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  • 101
    Publication Date: 2023-07-25
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉For both the meso‐ and synoptic scales, reduced mathematical models give insight into their dynamical behaviour. For the mesoscale, the weak temperature gradient approximation is one of several approaches, while for the synoptic scale the quasigeostrophic theory is well established. However, the way these two scales interact with each other is usually not included in such reduced models, thereby limiting our current perception of flow‐dependent predictability and upscale error growth. Here, we address the scale interactions explicitly by developing a two‐scale asymptotic model for the meso‐ and synoptic scales with two coupled sets of equations for the meso‐ and synoptic scales respectively. The mesoscale equations follow a weak temperature gradient balance and the synoptic‐scale equations align with quasigeostrophic theory. Importantly, the equation sets are coupled via scale‐interaction terms: eddy correlations of mesoscale variables impact the synoptic potential vorticity tendency and synoptic variables force the mesoscale vorticity (for instance due to tilting of synoptic‐scale wind shear). Furthermore, different diabatic heating rates—representing the effect of precipitation—define different flow characteristics. With weak mesoscale heating relatable to precipitation rates of 〈mml:math id="jats-math-1" display="inline" overflow="scroll"〉〈mml:mrow〉〈mml:mi〉𝒪〈/mml:mi〉〈mml:mo stretchy="false"〉(〈/mml:mo〉〈mml:mn〉6〈/mml:mn〉〈mml:mspace width="0.3em"/〉〈mml:mtext〉mm〈/mml:mtext〉〈mml:mo〉·〈/mml:mo〉〈mml:msup〉〈mml:mrow〉〈mml:mi mathvariant="normal"〉h〈/mml:mi〉〈/mml:mrow〉〈mml:mrow〉〈mml:mo form="prefix"〉−〈/mml:mo〉〈mml:mn〉1〈/mml:mn〉〈/mml:mrow〉〈/mml:msup〉〈mml:mo stretchy="false"〉)〈/mml:mo〉〈/mml:mrow〉〈/mml:math〉, the mesoscale dynamics resembles two‐dimensional incompressible vorticity dynamics and the upscale impact of the mesoscale on the synoptic scale is only of a dynamical nature. With a strong mesosocale heating relatable to precipitation rates of 〈mml:math id="jats-math-2" display="inline" overflow="scroll"〉〈mml:mrow〉〈mml:mi〉𝒪〈/mml:mi〉〈mml:mo stretchy="false"〉(〈/mml:mo〉〈mml:mn〉60〈/mml:mn〉〈mml:mspace width="0.3em"/〉〈mml:mtext〉mm〈/mml:mtext〉〈mml:mo〉·〈/mml:mo〉〈mml:msup〉〈mml:mrow〉〈mml:mi mathvariant="normal"〉h〈/mml:mi〉〈/mml:mrow〉〈mml:mrow〉〈mml:mo form="prefix"〉−〈/mml:mo〉〈mml:mn〉1〈/mml:mn〉〈/mml:mrow〉〈/mml:msup〉〈mml:mo stretchy="false"〉)〈/mml:mo〉〈/mml:mrow〉〈/mml:math〉, divergent motions and three‐dimensional effects become relevant for the mesoscale dynamics and the upscale impact also includes thermodynamical effects.〈/p〉
    Description: 〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉We develop a two‐scale asymptotic model for the meso‐ and synoptic scales following a weak temperature gradient balance and quasigeostrophic theory, but with explicit scale interactions and dependent on the mesoscale diabatic heating. With weak mesoscale heating, the mesoscale dynamics resembles 2D incompressible vorticity dynamics and the upscale impact on the synoptic scale is only of a dynamical nature. With strong mesoscale heating, divergent motions and 3D effects become relevant for the mesoscale and the upscale impact also includes thermodynamical effects. 〈boxed-text position="anchor" id="qj4456-blkfxd-0001" content-type="graphic" xml:lang="en"〉〈graphic position="anchor" id="jats-graphic-1" xlink:href="urn:x-wiley:00359009:media:qj4456:qj4456-toc-0001"〉
    Description: German Research Foundation (DFG)
    Keywords: ddc:551.5 ; asymptotics ; atmospheric dynamics ; mesoscale ; multiscale scale interactions ; quasigeostrophic ; synoptic scale
    Language: English
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  • 102
    Publication Date: 2023-07-26
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉Aquatic ecosystems play an important role in global methane cycling and many field studies have reported methane supersaturation in the oxic surface mixed layer (SML) of the ocean and in the epilimnion of lakes. The origin of methane formed under oxic condition is hotly debated and several pathways have recently been offered to explain the “methane paradox.” In this context, stable isotope measurements have been applied to constrain methane sources in supersaturated oxygenated waters. Here we present stable carbon isotope signatures for six widespread marine phytoplankton species, three haptophyte algae and three cyanobacteria, incubated under laboratory conditions. The observed isotopic patterns implicate that methane formed by phytoplankton might be clearly distinguished from methane produced by methanogenic archaea. Comparing results from phytoplankton experiments with isotopic data from field measurements, suggests that algal and cyanobacterial populations may contribute substantially to methane formation observed in the SML of oceans and lakes.〈/p〉
    Description: Plain Language Summary: Methane plays an important role in atmospheric chemistry and physics as it contributes to global warming and to the destruction of ozone in the stratosphere. Knowing the sources and sinks of methane in the environment is a prerequisite for understanding the global atmospheric methane cycle but also to better predict future climate change. Measurements of the stable carbon isotope composition of carbon—the ratio between the heavy and light stable isotope of carbon—help to identify methane sources in the environment and to distinguish them from other formation processes. We identified the carbon isotope fingerprint of methane released from phytoplankton including algal and cyanobacterial species. The observed isotope signature improves our understanding of methane cycling in the surface layers of aquatic environments helping us to better estimate methane emissions to the atmosphere.〈/p〉
    Description: Key Points: Stable carbon isotope values of methane emitted from six phytoplankton cultures incubated in the laboratory. Isotope fractionation between methane source signature and biomass of widespread algal and cyanobacterial species. Isotopic patterns of methane released by phytoplankton may be clearly distinguished from methane formed by methanogenic archaea.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: Spanish Ministry of Universities
    Description: https://doi.org/10.11588/data/YYLEKU
    Keywords: ddc:551.9 ; methane ; stable isotopes ; phytoplankton ; algae ; cyanobacteria ; methane paradox
    Language: English
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  • 103
    Publication Date: 2023-04-06
    Description: We present first data examples and an estimation of the magnitude of completeness for two BlueSeis-3A rotational seismometers deployed in the West-Bohemia/Vogtland region. The sensors show a surprisingly good sensitivity even for low magnitude events. In seven months, the "Seismologie-Verbund zur Erdbebenbeobachtung in Mitteldeutschland" reported 521 events occurring within a distance of up to 30 km. Based on the signal-noise-ratio, we estimate a magnitude of completeness around a local magnitude of 0.3 for the rotational sensors compared to the completeness of the catalog of -0.7. Moreover, we found that the transversal translation corresponds well to the vertical rotational component for a phase velocity of 2000 m/s and frequencies of 10 to 20 Hz. The data are intended to complement waveform inversions for seismic moment tensors. The study area is characterized by recurring seismic swarms, which are presumably driven by the migration of mantle fluids through the crust. In order to better understand the role of fluids in the earthquake mechanim a good resolution of the non-double-couple (i.e. volumetric and tensile) components of the seismic moment tensor is needed. In that regard, adding rotational data to the inversion has been shown beneficial in synthetic studies. The acquired data will present one of the first examples using field data to invert waveforms for the full seismic moment tensor.
    Description: poster
    Keywords: rotational seismology ; BlueSeis ; Vogtland/West-Bohemia
    Language: English
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  • 104
    Publication Date: 2023-03-15
    Description: Sea level rise caused by climate change represents a challenge to coastal flood protection measures, particularly in regions such as the federal state of Schleswig-Holstein. Large parts along the North Sea coast are protected by dikes and offshore islands provide additional shelter to the hinterland, which often lies just above or even beneath sea level. We have examined InSAR time series data from the German Ground Motion Service along the entire west coast dike route from the Danish border to Wedel. We want to estimate how these data can be used to detect and monitor ground motion processes related to dikes, especially in cases where PS (persistent scatterer) are irregularly distributed. We found, that mainly those parts of the dikes can be monitored by PS interferometry where the seaward dike base is shielded by heavy armourstone acting as sufficient back-scatters for radar waves. Here, ground motion processes induced by additional load of reinforcing construction work can be observed. In some regions the dikes are influenced by long-term, large-scale subsidence. We performed statistical analysis on low pass filtered PS time series to automatically identify significant ground motion and/or ground motion events within a local area of interest. Preliminary results suggest, that we may be able to identify dike segments which show signs of anomalous ground motion and thus should be monitored closely.
    Description: poster
    Keywords: InSAR ; Ground motion ; Schleswig-Holstein ; Dike ; Geophysik
    Language: English
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  • 105
    Publication Date: 2023-03-14
    Description: Providing measurements for scientific simulation software often requires tedious manual preprocessing of data sets. To overcome this problem and make it easy for simulation tools to access heterogeneous data sets directly, we have developed the Ice Data Hub. The Ice Data Hub combines available data from Earth or other planetary bodies including their meta data and allows it to be displayed, interpreted and exported. Most important is its functionality as an interface between data and simulation tools. For example, we develop models for thermodynamic melting processes that can evaluate measured data directly thanks to the Ice Data Hub. It can also be used as a black box, where a simulation tool queries the Hub to provide a property. This could, for example, be a material property at a certain depth. The accessing functionality for the user is wrapped in the sense that the user uses similar routines, regardless the format of data, e.g., analytical expression, look-up table or interpolant. To illustrate the capabilities of the Ice Data Hub, we show results of 1) thermal conductivity simulations in glacial ice with temperature data from Langenferner Glacier, Italy, and 2) trajectory models of ice melting probes compared with housekeeping data from field experiments at Taylor Glacier, Antarctica. 1) The observed temperature evolution from a measured time series of 1D temperature observations in an interval of one hour differs from the theoretically predicted temperature evolution, which was determined on the basis of an idealised seasonal and diurnal temperature variation at the surface and constant ice material parameters. Hence, we reconstruct spatio-temporally varying effective material parameters from these observations using the Crank Nicolson Method. 2) Ice melting probes are developed to penetrate ice and access potential subglacial water reservoirs for insitu studies. The ice-sheet transit provides an excellent opportunity to study the structure and composition of the ice itself using geophysical and other in-situ measurements. Both housekeeping data and scientific sensors of the ice melting probe can be used to derive ice properties and analyse it with various tools via the Ice Data Hub. The Ice Data Hub facilitates the functionality needed to make data repositories of different format simulationready and guarantee reproducibility of data-integrated simulations. It is planned to make the Ice Data Hub available as open source software in the near future.
    Description: poster
    Language: English
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  • 106
    Publication Date: 2024-02-12
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉Sediment composition in modern fluvial settings is commonly assessed regarding spatial but rarely temporal variability, potentially leading to a bias of unknown extent. Here, we present the grain‐size distribution, bulk chemical and mineralogical composition of a time‐series set of 36 suspended sediment samples from the Brahmaputra river, as well as clay and heavy mineral analysis of selected samples. Sampling covers the June–November 2021 period, which included two major flooding events. We show that the two flooding events are characterized by contrasting grain size, with the first event characterized by a grain‐size minimum and the second by a grain‐size maximum. Although grain sizes of the first flood and the period after the second are similar, their compositions differ significantly, highlighted by a factor‐two decrease of biotite largely compensated by an increase in quartz. By contrast, the content of garnet, clinopyroxene, sillimanite, and rutile increased compared to epidote and amphibole during the second flood event. By relating the results to spatio‐temporal rainfall and discharge patterns and basin morphology, we conclude that the first flooding primarily mobilized hydraulically pre‐sorted sediments from the exposed sandbars of the floodplains, while those sandbars are already submerged during the second flooding in a single‐channel system, resulting in higher sediment contributions from highland tributaries draining igneous and high‐grade metamorphic rocks. Such temporal variations pose constraints on the interpretation of compositional differences between individual samples regarding sediment provenance and dispersal and should be considered in studies of modern drainage basins as well as ancient sediment routing systems.〈/p〉
    Description: Plain Language Summary: Sediment provenance, which refers to where the sediment in a river comes from, is important to understand because it can tell us about the geology of an area, various earth‐surface processes and how the landscape is changing over time. However, sediment provenance is typically studied at a spatial scale in present day river basins, and temporal variability is rarely considered. This study examines the physical, chemical and mineralogical properties of sediment in the Brahmaputra river during two major flooding events that occurred in the same season. The results show that the sediment composition varies between the events, indicating a change in the relative proportions of distinct sources. This emphasizes the importance of considering temporal variations in sediment composition when interpreting sediment provenance signals.〈/p〉
    Description: Key Points: 〈list list-type="bullet"〉 〈list-item〉 〈p xml:lang="en"〉Time‐series analysis of sediment composition during two major flooding events of a single monsoon season is presented〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉The two flooding events show contrasting grain‐size, chemical and mineralogical composition〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉Temporal variations in sediment composition pose constraints on the interpretation of provenance and dispersal based on individual samples〈/p〉〈/list-item〉 〈/list〉 〈/p〉
    Description: DAAD
    Description: German Ministry of Education and Research
    Description: https://doi.org/10.5281/zenodo.7588054
    Description: http://flood.umd.edu/
    Keywords: ddc:551.3 ; sediment provenance ; temporal variability ; intra‐seasonal ; Brahmaputra ; eastern Himalaya
    Language: English
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  • 107
    Publication Date: 2024-02-12
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉Extreme temperature events have traditionally been detected assuming a unimodal distribution of temperature data. We found that surface temperature data can be described more accurately with a multimodal rather than a unimodal distribution. Here, we applied Gaussian Mixture Models (GMM) to daily near‐surface maximum air temperature data from the historical and future Coupled Model Intercomparison Project Phase 6 (CMIP6) simulations for 46 land regions defined by the Intergovernmental Panel on Climate Change. Using the multimodal distribution, we found that temperature extremes, defined based on daily data in the warmest mode of the GMM distributions, are getting more frequent in all regions. Globally, a 10‐year extreme temperature event relative to 1985–2014 conditions will occur 13.6 times more frequently in the future under 3.0°C of global warming levels (GWL). The frequency increase can be even higher in tropical regions, such that 10‐year extreme temperature events will occur almost twice a week. Additionally, we analyzed the change in future temperature distributions under different GWL and found that the hot temperatures are increasing faster than cold temperatures in low latitudes, while the cold temperatures are increasing faster than the hot temperatures in high latitudes. The smallest changes in temperature distribution can be found in tropical regions, where the annual temperature range is small. Our method captures the differences in geographical regions and shows that the frequency of extreme events will be even higher than reported in previous studies.〈/p〉
    Description: Plain Language Summary: Extreme temperature events are unusual weather conditions with exceptionally low or high temperatures. Traditionally, the temperature range was determined by assuming a single distribution, which describes the frequency of temperatures at a given climate using their mean and variability. This single distribution was then used to detect extreme weather events. In this study, we found that temperature data from reanalyses and climate models can be more accurately described using a mixture of multiple Gaussian distributions. We used the information from this mixture of Gaussians to determine the cold and hot extremes of the distributions. We analyzed their change in a future climate and found that hot temperature extremes are getting more frequent in all analyzed regions at a rate that is even higher than found in previous studies. For example, a global 10‐year event will occur 13.6 times more frequently under 3.0°C of global warming. Furthermore, our results show that the temperatures of hot days will increase faster than the temperature of cold days in equatorial regions, while the opposite will occur in polar regions. Extreme hot temperatures will be the new normal in highly populated regions such as the Mediterranean basin.〈/p〉
    Description: Key Points: 〈list list-type="bullet"〉 〈list-item〉 〈p xml:lang="en"〉Extreme temperature events are detected with Gaussian Mixture Models to follow a multimodal rather than a unimodal distribution〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉10‐year temperature extremes will occur 13.6 times more frequently under 3.0°C future warming〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉Colder days are getting warmer faster than hotter days in high latitudes, whereas it is the opposite for many regions in low latitudes〈/p〉〈/list-item〉 〈/list〉 〈/p〉
    Description: European Research Council http://dx.doi.org/10.13039/501100000781
    Description: https://github.com/EyringMLClimateGroup/pacal23jgr_GaussianMixtureModels_Extremes
    Description: https://doi.org/10.5281/zenodo.3401363
    Keywords: ddc:551.5 ; extreme events ; Gaussian mixture models ; daily maximum temperatures ; return periods ; bimodal distributions ; multimodal distributions
    Language: English
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  • 108
    Publication Date: 2024-02-12
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉Chaos terrains are geologically young and extensively disrupted surface features of Europa, thought to be an expression of the subsurface ocean interacting with the surface. The most prominent examples of this terrain on Europa are Conamara Chaos, and Thera and Thrace Maculae, all prime targets for the upcoming JUICE and Europa Clipper missions to assess the astrobiological potential of Europa. Of the three features, Thrace Macula is currently the least studied and understood. It intersects both Agenor Linea to the north and Libya Linea to the south, two important regional‐scale bands whose interaction with Thrace is yet to be fully unraveled, especially in terms of their relative ages of emplacement and activity. Using Galileo Solid State Imager data and Digital Terrain Models, we conducted detailed structural mapping and terrain analysis to develop a novel hypothesis on the mechanisms involved in the study area. We find that Thrace Macula is bordered along most sides by preexisting strike‐slip faults that have constrained its emplacement and areal distribution. We determine a sequence of events in the area involving the formation of Agenor Linea, followed by that of Libya Linea first and Thrace Macula later, and ultimately by strike‐slip tectonic activity likely driven by Libya Linea, that displaced a portion of Thrace Macula. Therefore, Thrace's subsurface material, uprising along faults postdating its formation, represents the freshest possible that could be sampled by future spacecraft in this region, a major consideration for the upcoming Europa Clipper mission.〈/p〉
    Description: Plain Language Summary: Europa, an icy moon of Jupiter with a large subterranean water reservoir, has unique surface features known as chaos terrains, believed to result from interactions between its subsurface ocean and surface. Of these terrains, Conamara Chaos and Thera and Thrace Maculae are prime targets for upcoming missions to investigate the astrobiological potential of Europa. However, Thrace Macula, which is situated between Agenor Linea to the north and Libya Linea to the south (two large‐scale bands, linear geological features), remains poorly understood. In this study, we used detailed mapping of faults and lineaments, together with topographical analysis, to propose a new hypothesis for the formation and evolution of Thrace Macula. Our findings suggest that preexisting tectonic faults constrained its emplacement and distribution, while a sequence of events starting with the formation of Agenor Linea, followed by Libya Linea first and Thrace Macula later, culminated in strike‐slip tectonic activity likely driven by Libya Linea that displaced a portion of Thrace Macula. These results imply that future spacecraft could sample Thrace's subsurface material uplifting along faults postdating its formation, the freshest available in this region. This research sheds light on Europa's regional history and its astrobiological potential.〈/p〉
    Description: Key Points: 〈list list-type="bullet"〉 〈list-item〉 〈p xml:lang="en"〉We conducted structural analysis on Thrace Macula, a chaotic terrain on Europa, based on imaging and newly processed topographic data〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉We found that preexisting strike‐slip faults border Thrace Macula and have constrained its emplacement and areal distribution〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉We provide insights into the history of Thrace and identify it as a prime location for future missions to sample fresh subsurface material〈/p〉〈/list-item〉 〈/list〉 〈/p〉
    Description: HORIZON EUROPE European Research Council http://dx.doi.org/10.13039/100019180
    Description: https://doi.org/10.17189/1520425
    Description: https://doi.org/10.5066/P9VKKK7C
    Description: https://doi.org/10.17169/refubium-38694
    Keywords: ddc:523 ; Europa ; chaos ; Thrace Macula ; strike‐slip tectonics ; Digital Terrain Models ; Europa Clipper
    Language: English
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  • 109
    Publication Date: 2024-02-28
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉The ultimate demise of the Laurentide Ice Sheet (LIS) and the preceding and succeeding oceanographic changes along the western Labrador Sea offer insights critically important to improve climate predictions of expected future climate warming and further melting of the Greenland ice cap. However, while the final disappearance of the LIS during the Holocene is rather well constrained, the response of sea ice during the resulting meltwater events is not fully understood. Here, we present reconstructions of paleoceanographic changes over the past 9.3 Kyr BP on the northwestern Labrador Shelf, with a special focus on the interaction between the final meltwater event around 8.2 Kyr BP and sea ice and phytoplankton productivity (e.g., IP〈sub〉25〈/sub〉, HBI III (Z), brassicasterol, dinosterol, biogenic opal, total organic carbon). Our records indicate low sea‐ice cover and high phytoplankton productivity on the Labrador Shelf prior to 8.9 Kyr BP, sea‐ice formation was favored by decreased surface salinities due to the meltwater events from Lake Agassiz‐Ojibway and the Hudson Bay Ice Saddle from 8.55 Kyr BP onwards. For the past ca. 7.5 Kyr BP sea ice is mainly transported to the study area by local ocean currents such as the inner Labrador and Baffin Current. Our findings provide new insights into the response of sea ice to increased meltwater discharge as well as shifts in atmospheric and oceanic circulation.〈/p〉
    Description: Key Points: 〈list list-type="bullet"〉 〈list-item〉 〈p xml:lang="en"〉Sea ice on the Labrador Shelf mainly follows the solar insolation and meltwater input from the decaying Laurentide Ice Sheet〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉Sea ice increased following the Lake Agassiz outburst and Hudson Bay Ice Saddle Collapse between 8.5 and 8.2 Kyr BP〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉Low sea ice conditions during the Holocene Thermal Maximum were replaced by an increase following the Neoglacial cooling trend〈/p〉〈/list-item〉 〈/list〉 〈/p〉
    Description: Ocean Frontier Institute
    Description: NSERC
    Description: https://doi.org/10.4095/221564
    Description: https://doi.org/10.1594/PANGAEA.949244
    Description: https://doi.org/10.5281/zenodo.8247131
    Description: https://doi.org/10.1594/PANGAEA.949065
    Description: https://doi.org/10.1594/PANGAEA.949056
    Keywords: ddc:551.7 ; sea ice ; Atlantic Ocean ; IP25 ; 8.2 event
    Language: English
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  • 110
    Publication Date: 2024-02-28
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉Extremely high land surface temperatures affect soil ecological processes, alter land‐atmosphere interactions, and may limit some forms of life. Extreme surface temperature hotspots are presently identified using satellite observations or deduced from complex Earth system models. We introduce a simple, yet physically based analytical approach that incorporates salient land characteristics and atmospheric conditions to globally identify locations of extreme surface temperatures and their upper bounds. We then provide a predictive tool for delineating the spatial extent of land hotspots at the limits to biological adaptability. The model is in good agreement with satellite observations showing that temperature hotspots are associated with high radiation and low wind speed and occur primarily in Middle East and North Africa, with maximum temperatures exceeding 85°C during the study period from 2005 to 2020. We observed an increasing trend in maximum surface temperatures at a rate of 0.17°C/decade. The model allows quantifying how upper bounds of extreme temperatures can increase in a warming climate in the future for which we do not have satellite observations and offers new insights on potential impacts of future warming on limits to plant growth and biological adaptability.〈/p〉
    Description: Plain Language Summary: While satellite imagery can identify extreme land surface temperatures, land and atmospheric conditions for the onset of maximum land surface temperature (LST) have not yet been globally explored. We developed a physically based analytical model for quantifying the value and spatial extent of maximum LST and provide insights into combinations of land and atmospheric conditions for the onset of such temperature extremes. Results show that extreme LST hotspots occur primarily in the Middle East and North Africa with highest values near 85°C. Importantly, persistence of surface temperatures exceeding 75°C limits vegetation growth and disrupts primary productivity such as in Lut desert in Iran. The study shows that with global warming, regions with prohibitive land surface temperatures will expand.〈/p〉
    Description: Key Points: 〈list list-type="bullet"〉 〈list-item〉 〈p xml:lang="en"〉Hotspots for high land surface temperatures (LSTs) were globally identified using a physically based analytical approach incorporating land and atmospheric conditions〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉High LSTs primarily occur in Middle East and North Africa with values exceeding 85°C〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉Maximum LSTs rising at a rate of 0.17°C/decade may limit plant growth and biological adaptability in a warming world〈/p〉〈/list-item〉 〈/list〉 〈/p〉
    Description: Hamburg University of Technology
    Description: European Union's Horizon Europe Research and Innovation Programme
    Description: https://disc.gsfc.nasa.gov/datasets/M2I1NXLFO_5.12.4/summary
    Description: https://disc.gsfc.nasa.gov/datasets/M2T1NXRAD_5.12.4/summary
    Description: https://doi.org/10.5067/MODIS/MCD12C1.006
    Description: https://doi.org/10.3133/ofr20111073
    Description: https://www.nccs.nasa.gov/services/data-collections/land-based-products/nex-gddp-cmip6
    Description: https://doi.org/10.3334/ORNLDAAC/1247
    Keywords: ddc:551.5 ; maximum land surface temperature (LST) ; land conditions ; atmospheric conditions ; LST hotspots
    Language: English
    Type: doc-type:article
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  • 111
    Publication Date: 2024-02-28
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉High spatio‐temporal resolution near‐surface projected data is vital for climate change impact studies and adaptation. We derived the highest statistically downscaled resolution multivariate ensemble currently available: daily 1 km until the end of the century. Deep learning models were employed to develop transfer functions for precipitation, water vapor pressure, radiation, wind speed, and, maximum, mean and minimum temperature. Perfect prognosis is the particular statistical downscaling methodology applied, using a subset of the ReKIS data set for Saxony as predictands, the ERA5 reanalysis as during‐training predictors and the CORDEX‐EUR11 ensemble as projected predictors. The performance of the transfer functions was validated with the VALUE framework, yielding highly satisfactory results. Particular attention was given to the three major perfect prognosis assumptions, for which several tests were carried out and thoroughly discussed. From the latter, we corroborated their fulfillment to a high degree, thus, the derived projections are considered adequate and relevant for impact modelers. In total, 18 runs for RCP85, 1 for RCP45, and 4 for RCP26 were downscaled under both stochastic and deterministic approaches. This multivariate ensemble could drive more accurate and diverse impact studies in the region. Generally, the projected climatologies are in agreement with coarser resolution projections. Nevertheless, statistical particularities were observed for some projections, thus, a list of caveats for potential users is given. Due to the scalability of the presented methodology, further possible applications with additional datasets are proposed. Lastly, several potential improvement prospects are discussed toward the ideal subsequent iteration of the perfect prognosis statistical downscaling methodology.〈/p〉
    Description: Plain Language Summary: There is a great worldwide demand for high spatio‐temporal resolution projections to develop climate change adaptation and mitigation schemes. Despite recent improvements, the resolution of both global and regional climate models is still too coarse to properly represent local variability, particularly in complex terrains. Depending on the application, impact modelers and decision makers require kilometer‐scale projections, with a minimum daily temporal resolution, of near‐surface variables. To fill this information gap, we employed artificial intelligence algorithms to downscale, to a novel daily 1 km resolution, a projection ensemble until the end of the century consisting of precipitation, water vapor pressure, radiation, wind speed, and, maximum, mean and minimum temperature. The ensemble comprises 18 runs of the business‐as‐usual worst‐case scenario (RCP85), 1 run of the stabilization scenario (RCP45), and 4 of the optimistic low‐emissions scenario (RCP26). The main assumptions of the methodology were thoroughly tested and discussed. The validation carried out yielded highly satisfactory results. Thus, we consider the projections to be adequate and relevant for impact studies. The region studied is located in Saxony (Germany), still, the methodology shown is potentially applicable anywhere in the world.〈/p〉
    Description: Key Points: 〈list list-type="bullet"〉 〈list-item〉 〈p xml:lang="en"〉Highest statistically downscaled spatio‐temporal resolution multivariate ensemble currently available, consisting of 23 projection runs〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉We downscaled precipitation, water vapor pressure, radiation, wind speed, and, maximum, mean and minimum temperature〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉The methodology complied to a high degree with the three perfect prognosis assumptions and is scalable to other spatio‐temporal resolutions〈/p〉〈/list-item〉 〈/list〉 〈/p〉
    Description: European Social Fund, Freistaat Sachsen http://dx.doi.org/10.13039/501100004895
    Description: https://rekis.hydro.tu-dresden.de/
    Description: https://doi.org/10.5281/zenodo.7570247
    Description: https://doi.org/10.5281/zenodo.7559173
    Description: https://doi.org/10.5281/zenodo.7558945
    Description: https://doi.org/10.5281/zenodo.8059248
    Description: https://doi.org/10.5281/zenodo.8198925
    Keywords: ddc:551.6 ; climate change ; statistical downscaling ; perfect prognosis ; ERA5 ; CORDEX ; deep learning ; multivariate ensemble
    Language: English
    Type: doc-type:article
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  • 112
    Publication Date: 2024-03-05
    Description: Land surface heterogeneity in conjunction with ambient winds influences the convective atmospheric boundary layer by affecting the distribution of incoming solar radiation and forming secondary circulations. This study performed coupled large‐eddy simulation (ICON‐LEM) with a land surface model (TERRA‐ML) over a flat river corridor mimicked by soil moisture heterogeneity to investigate the impact of ambient winds on secondary circulations. The coupled model employed double‐periodic boundary conditions with a spatial scale of 4.8 km. All simulations used the same idealized initial atmospheric conditions with constant incident radiation of 700 W⋅m〈sup〉−2〈/sup〉 and various ambient winds with different speeds (0 to 16 m⋅s〈sup〉−1〈/sup〉) and directions (e.g., cross‐river, parallel‐river, and mixed). The atmospheric states are decomposed into ensemble‐averaged, mesoscale, and turbulence. The results show that the secondary circulation structure persists under the parallel‐river wind conditions independently of the wind speed but is destroyed when the cross‐river wind is stronger than 2 m⋅s〈sup〉−1〈/sup〉. The soil moisture and wind speed determine the influence on the surface energy distribution independent of the wind direction. However, secondary circulations increase advection and dispersive heat flux while decreasing turbulent energy flux. The vertical profiles of the wind variance reflect the secondary circulation, and the maximum value of the mesoscale vertical wind variance indicates the secondary circulation strength. The secondary circulation strength positively scales with the Bowen ratio, stability parameter (−Z〈sub〉i〈/sub〉/L), and thermal heterogeneity parameter under cross‐river wind and mixed wind conditions. The proposed similarity analyses and scaling approach provide a new quantitative perspective on the impact of the ambient wind under heteronomous soil moisture conditions on secondary circulation.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Keywords: ddc:551.5 ; ambient winds ; Bowen ratio ; land surface model ; large‐eddy simulation ; moisture spatial heterogeneity ; secondary circulation ; similarity theory ; turbulence
    Language: English
    Type: doc-type:article
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  • 113
    Publication Date: 2024-03-05
    Description: Full‐field X‐ray nanoimaging is a widely used tool in a broad range of scientific areas. In particular, for low‐absorbing biological or medical samples, phase contrast methods have to be considered. Three well established phase contrast methods at the nanoscale are transmission X‐ray microscopy with Zernike phase contrast, near‐field holography and near‐field ptychography. The high spatial resolution, however, often comes with the drawback of a lower signal‐to‐noise ratio and significantly longer scan times, compared with microimaging. In order to tackle these challenges a single‐photon‐counting detector has been implemented at the nanoimaging endstation of the beamline P05 at PETRA III (DESY, Hamburg) operated by Helmholtz‐Zentrum Hereon. Thanks to the long sample‐to‐detector distance available, spatial resolutions of below 100 nm were reached in all three presented nanoimaging techniques. This work shows that a single‐photon‐counting detector in combination with a long sample‐to‐detector distance allows one to increase the time resolution for in situ nanoimaging, while keeping a high signal‐to‐noise level.
    Description: A direct photon‐counting detector was used for different nanoimaging phase contrast techniques, increasing the temporal resolution.
