ALBERT

Description: Energies, Vol. 11, Pages 44: Transient Stability Analysis of Islanded AC Microgrids with a Significant Share of Virtual Synchronous Generators Energies doi: 10.3390/en11010044 Authors: Chang Yuan Peilin Xie Dan Yang Xiangning Xiao As an advanced control method that could bring extra inertia and damping characteristics to inverter-based distributed generators, the virtual synchronous generator (VSG) has recently drawn considerable attention. VSGs are expected to enhance the frequency regulation capability of the local power grid, especially the AC microgrid in island mode. However, the cost of that performance promotion is potential instability. In this paper, the unstable phenomena of the islanded microgrid dominated by SGs and distributed generators (DSs) are addressed after mathematical modeling and detailed eigenvalue analyses respectively. The influence of VSG key parameters, e.g., virtual inertia, damping factor, and droop coefficient on system stability is investigated, and the corresponding mathematical calculation method of unstable region is obtained. The theoretical analysis is well supported by time domain simulation results. The predicted frequency oscillation suggests the consideration of stability constrain during the VSG parameters design procedure.

Description: Energies, Vol. 11, Pages 77: Anisotropy in Thermal Recovery of Oil Shale—Part 1: Thermal Conductivity, Wave Velocity and Crack Propagation Energies doi: 10.3390/en11010077 Authors: Guoying Wang Dong Yang Zhiqin Kang Jing Zhao In this paper, the evolution of thermal conductivity, wave velocity and microscopic crack propagation both parallel and perpendicular to the bedding plane in anisotropic rock oil shale were studied at temperatures ranging from room temperature to 600 °C. The results show that the thermal conductivity of the perpendicular to bedding direction (KPER) (PER: perpendicular to beeding direction), wave velocity of perpendicular to bedding diretion (VPER), thermal conduction coefficient of parallel to beeding direction (KPAR) and wave velocity of parallel to beeding direction (VPAR) (PAR: parallel to bedding direction) decreased with the increase in temperature, but the rates are different. KPER and VPER linearly decreased with increasing temperature from room temperature to 350 °C, with an obvious decrease at 400 °C corresponding to a large number of cracks generated along the bedding direction. KPER, VPER, KPAR and VPAR generally maintained fixed values from 500 °C to 600 °C. 400 °C has been identified as the threshold temperature for anisotropic evolution of oil shale thermal physics. In addition, the relationship between the thermal conductivity and wave velocity based on the anisotropy of oil shale was fitted using linear regression. The research in this paper can provide reference for the efficient thermal recovery of oil shale, thermal recovery of heavy oil reservoirs and the thermodynamic engineering in other sedimentary rocks.

Description: Energies, Vol. 11, Pages 64: Practical On-Board Measurement of Lithium Ion Battery Impedance Based on Distributed Voltage and Current Sampling Energies doi: 10.3390/en11010064 Authors: Xuezhe Wei Xueyuan Wang Haifeng Dai Battery impedance based state estimation methods receive extensive attention due to its close relation to internal dynamic processes and the mechanism of a battery. In order to provide impedance for a battery management system (BMS), a practical on-board impedance measuring method based on distributed signal sampling is proposed and implemented. Battery cell perturbing current and its response voltage for impedance calculation are sampled separately to be compatible with BMS. A digital dual-channel orthogonal lock-in amplifier is used to calculate the impedance. With the signal synchronization, the battery impedance is obtained and compensated. And the relative impedance can also be obtained without knowing the current. For verification, an impedance measuring system made up of electronic units sampling and processing signals and a DC-AC converter generating AC perturbing current is designed. A type of 8 Ah LiFePO4 battery is chosen and the valuable frequency range for state estimations is determined with a series of experiments. The battery cells are connected in series and the impedance is measured with the prototype. It is shown that the measurement error of the impedance modulus at 0.1 Hz–500 Hz at 5 °C–35 °C is less than 4.5% and the impedance phase error is less than 3% at <10 Hz at room temperature. In addition, the relative impedance can also be tracked well with the designed system.

Description: Energies, Vol. 11, Pages 80: Well Test Analysis for Fractured and Vuggy Carbonate Reservoirs of Well Drilling in Large Scale Cave Energies doi: 10.3390/en11010080 Authors: Cuiqiao Xing Hongjun Yin Kexin Liu Xingke Li Jing Fu A well test analysis model for fractured and vuggy carbonate reservoir of wells drilling in large scale cave considering wellbore storage and skin factor is established in this paper. The Laplace transformation and Stehfest numerical inversion are applied to obtain the results of wellbore pressure. Through the sensitivity analysis of different parameters for the well test typical curves, it is found that the change of the well test curves is in accordance with the theoretical analysis. With the increase of skin factor, the hump of well test typical curves is steeper. The storage ratio influences the depth and width of the concave in the pressure derivative curves. The cross flow coefficient mainly affects the position of the concave occurrence in the pressure derivative curves. The dimensionless reservoir radius mainly affects the middle and late stages of the log-log pressure type curves, and the later well test curves will be upturned for sealed boundary. The duration of the early stage of the log-log curves will become longer when drilling in large scale cave. The effective well radius is increased to a certain extent, which is in full agreement with the conclusions in this paper. The size of the caves has the same effect on the well test typical curves as wellbore storage coefficient. Due to acidification, fracturing, and other reasons, the boundary of the cave will collapse. Therefore, considering the wellbore storage coefficient and skin effect is very important during well testing. However, the existing models for well testing of fractured and vuggy carbonate reservoir often ignore the wellbore storage coefficient and skin effect. For fractured and vuggy carbonate reservoirs of well drilling in large scale cave, the existing models are not applicable. Since the previous models are mostly based on the triple-porosity medium and the equivalent continuum. The well test model for well drilling in large scale cave of fracture-cavity carbonate reservoirs with wellbore storage coefficient and skin factor in this work has significant application value for oil field.

Description: Energies, Vol. 11, Pages 32: High-Precision Speed Control Based on Multiple Phase-Shift Resonant Controllers for Gimbal System in MSCMG Energies doi: 10.3390/en11010032 Authors: Jian Feng Qing Wang Kun Liu The high precision speed control of gimbal servo system in magnetically suspended control moment gyro (MSCMG) suffers from periodic torque disturbances, which lead to periodic fluctuations in speed control. This paper proposes a novel multiple phase-shift resonant controller (MPRC) for a gimbal servo system to suppress the periodic torque ripples whose frequencies vary with the operational speed of the gimbal servo motor and high-speed motor. First, the periodic torque ripples caused by cogging torque, flux harmonics and the dynamic unbalance of the high speed rotor are analyzed. Second, the principle and structure of MPRC parallel with proportional integral (PI) controllers are discussed. The design and stability analysis of the proposed MPRC plus PI control scheme are given both for the current loop and speed loop. The closed-loop stability is ensured by adjusting the phase in the entire operational speed range. Finally, the effectiveness of the proposed control method is verified through simulation and experimental results.

Description: Energies, Vol. 11, Pages 1937: Evaluation of Fast Charging Efficiency under Extreme Temperatures Energies doi: 10.3390/en11081937 Authors: Germana Trentadue Alexandre Lucas Marcos Otura Konstantinos Pliakostathis Marco Zanni Harald Scholz Multi-type fast charging stations are being deployed over Europe as electric vehicle adoption becomes more popular. The growth of an electrical charging infrastructure in different countries poses different challenges related to its installation. One of these challenges is related to weather conditions that are extremely heterogeneous due to different latitudes, in which fast charging stations are located and whose impact on the charging performance is often neglected or unknown. The present study focused on the evaluation of the electric vehicle (EV) charging process with fast charging devices (up to 50 kW) at ambient (25 °C) and at extreme temperatures (−25 °C, −15 °C, +40 °C). A sample of seven fast chargers and two electric vehicles (CCS (combined charging system) and CHAdeMO (CHArge de Move)) available on the commercial market was considered in the study. Three phase voltages and currents at the wall socket, where the charger was connected, as well as voltage and current at the plug connection between the charger and vehicle have been recorded. According to SAE (Society of Automotive Engineers) J2894/1, the power conversion efficiency during the charging process has been calculated as the ratio between the instantaneous DC power delivered to the vehicle and the instantaneous AC power supplied from the grid in order to test the performance of the charger. The inverse of the efficiency of the charging process, i.e., a kind of energy return ratio (ERR), has been calculated as the ratio between the AC energy supplied by the grid to the electric vehicle supply equipment (EVSE) and the energy delivered to the vehicle’s battery. The evaluation has shown a varied scenario, confirming the efficiency values declared by the manufacturers at ambient temperature and reporting lower energy efficiencies at extreme temperatures, due to lower requested and, thus, delivered power levels. The lowest and highest power conversion efficiencies of 39% and 93% were observed at −25 °C and ambient temperature (+25 °C), respectively.

Description: Energies, Vol. 11, Pages 1934: Multi-Port Zero-Current Switching Switched-Capacitor Converters for Battery Management Applications Energies doi: 10.3390/en11081934 Authors: Yat Chi Fong Ka Wai Eric Cheng S. Raghu Raman Xiaolin Wang A novel implementation of multi-port zero-current switching (ZCS) switched-capacitor (SC) converters for battery management applications is presented. In addition to the auto-balancing feature offered by the SC technique, the proposed SC converter permits individual control of the charging or discharging current of the series-connected energy storage elements, such as the battery or super-capacitor cells. This approach enables advanced state control and accelerates the equalizing process by coordinated operation with the battery management system (BMS) and an adjustable voltage source, which can be implemented by a DC-DC converter interfaced to the energy storage string. Different configurations, including the single-input multi-output (SIMO), multi-input single-output (MISO) SC converters, and the corresponding altered circuits for string-to-cells, cells-to-string, as well as cells-to-cells equalizers, are discussed with a circuit analysis and derivation of the associated mathematical representation. The simulation study and experimental results indicated a significant increase in the balancing speed with the presence of BMS and closed-loop control of cell currents.

Description: Materials, Vol. 11, Pages 1287: Polysaccharide-Based Aerogel Bead Production via Jet Cutting Method Materials doi: 10.3390/ma11081287 Authors: Imke Preibisch Philipp Niemeyer Yusuf Yusufoglu Pavel Gurikov Barbara Milow Irina Smirnova The aim of this work is to develop a method to produce spherical biopolymer-based aerogel particles, which is capable for scale-up in the future. Therefore, the jet cutting method is suggested. Amidated pectin, sodium alginate, and chitosan are used as a precursor (a 1–3 wt. % solution) for particle production via jet cutting. Gelation is realized via two methods: the internal setting method (using calcium carbonate particles as cross-linkers and citric and acidic acid for pH adjustment) and the diffusion method (in calcium chloride solutions). Gel particles are subjected to solvent exchange to ethanol and consequent supercritical drying with CO2. Spherical aerogel particles with narrow particle size distributions in the range of 400 to 1500 µm and a specific surface area of around 500 m2/g are produced. Overall, it can be concluded that the jet cutting method is suitable for aerogel particle production, although the shape of the particles is not perfectly spherical in all cases. However, parameter adjustment might lead to even better shaped particles in further work. Moreover, the biopolymer-based aerogel particles synthesized in this study are tested as humidity absorbers in drying units for home appliances, particularly for dishwashers. It has been shown that for several cycles of absorption and desorption of humidity, aerogel particles are stable with an absorption capacity of around 20 wt. %.

Description: Materials, Vol. 11, Pages 1279: Computational Predictions and Microwave Plasma Synthesis of Superhard Boron-Carbon Materials Materials doi: 10.3390/ma11081279 Authors: Paul A. Baker Shane A. Catledge Sumner B. Harris Kathryn J. Ham Wei-Chih Chen Cheng-Chien Chen Yogesh K. Vohra Superhard boron-carbon materials are of prime interest due to their non-oxidizing properties at high temperatures compared to diamond-based materials and their non-reactivity with ferrous metals under extreme conditions. In this work, evolutionary algorithms combined with density functional theory have been utilized to predict stable structures and properties for the boron-carbon system, including the elusive superhard BC5 compound. We report on the microwave plasma chemical vapor deposition on a silicon substrate of a series of composite materials containing amorphous boron-doped graphitic carbon, boron-doped diamond, and a cubic hard-phase with a boron-content as high as 7.7 at%. The nanoindentation hardness of these composite materials can be tailored from 8 GPa to as high as 62 GPa depending on the growth conditions. These materials have been characterized by electron microscopy, X-ray photoelectron spectroscopy, Raman spectroscopy, X-ray diffraction, and nanoindentation hardness, and the experimental results are compared with theoretical predictions. Our studies show that a significant amount of boron up to 7.7 at% can be accommodated in the cubic phase of diamond and its phonon modes and mechanical properties can be accurately modeled by theory. This cubic hard-phase can be incorporated into amorphous boron-carbon matrices to yield superhard materials with tunable hardness values.

Description: Materials, Vol. 11, Pages 1290: Compositional Dependence of Phase Selection in CoCrCu0.1FeMoNi-Based High-Entropy Alloys Materials doi: 10.3390/ma11081290 Authors: Ning Liu Chen Chen Isaac Chang Pengjie Zhou Xiaojing Wang To study the effect of alloy composition on phase selection in the CoCrCu0.1FeMoNi high-entropy alloy (HEA), Mo was partially replaced by Co, Cr, Fe, and Ni. The microstructures and phase selection behaviors of the CoCrCu0.1FeMoNi HEA system were investigated. Dendritic, inter-dendritic, and eutectic microstructures were observed in the as-solidified HEAs. A simple face centered cubic (FCC) single-phase solid solution was obtained when the molar ratio of Fe, Co, and Ni was increased to 1.7 at the expense of Mo, indicating that Fe, Co, and Ni stabilized the FCC structure. The FCC structure was favored at the atomic radius ratio δ ≤ 2.8, valence electron concentration (VEC) ≥ 8.27, mixing entropy ΔS ≤ 13.037, local lattice distortion parameter α2 ≤ 0.0051, and ΔS/δ2 > 1.7. Mixed FCC + body centered cubic (BCC) structures occurred for 4.1 ≤ δ ≤ 4.3 and 7.71 ≤ VEC ≤ 7.86; FCC or/and BCC + intermetallic (IM) mixtures were favored at 2.8 ≤ δ ≤ 4.1 or δ > 4.3 and 7.39 < VEC ≤ 8.27. The IM phase is favored at electronegativity differences greater than 0.133. However, ΔS, α2, and ΔS/δ2 were inefficient in identifying the (FCC or/and BCC + IM)/(FCC + BCC) transition. Moreover, the mixing enthalpy cannot predict phase structures in this system.

Description: Materials, Vol. 11, Pages 1286: An Evaluation of Wetting and Adhesion of Three Bioceramic Root Canal Sealers to Intraradicular Human Dentin Materials doi: 10.3390/ma11081286 Authors: Jung-Hong Ha Hyeon-Cheol Kim Young Kyung Kim Tae-Yub Kwon Root canal sealers should have good wetting and adhesion with intraradicular dentin. This study evaluated the wetting and adhesion properties of three bioceramic root canal sealers on dentin using contact angle (CA) measurements and calculations based on the Owens–Wendt–Rabel–Kälble (OWRK) model and compared the properties with those of a resin sealer. Three bioceramic sealers (EndoSequence BC Sealer (BC); Endoseal MTA (EM); and MTA Fillapex (MF)) were tested, together with one epoxy resin-based sealer (AH Plus (AP)). Disc-shaped sealer specimens and human premolar teeth with flat and polished intraradicular dentin surfaces were prepared (n = 12). The CAs of two liquids (water and methylene iodide) were measured on the surfaces using the sessile drop method. The wetting and adhesion properties of the four sealers were calculated using the wetting envelope and isogram diagram, respectively. Group BC showed the best wettability among the four sealer groups. The best adhesion was achieved for group EM, followed by group BC, with a significant difference being present between the two groups (p < 0.05). The OWRK-based calculation indicated that the bioceramic BC and EM sealers showed superior wetting and adhesion properties to the AP sealers.

