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  • 1
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    Deciphering the Whisper of Volcanoes: Monitoring Velocity Changes at Kamchatka's Klyuchevskoy Group With Fluctuating Noise Fields (2023)
    Details
    Publication Date: 2023-06-21
    Description: Volcanic inflation and deflation often precede eruptions and can lead to seismic velocity changes (dv/v $dv/v$) in the subsurface. Recently, interferometry on the coda of ambient noise‐cross‐correlation functions yielded encouraging results in detecting these changes at active volcanoes. Here, we analyze seismic data recorded at the Klyuchevskoy Volcanic Group in Kamchatka, Russia, between summer of 2015 and summer of 2016 to study signals related to volcanic activity. However, ubiquitous volcanic tremors introduce distortions in the noise wavefield that cause artifacts in the dv/v $dv/v$ estimates masking the impact of physical mechanisms. To avoid such instabilities, we propose a new technique called time‐segmented passive image interferometry. In this technique, we employ a hierarchical clustering algorithm to find periods in which the wavefield can be considered stationary. For these periods, we perform separate noise interferometry studies. To further increase the temporal resolution of our results, we use an AI‐driven approach to find stations with similar dv/v $dv/v$ responses and apply a spatial stack. The impacts of snow load and precipitation dominate the resulting dv/v $dv/v$ time series, as we demonstrate with the help of a simple model. In February 2016, we observe an abrupt velocity drop due to the M7.2 Zhupanov earthquake. Shortly after, we register a gradual velocity increase of about 0.3% at Bezymianny Volcano coinciding with surface deformation observed using remote sensing techniques. We suggest that the inflation of a shallow reservoir related to the beginning of Bezymianny's 2016/2017 eruptive cycle could have caused this local velocity increase and a decorrelation of the correlation function coda.
    Description: Plain Language Summary: Before eruptions, volcanoes inflate due to the rising magma from below. Previous studies have found that these deformations can lead to small changes in the properties of the surrounding rock. We use passive image interferometry, a method that relies on the omnipresent background vibration of the Earth—mostly induced by the oceans, to measure these changes at the Klyuchevskoy Volcanic Group in Kamchatka, Russia. However, in Kamchatka, this background noise is masked and distorted by small earthquakes and tremors originating from the volcanoes themselves. We combine machine learning techniques with established monitoring methods to find times when these tremors remain similar. Afterward, we use data from these time periods in the conventional way to observe changes in the soil and the rock. Our results show that rain‐ and snowfall and the thickness of the snow cover exert the strongest influence on the properties of the rocks. Additionally, we found that a large magnitude 7.2 earthquake, which struck Kamchatka during our study, caused a slight weakening of the rocks due to microstructural damage. We register changes shortly before an eruption and suggest a connection to the beginning of an eruptive cycle in 2016.
    Description: Key Points: Fluctuating noise conditions lead to distortions in noise interferometry studies, which we avoid with the help of machine learning. The seismic velocity on Kamchatka is affected by numerous mechanisms, amongst them environmental, tectonic, and volcanic events. We observe a velocity increase at Bezymianny during February 2016 and link it to the beginning of the eruptive cycle.
    Description: German Research Foundation
    Description: https://doi.org/10.14470/K47560642124
    Description: https://doi.org/10.24381/cds.e2161bac
    Description: https://doi.org/10.5880/GFZ.2.4.2022.002
    Description: https://doi.org/10.5281/zenodo.7481934
    Keywords: ddc:551 ; seismology ; volcano monitoring ; machine learning ; ambient noise ; seismic velocity change ; time varying earth structure
    Language: English
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  • 2
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    Impact of Diurnal Warm Layers on Atmospheric Convection (2023)
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    Publication Date: 2023-12-05
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉This manuscript presents a study of oceanic diurnal warm layers (DWLs) in kilometer‐scale global coupled simulations and their impact on atmospheric convection in the tropics. With the implementation of thin vertical levels in the ocean, DWLs are directly resolved, and sea surface temperature (SST) fluctuations of up to several Kelvin appear in regions with low wind and high solar radiation. The increase of SST during the day causes an abrupt afternoon increase of atmospheric moisture due to enhanced latent heat flux (LHF), followed by an increase in cloud cover (CC) and cloud liquid water (CLW). However, although the diurnal SST amplitude is even exaggerated in comparison to reanalysis, this effect only lasts for 5–6 hr and leads to an absolute difference of 1% for CC and 0.01 kg m〈sup〉−2〈/sup〉 for CLW. This can be explained by the fact that the low wind over the SST anomalies dampens their potential effect on the LHF and hence clouds. All in all, the impact of DWLs on convective CC is found to be negligible in the tropical mean.〈/p〉
    Description: Plain Language Summary: The diurnal fluctuations of sea surface temperature (SST) have been extensively studied for the last decades, but the assessment of the importance of this phenomenon for atmospheric convection on the global scale has come within reach only very recently, thanks to the development of simulations with a horizontal resolution of O(1 km). In this manuscript we show that we can indeed observe an impact of SST fluctuations on moisture in the atmosphere. However, the impact on the amount of clouds in the tropics is found to be short‐lived and its magnitude negligible on average.〈/p〉
    Description: Key Points: 〈list list-type="bullet"〉 〈list-item〉 〈p xml:lang="en"〉diurnal warm layers (DWLs) increase atmospheric moisture〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉The increase of cloud cover (CC) following the formation of a DWL is immediate and only lasts for several hours〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉The magnitude of the CC increase is small and has no discernible influence on the global mean〈/p〉〈/list-item〉 〈/list〉 〈/p〉
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: https://gotm.net/
    Description: https://hdl.handle.net/21.11116/0000-000C-1447-E
    Keywords: ddc:551 ; diurnal warm layers (DWLs) ; atmospheric moisture ; cloud cover ; convection
    Language: English
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  • 3
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    Impact of Cyclonic Wind Anomalies Caused by Massive Winter Sea Ice Retreat in the Barents Sea on Atlantic Water Transport Toward the Arctic: A Model Study (2023)
    Details
    Publication Date: 2023-12-05
    Description: The Arctic is warming much faster than the global average. This is known as Arctic Amplification and is caused by feedbacks in the local climate system. In this study, we explore a previously proposed hypothesis that an associated wind feedback in the Barents Sea could play an important role by increasing the warm water inflow into the Barents Sea. We find that the strong recent decrease in Barents Sea winter sea ice cover causes enhanced ocean‐atmosphere heat flux and a local air temperature increase, thus a reduction in sea level pressure and a local cyclonic wind anomaly with eastward winds in the Barents Sea Opening. By investigating various reanalysis products and performing high‐resolution perturbation experiments with the ocean and sea ice model FESOM2.1, we studied the impact of cyclonic atmospheric circulation changes on the warm Atlantic Water import into the Arctic via the Barents Sea and Fram Strait. We found that the observed wind changes do not significantly affect the warm water transport into the Barents Sea, which rejects the wind‐feedback hypothesis. At the same time, the cyclonic wind anomalies in the Barents Sea increase the amount of Atlantic Water recirculating westwards in Fram Strait by a downslope shift of the West Spitsbergen Current, and thus reduce Atlantic Water reaching the Arctic basin via Fram Strait. The resulting warm‐water anomaly in the Greenland Sea Gyre drives a local anticyclonic circulation anomaly.
    Description: Plain Language Summary: The Barents Sea has been experiencing a rapid decrease in its winter sea ice extent during the last 30 years. The loss of sea ice creates new areas where, in winter, the relatively warm ocean loses heat to the cold atmosphere. As warm air rises, the warming reduces the sea level air pressure, changing the atmospheric circulation to develop a local anticlockwise wind system centered over the northern Barents Sea. The associated eastward winds in the Barents Sea Opening and southeastward winds in Fram Strait affect how warm water from the North Atlantic moves toward the Arctic. There has been a long debate on whether this wind anomaly can increase the warm Atlantic Water transport into the Barents Sea and thus cause a positive feedback mechanism for further reducing the sea ice through melting. We find that the observed atmospheric circulation changes have no significant impact on the Barents Sea warm water inflow and thus reject the wind feedback as a strong player in contributing to Arctic Amplification. However, strong anomalous southeastward winds in Fram Strait and the northern Nordic Seas cause a southward shift of the warm Atlantic Water recirculation and reduce its flow toward the Arctic.