    Keywords: ddc:548 ; nanotomography ; full‐field X‐ray microscopy ; near‐field holography ; near‐field ptychography ; Zernike phase contrast ; single‐photon‐counting detector ; phase contrast
    Language: English
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  • 114
    Publication Date: 2024-03-05
    Description: Arctic warming causes permafrost thaw and accelerates microbial decomposition of soil organic matter (SOM) to carbon dioxide (CO〈sub〉2〈/sub〉) and methane (CH〈sub〉4〈/sub〉). The determining factors for the ratio between CO〈sub〉2〈/sub〉 and CH〈sub〉4〈/sub〉 formation are still not well understood due to scarce in situ measurements, particularly in remote Arctic regions. We quantified the CO〈sub〉2〈/sub〉:CH〈sub〉4〈/sub〉 ratios of SOM decomposition in wet and dry tundra soils by using CO〈sub〉2〈/sub〉 fluxes from clipped plots and in situ CH〈sub〉4〈/sub〉 fluxes from vegetated plots. At the water‐saturated site, CO〈sub〉2〈/sub〉:CH〈sub〉4〈/sub〉 ratios decreased sharply from 95 at beginning of July to about 10 in August and September with a median of 12.2 (7.70–17.1; 25%–75% quartiles) over the whole vegetation period. When considering CH〈sub〉4〈/sub〉 oxidation, estimated to reduce in situ CH〈sub〉4〈/sub〉 fluxes by 10%–31%, even lower CO〈sub〉2〈/sub〉:CH〈sub〉4〈/sub〉 ratios were calculated (median 10.9–8.41). Active layer depth and soil temperature were the main factors controlling these ratios. Methane production was associated with subsoil (40 cm) temperature, while heterotrophic respiration was related to topsoil (5 cm) temperatures. As expected, CO〈sub〉2〈/sub〉:CH〈sub〉4〈/sub〉 ratios were substantially higher at the dry site (median 373, 292–500, 25%–75% quartiles). Both tundra types lost carbon preferentially in form of CO〈sub〉2〈/sub〉, and CH〈sub〉4〈/sub〉‐C represented only 0.27% of the dry tundra total carbon loss and 6.91% of the wet tundra total carbon loss. The current study demonstrates the dynamic of in situ CO〈sub〉2〈/sub〉:CH〈sub〉4〈/sub〉 ratios from SOM decomposition and will help improve simulations of future CO〈sub〉2〈/sub〉 and CH〈sub〉4〈/sub〉 fluxes from thawing tundra soils.
    Description: Plain Language Summary: Global warming causes the thaw of the permanently frozen soil in Arctic regions, exposing soil organic matter (SOM) previously frozen to decomposition, increasing the emission of carbon dioxide (CO〈sub〉2〈/sub〉) and methane (CH〈sub〉4〈/sub〉), which are greenhouse gases. It is crucial to quantify the ratio of CO〈sub〉2〈/sub〉 and CH〈sub〉4〈/sub〉 produced because CH〈sub〉4〈/sub〉 has a stronger global warming potential than CO〈sub〉2〈/sub〉. We partitioned SOM decomposition into CO〈sub〉2〈/sub〉 and CH〈sub〉4〈/sub〉 formation (CO〈sub〉2〈/sub〉:CH〈sub〉4〈/sub〉 ratios) in wet and dry tundra soils on Samoylov Island, Northeastern Siberia, and we related these ratios to environmental variables. Deeper active layer, which is the topsoil layer that freezes and thaws annually, and higher subsoil (40 cm) temperature at the interface between the active layer and the permafrost, foster CH4 production and decrease CO〈sub〉2〈/sub〉:CH〈sub〉4〈/sub〉 ratios. Carbon was preferentially lost in form of CO〈sub〉2〈/sub〉 by the soils, but CH〈sub〉4〈/sub〉 had a larger contribution to the carbon loss in the wet tundra. Our study indicates that warming and deepening of the active layer can result in rising CH〈sub〉4〈/sub〉 production. Further understanding of in situ CO〈sub〉2〈/sub〉:CH〈sub〉4〈/sub〉 ratios from SOM decomposition will help improve simulations on future CO〈sub〉2〈/sub〉 and CH〈sub〉4〈/sub〉 fluxes from thawing tundra soils.
    Description: Key Points: Topsoil (5 cm) warming increases the CO〈sub〉2〈/sub〉:CH〈sub〉4〈/sub〉 production ratio, while warming of subsoil (40 cm) leads to lower CO〈sub〉2〈/sub〉:CH〈sub〉4〈/sub〉 production ratios. The CO〈sub〉2〈/sub〉:CH〈sub〉4〈/sub〉 production ratio is associated with active‐layer depth (ALD) due to a direct effect of ALD on CH〈sub〉4〈/sub〉 production. Carbon was preferentially lost in form of CO〈sub〉2〈/sub〉 at wet and dry sites, but CH〈sub〉4〈/sub〉 had a higher contribution at the wet tundra site.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: Clusters of Excellence CliSAP
    Description: https://doi.pangaea.de/10.1594/PANGAEA.944841
    Description: https://doi.pangaea.de/10.1594/PANGAEA.944844
    Keywords: ddc:631.4 ; thaw depth ; methanogenesis ; heterotrophic respiration ; chamber ; greenhouse gases ; active layer thickening
    Language: English
    Type: doc-type:article
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  • 115
    Publication Date: 2024-03-05
    Description: We report the results of position ties for short baselines at eight geodetic sites based on phase delays that are extracted from global geodetic very‐long‐baseline interferometry (VLBI) observations rather than dedicated short‐baseline experiments. An analysis of phase delay observables at X band from two antennas at the Geodetic Observatory Wettzell, Germany, extracted from 107 global 24‐hr VLBI sessions since 2019 yields weighted root‐mean‐square scatters about the mean baseline vector of 0.3, 0.3, and 0.8 mm in the east, north, and up directions, respectively. Position ties are also obtained for other short baselines between legacy antennas and nearby, newly built antennas. They are critical for maintaining a consistent continuation of the realization of the terrestrial reference frame, especially when including the new VGOS network. The phase delays of the baseline WETTZ13N–WETTZELL enable an investigation of sources of error at the sub‐millimeter level. We found that a systematic variation of larger than 1 mm can be introduced to the Up estimates of this baseline vector when atmospheric delays were estimated. Although the sub‐millimeter repeatability has been achieved for the baseline vector WETTZ13N–WETTZELL, we conclude that long term monitoring should be conducted for more short baselines to assess the instrumental effects, in particular the systematic differences between phase delays and group delays, and to find common solutions for reducing them. This will be an important step toward the goal of global geodesy at the 1 mm level.
    Description: Plain Language Summary: We report the results of position ties for short baselines at eight geodetic sites based on phase delays that are extracted from global geodetic very‐long‐baseline interferometry (VLBI) observations rather than dedicated short‐baseline experiments. By using the inherently more precise observables—phase delays, a baseline vector repeatability of WETTZ13N–WETTZELL has been achieved at the sub‐millimeter level for the horizontal directions and at the 1 mm level for the vertical direction based on VLBI experiments of 107 days during 3.5 years. Position ties based on phase delays are also obtained for other short baselines between legacy antennas and nearby, newly built antennas, and they are critical to maintain a consistent continuation of the realization of terrestrial reference frame into the future of a network of these new antennas. We have evaluated the instrumental stability at the 1 mm level, which is an important step toward the goal of global geodesy at this level.
    Description: Key Points: Baseline vectors between legacy antennas and co‐located VGOS antennas are obtained from phase delays with the highest possible precision. Sources of error in short‐baseline observations are investigated at the 1 mm level in terms of their potential impacts.
    Description: Academy of Finland http://dx.doi.org/10.13039/501100002341
    Description: https://ivscc.gsfc.nasa.gov/productsdata/data.html
    Description: https://sourceforge.net/projects/nusolve/
    Keywords: ddc:526 ; geodetic VLBI ; phase delays ; reference frames ; ITRF ; VGOS ; GGOS
    Language: English
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  • 116
    Publication Date: 2024-03-05
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉Light‐absorbing impurities such as mineral dust can play a major role in reducing the albedo of snow surfaces. Particularly in spring, deposited dust particles lead to increased snow melt and trigger further feedbacks at the land surface and in the atmosphere. Quantifying the extent of dust‐induced variations is difficult due to high variability in the spatial distribution of mineral dust and snow. We present an extension of a fully coupled atmospheric and land surface model system to address the impact of mineral dust on the snow albedo across Eurasia. We evaluated the short‐term effects of Saharan dust in a case study. To obtain robust results, we performed an ensemble simulation followed by statistical analysis. Mountainous regions showed a strong impact of dust deposition on snow depth. We found a mean significant reduction of −1.4 cm in the Caucasus Mountains after 1 week. However, areas with flat terrain near the snow line also showed strong effects despite lower dust concentrations. Here, the feedback to dust deposition was more pronounced as increase in surface temperature and air temperature. In the region surrounding the snow line, we found an average significant surface warming of 0.9 K after 1 week. This study shows that the impact of mineral dust deposition depends on several factors. Primarily, these are altitude, slope, snow depth, and snow cover fraction. Especially in complex terrain, it is therefore necessary to use fully coupled models to investigate the effects of mineral dust on snow pack and the atmosphere.〈/p〉
    Description: Plain Language Summary: Dust particles such as Saharan dust can darken snow surfaces, leading to increased absorption of solar radiation. The result is earlier snow melt in the spring and a warming of the land surface. Predicting dust deposition and subsequent regional impacts is difficult because the distribution of snow and dust appears in complex patterns depending on the landscape. We extended an atmospheric and land surface model system to investigate the impact of Saharan dust particles across Eurasia during a Saharan dust transport event. We found that mountainous regions are particularly affected by the dust particles, leading to increased snowmelt. In addition, regions with thin and patchy snow cover show a strong response to the dust particles, mainly causing a warming of the land surface. We found that the effects of dust particles depend on different regional characteristics. Therefore, when investigating dust on snow, it is important to use model systems that represent both the atmospheric process and surface properties properly.〈/p〉
    Description: Key Points: 〈list list-type="bullet"〉 〈list-item〉 〈p xml:lang="en"〉There are regional effects due to the high spatial variability in mineral dust and snow properties〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉Thin snow layers favor a rise in temperature, higher elevations mainly show accelerated snow melt〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉We found a significant impact on surface radiation, temperature and snow cover properties〈/p〉〈/list-item〉 〈/list〉 〈/p〉
    Description: Initiative and Networking Fund of the Helmholtz Association
    Description: https://doi.org/10.35097/1579
    Keywords: ddc:551.5 ; light‐absorbing impurities ; dust on snow ; snow albedo ; regional impact ; modeling ; ensemble simulation
    Language: English
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  • 117
    Publication Date: 2024-03-06
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉The usually short lifetime of convective storms and their rapid development during unstable weather conditions makes forecasting these storms challenging. It is necessary, therefore, to improve the procedures for estimating the storms' expected life cycles, including the storms' lifetime, size, and intensity development. We present an analysis of the life cycles of convective cells in Germany, focusing on the relevance of the prevailing atmospheric conditions. Using data from the radar‐based cell detection and tracking algorithm KONRAD of the German Weather Service, the life cycles of isolated convective storms are analysed for the summer half‐years from 2011 to 2016. In addition, numerous convection‐relevant atmospheric ambient variables (e.g., deep‐layer shear, convective available potential energy, lifted index), which were calculated using high‐resolution COSMO‐EU assimilation analyses (0.0625°), are combined with the life cycles. The statistical analyses of the life cycles reveal that rapid initial area growth supports wider horizontal expansion of a cell in the subsequent development and, indirectly, a longer lifetime. Specifically, the information about the initial horizontal cell area is the most important predictor for the lifetime and expected maximum cell area during the life cycle. However, its predictive skill turns out to be moderate at most, but still considerably higher than the skill of any ambient variable is. Of the latter, measures of midtropospheric mean wind and vertical wind shear are most suitable for distinguishing between convective cells with short lifetime and those with long lifetime. Higher thermal instability is associated with faster initial growth, thus favouring larger and longer living cells. A detailed objective correlation analysis between ambient variables, coupled with analyses discriminating groups of different lifetime and maximum cell area, makes it possible to gain new insights into their statistical connections. The results of this study provide guidance for predictor selection and advancements of nowcasting applications.〈/p〉
    Description: 〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉Based on a combination of data of the cell tracking algorithm KONRAD of the German Weather Service and COSMO‐EU model analyses for the summer half‐years from 2011 to 2016, statistical relationships between storm attributes (lifetime and maximum horizontal area), and ambient variables as well as the storms' history are quantified. The initial growth of the cell area is a better indicator of the lifetime and maximum area than ambient variables are. Of the latter, measures of the midtropospheric wind and vertical wind shear, in particular, are most suitable for distinguishing between convective cells with short and long lifetimes, whereas higher convective instability favours larger cells. 〈boxed-text position="anchor" id="qj4505-blkfxd-0001" content-type="graphic" xml:lang="en"〉〈graphic position="anchor" id="jats-graphic-1" xlink:href="urn:x-wiley:00359009:media:qj4505:qj4505-toc-0001"〉 〈/graphic〉 〈/boxed-text〉〈/p〉
    Description: Bundesministerium für Digitales und Verkehr http://dx.doi.org/10.13039/100008383
    Keywords: ddc:551.6 ; convective storms ; life cycle ; multisource data ; nowcasting ; statistics ; weather prediction
    Language: English
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  • 118
    Publication Date: 2024-03-06
    Description: Numerical prediction of landslide runout and deposition is important for estimating landslide risk and developing mitigation plans. The choice of a suitable model and its parameters and a confident calibration strategy are crucial for numerical simulations. Here, we evaluated two constitutive models with a three‐dimensional smoothed particle hydrodynamics (SPH) method by simulating the catastrophic 11 October 2018 Baige landslide. The results indicate that both the soil mechanic and fluid models can capture the dynamic runout and deposition morphology while using different values of input parameters. A point‐wise comparison of deposit elevation can minimize the calibration error. Numerical models were constrained accurately by utilizing both the static observation data and dynamic seismic signals. The effects of friction on deep‐seated landslides motion and deposition are more significant than cohesion. The 3D model includes the effects of shear stresses and velocities inside the material body, resulting in a reduced friction coefficient compared to the 2D model (e.g., depth‐averaged model). Our study highlights the potential of the 3D SPH method for modeling large‐scale complex landslides.
    Description: Plain Language Summary: Landslides belong to a type of earth surface process recognized by their high damage potential. Computer models can simulate the landslides' movement to predict speed, forces, and deposition, which can help to delineate areas at risk and to design mitigation measures. We simulated the 2018 Baige landslide in China with a method known as smoothed particle hydrodynamics (SPH), to test whether it is suitable for landslide simulation and to investigate protocols for model calibration when including seismic data in addition to information on the landslide's deposit. In this method, the landslide body is represented by millions of small, moving, interacting particles, which offers advantages over established models in terms of computation time and details in the simulation. We find that SPH is suitable for modeling large‐scale natural landslides. The seismic data are more valuable in the model calibration than landslide deposit observations. The new approach yields landslide simulations that deliver more details on particle velocities within the landslide body, and their spatial and temporal distribution. These details can be used to infer the properties of landslides during the sliding process, which helps to better understand landslides in general and to set up models for events where little data are available.
    Description: Key Points: A three‐dimensional mesh‐less graphics processing unit‐accelerated smoothed particle hydrodynamics formulation is suitable for modeling large‐scale natural landslides. The selection of an appropriate constitutive model depends on the landslide features and materials. Including dynamic seismic signals into numerical model calibration routines in addition to topographic changes improves calibration.
    Description: National Natural Science Foundation of China http://dx.doi.org/10.13039/501100001809
    Description: Sichuan Science and Technology Program
    Description: Helmholtz‐ocpc Postdoc Program fellowship
    Description: Sino‐German Mobility programme
    Description: Youth Innovation Promotion Association of the Chinese Academy of Sciences http://dx.doi.org/10.13039/501100004739
    Description: https://figshare.com/articles/software/LOQUAT-master_zip/20486088
    Description: https://10.0.20.161/zenodo.7408675
    Keywords: ddc:551.3 ; landslides ; numerical modeling ; constitutive model ; model calibration routines ; friction ; cohesion
    Language: English
    Type: doc-type:article
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  • 119
    Publication Date: 2024-03-06
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉The drag coefficient, Stanton number and Dalton number are of particular importance for estimating the surface turbulent fluxes of momentum, heat and water vapor using bulk parameterization. Although these bulk transfer coefficients have been extensively studied over the past several decades in marine and large‐lake environments, there are no studies analyzing their variability for smaller lakes. Here, we evaluated these coefficients through directly measured surface fluxes using the eddy‐covariance technique over more than 30 lakes and reservoirs of different sizes and depths. Our analysis showed that the transfer coefficients (adjusted to neutral atmospheric stability) were generally within the range reported in previous studies for large lakes and oceans. All transfer coefficients exhibit a substantial increase at low wind speeds (〈3 m s〈sup〉−1〈/sup〉), which was found to be associated with the presence of gusts and capillary waves (except Dalton number). Stanton number was found to be on average a factor of 1.3 higher than Dalton number, likely affecting the Bowen ratio method. At high wind speeds, the transfer coefficients remained relatively constant at values of 1.6·10〈sup〉−3〈/sup〉, 1.4·10〈sup〉−3〈/sup〉, 1.0·10〈sup〉−3〈/sup〉, respectively. We found that the variability of the transfer coefficients among the lakes could be associated with lake surface area. In flux parameterizations at lake surfaces, it is recommended to consider variations in the drag coefficient and Stanton number due to wind gustiness and capillary wave roughness while Dalton number could be considered as constant at all wind speeds.〈/p〉
    Description: Plain Language Summary: In our study, we investigate the bulk transfer coefficients, which are of particular importance for estimation the turbulent fluxes of momentum, heat and water vapor in the atmospheric surface layer, above lakes and reservoirs. The incorrect representation of the surface fluxes above inland waters can potentially lead to errors in weather and climate prediction models. For the first time we made this synthesis using a compiled data set consisting of existing eddy‐covariance flux measurements over 23 lakes and 8 reservoirs. Our results revealed substantial increase of the transfer coefficients at low wind speeds, which is often not taken into account in models. The observed increase in the drag coefficient (momentum transfer coefficient) and Stanton number (heat transfer coefficient) could be associated with the presence of wind gusts and capillary waves. In flux parameterizations at lake surface, it is recommended to consider them for accurate flux representation. Although the bulk transfer coefficients were relatively constant at high wind speeds, we found that the Stanton number systematically exceeds the Dalton number (water vapor transfer coefficient), despite the fact they are typically considered to be equal. This difference may affect the Bowen ratio method and result in biased estimates of lake evaporation.〈/p〉
    Description: Key Points: 〈list list-type="bullet"〉 〈list-item〉 〈p xml:lang="en"〉Bulk transfer coefficients exhibit a substantial increase at low wind speed〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉The increase is explained by wind gustiness and capillary wave roughness〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉At higher wind speed, drag coefficient and Stanton number decrease with lake surface area〈/p〉〈/list-item〉 〈/list〉 〈/p〉
    Description: SHESF, Sao Francisco Hydroelectric Company
    Description: DOE Ameriflux Network Management Project
    Description: NSF North Temperate Lakes LTER
    Description: U.S. Department of Energy Office of Science
    Description: Japan Society for the Promotion of Science KAKENHI
    Description: Swedish Research Council
    Description: ÚNKP‐21‐3 New National Excellence Program of the Ministry for Innovation and Technology, Hungary
    Description: Russian Science Foundation http://dx.doi.org/10.13039/501100006769
    Description: Helmholtz Young Investigators Grant
    Description: Helmholtz Association of German Research Centers
    Description: Austrian Academy of Sciences
    Description: Autonome Provinz Bozen‐Südtirol
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: Russian Ministry of Science and Higher Education
    Description: National Research, Development and Innovation Office
    Description: ICOS‐Finland, University of Helsinki
    Description: https://doi.org/10.5281/zenodo.6597828
    Keywords: ddc:551.5 ; bulk transfer coefficients ; eddy‐covariance ; lakes ; reservoirs
    Language: English
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  • 120
    Publication Date: 2024-02-15
    Description: Entrainment and mixing play an essential role in shaping the droplet size distribution (DSD), with commensurate effects on cloud radiative properties or precipitation formation. In this paper, we use a model that considers all relevant scales related to entrainment and mixing by employing the linear eddy model (LEM) as a subgrid‐scale (SGS) mixing model, coupled with a large‐eddy simulation model and a Lagrangian cloud model (LCM) for a single cumulus congestus cloud. We confirm that the DSD is broadened toward small‐size droplets during homogeneous mixing. During inhomogeneous mixing, the DSD width remains almost unchanged. The DSD width can also be narrowed after mixing. We show that this happens when DSD is broadened toward small‐size droplets, which evaporate rapidly, while larger droplets are almost unaffected. In addition, when droplets ascend during mixing, DSD narrowing is caused when the adiabatic increase in supersaturation is slower than the average droplet evaporation, allowing only the largest droplets to benefit from the newly produced supersaturation. The narrowing mixing scenario prevents clouds from having too broad DSDs and causes the DSD relative dispersion to converge around 0.2 to 0.4. As this scenario is more frequent when the LEM SGS model is used, our results indicate that adequately modeling turbulent mixing is necessary to represent a realistic DSD shape.
    Description: Plain Language Summary: Clouds are always in contact with the surrounding air. Because the air outside the cloud is drier than the cloud, cloud droplets tend to evaporate when it enters the cloud. The size of the cloud droplets after evaporation can vary depending on the timescales of turbulent mixing and droplet evaporation. If the dry air mixes quickly, all droplets evaporate simultaneously. If the dry air is mixed slowly, only the droplets exposed to the dry air evaporate. However, this mixing occurs on small scales that traditional cloud models cannot account for. To account for this, we use a special model capable of representing all relevant scales. We confirm previous theoretical work that when mixing is fast, all droplets evaporate and the mean droplet size decreases. When mixing is slow, some droplets evaporate completely, but the average droplet size remains constant. We also observe cases where only small droplets evaporate while large droplets barely change. This scenario happens when there are many small droplets to evaporate or when additional moisture from cloud motion prevents larger droplets from evaporating completely.
    Description: Key Points: Changes in the droplet spectrum width under different mixing scenarios are investigated using a Lagrangian cloud model. While droplet spectrum broadening is common, narrowing occurs when the droplet size relative dispersion is large, or when droplets ascend. The interaction of these different mixing scenarios favors a relative dispersion of the droplet spectrum between 0.2 and 0.4.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: http://rossby.msrc.sunysb.edu/SAM.html
    Description: https://doi.org/10.5281/zenodo.7120916
    Keywords: ddc:551.5 ; entrainment and mixing ; cumulus clouds ; droplet size distribution ; Lagrangian cloud model ; mixing scenarios
    Language: English
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  • 121
    Publication Date: 2024-02-15
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉Ice wedge polygons on steep slopes have generally been described as being covered by periglacial sediments and, typically, the active layer on slopes becomes mobile during thaw periods, which can lead to solifluction. In West Greenland close to the ice margin, however, the active layer and ice wedge polygons are stable despite their occurrence on steep slopes with inclinations of ≥30°. We conducted a soil survey (including sampling for soil analyses and radiocarbon dating) in the Umimmalissuaq valley and installed a field station ~4 km east of the current ice margin to monitor soil temperature and water tension at depths of 10, 20 and 35 cm of the active layer on a steep, north‐facing slope in the middle of an ice wedge polygon from 2009 to 2015. Thawing and freezing periods lasted between 2 and 3 months and the active layer was usually completely frozen from November to April. We observed simultaneous and complete water saturation at all three depths of the active layer in one summer for 1 day. The amount of water in the active layer apparently was not enough to trigger solifluction during the summer thaw, even at slope inclinations above 30°. In addition, the dense shrub tundra absorbs most of the water during periods between thawing and freezing, which further stabilizes the slope. This process, together with the dry and continental climate caused by katabatic winds combined with no or limited frost heave, plays a crucial role in determining the stability of these slopes and can explain the presence of large‐scale stable ice wedge polygon networks in organic matter‐rich permafrost, which is about 5,000 years old. This study underlines the importance of soil hydrodynamics and local climate regime for landscape stability and differing intensities of solifluction processes in areas with strong geomorphological gradients and rising air temperatures.〈/p〉
    Keywords: ddc:551.3 ; permafrost ; soil temperature ; soil water tension ; solifluction
    Language: English
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  • 122
    Publication Date: 2024-02-15
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉In May 2012, a sediment‐laden flood along the Seti Khola (= river) caused 72 fatalities and widespread devastation for > 40 km in Pokhara, Nepal's second largest city. The flood was the terminal phase of a hazard cascade that likely began with a major rock‐slope collapse in the Annapurna Massif upstream, followed by intermittent ponding of meltwater and subsequent outburst flooding. Similar hazard cascades have been reported in other mountain belts, but peak discharges for these events have rarely been quantified. We use two hydrodynamic models to simulate the extent and geomorphic impacts of the 2012 flood and attempt to reconstruct the likely water discharge linked to even larger medieval sediment pulses. The latter are reported to have deposited several cubic kilometres of sediment in the Pokhara Valley. The process behind these sediment pulses is debated. We traced evidence of aggradation along the Seti Khola during field surveys and from RapidEye satellite images. We use two steady‐state flood models, HEC‐RAS and ANUGA, and high‐resolution topographic data, to constrain the initial flood discharge with the lowest mismatch between observed and predicted flood extents. We explore the physically plausible range of simplified flood scenarios, from meteorological (1000 m〈sup〉3〈/sup〉 s〈sup〉−1〈/sup〉) to cataclysmic outburst floods (600,000 m〈sup〉3〈/sup〉 s〈sup〉−1〈/sup〉). We find that the 2012 flood most likely had a peak discharge of 3700 m〈sup〉3〈/sup〉 s〈sup〉−1〈/sup〉 in the upper Seti Khola and attenuated to 500 m〈sup〉3〈/sup〉 s〈sup〉−1〈/sup〉 when arriving in Pokhara city. Simulations of larger outburst floods produce extensive backwater effects in tributary valleys that match with the locations of upstream‐dipping medieval‐age slackwater sediments in several tributaries of the Seti Khola. Our findings are consistent with the notion that the medieval sediment pulses were linked to outburst floods with peak discharges of >50,000 m〈sup〉3〈/sup〉 s〈sup〉−1〈/sup〉, though discharge may have been an order of magnitude higher.〈/p〉
    Description: 〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉We reconstruct the magnitudes of outburst floods which constitute the terminal phases of a recent and potentially much larger historic hazard cascades affecting the Pokhara Valley in the Nepal Himalayas. To this end, we calibrate two hydrodynamic models, HEC‐RAS and ANUGA, to sedimentary flood evidence – derived for the catastrophic 2012 flood from RapidEye satellite imagery and for the historic sediment pulses from slackwater deposits in the valley's stratigraphically youngest fill. 〈boxed-text position="anchor" content-type="graphic" id="esp5539-blkfxd-0001" xml:lang="en"〉 〈graphic position="anchor" id="jats-graphic-1" xlink:href="urn:x-wiley:01979337:media:esp5539:esp5539-toc-0001"〉 〈/graphic〉 〈/boxed-text〉〈/p〉
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: Deutsche Forschungsgemeinschaft (DFG) http://dx.doi.org/10.13039/501100001659
    Description: University of Potsdam http://dx.doi.org/10.13039/501100004238
    Description: National Science Foundation http://dx.doi.org/10.13039/100000001
    Description: https://doi.pangaea.de/10.1594/PANGAEA.941540
    Keywords: ddc:551.3 ; ANUGA ; GLOF ; HEC‐RAS ; hydrodynamic modelling ; peak discharge reconstruction ; RapidEye ; sedimentary evidence ; simulations
    Language: English
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  • 123
    Publication Date: 2024-02-15
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉Snow petrels (〈italic〉Pagodroma nivea〈/italic〉), which are endemic to the Antarctic region, produce proventricular stomach oil from ingested food for feeding purposes but also spit the oil in the immediate surrounds of the nests, where it forms encrustations over time (Antarctic mumiyo). These deposits provide a unique opportunity to understand the paleo‐ecological diet of snow petrels and because the seabirds forage in the ocean, they potentially provide an archive of past marine environmental conditions in the Southern Ocean. For validating methods for reconstructions we use compositional data obtained on modern stomach oils and DNA data from fecal samples of snow petrels. We find that the distribution of carboxylic acid compounds in modern stomach oils and in the fossil deposits are consistent with variable contributions of fish and krill, which are the main constituents of modern snow petrel diet, and allows inference of past changes in snow petrel diet from the fossil record. Analyses of mumiyo deposits from six regions in East Antarctica reveal systematic differences in the isotopic composition of organic matter (δ〈sup〉13〈/sup〉C and δ〈sup〉15〈/sup〉N) and carboxylic acid patterns. This may suggest regional and/or temporal variability in the composition of snow petrels diet, likely differing in response to the prevailing environmental conditions in the foraging range of the birds, such as sea‐ice variability, polynya activity and primary productivity. Our study provides confidence for using these approaches for broader scale paleo‐studies in the future and for an assessment of the temporal changes and regional variability in snow petrel diet.〈/p〉
    Description: Plain Language Summary: To better understand interactions of biological and physical processes in Antarctic marine ecosystems, we investigate fossil deposits of stomach oil of snow petrels for their use as a geological archive for past environmental changes. The deposits form over time in the surroundings of the nesting cavities of snow petrels, which produce stomach oil from ingested food but also spit it at nest robbers. In fresh oil the lipid and isotopic composition can be traced back to the composition of snow petrel food, such as variable proportions of fish and krill. From comparing the lipid and δ〈sup〉13〈/sup〉C‐isotopic composition of modern oil to fossil deposits we suggest it is possible to identify changes in the diet of snow petrels in the fossil record. Since the composition of the diet is closely linked to the prevailing environmental conditions in the marine foraging region of the birds, such as summer sea ice extent, this information can be used for paleoenvironmental reconstructions. Our study of deposits from widely separated regions in Antarctica shows that there are spatial and temporal differences in the composition of stomach oil deposits, likely related to the prevailing environmental conditions. This finding underpins the application of our approach.〈/p〉
    Description: Key Points: 〈list list-type="bullet"〉 〈list-item〉 〈p xml:lang="en"〉Modern stomach oil and feces of snow petrels are used to validate paleo‐proxies for environmental reconstructions in East Antarctica〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉Biomarkers and isotopic composition of fossil stomach oil deposits of snow petrels reflect past composition in diet〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉Changes in the composition of the paleo‐ecological diet reflect variations of environmental conditions in the coastal Southern Ocean〈/p〉〈/list-item〉 〈/list〉 〈/p〉
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: Australian Antarctic Division http://dx.doi.org/10.13039/501100005108
    Description: https://doi.org/10.1594/PANGAEA.951357
    Keywords: ddc:560 ; Antarctica ; paleoclimate ; sea ice ; fatty acids ; stable isotopes ; stomach oil deposits
    Language: English
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  • 124
    Publication Date: 2024-02-15
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉Machine learning (ML) has been increasingly applied to space weather and ionosphere problems in recent years, with the goal of improving modeling and forecasting capabilities through a data‐driven modeling approach of nonlinear relationships. However, little work has been done to quantify the uncertainty of the results, lacking an indication of how confident and reliable the results of an ML system are. In this paper, we implement and analyze several uncertainty quantification approaches for an ML‐based model to forecast Vertical Total Electron Content (VTEC) 1‐day ahead and corresponding uncertainties with 95% confidence intervals (CI): (a) Super‐Ensemble of ML‐based VTEC models (SE), (b) Gradient Tree Boosting with quantile loss function (Quantile Gradient Boosting, QGB), (c) Bayesian neural network (BNN), and (d) BNN including data uncertainty (BNN + D). Techniques that consider only model parameter uncertainties (a and c) predict narrow CI and over‐optimistic results, whereas accounting for both model parameter and data uncertainties with the BNN + D approach leads to a wider CI and the most realistic uncertainties quantification of VTEC forecast. However, the BNN + D approach suffers from a high computational burden, while the QGB approach is the most computationally efficient solution with slightly less realistic uncertainties. The QGB CI are determined to a large extent from space weather indices, as revealed by the feature analysis. They exhibit variations related to daytime/nightime, solar irradiance, geomagnetic activity, and post‐sunset low‐latitude ionosphere enhancement.〈/p〉
    Description: Plain Language Summary: Space weather describes the varying conditions in the space environment between the Sun and Earth that can affect satellites and technologies on Earth, such as navigation systems, power grids, radio, and satellite communications. The manifestation of space weather in the ionosphere can be characterized using the Vertical Total Electron Content (VTEC) derived from Global Navigation Satellite Systems observations. In this study, the machine learning (ML) approach is applied to approximate the nonlinear relationships of Sun‐Earth processes using data on solar activity, solar wind, magnetic field, and VTEC. However, the measurements and the modeling approaches are subject to errors, increasing the uncertainty of the results when forecasting future instances. For reliable forecasting, it is necessary to quantify the uncertainties. Quantifying the uncertainty is also helpful for understanding the ML‐based model and the problem of VTEC and space weather forecasting. Therefore, in this study, ML‐based models are developed to forecast VTEC within the ionosphere, including the manifestation of space weather, while the degree of reliability is quantified with a target value of 95% confidence.〈/p〉
    Description: Key Points: 〈list list-type="bullet"〉 〈list-item〉 〈p xml:lang="en"〉Machine learning‐based Vertical Total Electron Content models with 95% confidence intervals (CI) are developed for the first time using four approaches to quantify uncertainties〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉Bayesian Neural Network quantifying model and data uncertainties contains ground truth within CIs, but is computationally intensive〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉Quantile Gradient Boosting is fastest with comparable performance in terms of uncertainty; CIs largely determined from space weather indices〈/p〉〈/list-item〉 〈/list〉 〈/p〉
    Description: Deutscher Akademischer Austauschdienst http://dx.doi.org/10.13039/501100001655
    Description: https://www.tensorflow.org/
    Description: https://doi.org/10.21105/joss.03021
    Description: http://www.aiub.unibe.ch/download/CODE
    Description: https://kauai.ccmc.gsfc.nasa.gov/instantrun/iri
    Description: https://doi.org/10.5281/zenodo.7741342
    Description: https://doi.org/10.5281/zenodo.7858906
    Description: https://doi.org/10.5281/zenodo.7858661
    Keywords: ddc:551.5 ; machine learning ; uncertainty quantification ; confidence intervals ; probabilistic ionosphere forecast ; space weather ; ensemble ; Bayesian neural network ; quantile gradient boosting
    Language: English
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  • 125
    Publication Date: 2024-02-15
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉The formation and structural evolution of complex intracontinental basins, like the North German Basin, mark fundamental earth processes. Understanding these is not only essential to basic research but also of socioeconomic importance because of the multitude of resources, potential hazards, and subsurface use capability in such basins. As part of the Central European Basin System, major subsidence and structural differentiation affected the Baltic sector of the North German Basin in Permian‐to‐Jurassic times. A dense network of high‐resolution 2D seismic data together with nearby wells allow the creation of regional maps with refined stratigraphic subdivision of unprecedented spatial resolution covering the bays of Kiel and Mecklenburg (Baltic Sea). Cross sections along the basin margin allow reconstruction of the structural evolution of the Zechstein salt and its overburden. At the northern basin margin, near the Kegnaes Diapir, thinning of the Buntsandstein and divergent reflectors indicate Early Triassic faulting and salt movement. In the Late Triassic, tectonic activity increased as expressed by the onset of salt movement in the north‐eastern Glückstadt Graben, major growth of the Kegnaes Diapir and faulting at the north‐eastern basin margin during deposition of the Keuper (Erfurt, Grabfeld, Stuttgart and Weser formations). At the north‐eastern basin margin, we interpret the accumulation of Keuper and Jurassic deposits as an infill of a local sub‐basin bordered by the Werre Fault Zone and Agricola Fault System. Between the Glückstadt Graben and the north‐eastern basin margin, the Eastholstein–Mecklenburg Block formed a more stable area, where salt movement first began during the latest Triassic. In the peripheral part of the basin, salt movement was triggered by thin‐skinned extension associated with thick‐skinned faulting within the axial parts of major graben systems. Indications for gravity gliding are absent. Reactive diapirism is restricted to the basin margin, where reduced overburden thickness and Late Triassic erosion allowed diapiric breakthrough.〈/p〉
    Description: 〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉We investigate the complex evolution of the northern intracontinental North German Basin and elucidate the impact of regional tectonics on salt movement in Permian‐to‐Jurassic times. We describe the onset and characteristics of salt movement throughout the study area and explain observed isolated diapirism at the basin margin.〈boxed-text position="anchor" content-type="graphic" id="bre12760-blkfxd-0001" xml:lang="en"〉〈graphic position="anchor" id="jats-graphic-1" xlink:href="urn:x-wiley:0950091X:media:bre12760:bre12760-toc-0001"〉 〈/graphic〉〈/boxed-text〉〈/p〉
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Keywords: ddc:551.8 ; North German Basin ; Baltic sector ; Triassic-Jurassic structural evolution ; salt tectonics ; seismic imaging
    Language: English
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  • 126
    Publication Date: 2024-02-14
    Description: The United Nations Food and Agricultural Organization (FAO) approved the Hargreaves‐Samani formula (HAR‐85) as an alternative to the standard Penman‐Monteith method (FAO‐PM) for estimating grass reference evapotranspiration (ETo). With much less data demand, HAR‐85 is unequivocally useful where meteorological variables are often scarce, incomplete or unavailable. Herein, we evaluate HAR‐85 against FAO‐PM across 2.505 million km2, representing Sudan and South Sudan and encompassing wide hydroclimate domains including the Nile River. We further propose simple year‐round and seasonal adjustment models to correcting HAR‐85 across the entire study area. The models express HAR‐85's error in multiple linear regressions in terms of latitude, longitude, altitude and/or monthly rainfall. Varying data periods, including odd, even and all years, are used in the evaluation and the adjustment models development and validation processes to investigate the influence of changing data period. A suit of eight performance indicators shows dependency of the original bias of HAR‐85 on the geographical location, monthly rainfall amount, season of the year and data period. All error indicators amplify southward from the hyper‐arid region to the dry sub‐humid zone. For example, the mean bias error (MBE) ranges from −0.51 to 1.29 mm/day, respectively. Study area‐wide, HAR‐85 least represents FAO‐PM during the hottest month and the transitional month (between the wet and dry‐cool seasons) with MBE of 0.65 and 0.70 mm/day, respectively. Conversely, it represents FAO‐PM the most in the wettest month, with smallest MBE of 0.32 mm/day. Beholding this spatiotemporal trait, the final yearly and seasonal adjustment models developed herein enormously moderate the predominant overestimation of the original HAR‐85. The former model explains 46.7% of the error variance whereas 36.9% to 62.3% of the variation in the error is explainable by the latter models. These adjustment models narrow the monthly MBE among the stations from −0.71‐2.17 to −0.80‐1.20 and −0.65‐0.99 mm/day, respectively. Without undermining the accuracy, the year‐round adjustment model can still be feasibly recommended for general use across the study area.