Description: Materials, Vol. 11, Pages 1281: Investigation of Cutting Temperature during Turning Inconel 718 with (Ti,Al)N PVD Coated Cemented Carbide Tools Materials doi: 10.3390/ma11081281 Authors: Jinfu Zhao Zhanqiang Liu Qi Shen Bing Wang Qingqing Wang Physical Vapor Deposition (PVD) Ti1−xAlxN coated cemented carbide tools are commonly used to cut difficult-to-machine super alloy of Inconel 718. The Al concentration x of Ti1−xAlxN coating can affect the coating microstructure, mechanical and thermo-physical properties of Ti1−xAlxN coating, which affects the cutting temperature in the machining process. Cutting temperature has great influence on the tool life and the machined surface quality. In this study, the influences of PVD (Ti,Al)N coated cemented carbide tools on the cutting temperature were analyzed. Firstly, the microstructures of PVD Ti0.41Al0.59N and Ti0.55Al0.45N coatings were inspected. The increase of Al concentration x enhanced the crystallinity of PVD Ti1−xAlxN coatings without epitaxy growth of TiAlN crystals. Secondly, the mechanical and thermo-physical properties of PVD Ti0.41Al0.59N and Ti0.55Al0.45N coated tools were analyzed. The pinning effects of coating increased with the increasing of Al concentration x, which can decrease the friction coefficient between the PVD Ti1−xAlxN coated cemented carbide tools and the Inconel 718 material. The coating hardness and thermal conductivity of Ti1−xAlxN coatings increased with the increase of Al concentration x. Thirdly, the influences of PVD Ti1−xAlxN coated tools on the cutting temperature in turning Inconel 718 were analyzed by mathematical analysis modelling and Lagrange simulation methods. Compared with the uncoated tools, PVD Ti0.41Al0.59N coated tools decreased the heat generation as well as the tool temperature to reduce the thermal stress generated within the tools. Lastly, the influences of Ti1−xAlxN coatings on surface morphologies of the tool rake faces were analyzed. The conclusions can reveal the influences of PVD Ti1−xAlxN coatings on cutting temperature, which can provide guidance in the proper choice of Al concentration x for PVD Ti1−xAlxN coated tools in turning Inconel 718.

Description: Materials, Vol. 11, Pages 1278: Study on Near-Net Forming Technology for Stepped Shaft by Cross-Wedge Rolling Based on Variable Cone Angle Billets Materials doi: 10.3390/ma11081278 Authors: Sutao Han Xuedao Shu Chang Shu Considering problems about concaves at the stepped shaft ends, this paper established the plastic flow kinetic theories about metal deforming during the cross-wedge rolling (CWR) process. By means of the DEFORM-3D finite element software and the point tracing method, the forming process of stepped shafts and the forming mechanism of concaves at shaft ends were studied. Based on the forming features of stepped shafts, rolling pieces were designed using variable cone angle billets. Single-factor tests were conducted to analyze the influence law of the shape parameters of billet with variable cone angle on end concaves, and rolling experiments were performed for verification. According to the results, during the rolling process of stepped shafts, concaves will come into being in stages, and the increasing tendency of its depth is due to the wave mode, the parameters of cone angle α, the first cone section length n. Furthermore, the total cone section length m has an increasingly weaker influence on the end concaves. Specifically, cone angle α has the most significant influence on the quality of shaft ends, which is about twice the influence of the total cone section length m. The concave depth will decrease at the beginning, and then increase with the increasing of the cone angle α and the first cone section length n, and it will decrease with the increasing of the total cone section length m. Finite element numerical analysis results are perfectly consistent with experimental results, with the error ratio being lower than 5%. The results provide a reliable theoretical basis for effectively disposing of end concave problems during CWR, rationally confirming the shape parameters of billets with a variable cone angle, improving the quality of stepped shaft ends, and realizing the near-net forming process of cross-wedge rolling without a stub bar.

Description: Materials, Vol. 11, Pages 1276: Tool Wear Mechanism in Cutting of Stack CFRP/UNS A97075 Materials doi: 10.3390/ma11081276 Authors: Severo Raul Fernandez-Vidal Sergio Fernandez-Vidal Moises Batista Jorge Salguero The aeronautics industry’s competitiveness has led to the need to increase productivity with one shot drilling (OSD) systems capable of drilling stacks of dissimilar materials (fibre/metal laminates, FML) in order to reduce riveting times. Among the materials that constitute the current aeronautical models, composite materials and aluminium (Al) and titanium (Ti) alloys stand out. These one-pass machining techniques produce high-quality holes, especially when all the elements that have to be joined are made of the same material. This work has followed a conventional OSD strategy and the same cutting conditions applied to CFRP (carbo-fibre-reinforced polymer), Al and CFRP/Al stacked sheets to know the wear mechanisms produced. With this purpose, results were obtained by using current specific techniques, such as microstructural analysis, monitoring of the shear forces and analysis of macrogeometric deviations. It has been determined that when these drilling techniques are applied under the same cutting conditions to stacks of materials of a different nature, the results of the wear mechanisms acting on the tool differ from those obtained when machining each material separately. This article presents a comparison between the effects of tool wear during dry drilling of CFRP and UNS A97075 plates separately and when machined as stacks.

Description: Energies, Vol. 11, Pages 1947: Design, Operation, Modeling and Grid Integration of Power-to-Gas Bioelectrochemical Systems Energies doi: 10.3390/en11081947 Authors: Raúl Santiago Muñoz-Aguilar Daniele Molognoni Pau Bosch-Jimenez Eduard Borràs Mónica Della Pirriera Álvaro Luna This paper deals with the design, operation, modeling, and grid integration of bioelectrochemical systems (BES) for power-to-gas application, through an electromethanogenesis process. The paper objective is to show that BES-based power-to-gas energy storage is feasible on a large scale, showing a first approximation that goes from the BES design and operation to the electrical grid integration. It is the first study attempting to cover all aspects of a BES-based power-to-gas technology, on authors’ knowledge. Designed BES reactors were based on a modular architecture, suitable for a future scaling-up. They were operated in steady state for eight months, and continuously monitored in terms of power consumption, water treatment, and biomethane production, in order to obtain data for the following modeling activity. A black box linear model of the BES was computed by using least-square methods, and validated through comparison with collected experimental data. Afterwards, a BES stack was simulated through several series and parallel connections of reactors, in order to obtain higher power consumption and test the grid integration of a real application system. The renewable energy surplus and energy price variability were evaluated for the grid integration of the BES stack. The BES stack was then simulated as energy storage system during low energy price periods, and tested experimentally with a real time system.

Description: Energies, Vol. 11, Pages 1948: The Optimization of Hybrid Power Systems with Renewable Energy and Hydrogen Generation Energies doi: 10.3390/en11081948 Authors: Fu-Cheng Wang Yi-Shao Hsiao Yi-Zhe Yang This paper discusses the optimization of hybrid power systems, which consist of solar cells, wind turbines, fuel cells, hydrogen electrolysis, chemical hydrogen generation, and batteries. Because hybrid power systems have multiple energy sources and utilize different types of storage, we first developed a general hybrid power model using the Matlab/SimPowerSystemTM, and then tuned model parameters based on the experimental results. This model was subsequently applied to predict the responses of four different hybrid power systems for three typical loads, without conducting individual experiments. Furthermore, cost and reliability indexes were defined to evaluate system performance and to derive optimal system layouts. Finally, the impacts of hydrogen costs on system optimization was discussed. In the future, the developed method could be applied to design customized hybrid power systems.

Description: Energies, Vol. 11, Pages 1946: A Novel Multi-Population Based Chaotic JAYA Algorithm with Application in Solving Economic Load Dispatch Problems Energies doi: 10.3390/en11081946 Authors: Jiangtao Yu Chang-Hwan Kim Abdul Wadood Tahir Khurshiad Sang-Bong Rhee The economic load dispatch (ELD) problem is an optimization problem of minimizing the total fuel cost of generators while satisfying power balance constraints, operating capacity limits, ramp-rate limits and prohibited operating zones. In this paper, a novel multi-population based chaotic JAYA algorithm (MP-CJAYA) is proposed to solve the ELD problem by applying the multi-population method (MP) and chaotic optimization algorithm (COA) on the original JAYA algorithm to guarantee the best solution of the problem. MP-CJAYA is a modified version where the total population is divided into a certain number of sub-populations to control the exploration and exploitation rates, at the same time a chaos perturbation is implemented on each sub-population during every iteration to keep on searching for the global optima. The proposed MP-CJAYA has been adopted to ELD cases and the results obtained have been compared with other well-known algorithms reported in the literature. The comparisons have indicated that MP-CJAYA outperforms all the other algorithms, achieving the best performance in all the cases, which indicates that MP-CJAYA is a promising alternative approach for solving ELD problems.

Description: Energies, Vol. 11, Pages 1944: Prediction of Mud Pressures for the Stability of Wellbores Drilled in Transversely Isotropic Rocks Energies doi: 10.3390/en11081944 Authors: Chiara Deangeli Omoruyi Omoman Omwanghe Serious borehole instability problems are often related to the presence of weakness planes in rock formations. In this study, we investigated the stability of wellbores drilled along a principal direction and parallel to the weakness planes. We used three different strength criteria (weakness plane model, Hoek and Brown and Nova and Zaninetti) to calculate the mud pressures to avoid slip and tensile failure along the weakness planes. We identified the orientation of the weakness planes that generate the most critical slip condition as a function of the friction angle of the planes. We also identified the range of orientations of the weakness planes that corresponds with the lower mud pressure window. We confirmed the validity of the proposed relationships with comparative stability analyses by using analytical solutions and numerical simulations (Ubiquitous Joint Model, FLAC). We found that the mud pressures calculated with the Hoek and Brown criterion show a particular trend, which cannot be predicted by the weakness plane model. We provided two normalized stability charts to predict mud pressures to prevent slip along the weakness planes in the critical slip condition. Finally, we corroborated our findings by simulating the stability of wellbores drilled in the Pedernales Field (Venezuela) and in oil fields located in Bohai Bay (China).

Description: Energies, Vol. 11, Pages 1945: Baltic Power Systems’ Integration into the EU Market Coupling under Different Desynchronization Schemes: A Comparative Market Analysis Energies doi: 10.3390/en11081945 Authors: Ettore Bompard Shaghayegh Zalzar Tao Huang Arturs Purvins Marcelo Masera Currently, the power transmission system of the Baltic states is synchronized with the Integrated/Unified Power System (IPS/UPS), which includes the Russian grid, and the IPS/UPS provides frequency regulation and system security within the Baltic states. Since joining the European Union (EU) in 2004, the Baltic states have been following the EU’s energy policy targets. The Baltics are presently participating in a European electricity market, i.e., the NordPool market, while they are expected to join the pan-European electricity market—the European target model for power market integration. Moreover, from a power grid perspective, EU energy policies intend to desynchronize the power grid of the Baltic states from the IPS/UPS over the coming years. This paper evaluates these policy trends through market impacts, and it complements existing studies on Baltic-IPS/UPS desynchronization in terms of wholesale electricity prices, generation surpluses, primary reserve adequacy, and redispatch costs. Participation of the Baltic states in the integrated pan-European day-ahead electricity market with zonal pricing was modeled for 2030, followed by a national redispatch, with detailed power grid modeling of Baltic states to solve potential intrazonal congestion. The simulation results imply the superiority of the Baltics’ synchronization to continental Europe, compared to the other schemes.

Description: Energies, Vol. 11, Pages 1941: Assessment of Energetic, Economic and Environmental Performance of Ground-Coupled Heat Pumps Energies doi: 10.3390/en11081941 Authors: Matteo Rivoire Alessandro Casasso Bruno Piga Rajandrea Sethi Ground-coupled heat pumps (GCHPs) have a great potential for reducing the cost and climate change impact of building heating, cooling, and domestic hot water (DHW). The high installation cost is a major barrier to their diffusion but, under certain conditions (climate, building use, alternative fuels, etc.), the investment can be profitable in the long term. We present a comprehensive modeling study on GCHPs, performed with the dynamic energy simulation software TRNSYS, reproducing the operating conditions of three building types (residential, office, and hotel), with two insulation levels of the building envelope (poor/good), with the climate conditions of six European cities. Simulation results highlight the driving variables for heating/cooling peak loads and yearly demand, which are the input to assess economic performance and environmental benefits of GCHPs. We found that, in Italy, GCHPs are able to reduce CO2 emissions up to 216 g CO2/year per euro spent. However, payback times are still quite high, i.e., from 8 to 20 years. This performance can be improved by changing taxation on gas and electricity and using hybrid systems, adding a fossil-fuel boiler to cover peak heating loads, thus reducing the overall installation cost compared to full-load sized GCHP systems.

Description: Energies, Vol. 11, Pages 1940: The Selection of Wind Power Project Location in the Southeastern Corridor of Pakistan: A Factor Analysis, AHP, and Fuzzy-TOPSIS Application Energies doi: 10.3390/en11081940 Authors: Yasir Ahmed Solangi Qingmei Tan Muhammad Waris Ali Khan Nayyar Hussain Mirjat Ifzal Ahmed Pakistan has sufficient wind energy potential across various locations of the country. However, so far, wind energy development has not attained sufficient momentum matching its potential. Amongst various other challenges, the site selection for wind power development has always been a primary concern of the decision-makers. Principally, wind project site selection decisions are driven by various multifaceted criteria. As such, in this study, a robust research framework comprising of factor analysis (FA) of techno-economic and socio-political factors, and a hybrid analytical hierarchy process (AHP) and fuzzy technique for order of preference by similarity to ideal solution (FTOPSIS) have been used for the prioritization of sites in the southeastern region of Pakistan. The results of this study reveal economic and land acquisition as the most significant criteria and sub-criteria, respectively. From the eight different sites considered, Jamshoro has been prioritized as the most suitable location for wind project development followed by Hyderabad, Nooriabad, Gharo, Keti Bandar, Shahbandar, Sajawal, and Talhar. This study provides a comprehensive decision support framework comprising of FA and a hybrid AHP and Fuzzy TOPSIS for the systematic analysis to prioritize suitable sites for the wind project development in Pakistan.

Description: Energies, Vol. 11, Pages 1943: Impacts of Low-Carbon Fuel Standards in Transportation on the Electricity Market Energies doi: 10.3390/en11081943 Authors: Ahmad Karnama João Abel Peças Lopes Mauro Augusto da Rosa Electric Vehicles (EVs) are increasing the interdependence of transportation policies and the electricity market dimension. In this paper, an Electricity Market Model with Electric Vehicles (EMMEV) was developed, exploiting an agent-based model that analyzes how carbon reduction policy in transportation may increase the number of Electric Vehicles and how that would influence electricity price. Agents are Energy Service Providers (ESCOs) which can distribute fuels and their objective is to maximize their profit. In this paper, the EMMEV is used to analyze the impacts of the Low-Carbon Fuel Standard (LCFS), a performance-based policy instrument, on electricity prices and EV sales volume. The agents in EMMEV are regulated parties in LCFS should meet a certain Carbon Intensity (CI) target for their distributed fuel. In case they cannot meet the target, they should buy credits to compensate for their shortfall and if they exceed it, they can sell their excess. The results, considering the assumptions and limitations of the model, show that the banking strategy of the agents contributing in the LCFS might have negative impact on penetration of EVs, unless there is a regular Credit Clearance to trade credits. It is also shown that the electricity price, as a result of implementing the LCFS and increasing number of EVs, has increased between 2% and 3% depending on banking strategy.

Description: Materials, Vol. 11, Pages 1294: High Capacity and High Efficiency Maple Tree-Biomass-Derived Hard Carbon as an Anode Material for Sodium-Ion Batteries Materials doi: 10.3390/ma11081294 Authors: Yuesheng Wang Zimin Feng Wen Zhu Vincent Gariépy Catherine Gagnon Manon Provencher Dharminder Laul René Veillette Michel L. Trudeau Abdelbast Guerfi Karim Zaghib Sodium-ion batteries (SIBs) are in the spotlight because of their potential use in large-scale energy storage devices due to the abundance and low cost of sodium-based materials. There are many SIB cathode materials under investigation but only a few candidate materials such as carbon, oxides and alloys were proposed as anodes. Among these anode materials, hard carbon shows promising performances with low operating potential and relatively high specific capacity. Unfortunately, its low initial coulombic efficiency and high cost limit its commercial applications. In this study, low-cost maple tree-biomass-derived hard carbon is tested as the anode for sodium-ion batteries. The capacity of hard carbon prepared at 1400 °C (HC-1400) reaches 337 mAh/g at 0.1 C. The initial coulombic efficiency is up to 88.03% in Sodium trifluoromethanesulfonimide (NaTFSI)/Ethylene carbonate (EC): Diethyl carbonate (DEC) electrolyte. The capacity was maintained at 92.3% after 100 cycles at 0.5 C rates. The in situ X-ray diffraction (XRD) analysis showed that no peak shift occurred during charge/discharge, supporting a finding of no sodium ion intercalates in the nano-graphite layer. Its low cost, high capacity and high coulombic efficiency indicate that hard carbon is a promising anode material for sodium-ion batteries.

Description: Materials, Vol. 11, Pages 1291: Synthesis and Plasmonic Chiroptical Studies of Sodium Deoxycholate Modified Silver Nanoparticles Materials doi: 10.3390/ma11081291 Authors: Jing Wang Kai-Xuan Fei Xin Yang Shuai-Shuai Zhang Yin-Xian Peng Sodium deoxycholate modified silver nanoparticles prepared in the presence of sodium deoxycholate as a chiral inducer exhibit plasmonic circular dichroism (CD) signals. The plasmon-induced chirality arises from the presence of chiral molecules (sodium deoxycholate) on the surface of Ag nanoparticles, which transfer their chiral properties to the visible wavelength range due to the Coulomb interactions between the chiral molecules and plasmonic nanoparticles. The prepared Ag nanoparticles (NPs) exhibit distinct line shapes of plasmonic CD, which can be tailored by varying the pH values of the solutions. A mechanism was proposed to explain the generation of the distinct plasmonic CD shapes, which indicated that the arrangements of chiral molecules in the plasmonic hot spots between Ag NPs are crucial for the induced plasmonic CD.