    Description: Key Points: A hypothesis that a wind feedback contributes to Arctic Amplification is rejected by performing dedicated wind perturbation simulations. Winter sea ice retreat in the northern Barents Sea causes anomalous cyclonic winds by locally enhancing ocean heat loss. Anomalous cyclonic winds result in less Atlantic Water transport through Fram Strait.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: North‐German Supercomputing Alliance
    Description: https://github.com/FESOM/fesom2
    Description: https://doi.org/10.7265/N5K072F8
    Description: https://doi.org/10.5065/D6HH6H41
    Description: https://doi.org/10.5065/D6WH2N0S
    Description: https://github.com/FESOM/pyfesom2
    Description: https://doi.org/10.5281/zenodo.7458143
    Keywords: ddc:551 ; Barents Sea ; Arctic Amplification ; feedback ; Atlantic water ; modeling ; Fram Strait
    Language: English
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  • 4
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    Neogene aridification and lake development in the Issyk‐Kul basin, Kyrgyzstan (2023)
    Details
    Publication Date: 2023-11-24
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉Uplift of the Tian Shan range modified regional climate during Cenozoic aridification in Central Asia. This study presents facies analyses and Neogene oxygen and carbon isotopic records from magnetostratigraphically dated terrestrial sedimentary sections on the southern side of the intermontane Issyk‐Kul basin in the Kyrgyz Tian Shan and 〈sup〉26〈/sup〉Al/〈sup〉10〈/sup〉Be isochron burial ages from the southern and eastern sides of the basin. The δ〈sup〉18〈/sup〉O and δ〈sup〉13〈/sup〉C data show a positive ca. 2‰ shift in values between ca. 8 and 7 Ma and a change from a negative to a positive trend. This change is attributed to the upwind growth of the Kyrgyz, Kungey and Trans Ili (Zaili) ranges, which diverted the westerlies, thereby changing the Issyk‐Kul basin from a windward to a leeward position, enhancing aridification and establishing the modern‐day spring and summer precipitation regime within the basin. Two 4 to 5 Ma 〈sup〉26〈/sup〉Al/〈sup〉10〈/sup〉Be isochron burial ages constrain the onset of Sharpyl Dak deposition on the eastern side of the basin; southward paleocurrent directions there suggest the eastward growth of the Kungey range in the Pliocene. Increased subsidence on the southern side of the basin and local tectonically induced river system reorganization led to the commencement of lake formation at ca. 5 Ma, followed by a ca. 2 Ma local depositional hiatus. The transition from sandstones of the Chu sedimentary group to conglomerates of the Sharpyl Dak group, marking a change from fluvial‐alluvial deposits to a proximal alluvial fan, is dated at 2.6–2.8 Ma by 〈sup〉26〈/sup〉Al/〈sup〉10〈/sup〉Be isochron burial dating on the southern side of the basin, driven either by tectonics or Northern Hemisphere glaciation. This study concludes that the late Miocene–Pliocene northward growth of Tian Shan significantly altered environmental conditions within the range, preventing the moisture‐bearing westerlies from reaching the intermontane Issyk‐Kul basin and promoting lake formation and expansion.〈/p〉
    Description: 〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉The late Miocene–Pliocene northward growth of Tian Shan created an orographic barrier that diverted the moisture‐bearing westerlies and enhanced aridification in the Issyk‐Kul basin. Reorganization of the river systems and enhanced subsidence led to the formation of an internally drained lake in Pliocene. The transition from sandstone to conglomerate (Sharpyl Dak group) deposition, linked to a change in climate and/or tectonic activity, occurred diachronously within the basin.〈boxed-text position="anchor" content-type="graphic" id="bre12751-blkfxd-0001" xml:lang="en"〉〈graphic position="anchor" id="jats-graphic-1" xlink:href="urn:x-wiley:0950091X:bre12751:bre12751-toc-0001"〉 〈/graphic〉〈/boxed-text〉〈/p〉
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: University of Wollongong http://dx.doi.org/10.13039/501100001777
    Keywords: ddc:551 ; Cenozoic aridification ; Central Asia ; cosmogenic 26Al/10Be ; tectonic uplift ; westerlies ; δ18O and δ13C stable isotopes
    Language: English
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  • 5
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    Dissolved gases in the deep North Atlantic track ocean ventilation processes (2023)
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    Publication Date: 2023-03-21
    Description: Gas exchange between the atmosphere and ocean interior profoundly impacts global climate and biogeochemistry. However, our understanding of the relevant physical processes remains limited by a scarcity of direct observations. Dissolved noble gases in the deep ocean are powerful tracers of physical air-sea interaction due to their chemical and biological inertness, yet their isotope ratios have remained underexplored. Here, we present high-precision noble gas isotope and elemental ratios from the deep North Atlantic (~32°N, 64°W) to evaluate gas exchange parameterizations using an ocean circulation model. The unprecedented precision of these data reveal deep-ocean undersaturation of heavy noble gases and isotopes resulting from cooling-driven air-to-sea gas transport associated with deep convection in the northern high lati-tudes. Our data also imply an underappreciated and large role for bubble-mediated gas exchange in the global air-sea transfer of sparingly soluble gases, including O2, N2, and SF6. Using noble gases to validate the physical representation of air-sea gas exchange in a model also provides a unique opportunity to distinguish physical from biogeochemical signals. As a case study, we compare dissolved N2/Ar measurements in the deep North Atlantic to physics-only model predictions, revealing excess N2 from benthic denitrification in older deep waters (below 2.9 km). These data indicate that the rate of fixed N removal in the deep Northeastern Atlantic is at least three times higher than the global deep-ocean mean, suggesting tight coupling with organic carbon export and raising potential future implications for the marine N cycle.
    Description: NSF, UK NERC, University of Oxford Advanced Research Computing facility
    Description: https://www.bco-dmo.org/project/887496
    Description: research
    Keywords: ddc:551 ; gas exchange ; nitrogen cycle ; overturning circulation ; air-sea interaction ; noble gases
    Language: English
    Type: doc-type:article , publishedVersion
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  • 6
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    High Heat Flow Anomaly Within the St Paul Fracture Zone: Heat Advection and/or Inherent Thermal Structure? (2023)
    Details
    Publication Date: 2023-07-21
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉Heat flow across oceanic transform faults (TFs) and fracture zones (FZs) has rarely been studied in detail, despite these features representing distinct thermal boundaries within the oceanic lithosphere. Here, we present heat flow measurements across the St Paul fracture zone (SPFZ) in the equatorial Atlantic Ocean, from 48 Ma crust in the south to 71 Ma in the north. To the north of the FZ we find a basal heat flow of 63 mWm〈sup〉−2〈/sup〉, and to the south a basal heat flow of 79 mWm〈sup〉−2〈/sup〉, both in agreement with plate cooling models. However, within the SPFZ we find a heat flow of 83 mWm〈sup〉−2〈/sup〉, greater than the values of the adjacent crust and 10–15 mWm〈sup〉−2〈/sup〉 higher than predicted from conductive cooling models, suggesting that the thermal structure of the FZ has been modified. Evidence from seismic and sub‐bottom profiler data indicate recent active deformation within the SPFZ, potentially driven by lithospheric flexure across the FZ or temporal changes in TF configuration. We propose that this deformation may enable fluid circulation and heat advection within the basement, creating the seafloor heat flow anomaly within the FZ. These findings suggest that FZs may remain important zones predisposed to host deformation and fluid flow in the oceanic lithosphere, despite not being active plate boundaries.〈/p〉
    Description: Key Points: A high heat flow anomaly of 10–15 mWm〈sup〉−2〈/sup〉 is observed in the St Paul fracture zone compared to the adjacent oceanic crust. The heat flow anomaly is likely due to tectonically driven fluid flow but thermal rejuvenation at the transform fault could also contribute. Fracture zones may act as high permeability pathways for fluid flow, and form and evolve differently to standard oceanic lithosphere.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: FP7 Ideas: European Research Council http://dx.doi.org/10.13039/100011199
    Description: https://doi.pangaea.de/10.1594/PANGAEA.950419
    Description: https://doi.pangaea.de/10.1594/PANGAEA.950420
    Keywords: ddc:551 ; fracture zone ; heat flow ; oceanic crust ; St Paul ; fluid flow ; lithosphere
    Language: English
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  • 7
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    Insights Into NOx and HONO Chemistry in the Tropical Marine Boundary Layer at Cape Verde During the MarParCloud Campaign (2023)
    Details
    Publication Date: 2023-11-15
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉Chemical processing of reactive nitrogen species, especially of NO〈sub〉〈italic〉x〈/italic〉〈/sub〉 (= NO + NO〈sub〉2〈/sub〉) and nitrous acid (HONO), determines the photochemical ozone production and oxidation capacity in the troposphere. However, sources of HONO and NO〈sub〉〈italic〉x〈/italic〉〈/sub〉 in the remote marine atmosphere are still poorly understood. In this work, the multiphase chemistry mechanism CAPRAM in the model framework SPACCIM was used to study HONO formation at Cape Verde (CVAO) in October 2017, adopted with the input of current parameterizations for various HONO sources. Three simulations were performed that adequately reproduced ambient HONO levels and its diurnal pattern. The model performance for NO〈sub〉〈italic〉x〈/italic〉〈/sub〉 and O〈sub〉3〈/sub〉 improves significantly when considering dust‐surface‐photocatalytic conversions of reactive nitrogen compounds with high correlation coefficients up to 0.93, 0.56, and 0.89 for NO, NO〈sub〉2〈/sub〉, and O〈sub〉3〈/sub〉, respectively. Photocatalytic conversion of the adsorbed HNO〈sub〉3〈/sub〉 on dust is modeled to be the predominant contributor for daytime HONO at CVAO, that is, accounting for about 62% of the chemical formation rate at noontime. In contrast, the ocean‐surface‐mediated conversion of NO〈sub〉2〈/sub〉 to HONO and other discussed pathways are less important. The average OH levels at midday (9:00–16:00) modeled for cluster trajectory 1, 2, and 3 are 5.2, 5.1, and 5.2 × 10〈sup〉6〈/sup〉 molecules cm〈sup〉−3〈/sup〉, respectively. Main OH formation is driven by O〈sub〉3〈/sub〉 photolysis with a contribution of 74.6% to the total source rate, while HONO photolysis is negligible (∼1.8%). In summary, this study highlights the key role of dust aerosols for HONO formation and NO〈sub〉〈italic〉x〈/italic〉〈/sub〉 cycling at CVAO and possibly in other dust‐affected regions, urgently calling for further investigations using field and model studies.〈/p〉
    Description: Plain Language Summary: Chemical processing of NO〈sub〉〈italic〉x〈/italic〉〈/sub〉 (= NO + NO〈sub〉2〈/sub〉) and nitrous acid (HONO) is important for the tropospheric O〈sub〉3〈/sub〉 budget and oxidation capacity. However, the sources of HONO and cycling of NO〈sub〉〈italic〉x〈/italic〉〈/sub〉 in the remote marine atmosphere are still poorly explored. A detailed multiphase chemistry model simulation showed a better performance of HONO, NO〈sub〉〈italic〉x〈/italic〉〈/sub〉 and O〈sub〉3〈/sub〉 when considering dust‐surface‐photocatalytic conversions of reactive nitrogen compounds, especially the photocatalytic conversion of the adsorbed HNO〈sub〉3〈/sub〉 on dust. The simulations demonstrated that OH formation is mainly driven by the O〈sub〉3〈/sub〉 photolysis, while HONO photolysis is a negligible OH radical source due to its low concentration levels at Cape Verde. The study highlights the key role of dust aerosols for HONO and NO〈sub〉〈italic〉x〈/italic〉〈/sub〉 chemistry in the remote marine boundary layer.〈/p〉
    Description: Key Points: 〈list list-type="bullet"〉 〈list-item〉 〈p xml:lang="en"〉The sources of HONO and NO〈sub〉〈italic〉x〈/italic〉〈/sub〉 at Cape Verde are well modeled with CAPRAM〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉Photocatalytic conversion of adsorbed HNO〈sub〉3〈/sub〉 on dust is the predominant contributor for daytime HONO〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉Photolysis of O〈sub〉3〈/sub〉 is the prevailing source of OH radical at Cape Verde, while HONO photolysis is a negligible OH radical source〈/p〉〈/list-item〉 〈/list〉 〈/p〉
    Description: Leibniz Association SAW
    Description: Horizon 2020 Framework Programme http://dx.doi.org/10.13039/100010661
    Description: National Key Research and Development Program of China http://dx.doi.org/10.13039/501100012166
    Description: National Natural Science Foundation of China http://dx.doi.org/10.13039/501100001809
    Description: https://doi.org/10.5281/zenodo.8070265
    Description: http://mcm.york.ac.uk/
    Description: https://capram.tropos.de/
    Description: https://ebas.nilu.no/
    Description: https://www.ready.noaa.gov/HYSPLIT_traj.php
    Keywords: ddc:551 ; HONO ; NOx ; CAPRAM ; heterogenous chemistry ; mineral dust ; OH radical ; marine boundary layer
    Language: English
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  • 8
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    North Atlantic Drift Sediments Constrain Eocene Tidal Dissipation and the Evolution of the Earth‐Moon System (2023)
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    Publication Date: 2023-11-18
    Description: Cyclostratigraphy and astrochronology are now at the forefront of geologic timekeeping. While this technique heavily relies on the accuracy of astronomical calculations, solar system chaos limits how far back astronomical calculations can be performed with confidence. High‐resolution paleoclimate records with Milankovitch imprints now allow reversing the traditional cyclostratigraphic approach: Middle Eocene drift sediments from Newfoundland Ridge are well‐suited for this purpose, due to high sedimentation rates and distinct lithological cycles. Per contra, the stratigraphies of Integrated Ocean Drilling Program Sites U1408–U1410 are highly complex with several hiatuses. Here, we built a two‐site composite and constructed a conservative age‐depth model to provide a reliable chronology for this rhythmic, highly resolved (〈1 kyr) sedimentary archive. Astronomical components (g‐terms and precession constant) are extracted from proxy time‐series using two different techniques, producing consistent results. We find astronomical frequencies up to 4% lower than reported in astronomical solution La04. This solution, however, was smoothed over 20‐Myr intervals, and our results therefore provide constraints on g‐term variability on shorter, million‐year timescales. We also report first evidence that the g〈sub〉4〈/sub〉–g〈sub〉3〈/sub〉 “grand eccentricity cycle” may have had a 1.2‐Myr period around 41 Ma, contrary to its 2.4‐Myr periodicity today. Our median precession constant estimate (51.28 ± 0.56″/year) confirms earlier indicators of a relatively low rate of tidal dissipation in the Paleogene. Newfoundland Ridge drift sediments thus enable a reliable reconstruction of astronomical components at the limit of validity of current astronomical calculations, extracted from geologic data, providing a new target for the next generation of astronomical calculations.