    Description: For the vast area encompassing Sudan and South Sudan, with hyper‐arid, arid, semi‐arid and dry sub‐humid climates, the performance of the simple Hargreaves‐Samani formula is evaluated against FAO Penman‐Monteith method for estimating grass reference evapotranspiration (ETo). ETo is essentially latitude, rainfall, season and timescale dependent with dominant overestimation. Adjustment is proposed through year‐round and seasonal multiple linear regressions on latitude, altitude, longitude and monthly rainfall, explaining ~37‐62% of the bias error.
    Keywords: ddc:551.5 ; arid climates ; evaluation ; FAO Penman‐Monteith method ; grass reference evapotranspiration ; Hargreaves‐Samani method ; sub‐humid climates ; Sudan ; validation
    Language: English
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  • 127
    Publication Date: 2024-02-14
    Description: We study a strong clear air turbulence (CAT) event experienced by the German High‐Altitude Long‐Range research aircraft (HALO) during the Southern Hemisphere Transport, Dynamics, and Chemistry campaign. HALO encountered CAT leeward of the southern Andes Mountains, where tropospheric airflow favored vertically propagating mountain waves that were refracted southeastward into the core of tropopause jet. Turbulence is quantified using spectral quantities and structure functions computed from in situ 100 Hz flight level data. The detected CAT region exhibits strong patchiness, characterized by separated bursts in turbulent kinetic energy and energy dissipation rate. The high resolution in situ observations reveal different turbulent scaling within each patch, in both spectra and structure functions, and following Monin and Yaglom's conversion law. One patch follows power laws with exponents −1.71 ± 0.06, −1.771 ± 0.006, and −1.56 ± 0.05 for the velocity components w, v, and u, respectively, while another patch has exponents −2.17 ± 0.12, −2.50 ± 0.08, and −1.92 ± 0.09. These patches are mediated by a third patch with less clear scaling. While the patches can deviate from Kolmogorov scaling due to the anisotropy of the airflow, they still display evidence of CAT with enhanced energy dissipation rates.
    Description: Plain Language Summary: Clear air turbulence (CAT) is a common phenomenon in upper layers of the atmosphere, often triggered by the instability of internal gravity waves or by strong wind shear. CAT can be disruptive for airplanes and uncomfortable for pilots and passengers. Nevertheless, the relationship between CAT formation and the resulting strength of bumpiness experienced by an aircraft is not fully understood. Most of these turbulent regions are patchy and exhibit sudden inhomogeneous bursts of velocity and temperature variations. However, CAT is often quantified using spectral quantities assuming isotropic and homogeneous turbulence. Here, we present a case study of a CAT event observed in the lowermost stratosphere during a research flight in the lee of the Andes Mountains near the Drake Passage in South America. The unique 100 Hz high resolution in situ observations allow the study of individual patches within the turbulent event. Their statistical properties can deviate significantly from those of homogeneous and isotropic turbulence, indicating thermal stratification as an important parameter determining the spectral response.
    Description: Key Points: Moderate‐to‐severe clear air turbulence (CAT) over the Southern Andes is analyzed using 100 Hz in situ data obtained during a flight of the Southern Hemisphere Transport, Dynamics, and Chemistry campaign. Vertical propagation of mountain waves in the lee of the Southern Andes is recognized as the main source for the turbulence observed. Anisotropy due to thermal stratification results in turbulent patches within the CAT region with non‐Kolmogorov turbulence scaling.
    Description: Ministerio de Defensa, Argentina http://dx.doi.org/10.13039/501100016156
    Description: Federal Ministry for Education and Research
    Description: https://doi.org/10.5281/zenodo.6918363
    Description: https://halo-db.pa.op.dlr.de/mission/116
    Description: https://www.ecmwf.int/en/forecasts/datasets/reanalysis-datasets/era5
    Keywords: ddc:551.5 ; southern Andes ; clear air turbulence (CAT) ; gravity waves dynamics ; German High-Altitude Long-Range research aircraft (HALO)
    Language: English
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  • 128
    Publication Date: 2024-02-14
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉Aseismic slip may occur during a long preparatory phase preceding earthquakes, and what controls it remains poorly understood. In this study, we explored the role of load point velocity and surface roughness on slow slip during the preparatory stage prior to stick‐slip events. To that end, we conducted displacement‐rate controlled friction experiments by imposing varying load point velocities on sawcut granite samples with different surface roughness at a confining pressure of 35 MPa. We measured the average slip along the fault with the recorded far‐field displacements and strain changes, while acoustic emission sensors and local strain gages were used to capture local slip variations. We found that the average amount of aseismic slip during the preparatory stage increases with roughness, whereas precursory slip duration decreases with increased load point velocity. These results reveal a complex slip pattern on rough faults which leads to dynamic ruptures at high load point velocities.〈/p〉
    Description: Plain Language Summary: Earthquakes occur mostly along preexisting faults in the earth crust. These faults exhibit various geometrical complexities and are subjected to different strain rates. In the laboratory, we produce earthquake analogs by sliding sawcut granite blocks. We vary the geometrical complexity of the faults by roughening their surfaces and modify the strain rate by displacing the blocks at varying velocities. Under these different conditions, we measure how the forces accumulated by friction are released, by measuring stresses and displacements applied on the block's edges, using local strain deformation sensors, and by recording very small earthquakes occurring during sliding along the sawcut faults. We find that smooth sawcut faults tend to release all the energy accumulated very abruptly, after a very small amount of slip, regardless of the load point velocity applied. The processes leading to failure in the case of a rough fault are much more complex, involving a large amount of slip, and numerous small earthquakes which are distributed heterogeneously in space and time.〈/p〉
    Description: Key Points: 〈list list-type="bullet"〉 〈list-item〉 〈p xml:lang="en"〉Acoustic emissions highlight the complex preparatory phase prior stick‐slips on rough faults〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉Preparatory slip increases with roughness and the duration of the preparatory phase decreases with increasing load point velocity〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉Rough and heterogeneous faults are more stable than smooth faults, but can become unstable with a small increase of load point velocity〈/p〉〈/list-item〉 〈/list〉 〈/p〉
    Description: SAIDAN
    Description: https://doi.org/10.5281/zenodo.6411819
    Keywords: ddc:550.78 ; rock friction ; roughness ; dynamic rupture ; acoustic emissions
    Language: English
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  • 129
    Publication Date: 2024-02-14
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉ABSTRACT〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉The Permian–Triassic and Triassic–Jurassic critical intervals are among the most significant ecological upheavals in the Phanerozoic. Both evolutionary junctures are characterized by environmental deterioration associated with a marked biodiversity decline. In this study, Permian–Triassic and Triassic–Jurassic boundary sections from South China and the Northern Calcareous Alps were investigated. In order to reconstruct the interplay between biotic and abiotic processes, a multifaceted approach that included optical microscopy, X‐ray diffraction, Raman spectroscopy, stable carbon isotopes and lipid biomarkers was employed. The lower parts of these two sections are similar as both consist of limestone with abundant fossils of eukaryotic organisms. However, the Permian–Triassic record is dominated by dasyclad green algae and fusulinid foraminifera, while the Triassic–Jurassic record is typified by corals and coralline sponges. Moving upward, both sections consist mainly of micrite and marl. Concerning the Permian–Triassic section, it transits to volcanic ash intercalated by a distinct limestone bed with abundant calcispheres (tentatively attributed to ancestors of dinoflagellates). The Triassic–Jurassic section does not provide direct evidence for volcanic activity, but also becomes rich in calcisphere‐type cysts towards the top. Additionally, the section preserves abundant 4‐methyl sterenes (diagnostic for dinoflagellates) and C〈sub〉37–39〈/sub〉 〈italic toggle="no"〉n〈/italic〉‐alkanes (indicative for haptophytes). Hence, both critical intervals were associated with marked blooms of (ancestral) dinoflagellates and haptophytes (for example, coccolithophorids). These blooms were followed by ecological lag‐phases, as indicated by low carbonate contents and scarce fossils which only increased further up the sections. For both critical intervals, it is commonly assumed that the formation of voluminous volcanic provinces (Siberian Traps and Central Atlantic Magmatic Province, respectively), as well as associated processes (for example, burning of organic‐rich sediments such as coal), resulted in ecological devastation. However, results suggest that volcanism also had a positive effect on certain planktonic primary producers such as dinoflagellates and haptophytes, perhaps by delivering essential nutrients.〈/p〉
    Description: China Council Scholarship
    Description: Teach@Tübingen Fellowship
    Keywords: ddc:560 ; Calcispheres ; dinoflagellates ; haptophytes ; lipid biomarkers ; mass extinctions ; microfacies ; stable carbon isotopes
    Language: English
    Type: doc-type:article
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  • 130
    Publication Date: 2024-02-14
    Description: Machine learning (ML) has received enormous attention in science and beyond. Discussed here are the status, opportunities, challenges and limitations of ML as applied to X‐ray and neutron scattering techniques, with an emphasis on surface scattering. Typical strategies are outlined, as well as possible pitfalls. Applications to reflectometry and grazing‐incidence scattering are critically discussed. Comment is also given on the availability of training and test data for ML applications, such as neural networks, and a large reflectivity data set is provided as reference data for the community.
    Description: The status, opportunities, challenges and limitations of machine learning are discussed as applied to X‐ray and neutron scattering techniques, with an emphasis on surface scattering.
    Keywords: ddc:548 ; surface scattering ; X‐ray diffraction ; neutron scattering ; machine learning ; data analysis
    Language: English
    Type: doc-type:article
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  • 131
    Publication Date: 2024-02-21
    Description: The storage ring upgrade of the European Synchrotron Radiation Facility makes ESRF–EBS the most brilliant high‐energy fourth‐generation light source, enabling in situ studies with unprecedented time resolution. While radiation damage is commonly associated with degradation of organic matter such as ionic liquids or polymers in the synchrotron beam, this study clearly shows that highly brilliant X‐ray beams readily induce structural changes and beam damage in inorganic matter, too. Here, the reduction of Fe3+ to Fe2+ in iron oxide nanoparticles by radicals in the brilliant ESRF–EBS beam, not observed before the upgrade, is reported. Radicals are created due to radiolysis of an EtOH–H2O mixture with low EtOH concentration (∼6 vol%). In light of extended irradiation times during insitu experiments in, for example, battery and catalysis research, beam‐induced redox chemistry needs to be understood for proper interpretation of insitu data.
    Description: With the increased brilliance at the European Research Facility–Extremely Brilliant Source (ESRF–EBS), a beam‐induced reduction of non‐stochiometric iron oxide nanoparticles (almost maghemite composition) to magnetite was observed in a mixture of ethanol and water with low ethanol concentration.
    Keywords: ddc:548 ; beam‐induced radiolysis ; radiation damage on inorganic materials ; ESRF–EBS
    Language: English
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  • 132
    Publication Date: 2024-02-21
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉ABSTRACT〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉Pleistocene faunal assemblages are often highly fragmented, hindering taxonomic identifications and interpretive potentials. In this paper, we apply four different methodologies to morphologically unidentifiable bone fragments from the Neanderthal open‐air site of Salzgitter‐Lebenstedt (Germany). First, we recorded zooarchaeological attributes for all 1362 unidentifiable bones recovered in 1977. Second, we applied zooarchaeology by mass spectrometry (ZooMS) to 761 fragments, and calculated glutamine deamidation values. Third, we assessed the collagen preservation of 30 fragments by near‐infrared spectroscopy (NIR) and, finally, we pretreated 10 bones with high predicted collagen values for radiocarbon dating. All returned dates at, or beyond, the limit of radiocarbon dating, indicating an age of older than 51 000 years ago. The ZooMS faunal spectrum confirms a cold environment, dominated by reindeer, alongside mammoth, horse and bison. The low occurrence of carnivore modifications (1%) contrasts with an abundance of human modifications (23%). Cut marks and marrow fractures were observed across reindeer, horse and bison. The mammoth remains are less well preserved and show a lower degree of human modifications, indicating, perhaps, a different taphonomic history. Overall, this study illustrates the importance of retaining, studying and incorporating the unidentifiable bone fraction to optimize interpretations of site formation and subsistence behaviour at Palaeolithic sites.〈/p〉
    Description: Max‐Planck‐Gesellschaft http://dx.doi.org/10.13039/501100004189
    Keywords: ddc:560 ; Middle Palaeolithic ; Neanderthal subsistence ; near‐infrared spectroscopy ; radiocarbon dating ; zooarchaeology by mass spectrometry
    Language: English
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  • 133
    Publication Date: 2024-02-21
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉The prediction skill of sub‐seasonal forecast models is evaluated for seven year‐round weather regimes in the Atlantic–European region. Reforecasts based on models from three prediction centers are considered and verified against weather regimes obtained from ERA‐Interim reanalysis. Results show that predicting weather regimes as a proxy for the large‐scale circulation outperforms the prediction of raw geopotential height. Greenland blocking tends to have the longest year‐round skill horizon for all three models, especially in winter. On the other hand, the skill is lowest for the European blocking regime for all three models, followed by the Scandinavian blocking regime. Furthermore, all models struggle to forecast flow situations that cannot be assigned to a weather regime (so‐called no regime), in comparison with weather regimes. Related to this, variability in the occurrence of no regime, which is most frequent in the transition seasons, partly explains the predictability gap between transition seasons and winter and summer. We also show that models have difficulties in discriminating between related regimes. This can lead to misassignments in the predicted regime during flow situations in which related regimes manifest. Finally, we document the changes in skill between model versions, showing important improvements for the ECMWF and NCEP models. This study is the first multi‐model assessment of year‐round weather regimes in the Atlantic–European domain. It advances our understanding of the predictive skill for weather regimes, reveals strengths and weaknesses of each model, and thus increases our confidence in the forecasts and their usefulness for decision‐making.〈/p〉
    Description: 〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉This study is the first sub‐seasonal multi‐model assessment of seven year‐round weather regimes in the Atlantic–European domain. Greenland blocking tends to have the longest year‐round skill horizon for all models, especially in winter. The skill is lowest for the European blocking regime for all models, followed by Scandinavian blocking. Variability in the occurrence of no regime partly explains the predictability gap between the transition seasons and winter and summer. 〈boxed-text position="anchor" id="qj4512-blkfxd-0001" content-type="graphic" xml:lang="en"〉〈graphic position="anchor" id="jats-graphic-1" xlink:href="urn:x-wiley:00359009:media:qj4512:qj4512-toc-0001"〉 〈/graphic〉 〈/boxed-text〉〈/p〉
    Description: Helmholtz Association http://dx.doi.org/10.13039/501100001656
    Description: AXPO Solutions AGN/A
    Keywords: ddc:551.6 ; blocking ; Europe ; North Atlantic oscillation ; windows of opportunity
    Language: English
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  • 134
    Publication Date: 2024-02-21
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉The Mg/Ca of marine calcareous Planktic Foraminifera (PF) shells is commonly used for sea surface temperature reconstructions. However, compared to open marine environments, hypersaline (>40) oligotrophic seas have been shown to accommodate PF with higher Mg/Ca and divergent temperature to Mg/Ca relationships. To investigate influencing factors of PF Mg uptake in hypersaline regions, we measured the Mg/Ca of two flux‐dominating PF species, 〈italic〉Globigerinoides ruber albus〈/italic〉 and 〈italic〉Turborotalita clarkei〈/italic〉, derived from a monthly resolved time series of sediment traps in the Gulf of Aqaba, northern Red Sea as well as the corresponding temperature, salinity, and 〈italic〉p〈/italic〉H values. The PF exhibit elevated Mg/Ca which cannot be explained by post‐deposition or interstitial sediment diagenetic processes. 〈italic〉G. ruber albus〈/italic〉 displays Mg/Ca trends that strongly follow seasonal mixed layer temperature changes. Conversely, 〈italic〉T〈/italic〉. 〈italic〉clarkei〈/italic〉 Mg/Ca trends do not follow temperature but rather show significant Mg/Ca enrichment following mixing of the surface water column. We present a framework for incorporating elevated Mg/Ca into global Mg/Ca‐T calibrations for 〈italic〉G〈/italic〉. 〈italic〉ruber albus〈/italic〉 and present a new Mg/Ca‐T calibration suitable for hypersaline marine environments.〈/p〉
    Description: Plain Language Summary: Past seawater temperature is reconstructed from the magnesium‐to‐calcium ratio (Mg/Ca) in the calcareous shells of a group of marine microplankton called foraminifera. Two foraminifer species, 〈italic〉Globigerinoides ruber albus〈/italic〉 and 〈italic〉Turborotalita clarkei〈/italic〉, are abundant in the Gulf of Aqaba, northern Red Sea, at year‐round high temperatures and salinities. The shells of these foraminifera have elevated Mg/Ca relative to other marine regions, and here, we explore the factors causing this. The Mg/Ca values of both 〈italic〉G〈/italic〉. 〈italic〉ruber albus〈/italic〉 and 〈italic〉T〈/italic〉. 〈italic〉clarkei〈/italic〉 reflect the environmental conditions of the water column. For 〈italic〉G〈/italic〉. 〈italic〉ruber albus〈/italic〉, temperature and salinity appear to be factors responsible for the Mg/Ca trends and elevated values. We incorporate the new Mg/Ca data for 〈italic〉G〈/italic〉. 〈italic〉ruber albus〈/italic〉 to calibrate elevated Mg/Ca with temperature for high‐salinity (>40) marine environments. The Mg/Ca of the deeper dwelling 〈italic〉T〈/italic〉. 〈italic〉clarkei〈/italic〉 show higher ratios following deep mixing of the surface water column and may indicate annually recurring phytoplankton blooms caused by nutrient input into the sunlit ocean surface.〈/p〉
    Description: Key Points: 〈list list-type="bullet"〉 〈list-item〉 〈p xml:lang="en"〉A new Mg/Ca temperature calibration for high salinity environments is presented for 〈italic〉Globigerinoides ruber albus〈/italic〉〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉A framework for incorporating high salinity environments into global Mg/Ca‐T calibrations is provided〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉Enhanced Mg/Ca in subsurface dwelling 〈italic〉Turborotalita clarkei〈/italic〉 may indicate seasonal deep mixing of the upper water column〈/p〉〈/list-item〉 〈/list〉 〈/p〉
    Description: Israel Science Foundation http://dx.doi.org/10.13039/501100003977
    Description: Minerva PhD Fellowship Stipend
    Description: Advance School for Environmental Studies
    Description: https://doi.org/10.1594/PANGAEA.959629
    Description: https://doi.org/10.17617/3.EXFQC2
    Keywords: ddc:551.9 ; Gulf of Aqaba ; Planktic Foraminifera shells ; Mg/Ca ; sea surface temperature reconstructions
    Language: English
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  • 135
    Publication Date: 2024-02-21
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉We quantify sea ice concentration (SIC) changes related to synoptic cyclones separately for each month of the year in the Greenland, Barents and Kara Seas for 1979–2018. We find that these SIC changes can be statistically significant throughout the year. However, their strength varies from region to region and month to month, and their sign strongly depends on the considered time scale (before/during vs. after cyclone passages). Our results show that the annual cycle of cyclone impacts on SIC is related to varying cyclone intensity and traversed sea ice conditions. We further show that significant changes in these cyclone impacts have manifested in the last 40 years, with the strongest changes occurring in October and November. For these months, SIC decreases before/during cyclones have more than doubled in magnitude in the Barents and Kara Seas, while SIC increases following cyclones have weakened (intensified) in the Barents Sea (Kara Sea).〈/p〉
    Description: Plain Language Summary: We study how the sea ice cover in the Arctic Ocean changes due to the passage of low‐pressure systems (cyclones). Our study covers all years between 1979 and 2018 and each individual month of the year. Our results show that the passage of cyclones can affect the sea ice year around, but the strength and the sign (less or more sea ice concentration due to cyclones) of this impact varies strongly. These variations in cyclone impacts throughout the year are related to variations in the strength of the cyclones and changes in the state of the sea ice cover (e.g., thinner vs. thicker ice). We further show that the cyclone impact on the Arctic sea ice has changed during the last 40 years. These changes are strongest in autumn, particularly in October and November. In these months, the strength of the destructive cyclone impacts on sea ice has more than doubled in some regions of the Arctic compared to previous times. In some regions, however, also the strength of ice preserving cyclone impacts (more sea ice due to cyclones) has intensified recently.〈/p〉
    Description: Key Points: 〈list list-type="bullet"〉 〈list-item〉 〈p xml:lang="en"〉Cyclones can significantly impact the sea ice in the Atlantic Arctic in all months of the year, but with strong spatiotemporal variations〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉Impacts are stronger in the cold season than in summer due to variations in cyclone intensity and traversed sea ice conditions〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉Significant changes emerged throughout the year, recently strongest in the Barents Sea in autumn due to a reduced mean ice concentration〈/p〉〈/list-item〉 〈/list〉 〈/p〉
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: Horizon 2020 Framework Programme http://dx.doi.org/10.13039/100010661
    Description: https://doi.org/10.24381/cds.adbb2d47
    Description: https://www.cen.uni-hamburg.de/icdc/data/ocean/easy-init-ocean/ecmwf-oras5.html
    Keywords: ddc:551.5 ; cyclones ; sea ice ; Arctic ; atmosphere‐sea ice interactions ; climate change
    Language: English
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  • 136
    Publication Date: 2024-02-21
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉Linear kinematic features (LKFs) are found everywhere in the Arctic sea‐ice cover. They are strongly localized deformations often associated with the formation of leads and pressure ridges. In viscous‐plastic (VP) sea‐ice models, the simulation of LKFs depends on several factors such as the grid resolution, the numerical solver convergence, and the placement of the variables on the mesh. In this study, we compare two recently proposed discretization with a CD‐grid placement with respect to their ability to reproduce LKFs. The first (CD1) is based on a nonconforming finite element discretization, whereas the second (CD2) uses a conforming subgrid discretization. To analyze their resolution properties, we evaluate runs from different models (e.g., FESOM, MPAS) on a benchmark problem using quadrilateral, hexagonal and triangular meshes. Our findings show that the CD1 setup simulates more deformation structure than the CD2 setup. This highlights the importance of the type of spatial discretization for the simulation of LKFs. Due to the higher number of degrees of freedom, both CD‐grids resolve more LKFs than traditional A, B, and C‐grids at fixed mesh level. This is an advantage of the CD‐grid approach, as high spatial mesh resolution is needed in VP sea‐ice models to simulate LKFs.〈/p〉
    Description: Plain Language Summary: Sea ice in the polar regions is an important component of the climate system. Satellite images demonstrate that the sea‐ice cover can contain long features, such as cracks or leads and areas of increased sea‐ice density known as pressure ridges. In order to simulate these features, mathematical equations that describe the drift of ice are solved on a computational grid. A recent study showed that the simulation of these features on a grid with a given spacing is influenced by the way the variables are placed on grid cells. Locating them at the edge midpoints of the cells leads to simulations with more features than placing the variables on vertices or centers of cells. In this contribution, we show that, along with the placement, also the mathematical method used to approximate the equations on the computational grid plays a pivotal role on the number of simulated features.〈/p〉
    Description: Key Points: 〈list list-type="bullet"〉 〈list-item〉 〈p xml:lang="en"〉The type of spatial discretization used in CD‐grid approximations is important for the amount of simulated local kinematic features (LKFs)〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉The CD‐grid discretization based on nonconforming finite elements simulates the highest amount of LKFs〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉The CD‐grids resolve more LKFs than A‐grids, B‐grids, or C‐grids〈/p〉〈/list-item〉 〈/list〉 〈/p〉
    Description: German Research Foundation
    Description: https://doi.org/10.5281/zenodo.7662610
    Description: https://doi.org/10.5281/zenodo.7646908
    Description: https://data.mendeley.com/datasets/7h9hkjvx48/1
    Keywords: ddc:550.724 ; sea‐ice dynamics ; CD‐grids ; linear kinematic features ; nonconforming finite elements
    Language: English
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  • 137
    Publication Date: 2024-02-21
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉Bottom‐current related sediments have been commonly used for paleoceanographic reconstructions. However, the strength and variability of bottom currents are poorly understood and thus the processes that control sedimentation in deep environments are not clear. In this study, we focus on the Drake Passage, which is connected to the Antarctic Circumpolar Current, that has a major impact on the global climate. We studied the intensity and variability of bottom currents and how they are related to sedimentary processes. For this purpose, we used 27‐years from GLORYS12 Mercator Ocean reanalysis at high resolution to evaluate the bottom current dynamics. Geophysical data and surface grain size measurements were used to identify the type of sediment deposits. Our results show that the dynamics of bottom currents is disconnected from the sea surface dynamics, and bottom circulation is strongly controlled by the rough topography of the Drake Passage. The patterns for the first modes of bottom‐current variability are related to the local topography and seem to generally control the distribution of contourites. The second and third EOF modes show patterns in the bottom currents that differ from the mean field, and they may affect the rate of erosion and deposition differently. Time series of bottom currents reveals multiple high‐speed current events, but contourite drifts seem to accumulate preferentially in zones of slow and stable bottom currents. Our study highlights the potential of using ocean reanalysis to better constrain bottom currents in zones of scarce data and to plan future campaigns of direct measurements.〈/p〉
    Description: Plain Language Summary: As a result of its unique geography, the Southern Ocean contains the largest ocean current in the world ocean, the Antarctic Circumpolar Current (ACC). The Drake Passage (DP) is the major geographic constriction for the ACC and exerts a strong control on the exchange of physical, chemical, and biological properties between the ocean basins. Yet, the bottom dynamics and the relation with sedimentary processes remain to be studied. We analyzed the currents flowing near the seafloor using a high resolution (1°/12°) reanalysis and compared the bottom dynamics with the characteristics of the seafloor sediments obtained using geophysical data sets and sediment cores. We found that the complex topography of the DP plays an essential role in bottom‐current dynamics and that the circulation pattern near the seabed is often different from the sea surface circulation. The largest sediment deposits are located in the zones with weakest bottom current activity.〈/p〉
    Description: Key Points: 〈list list-type="bullet"〉 〈list-item〉 〈p xml:lang="en"〉The variability of bottom currents in the Drake Passage is described using the ocean reanalysis GLORYS12〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉Bottom currents are strongly controlled by the topography and are often disconnected from the surface circulation〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉Sedimentary processes are dominated by the influence of local topography and bottom currents〈/p〉〈/list-item〉 〈/list〉 〈/p〉
    Description: Deutscher Akademischer Austauschdienst http://dx.doi.org/10.13039/501100001655
    Description: https://doi.org/10.48670/moi-00021
    Description: https://doi.org/10.17882/59800
    Description: https://doi.org/10.1594/PANGAEA.864950
    Description: https://doi.org/10.1594/PANGAEA.864807
    Description: https://doi.org/10.1594/PANGAEA.862944
    Description: https://doi.pangaea.de/10.1594/PANGAEA.907140
    Description: https://doi.org/10.1038/s41597-022-01366-7
    Description: http://www.eoas.ubc.ca/7Erich/map.html
    Description: https://odv.awi.de/
    Keywords: ddc:551.46 ; Drake Passage ; bottom currents ; sedimentary features ; Southern Ocean ; bathymetry
    Language: English
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  • 138
    Publication Date: 2024-02-21
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉For better projections of sea level rise, two things are needed: an improved understanding of the contributing processes and their accurate representation in climate models. A major process is basal melting of ice shelves and glacier tongues by the ocean, which reduces ice sheet stability and increases ice discharge into the ocean. We study marine melting of Greenland's largest floating ice tongue, the 79° North Glacier, using a high‐resolution, 2D‐vertical ocean model. While our fjord model is idealized, the results agree with observations of melt rate and overturning strength. Our setup is the first application of adaptive vertical coordinates to an ice cavity. Their stratification‐zooming allows a vertical resolution finer than 1 m in the entrainment layer of the meltwater plume, which is important for the plume development. We find that the plume development is dominated by entrainment only initially. In the stratified upper part of the cavity, the subglacial plume shows continuous detrainment. It reaches neutral buoyancy near 100 m depth, detaches from the ice, and transports meltwater out of the fjord. Melting almost stops there. In a sensitivity study, we show that the detachment depth depends primarily on stratification. Our results contribute to the understanding of ice–ocean interactions in glacier cavities. Furthermore, we suggest that our modeling approach with stratification‐zooming coordinates will improve the representation of these interactions in global ocean models. Finally, our idealized model topography and forcing are close to a real fjord and completely defined analytically, making the setup an interesting reference case for future model developments.〈/p〉
    Description: Plain Language Summary: The global increase of sea levels is a consequence of human‐induced climate change. It presents a threat to coastal regions and demands action to protect human life and infrastructure near the coast. Planning protective measures requires projections of sea level rise, computed with climate models. We present an approach to improve the simulation of an important contributor to sea level rise: melting of floating ice shelves by ocean circulation. Our modeling approach uses a vertical model grid that evolves over time. The temporal evolution depends on the density structure of the ocean. Large density differences appear just below an ice shelf, where fresh meltwater mixes with salty seawater. The adaptive grid of our model resolves this mixing process in great detail. This is important for an accurate computation of the melt rate and enables us to study in depth the ice shelf–ocean interactions. We study them at the glacier tongue of the 79° North Glacier, which is Greenland's largest ice shelf. The physical understanding gained from our simulations is also applicable to other floating glacier tongues and ice shelves. We suggest that using the presented model technique in global ocean models can improve projections of melting and sea level rise.〈/p〉
    Description: Key Points: 〈list list-type="bullet"〉 〈list-item〉 〈p xml:lang="en"〉Melting of the 79° North Glacier ice tongue by turbulent ocean currents is studied with an idealized 2D‐vertical fjord model〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉The subglacial plume behaves like an entraining plume close to the grounding line and like a detraining gravity current further downstream〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉A vertical resolution finer than 1 m is achieved in the subglacial plume by using adaptive vertical coordinates that zoom to stratification〈/p〉〈/list-item〉 〈/list〉 〈/p〉
    Description: Bundesministerium für Bildung und Forschung http://dx.doi.org/10.13039/501100002347
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: German Academic Exchange Service
    Description: https://doi.org/10.5281/zenodo.7755753
    Description: https://doi.org/10.5281/zenodo.7755908
    Description: https://doi.org/10.5281/zenodo.7741925
    Description: https://doi.org/10.1594/PANGAEA.885358