Description: Materials, Vol. 11, Pages 1293: The 3 R’s for Platelet-Rich Fibrin: A “Super” Tri-Dimensional Biomaterial for Contemporary Naturally-Guided Oro-Maxillo-Facial Soft and Hard Tissue Repair, Reconstruction and Regeneration Materials doi: 10.3390/ma11081293 Authors: Consuelo C. Zumarán Marcelo V. Parra Sergio A. Olate Eduardo G. Fernández Francisco T. Muñoz Ziyad S. Haidar Platelet-Rich fibrin (PRF) is a three-dimensional (3-D) autogenous biomaterial obtained via simple and rapid centrifugation from the patient’s whole blood samples, without including anti-coagulants, bovine thrombin, additives, or any gelifying agents. At the moment, it is safe to say that in oral and maxillofacial surgery, PRFs (particularly, the pure platelet-rich fibrin or P-PRF and leukocyte and platelet-rich fibrin or L-PRF sub-families) are receiving the most attention, essentially because of their simplicity, cost-effectiveness, and user-friendliness/malleability; they are a fairly new “revolutionary” step in second-generation therapies based on platelet concentration, indeed. Yet, the clinical effectiveness of such surgical adjuvants or regenerative platelet concentrate-based preparations continues to be highly debatable, primarily as a result of preparation protocol variability, limited evidence-based clinical literature, and/or poor understanding of bio-components and clinico-mechanical properties. To provide a practical update on the application of PRFs during oral surgery procedures, this critical review focuses on evidence obtained from human randomized and controlled clinical trials only. The aim is to serve the reader with current information on the clinical potential, limitations, challenges, and prospects of PRFs. Accordingly, reports often associate autologous PRFs with early bone formation and maturation; accelerated soft-tissue healing; and reduced post-surgical edema, pain, and discomfort. An advanced and original tool in regenerative dentistry, PRFs present a strong alternative and presumably cost-effective biomaterial for oro-maxillo-facial tissue (soft and hard) repair and regeneration. Yet, preparation protocols continue to be a source of confusion, thereby requiring revision and standardization. Moreover, to increase the validity, comprehension, and therapeutic potential of the reported findings or observations, a decent analysis of the mechanico-rheological properties, bio-components, and their bioactive function is eagerly needed and awaited; afterwards, the field can progress toward a brand-new era of “super” oro-dental biomaterials and bioscaffolds for use in oral and maxillofacial tissue repair and regeneration, and beyond.

Description: Energies, Vol. 11, Pages 1961: A Novel High Efficiency Quasi-Resonant Converter Energies doi: 10.3390/en11081961 Authors: Tianyu Zhu Jianze Wang Yanchao Ji Yiqi Liu In this paper, a new constant-frequency quasi-resonant converter is proposed. Compared with the traditional LLC converter, the proposed converter can effectively reduce the range of the operating frequency. The output voltage is changed to adjust the reactance of the resonant cavity. The proposed converter has a better loss factor. To verify the theoretical analysis and soft-switching condition, a 250 W, 100 V output prototype was built and compared with the full-bridge LLC converter. Analysis and experimental results verify that a smaller operating frequency range and volume of the transformers, a soft-switching condition, and a higher overall efficiency are achieved with the proposed converter.

Description: Energies, Vol. 11, Pages 1957: Dual-Temperature Evaluation of a High-Temperature Insulation System for Liquid-Immersed Transformer Energies doi: 10.3390/en11081957 Authors: Xiaojing Zhang Lu Ren Haichuan Yu Yang Xu Qingquan Lei Xin Li Baojia Han A high-temperature oil–paper insulation system offers an opportunity to improve the overloading capability of distribution transformers facing seasonal load variation. A high-temperature electrical insulation system (EIS) was chosen due to thermal calculation based on a typical loading curve on the China Southern Power Grid. In order to evaluate candidate high-temperature insulation systems, Nomex® T910 (aramid-enhanced cellulose) immersed in FR3 (natural ester) was investigated by a dual-temperature thermal aging test compared with a conventional insulation system, Kraft paper impregnated with mineral oil. Throughout the thermal aging test, mechanical, chemical, and dielectric parameters of both paper and insulating oil were investigated in each aging cycle. The thermal aging results determined that the thermal class of the FR3-T910 insulation system meets the request of overloading transformer needs.

Description: Energies, Vol. 11, Pages 1954: Experimental Study of Flow-Induced Whistling in Pipe Systems Including a Corrugated Section Energies doi: 10.3390/en11081954 Authors: Hee-Chang LIM Faran RAZI When air flows through pipe systems that include a corrugated segment, a whistling tone is generated and increases in intensity with increasing flow velocity. This whistling sound is related to the particular geometry of corrugated pipes, which is in the form of alternating cavities. This whistling is an environmental noise problem as well as a possible structural danger because of the resulting induced vibration. This paper studies the whistling behavior of various pipe systems with a combination of smooth and corrugated pipes through a series of experiments. The considered pipe systems consist of two smooth pipes attached at the upstream and downstream ends of a corrugated segment. Experiments with smooth and corrugated pipes, which had inner diameters of 15.25 and 16.5 mm, respectively, and various lengths, were performed for flow velocities of up to approximately 30 m/s. The minimum and maximum Strouhal numbers (St) obtained during our experiments were 0.25 and 0.38, respectively. For all pipe configurations investigated in this study, the lowest Mach number at which whistling was observed was 0.017, and the maximum was 0.093. The lowest frequency at which whistling was detected in our experiments was 650 Hz, and the highest was 3080 Hz. The results presented in the form of different variables and dimensionless parameters, including the frequency, Mach number, Strouhal number, and Helmholtz number. The average mode gap and number of excited acoustic modes were also taken into account for all considered configurations. The pipe systems with longer corrugated segments had broader whistling ranges than did configurations with shorter segments, indicating that the number of cavities inside the corrugated pipe has a direct effect on whistling. Increasing the smooth pipe length (either upstream or downstream) resulted in a decrease in the average mode gap between successive modes. The number of excited acoustic modes was primarily related to the corrugated segment length, but the smooth pipe length also had a pronounced effect on the excited modes for a constant corrugation length. The highest number of excited modes (13) was seen in the case of corrugated length 450 mm and smooth pipe length (either upstream or downstream) 400 mm while the lowest number of excited modes (1) was observed for corrugated length 250 mm and smooth pipe length (downstream) 300 mm and 400 mm.

Description: Energies, Vol. 11, Pages 1950: Investigation of Injection Strategy of Branched-Preformed Particle Gel/Polymer/Surfactant for Enhanced Oil Recovery after Polymer Flooding in Heterogeneous Reservoirs Energies doi: 10.3390/en11081950 Authors: Hong He Jingyu Fu Baofeng Hou Fuqing Yuan Lanlei Guo Zongyang Li Qing You The heterogeneous phase combination flooding (HPCF) system which is composed of a branched-preformed particle gel (B-PPG), polymer, and surfactant has been proposed to enhance oil recovery after polymer flooding in heterogeneous reservoirs by mobility control and reducing oil–water interfacial tension. However, the high cost of chemicals can make this process economically challenging in an era of low oil prices. Thus, in an era of low oil prices, it is becoming even more essential to optimize the heterogeneous phase combination flooding design. In order to optimize the HPCF process, the injection strategy has been designed such that the incremental oil recovery can be maximized using the corresponding combination of the B-PPG, polymer, and surfactant, thereby ensuring a more economically-viable recovery process. Different HPCF injection strategies including simultaneous injection and alternation injection were investigated by conducting parallel sand pack flooding experiments and large-scale plate sand pack flooding experiments. Results show that based on the flow rate ratio, the pressure rising area and the incremental oil recovery, no matter whether the injection strategy is simultaneous injection or alternation injection of HPCF, the HPCF can significantly block high permeability zone, increase the sweep efficiency and oil displacement efficiency, and effectively improve oil recovery. Compared with the simultaneous injection mode, the alternation injection of HPCF can show better sweep efficiency and oil displacement efficiency. Moreover, when the slug of HPCF and polymer/surfactant with the equivalent economical cost is injected by alternation injection mode, as the alternating cycle increases, the incremental oil recovery increases. The remaining oil distribution at different flooding stages investigated by conducting large-scale plate sand pack flooding experiments shows that alternation injection of HPCF can recover more remaining oil in the low permeability zone than simultaneous injection. Hence, these findings could provide the guidance for developing the injection strategy of HPCF to further enhance oil recovery after polymer flooding in heterogeneous reservoirs in the era of low oil prices.

Description: Materials, Vol. 11, Pages 1301: Spiral Bevel Gears Face Roughness Prediction Produced by CNC End Milling Centers Materials doi: 10.3390/ma11081301 Authors: Álvaro Álvarez Amaia Calleja Mikel Arizmendi Haizea González Luis Norberto Lopez de Lacalle The emergence of multitasking machines in the machine tool sector presents new opportunities for the machining of large size gears and short production series in these machines. However, the possibility of using standard tools in conventional machines for gears machining represents a technological challenge from the point of view of workpiece quality. Machining conditions in order to achieve both dimensional and surface quality requirements need to be determined. With these considerations in mind, computer numerical control (CNC) methods to provide useful tools for gear processing are studied. Thus, a model for the prediction of surface roughness obtained on the teeth surface of a machined spiral bevel gear in a multiprocess machine is presented. Machining strategies and optimal machining parameters were studied, and the roughness model is validated for 3 + 2 axes and 5 continuous axes machining strategies.

Description: Materials, Vol. 11, Pages 1302: Enhanced Cycling Stability of LiCuxMn1.95−xSi0.05O4 Cathode Material Obtained by Solid-State Method Materials doi: 10.3390/ma11081302 Authors: Hongyuan Zhao Fang Li Xiuzhi Bai Tingting Wu Zhankui Wang Yongfeng Li Jianxiu Su The LiCuxMn1.95−xSi0.05O4 (x = 0, 0.02, 0.05, 0.08) samples have been obtained by a simple solid-state method. XRD and SEM characterization results indicate that the Cu-Si co-doped spinels retain the inherent structure of LiMn2O4 and possess uniform particle size distribution. Electrochemical tests show that the optimal Cu-doping amount produces an obvious improvement effect on the cycling stability of LiMn1.95Si0.05O4. When cycled at 0.5 C, the optimal LiCu0.05Mn1.90Si0.05O4 sample exhibits an initial capacity of 127.3 mAh g−1 with excellent retention of 95.7% after 200 cycles. Moreover, when the cycling rate climbs to 10 C, the LiCu0.05Mn1.90Si0.05O4 sample exhibits 82.3 mAh g−1 with satisfactory cycling performance. In particular, when cycled at 55 °C, this co-doped sample can show an outstanding retention of 94.0% after 100 cycles, whiles the LiMn1.95Si0.05O4 only exhibits low retention of 79.1%. Such impressive performance shows that the addition of copper ions in the Si-doped spinel effectively remedy the shortcomings of the single Si-doping strategy and the Cu-Si co-doped spinel can show excellent cycling stability.

Description: Materials, Vol. 11, Pages 1297: A Straightforward Substitution Strategy to Tune BODIPY Dyes Spanning the Near-Infrared Region via Suzuki–Miyaura Cross-Coupling Materials doi: 10.3390/ma11081297 Authors: Guanglei Li Yu Otsuka Takuya Matsumiya Toshiyuki Suzuki Jianye Li Masashi Takahashi Koji Yamada In this study, a series of new red and near-infrared (NIR) dyes derived from 4,4-difluoro-4-bora-3a,4a-diaza-s-indacene (BODIPY) were developed by introducing thiophene and its derivatives to the 3- and 5- positions of the dichloroBODIPY core. For the first time, cyclictriol boronates and N-methyliminodiacetic acid (MIDA) boronate were used as organoboron species to couple with 3,5-dichloroBODIPY via the one-step Suzuki–Miyaura cross-coupling. Six kinds of thieno-expended BODIPY dyes were synthesized in acceptable yields ranging from 31% to 79%. All six dyes showed different absorption and emission wavelengths spanning a wide range (c.a. 600–850 nm) in the red and NIR regions with relatively high quantum yields (19–85%). Cellular imaging of 8-(2,6-dimethylphenyl)-re3,5-di(2-thienyl)-BODIPY (dye 1) was conducted using bovine cumulus cells, and the fluorescence microscopy images indicated that the chromophore efficiently accumulated and was exclusively localized in the cytoplasm, suggesting it could be utilized as a subcellular probe. All six dyes were characterized using 1H-NMR and mass spectrometry.

Description: Energies, Vol. 11, Pages 1966: Possible Interactions and Interferences of Copper, Chromium, and Arsenic during the Gasification of Contaminated Waste Wood Energies doi: 10.3390/en11081966 Authors: Shurooq Badri Al-Badri Ying Jiang Stuart Thomas Wagland A considerable proportion (about 64%) of biomass energy is produced from woody biomass (wood and its wastes). However, waste wood (WW) is very often contaminated with metal(loid) elements at concentrations leading to toxicity emissions and damages to facilities during thermal conversion. Therefore, procedures for preventing and/or alleviating the negative impacts of these elements require further development, particularly by providing informative and supportive information regarding the phase transformations of the metal(loid)s during thermal conversion processes. Although it is well known that phase transformation depends on different factors such as elements’ vaporization characteristics, operational conditions, and process configuration; however, the influences of reaction atmosphere composition in terms of interactions and interferences are rarely addressed. In response, since Cu, Cr, and As (CCA-elements) are the most regulated elements in woody biomass, this paper aims to explore the possible interactions and interferences among CCA-elements themselves and with Ca, Na, S, Cl, Fe, and Ni from reaction atmosphere composition perspectives during the gasification of contaminated WW. To do so, thermodynamic equilibrium calculations were performed for Boudouard reaction (BR) and partial combustion reaction (PCR) with temperature ranges of 0–1300 °C and 0–1800 °C, respectively, and both reactions were simulated under pressure conditions of 1, 20, and 40 atm. Refinement of the occurred interactions and interferences reveals that Ni-As interactions generate dominant species As2Ni5 and As8Ni11, which increase the solid–gaseous transformation temperature of As. Moreover, the interactions between Ca and Cr predominantly form C3Cr7; whereas the absence of Ca leads to Cr2Na2O4 causing instability in the Cr phase transformation.

Description: Energies, Vol. 11, Pages 1967: Dry Fuel Jet Half-Angle Measurements and Correlation for an Entrained Flow Gasifier Energies doi: 10.3390/en11081967 Authors: Francis Kus Robin Hughes Arturo Macchi Poupak Mehrani Marc Duchesne Reduced order models (ROMs) are increasingly applied to entrained flow gasification development due to reduced computational requirements relative to computational fluid dynamics (CFD) models. However, they require greater a posteriori knowledge of the reactor physics. A significant parameter influencing ROM outputs is the jet half-angle of the solid fuel and oxidant mixture in the gasifier. Thus, it is important to understand the geometry of the jet in the gasifier, and how it is dependent on operating parameters, such as solid and carrier gas flow rates. In this work, an existing model for jet half-angles, which considers the ratio of surrounding gas density to jet core density, is extended to a dry solids jet with impinging gas. The model is fitted to experimental jet half-angles. The jet half-angle of a non-reactive flow was measured using laser-sheet imaging for solid fluxes in the range of 460–880 kg/m2·s and carrier gas fluxes in the range of 43–90 kg/m2·s at the transport line outlet. Jet half-angles ranged from 5.6° to 11.3°, increasing with lower solid/gas loading ratios. CFD simulations of two reactive conditions, with solid and gas fluxes similar to experiments, were used to test the applicability of the proposed jet half-angle model.

Description: Energies, Vol. 11, Pages 1968: A Review on Recent Advances and Future Trends of Transformerless Inverter Structures for Single-Phase Grid-Connected Photovoltaic Systems Energies doi: 10.3390/en11081968 Authors: Kamran Zeb Imran Khan Waqar Uddin Muhammad Adil Khan P. Sathishkumar Tiago Davi Curi Busarello Iftikhar Ahmad H. J. Kim The research significance of various scientific aspects of photovoltaic (PV) systems has increased over the past decade. Grid-tied inverters the vital elements for the effective interface of Renewable Energy Resources (RER) and utility in the distributed generation system. Currently, Single-Phase Transformerless Grid-Connected Photovoltaic (SPTG-CPV) inverters (1–10 kW) are undergoing further developments, with new designs, and interest of the solar market. In comparison to the transformer (TR) Galvanic Isolation (GI)-based inverters, its advantageous features are lower cost, lighter weight, smaller volume, higher efficiency, and less complexity. In this paper, a review of SPTG-CPV inverters has been carried out. The basic operational principles of all SPTG-CPV inverters are presented in details for positive, negative, and zero cycles. A comprehensive analysis of each topology has been deliberated. A comparative assessment is also performed based on weaknesses, strengths, component ratings, efficiency, total harmonic distortion (THD), semiconductor device losses, and leakage current of various SPTG-CPV inverters schemes. Typical PV inverter structures and control schemes for grid connected three-phase system and single-phase systems are also discussed, described, and reviewed. Comparison of various industrial grids-connected PV inverters is also performed. Loss analysis is also performed for various topologies at 1 kW. Selection of appropriate topologies for their particular application is thoroughly presented. Then, discussion and forthcoming progress are emphasized. Lastly, the conclusions are presented. More than 100 research publications on the topic of SPTG-CPV inverter topologies, configurations, and control schematics along with the recent developments are thoroughly reviewed and classified for quick reference.

