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  • Elsevier  (378,948)
  • American Meteorological Society
  • 2020-2023  (413)
  • 1995-1999  (385,813)
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  • 101
    Publication Date: 2022-02-11
    Description: Fluids supplied by stored magma at depth are causal factors of volcanic unrest, as they can cause pressurization/ heating of hydrothermal systems. However, evidence for links between hydrothermal pressurization, CO2 emission and volcano seismicity have remained elusive. Here, we use recent (2010−2020) observations at Campi Flegrei caldera (CFc) to show hydrothermal pressure, gas emission and seismicity at CFc share common source areas and well-matching temporal evolutions. We interpret the recent escalation in seismicity and surface gas emissions as caused by pressure-temperature increase at the top of a vertically elongated (0.3–2 km deep) gas front. Using mass (steam) balance considerations,we showhydrothermal pressurization is causing energy transfer from the fluids to the host rocks, ultimately triggering low magnitude earthquakes within a seismogenetic volume containing the hydrothermal system. This mechanism is probably common to other worldwide calderas in similar hydrothermal activity state.
    Description: MIUR project n. PRIN2017-2017LMNLAW“Connect4Carbon”
    Description: Published
    Description: 107245
    Description: 4V. Processi pre-eruttivi
    Description: JCR Journal
    Keywords: CO2 emission ; Campi Flegrei ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 102
    Publication Date: 2021-12-23
    Description: Machine learning is becoming increasingly important in scientific and technological progress, due to its ability to create models that describe complex data and generalize well. The wealth of publicly-available seismic data nowadays requires automated, fast, and reliable tools to carry out a multitude of tasks, such as the detection of small, local earthquakes in areas characterized by sparsity of receivers. A similar application of machine learning, however, should be built on a large amount of labeled seismograms, which is neither immediate to obtain nor to compile. In this study we present a large dataset of seismograms recorded along the vertical, north, and east components of 1487 broad-band or very broad-band receivers distributed worldwide; this includes 629,095 3-component seismograms generated by 304,878 local earthquakes and labeled as EQ, and 615,847 ones labeled as noise (AN). Application of machine learning to this dataset shows that a simple Convolutional Neural Network of 67,939 parameters allows discriminating between earthquakes and noise single-station recordings, even if applied in regions not represented in the training set. Achieving an accuracy of 96.7, 95.3, and 93.2% on training, validation, and test set, respectively, we prove that the large variety of geological and tectonic settings covered by our data supports the generalization capabilities of the algorithm, and makes it applicable to real-time detection of local events. We make the database publicly available, intending to provide the seismological and broader scientific community with a benchmark for time-series to be used as a testing ground in signal processing.
    Description: Published
    Description: 1-10
    Description: 1SR TERREMOTI - Sorveglianza Sismica e Allerta Tsunami
    Description: N/A or not JCR
    Keywords: Physics - Geophysics; Physics - Geophysics ; dataset for machine learning in seismology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 103
    Publication Date: 2021-12-23
    Description: After the 2004 Indian Ocean (IOT) and the 2011 Tohoku-oki tsunamis, new research in tsunami-related fields was strongly stimulated worldwide and also in the Mediterranean. This research growth yields substantial advancements in tsunami knowledge. Among these advancements is the “Paleotsunami” research that has marked particular progress on the reconstruction of the tsunami history of a region. As an integration of the historical documentation available in the Mediterranean and the Gulf of Cadiz areas, geological and geoarchaeological records provide the insights to define the occurrence, characteristics, and impact of tsunamis of the past. Here, we present the recent advancements done for both the onshore and offshore realms. As for the onshore, we discuss case studies dealing with recent high-resolution works based on: a) direct push in situ sensing techniques, applied to identification and characterization of typical paleotsunami deposits features; b) combined XRF- X-CT approach, implemented for the identification of fine-scale sedimentary structures useful for the definition of the causative flow dynamics; c) the geoarchaeological “new field” contribution, with the development of specific diagnostic criteria in search for tsunami impact traces in archaeological strata; d) comparison of multiple dating methods and of different modeling codes for the definition of the potential source for the displacement of boulders of exceptional dimension, identified by 3D size calculation. As for the offshore advancements, we present case studies focusing on the recognition of tsunami deposits and their sedimentary traces in the geological record from the nearshore, thanks to diver-operated coring equipment, down to the continental slope, by means of vibracorer and long gravity core sampling in deeper areas. The examples provided show a multiproxy approach with a high potential of retrieving a complete record of paleotsunami traces at least during the Holocene. This is based on the combination of multidisciplinary approaches including X-ray imaging, high-resolution measurement of physical properties, X- ray fluorescence data, grain-size analysis, micropaleontology, palynological content, isotopic and optically stimulated luminescence dating methods.
    Description: Published
    Description: 103578
    Description: 6T. Studi di pericolosità sismica e da maremoto
    Description: JCR Journal
    Keywords: Paleotsunami deposits ; Mediterranean Sea ; High-resolution studies ; Archeology ; backwash wave ; Geology ; tsunami ; paleotsunami deposits ; Mediterranean Sea
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 104
    Publication Date: 2022-02-03
    Description: This work presents the first 3D geological model of the Rome coastal area that integrates available subsurface geological, stratigraphic and geophysical data with surface geochemical data obtained both from the literature and new surveys. The model provides new insights into the stratigraphic and tectonic setting of the area and the geological factors controlling both natural and human-induced gas emissions. This sector of the Italian Tyrrhenian margin has been historically affected by natural emissions of deep CO2 and thermogenic CH4, stored in permeable layers but with local migration to the surface along buried normal faults. In addition to natural processes, human activities can also cause leakage and serious health risks, such as the abrupt gas release in August 2013, that was triggered by borehole drillings near the Rome international airport. The presented 3D reconstruction unveils the link between faults, stratigraphy, lithology and the distribution of the soil gas anomalies. It provides information about the depth of the reservoir that can potentially trap endogenous gases, and the location and geometry of the main faults along which the gas migrates towards the surface. Furthermore, reconstruction of the distribution and thickness of important clay layers better constrains the low permeable areas that prevent gas escape. The 3D model, coupled with the geochemical information, can serve as a useful tool for the local administration to perform land-use planning and manage the local geological and degassing hazards that affect this highly urbanized area near Rome. Furthermore, we estimate that the large amount of CO2 broadly released in the area also provides a contribution to the budget of natural greenhouse gases in the atmosphere.
    Description: Published
    Description: 106527
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Keywords: 3D geological model ; Soil gas ; Active faults ; Surface degassing ; Geological hazards ; Tiber delta ; 04.04. Geology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 105
    Publication Date: 2022-02-02
    Description: Ion temperature data recorded by Millstone Hill incoherent scatter radar (42.61 N, 288.51 E) over four full solar cycles (from 1970 to 2018) are analyzed to depict its climatological behavior in the range of altitudes between 100 and 550 km. The ion temperature dependencies on altitude, local time, month of the year, and solar activity level are studied through a climatological analysis based on binning and boxplot representation of statistical values. Binned observations of ion temperature are compared with International Reference Ionosphere (IRI) modeled values (IRI-2016 version). This comparison reveals several shortcomings in the IRI modeling of the ion temperature at ionosphere altitudes, in particular for the altitudinal, diurnal, seasonal, and solar activity description. The main finding of this study is that the overall IRI overestimation of the ion temperature can be probably ascribed to the long-term ionosphere cooling. Moreover, the study suggests that the IRI ion temperature model needs to implement the seasonal and solar activity dependence, and introduce a more refined diurnal description to allow multiple diurnal maxima seen in observations. The IRI ion temperature anchor point at 430 km is investigated in more detail to show how also a better description of the altitude dependence is desirable for modeling purposes. Some hints and clues are finally given to improve the IRI ion temperature model.
    Description: Published
    Description: 2186-2203
    Description: 2A. Fisica dell'alta atmosfera
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 106
    Publication Date: 2022-02-02
    Description: TITIPy (Topside Ionosphere Turbulence Indices with Python) is a stand-alone Python tool developed for the calculation and mapping of RODI, ROTI, and ROTEI indices, for the characterization of the turbulent state of the topside ionosphere. Data gathered by Langmuir Probes and Precise Orbit Determination antennas on-board ESA Swarm satellites constellation are used to calculate topside ionosphere indices with a high time rate and a global coverage. From the study of these topside indices, information on physical mechanisms involved in the formation of small-scale irregularities (both spatial and temporal) can be drawn, particularly at high and low latitudes. TITIPy provides outputs as time series of calculated indices in text files, and figures as maps in geographic and magnetic coordinates. TITIPy is particularly suited for the investigation of the topside ionosphere irregularities, and for the identification of peculiar spatial and temporal patterns. The paper describes the TITIPy design and code workflow along with a detailed explanation of RODI, ROTI, and ROTEI indices calculation. Furthermore, an example of application based on data collected during the St. Patrick 2015 geomagnetic storm is also shown. TITIPy is open-source and freely downloadable at https://github.com/pignalberi/TITIPy.
    Description: Published
    Description: 104675
    Description: 2A. Fisica dell'alta atmosfera
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 107
    Publication Date: 2022-02-14
    Description: The influence of the Atlantic multidecadal variability (AMV) on the North Atlantic storm track and eddy-driven jet in the winter season is assessed via a coordinated analysis of idealized simulations with state-of-the-art coupled models. Data used are obtained from a multimodel ensemble of AMV± experiments conducted in the framework of the Decadal Climate Prediction Project component C. These experiments are performed by nudging the surface of the Atlantic Ocean to states defined by the superimposition of observed AMV± anomalies onto the model climatology. A robust extratropical response is found in the form of a wave train extending from the Pacific to the Nordic seas. In the warm phase of the AMV compared to the cold phase, the Atlantic storm track is typically contracted and less extended poleward and the low-level jet is shifted toward the equator in the eastern Atlantic. Despite some robust features, the picture of an uncertain and model-dependent response of the Atlantic jet emerges and we demonstrate a link between model bias and the character of the jet response.
    Description: Published
    Description: 347-360
    Description: 4A. Oceanografia e clima
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 108
    Publication Date: 2021-10-13
    Description: Landslides are widespread natural phenomena that play an important role in landscape evolution and are responsible for several casualties and damages. Slope instability is linked to the combination of geological, geomorphological, and climatic factors with various triggering mechanisms; among these, seismic shaking can induce relevant changes in the landscape, leading to coseismic and post-seismic phenomena such as landslide events. The Abruzzo Region (Central Italy) is severely affected by Earthquake-Induced Landslides (EILs), linked to the geomorphological dynamics and the severe seismicity of the area. The distribution, mechanisms, and typology of landslides are strictly related to the different physiographic and geological-structural settings. This paper focuses on the realisation of an EILs susceptibility map, following a heuristic approach combined with a statistical analysis, integrated using GIS technology. This approach led to the identification of nine instability factors. These factors were analysed for the construction of thematic maps. Hence, each factor was assigned proper expert-based ranks and weights based on the critical evaluation of literature data as well as on available landslide inventories and combined in a preliminary map wherein high/low numerical values correspond to a high/low propensity of the slope to fail; furthermore, a statistical analysis of these values was performed to derive suitable susceptibility classes. Results presented herein highlight the robustness of the approach; remarkably, the applied methodology is suitable even in areas where a detailed landslide catalogue is lacking, when the same classification and weighting of available parameters is performed. The statistical analyses and the adoption of an absolute scale ranging from minimum to maximum potential values, finally, ensures the comparability of results among different study areas. Finally, this work represents a scientific and multidisciplinary tool for better defining situations that could lead to hazards (such as landslides) following an earthquake to develop sustainable territorial planning, emergency management, and loss-reduction measures.
    Description: Published
    Description: 105729
    Description: 2T. Deformazione crostale attiva
    Description: JCR Journal
    Keywords: 04.04. Geology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 109
    Publication Date: 2021-10-13
    Description: The needs of society and the emerging blue economy require access and integration of data and information for the construction of dedicated products. A “transparent and accessible ocean” is one of the key objectives of the Ocean Decade 2021–30. In this context, marine infrastructures become significant components of a global knowledge environment, enabling environmental assessment and providing the necessary data for scientifically valid actions to protect and restore ocean health, to use marine resources in a sustainable way. The data is collected, analyzed, organized, and used by people and their good use/reuse can be obtained with social practices, technological and physical agreements aimed at facilitating collaborative knowledge, decision-making, inference. The vision is a digital ocean data ecosystem made up of multiple, interoperable, and scalable components. The huge amount of data and the resulting products can drive the development of new knowledge as well as new applications and services. Predictive capabilities that derive from the digital ecosystem enable the implementation of services for real-time decision-making, multihazard warning systems, and advance marine space planning. The chapter develops following the progressive complexity and information content of products deriving from oceanic data: data cycle and data collections, data products, oceanic reanalysis. The chapter discusses the new challenges of data products and the complexity of deriving them.
    Description: Published
    Description: 197-280
    Description: 4A. Oceanografia e clima
    Keywords: 03.02. Hydrology ; 05.02. Data dissemination
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: book chapter
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  • 110
    Publication Date: 2021-11-26
    Description: Lava flows are recurring and widespread hazards that affect areas around active volcanoes, having the potential to cause significant social and economic loss. The ongoing demographic congestion around volcanoes increases the potential risk and leads to a growing demand for faster and more accurate systems to safeguard the population. The main mitigation action for slowing down and possibly diverting lava flows is the building of artificial barriers, that can limit their destructive effects and reduce losses. Here we present a Particle Swarm Optimization algorithm for the configuration of artificial barriers, in terms of location and geometric features. The goal is to minimize the lava flow impact based on the spatial distribution of exposed elements, using the physics-based MAGFLOW model to run the lava flow scenarios for each barrier configuration. Our algorithm has been tested on Etna (Italy), showing how it can effectively safeguard the threatened areas, diverting lava away from them.
    Description: Published
    Description: 105023
    Description: 6V. Pericolosità vulcanica e contributi alla stima del rischio
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 111
    Publication Date: 2021-11-25
    Description: Between 9 March and 18 May 2020, strict lockdown measures were adopted in Italy for containing the COVID-19 pandemic: in Rome, despite vehicular traffic on average was more than halved, it was not observed a evident decrease of the airborne particulate matter (PM) concentrations, as assessed by air quality data. In this study, daily PM10 filters were collected from selected automated stations operated in Rome by the regional network of air quality monitoring: their magnetic properties - including magnetic susceptibility, hysteresis parameters and FORC (first order reversal curves) diagrams - were compared during and after the lockdown, for outlining the impact of the COVID-19 measures on airborne particulate matter. In urban traffic sites, the PM10 concentrations did not significantly change after the end of the lockdown, when vehicular traffic promptly returned to its usual levels; conversely, the average volume and mass magnetic susceptibilities approximately doubled, and the linear correlation between volume magnetic susceptibility and PM10 concentration became significant, pointing out the link between PM10 concentrations and the increasing levels of traffic-related magnetic emissions. Magnetite-like minerals, attributed to non-exhaust brakes emissions, dominated the magnetic fraction of PM10 near urban traffic sites, with natural magnetic components emerging in background sites and during exogenous dusts atmospheric events. Magnetic susceptibility constituted a fast and sensitive proxy of vehicular particulate emissions: the magnetic properties can play a relevant role in the source apportionment of PM10, especially when unsignificant variations in its concentration levels may mask important changes in the traffic-related magnetic fraction. As a further hint, increasing attention should be drawn to the reduction of brake wear emissions, that are overcoming by far fuel exhausts as the main particulate pollutant in traffic contexts.
    Description: Published
    Description: 118191
    Description: 1A. Geomagnetismo e Paleomagnetismo
    Description: JCR Journal
    Keywords: Airborne particulate matter; Brakes emissions; COVID-19 lockdown; Magnetic monitoring; PM(10) filters; Urban traffic
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 112
    Publication Date: 2021-12-06
    Description: The youngest (last 1500 years) volcanic eruptions of Lipari, within the Aeolian Archipelago, produced the prominent pumice cone of Monte Pilato and the obsidian lava flows of Rocche Rosse and Forgia Vecchia, concentrated in the north-eastern sector of the island as well as highly dispersed white-coloured, fine-grained tephra layers of rhyolitic composition in terrestrial and marine settings on the regional scale. Here we describe in detail the stratigraphy of pyroclastic successions and lava flows erupted by different vents - Monte Pilato, Forgia Vecchia, Lami, and Rocche Rosse - combining field observations, sedimentological characteristics of the tephra deposits, and major and trace element compositions of the volcanic glass. All the pyroclastic materials consist of aphyric pumice lapilli and ash with a largely homogeneous rhyolitic composition. The Monte Pilato and Forgia Vecchia deposits primarily consist of highly vesicular pumice fragments and subordinate obsidian clasts, whilst Rocche Rosse and Lami are characterized by moderately vesicular juvenile fragments with a more significant fraction of obsidian. The Lami tephra also contains peculiar pumice clasts with a fibrous texture and breadcrust bombs. Stratigraphic relationships, and paleomagnetic and 14C ages of the lava and pyroclastic deposits are combined with the archaeological information and historical reports, enabling us to provide an accurate chrono-stratigraphic framework for the youngest eruptions of Lipari. Following the 8th century CE eruption of Monte Pilato, which produced a pumice cone and a obsidian lava flow, activity resumed in the second half of 13th century CE with the explosive eruption of Forgia Vecchia that culminated in the emission of a bilobate obsidian lava flow. This eruption was shortly followed by the explosive eruptions of Lami and Rocche Rosse, the latter concluded with the emission of the widely renowned obsidian lava flow. By integrating stratigraphy and geochemistry of tephra deposits with a new chronological scheme, our work facilitates the refinement of proximal-to-distal correlation of Lipari's rhyolitic tephra in continental marine environments of the central Mediterranean area in the last 1500 years. A fine-grained, rhyolitic ash found on Stromboli (~40 km NE from Lipari) has an origin from the Monte Pilato and thus, constrains tephra dispersion towards the NE. Very similar ash beds dispersed southwards and interlayered within the near-source deposits of La Fossa, Vulcano island (~10 km from Lipari) exhibit features that are consistent with the younger activities of the Rocche Rosse eruption. A possible link between previously identified rhyolitic ash layers identified in marine cores of the Ionian Sea and the Forgia Vecchia eruption are postulated, although the age and textural characteristics of these distal tephra are not univocal in indicating a correlation to either Monte Pilato or Forgia Vecchia.
    Description: Published
    Description: 107397
    Description: 1A. Geomagnetismo e Paleomagnetismo
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 113
    Publication Date: 2021-11-26
    Description: Volcanic gas dispersal can be a serious threat to people living near active volcanoes since it can have short- and long-term effects on human health, and severely damage crops and agricultural land. In recent decades, reliable computational models have significantly advanced, and now they may represent a valuable tool to make quan- titative and testable predictions, supporting gas dispersal forecasting and hazard assessments for public safety. Before applying a specific modelling tool into hazard quantification, its calibration and its sensitivity to initial and boundary conditions should be carefully tested against available data, in order to produce unbiased hazard quantifications. In this study, we provided a number of prototypical tests aimed to validate the modelling of gas dispersal from a hazard perspective. The tests were carried out at La Soufrière de Guadeloupe volcano, one of the most active gas emitters in the Lesser Antilles. La Soufrière de Guadeloupe has shown quasi-permanent degassing of a low-temperature hydrothermal nature since its last magmatic eruption in 1530 CE, when the current dome was emplaced. We focused on the distribu- tion of CO2 and H2S discharged from the three main present-day fumarolic sources at the summit, using the mea- surements of continuous gas concentrations collected in the period March–April 2017. We developed a new probabilistic implementation of the Eulerian code DISGAS-2.0 for passive gas dispersion coupled with the mass-consistent Diagnostic Wind Model, using local wind measurements and atmospheric stability information from a local meteorological station and ERA5 reanalysis data. We found that model outputs were not significantly affected by the type of wind data but rather upon the relative positions of fumaroles and measurement stations. Our results reproduced the statistical variability in daily averages of observed data over the investigated period within acceptable ranges, indicating the potential usefulness of DISGAS-2.0 as a tool for reproducing the observed fumarolic degassing and for quantifying gas hazard at La Soufrière. The adopted testing procedure allows for an aware application of simulation tools for quantifying the hazard, and thus we think that this kind of testing should actually be the first logical step to be taken when applying a simulator to assess (gas) hazard in any other volcanic contexts.
    Description: Published
    Description: 107312
    Description: 6V. Pericolosità vulcanica e contributi alla stima del rischio
    Description: JCR Journal
    Keywords: Passive gas dispersion ; Numerical modelling ; ERA5 reanalysis ; Mass consistent wind model ; La Soufrière de Guadeloupe
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 114
    Publication Date: 2021-11-29
    Description: In this work, we propose a wavelet-based filtering for soil CO2 flux time series. The filter relies on the detection of the periodic components achieved by means of the long-term time-frequency characterization of the time series. For this purpose, we exploited the vast data set coming from the monitoring network installed at Mt. Etna volcano (Italy). The network provides hourly measure of CO2 flux together with the measure of the climatic variables. These data allow to investigate the relationships between CO2 time series and the potentially influencing meteorological factors. This has been assessed calculating the wavelet coherence between CO2 time series against air temperatures, atmospheric pressure, and relative humidity in all the sites where these information were available. Results highlight the occurrence of marked cycles at about ∼1 year for the most of the sites while shorter cycles occur only at some sites. From these cycles a periodic signal can be calculated, and therefore opportunely removed from the time CO2 series to enhance the volcano-related anomalies. We found also common cycles among CO2 and the climatic variables, which synchronicity is constant over time but it is site-specific. Starting from this consideration, we calculated a reference signal for CO2 combining analytically the temperature, the pressure, and the humidity cycles: this model of the climatic effect has been used to predict the seasonal trend of the CO2 output.
    Description: Published
    Description: 107421
    Description: 1IT. Reti di monitoraggio e sorveglianza
    Description: JCR Journal
    Keywords: Soil CO2 ; Continuous wavelet transform ; Spectral analysis ; Etna
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 115
    Publication Date: 2021-12-14
    Description: Seismic stations are usually used to record seismic event and, therefore, they are recommended to be installed far from railways and traffic roads in order to avoid the superposition of ambient noise signals to those provoked by an earthquake. In this paper, instead, seismic stations, placed intentionally in areas near railway and traffic roads, are used to characterize the subsoil spectral properties and to assess the effect of vibrations due to trains and vehicles. A cemetery in the green countryside near Florence is chosen as a reference case study to deal with this topic. Most of the buildings in the cemetery area are affected by an extensive crack pattern. In January 2020 five seismic stations were installed in order to evaluate if the trains running in the tunnels of the regional and high-speed railway lines located below and in the vicinity of the cemetery and the vehicles traveling on the nearby A1 highway and regional road can produce vibrations in the ground that justify the observed damage pattern. Collected data are analyzed using the Nakamura technique in order to estimate the dynamic properties of the ground and compared to the limits provided by the current regulations. Furthermore, the trend of the Root Mean Square average over the entire recording period is computed as well. From the obtained results, it is possible to highlight that the average daily oscillation level increases from early morning until 7 p.m. and then it decreases, and also that the highest am­ plitudes of transients are concentrated in the late evening and during the night, when the background noise is lower. Furthermore, the computed values of the maximum and average amplitudes are lower than those that can cause damage to buildings as defined by the guidelines, the eigenfrequency of the ground falls in a range far from that ascribable to the cemetery buildings, so that the resonance effects can be excluded. In order to confirm these results, the amplitude of ground shaking due to recorded transients is compared to that produced by two earthquakes (a 3.4 Mw local earthquake at more than 100 km and a Mw 6.6 teleseism from Turkey) which occurred during the monitoring period. One can conclude that it seems unlikely that the shaking produced by nearby vehicles and trains could be responsible for the observed damage.
    Description: The study was partially funded by the Municipality of Figline-Incisa Valdarno.
    Description: Published
    Description: e00623
    Description: 5T. Sismologia, geofisica e geologia per l'ingegneria sismica
    Description: JCR Journal
    Keywords: Ambient vibrations ; Soil amplification
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 116
    Publication Date: 2021-12-23
    Description: The eruptive activity of a volcano modifies its surface topography through morphological changes generated by the deposition of emitted volcanic material and resulting gravity-driven processes,which can form accumulation of material in addition to the most common erosional phenomena. Mapping and quantifying such morphological changes allow to derive new data useful to better describe and understand the eruptive history of the volcano itself. Nowadays, one of the mostly used method to identify such morphological changes consists of comparing Digital Elevation Models (DEM) of the volcanic area before and after an eruptive event. If the eruptive event is referred to periods prior to 1980's, the only method to reproduce DEMs consists of elaborating the historical cartography that is often available only in paper format. In thisworkwe aimto prove the reliability of this approach, presenting a study on the morphological changes (from 1876 to 1944) of the summit caldera of the Somma–Vesuvio volcano (Italy). For the first time, we compare DEMs derived from historical maps (1876, 1906 and1929) and a DEM dated 2012 obtained by remote sensing. The four models of the caldera, digitally reproducedat the same spatial resolution, are morphologically investigated through specific maps derived from the DEMs and a set of height profiles. In addition, further morphometric analyses and accurate quantifications in volume and surface are presented and discussed for a portion of the Somma-Vesuvio summit caldera, represented by the Gran Cono edifice. Considering the different typology of the source data used in this study, it is also provided a discussion on the respective accuracies that, especially for the historical maps, represent a crucial point for obtaining DEMs able to reproduce topographies more realistic as possible. For this reason, despite data source were processed following rigours criteria, the calculations of volume, surface and distance related to the morphological changes of the volcano are associated to an accurate quantification of the error. Following this, the main results obtained in this study are: i) the identification of several past volcanic deposits and the estimation of the related thicknesses, both in good agreement with published literature; ii) the quantification of the morphological changes of theGran Cono from 1876 to 1944 resulting in a volume and surface growth of 133 ×106m3(±5%) and ~0.14 km2, respectively; iii) the identification of a possible migration path of the centroid of the Gran Cono crater along the SW-NE preferential direction during the investigated period.