    Keywords: ddc:551.46 ; numerical model ; glacier fjord ; Greenland ; physical oceanography ; ice melting ; high‐resolution
    Language: English
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  • 139
    Publication Date: 2024-02-22
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉Recent climate change has brought new patterns of extreme events in terms of both drought and heavy rainfall to the drought‐prone African Sahel. The effects of these recent extreme events on the performance of the Sahel farming systems are still weakly investigated. This study aims at assessing effects of droughts versus floods on crop yield levels and losses, focusing on the so‐called recovery period, particularly 2001–2020. A newly developed productivity‐drought condition index (PDCI) is utilized to assess agricultural productivity as related to drought or flood in a highly vulnerable region, that is, the Sudanese Sahel. Four farming systems, namely traditional rainfed, mechanized rainfed, gravity irrigated and spate irrigated systems, with sorghum and millet as staple food crops, are considered. The PDCI is defined as a function of the integrated normalized difference vegetation index (iNDVI) over the growing season. To address temporal and spatial variabilities, scaling of the PDCI is done in two dimensions: space and time. Crop statistics are used to derive yield losses. Our results show that both drought and flood episodes (seven and six episodes, respectively) can be captured using the PDCI. Drought remains the most relevant risk to Sahel's crop productivity. Some recent large‐scale floods led to yield loss. However, floods cause smaller risks to agricultural productivity compared to droughts. Floods may even result in enhanced crop yields. Based upon scaling in the time or space domain, ranking the severity of drought impacts on crop yield for individual years from 2001 to 2020 reveals least to slightly different results. Vulnerability to drought depends on the crop type and farming system. Drought effect on crop yield from the irrigated sector is clear on individual years but not as a general statistical relationship. The parameter ‘percentage area under drought’ explains around one‐third of the variation in the rainfed crop yield. The spate irrigation scheme, the gravity irrigated system and the rainfed farmlands experienced respectively 87%, 57% and 46% of area under drought on average. Irrigated systems produce much higher crop yields than rainfed systems. The mechanized system is more drought‐vulnerable than the traditional system. These results call for identifying agricultural management pathways that recognize the combined implications of both hydrological extremes for the region's food security.〈/p〉
    Description: 〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉A newly devised productivity‐drought condition index (PDCI) based on integrated normalized difference vegetation index (iNDVI) data is used to capture the performance of different Sahel farming systems. The performance is evaluated spatially and temporally in a comparative study of effects of droughts versus floods on crop yield levels and losses during 2001–2020. Our research shows that: Crop productivity of all farming systems is severely affected by drought; Flood events can also lead to a decline in productivity, but usually to a much lesser extent; The vulnerability to droughts and floods depends upon the farming system and crop type. Our analysis shows that the farming systems in the Sudanese Sahel have not reverted to conditions that could be described as a Sahel recovery. This study calls for agricultural management decisions, which are specific for the different farming systems, in response to climate variability.〈boxed-text position="anchor" content-type="graphic" id="hyp14978-blkfxd-0001" xml:lang="en"〉 〈graphic position="anchor" id="jats-graphic-1" xlink:href="urn:x-wiley:08856087:media:hyp14978:hyp14978-toc-0001"〉 〈/graphic〉 〈/boxed-text〉〈/p〉
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: https://doi.org/10.1594/PANGAEA.921846
    Description: https://edcintl.cr.usgs.gov/downloads/sciweb1/shared/fews/web/africa/east/dekadal/emodis/ndvi_c6/
    Description: https://earlywarning.usgs.gov/fews/datadownloads/East 20Africa/eMODIS 20NDVI 20C6
    Keywords: ddc:630 ; drought ; farming system ; flood ; normalized difference vegetation index ; performance ; productivity‐drought condition index ; Sahel ; yield loss
    Language: English
    Type: doc-type:article
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  • 140
    Publication Date: 2024-02-23
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉ABSTRACT〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉The study examines bioclastic carbonate contourites that arise from the broad spectrum of bottom‐current related sedimentary processes ranging from deposition to erosion. The result of the intermittent accumulation of sediment are thin and condensed successions with abundant hiatuses. Such bottom‐current deposits are poorly known, since the broadly accepted contourite‐facies model, the bi‐gradational sequence, characterizes environments of contourite depositional systems as a continuous accretion of fine‐grained siliciclastic sediments. To increase current understanding of the carbonate facies within hiatal contourite records, the Eifelian–Frasnian of the Tafilalt Platform in Morocco was investigated. The succession is divided into five facies associations that are interpreted to reflect pelagic sedimentation and deposition from bottom currents on a contourite terrace, a gently inclined section of the upper slope of Gondwana shaped by a water‐mass interface. Contourite deposition was mainly controlled by oxic clear‐water currents (documented by moderately to completely bioturbated limestones with abundant hydrogenetic ferromanganese nodules, and low organic‐carbon contents), at times also by an anoxic water mass (featured by organic‐rich coquinas with absent to sparse bioturbation and predominantly syngenetic framboidal pyrites). Biostratigraphic data and the overall depositional architecture display palaeoceanographic hydrodynamic processes associated with a shifting water‐mass interface. The inner terrace was characterized by an alongslope contourite channel and a small mounded drift at its downslope margin. Energetic bottom currents furthermore caused abraded surfaces, i.e. plain areas of non‐deposition and localized erosion, and sandy condensation layers. The microfacies reflects repeated alternation between suspension deposition, winnowing of fines, bedload traction, dynamic sediment bypassing and reworking, together with concomitant seafloor cementation. Coquinas of mainly planktonic and nektonic organisms are identified as integral parts of bi‐gradational contourite sequences showing inverse and normal grading. Hiatal lag concentrations of carbonate intraclasts, ferromanganese nodules and conodonts often drape hardgrounds and erosional surfaces at the midpoint of these frequently incomplete sequences. This Devonian case provides the opportunity to investigate the spatial and temporal variability of the bed‐scale contourite sequence, also with regard to the drift‐scale depositional architecture. In addition, the identified high‐resolution record is a starting point for unravelling the pattern of oceanic circulation in the Devonian greenhouse world.〈/p〉
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Keywords: ddc:551.7 ; Anti‐Atlas ; bi‐gradational sequence ; bioclastic contourite ; carbonate contourite ; cephalopod limestone ; contourite channel ; contourite terrace
    Language: English
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  • 141
    Publication Date: 2024-01-24
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉Reliable prediction of heavy precipitation events causing floods in a world of changing climate is crucial for the development of appropriate adaption strategies. Many attempts to provide such predictions have already been conducted but there is still much potential for improvement left. This is particularly true for statistical downscaling of heavy precipitation due to changes present in the corresponding atmospheric drivers. In this study, a circulation pattern (CP) conditional downscaling to the station level is proposed which considers occurring frequency changes of CPs. Following a strict circulation‐to‐environment approach we use atmospheric predictors to derive CPs. Subsequently, precipitation observations are used to derive CP conditional cumulative distribution functions (CDFs) of daily precipitation. Raw precipitation time series are sampled from these CDFs. Bias correction is applied to the sampled time series with quantile mapping (QM) and parametric transfer functions (PTFs) as methods being tested. The added value of this CP conditional downscaling approach is evaluated against the corresponding common non‐CP conditional approach. The performance evaluation is conducted by using Kling–Gupta Efficiency (KGE), root mean squared error (RMSE), and mean absolute error (MAE) metrics. In both cases the applied bias correction is identical. Potential added value can therefore only be attributed to the CP conditioning. It can be shown that the proposed CP conditional downscaling approach is capable of yielding more reliable and accurate downscaled daily precipitation time series in comparison to a non‐CP conditional approach. This can be seen in particular for the extreme parts of the distribution. Above the 95th percentile, an average performance gain of +0.24 and a maximum gain of +0.6 in terms of KGE is observed. These findings support the assumption of conserving and utilizing atmospheric information through CPs can be beneficial for more reliable statistical precipitation downscaling. Due to the availability of these atmospheric predictors in climate model output, the presented method is potentially suitable for downscaling precipitation projections.〈/p〉
    Description: Bundesministerium für Bildung und Forschung http://dx.doi.org/10.13039/501100002347
    Description: https://cds.climate.copernicus.eu/cdsapp#!/dataset/reanalysis-era5-pressure-levels?tab=overview
    Description: https://cdc.dwd.de/portal/
    Keywords: ddc:551.5 ; bias correction ; circulation patterns ; ERA5 ; extreme events ; heavy precipitation ; simulated annealing ; statistical downscaling
    Language: English
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  • 142
    Publication Date: 2024-01-24
    Description: 〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉The reactivation of faults and possible impact on barrier integrity marks a critical aspect for investigations on subsurface usage capabilities. Glacial isostatic adjustments, originating from repeated Quaternary glaciations of northern Europe, cause tectonic stresses on pre‐existing fault systems and structural elements of the North German and Norwegian–Danish basins. Notably, our current understanding of the dynamics and scales of glacially induced fault reactivation is rather limited. A high‐resolution 2D seismic data set recently acquired offshore northeastern Langeland Island allows the investigation of a fault and graben system termed the Langeland Fault System. Seismo‐stratigraphic interpretation of reflection seismic data in combination with diffraction imaging unravels the spatial character of the Langeland Fault System along an elevated basement block of the Ringkøbing–Fyn High. In combination with sediment echosounder data, the data set helps to visualize the continuation of deep‐rooted faults up to the sea floor. Initial Mesozoic faulting occurred during the Triassic. Late Cretaceous inversion reactivated a basement fault flanking the southern border of the elevated basement block of the Ringkøbing–Fyn High while inversion is absent in the Langeland Fault System. Here, normal faulting occurred in the Maastrichtian–Danian. We show that a glacial or postglacial fault reactivation occurred within the Langeland Fault System, as evident by the propagation of the faults from the deeper subsurface up to the sea floor, dissecting glacial and postglacial successions. Our findings suggest that the Langeland Fault System was reactivated over a length scale of a minimum of 8.5 km. We discuss the causes for this Quaternary fault reactivations in the context of glacially induced faulting and the present‐day stress field. The combination of imaging techniques with different penetration depths and vertical resolution used in this study is rarely realized in the hinterland. It can therefore be speculated that many more inherited, deep‐rooted faults were reactivated in Pleistocene glaciated regions.〈/p〉
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: https://doi.org/10.1594/PANGAEA.954017
    Keywords: ddc:551.8 ; Langeland Fault System ; Quaternary ; fault reactivation ; seismo-stratigraphic interpretation
    Language: English
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  • 143
    Publication Date: 2024-01-24
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉Mesoscale eddies are frequently observed in the Eastern Tropical North Atlantic (ETNA), yet their effects on the transport and distribution of biogeochemical solutes, and specifically on the production and remineralization of dissolved organic matter (DOM) remain difficult to elucidate. Here, we investigated the submesoscale variability of chromophoric DOM (CDOM) and fluorescent DOM (FDOM) together with microbial production and remineralization processes in two cyclonic eddies (CEs) in the ETNA during summer and winter 2019. One CE, formed near the coast off Mauritania during the post‐upwelling season, was sampled along a ∼900 km zonal corridor between Mauritania and the Cape Verde Islands. The other CE, formed nearby Brava Island, was out of coastal influence. Four fluorescent components were identified with parallel factor analysis, two humic‐like, and two protein‐like components. Humic‐like FDOM components correlated to optode‐based community respiration and were also good indicators of upwelling associated with the Brava Island CE as they correlated to physical parameters (e.g., temperature) and to dissolved inorganic nitrogen. The tryptophan‐like FDOM components correlated with the carbon and nitrogen content of semi‐labile DOM, phytoplankton biomass, community respiration, and bacterial production. Overall, our study revealed that DOM optical properties are suitable for tracing freshly produced organic matter and the transport of remineralized DOM within offshore eddies.〈/p〉
    Description: Plain Language Summary: Mesoscale eddies are ubiquitous circulation features in the ocean with horizontal scales on the order of 100 km and lifetimes of days to months. Their swirling motion can cause nutrients from deeper waters to be transported to the surface, stimulating phytoplankton biomass and resulting in the production of dissolved organic matter. However, these effects are difficult to quantify and proxies (biomarkers) are needed to monitor the impact of eddies at high resolution. In this work, we used the optical properties of the dissolved organic matter, especially the fraction capable of fluorescence (FDOM) as biomarker in two cyclonic eddies, one formed in an eastern boundary upwelling system and one formed offshore by winds/Island interaction. We identified four FDOM components, among which an indicator of cyclonic eddy productivity and two indicators of dissolved organic matter recycling, which also tracked nutrient transport in the offshore cyclonic eddy. Our study highlights that continuous FDOM data obtained with sensors could help to follow eddy development and influence on seawater biogeochemistry.〈/p〉
    Description: Key Points: 〈list list-type="bullet"〉 〈list-item〉 〈p xml:lang="en"〉Four fluorescent dissolved organic matter (FDOM) components were studied in two cyclonic eddies (CEs) in the Eastern Tropical North Atlantic〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉Tryptophan‐like FDOM was an indicator of the CEs' productivity as it correlated with semi‐labile dissolved organic matter and microbial metabolic activities〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉Humic‐like FDOM was a by‐product of microbial respiration; its distribution within an offshore CE covaried with nutrient upwelling〈/p〉〈/list-item〉 〈/list〉 〈/p〉
    Description: Bundesministerium für Bildung und Forschung http://dx.doi.org/10.13039/501100002347
    Keywords: ddc:https://doi.pangaea.de/10.1594/PANGAEA.959742 ; ddc:https://doi.org/10.1594/PANGAEA.950510 ; ddc:577.7 ; PARAFAC ; Atlantic Ocean ; Mauritanian upwelling system ; mesoscale eddies ; fluorescence dissolved organic matter (FDOM) ; DOC
    Language: English
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  • 144
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    John Wiley & Sons, Inc. | Hoboken, USA
    Publication Date: 2024-01-24
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉The IPCC's Sixth Assessment Report warns in stark terms that many long inhabited parts of the world are now on course to become uninhabitable. As astronomers continue to search the universe for new habitable planets, it is equally essential to historicize the consequences of changing habitability on this one. This article reviews how scholars have engaged with the widely noted but rarely theorized categories of “habitability” and “uninhabitability.” While tracing longer imperial genealogies, the primary focus is on notions of habitability in relation to European global empires in the nineteenth and twentieth centuries, and their postcolonial legacies. The article traces three key themes in the literature: that habitability was inherently limited, and beyond those limits allegedly lay uninhabitability; that habitability was differential and that certain places were habitable for some groups but not others (but that this might be changed by technological interventions); and finally, that the limits of habitability were not static, but could change for both better and worse. Here the links between colonialism and ideas of acclimatization, terraforming, “improvement,” deliberate uninhabitability, and an “Anthropocene” have all been central to the literature. These have often been closely associated with insidious forms of environmental determinism, which are taking on new forms in an age of crisis (especially in narratives around climate and migration). By drawing together previously disparate literatures, this article ultimately calls on scholars to embrace habitability studies more widely, and to expand on their interdisciplinary potential for communicating the societal consequences of a changing climate.〈/p〉
    Description: European Commission http://dx.doi.org/10.13039/501100000780
    Description: Irish Research Council http://dx.doi.org/10.13039/501100002081
    Keywords: ddc:910 ; Anthropocene ; climate change ; empire ; environmental determinism ; habitability
    Language: English
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  • 145
    Publication Date: 2024-01-24
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉Sudden stratospheric warming (SSW) events can form a window of forecast opportunity for polar vortex predictions on subseasonal‐to‐seasonal time scales. Analyzing numerical ensemble simulations, we quantify the associated enhanced predictability due to reduced upward planetary wave fluxes during the mostly radiatively driven recovery phase following SSWs. Ensembles that predict an SSW show reduced ensemble spread in terms of polar vortex strength for several weeks to follow, as well as a corresponding reduction in forecast errors. This increased predictability is particularly pronounced for strong SSWs and even occurs if not all ensemble members predict a major SSW. Furthermore, we found a direct impact of the occurrence of SSWs on the date of the final warming (FW): the decrease in upward wave fluxes delays the FW significantly. The reduced spread after SSWs and the delay in FW date have potentially further implications for (subseasonal) predictions of the tropospheric and mesospheric circulations.〈/p〉
    Description: Plain Language Summary: The polar vortex is a large scale circulation active during winter in the higher levels of the polar atmosphere. Changes in the strength of the polar vortex can have an impact on the weather over mid‐latitude regions like Europe. This is the case especially for the period after so‐called sudden stratospheric warming (SSW) events, where the polar vortex breaks down very abruptly and then slowly recovers over several weeks. Such a break‐down of the polar vortex tends to suppress wave activity and hence reduces the dynamical variability in the polar stratosphere, leading to a more predictable evolution of the circulation. We quantify the strength and timescale of this increase in predictability of the polar vortex after an SSW using a large set of winter time model forecasts.〈/p〉
    Description: Key Points: 〈list list-type="bullet"〉 〈list-item〉 〈p xml:lang="en"〉Sudden stratospheric warmings (SSWs) lead to reduced forecast spread in the polar stratosphere for several weeks after the event〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉Reduced forecast spread after SSWs is driven by suppressed vertical planetary wave propagation due to persistent negative wind anomalies〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉Final warmings are delayed for winters with SSW, consistent with reduced upward wave fluxes following the SSW〈/p〉〈/list-item〉 〈/list〉 〈/p〉
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: https://apps.ecmwf.int/datasets/data/s2s-realtime-instantaneous-accum-ecmf/levtype=sfc/type=cf/
    Description: https://cds.climate.copernicus.eu/cdsapp#!/dataset/reanalysis-era5-pressure-levels?tab=overview
    Description: https://doi.org/10.5282/ubm/data.395
    Keywords: ddc:551.5 ; sudden stratospheric warming ; final warming ; strat‐trop‐coupling ; polar vortex ; predictability ; window of forecast opportunity
    Language: English
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  • 146
    Publication Date: 2024-01-24
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉Climate change poses increasingly severe risks for coastal ecosystems and coastal communities all around the globe. This condition requires implementing climate adaptation policy and advancing scientific knowledge to adapt to the current and future climate risks. However, implementing climate adaptation policy in coastal areas is still in its infancy. This paper provides insight into 650 peer‐reviewed empirical research studies on coastal climate adaptation from the past two decades, providing global evidence on the status quo and distilling six relevant research gaps: (a) minimal contribution to the implementation phase of the adaptation policy cycle; (b) geographical imbalance toward specific ecoregions and coastal sub‐systems; (c) less attention to regional scale; (d) lack of sectoral integration; (e) poor contextualization within policy and coastal governance instruments and management arrangements; (f) limited economic and financial focus. Therefore, this paper identifies areas where future empirical research can help fill current knowledge gaps and improve coastal communities' ability to adapt to climate change. This increased knowledge will enhance the resilience of coastal social‐ecological systems in the face of environmental challenges.〈/p〉
    Description: Plain Language Summary: Coastal regions are complex environments and are severely threatened by climate change. These regions are particularly vulnerable to rising sea levels, more frequent and intense storms, altered precipitation patterns, and higher ocean temperatures. These changes can pose pervasive threats to coastal communities, ecosystems, infrastructure, and economic activities. This manuscript reviews the last 20 years of coastal adaptation science and provides evidence of six areas where further research is needed. In our analysis, we adopt a worldwide scale and multidisciplinary perspective to review 650 publications and draw some conclusions and recommendations around which science could benefit coastal adaptation to climate change. Overall, we find a geographical imbalance of knowledge production which mostly neglects the global south, and that science needs to boost cooperation across borders and economic sectors and services.〈/p〉
    Description: Key Points: 〈list list-type="bullet"〉 〈list-item〉 〈p xml:lang="en"〉Scientific contribution to the adaptation policy cycle needs an implementation perspective〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉Adaptation research must advance knowledge in highly climate‐sensitive ecoregions, across borders and sectors〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉Economic barriers to coastal adaptation have been overlooked globally〈/p〉〈/list-item〉 〈/list〉 〈/p〉
    Description: Helmholtz‐Zentrum Hereon project I2B – CoastalClimateServices@GERICS
    Description: https://doi.org/10.5281/ZENODO.8146458
    Keywords: ddc:333.917 ; coastal adaptation ; adaptation policy cycle ; coastal management ; adaptation strategies ; economic sectors ; scientific knowledge
    Language: English
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  • 147
    Publication Date: 2024-01-24
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉In order not to significantly overshoot maximum levels of warming like the 1.5 and 2°C target we must stay within a fixed emissions budget. How to fairly distribute the entitlements to emit within such a budget is perhaps the most intensely discussed question in all of climate justice. In our review we discuss the most prominent proposals in moral and political philosophy on how to solve this question and put a special emphasis on scholarly contributions from the last decade. We canvass the arguments for and against emissions egalitarianism, emissions sufficientarianism, and emissions grandfathering as well as the debates surrounding them. These are how to deal with non‐compliance, how to split emissions between producers and consumers, how to best account for terrestrial carbon sinks, and whether emissions from having children should be subtracted from parents' emissions budgets. From the viewpoint of justice, it matters not only that we act against climate change but also how we do so. This review aims to elucidate one of the major ways in which our reaction to climate change could be just or unjust.〈/p〉
    Description: Bundesministerium für Bildung und Forschung http://dx.doi.org/10.13039/501100002347
    Keywords: ddc:363.7 ; carbon sinks ; emissions egalitarianism ; historical responsibility ; integrationism ; non‐compliance
    Language: English
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  • 148
    Publication Date: 2024-01-24
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉Jet streams are important sources of non‐orographic internal gravity waves and clear air turbulence (CAT). We analyze non‐orographic gravity waves and CAT during a merger of the polar front jet stream (PFJ) with the subtropical jet stream (STJ) above the southern Atlantic. Thereby, we use a novel combination of airborne observations covering the meso‐scale and turbulent scale in combination with high‐resolution deterministic short‐term forecasts. Coherent phase lines of temperature perturbations by gravity waves stretching along a highly sheared tropopause fold are simulated by the ECMWF IFS (integrated forecast system) forecasts. During the merging event, the PFJ reverses its direction from approximately antiparallel to parallel with respect to the STJ, going along with strong wind shear and horizontal deformation. Temperature perturbations in limb‐imaging and lidar observations onboard the research aircraft HALO during the SouthTRAC campaign show remarkable agreement with the IFS data. Ten hours earlier, the IFS data show an “X‐shaped” pattern in the temperature perturbations emanating from the sheared tropopause fold. Tendencies of the IFS wind components show that these gravity waves are excited by spontaneous emission adjusting the strongly divergent flow when the PFJ impinges the STJ. In situ observations of temperature and wind components at 100 Hz confirm upward propagation of the probed portion of the gravity waves. They furthermore reveal embedded episodes of light‐to‐moderate CAT, Kelvin Helmholtz waves, and indications for partial wave reflection. Patches of low Richardson numbers in the IFS data coincide with the CAT observations, suggesting that this event was accessible to turbulence forecasting.〈/p〉
    Description: Plain Language Summary: Gravity waves play an in important role in vertical and horizontal energy transport in the atmosphere and are significant factors in wheather forecasting and climate projections. Among other processes, tropospheric jet streams are known to be sources of gravity waves. They furthermore can be accompanied by tropopause folds (i.e., local tropopause depressions, where stratospheric air can reach deeply into the troposphere) and turbulence, which is relevant for aviation safety. Using a novel combination of airborne observations and data by a state‐of‐the‐art forecasting system, we analyze gravity waves and turbulence during a merger of tropospheric jet streams above the southern Atlantic. The observations show a high degree of agreement with the forecast data from the troposphere to the stratosphere. Ten hours earlier, the forcast data show an “X‐shaped” gravity wave structure that emerges from a highly sheared tropopause fold between the merging jet streams. Fast in situ observations at the flight level provide information on the characteristics of the observed waves and show light‐to‐moderate turbulence, small‐scale waves and indications for partial wave reflection. The observed turbulence events are consistently located in regions where the forecast data suggest potential for turbulence.〈/p〉
    Description: Key Points: 〈list list-type="bullet"〉 〈list-item〉 〈p xml:lang="en"〉Non‐orographic internal gravity waves and clear air turbulence are observed in merging jet streams〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉State‐of‐the art high resolution forecast agrees with novel combination of airborne sensors〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉“X‐shaped” gravity wave feature resulting from merging jet streams at a highly sheared tropopause fold〈/p〉〈/list-item〉 〈/list〉 〈/p〉
    Description: Bundesministerium für Bildung und Forschung http://dx.doi.org/10.13039/501100002347
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: https://doi.org/10.5445/IR/1000151856
    Description: https://www.ecmwf.int/en/forecasts
    Description: https://www.ready.noaa.gov/
    Keywords: ddc:551.5 ; gravity waves ; jet streams ; clear air turbulence ; remote sensing ; in situ observations ; field campaigns
    Language: English
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  • 149
    Publication Date: 2024-01-24
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉Flood risk assessments require different disciplines to understand and model the underlying components hazard, exposure, and vulnerability. Many methods and data sets have been refined considerably to cover more details of spatial, temporal, or process information. We compile case studies indicating that refined methods and data have a considerable effect on the overall assessment of flood risk. But are these improvements worth the effort? The adequate level of detail is typically unknown and prioritization of improvements in a specific component is hampered by the lack of an overarching view on flood risk. Consequently, creating the dilemma of potentially being too greedy or too wasteful with the resources available for a risk assessment. A “sweet spot” between those two would use methods and data sets that cover all relevant known processes without using resources inefficiently. We provide three key questions as a qualitative guidance toward this “sweet spot.” For quantitative decision support, more overarching case studies in various contexts are needed to reveal the sensitivity of the overall flood risk to individual components. This could also support the anticipation of unforeseen events like the flood event in Germany and Belgium in 2021 and increase the reliability of flood risk assessments.〈/p〉
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: BMBF http://dx.doi.org/10.13039/501100002347
    Description: Federal Environment Agency http://dx.doi.org/10.13039/501100010809
    Description: http://howas21.gfz-potsdam.de/howas21/
    Description: https://www.umwelt.niedersachsen.de/startseite/themen/wasser/hochwasser_amp_kustenschutz/hochwasserrisikomanagement_richtlinie/hochwassergefahren_und_hochwasserrisikokarten/hochwasserkarten-121920.html
    Description: https://download.geofabrik.de/europe/germany.html
    Description: https://emergency.copernicus.eu/mapping/list-of-components/EMSN024
    Description: https://data.jrc.ec.europa.eu/collection/id-0054
    Description: https://oasishub.co/dataset/surface-water-flooding-footprinthurricane-harvey-august-2017-jba
    Description: https://www.wasser.sachsen.de/hochwassergefahrenkarte-11915.html
    Keywords: ddc:551.48 ; decision support ; extreme events ; integrated flood risk management ; risk assessment
    Language: English
    Type: doc-type:article
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  • 150
    Publication Date: 2024-02-06
    Description: Turkey serves as an important food hub for neighboring countries in the water‐scarce Middle East and North African region, and self‐sufficiency in agri‐food production is one of the country's major policy objectives. The Turkish government had therefore introduced various support measures for its inefficient livestock sector, including payments for irrigated fodder crops, which are likely to increase water depletion. To simultaneously assess the economic and environmental effects of these policies, we link an economy‐wide computable general equilibrium model of Turkey to a newly developed water footprint module. We find that removal of direct livestock support may not lead to large water savings, but may instead redirect irrigation water to higher value crops. Conversely, removal of fodder subsidies and overall efficiency improvements in livestock can lead to overall water savings and net economic gains.
    Description: Plain Language Summary: Turkey is a major exporter of food for the dry Middle East and North African region, while the goal of the Turkish government is to become more independent of imported livestock products. The government therefore pays different subsidies to encourage production within Turkey's inefficient livestock sector. As part of this strategy, a subsidy is paid to fodder crops that are irrigated with an increasing amount of water, although water resources in Turkey are already under stress. We therefore develop a new methodology that combines an economic model of the Turkish economy with a new water footprint calculation tool. With this method, we assess how different types of subsidies affect water use in Turkey through economic linkages and livestock‐related policies. Our model results show that removal of subsidies which are directly paid to livestock producers would not much reduce irrigation water use. However, the valuable irrigation water would increasingly be used to produce high value export crops such as vegetables, rather than low value fodder crops. Moreover, the abolishment of subsidies directly paid to fodder crop producers and technical measures that spur productivity in the livestock sector can achieve both, a reduction in irrigation water use and better economic outcomes.
    Description: Key Points: Removal of direct Turkish livestock support may not lead to large water savings but redirects irrigation water to higher value crops. Removal of fodder subsidies shows the largest potential for water savings out of all scenarios. Improvements to overall economic efficiency in Turkey's livestock sector lead to net economic gains without major effects on blue water use.