    Description: Plain Language Summary: The traditional cyclostratigraphic approach is to align and correlate a geologic depth‐series with an astronomical solution. However, the chaotic nature of the Solar System prevents astronomers from precisely calculating planetary motions beyond 40–50 million years ago. This in turn limits the options for geologists to use the resulting oscillations in Earth's climate system as a metronome for determining geologic time. In this study, we reversed the cyclostratigraphic approach and used the highly rhythmical sedimentary deposits from Newfoundland Ridge (North Atlantic) to back‐calculate planetary motions at ∼41 million years ago. The superior quality of the Newfoundland Ridge geoarchive originates from the combination of relatively high sedimentation rates (∼4 cm/kyr) and the time‐continuous character of our two‐site composite record between 39.5 and 42.8 million years ago. In this work, we had to first overcome considerable challenges in reconstructing the timing of sediment deposition, which we did with highly resolved geochemical measurements from two sites. We then were able to extract information on the Earth's planetary motion and on the Earth‐Moon interactions. These astronomical reconstructions based on geological data can now be used by astronomers to describe the evolution of the solar system further back in time than was previously possible.
    Description: Key Points: A new precession‐based cyclostratigraphy for the middle Eocene intervals of IODP Sites U1408 and U1410. Variability in astronomical fundamental frequencies (g‐terms) on million‐year timescales is larger than previously assumed. Our precession constant estimate for 41 Ma (51.28 ± 0.56″/year) confirms earlier indicators of slower tidal dissipation in the Paleogene.
    Description: National Science Foundation http://dx.doi.org/10.13039/100000001
    Description: University of California http://dx.doi.org/10.13039/100005595
    Description: Belgian American Educational Foundation http://dx.doi.org/10.13039/100001491
    Description: https://paloz.marum.de/AstroComputation/index.html
    Description: https://paloz.marum.de/confluence/display/ESPUBLIC/NAFF
    Keywords: ddc:551 ; North Atlantic ; Eocene ; cyclostratigraphy ; astrochronology
    Language: English
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  • 9
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    Revealing the Extent of Submarine Permafrost and Gas Hydrates in the Canadian Arctic Beaufort Sea Using Seismic Reflection Indicators (2023)
    Details
    Publication Date: 2023-12-12
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉The Canadian Arctic Southern Beaufort Sea is characterized by prominent relict submarine permafrost and gas hydrate occurrences formed by subaerial exposure during extensive glaciations in Pliocene and Pleistocene. Submarine permafrost is still responding to the thermal change as a consequence of the marine transgression that followed the last glaciation. Submarine permafrost is still underexplored and is currently the focus of several research projects as its degradation releases greenhouse gases that contribute to climate change. In this study, seismic reflection indicators are used to investigate the presence of submarine permafrost and gas hydrates on the outer continental shelf where the base of permafrost is expected to cross‐cut geological layers. To address the challenges of marine seismic data collected in shallow water environments, we utilize a representative synthetic model to assess the data processing and the detection of submarine permafrost and gas hydrate by seismic data. The synthetic model allows us to minimize the misinterpretation of acquisition and processing artifacts. In the field data, we identify features along with characteristics arising from the top and base of submarine permafrost and the base of the gas hydrate stability zone. This work shows the distribution of the present submarine permafrost along the southern Canadian Beaufort Sea region and confirms its extension to the outer continental shelf. It supports the general shape suggested by previous works and previously published numerical models.〈/p〉
    Description: Plain Language Summary: Submarine permafrost, ground beneath the seafloor that perennially remains below 0°C, is present on the continental shelf of the Canadian Beaufort Sea. During the Late Pleistocene (∼1 Million years ago), the continental shelf was subaerially exposed to the cold Arctic air causing the formation of ice in the ground. This period was followed by a sea level rise that flooded the continental shelf with warmer waters, resulting in an intensive change of the thermal regime. The relict permafrost still reacts to this thermal change and is continuously thawing. Associated with the presence of relict permafrost, extensive gas hydrates exist to >1,000 m below the seafloor. Climate warming threatens both the stability of permafrost and associated gas hydrates. Their thawing and decomposition can cause a release of greenhouse gases which in turn amplifies climate warming. This study uses marine seismic reflection data to identify permafrost and gas hydrate in the southern Canadian Beaufort Sea. We find indicators of the top and base of permafrost and the base of the gas hydrate stability zone in the outer continental shelf area. Our work shows that the permafrost and gas hydrates still extend to the outer continental shelf and thereby supports previously published numerical models.〈/p〉
    Description: Key Points: 〈list list-type="bullet"〉 〈list-item〉 〈p xml:lang="en"〉Seismic reflection data reveal occurrences and extent of submarine permafrost and associated gas hydrates at the Canadian Beaufort Shelf〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉Synthetic modeling of permafrost and gas hydrate is required to assess seismic processing minimizing the potential for misinterpretation〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉Indicators of top and base of permafrost and the base of gas hydrate stability support previously published numerical models〈/p〉〈/list-item〉 〈/list〉 〈/p〉
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: Korean Ministry of Oceans and Fisheries
    Description: Environmental Geoscience Program of the Geological Survey of Canada
    Description: https://dx.doi.org/doi:10.22663/KOPRI-KPDC-00001958.3
    Keywords: ddc:551 ; submarine permafrost ; gas hydrate ; marine seismic ; Canadian Beaufort Sea ; seismic reflection
    Language: English
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  • 10
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    Atmospheric CO2 Concentration Based on Boron Isotopes Versus Simulations of the Global Carbon Cycle During the Plio‐Pleistocene (2023)
    Details
    Publication Date: 2023-09-13
    Description: Atmospheric carbon dioxide concentrations (pCO〈sub〉2〈/sub〉) beyond ice core records have been reconstructed from δ〈sup〉11〈/sup〉B derived from planktic foraminifera found in equatorial sediment cores. Here, I applied a carbon cycle model over the Plio‐Pleistocene to evaluate the assumptions leading to these numbers. During glacials times, simulated atmospheric pCO〈sub〉2〈/sub〉 was unequilibrated with pCO〈sub〉2〈/sub〉 in the equatorial surface ocean by up to 35 ppm while the δ〈sup〉11〈/sup〉B‐based approaches assume unchanged (quasi)equilibrium between both. In the Pliocene, δ〈sup〉11〈/sup〉B‐based estimates of surface ocean pH are lower in the Pacific than in the Atlantic resulting in higher calculated pCO〈sub〉2〈/sub〉. This offset in pH between ocean basins is not supported by models. To calculate pCO〈sub〉2〈/sub〉 in surface waters out of the δ〈sup〉11〈/sup〉B‐based pH some assumptions on either total alkalinity or dissolved inorganic carbon are necessary. However, the assumed values of these under‐constrained variables were according to my results partly inconsistent with chemically possible combinations within the marine carbonate system. The model results show glacial/interglacial variability in total alkalinity of the order of 100 μmol/kg, which is rarely applied to proxy reconstructions. Simulated atmospheric pCO〈sub〉2〈/sub〉 is tightly (r〈sup〉2〈/sup〉 〉 0.9) related to equatorial surface‐ocean pH, which can be used for consistency checks. Long‐term trends in volcanic CO〈sub〉2〈/sub〉 outgassing and the strength of the continental weathering fluxes are still unconstrained, allowing for a wide range of possible atmospheric pCO〈sub〉2〈/sub〉 across the Plio‐Pleistocene. Nevertheless, this carbon cycle analysis suggests that reported atmospheric pCO〈sub〉2〈/sub〉 above 500 ppm in the Pliocene might, for various reasons, need to be revised to smaller numbers.