    Description: Published
    Description: 107624
    Description: 6V. Pericolosità vulcanica e contributi alla stima del rischio
    Description: JCR Journal
    Keywords: Digital Elevation Model, Historical cartography,Airborne Laser Scanning technology, Somma-Vesuvio volcano, Morphological changes quantifications
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 117
    Publication Date: 2022-02-11
    Description: Prior to the 2018 lower East Rift Zone (ERZ) eruption and summit collapse of Kīlauea Volcano, Hawai‘i, continuous gravimeters operated on the vent rims of ongoing eruptions at both the summit and Pu‘u ‘Ō‘ō. These instruments captured the onset of the 2018 lower ERZ eruption and the effects of lava withdrawal from both locales, providing constraints on the timing and style of activity and the physical properties of the lava lakes at both locations. At the summit, combining gravity, lava level, and a three-dimensional model of the vent indicates that the upper ∼200 m of the lava lake had a density of about 1700 kg m−3, slightly greater than estimates from 2011–2015 and possibly indicating a gradual densification over time. At Pu‘u ‘Ō‘ō, gravity and vent geometry were used to model both the density and the rate of crater collapse, which was unknown owing to a lack of visual observations. Results suggest the withdrawal of at least m3 of lava over the course of two hours, and a material density of 1800–1900 kg m−3. In addition, gravity data at Pu‘u ‘Ō‘ō captured a transient decrease and increase about an hour prior to crater collapse and that was probably related to a small, short-lived fissure eruption on the west flank of the cone and possibly to dike intrusion beneath Pu‘u ‘Ō‘ō. The fissure was the first event in the subsequent cascade that ultimately led to the extrusion of over 1 km3 of lava from lower ERZ vents, collapse of the summit caldera floor by more than 500 m, and the destruction of over 700 homes and other structures. These results emphasize the importance of continuous gravity in operational monitoring of active volcanoes.
    Description: Published
    Description: 117003
    Description: 4V. Processi pre-eruttivi
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 118
    Publication Date: 2022-02-11
    Description: Extensive geophysical and geodetic measurements were carried out to evaluate the groundwater aquifer, trace the basement relief, as well as detect the igneous intrusions and structural elements (mainly faults) that affect the occurrence of groundwater in the study area. The fieldwork included resistivity sounding, a geomagnetic survey, and Global Positioning System measurements. The magnetic results showed the presence of a group of main faults in East-west trend at the western part of the area and major fault at the northern part of the area of NW-SW trend. The findings also showed the presence of two igneous rock intrusions located in the middle of the eastern part of the valley. Pronounced differences in the depths of basement rocks have been identified, ranging between 0 and 900 m from the surface. Both high horizontal movements and high shear strain rates have been found to be concentrated at the southeast of the study area and it was noted that high stress was accumulated along the main observed faults and at the main groundwater aquifers. The geoelectrical results confirmed the presence of two aquifers; a shallow aquifer (Quaternary aquifer) that narrows northwards and a Nubian sandstone aquifer, which considered the main aquifer. The Nubian sandstone aquifer carries groundwater in the region, which overlies the last geoelectric unit represented by the basement complex layer and geological structures affecting the potential availability of groundwater in the study area, as proved by the geomagnetic survey and stress accumulation.
    Description: Researchers Supporting Project number (RSP-2021/351), King Saud University, Riyadh, Saudi Arabia
    Description: Published
    Description: 101549
    Description: 2T. Deformazione crostale attiva
    Description: JCR Journal
    Keywords: GPS ; stress ; strain ; geomagnetic ; geoelectric ; groundwater ; 04. Solid Earth
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 119
    Publication Date: 2022-02-11
    Description: This work describes the data used in the EPSL research article "Quantifying strong seismic propagation effects in the upper volcanic edifice using sensitivity kernels". The dataset is generated in order to investigate to what extent the seismic signals recorded on volcanoes are affected by near surface velocity structure. Data were calculated using the computational spectral elements scheme SPECFEM2D, where the wave propagation beneath Mount Etna volcano, Italy, was simulated in both homogeneous and heterogeneous models. The heterogeneous model comprises a low-velocity superficial structure (top several hundred meters) based on the previously published studies. Several different source mechanisms and locations were used in the simulations. The seismic wavefield was "recorded" by 15 surface receivers distributed along the surface of the volcano. The associated sensitivity kernels were also computed. These kernels highlight the region of the velocity model that affects the recorded seismogram within a desired time window. The text files describing the velocity models used in the simulations are also provided. The data may be of interest to volcano seismologists, as well as earthquake seismologists studying path effects and wave propagation through complex media.
    Description: European Union Seventh Framework Programme (FP7/2007 2013) under the project NEMOH, grand agreement no. 289976.
    Description: Published
    Description: 106673
    Description: 4V. Processi pre-eruttivi
    Description: JCR Journal
    Keywords: Near surface velocity structure; Numerical simulations; Sensitivity kernels; Specfem2d; Volcanic edifice; Volcano seismic sources
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 120
    Publication Date: 2022-02-11
    Description: In volcanic environments, the correct interpretation of the signals recorded by a seismic station is critical for a determination of the internal state of the volcano. Those signals contain information about both the seismic source and the properties of the path travelled by the seismic wave. Therefore, understanding the path effect is necessary for both source inversions and geophysical investigation of the volcanoes' properties at depth. We present an application of the seismic adjoint methodology and sensitivity kernel analysis to investigate seismic wave propagation effects in the upper volcanic edifice. We do this by performing systematic numerical simulations to calculate synthetic seismograms in two-dimensional models of Mount Etna, Italy, considering different wave velocity properties. We investigate the relationship between different portions of a seismogram and different parts of the structural volcano model. In particular, we examine the influence of known near-surface low-velocity volcanic structure on the recorded seismic signals. Results improve our ability to understand path effects highlighting the importance of the shallowest velocity structure in shaping the recorded seismograms and support recent studies that show that, although long-period seismic events are commonly associated with magma movements in resonant conduits, these events can be reproduced without the presence of fluids. We conclude that edifice heterogeneities impart key signatures on volcano seismic traces that must be considered when investigating volcano seismic sources.
    Description: Published
    Description: 116683
    Description: 4V. Processi pre-eruttivi
    Description: JCR Journal
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  • 121
    Publication Date: 2022-02-14
    Description: High-elevation plateaus that are positioned in between topographic barriers are common orogenic features in the South American continent, formed under a range of evolving environmental conditions. For example, in the central Andes (Bolivia-Argentina), the Puna-Altiplano is arid and endorheic with a poorly developed fluvial system, while in the northern Andes (Colombia) the Chiquinquirà and Tunja highlands are characterized by a humid equatorial exorheic fluvial system. In addition to a plateau-like low-relief surface at 2500 m, the landscape of the northern Eastern Cordillera and SantanderMassif (northern Colombia) displays a lower elevation (~1500m) low-relief landscape (Mesas) comprising river captures, windgaps, and a disconnected alluvial fan that collectively record a transient state. This configuration has been achieved through a combination of compressive deformation and sub-crustal processes. The compressive shortening started to occur in the Paleogene and is still active, whereas regional surface uplift related to slab flattening andmantlewedge hydration startedintheLateMiocene/Pliocene.To disentangle the crustal vs sub-crustal forcing and to investigate the relative timing of drainage network evolutionwe combine the analysis of topography, hydrography (river longitudinal profiles, morphometric parameters, drainage divide stability), knickpoint migration (celerity model), paleo-longitudinal profile modeling, satellite images, and field observations. In particular, we show that during the development of the low-relief Mesas landscape the older Chiquinquirà highland was a closed drainage and that the lower portion of the Suárez River flowed northward into the Bucaramanga depression forced by the Los Cobardes Anticline topographic barrier. The Suárez River collected waters from the southern SantanderMassif and the upper reach of the Chicamocha River, which was draining the Tunja highland. An abandoned windgap deposit on the eastern edge of the Mesa de Barichara suggests that the lower portion of the Chicamocha Riverwas not yet formed. Subsequent to the Chiquinquirà highland drainage opening, two main tributaries of the Magdalena River, the Lebrija and Sogamoso, captured the Suárez River in a short temporal sequence. A knickpoint celerity model allows us to date the Lebrija capture of the Bucaramanga depression at ~260–270 ka and the subsequent Sogamoso capture at 190–220 ka. Only during this final stage, the lowermost Chicamocha River section formed and the drainage network developed to its present configuration. Finally,we suggest that the early Cenozoic rift inversion has controlled the drainage network pattern and the late Miocene sub-crustal-induced surface uplift has driven the main fluvial network reorganization.
    Description: Published
    Description: 107847
    Description: 2T. Deformazione crostale attiva
    Description: JCR Journal
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  • 122
    Publication Date: 2022-02-11
    Description: The evolution of volcanic activity observed at the New South East Crater (NSEC) and Voragine (VOR) between July 2019 and January 2020 has been deciphered by taking into account the changes of textures and chemical zoning of plagioclase and olivine crystals from the erupted lavas and tephra. The petrological observations have been integrated with analyses of the amplitude and source location of volcanic tremor and infrasound data. Characteristics of crystals erupted on July 2019 at the NSEC reflect protracted intrusions of magma into the mid-upper section of the plumbing system, approximately within 290–120 MPa, which acted as the main zone of magma accumulation and crystallization before the beginning of the eruptive activity. Textures and compositions of crystals erupted at VOR emphasize the beginning of volcanic activity driven by recharge/discharge phases that mostly affect the shallowest portion of the Mt. Etna plumbing system (〈40 MPa). At the end of 2019, mineral compositions and zoning patterns changed again in accordance with eruption dynamics. The observed changes reflect the transition from an early phase, between November and December 2019, characterized by substantial equilibrium during magma storage and transport toward higher disequilibrium conditions and eruptive frequency, in January 2020. This has been associated to episodes of deep replenishment of mafic magmas displacing the resident one. Diffusion chronometry applied to zoned olivines shows that most of the episodes of magma intrusion correlate temporally with changes in the features of both volcanic tremor and infrasonic events in terms of amplitude and source location, providing evidence that such geophysical signals are directly related to the magma dynamics in the upper plumbing system.
    Description: Published
    Description: 107350
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Description: JCR Journal
    Keywords: 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 123
    Publication Date: 2022-02-14
    Description: Shallow water equations are widely used in the simulation of those geophysical flows for which the flow horizontal length scale is much greater than the vertical one. Inspired by the example of lava flows, we consider here a modified model with an additional transport equation for a scalar quantity (e.g., temperature), and the derivation of the shallow water equations from depth-averaging the Navier-Stokes equations is presented. The assumption of constant vertical profiles for some of the model variables is relaxed allowing the presence of vertical profiles, and it follows that the non-linearity of the flux terms results in the introduction of appropriate shape coefficients. The space discretization of the resulting system of hyperbolic partial differential equations is obtained with a modified version of the finite volume central-upwind scheme introduced by Kurganov and Petrova in 2007. The time discretization is based on an implicit-explicit Runge-Kutta method which couples properly the hyperbolic part and the stiff source terms, avoiding the use of a very small time step; the use of complex arithmetic increases accuracy in the implicit treatment of stiff terms. The whole scheme is proved to preserve the positivity of flow thickness and the stationary steady-states. Some numerical experiments are performed to validate the proposed method and to show the incidence on the numerical solutions of shape coefficients introduced in the model.
    Description: Published
    Description: 482-505
    Description: 5V. Processi eruttivi e post-eruttivi
    Description: JCR Journal
    Keywords: Shallow water equations ; Viscous fluids ; Finite Volume ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 124
    Publication Date: 2022-02-11
    Description: In this work, a partitioned fluid-structure interaction solver is presented. Fluid flow problem is solved with time-discontinuous deforming domain stabilized space-time finite element method. Flow is computed with pressure primitive variables which permit to use the same numerical technique for both compressible and incompressible regimes. Elastic deformation of the structure is modelled in the Lagrangian frame of reference with Saint-Venant Kirchhoff and Neo-Hookean material models - both are non-linear and valid for large deformations. Structure equations are discretized with Galerkin finite element method for space and with generalized-alpha method for the time. Mesh motion is modelled with the elastic deformation method. An implicit algorithm is presented to couple the different solvers. The details are provided on the implementation of the solvers in parallel software. The numerical code is verified and validated on several compressible and incompressible flow benchmarks widely used in the literature. The results demonstrate that the developed solver successfully detects the accurate interaction between fluid and structure.
    Description: Published
    Description: 182-195
    Description: 4V. Processi pre-eruttivi
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 125
    Publication Date: 2022-02-11
    Description: The Tolhuaca hydrothermal system is one of the few attested geothermal resources in Chile. While recent investigations provided some insights into the depth and temperature of the geothermal reservoirs and the chemical and mineralogical evolution of the hydrothermal system, little is still known about the CO2 degassing of the system and the local and shallow control of fluid pathways. Here, we document the soil CO2 degassing and soil temperature distributions in the southern part of the Tolhuaca hydrothermal system and at one of its northern fumaroles, and provide a first estimate of its total CO2 release. The surveyed area is responsible for a total CO2 emission of up to 30 t d-1. Hydrothermal CO2 emissions (~ 4-27 t d-1) are mostly restricted to the thermal manifestations or generally distributed along NNW trending lineaments, sharing the same orientation as the volcanic vents and thermal springs and fumaroles. Hydrothermal CO2 fluxes, fumaroles and thermal springs are generally encountered in topographic lows, in close vicinity of streams and often in clay-rich pyroclastic units, highlighting a relation between landscape evolution and the activity of the hydrothermal system. We suggest that glacial unloading and incision of the stream inside the clay-rich units have likely enhanced locally the permeability, creating a preferential pathway for the migration of deeper fluid to the surface. As several hydrothermal systems in the Andes are found on the flank of volcanoes hosting glaciers, we propose that they could have had a similar development to that of the Tolhuaca hydrothermal system.
    Description: Published
    Description: 107316
    Description: 4V. Processi pre-eruttivi
    Description: JCR Journal
    Keywords: CO2 emission ; Tolhuaca volcano
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 126
    Publication Date: 2022-02-14
    Description: Exposure to styrene is a major safety concern in the fibreglass processing industry. This compound is classified by the International Agency for Research on Cancer as a possible human carcinogen. Several types of analytical equipment exist for detecting volatile organic compounds (VOCs) in the atmosphere; however, most of them operate ex-situ or do not provide easy discrimination between different molecules. This work introduces an improved and portable method based on FTIR spectroscopy to analyse toxic gaseous substances in working sites down to a concentration of less than 4 ppm. Styrene and a combination of VOCs typically associated with it in industrial processes, such as acetone, ethanol, xylene and isopropanol, have been used to calibrate and test the methodology. The results demonstrate that the technique offers the possibility to discriminate between different gaseous compounds in the atmosphere with a high degree of confidence and obtain very accurate quantitative information on their concentration, down to the ppm level, even when different VOCs are present in a mixture.
    Description: Published
    Description: 122510
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Keywords: Environmental sensors; Infrared spectroscopy; Volatile organic compounds
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 127
    Publication Date: 2022-02-14
    Description: This paper deals with the first geochemical data from an unexplored sector of the Cordón de Inacaliri Volcanic Complex (Central Andes, Chile). The site is located at ∼5,150-5,200 m a.s.l., inside the Pabelloncito graben where, at about 9 km NW of the studied area, the only currently working geothermal power plant of South America, named Cerro Pabellón, occurs. Diffuse soil CO2 and soil temperature measurements were carried out to unravel the structural control on the rising fluids and estimate the total CO2 output, the heat flow rate and the heat flux, aimed at assessing a preliminary evaluation of the geothermal potential of the area. The study area is characterized by a pervasive hydrothermal mineralogical alteration, CO2 flux values of up to ∼4,400 g m-2 d-1 and soil temperatures up to the boiling point of water at that altitude. All these features are likely related to an endogenous source. Spatial distribution of both soil CO2 flux and temperature depict an ENE-striking lineament, whose intersection with the NW-striking Pabelloncito graben forms a favourable structural setting for the discharge of hydrothermal fluids. The total CO2 output emission of the studied area (∼0.0179 km2) was ∼0.53 t d-1, with an associated discharge of steam of 6.45 t d-1 (CO2/H2O ratio = 0.08). An electric capacity potential of 1.08 MWe km-2 was computed from the heat flow rate and heat flux values. Our results suggest that this part of the Pabelloncito graben is an interesting geothermal prospect and a good candidate for further exploration studies.
    Description: Published
    Description: 101961
    Description: 1TR. Georisorse
    Description: JCR Journal
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  • 128
    Publication Date: 2022-02-11
    Description: Grooves represent the evidence of tectonic activity that deformed Ganymede surface during its geologic evolution. In this work, we investigate the main characteristics of Ganymede's groove populations on four different areas located at the equatorial region of the satellite (Uruk Sulcus, Babylon Sulci, Phrygia Sulcus and Mysia Sulci). Specifically, we analyse i) the grooves length distribution to provide a framework for their evolution and ii) the grooves self-similar clustering to infer their vertical penetration inside Ganymede icy shell. For each dataset, we find that the grooves distribution is well fitted by an exponential-law and a power-law distribution depending on the structure length. This implies the presence of confined structures in a shallow layer of the icy crust (relatively shorter, exponentially-fitted structures) and crustal-scale structures that could theoretically reach the crust-ocean interface (relatively longer, power law-fitted structures). In addition, the existence of two exponential distributions for few datasets suggest that there could be two different system of structure confined within specific mechanical crust layers. The thickness of the penetrated icy shell is retrieved through the self-similar clustering analysis and ranges between 105 and 130 km for the examined datasets. This value agrees with independent estimates of the icy shell thickness, ranging between 80 and 150 km. Moreover, our results support the hypothesis that a large number of grooves penetrate the brittle icy crust, with sets of fractures vertically confined in different mechanical layers, while the penetration of few interconnected faults underlying longer grooves may interest the whole icy crust above the liquid ocean.
    Description: Published
    Description: 105140
    Description: 1T. Struttura della Terra
    Description: JCR Journal
    Keywords: GALILEAN SATELLITES ; DARK TERRAIN ; FAULT EVOLUTION ; TECTONICS ; PATTERNS GEOMETRY ; JUPITER
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 129
    Publication Date: 2022-10-26
    Description: © The Author(s), 2021. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Schwestermann, T., Eglinton, T., I., Haghipour, N., McNichol, A. P., Ikehara, K., & Strasser, M. Event-dominated transport, provenance, and burial of organic carbon in the Japan Trench. Earth and Planetary Science Letters, 563, (2021): 116870, https://doi.org/10.1016/j.epsl.2021.116870.
    Description: The delivery of organic carbon (OC) to the ocean's deepest trenches in the hadal zone is poorly understood, but may be important for the carbon cycle, contain crucial information on sediment provenance and event-related transport processes, and provide age constraints on stratigraphic sequences in this terminal sink. In this study, we systematically characterize bulk organic matter (OM) and OC signatures (TOC/TN, C, 14C), as well as those from application of serial thermal oxidation (ramped pyrolysis/oxidation) of sediment cores recovered along an entire hadal trench encompassing high stratigraphic resolution records spanning nearly 2000 years of deposition. We analyze two cores from the southern and northern Japan Trench, where submarine canyon systems link shelf with trench. We compare results with previously published data from the central Japan Trench, where canyon systems are absent. Our analyses enable refined dating of the stratigraphic record and indicate that event deposits arise from remobilization of relatively surficial sediment coupled with deeper erosion along turbidity current pathways in the southern and central study site and from canyon flushing events in the northern study site. Furthermore, our findings indicate deposition of predominantly marine OC within hemipelagic background sediment as well as associated with event deposits along the entire trench axis. This implies that canyon systems flanking the Japan Trench do not serve as a short-circuit for injection of terrestrial OC to the hadal zone, and that tropical cyclones are not major agents for sediment and carbon transfer into this trench system. These findings further support previous Japan Trench studies interpreting that event deposits originate from the landward trench slope and are earthquake-triggered. The very low terrestrial OC input into the Japan Trench can be explained by the significant distance between trench and hinterland (〉180 km), and the physiography of the canyons that do not connect to coast and river systems. We suggest that detailed analyzes of long sedimentary records are essential to understand OC transfer, deposition and burial in hadal trenches.
    Description: The cruise was supported by the German Bundesministerium für Bildung und Forschung (BMBF 03G0251A) and the Deutsche Forschungsgemeinschaft. We acknowledge the Kochi core repository for additional surface samples of Japanese Cruises. Al Gagnon and Mary Lardie are thanked for their great help and technical assistance with the RPO instrument at NOSAMS. APM and the NOSAMS work were supported by the National Science Foundation Cooperative Agreement OCE-1239667. We appreciate the assistance from members of the Laboratory of Ion Beam Physics for the AMS measurements. Rui Bao is acknowledged for helpful discussions. A special thank you goes to Madalina Jaggi for her technical assistance for the C analysis of rinsed samples. This study was supported by the Austrian Science Fund (FWF P29678-N28) and a postgraduate grant by the International Association of Sedimentologists (IAS). We also acknowledge constructive support by the two reviewers (Jordon Hemingway and an anonymous). The authors declare no conflict of interests. The bathymetric data used in figure 1 is available at JAMSTEC-DARWIN database (http://www.godac.jamstec.go.jp/darwin/e) and Bundesamt für Seeschifffahrt und Hydrographie (https://www.bsh.de/DE/DATEN/Ozeanographisches_Datenzentrum/Vermessungsdaten/Nordpazifischer_Ozean/nordpazifik_node.html). Data of carbon analyses are displayed in the supporting information and also available from the corresponding author on reasonable request.
    Keywords: Carbon isotopes ; Carbon provenance ; Hadal zone event-stratigraphy ; Carbon transfer ; Japan Trench ; Ramped Pyr/Ox
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  • 130
    Publication Date: 2022-10-26
    Description: © The Author(s), 2020. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Gu, S., Liu, Z., Oppo, D. W., Lynch-Stieglitz, J., Jahn, A., Zhang, J., & Wu, L. Assessing the potential capability of reconstructing glacial Atlantic water masses and AMOC using multiple proxies in CESM. Earth and Planetary Science Letters, 541, (2020): 11629, doi:10.1016/j.epsl.2020.116294.
    Description: Reconstructing the Atlantic Meridional Overturning Circulation (AMOC) during the Last Glacial Maximum (LGM) is essential for understanding glacial-interglacial climate change and the carbon cycle. However, despite many previous studies, uncertainties remain regarding the glacial water mass distributions in the Atlantic and the AMOC intensity. Here we use an isotope enabled ocean model with multiple geotracers (δ 13 C,E Νd,231 Pa/ 230Th,δ 18 Ο and Δ 14 C) and idealized water tracers to study the potential constraints on LGM ocean circulation from multiple proxies. Our model suggests that the glacial Atlantic water mass distribution can be accurately constrained by the air-sea gas exchange signature of water masses (δ13 C AS), but E Nd might overestimate the North Atlantic Deep Water (NADW) percentage in the deep Atlantic probably because of the boundary source of Nd. A sensitivity experiment with an AMOC of similar geometry but much weaker strength suggests that the correct AMOC geometry is more important than the AMOC strength for simulating the observed glacial δ13 C AS and E Nd and distributions. The kinematic tracer 231Pa/230Th is sensitive to AMOC intensity, but the interpretation might be complicated by the AMOC geometry and AABW transport changes during the LGM. δ 18 Ο in the benthic foraminifera (δ 18 Οc) from the Florida Straits provides a consistent measure of the upper ocean boundary current in the model, which potentially provides an unambiguous method to reconstruct glacial AMOC intensity. Finally, we propose that the moderate difference between AMOC intensity at LGM and PD, if any, is caused by the competition of the responses to CO2 forcing and continental ice sheet forcing.
    Description: We thank two anonymous reviewers for their useful and constructive comments. We also thank Editor Dr Laura F. Robinson for handling the manuscript. This work is supported by National Science Foundation of China No. 41630527, US National Science Foundation (NSF) P2C2 projects (1401778, 1401802, and 1566432). We would like to acknowledge the high-performance computing support from Yellowstone (ark:/85065/d7wd3xhc) and Cheyenne (doi:10.5065/D6RX99HX) provided by NCAR's Computational and Information Systems Laboratory, sponsored by the National Science Foundation and from Center for High Performance Computing and System Simulation, Pilot National Laboratory for Marine Science and Technology (Qingdao). Data used to produce the results in this study can be obtained from HPSS at CISL: /home/sgu28/CTRACE_decadal or by contacting the authors.
    Keywords: Last Glacial Maximum ; AMOC ; Water mass ; Multi-proxy
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  • 131
    Publication Date: 2022-10-26
    Description: © The Author(s), 2021. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Elling, F. J., Hemingway, J. D., Kharbush, J. J., Becker, K. W., Polik, C. A., & Pearson, A. Linking diatom-diazotroph symbioses to nitrogen cycle perturbations and deep-water anoxia: insights from Mediterranean sapropel events. Earth and Planetary Science Letters, 571, (2021): 117110, https://doi.org/10.1016/j.epsl.2021.117110.