Description: Energies, Vol. 11, Pages 1964: Lightning Impulse Withstand of Natural Ester Liquid Energies doi: 10.3390/en11081964 Authors: Stephanie Haegele Farzaneh Vahidi Stefan Tenbohlen Kevin J. Rapp Alan Sbravati Due to the low biodegradability of mineral oil, intense research is conducted to define alternative liquids with comparable dielectric properties. Natural ester liquids are an alternative in focus; they are used increasingly as insulating liquid in distribution and power transformers. The main advantages of natural ester liquids compared to mineral oil are their good biodegradability and mainly high flash and fire points providing better fire safety. The dielectric strength of natural ester liquids is comparable to conventional mineral oil for homogeneous field arrangements. However, many studies showed a reduced dielectric strength for highly inhomogeneous field arrangements. This study investigates at which degree of inhomogeneity differences in breakdown voltage between the two insulating liquids occur. Investigations use lightning impulses with different electrode arrangements representing different field inhomogeneity factors and different gap distances. To ensure comparisons with existing transformer geometries, investigations are application-oriented using a transformer conductor model, which is compared to other studies. Results show significant differences in breakdown voltage from an inhomogeneity factor of 0.1 (highly inhomogeneous field) depending on the gap distance. Larger electrode gaps provide a larger inhomogeneity at which differences in breakdown voltages occur.

Description: Energies, Vol. 11, Pages 1963: Numerical Analysis to Determine Reliable One-Diode Model Parameters for Perovskite Solar Cells Energies doi: 10.3390/en11081963 Authors: Esteban Velilla Juan Bernardo Cano Keony Jimenez Jaime Valencia Daniel Ramirez Franklin Jaramillo With the aim to determine the photo-generated current, diode saturation current, ideality factor, shunt, and series resistances related to the one-diode model for p-i-n planar perovskite solar cells, reference cells with active area of approximately 1 cm2 and efficiencies ranging between 4.6 and 12.2% were fabricated and characterized at standard test conditions. To estimated feasible parameters, the mean square error between the I-V curve data of these cells and the circuital model results were minimized using a Genetic Algorithm combined with the Nelder-Mead method. When considering the optimization process solutions, a numerical sensitivity analysis of the error as a function of the estimated parameters was carried out. Based on the errors behavior that is showed graphically through maps, it was demonstrated that the set of parameters estimated for each cell were reliable, meaningful, and realistic, and being related to errors lower than 9.1 × 10−9. Therefore, these results can be considered as global solutions of the optimization process. Moreover, based on the lower errors obtained from the optimization process, it was possible to affirm that the one-diode model is suitable to model the I-V curve of perovskite solar cells. Finally, the estimated parameters suggested that the average ideality factor is close to 2 when the fill factor of the I-V curves is higher than 0.5. Lower fill factors corresponded to ideality that was higher than 3, linked to lower efficiencies, and high loses effects reflected on lower shunt resistances. Lower ideality factor of 1.4 corresponds to the best performing solar cells.

Description: Energies, Vol. 11, Pages 1962: Energy Loss Allocation in Smart Distribution Systems with Electric Vehicle Integration Energies doi: 10.3390/en11081962 Authors: Paulo M. De Oliveira-De Jesus Mario A. Rios Gustavo A. Ramos This paper presents a three-phase loss allocation procedure for distribution networks. The key contribution of the paper is the computation of specific marginal loss coefficients (MLCs) per bus and per phase expressly considering non-linear load models for Electric Vehicles (EV). The method was applied in a unbalanced 12.47 kV feeder with 12,780 households and 1000 EVs under peak and off-peak load conditions. Results obtained were also compared with the traditional roll-in embedded allocation procedure (pro rata) using non-linear and standard constant power models. Results show the influence of the non-linear load model in the energy losses allocated. This result highlights the importance of considering an appropriate EV load model to appraise the overall losses encouraging the use and further development of the methodology

Description: Materials, Vol. 11, Pages 1308: Observation of Morphology Changes of Fine Eutectic Si Phase in Al-10%Si Cast Alloy during Heat Treatment by Synchrotron Radiation Nanotomography Materials doi: 10.3390/ma11081308 Authors: Shougo Furuta Masakazu Kobayashi Kentaro Uesugi Akihisa Takeuchi Tomoya Aoba Hiromi Miura A series of three-dimensional morphology changes of fine eutectic Si-particles during heat treatment have been investigated in Self-modified and Sr-modified Al-10%Si cast alloys by means of synchrotron radiation nanotomography utilizing a Fresnel zone plate and a Zernike phase plate in this study. The coral-like shape particles observed in Sr-modified cast alloy fragmented at branch and neck during heat treatment at 773 K. The fragmentation occurred up to 900 s. After that, the fragmented particles grew and spheroidized by Ostwald ripening. On the other hand, rod-like shaped eutectic Si-particles observed in self-modified cast alloy were larger in size compared with the particle size in Sr-modified cast alloy. Separation of eutectic Si-particles in Self-modified cast alloy occurred up to approximately 900 s, which was similar tendency to that in Sr-modified cast alloy. However, it was found that the morphology change behavior was very complex in rod-like shape Si-particles. The three-dimensional morphology changes of fine eutectic Si-particles in both cast alloys, specifically fragmentation and spheroidizing, can be connected to changes in mechanical properties.

Description: Materials, Vol. 11, Pages 1306: Pattern-Dependent Mammalian Cell (Vero) Morphology on Tantalum/Silicon Oxide 3D Nanocomposites Materials doi: 10.3390/ma11081306 Authors: Hassan I. Moussa Megan Logan Wing Y. Chan Kingsley Wong Zheng Rao Marc G. Aucoin Ting Y. Tsui The primary goal of this work was to investigate the resulting morphology of a mammalian cell deposited on three-dimensional nanocomposites constructed of tantalum and silicon oxide. Vero cells were used as a model. The nanocomposite materials contained comb structures with equal-width trenches and lines. High-resolution scanning electron microscopy and fluorescence microscopy were used to image the alignment and elongation of cells. Cells were sensitive to the trench widths, and their observed behavior could be separated into three different regimes corresponding to different spreading mechanism. Cells on fine structures (trench widths of 0.21 to 0.5 μm) formed bridges across trench openings. On larger trenches (from 1 to 10 μm), cells formed a conformal layer matching the surface topographical features. When the trenches were larger than 10 μm, the majority of cells spread like those on blanket tantalum films; however, a significant proportion adhered to the trench sidewalls or bottom corner junctions. Pseudopodia extending from the bulk of the cell were readily observed in this work and a minimum effective diameter of ~50 nm was determined for stable adhesion to a tantalum surface. This sized structure is consistent with the ability of pseudopodia to accommodate ~4–6 integrin molecules.

Description: Materials, Vol. 11, Pages 1307: In Situ DRIFTS Studies of NH3-SCR Mechanism over V2O5-CeO2/TiO2-ZrO2 Catalysts for Selective Catalytic Reduction of NOx Materials doi: 10.3390/ma11081307 Authors: Yaping Zhang Xiupeng Yue Tianjiao Huang Kai Shen Bin Lu TiO2-ZrO2 (Ti-Zr) carrier was prepared by a co-precipitation method and 1 wt. % V2O5 and 0.2 CeO2 (the Mole ratio of Ce to Ti-Zr) was impregnated to obtain the V2O5-CeO2/TiO2-ZrO2 catalyst for the selective catalytic reduction of NOx by NH3. The transient activity tests and the in situ DRIFTS (diffuse reflectance infrared Fourier transform spectroscopy) analyses were employed to explore the NH3-SCR (selective catalytic reduction) mechanism systematically, and by designing various conditions of single or mixing feeding gas and pre-treatment ways, a possible pathway of NOx reduction was proposed. It was found that NH3 exhibited a competitive advantage over NO in its adsorption on the catalyst surface, and could form an active intermediate substance of -NH2. More acid sites and intermediate reaction species (-NH2), at lower temperatures, significantly promoted the SCR activity of the V2O5-0.2CeO2/TiO2-ZrO2 catalyst. The presence of O2 could promote the conversion of NO to NO2, while NO2 was easier to reduce. The co-existence of NH3 and O2 resulted in the NH3 adsorption strength being lower, as compared to tests without O2, since O2 could occupy a part of the active site. Due to CeO2’s excellent oxygen storage-release capacity, NH3 adsorption was weakened, in comparison to the 1 wt. % V2O5-0.2CeO2/TiO2-ZrO2 catalyst. If NOx were to be pre-adsorbed in the catalyst, the formation of nitrate and nitro species would be difficult to desorb, which would greatly hinder the SCR reaction. All the findings concluded that NH3-SCR worked mainly through the Eley-Rideal (E-R) mechanism.

Description: Energies, Vol. 11, Pages 1970: Increase in Robustness against Effects of Coil Misalignment on Electrical Parameters Using Magnetic Material Layer in Planar Coils of Wireless Power Transfer Transformer Energies doi: 10.3390/en11081970 Authors: Joao Victor Pinon Pereira Dias Masafumi Miyatake Utilization of wireless power transfer in light rail transits is seen as one solution for electrification of lines. The main advantage of this supply system is the reduction of installation; moreover, the alignment between the transmitter coil in the track and the receiver coil in the train should be perfect in order not to affect the power transfer. To reduce the effects of misalignment on the input and output electric parameters of the system, a new planar core and coil design, called hybrid intercore coil, is proposed. The proposed design uses a magnetic material layer between the windings in the inner half of the coil to create a non-uniform magnetic field distribution, which makes the system more robust against the effects of coil misalignment on the system current and voltage. Simulations with finite element method software were conducted to compare designs. The results show that the proposed design is less susceptible to the effects of misalignment and is more efficient. Prototype cores were constructed to verify the simulation results. Measurements show a smaller input overcurrent and output overvoltage when operating in resonance mode. The proposed design reduced the effects of coil misalignment on electrical parameters.

Description: Energies, Vol. 11, Pages 1971: A New Lumped Parameter Model for Natural Gas Pipelines in State Space Energies doi: 10.3390/en11081971 Authors: Kai Wen Zijie Xia Weichao Yu Jing Gong Many algorithms and numerical methods, such as implicit and explicit finite differences and the method of characteristics, have been applied for transient flow in gas pipelines. From a computational point of view, the state space model is an effective method for solving complex transient problems in pipelines. However, the impulse output of the existing models is not the actual behavior of the pipeline. In this paper, a new lumped parameter model is proposed to describe the inertial nature of pipelines with inlet/outlet pressure and flow rate as outer variables in the state space. Starting from the basic mechanistic partial differential equations of the general one-dimensional compressible gas flow dynamics under isothermal conditions, the transfer functions are first acquired as the fundamental work. With Taylor-expansion and a transformation procedure, the inertia state space models are derived with proper simplification. Finally, three examples are used to illustrate the effectiveness of the proposed model. With the model, a real-time automatic scheduling scheme of the natural gas pipeline could be possible in the future.

Description: Energies, Vol. 11, Pages 1972: Comprehensive Design and Analysis of a State-Feedback Controller for a Dynamic Voltage Restorer Energies doi: 10.3390/en11081972 Authors: Javier Roldán-Pérez Aurelio García-Cerrada Alberto Rodríguez-Cabero Juan Luis Zamora-Macho Voltage sags result in unwanted operation stops and large economical losses in industrial applications. A dynamic voltage restorer (DVR) is a power-electronics-based device conceived to protect high-power installations against these events. However, the design of a DVR control system is not straightforward and it has some peculiarities. First of all, a DVR includes a resonant (LC) connection filter with a lightly damped resonance. Secondly, the control system of a DVR should work properly regardless of the type of load, which can be linear or non-linear, to be protected. In this paper, a digital state-feedback (SF) controller for a DVR is proposed to address these issues. The design and features of the SF controller are studied in detail. Two pole-placement alternatives are discussed and the system robustness is tested under variations in the system parameters. Furthermore, implementation aspects such as discretization not commonly addressed in the literature are described. The controller is implemented in its incremental form. A decoupling system for the dq-axis dynamics that takes into account system delays and the load current is proposed and analytically studied. The proposed controller is compared with two other alternatives found in the literature: a Proportional-Integral-Differential (PID) controller and a cascade controller. The effect of the load connected downstream a DVR is also studied, revealing the potential of the SF controller to damp the resonance under light load conditions. All control system developments were tested in a 5 kVA prototype of a DVR connected to a configurable grid.

Description: Energies, Vol. 11, Pages 1987: Distributed Energy Resources Scheduling and Aggregation in the Context of Demand Response Programs Energies doi: 10.3390/en11081987 Authors: Pedro Faria João Spínola Zita Vale Distributed energy resources can contribute to an improved operation of power systems, improving economic and technical efficiency. However, aggregation of resources is needed to make these resources profitable. The present paper proposes a methodology for distributed resources management by a Virtual Power Player (VPP), addressing the resources scheduling, aggregation and remuneration based on the aggregation made. The aggregation is made using K-means algorithm. The innovative aspect motivating the present paper relies on the remuneration definition considering multiple scenarios of operation, by performing a multi-observation clustering. Resources aggregation and remuneration profiles are obtained for 2592 operation scenarios, considering 548 distributed generators, 20,310 consumers, and 10 suppliers.

Description: Energies, Vol. 11, Pages 1986: The Influence of Local Environmental, Economic and Social Variables on the Spatial Distribution of Photovoltaic Applications across China’s Urban Areas Energies doi: 10.3390/en11081986 Authors: Alin Lin Ming Lu Pingjun Sun The capacity of new installed photovoltaic (PV) in China in 2017 was increased to 53.06 GW, reaching a total of 402.5 GW around the world. Photovoltaic applications have a significant role in the reduction of greenhouse gas emissions and alleviating electricity shortages in the sustainable development process of cities. Research on the factors that influenced the spatial distribution of photovoltaic applications mostly focus on a certain project or a region. However, it is a complicated process for decision-making of photovoltaic installations in urban areas. This study uses zip code level data from 83 cities to investigate the influence of local environmental, economic and social variables on the spatial distribution of photovoltaic applications across China’s urban areas. By analyzing the current situation, the locations of urban photovoltaic applications are collected and presented. Statistical analysis software is used to evaluate the influence of selected variables. In this paper, correlation analysis, principle component analysis (PCA) and cluster analysis are generated to predict urban photovoltaic installations. The results of this research show that Gross Domestic Product (GDP), electricity consumption, policy incentives, the number of photovoltaic companies, population, age, education and rate of urbanization were important factors that influenced the adoption of urban photovoltaic systems. The results also indicate that Southeast China and Hangzhou Province are currently the most promising areas as they have a higher rate of solar photovoltaic installation. These conclusions have significancefor energy policy and planning strategies by predicting the future development of urban photovoltaic applications.

Description: Energies, Vol. 11, Pages 1985: Design, Construction, and Testing of a Gasifier-Specific Solid Oxide Fuel Cell System Energies doi: 10.3390/en11081985 Authors: Alvaro Fernandes Joerg Brabandt Oliver Posdziech Ali Saadabadi Mayra Recalde Liyuan Fan Eva O. Promes Ming Liu Theo Woudstra Purushothaman Vellayan Aravind This paper describes the steps involved in the design, construction, and testing of a gasifier-specific solid oxide fuel cell (SOFC) system. The design choices are based on reported thermodynamic simulation results for the entire gasifier- gas cleanup-SOFC system. The constructed SOFC system is tested and the measured parameters are compared with those given by a system simulation. Furthermore, a detailed exergy analysis is performed to determine the components responsible for poor efficiency. It is concluded that the SOFC system demonstrates reasonable agreement with the simulated results. Furthermore, based on the exergy results, the components causing major irreversible performance losses are identified.