    Description: Key Points: Simulated equatorial surface ocean 𝑝CO〈sub〉2〈/sub〉 is near‐equilibrium with atmosphere during interglacials but enriched (≤35 ppm) during glacials. Models suggest similar equatorial surface 𝑝H in Pacific and in Atlantic in high CO〈sub〉2〈/sub〉 worlds while Pliocene reconstructions show offsets. Carbon cycle model analysis suggests that reported CO〈sub〉2〈/sub〉 values above 500 ppm in the Pliocene might need revisions to smaller numbers.
    Keywords: ddc:551 ; carbon cycle ; modeling ; CO2 ; boron isotopes ; pH ; Plio‐Pleistocene
    Language: English
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  • 11
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    A Comparison Study of Mg/Ca‐, Alkenone‐, and TEX86‐Derived Temperatures for the Brazilian Margin (2023)
    Details
    Publication Date: 2023-12-14
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉The reconstruction of accurate sea‐surface temperatures (SST) is of utmost importance due to the ocean's central role in the global climate system. Yet, a number of environmental processes might bias reliable SST estimations. Here, we investigate the fidelity of SST reconstructions for the western tropical South Atlantic (WTSA) for the interval covered by Marine Isotope Stages (MIS) 6–5, utilizing a core collected off eastern Brazil at ∼20°S. This interval was selected as previous SST estimates based on Mg/Ca ratios of planktic foraminifera suggested a peculiar pooling of warm surface waters in the WTSA during MIS 6 despite glacial boundary conditions. To ground‐truth the Mg/Ca‐based SST data we generated SST reconstructions on the same core material using the alkenone and TEX〈sub〉86〈/sub〉 paleothermometers. Comparison with alkenone‐based temperature estimates corroborate the previous Mg/Ca‐based SST reconstructions, supporting the suggestion of a warm‐water anomaly during MIS 6. In contrast, TEX〈sub〉86〈/sub〉‐derived temperatures, albeit representing annual mean SST in recent core top samples, are up to 6°C colder than Mg/Ca‐ and alkenone‐based SST reconstructions. We interpret the periods of anomalously cold TEX〈sub〉86〈/sub〉‐temperatures as a result of a vertical migration of the TEX〈sub〉86〈/sub〉 producers (heterotrophic marine Thaumarchaeota) toward greater water depths, following food availability during phases of enhanced fluvial suspension input. Likewise, the data suggest that alkenone‐based SST are, albeit to a minor degree when compared to TEX〈sub〉86〈/sub〉, affected by river run‐off and/or a seasonal bias in the growth season of haptophyte algae.〈/p〉
    Description: Plain Language Summary: In this study, we investigate the accuracy of sea‐surface temperature (SST) reconstructions for the western tropical South Atlantic (WTSA) for the interval covered by Marine Isotope Stages (MIS) 6–5—the penultimate glacial‐interglacial cycle (ca. 190,000 to 70,00 years before present). This time interval was selected because previous SST estimates based on Mg/Ca ratios of planktic foraminifera suggested a pooling of warm surface waters in the WTSA during late MIS 6 despite the cold glacial conditions. To verify the Mg/Ca‐based SST data, we generated temperature reconstructions from a core located off Eastern Brazil using two common paleothermometers that based on lipid biomarkers: alkenone and TEX〈sub〉86〈/sub〉. The alkenone‐based temperature estimates agree with previous Mg/Ca‐based SST reconstructions, supporting the existence of a warm‐water anomaly in the WTSA during MIS 6. On the other hand, TEX〈sub〉86〈/sub〉‐derived temperatures were up to 6°C colder than Mg/Ca‐ and alkenone‐based SST reconstructions. This discrepancy might be a result of a vertical migration of the TEX86 producers toward greater water depths where they feed on particles of organic matter. These migrations into deeper waters occurred during phases of increased river run‐off fluvial suspension input which enhanced surface primary productivity and facilitated vertical particle flux through the water column.〈/p〉
    Description: Key Points: 〈list list-type="bullet"〉 〈list-item〉 〈p xml:lang="en"〉Parallel Mg/Ca (〈italic〉Globigerinoides ruber〈/italic〉), alkenone and TEX〈sub〉86〈/sub〉‐based temperature estimates in the western tropical South Atlantic (WTSA) across Marine Isotope Stages (MIS) 6–5〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉Mg/Ca and alkenones represent annual mean sea surface temperatures, but most TEX〈sub〉86〈/sub〉‐based temperatures deviate to colder values〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉Anomalous sea surface warming in the WTSA during late MIS 6 appears as a robust signal〈/p〉〈/list-item〉 〈/list〉 〈/p〉
    Description: R/V METEOR
    Description: DFG
    Description: CNPq
    Description: FAPESP
    Description: Alexander von Humboldt‐Stiftung http://dx.doi.org/10.13039/100005156
    Description: https://doi.org/10.1594/PANGAEA.956207
    Keywords: ddc:551 ; Mg/Ca ; alkenones ; TEX86 ; MIS 6 ; Brazilian Margin ; MIS 5
    Language: English
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  • 12
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    Oxygen Dependent Temperature Regulation of Benthic Fluxes in Reservoirs (2023)
    Details
    Publication Date: 2023-12-16
    Description: Temperature and dissolved oxygen concentration are critical factors affecting the exchange of solutes between sediment and water; both factors will be affected by warming of lakes and thereby influence water quality. Temperature and oxygen responses of single solute fluxes are well known; however, not much is known about the interaction of temperature and oxygen in regulating the balance of different fluxes in the benthic environment. We analyzed benthic flux (mobilization and immobilization) data of various solutes (dissolved organic carbon (DOC), CH〈sub〉4〈/sub〉, NO〈sub〉3〈/sub〉〈sup〉−〈/sup〉‐N, NH〈sub〉4〈/sub〉+〈/sup〉‐N, SRP, SO〈sub〉4〈/sub〉〈sup〉−〈/sup〉, Fe, Mn, and O〈sub〉2〈/sub〉) collected from laboratory incubations of 142 sediment cores from 5 different reservoirs incubated under varying in situ temperature and oxygen conditions. Oxygen was the primary driver of benthic fluxes, while temperature and total organic content were secondary. Temperature effects on benthic fluxes were stronger under anoxic conditions which imply that warming will substantially increase the benthic fluxes if the sediment surface becomes anoxic. The varying temperature response of processes underlying the studied fluxes will result in a shift of their relative importance in the benthic environment, especially in shallow lakes that are more vulnerable to warming. For example, more anoxic conditions will shift the equilibrium between net sulfate reduction and methane release toward the latter. We also predict that physical effects of warming leading to hypolimnetic oxygen depletion, that is, stronger stratification and longer hypolimnetic confinement will increase the benthic mobilization of phosphorus, DOC, and methane into water and immobilization of sulfate by the sediments even in deep lakes.
    Description: Plain Language Summary: Temperature and dissolved oxygen concentration control the release of undesirable components buried in lake or reservoir sediments, that is, nutrients, metals, and organic matter, which can cause water quality problems. We investigated the effects of rising temperature and levels of oxygen on the release of undesirable components by performing experiments using sediments and water from five different reservoirs. The sediments with a layer of water on top were incubated under different in situ temperature (low and high) and oxygen conditions (with and without). Our results show that the absence of oxygen was the main cause of the release of nutrients and metals. When there was no oxygen in the sediment and water, nutrients and metals were released from the sediment into the water and this effect increased when temperature was high. There is higher possibility that phosphorus, dissolved organic carbon, and methane will be released from sediments in some reservoirs as a result of global warming.
    Description: Key Points: Solute fluxes from benthic lake sediments varied in response to temperature, with oxygen fluxes responding most strongly. Temperature effects on the magnitude of benthic fluxes were stronger under anoxic than oxic conditions. Direct temperature effects on reservoir water quality will be small compared to indirect effects through anoxia facilitation.