    Description: Elevated organic matter (OM) export flux promotes marine anoxia, thus increasing carbon sequestration efficiency and decreasing atmospheric carbon dioxide levels. However, the mechanisms that trigger and sustain anoxic events—particularly those associated with nutrient-poor, oligotrophic surface waters—remain poorly constrained. Mediterranean Sea sapropels are well-preserved sediments deposited during episodic anoxic events throughout the Plio-Pleistocene; as such, they may provide unique insight into the biogeochemical and ecological drivers of—and responses to—marine anoxia. Using biomarker distributions, we demonstrate that anaerobic ammonium oxidizing (anammox) bacteria and diazotrophic endosymbionts of mat- and/or raft-forming diatoms were both abundant during sapropel events, particularly in the Ionian and Libyan seas. In these sapropels, the carbon isotope compositions of anammox biomarkers directly capture progressive 13C-depletion in deep-water dissolved inorganic carbon, indicating sustained carbon sequestration. To explain these observations, we propose a reinforcing feedback whereby initial nutrient and/or circulation perturbations promote fixed nitrogen loss via intensified anammox and heterotrophic denitrification, which in turn favors proliferation of rapidly sinking diatom-diazotroph symbiotic consortia, increases OM burial flux, and sustains anoxia. This mechanism resolves the long-standing conundrum that small and buoyant diazotrophs are apparently associated with high OM export during periods of marine anoxia and oligotrophy.
    Description: This work was funded through the Gordon and Betty Moore Foundation and US National Science Foundation grants 1843285, 1702262 and 1349126 (to A.P.). Additional financial support was provided by the Postdoctoral Program at the Woods Hole Oceanographic Institution and U.S. Geological Survey (K.W.B.).
    Keywords: Nammox ; Anoxia ; Compound-specific, δ13, C ; Diatom-diazotroph symbioses ; N2-fixation ; Mediterranean sapropels
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  • 132
    Publication Date: 2022-10-26
    Description: © The Author(s), 2022. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Zhang, F., Lin, J., Zhou, Z., Yang, H., & Morgan, J. P. Mechanism of progressive broad deformation from oceanic transform valley to off-transform faulting and rifting. Innovation, 3(1), (2022): 100193, https://doi.org/10.1016/j.xinn.2021.100193.
    Description: Oceanic transform faults (TFs) are commonly viewed as single, narrow strike-slip seismic faults that offset two mid-ocean ridge segments. However, broad zones of complex deformation are ubiquitous at TFs. Here, we propose a new conceptual model for the progressive deformation within broad zones at oceanic TFs through detailed morphological, seismic, and stress analyses. We argue that, under across-transform extension due to a change in plate motion, plate deformation occurs first along high-angle transtensional faults (TTFs) within the transform valleys. Off-transform normal faults (ONFs) form when across-transform deviatoric extensional stresses exceed the yield strength of the adjacent oceanic lithosphere. With further extension, these normal faults can develop into off-transform rift zones (ORZs), some of which can further develop into transform plate boundaries. We illustrate that such progressive complex deformation is an inherent feature of oceanic TFs. The new conceptual model provides a unifying theory to explain the observed broad deformation at global transform systems.
    Description: We benefited from discussions with Drs. Tao Zhang, Huihui Weng, Yen Joe Tan, the SCSIO Deep Ocean Geodynamics Group, the CUHK Seismology Group, and the participants of the InterRidge transform fault workshop in France, 2018. This work was supported by the Southern Marine Science and Engineering Guangdong Laboratory (Guangzhou) (GML2019ZD0205), NSFC grants (41976064, 41890813, 41976066, 91628301, and 91858207), CAS grants (Y4SL021001, QYZDY-SSW-DQC005, 133244KYSB20180029, 131551KYSB20200021, and ISEE2021PY03), National Key R&D Program of China grants (2018YFC0309800 and 2018YFC0310105), the Guangdong Basic and Applied Basic Research Foundation (2021A1515012227), and Hong Kong Research Grant Council grants (14304820 and 14306119).
    Keywords: Transform fault deformation ; Off-transform faulting and rifting ; Plate rotation ; Transtensional fault ; Ridge-transform interaction
    Repository Name: Woods Hole Open Access Server
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  • 133
    Publication Date: 2022-10-28
    Description: Katla is a threatening volcano in Iceland, partly covered by the M\'yrdalsj\"okull ice cap. The volcano has a large caldera with several active geothermal areas. A peculiar cluster of long-period seismic events started on Katla's south flank in July 2011, during an unrest episode in the caldera that culminated in a glacier outburst. The seismic events were tightly clustered at shallow depth in the Gvendarfell area, 4 km south of the caldera, under a small glacier stream on the southern margin of M\'yrdalsj\"okull. No seismic events were known to have occurred in this area before. The most striking feature of this seismic cluster is its temporal pattern, characterized by regular intervals between repeating seismic events, modulated by a seasonal variation. Remarkable is also the stability of both the time and waveform features over a long time period, around 3.5 years. No comparable examples have been found in the literature. Both volcanic and glacial processes can produce similar waveforms and therefore have to be considered as potential seismic sources. Discerning between these two causes is critical for monitoring glacier-clad volcanoes and has been controversial at Katla. For this new seismic cluster on the south flank we regard volcano-related processes as more likely than glacial ones for the following reasons: 1) the seismic activity started during an unrest episode involving sudden melting of the glacier and a j\"okulhlaup; 2) the glacier stream is small and stagnant; 3) the seismicity remains regular and stable for years; 4) there is no apparent correlation with short-term weather changes, such as rain storms. We suggest that a small, shallow hydrothermal system was activated on Katla's south flank in 2011, either by a minor magmatic injection or by changes of permeability in a local crack system.
    Description: Published
    Description: 28-40
    Description: 3T. Fisica dei terremoti e Sorgente Sismica
    Description: JCR Journal
    Keywords: Physics - Geophysics; Physics - Geophysics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 134
    Publication Date: 2022-09-15
    Description: We have mapped and constrained the timing of tectonically deformed uplifted Late Quaternary palaeoshorelines in the Messina Strait, southern Italy, an area above a subduction zone containing active normal faults. The palaeoshorelines are preserved from up to thirteen Late Quaternary sea-level highstands, providing a record of the deformation over this timescale (~500 ka) for the Messina-Taormina Fault, the Reggio Calabria Fault and the Armo Fault. The palaeoshorelines reveal spatial patterns of uplift through time along the strike of these normal faults, and, given the across strike arrangement of the faults, also reveal how the contribution of each fault to the regional strain-rate progressed through time. The results reveal that the uplift rates mapped within the fault hangingwalls and footwalls were not constant through time, with a marked change in the location of strain accumulation at ~50 ka. The uplift rates, once converted into throw-rates, imply that the three faults comprised similar throw-rates prior to ~50 ka (in the range 0.77–0.96 mm/yr), with the Armo and Reggio Calabria faults then switching to lower rates (0.32 mm/yr and 0.33 mm/yr respectively), whilst the Messina-Taormina Fault accelerated to 2.34 mm/yr. The regional extension rate, gained by summing the implied heave rates across the three faults, was maintained through time despite this re-organisation of local strain accumulation at ~50 ka. We explain these out-of-phase fault throw-rate changes during the constant-rate regional extension conditions as due to interactions between these upper plate normal faults. We finally discuss how fault throw-rates changing through time may affect a long-term seismic hazard assessment within active normal fault systems.
    Description: Published
    Description: 105432
    Description: 2T. Deformazione crostale attiva
    Description: JCR Journal
    Keywords: Crustal Deformation ; Active Faults ; Marine terraces ; Uplift ; 04.04. Geology ; 04.07. Tectonophysics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 135
    Publication Date: 2022-09-15
    Description: Innovations in virtual reality (VR) technology have led to exciting possibilities in teaching earth sciences, allowing students to experience complex geological sites that, due to cost and logistical reasons, they would not normally be able to experience. The need for high quality online digital learning resources and blended learning was brought to the forefront during the SARS-CoV-2 pandemic, as courses with a traditional physical field work component were forced to move online and provide alternatives to students. While it is unlikely that virtual field trips (VFT) would be accepted by students as a replacement of real-world fieldwork moving out of the pandemic, research shows promise that using IVR experiences can lead to enhanced learning outcomes in geosciences, warranting its inclusion on the curricula. This paper presents the outputs of a project to improve student learning in complex geological environments using VR. Here we outline a workflow that was developed to collect high resolution imagery using remote sensing to create digital outcrop models (DOM) of complex geological sites. Using this framework, this paper will then explore the use of VR for an investigation of the Husavik Triple Junction, a complex structural site in northern Iceland, explaining how the drone data was converted to a 3D DOM and demonstrating how VR can be used to simulate real world field mapping. Finally, we describe how these IVR activities have been integrated into taught modules at postgraduate level and discuss how the use of IVR experiences can complement existing geoscience curriculum design.
    Description: Erasmus+ Key Action 2 funded project 2017-1-UK01-KA203-036719 3DTeLC-Bringing the 3Dworld into the classroom: a new approach to Teaching, Learning and Communicating the science of geohazards in terrestrial and marine environments coordinated by M. Whitworth. (https://ec.europa.eu/programmes/erasmus-plus/projects/eplus-projectdetails/#project/2017-1-UK01-KA203-036719and http://www.3dtelc.com) and the MIUR Project ACPR15T4_00098–Argo3D, coordinated by A. Tibaldi (http://argo3d.unimib.it/).
    Description: Published
    Description: 104681
    Description: 1TM. Formazione
    Description: JCR Journal
    Keywords: Virtual reality ; Geosciences ; Teaching ; Fieldwork ; Structural geology ; Digital outcrop model ; 05.04. Instrumentation and techniques of general interest ; 04.04. Geology ; 05.03. Educational, History of Science, Public Issues
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  • 136
    Publication Date: 2022-09-30
    Description: Mud volcanoes are rapidly-evolving geological phenomena characterized by the surface expulsion of sediments and fluids from over-pressurized underlying reservoirs. We investigate the Nirano Mud Volcano, Northern Italy, with seismic methods to better understand the dynamic evolution of the system and shed light on its subsurface structure. Our study allowed to detect and characterize three different types of high-frequency drumbeat signals that are present in the most active part of the mud volcano plumbing system. With a back-projection method based on the cross-correlation envelope of signals recorded at different station pairs, we can determine the source location of the drumbeats. These coincide with the location of V/H (vertical-to-horizontal) amplitude peaks obtained from an ambient vibration profile and resistivity anomalies identified in a previous study. We observe that the drumbeats are P-wave dominated signals, with characteristics similar to those found in magmatic settings, i.e. LPs (long-period signals). We suggest that such tremors originate from the migration of mud and gas inside the mud volcanic conduits. The source location, waveform and frequency content of the drumbeats evolve over time. We found that drumbeat occurrence is directly linked with morphological changes at surface.
    Description: Published
    Description: 107619
    Description: 7A. Geofisica per il monitoraggio ambientale
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 137
    Publication Date: 2022-10-10
    Description: There are three classes of geothermometers and fCO2-indicators (collectively known as geoindicators): the traditional or classical ones, the theoretical activity-based geoindicators, and multicomponent chemical geothermometry. Most traditional geothermometers (e.g., SiO2, Nasingle bondK, Na-K-Ca, Ksingle bondMg) are linear functions linking the logarithm of the equilibrium constant of the controlling reaction to the absolute temperature reciprocal. Total concentrations are considered in most traditional geothermometers. Thanks to these two characteristics, the traditional geothermometers are simple to be used, which explains their widespread use. However, there are at least two issues which have been disregarded or not properly considered in the derivation of traditional geothermometers. One is that total concentrations of relevant solutes can deviate considerably from the activities of the aqueous species participating to the controlling mineral-solution reactions due to the formation of aqueous complexes. The other concerns the hydrothermal minerals, with some having variable composition and adularia being affected by Alsingle bondSi order-disorder on the tetrahedral sites. To overcome these two issues, theoretical activity-based geoindicators were recently proposed. To use these geoindicators is necessary to run a speciation program, but computed temperatures and CO2 fugacities are more reliable than those given by traditional geoindicators and additional information is obtained on the hydrothermal minerals present in the geothermal aquifer. Multicomponent chemical geothermometry consists in simulating the heating of the aqueous solution of interest from the P-T conditions present at the surface to those occurring in the geothermal aquifer. Both multicomponent chemical geothermometry and theoretical activity-based geoindicators call for the use of a suitable computer code and an internally consistent thermodynamic database. It would be desirable for the database to be shared, accepted and used by the entire scientific community.
    Description: Published
    Description: 107097
    Description: 1TR. Georisorse
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 138
    Publication Date: 2022-10-28
    Description: A representative fluid sampling of surface geothermal manifestations and its analytical data quality assurance and quality control (QA/QC) are challenging aspects of understanding the geothermal reservoir processes. To achieve these goals, an interlaboratory test for the chemical analyses of ten water samples: one synthetic water, two lake waters (i.e., duplicated), one stream water, and six water samples from two geothermal wells of Los Azufres Geothermal field (LAGF), Michoacan, Mexico, was conducted. The geothermal wells were sampled at four points: (1) total discharge of condensed fluid at the wellhead, (2) separate liquid condensed in the well separator, (3) flushed liquid at the weir box, and (4) separated vapor condensed at the well-separator (data taken from Verma et al., 2022). Sixteen laboratories from ten countries reported their results. The pH, electrical conductivity, Ca2+, Li+, SO4 2 B, and Si-total measurements were 8.35 ± 0.04, 12.25 ± 0.53 mS/cm, 25 ± 1 mg/l, 18 ± 1 mg/l, 569 ± 33 mg/l, 320 ± 21 mg/l, and 20.5 ± 0.7 mg/l, which are close to the conventional true values, 8.40, 12.31 mS/cm, 23 mg/l, 19 mg/l, 647 mg/l, 330 mg/l, and 20.0 mg/l, respectively. Analytical errors for major ions, Na+, Cl
    Description: Published
    Description: 105477
    Description: 2IT. Laboratori analitici e sperimentali
    Description: JCR Journal
    Keywords: Geothermal water ; Inter-laboratory test ; Geothermal system ; Los Azufres ; Geochemical modeling ; Uncertainty propagation ; NIST Uncertainty machine ; 05.04. Instrumentation and techniques of general interest
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 139
    Publication Date: 2022-10-24
    Description: The Earth is a dynamic planet, where earthquakes and volcanoes are among some of its most outstanding expressions. Just like our planet as a whole is subject to lunisolar gravitational tides, seismic and volcanic activity are also influenced by the relative motion of the Sun and Moon. This tidal influence takes different forms, spanning different spatial and temporal scales, from quasiperiodic patterns with semidiurnal to multiannual periods to the triggering of earthquakes and volcanic eruptions. Tidal stresses have been primarily evoked as driving forces, although they are 3–5 orders of magnitude smaller than tectonic stresses, which makes cause-effect relationships elusive. This chapter reviews the different observations of tidal influence in geophysical and geochemical data acquired in tectonic and volcanic settings, as well as the methods that have been developed to detect it. Using case studies, we provide some insights on the sensitivity of geological systems to tidal stresses.
    Description: Published
    Description: 333-364
    Description: 4V. Processi pre-eruttivi
    Keywords: Volcanic activity ; Seismic activity ; Solid Earth and ocean tides ; External forcing ; Tidal triggering ; 04. Solid Earth
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: book chapter
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  • 140
    Publication Date: 2022-10-28
    Description: A 23 hour tremor burst was recorded on July 8-9th 2011 at the Katla subglacial volcano, one of the most active and hazardous volcanoes in Iceland. This was associated with deepening of cauldrons on the ice cap and a glacial flood that caused damage to infrastructure. Increased earthquake activity within the caldera started a few days before and lasted for months afterwards and new seismic activity started on the south flank. No visible eruption broke the ice and the question arose as to whether this episode relates to a minor subglacial eruption with the tremor being generated by volcanic processes, or by the flood. The tremor signal consisted of bursts with varying amplitude and duration. We have identified and described three different tremor phases, based on amplitude and frequency features. A tremor phase associated with the flood was recorded only at stations closest to the river that flooded, correlating in time with rising water level observed at gauging stations. Using back-projection of double cross-correlations, two other phases have been located near the active ice cauldrons and are interpreted to be caused by volcanic or hydrothermal processes. The greatly increased seismicity and evidence of rapid melting of the glacier may be explained by a minor sub-glacial eruption. It is also plausible that the tremor was generated by hydrothermal boiling and/or explosions with no magma involved. This may have been induced by pressure drop triggered by the release of water when the glacial flood started. All interpretations require an increase of heat released by the volcano.
    Description: Published
    Description: 63-78
    Description: 3T. Fisica dei terremoti e Sorgente Sismica
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: JCR Journal
    Keywords: Physics - Geophysics; Physics - Geophysics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 141
    Publication Date: 2022-10-24
    Description: Scintillations are caused by ionospheric irregularities and can affect the propagation of trans-ionospheric radio signals. One way to understand and predict the impact of such irregularities on Global Navigation Satellite System (GNSS) signals is through the spatial/temporal characterization of the scintillation’s climatology during different phases of a solar cycle covering different latitudes and longitudes. This characterization is performed using amplitude scintillation index S4, during the full solar cycle 24, in the South American (SA) sector. The investigation considers the diurnal, daily, and seasonal variation of S4 index for climatological purpose, and the goal of this study is to investigate the scintillations covering a large spatial scale during the full solar cycle 24. The characterization shows a latitudinal asymmetry, whereas at the south, the scintillations were more frequent and their peak was more distant from the magnetic equator, which can be attributed by the South Atlantic Magnetic Anomaly (SAMA), and/or by the transequatorial meridional neutral winds. It also shows a longitudinal asymmetry, where the scintillations at the eastern sector occurred between November and February, while at the western sector, they occurred during the months of October, November, February and March, which can be attributed to the difference between the magnetic and geographic equators. The occurrence of scintillations during two distinct geomagnetic storms with similar storm time in the SA sector is also presented.
    Description: Published
    Description: 105872
    Description: 2A. Fisica dell'alta atmosfera
    Description: JCR Journal
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  • 142
    Publication Date: 2022-11-03
    Description: This paper presents new chemical and isotopic data on gases from deep oil and gas fields, bubbling gases, dissolved gases in groundwaters and dry seeps of the Southern Po River Basin (Emilia-Romagna, Italy), aiming to (i) characterize and differentiate the various types of deep natural gases; (ii) identify the source(s) of methane and light hydrocarbons in shallow aquifers and surface gas-rich emissions; (iii) propose a conceptual model of natural fluid migration pathways in the sedimentary prism of the Southern Po River Basin. Based on the isotopic composition of CH4 and C2–C4 n-alkanes, CH4/(C2H6+C3H8) ratio, relative proportion of the C7 hydrocarbons and relative concentration of cyclic compounds with respect to the total cyclic abundance, three main deep reservoirs of hydrocarbons are identified in the subsurface of the Southern Po River Basin: (1) microbial gas hosted in Pliocene-Pleistocene marine sediments, (2) thermogenic gas hosted in Miocene deposits and (3) thermogenic gas produced in Triassic carbonates. Helium isotopes of these deep fluids indicate an almost pure crustal origin (Rc/Ra values = 0.014–0.04), with negligible contributions from mantle-derived helium. A variable contribution of atmosphere-derived fluids is highlighted by low 4He/20Ne (down to 5.42) and 40Ar/36Ar (≤319.5) values. Comparison of chemical and isotopic signatures of deep and surficial hydrocarbon occurrences suggests that methane in shallow groundwaters or gas seeps is sourced by microbial gas migrating upward from deep Plio-Pleistocene reservoirs, with no detectable contributions of Triassic or Miocene thermogenic hydrocarbons. At shallow depths (roughly around 20–50 m.b.g.l.), Plio-Pleistocene microbial methane appears to be mainly stored in anoxic aquifers. However, where CH4 further migrates upwards and reaches aerobic environments (e.g., aquifers or soils), it readily undergoes a process of exothermic microbial oxidation mediated by methanotrophic bacteria. Where the structural architecture of the sedimentary sequence favors the migration of fluids, the methanotrophic biofilter is bypassed and CH4 is discharged through soil diffuse degassing or gas bubbling at water wells. We argue that microbial consumption might be able to bio-sequester significant amounts of Plio-Pleistocene deep-sourced methane in the form of CO2 and biomass. Such process might be widespread in the subsurface of the Southern Po River Basin and, possibly, in other foreland basins worldwide.
    Description: Published
    Description: 105981
    Description: 9T. Geochimica dei fluidi applicata allo studio e al monitoraggio di aree sismiche
    Description: JCR Journal
    Keywords: Methane ; Po river basin ; Emilia-romagna region ; Natural gas geochemistry ; Hydrocarbon source rocks ; Gas accumulation and migration ; Thermogenic gas ; Microbial gas
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 143
    Publication Date: 2022-11-22
    Description: To refine knowledge about terrace phases and uplift history for a tectonically poor deformed region, we apply the synchronous correlation method to reconstruct the chronology of a poorly constrained sequence of raised palaeoshorelines on the Apulian foreland, southern Italy. This work uses new chronological constraints obtained by amino acid racemisation (AAR) and isoleucine/alloisoleucine epimerisation (IE) on Patella spp., Thetystrombus latus (Gmelin), Glycymeris sp., and ostracods and U-series dating on corals Hoplangia durotrix Gosse and Cladocora caespitosa Linneo. This procedure provides a quantitative estimate of the vertical movements and associated rates within a region of the Apulian foreland. The synchronous correlation method uses sea-level highstands and uplift rate(s) as inputs; in particular, for sea-level highstands, the inputs are the age of the highstands and the sea-level elevation of the highstands relative to the present-day sea level. The output is a set of currently expected elevations of each sea-level highstand (the present elevations of palaeoshorelines). We then used regression analysis to assess the robustness between our observed palaeoshorelines and expected elevations of sea-level highstands. Our results show that the best fitting scenario is obtained using the sea-level curves of (i) Waelbroeck et al. (2002) from present to 410 ky BP and (ii) Rohling et al. (2014) from 410 to 590 ky BP as inputs for our synchronous correlation method, with uplift rates ranging from 0.09 mm/y to 0.07 mm/y with a mean value of 0.08 mm/y from 590 ky BP onwards. We recognised palaeoshorelines in the field belonging to the following highstands: 120 ky BP (MIS 5.5, second peak), 127 ky BP (MIS 5.5, first peak), 212 ky BP (MIS 7.3), 330 ky BP (MIS 9.3), 410 (MIS 11), 525 ky BP (MIS 13.3), and 590 ky BP (MIS 15). Our results show field observations of the reoccupation effect of younger palaeoshorelines over older ones due to the relatively slow uplift rates measured in the investigated area as predicted by our synchronous correlation method. In particular, we show a well-mapped and described reoccupation of the MIS 5.5 palaeoshoreline over the MIS 7.3 palaeoshoreline, constrained by new absolute dating. In addition, the data from the Apulian foreland suggest an MIS 7.3 highstand close to the present sea level.
    Description: Published
    Description: 108530
    Description: 2T. Deformazione crostale attiva
    Description: JCR Journal
    Keywords: Crustal Deformation ; Uplift ; Marine terraces ; Absolute dating ; 04.04. Geology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 144
    Publication Date: 2022-12-01
    Description: Author Posting. © American Meteorological Society, 2022. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Bulletin of the American Meteorological Society 103(6), (2022): E1502-E1521, https://doi.org/10.1175/bams-d-21-0227.1.
    Description: Climate observations inform about the past and present state of the climate system. They underpin climate science, feed into policies for adaptation and mitigation, and increase awareness of the impacts of climate change. The Global Climate Observing System (GCOS), a body of the World Meteorological Organization (WMO), assesses the maturity of the required observing system and gives guidance for its development. The Essential Climate Variables (ECVs) are central to GCOS, and the global community must monitor them with the highest standards in the form of Climate Data Records (CDR). Today, a single ECV—the sea ice ECV—encapsulates all aspects of the sea ice environment. In the early 1990s it was a single variable (sea ice concentration) but is today an umbrella for four variables (adding thickness, edge/extent, and drift). In this contribution, we argue that GCOS should from now on consider a set of seven ECVs (sea ice concentration, thickness, snow depth, surface temperature, surface albedo, age, and drift). These seven ECVs are critical and cost effective to monitor with existing satellite Earth observation capability. We advise against placing these new variables under the umbrella of the single sea ice ECV. To start a set of distinct ECVs is indeed critical to avoid adding to the suboptimal situation we experience today and to reconcile the sea ice variables with the practice in other ECV domains.
    Description: PH’s contribution was funded under the Australian Government’s Antarctic Science Collaboration Initiative program, and contributes to Project 6 of the Australian Antarctic Program Partnership (ASCI000002). PH acknowledges support through the Australian Antarctic Science Projects 4496 and 4506, and the International Space Science Institute (Bern, Switzerland) project #405.
    Description: 2022-12-01
    Keywords: Sea ice ; Climate change ; Climatology ; Climate records
    Repository Name: Woods Hole Open Access Server
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  • 145
    Publication Date: 2022-11-27
    Description: Author Posting. © American Meteorological Society, 2022. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 52(6), (2022): 1233-1244, https://doi.org/10.1175/jpo-d-21-0223.1.