Description: Energies, Vol. 11, Pages 1984: Experimental Study of Mixed Gas Hydrates from Gas Feed Containing CH4, CO2 and N2: Phase Equilibrium in the Presence of Excess Water and Gas Exchange Energies doi: 10.3390/en11081984 Authors: Ludovic Nicolas Legoix Livio Ruffine Christian Deusner Matthias Haeckel This article presents gas hydrate experimental measurements for mixtures containing methane (CH4), carbon dioxide (CO2) and nitrogen (N2) with the aim to better understand the impact of water (H2O) on the phase equilibrium. Some of these phase equilibrium experiments were carried out with a very high water-to-gas ratio that shifts the gas hydrate dissociation points to higher pressures. This is due to the significantly different solubilities of the different guest molecules in liquid H2O. A second experiment focused on CH4-CO2 exchange between the hydrate and the vapor phases at moderate pressures. The results show a high retention of CO2 in the gas hydrate phase with small pressure variations within the first hours. However, for our system containing 10.2 g of H2O full conversion of the CH4 hydrate grains to CO2 hydrate is estimated to require 40 days. This delay is attributed to the shrinking core effect, where initially an outer layer of CO2-rich hydrate is formed that effectively slows down the further gas exchange between the vapor phase and the inner core of the CH4-rich hydrate grain.

Description: Energies, Vol. 11, Pages 1991: Operation and Economic Assessment of Hybrid Refueling Station Considering Traffic Flow Information Energies doi: 10.3390/en11081991 Authors: Suyang Zhou Yuxuan Zhuang Wei Gu Zhi Wu It is anticipated that the penetration of “Green-Energy” vehicles, including Electric Vehicle (EV), Fuel Cell Vehicle (FCV), and Natural Gas Vehicle (NGV) will keep increasing in next decades. The demand of refueling stations will correspondingly increase for refueling these “Green-Energy” vehicles. While such kinds of “Green-Energy” vehicles can provide both social and economic benefits, effective management of refueling various kinds of these vehicles is necessary to maintain vehicle users’ comfortabilities and refueling station’s return on investment. To tackle these problems, this paper proposes a novel energy management approach for hybrid refueling stations with EV chargers, Hydrogen pumps and gas pumps. Firstly, the detailed models of EV chargers, Hydrogen pumps with electrolyte and hydrogen tank, the gas pumps with gas tank, renewable resources, and battery energy storage systems are established. The forecasting methodologies for renewable energy, electricity price and the traffic flow are also presented to support the hybrid refueling station modeling and operation. Then, a management approach is adopted to manage the refueling various kinds of vehicles with considerations of the refueling station profitability. Finally, the proposed management approach is verified under four different kinds of tariffs- Economy-7, Economy-10, Flat-rate, and Real-Time Pricing (RTP), finding that the proposed management approach has the best performance under RTP tariff. The economic assessment of the Energy Storage System (ESS) is also performed. It is found that the ESS can make the saving up to $127 per day. Different sizes of gas storage tank are compared in the final section as well. The result shows that increasing the size of the tank does not bring attractive extra benefits with the consideration of the investment on enlarging the tank size.

Description: Materials, Vol. 11, Pages 1284: Microstructures and Compressive Properties of Al Matrix Composites Reinforced with Bimodal Hybrid In-Situ Nano-/Micro-Sized TiC Particles Materials doi: 10.3390/ma11081284 Authors: Feng Qiu Hao-Tian Tong Yu-Yang Gao Qian Zou Bai-Xin Dong Qiang Li Jian-Ge Chu Fang Chang Shi-Li Shu Qi-Chuan Jiang Bimodal hybrid in-situ nano-/micro-size TiC/Al composites were prepared with combustion synthesis of Al-Ti-C system and hot press consolidation. Attempt was made to obtain in-situ bimodal-size TiC particle reinforced dense Al matrix composites by using different carbon sources in the reaction process of hot pressing forming. Microstructure showed that the obtained composites exhibited reasonable bimodal-sized TiC distribution in the matrix and low porosity. With the increasing of the carbon nano tube (CNT) content from 0 to 100 wt. %, the average size of the TiC particles decreases and the compressive strength of the composite increase; while the fracture strain increases first and then decreases. The compressive properties of the bimodal-sized TiC/Al composites, especially the bimodal-sized composite synthesized by Al-Ti-C with 50 wt. % CNTs as carbon source, were improved compared with the composites reinforced with single sized TiC. The strengthening mechanism of the in-situ bimodal-sized particle reinforced aluminum matrix composites was revealed.

Description: Materials, Vol. 11, Pages 1283: Biocompatible and Implantable Optical Fibers and Waveguides for Biomedicine Materials doi: 10.3390/ma11081283 Authors: Roya Nazempour Qianyi Zhang Ruxing Fu Xing Sheng Optical fibers and waveguides in general effectively control and modulate light propagation, and these tools have been extensively used in communication, lighting and sensing. Recently, they have received increasing attention in biomedical applications. By delivering light into deep tissue via these devices, novel applications including biological sensing, stimulation and therapy can be realized. Therefore, implantable fibers and waveguides in biocompatible formats with versatile functionalities are highly desirable. In this review, we provide an overview of recent progress in the exploration of advanced optical fibers and waveguides for biomedical applications. Specifically, we highlight novel materials design and fabrication strategies to form implantable fibers and waveguides. Furthermore, their applications in various biomedical fields such as light therapy, optogenetics, fluorescence sensing and imaging are discussed. We believe that these newly developed fiber and waveguide based devices play a crucial role in advanced optical biointerfaces.

Description: Materials, Vol. 11, Pages 1282: Development of a Novel in Silico Model to Investigate the Influence of Radial Clearance on the Acetabular Cup Contact Pressure in Hip Implants Materials doi: 10.3390/ma11081282 Authors: Saverio Affatato Massimiliano Merola Alessandro Ruggiero A hip joint replacement is considered one of the most successful orthopedic surgical procedures although it involves challenges that must be overcome. The patient group undergoing total hip arthroplasty now includes younger and more active patients who require a broad range of motion and a longer service lifetime of the implant. The current replacement joint results are not fully satisfactory for these patients’ demands. As particle release is one of the main issues, pre-clinical experimental wear testing of total hip replacement components is an invaluable tool for evaluating new implant designs and materials. The aim of the study was to investigate the cup tensional state by varying the clearance between head and cup. For doing this we use a novel hard-on-soft finite element model with kinematic and dynamic conditions calculated from a musculoskeletal multibody model during the gait. Four different usual radial clearances were considered, ranging from 0 to 0.5 mm. The results showed that radial clearance plays a key role in acetabular cup stress-strain during the gait, showing from the 0 value to the highest, 0.5, a difference of 44% and 35% in terms of maximum pressure and deformation, respectively. Moreover, the presented model could be usefully exploited for complete elastohydrodynamic synovial lubrication modelling of the joint, with the aim of moving towards an increasingly realistic total hip arthroplasty in silico wear assessment accounting for differences in radial clearances.

Description: Materials, Vol. 11, Pages 1277: Filtration of Sub-3.3 nm Tungsten Oxide Particles Using Nanofibrous Filters Materials doi: 10.3390/ma11081277 Authors: Raheleh Givehchi Qinghai Li Zhongchao Tan This work aims to understand the effects of particle concentration on the filtration of nanoparticles using nanofibrous filters. The filtration efficiencies of triple modal tungsten oxide (WOx) nanoparticles were experimentally determined at three different concentrations for the size range of 0.82–3.3 nm in diameter. All tests were conducted using polyvinyl alcohol (PVA) nano-fibrous filters at an air relative humidity of 2.9%. Results showed that the filtration efficiencies of sub-3.3 nm nanoparticles depended on the upstream particle concentration. The lower the particle concentration was, the higher the filtration efficiency was.

Description: Materials, Vol. 11, Pages 1280: Porous Silk Fibroin Microspheres Sustainably Releasing Bioactive Basic Fibroblast Growth Factor Materials doi: 10.3390/ma11081280 Authors: Jing Qu Lu Wang Longxing Niu Jiaming Lin Qian Huang Xuefeng Jiang Mingzhong Li Basic fibroblast growth factor (bFGF) plays a significant role in stimulating cell proliferation. It remains a challenge in the field of biomaterials to develop a carrier with the capacity of continuously releasing bioactive bFGF. In this study, porous bFGF-loaded silk fibroin (SF) microspheres, with inside-out channels, were fabricated by high-voltage electrostatic differentiation, and followed by lyophilization. The embedded bFGF exhibited a slow release mode for over 13 days without suffering burst release. SEM observations showed that incubated L929 cells could fully spread and produce collagen-like fibrous matrix on the surface of SF microspheres. CLSM observations and the results of cell viability assay indicated that bFGF-loaded microspheres could significantly promote cell proliferation during five to nine days of culture, compared to bFGF-unloaded microspheres. This reveals that the bFGF released from SF microspheres retained obvious bioactivity to stimulate cell growth. Such microspheres sustainably releasing bioactive bFGF might be applied to massive cell culture and tissue engineering as a matrix directly, or after being combined with three-dimensional scaffolds.

Description: Energies, Vol. 11, Pages 1998: Design Issues for Claw Pole Machines with Soft Magnetic Composite Cores Energies doi: 10.3390/en11081998 Authors: Chengcheng Liu Jiawei Lu Youhua Wang Gang Lei Jianguo Zhu Youguang Guo By using global ring winding, the torque coefficient of the transverse flux machine (TFM) is proportional to its number of pole pairs, and thus the TFM possesses high torque density ability when compared with other electrical machines. As a special kind of TFM, the claw pole machine (CPM) can have more torque due to its special claw pole teeth. The manufacturing of CPM or TFM with silicon steels was very difficult in the past, and is a handicap for the progress of this kind of machine. Thanks to the advent of soft magnetic composite (SMC) materials, the manufacturing process of CPM has become more and more simple. More attention has been paid to this kind of technology, and some mass production CPMs with SMC cores have appeared. However, there are few works that discuss the key design issues for this kind of machine. In this paper, a small CPM with SMC is used as as a research benchmark. Various design methods that can be adopted to improve its performance have been studied, including unequal stator claw pole teeth, a skewing magnet design, consequent pole design, and etc. The 3D finite element method (FEM) is used for the machine analysis, and it is verified by the experimental results of a CPM with SMC cores.

Description: Energies, Vol. 11, Pages 1992: Assessment and Performance Evaluation of a Wind Turbine Power Output Energies doi: 10.3390/en11081992 Authors: Akintayo Temiloluwa Abolude Wen Zhou Estimation errors have constantly been a technology bother for wind power management, often time with deviations of actual power curve (APC) from the turbine power curve (TPC). Power output dispersion for an operational 800 kW turbine was analyzed using three averaging tine steps of 1-min, 5-min, and 15-min. The error between the APC and TPC in kWh was about 25% on average, irrespective of the time of the day, although higher magnitudes of error were observed during low wind speeds and poor wind conditions. The 15-min averaged time series proved more suitable for grid management and energy load scheduling, but the error margin was still a major concern. An effective power curve (EPC) based on the polynomial parametric wind turbine power curve modeling technique was calibrated using turbine and site-specific performance data. The EPC reduced estimation error to about 3% in the aforementioned time series during very good wind conditions. By integrating statistical wind speed forecasting methods and site-specific EPCs, wind power forecasting and management can be significantly improved without compromising grid stability.

Description: Energies, Vol. 11, Pages 1995: Active-Current Control of Large-Scale Wind Turbines for Power System Transient Stability Improvement Based on Perturbation Estimation Approach Energies doi: 10.3390/en11081995 Authors: Peng Shen Lin Guan Zhenlin Huang Liang Wu Zetao Jiang This paper proposes an active-current control strategy for large-scale wind turbines (WTs) to improve the transient stability of power systems based on a perturbation estimation (PE) approach. The main idea of this control strategy is to mitigate the generator imbalance of mechanical and electrical powers by controlling the active-current of WTs. The effective mutual couplings of synchronous generators and WTs are identified using a Kron-reduction technique first. Then, the control object of each WT is assigned based on the identified mutual couplings. Finally, an individual controller is developed for each WT using a PE approach. In the control algorithm, a perturbation state (PS) is introduced for each WT to represent the comprehensive effect of the nonlinearities and parameter variations of the power system, and then it is estimated by a designed perturbation observer. The estimated PS is employed to compensate the actual perturbation, and to finally achieve the adaptive control design without requiring an accurate system model. The effectiveness of the proposed control approach on improving the system transient stability is validated in the modified IEEE 39-bus system.

Description: Energies, Vol. 11, Pages 2018: Technological Solutions for Recycling Ash Slag from the Cao Ngan Coal Power Plant in Vietnam Energies doi: 10.3390/en11082018 Authors: Thriveni Thenepalli Nguyen Thi Minh Ngoc Lai Quang Tuan Trinh Hai Son Ho Huu Hieu Dang Tran Nhu Thuy Nguyen Thi Thanh Thao Duong Thi Thanh Tam Doan Thi Ngoc Huyen Tran Tan Van Ramakrishna Chilakala Ji Whan Ahn Annually, coal-fired power plants in Vietnam discharge hundreds of thousand tons of coal ash. Most of this ash goes into the environment without treatment or any plan for the efficient reuse of this precious resource. There are many reasons for this, such as poor quality of the ash, no suitable and feasible ash treatment technology, a lack of awareness about environmental pollution and resource saving, and inappropriate sanctions and policies. This study analyzed and summarized information and data pertaining to the current status of the production, discharge, and utilization of coal ash from the Cao Ngan Power Plant (CNPP) in Thai Nguyen Province, Vietnam. In addition, the potential for applying advanced emission reduction technologies in order to recycle coal ash for cement production, as well as geographical, socio-economic, and market factors were assessed. This paper reveals the results of a preliminary assessment of carbon-mineralization technologies which seek to achieve the following three goals: (1) effectively disposing of coal ash to protect the environment and local community, (2) contributing to the nationally determined effort to mitigate greenhouse gas emissions which cause climate change, and (3) making value-added products and bringing economic benefits to a sustainable society.

Description: Energies, Vol. 11, Pages 2017: An Experimental Investigation of Thermal Characteristics of Phase Change Material Applied to Improve the Isothermal Operation of a Refrigerator Energies doi: 10.3390/en11082017 Authors: Seok-Joon Lee Seul-Hyun Park We investigated the thermal performance of a refrigerator with a functional duct unit (FDU) which was charged with a phase change material (PCM) and designed to replace the existing expandable polystyrene (EPS) duct unit. Since the performance of the FDU is dependent upon the thermal characteristics of the PCM, the eutectic water–salt solution as the PCM was prepared and tested to optimize the thermal characteristics. The thermal properties of the PCM were examined by the T-history method. When the PCM contained 1 wt.% eutectic molten salt compounds, the phase change temperature was approximately −0.5 °C, the supercooling temperature was approximately −2.9 °C, and the latent heat was 304.9 kJ/kg. Compared with other PCMs of different eutectic molten salt concentrations, this PCM was found to have the most appropriate thermal properties for the FDU. Therefore, the PCM with 1 wt.% eutectic molten salt compounds was used in the FDU, which was installed in a 200 L top-mounted freezer (TMF). For a quantitative comparison of the operational performance, an FDU and an EPS duct were installed alternately in a refrigerator operated under the same conditions and analyzed in terms of internal temperature variation and operational characteristics. When the EPS duct was replaced by the FDU, the temperature deviation measured during a defrosting operation was observed to become smaller. Moreover, during a power outage, the refrigerator with the FDU released heat owing to the phase change of the PCM, thereby preventing temperature rise inside the refrigerator.

Description: Energies, Vol. 11, Pages 2016: The Synergies of Shared Autonomous Electric Vehicles with Renewable Energy in a Virtual Power Plant and Microgrid Energies doi: 10.3390/en11082016 Authors: Riccardo Iacobucci Benjamin McLellan Tetsuo Tezuka The introduction of shared autonomous electric vehicles (SAEVs), expected within the next decade, can transform the car into a service, accelerate electrification of the transport sector, and allow for large scale control of electric vehicle charging. In this work, we investigate the potential for this system to provide aggregated storage when combined with intermittent renewable energy sources. We develop a simulation methodology for the optimization of vehicle charging in the context of a virtual power plant or microgrid, with and without grid connection or distributed dispatchable generators. The model considers aggregate storage availability from vehicles based on transport patterns taking into account the necessary vehicle redistribution. We investigate the case of a grid-connected VPP with rooftop solar and the case of a isolated microgrid with solar, wind, and dispatchable generation. We conduct a comprehensive sensitivity analysis to study the effect of several parameters on the results for both cases.

Description: Energies, Vol. 11, Pages 2015: Energy-Efficient Clusters for Object Tracking Networks Energies doi: 10.3390/en11082015 Authors: Yang-Hsin Fan Smart cities have hundreds of thousands of devices for tracking data on crime, the environment, and traffic (such as data collected at crossroads and on streets). This results in higher energy usage, as they are recording information persistently and simultaneously. Moreover, a single object tracking device, on a corner at an intersection for example has a limited scope of view, so more object tracking devices are added to broaden the view. As an increasing number of object tracking devices are constructed on streets, their efficient energy consumption becomes a significant issue. This work is concerned with decreasing the energy required to power these systems, and proposes energy-efficient clusters (EECs) of object tracking systems to achieve energy savings. First, we analyze a current object tracking system to establish an equivalent model. Second, we arrange the object tracking system in a cluster structure, which facilitates the evaluation of energy costs. Third, the energy consumption is assessed as either dynamic or static, which is a more accurate system for determining energy consumption. Fourth, we analyze all possible scenarios of the object’s location and the resulting energy consumption, and derive a number of formulas for the fast computation of energy consumption. Finally, the simulation results are reported. These results show the proposed EEC is an effective way to save energy, compared with the energy consumption benchmarks of current technology.