    Description: German Federal Ministry of Education and Research
    Description: MINECO
    Description: https://doi.pangaea.de/10.1594/PANGAEA.928570
    Keywords: ddc:551 ; temperature dependency ; oxygen ; benthic fluxes ; reservoirs ; anoxia ; activation energy
    Language: English
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  • 13
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    Advances in New Zealand's Tephrochronostratigraphy Using Marine Drill Sites: The Neogene (2023)
    Details
    Publication Date: 2023-12-16
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉Three volcanic arcs have been the source of New Zealand's volcanic activity since the Neogene: Northland arc, Coromandel Volcanic Zone (CVZ) and Taupō Volcanic Zone (TVZ). The eruption chronology for the Quaternary, sourced by the TVZ, is well studied and established, whereas the volcanic evolution of the precursor arc systems, like the CVZ (central activity c. 18 to 2 Ma), is poorly known due to limited accessibility to, or identification of, onshore volcanic deposits and their sources. Here, we investigate the marine tephra record of the Neogene, mostly sourced by the CVZ, of cores from IODP Exp. 375 (Sites U1520 and U1526), ODP Leg 181 (Sites 1123, 1124 and 1125), IODP Leg 329 (Site U1371) and DSDP Leg 90 (Site 594) offshore of New Zealand. In total, we identify 306 primary tephra layers in the marine sediments. Multi‐approach age models (e.g. biostratigraphy, zircon ages) are used in combination with geochemical fingerprinting (major and trace element compositions) and the stratigraphic context of each marine tephra layer to establish 168 tie‐lines between marine tephra layers from different holes and sites. Following this approach, we identify 208 explosive volcanic events in the Neogene between c. 17.5 and 2.6 Ma. This is the first comprehensive study of New Zealand's Neogene explosive volcanism established from tephrochronostratigraphic studies, which reveals continuous volcanic activity between c. 12 and 2.6 Ma with an abrupt compositional change at c. 4.5 Ma, potentially associated with the transition from CVZ to TVZ.〈/p〉
    Description: Plain Language Summary: Since 18 Ma, volcanic activity in New Zealand is dominantly sourced by the Coromandel Volcanic Zone (CVZ). Most caldera systems of the CVZ identified so far are located on Coromandel Peninsula in the NW of North Island, New Zealand, but studies of the CVZ are rare mainly due to the limited accessibility of its volcanic deposits, as well as missing stratigraphic continuity between different outcrops and the volcanic source. Here, our ocean drilling tephra record—mainly volcanic ash from explosive eruptions, distributed and falling out over the ocean—has a great potential to reveal the eruption history of the CVZ because it is preserved in marine sediments in a nearly undisturbed stratigraphic context. We analyzed ∼400 marine tephra layers from multiple ocean sediment cores off the coast of New Zealand for their geochemical glass compositions and identified 306 as largely undisturbed ash deposits. These primary ash deposits correspond to a total number of 208 Neogene volcanic events. Different dating methods result in a continuous marine tephra record for the last 12 Ma, equivalent to a unique and most complete eruptive history for the CVZ. This enables us to further unravel changes in the composition of the associated magmas with time.〈/p〉
    Description: Key Points: 〈list list-type="bullet"〉 〈list-item〉 〈p xml:lang="en"〉New Zealand's Neogene explosive volcanism based on the marine tephra record〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉Geochemical fingerprinting of marine tephra layers across the study area to establish volcanic events〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉Insights into geochemical variations with time, repose times and spatiotemporal distribution〈/p〉〈/list-item〉 〈/list〉 〈/p〉
    Description: DFG
    Description: Marsden project
    Description: https://doi.org/10.14379/iodp.proc.372B375.210.2023
    Keywords: ddc:551 ; marine tephrochronostratigraphy ; geochemical fingerprinting ; correlations of marine tephras between individual drill sites ; IODP ; ODP and DSDP drill sites ; neogene eruption record of New Zealand
    Language: English
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  • 14
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    A Snapshot on the Buildup of the Stable Water Isotopic Signal in the Upper Snowpack at EastGRIP on the Greenland Ice Sheet (2023)
    Zuhr, Alexandra M. ; Wahl, Sonja ; Steen‐Larsen, Hans Christian ; [et al.]
    Details
    Publication Date: 2024-04-19
    Description: The stable water isotopic composition in firn and ice cores provides valuable information on past climatic conditions. Because of uneven accumulation and post‐depositional modifications on local spatial scales up to hundreds of meters, time series derived from adjacent cores differ significantly and do not directly reflect the temporal evolution of the precipitated snow isotopic signal. Hence, a characterization of how the isotopic profile in the snow develops is needed to reliably interpret the isotopic variability in firn and ice cores. By combining digital elevation models of the snow surface and repeated high‐resolution snow sampling for stable water isotope measurements of a transect at the East Greenland Ice‐core Project campsite on the Greenland Ice Sheet, we are able to visualize the buildup and post‐depositional changes of the upper snowpack across one summer season. To this end, 30 cm deep snow profiles were sampled on six dates at 20 adjacent locations along a 40 m transect. Near‐daily photogrammetry provided snow height information for the same transect. Our data shows that erosion and redeposition of the original snowfall lead to a complex stratification in the δ〈sup〉18〈/sup〉O signature. Post‐depositional processes through vapor‐snow exchange affect the near surface snow with d‐excess showing a decrease in surface and near‐surface layers. Our data suggests that the interplay of stratigraphic noise, accumulation intermittency, and local post‐depositional processes form the proxy signal in the upper snowpack.
    Description: Plain Language Summary: We study the process of the formation of the stable water isotope signal in surface snow on the Greenland Ice Sheet to better understand temperature information which is stored as a climate proxy in snow and ice. Our data consist of high‐resolution surface topography information illustrating the timing and location of snowfall, erosion, and redeposition along a transect of 40 m, as well as stable water isotope records of the upper 30 cm of the snowpack sampled biweekly on 20 positions at the same 40 m long transect. The data cover a 2‐month period during the summer of 2019. We find that the isotopic composition shows spatial variability of layers with low and high values, presumably winter and summer layers. We further observe that prevailing surface structures, such as dunes, influence the snow deposition and contribute to the found variable structure of the climatic information. Eventually, snow accumulation alone cannot explain all of the observed patterns in the isotopic data which is likely related to exchange processes between the snow and the atmosphere which modify the signal in the snow column after deposition.
    Description: Key Points: Combining digital elevation models and repeated snow sampling reveals the heterogeneous buildup of δ〈sup〉18〈/sup〉O signal in the snow column. Surface structures (stratigraphic noise) substantially contribute to internal heterogeneity in δ〈sup〉18〈/sup〉O signature in the upper snowpack. Proxy signals are formed in the surface layer by local processes, advected downwards with limited post‐depositional influences below 10 cm.
    Description: Horizon 2020 Framework Programme http://dx.doi.org/10.13039/100010661
    Description: A. P. Møller Foundation, University of Copenhagen
    Description: US National Science Foundation, Office of Polar Programs
    Description: Alfred Wegener Institute, Helmholtz Centre for Polar and Marine Research
    Description: National Institute of Polar Research and Arctic Challenge for Sustainability
    Description: University of Bergen
    Description: Trond Mohn Foundation
    Description: Swiss National Science Foundation
    Description: French Polar Institute Paul‐Emile Victor, Institute for Geosciences and Environmental Research
    Description: University of Manitoba
    Description: Chinese Academy of Sciences
    Description: Beijing Normal University
    Description: https://doi.org/10.1594/PANGAEA.954944
    Description: https://doi.org/10.1594/PANGAEA.954945
    Description: https://doi.org/10.1594/PANGAEA.951583
    Description: https://doi.org/10.1594/PANGAEA.925618
    Description: https://doi.org/10.1594/PANGAEA.928827
    Description: https://www.agisoft.com/downloads/installer/
    Keywords: ddc:551 ; proxy ; Greenland ; isotopes ; structure‐from‐motion ; snow accumulation ; ice core
    Language: English
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  • 15
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    Assessing Volcanic Controls on Miocene Climate Change (2022)
    Details
    Publication Date: 2022-03-25
    Description: The Miocene period saw substantially warmer Earth surface temperatures than today, particularly during a period of global warming called the Mid Miocene Climatic Optimum (MMCO; ∼17–15 Ma). However, the long‐term drivers of Miocene climate remain poorly understood. By using a new continuous climate‐biogeochemical model (SCION), we can investigate the interaction between volcanism, climate and biogeochemical cycles through the Miocene. We identify high tectonic CO2 degassing rates and further emissions associated with the emplacement of the Columbia River Basalt Group as the primary driver of the background warmth and the MMCO respectively. We also find that enhanced weathering of the basaltic terrane and input of explosive volcanic ash to the oceans are not sufficient to drive the immediate cooling following the MMCO and suggest that another mechanism, perhaps the change in ocean chemistry due to massive evaporite deposition, was responsible.
    Description: Plain Language Summary: The Miocene period was much warmer than today, with the Mid Miocene Climatic Optimum (MMCO, roughly 17–15 million years ago) especially warm. Due to the high surface temperatures, comparisons to projected climatic conditions as a result of anthropogenic climate change have been drawn. However, the drivers of climate during the Miocene are not well understood. By using a new type of climate model, we investigate the impact volcanic eruptions had on the period, and link the extreme warmth of the MMCO with greenhouse gas release from the eruption of the Columbia River Basalts Group (CRBG). We find weathering of the CRBG does not explain the cooling at the end of the MMCO, and so discuss other potential explanations such as evaporite deposition.
    Description: Key Points: A new climate‐biogeochemical model allows investigation of drivers of climate change in the Miocene. Columbia River Basalt Group (CRBG) degassing is sufficient to have caused the Mid Miocene Climatic Optimum (MMCO). Weathering of CRBG insufficient to drive cooling after the MMCO. This may be linked to evaporite deposition and changes to marine chemistry.
    Description: UK Natural Environment Research Council
    Description: French Research Agency (ANR)
    Keywords: ddc:551
    Language: English
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  • 16
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    Investigating the Basal Shear Zone of the Submarine Tuaheni Landslide Complex, New Zealand: A Core‐Log‐Seismic Integration Study (2022)
    Details
    Publication Date: 2022-03-29
    Description: Although submarine landslides have been studied for decades, a persistent challenge is the integration of diverse geoscientific datasets to characterize failure processes. We present a core‐log‐seismic integration study of the Tuaheni Landslide Complex to investigate intact sediments beneath the undeformed seafloor as well as post‐failure landslide deposits. Beneath the undeformed seafloor are coherent reflections underlain by a weakly‐reflective and chaotic seismic unit. This chaotic unit is characterized by variable shear strength that correlates with density fluctuations. The basal shear zone of the Tuaheni landslide likely exploited one (or more) of the low shear strength intervals. Within the landslide deposits is a widespread “Intra‐debris Reflector”, previously interpreted as the landslide's basal shear zone. This reflector is a subtle impedance drop around the boundary between upper and lower landslide units. However, there is no pronounced shear strength change across this horizon. Rather, there is a pronounced reduction in shear strength ∼10–15 m above the Intra‐debris Reflector that presumably represents an induced weak layer that developed during failure. Free gas accumulates beneath some regions of the landslide and is widespread deeper in the sedimentary sequence, suggesting that free gas may have played a role in pre‐conditioning the slope to failure. Additional pre‐conditioning or failure triggers could have been seismic shaking and associated transient fluid pressure. Our study underscores the importance of detailed core‐log‐seismic integration approaches for investigating basal shear zone development in submarine landslides.
    Description: Plain Language Summary: Submarine landslides move enormous amounts of sediment across the seafloor and have the potential to generate damaging tsunamis. To understand how submarine landslides develop, we need to be able to image and sample beneath the seafloor in regions where landslides have occurred. To image beneath the seafloor we generate sound waves in the ocean and record reflections from those waves, enabling us to produce “seismic images” of sediment layers and structures beneath the seafloor. We then use scientific drilling to sample the sediment layers and measure physical properties. In this study, we combine seismic images and drilling results to investigate a submarine landslide east of New Zealand's North Island. Drilling next to the landslide revealed a ∼25 m‐thick layer of sediment (from ∼75–95 m below the seafloor) that has strong variations in sediment strength and density. We infer that intervals of relatively low strength within this layer developed into the main sliding surface of the landslide. Additionally, results from within the landslide suggest that the process of landslide emplacement has induced a zone of weak sediments closer to the seafloor. Our study demonstrates how combining seismic images and drilling data helps to understand submarine landslide processes.