    Description: The Sverdrup relation is the backbone of wind-driven circulation theory; it is a simple relation between the meridional transport of the wind-driven circulation in the upper ocean and the wind stress curl. However, the relation is valid for steady circulation only. In this study, a time-dependent Sverdrup relation is postulated, in which the meridional transport in a time-dependent circulation is the sum of the local wind stress curl term and a time-delayed term representing the effect of the eastern boundary condition. As an example, this time-dependent Sverdrup relation is evaluated through its application to the equatorial circulation in the Indian Ocean, using reanalysis data and a reduced gravity model. Close examination reveals that the southward Somali Current occurring during boreal winter is due to the combination of the local wind stress curl in the Arabian Sea and delayed signals representing the time change of layer thickness at the eastern boundary.
    Description: This work is supported by NSFC (41822602, 41976016, 42005035, 42076021), the Strategic Priority Research Program of Chinese Academy of Sciences (XDB42000000, XDA 20060502), Key Special Project for Introduced Talents Team of Southern Marine Science and Engineering Guangdong Laboratory (Guangzhou) (GML2019ZD0306), Guangdong Basic and Applied Basic Research Foundation (2021A1515011534), Youth Innovation Promotion Association CAS, ISEE2021ZD01, and LTOZZ2002. The numerical simulation is supported by the High-Performance Computing Division in the South China Sea Institute of Oceanology.
    Description: 2022-11-27
    Keywords: Ocean circulation ; Ocean dynamics ; Rossby waves ; Wind stress curl
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  • 146
    Publication Date: 2022-11-18
    Description: © The Author(s), 2022. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Wiebe, P., Baumgartner, M., Copley, N., Lawson, G., Davis, C., Ji, R., & Greene, C. Does predation control the diapausing stock of Calanus finmarchicus in the Gulf of Maine? Progress In Oceanography, 206, (2022): 102861, https://doi.org/10.1016/j.pocean.2022.102861.
    Description: The variability of zooplankton populations is controlled by external and internal forcing, with the former being principally large-scale changes in circulation, and the latter being driven by in situ growth, competition, and predation. Assessing the relative importance of these forcings is challenging and requires analyses of multifaceted observational data. As part of the U.S. GLOBEC Georges Bank program, a series of cruises were conducted in fall 1997, 1998, and 1999 to survey diapausing populations of Calanus finmarchicus and their predators in Wilkinson, Jordan, and Georges Basins of the Gulf of Maine. Station and underway sampling were conducted using net (1 m2 MOCNESS) and bioacoustic (BIOMAPER-II) systems, respectively, to acquire vertically stratified data for zooplankton biomass, taxonomic, size, and life-stage composition, together with associated environmental data. The results show that the autumn diapausing C. finmarchicus abundance was much lower in 1998 than in 1997 or 1999, even though the overall zooplankton biomass levels were comparable between the three years. The size frequency distribution of the diapausing individuals had a bi-modal pattern in 1997 and 1999, but a single mode in 1998, indicating the demise of an early cohort of the diapausing stock. The relative biomass and computed energy demand of potential invertebrate predators (euphausiids, decapods, medusae, and siphonophores) was found to be higher in 1998 and could account for the missing C. finmarchicus cohort. Evidence collected from this study supports the hypothesis that local predation has the potential to control the diapausing stock of C. finmarchicus in the Gulf of Maine.
    Description: RJ received support from the Northeast US Shelf Long Term Ecological Research (NES-LTER) project (NSF OCE-1655686) and the US MBON Gulf of Maine project to NERACOOS (NOPP award NA19NOS0120197 and BOEMUMaine Cooperative Agreement M19AC00022) for analyzing the size data and working on the manuscript. Research support was provided by the US GLOBEC Georges Bank Program through the CILER Cooperative Agreement NA-67RJO148 (NOAA Coastal Ocean Program).
    Keywords: Gulf of Maine ; Calanus finmarchicus ; Fall abundance variability ; Calanus C5 size variability ; Predation control
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  • 147
    Publication Date: 2022-12-09
    Description: Author Posting. © American Meteorological Society, 2022. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 52(7), (2022): 1333-1350, https://doi.org/10.1175/jpo-d-21-0298.1.
    Description: Idealized numerical simulations were conducted to investigate the influence of channel curvature on estuarine stratification and mixing. Stratification is decreased and tidal energy dissipation is increased in sinuous estuaries compared to straight channel estuaries. We applied a vertical salinity variance budget to quantify the influence of straining and mixing on stratification. Secondary circulation due to the channel curvature is found to affect stratification in sinuous channels through both lateral straining and enhanced vertical mixing. Alternating negative and positive lateral straining occur in meanders upstream and downstream of the bend apex, respectively, corresponding to the normal and reversed secondary circulation with curvature. The vertical mixing is locally enhanced in curved channels with the maximum mixing located upstream of the bend apex. Bend-scale bottom salinity fronts are generated near the inner bank upstream of the bend apex as a result of interaction between the secondary flow and stratification. Shear mixing at bottom fronts, instead of overturning mixing by the secondary circulation, provides the dominant mechanism for destruction of stratification. Channel curvature can also lead to increased drag, and using a Simpson number with this increased drag coefficient can relate the decrease in stratification with curvature to the broader estuarine parameter space.
    Description: The research leading to these results was funded by NSF Awards OCE-1634481 and OCE-2123002.
    Description: 2022-12-09
    Keywords: Estuaries ; Mixing ; Secondary circulation ; Fronts ; Tides ; Numerical analysis/modeling
    Repository Name: Woods Hole Open Access Server
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  • 148
    Publication Date: 2022-12-16
    Description: Author Posting. © American Meteorological Society, 2022. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 52(7), (2022): 1415–1430. https://doi.org/10.1175/JPO-D-21-0147.1.
    Description: Strong subinertial variability near a seamount at the Xisha Islands in the South China Sea was revealed by mooring observations from January 2017 to January 2018. The intraseasonal deep flows presented two significant frequency bands, with periods of 9–20 and 30–120 days, corresponding to topographic Rossby waves (TRWs) and deep eddies, respectively. The TRW and deep eddy signals explained approximately 60% of the kinetic energy of the deep subinertial currents. The TRWs at the Ma, Mb, and Mc moorings had 297, 262, and 274 m vertical trapping lengths, and ∼43, 38, and 55 km wavelengths, respectively. Deep eddies were independent from the upper layer, with the largest temperature anomaly being 〉0.4°C. The generation of the TRWs was induced by mesoscale perturbations in the upper layer. The interaction between the cyclonic–anticyclonic eddy pair and the seamount topography contributed to the generation of deep eddies. Owing to the potential vorticity conservation, the westward-propagating tilted interface across the eddy pair squeezed the deep-water column, thereby giving rise to negative vorticity west of the seamount. The strong front between the eddy pair induced a northward deep flow, thereby generating a strong horizontal velocity shear because of lateral friction and enhanced negative vorticity. Approximately 4 years of observations further confirmed the high occurrence of TRWs and deep eddies. TRWs and deep eddies might be crucial for deep mixing near rough topographies by transferring mesoscale energy to small scales.
    Description: This work was supported by the National Natural Science Foundation of China (92158204, 91958202, 42076019, 41776036, 91858203), the Open Project Program of State Key Laboratory of Tropical Oceanography (project LTOZZ2001), and Key Special Project for Introduced Talents Team of Southern Marine Science and Engineering Guangdong Laboratory (Guangzhou) (GML2019ZD0304).
    Description: 2022-12-16
    Keywords: Abyssal circulation ; Ocean circulation ; Ocean dynamics ; Intraseasonal variability
    Repository Name: Woods Hole Open Access Server
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  • 149
    Publication Date: 2022-12-22
    Description: The geological carbon cycle has played a key role in controlling climate throughout Earth’s history. For the last ∼ 3 billion years plate tectonics has driven subduction. Subducted slabs have transported CO_2 from the lithosphere, hydrosphere, and atmosphere into the Earth, from where it may be released back to the surface through processes such as arc volcanism or can be stored in the deep interior over geological time. Carbonate-bearing sediments and basalts of altered oceanic crust are the primary media by which carbon is subducted. Therefore, quantifying the depth and amount of CO_2 released from different carbonate-bearing lithologies during subduction is fundamental to understanding whether CO_2 is recycled through arc volcanism or buried in the mantle. The magnitude of CO_2 released from subducting slabs at fore- and sub-arc depths is controlled by processes including ocean crust alteration (i.e., carbonation), metamorphic decarbonation, carbonate dissolution and slab-melting. However, the relative contribution of these processes to overall slab decarbonation is still debated, and will be complex given the variety of sedimentary lithologies and subduction geodynamics. Here, we present a global arc-by-arc lithology-specific analysis of the magnitude of slab CO_2 released purely by metamorphic decarbonation of carbonate-bearing sediment and basalt during subduction of altered oceanic crust, using a thermodynamically rigorous model. We find that metamorphic decarbonation is highly efficient in low carbonate sediments, such as carbonated clay, and in carbonated basalts of altered oceanic crust, causing all of their CO_2 to be removed. Sediments with medium and higher carbonate contents, such as chalk and limestone, are only partially decarbonated, but the combination of metamorphic decarbonation and carbonate dissolution promotes efficient carbon loss. Together they can explain observed magmatic CO_2 emissions in carbonate-rich arcs. Warm slabs, such as Mexico and Cascadia, produce complete metamorphic decarbonation of carbonate minerals beneath fore-arcs. Under more common cold and intermediate thermal regimes metamorphic decarbonation of carbonate minerals occurs at depths between ∼ 80 and 170 km ( ∼ 2.3 to 5.5 GPa) promoting CO_2 input into the mantle sources of volcanic arcs. Overall, our results demonstrate that sub-arc decarbonation is typically considered an important potential source of slab-derived CO_2 , which needs to be considered together with carbonate dissolution to explain observed volcanic CO_2 emissions. In many arcs the modelled CO_2 flux from sediment and basalts of altered oceanic crust into the wedge exceeds the observed CO 2 output suggesting that the mantle wedge and arc lithosphere may sequester some CO_2 .
    Description: Published
    Description: 117945
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 150
    Publication Date: 2022-12-01
    Description: An accurate survey of old and new datasets allowed us to probe the nature and role of fluids in the seismogenic processes of the Apennines mountain range in Italy. New datasets include the 1985–2021 instrumented seismicity catalog, the computed seismogenic thickness, and geodetic velocities and strains, whereas data from the literature comprise focal mechanism solutions, CO2 release, Moho depth, tomographic seismic velocities, heat flow and Bouguer gravity anomalies. Most of the inspected datasets highlight differences between the western and eastern domains of the Apennines, while the transition zone is marked by high geodetic strain, prevailing uplift at the surface and high seismic release, and spatially corresponds with the overlapping Tyrrhenian and Adriatic Mohos. Published tomographic models suggest the presence of a large hot asthenospheric mantle wedge which intrudes beneath the western side of the Apennines and disappears at the southern tip of the southern Apennines. This wedge modulates the thermal structure and rheology of the overlying crust as well as the melting of carbonate-rich sediments of the subducting Adriatic lithosphere. As a result, CO2-rich fluids of mantle-origin have been recognized in association with the occurrence of destructive seismic sequences in the Apennines. The stretched western domain of the Apennines is characterized by a broad pattern of emissions from CO2-rich fluids that vanishes beneath the axial belt of the chain, where fluids are instead trapped within crustal overpressurized reservoirs, favoring their involvement in the evolution of destructive seismic sequences in that region. In the Apennines, areas with high mantle He are associated with different degrees of metasomatism of the mantle wedge from north to south. Beneath the chain, the thickness and permeability of the crust control the formation of overpressurized fluid zones at depth and the seismicity is favored by extensional faults that act as high permeability pathways. This multidisciplinary study aims to contribute to our understanding of the fluid-related mechanisms of earthquake preparation, nucleation and evolution encouraging a multiparametric monitoring system of different geophysical and geochemical observables that could lead the creation of a data-constrained and reliable conceptual model of the role of fluids in the preparatory phase of earthquakes in the Apennines.
    Description: The INGV Earthquake Department Strategic Project FURTHER “The role of FlUids in the pReparaTory pHase of EaRthquakes in Southern Apennines”
    Description: Published
    Description: 104236
    Description: 1T. Struttura della Terra
    Description: 2T. Deformazione crostale attiva
    Description: 3T. Fisica dei terremoti e Sorgente Sismica
    Description: 4T. Sismicità dell'Italia
    Description: 9T. Geochimica dei fluidi applicata allo studio e al monitoraggio di aree sismiche
    Description: JCR Journal
    Keywords: CO2 Earth degassing ; Earthquakes ; Mantle wedge ; Subduction ; Apennines ; 04.06. Seismology ; Geochemistry ; 04.03. Geodesy
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 151
    Publication Date: 2022-12-14
    Description: New constraints were set on the age of marine deposits in the Pontine Plain and of the related sea level indicators on the Tyrrhenian Sea coast of central Italy by twelve new 40Ar/39Ar dates on detrital sanidine from these deposits. By combining a new geomorphologic analysis and previous morpho-pedostratigraphic studies with these geochronological constraints we reconstructed the geometry of four marine terraces and correlated these with the highstands during the marine isotopic stages (MIS) 9.3, 7.5, 5.5 and 5.3. Results point to a progressive tilting of the terraces, the elevation increasing from the SE to the NW due to differential tectonic uplift that occurred over the last 300 ka. We identified a MIS 9 sea level at 30 - 25 m asl in the northwestern sector, whereas the MIS 7.5 sea level reached a maximum of 24 m asl in the NWand descended to 18 m asl in the central sector. Moderate tilting affected the MIS 5.5 sea level, with an elevation of 12 to 9.5 m asl in between the Anzio and Circeo headlands. Finally, an undeformed MIS 5.3 sea level at ca. 3 m asl is indicated throughout this coastal reach, confirming previous data suggesting a much higher absolute sea level during this highstand with respect to the d18O-derived predicted level.
    Description: Published
    Description: 107866
    Description: 2T. Deformazione crostale attiva
    Description: JCR Journal
    Keywords: Marine terraces ; MIS 5 sea level ; Pontine Plain ; Tyrrhenian Sea ; 04.04. Geology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 152
    Publication Date: 2022-12-21
    Description: Author Posting. © American Meteorological Society, 2022. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 52(12), (2022): 2923–2933, https://doi.org/10.1175/jpo-d-22-0064.1.
    Description: The characteristics and dynamics of depth-average along-shelf currents at monthly and longer time scales are examined using 17 years of observations from the Martha’s Vineyard Coastal Observatory on the southern New England inner shelf. Monthly averages of the depth-averaged along-shelf current are almost always westward, with the largest interannual variability in winter. There is a consistent annual cycle with westward currents of 5 cm s−1 in summer decreasing to 1–2 cm s−1 in winter. Both the annual cycle and interannual variability in the depth-average along-shelf current are predominantly driven by the along-shelf wind stress. In the absence of wind forcing, there is a westward flow of ∼5 cm s−1 throughout the year. At monthly time scales, the depth-average along-shelf momentum balance is primarily between the wind stress, surface gravity wave–enhanced bottom stress, and an opposing pressure gradient that sets up along the southern New England shelf in response to the wind. Surface gravity wave enhancement of bottom stress is substantial over the inner shelf and is essential to accurately estimating the bottom stress variation across the inner shelf.
    Description: The National Science Foundation, Woods Hole Oceanographic Institution, the Massachusetts Technology Collaborative, and the Office of Naval Research have supported the construction and maintenance of MVCO. The analysis presented here was partially funded by the National Science Foundation under Grants OCE 1558874 and OCE 1655686.
    Keywords: Continental shelf/slope ; Coastal flows ; Momentum ; Ocean dynamics ; Wind stress
    Repository Name: Woods Hole Open Access Server
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  • 153
    Publication Date: 2022-12-21
    Description: Author Posting. © American Meteorological Society, 2022. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 52(12), (2022): 2909-2921, https://doi.org/10.1175/jpo-d-22-0063.1.
    Description: A remarkably consistent Lagrangian upwelling circulation at monthly and longer time scales is observed in a 17-yr time series of current profiles in 12 m of water on the southern New England inner shelf. The upwelling circulation is strongest in summer, with a current magnitude of ∼1 cm s−1, which flushes the inner shelf in ∼2.5 days. The average winter upwelling circulation is about one-half of the average summer upwelling circulation, but with larger month-to-month variations driven, in part, by cross-shelf wind stresses. The persistent upwelling circulation is not wind-driven; it is driven by a cross-shelf buoyancy force associated with less-dense water near the coast. The cross-shelf density gradient is primarily due to temperature in summer, when strong surface heating warms shallower nearshore water more than deeper offshore water, and to salinity in winter, caused by fresher water near the coast. In the absence of turbulent stresses, the cross-shelf density gradient would be in a geostrophic, thermal-wind balance with the vertical shear in the along-shelf current. However, turbulent stresses over the inner shelf attributable to strong tidal currents and wind stress cause a partial breakdown of the thermal-wind balance that releases the buoyancy force, which drives the observed upwelling circulation. The presence of a cross-shelf density gradient has a profound impact on exchange across this inner shelf. Many inner shelves are characterized by turbulent stresses and cross-shelf density gradients with lighter water near the coast, suggesting turbulent thermal-wind-driven coastal upwelling may be a broadly important cross-shelf exchange mechanism.
    Description: The National Science Foundation, Woods Hole Oceanographic Institution, the Massachusetts Technology Collaborative, and the Office of Naval Research have supported the construction and maintenance of MVCO. The analysis presented here was partially funded by the National Science Foundation under Grants OCE 1558874 and OCE 1655686.
    Keywords: Buoyancy ; Coastal flows ; Currents ; Dynamics ; Lagrangian circulation/transport ; Upwelling/downwelling
    Repository Name: Woods Hole Open Access Server
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  • 154
    Publication Date: 2022-12-27
    Description: The characterization of the fling-step represents a challenging task due to the shortage of near-source records with permanent tectonic displacement and the limitation in retrieving the fling-amplitude from accelerometric waveforms. In recent years, innovative ground-motion processing techniques have been developed for a more accurate estimation of both fling-displacements and spectral displacements in contrast to traditional bandpass filtering, although their application is still unusual. In this paper, we exploit the newly released dataset of the Near-Source Strong-motion records (NESS2) uniformly processed with the extended BASeline COrrection technique (eBASCO), against which we propose: (1) a new empirically-based ground motion model (GMM) for the prediction of the fling-step, and (2) an adjustment factor of the spectral displacements predicted by a reference GMM to account for the contribution of the fling-step at long periods. Such models are in agreement with observations and existing GMMs, and thus could be advantageously employed in seismic hazard analyses.
    Description: Published
    Description: 107294
    Description: 5T. Sismologia, geofisica e geologia per l'ingegneria sismica
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 155
    Publication Date: 2022-12-27
    Description: The 1915, Mw6.7, Fucino earthquake is one of the most destructive events occurred in the central-southern Apennines (Central Italy) in pre-instrumental era, involving normal faulting in a deep alluvial basin. This study shows the application of the empirical non-ergodic approach (NESK method) for mapping ground shaking related to this historical event, taking into account the regional features of source, propagation and site contributions. Corrections of the source-region and spatially correlated maps of site and path residuals are combined with median prediction at the reference rock (i.e. without site amplification) to generate spatially variable ground shaking and associated variability in terms of peak ground acceleration and spectral ordinates at vibration periods from 0.01s to 2s. The method captures the main spatial non-stationarities and anisotropies of the shaking fields produced by this earthquake in and around the Fucino basin. In particular, we obtain patterns of seismic motion quite in accordance with the results of other methods and the macroseismic intensity field. Marked amplifications of the shaking in the long-periods are also captured, due to the coupling of 3D site effects, especially in the deeper portion of the basin, with propagation effects mainly focused towards the eastern part of the fault. These results confirm that the non-ergodic shaking scenarios from NESK can provide useful indications even in the case of very complex seismological and geological contexts, such as in the case of strong events in deep sedimentary basins.
    Description: Published
    Description: 107622
    Description: 5T. Sismologia, geofisica e geologia per l'ingegneria sismica
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 156
    Publication Date: 2022-12-27
    Description: Magmas often experience severe disequilibrium conditions during their migration through the Earth's crust and the subsequent emplacement on its surface. During their transport, magmas are subjected to a wide range of cooling (q) and deformation rates (), generating physico-chemical perturbations in the magmatic system able to inhibit or promote crystallization processes. Quantifying the magnitude and timescale of kinetic effects is essential to correctly constrain the rheological evolution of magmas and their ability to flow. Here we present a suite of cooling deformation experiments (CDE) conducted on a basalt from Mt. Etna (Sicily, Italy) to disentangle and model the concurrent effects of q (from 1 to 10 °C/min) and (from 1 to 10 s−1) on the rheology of the system. The analysis of the temporal evolution of viscosity indicates that both q and strongly affect the onset of crystallization and achievement of a rheological cut-off over time, which represents the steep viscosity increase responsible for inhibiting magma flow. Both these rheological thresholds occur at lower T and earlier in time with increasing q, as well as at higher T and earlier in time with increasing . To reproduce the observed effects of crystallization on the apparent viscosity, we adopt a stretched exponential function that identifies two main crystallization regimes: i) a first shear-induced crystallization regime, characterized by a gentle viscosity increase and ii) a second cooling-dominated regime, marked by a steeper viscosity increase. The relative extent of these crystallization regimes strictly depends on the interplay between q and on the crystallization kinetics and suggest a first order control of q and a subordinate role of .
    Description: Published
    Description: 117725
    Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Description: JCR Journal
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  • 157
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    Unknown
    Elsevier
    In:  EPIC3Journal of Sea Research, Elsevier, 187, pp. 102245, ISSN: 13851101
    Publication Date: 2022-07-15
    Description: Foraminifera nourishing on fresh organic matter often exhibit an epibiotic or even an epizoic lifestyle. This study investigates the colonization of sponges by foraminifera. For this purpose, 12 siliceous sponges of different genera (Asconema, Geodia, Lissodendoryx and Schaudinnia) and order Haplosclerida were collected in 2018 with a ROV in water depths of 223 to 625 m in the Norwegian-Greenland Sea. Sponges were stained with a Rose Bengal/ ethanol mixture to allow a differentiation between foraminifera that had been recently alive and empty tests. Each sponge sample contained 3–42 dead and 1–10 living foraminiferal individuals per cm3 and summarizing up to 78 different taxa on one single sponge (Geodia phlegraei). Even on Geodia barretti, which is able to release barrettin (an alkaloid) to avoid colonialization by other organisms, living foraminiferal individuals (1 ind./cm3) were observed. The highest foraminiferal densities (living and dead individuals) were recorded on Haplosclerida sp. (49 ind./cm3) and Geodia sp. (45 ind./cm3). The lowest densities of foraminifera were found on G. barretti (3–14 ind./cm3) and on Lissodendoryx complicata (9 ind./cm3). The foraminiferal diversity ranges from 7.04 to 17.38 for Fisher α and from 2.40 to 3.33 (Shannon-Wiener (H)S). The highest diversity was found on G. phlegraei and the lowest one on L. complicata. This study is highlighting the ecosystem engineering role of sponges providing niche habitats for a high number of foraminifera.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , NonPeerReviewed , info:eu-repo/semantics/article
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  • 158
    Publication Date: 2022-07-14
    Description: Forest destruction by ‘a‘ ̄a lava flow is common. However, mechanical and thermal interactions between the invading lava and the invaded forest are poorly constrained. We complete mapping, thermal image and sample analyses of a channel-fed ‘a‘a ̄ lava flow system that invaded forest on the NE flank of Mt. Etna (Italy) in 2002. These lava flows destroyed 231,000 trees, only 2% of which are still visible as felled trunks on the levees or at the channel-levee contact. The remaining 98% were first felled by the flow front, with the trunks then buried by the flow. Rare tree molds can be found at the rubble levee base where trees were buried by avalanching hot breccia and then burnt through, with a time scale for total combustion being a few days. Protruding trunks fell away from the flow, if felled by blocks avalanching down the levee flank, or became aligned with the flow if falling onto the moving stream. Estimated cooling rates (0.1–5.5 ◦C km− 1) are normal for well-insulated ‘a‘a ̄ flow, suggesting no thermal interaction. We find the highest phenocryst concentrations (of 50–60%, above an expected value of 30–40%) in low velocity (〈0.5 m s− 1) locations. These low velocity zones are also characterized by high trunk concentrations. Thus, the common factor behind crystal and trunk deposition is velocity. That is, when the lava slows down, crystal settling occurs and trunks are preferentially deposited. Thus, although we find no thermal or textural effects due to the presence of the forest, we do find mechanical and environmental in- teractions where the trees are consumed to become part of the flow.
    Description: This research was financed by the Agence National de la Recherche through the project LAVA (Program: DS0902 2016; Project: ANR-16 CE39-0009). We very much thank Sean I. Peters and an anonymous reviewer for their extremely constructive advice and support. This is ANR-LAVA contribution no. 23 and Laboratory of Excellence ClerVolc contribution no. 552.
    Description: Published
    Description: 107621
    Description: 6V. Pericolosità vulcanica e contributi alla stima del rischio
    Description: JCR Journal
    Keywords: Channelized ‘a‘ ̄a lava flow ; thermal imagery ; lava flows ; 2002-03 eruption ; forest destruction ; tree molds ; Etna volcano ; cooling rates ; Interaction lava and trees ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 159
    Publication Date: 2022-06-21
    Description: Author Posting. © American Meteorological Society, 2022. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 52(6),(2022): 1191-1204, https://doi.org/10.1175/jpo-d-21-0242.1.