Description: Energies, Vol. 11, Pages 2014: Effect of Sodium Chloride and Thiourea on Pollutant Formation during Combustion of Plastics Energies doi: 10.3390/en11082014 Authors: María E. Iñiguez Juan A. Conesa Andrés Fullana Thermal decomposition of different samples containing a mixture of plastics (polyethylene (PE), polypropylene (PP), polyethylene terephthalate (PET), and nylon) combined with NaCl and metal oxides (Fe2O3, CuO) was studied under an air atmosphere at 850 °C using a reactor, followed by analysis of the evolved products. Combustion runs were performed to study how the presence of such compounds influences the production of pollutants. Here, we report the analyses of the emissions of the main gases, as well as volatiles and semivolatiles, including polyaromatic hydrocarbons (PAHs), polychlorinated benzenes and phenols, and polybrominated phenols. Results show that the production of chlorinated pollutants did not increase in the presence of NaCl, but the presence of other metals during the decomposition led to the production of a great amount of pollutants. In this regard, the emission of chlorinated phenols increased from 110 to ca. 250 mg/kg when the sample included a small quantity of a transition metal oxide. Additionally, the presence of an inhibitor—thiourea (TUA)—was tested. Results confirm that adding TUA to the sample reduced these emissions to a considerable extent, with the emission of chlorinated phenols amounting to 65 mg/kg.

Description: Energies, Vol. 11, Pages 2013: Establishment of an Improved Material-Drilling Power Model to Support Energy Management of Drilling Processes Energies doi: 10.3390/en11082013 Authors: Shun Jia Qingwen Yuan Wei Cai Qinghe Yuan Conghu Liu Jingxiang Lv Zhongwei Zhang Drilling processes, as some of the most widely used machining processes in the manufacturing industry, play an important role in manufacturing process energy-saving programs. However, research focus on energy modeling of drilling processes, especially for the modeling of material-drilling power, are really scarce. To bridge this gap, an improved material-drilling power model is proposed in this paper. The obtained material-drilling power model can improve the accuracy of the material-drilling power and lay a good foundation for energy modeling and optimization of drilling processes. Finally, experimental studies were carried out on an XHK-714F CNC machining center (Hangzhou HangJi Machine Tool Co., Ltd., Hangzhou, China) and a JTVM6540 CNC milling machine (Jinan Third Machine Tool Co., Ltd., Jinan, China). The results showed that predictive accuracies with the proposed model are generally higher than 96% for all the test cases.

Description: Energies, Vol. 11, Pages 2012: Estimation of Load Pattern for Optimal Planning of Stand-Alone Microgrid Networks Energies doi: 10.3390/en11082012 Authors: Chang Koo Lee Byeong Gwan Bhang David Kwangsoon Kim Sang Hun Lee Hae Lim Cha Hyung Keun Ahn This paper proposes a method for estimating the load pattern for optimal planning of stand-alone renewable microgrids and verifies when the basic data for microgrid design are limited. To estimate a proper load pattern for optimal microgrid design when the data obtained in advance are insufficient, the least squares method is used to compare the similarity of annual power consumption between the subject area and eight islands in Korea whose actual load patterns were previously obtained. Similarity is compared in terms of annual (every month), seasonal, bi-monthly, and monthly averages. To verify the validity of the proposed estimation method, the applied proposed estimation method is used for two islands that have already installed a microgrid consisting of photovoltaic, wind power, energy storage systems, and diesel generators. In comparing the actual data from the two islands, the costs of electricity in terms of microgrid operations show improvements of 37.2% and 29.8%, respectively.

Description: Materials, Vol. 11, Pages 1332: Biocompatible/Biodegradable Electrowetting on Dielectric Microfluidic Chips with Fluorinated CTA/PLGA Materials doi: 10.3390/ma11081332 Authors: Kaidi Zhang Lei Chao Jia Zhou One of the major hurdles in the development of biocompatible/biodegradable EWOD (Electrowetting-on-dielectric) devices is the biocompatibility of the dielectric and hydrophobic layers. In this study, we address this problem by using reactive ion etching (RIE) to prepare a super-hydrophobic film combining fluorinated cellulose triacetate (CTA) and poly (lactic-co-glycolic acid) (PLGA). The contact angle (CA) of water droplets on the proposed material is about 160°. X-ray photoelectron spectroscopy (XPS) and atomic force microscopy (AFM) characterizations indicate that a slight increase in the surface roughness and the formation of CFx (C-F or CF2) bonds are responsible for the super-hydrophobic nature of the film. Alternating Current (AC) static electrowetting and droplet transportation experiments evidence that contact angle hysteresis and contact line pinning are greatly reduced by impregnating the CTA/PLGA film with silicon oil. Therefore, this improved film could provide a biocompatible alternative to the typical Teflon® or Cytop® films as a dielectric and hydrophobic layer.

Description: Energies, Vol. 11, Pages 2008: Short-Term Load Forecasting of Natural Gas with Deep Neural Network Regression † Energies doi: 10.3390/en11082008 Authors: Gregory D. Merkel Richard J. Povinelli Ronald H. Brown Deep neural networks are proposed for short-term natural gas load forecasting. Deep learning has proven to be a powerful tool for many classification problems seeing significant use in machine learning fields such as image recognition and speech processing. We provide an overview of natural gas forecasting. Next, the deep learning method, contrastive divergence is explained. We compare our proposed deep neural network method to a linear regression model and a traditional artificial neural network on 62 operating areas, each of which has at least 10 years of data. The proposed deep network outperforms traditional artificial neural networks by 9.83% weighted mean absolute percent error (WMAPE).

Description: Materials, Vol. 11, Pages 1336: Fatigue Crack Growth Behavior of the MIG Welded Joint of 06Cr19Ni10 Stainless Steel Materials doi: 10.3390/ma11081336 Authors: Lanqing Tang Caifu Qian Ayhan Ince Jing Zheng Huifang Li Zhichao Han In this paper, the fatigue crack growth behavior of the base metal (BM), the weld metal (WM) and the heat-affected zone (HAZ) in the metal-inert gas (MIG) welded joints of the 06Cr19Ni10 stainless steel are analyzed and studied. Results of the fatigue crack propagation tests show that a new fatigue crack initiates at the crack tip of a pre-existing crack, then propagates perpendicular to the direction of cyclic fatigue loads. This observation indicates that the original mixed-mode crack transforms into the mode I crack. The WM specimen has the largest fatigue crack growth rate, followed by the HAZ specimen and the BM specimen. To illustrate the differences in fatigue crack growth behavior of the three different types of specimens, metallographic structure, fracture morphology and residual stresses of the BM, HAZ and WM are investigated and discussed. The metallographic observations indicate that the mean grain size of the HAZ is relatively larger than that of the BM. The fractographic analysis shows that the WM has the largest fatigue striation width, followed by the HAZ and the BM. It is also found that the depth of dimple in the WM is relatively shallower than the one in the HAZ and BM, implying the poor plasticity behavior of the material. Analysis results of the residual stress analysis demonstrate a high level of tensile residual stress appearance in the WM and HAZ.

Description: Materials, Vol. 11, Pages 1337: Variations of the Elastic Properties of the CoCrFeMnNi High Entropy Alloy Deformed by Groove Cold Rolling Materials doi: 10.3390/ma11081337 Authors: Paul Lohmuller Laurent Peltier Alain Hazotte Julien Zollinger Pascal Laheurte Eric Fleury The variations of the mechanical properties of the CoCrFeMnNi high entropy alloy (HEA) during groove cold rolling process were investigated with the aim of understanding their correlation relationships with the crystallographic texture. Our study revealed divergences in the variations of the microhardness and yield strength measured from samples deformed by groove cold rolling and conventional cold rolling processes. The crystallographic texture analyzed by electron back scattered diffraction (EBSD) revealed a hybrid texture between those obtained by conventional rolling and drawing processes. Though the groove cold rolling process induced a marked strengthening effect in the CoCrFeMnNi HEA, the mechanical properties were also characterized by an unusual decrease of the Young’s modulus as the applied groove cold rolled deformation increased up to about 0.5 before reaching a stabilized value. This decrease of the Young’s modulus was attributed to the increased density of mobile dislocations induced by work hardening during groove cold rolling processing.

Description: Energies, Vol. 11, Pages 2024: Coupled Fluid-Thermal Analysis for Induction Motors with Broken Bars Operating under the Rated Load Energies doi: 10.3390/en11082024 Authors: Ying Xie Jinpeng Guo Peng Chen Zhiwei Li Thermal stress of the rotor in a squirrel cage induction motor is generated due to the temperature rise, it is also one of the factors causing the broken bar fault because the structure of the rotor would be destroyed if the stress of the rotor bars exceed the strength limit. The coupled fluid-thermal analysis for the induction motor with healthy and broken bar rotors is performed in this paper. Much concern has been committed to establishment of the fluid model on the basis of computational fluid dynamic (CFD) theory. The heat field of the prototypes is analysed so that the effect of the asymmetrical rotor on the motor heat performance can be investigated in depth. Eventually, the efficiency of the presented model and method, for the totally enclosed fan cooled (TEFC) induction motor, can be verified through experimental results. In addition, this paper reports a quantitative analysis of the heat flux distribution of the fault rotor, and the heat flux density of the bars is investigated in detail. Then, the part most likely to break in the rotor as a result of the thermal load is identified.

Description: Energies, Vol. 11, Pages 2021: Pilot Protection Based on Amplitude of Directional Travelling Wave for Voltage Source Converter-High Voltage Direct Current (VSC-HVDC) Transmission Lines Energies doi: 10.3390/en11082021 Authors: Lingtong Jiang Qing Chen Wudi Huang Lei Wang Yu Zeng Pu Zhao This paper presents a novel pilot protection scheme of DC cable line in voltage-source-converter (VSC) based multi-terminal DC (MTDC) grids, which utilizes a novel phase-mode transformation to decouple the bipolar DC cable current into six mode and it uses the stationary wavelet transform to extract the modulus maxima of fault initial traveling waves current (FITWC). With accurate amplitude and polarities of the FITWC being collected from the fault-detection devices located at each terminal, the proposed scheme can correctly determine the faulty segment and the faulty pole. In this paper, the ratio of amplitudes between sixth mode forward and backward travelling wave currents is used to judge the faulty segment and the polarity of fifth mode forward travelling wave current is used to identify the faulty pole. A four-terminal VSC-based MTDC grid was built in PSCAD/EMTDC to evaluate the performance of the fault-protection scheme. Simulation results for different cases demonstrate that the proposed protection scheme is robust against noise, and has been tested successfully for fault resistance of up to 400 Ω. Since the scheme merely needs the characteristics of FITWCs, the practical difficulties of detecting subsequent travelling waves are avoided. Moreover, only the state signal is needed to send to the other side in proposed scheme, so low communication speed can satisfy the requirement of relay protection and it does not need the data synchronization seriously.

Description: Materials, Vol. 11, Pages 1350: Removal of Zinc Ions Using Hydroxyapatite and Study of Ultrasound Behavior of Aqueous Media Materials doi: 10.3390/ma11081350 Authors: Simona Liliana Iconaru Mikael Motelica-Heino Régis Guegan Mihai Valentin Predoi Alina Mihaela Prodan Daniela Predoi The present study demonstrates the effectiveness of hydroxyapatite nanopowders in the adsorption of zinc in aqueous solutions. The synthesized hydroxyapatites before (HAp) and after the adsorption of zinc (at a concentration of 50 mg/L) in solution (HApD) were characterized using X-ray diffraction (XRD), and scanning and transmission electron microscopy (SEM and TEM, respectively). The effectiveness of hydroxyapatite nanopowders in the adsorption of zinc in aqueous solutions was stressed out through ultrasonic measurements. Both Langmuir and Freundlich models properly fitted on a wide range of concentration the equilibrium adsorption isotherms, allowing us to precisely quantify the affinity of zinc to hydroxyapatite nanopowders and to probe the efficacy of hydroxyapatite in removal of zinc ions from aqueous solutions in ultrasonic conditions.

Description: Materials, Vol. 11, Pages 1344: Reducing Porosity and Refining Grains for Arc Additive Manufacturing Aluminum Alloy by Adjusting Arc Pulse Frequency and Current Materials doi: 10.3390/ma11081344 Authors: Donghai Wang Jiping Lu Shuiyuan Tang Lu Yu Hongli Fan Lei Ji Changmeng Liu Coarse grains and gas pores are two main problems that limit the application of additive manufacturing aluminum alloys. To reduce porosity and refine grains, this paper presents a quantitative investigation into the effect of pulse frequency and arc current on the porosity and grains of arc additive manufacturing Al–5Si alloy. The experiment results show that pulse frequency and arc current have a significant impact on the macrostructure, microstructure, porosity, and tensile properties of the samples. Fine grains and a uniform microstructure can be obtained with low pulse frequency and low arc current as a result of the rapid cooling of the molten pool. With the increase of pulse frequency, density shows a trend that firstly escalates and attains the maximum value at 50 Hz, but later declines as a result of the relation between pores formation and gas escape. Moreover, better tensile properties can be obtained at low pulse frequency and low arc current because of the finer grains.

Description: Materials, Vol. 11, Pages 1345: Development of a Photo-Crosslinking, Biodegradable GelMA/PEGDA Hydrogel for Guided Bone Regeneration Materials Materials doi: 10.3390/ma11081345 Authors: Yihu Wang Ming Ma Jianing Wang Weijie Zhang Weipeng Lu Yunhua Gao Bing Zhang Yanchuan Guo Gelatin-based hydrogel, which mimics the natural dermal extracellular matrix, is a promising tissue engineering material. However, insufficient and uncontrollable mechanical and degradation properties remain the major obstacles for its application in medical bone regeneration material. Herein, we develop a facile but efficient strategy for a novel hydrogel as guided bone regeneration (GBR) material. In this study, methacrylic anhydride (MA) has been used to modify gelatin to obtain photo-crosslinkable methacrylated gelatin (GelMA). Moreover, the GelMA/PEGDA hydrogel was prepared by photo-crosslinking GelMA and PEGDA with photoinitiator I2959 under UV treatment. Compared with the GelMA hydrogel, the GelMA/PEGDA hydrogel exhibits several times stronger mechanical properties than pure GelMA hydrogel. The GelMA/PEGDA hydrogel shows a suitable degradation rate of more than 4 weeks, which is beneficial to implant in body. In vitro cell culture showed that osteoblast can adhere and proliferate on the surface of the hydrogel, indicating that the GelMA/PEGDA hydrogel had good cell viability and biocompatibility. Furthermore, by changing the quantities of GelMA, I2959, and PEGDA, the gelation time can be controlled easily to meet the requirement of its applications. In short, this study demonstrated that PEGDA enhanced the performance and extended the applications of GelMA hydrogels, turning the GelMA/PEGDA hydrogel into an excellent GBR material.

Description: Materials, Vol. 11, Pages 1352: Study on Upconversion and Thermal Properties of Tm3+/Yb3+ Co-Doped La2O3-Nb2O5-Ta2O5 Glasses Materials doi: 10.3390/ma11081352 Authors: Minghui Zhang Haiqin Wen Xiuhong Pan Jianding Yu Hui Shao Fei Ai Huimei Yu Meibo Tang Lijun Gai The effect of Yb3+ ions on upconversion luminescence and thermal properties of Tm3+/Yb3+ co-doped La2O3-Nb2O5-Ta2O5 glasses has been studied. Glass transition temperature is around 740 °C, indicating high thermal stability. The effect of Yb3+ ions on the thermal stability is not obvious. Both the glass forming ability and the upconversion luminescence first increase and then decrease with the increase of Yb3+ ions. The glasses perform low glass forming ability with ΔT around 55 °C. Blue and red emissions centered around 477, 651, and 706 nm are obtained at the excitation of 976 nm laser. The upconversion luminescence mechanism is energy transfer from Yb3+ to Tm3+ mixed with two- and three- photon processes. The thermal kinetic Differential Thermal Analysis (DTA)-analysis indicates that the average activation energy first increases and then decreases with the increase of Yb3+ ions. This result can be introduced in order to improve upconversion luminescence of glasses by crystallization in the future. Tm3+/Yb3+ co-doped La2O3-Nb2O5-Ta2O5 glasses with good upconversion and thermal properties show promising applications in solid-state laser, optical temperature sensing.