    Description: Key Points: We integrate scientific drilling data with seismic reflection data to investigate the submarine Tuaheni Landslide Complex. Basal shear zone of the landslide likely exploited a relatively low shear strength interval within an older (buried) mass transport deposit. Landslide emplacement seems to have induced an additional weak zone that is shallower than the interpreted base of the landslide deposit.
    Description: Marsden Fund (Royal Society of New Zealand Marsden Fund) http://dx.doi.org/10.13039/501100009193
    Description: European Consortium for Ocean Research Drilling
    Description: International Ocean Drilling Program, Science Support Program
    Description: New Zealand Ministry for Business Innovation and Employment
    Description: Deutsche Forschungsgemeinschaft (DFG) http://dx.doi.org/10.13039/501100001659
    Description: https://doi.pangaea.de/10.1594/PANGAEA.928073
    Keywords: ddc:622.15 ; ddc:551
    Language: English
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  • 17
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    A Combined Cosmogenic Nuclides Approach for Determining the Temperature‐Dependence of Erosion (2022)
    Details
    Publication Date: 2022-06-26
    Description: Physical weathering in cold, steep bedrock hillslopes occurs at rates that are thought to depend on temperature, but our ability to quantify the temperature‐dependence of erosion remains limited when integrating over geomorphic timescales. Here, we present results from a 1D numerical model of in‐situ cosmogenic 10Be, 14C, and 3He concentrations that evolve as a function of erosion rate, erosion style, and ground surface temperature. We used the model to explore the suitability of these nuclides for quantifying erosion rates in areas undergoing non‐steady state erosion, as well as the relationship between bedrock temperature, erosion rate, and erosional stochasticity. Our results suggest that even in stochastically eroding settings, 10Be‐derived erosion rates of amalgamated samples can be used to estimate long‐term erosion rates, but infrequent large events can lead to bias. The ratio of 14C to 10Be can be used to evaluate erosional stochasticity, and to determine the offset between an apparent 10Be‐derived erosion rate and the long‐term rate. Finally, the concentration of 3He relative to that of 10Be, and the paleothermometric interpretations derived from it, are unaffected by erosional stochasticity. These findings, discussed in the context of bedrock hillslopes in mountainous regions, indicate that the 10Be‐14C‐3He system in quartz offers a method to evaluate the temperature‐sensitivity of bedrock erosion rates in cold, high‐alpine environments.
    Description: Plain Language Summary: All mountains erode, but not all mountains erode in the same way and at the same rate. In cold mountainous landscapes, temperature is thought to be an important control on erosion. Previous research suggests that rocks fracture by frost most effectively at temperatures between −3°C and −8°C, and that the warming and thawing of permanently frozen ground (permafrost) destabilizes hillslopes and leads to more and larger rockfalls. However, our ability to test these hypotheses is limited, due to difficulties in measuring or estimating erosion rates and linking them with the temperatures that rocks experience. In this paper we present the results of a computer modeling study that tests the suitability of geochemical tools as measures of erosion rate, erosion style, and long‐term bedrock temperature. We find that these geochemical tracers, called cosmogenic nuclides, can be used to determine erosion rates, even in places that are prone to rare rockfalls, together with the long‐term bedrock temperature. They are therefore uniquely suitable for evaluating the link between temperatures and erosion rates in cold bedrock hillslopes over long timescales.
    Description: Key Points: Cosmogenic 10Be, 14C, and 3He is used to determine erosion rates, erosion styles, and bedrock temperatures in cold regions. 14C/10Be ratios of surface samples reflect the depth at which material was previously eroded, allowing for determination of erosion style. 14C/10Be ratios combined with 10Be‐derived erosion rates improve erosion rate estimates in stochastically eroding environments.
    Description: European Research Council Horizon 2020
    Description: https://doi.org/10.5880/GFZ.3.3.2022.001
    Keywords: ddc:551
    Language: English
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    The Subducting Slab as a Chromatographic Column: Regimes of Sub‐Solidus Mass Transport as a Function of Lithospheric Hydration State, With Special Reference to the Fate of Carbonate (2022)
    Details
    Publication Date: 2022-06-24
    Description: We investigate the chemical budget of subduction zones at sub‐solidus conditions using a thermodynamic‐numerical simulation in which all major rock components are treated as soluble and potentially mobile in aqueous fluids. This new strategy significantly improves the accuracy of predicted fluid‐rock equilibrium compositions in open petrological systems. We show that all slabs release volatiles and nonvolatiles to the mantle wedge, contributing to its refertilization. But some mobile constituents, such as alkali and alumina, may be trapped along layer boundaries or traverse without interaction depending on chemical contrasts between adjacent lithologies. The accumulation of igneous alumina and silica in the limestones of the central‐eastern Pacific slabs drives their decarbonation and is marked by metasomatic garnet growth. Those slabs are also predicted to lose much of their alkalis before sub‐arc depth. Even when they are produced in the altered mafic and ultramafic layers, fluids reach the slab/mantle wedge interface with distinct compositional signatures that are typical of the sedimentary cover. We distinguished supply and transport limited regimes of element subduction by testing the sensitivity of our mass balance to changes in slab hydration state (HS). Transport limited slabs sensitive to HS include notably a hotspot of carbon release to the mantle wedge (e.g., Costa Rica). Finally, we show that the quantitative budgets do depend on the geometry of fluid flows, and on assuming that slabs are mechanically continuous structures, which is questionable. Taken together, these insights will help better constrain the long‐term chemical evolution of the shallow planetary interior, and the thermomechanical behavior of the subduction interface.
    Description: Plain Language Summary: Subduction zones return chemical elements from the surface to the deep Earth. But quantifying this transfer has been challenging. Here, we present a model where all major elements are partly mobile in the fluid phase, enabling us to compile a chemical budget for subduction zones in which only fluids mediate mass transport. We identify transport and supply regimes of element subduction as a function of lithospheric hydration state, rock compositions, and slab temperature. We show that the transport of many rock‐forming elements such as SiO2, CaO, and Al2O3, within and out of the slab, modifies rock composition and contributes to the efficiency of slab decarbonation. Our model of subduction fluid and rock compositions has important implications to understand the role of slab‐derived metasomatic fluid in modifying the composition of the mantle wedge over time, the mechanical properties of deeply subducted rocks, and it will inform future investigations for the high‐pressure petrology of rocky planets in general.
    Description: Key Points. Inter dependence of element transfers in subduction zones. Thermodynamics of intra‐slab metasomatism of major elements. Transport‐ and supply limited regimes of carbonate subduction.
    Description: Alexander von Humboldt‐Stiftung (Humboldt‐Stiftung) http://dx.doi.org/10.13039/100005156
    Description: Branco Weiss Fellowship—Society in Science
    Description: Swiss National Science Foundation
    Description: https://osf.io/y84d2/
    Keywords: ddc:551
    Language: English
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    Impact of Spreading Rate and Age‐Offset on Oceanic Transform Fault Morphology (2022)
    Details
    Publication Date: 2022-06-22
    Description: Oceanic transform faults (OTFs) are an inherent part of seafloor spreading and plate tectonics, whereas the process controlling their morphology remains enigmatic. Here, we systematically quantify variations in transform morphology and their dependence on spreading rate and age‐offset, based on a compilation of shipborne bathymetric data from 94 OTFs at ultraslow‐ to intermediate‐spreading ridges. In general, the length, width and depth of OTFs scale systematically better with age‐offset rather than spreading rate. This observation supports recent geodynamic models proposing that cross‐transform extension scaling with age‐offset, is a key process of transform dynamics. On the global scale, OTFs with larger age‐offsets tend to have longer, wider, and deeper valleys. However, at small age‐offsets (〈5 Myr), scatters in the depth and width of OTFs increase, indicating that small age‐offset OTFs with weak lithospheric strength are easily affected by secondary tectonic processes.
    Description: Plain Language Summary: In the past 5 decades, studies on oceanic transform faults (OTFs) have revealed significant complexity in their morphology, which calls for detailed quantitative analysis to study the processes controlling the morphology of OTFs. Using the most complete and advanced compilation of bathymetric data from ultraslow‐ to intermediate‐spreading ridges, we parameterized the morphological characteristics of OTFs and extracted length, width and depth for each transform fault from the compiled bathymetric data. Moreover, correlations between these morphological parameters and related tectonic factors (e.g., spreading rate, age‐offset) were investigated in this study. We find that correlations between morphological features and spreading rate are rather weak. Comparison of correlations suggests that age‐offset scales better with the morphological parameters, along with scatters mostly at small age‐offsets, indicating small‐age‐offset OTFs are unstable due to their weak lithospheric strength. Our observation evidences extensional tectonics at OTFs.
    Description: Key Points: We compiled multibeam bathymetric data of 94 oceanic transform faults (OTFs) to quantify their morphological characteristics. Morphology of OTFs is dominated by age‐offset rather than spreading rate. Transform valleys get systematically deeper and wider with increasing age‐offset, implying extensional tectonics at OTFs.
    Description: China Scholarship Council
    Description: http://doi.org/10.5281/zenodo.4774185
    Keywords: ddc:551
    Language: English
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    Role of Poroelasticity During the Early Postseismic Deformation of the 2010 Maule Megathrust Earthquake (2022)
    Peña, Carlos ; Metzger, Sabrina ; Heidbach, Oliver ; [et al.]
    Details
    Publication Date: 2022-09-29
    Description: Megathrust earthquakes impose changes of differential stress and pore pressure in the lithosphere‐asthenosphere system that are transiently relaxed during the postseismic period primarily due to afterslip, viscoelastic and poroelastic processes. Especially during the early postseismic phase, however, the relative contribution of these processes to the observed surface deformation is unclear. To investigate this, we use geodetic data collected in the first 48 days following the 2010 Maule earthquake and a poro‐viscoelastic forward model combined with an afterslip inversion. This model approach fits the geodetic data 14% better than a pure elastic model. Particularly near the region of maximum coseismic slip, the predicted surface poroelastic uplift pattern explains well the observations. If poroelasticity is neglected, the spatial afterslip distribution is locally altered by up to ±40%. Moreover, we find that shallow crustal aftershocks mostly occur in regions of increased postseismic pore‐pressure changes, indicating that both processes might be mechanically coupled.