    Description: A simplified quasigeostrophic (QG) analytical model together with an idealized numerical model are used to study the effect of uneven ice–ocean stress on the temporal evolution of the geostrophic current under sea ice. The tendency of the geostrophic velocity in the QG model is given as a function of the lateral gradient of vertical velocity and is further related to the ice–ocean stress with consideration of a surface boundary layer. Combining the analytical and numerical solutions, we demonstrate that the uneven stress between the ice and an initially surface-intensified, laterally sheared geostrophic current can drive an overturning circulation to trigger the displacement of isopycnals and modify the vertical structure of the geostrophic velocity. When the near-surface isopycnals become tilted in the opposite direction to the deeper ones, a subsurface velocity core is generated (via geostrophic setup). This mechanism should help understand the formation of subsurface currents in the edge of Chukchi and Beaufort Seas seen in observations. Furthermore, our solutions reveal a reversed flow extending from the bottom to the middepth, suggesting that the ice-induced overturning circulation potentially influences the currents in the deep layers of the Arctic Ocean, such as the Atlantic Water boundary current.
    Description: This work was funded by the National Key Research and Development Program of China (Grant 2017YFA0604600), the National Natural Science Foundation of China (Grant 41676019), the Fundamental Research Funds for the Central Universities (Grant 2019B81214), the Postgraduate Research and Practice Innovation Program of Jiangsu Province (Grant KYCX19_0384), and the National Science Foundation (MAS, Grants OPP-1822334, OCE-2122633).
    Keywords: Arctic ; Sea ice ; Channel flows ; Vertical motion ; Ekman pumping ; Idealized models ; Quasigeostrophic models
    Repository Name: Woods Hole Open Access Server
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  • 160
    Publication Date: 2022-06-10
    Description: In fold and thrust belts developing at convergent margins, the migration of the advancing wedge is accompanied by bulging of the downgoing plate, followed by the development of a foredeep basin filled by a thick succession of syn-orogenic sediments. The transition from forebulge to foredeep marks a key moment in the evolution of the orogenic system. In deep water environments, the record of this transition is typically complete and progressive. Conversely, in the shallow-water/continental environment of many collisional systems, the uplift of the forebulge area can imply emersion and erosion, obliterating the stratigraphic record of key steps of the evolution of the orogenic system. The southern Apennines constitute one of these collisional fold and thrust belts where the development of the forebulge has implied emersion and erosion, with the development of a Miocene forebulge erosional unconformity, accompanied by extensional deformation associated with the bending of the lithosphere during the forebulge stage. In this paper, we use strontium isotope stratigraphy to constrain with unprecedented time-resolution the age of the forebulge unconformity in areas presently incorporated in the northern sector of the southern Apennines fold and thrust belt. Integration of our results and those of previous studies indicates, at the regional scale, a younging toward the foreland of the forebulge unconformity across the belt. Our highresolution ages also reveal a diachronous onset of the flexural subsidence over short distances, associated with the occurrence of horst and graben structures, possibly resulting from inherited paleotopography along with forebulge extension. This work highlights how high-resolution dating is critical to unravel the evolution of foreland basin systems at different scales.
    Description: Published
    Description: 105634
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: 2TR. Ricostruzione e modellazione della struttura crostale
    Description: 2IT. Laboratori analitici e sperimentali
    Description: JCR Journal
    Keywords: Foreland basin system ; Forebulge unconformity ; Strontium isotope stratigraphy ; Forebulge extension ; Miocene ; Southern Apennines (Italy)
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 161
    Publication Date: 2022-06-06
    Description: Magmatic and sub-solidus fabrics in intrusive rocks are frequently used to infer the relative timing of deformation with respect to magma emplacement and cooling. Here, we describe the relationships between strain and fabric development in leucogranite sheets (pegmatite, aplite) emplaced into shear zones that localized post-thermal peak deformation in the contact aureole of an upper crustal pluton (〈0.2 GPa) on the Island of Elba, Italy. The leucogranite sheets present igneous, mylonitic, and cataclastic fabrics. Detailed meso- and microscopic structural analysis suggests that the dykes emplaced in the shear zones behaved as competent, rigid bodies during mylonitic deformation of the host rocks. Thermal modelling indicates that emplacement and cooling of the sheets occurred very rapidly (a few days to years) compared to typical tectonic strain rates and strain accumulation timescales in the host rocks. Such a fast cooling does not allow melt or magma-induced thermal softening in the host rocks during deformation. The development of mylonitic and cataclastic fabrics in the dykes was controlled by the localized activation of fluid-controlled reaction softening mechanisms (mylonitic fabric) and embrittlement during cooling in sites of high-strain (cataclastic fabric). We show that a broad spectrum of fabrics can form in igneous sheet intrusions emplaced at the same time and crustal level. The coexistence of isotropic (non-foliated igneous) versus anisotropic (mylonitic and cataclastic) fabrics in igneous sheet intrusions should therefore be evaluated in terms of tectonic strain rates, cooling rates, thermal state of the host, distribution of heterogeneous strain, and activation of strain softening mechanisms. Our observations highlight that the concepts of pre-, syn-, late- and post-tectonic fabrics in intrusive igneous rocks should be used with caution when interpreting relative timing relationships between deformation and magmatism.
    Description: Published
    Description: 104600
    Description: 1T. Struttura della Terra
    Description: JCR Journal
    Keywords: Shear zones ; Igneous sheets Magma emplacementGranite deformationPegmatite ; Magma emplacement ; Granite deformation ; Pegmatite ; Elba Island ; Emplacement of a felsic dyke swarm during progressive heterogeneous deformation
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 162
    Publication Date: 2022-06-16
    Description: Magnetic biomonitoring methodologies were applied at Villa Farnesina, Rome, a masterpiece of the Italian Renaissance, with loggias frescoed by renowned artists such as Raffaello Sanzio. Plant leaves were sampled in September and December 2020 and lichen transplants were exposed from October 2020 to early January 2021 at increasing distances from the main trafficked road, Lungotevere Farnesina, introducing an outdoor vs. indoor mixed sampling design aimed at assessing the impact of vehicular particulate matter (PM) on the Villa Loggias. The magnetic properties of leaves and lichens - inferred from magnetic susceptibility values, hysteresis loops and first order reversal curves - showed that the bioaccumulation of magnetite-like particles, associated with trace metals such as Cu, Ba and Sb, decreased exponentially with the distance from the road, and was mainly linked to metallic emission from vehicle brake abrasion. For the frescoed Halls, ca. 30 m from the road, the exposure to traffic-related emissions was very limited or negligible. Tree and shrub leaves of the Lungotevere and of the Villa's Gardens intercepted much traffic-derived PM, thus being able to protect the indoor cultural heritage and providing an essential conservation service. It is concluded that the joint use of magnetic and chemical analyses can profitably be used for evaluating the impact of particulate pollution on cultural heritage within complex metropolitan contexts as a preventive conservation measure.
    Description: Published
    Description: 153729
    Description: 1A. Geomagnetismo e Paleomagnetismo
    Description: 7A. Geofisica per il monitoraggio ambientale
    Description: JCR Journal
    Keywords: Brake wear; Cultural heritage; Lichen transplants; Magnetic biomonitoring; Preventive conservation; Traffic-related particulate matter
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 163
    Publication Date: 2022-06-09
    Description: Near-continuous monitoring both of gas emissions (CO2, CH4 and H2S) and of water temperature at Santa Venera al Pozzo thermal springs (SE foot of Mt. Etna volcano, Sicily, Italy) was conducted from December 2017 to April 2019, using a novel and cheaper Chromatography Monitoring System (CMS) coupled with a water temperature sensor. The results showed methane as predominant gas and temporal changes in gas concentrations that were in part due to daily fluctuations, which caused small amplitude variations, and in part due to non-environmental causes. These latter were correlated with the occurrence of strong earthquakes and slow tectonic events related to magmatic intrusions, but not with input of magmatic gases into the thermal aquifer, given the nonmagmatic origin of all monitored gases. Methane spikes were observed during many volcano-tectonic events and call for a deep source of this gas. H2S was detected only during the strongest local tectonic events, including a Mw 4.9 earthquake, suggesting that this gas has a common origin as CH4 (i.e., mixing between microbial and thermogenic gas), but it is released only when tectonic stress is applied for sufficiently long periods as to cause H2S oversaturation in the hydrothermal aquifer. Water temperature decreases were also observed immediately after the two strongest earthquakes in the area, which helped us produce a comprehensive model to explain the observed geochemical variations. Our approach allowed revealing the great sensitivity of gases such as CH4 and especially H2S to tectonic stress, thus making them valuable indicators of impending strong tectonic or volcanotectonic events.
    Description: Published
    Description: 229388
    Description: 9T. Geochimica dei fluidi applicata allo studio e al monitoraggio di aree sismiche
    Description: JCR Journal
    Keywords: Earthquakes ; Volcanic activity ; Geothermal systems ; Fluids ; Tectonics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 164
    Publication Date: 2022-05-24
    Description: The assessment of potential radon-hazardous environments is nowadays a critical issue in planning, monitoring, and developing appropriate mitigation strategies. Although some geological structures (e.g., fault systems) and other geological factors (e.g., radionuclide content, soil organic or rock weathering) can locally affect the radon occurrence, at the basis of a good implementation of radon-safe systems, optimized modelling at territorial scale is required. The use of spatial regression models, adequately combining different types of predictors, represents an invaluable tool to identify the relationships between radon and its controlling factors as well as to construct Geogenic Radon Potential (GRP) maps of an area. In this work, two GRP maps were developed based on field measurements of soil gas radon and thoron concentrations and gamma spectrometry of soil and rock samples of the Euganean Hills (northern Italy) district. A predictive model of radon concentration in soil gas was reconstructed taking into account the relationships among the soil gas radon and seven predictors: terrestrial gamma dose radiation (TGDR), thoron (220Rn), fault density (FD), soil permeability (PERM), digital terrain model (SLOPE), moisture index (TMI), heat load index (HLI). These predictors allowed to elaborate local spatial models by using the Empirical Bayesian Regression Kriging (EBRK) in order to find the best combination and define the GRP of the Euganean Hills area. A second GRP map based on the Neznal approach (GRPNEZ) has been modelled using the TGDR and 220Rn, as predictors of radon concentration, and FD as predictor of soil permeability. Then, the two GRP maps have been compared. Results highlight that the radon potential is mainly driven by the bedrock type but the presence of fault systems and topographic features play a key role in radon migration in the subsoil and its exhalation at the soil/atmosphere boundary.
    Description: Published
    Description: 152064
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Keywords: Euganean Hills ; Geogenic Radon Potential ; Geostatistics ; Natural radioactivity ; Radon ; Regression kriging ; 04. Solid Earth
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 165
    Publication Date: 2022-06-30
    Description: A full review of the 79 CE Plinian eruption of Vesuvius is presented through a multidisciplinary approach, exploiting the integration of historical, stratigraphic, sedimentological, petrological, geophysical, paleoclimatic, and modelling studies dedicated to this famous and devastating natural event. All studies have critically been reviewed and integrated with original data, spanning from proximal to ultradistal findings of the 79 CE eruption products throughout the Mediterranean. The work not only combines different investigation approaches (stratigraphic, petrological, geophysical, modelling), but also follows temporally the 79 CE eruptive and depo sitional events, from the magma chamber to the most distal tephras. This has allowed us first to compile a full database of all findings of those deposits, then to relate the products (the deposits) to the genetic thermo mechanical processes (the eruption), and lastly to better assess both the local and regional impacts of the 79 CE eruption in the environment. This information leads to a number of open issues (e.g., regional environmental impact vs. local pyroclastic current impact) that are worthy of further investigations, although the 79 CE eruption of Vesuvius is one of the best studied eruptions in volcanology. The structure of the work follows three macro-categories, the historical aspects, the products, and the processes of the 79 CE eruption. For each investigation approach (from stratigraphy to modelling), all dedicated studies and original data are discussed. The open issues are then synthesized in the discussion under a global view of Plinian eruptions, from the magma setting to its dispersion as pyroclasts flowing on the surface vs. falling from the volcanic plume. In this way, a lesson from the past, in particular from the well-studied 79 CE eruption of Vesuvius, will be of help for a better synchronization of processes and products in future developments. Lastly, various aspects for volcanic hazard assessment of Plinian eruptions are highlighted from the tephra distribution and modelling points of view, as these large natural phenomena can have a larger impact than previously thought, also at other active volcanoes.
    Description: Published
    Description: 104072
    Description: 1V. Storia eruttiva
    Description: 4V. Processi pre-eruttivi
    Description: 5V. Processi eruttivi e post-eruttivi
    Description: 6V. Pericolosità vulcanica e contributi alla stima del rischio
    Description: JCR Journal
    Keywords: 79 CE eruption ; Vesuvius ; Plinian eruption ; Pompeii ; Multidisciplinary approach ; Pyroclastic succession ; Pyroclastic currents ; 79 CE tephra dispersal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 166
    Publication Date: 2022-09-13
    Description: © The Author(s), 2022. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Nelson, R. K., Scarlett, A. G., Gagnon, M. M., Holman, A. I., Reddy, C. M., Sutton, P. A., & Grice, K. Characterizations and comparison of low sulfur fuel oils compliant with 2020 global sulfur cap regulation for international shipping. Marine Pollution Bulletin, 180, (2022): 113791, https://doi.org/10.1016/j.marpolbul.2022.113791.
    Description: The International Marine Organization 2020 Global Sulfur Cap requires ships to burn fuels with 〈0.50% S and some countries require 〈0.10% S in certain Sulfur Emission Control Areas but little is known about these new types of fuels. Using both traditional GC–MS and more advanced chromatographic and mass spectrometry techniques, plus stable isotopic, δ13C and δ2H, analyses of pristane, phytane and n-alkanes, the organic components of a suite of three 0.50% S and three 0.10% S compliant fuels were characterized. Two oils were found to be near identical but all of the remaining oils could be forensically distinguished by comparison of their molecular biomarkers and by the profiles of the heterocyclic parent and alkylated homologues. Oils could also be differentiated by their δ13C and δ2H of n-alkanes and isoprenoids. This study provides important forensic data that may prove invaluable in the event of future oil spills.
    Description: This research did not receive any specific grant from funding agencies in the public, commercial, or not-for-profit sectors. CMR and RKN were supported by the National Science Foundation (OCE-1634478 and OCE-1756242). GC × GC analysis support provided by WHOI's Investment in Science Fund.
    Keywords: International Maritime Organisation ; Biomarkers ; Fuel oil ; Heterocyclics ; GC × GC ; Mass spectrometry
    Repository Name: Woods Hole Open Access Server
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  • 167
    Publication Date: 2022-09-05
    Description: The chemical composition of gases emitted by active volcanoes reflects both magma degassing and shallower processes, such as fluid-rock hydrothermal interaction and mixing with atmospheric-derived fluids. Untangling the magmatic fluid endmember within surface gas emission is therefore challenging, even with the use of well-known magma degassing tracers such as noble gases. Here, we investigate the deep magmatic fluid composition at the Nisyros caldera (Aegean Arc, Greece) by measuring nitrogen and noble gas abundances and isotopes in naturally degassing fumaroles. Gas samples were collected from 32 fumarolic vents at water-boiling temperature between 2018 and 2021. These fumaroles are admixtures of magmatic fluids typical of subduction zones, groundwater (or air saturated water, ASW), and air. The N2, He, and Ar composition of the magmatic endmember is calculated by reverse mixing modeling and shows N2/He = 31.8 ± 4.5, N2/Ar = 281.6, d15N = +7 ± 3 ‰, 3He/4He = 6.2 Ra (where Ra is air 3He/4He), and 40Ar/36Ar = 551.6 ± 19.8. Although N2/He is significantly low with respect to typical values for arc volcanoes (1,000–10,000), the contribution of subducted sediments to the Aegean Arc magma generation is reflected by the positive d15N values of Nisyros fumaroles. The low N2/He ratio indicates N2-depletion due to solubility-controlled differential degassing of an upper-crustal silicic (dacitic/rhyodacitic) melt in a high-crystallinity reservoir. We compare our 2018–2021 data with N2, He, and Ar values collected from the same fumaroles during a hydrothermal unrest following the seismic crisis in 1996–1997. Results show additions of both magmatic fluid and ASW during this unrest. In the same period, fumarolic vents display an increase in magmatic species relative to hydrothermal gas, such as CO2/CH4 and He/CH4 ratios, an increase of 50 C in the equilibrium temperature of the hydrothermal system (up to 325 C), and greater amounts of vapor separation. These variations reflect an episode of magmatic fluid expulsion during the seismic crisis. The excess of heat and mass supplied by the magmatic fluid injection is then dissipated through boiling of deeper and peripheral parts of the hydrothermal system. Reverse mixing modeling of fumarolic N2-He-Ar has therefore important ramifications not only to disentangle the magmatic signature from gases emitted during periods of dormancy, but also to trace episodes of magmatic outgassing and better understand the state of the upper crustal reservoir.
    Description: Published
    Description: 68-84
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: 4V. Processi pre-eruttivi
    Description: JCR Journal
    Keywords: Noble gases ; Nitrogen isotope ; Mixing modeling ; Magmatic degassing ; High-crystallinity mush ; Caldera ; Unrest ; CO2 ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 168
    Publication Date: 2022-05-26
    Description: © The Author(s), 2019. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Renfrew, I. A., Pickart, R. S., Vage, K., Moore, G. W. K., Bracegirdle, T. J., Elvidge, A. D., Jeansson, E., Lachlan-Cope, T., McRaven, L. T., Papritz, L., Reuder, J., Sodemann, H., Terpstra, A., Waterman, S., Valdimarsson, H., Weiss, A., Almansi, M., Bahr, F., Brakstad, A., Barrell, C., Brooke, J. K., Brooks, B. J., Brooks, I. M., Brooks, M. E., Bruvik, E. M., Duscha, C., Fer, I., Golid, H. M., Hallerstig, M., Hessevik, I., Huang, J., Houghton, L., Jonsson, S., Jonassen, M., Jackson, K., Kvalsund, K., Kolstad, E. W., Konstali, K., Kristiansen, J., Ladkin, R., Lin, P., Macrander, A., Mitchell, A., Olafsson, H., Pacini, A., Payne, C., Palmason, B., Perez-Hernandez, M. D., Peterson, A. K., Petersen, G. N., Pisareva, M. N., Pope, J. O., Seidl, A., Semper, S., Sergeev, D., Skjelsvik, S., Soiland, H., Smith, D., Spall, M. A., Spengler, T., Touzeau, A., Tupper, G., Weng, Y., Williams, K. D., Yang, X., & Zhou, S. The Iceland Greenland Seas Project. Bulletin of the American Meteorological Society, 100(9), (2019): 1795-1817, doi:10.1175/BAMS-D-18-0217.1.
    Description: The Iceland Greenland Seas Project (IGP) is a coordinated atmosphere–ocean research program investigating climate processes in the source region of the densest waters of the Atlantic meridional overturning circulation. During February and March 2018, a field campaign was executed over the Iceland and southern Greenland Seas that utilized a range of observing platforms to investigate critical processes in the region, including a research vessel, a research aircraft, moorings, sea gliders, floats, and a meteorological buoy. A remarkable feature of the field campaign was the highly coordinated deployment of the observing platforms, whereby the research vessel and aircraft tracks were planned in concert to allow simultaneous sampling of the atmosphere, the ocean, and their interactions. This joint planning was supported by tailor-made convection-permitting weather forecasts and novel diagnostics from an ensemble prediction system. The scientific aims of the IGP are to characterize the atmospheric forcing and the ocean response of coupled processes; in particular, cold-air outbreaks in the vicinity of the marginal ice zone and their triggering of oceanic heat loss, and the role of freshwater in the generation of dense water masses. The campaign observed the life cycle of a long-lasting cold-air outbreak over the Iceland Sea and the development of a cold-air outbreak over the Greenland Sea. Repeated profiling revealed the immediate impact on the ocean, while a comprehensive hydrographic survey provided a rare picture of these subpolar seas in winter. A joint atmosphere–ocean approach is also being used in the analysis phase, with coupled observational analysis and coordinated numerical modeling activities underway.
    Description: The IGP has received funding from the U.S. National Science Foundation: Grant OCE-1558742; the U.K.’s Natural Environment Research Council: AFIS (NE/N009754/1); the Research Council of Norway: MOCN (231647), VENTILATE (229791), SNOWPACE (262710) and FARLAB (245907); and the Bergen Research Foundation (BFS2016REK01). We thank all those involved in the field work associated with the IGP, particularly the officers and crew of the Alliance, and the operations staff of the aircraft campaign.
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  • 169
    Publication Date: 2022-05-26
    Description: © The Author(s), 2019. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Du, J., Park, K., Yu, X., Zhang, Y. J., & Ye, F. Massive pollutants released to Galveston Bay during Hurricane Harvey: Understanding their retention and pathway using Lagrangian numerical simulations. Science of the Total Environment, 704, (2019): 135364, doi: 10.1016/j.scitotenv.2019.135364.
    Description: Increasing frequency of extreme precipitation events under the future warming climate makes the storm-related pollutant release more and more threatening to coastal ecosystems. Hurricane Harvey, a 1000-year extreme precipitation event, caused massive pollutant release from the Houston metropolitan area to the adjacent Galveston Bay. 0.57 × 106 tons of raw sewage and 22,000 barrels of oil, refined fuels and chemicals were reportly released during Harvey, which would likely deteriorate the water quality and damage the coastal ecosystem. Using a Lagrangian particle-tracking method coupled with a validated 3D hydrodynamic model, we examined the retention, pathway, and fate of the released pollutants. A new timescale, local exposure time (LET), is introduced to quantitatively evaluate the spatially varying susceptibility inside the bay and over the shelf, with a larger LET indicating the region is more susceptible to the released pollutants. We found LET inside the bay is at least one order of magnitude larger for post-storm release than storm release due to a quick recovery in the system's flushing. More than 90% of pollutants released during the storm exited the bay within two days, while those released after the storm could stay inside the bay for up to three months. This implies that post-storm release is potentially more damaging to water quality and ecosystem health. Our results suggest that not only the amount of total pollutant load but also the release timing should be considered when assessing a storm's environmental and ecological influence, because there could be large amounts of pollutants steadily and slowly discharged after storm through groundwater, sewage systems, and reservoirs.
    Description: We like to acknowledge the Texas Coastal Management Program, the Texas General Land Office and NOAA for partial funding of this project through CMP Contract #19-040-000-B074. This work was performed using computing facilities at the College of William and Mary, which were provided by contributions from the National Science Foundation, the Commonwealth of Virginia Equipment Trust Fund and the Office of Naval Research.
    Keywords: Storm discharge ; Retention ; Local exposure time ; Particle tracking ; SCHISM
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  • 170
    Publication Date: 2022-05-26
    Description: Author Posting. © American Meteorological Society, 2019. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 49(12), (2019): 3127-3143, doi: 10.1175/JPO-D-19-0011.1.
    Description: The Intermediate Western Boundary Current (IWBC) transports Antarctic Intermediate Water across the Vitória–Trindade Ridge (VTR), a seamount chain at ~20°S off Brazil. Recent studies suggest that the IWBC develops a strong cyclonic recirculation in Tubarão Bight, upstream of the VTR, with weak time dependency. We herein use new quasi-synoptic observations, data from the Argo array, and a regional numerical model to describe the structure and variability of the IWBC and to investigate its dynamics. Both shipboard acoustic Doppler current profiler (ADCP) data and trajectories of Argo floats confirm the existence of the IWBC recirculation, which is also captured by our Regional Oceanic Modeling System (ROMS) simulation. An “intermediate-layer” quasigeostrophic (QG) model indicates that the ROMS time-mean flow is a good proxy for the IWBC steady state, as revealed by largely parallel isolines of streamfunction ψ⎯ and potential vorticity Q⎯; a ψ⎯−Q⎯ scatter diagram also shows that the IWBC is potentially unstable. Further analysis of the ROMS simulation reveals that remotely generated, westward-propagating nonlinear eddies are the main source of variability in the region. These eddies enter the domain through the Tubarão Bight eastern edge and strongly interact with the IWBC. As they are advected downstream and negotiate the local topography, the eddies grow explosively through horizontal shear production.
    Description: We thank Frank O. Smith for copy editing and proofreading this manuscript. This study was financed in part by Coordenação de Aperfeiçoamento de Pessoal de Nível Superior—CAPES, Brazil—Finance Code 001 and by Projeto REMARSUL (Processo CAPES 88882.158621/2014-01), Projeto VT-Dyn (Processo FAPESP 2015/21729-4) and Projeto SUBMESO (Processo CNPq 442926/2015-4). Rocha was supported by a WHOI Postdoctoral Scholarship.
    Description: 2020-06-06
    Keywords: South Atlantic Ocean ; Instability ; Mesoscale processes ; Intermediate waters ; In situ oceanic observations ; Quasigeostrophic models
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  • 171
    Publication Date: 2022-05-26
    Description: © The Author(s), 2019. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Mundl-Petermeier, A., Walker, R. J., Jackson, M. G., Blichert-Toft, J., Kurz, M. D., & Halldorsson, S. A. Temporal evolution of primordial tungsten-182 and he-3/He-4 signatures in the Iceland mantle plume. Chemical Geology, 525, (2019): 245-259. doi: 10.1016/j.chemgeo.2019.07.026.