    Description: https://www.gtap.agecon.purdue.edu/databases/v9/default.asp
    Description: https://waterfootprint.org/en/resources/waterstat/product-water-footprint-statistics/
    Description: https://doi.org/10.5194/essd-13-2025-2021
    Description: https://www.ifpri.org/publication/standard-computable-general-equilibrium-cge-model-gams-0
    Description: https://doi.org/10.6084/m9.figshare.19486772.v1
    Keywords: ddc:631 ; Turkey ; water ; livestock ; CGE model ; agricultural subsidies
    Language: English
    Type: doc-type:article
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  • 151
    Publication Date: 2024-02-06
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉We have performed in situ time‐of‐flight neutron diffraction experiments to examine the uptake of deuterium in iron monosulfide at pressures up to 11.4 GPa and temperatures to 1300 K. A D〈sub〉2〈/sub〉 fluid was formed in the experiments through the decomposition of ND〈sub〉3〈/sub〉BD〈sub〉3〈/sub〉, resulting in an oxygen fugacity of approximately 1.2 log units below the iron‐wüstite buffer. Deuterium positions and site occupancies were determined in FeS V, using Rietveld refinements of the powder neutron diffraction patterns. Our structural model indicates that two normally unoccupied sites in the 〈italic〉P〈/italic〉6〈sub〉3〈/sub〉/〈italic〉mmc〈/italic〉 FeS V structure, at Wyckoff positions 〈italic〉6h〈/italic〉 and 〈italic〉4f〈/italic〉, are partially occupied by D atoms, with the latter being more dominant. The deuterium content D〈sub〉x〈/sub〉 in FeSD〈sub〉X〈/sub〉 increases with both pressure and temperature over the experimental conditions explored, from 0.126 (14) at 2.3 GPa and 787 K to 1.20 (16) at 9.7 GPa and 1300 K. The unit‐cell volume expansion per deuterium atom is 1.53 ± 0.16 Å〈sup〉3〈/sup〉 at 6.9 GPa and 960 K, which is smaller than that determined for metallic iron phases at similar conditions. The variation in unit‐cell volume indicates that most deuterium is lost from FeS V upon temperature quenching at high‐pressures. By fitting the obtained FeS V deuterium site occupancies to a thermodynamic model, estimates for the hydrogen contents of iron monosulfide at conditions and oxygen fugacities consistent with the base of the cratonic lithosphere can be made. This results in values in the range of 1,700–2,700 ppm, which contribute to approximately 2–3 ppm hydrogen in the bulk mantle.〈/p〉
    Description: Plain Language Summary: Small amounts of iron sulfide minerals are found in most rocks from the Earth's mantle and as inclusions trapped in natural diamonds. Hydrogen may dissolve into iron sulfide minerals under high pressures and temperature, but is most likely lost once pressure and temperature are removed. In this study, we determined deuterium contents (deuterium was used as a proxy for hydrogen as it has better neutron scattering properties) in iron sulfide, held under high pressure and temperature conditions, using neutron diffraction measurements. Our results show that the amount of deuterium in iron sulfide increases with both pressure and temperature, but the deuterium is lost on recovery to room conditions. The results are used to estimate hydrogen contents of iron sulfide minerals in the deep continental lithospheric mantle, which are found to be in the range 1,700–2,700 ppm. This corresponds to approximately 2–3 ppm of hydrogen in the bulk mantle.〈/p〉
    Description: Key Points: 〈list list-type="bullet"〉 〈list-item〉 〈p xml:lang="en"〉Deuterium contents in iron sulfide were measured at high‐〈italic〉P〈/italic〉, up to 11.4 GPa and high‐〈italic〉T〈/italic〉 to 1300 K in in situ neutron diffraction experiments〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉The total deuterium content, D〈sub〉x〈/sub〉 in FeSD〈sub〉X〈/sub〉, increases with both 〈italic〉P〈/italic〉 and 〈italic〉T〈/italic〉, from 0.126 (14) at 2.3 GPa and 787 K to 1.20 (16) at 9.7 GPa and 1300 K〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉A thermodynamic model shows that the hydrogen contents of iron monosulfide at the base of the cratonic lithosphere could be 1,700–2,700 ppm〈/p〉〈/list-item〉 〈/list〉 〈/p〉
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: https://doi.org/10.6084/m9.figshare.21820677.v2
    Keywords: ddc:550.724 ; iron monosulfide ; neutron diffraction ; deuterium ; Earth's mantle
    Language: English
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  • 152
    Publication Date: 2024-02-06
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉The total meridional heat transport (MHT) is relatively stable across different climates. Nevertheless, the strength of individual processes contributing to the total transport are not stable. Here we investigate the MHT and its main components especially in the atmosphere, in five coupled climate model simulations from the Deep‐Time Model Intercomparison Project (DeepMIP). These simulations target the early Eocene climatic optimum, a geological time period with high CO〈sub〉2〈/sub〉 concentrations, analog to the upper range of end‐of‐century CO〈sub〉2〈/sub〉 projections. Preindustrial and early Eocene simulations, at a range of CO〈sub〉2〈/sub〉 levels are used to quantify the MHT changes in response to both CO〈sub〉2〈/sub〉 and non‐CO〈sub〉2〈/sub〉 related forcings. We found that atmospheric poleward heat transport increases with CO〈sub〉2〈/sub〉, while oceanic poleward heat transport decreases. The non‐CO〈sub〉2〈/sub〉 boundary conditions cause more MHT toward the South Pole, mainly through an increase in the southward oceanic heat transport. The changes in paleogeography increase the heat transport via transient eddies at the northern mid‐latitudes in the Eocene. The Eocene Hadley cells do not transport more heat poleward, but due to the warmer atmosphere, especially the northern cell, circulate more heat in the tropics, than today. The monsoon systems' poleward latent heat transport increases with rising CO〈sub〉2〈/sub〉 concentrations, but this change is counterweighted by the globally smaller Eocene monsoon area. Our results show that the changes in the monsoon systems' latent heat transport is a robust feature of CO〈sub〉2〈/sub〉 warming, which is in line with the currently observed precipitation increase of present day monsoon systems.〈/p〉
    Description: Plain Language Summary: In the Earth's climate system both the atmosphere and the ocean are transporting heat through different processes from the tropics toward the poles. We investigate the transport of the atmosphere in several climate model set ups, which aim to simulate the very warm climate of the early Eocene (∼56–48 Myr ago). This period is relevant, because the atmospheric CO〈sub〉2〈/sub〉 concentration was close to our pessimistic projection of CO〈sub〉2〈/sub〉 concentration for the end of the century. In our study we separate the results into transport changes due to the different set up of the Eocene, and transport changes due to larger CO〈sub〉2〈/sub〉 concentration values. We found that with rising CO〈sub〉2〈/sub〉 values the atmosphere transports more heat from the tropics to the poles. The different location of the continents and seas is influencing the heat transport of the midlatitude cyclones. The Eocene tropical meridional overturning circulation's poleward heat transport does not increase, but it circulates more heat than today. The monsoon systems seem to be affecting a globally smaller area in the Eocene, but they are also more effective in transporting heat. This conclusion is in line with the observation, that current day monsoon systems' precipitation increases, as our CO〈sub〉2〈/sub〉 concentration rises.〈/p〉
    Description: Key Points: 〈list list-type="bullet"〉 〈list-item〉 〈p xml:lang="en"〉The latent heat transport of the monsoon increases through the Eocene higher CO〈sub〉2〈/sub〉 concentration, but it is reduced by the Eocene topography〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉The poleward heat transport of midlatitude cyclones is higher in the Northern Hemisphere in the Eocene, due to the different topography〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉The Eocene northern Hadley cell circulates more heat, than in the present, while its net poleward heat transport is even less than today〈/p〉〈/list-item〉 〈/list〉 〈/p〉
    Description: Hessisches Ministerium für Wissenschaft und Kunst http://dx.doi.org/10.13039/501100003495
    Description: National Science Fundation
    Description: Swedish Research Council
    Description: NERC SWEET
    Description: Kakenhi
    Description: National Center for Atmospheric Research
    Description: Australian Research Council
    Description: https://www.deepmip.org/data-eocene/
    Description: https://doi.org/10.24381/cds.6860a573
    Description: https://doi.org/10.24381/cds.f17050d7
    Description: https://doi.org/10.5281/zenodo.7958397
    Description: 551.6
    Keywords: meridional heat transport ; early Eocene climatic optimum ; paleoclimate ; monsoon ; CO2 effect ; DeepMIP
    Language: English
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  • 153
    Publication Date: 2024-02-09
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉Gas transport in soils is usually assumed to be purely diffusive, although several studies have shown that non‐diffusive processes can significantly enhance soil gas transport. These processes include barometric air pressure changes, wind‐induced pressure pumping and static air pressure fields generated by wind interacting with obstacles. The associated pressure gradients in the soil can cause advective gas fluxes that are much larger than diffusive fluxes. However, the contributions of the respective transport processes are difficult to separate. We developed a large chamber system to simulate pressure fields and investigate their influence on soil gas transport. The chamber consists of four subspaces in which pressure is regulated by fans that blow air in or out of the chamber. With this setup, we conducted experiments with oscillating and static pressure fields. CO〈sub〉2〈/sub〉 concentrations were measured along two soil profiles beneath the chamber. We found a significant relationship between static lateral pressure gradients and the change in the CO〈sub〉2〈/sub〉 profiles (R〈sup〉2〈/sup〉 = 0.53; 〈italic toggle="no"〉p〈/italic〉‐value 〈2e‐16). Even small pressure gradients between −1 and 1 Pa relative to ambient pressure resulted in an increase or decrease in CO〈sub〉2〈/sub〉 concentrations of 8% on average in the upper soil, indicating advective flow of air in the pore space. Positive pressure gradients resulted in decreasing, negative pressure gradients in increasing CO〈sub〉2〈/sub〉 concentrations. The concentration changes were probably caused by an advective flow field in the soil beneath the chamber generated by the pressure gradients. No effect of oscillating pressure fields was observed in this study. The results indicate that static lateral pressure gradients have a substantial impact on soil gas transport and therefore are an important driver of gas exchange between soil and atmosphere. Lateral pressure gradients in a comparable range can be induced under windy conditions when wind interacts with terrain features. They can also be caused by chambers used for flux measurements at high wind speed or by fans used for head‐space mixing within the chambers, which yields biased flux estimates.〈/p〉
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Keywords: ddc:631.4 ; advective flux ; chamber flux measurements ; static air pressure fields ; wind‐induced pressure pumping
    Language: English
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  • 154
    Publication Date: 2024-02-09
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉Fluid flow in fracture porosity in the Earth's crust is in general accompanied by crystallization or dissolution depending on the state of saturation. The evolution of the microstructure in turn affects the transport and mechanical properties of the rock, but the understanding of this coupled system is incomplete. Here, we aim to simulate spatio‐temporal observations of laboratory experiments at the grain scale (using potash alumn), where crystals grow in a fracture during reactive flow, and show a varying growth rate along the fracture due to saturation differences. We use a multiphase‐field modeling approach, where reactive fluid flow and crystal growth is computed and couple the chemical driving force for grain growth to the local saturation state of the fluid. The supersaturation of the fluid is characterized by a concentration field which is advected by fluid flow and in turn affects the crystal growth with anisotropic growth kinetics. The simulations exhibit good agreement with the experimental results, providing the basis for upscaling our results to larger scale computations of combined multi‐physical processes in fractured porous media for applications as groundwater protection, geothermal, and hydrocarbon reservoir prediction, water recovery, or storing H〈sub〉2〈/sub〉 or CO〈sub〉2〈/sub〉 in the subsurface.〈/p〉
    Description: Plain Language Summary: In the Earth's crust fluid flow can occur in fractured rock and depending on the composition of the fluid and physical conditions minerals can precipitate or dissolve. This affects the properties of the rock system and is for example, of interest to subsurface engineering applications. In this work we simulate observations of laboratory experiments at the grain scale, where crystals grow in an open fracture during fluid flow. In these experiments, the growth rate of the crystals varies along the fracture since the supersaturation of the fluid decreases due to the crystallization. We use a multiphase‐field model for the numerical simulation of crystal growth in the open fracture and combine it with reactive fluid flow. With the presented model the driving force for grain growth is coupled to the local supersaturation, which enables the incorporation of reactive mass transport in open fractures. Our phase‐field simulations agree with the laboratory experiments. The presented simulative approach can be used for upscaling the results on microscale to larger length and time scales and can help to better predict the subsurface behavior for example, of groundwater, fractured geothermal, and hydrocarbon reservoirs.〈/p〉
    Description: Key Points: 〈list list-type="bullet"〉 〈list-item〉 〈p xml:lang="en"〉Reactive fluid flow with advective mass transfer causes locally variable precipitation rate in open fracture〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉A higher flow velocity or a higher supersaturation results in faster precipitation along the flow channel〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉Phase‐field modeling allows reproduction of laboratory crystal growth experiments from an advecting fluid using transmitted light microscopy〈/p〉〈/list-item〉 〈/list〉 〈/p〉
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: Helmholtz Association http://dx.doi.org/10.13039/501100009318
    Description: https://doi.org/10.5281/zenodo.7516287
    Description: http://www.steinbeis.de/
    Keywords: ddc:550.724 ; phase‐field modeling ; fluid flow ; supersaturation ; crystal growth ; flow channel
    Language: English
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  • 155
    Publication Date: 2024-02-05
    Description: Eastward zonal jets at intermediate depths of 300–800 m connect the oxygen‐rich western boundary of the Atlantic basin with the oxygen minimum zones (OMZs) on the eastern boundary. They are not well represented in climate models because the low horizontal resolution of these models yields excessive viscosity. We use two physical‐biogeochemical model configurations of the Tropical Atlantic to show that the increase in resolution results in more robust intermediate zonal jets and a better representation of the OMZs. The OMZ structure is distorted at low‐resolution as surface, westward jets advect low‐oxygen waters from the eastern boundary much further west than in the climatology. The emergence of robust eastward jets in the high‐resolution run alleviate this problem and reproduce the Atlantic OMZs more accurately. The asymmetry between westward and eastward jets occurs because the former are associated with homogenous potential vorticity regions originating in the eastern boundary while the latter are associated with potential vorticity gradients. Intermediate, eastward jets constrain the westward expansion of the OMZs by supplying oxygen to their western edge. Within the OMZs, higher resolution allows a better representation of the boundary current system and eddying processes at depth which redistribute of low oxygen values from the productive eastern boundary. Basin‐scale, high‐resolution simulations reproduce more accurately the transfer of energy across scales that results in robust zonal jets as well as their impact on the ocean biogeochemistry. Accurate model predictions provide a pathway to disentangle natural and anthropogenic causes of ocean deoxygenation.
    Description: Plain Language Summary: Long‐term averages of ocean velocities reveal the existence of east‐west, alternating currents along multiple latitudes. These currents are difficult to observe and model because of their small speeds at great depths. Despite their low intensity, in the long‐term they can transport tracers across the ocean basins with oxygen being a very important one as it provides conditions for aerobic respiration in so‐called oxygen minimum zones (OMZs) on the eastern side of the basin. Long‐term measurements show that oxygen concentrations are decreasing in various regions of the ocean and that OMZs are expanding, which can be a problem as these regions may become inhospitable for aerobic life. That is why we need to understand the processes that supply oxygen to OMZs and are important for their evolution with time. Models can be used as tools for testing hypotheses regarding the expansion or contraction of OMZs in the future. However, models must be shown to correctly simulate the dynamics and biogeochemistry of the region as a whole. Our results show that these intermediate east‐west current systems are important in structuring the OMZs and that higher‐resolution, basin‐scale simulations are necessary to correctly simulate their impact on oxygen concentrations in the ocean.
    Description: Key Points: Intermediate, eastward zonal jets are an important oxygen supply route to the oxygen minimum zones and modulate their westward extent. Robust, intermediate zonal jets emerge in a high‐resolution (3 km), basin‐scale simulation with robust eddying motions at depth. A correct representation of the zonal jets in climate models is key for reliable, long‐term forecasts of ocean deoxygenation.
    Description: Changing Earth ‐ Helmholtz Association
    Description: https://doi.org/10.5281/zenodo.7229219
    Description: https://doi.org/10.5281/zenodo.7081664
    Description: https://doi.org/10.5281/zenodo.7234366
    Keywords: ddc:551.46 ; zonal jets ; oxygen minimum zones ; biogeochemical modeling ; Tropical Atlantic
    Language: English
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  • 156
    Publication Date: 2024-02-05
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉ABSTRACT〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉The recent rise in air temperatures detected at high altitudes of the Tibetan Plateau has accelerated glacier melt and retreat. Moreover, enhanced monsoonal precipitation has increased runoff and transport of allochthonous material to the lakes. Consequently, water levels are rising, modifying the spatial distribution and composition of local aquatic biota. To infer these environmental and biological changes in recent decades, a 30‐cm‐long sediment core, representing the past ~160 years, from Nam Co, an endorheic lake, was analyzed for subfossil chironomid assemblages and sediment geochemistry. In total, 25 chironomid morphotypes were identified. Nineteen were considered as non‐rare taxa (abundances ≥2%) and six as rare taxa (abundances 〈2%). Since 1956 〈sc〉ce〈/sc〉, higher chironomid richness (〈italic〉S〈/italic〉 = 19) is evident compared to the previous 100 years. The simultaneous decrease in the abundance of profundal 〈italic〉Micropsectra radialis〈/italic〉‐type and increase of both 〈italic〉Chironomus〈/italic〉 and 〈italic〉Procladius〈/italic〉, taxa adapted to more eurytopic and slightly warmer water bodies, indicate increasing water temperatures and intensified primary productivity. The dominance of littoral chironomid assemblages reflects increasing lake water levels, flooded shorelines and expansion of littoral areas driven by increased precipitation and glacial meltwater input both resulting from the increase in air temperatures. This scenario is confirmed by increases in total nitrogen and Zr/Rb ratios, indicating higher productivity and coarser grain size as a consequence of increased runoff via the Niya Qu. These hydrological changes have resulted in a positive water balance that can be linked to an increase in moisture supply from the Indian summer monsoon and glacier melt, reflecting increasing temperatures and precipitation since 1956 〈sc〉ce〈/sc〉, ultimately driven by anthropogenic warming.〈/p〉
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Keywords: ddc:577.6 ; chironomid ; Indian summer monsoon ; Nam Co ; Niya Qu ; nutrients ; runoff ; water level
    Language: English
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  • 157
    Publication Date: 2024-02-05
    Description: We present an experimental study simulating atmospheric dust devils in a controlled laboratory experiment. The experimental facility, called the “Barrel of Ilmenau” (www.ilmenauer-fass.de) represents a classical Rayleigh‐Bénard set‐up and is believed to model the phenomena in a convective atmospheric boundary layer fairly well. Our work complements and extends the numerical work of Giersch and Raasch (2021)https//doi.org/10.1029/2020jd034334 by experiments. Dust devils are thermal convective vortices with a vertical axis of rotation visualized by entrained soil particles. They evolve in the convective atmospheric boundary layer and are believed to substantially contribute to the aerosol transport into the atmosphere. Thus, their evolution, size, lifetime, and frequency of occurrence are of particular research interest. Extensive experimental studies have been conducted by field measurements and laboratory experiments so far. Beyond that, our study is the first attempt of Rayleigh‐Bénard convection (RBC) in air to investigate dust devil‐like vortices in a laboratory experiment. Up to now, this set‐up mimics the natural process of dust devil evolution as closest to reality. The flow measurement was carried out by particle tracking velocimetry using neutrally buoyant soap bubbles. We initially identified dust devil‐like vortices by eye from the Lagrangian velocity field, and in a later, more sophisticated analysis by a specific algorithm from the corresponding Eulerian velocity field. We analyzed their frequency of occurrence, observation time, and size. With our work, we could demonstrate that turbulent RBC is an appropriate model to mimic the natural process of the evolution of dust devils in the convective atmospheric boundary layer without artificial stimulation.
    Description: Plain Language Summary: We could experimentally demonstrate that dust devil‐like vortices spontaneously arise in turbulent Rayleigh‐Bénard convection. This first‐time experimental survey simulates the evolution of dust devil‐like vortices in a laboratory experiment which mimics the convective atmospheric boundary layer quite closely and gets by without any artificial input of rotation. Dust devil‐like vortices are measured and identified using the particle tracking velocimetry technique. Within an observation period of 2 hr, 56 dust devil‐like vortices could be detected in total. Their properties coincide quite well with those structures identified in very recent direct numerical simulations (DNS) by Giersch and Raasch (2021, https//doi.org/10.1029/2020jd034334). As well, they show similarity to atmospheric dust devils. The size of our experimentally generated dust devil‐like vortices starts at about 1 dm and ranges up to about 1 m. This is larger than in DNS, but still smaller than in the atmosphere or in large eddy simulation.
    Description: Key Points: Dust devil‐like vortices spontaneously evolve in turbulent Rayleigh‐Bénard convection at sufficiently high Rayleigh numbers Ra 〉 1010. We studied their properties in a large‐scale Rayleigh‐Bénard experiment using Lagrangian particle tracking velocimetry. The vortical structures in the laboratory experiment are weaker than atmospheric dust devils, but they exhibit similar features.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: https://ftp.tu-ilmenau.de/hpc-private/mb/Dust_Devil_Scripts.rar
    Description: https://ftp.tu-ilmenau.de/hpc-private/mb/Kaestner_et_al_2022_dust_devil-like_vortex_in_turbulent_Rayleigh_Benard_convection.avi
    Keywords: ddc:550.724 ; dust devils ; particle tracking velocimetry ; Rayleigh‐Bénard convection ; turbulence ; atmospheric boundary layer
    Language: English
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  • 158
    Publication Date: 2024-02-05
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉The Arctic forests of the Eocene, which thrived under elevated CO〈sub〉2〈/sub〉, a temperate climate, high precipitation and annually extremely different daylengths, represent a quite spectacular no‐analogue habitat of Earth's greenhouse past. The aim of this study was to improve our understanding of the ecophysiology of Arctic broad‐leaved deciduous forests of the Eocene, by analyzing leaf photosynthesis and tree productivity based on gas exchange modeling for two fossil Eocene sites, Svalbard and Ellesmere Island. For this, a single‐leaf photosynthesis model that includes heat transfer and leaf senescence was derived. Environmental conditions were based on available palaeoclimate data and a CO〈sub〉2〈/sub〉 level of 800 μmol/mol. Additionally, different light regimes (diffusivity and transmissivity) were considered. With this model, annual photosynthesis was calculated on the basis of annual temperature and day lengths (derived by celestial mechanics). To obtain productivity of a whole deciduous broad‐leaved tree, the single leaf data were then upscaled by a canopy model. The results indicate that productivity was enhanced at both high latitude sites by elevated CO〈sub〉2〈/sub〉, temperature of the growing season and high maximum daylength (24 hr) during late spring and early summer. With productivity values about 30%–60% higher as for a mid‐latitude continental European forest, the results indicate a potential for high productivity at the Eocene polar sites which is in the range of extant tropical forests. In contrast to speculations, no evidence for a selective advantage of large leaf size—as shown by various fossil leaves from high latitude sites—could be found.〈/p〉
    Description: Plain Language Summary: Greenhouse conditions of the past allowed forests to thrive in the Arctic. The productivity of early Eocene broad‐leaved trees, growing about 55–45 million years ago within the Arctic circle, was studied by applying physiological models to the climate conditions of the past. The Arctic environment during that time was non‐analogous, meaning that today there is no spot on Earth showing the same conditions which included a temperate climate, ample precipitation, 24 hr of daylight during early summer and a CO〈sub〉2〈/sub〉 concentration twice as high as today's CO〈sub〉2〈/sub〉 concentration. It was found that under these conditions, tree productivity is up to about 30%–60% higher as that of an extant temperate mid‐latitude forest. Knowledge on the ecology of high‐latitude environments of past greenhouse periods can provide valuable information for possible climate change scenarios of the future.〈/p〉
    Description: Key Points: 〈list list-type="bullet"〉 〈list-item〉 〈p xml:lang="en"〉Lush forests thrived in the Arctic during the Eocene under non‐analogous climatic conditions〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉Tree productivity of Eocene forests was studied for two exemplary fossil Arctic sites based on a photosynthesis model〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉Compared to extant deciduous forests, productivity of Arctic Eocene forests was in the range of modern tropical forests〈/p〉〈/list-item〉 〈/list〉 〈/p〉
    Description: ftp://palantir.boku.ac.at/Public/MODIS_EURO
    Description: https://land.copernicus.eu/pan-european/corine-land-cover/clc2018
    Keywords: ddc:561 ; Eocene ; Arctic forests ; Svalbard ; Ellesmere Island ; photosynthesis
    Language: English
    Type: doc-type:article
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  • 159
    Publication Date: 2023-10-31
    Description: Quantification of the temporally varying streamflow intermittence at continental scales provides an important basis for evaluating biodiversity, ecosystem functions and ecosystem services in rivers as well as water resources for humans. As streamflow intermittence is often more prevalent in small upstream river reaches than in large downstream rivers, quantification needs to be done with a high spatial resolution. Aggregated to five classes (0, 1-2, 3-15, 16-29, 30-31 no-flow days), the number of no-flow days of approximately 1.5 million river reaches in Europe was estimated for each of the 468 months in the period 1981-2019 using a two-step Random Forest modeling approach. The model was developed based on a custom version of the 15 arc-sec HydroSHEDS drainage direction dataset. Data for 18 predictor variables (on hydrology, climate, physiography, geology, and land cover) as well as daily streamflow observed at 1,915 streamflow gauging stations were prepared as input to the RF model. In addition to upstream drainage area and slope, predictors based on time series of streamflow in 15 arc-sec grid cells were found to be most important for the RF model. These time series were generated by downscaling the 0.5 arc-deg runoff of the global hydrological model WaterGAP (downscaled streamflow is also already available for South America). In Europe but not in South America, the performance of downscaled monthly WaterGAP v2.2e streamflow as compared to streamflow observations is, on average, satisfactory also for small drainage basins of less than 10 km2. While 99% and 95% of the observed perennial station-months are predicted correctly for the calibration and validation periods, respectively, the RF approach tends to overestimate intermittence Considering only the intermittent station-months, the frequency of predicting the correct class among the four classes is about 56% and 47% for the calibration and the validation period, respectively. 9% of all reach-months are simulated to be intermittent. The temporal and spatial patterns of simulated intermittence classes are plausible. The simulated intermittence class in each reach-month will be used by the other DRYvER Work Packages to upscale models developed at the Drying River Network scale.
    Description: report
    Keywords: Streamflow ; Random Forest ; Downscaling ; No-flow days ; Streamflow intermittence ; Continental scale
    Language: English
    Type: doc-type:book
    Format: 59
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  • 160
    Publication Date: 2023-11-13
    Description: Rifting and continental break‐up are fundamental tectonic processes, the understanding of which is of prime importance. However, the vast temporal and spatial scales involved pose major limitations to researchers. Analog tectonic modeling represents a great means to mitigate these limitations, but studying the complex internal deformation of lithospheric‐scale models remains a challenge. We therefore present a novel method for lithospheric‐scale rifting models that are uniquely monitored in an X‐ray CT scanner, which combined with digital image correlation (DIC) techniques, provides unparalleled insights into model deformation. Our first models illustrate how the degree of coupling between competent lithospheric layers, which are separated by a weak lower crustal layer, strongly impacts rift system development. Low coupling isolates the upper crust from the upper lithospheric mantle layer below, preventing an efficient transfer of deformation between both layers. By contrast, fast rifting increases coupling, so that deformation in the mantle is efficiently transferred to the upper crust, inducing either a symmetric or asymmetric (double) rift system. Furthermore, oblique divergence may lead to en echelon graben arrangements and delayed exhumation of the lower crustal layer. The successful application of our novel modeling approach, yielding these first‐order insights, provides a clear incentive to continue running lithospheric‐scale rifting models, and to apply advanced monitoring techniques to extract as much information from models as possible. There is indeed a broad range of opportunities for follow‐up studies within (and beyond) the field of rift tectonics.
    Description: Plain Language Summary: The Earth's surface consists of tectonic plates that are in constant motion, driven by titanic forces deep within the planet. One of the key plate tectonic processes is the stretching (rifting) and eventual break‐up of continents, leading to the opening of oceanic basins. Understanding the mechanisms involved is of great importance. However, studying continental break‐up is challenging due to the vast size of plate tectonic systems, and the extensive timescales over which they evolve: plate tectonic processes can rarely be directly observed. A practical solution to this issue is the use of analog experiments, which reproduce these processes in a matter of hours or days in a modestly sized laboratory. However, a major obstacle that remains is the opacity of these models: similar to tectonic plates, these models are opaque, so that their internal evolution remains hidden. X‐ray CT‐scanning provides an unrivaled means to reveal a model's internal structures during a model run. Here we present the first‐ever application of CT‐scanning to monitor relatively complex lithospheric‐scale models of continental rifting. The CT scans provide unique insights into the internal evolution of such models, and we point out various possibilities for interesting follow‐up studies.
    Description: Key Points: We present the first‐ever lithospheric‐scale analog models of rifting monitored in a CT scanner, revealing their complex internal deformation. We quantify this deformation via Digital Image Correlation analysis, and show the impact of coupling and oblique rifting on rift evolution. The successful application of our novel modeling approach provides a strong incentive for follow‐up tectonic modeling studies.
    Description: Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung http://dx.doi.org/10.13039/501100001711
    Description: Helmholtz‐Zentrum Potsdam ‐ Deutsches GeoForschungsZentrum GFZ http://dx.doi.org/10.13039/501100010956
    Description: https://doi.org/10.5880/fidgeo.2022.030
    Description: https://doi.org/10.5880/fidgeo.2022.008
    Description: https://doi.org/10.5880/fidgeo.2023.006
    Description: https://doi.org/10.5880/fidgeo.2023.005
    Keywords: ddc:550.78 ; rifting ; analog modeling ; continental break‐up ; X‐ray CT‐scanning ; visualization ; monitoring
    Language: English
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  • 161
    Publication Date: 2023-11-13
    Description: We assessed the spatial and temporal variability of the Arctic Boundary Current (ABC) using seven oceanographic moorings, deployed across the continental slope north of Severnaya Zemlya in 2015–2018. Transports and individual water masses were quantified based on temperature and salinity recorders and current profilers. Our results were compared with observations from the northeast Svalbard and the central Laptev Sea continental slopes to evaluate the hydrographic transformation along the ABC pathway. The highest velocities (〉0.30 m s〈sup〉−1〈/sup〉) of the ABC occurred at the upper continental slope and decreased offshore to below 0.03 m s〈sup〉−1〈/sup〉 in the deep basin. The ABC showed seasonal variability with velocities two times higher in winter than in summer. Compared to upstream conditions in Svalbard, water mass distribution changed significantly within 20 km of the shelf edge due to mixing with‐ and intrusion of shelf waters. The ABC transported 4.15 ± 0.3 Sv in the depth range 50–1,000 m, where 0.88 ± 0.1, 1.5 ± 0.2, 0.61 ± 0.1 and 1.0 ± 0.15 Sv corresponded to Atlantic Water (AW), Dense Atlantic Water (DAW), Barents Sea Branch Water (BSBW) and Transformed Atlantic Water (TAW). 62–70% of transport was constrained to within 30–40 km of the shelf edge, and beyond 84 km, transport increases were estimated to be 0.54 Sv. Seasonality of TAW derived from local shelf‐processes and advection of seasonal‐variable Fram Strait waters, while BSBW transport variability was dominated by temperature changes with maximum transport coinciding with minimum temperatures. Further Barents Sea warming will likely reduce TAW and BSBW transport leading to warmer conditions along the ABC pathway.
    Description: Plain Language Summary: We assessed the structure and seasonal variability of the flow and water masses of the Arctic Boundary Current (ABC) in the region north of Severnaya Zemlya. This current is important in the Arctic Ocean as it transports relatively warm and saline waters along the Eurasian Arctic continental slope. We quantified the flow, transport and hydrographic variability of the ABC. Compared to observations from upstream, our results indicate that the water masses away from the shelf break maintained the hydrographic characteristics from upstream. In contrast, the water masses near the shelf break were significantly cooled and freshened due to intrusion of‐ and mixing with shelf waters. The water masses near the shelf break showed a seasonal signal in volume transport and temperature which derives from local shelf processes, advection of seasonal‐variable waters along the ABC pathway and the seasonal cooling of the Barents Sea. If the warming trend in the Barents Sea continues, warmer waters are expected to be advected eastward along the Eurasian continental slope by the ABC.
    Description: Key Points: We quantify the Arctic Boundary Current (ABC) transport north of Severnaya Zemlya with a 2015–2018 mooring array. Hydrographic changes along the ABC pathway are most prominent at the continental slope due to the interaction with shelf water. Seasonality of water masses from the shelf sea was observed in transport, temperature and off‐shelf excursions within the ABC.
    Description: Bundesministerium für Bildung und Forschung http://dx.doi.org/10.13039/501100002347
    Description: EC Horizon 2020 Framework Programme http://dx.doi.org/10.13039/100010661
    Description: Russian Science Foundation http://dx.doi.org/10.13039/501100006769
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: https://doi.pangaea.de/10.1594/PANGAEA.951363
    Description: https://doi.pangaea.de/10.1594/PANGAEA.951394
    Description: https://doi.pangaea.de/10.1594/PANGAEA.951394
    Description: https://doi.pangaea.de/10.1594/PANGAEA.954244
    Description: https://doi.pangaea.de/10.1594/PANGAEA.954249
    Description: https://doi.pangaea.de/10.1594/PANGAEA.954299
    Description: https://doi.pangaea.de/10.1594/PANGAEA.954352
    Keywords: ddc:551.48 ; Arctic Boundary Current ; seasonal transport variability ; water mass transport ; along‐slope current
    Language: English
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  • 162
    Publication Date: 2023-11-13
    Description: Ocean island basalts (OIB) show variable 〈sup〉182〈/sup〉W deficits that have been attributed to either early differentiation of the mantle or core‐mantle interaction. However, 〈sup〉182〈/sup〉W variations may also reflect nucleosynthetic isotope heterogeneity inherited from Earth's building material, which would be evident from correlated 〈sup〉182〈/sup〉W and 〈sup〉183〈/sup〉W anomalies. Some datasets for OIB indeed show hints for such correlated variations, meaning that a nucleosynthetic origin of W isotope anomalies in OIB cannot be excluded. We report high‐precision W isotope data for OIB from Samoa and Hawaii, which confirm previously reported 〈sup〉182〈/sup〉W deficits for these samples, but also demonstrate that none of these samples have resolvable 〈sup〉183〈/sup〉W anomalies. These data therefore rule out a nucleosynthetic origin of the 〈sup〉182〈/sup〉W deficits in OIB, which most likely reflect the entrainment of either core material or an overabundance of late‐accreted materials within OIB mantle sources. If these processes occurred over Earth's history, they may have also been responsible for shifting the 〈sup〉182〈/sup〉W composition of the bulk mantle to its modern‐day value. We also report Mo isotope data for some Hawaiian OIB, which reveal no resolved nucleosynthetic Mo isotopic anomalies. This is consistent with inheritance of 〈sup〉182〈/sup〉W deficits in OIB from the addition of either core or late‐accreted material, but only if these materials have a non‐carbonaceous (NC) meteorite‐like heritage. As such, these data rule out significant contributions of carbonaceous chondrite (CC)‐like materials to either Earth's core or late accretion.
