacts create a bipolar plasma, and hence, a virtual "double injection." © 1999 American Institute of Physics.
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    Journal of Applied Physics 86 (1999), S. 4477-4482 
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    Topics: Physics
    Notes: We have calculated the effect of an electric field applied along the direction of carrier confinement on the exciton linewidth due to the scattering of excitons by ionized impurities in semiconducting quantum well structures. The contributions to the linewidth due to the elastic and inelastic scattering of the excitons by the ionized impurities have both been taken into account. Both these contributions to the linewidth are found to increase with the applied electric field except for the narrowest wells. However, the linewidth is found to initially decrease with increasing well width for all electric fields and then increase again with increasing well widths for finite electric field for the case where the exciton is scattered elastically. The minimum in the linewidth as a function of well width shifts to smaller well widths with increasing electric field. In the absence of an electric field, the linewidth continues to decrease with increasing well width. When the exciton is ionized as a result of the scattering, the linewidth increases with well width for all nonzero electric fields. However, in the absence of the electric field, the linewidth decreases with increasing well width. This reflects the effect of decreasing confinement on the scattering by ionized impurities. In the case of elastic scattering of the exciton by the ionized impurities, the linewidth has a maximum as a function of the exciton energy with the maximum shifting to lower energies as the well width decreases. For scattering which results in the ionization of the exciton, there is a threshold in the linewidth as a function of the exciton's center of mass energy with the threshold being larger for smaller well widths. The contribution to the linewidth due to elastic scattering of the exciton is many orders of magnitude larger than that due to scattering in which the exciton is ionized. © 1999 American Institute of Physics.
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    Journal of Applied Physics 86 (1999), S. 4498-4508 
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    Topics: Physics
    Notes: Laser-induced surface deformation and surface relief grating formation at different intensity levels on azobenzene-functionalized polymer films were investigated. The surface deformation profile induced by a Gaussian laser beam at low intensities reveals strong polarization dependence and establishes that an optical-field component in the direction of the optical-field gradient is essential for this deformation process. A theoretical analysis based on the optical-field gradient force model is presented to account for the deformation behavior at low intensities. In the higher-intensity regime, however, a different mechanism is found to dominate the surface deformation process. Simultaneous formation of two different types of topographic gratings is observed in a two-beam interference experiment. The phase relationship between these surface relief gratings and the interference intensity pattern was deduced based on the results from the single-beam experiments. The erasing behaviors of the two distinct surface relief gratings were experimentally investigated to highlight the two mechanisms involved in these grating recordings. © 1999 American Institute of Physics.
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    Journal of Applied Physics 86 (1999), S. 4515-4519 
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    Topics: Physics
    Notes: The four organic–organic heterointerfaces formed by depositing the organic semiconductor bathocuproine on tris(8-hydroxy-quinoline)aluminum (Alq3), N,N′-diphenyl-N,N′-bis(1-naphthyl)-1,1′ biphenyl-4,4″ diamine (α-NPD), 4,4′-N,N′-dicarbazolyl-biphenyl (CBP), and copper phthalocyanine (CuPc) have been studied using ultraviolet photoelectron spectroscopy. The relative positions of the vacuum levels and highest occupied molecular orbital levels of the organics were measured at each interface. Within our experimental uncertainty of 100 meV, the vacuum levels were found to align at all four interfaces. © 1999 American Institute of Physics.
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    Journal of Applied Physics 86 (1999), S. 4997-5003 
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    Topics: Physics
    Notes: GaAs when exposed to a 7 V anodic bias in aqueous HCl, forms pitted structures from which visible photoluminescence has been observed. Previous work in our laboratory identified the source of the luminescence to be arsenic oxide microcrystals, formed during the electrochemical oxidation, which evolve in composition and morphology during the course of the anodic processing. The density and size of pits is dependent on the solution conditions as well as the applied potential program (stepped vs swept to 7 V. At early times (t〈30 min) the pits are composed of a mixture of small (∼1 μm) and larger (10's of μm) faceted microcrystals identified by x-ray photoelectron spectroscopy and energy-dispersive x-ray analysis to be a combination of As(III) and As(V) oxides. At longer times As(III) oxides predominate, and the smaller microcrystals are no longer observed, suggesting that the smaller microcrystals are As(V) oxide, and that they evolve chemically into As(III) oxide over the course of the oxidation. A suitable reaction pathway which explains the observed predominance of As(III) species is suggested. The luminescence properties of these electrochemically produced structures were investigated by near-field excitation. The luminescent properties evolve in parallel with the morphology and composition although the form of the spectrum is invariant in time and consistent with that obtained from bulk As2O3 and As2O5. The similarity of emission obtained from the two types of microcrystals suggests an impurity-related origin. © 1999 American Institute of Physics.
