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  • 1
    Publication Date: 2023-11-18
    Description: Cyclostratigraphy and astrochronology are now at the forefront of geologic timekeeping. While this technique heavily relies on the accuracy of astronomical calculations, solar system chaos limits how far back astronomical calculations can be performed with confidence. High‐resolution paleoclimate records with Milankovitch imprints now allow reversing the traditional cyclostratigraphic approach: Middle Eocene drift sediments from Newfoundland Ridge are well‐suited for this purpose, due to high sedimentation rates and distinct lithological cycles. Per contra, the stratigraphies of Integrated Ocean Drilling Program Sites U1408–U1410 are highly complex with several hiatuses. Here, we built a two‐site composite and constructed a conservative age‐depth model to provide a reliable chronology for this rhythmic, highly resolved (〈1 kyr) sedimentary archive. Astronomical components (g‐terms and precession constant) are extracted from proxy time‐series using two different techniques, producing consistent results. We find astronomical frequencies up to 4% lower than reported in astronomical solution La04. This solution, however, was smoothed over 20‐Myr intervals, and our results therefore provide constraints on g‐term variability on shorter, million‐year timescales. We also report first evidence that the g〈sub〉4〈/sub〉–g〈sub〉3〈/sub〉 “grand eccentricity cycle” may have had a 1.2‐Myr period around 41 Ma, contrary to its 2.4‐Myr periodicity today. Our median precession constant estimate (51.28 ± 0.56″/year) confirms earlier indicators of a relatively low rate of tidal dissipation in the Paleogene. Newfoundland Ridge drift sediments thus enable a reliable reconstruction of astronomical components at the limit of validity of current astronomical calculations, extracted from geologic data, providing a new target for the next generation of astronomical calculations.
    Description: Plain Language Summary: The traditional cyclostratigraphic approach is to align and correlate a geologic depth‐series with an astronomical solution. However, the chaotic nature of the Solar System prevents astronomers from precisely calculating planetary motions beyond 40–50 million years ago. This in turn limits the options for geologists to use the resulting oscillations in Earth's climate system as a metronome for determining geologic time. In this study, we reversed the cyclostratigraphic approach and used the highly rhythmical sedimentary deposits from Newfoundland Ridge (North Atlantic) to back‐calculate planetary motions at ∼41 million years ago. The superior quality of the Newfoundland Ridge geoarchive originates from the combination of relatively high sedimentation rates (∼4 cm/kyr) and the time‐continuous character of our two‐site composite record between 39.5 and 42.8 million years ago. In this work, we had to first overcome considerable challenges in reconstructing the timing of sediment deposition, which we did with highly resolved geochemical measurements from two sites. We then were able to extract information on the Earth's planetary motion and on the Earth‐Moon interactions. These astronomical reconstructions based on geological data can now be used by astronomers to describe the evolution of the solar system further back in time than was previously possible.
    Description: Key Points: A new precession‐based cyclostratigraphy for the middle Eocene intervals of IODP Sites U1408 and U1410. Variability in astronomical fundamental frequencies (g‐terms) on million‐year timescales is larger than previously assumed. Our precession constant estimate for 41 Ma (51.28 ± 0.56″/year) confirms earlier indicators of slower tidal dissipation in the Paleogene.
    Description: National Science Foundation http://dx.doi.org/10.13039/100000001
    Description: University of California http://dx.doi.org/10.13039/100005595
    Description: Belgian American Educational Foundation http://dx.doi.org/10.13039/100001491
    Description: https://paloz.marum.de/AstroComputation/index.html
    Description: https://paloz.marum.de/confluence/display/ESPUBLIC/NAFF
    Keywords: ddc:551 ; North Atlantic ; Eocene ; cyclostratigraphy ; astrochronology
    Language: English
    Type: doc-type:article
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  • 2
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 112 (2000), S. 10173-10178 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The collisional loss of vibrational energy from polyatomic molecules in triplet electronic states has been studied in new detail through a variant of the competitive radiationless decay (CRD) method. Experimental transient absorption kinetics for T1 pyrazine vapor in the presence of helium relaxer reveals the competition between unimolecular radiationless decay and collisional vibrational relaxation. These data have been simulated with Monte Carlo stochastic calculations equivalent to full master equation solutions that model the distribution of donor vibrational energies during relaxation. The simulations included energy-dependent processes of T1→S0 radiationless decay, Tn←T1 optical absorption, and collisional energy loss. The simulation results confirm earlier findings of energy loss tendencies that increase strongly for pyrazine vibrational energies above ∼2000 cm−1. It is also found that the experimental data are not accurately simulated over a range of relaxer pressures if a simple exponential step-size distribution function is used to model collisional energy changes. Improved simulations are obtained by including an additional, low-probability channel representing large energy changes. This second