Description: Energies, Vol. 11, Pages 2042: Time-Resolved Temperature Map Prediction of Concentration Photovoltaics Systems by Means of Coupled Ray Tracing Flux Analysis and Thermal Quadrupoles Modelling Energies doi: 10.3390/en11082042 Authors: Alejandro Mateos-Canseco Manuel I. Peña-Cruz Arturo Díaz-Ponce Jean-Luc Battaglia Christophe Pradère Luis David Patino-Lopez A transient 3D thermal model based on the thermal quadrupole method, coupled to ray tracing analysis, is presented. This methodology can predict transient temperature maps under any time-fluctuating irradiance flux—either synthetic or experimental—providing a useful tool for the design and parametric optimization of concentration photovoltaics systems. Analytic simulations of a concentration photovoltaics system thermal response and assessment of in-plane thermal gradients induced by fast tracking point perturbations, like those induced by wind, are provided and discussed for the first time. Computation times for time-resolved temperature maps can be as short as 9 s for a full month of system operation, with stimuli inspired by real data. Such information could pave the way for more accurate studies of cell reliability under any set of worldwide irradiance conditions.

Description: Energies, Vol. 11, Pages 2035: Experimental Investigation of Flow-Induced Motion and Energy Conversion of a T-Section Prism Energies doi: 10.3390/en11082035 Authors: Nan Shao Jijian Lian Guobin Xu Fang Liu Heng Deng Quanchao Ren Xiang Yan Flow-induced motion (FIM) performs well in energy conversion but has been barely investigated, particularly for prisms with sharp sections. Previous studies have proven that T-section prisms that undergo galloping branches with high amplitude are beneficial to energy conversions. The FIM experimental setup designed by Tianjin University (TJU) was improved to conduct a series of FIM responses and energy conversion tests on a T-section prism. Experimental results are presented and discussed, to reveal the complete FIM responses and power generation characteristics of the T-section prism under different load resistances and section aspect ratios. The main findings are summarized as follows. (1) Hard galloping (HG), soft galloping (SG), and critical galloping (CG) can be observed by varying load resistances. When the load resistances are low, HG occurs; otherwise, SG occurs. (2) In the galloping branch, the highest amplitude and the most stable oscillation cause high-quality electrical energy production by the generator. Therefore, the galloping branch is the best branch for harvesting energy. (3) In the galloping branch, as the load resistances decrease, the active power continually increases until the prism is suppressed from galloping to a vortex-induced vibration (VIV) lower branch with a maximum active power Pharn of 21.23 W and a maximum ηout of 20.2%. (4) Different section aspect ratios (α) can significantly influence the FIM responses and energy conversions of the T-section prism. For small aspect ratios, galloping is hardly observed in the complete responses, but the power generation efficiency (ηout,0.8 = 27.44%) becomes larger in the galloping branch.

Description: Materials, Vol. 11, Pages 1372: The Effect of the Morphology of Coarse Aggregate on the Properties of Self-Compacting High-Performance Fibre-Reinforced Concrete Materials doi: 10.3390/ma11081372 Authors: Krzysztof Ostrowski Łukasz Sadowski Damian Stefaniuk Daniel Wałach Tomasz Gawenda Konrad Oleksik Ireneusz Usydus When understanding the effect of the morphology of coarse aggregate on the properties of a fresh concrete mixture, the strength and deformability of self-compacting high-performance fibre-reinforced concrete (SCHPFRC) can be seen to be critical for its performance. In this research, regular and irregular grains were separated from granite coarse aggregate. The morphology of these grains was described while using digital image analysis. As a result, the aspect ratio, roundness and area ratio were determined in order to better understand this phenomenon. Then, the principal rheological, physical, and mechanical properties of SCHPFRC were determined. The obtained results indicated that the morphology of the grains of coarse aggregate has an impact on the strength and stiffness properties of SCHPFRC. Moreover, significant differences in the transverse strain of concretes were observed. The morphology of the coarse aggregate also has an impact on the rheological parameters of a fresh concrete mixture. To better understand this phenomenon, the hypothesized mechanism of the formation of SCHPFRC caused by different morphology of coarse aggregate was proposed at the end of the article.

Description: Materials, Vol. 11, Pages 1364: Recent Developments in Spectroscopic Techniques for the Detection of Explosives Materials doi: 10.3390/ma11081364 Authors: Wei Zhang Yue Tang Anran Shi Lirong Bao Yun Shen Ruiqi Shen Yinghua Ye Trace detection of explosives has been an ongoing challenge for decades and has become one of several critical problems in defense science; public safety; and global counter-terrorism. As a result, there is a growing interest in employing a wide variety of approaches to detect trace explosive residues. Spectroscopy-based techniques play an irreplaceable role for the detection of energetic substances due to the advantages of rapid, automatic, and non-contact. The present work provides a comprehensive review of the advances made over the past few years in the fields of the applications of terahertz (THz) spectroscopy; laser-induced breakdown spectroscopy (LIBS), Raman spectroscopy; and ion mobility spectrometry (IMS) for trace explosives detection. Furthermore, the advantages and limitations of various spectroscopy-based detection techniques are summarized. Finally, the future development for the detection of explosives is discussed.

Description: Materials, Vol. 11, Pages 1362: Numerical Modelling of the Effect of Filler/Matrix Interfacial Strength on the Fracture of Cementitious Composites Materials doi: 10.3390/ma11081362 Authors: Xiaowei Ouyang Zichao Pan Zhiwei Qian Yuwei Ma Guang Ye Klaas van Breugel The interface between filler and hydration products can have a significant effect on the mechanical properties of the cement paste system. With different adhesion properties between filler and hydration products, the effect of microstructural features (size, shape, surface roughness), particle distribution and area fraction of filler on the fracture behavior of a blended cement paste system is supposed to be different, as well. In order to understand the effect of the microstructural features, particle distribution and area fraction of filler on the fracture behavior of a blended cement paste system with either strong or weak filler-matrix interface, microscale simulations with a lattice model are carried out. The results show that the strength of the filler-matrix interface plays a more important role than the microstructural features, particle distribution and area fraction of filler in the crack propagation and the strength of blended cement paste. The knowledge acquired here provides a clue, or direction, for improving the performance of existing fillers. To improve the performance of fillers in cement paste in terms of strength, priority should be given to improving the bond strength between filler particles and matrix, not to modifying the microstructural features (i.e., shape and surface roughness) of the filler.

Description: Materials, Vol. 11, Pages 1361: Phase Stability and Properties of Ti-Nb-Zr Thin Films and Their Dependence on Zr Addition Materials doi: 10.3390/ma11081361 Authors: Jeonghyeon Yang Munkhbayar Baatarsukh Joohyeon Bae Sunchul Huh Hyomin Jeong Byeongkeun Choi Taehyun Nam Jungpil Noh Ternary Ti-Nb-Zr alloys were prepared by a magnetron sputtering method with porous structures observed in some of them. In bulk, in order to control the porous structure, a space holder (NH4HCO3) is used in the sintering method. However, in the present work, we show that the porous structure is also dependent on alloy composition. The results from Young’s modulus tests confirm that these alloys obey d-electrons alloy theory. However, the Young’s modulus of ternary thin films (≈80–95 GPa) is lower than that for binary alloys (≈108–123 GPa). The depth recovery ratio of ternary Ti-Nb-Zr thin films is also higher than that for binary β-Ti-(25.9–34.2)Nb thin film alloys.

Description: Materials, Vol. 11, Pages 1358: POSS Nanofiller-Induced Enhancement of the Thermomechanical Properties in a Fluoroelastomer Terpolymer Materials doi: 10.3390/ma11081358 Authors: Daphné Berthier Marie-Pierre Deffarges Nicolas Berton Mathieu Venin Florian Lacroix Bruno Schmaltz Yohan Tendron Eric Pestel François Tran-Van Stéphane Méo The present study reports on the use of three types of polyhedral oligomeric silsesquioxanes (POSS) nanoparticles with various organic substituents as fillers in a fluoroelastomer (FKM). A series of/POSS elastomer composite thin films is prepared. Microstructural SEM/TEM (scanning electron microscopy/transmission electron microscopy) imaging reveals a dispersion state allowing the presence of micron-sized domains. The influence of POSS content is studied in order to optimize thermal stability and mechanical properties of the composite thin films. Both POSS-A (with an acryloyl functional group and seven isobutyl substituents) and POSS-P (with eight phenyl substituents) lead to higher thermal stability and modulus of the composites, with respect to the unfilled FKM terpolymer matrix. covalent grafting of POSS-A onto the FKM network is found to play a critical role. Enhanced storage modulus in the rubbery plateau region (+210% at 200 °C for 20 phr) suggests that POSS-A is particularly suitable for high temperature applications.

Description: Materials, Vol. 11, Pages 1363: Synthesis of Gold Functionalised Nanoparticles with the Eranthis hyemalis Lectin and Preliminary Toxicological Studies on Caenorhabditis elegans Materials doi: 10.3390/ma11081363 Authors: Jamila Djafari Marie T. McConnell Hugo M. Santos José Luis Capelo Emilia Bertolo Simon C. Harvey Carlos Lodeiro Javier Fernández-Lodeiro The lectin found in the tubers of the Winter Aconite (Eranthis hyemalis) plant (EHL) is a Type II Ribosome Inactivating Protein (RIP). Type II RIPs have shown anti-cancer properties and have great potential as therapeutic agents. Similarly, colloidal gold nanoparticles are successfully used in biomedical applications as they can be functionalised with ligands with high affinity and specificity for target cells to create therapeutic and imaging agents. Here we present the synthesis and characterization of gold nanoparticles conjugated with EHL and the results of a set of initial assays to establish whether the biological effect of EHL is altered by the conjugation. Gold nanoparticles functionalised with EHL (AuNPs@EHL) were successfully synthesised by bioconjugation with citrate gold nanoparticles (AuNPs@Citrate). The conjugates were analysed by UV-Vis spectroscopy, Dynamic Light Scattering (DLS), Zeta Potential analysis, and Transmission Electron Microscopy (TEM). Results indicate that an optimal functionalisation was achieved with the addition of 100 µL of EHL (concentration 1090 ± 40 µg/mL) over 5 mL of AuNPs (concentration [Au0] = 0.8 mM). Biological assays on the effect of AuNPs@EHL were undertaken on Caenorhabditis elegans, a free-living nematode commonly used for toxicological studies, that has previously been shown to be strongly affected by EHL. Citrate gold nanoparticles did not have any obvious effect on the nematodes. For first larval stage (L1) nematodes, AuNPs@EHL showed a lower biological effect than EHL. For L4 stage, pre-adult nematodes, both EHL alone and AuNPs@EHL delayed the onset of reproduction and reduced fecundity. These assays indicate that EHL can be conjugated to gold nanoparticles and retain elements of biocidal activity.

Description: Materials, Vol. 11, Pages 1359: Facile Fabrication of Dumbbell-Like β-Bi2O3/Graphene Nanocomposites and Their Highly Efficient Photocatalytic Activity Materials doi: 10.3390/ma11081359 Authors: Jun Yang Taiping Xie Chenglun Liu Longjun Xu β-Bi2O3 decorated graphene nanosheets (β-Bi2O3/GN) were prepared by a facile solution mixing method. The crystal structure, surface morphology, and photo absorbance properties of the products were characterized by XRD, SEM, and UV-VIS diffuse reflection, respectively. Moreover, the effect of graphene content on photocatalytic activity was systematically investigated, and the results indicated that these composites possessed a high degradation rate of Rhodamine B (RhB), which was three times higher than that of bare β-Bi2O3 when graphene content was 1 wt %. This high photocatalytic activity was attributed predominantly to the presence of graphene, which served as an electron collector and transporter to efficiently lengthen the lifetime of the photogenerated charge carriers from β-Bi2O3.

Description: Materials, Vol. 11, Pages 1357: Radial Compressive Property and the Proof-of-Concept Study for Realizing Self-expansion of 3D Printing Polylactic Acid Vascular Stents with Negative Poisson’s Ratio Structure Materials doi: 10.3390/ma11081357 Authors: Zichao Wu Ji Zhao Wenzheng Wu Peipei Wang Bofan Wang Guiwei Li Shuo Zhang Biodegradable stents offer the potential to reduce the in-stent restenosis by providing support long enough for the vessel to heal. The polylactic acid (PLA) vascular stents with negative Poisson’s ratio (NPR) structure were manufactured by fused deposition modeling (FDM) 3D printing in this study. The effects of stent diameter, wall thickness and geometric parameters of arrowhead NPR structure on radial compressive property of 3D-printed PLA vascular stent were studied. The results showed that the decrease of stent diameter, the increase of wall thickness and the increase of the surface coverage could enhance the radial force (per unit length) of PLA stent. The radial and longitudinal size of PLA stent with NPR structure decreased simultaneously when the stent was crimped under deformation temperature. The PLA stent could expand in both radial and longitudinal direction under recovery temperature. When the deformation temperature and recovery temperature were both 65 °C, the diameter recovery ratio of stent was more than 95% and the maximum could reach 98%. The length recovery ratio was above 97%. This indicated the feasibility of utilizing the shape memory effect (SME) of PLA to realize the expansion of 3D-printed PLA vascular stent under temperature excitation.

Description: Materials, Vol. 11, Pages 1360: Effect of Annealing Temperature on ECD Grown Hexagonal-Plane Zinc Oxide Materials doi: 10.3390/ma11081360 Authors: Sukrit Sucharitakul Rangsan Panyathip Supab Choopun Zinc oxide (ZnO) offers a great potential in several applications from sensors to Photovoltaic cells thanks to the material’s dependency, to its optical and electrical properties and crystalline structure architypes. Typically, ZnO powder tends to be grown in the form of a wurtzite structure allowing versatility in the phase of material growths; albeit, whereas in this work we introduce an alternative in scalable yet relatively simple 2D hexagonal planed ZnO nanoflakes via the electrochemical deposition of commercially purchased Zn(NO3)2 and KCl salts in an electrochemical process. The resulting grown materials were analyzed and characterized via a series of techniques prior to thermal annealing to increase the grain size and improve the crystal quality. Through observation via scanning electron microscope (SEM) images, we have analyzed the statistics of the grown flakes’ hexagonal plane’s size showing a non-monotonal strong dependency of the average flake’s hexagonal flakes’ on the annealing temperature, whereas at 300 °C annealing temperature, average flake size was found to be in the order of 300 μm2. The flakes were further analyzed via transmission electron microscopy (TEM) to confirm its hexagonal planes and spectroscopy techniques, such as Raman Spectroscopy and photo luminescence were applied to analyze and confirm the ZnO crystal signatures. The grown materials also underwent further characterization to gain insights on the material, electrical, and optical properties and, hence, verify the quality of the material for Photovoltaic cells’ electron collection layer application. The role of KCl in aiding the growth of the less preferable (0001) ZnO is also investigated via various prospects discussed in our work. Our method offers a relatively simple and mass-producible method for synthesizing a high quality 2D form of ZnO that is, otherwise, technically difficult to grow or control.

Description: Materials, Vol. 11, Pages 1365: Composites of Laponite and Cu–Mn Hopcalite-Related Mixed Oxides Prepared from Inverse Microemulsions as Catalysts for Total Oxidation of Toluene Materials doi: 10.3390/ma11081365 Authors: Bogna D. Napruszewska Alicja Michalik Anna Walczyk Dorota Duraczyńska Roman Dula Wojciech Rojek Lidia Lityńska-Dobrzyńska Krzysztof Bahranowski Ewa M. Serwicka Composites of Laponite and Cu–Mn hopcalite-related mixed oxides, prepared from hydrotalcite-like (Htlc) precursors obtained in inverse microemulsions, were synthesized and characterized with XRF, XRD, SEM, TEM, H2 temperature-programmed reduction (TPR), and N2 adsorption/desorption at −196 °C. The Htlc precursors were precipitated either with NaOH or tetrabutylammonium hydroxide (TBAOH). Al was used as an element facilitating Htlc structure formation, and Ce and/or Zr were added as promoters. The composites calcined at 600 °C are mesoporous structures with similar textural characteristics. The copper–manganite spinel phases formed from the TBAOH-precipitated precursors are less crystalline and more susceptible to reduction than the counterparts obtained from the precursors synthesized with NaOH. The Cu–Mn-based composites are active in the combustion of toluene, and their performance improves further upon the addition of promoters in the following order: Ce < Zr < Zr + Ce. The composites whose active phases are prepared with TBAOH are more active than their counterparts obtained with the use of the precursors precipitated with NaOH, due to the better reducibility of the less crystalline mixed oxide active phase.