    Description: Studies of short-lived radiogenic isotope systems and noble gas isotopic compositions of plume-derived rocks suggest the existence of primordial domains in Earth's present-day mantle. Tungsten-182 anomalies together with high 3He/4He in Phanerozoic rocks from large igneous provinces and ocean island basalts demonstrate the preservation of early-formed (within the first 60 Ma of solar system history) mantle domains tapped by modern mantle plumes. It has proven difficult to link the evidence for primordial domains with geochemical evidence for more recent processes, such as recycling. The Greenland-Iceland plume system, starting with eruptions of the Paleocene North Atlantic Igneous Province, is later manifested in the mid-Miocene to modern volcanic products of Iceland. Here, we report Pb isotopic compositions, μ182W (deviations in 182W/184W of a sample from a laboratory reference standard in parts per million), and 3He/4He, as well as highly siderophile element concentrations and Re-Os isotopic systematics of basaltic samples erupted at different times during the ~60 Ma history of the Greenland-Iceland plume. Paleocene samples from Greenland, representing the early stage of the mantle plume, are characterized by variable 3He/4He ranging from 7 to 48 R/RA (measured 3He/4He normalized to the atmospheric ratio) and an average μ182W of −4.0 ± 3.6 (2SD), within modern upper mantle-like values of 0 ± 4.5. The basalts from Iceland can be divided into two groups based on their Pb isotope compositions. One group, consisting mostly of Miocene basalts, is characterized by 206Pb/204Pb ranging from ~18.4 to 18.5, 3He/4He ranging from 17.8 to 40.2 R/RA, and μ182W values ranging from +1.7 to −9.1 ± 4.5. The other group, consisting mainly of Pleistocene and Holocene basalts, is characterized by higher 206Pb/204Pb, ranging from ~18.7 to 19.2, 3He/4He ranging from 7.9 to 25.7 R/RA, and μ182W values ranging from −0.6 to −11.7 ± 4.5. Collectively, the Greenland-Iceland suite examined requires mixing between a minimum of three mantle source domains characterized by distinct Pb-He-W isotopic compositions, in order to account for this range of isotopic data. The temporal changes in the isotopic data for these rocks appear to track the dominant contributing plume components as the system evolved. One of the domains is indistinguishable from the ambient upper oceanic mantle and contributed substantial material throughout the time progression. The other two domains are most likely primordial reservoirs that underwent limited de-gassing. Given the negative μ182W values in some rocks, one of these domains likely formed within the first 60 Ma of solar system history and is a major contributor to the youngest basalts. The isotopic characteristics of Greenland-Iceland plume-derived rocks reveal episodic changes in the source component proportions.
    Description: This study was supported by NSF grant EAR-1624587 (to RJW and AMP). AMP acknowledges FWF grant V659-N29. MJ acknowledges NSF grant EAR-1624840, and MK acknowledges OCE-1259218. We would like to thank Lotte M. Larsen and Asger K. Pedersen for providing the West Greenland samples, and Bernard Marty for the samples from East Greenland. We thank Catherine Chauvel for the editorial handling and Rita Parai, Dominique Weis, David Graham and an anonymous reviewer for the helpful and constructive comments on this and an earlier version of the manuscript.
    Keywords: μ182W ; Iceland ; Mantle plume ; 3He/4He ; Primordial reservoir
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  • 172
    Publication Date: 2022-05-26
    Description: © The Author(s), 2020. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Wheat, C. G., Seewald, J. S., & Takai, K. Fluid transport and reaction processes within a serpentinite mud volcano: South Chamorro Seamount. Geochimica Et Cosmochimica Acta, 269, (2020): 413-428, doi: 10.1016/j.gca.2019.10.037
    Description: Natural fluids with a pH (25 °C) up to 12.3 were collected from a sub-seafloor borehole observatory (Ocean Drilling Program (ODP) Hole 1200C) on South Chamorro Seamount, a serpentinite mud volcano in the Mariana forearc. We used systematic differences in the chemical compositions of pore waters from drilling operations during ODP Leg 195 and borehole fluids collected subsequently from Hole 1200C to define two endmember solutions, one of which was a sulfate-rich fluid with a methane concentration of 50 mM that ascends from the subduction channel and the other was a low-sulfate fluid. The sequence of sample collection and fluid compositions constrain subsurface hydrologic conditions. Deep-sourced, sulfate- and methane-rich, sterile fluids from the subduction channel can reach the seafloor unchanged within the central conduit, whereas other fluid pathways likely intersect the pelagic sediment that underlies the serpentinite mud volcano, providing potentially suitable conditions and inoculum for microbial anaerobic oxidation of methane (AOM). These AOM-affected, low-sulfate fluids also make it to the seafloor where they discharge. The source of the sulfate- and methane-rich fluid in the subduction channel is attributed to abiotic methane production fueled by hydrogen production from serpentinization and carbonate dissolution. This methane production includes a mechanism to raise the pH above values from serpentinization alone. Results from South Chamorro Seamount represent an end member along a transect defined by the distance from the trench. Results from this site are applied to other serpentinite mud volcanoes along this transect to speculate on likely chemical conditions within shallower and cooler portions of the subduction channel.
    Description: The authors thank the entire shipboard parties of cruises NT09-01 and NT09-07 on the R/V Nastushima and the crews and pilots of the ROV HyperDolphin. We also thank Tom Pettigrew for removing the dummy plug and designing the insert for the borehole. This research was supported by the National Science Foundation (OCE-0727120 and 1439564 (CGW) and OCE--0725204 (JS)) and the Japan Agency for Marine-Earth Science and Technology. This is C-DEBI contribution 497.
    Keywords: Serpentinization ; Mud volcano ; Subduction ; Mariana forearc ; Dissolved gases ; Anaerobic methane oxidation
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  • 173
    Publication Date: 2022-05-26
    Description: © The Author(s), 2019. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Kwon, Y., Seo, H., Ummenhofer, C. C., & Joyce, T. M. Impact of multidecadal variability in Atlantic SST on winter atmospheric blocking. Journal of Climate, 33(3), (2020): 867-892, doi: 10.1175/JCLI-D-19-0324.1.
    Description: Recent studies have suggested that coherent multidecadal variability exists between North Atlantic atmospheric blocking frequency and the Atlantic multidecadal variability (AMV). However, the role of AMV in modulating blocking variability on multidecadal times scales is not fully understood. This study examines this issue primarily using the NOAA Twentieth Century Reanalysis for 1901–2010. The second mode of the empirical orthogonal function for winter (December–March) atmospheric blocking variability in the North Atlantic exhibits oppositely signed anomalies of blocking frequency over Greenland and the Azores. Furthermore, its principal component time series shows a dominant multidecadal variability lagging AMV by several years. Composite analyses show that this lag is due to the slow evolution of the AMV sea surface temperature (SST) anomalies, which is likely driven by the ocean circulation. Following the warm phase of AMV, the warm SST anomalies emerge in the western subpolar gyre over 3–7 years. The ocean–atmosphere interaction over these 3–7-yr periods is characterized by the damping of the warm SST anomalies by the surface heat flux anomalies, which in turn reduce the overall meridional gradient of the air temperature and thus weaken the meridional transient eddy heat flux in the lower troposphere. The anomalous transient eddy forcing then shifts the eddy-driven jet equatorward, resulting in enhanced Rossby wave breaking and blocking on the northern flank of the jet over Greenland. The opposite is true with the AMV cold phases but with much shorter lags, as the evolution of SST anomalies differs in the warm and cold phases.
    Description: We gratefully acknowledge support from the NSF Climate and Large-scale Dynamics Program (AGS-1355339) to Y-OK, HS, CCU, and TMJ, the NASA Physical Oceanography Program (NNX13AM59G) to Y-OK, HS, and TMJ, NOAA CPO Climate Variability and Predictability Program (NA13OAR4310139) and DOE CESD Regional and Global Model Analysis Program (DE-SC0019492) to Y-OK, and NSF Physical Oceanography Program (OCE-1419235) to HS. We are very grateful to the three anonymous reviewers and editor Dr. Mingfang Ting, for their thorough and insightful suggestions. The NOAA 20CR dataset was downloaded from the NOAA Earth System Research Laboratory Physical Science Division webpage (https://www.esrl.noaa.gov/psd/data/20thC_Rean/). Support for the 20CR Project version 2c dataset is provided by the U.S. Department of Energy, Office of Science Biological and Environmental Research (BER), and by the National Oceanic and Atmospheric Administration Climate Program Office. The HadISST dataset was downloaded from the U.K. Met Office Hadley Centre webpage (https://www.metoffice.gov.uk/hadobs/hadisst/). The ERA-20C dataset was downloaded from the ECMWF webpage (https://apps.ecmwf.int/datasets/data/era20c-daily/). The ERSST5 dataset was provided by the NOAA Earth System Research Laboratory Physical Science Division (https://www.esrl.noaa.gov/psd/data/gridded/data.noaa.ersst.v5.html).
    Keywords: North Atlantic Ocean ; Atmosphere-ocean interaction ; Blocking ; Climate variability ; Multidecadal variability ; North Atlantic Oscillation
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  • 174
    Publication Date: 2022-05-26
    Description: Author Posting. © American Meteorological Society, 2020. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 50(2), (2020): 415-437, doi:10.1175/JPO-D-19-0019.1.
    Description: Results are presented from two dye release experiments conducted in the seasonal thermocline of the Sargasso Sea, one in a region of low horizontal strain rate (~10−6 s−1), the second in a region of intermediate horizontal strain rate (~10−5 s−1). Both experiments lasted ~6 days, covering spatial scales of 1–10 and 1–50 km for the low and intermediate strain rate regimes, respectively. Diapycnal diffusivities estimated from the two experiments were κz = (2–5) × 10−6 m2 s−1, while isopycnal diffusivities were κH = (0.2–3) m2 s−1, with the range in κH being less a reflection of site-to-site variability, and more due to uncertainties in the background strain rate acting on the patch combined with uncertain time dependence. The Site I (low strain) experiment exhibited minimal stretching, elongating to approximately 10 km over 6 days while maintaining a width of ~5 km, and with a notable vertical tilt in the meridional direction. By contrast, the Site II (intermediate strain) experiment exhibited significant stretching, elongating to more than 50 km in length and advecting more than 150 km while still maintaining a width of order 3–5 km. Early surveys from both experiments showed patchy distributions indicative of small-scale stirring at scales of order a few hundred meters. Later surveys show relatively smooth, coherent distributions with only occasional patchiness, suggestive of a diffusive rather than stirring process at the scales of the now larger patches. Together the two experiments provide important clues as to the rates and underlying processes driving diapycnal and isopycnal mixing at these scales.
    Description: Results are presented from two dye release experiments conducted in the seasonal thermocline of the Sargasso Sea, one in a region of low horizontal strain rate (~10−6 s−1), the second in a region of intermediate horizontal strain rate (~10−5 s−1). Both experiments lasted ~6 days, covering spatial scales of 1–10 and 1–50 km for the low and intermediate strain rate regimes, respectively. Diapycnal diffusivities estimated from the two experiments were κz = (2–5) × 10−6 m2 s−1, while isopycnal diffusivities were κH = (0.2–3) m2 s−1, with the range in κH being less a reflection of site-to-site variability, and more due to uncertainties in the background strain rate acting on the patch combined with uncertain time dependence. The Site I (low strain) experiment exhibited minimal stretching, elongating to approximately 10 km over 6 days while maintaining a width of ~5 km, and with a notable vertical tilt in the meridional direction. By contrast, the Site II (intermediate strain) experiment exhibited significant stretching, elongating to more than 50 km in length and advecting more than 150 km while still maintaining a width of order 3–5 km. Early surveys from both experiments showed patchy distributions indicative of small-scale stirring at scales of order a few hundred meters. Later surveys show relatively smooth, coherent distributions with only occasional patchiness, suggestive of a diffusive rather than stirring process at the scales of the now larger patches. Together the two experiments provide important clues as to the rates and underlying processes driving diapycnal and isopycnal mixing at these scales.
    Description: 2020-08-06
    Keywords: Ocean ; Atlantic Ocean ; Diapycnal mixing ; Diffusion ; Dispersion ; Mixing
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  • 175
    Publication Date: 2022-05-26
    Description: Author Posting. © American Meteorological Society, 2020. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of the Atmospheric and Oceanic Technology 37(5), (2020): 789-806, doi:10.1175/JTECH-D-18-0244.1.
    Description: Realistic ocean state prediction and its validation rely on the availability of high quality in situ observations. To detect data errors, adequate quality check procedures must be designed. This paper presents procedures that take advantage of the ever-growing observation databases that provide climatological knowledge of the ocean variability in the neighborhood of an observation location. Local validity intervals are used to estimate binarily whether the observed values are considered as good or erroneous. Whereas a classical approach estimates validity bounds from first- and second-order moments of the climatological parameter distribution, that is, mean and variance, this work proposes to infer them directly from minimum and maximum observed values. Such an approach avoids any assumption of the parameter distribution such as unimodality, symmetry around the mean, peakedness, or homogeneous distribution tail height relative to distribution peak. To reach adequate statistical robustness, an extensive manual quality control of the reference dataset is critical. Once the data have been quality checked, the local minima and maxima reference fields are derived and the method is compared with the classical mean/variance-based approach. Performance is assessed in terms of statistics of good and bad detections. It is shown that the present size of the reference datasets allows the parameter estimates to reach a satisfactory robustness level to always make the method more efficient than the classical one. As expected, insufficient robustness persists in areas with an especially low number of samples and high variability.
    Description: This study has been conducted using EU Copernicus Marine Service Information and was supported by the European Union within the EU Copernicus Marine Service In Situ phase-I and phase-II contracts led by Ifremer. The publication was also supported by SOERE CTDO2 in France. The Argo data were collected and made freely available by the International Argo Program and the national programs that contribute to it (see http://www.argo.ucsd.edu, http://argo.jcommops.org). The Argo Program is part of the Global Ocean Observing System (http://doi.org/10.17882/42182). The marine mammal data were collected and made freely available by the International MEOP Consortium and the national programs that contribute to it (see http://www.meop.net; https://doi.org/10.17882/45461). Aleix Gelabert and Dídac Costa were the skippers of the OPOO, sponsored by the Intergovernmental Oceanographic Commission (UNESCO) and Pharmaton. The BWR is a periodic oceanic race organized by the Fundació Navegació Oceànica de Barcelona (FNOB). Reviewer D. Briand provided some useful comments on the final version of the draft paper before submission.
    Description: 2020-11-04
    Keywords: Ocean ; Climatology ; Salinity ; Temperature ; Data quality control ; Oceanic variability
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  • 176
    Publication Date: 2022-05-26
    Description: Author Posting. © American Meteorological Society, 2020. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 50(5), (2020): 1245-1263, doi:10.1175/JPO-D-19-0213.1.
    Description: We use laboratory experiments and theoretical modeling to investigate the surface expression of a subglacial discharge plume, as occurs at many fjords around Greenland. The experiments consider a fountain that is released vertically into a homogeneous fluid, adjacent either to a vertical or a sloping wall, that then spreads horizontally at the free surface before sinking back to the bottom. We present a model that separates the fountain into two separate regions: a vertical fountain and a horizontal, negatively buoyant jet. The model is compared to laboratory experiments that are conducted over a range of volume fluxes, density differences, and ambient fluid depths. It is shown that the nondimensionalized length, width, and aspect ratio of the surface expression are dependent on the Froude number, calculated at the start of the negatively buoyant jet. The model is applied to observations of the surface expression from a Greenland subglacial discharge plume. In the case where the discharge plume reaches the surface with negative buoyancy the model can be used to estimate the discharge properties at the base of the glacier.
    Description: We gratefully acknowledge technical assistance from Anders Jensen and thank anonymous reviewers for improving the clarity of the manuscript. CM thanks the Weston Howard Jr. Scholarship for funding. Support to CC was given by NSF project OCE-1434041 and OCE-1658079.
    Description: 2020-10-27
    Keywords: Ocean ; Glaciers ; Ice sheets ; Convection ; Laboratory/physical models
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  • 177
    Publication Date: 2022-05-26
    Description: Author Posting. © American Meteorological Society, 2020. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 50(3), (2020): 679-694, doi:10.1175/JPO-D-19-0218.1.
    Description: The zonally integrated flow in a basin can be separated into the divergent/nondivergent parts, and a uniquely defined meridional overturning circulation (MOC) can be calculated. For a basin with significant volume exchange at zonal open boundaries, this method is competent in removing the components associated with the nonzero source terms due to zonal transports at open boundaries. This method was applied to the zonally integrated flow in the Indian Ocean basin extended all the way to the Antarctic by virtue of the ECCO dataset. The contributions due to two major zonal flow systems at open boundaries, the Indonesian Throughflow (ITF) and the Antarctic Circumpolar Current (ACC), were well separated from the rotational flow component, and a nondivergent overturning circulation pattern was identified. Comparisons with previous studies on the MOC of the Indian Ocean in different seasons showed overall consistency but with refinements in details to the south of the entry of the ITF, reflecting the influence of ITF on the MOC pattern in the domain. Other options of decomposition are also examined.
    Description: LH was supported by the National Basic Research Program of China through Grant 2019YFA0606703 and “The Fundamental Research Funds of Shandong University” (2019GN051). The authors thank the anonymous reviewers and the editor for their constructive comments. Code availability: The Matlab code that performs the decomposition and produces some figures in this paper is available at https://github.com/lei-han-SDU/IMOC/.
    Description: 2020-09-02
    Keywords: Meridional overturning circulation ; Ocean circulation ; Streamfunction
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  • 178
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    American Meteorological Society
    Publication Date: 2022-05-26
    Description: Author Posting. © American Meteorological Society, 2020. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 50(9), (2020): 2491-2506, doi:10.1175/JPO-D-20-0056.1.
    Description: An idealized two-layer shallow water model is applied to the study of the dynamics of the Arctic Ocean halocline. The model is forced by a surface stress distribution reflective of the observed wind stress pattern and ice motion and by an inflow representing the flow of Pacific Water through Bering Strait. The model reproduces the main elements of the halocline circulation: an anticyclonic Beaufort Gyre in the western basin (representing the Canada Basin), a cyclonic circulation in the eastern basin (representing the Eurasian Basin), and a Transpolar Drift between the two gyres directed from the upwind side of the basin to the downwind side of the basin. Analysis of the potential vorticity budget shows a basin-averaged balance primarily between potential vorticity input at the surface and dissipation at the lateral boundaries. However, advection is a leading-order term not only within the anticyclonic and cyclonic gyres but also between the gyres. This means that the eastern and western basins are dynamically connected through the advection of potential vorticity. Both eddy and mean fluxes play a role in connecting the regions of potential vorticity input at the surface with the opposite gyre and with the viscous boundary layers. These conclusions are based on a series of model runs in which forcing, topography, straits, and the Coriolis parameter were varied.
    Description: This study was supported by National Science Foundation Grant OPP-1822334. Comments and suggestions from two anonymous referees greatly helped to improve the paper.
    Description: 2021-02-17
    Keywords: Eddies ; Ekman pumping/transport ; Ocean circulation ; Ocean dynamics ; Potential vorticity ; Shallow-water equations
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  • 179
    Publication Date: 2022-05-26
    Description: © The Author(s), 2020. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Melle, W., Klevjer, T., Strand, E., Wiebe, P. H., Slotte, A., & Huse, G. Fine-scale observations of physical and biological environment along a herring feeding migration route. Deep-Sea Research Part II: Topical Studies in Oceanography, 180, (2020): 104845, doi:10.1016/j.dsr2.2020.104845.
    Description: We observed herring horizontal and vertical distribution during feeding migration along a 128 km transect across the Arctic front of the Norwegian and Iceland seas, in early June, in relation to its physical, chemical and biological environment, distribution of prey organisms and pelagic and mesopelagic competitors. The Norwegian Spring Spawning herring is one of the largest and economically most important stocks of pelagic fish in the world and understanding what controls its feeding migration is, and has been for centuries, a major research question that also has major implications for management. High resolution ecosystem data were obtained by hull mounted multi-frequency acoustics and a towed platform undulating between 10 and 400 m equipped with multi-frequency acoustics, temperature, salinity and fluorescence sensors, an Optical Plankton Counter and a Video Plankton Recorder. Additional sampling was done by MOCNESS, Macroplankton trawl, and CTD equipped with water bottles for temperature, salinity, nutrients and chlorophyll at discrete stations along the transect. Biological characteristics and stomach content of the herring were obtained from samples at discrete trawl stations. The Arctic front proved to be an important transitional zone in zooplankton biomass, abundance and diversity. Phenology of phyto- and zooplankton also changed across the front, being somewhat delayed on the cold side. The herring were distributed all along the transect showing a shallow distribution on the warm side and both deep and shallow on the cold side, not clearly related to light and time of the day. The herring stomach content was higher on the cold side. There was no significant pattern in average age, weight, or body length of the herring along the transect. The herring were present and fed in the area of the transect during the time when the overwintering generation of Calanus finmarchicus dominated, before the development of the new generation of the year. We suggest that the phenology of C. finmarchicus can be an important driver of the herring feeding migration. While prey-availability was higher on the Arctic side of the front, light conditions for visual feeding at depth were probably better on the Atlantic side. The herring did not show classical dial vertical migration, but its prey did, and the herring's prey were probably available within the upper 100 m during the course of a 24 h cycle. With a general westward direction of migration, the herring along the transect moved towards lower temperatures and temperature did not seem to be a probable driver for migration. We conclude that fine-scale studies of herring migration and feeding can increase our understanding of the migratory processes and add to our understanding of large-scale distributional patterns, changes therein, and herring trophodynamics and ecological role. The fine-resolution parameters can also be important as input to ecosystem models.
    Description: We would also like to acknowledge the funding from Euro-BASIN, EU FP7, Grant agreement No 264933, HARMES, Research Council of Norway project number 280546 and MEESO, EU H2020 research and innovation programme, Grant Agreement No 817669.
    Keywords: Herring ; Feeding migration ; Environment ; Prey distribution ; Fine-scale observation
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  • 180
    Publication Date: 2022-05-26
    Description: Author Posting. © American Meteorological Society, 2020. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Bulletin of the American Meteorological Society 101(6), (2020): E897-E904, doi:10.1175/BAMS-D-19-0047.1.
    Description: Over the past 15 years, numerous studies have suggested that the sinking branches of Earth’s Hadley circulation and the associated subtropical dry zones have shifted poleward over the late twentieth century and early twenty-first century. Early estimates of this tropical widening from satellite observations and reanalyses varied from 0.25° to 3° latitude per decade, while estimates from global climate models show widening at the lower end of the observed range. In 2016, two working groups, the U.S. Climate Variability and Predictability (CLIVAR) working group on the Changing Width of the Tropical Belt and the International Space Science Institute (ISSI) Tropical Width Diagnostics Intercomparison Project, were formed to synthesize current understanding of the magnitude, causes, and impacts of the recent tropical widening evident in observations. These working groups concluded that the large rates of observed tropical widening noted by earlier studies resulted from their use of metrics that poorly capture changes in the Hadley circulation, or from the use of reanalyses that contained spurious trends. Accounting for these issues reduces the range of observed expansion rates to 0.25°–0.5° latitude decade‒1—within the range from model simulations. Models indicate that most of the recent Northern Hemisphere tropical widening is consistent with natural variability, whereas increasing greenhouse gases and decreasing stratospheric ozone likely played an important role in Southern Hemisphere widening. Whatever the cause or rate of expansion, understanding the regional impacts of tropical widening requires additional work, as different forcings can produce different regional patterns of widening.
    Description: We thank U.S. CLIVAR and ISSI for funding the two working groups. We thank all members of the working groups for helpful discussions, and the U.S. CLIVAR and ISSI offices and their sponsoring agencies (NASA, NOAA, NSF, DOE, ESA, Swiss Confederation, Swiss Academy of Sciences, and University of Bern) for supporting these groups and activities.
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  • 181
    Publication Date: 2022-05-26
    Description: © The Author(s), 2020. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Horowitz, E. J., Cochran, J. K., Bacon, M. P., & Hirschberg, D. J. 210Po and 210Pb distributions during a phytoplankton bloom in the North Atlantic: implications for POC export. Deep-Sea Research Part I: Oceanographic Research Papers, 164, (2020): 103339, doi:10.1016/j.dsr.2020.103339.
    Description: During the North Atlantic Bloom Experiment (NABE) of the Joint Global Ocean Flux Study (JGOFS), water column sampling for particulate and dissolved 210Po and 210Pb was performed four times (26 April and 4, 20, 30 May 1989) during a month-long Lagrangian time-series occupation of the NABE site, as well as one-time samplings at stations during transit to and from the site. There are few prior studies documenting short-term changes in 210Po and 210Pb profiles over the course of a phytoplankton bloom, and we interpret the profiles in terms of the classical “steady-state” (SS) approach used in most studies, as well as by using a non-steady state approach suggested by the temporal evolution of the profiles. Changes in 210Po profiles during a bloom are expectable as this radionuclide is scavenged and exported. During NABE, 210Pb profiles also displayed non-steady state, with significant increases in upper water column inventory occurring midway through the experiment. Export of 210Po from the upper 150 m using the classic “steady-state” model shows increases from 0.5 ± 8.5 dpm m−2 d−1 to 68.2 ± 4.2 dpm m−2 d−1 over the ~one-month occupation. Application of a non-steady state model, including changes in both 210Pb and 210Po profiles, gives higher 210Po export fluxes. Detailed depth profiles of particulate organic carbon (〉0.8 μm) and particulate 210Po (〉0.4 μm) are available from the 20 and 30 May samplings and show maxima in POC/Po at ~37 m. Applying the POC/210Po ratios at 150 m to the “steady state” 210Po fluxes yields POC export from the upper 150 m of 8.2 ± 1.5 mmol C m− 2 d−1 on 20 May and 6.0 ± 1.6 mmol C m−2 d−1 on 30 May. The non-steady state model applied to the interval 20 to 30 May yields POC export of 24.3 mmol C m−2 d−1. The non-steady state (NSS) 210Po-derived POC fluxes are comparable to, but somewhat less than, those estimated previously from 234Th/238U disequilibrium for the same time interval (37.3 and 45.0 mmol m−2 d−1, depending on the POC/Th ratio used). In comparison, POC fluxes measured with a floating sediment trap deployed at 150 m from 20 to 30 May were 11.6 mmol m−2 d−1. These results suggest that non-steady state Po-derived POC fluxes during the NABE agree well with those derived from 234Th/238U disequilibrium and agree with sediment trap fluxes within a factor of ~2. However, unlike the 234Th-POC flux proxy, non-steady stage changes in profiles of 210Pb, the precursor of 210Po, must be considered.