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    Journal of Applied Physics 86 (1999), S. 5026-5035 
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    Topics: Physics
    Notes: The energy resolution of a method for measuring localized-state distributions in amorphous and polymeric semiconductors has been improved in terms of Tikhonov regularization. The method is based on the analysis of transient photoconductivity data using Laplace transforms, and is valid for both pre- and postmonomolecular recombination regimes of the transient photoconductivity. The improvement of the energy resolution is shown using transient photoconductivity data numerically generated from model localized-state distributions appropriate for the materials. In addition, the measurement of localized-state distributions from time-of-flight transient photocurrents is examined. The applicability of the method with improved energy resolution is demonstrated for undoped hydrogenated amorphous silicon, poly(para-phenylene vinylene) and poly(methylphenylsilane). © 1999 American Institute of Physics.
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    Journal of Applied Physics 86 (1999), S. 4004-4007 
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    Source: AIP Digital Archive
    Topics: Physics
    Notes: The oxidation kinetics of silicon in inductively coupled oxygen plasma (ICP) was studied at temperatures ranging from 350 to 450 °C. The oxide growth kinetics was described by a linear-parabolic growth law, with a rapid initial growth and a negative linear-rate constant. Under oxygen pressure of 10 mTorr, the initial oxide growth at 350 °C (thickness below 25 nm) was faster than at 400 °C. An analysis of transverse-optical mode frequencies and etch rates indicated that the density of the surface oxide was lower than that of the bulk oxide. The oxidation kinetics was explained qualitatively by assuming that the ICP oxide consisted of a surface layer with a larger diffusion coefficient and a bulk layer with a smaller diffusion coefficient. On the other hand, the ICP oxidation of silicon with a thin chemical oxide showed a positive linear-rate constant and no surface layer effect, supporting the fact that the oxide grown by the ICP oxidation has a low-density surface layer with a larger diffusion coefficient. © 1999 American Institute of Physics.
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  • 91
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 86 (1999), S. 4040-4042 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We propose evaporative induction heating as a method for the reliable production of coatings for glass cells suitable for the optical pumping and storage of hyperpolarized xenon. The long spin-lattice relaxation times of hyperpolarized xenon-129 contained in cells coated with polyethylene or dotriacontane showed that high quality coatings could be prepared this way. Measurements on cells coated with deuteriated versions of these compounds showed that the expected improvement in performance with isotopic substitution did not occur. This leads to some questions about the level of understanding of wall-induced relaxation in polarization cells. © 1999 American Institute of Physics.
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  • 92
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 86 (1999), S. 4049-4051 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Low energy ion-induced secondary electron emission from the surface of thin (500–5000 Å) polycrystalline MgO films has been investigated with various noble gas ions at energies ranging from 45 to 300 eV. The dependence of secondary electron emission coefficient γi on the type and energy of ions is reported and interpreted in terms of electron ejection mechanisms. As-deposited MgO films showed an initial fluctuation in the secondary emission current, which upon annealing or after a certain ion bombardment time irreversibly disappeared. © 1999 American Institute of Physics.
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  • 93
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 86 (1999), S. 4052-4054 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The high-temperature dielectric properties of thin-film AlN that were pulsed-laser deposited on a heavily doped n-type 6H–SiC substrate are investigated from 25 to 450 °C. Capacitor leakage current densities of low 10−8 A/cm2 at 25 °C and mid 10−3 A/cm2 at 450 °C are reported for a 1.7 MV/cm dielectric field. The primary high-temperature leakage mechanism appears to be Schottky emission with a zero-field barrier height of 1.76 eV. A dielectric strength in excess of 1.7 MV/cm at 450 °C is reported. © 1999 American Institute of Physics.
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  • 94
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 86 (1999), S. 2945-2952 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We present high accuracy measurements of gain, loss, and transparency energy in long-wavelength semiconductors based on a hybrid approach using the fundamental relationship between the gain and the spontaneous emission spectra. Independent measurements of optical gain, transparency energy, and loss show the accuracy and validity of this technique. These results are compared with those obtained by the non-Markovian gain model with many-body effects under the spontaneous emission transformation method. It is found that the hybrid approach for the gain spectrum alleviates many of the problems related to the poor signal to noise ratio in the amplified-spontaneous emission near and below the band edge. The theoretical spectra compare well with the measured spectra for both the transverse electric and transverse magnetic polarizations. © 1999 American Institute of Physics.