    Description: Plain Language Summary: Large earthquakes modify the state of stress and pore pressure in the upper crust and mantle. These changes induce stress relaxation processes and pore pressure diffusion in the postseismic phase. The two main stress relaxation processes are postseismic slip along the rupture plane of the earthquake and viscoelastic deformation in the rock volume. These processes decay with time, but can sustain over several years or decades, respectively. The other process that results in volumetric crustal deformation is poroelasticity due to pore pressure diffusion, which has not been investigated in detail. Using postseismic surface displacement data acquired by radar satellites after the 2010 Maule earthquake, we show that poroelastic deformation may considerably affect the vertical component of the observed geodetic signal during the first months. Poroelastic deformation also has an impact on the estimation of the postseismic slip, which in turn affects the energy stored at the fault plane that is available for the next event. In addition, shallow aftershocks within the continental crust show a good, positive spatial correlation with regions of increased postseismic pore‐pressure changes, suggesting they are linked. These findings are thus important to assess the potential seismic hazard of the segment.
    Description: Key Points: A poro‐viscoelastic deformation model improves the geodetic data misfit by 14% compared to an elastic model that only accounts for afterslip. Poroelastic deformation mainly produces surface uplift and landward displacement patterns on the coastal forearc region. Neglecting poroelastic effects may locally alter the afterslip amplitude by up to ±40% near the region of maximum coseismic slip.
    Description: Helmholtz Association (亥姆霍兹联合会致力) http://dx.doi.org/10.13039/501100009318
    Keywords: ddc:551
    Language: English
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    Temporal evolution of headwall erosion rates derived from cosmogenic nuclide concentrations in the medial moraines of Glacier d'Otemma, Switzerland (2022)
    Details
    Publication Date: 2022-10-04
    Description: Climate change affects the stability and erosion of high‐alpine rock walls above glaciers (headwalls) that deliver debris to glacier surfaces. Since supraglacial debris in the ablation zone alters the melt behaviour of the underlying ice, the responses of debris‐covered glaciers and of headwalls to climate change may be coupled. In this study, we analyse the beryllium‐10 (10Be)‐cosmogenic nuclide concentration history of glacial headwalls delivering debris to the Glacier d'Otemma in Switzerland. By systematic downglacier‐profile‐sampling of two parallel medial moraines, we assess changes in headwall erosion through time for small, well‐defined debris source areas. We compute apparent headwall erosion rates from 10Be concentrations ([10Be]), measured in 15 amalgamated medial moraine debris samples. To estimate both the additional 10Be production during glacial debris transport and the age of our samples we combine our field‐based data with a simple model that simulates downglacier debris trajectories. Furthermore, we evaluate additional grain size fractions for eight samples to test for stochastic mass wasting effects on [10Be]. Our results indicate that [10Be] along the medial moraines vary systematically with time and consistently for different grain sizes. [10Be] are higher for older debris, closer to the glacier terminus, and lower for younger debris, closer to the glacier head. Computed apparent headwall erosion rates vary between ~0.6 and 10.8 mm yr−1, increasing over a maximum time span of ~200 years towards the present. As ice cover retreats, newly exposed headwall surfaces may become susceptible to enhanced weathering and erosion, expand to lower elevations, and contribute formerly shielded bedrock of likely different [10Be]. Hence, we suggest that recently lower [10Be] reflect the deglaciation of the debris source areas since the end of the Little Ice Age.
    Description: In glacial landscapes, systematic downglacier‐sampling of medial moraine debris holds the potential to assess changes in headwall erosion through time. Cosmogenic beryllium‐10 (10Be) concentrations within the medial moraines of Glacier d'Otemma, Switzerland, broadly increase downglacier and translate into increasing headwall erosion rates towards the present. These trends may reflect processes associated with the exposure of new bedrock surfaces across recently deglaciating source headwalls.
    Description: European Research Council (ERC) H2020‐EU.1.1.
    Description: https://doi.org/10.5880/GFZ.3.3.2021.007
    Keywords: ddc:551
    Language: English
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    Basin‐scale estimates of greenhouse gas emissions from the Mara River, Kenya: Importance of discharge, stream size, and land use/land cover (2022)
    Mwanake, Ricky M. ; Gettel, Gretchen M. ; Ishimwe, Clarisse ; [et al.]
    John Wiley & Sons, Inc. | Hoboken, USA
    Details
    Publication Date: 2022-10-04
    Description: Greenhouse gas fluxes (CO2, CH4, and N2O) from African streams and rivers are under‐represented in global datasets, resulting in uncertainties in their contributions to regional and global budgets. We conducted year‐long sampling of 59 sites in a nested‐catchment design in the Mara River, Kenya in which fluxes were quantified and their underlying controls assessed. We estimated annual basin‐scale greenhouse gas emissions from measured in‐stream gas concentrations, modeled gas transfer velocities, and determined the sensitivity of up‐scaling to discharge. Based on the total annual CO2‐equivalent emissions calculated from global warming potentials (GWP), the Mara basin was a net greenhouse gas source (294 ± 35 Gg CO2 eq yr−1). Lower‐order streams (1–3) contributed 81% of the total fluxes, and higher stream orders (4–8) contributed 19%. Cropland‐draining streams also exhibited higher fluxes compared to forested streams. Seasonality in stream discharge affected stream widths (and stream area) and gas exchange rates, strongly influencing the basin‐wide annual flux, which was 10 times higher during the high and medium discharge periods than the low discharge period. The basin‐wide estimate was underestimated by up to 36% if discharge was ignored, and up to 37% for lower stream orders. Future research should therefore include seasonality in stream surface areas in upscaling procedures to better constrain basin‐wide fluxes. Given that agricultural activities are a major factor increasing riverine greenhouse gas fluxes in the study region, increased conversion of forests and agricultural intensification has the possibility of increasing the contribution of the African continent to global greenhouse gas sources.
    Description: Deutscher Akademischer Austauschdienst http://dx.doi.org/10.13039/501100001655
    Description: IHE Delft Institute for Water Education
    Description: Federal Ministry of Education and Research http://dx.doi.org/10.13039/501100002347
    Description: Helmholtz Association http://dx.doi.org/10.13039/501100009318
    Description: TERENO Bavarian Alps/ Pre‐Alps Observatory
    Keywords: ddc:551
    Language: English
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    Deepening the Late Quaternary's Deep Ocean Carbon Mysteries (2022)
    Details
    Publication Date: 2022-10-04
    Description: Changes to the carbon content of the deep ocean, the largest reservoir in the surficial carbon cycle, are capable of altering atmospheric carbon dioxide concentrations and thereby Earth's climate. While the role of the deep ocean's carbon inventory in the last ice age has been thoroughly investigated, comparatively little is known about whether the deep ocean contributed to the change in the pacing and intensity of ice ages around 1 million years ago during the Mid‐Pleistocene Transition (MPT). Qin et al. (2022, https://doi.org/10.1029/2021GL097121) provide new reconstructions of deep ocean carbonate ion saturation, a proxy for carbon content, from the deep Pacific Ocean across the MPT. Intriguingly, their results show that a reduction in deep Pacific carbonate ion saturation across the MPT occurred at different intervals from carbonate ion saturation decline in the deep Atlantic Ocean. These results suggest a more nuanced contribution of whole‐ocean carbon sequestration to the climate changes reconstructed across the MPT.
    Description: Plain Language Summary: Earth's periodic ice ages became longer and more intense around 1 million years ago. While the underlying reasons for this climate change remain debated, it is widely understood that the deep ocean may have played an important role by storing the potent greenhouse gas carbon dioxide away from the atmosphere. New research by Qin et al. (2022, https://doi.org/10.1029/2021gl097121) shows that the deep Pacific Ocean did indeed accumulate additional carbon around the time of this million‐year old climate transition. However, the new results also show that Pacific Ocean accumulated carbon over different intervals than the Atlantic Ocean, deepening the mystery around how and why this carbon uptake occurred.
    Description: Key Points: The deep Atlantic and Pacific Oceans accumulated carbon at different intervals during the mid‐Pleistocene transition.
    Description: National Science Foundation http://dx.doi.org/10.13039/100000001
    Description: https://doi.org/10.1029/2021GL097121
    Keywords: ddc:551
    Language: English
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    Variability in the Concentration of Lithium in the Indo‐Pacific Ocean (2022)
    Details
    Publication Date: 2022-10-04
    Description: Lithium has limited biological activity and can readily replace aluminium, magnesium and iron ions in aluminosilicates, making it a proxy for the inorganic silicate cycle and its potential link to the carbon cycle. Data from the North Pacific Ocean, tropical Indian Ocean, Southern Ocean and Red Sea suggest that salinity normalized dissolved lithium concentrations vary by up to 2%–3% in the Indo‐Pacific Ocean. The highest lithium concentrations were measured in surface waters of remote North Pacific and Indian Ocean stations that receive relatively high fluxes of dust. The lowest dissolved lithium concentrations were measured just below the surface mixed layer of the stations with highest surface water concentrations, consistent with removal into freshly forming aluminium rich phases and manganese oxides. In the North Pacific, water from depths 〉2,000 m is slightly depleted in lithium compared to the initial composition of Antarctic Bottom Water, likely due to uptake of lithium by authigenically forming aluminosilicates. The results of this study suggest that the residence time of lithium in the ocean may be significantly shorter than calculated from riverine and hydrothermal fluxes.