    Description: Plain Language Summary: Some ocean island basalts (OIB) may contain a record of processes and characteristics of the deepest parts of Earth's mantle, including at the boundary between the iron‐rich core and mantle. Like some prior studies, we measured tungsten isotopes within OIB from Hawaii and Samoa, and report that tungsten isotopes in these OIB differ in their characteristics compared to what is observed in modern rocks that are most representative of the upper part of Earth's mantle. One explanation for these tungsten isotope anomalies is that they are a signature of chemical interaction between the core and lower mantle, suggesting that the core 'leaks' into the lower mantle. Another possibility proposed here is that these tungsten isotope anomalies reflect ancient crust that contained dense, meteorite‐like materials, which sank to the bottom of the mantle during Earth's early history. Using isotopes of another element, molybdenum, we show that the source(s) of these tungsten isotope anomalies do not contain a significant number of materials that originated from the outer Solar System before being added to Earth during its formation.
    Description: Key Points: 〈sup〉182〈/sup〉W deficits in ocean island basalts are confirmed, but correlated 〈sup〉182〈/sup〉W–〈sup〉183〈/sup〉W anomalies present in prior datasets are not confirmed. 〈sup〉182〈/sup〉W deficits may reflect core‐mantle interaction or an overabundance of late‐accreted materials, but not nucleosynthetic effects. Mo isotope data similar to BSE estimate; W‐Mo data rule out significant contribution of CC‐like material to Earth's core or late accretion.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: https://doi.org/10.35003/YCUKOX
    Keywords: ddc:551.9 ; core‐mantle interaction ; late accretion ; tungsten isotopes ; molybdenum isotopes ; ocean island basalts ; nucleosynthetic effects
    Language: English
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  • 163
    Publication Date: 2023-11-13
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉Owing to the complicated spatial–temporal characteristics of East Asian precipitation (EAP), climate models have limited skills in simulating the modern Asian climate. This consequently leads to large uncertainties in simulations of the past EAP variation and future projections. Here, we explore the performance of the newly developed Alfred Wegener Institute Climate Model, version 3 (AWI‐CM3) in simulating the climatological summer EAP. To test whether the model's skill depends on its atmosphere resolution, we design two AWI‐CM3 simulations with different horizontal resolutions. The result shows that both simulations have acceptable performance in simulating the summer mean EAP, generally better than the majority of individual models participating in the Coupled Model Intercomparison Project (CMIP6). However, for the monthly EAP from June to August, AWI‐CM3 exhibits a decayed skill, which is due to the subseasonal movement of the western Pacific subtropical high bias. The higher‐resolution AWI‐CM3 simulation shows an overall improvement relative to the one performed at a relatively lower resolution in all aspects taken into account regarding the EAP. We conclude that AWI‐CM3 is a suitable tool for exploring the EAP for the observational period. Having verified the model's skill for modern climate, we suggest employing the AWI‐CM3, especially with high atmosphere resolution, both for applications in paleoclimate studies and future projections.〈/p〉
    Description: 〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉This figure shows the skill scores of AWI‐CM3 and CMIP6 models in simulating the climatological summer East Asian precipitation (EAP), which indicates that AWI‐CM3 simulations perform better than most CMIP6 individual models for the summer mean EAP, while AWI‐CM3's skills decay from June to August.〈boxed-text position="anchor" content-type="graphic" id="joc8075-blkfxd-0001" xml:lang="en"〉 〈graphic position="anchor" id="jats-graphic-1" xlink:href="urn:x-wiley:08998418:media:joc8075:joc8075-toc-0001"〉 〈alt-text〉image〈/alt-text〉 〈/graphic〉 〈/boxed-text〉〈/p〉
    Description: National Natural Science Foundation of China http://dx.doi.org/10.13039/501100001809
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: Helmholtz Climate Initiative REKLIM
    Description: Helmholtz Program
    Description: Bundesministerium für Bildung und Forschung http://dx.doi.org/10.13039/501100002347
    Description: China Scholarship Council http://dx.doi.org/10.13039/501100004543
    Description: https://opendata.dwd.de/climate_environment/GPCC/html/fulldata-monthly_v2022_doi_download.html
    Description: https://crudata.uea.ac.uk/cru/data/hrg/cru_ts_4.05
    Description: http://aphrodite.st.hirosaki-u.ac.jp/products.html
    Description: https://jra.kishou.go.jp/JRA-55/index_en.html
    Description: https://esgf-node.llnl.gov/search/cmip6
    Keywords: ddc:551.6 ; AWI‐CM3 ; CMIP6 ; East Asia ; summer precipitation
    Language: English
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  • 164
    Publication Date: 2023-11-13
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉The decomposition of allochthonous organic matter, such as leaves, is a crucial ecosystem process in low‐order streams. Microbial communities, including fungi and bacteria, colonize allochthonous organic material, break up large molecules, and increase the nutritional value for macroinvertebrates. Environmental variables are known to affect microbial as well as macroinvertebrate communities and alter their ability to decompose organic matter. Studying the relationship between environmental variables and decomposition has mainly been realized using leaves, with the drawbacks of differing substrate composition and consequently between‐study variability. To overcome these drawbacks, artificial substrates have been developed, serving as standardizable surrogates. In the present study, we compared microbial and total decomposition of leaves with the standardized substrates of decotabs and, only for microbial decomposition, of cotton strips, across 70 stream sites in a Germany‐wide study. Furthermore, we identified the most influential environmental variables for the decomposition of each substrate from a range of 26 variables, including pesticide toxicity, concentrations of nutrients, and trace elements, using stability selection. The microbial as well as total decomposition of the standardized substrates (i.e., cotton strips and decotabs) were weak or not associated with that of the natural substrate (i.e., leaves, 〈italic〉r〈/italic〉² 〈 0.01 to 〈italic〉r〈/italic〉² = 0.04). The decomposition of the two standardized substrates, however, showed a moderate association (〈italic〉r〈/italic〉² = 0.21), which is probably driven by their similar composition, with both being made of cellulose. Different environmental variables were identified as the most influential for each of the substrates and the directions of these relationships contrasted between the substrates. Our results imply that these standardized substrates are unsuitable surrogates when investigating the decomposition of allochthonous organic matter in streams. 〈italic〉Environ Toxicol Chem〈/italic〉 2023;42:2007–2018. © 2023 The Authors. 〈italic〉Environmental Toxicology and Chemistry〈/italic〉 published by Wiley Periodicals LLC on behalf of SETAC.〈/p〉
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: Umweltbundesamt http://dx.doi.org/10.13039/501100010809
    Description: https://doi.org/10.1594/PANGAEA.931673
    Keywords: ddc:577.2 ; Leaf decomposition ; Decotabs ; Cotton strips ; Agriculture ; Fungicides ; Insecticides ; Stressors
    Language: English
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  • 165
    Publication Date: 2023-11-15
    Description: Droughts can lead to extreme low flow situations in rivers, with resulting severe impacts. Upstream snow and ice melt in many of the world's mountain water towers can alleviate the hydrological consequences of drought, yet global warming threatens the cryosphere. To improve the understanding of melt water contributions during drought in the case of future glacier retreat, we developed stress‐test storyline scenarios to model streamflow and tested them in the European river Rhine basin. Meteorological conditions of past drought and low flow years in Europe, 1976, 2003, and 2018, were repeated at three future moments in time, representing nowadays, near future and far future conditions. The latter two conditions were obtained by climate projections under the RCP8.5 scenario. Results show that the low flow situations caused by the meteorological drought situations aggravate in future conditions, more so for the far future and for the year 2003 because of the relatively large glacier ice melt contribution in the past. Summer (July–September) streamflow may decline by 5%–25% far downstream and 30%–70% upstream and the duration of extreme low flow situations may double compared to the selected past drought events. These results are relevant for the Rhine as a major European river but stand exemplary for many other river basins and highlight the importance of cryospheric changes for downstream low flow situations in a changing climate. The stress‐test scenarios allow a glimpse into future extreme low flow events aiding adaptation planning, and might be adapted to include other important low flow drivers.
    Description: Plain Language Summary: Extended periods with strongly reduced rainfall, in combination with hot summers, lead to accumulating water shortages. As a result, water levels in rivers drop which causes problems, e.g., for shipping, cooling of power plants and drinking and irrigation water supply. During such drought periods, melt water from snow and ice is important for water supply. However, glaciers are projected to further decline in a warming climate, possibly worsen future low flow situations. To quantify this effect, we modeled the amount of water flowing through the Rhine basin (a) for past low flow events in 1976, 2003, and 2018 and (b) for hypothetical situations where we repeat the weather data of those past low flow years at three moments in the future. The results show that flows upstream and downstream in the river Rhine would get even lower in future conditions and cause low flow situations to lengthen considerably. Especially for the year 2003, which had high ice melt contributions in the past, changes are large. In summer, the flow during already critical low flow situations may decrease by up to 70% upstream, and by up to 30% downstream. The results show a glimpse into future low flow events and may help adaptation planning.
    Description: Key Points: A model framework for the Rhine basin was developed to simulate streamflow during extreme past drought years in future conditions. Extreme low flows as in 1976, 2003, and 2018 would aggravate in a future with declined glacier cover and snow pack. Repeating the drought and heatwave of 2003 in the future results in largest reductions in summer streamflow (70% upstream, 30% downstream).
    Description: CHR, International Commission for the Hydrology of the Rhine Basin
    Description: STAY! Scholarship New University Endowment Freiburg
    Description: https://doi.org/10.1002/joc.773
    Description: https://www.geo.uzh.ch/en/units/h2k/Services/HBV-Model/HBV-Download.html
    Description: https://doi.org/10.6094/UNIFR/233644
    Description: https://doi.org/10.6094/UNIFR/226494
    Description: https://doi.org/10.6094/UNIFR/226492
    Description: https://doi.org/10.6094/UNIFR/233639
    Description: https://doi.org/10.1657/1938-4246-46.4.933
    Description: https://doi.org/10.1080/00291957708545328
    Description: https://doi.org/10.3189/172756411799096295
    Keywords: ddc:551.48 ; drought and low flows ; glacier ; upstream‐downstream ; glacio‐hydrological modeling ; Rhine ; stress‐test storylines
    Language: English
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  • 166
    Publication Date: 2023-11-15
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉Chemical processing of reactive nitrogen species, especially of NO〈sub〉〈italic〉x〈/italic〉〈/sub〉 (= NO + NO〈sub〉2〈/sub〉) and nitrous acid (HONO), determines the photochemical ozone production and oxidation capacity in the troposphere. However, sources of HONO and NO〈sub〉〈italic〉x〈/italic〉〈/sub〉 in the remote marine atmosphere are still poorly understood. In this work, the multiphase chemistry mechanism CAPRAM in the model framework SPACCIM was used to study HONO formation at Cape Verde (CVAO) in October 2017, adopted with the input of current parameterizations for various HONO sources. Three simulations were performed that adequately reproduced ambient HONO levels and its diurnal pattern. The model performance for NO〈sub〉〈italic〉x〈/italic〉〈/sub〉 and O〈sub〉3〈/sub〉 improves significantly when considering dust‐surface‐photocatalytic conversions of reactive nitrogen compounds with high correlation coefficients up to 0.93, 0.56, and 0.89 for NO, NO〈sub〉2〈/sub〉, and O〈sub〉3〈/sub〉, respectively. Photocatalytic conversion of the adsorbed HNO〈sub〉3〈/sub〉 on dust is modeled to be the predominant contributor for daytime HONO at CVAO, that is, accounting for about 62% of the chemical formation rate at noontime. In contrast, the ocean‐surface‐mediated conversion of NO〈sub〉2〈/sub〉 to HONO and other discussed pathways are less important. The average OH levels at midday (9:00–16:00) modeled for cluster trajectory 1, 2, and 3 are 5.2, 5.1, and 5.2 × 10〈sup〉6〈/sup〉 molecules cm〈sup〉−3〈/sup〉, respectively. Main OH formation is driven by O〈sub〉3〈/sub〉 photolysis with a contribution of 74.6% to the total source rate, while HONO photolysis is negligible (∼1.8%). In summary, this study highlights the key role of dust aerosols for HONO formation and NO〈sub〉〈italic〉x〈/italic〉〈/sub〉 cycling at CVAO and possibly in other dust‐affected regions, urgently calling for further investigations using field and model studies.〈/p〉
    Description: Plain Language Summary: Chemical processing of NO〈sub〉〈italic〉x〈/italic〉〈/sub〉 (= NO + NO〈sub〉2〈/sub〉) and nitrous acid (HONO) is important for the tropospheric O〈sub〉3〈/sub〉 budget and oxidation capacity. However, the sources of HONO and cycling of NO〈sub〉〈italic〉x〈/italic〉〈/sub〉 in the remote marine atmosphere are still poorly explored. A detailed multiphase chemistry model simulation showed a better performance of HONO, NO〈sub〉〈italic〉x〈/italic〉〈/sub〉 and O〈sub〉3〈/sub〉 when considering dust‐surface‐photocatalytic conversions of reactive nitrogen compounds, especially the photocatalytic conversion of the adsorbed HNO〈sub〉3〈/sub〉 on dust. The simulations demonstrated that OH formation is mainly driven by the O〈sub〉3〈/sub〉 photolysis, while HONO photolysis is a negligible OH radical source due to its low concentration levels at Cape Verde. The study highlights the key role of dust aerosols for HONO and NO〈sub〉〈italic〉x〈/italic〉〈/sub〉 chemistry in the remote marine boundary layer.〈/p〉
    Description: Key Points: 〈list list-type="bullet"〉 〈list-item〉 〈p xml:lang="en"〉The sources of HONO and NO〈sub〉〈italic〉x〈/italic〉〈/sub〉 at Cape Verde are well modeled with CAPRAM〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉Photocatalytic conversion of adsorbed HNO〈sub〉3〈/sub〉 on dust is the predominant contributor for daytime HONO〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉Photolysis of O〈sub〉3〈/sub〉 is the prevailing source of OH radical at Cape Verde, while HONO photolysis is a negligible OH radical source〈/p〉〈/list-item〉 〈/list〉 〈/p〉
    Description: Leibniz Association SAW
    Description: Horizon 2020 Framework Programme http://dx.doi.org/10.13039/100010661
    Description: National Key Research and Development Program of China http://dx.doi.org/10.13039/501100012166
    Description: National Natural Science Foundation of China http://dx.doi.org/10.13039/501100001809
    Description: https://doi.org/10.5281/zenodo.8070265
    Description: http://mcm.york.ac.uk/
    Description: https://capram.tropos.de/
    Description: https://ebas.nilu.no/
    Description: https://www.ready.noaa.gov/HYSPLIT_traj.php
    Keywords: ddc:551 ; HONO ; NOx ; CAPRAM ; heterogenous chemistry ; mineral dust ; OH radical ; marine boundary layer
    Language: English
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  • 167
    Publication Date: 2023-11-16
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉The Baltic Basin is known for its numerous Paleozoic hydrocarbon reservoirs. There is published evidence that hydrocarbons are leaking from the seafloor, however, little is known about the hydrocarbon migration pathways from Paleozoic source and reservoir rocks toward the seafloor and their escape structures. To investigate these processes, we utilize a new set of multibeam, parametric sediment sub‐bottom profiler and 2D seismic reflection data. The integrated analysis of seismic profiles, diffraction imaging and bathymetric maps allow to identify a hydrocarbon migration system within Silurian and Devonian strata that consists of layer parallel and updip migration beneath sealing layers, migration across seals along faults, and seafloor escape structures in form of elongated depressions. The general migration trend is directed updip, from the Paleozoic reservoirs below the southeastern Baltic Sea toward the Gotland Depression in the northwest. The locations of the hydrocarbon escape structures at the seafloor and their elongated shape are mainly controlled by the regional geological setting of outcropping Paleozoic layers. In addition, iceberg scouring may have facilitated hydrocarbon migration through the Quaternary deposits. The description of this hydrocarbon migration system fills the gap between the known reservoirs and the observed hydrocarbon accumulations and seepages. With regard to potential Carbon Capture and Storage projects, the identification of this hydrocarbon migration system is of great importance, as potential storage sites may be leaking.〈/p〉
    Description: Plain Language Summary: The Baltic Basin including the Baltic Sea is well known for its hydrocarbon reservoirs with ongoing oil production since the 1940s. While there is some published evidence that hydrocarbons are leaking from the seafloor, little is known about the pathways from the reservoirs toward theses leakages. In this study, we use three imaging techniques for the seafloor, the uppermost sediments and the first few kilometers of the subsurface to image the hydrocarbon migration pathways and their escape structures. We find that hydrocarbons are migrating along dipped geological layers from the reservoirs in the southeast toward the Gotland Deep in the northwest. Additionally, we also observe that hydrocarbons are penetrating through these geological layers at locations of pre‐existing small‐scale fractures. The locations, at which the hydrocarbons escape from the seafloor, are mainly controlled by the regional tectonic setting. In addition, iceberg scouring may have had an influence on the exact escape locations. With our findings in this study, we fill the gap between the known reservoirs and the observed seepages and can contribute to questions regarding the potential storage of CO〈sub〉2〈/sub〉 in the Baltic Basin.〈/p〉
    Description: Key Points: 〈list list-type="bullet"〉 〈list-item〉 〈p xml:lang="en"〉Numerous elongated fluid escape depressions are observed at the eastern margin of the Gotland Deep, central Baltic Sea〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉First evidence for fluid migration pathways from Paleozoic toward Quaternary strata in the region〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉Locations of fluid escape is controlled by the regional tectonic setting〈/p〉〈/list-item〉 〈/list〉 〈/p〉
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: https://doi.org/10.1594/PANGAEA.957436
    Description: https://doi.org/10.1594/PANGAEA.956740
    Description: https://doi.org/10.1594/PANGAEA.957422
    Keywords: ddc:622.1 ; seismic interpretation ; diffraction imaging ; Baltic Sea ; fluid migration pathways ; pockmarks ; carbon capture and storage
    Language: English
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  • 168
    Publication Date: 2023-11-16
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉Recent decades have witnessed a sharp biodiversity decline in freshwaters due to multiple stressors. The presence of multiple stressors is expected to affect community structure and interactions in freshwater ecosystems, with subsequent functional consequences. We synthesized the state of experimental, manipulative multiple‐stressor studies that focused on multispecies assemblages in freshwaters. Compared to rivers and lakes, wetland and groundwater ecosystems have received much less attention in identified multiple‐stressor research. Most of the identified studies investigated combinations of abiotic stressors (e.g., nutrients, pesticides, heavy metals, warming, altered flow and sedimentation) on microbes and invertebrates while biotic stressors and vertebrates have been largely overlooked. The responses of community structure (e.g., alpha diversity, biomass, and abundance), some community/ecosystem functions (e.g., photosynthesis and autotrophic activity, leaf litter degradation), and morphological traits like body size and growth forms were frequently investigated. We observed a clear gap in biotic interactions under multiple‐stressor conditions, which, although difficult to study, could impede a deeper mechanistic understanding of how multiple stressors affect freshwater assemblages and associated ecological processes. Although information on ecosystem recovery pathways following restoration is critical for freshwater management, few studies were designed to provide such information, signifying the disconnections between multiple‐stressor research and environmental practice. To bridge these gaps, researchers and environmental practitioners need to work together to identify key stressors and interactions at different spatial and temporal scales and prioritize stressor management. Such collaborations will enhance the translation of multiple‐stressor research into efficient management strategies to protect and restore freshwater ecosystems.〈/p〉
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: Deutscher Akademischer Austauschdienst http://dx.doi.org/10.13039/501100001655
    Description: Leibniz‐Gemeinschaft
    Description: German Federal Ministry of Education and Research (BMBF)
    Keywords: ddc:333.95 ; biodiversity ; freshwater ; management ; multiple stressors ; systematic literature review
    Language: English
    Type: doc-type:article
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  • 169
    Publication Date: 2023-11-16
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉Floods cause average annual losses of more than US$30 billion in the US and are estimated to significantly increase due to global change. Flood resilience, which currently differs strongly between socio‐economic groups, needs to be substantially improved by proactive adaptive measures, such as timely purchase of flood insurance. Yet, knowledge about the state and uptake of private adaptation and its drivers is so far scarce and fragmented. Based on interpretable machine learning and large insurance and socio‐economic open data sets covering the whole continental US we reveal that flood insurance purchase is characterized by reactive behavior after severe flood events. However, we observe that the Community Rating System helps overcome this behavior by effectively fostering proactive insurance purchase, irrespective of socio‐economic backgrounds in the communities. Thus, we recommend developing additional targeted measures to help overcome existing inequalities, for example, by providing special incentives to the most vulnerable and exposed communities.〈/p〉
    Description: Plain Language Summary: Flood resilience of individuals and communities can be improved by bottom‐up strategies, such as insurance purchase, or top‐down measures like the US National Flood Insurance Program's Community Rating System (CRS). Our interpretable machine learning approach shows that flood insurances are mostly purchased reactively, after the occurrence of a flood event. Yet, reactive behaviors are ill‐suited as more extreme events are expected under future climate, also in areas that were not previously flooded. The CRS counteracts this behavior by fostering proactive adaptation across a widespread range of socio‐economic backgrounds. Future risk management including the CRS should support and motivate individuals' proactive adaptation with a particular focus on highly vulnerable social groups to overcome existing inequalities in flood risk.〈/p〉
    Description: Key Points: 〈list list-type="bullet"〉 〈list-item〉 〈p xml:lang="en"〉Flood insurance purchase in the US is dominated by reactive behavior after severe floods〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉The Community Rating System (CRS) fosters proactive insurance adoption irrespective of socio‐economic background〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉The CRS should further balance existing inequalities by targeting specific population segments〈/p〉〈/list-item〉 〈/list〉 〈/p〉
    Description: https://api.census.gov/data/2018/acs/
    Description: https://www.fema.gov/about/openfema/data-sets#nfip
    Description: https://www.fema.gov/fact-sheet/community-rating-system-overview-and-participation
    Description: https://msc.fema.gov/portal/home
    Description: https://www.fema.gov/case-study/information-about-community-rating-system
    Description: https://doi.org/10.5281/zenodo.8067448
    Keywords: ddc:363.34 ; FEMA ; machine learning ; flood insurance ; human behavior ; flood resilience
    Language: English
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  • 170
    Publication Date: 2023-11-02
    Description: The impact of cloud condensation nuclei (CCN) concentration on microphysical processes within thunderstorms and the resulting surface precipitation is not fully understood yet. In this work, an analysis of the microphysical pathways occurring in these clouds is proposed to systematically investigate and understand these sensitivities. Thunderstorms were simulated using convection‐permitting (1 km horizontal grid spacing) idealized simulations with the ICON model, which included a 2‐moment microphysics parameterization. Cloud condensation nuclei concentrations were increased from 100 to 3,200 CCN/cm3, in five different wind shear environments ranging from 18 to 50 m/s. Large and systematic decreases of surface precipitation (up to 35%) and hail (up to 90%) were found as CCN was increased. Wind shear changes the details, but not the sign, of the sensitivity to CCN. The microphysical process rates were tracked throughout each simulation, closing the mass budget for each hydrometeor class, and collected together into “microphysical pathways,” which quantify the different growth processes leading to surface precipitation. Almost all surface precipitation occurred through the mixed‐phase pathway, where graupel and hail grow by riming and later melt as they fall to the surface. The mixed‐phase pathway is sensitive to CCN concentration changes as a result of changes to the riming rate, which were systematically evaluated. Supercooled water content was almost insensitive to increasing CCN concentration, but decreased cloud drop size led to a large reduction in the riming efficiency (from 0.79 to 0.24) between supercooled cloud drops and graupel or hail, resulting in less surface precipitation.
    Description: Plain Language Summary: The amount of rain and hail from thunderstorms can be influenced by the amount of pollution in the form of aerosol particles, which determine how many cloud droplets form and how large they are. Unfortunately, different numerical models give different answers on whether rain and hail increase or decrease if pollution increases. In this article, we present a new analysis method helping to identify the small‐scale processes which are responsible for the increase or decrease in a specific numerical scheme. We apply it to simulations of thunderstorms and show that the decrease of rain and hail in the numerical model used here is mostly linked to the riming process. Riming is the collision of cloud droplets and frozen particles at temperatures below 0°C, such that the liquid water freezes to the surface of the ice particles and makes them bigger. Less riming occurs when pollution increases, because cloud droplets are smaller. This process is very important because nearly all rain reaching the surface consists of melted ice particles.
    Description: Key Points: Microphysical pathways are constructed by tracking microphysical processes rates and closing the hydrometeor mass budget. More cloud condensation nuclei lead to less surface precipitation and hail, due to smaller cloud drop sizes and reduced riming collection efficiency. Simulations with constant riming collection efficiency reveal two different hail formation pathways.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: HORIZON EUROPE European Research Council http://dx.doi.org/10.13039/100019180
    Description: https://doi.org/10.5445/IR/1000156063
    Keywords: ddc:551.5 ; convective clouds ; hail ; riming ; precipitation ; CCN ; convection‐permitting simulation
    Language: English
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  • 171
    Publication Date: 2023-11-02
    Description: Abstract Phase relations in the MgSiO〈sub〉3〈/sub〉–MgAl〈sub〉2〈/sub〉O〈sub〉4〈/sub〉–Al〈sub〉2〈/sub〉O〈sub〉3〈/sub〉 system are investigated at 27 GPa and 2000–2600 K using a multi‐anvil apparatus. The AlAlO〈sub〉3〈/sub〉 content in the bridgmanite increases from 8.6 to 20.0 mol% with increasing temperature from 2000 to 2600 K, while the MgAlO〈sub〉2.5〈/sub〉 content remains nearly constant, that is, 3–4 mol% at these temperatures. Therefore, the presence of an additional Al‐bearing phase suppresses the oxygen vacancy substitution for Al〈sup〉3+〈/sup〉 in bridgmanite. Conversely, significant amounts of the Al〈sub〉8/3〈/sub〉O〈sub〉4〈/sub〉 component can be dissolved into the calcium‐ferrite type MgAl〈sub〉2〈/sub〉O〈sub〉4〈/sub〉–Mg〈sub〉2〈/sub〉SiO〈sub〉4〈/sub〉–Al〈sub〉8/3〈/sub〉O〈sub〉4〈/sub〉 phase (CF‐phase), implying that the CF‐phase likely contains some amount of vacancies. Therefore, the CF‐phase could also be a candidate mineral for transporting volatiles into the lower mantle. Our results, combined with previous studies on Al‐bearing bridgmanite, indicate that, once the Al per formula unit exceeds 0.12 in bridgmanite, the MgAlO〈sub〉2.5〈/sub〉 content remains nearly constant and the AlAlO〈sub〉3〈/sub〉 component becomes dominant.
    Description: Plain Language Summary: Bridgmanite, the most abundant mineral in the Earth's mantle, can contain Al〈sup〉3+〈/sup〉 in the forms of MgAlO〈sub〉2.5〈/sub〉 and AlAlO〈sub〉3〈/sub〉. To constrain the substitution mechanism of Al〈sup〉3+〈/sup〉 in bridgmanite, we investigate the MgAlO〈sub〉2.5〈/sub〉 and AlAlO〈sub〉3〈/sub〉 contents in bridgmanite coexisting with a calcium‐ferrite type phase and corundum at different temperatures. Our results demonstrate that the MgAlO〈sub〉2.5〈/sub〉 content reaches saturation (3–4 mol%) when an additional Al‐bearing phase exists in the system.
    Description: Key Points: The MgAlO〈sub〉2.5〈/sub〉 content in bridgmanite remains constant with temperature when bridgmanite coexists with corundum and the CF‐phase. The MgAlO〈sub〉2.5〈/sub〉 content in bridgmanite reaches a solubility of 3–4 mol% when bridgmanite coexists with an additional Al‐bearing phase. A significant amount of the Al〈sub〉8/3〈/sub〉O〈sub〉4〈/sub〉 component can be dissolved into the CF‐phase.
    Description: HORIZON EUROPE European Research Council http://dx.doi.org/10.13039/100019180
    Description: Japan Society for the Promotion of Science London http://dx.doi.org/10.13039/501100000646
    Description: cooperative research program of the Earthquake Research Institute
    Description: https://doi.org/10.5281/zenodo.7512647
    Keywords: ddc:549 ; Al‐bearing bridgmanite ; Al substitute mechanism ; phase relation ; volatile
    Language: English
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  • 172
    Publication Date: 2023-11-02
    Description: Extra‐tropical cyclones are an important source of weather variability in the mid‐latitudes. Multiple occurrences in a short period of time at a particular location are denominated serial cyclone clustering (SCC), and potentially lead to large societal impacts. We investigate the relationship between SCC affecting Western Europe and large‐scale weather regimes (WRs) in the North Atlantic‐European region in boreal winter. We find that SCC in low latitudes (45°N) is predominantly associated with the anticyclonic Greenland Blocking WR. In contrast, SCC in mid and high latitudes (55°N, 65°N) is mostly linked to different cyclonic WRs. Thereby, SCC occurs typically within a well‐established WR that builds up prior to SCC and decays after SCC. Thus, SCC events are closely associated with recurrent, quasi‐stationary and persistent large‐scale flow patterns (WRs). This mutual relationship reveals the potential of WRs in forecasting storm series and associated impacts on sub‐seasonal to seasonal time scales.
    Description: Plain Language Summary: Serial cyclone clustering describes the occurrence of multiple extra‐tropical cyclones within a certain time frame and a spatially restricted region. Since extra‐tropical cyclones can be associated with strong winds and heavy precipitation, multiple occurrences can lead to large cumulative impacts in the affected areas. We analyze the relationship between serial cyclone clustering (SCC) in Western Europe and so‐called weather regimes (WRs) in the North Atlantic‐European region in boreal winter. These regimes describe slow evolving and enduring large‐scale atmospheric circulation patterns. Relationships with certain regime types are identified but depend on the latitude at which the clustered frequency of extra‐tropical cyclones is found. When SCC occurs in low latitudes (45°N), it mostly appears coincident with anticyclonic large‐scale flow patterns. In contrast, SCC in mid and high latitudes (55°N, 65°N) often occurs simultaneously with different cyclonic regimes. We find that periods of SCC occur typically within WR life cycles pointing to the fact that both, the WRs and SCC periods, are interlinked. This relationship may facilitate forecasting storm series and associated impacts on time scales beyond 2 weeks.
    Description: Key Points: A close relationship is found between serial cyclone clustering (SCC) at 5°W and weather regimes (WRs) in the North Atlantic‐European region. SCC in mid and high latitudes (55°N, 65°N) is mainly associated with cyclonic and in low latitudes (45°N) with anticyclonic WR life cycles. Regardless of the selected latitude, SCC occurs mostly during an active regime life cycle and is manifested in a well‐established WR.