channel would represent "supercollisions," which have not previously been recognized in the vibrational relaxation of triplet state polyatomics. © 2000 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 99 (1995), S. 17380-17385 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 110 (1999), S. 5047-5055 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: To further explore the collisional vibrational relaxation of triplet state polyatomic molecules, studies of pyrazine have been extended to its fully deuterated isotopomer (pyrazine-d4) and methyl derivative (2-methylpyrazine). The lowest triplet states of these compounds were prepared with 5596 and 5149 cm−1, respectively, of vibrational excitation through pulsed optical excitation followed by intersystem crossing. Collisional vibrational energy loss was then monitored using the refined competitive radiationless decay (CRD) method. The average energy losses per gas kinetic collision were measured as a function of donor vibrational energy for relaxation by He, Ne, Ar, Kr, Xe, H2, D2, CO2, H2O, CH4, and CH3F. Deuteration is found to cause very little change in the efficient energy loss behavior measured earlier in T1 pyrazine-h4. By contrast, methylation significantly increases the average energy lost per collision and also seems to lower the energy threshold for rapid relaxation. It is deduced that vibronic coupling between T1 and nearby triplet states is largely responsible for the high susceptibility to collisional energy loss. Many other molecules with closely spaced excited states may be expected to show collisional vibrational relaxation that is significantly enhanced by electronic excitation. © 1999 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 108 (1998), S. 9404-9413 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Gas phase collisional vibrational relaxation of pyrazine in its lowest triplet electronic state has been further investigated using a refined version of the competitive radiationless decay (CRD) method. Improvements to the experimental apparatus now provide primary kinetic data of much greater accuracy and precision, allowing the use of sample pressures low enough to ensure negligible self-relaxation. A major refinement of the data handling procedure permits the sample's energy-dependent triplet–triplet molar absorptivity to be determined through an iterative analysis. To validate the refined CRD method, average energy loss per collision has been deduced as a function of donor energy under conditions of varying sample pressure, relaxer pressure, excitation beam energy, and excitation wavelength. Consistent results have been obtained for all of these variations, suggesting the absence of major systematic errors. The two main findings of earlier pyrazine triplet relaxation studies are confirmed by the new measurements: the presence of a threshold donor energy above which relaxation becomes much more efficient, and relatively large values of average energy loss per collision. Comparing to results from a recent ground state study [L. A. Miller and J. R. Barker, J. Chem. Phys. 105, 1383 (1996)], it is found that pyrazine containing 5000 cm−1 of vibrational energy is relaxed by a variety of monatomic, diatomic, and polyatomic gases approximately seven times more efficiently when the donor is in its triplet rather than its ground electronic state. The order of relaxer efficiencies toward triplet pyrazine is found to be He〈H2〈Ne〈D2〈N2〈Kr〈Ar〈Xe〈CH4〈CO〈CO2〈CH3F〈H2O. Energy loss efficiencies correlate rather well with relaxer boiling points. © 1998 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Chinese Astronomy and Astrophysics 6 (1982), S. 216-220 
    ISSN: 0275-1062
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Physics
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Chinese Astronomy and Astrophysics 5 (1981), S. 235-241 
    ISSN: 0275-1062
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Physics
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Chinese Astronomy and Astrophysics 6 (1982), S. 181-185 
    ISSN: 0275-1062
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Physics
    Type of Medium: Electronic Resource
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  • 9
    ISSN: 1434-6036
    Keywords: PACS. 74.72.Dn La-based cuprates – 74.25.Ha Magnetic properties – 74.90.+n Other topics in superconductivity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract: We have measured the zero field and field cooled magnetization of the lightly oxygen doped Cu-rich La2CuO 4 + δ in a wide temperature range (5 K to 350 K). The data together with the evolution of the magnetic hysteresis loop suggest that the ferromagnetism with Curie temperature of 280 K coexists with superconductivity below the transition temperature ∼ 34 K. The coexistence occurs in the hole-rich clusters of size ? 150 nm, which are electronic phase separated from the hole-poor antiferromagnetic background.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Springer
    Journal of chemical crystallography 23 (1993), S. 645-648 
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The crystal and molecular structure of the title compound (C19H22N2S) has been investigated by single crystal X-ray methods. The crystals are orthorhombic, space groupPbca, with cell dimensions:a=12.082(2)Å,b=11.460(2)Å,c=25.128(4)Å. The structure was solved by direct methods, and refined with 1225 independent reflections by a full-matrix, least-squares procedure, which converged toR=0.042. The benzene and thiazole planes are coplanar and the cyclohexane ring adopts a chair conformation.
    Type of Medium: Electronic Resource
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