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  • 95
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 86 (1999), S. 2959-2966 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: This article describes the use of optical methods based on picosecond transient gratings to stimulate and detect ultrasonic acoustic modes in several important structures with dimensions less than ∼200 μm: single-mode optical fiber, cylindrical microcapillary tubes, and planar microfluidic networks. The measurements illuminate the characteristics and dispersion of acoustic modes—Rayleigh and Lamb-like modes and Scholte–Stoneley waves—in three-dimensional microsystems with feature sizes that are comparable to the modal wavelengths. The results demonstrate, for example, the ability to measure, rapidly and nondestructively, the mechanical characteristics of on-fiber metal and polymer coatings. They also illustrate real-time monitoring of the elastic and loss moduli, and thermal diffusivities of nanoliter volumes of material contained in planar microfluidic channels during the course of photochemical curing reactions. The techniques are potentially useful for applications ranging from characterization of high-frequency acoustic modes in optical fiber that may be relevant to new types of in-fiber acousto-optic filters and modulators, to detection in microfluidic total analysis systems. © 1999 American Institute of Physics.
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  • 96
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 86 (1999), S. 4713-4713 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: © 1999 American Institute of Physics.
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  • 97
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 86 (1999), S. 3508-3511 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Previous work has shown that when short-pitch cholesteric liquid crystals are aligned in cells with the helical axis in the plane of the substrate in a well-defined direction, then application of an electric field across the cells may result in microsecond in-plane switching due to the flexoelectric effect. Moreover, the response to the electric field is linear and temperature independent. Hence this device geometry has great potential since fast, temperature-independent switching with analogue gray scale may be realized. Up to now, however, the alignment of the helix in the plane of the substrate achieved, for example, by rubbed polyimide layers has been rather unstable, since it relaxes to a Grandjean texture in a time scale determined by the cell thickness. This time is generally of the order of minutes. Here we report a method for the attainment of stable anchoring of the unidirectional lying helix texture using periodic anchoring conditions. © 1999 American Institute of Physics.
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  • 98
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 86 (1999), S. 4709-4710 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: An attempt to use direct simulation Monte Carlo (DSMC) method for pulsed laser ablation at laser fluence as high as 17 J/cm2 is analyzed. Under these conditions, however, the evaporation flux is very high which results in a very high laser plume density. Therefore, both collision rate and collisional zone near the target are too large to effectively use a conventional DSMC technique whose possibilities are always limited by finite computer storage and available computation time. Nevertheless, the authors of the considered paper claim to propose a new approach to overcome the restrictions of DSMC. We found that the main idea of the approach is the plume reduction in space. However, according to the dimension theory, under this transformation one should preserve the Knudsen number, that defines the degree of rarefaction, and, hence, the number of cells to be used in DSMC. Therefore, the number density of the plume should be increased and particle collisions should be calculated with higher frequency than in the case without space reduction. In our opinion, this important point was neglected by the authors, the collision frequency was not increased, and the number of cells was not properly chosen. As a result, the proposed approach does not break the DSMC restrictions, and the results obtained do not correspond to the experiments with high evaporation flux. © 1999 American Institute of Physics.
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  • 99
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 86 (1999), S. 3694-3698 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: A theoretical investigation of plane-wave electromagnetic scattering in active dielectric sphere predicted the existence of anomalous resonances that occur at discrete wavelengths. These resonances may be understood from a leaky wave phase matching boundary conditions, in which the gain in the dielectric exactly makes up for the radiative loss of a mode. This results in a radiative mode that does not decay in time, therefore it is described as a lossless radiative mode. Experiments have been performed to verify the existence of these resonances. Optical pumping was used to provide the gain, and the threshold of each resonant mode was found to be a function of the dye concentration and the radius of the dielectric sphere. © 1999 American Institute of Physics.
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  • 100
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 86 (1999), S. 3714-3720 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: AlGaN/GaN quantum well (QW) structures are grown on c-plane sapphire substrates by molecular beam epitaxy. Control at the monolayer scale of the well thickness is achieved and sharp QW interfaces are demonstrated by the low photoluminescence linewidth. The QW transition energy as a function of the well width evidences a quantum-confined Stark effect due to the presence of a strong built-in electric field. Its origin is discussed in terms of piezoelectricity and spontaneous polarization. Its magnitude versus the Al mole fraction is determined. The role of the sample structure geometry on the electric field is exemplified by changing the thickness of the AlGaN barriers in multiple-QW structures. Straightforward electrostatic arguments well account for the overall trends of the electric-field variations. © 1999 American Institute of Physics.
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