    Description: German Research Foundation
    Description: AXA Research Fund http://dx.doi.org/10.13039/501100001961
    Description: Helmholtz Association http://dx.doi.org/10.13039/501100009318
    Description: BMBF ClimXtreme
    Description: https://www.ecmwf.int/en/forecasts/datasets/reanalysis-datasets/era-interim
    Keywords: ddc:551.5 ; serial cyclone clustering ; weather regimes ; atmospheric dynamics ; sub‐seasonal prediction
    Language: English
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  • 173
    Publication Date: 2023-11-02
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉Rice is a staple crop in the Vietnam Mekong Delta (VMD) in which more than half of Vietnam's rice is produced. However, rice production in the VMD is threatened by increasing saltwater intrusion due to land subsidence and climate change induced sea level rise. Saltwater intrusion into lowland areas through the canal system or capillary rise of saline water from near surface saline water tables may result in salt accumulation in the topsoil. Therefore, it is important to disentangle the two effects and their relative importance to implement appropriate strategies for water and salinity management for adapting rice production systems of the VMD to climate change. Here, we report on the possibility of using geoelectrical methods to evaluate the potential threat of subsoil salinity to rice production. To evaluate the level of subsoil salinity, we measured soil electrical resistivity using an ARES II to a depth of 40 m in a case study comprising five locations in the VMD. Electrical resistivity measurements were calibrated to soil types, which were identified through evaluating 1 m core sections obtained by drilling down to 40 m depth. The relationship between drilling data and soil resistivity was determined by applying clustering and principal component analysis. Resistivity values smaller than 3 Ω m were clearly identified as indicative for a saline water table. The results show a direct link between the depth of the saline water table and the proximity to the sea, but not to the rice production system (single, double, or triple cropping). This study proved for the first time the applicability of the electrical resistivity tomography method for identifying groundwater tables and evaluating subsoil salinity on an agricultural field scale in the VMD.〈/p〉
    Description: Bundesministerium für Bildung und Forschung http://dx.doi.org/10.13039/501100002347
    Description: Federal Ministry of Education and Research (BMBF, Germany)
    Keywords: ddc:631.4 ; conductivity ; electrical resistivity tomography ; groundwater ; site effect
    Language: English
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  • 174
    Publication Date: 2023-11-02
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉Shock‐related calcite twins are characterized in calcite‐bearing metagranite cataclasites within crystalline megablocks of the Ries impact structure, Germany, as well as in cores from the FBN1973 research drilling. The calcite likely originates from pre‐impact veins within the Variscan metagranites and gneisses, while the cataclasis is due to the Miocene impact. Quartz in the metagranite components does not contain planar deformation features, indicating low shock pressures (〈7 GPa). Calcite, however, shows a high density (>1/μm) of twins with widths 〈100 nm. Different types of twins (〈italic toggle="no"〉e〈/italic〉‐, 〈italic toggle="no"〉f‐〈/italic〉, and 〈italic toggle="no"〉r〈/italic〉‐twins) crosscutting each other can occur in one grain. Interaction of 〈italic toggle="no"〉r〈/italic〉‐ and 〈italic toggle="no"〉f〈/italic〉‐twins results in 〈italic toggle="no"〉a〈/italic〉‐type domains characterized by a misorientation relative to the host with a misorientation angle of 35°–40° and a misorientation axis parallel to an 〈italic toggle="no"〉a〈/italic〉‐axis. Such 〈italic toggle="no"〉a〈/italic〉‐type domains have not been recorded from deformed rocks in nature before. The high twin density and activation of different twin systems in one grain require high differential stresses (on the order of 1 GPa). Twinning of calcite at high differential stresses is consistent with deformation during impact cratering at relatively low shock pressure conditions. The twinned calcite microstructure can serve as a valuable low shock barometer.〈/p〉
    Description: Bavarian Natural History Collections
    Keywords: ddc:549 ; Ries impact structure ; twinned calcites ; cataclasis
    Language: English
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  • 175
    Publication Date: 2023-11-14
    Description: The Ries impact is the most important cosmic event in the younger geological history of Europe. Its effects reach far beyond the area considered so far and are documented in manifold evidence. In this paper, the widely scattered reports in the literature are compiled and supported with investigations by the authors. Besides well‐known ejecta features like the Brockhorizont, Reuter's blocks, and moldavites, little known or forgotten indications, like a lechatelierite and β‐cristobalite occurrence in Bavaria and unusual sedimentation phenomena in northern Germany, are presented. The paleogeographic reconstruction shows that the Ries impact occurred on the southern side of the Neogene Central European mainland. Large parts of this erosional area were devastated by the impact. Pressure waves and thermal radiation had a lasting effect on the landscape within hundreds of kilometers around the impact site. Destruction of the vegetation cover by impact‐induced storms, wildfires, and heavy rainfall generated intense erosion. The adjacent sedimentation area to the north (Paleo‐North Sea) experienced an increased and short‐term supply of terrestrial debris to the marine environment. The stratigraphic coincidence of these exceptional sediments with the Ries event leads us to conclude that the distal effects of the impact are present here, which have so far received little or no attention in this context. The paper considers the different indications and sets them in a large‐scale context.
    Keywords: ddc:551.397 ; Ries impact ; distal effects ; sedimentation phenomena
    Language: English
    Type: doc-type:article
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  • 176
    Publication Date: 2023-11-14
    Description: Simulating magma propagation pathways requires both a well‐calibrated model for the stress state of the volcano and models for dike advance within such a stress field. Here, we establish a framework for calculating computationally efficient and flexible magma propagation scenarios in the presence of caldera structures. We first develop a three‐dimensional (3D) numerical model for the stress state at volcanoes with mild topography, including the stress induced by surface loads and unloading due to the formation of caldera depressions. Then, we introduce a new, simplified 3D model of dike propagation. Such a model captures the complexity of 3D magma trajectories with low running time, and can backtrack dikes from a vent to the magma storage region. We compare the new dike propagation model to a previously published 3D model. Finally, we employ the simplified model to produce shallow dike propagation scenarios for a set of synthetic caldera settings with increasingly complex topographies. The resulting synthetic magma pathways and eruptive vent locations broadly reproduce the variability observed in natural calderas.
    Description: Plain Language Summary: Understanding the pathways that bring magma from an underground chamber to the surface helps to prepare for future eruptions in volcanic areas. Dikes are fractures filled with magma and represent the most common mechanism of magma transport in the Earth's crust. Their trajectories may be curved if the Earth's crust is deformed by the load of topography or by tectonic forces. Here we first discuss a model of such deformation processes in volcanic regions with complex but mild topography. Then, we develop a simplified dike propagation model that we compare to a more sophisticated one. Next, we combine our models and simulate magma pathways in artificially‐generated scenarios.
    Description: Key Points: We present numerical models of crustal stress state in the presence of caldera structures. We develop a fast dike propagation model and validate it on a previous numerical model. We combine our stress and dike models to simulate magma pathways at synthetic calderas.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: http://persson.berkeley.edu/distmesh/
    Description: https://doi.org/10.5281/zenodo.3694164
    Description: https://doi.org/10.5281/zenodo.4726796
    Description: https://doi.org/10.5281/zenodo.4727208
    Description: https://doi.org/10.5880/GFZ.2.1.2023.001
    Keywords: ddc:550.278 ; dike propagation ; magma pathways ; stress modeling ; pre‐eruptive scenarios ; calderas
    Language: English
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  • 177
    Publication Date: 2023-11-14
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉Standard models of force balance along Jovian field lines predict the location of the Io Plasma Torus to be the centrifugal equator of Jupiter’s magnetosphere, that is, the position along the magnetic field lines farthest away from Jupiter’s rotational axis. In many models, the centrifugal equator is assumed to lay on a plane, calculated from a (shifted) dipole magnetic field, rather than on a warped surface which incorporates Jupiter’s higher magnetic field moments. In this work, we use Hubble Space Telescope observations of the Io Main Footprint to constrain density, scale height, and lateral position of the Io Plasma Torus. Therefore, we employ the leading angle of the footprints to calculate expected travel times of Alfvén waves and carry out an inversion of the observations. For the magnetic field, we use the JRM33 magnetic field model. The inversion results show peak densities between 〈italic〉ρ〈/italic〉〈sub〉0〈/sub〉 = 1,830 cm〈sup〉−3〈/sup〉 and 〈italic〉ρ〈/italic〉〈sub〉0〈/sub〉 = 2,032 cm〈sup〉−3〈/sup〉 and scale heights between 〈italic〉H〈/italic〉 = 0.92〈italic〉R〈/italic〉〈sub〉〈italic〉J〈/italic〉〈/sub〉 and 〈italic〉H〈/italic〉 = 0.97〈italic〉R〈/italic〉〈sub〉〈italic〉J〈/italic〉〈/sub〉 consistent with current literature values. Using a warped multipole centrifugal equator instead of a planar dipole increases the quality of the fit by about 25%. We additionally develop two tests to confirm that the multipole centrifugal equator from the JRM33 model fits explains the applied data set better than the dipole centrifugal equator. The quadropole moments alter Io’s relative position to the torus, which changes the plasma density around Io by up to Δ〈italic〉ρ〈/italic〉/〈italic〉ρ〈/italic〉 = 20%.〈/p〉
    Description: Key Points: 〈list list-type="bullet"〉 〈list-item〉 〈p xml:lang="en"〉Based on the Io Footprint positions, we show quantitatively that the Io Plasma Torus is centered on the centrifugal equator of Jupiter’s multipole magnetic field〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉Position of the Io Footprint can be used to constrain a density model of the Io Plasma Torus〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉The displacement of the Io Plasma Torus due to higher magnetic field moments can change the plasma density at Io by up to 20%〈/p〉〈/list-item〉 〈/list〉 〈/p〉
    Description: HORIZON EUROPE European Research Council
    Description: International Space Science Institute (ISSI) in Bern, through ISSI International Team project 515
    Description: https://doi.org/10.5281/zenodo.8214702
    Keywords: ddc:523 ; Io Plasma Torus ; inversion ; Io Footprint ; Alfven wings ; magnetic field model
    Language: English
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  • 178
    Publication Date: 2023-11-18
    Description: Spatiotemporal characterisation of the soil redox status within the capillary fringe (CF) is a challenging task. Air‐filled porosities (ε), oxygen concentration (O〈sub〉2〈/sub〉) and soil redox potential (EH) are interrelated soil variables within active biogeochemical domains such as the CF. We investigated the impact of water table (WT) rise and drainage in an undisturbed topsoil and subsoil sample taken from a Calcaric Gleysol for a period of 46 days. We merged 1D (EH and matric potential) and 2D (O〈sub〉2〈/sub〉) systems to monitor at high spatiotemporal resolution redox dynamics within self‐constructed redoxtron housings and complemented the data set by a 3D pore network characterization using X‐ray microtomography (X‐ray μCT). Depletion of O〈sub〉2〈/sub〉 was faster in the organic matter‐ and clay‐rich aggregated topsoil and the CF extended 〉10 cm above the artificial WT. The homogeneous and less‐aggregated subsoil extended only 4 cm above the WT as indicated by ε–O〈sub〉2〈/sub〉–EH data during saturation. After drainage, 2D O〈sub〉2〈/sub〉 imaging revealed a fast aeration towards the lower depths of the topsoil, which agrees with the connected ε derived by X‐ray μCT (ε〈sub〉CT_conn〈/sub〉) of 14.9% of the total porosity. However, small‐scaled anoxic domains with O〈sub〉2〈/sub〉 saturation 〈5% were apparent even after lowering the WT (down to 0.25 cm〈sup〉2〈/sup〉 in size) for 23 days. These domains remained a nucleus for reducing soil conditions (E〈sub〉H〈/sub〉 〈 −100 mV), which made it challenging to characterise the soil redox status in the CF. In contrast, the subsoil aeration reached O〈sub〉2〈/sub〉 saturation after 8 days for the complete soil volume. Values of ε〈sub〉CT_conn〈/sub〉 around zero in the subsoil highlighted that soil aeration was independent of this parameter suggesting that other variables such as microbial activity must be considered when predicting the soil redox status from ε alone. The use of redoxtrons in combination with localised redox‐measurements and image based pore space analysis resulted in a better 2D/3D characterisation of the pore system and related O〈sub〉2〈/sub〉 transport properties. This allowed us to analyse the distribution and activity of microbiological niches highly associated with the spatiotemporal variable redox dynamics in soil environments. Highlights: The time needed to turn from reducing to oxidising (period where all platinum electrodes feature E〈sub〉H〈/sub〉 〉 300 mV) condition differ for two samples with contrasting soil structure. The subsoil with presumably low O〈sub〉2〈/sub〉 consumption rates aerated considerably faster than the topsoil and exclusively by O〈sub〉2〈/sub〉 diffusion through medium‐ and fine‐sized pores. To derive the soil redox status based upon the triplet ε–O〈sub〉2〈/sub〉–E〈sub〉H〈/sub〉 is challenging at present in heterogeneous soil domains and larger soil volumes than 250 cm〈sup〉3〈/sup〉. Undisturbed soil sampling along with 2D/3D redox measurement systems (e.g., redoxtrons) improve our understanding of redox dynamics within the capillary fringe.
    Keywords: ddc:631.4 ; environmental monitoring ; incubation experiments ; redox processes ; soil reducing conditions ; undisturbed soil ; X‐ray microtomography
    Language: English
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  • 179
    Publication Date: 2023-11-18
    Description: Magnetic field reversals are irregular events in Earth's history when the geomagnetic field changes its polarity. Reversals are recorded by spot and continuous remanent magnetization data collected from lava flows and marine sediments, respectively. The latest field reversal, the Matuyama‐Brunhes reversal (MBR), is better covered by paleomagnetic data than prior field reversals, hence providing an opportunity to understand the physical mechanisms. Despite the quantity of data, a full understanding of the MBR is still lacking. The evolution of the MBR in time and space is explored in this work by compiling a global set of paleomagnetic data, both from sediments and volcanic rocks, which encompass the period 900–700 ka. After careful evaluation of data and dating quality, regional and global stacks of virtual axial dipole moment (VADM), virtual geomagnetic pole (VGP), and paleosecular variation index (Pi) are constructed from the sediment records using bootstrap resampling. Individual VADMs and VGPs calculated from lavas are compared to these stacks. Four phases of full‐vector field instability are observed in these stacks over the period 800–770 ka. The first three phases, observed at 800–785 ka, reflect a rapid weakening of the field coupled with low VGP latitude, after which the field returned to the reverse polarity of the Matuyama chron. The fourth phase, lasting from 780 to 770 ka, is when the field reversal process completed, such that the field entered the Brunhes normal polarity state. These findings point to a complex reversal process lasting ∼30 Kyr, with the reversal ending at ∼770 ka.
    Description: Plain Language Summary: The Earth's magnetic field, or geomagnetic field, which humans and some animals use for navigation, shields us from solar and cosmic radiation. The magnetic North and South poles have repeatedly, but infrequently changed their positions over Earth's history, a phenomenon known as magnetic field reversal. During a reversal, the magnetic field intensity decreased to low levels, which could have had a detrimental impact on our planet as the magnetic shielding is diminished. The magnetic field last switched polarity from the Matuyama reverse state to the current Brunhes normal polarity in the most recent field reversal. This work used regional and global stacks of paleomagnetic sediment records with reasonable age control, to investigate the Matuyama‐Brunhes reversal. From these stacks, we find that the last field reversal took ∼30 Kyr to evolve, beginning at about 800 ka and ending at around 770 ka. Our data compilation indicates that the reversal lasted longer in records from high latitudes than low‐ to mid latitudes records, which confirms a previous suggestion that local reversal duration is latitudinal dependent.
    Description: Key Points: Global characteristics of the Matuyama‐Brunhes field reversal were examined from well‐dated high‐quality lava and marine core data. The Matuyama‐Brunhes reversal started at 800 ka and the whole process lasted 30 ka. The new data compilation generally confirms longer regional reversal duration at high latitudes compared to low latitudes.
    Description: Alexander von Humboldt Foundation http://dx.doi.org/10.13039/501100010956
    Description: Discovery Fellowship, GFZ Potsdam, Germany.
    Description: https://earthref.org/ERDA/2545/
    Keywords: ddc:538.7 ; paleomagnetic sediment records ; Matuyama-Brunhes geomagnetic field reversal
    Language: English
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  • 180
    Publication Date: 2023-11-18
    Description: Phosphorus is a nonrenewable resource, which is required for crop growth and to maintain high yields. The soil P cycle is very complex, and new model approaches can lead to a better understanding of those processes and further guide to research gaps. The objective of this study was to present a P‐submodel, which has been integrated in the existing Carbon Candy Balance (CCB) model that already comprises a C and N module. The P‐module is linked to the C mineralization and the associated C‐pools via the C/P ratio of fresh organic material. Besides the organic P cycling, the module implies a plant‐available P‐pool (P〈sub〉av〈/sub〉), which is in a dynamic equilibrium with the nonavailable P‐pool (P〈sub〉na〈/sub〉) that comprises the strongly sorbed and occluded P fraction. The model performance was tested and evaluated on four long‐term field experiments with mineral P fertilization, farmyard manure as organic fertilizer and control plots without fertilization. The C dynamics and the P〈sub〉av〈/sub〉 dynamics were modelled with overall good results. The relative RMSE for the C was below 10% for all treatments, while the relative RMSE for P〈sub〉av〈/sub〉 was below 15% for most treatments. To accommodate for the rather small variety of available P‐models, the presented CNP‐model is designed for agricultural field sites with a relatively low data input, namely air temperature, precipitation, soil properties, yields and management practices. The CNP‐model offers a low entry threshold model approach to predict the C‐N and now the P dynamics of agricultural soils.
    Description: Fachagentur Nachwachsende Rohstoffe http://dx.doi.org/10.13039/501100010812
    Keywords: ddc:631.4 ; CNP‐model ; soil P dynamics ; soil process modelling ; total P and available P
    Language: English
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  • 181
    Publication Date: 2023-11-18
    Description: Cyclostratigraphy and astrochronology are now at the forefront of geologic timekeeping. While this technique heavily relies on the accuracy of astronomical calculations, solar system chaos limits how far back astronomical calculations can be performed with confidence. High‐resolution paleoclimate records with Milankovitch imprints now allow reversing the traditional cyclostratigraphic approach: Middle Eocene drift sediments from Newfoundland Ridge are well‐suited for this purpose, due to high sedimentation rates and distinct lithological cycles. Per contra, the stratigraphies of Integrated Ocean Drilling Program Sites U1408–U1410 are highly complex with several hiatuses. Here, we built a two‐site composite and constructed a conservative age‐depth model to provide a reliable chronology for this rhythmic, highly resolved (〈1 kyr) sedimentary archive. Astronomical components (g‐terms and precession constant) are extracted from proxy time‐series using two different techniques, producing consistent results. We find astronomical frequencies up to 4% lower than reported in astronomical solution La04. This solution, however, was smoothed over 20‐Myr intervals, and our results therefore provide constraints on g‐term variability on shorter, million‐year timescales. We also report first evidence that the g〈sub〉4〈/sub〉–g〈sub〉3〈/sub〉 “grand eccentricity cycle” may have had a 1.2‐Myr period around 41 Ma, contrary to its 2.4‐Myr periodicity today. Our median precession constant estimate (51.28 ± 0.56″/year) confirms earlier indicators of a relatively low rate of tidal dissipation in the Paleogene. Newfoundland Ridge drift sediments thus enable a reliable reconstruction of astronomical components at the limit of validity of current astronomical calculations, extracted from geologic data, providing a new target for the next generation of astronomical calculations.
    Description: Plain Language Summary: The traditional cyclostratigraphic approach is to align and correlate a geologic depth‐series with an astronomical solution. However, the chaotic nature of the Solar System prevents astronomers from precisely calculating planetary motions beyond 40–50 million years ago. This in turn limits the options for geologists to use the resulting oscillations in Earth's climate system as a metronome for determining geologic time. In this study, we reversed the cyclostratigraphic approach and used the highly rhythmical sedimentary deposits from Newfoundland Ridge (North Atlantic) to back‐calculate planetary motions at ∼41 million years ago. The superior quality of the Newfoundland Ridge geoarchive originates from the combination of relatively high sedimentation rates (∼4 cm/kyr) and the time‐continuous character of our two‐site composite record between 39.5 and 42.8 million years ago. In this work, we had to first overcome considerable challenges in reconstructing the timing of sediment deposition, which we did with highly resolved geochemical measurements from two sites. We then were able to extract information on the Earth's planetary motion and on the Earth‐Moon interactions. These astronomical reconstructions based on geological data can now be used by astronomers to describe the evolution of the solar system further back in time than was previously possible.
    Description: Key Points: A new precession‐based cyclostratigraphy for the middle Eocene intervals of IODP Sites U1408 and U1410. Variability in astronomical fundamental frequencies (g‐terms) on million‐year timescales is larger than previously assumed. Our precession constant estimate for 41 Ma (51.28 ± 0.56″/year) confirms earlier indicators of slower tidal dissipation in the Paleogene.
    Description: National Science Foundation http://dx.doi.org/10.13039/100000001
    Description: University of California http://dx.doi.org/10.13039/100005595
    Description: Belgian American Educational Foundation http://dx.doi.org/10.13039/100001491
    Description: https://paloz.marum.de/AstroComputation/index.html
    Description: https://paloz.marum.de/confluence/display/ESPUBLIC/NAFF
    Keywords: ddc:551 ; North Atlantic ; Eocene ; cyclostratigraphy ; astrochronology
    Language: English
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  • 182
    Publication Date: 2023-11-18
    Description: The eastern European Alps are shaped by the indentation of Adria into Europe. Recent tomography, depicting detached slab fragments, has been interpreted as evidence of continuous southward subduction of European lithosphere, contrary to an often‐invoked subduction polarity reversal. Orogen‐scale exhumation, driven by rock displacement along active faults, may reflect subduction polarity within the framework of doubly‐vergent Coulomb wedge theory, provided the absence of rheological contrasts across the colliding plates. Low‐temperature thermochronology can evaluate crustal cooling in response to changes in tectonic and erosional boundary conditions. This study investigates the consistency of observed crustal re‐organization, exhumation, and mantle processes in the Eastern Alps. Thermo‐kinematic forward models driven by reconstructions of crustal shortening along the TRANSALP geophysical transect were subjected to variations in shortening rates, thermophysical parameters, and topographic evolution, supplemented by new fission‐track data. The thermo‐kinematic models reproduce: (a) the orogen‐scale structural geometry, (b) the distribution of thermochronometer ages, (c) observed time‐temperature paths, and (f) the present‐day surface heat flux. Results suggest that exhumation is driven by rock displacement along active faults without the need to involve mantle‐driven buoyancy forces. Taken together, the results identify two possible scenarios: if the Tauern Ramp is a retro‐thrust and the southward shift of deformation in the Southern Alps is a response to new Coulomb‐wedge conditions, then our results support a Mid‐Miocene reversal of the subduction polarity. Alternatively, crustal deformation does not reflect mantle processes entailing a high degree of inter‐plate decoupling.
    Description: Plain Language Summary: The convergence between the African and Eurasian plates created the European Alps. This process led to the Eurasian plate underlaying the African plate. It has been argued that this tectonic geometry changed, that is, Adria underlies Europe at present. Here we investigate whether changes in erosion and cooling of the crust over geologic time along a north‐to‐south profile in the Eastern Alps during the collision reflects deep seated mantle processes given the absence of rheological contrasts across the involved tectonic plates. New models for the structural and thermal evolution of the crust along the profile reproduce present‐day structural and thermal observations. Model predictions are sensitive to heat production in the crust. Furthermore, these models indicate that cooling of the crust through erosion was primarily driven by the displacement of rocks toward the surface along active faults. Two possible tectonic scenarios are suggested: The pattern of fault activity during the collision is characteristic for an overlying European plate promoting that now the Adriatic plate lies under the European plate. If this is the case, this change in tectonic geometry likely occurred about 10–20 million years ago. Alternatively, crustal deformation does not reflect mantle processes because the interface between the two colliding plates is highly decoupled along the profile.
    Description: Key Points Exhumation in the eastern European Alps along TRANSALP is primarily driven by cooling through rock displacement along active faults The thermo‐kinematic reconstruction emphasizes contrasts in the deformation north and south along TRANSALP since the Mid‐Miocene In the absence of inter‐plate rheological contrasts deformation patterns favor a reversal in subduction polarity since the Mid‐Miocene
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: https://doi.org/10.5880/fidgeo.2022.017
    Description: https://doi.org/10.5281/zenodo.7785668
    Description: https://doi.org/10.1186/s40562-017-0098-z
    Description: https://doi.org/10.1016/j.epsl.2004.05.040
    Description: https://doi.org/10.1007/s00531-014-1060-3
    Keywords: ddc:551.8 ; European Alps ; TRANSALP ; thermochronology ; subduction polarity reversal ; tectonic reconstruction ; continental collision
    Language: English
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  • 183
    Publication Date: 2023-11-17
    Description: One important component of precipitating convection is the formation of convective downdrafts. They can terminate the initial updraft, affect the mean properties of the boundary layer, and cause strong winds at the surface. While the basic forcing mechanisms for downdrafts are well understood, it is difficult to formulate general relationships between updrafts, environmental conditions, and downdrafts. To better understand what controls different downdraft properties, we analyze downdrafts over tropical oceans in a global storm resolving simulation. Using a global model allows us to examine a large number of downdrafts under naturally varying environmental conditions. We analyze the various factors affecting downdrafts using three alternative methods. First, hierarchical clustering is used to examine the correlation between different downdraft, updraft, and environmental variables. Then, either random forests or multiple linear regression are used to estimate the relationships between downdraft properties and the updraft and environmental predictors. We find that these approaches yield similar results. Around 75% of the variability in downdraft mass flux and 37% of the variability in downdraft velocity are predictable. Analyzing the relative importance of our various predictors, we find that downdrafts are coupled to updrafts via the precipitation generation argument. In particular, updraft properties determine rain amount and rate, which then largely control the downdraft mass flux and, albeit to a lesser extent, the downdraft velocity. Among the environmental variables considered, only lapse rate is a valuable predictor: a more unstable environment favors a higher downdraft mass flux and a higher downdraft velocity.
    Description: Plain Language Summary: Once a cloud begins to rain, the air inside or below the cloud can gain negative buoyancy and sink to the ground. This downward movement of air is called a downdraft. Downdrafts can end the life cycle of a cloud and also result in strong, sometimes destructive, wind gusts at the surface. The basic driving forces for downdrafts are well understood. For example, we know that evaporation of rain and the associated latent cooling of air is usually critical in causing the air to become negatively buoyant. Even though the basic driving forces are known, many interrelated processes contribute simultaneously to the strength of the downdraft, making it difficult to predict the strength of a downdraft under specific conditions. In this study, we use an atmospheric simulation whose model domain spans the globe and can explicitly resolve rain clouds. Compared to previous studies, the use of a global domain allows us to study a very large number of rain clouds, and their associated downdrafts, which form under very different, naturally varying environmental conditions. Machine learning techniques and traditional statistical methods agree on the result that the strength of the downdraft can be well predicted if we know the strength of the updraft that caused the downdraft or, even better, if we know the amount of rain that an updraft produced. Surprisingly, we have found that downdrafts can be predicted only slightly better if we also know other environmental conditions of the air surrounding the downdraft, such as the temperature and/or humidity profiles.
    Description: Key Points: The best predictors of downdraft mass flux and velocity are rain amount and rate, respectively. Updraft properties impact downdraft properties through their control on rain formation. For a given rain amount and rate, environmental conditions add little skill to downdraft prediction.