Description: Energies, Vol. 11, Pages 2070: A Simple Assessment of Housing Retrofit Policies for the UK: What Should Succeed the Energy Company Obligation? Energies doi: 10.3390/en11082070 Authors: Luciana Maria Miu Natalia Wisniewska Christoph Mazur Jeffrey Hardy Adam Hawkes Despite the need for large-scale retrofit of UK housing to meet emissions reduction targets, progress to date has been slow and domestic energy efficiency policies have struggled to accelerate housing retrofit processes. There is a need for housing retrofit policies that overcome key barriers within the retrofit sector while maintaining economic viability for customers, funding organizations, and effectively addressing UK emission reductions and fuel poverty targets. In this study, we use a simple assessment framework to assess three policies (the Variable Council Tax, the Variable Stamp Duty Land Tax, and Green Mortgage) proposed to replace the UK’s current major domestic retrofit programme known as the Energy Company Obligation (ECO). We show that the Variable Council Tax and Green Mortgage proposals have the greatest potential for overcoming the main barriers to retrofit policies while maintaining economic viability and contributing to high-level UK targets. We also show that, while none of the assessed schemes are capable of overcoming all retrofit barriers on their own, a mix of all three policies could address most barriers and provide key benefits such as wide coverage of property markets, operation on existing financial infrastructures, and application of a “carrot-and-stick” approach to incentivize retrofit. Lastly, we indicate that the specific support and protection of fuel-poor households cannot be achieved by a mix of these policies and a complementary scheme focused on fuel-poor households is required.

Description: Energies, Vol. 11, Pages 2069: Layout Optimization Design of Two Vortex Induced Piezoelectric Energy Converters (VIPECs) Using the Combined Kriging Surrogate Model and Particle Swarm Optimization Method Energies doi: 10.3390/en11082069 Authors: Xinyu An Baowei Song Zhaoyong Mao Congcong Ma The layout configuration of Vortex Induced Piezoelectric Energy Converters (VIPECs) is essential to improve its overall performance. Based on the formations of migrating geese, the configuration is characterized by two nondimensionalized layout parameters. A number of sampled points for different configurations are simulated with the two-dimensional Computation Fluid Dynamics (CFD) method. The influence of layout configurations on VIPECs’ lift force and wake structure is investigated and the generated open circuit output voltage is obtained through the derived output voltage equation. The response surface model of the output voltage of both the leading VIPEC and the following VIPEC and their summation are established using the Kriging surrogate model based on the obtained simulation results. Then, optimal layout parameters are found through the Particle Swarm Optimization (PSO) algorithm, and its predicted result is compared with that of the CFD simulation. The simulation and optimization results reveal that the output voltage is not always consistent with the lift force on the plate. When VIPECs are placed in parallel with a certain spacing, their overall performance increases. The summation of output voltage is predicted to improve by approximately 63.7% compared to two single VIPECs when they are placed at the optimal layout parameters.

Description: Energies, Vol. 11, Pages 2057: Heat Transfer Coefficient Identification in Mini-Channel Flow Boiling with the Hybrid Picard–Trefftz Method Energies doi: 10.3390/en11082057 Authors: Mirosław Grabowski Sylwia Hożejowska Anna Pawińska Mieczysław E. Poniewski Jacek Wernik This paper summarizes the results of the flow boiling heat transfer study with ethanol in a 1.8 mm deep and 2.0 mm wide horizontal, asymmetrically heated, rectangular mini-channel. The test section with the mini-channel was the main part of the experimental stand. One side of the mini-channel was closed with a transparent sight window allowing for the observation of two-phase flow structures with the use of a fast film camera. The other side of the channel was the foil insulated heater. The infrared camera recorded the 2D temperature distribution of the foil. The 2D temperature distributions in the elements of the test section with two-phase flow boiling were determined using (1) the Trefftz method and (2) the hybrid Picard–Trefftz method. These methods solved the triple inverse heat conduction problem in three consecutive elements of the test section, each with different physical properties. The values of the local heat transfer coefficients calculated on the basis of the Robin boundary condition were compared with the coefficients determined with the simplified approach, where the arrangement of elements in the test section was treated as a system of planar layers.

Description: Energies, Vol. 11, Pages 2056: Macroscopic and Microscopic Spray Characteristics of Diesel and Gasoline in a Constant Volume Chamber Energies doi: 10.3390/en11082056 Authors: Moo-Yeon Lee Gee-Soo Lee Chan-Jung Kim Jae-Hyeong Seo Ki-Hyun Kim The aim of this study is to investigate the spray characteristics of diesel and gasoline under various ambient conditions. Ambient conditions were simulated, ranging from atmospheric conditions to high pressure and temperature conditions such as those inside a combustion chamber of an internal combustion engine. Spray tip penetration and spray cross-sectional area were calculated in liquid and vapor spray development. In addition, initial spray development and end of injection near nozzle were visualized microscopically, to study spray atomization characteristics. Three injection pressures of 50 MPa, 100 MPa, and 150 MPa were tested. The ambient temperature was varied from 300 K to 950 K, and the ambient density was maintained between 1 kg/m3 and 20 kg/m3. Gasoline and diesel exhibited similar liquid penetration and spray cross-sectional area at every ambient density condition under non-evaporation. As the ambient temperature increased, liquid penetration length and spray area of both fuels’ spray were shortened and decreased by fuel evaporation near the spray boundary. However, the two fuels were characterized by different slopes in the decrement trend of spray area as the ambient temperature increased. The decrement slope trend coincided considerably with the distillation curve characteristics of the two fuels. Vapor spray boundary of gasoline and diesel was particularly similar, despite the different amount of fuel evaporation. It was assumed that the outer spray boundary of gasoline and diesel is always similar when using the same injector and injection conditions. In microscopic spray visualization, gasoline spray displayed a more unstable and asymmetric spray shape, with more dispersed and distributed fuel ligaments during initial spray development. Large amounts of fuel vapor cloud were observed near the nozzle at the end of the injection process with gasoline. Some amounts of this vapor cloud were attributed to the evaporation of residual fuel in the nozzle sac.

Description: Energies, Vol. 11, Pages 2055: Energy Retrofitting Strategies and Economic Assessments: The Case Study of a Residential Complex Using Utility Bills Energies doi: 10.3390/en11082055 Authors: Cesare Biserni Paolo Valdiserri Dario D’Orazio Massimo Garai Promotion of retrofit actions on existing buildings is a goal in Italy, since most of them were built before the 80′s when little attention was paid to energy saving. This paper presents an integrated passive design approach to reduce the heating demand and limit the costs of a representative existing residential complex located in Bologna, in the northern part of Italy. To this purpose, we explored different scenarios upon actions taken on the building structure: (1) High efficiency windows; (2) additional insulation on the external walls; or (3) the simultaneous application of high efficiency windows and improved thermal envelope, on both external walls and roofing. The numerical optimization has been performed dynamically using TRNSYS simulation tool, to evaluate energy consumptions in different structural conditions. Then, the developed model has been calibrated by the real consumption data deduced from energy bills (years 2009–2015). Finally, the energy results obtained in the above mentioned different scenarios have been evaluated under an economic assessment of cost investment: It has been highlighted that the payback time (PBT) results to be strongly influenced by the national policies of fiscal incentives. According to the present model, the most profitable condition is obtained when additional insulation on the external walls is applied: The total amount of energy saving resulted to be equal to 930.4 MWh, with an optimal PBT of roughly six years, when tax refund was contemplated.

Description: Energies, Vol. 11, Pages 2052: A Fractional Order Power System Stabilizer Applied on a Small-Scale Generation System Energies doi: 10.3390/en11082052 Authors: Florindo A. de C. Ayres Junior Carlos T. da Costa Junior Renan L. P. de Medeiros Walter Barra Junior Cleonor C. das Neves Marcelo K. Lenzi Gabriela de M. Veroneze In this paper, a Fractional Order Power System controller (FOPSS) is designed, and its performance and robustness are experimentally evaluated by tests in a 10 kVA laboratory scale power system. The FOPSS design methodology is based on the tuning of an additional design variable, namely the fractional order of the controller transfer function. This design variable is tuned aiming to obtain a tradeoff between satisfactory damping of dominant oscillating mode and improved closed-loop system robustness. For controller synthesis, transfer function models were estimated from data collected at selected operating points and subsequently applied for the controller design and for obtaining upper bounds estimates on the operating-point depends on plant uncertainties. The experimental results show that the FOPPS was able to obtain a robust performance for the considered set of the power system operating conditions.

Description: Energies, Vol. 11, Pages 2054: Lifetime Prediction of a Polymer Electrolyte Membrane Fuel Cell under Automotive Load Cycling Using a Physically-Based Catalyst Degradation Model Energies doi: 10.3390/en11082054 Authors: Manik Mayur Mathias Gerard Pascal Schott Wolfgang G. Bessler One of the bottlenecks hindering the usage of polymer electrolyte membrane fuel cell technology in automotive applications is the highly load-sensitive degradation of the cell components. The cell failure cases reported in the literature show localized cell component degradation, mainly caused by flow-field dependent non-uniform distribution of reactants. The existing methodologies for diagnostics of localized cell failure are either invasive or require sophisticated and expensive apparatus. In this study, with the help of a multiscale simulation framework, a single polymer electrolyte membrane fuel cell (PEMFC) model is exposed to a standardized drive cycle provided by a system model of a fuel cell car. A 2D multiphysics model of the PEMFC is used to investigate catalyst degradation due to spatio-temporal variations in the fuel cell state variables under the highly transient load cycles. A three-step (extraction, oxidation, and dissolution) model of platinum loss in the cathode catalyst layer is used to investigate the cell performance degradation due to the consequent reduction in the electro-chemical active surface area (ECSA). By using a time-upscaling methodology, we present a comparative prediction of cell end-of-life (EOL) under different driving behavior of New European Driving Cycle (NEDC) and Worldwide Harmonized Light Vehicles Test Cycle (WLTC).

Description: Energies, Vol. 11, Pages 1453: Comments to Paper Entitled: Development of a Data-Driven Predictive Model of Supply Air Temperature in an Air-Handling Unit for Conserving Energy. Energies 2018, 11, 407 Energies doi: 10.3390/en11061453 Authors: Yaolin Lin Wei Yang I have read, with interest, the article authorized by Hong and Kim, which was published in Energies 2018, 11, 407; doi:10.3390/en11020407: entitled “Development of a Data-Driven Predictive Model of Supply Air Temperature in an Air-Handling Unit for Conserving Energy”[...]

Description: Energies, Vol. 11, Pages 1450: Investigation of Water Hammer Protection in Water Supply Pipeline Systems Using an Intelligent Self-Controlled Surge Tank Energies doi: 10.3390/en11061450 Authors: Wuyi Wan Boran Zhang A surge tank is a common pressure control device in long pressurized pipelines. The performance is greatly influenced by the location, cross area, and the characteristics of the connector. In order to improve the property of the surge tank, the effect of the connector is numerically analyzed by the method of characteristics (MOC). A hysteretic effect can occur when the discharge capacity is limited. Therefore, the performance of the surge tank can be improved if the discharge capacity of the connector is appropriately controlled according to the different conditions. For the adjustability of the connector’s discharge capacity, a kind of intelligent self-controlled surge tank (IST) is proposed. In addition, through simulations and analysis, IST is proved to have advantages in pressure control and applicability compared to normal surge tanks.

Description: Energies, Vol. 11, Pages 1452: Impact of Demand Response Programs on Optimal Operation of Multi-Microgrid System Energies doi: 10.3390/en11061452 Authors: Anh-Duc Nguyen Van-Hai Bui Akhtar Hussain Duc-Huy Nguyen Hak-Man Kim The increased penetration of renewables is beneficial for power systems but it poses several challenges, i.e., uncertainty in power supply, power quality issues, and other technical problems. Backup generators or storage system have been proposed to solve this problem but there are limitations remaining due to high installation and maintenance cost. Furthermore, peak load is also an issue in the power distribution system. Due to the adjustable characteristics of loads, strategies on demand side such as demand response (DR) are more appropriate in order to deal with these challenges. Therefore, this paper studies how DR programs influence the operation of the multi-microgrid (MMG). The implementation is executed based on a hierarchical energy management system (HiEMS) including microgrid EMSs (MG-EMSs) responsible for local optimization in each MG and community EMS (C-EMS) responsible for community optimization in the MMG. Mixed integer linear programming (MILP)-based mathematical models are built for MMG optimal operation. Five scenarios consisting of single DR programs and DR groups are tested in an MMG test system to evaluate their impact on MMG operation. Among the five scenarios, some DR programs apply curtailing strategies, resulting in a study about the influence of base load value and curtailable load percentage on the amount of curtailed load and shifted load as well as the operation cost of the MMG. Furthermore, the impact of DR programs on the amount of external and internal trading power in the MMG is also examined. In summary, each individual DR program or group could be handy in certain situations depending on the interest of the MMG such as external trading, self-sufficiency or operation cost minimization.

Description: Energies, Vol. 11, Pages 1449: Short-Term Load Forecasting for Electric Bus Charging Stations Based on Fuzzy Clustering and Least Squares Support Vector Machine Optimized by Wolf Pack Algorithm Energies doi: 10.3390/en11061449 Authors: Xing Zhang Accurate short-term load forecasting is of momentous significance to ensure safe and economic operation of quick-change electric bus (e-bus) charging stations. In order to improve the accuracy and stability of load prediction, this paper proposes a hybrid model that combines fuzzy clustering (FC), least squares support vector machine (LSSVM), and wolf pack algorithm (WPA). On the basis of load characteristics analysis for e-bus charging stations, FC is adopted to extract samples on similar days, which can not only avoid the blindness of selecting similar days by experience, but can also overcome the adverse effects of unconventional load data caused by a sudden change of factors on training. Then, WPA with good global convergence and computational robustness is employed to optimize the parameters of LSSVM. Thus, a novel hybrid load forecasting model for quick-change e-bus charging stations is built, namely FC-WPA-LSSVM. To verify the developed model, two case studies are used for model construction and testing. The simulation test results prove that the proposed model can obtain high prediction accuracy and ideal stability.

Description: Energies, Vol. 11, Pages 1447: The Effect of Unbalanced Impedance Loads on the Short-Circuit Current Energies doi: 10.3390/en11061447 Authors: Insu Kim Conventional short-circuit studies often neglect the load current because the short-circuit current (SCC) flowing from generators is much greater than the SCC that is affected by various loading conditions. As distributed or clustered loads that are unbalanced in phases are connected to the grid, they can also change the magnitude and phase angle of the SCC, despite their small capacities. Thus, the objective of this study is to present algorithms that are able to analyze such an impedance unbalanced load. For this purpose, this study initially derives an SCC model of the unbalanced impedance load in phases. Since the proposed SCC model requires the pre-fault voltage, it uses a power-flow analysis algorithm that iteratively calculates the current that is to be injected and the pre-fault voltage, using the bus impedance matrix. Then, the proposed SCC calculation algorithm transforms the unbalanced loads into equivalent impedances, using the pre-fault voltage, and adds them to sequence networks as input data, using the proposed SCC model. The proposed algorithms are verified in various case studies. As a result, the proposed SCC calculation algorithms are more accurate, because they do not neglect unbalanced loads.

Description: Energies, Vol. 11, Pages 1451: Design of a Path-Tracking Steering Controller for Autonomous Vehicles Energies doi: 10.3390/en11061451 Authors: Chuanyang Sun Xin Zhang Lihe Xi Ying Tian This paper presents a linearization method for the vehicle and tire models under the model predictive control (MPC) scheme, and proposes a linear model-based MPC path-tracking steering controller for autonomous vehicles. The steering controller is designed to minimize lateral path-tracking deviation at high speeds. The vehicle model is linearized by a sequence of supposed steering angles, which are obtained by assuming the vehicle can reach the desired path at the end of the MPC prediction horizon and stay in a steady-state condition. The lateral force of the front tire is directly used as the control input of the model, and the rear tire’s lateral force is linearized by an equivalent cornering stiffness. The course-direction deviation, which is the angle between the velocity vector and the path heading, is chosen as a control reference state. The linearization model is validated through the simulation, and the results show high prediction accuracy even in regions of large steering angle. This steering controller is tested through simulations on the CarSim-Simulink platform (R2013b, MathWorks, Natick, MA, USA), showing the improved performance of the present controller at high speeds.

Description: Energies, Vol. 11, Pages 1442: Interaction of Wind Turbine Wakes under Various Atmospheric Conditions Energies doi: 10.3390/en11061442 Authors: Sang Lee Peter Vorobieff Svetlana Poroseva We present a numerical study of two utility-scale 5-MW turbines separated by seven rotor diameters. The effects of the atmospheric boundary layer flow on the turbine performance were assessed using large-eddy simulations. We found that the surface roughness and the atmospheric stability states had a profound effect on the wake diffusion and the Reynolds stresses. In the upstream turbine case, high surface roughness increased the wind shear, accelerating the decay of the wake deficit and increasing the Reynolds stresses. Similarly, atmospheric instabilities significantly expedited the wake decay and the Reynolds stress increase due to updrafts of the thermal plumes. The turbulence from the upstream boundary layer flow combined with the turbine wake yielded higher Reynolds stresses for the downwind turbine, especially in the streamwise component. For the downstream turbine, diffusion of the wake deficits and the sharp peaks in the Reynolds stresses showed faster decay than the upwind case due to higher levels of turbulence. This provides a physical explanation for how turbine arrays or wind farms can operate more efficiently under unstable atmospheric conditions, as it is based on measurements collected in the field.