    Description: We are grateful to T. Hammar and A. Fleer (WHOI) for assistance at sea and in the laboratory. This work was supported originally by National Science Foundation (United States) grant OCE-8819544 to JKC and more recently by OCE-1736591. We thank Stephen Thurston (American Museum of Natural History) for graphics assistance Robert Aller, Steven Beaupre, and two anonymous reviewers for helpful comments.
    Keywords: Polonium-210 ; Lead-210 ; 210Po ; 210Pb ; North Atlantic ; Spring bloom ; POC flux
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  • 182
    Publication Date: 2022-05-26
    Description: © The Author(s), 2020. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Lin, P., Pickart, R. S., Fissel, D., Ross, E., Kasper, J., Bahr, F., Torres, D. J., O'Brien, J., Borg, K., Melling, H., & Wiese, F. K. Circulation in the vicinity of Mackenzie Canyon from a year-long mooring array. Progress in Oceanography, 187, (2020): 102396, doi:10.1016/j.pocean.2020.102396.
    Description: Data from a five-mooring array extending from the inner shelf to the continental slope in the vicinity of Mackenzie Canyon, Beaufort Sea are analyzed to elucidate the components of the boundary current system and their variability. The array, part of the Marine Arctic Ecosystem Study (MARES), was deployed from October 2016 to September 2017. Four distinct currents were identified: an eastward-directed flow adjacent to the coast; a westward-flowing, surface-intensified current centered on the outer-shelf; a bottom-intensified shelfbreak jet flowing to the east; and a recirculation at the base of the continental slope within the canyon. The shelf current transports −0.120.03 Sv in the mean and is primarily wind-driven. The response is modulated by the presence of ice, with little-to-no signal during periods of nearly-immobile ice cover and maximum response when there is partial ice cover. The shelfbreak jet transports 0.030.02 Sv in the mean, compared to 0.080.02 Sv measured upstream in the Alaskan Beaufort Sea over the same time period. The loss of transport is consistent with a previous energetics analysis and the lack of Pacific-origin summer water downstream. The recirculation in the canyon appears to be the result of local dynamics whereby a portion of the westward-flowing southern limb of the Beaufort Gyre is diverted up the canyon across isobaths. This interpretation is supported by the fact that the low-frequency variability of the recirculation is correlated with the wind-stress curl in the Canada Basin, which drives the Beaufort gyre.
    Description: The authors are indebted to Fisheries and Oceans Canada for building the logistics for MARES into the at-sea missions of the Integrated Beaufort Observatory. We are grateful to the captain and crew of the CCGS Sir Wilfred Laurier for ably deploying and recovering the MARES array. Marshall Swartz assisted with the cruise preparation logistics. We thank the two anonymous reviewers for their input which helped improve the paper. This project was funded by the US Bureau of Ocean Energy Management (BOEM), on behalf of the National Ocean Partnership Program. The Canadian contribution was supported by the Environmental Studies Research Fund (ESRF Project 2014-02N). MARES publication 003.
    Keywords: Canadian Beaufort Sea ; Mackenzie Canyon ; Boundary currents ; Canyon circulation ; Ice-ocean interaction
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  • 183
    Publication Date: 2022-05-26
    Description: Author Posting. © American Meteorological Society, 2020. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 50(4), (2020): 887-905, doi:10.1175/JPO-D-19-0110.1.
    Description: The Equatorial Undercurrent (EUC) encounters the Galápagos Archipelago on the equator as it flows eastward across the Pacific. The impact of the Galápagos Archipelago on the EUC in the eastern equatorial Pacific remains largely unknown. In this study, the path of the EUC as it reaches the Galápagos Archipelago is measured directly using high-resolution observations obtained by autonomous underwater gliders. Gliders were deployed along three lines that define a closed region with the Galápagos Archipelago as the eastern boundary and 93°W from 2°S to 2°N as the western boundary. Twelve transects were simultaneously occupied along the three lines during 52 days in April–May 2016. Analysis of individual glider transects and average sections along each line show that the EUC splits around the Galápagos Archipelago. Velocity normal to the transects is used to estimate net horizontal volume transport into the volume. Downward integration of the net horizontal transport profile provides an estimate of the time- and areal-averaged vertical velocity profile over the 52-day time period. Local maxima in vertical velocity occur at depths of 25 and 280 m with magnitudes of (1.7 ± 0.6) × 10−5 m s−1 and (8.0 ± 1.6) × 10−5 m s−1, respectively. Volume transport as a function of salinity indicates that water crossing 93°W south (north) of 0.4°S tends to flow around the south (north) side of the Galápagos Archipelago. Comparisons are made between previous observational and modeling studies with differences attributed to effects of the strong 2015/16 El Niño event, the annual cycle of local winds, and varying longitudes between studies of the equatorial Pacific.
    Description: This work was supported by National Science Foundation (Grants OCE-1232971 and OCE-1233282) and the NASA Earth and Space Science Fellowship Program (Grant 80NSSC17K0443).
    Keywords: Tropics ; Boundary currents ; Topographic effects ; Transport ; Upwelling/downwelling ; In situ oceanic observations
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  • 184
    Publication Date: 2022-05-26
    Description: Author Posting. © American Meteorological Society, 2020. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 50(10), (2020): 2849-2871, https://doi.org/10.1175/JPO-D-20-0086.1.
    Description: The structure, transport, and seasonal variability of the West Greenland boundary current system near Cape Farewell are investigated using a high-resolution mooring array deployed from 2014 to 2018. The boundary current system is comprised of three components: the West Greenland Coastal Current, which advects cold and fresh Upper Polar Water (UPW); the West Greenland Current, which transports warm and salty Irminger Water (IW) along the upper slope and UPW at the surface; and the Deep Western Boundary Current, which advects dense overflow waters. Labrador Sea Water (LSW) is prevalent at the seaward side of the array within an offshore recirculation gyre and at the base of the West Greenland Current. The 4-yr mean transport of the full boundary current system is 31.1 ± 7.4 Sv (1 Sv ≡ 106 m3 s−1), with no clear seasonal signal. However, the individual water mass components exhibit seasonal cycles in hydrographic properties and transport. LSW penetrates the boundary current locally, through entrainment/mixing from the adjacent recirculation gyre, and also enters the current upstream in the Irminger Sea. IW is modified through air–sea interaction during winter along the length of its trajectory around the Irminger Sea, which converts some of the water to LSW. This, together with the seasonal increase in LSW entering the current, results in an anticorrelation in transport between these two water masses. The seasonality in UPW transport can be explained by remote wind forcing and subsequent adjustment via coastal trapped waves. Our results provide the first quantitatively robust observational description of the boundary current in the eastern Labrador Sea.
    Description: A.P., R.S.P., F.B., D.J.T., and A.L.R. were funded by Grants OCE-1259618 and OCE-1756361 from the National Science Foundation. I.L.B, F.S., and J.H. were supported by U.S. National Science Foundation Grants OCE-1258823 and OCE-1756272. Mooring data from MA2 was funded by the European Union 7th Framework Programme (FP7 2007-2013) under Grant 308299 (NACLIM) and the Horizon 2020 research and innovation program under Grant 727852 (Blue-Action). J.K. and M.O. acknowledge EU Horizon 2020 funding Grants 727852 (Blue-action) and 862626 (EuroSea) and from the German Ministry of Research and Education (RACE Program). G.W.K.M. acknowledges funding from the Natural Sciences and Engineering Research Council.
    Keywords: Boundary currents ; Convection ; Deep convection ; Transport ; In situ oceanic observations ; Seasonal cycle
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  • 185
    Publication Date: 2022-05-26
    Description: Author Posting. © American Meteorological Society, 2020. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Bulletin of the American Meteorological Society 101(11), (2020): E1996-E2004, https://doi.org/10.1175/BAMS-D-19-0305.1.
    Description: A long-standing challenge in oceanography is the observing, modeling, and prediction of vertical transport, which links the sunlit and atmospherically mediated surface boundary layer with the deeper ocean. Vertical motions play a critical role in the exchange of heat, freshwater, and biogeochemical tracers between the surface and the ocean interior. The most intense vertical velocities occur at horizontal scales less than 10 km, making them difficult to observe in the ocean and to resolve in models. Understanding how finescale turbulent motions and 0.1–10 km submesoscale processes contribute to the large-scale budgets of nutrients, oxygen, carbon, and heat and affect sea surface temperature, the air–sea exchange of gases, and the carbon cycle is one of the key challenges in oceanography.
    Description: CALYPSO is a Departmental Research Initiative (DRI) funded by the U.S. Office of Naval Research (ONR). It is a collaborative program involving more than 30 scientists and students and multiple institutions in the United States, Spain, and Italy. Measurements were conducted from the NRV Alliance, Pourquoi Pas?, and SOCIB. We are grateful to the captains and crews of these research vessels and the technical and scientific staff involved in making measurements, running models, analyzing data, and providing support.
    Description: 2021-05-01
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  • 186
    Publication Date: 2022-05-26
    Description: © The Author(s), 2021. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Lin, H., Tarnas, J. D., Mustard, J. F., Zhang, X., Wei, Y., Wan, W., Klein, F., & Kellner, J. R. Dynamic aperture factor analysis/target transformation (DAFA/TT) for Mg-serpentine and Mg-carbonate mapping on Mars with CRISM near-infrared data. Icarus, 355, (2021): 114168, https://doi.org/10.1016/j.icarus.2020.114168.
    Description: Serpentine and carbonate are products of serpentinization and carbonation processes on Earth, Mars, and other celestial bodies. Their presence implies that localized habitable environments may have existed on ancient Mars. Factor Analysis and Target Transformation (FATT) techniques have been applied to hyperspectral data from the Compact Reconnaissance Imaging Spectrometer for Mars (CRISM) to identify possible serpentine and Mg-carbonate-bearing outcrops. FATT techniques are capable of suggesting the presence of individual spectral signals in complex spectral mixtures. Applications of FATT techniques to CRISM data thus far only evaluate whether an entire analyzed image (≈ 3 × 105 pixels) may contain spectral information consistent with a specific mineral of interest. The spatial distribution of spectral signal from the possible mineral is not determined, making it difficult to validate a reported detection and also to understand the geologic context of any purported detections. We developed a method called Dynamic Aperture Factor Analysis/Target Transformation (DAFA/TT) to highlight the locations in a CRISM observation (or any similar laboratory or remotely acquired data set) most likely to contain spectra of specific minerals of interest. DAFA/TT determines the locations of possible target mineral spectral signals within hyperspectral images by performing FATT in small moving windows with different geometries, and only accepting pixels with positive detections in all cluster geometries as possible detections. DAFA/TT was applied to a hyperspectral image of a serpentinite from Oman for validation testing in a simplified laboratory setting. The mineral distribution determined by DAFA/TT application to the laboratory hyperspectral image was consistent with Raman analysis of the serpentinite sample. DAFA/TT also successfully mapped the spatial distribution of Mg-serpentine and Mg-carbonate previously detected in CRISM data using band parameter mapping and extraction of ratioed spectra. We applied DAFA/TT to CRISM images in some olivine-rich regions of Mars to characterize the spatial distribution of Mg-serpentine and Mg-carbonate-bearing outcrops.
    Description: This work was supported by the National Natural Science Foundation of China (grant no. 41671360, 41525016, 41902318). JFM and JDT acknowledge NASA support through a subcontract from the Applied Physics Lab for CRISM investigations. H. Lin also acknowledges the support from the key research Program of the Institute of Geology and Geophysics, CAS (IGGCAS-201905). The Headwall imaging spectrometer was acquired using funds to JRK from The Institute at Brown for Environment and Society and Brown University. The DAFA/TT codes are available on GitHub (https://github.com/linhoml?tab=repositories).
    Keywords: Dynamic aperture ; Factor analysis and target transformation ; Serpentine ; Carbonate ; Mars
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  • 187
    Publication Date: 2022-05-26
    Description: Author Posting. © American Meteorological Society, 2020. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 50(4), (2020): 1045-1064, doi:10.1175/JPO-D-19-0137.1.
    Description: Three simulations of the circulation in the Gulf of Mexico (the “Gulf”) using different numerical general circulation models are compared with results of recent large-scale observational campaigns conducted throughout the deep (〉1500 m) Gulf. Analyses of these observations have provided new understanding of large-scale mean circulation features and variability throughout the deep Gulf. Important features include cyclonic flow along the continental slope, deep cyclonic circulation in the western Gulf, a counterrotating pair of cells under the Loop Current region, and a cyclonic cell to the south of this pair. These dominant circulation features are represented in each of the ocean model simulations, although with some obvious differences. A striking difference between all the models and the observations is that the simulated deep eddy kinetic energy under the Loop Current region is generally less than one-half of that computed from observations. A multidecadal integration of one of these numerical simulations is used to evaluate the uncertainty of estimates of velocity statistics in the deep Gulf computed from limited-length (4 years) observational or model records. This analysis shows that the main deep circulation features identified from the observational studies appear to be robust and are not substantially impacted by variability on time scales longer than the observational records. Differences in strengths and structures of the circulation features are identified, however, and quantified through standard error analysis of the statistical estimates using the model solutions.
    Description: This work was supported by the Gulf Research Program of the National Academy of Sciences under Awards 2000006422 and 2000009966. The content is solely the responsibility of the authors and does not necessarily represent the official views of the Gulf Research Program or the National Academy of Sciences. The authors acknowledge the GLORYS project for providing the ocean reanalysis data used in the ROMS simulation. GLORYS is jointly conducted by MERCATOR OCEAN, CORIOLIS, and CNRS/INSU. Installation, recovery, data acquisition, and processing of the CANEK group current-meter moorings were possible because of CICESE-PetróleosMexicanos Grant PEP-CICESE 428229851 and the dedicated work of the crew of the B/O Justo Sierra and scientists of the CANEK group. The authors thank Dr. Aljaz Maslo, CICESE, for assistance with analysis of model data. The Bureau of Ocean Energy Management (BOEM), U.S. Dept. of the Interior, provided funding for the Lagrangian Study of the Deep Circulation in the Gulf of Mexico and the Observations and Dynamics of the Loop Current study. HYCOM simulation data are available from the HYCOM data server (https://www.hycom.org/data/goml0pt04/expt-02pt2), MITgcm data are available from the ECCO data server (http://ecco.ucsd.edu/gom_results2.html), and the ROMS simulation data are available from GRIIDC (NA.x837.000:0001).
    Keywords: Ocean circulation ; Abyssal circulation ; Bottom currents/bottom water ; Eddies ; Ocean models
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  • 188
    Publication Date: 2022-10-27
    Description: © The Author(s), 2020. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Hirst, W. G., Biswas, A., Mahalingan, K. K., & Reber, S. Differences in intrinsic tubulin dynamic properties contribute to spindle length control in Xenopus species. Current Biology, 30(11), (2020): 2184-2190.e5, doi: 10.1016/j.cub.2020.03.067.
    Description: The function of cellular organelles relates not only to their molecular composition but also to their size. However, how the size of dynamic mesoscale structures is established and maintained remains poorly understood [1, 2, 3]. Mitotic spindle length, for example, varies several-fold among cell types and among different organisms [4]. Although most studies on spindle size control focus on changes in proteins that regulate microtubule dynamics [5, 6, 7, 8], the contribution of the spindle’s main building block, the αβ-tubulin heterodimer, has yet to be studied. Apart from microtubule-associated proteins and motors, two factors have been shown to contribute to the heterogeneity of microtubule dynamics: tubulin isoform composition [9, 10] and post-translational modifications [11]. In the past, studying the contribution of tubulin and microtubules to spindle assembly has been limited by the fact that physiologically relevant tubulins were not available. Here, we show that tubulins purified from two closely related frogs, Xenopus laevis and Xenopus tropicalis, have surprisingly different microtubule dynamics in vitro. X. laevis microtubules combine very fast growth and infrequent catastrophes. In contrast, X. tropicalis microtubules grow slower and catastrophe more frequently. We show that spindle length and microtubule mass can be controlled by titrating the ratios of the tubulins from the two frog species. Furthermore, we combine our in vitro reconstitution assay and egg extract experiments with computational modeling to show that differences in intrinsic properties of different tubulins contribute to the control of microtubule mass and therefore set steady-state spindle length.
    Description: This article was prompted by our stay at the Marine Biological Laboratory (MBL), Woods Hole, MA in the summer of 2016 funded by the Princeton-Humboldt Strategic Partnership Grant together with the lab of Sabine Petry (Princeton University). We thank Jeff Woodruff (UT Southwestern), David Drechsel (IMP), and Marcus J. Taylor (MPI IB) for constructive criticism and comments on the manuscript and Helena Jambor for constructive comments on figure design. We thank the AMBIO imaging facility (Charité, Berlin) and Nikon at MBL for imaging support, Aliona Bogdanova and Barbara Borgonovo (MPI CBG) for their help with protein purification, and Francois Nedelec (University of Cambridge) for help with Cytosim. We are grateful to the Görlich lab (MPI BPC), in particular Bastian Hülsmann and Jens Krull, and the NXR for supply with X. tropicalis frogs. We thank Antonina Roll-Mecak (National Institute of Neurological Disorders and Stroke) for help with mass spectrometry analysis and discussions and Duck-Yeon Lee in the Biochemistry Core (National Heart, Lung and Blood Institute) for access to mass spectrometers. For mass spectrometry, we would like to acknowledge the assistance of Benno Kuropka and Chris Weise from the Core Facility BioSupraMol supported by the Deutsche Forschungsgemeinschaft (DFG). We thank all former and current members of the Reber lab for discussion and helpful advice, in particular, Christoph Hentschel and Soma Zsoter for technical assistance and Sebastian Reusch for help with tubulin purification. S.R. acknowledges funding from the IRI Life Sciences (Humboldt-Universität zu Berlin, Excellence Initiative/DFG). W.G.H. was supported by the Alliance Berlin Canberra co-funded by a grant from the Deutsche Forschungsgemeinschaft (DFG) for the International Research Training Group (IRTG) 2290 and the Australian National University. K.K.M. was supported by funds in the Roll-Mecak lab, intramural program of the National Institute of Neurological Disorders and Stroke.
    Keywords: Spindle scaling ; Tubulin ; Microtubule dynamics ; Xenopus ; Spindle length
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  • 189
    Publication Date: 2022-10-27
    Description: © The Author(s), 2022. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Molines, A. T., Lemière, J., Gazzola, M., Steinmark, I. E., Edrington, C. H., Hsu, C.-T., Real-Calderon, P., Suhling, K., Goshima, G., Holt, L. J., Thery, M., Brouhard, G. J., & Chang, F. Physical properties of the cytoplasm modulate the rates of microtubule polymerization and depolymerization. Developmental Cell, 57(4), (2022): 466-479.e6, https://doi.org/10.1016/j.devcel.2022.02.001.
    Description: The cytoplasm is a crowded, visco-elastic environment whose physical properties change according to physiological or developmental states. How the physical properties of the cytoplasm impact cellular functions in vivo remains poorly understood. Here, we probe the effects of cytoplasmic concentration on microtubules by applying osmotic shifts to fission yeast, moss, and mammalian cells. We show that the rates of both microtubule polymerization and depolymerization scale linearly and inversely with cytoplasmic concentration; an increase in cytoplasmic concentration decreases the rates of microtubule polymerization and depolymerization proportionally, whereas a decrease in cytoplasmic concentration leads to the opposite. Numerous lines of evidence indicate that these effects are due to changes in cytoplasmic viscosity rather than cellular stress responses or macromolecular crowding per se. We reconstituted these effects on microtubules in vitro by tuning viscosity. Our findings indicate that, even in normal conditions, the viscosity of the cytoplasm modulates the reactions that underlie microtubule dynamic behaviors.
    Description: This work was supported by grants to F.C. (NIH GM115185, NIH GM056836, NIH GM146438), to L.J.H. (American Cancer Society RSG-19-073-01-TBE, Pershing Square Sohn Cancer Award, Chan Zuckerberg Initiative, NIH GM132447 and NIH CA240765), to G.G. (JSPS KAKENHI 17H06471 and 18KK0202), to K.S. (UK’s Biotechnology and Biological Sciences Research Council (BBSRC) grant BB/R004803/1) and to M.T. (ERC Consolidator Grant 771599). I.E.S. was supported by King’s College London through a LIDo (London Interdisciplinary Doctoral programme) iCASE studentship.
    Keywords: Cytoskeleton dynamics ; Microtubules ; Cytoplasm ; Crowding ; Viscosity ; Diffusion ; Density ; Rheology ; Mitosis ; Fission yeast Schizosaccharomyces pombe
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  • 190
    Publication Date: 2022-10-26
    Description: © The Author(s), 2020. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Marty, B., Almayrac, M., Barry, P. H., Bekaert, D., V., Broadley, M. W., Byrne, D. J., Ballentine, C. J., & Caracausi, A. An evaluation of the C/N ratio of the mantle from natural CO2-rich gas analysis: Geochemical and cosmochemical implications. Earth and Planetary Science Letters, 551, (2020): 116574, doi:10.1016/j.epsl.2020.116574.
    Description: The terrestrial carbon to nitrogen ratio is a key geochemical parameter that can provide information on the nature of Earth's precursors, accretion/differentiation processes of our planet, as well as on the volatile budget of Earth. In principle, this ratio can be determined from the analysis of volatile elements trapped in mantle-derived rocks like mid-ocean ridge basalts (MORB), corrected for fractional degassing during eruption. However, this correction is critical and previous attempts have adopted different approaches which led to contrasting C/N estimates for the bulk silicate Earth (BSE) (Marty and Zimmermann, 1999; Bergin et al., 2015). Here we consider the analysis of CO2-rich gases worldwide for which a mantle origin has been determined using noble gas isotopes in order to evaluate the C/N ratio of the mantle source regions. These gases experienced little fractionation due to degassing, as indicated by radiogenic 4He / 40Ar* values (where 4He and 40Ar* are produced by the decay of U+Th, and 40K isotopes, respectively) close to the mantle production/accumulation values. The C/N and C/3 He ratios of gases investigated here are within the range of values previously observed in oceanic basalts. They point to an elevated mantle C/N ratio (∼350-470, molar) higher than those of potential cosmochemical accretionary endmembers. For example, the BSE C/N and 36 Ar / N ratios (160-220 and 75 x 10-7, respectively) are higher than those of CM-CI chondrites but within the range of CV-CO groups. This similarity suggests that the Earth accreted from evolved planetary precursors depleted in volatile and moderately volatile elements. Hence the high C / N composition of the BSE may be an inherited feature rather than the result of terrestrial differentiation. The C / N and 36 Ar / N ratios of the surface (atmosphere plus crust) and of the mantle cannot be easily linked to any known chondritic composition. However, these compositions are consistent with early sequestration of carbon into the mantle (but not N and noble gases), permitting the establishment of clement temperatures at the surface of our planet.
    Description: M.A, D.V.B, M.W.B, D.J.B and B.M were supported by the European Research Council (PHOTONIS project, grant agreement No. 695618 to B.M.). Samples were collected as part of Study # YELL-08056 - Xenon anomalies in the Yellowstone Hotspot. We would like to thank Annie Carlson and all of the rangers at the Yellowstone National Park for providing invaluable advice and help when collecting the samples. This work was partially supported by a grant (G-2016-7206) from the Alfred P. Sloan Foundation and the Deep Carbon Observatory to P.H.B as well as NSF award 2015789 to P.H.B.. Sampling at Mt. Etna and gas analysis was supported by Instituto Nazionale di Geofisica e Vulcanologia Palermo. Fruitful discussions with Marc Hirschmann helped us to shape the ideas presented in this work. We acknowledge detailed and insightful reviews by Sami Mikhail and an anonymous reviewer, and efficient editing by Frederic Moynier. This is CRPG contribution 2741.
    Keywords: Carbon ; Nitrogen ; Earth ; Mantle ; Gases
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  • 191
    Publication Date: 2022-10-26
    Description: © The Author(s), 2022. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Jonell, T., Giosan, L., Clift, P., Carter, A., Bretschneider, L., Hathorne, E., Barbarano, M., Garzanti, E., Vezzoli, G., & Naing, T. No modern Irrawaddy River until the late Miocene-Pliocene. Earth and Planetary Science Letters, 584, (2022): 117516, https://doi.org/10.1016/j.epsl.2022.117516.