    Description: Max Planck Institute for Meteorology
    Description: ARC Centre of Excellence for Climate Extremes
    Description: https://mpimet.mpg.de/en/science/modeling-with-icon/code-availability
    Description: http://hdl.handle.net/21.11116/0000-0009-A854-B
    Keywords: ddc:551.6 ; convective downdrafts ; global storm resolving simulation ; machine learning ; random forest ; multiple linear regression
    Language: English
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  • 184
    Publication Date: 2023-11-17
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈sec xmlns:mml="http://www.w3.org/1998/Math/MathML" id="ejss13362-sec-1003" xml:lang="en"〉 〈p xml:lang="en"〉Long‐term experiments (LTEs) have provided data to modellers and agronomists to investigate changes and dynamics of soil organic carbon (SOC) under different cropping systems. As treatment changes have occurred due to agricultural advancements, so too have analytical soil methods. This may lead to method bias over time, which could affect the robust interpretation of data and conclusions drawn. This study aims to quantify differences in SOC due to changes in dry combustion methods over time, using soil samples of a LTE established in 1963 that focuses on mineral and organic fertilizer management in the temperate zone of Northeast Germany. For this purpose, 1059 soil samples, collected between 1976 and 2008, have been analysed twice, once with their historical laboratory method right after sampling, and a second time in 2016 when all samples were analysed using the same elementary analyser. In 9 of 11 soil sampling campaigns, a paired 〈italic toggle="no"〉t〈/italic〉‐test provided evidence for significant differences in the historical SOC values when compared with the re‐analysed concentrations of the same LTE sample. In the sampling years 1988 and 2004, the historical analysis obtained about 0.9 g kg〈sup〉−1〈/sup〉 lower SOC compared with the re‐analysed one. For 1990 and 1998, this difference was about 0.4 g kg〈sup〉−1〈/sup〉. Correction factors, an approach often used to correct for different analytical techniques, could only be applied for 5 of 11 sampling campaigns to account for constant and proportional systematic method error. For this particular LTE, the interpretation of SOC changes due to agronomic management (here fertilization) deviates depending on the analytical method used, which may weaken the explanatory power of the historical data. We demonstrate that analytical method changes over time present one of many challenges in the interpretation of time series data of SOC dynamics. Therefore, LTE site managers need to ensure providing all necessary protocols and data in order to retrace method changes and if necessary recalculate SOC.〈/p〉 〈/sec〉〈sec xmlns:mml="http://www.w3.org/1998/Math/MathML" id="ejss13362-sec-0003" xml:lang="en"〉 〈title〉Highlights〈/title〉 〈p xml:lang="en"〉〈list list-type="bullet" id="ejss13362-list-0001"〉 〈list-item id="ejss13362-li-0001"〉〈p〉A total of 1059 LTE soil samples taken between 1976 and 2008 were re‐analysed for SOC in 2016〈/p〉〈/list-item〉 〈list-item id="ejss13362-li-0002"〉〈p〉Several methodological changes for SOC determination led to significant different SOC concentration in the same sample〈/p〉〈/list-item〉 〈list-item id="ejss13362-li-0003"〉〈p〉Interpretation and time series of LTE soil data suffer from consideration of analytical method changes and poor documentation of the same〈/p〉〈/list-item〉 〈list-item id="ejss13362-li-0004"〉〈p〉Soil archive establishment, thorough method protocols and diligent proficiency testing after soil method changes ameliorate the dilemma〈/p〉〈/list-item〉 〈/list〉〈/p〉 〈/sec〉
    Description: Brandenburger Staatsministerium für Wissenschaft, Forschung und Kultur http://dx.doi.org/10.13039/501100004581
    Description: Bundesministerium für Bildung und Forschung http://dx.doi.org/10.13039/501100004937
    Description: https://doi.org/10.4228/zalf-acge-b683
    Keywords: ddc:631.4 ; Bland–Altman ; carbon stocks ; data trueness ; Deming regression ; method bias ; soil archive ; soil survey
    Language: English
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  • 185
    Publication Date: 2023-11-17
    Description: 〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉Detrital single‐grain zircon U–Pb geochronology is a powerful tool for provenance studies if information on the source rocks is available. This paper proposes a new source‐rock classification tool that uses the degree of annealing of radiation damage in detrital zircon; the annealing is expressed by the relationship between the width (full‐width at half‐maximum; FWHM) of the 〈italic toggle="no"〉v〈/italic〉〈sub〉3〈/sub〉[SiO〈sub〉4〈/sub〉] Raman band at ~1008 cm〈sup〉−1〈/sup〉 and the calculated α‐dose. The host rocks of the zircons are classified into three types according to their emplacement process and/or thermal history: volcanic and rapidly cooled plutonic and high‐grade metamorphic rocks (type 1); rocks with hydrothermal zircons (type 2); slowly cooled igneous and metamorphic rocks (type 3). We construct a naive Bayes prediction model by training it with a collection of zircons of known types. The unknown zircons are assigned a probability of derivation from a specific host‐rock type. This classification scheme is best used as an accessory tool in provenance studies that apply detrital zircon U–Pb geochronology.〈/p〉
    Description: 〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉Zircons are classified into three types based on annealing state revealed by Raman analysis and calculated α‐dose. This classification can be used to distinguish zircon in provenance study.〈boxed-text position="anchor" content-type="graphic" id="gj4751-blkfxd-0001" xml:lang="en"〉 〈graphic position="anchor" id="jats-graphic-1" xlink:href="urn:x-wiley:00721050:media:gj4751:gj4751-toc-0001"〉 〈/graphic〉 〈/boxed-text〉〈/p〉
    Description: Natural Science Foundation of Hubei Province http://dx.doi.org/10.13039/501100003819
    Description: National Natural Science Foundation of China http://dx.doi.org/10.13039/501100001809
    Keywords: ddc:549 ; annealing ; Bayesian probability ; provenance analysis ; radiation damage ; zircon classification
    Language: English
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  • 186
    Publication Date: 2023-11-17
    Description: 〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉Laser ablation multi‐collector‐inductively coupled plasma‐mass spectrometry (LA‐MC‐ICP‐MS) has become a valuable tool for the 〈italic toggle="no"〉in situ〈/italic〉 measurement of the boron isotope composition of geological samples at high (tens to hundreds of μm) spatial resolution. That said, this application suffers from significant analytical challenges. We focus in this study on the underlying processes of two of the main causes for inaccuracies using this technique. We provide empirical evidence that not only Ca ions (Sadekov 〈italic〉et al〈/italic〉. 2019, Standish 〈italic〉et al〈/italic〉. 2019, Evans 〈italic〉et al〈/italic〉. 2021) but also Ar ions, that are reflected within the flight tube of the mass spectrometer, are the source for previously reported issues with spectral baselines. We also address the impact of plasma conditions on the instrumental mass fractionation as a source for matrix‐ and mass‐load‐related analytical biases. Comparing experimental data with the results of a dedicated release and diffusion model (RDM) we estimate that a close to complete (~ 97%) release of boron from the sample aerosol is needed to allow for consistently accurate LA boron isotope measurement results without the need for corrections.〈/p〉
    Description: Key Points: 〈list list-type="bullet" id="ggr12500-list-0101"〉 〈list-item〉〈p〉Two separate main sources for inaccuracy of boron isotope measurements by laser ablation: B isotope fractionation in the ICP and the known scattered ion baseline problem.〈/p〉〈/list-item〉 〈list-item〉〈p〉Boron isotope fractionation in the ICP varies systematically with plasma condition (NAI).〈/p〉〈/list-item〉 〈list-item〉〈p〉Behaviour of B isotopes within the ICP simulated by a release and diffusion model (RDM).〈/p〉〈/list-item〉 〈/list〉 〈boxed-text position="anchor" content-type="graphic" id="ggr12511-blkfxd-0001" xml:lang="en"〉 〈graphic position="anchor" id="jats-graphic-1" xlink:href="urn:x-wiley:16394488:media:ggr12511:ggr12511-toc-0001"〉 〈/graphic〉 〈/boxed-text〉 〈/p〉
    Keywords: ddc:550.78 ; boron isotopes ; laser ablation ; scattered ions ; mass fractionation ; plasma conditions
    Language: English
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  • 187
    Publication Date: 2023-11-17
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉〈italic toggle="no"〉Aeolus〈/italic〉 is the first satellite mission to acquire vertical profiles of horizontal line‐of‐sight winds globally and thus fills an important gap in the Global Observing System, most notably in the Tropics. This study explores the impact of this dataset on analyses and forecasts from the European Centre for Medium‐Range Weather Forecasts (ECMWF) and Deutscher Wetterdienst (DWD), focusing specifically on the West African Monsoon (WAM) circulation during the boreal summers of 2019 and 2020. The WAM is notoriously challenging to forecast and is characterized by prominent and robust large‐scale circulation features such as the African Easterly Jet North (AEJ‐North) and Tropical Easterly Jet (TEJ). Assimilating 〈italic toggle="no"〉Aeolus〈/italic〉 generally improves the prediction of zonal winds in both forecasting systems, especially for lead times above 24 h. These improvements are related to systematic differences in the representation of the two jets, with the AEJ‐North weakened at its southern flank in the western Sahel in the ECMWF analysis, while no obvious systematic differences are seen in the DWD analysis. In addition, the TEJ core is weakened in the ECMWF analysis and strengthened on its southern edge in the DWD analysis. The regions where the influence of 〈italic toggle="no"〉Aeolus〈/italic〉 on the analysis is greatest correspond to the Intertropical Convergence Zone (ITCZ) region for ECMWF and generally the upper troposphere for DWD. In addition, we show the presence of an altitude‐ and orbit‐dependent bias in the Rayleigh‐clear channel, which causes the zonal winds to speed up and slow down diurnally. Applying a temperature‐dependent bias correction to this channel contributes to a more accurate representation of the diurnal cycle and improved prediction of the WAM winds. These improvements are encouraging for future investigations of the influence of 〈italic toggle="no"〉Aeolus〈/italic〉 data on African Easterly Waves and associated Mesoscale Convective Systems.〈/p〉
    Description: 〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉Forecasting in tropical Africa is hampered by large model errors and low availability of conventional observations. The assimilation of 〈italic〉Aeolus〈/italic〉 wind data into the operational ECMWF system leads to a consistent root‐mean‐square error (RMSE) reduction of the order of 2% in +48 h zonal wind forecasts over the region during boreal summer 2019, including the African and Tropical Easterly Jets (AEJ, TEJ) and subtropical jets (STJ). 〈boxed-text position="anchor" id="qj4442-blkfxd-0001" content-type="graphic" xml:lang="en"〉〈graphic position="anchor" id="jats-graphic-1" xlink:href="urn:x-wiley:00359009:media:qj4442:qj4442-toc-0001"〉 〈/graphic〉 〈/boxed-text〉〈/p〉
    Description: https://aeolus-ds.eo.esa.int/oads/access/collection
    Keywords: ddc:551.6 ; aeolus satellite ; doppler wind lidar ; data assimilation ; numerical weather prediction impact ; African easterly jet ; tropical easterly jet ; observing system experiments
    Language: English
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  • 188
    Publication Date: 2023-12-07
    Description: Publishing data with a DOI (Digital Object Identifier) is becoming increasingly popular, and many researchers are being asked by journals to publish the data underlying the research results described in the article. Where does the data come from and how do I cite it correctly? […] This publication is a translation of the FID GEO article in 〈a href="http://doi.org/10.23689/fidgeo-5688"〉GMIT 90.〈/a〉
    Description: research
    Keywords: ddc:550 ; GMIT ; Geowissenschaftliche Mitteilungen
    Language: English
    Type: doc-type:article , publishedVersion
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  • 189
    Publication Date: 2023-12-07
    Description: The ORCID is an open alphanumeric identifier used to uniquely identify researchers.In an increasingly connected scientific landscape, the growing number of published research outputs (data, text, software) and new open publishing models pose major challenges for scientific publication management. The repositories available to FID GEO, GEO-LEOe-docs (SUB Goettingen) and GFZ Data Services (GFZ), have long been working with PIDs such as the Digital Object Identifier (DOI ) and the Open Researcher and Contributor iD (ORCID iD ), and recommend the use of the ORCID. This publication is a translation of the FID GEO article in 〈a href="http://doi.org/10.23689/fidgeo-5832"〉GMIT 87.〈/a〉
    Description: DFG, SUB Göttingen, GFZ Potsdam
    Description: research
    Keywords: ddc:550 ; GMIT
    Language: English
    Type: doc-type:article , publishedVersion
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  • 190
    Publication Date: 2023-12-12
    Description: Strain energy from tectonic loading can be partly released through aseismic creep. Earthquake repeaters, repeatedly activated brittle fault patches surrounded by creep, indicate steady‐state creep that affects the amount of seismic energy available for the next large earthquake along a plate contact. The offshore Main Marmara Fault (MMF) of the North Anatolian Fault Zone represents a seismic gap capable of generating a M 〉 7 earthquake in direct vicinity to the mega‐city Istanbul. Based on a newly compiled seismicity catalog, we identify repeating earthquakes to resolve the spatial creep variability along the MMF during a 15‐year period. We observe a maximum of seismic repeaters indicating creep along the central and western MMF segments tapering off toward the locked onshore Ganos fault in the west, and the locked offshore Princes Islands segment immediately south of Istanbul in the east. This indicates a high degree of spatial creep variability along the Istanbul‐Marmara seismic gap.
    Description: Plain Language Summary: The relative motion of tectonic plates deforms these plates along their contact zone until the plate contact ruptures in an earthquake. However, some of this deformation can be released without earthquakes by so‐called aseismic creep in which the plates creep past each other. Within this creep zone, sometimes some brittle patches exist that interlock during the plate creep and rupture repeatedly in smaller earthquakes that are very similar. They are called earthquake repeaters. In the Sea of Marmara south of Istanbul lies the contact between the Eurasian and the Anatolian plates, the so‐called Main Marmara Fault (MMF). This plate contact did not rupture for a long time and thus a large magnitude event is expected here. We observe a large number of earthquake repeaters in the western offshore part of the MMF while no earthquake repeaters are found toward the east south of Istanbul or onshore toward the west. These areas seem to be locked and might accumulate deformation for a future large earthquake. The zones in between show an intermediate behavior with fewer earthquake repeaters indicating less creep. These results are important for the seismic risk and hazard assessment for the mega‐city of Istanbul.
    Description: Key Points: Earthquake repeaters along the Main Marmara Fault are identified based on a newly derived homogeneous earthquake catalog spanning 15 years. Seismic creep estimated from these repeaters is highly variable along‐strike with higher creep values along the western part. A repeating earthquake sequence showing accelerated activity after a nearby Mw 5.2 earthquake is observed.
    Description: Helmholtz Association http://dx.doi.org/10.13039/501100009318
    Description: https://doi.org/10.5880/GFZ.4.2.2023.002
    Description: http://doi.org/10.7914/SN/TU
    Description: http://doi.org/10.7914/SN/KO
    Description: http://doi.org/10.7914/SN/PZ
    Description: http://doi.org/10.7914/SN/TB
    Description: http://alomax.free.fr/nlloc/
    Description: https://www.ldeo.columbia.edu/%7Efelixw/hypoDD.html
    Description: http://doi.org/10.5281/zenodo.3407866
    Description: https://doi.org/10.1029/2019gc008515
    Keywords: ddc:551.22 ; repeating earthquakes ; Marmara Sea ; fault creep ; seismic cyle ; seismic gap
    Language: English
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  • 191
    Publication Date: 2023-12-12
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉The Canadian Arctic Southern Beaufort Sea is characterized by prominent relict submarine permafrost and gas hydrate occurrences formed by subaerial exposure during extensive glaciations in Pliocene and Pleistocene. Submarine permafrost is still responding to the thermal change as a consequence of the marine transgression that followed the last glaciation. Submarine permafrost is still underexplored and is currently the focus of several research projects as its degradation releases greenhouse gases that contribute to climate change. In this study, seismic reflection indicators are used to investigate the presence of submarine permafrost and gas hydrates on the outer continental shelf where the base of permafrost is expected to cross‐cut geological layers. To address the challenges of marine seismic data collected in shallow water environments, we utilize a representative synthetic model to assess the data processing and the detection of submarine permafrost and gas hydrate by seismic data. The synthetic model allows us to minimize the misinterpretation of acquisition and processing artifacts. In the field data, we identify features along with characteristics arising from the top and base of submarine permafrost and the base of the gas hydrate stability zone. This work shows the distribution of the present submarine permafrost along the southern Canadian Beaufort Sea region and confirms its extension to the outer continental shelf. It supports the general shape suggested by previous works and previously published numerical models.〈/p〉
    Description: Plain Language Summary: Submarine permafrost, ground beneath the seafloor that perennially remains below 0°C, is present on the continental shelf of the Canadian Beaufort Sea. During the Late Pleistocene (∼1 Million years ago), the continental shelf was subaerially exposed to the cold Arctic air causing the formation of ice in the ground. This period was followed by a sea level rise that flooded the continental shelf with warmer waters, resulting in an intensive change of the thermal regime. The relict permafrost still reacts to this thermal change and is continuously thawing. Associated with the presence of relict permafrost, extensive gas hydrates exist to >1,000 m below the seafloor. Climate warming threatens both the stability of permafrost and associated gas hydrates. Their thawing and decomposition can cause a release of greenhouse gases which in turn amplifies climate warming. This study uses marine seismic reflection data to identify permafrost and gas hydrate in the southern Canadian Beaufort Sea. We find indicators of the top and base of permafrost and the base of the gas hydrate stability zone in the outer continental shelf area. Our work shows that the permafrost and gas hydrates still extend to the outer continental shelf and thereby supports previously published numerical models.〈/p〉
    Description: Key Points: 〈list list-type="bullet"〉 〈list-item〉 〈p xml:lang="en"〉Seismic reflection data reveal occurrences and extent of submarine permafrost and associated gas hydrates at the Canadian Beaufort Shelf〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉Synthetic modeling of permafrost and gas hydrate is required to assess seismic processing minimizing the potential for misinterpretation〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉Indicators of top and base of permafrost and the base of gas hydrate stability support previously published numerical models〈/p〉〈/list-item〉 〈/list〉 〈/p〉
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: Korean Ministry of Oceans and Fisheries
    Description: Environmental Geoscience Program of the Geological Survey of Canada
    Description: https://dx.doi.org/doi:10.22663/KOPRI-KPDC-00001958.3
    Keywords: ddc:551 ; submarine permafrost ; gas hydrate ; marine seismic ; Canadian Beaufort Sea ; seismic reflection
    Language: English
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  • 192
    Publication Date: 2023-12-12
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉The body size of marine ectotherms is often negatively correlated with ambient water temperature, as seen in many clades during the hyperthermal crisis of the end‐Permian mass extinction (〈italic toggle="no"〉c〈/italic〉. 252 Ma). However, in the case of ostracods, size changes during ancient hyperthermal events are rarely quantified. In this study, we evaluate the body size changes of ostracods in the Aras Valley section (northwest Iran) in response to the drastic warming during the end‐Permian mass extinction at three taxonomic levels: class, order, species. At the assemblage level, the warming triggers a complete species turnover in the Aras Valley section, with larger, newly emerging species dominating the immediate post‐extinction assemblage for a short time. Individual ostracod species and instars do not show dwarfing or a change in body size as an adaptation to the temperature stress during the end‐Permian crisis. This may indicate that the ostracods in the Aras Valley section might have been exceptions to the temperature–size rule (TSR), using an adaptation mechanism that does not involve a decrease in body size. This adaptation might be similar to the accelerated development despite constant instar body sizes that can be observed in some recent experimental studies of ostracod responses to thermal stress.〈/p〉
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: https://doi.org/10.5061/dryad.xgxd254mb
    Keywords: ddc:565 ; Permian–Triassic ; Ostracoda ; body size ; mass extinction ; Aras Valley section
    Language: English
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  • 193
    Publication Date: 2023-12-12
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉This study provides a descriptive characterization of the modern sedimentary processes in Lake Issyk Kul, Kyrgyzstan, important for the selection of a suitable coring or deep‐drilling site, interpretation of future core data and applicability of proxies. The quasi‐equidistant sampling grid of 66 sediment surface samples covers the entirety of the lake basin and is complemented by 10 samples from the major inflows. The methodological approach includes geochemical, granulometric, lipid biomarker, diatom, and statistical analyses. The quantitative and qualitative changes in sediment composition yield information on its generic origin and prevailing transport and depositional environments. The composition of the surface sediments in Issyk Kul is highly heterogenous. Nearshore deposition is mainly controlled by wave action and by fluvial sediment supply with highest quantities of detrital input coming from the high‐energetic, eastern tributaries. Sediments in the deep central basin are mainly produced in situ and dominated by authigenic calcite. Biogenic accumulation is overall low, except for the western extremity of the lake, where the nearshore, shallow‐water, and low‐energetic environment favors aquatic productivity and subsequent preservation of organic material and diatoms. Redeposition of sediments is a dominant process along the slopes across the southern and western basin floor, where run‐out distances of mass movement deposits are up to 5 km. Directional sediment transport by lake currents appears to be less important, except for the transport of very fine‐grained organic matter. Biomarker‐inferred temperature reconstructions suggest lake surface temperatures of ∼15°C in the western littoral zone and in Tyup Bay and a decrease to ∼13°C basinward.〈/p〉
    Description: Plain Language Summary: Intensive research on the natural component of climate variability on geological time scales is needed to better understand and validate current and future climate change. Lakes can provide continuous sediment successions that allow us to reconstruct regional trends in climate and environment dynamics far beyond the industrial age. In continental Eurasia, Lake Issyk Kul, one of the deepest and largest mountain lakes in the world, has long been targeted for a deep‐drilling campaign, because its sediment succession potentially holds information of the past ∼10 million years. Prerequisite for future drilling is a better understanding of prevailing transport and (re)deposition mechanisms in Lake Issyk Kul. The overarching aim of this study is to test the applicability of different proxies, vital for the interpretation of future sediment core data. Therefore, a quasi‐equidistant sampling grid of up to 66 sediment surface (and 10 river) samples spanning the entire lake basin of Lake Issyk Kul was examined by means of sedimentological, geochemical, biological, and statistical analyses. The interpretation provides insights into spatial differences in, for example, clastic input from major rivers, biogenic sedimentation, and endogenic precipitation of calcium carbonates.〈/p〉
    Description: Key Points: 〈list list-type="bullet"〉 〈list-item〉 〈p xml:lang="en"〉The study provides information on the prevailing transport and (re)deposition mechanisms in Lake Issyk Kul today〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉Geochemical, granulometric, lipid biomarker, diatom, and statistical analyses were performed on surface sediment and inlet stream samples〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉The results are prerequisite to interpret longer sediment successions from the lake〈/p〉〈/list-item〉 〈/list〉 〈/p〉
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: https://doi.org/10.5281/zenodo.8059855
    Keywords: ddc:551.3 ; Issyk Kul ; modern sedimentary processes ; climate ; geochemistry ; grain‐size ; XRF ; lipid biomarker ; diatoms
    Language: English
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  • 194
    Publication Date: 2023-12-12
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉Reducing flood risk through disaster planning and risk management requires accurate estimates of exposure, damage, casualties, and environmental impacts. Models can provide such information; however, computational or data constraints often lead to the construction of such models by aggregating high‐resolution flood hazard grids to a coarser resolution, the effect of which is poorly understood. Through the application of a novel spatial classification framework, we derive closed‐form solutions for the location (e.g., flood margins) and direction of bias from flood grid aggregation independent of any study region. These solutions show bias of some key metric will always be present in regions with marginal inundation; for example, inundation area will be positively biased when water depth grids are aggregated and volume will be negatively biased when water surface elevation grids are aggregated through averaging. In a separate computational analysis, we employ the same framework to a 2018 flood and successfully reproduce the findings of our study‐region‐independent derivation. Extending the investigation to the exposure of buildings, we find regions with marginal inundation are an order of magnitude more sensitive to aggregation errors, highlighting the importance of understanding such artifacts for flood risk modelers. Of the two aggregation routines considered, averaging water surface elevation grids better preserved flood depths at buildings than averaging of water depth grids. This work provides insight into, and recommendations for, aggregating grids used by flood risk models.〈/p〉
    Description: Key Points: 〈list list-type="bullet"〉 〈list-item〉 〈p xml:lang="en"〉Through a novel framework, we show analytically that hazard grid aggregation leads to bias of key metrics independent of any study region〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉This aggregation is shown to always positively bias inundation area when water depth grids are aggregated〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉For example, aggregating from 1 to 512 m resolution resulted in a doubling of the inundated area for a 2018 flood in Canada〈/p〉〈/list-item〉 〈/list〉 〈/p〉
    Description: Deutsche Forschungsgemeinschaft
    Description: https://doi.org/10.5281/zenodo.8271996
    Description: https://doi.org/10.5281/zenodo.8271965
    Description: http://geonb.snb.ca/li/index.html
    Description: http://www.snb.ca/geonb1/e/DC/floodraahf.asp
    Keywords: ddc:551.48 ; flood risk ; model scaling ; data aggregation ; flood hazard ; error ; resampling
    Language: English
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  • 195
    Publication Date: 2023-12-12
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉Infrared spectroscopy in the visible to near‐infrared (vis–NIR) and mid‐infrared (MIR) regions is a well‐established approach for the prediction of soil properties. Different data fusion and training approaches exist, and the optimal procedures are yet undefined and may depend on the heterogeneity present in the set and on the considered scale. The objectives were to test the usefulness of partial least squares regressions (PLSRs) for soil organic carbon (SOC), total carbon (C〈sub〉t〈/sub〉), total nitrogen (N〈sub〉t〈/sub〉) and pH using vis–NIR and MIR spectroscopy for an independent validation after standard calibration (use of a general PLSR model) or using memory‐based learning (MBL) with and without spiking for a national spectral database. Data fusion approaches were simple concatenation of spectra, outer product analysis (OPA) and model averaging. In total, 481 soils from an Austrian forest soil archive were measured in the vis–NIR and MIR regions, and regressions were calculated. Fivefold calibration‐validation approaches were carried out with a region‐related split of spectra to implement independent validations with n ranging from 47 to 99 soils in different folds. MIR predictions were generally superior over vis–NIR predictions. For all properties, optimal predictions were obtained with data fusion, with OPA and spectra concatenation outperforming model averaging. The greatest robustness of performance was found for OPA and MBL with spiking with 〈italic toggle="no"〉R〈/italic〉〈sup〉2〈/sup〉 ≥ 0.77 (N), 0.85 (SOC), 0.86 (pH) and 0.88 (C〈sub〉t〈/sub〉) in the validations of all folds. Overall, the results indicate that the combination of OPA for vis–NIR and MIR spectra with MBL and spiking has a high potential to accurately estimate properties when using large‐scale soil spectral libraries as reference data. However, the reduction of cost‐effectiveness using two spectrometers needs to be weighed against the potential increase in accuracy compared to a single MIR spectroscopy approach.〈/p〉
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Keywords: ddc:631.4 ; data fusion ; independent validation ; infrared spectroscopy ; MBL ; nitrogen ; outer product analysis ; pH ; soil organic carbon ; spiking ; total carbon
    Language: English
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  • 196
    Publication Date: 2023-12-12
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉Reducing carbon dioxide to value‐added chemicals by electrolysis is a promising strategy to substitute fossil‐based processes. Research on CO〈sub〉2〈/sub〉 electrolysis has vastly progressed, focusing on catalysis and electrode design, leaving an essential question on the central part of the electrolyzer: Which type of ion exchange membrane is best suited for CO〈sub〉2〈/sub〉 electrolysis from an economic perspective? To address this question, holistic process optimization of CO〈sub〉2〈/sub〉 reduction and product purification is applied. The findings demonstrate that CO〈sub〉2〈/sub〉 electrolysis with an anion exchange membrane shows competitive production costs for CO of 796 €/t〈sub〉CO〈/sub〉, outperforming cation exchange and bipolar membranes. Unlike often described, the CO〈sub〉2〈/sub〉 pumping effect does not significantly impair the economics but offers an efficient indirect regeneration of dissociated CO〈sub〉2〈/sub〉. Furthermore, the results emphasize selective reduction of CO〈sub〉2〈/sub〉 rather than co‐electrolysis of CO〈sub〉2〈/sub〉 and H〈sub〉2〈/sub〉O. While pointing to a positive economic perspective, life‐cycle assessment highlights the need to minimize CO〈sub〉2〈/sub〉 emissions related to electricity consumption and incomplete CO〈sub〉2〈/sub〉 utilization.〈/p〉
    Description: 〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉Holistic optimization of CO〈sub〉2〈/sub〉 electrolysis and downstream processing highlighted an electrolyzer with an anion exchange membrane to be the most economical for CO production. Interestingly, the CO〈sub〉2〈/sub〉 pumping effect offers an efficient indirect regeneration of dissociated CO〈sub〉2〈/sub〉. Moreover, selective CO〈sub〉2〈/sub〉 reduction is emphasized from economic and ecological assessment, demanding mitigation of CO〈sub〉2〈/sub〉 emissions related to electricity consumption and incomplete utilization. 〈boxed-text position="anchor" content-type="graphic" xml:lang="en"〉 〈graphic position="anchor" id="jats-graphic-1" xlink:href="urn:x-wiley:23667486:media:adsu202300077:adsu202300077-gra-0001"〉 〈/graphic〉 〈/boxed-text〉〈/p〉
    Keywords: ddc:333.7 ; carbon utilization ; electrochemical CO2 reduction ; holistic process optimization ; life‐cycle assessment ; techno‐economic assessment
    Language: English
    Type: doc-type:article
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  • 197
    Publication Date: 2023-12-12
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉To first order, the magnetopause (MP) is defined by a pressure balance between the solar wind and the magnetosphere. The boundary moves under the influence of varying solar wind conditions and transient foreshock phenomena, reaching unusually large and small distances from the Earth. We investigate under which solar wind conditions such extreme MP distortions occur. Therefore, we construct a database of magnetopause crossings (MPCs) observed by the THEMIS spacecraft in the years 2007 to mid‐2022 using a simple Random Forest Classifier. Roughly 7% of the found crossing events deviate beyond reported errors in the stand‐off distance from the Shue et al. (1998, 〈ext-link ext-link-type="uri" xlink:href="https://doi.org/10.1029/98JA01103"〉https://doi.org/10.1029/98JA01103〈/ext-link〉) MP model and thus are termed extreme distortions. We find the occurrence of these extreme events in terms of expansion or compression of the MP to be linked to different solar wind parameters, most notably to the IMF magnitude, cone angle, velocity, Alfvén Mach number and temperature. Foreshock transients like hot‐flow anomalies and foreshock bubbles could be responsible for extreme magnetospheric expansions. The results should be incorporated into future magnetopause models and may be helpful for the reconstruction of the MP locations out of soft x‐ray images, relevant for the upcoming SMILE mission.〈/p〉
    Description: Key Points: 〈list list-type="bullet"〉 〈list-item〉 〈p xml:lang="en"〉More than 160.000 magnetopause crossings (MPCs) identified in THEMIS data between 2007 and 2022 using a Random Forest Classifier〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉Magnetopause crossings that extremely deviate in location from the Shue et al. (1998, 〈ext-link ext-link-type="uri" xlink:href="https://doi.org/10.1029/98JA01103"〉https://doi.org/10.1029/98JA01103〈/ext-link〉) model are quite common〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉Important solar wind parameters associated with deviations include the interplanetary magnetic field cone angle, solar wind velocity and Alfvén Mach number〈/p〉〈/list-item〉 〈/list〉 〈/p〉
    Description: German Ministerium für Wirtschaft und Klimaschutz and Deutsches Zentrum für Luft‐und Raumfahrt http://dx.doi.org/10.13039/501100002946
    Description: UKRI Stephen Hawking Fellowship
    Description: German Ministry for Economy and Technology and
    Description: German Center for Aviation and Space
    Description: https://osf.io/b6kux/
    Description: https://github.com/spedas/pyspedas
    Description: http://themis.ssl.berkeley.edu/data/themis/
    Description: https://omniweb.gsfc.nasa.gov/
    Description: https://scikit-learn.org/stable/supervised_learning.html#supervised-learning
    Keywords: ddc:538.7 ; magnetopause ; solar wind ; statistics ; machine learning ; THEMIS
    Language: English
    Type: doc-type:article
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  • 198
    Publication Date: 2023-12-12
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉Global warming, bioinvasions, and parasitism affect single‐species performances and species interactions, substantially impacting the structure and stability of marine ecosystems. In light of accelerated global change, the information derived from studies focusing on single species and single drivers is insufficient, calling for a multi‐stressor approach under near‐natural conditions. We investigated the effects of warming (+3°C) on the performance of a benthic community composed of native and invasive macroalgae, consumers and a trematode parasite in a mesocosm setting. We also assessed the effects of warming and parasitism on the survival and growth of gastropods and mussels and the thermal dependency of trematode performance. Our findings show that warming and grazing by infected gastropods had a large detrimental effect on the invasive macroalga growth. Furthermore, the single and interactive effects of parasitism and warming were detrimental to intermediate host survival and growth, especially to large mussels. Finally, cercarial emergence positively correlated to the natural peaks of summer temperatures, while infection intensity in mussels was higher in larger individuals. Our findings suggest that grazing and warming will be detrimental to the invasive macroalga, favoring the native alga. Moreover, parasitism will enhance grazing, especially in summer, when higher temperatures trigger parasite development. However, parasite‐enhanced grazing may be buffered by higher mortality or a shift in the size of infected intermediate hosts under warming. Our findings demonstrate how complex effects of ocean warming can be on food webs and how they can be mediated by parasitism and, as a result, influence native and invasive macroalgae differently.〈/p〉
    Description: Bundesministerium für Bildung und Forschung http://dx.doi.org/10.13039/501100002347
    Keywords: ddc:577.7 ; Baltic community ; climate change ; bioinvasions ; parasitism ; interactive effects ; macroalgae growth
    Language: English
    Type: doc-type:article
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  • 199
    Publication Date: 2023-11-28
    Description: Horizontal gravity wave (GW) refraction was observed around the Andes and Drake Passage during the SouthTRAC campaign. GWs interact with the background wind through refraction and dissipation. This interaction helps to drive midatmospheric circulations and slows down the polar vortex by taking GW momentum flux (GWMF) from one location to another. The SouthTRAC campaign was composed to gain improved understanding of the propagation and dissipation of GWs. This study uses observational data from this campaign collected by the German High Altitude Long Range research aircraft on 12 September 2019. During the campaign a minor sudden stratospheric warming in the southern hemisphere occurred, which heavily influenced GW propagation and refraction and thus also the location and amount of GWMF deposition. Observations include measurements from below the aircraft by Gimballed Limb Observer for Radiance Imaging of the Atmosphere and above the aircraft by Airborne Lidar for the Middle Atmosphere. Refraction is identified in two different GW packets as low as ≈4 km and as high as 58 km. One GW packet of orographic origin and one of nonorographic origin is used to investigate refraction. Observations are supplemented by the Gravity‐wave Regional Or Global Ray Tracer, a simplified mountain wave model, ERA5 data and high‐resolution (3 km) WRF data. Contrary to some previous studies we find that refraction makes a noteworthy contribution in the amount and the location of GWMF deposition. This case study highlights the importance of refraction and provides compelling arguments that models should account for this.
    Description: Plain Language Summary: Gravity waves (GWs) are very important for models to reproduce a midatmospheric circulations. But the fact is that models oversimplify the GW physics which results in GWs being underrepresented in models. GW refraction is one of the processes not captured by the physics in model parameterization schemes. This article uses high‐resolution observations from the SouthTRAC campaign to show how GWs refract and highlight the importance there‐of. This case study shows a 25% increase in the GWMF during propagation. The increase in momentum flux is linked to refraction which results in a shortening in the GW horizontal wavelength. This article shows that refraction is important for the amount as well as the location of GWMF deposition. This case study highlights the importance of refraction and provides compelling arguments that models should account for this.
    Description: Key Points: A case study reveals that refraction results in a 25% increase in gravity wave momentum flux (GWMF). Including refraction dynamics affects the location of GWMF deposition. Refraction is prominent in strong wind gradients (i.e., displaced vortex conditions).
    Description: ANPCYT PICT
    Description: DFG
    Description: Bundesministerium für Bildung und Forschung http://dx.doi.org/10.13039/501100002347
    Description: Instituto de Física de Buenos Aires
    Description: SNCAD MinCyT initiative
    Description: HALO‐SPP
    Description: ROMIC WASCLIM
    Description: https://doi.org/10.5281/zenodo.6997443
    Description: https://cds.climate.copernicus.eu/cdsapp%23%21/home
    Keywords: ddc:551.5 ; gravity wave ; mountain wave ; refraction ; Andes ; Drake Passage ; gravity wave momentum flux
    Language: English
    Type: doc-type:article
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  • 200
    Publication Date: 2023-11-27
    Description: Using the 5 km coupled general circulation model ICON, the surface internal wave energy source, crucial for the oceanic circulation, is quantified as the wind‐induced wave energy flux that radiates from the mixed layer bottom (MLB) into the ocean interior. Our result lowers the previous estimates of the wind power input to surface near‐inertial motions from up to more than 1 TW down to about 0.23–0.27 TW, depending on season. We point out that the estimate of the wind input to ocean depends not only on the wind stress used—as suggested by previous studies—but also on the ocean model used. While the surface currents in a slab ocean model or a non‐eddying ocean circulation model are strongly determined by the wind forcing, the surface currents in the 5 km ICON model can be more strongly determined by internal instability process (eddy) than by wind stress forcing from less‐extreme weather disturbances. The resulting more or less random alignment of surface current and wind stress can presumably lead to a lower wind input to surface near‐inertial motions. Of the surface wave energy source, about 30% is fluxed down into the interior ocean. This percentage roughly doubles those from previous studies, due to the stronger wave energy flux related to stronger inertial waves generated by the tropical cyclones simulated by the 5 km ICON model. Overall, the low wind input at near‐inertial frequencies produces a wind‐induced wave energy source at the MLB that is well below 0.1 TW.
    Description: Plain Language Summary: For maintaining the oceanic overturning circulation, energy is needed to mix the dense water up and light water down. The main energy source for mixing arises from breaking of internal waves. A considerable portion of this source comes from waves excited by winds at the sea surface. This paper quantifies this wave energy source based on a frontier simulation of a coupled atmosphere‐ocean general circulation model at a horizontal resolution of 5 km. This model is capable to simulate tropical cyclones (hurricanes and typhoons) and less‐extreme small‐scale and short‐living weather disturbances and oceanic mesoscale eddies, which were not represented by the models used in most of the previous studies. Taking these new features into account, we find that the wind‐induced wave energy source is less than 0.1 TW.
    Description: Key Points: Relatively low wind power input to near‐inertial motions in a 5 km global coupled simulation. Energy flux radiating from the mixed layer bottom as interior wave energy source. Strong internal waves excited by tropical cyclones simulated by a 5 km global coupled general circulation model.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: http://hdl.handle.net/21.11116/0000-000A-C1FA-2
    Keywords: ddc:551.5 ; wind‐induced wave energy source ; km‐scale coupled GCM ; internal waves generated by tropical cyclones
    Language: English
    Type: doc-type:article
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