    Description: The deposits of large Asian rivers with unique drainage geometries have attracted considerable attention due to their explanatory power concerning tectonism, surface uplift and upstream drainage evolution. This study presents the first petrographic, heavy mineral, Nd and Sr isotope geochemistry, and detrital zircon geochronology results from the Holocene Irrawaddy megadelta alongside modern and ancient sedimentary provenance datasets to assess the late Neogene evolution of the Irrawaddy River. Contrary to models advocating a steady post-middle Miocene river, we reveal an evolution of the Irrawaddy River more compatible with regional evidence for kinematic reorganization in Myanmar during late-stage India-Asia collision. Quaternary sediments are remarkably consistent in terms of provenance but highlight significant decoupling amongst fine and coarse fraction 87Sr/86Sr and due to hydraulic sorting. Only well after the late Miocene do petrographic, heavy mineral, isotope geochemistry, and detrital zircon U–Pb results from the trunk Irrawaddy and its tributaries achieve modern-day signatures. The primary driver giving rise to the geometry and provenance signature of the modern Irrawaddy River was regional late Miocene (≤10 Ma) basin inversion coupled with uplift and cumulative displacement along the Sagaing Fault. Middle to late Miocene provenance signatures cannot be reconciled with modern river geometries, and thus require significant loss of headwaters feeding the Chindwin subbasin after ∼14 Ma and the northern Shwebo subbasin after ∼11 Ma. Large-scale reworking after ∼7 Ma is evidenced by modern Irrawaddy River provenance, by entrenchment of the nascent drainage through Plio-Pleistocene inversion structures, and in the transfer of significant sediment volumes to the Andaman Sea.
    Description: TNJ was supported in initial stages of this project by a Postdoctoral Research Fellowship at UQ and software support by LSU. LG thanks support from the Andrew W. Mellon Foundation via Woods Hole Oceanographic Institution. The Charles T. McCord chair at LSU funded coring and detrital zircon U–Pb geochronology essential to the study.
    Keywords: Provenance ; Sediment ; Irrawaddy ; Zircon ; Isotope geochemistry ; Petrography
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  • 192
    Publication Date: 2022-10-11
    Description: © The Author(s), 2022. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Våge, K., Semper, S., Valdimarsson, H., Jónsson, S., Pickart, R., & Moore, G. Water mass transformation in the Iceland Sea: contrasting two winters separated by four decades. Deep Sea Research Part I: Oceanographic Research Papers, 186, (2022): 103824, https://doi.org/10.1016/j.dsr.2022.103824.
    Description: Dense water masses formed in the Nordic Seas flow across the Greenland–Scotland Ridge and contribute substantially to the lower limb of the Atlantic Meridional Overturning Circulation. Originally considered an important source of dense water, the Iceland Sea gained renewed interest when the North Icelandic Jet — a current transporting dense water from the Iceland Sea into Denmark Strait — was discovered in the early 2000s. Here we use recent hydrographic data to quantify water mass transformation in the Iceland Sea and contrast the present conditions with measurements from hydrographic surveys conducted four decades earlier. We demonstrate that the large-scale hydrographic structure of the central Iceland Sea has changed significantly over this period and that the locally transformed water has become less dense, in concert with a retreating sea-ice edge and diminished ocean-to-atmosphere heat fluxes. This has reduced the available supply of dense water to the North Icelandic Jet, but also permitted densification of the East Greenland Current during its transit through the presently ice-free western Iceland Sea in winter. Together, these changes have significantly altered the contribution from the Iceland Sea to the overturning in the Nordic Seas over the four decade period.
    Description: Support for this work was provided by the Trond Mohn Foundation, Norway under grant BFS2016REK01 (K.V. and S.S.), the European Union’s Horizon 2020 research and innovation programme under the Marie Skłodowska-Curie grant agreement no. 101022251 (S.S.), the US National Science Foundation under grants OCE-1259618 and OCE- 1948505 (R.S.P), and the Natural Sciences and Engineering Research Council of Canada (G.W.K.M).
    Keywords: Iceland Sea ; Water mass transformation ; North Icelandic Jet ; Iceland–Faroe Slope Jet ; East Greenland Current ; Denmark Strait overflow water
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  • 193
    Publication Date: 2022-10-12
    Description: Author Posting. © American Meteorological Society, 2022. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 52(10), (2022): 2431-2444, https://doi.org/10.1175/jpo-d-22-0024.1.
    Description: A three-dimensional inertial model that conserves quasigeostrophic potential vorticity is proposed for wind-driven coastal upwelling along western boundaries. The dominant response to upwelling favorable winds is a surface-intensified baroclinic meridional boundary current with a subsurface countercurrent. The width of the current is not the baroclinic deformation radius but instead scales with the inertial boundary layer thickness while the depth scales as the ratio of the inertial boundary layer thickness to the baroclinic deformation radius. Thus, the boundary current scales depend on the stratification, wind stress, Coriolis parameter, and its meridional variation. In contrast to two-dimensional wind-driven coastal upwelling, the source waters that feed the Ekman upwelling are provided over the depth scale of this baroclinic current through a combination of onshore barotropic flow and from alongshore in the narrow boundary current. Topography forces an additional current whose characteristics depend on the topographic slope and width. For topography wider than the inertial boundary layer thickness the current is bottom intensified, while for narrow topography the current is wave-like in the vertical and trapped over the topography within the inertial boundary layer. An idealized primitive equation numerical model produces a similar baroclinic boundary current whose vertical length scale agrees with the theoretical scaling for both upwelling and downwelling favorable winds.
    Description: This research is supported in part by the China Scholarship Council (201906330102). H. G. is financially supported by the China Scholarship Council to study at WHOI for 2 years as a guest student. M.S. is supported by the National Science Foundation Grant OCE-1922538. Z. C. is supported by the ‘Taishan/Aoshan’ Talents program (2017ASTCPES05) the Fundamental Research Funds for the Central Universities (202072001).
    Description: 2023-03-30
    Keywords: Ekman pumping/transport ; Upwelling/downwelling ; Coastal flows
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  • 194
    Publication Date: 2022-10-12
    Description: Author Posting. © American Meteorological Society, 2022. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 52(10), (2022): 2325–2341, https://doi.org/10.1175/jpo-d-21-0015.1.
    Description: The ocean surface boundary layer is a gateway of energy transfer into the ocean. Wind-driven shear and meteorologically forced convection inject turbulent kinetic energy into the surface boundary layer, mixing the upper ocean and transforming its density structure. In the absence of direct observations or the capability to resolve subgrid-scale 3D turbulence in operational ocean models, the oceanography community relies on surface boundary layer similarity scalings (BLS) of shear and convective turbulence to represent this mixing. Despite their importance, near-surface mixing processes (and ubiquitous BLS representations of these processes) have been undersampled in high-energy forcing regimes such as the Southern Ocean. With the maturing of autonomous sampling platforms, there is now an opportunity to collect high-resolution spatial and temporal measurements in the full range of forcing conditions. Here, we characterize near-surface turbulence under strong wind forcing using the first long-duration glider microstructure survey of the Southern Ocean. We leverage these data to show that the measured turbulence is significantly higher than standard shear-convective BLS in the shallower parts of the surface boundary layer and lower than standard shear-convective BLS in the deeper parts of the surface boundary layer; the latter of which is not easily explained by present wave-effect literature. Consistent with the CBLAST (Coupled Boundary Layers and Air Sea Transfer) low winds experiment, this bias has the largest magnitude and spread in the shallowest 10% of the actively mixing layer under low-wind and breaking wave conditions, when relatively low levels of turbulent kinetic energy (TKE) in surface regime are easily biased by wave events.
    Description: This paper is VIMS Contribution 4103. Computational resources were provided by the VIMS Ocean-Atmosphere and Climate Change Research Fund. AUSSOM was supported by the OCE Division of the National Science Foundation (1558639).
    Keywords: Turbulence ; Wind shear ; Boundary layer ; Parameterization
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  • 195
    Publication Date: 2022-10-18
    Description: © The Author(s), 2022. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Pold, G., Kwiatkowski, B. L., Rastetter, E. B., & Sistla, S. A. Sporadic P limitation constrains microbial growth and facilitates SOM accumulation in the stoichiometrically coupled, acclimating microbe-plant-soil model. Soil Biology & Biochemistry, 165, (2022): 108489, https://doi.org/10.1016/j.soilbio.2021.108489.
    Description: Requirements for biomass carbon (C), nitrogen (N), and phosphorus (P) constrain organism growth and are important agents for structuring ecosystems. Arctic tundra habitats are strongly nutrient limited as decomposition and recycling of nutrients are slowed by low temperature. Modeling interactions among these elemental cycles affords an opportunity to explore how disturbances such as climate change might differentially affect these nutrient cycles. Here we introduce a C–N–P-coupled version of the Stoichiometrically Coupled Acclimating Microbe-Plant-Soil (SCAMPS) model, “SCAMPS-CNP”, and a corresponding modified CN-only model, “SCAMPS-CN”. We compared how SCAMPS-CNP and the modified SCAMPS-CN models project a moderate (RCP 6.0) air warming scenario will impact tussock tundra nutrient availability and ecosystem C stocks. SCAMPS-CNP was characterized by larger SOM and smaller organism C stocks compared to SCAMPS-CN, and a greater reduction in ecosystem C stocks under warming. This difference can largely be attributed to a smaller microbial biomass in the CNP model, which, instead of being driven by direct costs of P acquisition, was driven by variable resource limitation due to asynchronous C, N, and P availability and demand. Warming facilitated a greater relative increase in plant and microbial biomass in SCAMPS-CNP, however, facilitated by increased extracellular enzyme pools and activity, which more than offset the metabolic costs associated with their production. Although the microbial community was able to flexibly adapt its stoichiometry and become more bacteria-like (N-rich) in both models, its stoichiometry deviated further from its target value in the CNP model because of the need to balance cellular NP ratio. Our results indicate that seasonality and asynchrony in resources affect predicted changes in ecosystem C storage under warming in these models, and therefore build on a growing body of literature indicating stoichiometry should be considered in carbon cycling projections.
    Description: This work was funded by the National Science Foundation Signals in the Soil grant number 1841610 to SAS and EBR.
    Keywords: Stoichiometry ; Modeling ; Microbial physiology ; Tundra ; Climate change
    Repository Name: Woods Hole Open Access Server
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  • 196
    Publication Date: 2022-10-18
    Description: © The Author(s), 2022. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Tamborski, J., Cai, P., Eagle, M., Henderson, P., & Charette, M. Revisiting 228Th as a tool for determining sedimentation and mass accumulation rates. Chemical Geology, 607, (2022): 121006, https://doi.org/10.1016/j.chemgeo.2022.121006.
    Description: The use of 228Th has seen limited application for determining sedimentation and mass accumulation rates in coastal and marine environments. Recent analytical advances have enabled rapid, precise measurements of particle-bound 228Th using a radium delayed coincidence counting system (RaDeCC). Herein we review the 228Th cycle in the marine environment and revisit the historical use of 228Th as a tracer for determining sediment vertical accretion and mass accumulation rates in light of new measurement techniques. Case studies comparing accumulation rates from 228Th and 210Pb are presented for a micro-tidal salt marsh and a marginal sea environment. 228Th and 210Pb have been previously measured in mangrove, deltaic, continental shelf and ocean basin environments, and a literature synthesis reveals that 228Th (measured via alpha or gamma spectrometry) derived accumulation rates are generally equal to or greater than estimates derived from 210Pb, reflecting different integration periods. Use of 228Th is well-suited for shallow (〈15 cm) cores over decadal timescales. Application is limited to relatively homogenous sediment profiles with minor variations in grain size and minimal bioturbation. When appropriate conditions are met, complimentary use of 228Th and 210Pb can demonstrate that the upper layers of a core are undisturbed and can improve spatial coverage in mapping accumulation rates due to the higher sample throughput for sediment 228Th.
    Description: This research was undertaken thanks in part to funding from the Canada First Research Excellence Fund, through the Ocean Frontier Institute. This project was supported by U.S. Geological Survey Coastal and Marine Hazards and Resources Program. Any use of trade, firm or product names is for descriptive purposes only and does not imply endorsement by the U.S. Government. PC acknowledges the support of the Natural Science Foundation of China (NSFC) through Grants No. 92058205.
    Keywords: Sedimentation ; Mass accumulation ; Thorium isotopes ; Lead-210 ; Wetlands ; Sea level rise
    Repository Name: Woods Hole Open Access Server
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  • 197
    Publication Date: 2022-10-26
    Description: © The Author(s), 2021. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Gu, S., Liu, Z., Oppo, D. W., Lynch-Stieglitz, J., Jahn, A., Zhang, J., Lindsay, K., & Wu, L. Remineralization dominating the δ13 C decrease in the mid-depth Atlantic during the last deglaciation. Earth and Planetary Science Letters, 571, (2021): 117106, https://doi.org/10.1016/j.epsl.2021.117106.
    Description: δ 13 C records from the mid-depth Atlantic show a pronounced decrease during the Heinrich Stadial 1 (HS1), a deglacial episode of dramatically weakened Atlantic Meridional Ocean Circulation (AMOC). Proposed explanations for this mid-depth decrease include a greater fraction of δ 13 C -depleted southern sourced water (SSW), a δ 13 C decrease in the North Atlantic Deep Water (NADW) end-member, and accumulation of the respired organic carbon. However, the relative importance of these proposed mechanisms cannot be quantitatively constrained from current available observations alone. Here we diagnose the individual contributions to the deglacial Atlantic mid-depth δ 13 C change from these mechanisms using a transient simulation with carbon isotopes and idealized tracers. We find that although the fraction of the low- δ 13 C SSW increases in response to a weaker AMOC during HS1, the water mass mixture change only plays a minor role in the mid-depth Atlantic δ 13 C decrease. Instead, increased remineralization due to the AMOC-induced mid-depth ocean ventilation decrease is the dominant cause. In this study, we differentiate between the deep end-members, which are assigned to deep water regions used in previous paleoceanography studies, and the surface end-members, which are from the near-surface water defined from the physical origin of deep water masses. We find that the deep NADW end-member includes additional remineralized material accumulated when sinking from the surface (surface NADW end-member). Therefore, the surface end-members should be used in diagnosing mechanisms of changes. Furthermore, our results suggest that remineralization in the surface end-member is more critical than the remineralization along the transport pathway from the near-surface formation region to the deep ocean, especially during the early deglaciation.
    Description: This work is supported by US National Science Foundation (NSF) P2C2 projects (1401778, 1401802, and 1566432), and the National Science Foundation of China No. 41630527. S.G. is supported by Shanghai Pujiang program.
    Keywords: δ13 C ; Water mass composition ; Remineralization ; End-member ; HS1
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  • 198
    Publication Date: 2022-10-26
    Description: © The Author(s), 2022. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Tyne, R., Barry, P., Cheng, A., Hillegonds, D., Kim, J.-H., McIntosh, J., & Ballentine, C. Basin architecture controls on the chemical evolution and 4He distribution of groundwater in the Paradox Basin. Earth and Planetary Science Letters, 589, (2022):117580, https://doi.org/10.1016/j.epsl.2022.117580.
    Description: Fluids such as 4He, H2, CO2 and hydrocarbons accumulate within Earth's crust. Crustal reservoirs also have potential to store anthropogenic waste (e.g., CO2, spent nuclear fuel). Understanding fluid migration and how this is impacted by basin stratigraphy and evolution is key to exploiting fluid accumulations and identifying viable storage sites. Noble gases are powerful tracers of fluid migration and chemical evolution, as they are inert and only fractionate by physical processes. The distribution of 4He, in particular, is an important tool for understanding diffusion within basins and for groundwater dating. Here, we report noble gas isotope and abundance data from 36 wells across the Paradox Basin, Colorado Plateau, USA, which has abundant hydrocarbon, 4He and CO2 accumulations. Both groundwater and hydrocarbon samples were collected from 7 stratigraphic units, including within, above and below the Paradox Formation (P.Fm) evaporites. Air-corrected helium isotope ratios (0.0046 - 0.127 RA) are consistent with radiogenic overprinting of predominantly groundwater-derived noble gases. The highest radiogenic noble gas concentrations are found in formations below the P.Fm. Atmosphere-derived noble gas signatures are consistent with meteoric recharge and multi-phase interactions both above and below the P.Fm, with greater groundwater-gas interactions in the shallower formations. Vertical diffusion models, used to reconstruct observed groundwater helium concentrations, show the P.Fm evaporite layer to be effectively impermeable to helium diffusion and a regional barrier for mobile elements but, similar to other basins, a basement 4He flux is required to accumulate the 4He concentrations observed beneath the P.Fm. The verification that evaporites are regionally impermeable to diffusion, of even the most diffusive elements, is important for sub-salt helium and hydrogen exploration and storage, and a critical parameter in determining 4He-derived mean groundwater ages. This is critical to understanding the role of basin stratigraphy and deformation on fluid flow and gas accumulation.
    Description: This work was supported by a Natural Environment Research Council studentship to R.L. Tyne (Grant ref. NE/L002612/1). We gratefully acknowledge the William F. Keck Foundation for support of this research, and the National Science Foundation (NSF EAR #2120733). J.C. McIntosh and C.J. Ballentine are fellows of the CIFAR Earth4D Subsurface Science and Exploration Program. The authors would like to acknowledge the U.S. Bureau of Reclamation, Paradox Resources, Navajo Petroleum, US Oil and Gas INC, Anson Resources, Lantz Indergard (Lisbon Valley Mining Co.), Ambria Dell'Oro and Mohammad Marza for help with sampling.
    Keywords: Noble gases ; Helium ; Paradox Basin ; Crustal fluid dating ; Groundwater migration
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  • 199
    Publication Date: 2022-10-26
    Description: © The Author(s), 2022. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Broadley, M., Byrne, D., Ardoin, L., Almayrac, M., Bekaert, D., & Marty, B. High precision noble gas measurements of hydrothermal quartz reveal variable loss rate of Xe from the Archean atmosphere. Earth and Planetary Science Letters, 588, (2022): 117577, https://doi.org/10.1016/j.epsl.2022.117577.
    Description: Determining the composition of the Archean atmosphere and oceans is vital to understanding the environmental conditions that existed on the surface of the early Earth. The analysis of atmospheric remnants in fluid inclusions trapped in Archean-aged samples has shown that the Xe isotopic signature of the Archean atmosphere progressively evolved via mass-dependent fractionation, arriving at a modern atmospheric composition around the Archean-Proterozoic transition. The mechanisms driving this evolution are however not well constrained, and it is not yet clear whether the evolution proceeded continuously or via episodic bursts. Providing further constraints on the evolution of Xe in the Archean atmosphere is hampered by the limited amounts of atmospheric gas trapped within fluid inclusions during mineral formation, which impacts the precision at which the Archean atmosphere can be determined. Here, we develop a new crush-and-accumulate extraction technique that enables the heavy noble gases (Ar, Kr and Xe) released from crushing large quantities of hydrothermal quartz to be accumulated and analysed to a higher precision than was previously possible. Using this new technique, we re-evaluate the composition of atmospheric gases trapped within fluid inclusions of 3.3 Ga quartz samples from Barberton, South Africa. We find that the Xe isotopic signature is fractionated by +10.3 ± 1.0‰u−1 (2 SE) relative to modern atmosphere, which is within uncertainty of, but slightly lower than, the previous determination of 12.9 ± 2.4‰u−1 for this sample (Avice et al., 2017). We show for the first time that the Kr/Xe ratio measured within Archean quartz samples is enriched in Xe compared to the modern atmosphere, demonstrating that the atmosphere has lost Xe since the Archean. This further reinforces the proposal of atmospheric escape as the primary mechanism for Earth's Xe loss. We further show that the atmospheric Kr/Xe and Xe isotope fractionation recorded in the Barberton quartz at 3.3 Ga is incompatible with a model describing atmospheric loss at a continuous rate under a constant fractionation factor. This gives credence to numerical models of hydrodynamic escape, which suggest that Xe was lost from the Archean atmosphere in episodic bursts rather than at a constant rate. Refining the evolution curve of atmospheric Xe isotopes using the new technique presented here has the potential to shed light on discrete atmospheric events that punctuated the evolution of the Archean Earth and accompanied the evolution of life.
    Description: This study was supported by the European Research Council (PHOTONIS project, grant agreement No. 695618). This is CRPG contribution #2820.
    Keywords: Archean atmosphere ; Noble gases ; Xenon ; Atmospheric escape
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  • 200
    Publication Date: 2022-05-27
    Description: © The Author(s), 2021. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Anderson, D. M., Fensin, E., Gobler, C. J., Hoeglund, A. E., Hubbard, K. A., Kulis, D. M., Landsberg, J. H., Lefebvre, K. A., Provoost, P., Richlen, M. L., Smith, J. L., Solow, A. R., & Trainer, V. L. Marine harmful algal blooms (HABs) in the united states: history, current status and future trends. Harmful Algae, 102, (2021): 101975, https://doi.org/10.1016/j.hal.2021.101975.
    Description: Harmful algal blooms (HABs) are diverse phenomena involving multiple. species and classes of algae that occupy a broad range of habitats from lakes to oceans and produce a multiplicity of toxins or bioactive compounds that impact many different resources. Here, a review of the status of this complex array of marine HAB problems in the U.S. is presented, providing historical information and trends as well as future perspectives. The study relies on thirty years (1990–2019) of data in HAEDAT - the IOC-ICES-PICES Harmful Algal Event database, but also includes many other reports. At a qualitative level, the U.S. national HAB problem is far more extensive than was the case decades ago, with more toxic species and toxins to monitor, as well as a larger range of impacted resources and areas affected. Quantitatively, no significant trend is seen for paralytic shellfish toxin (PST) events over the study interval, though there is clear evidence of the expansion of the problem into new regions and the emergence of a species that produces PSTs in Florida – Pyrodinium bahamense. Amnesic shellfish toxin (AST) events have significantly increased in the U.S., with an overall pattern of frequent outbreaks on the West Coast, emerging, recurring outbreaks on the East Coast, and sporadic incidents in the Gulf of Mexico. Despite the long historical record of neurotoxic shellfish toxin (NST) events, no significant trend is observed over the past 30 years. The recent emergence of diarrhetic shellfish toxins (DSTs) in the U.S. began along the Gulf Coast in 2008 and expanded to the West and East Coasts, though no significant trend through time is seen since then. Ciguatoxin (CTX) events caused by Gambierdiscus dinoflagellates have long impacted tropical and subtropical locations in the U.S., but due to a lack of monitoring programs as well as under-reporting of illnesses, data on these events are not available for time series analysis. Geographic expansion of Gambierdiscus into temperate and non-endemic areas (e.g., northern Gulf of Mexico) is apparent, and fostered by ocean warming. HAB-related marine wildlife morbidity and mortality events appear to be increasing, with statistically significant increasing trends observed in marine mammal poisonings caused by ASTs along the coast of California and NSTs in Florida. Since their first occurrence in 1985 in New York, brown tides resulting from high-density blooms of Aureococcus have spread south to Delaware, Maryland, and Virginia, while those caused by Aureoumbra have spread from the Gulf Coast to the east coast of Florida. Blooms of Margalefidinium polykrikoides occurred in four locations in the U.S. from 1921–2001 but have appeared in more than 15  U.S. estuaries since then, with ocean warming implicated as a causative factor. Numerous blooms of toxic cyanobacteria have been documented in all 50  U.S. states and the transport of cyanotoxins from freshwater systems into marine coastal waters is a recently identified and potentially significant threat to public and ecosystem health. Taken together, there is a significant increasing trend in all HAB events in HAEDAT over the 30-year study interval. Part of this observed HAB expansion simply reflects a better realization of the true or historic scale of the problem, long obscured by inadequate monitoring. Other contributing factors include the dispersion of species to new areas, the discovery of new HAB poisoning syndromes or impacts, and the stimulatory effects of human activities like nutrient pollution, aquaculture expansion, and ocean warming, among others. One result of this multifaceted expansion is that many regions of the U.S. now face a daunting diversity of species and toxins, representing a significant and growing challenge to resource managers and public health officials in terms of toxins, regions, and time intervals to monitor, and necessitating new approaches to monitoring and management. Mobilization of funding and resources for research, monitoring and management of HABs requires accurate information on the scale and nature of the national problem. HAEDAT and other databases can be of great value in this regard but efforts are needed to expand and sustain the collection of data regionally and nationally.
    Description: Support for DMA, MLR, and DMK was provided through the Woods Hole Center for Oceans and Human Health (National Science Foundation grant OCE-1840381 and National Institutes of Health grants NIEHS‐1P01-ES028938–01) and the U.S. National Office for Harmful Algal Blooms with funding from NOAA's National Centers for Coastal Ocean Science (NCCOS) through the Cooperative Institute for the North Atlantic Region (CINAR) (NA14OAR4320158, NA19OAR4320074). Funding for KAL and DMA was provided by the National Oceanic and Atmospheric Administration National Centers for Coastal Ocean Science Competitive Research Program under award NA20NOS4780195 to the Woods Hole Oceanographic Institution and NOAA's Northwest Fisheries Science Center. We also acknowledge support for A.H. from the National Oceanic and Atmospheric Administration [NOAA] Office of Ocean and Coastal Resource Management Award NA19NOS4780183, C.J.G from NOAA-MERHAB (NA19NOS4780186) and (NA16NOS4780189) for VLT Support was also received for JLS, CJG, and VLT from NOAA-NCCOS-ECOHAB under awards NA17NOS4780184 and NA19NOS4780182. This is ECOHAB publication number ECO972.
    Keywords: HAB ; Harmful algal bloom ; Red tide ; Eutrophication ; Time series ; HAEDAT
    Repository Name: Woods Hole Open Access Server
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