    Description: Key Points: Li/Na ratios vary by up to 2%–3% in the Indian and Pacific Oceans. Authigenic formation of aluminosilicates slightly deplete deep‐water lithium concentrations in the North Pacific. The residence time of lithium in the ocean is 240,000 ± 70,000 years, based on removal from North Pacific deep‐water.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: MoES, Indian National Centre for Ocean Information Services http://dx.doi.org/10.13039/501100004814
    Description: National Science Foundation USA
    Description: https://doi.pangaea.de/10.1594/PANGAEA.941888
    Keywords: ddc:551
    Language: English
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    Analytical Solutions for Gravity Changes Caused by Triaxial Volumetric Sources (2022)
    Details
    Publication Date: 2022-06-17
    Description: Volcanic crises are often associated with magmatic intrusions or the pressurization of magma chambers of various shapes. These volumetric sources deform the country rocks, changing their density, and cause surface uplift. Both the net mass of intruding magmatic fluids and these deformation effects contribute to surface gravity changes. Thus, to estimate the intrusion mass from gravity changes, the deformation effects must be accounted for. We develop analytical solutions and computer codes for the gravity changes caused by triaxial sources of expansion. This establishes coupled solutions for joint inversions of deformation and gravity changes. Such inversions can constrain both the intrusion mass and the deformation source parameters more accurately.
    Description: Plain Language Summary: Volcanic crises are usually associated with magmatic fluids that intrude and deform the host rocks before potentially breaching the Earth's surface. It is important to estimate how much fluid (mass and volume) is on the move. Volume can be determined from the measured surface uplift. Mass can be determined from surface gravity changes. The fluid intrusion increases the mass below the volcano, thereby increasing the gravity and pressurizing the rocks. This dilates parts of the host rock and compresses other parts, changing the rock density and redistributing the rock mass. This causes secondary gravity changes, called deformation‐induced gravity changes. The measured gravity change is always the sum of the mass and deformation‐induced contributions. Here, we develop mathematical equations for the rapid estimation of these deformation‐induced gravity changes caused by arbitrary intrusion shapes. This way we can take the mass contribution apart from the deformation contribution. We show that by using this solution not only the intrusion mass, but also other intrusion parameters, including the volume, depth, and shape can be calculated more accurately.
    Description: Key Points; We develop analytical solutions for gravity changes due to the point Compound Dislocation Model simulating triaxial expansions. Rapid coupled inversions of deformation and gravity changes, accounting for deformation‐induced gravity changes are now possible. For shallow sources, estimation errors in the chamber volume change may lead to large biases in the simulated gravity changes.
    Description: EU Horizon 2020 programme NEWTON‐g project, under the FETOPEN‐ Grant Agreement No.
    Description: Deutsche Forschungsgemeinschaft (DFG) http://dx.doi.org/10.13039/501100001659
    Description: https://volcanodeformation.com/onewebmedia/pCDMgravity.zip
    Keywords: ddc:551
    Language: English
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    The Arctic Ocean in CMIP6 Models: Biases and Projected Changes in Temperature and Salinity (2022)
    Details
    Publication Date: 2022-06-17
    Description: We examine the historical evolution and projected changes in the hydrography of the deep basin of the Arctic Ocean in 23 climate models participating in the Coupled Model Intercomparison Project Phase 6 (CMIP6). The comparison between historical simulations and observational climatology shows that the simulated Atlantic Water (AW) layer is too deep and thick in the majority of models, including the multi‐model mean (MMM). Moreover, the halocline is too fresh in the MMM. Overall our findings indicate that there is no obvious improvement in the representation of the Arctic hydrography in CMIP6 compared to CMIP5. The climate change projections reveal that the sub‐Arctic seas are outstanding warming hotspots, causing a strong warming trend in the Arctic AW layer. The MMM temperature increase averaged over the upper 700 m at the end of the 21st century is about 40% and 60% higher in the Arctic Ocean than the global mean in the SSP245 and SSP585 scenarios, respectively. Salinity in the upper few hundred meters is projected to decrease in the Arctic deep basin in the MMM. However, the spread in projected salinity changes is large and the tendency toward stronger halocline in the MMM is not simulated by all the models. The identified biases and projection uncertainties call for a concerted effort for major improvements of coupled climate models.
    Description: Plain Language Summary: Coupled climate models are crucial tools for understanding and projecting climate change, especially for the Arctic where the climate is changing at unprecedented rates. A cold fresh layer of water (aka halocline) has been protecting sea‐ice at the surface from the warm layer of water (aka Atlantic Water layer) which flows underneath and could potentially accelerate sea ice melting from below. Climate change disturbs this vertical structure by changing the temperature and salinity of the Arctic Ocean (in a process known as Atlantification and Pacification) which may lead to additional sea ice basal melting and accelerate sea ice decline. We examined the simulated temperature and salinity in the Arctic Ocean deep basin in state‐of‐the‐art climate model simulations which provided the basis for the IPCC Assessment Report. We found that although there are persistent inaccuracies in the representation of Arctic temperature and salinity, the Arctic Ocean below 100 m is subject to much stronger warming than the average global ocean. On the other hand, the upper Arctic Ocean salinity is projected to decrease, which on average may strengthen the isolation of sea ice from Atlantic Water heat in the Arctic deep basin area.
    Description: Key Points: A too deep and thick Arctic Atlantic Water layer continues to be a major issue in contemporary climate models contributing to the CMIP6. The Arctic Ocean below the halocline is subject to much stronger warming than the global mean during the 21st century. The multi‐model mean upper ocean salinity is projected to decrease in the future but with high uncertainty.
    Description: European union's Horizon 2020 research and innovation programme
    Description: German Helmholtz climate initiative REKLIM
    Description: Deutsche Forschungsgemeinschaft (DFG) http://dx.doi.org/10.13039/501100001659
    Description: https://esgf-data.dkrz.de/projects/esgf-dkrz/
    Description: http://psc.apl.washington.edu/nonwp_projects/PHC/Data3.html
    Keywords: ddc:551
    Language: English
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    Denitrification‐Driven Transcription and Enzyme Production at the River‐Groundwater Interface: Insights From Reactive‐Transport Modeling (2022)
    Details
    Publication Date: 2022-12-06
    Description: Molecular‐biological data and omics tools have increasingly been used to characterize microorganisms responsible for the turnover of reactive compounds in the environment, such as reactive‐nitrogen species in groundwater. While transcripts of functional genes and enzymes are used as measures of microbial activity, it is not yet clear how they are quantitatively related to actual turnover rates under variable environmental conditions. As an example application, we consider the interface between rivers and groundwater which has been identified as a key driver for the turnover of reactive‐nitrogen compounds, that cause eutrophication of rivers and endanger drinking water production from groundwater. In the absence of measured data, we developed a reactive‐transport model for denitrification that simultaneously predicts the distributions of functional‐gene transcripts, enzymes, and reaction rates. Applying the model, we evaluate the response of transcripts and enzymes at the river‐groundwater interface to stable and dynamic hydrogeochemical regimes. While functional‐gene transcripts respond to short‐term (diurnal) fluctuations of substrate availability and oxygen concentrations, enzyme concentrations are stable over such time scales. The presence of functional‐gene transcripts and enzymes globally coincides with the zones of active denitrification. However, transcript and enzyme concentrations do not directly translate into denitrification rates in a quantitative way because of nonlinear effects and hysteresis caused by variable substrate availability and oxygen inhibition. Based on our simulations, we suggest that molecular‐biological data should be combined with aqueous geochemical data, which can typically be obtained at higher spatial and temporal resolution, to parameterize and calibrate reactive‐transport models.
    Description: Plain Language Summary: Molecular‐biological tools can detect how many enzymes, functional genes, and gene transcripts (i.e., precursors of enzyme production) associated with a microbial reaction exist in a sample from the environment. Although these measurements contain valuable information about the number of bacteria and how active they are, they do not directly say how quickly a contaminant like nitrate disappears. Nitrate, from agriculture and other sources, threatens groundwater quality and drinking water production. In the process of denitrification, bacteria can remove nitrate by converting it into harmless nitrogen gas using specialized enzymes. The interface between rivers and groundwater is known as a place where denitrification takes place. In this study, we use a computational model to simulate the coupled dynamics of denitrification, bacteria, transcripts, and enzymes when nitrate‐rich groundwater interacts with a nearby river. The simulations yield complex and nonunique relationships between the denitrification rates and the molecular‐biological variables. While functional‐gene transcripts respond to daily fluctuations of environmental conditions, enzyme concentrations and genes are stable over such time scales. High levels of functional‐gene transcripts therefore provide a good qualitative indicator of reactive zones. Quantitative predictions of nitrate turnover, however, will require high‐resolution measurements of the reacting compounds, genes, and transcripts.
    Description: Key Points: We simulate the distributions of functional‐gene transcripts and enzymes related to denitrification at the river‐groundwater interface. Functional‐gene transcripts respond quickly to diurnal fluctuations of substrate and oxygen concentrations. Substrate limitation and oxygen inhibition impede the direct prediction of denitrification rates from transcript or enzyme concentrations.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: https://doi.org/10.5281/zenodo.6584591
    Description: https://gitlab.com/astoeriko/nitrogene
    Description: https://doi.org/10.5281/zenodo.6584641
    Description: https://gitlab.com/astoeriko/adrpy
    Description: https://doi.org/10.5281/zenodo.5213947
    Description: https://github.com/aseyboldt/sunode
    Keywords: ddc:551 ; reactive‐transport modeling ; denitrification ; groundwater‐river interface ; functional genes ; transcripts ; molecular biology
    Language: English
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    Continental Break‐Up Under a Convergent Setting: Insights From P Wave Radial Anisotropy Tomography of the Woodlark Rift in Papua New Guinea (2022)
    Details
    Publication Date: 2022-12-05
    Description: To explore the dynamic mechanism of continental rifting within a convergent setting, we determine the first P wave radial anisotropic tomography beneath the Woodlark rift in southeastern Papua New Guinea, which develops within the obliquely colliding zone between the Australian and southwest Pacific plates. The rift zone is depicted as localized low‐velocity anomalies with positive radial anisotropy, which rules out a dominant role of active mantle upwelling in promoting the rift development and favors passive rifting with decompression melting as main processes. Downwelling slab relics in the upper mantle bounding the rift zone are revealed based on observed high‐velocity anomalies and negative radial anisotropy, which may contribute to the ultra‐high pressure rock exhumations and rift initiation. Our observations thus indicate that the Woodlark rift follows a passive model and is mainly driven by slab pull from the northward subduction of the Solomon plate.
    Description: Plain Language Summary: The Woodlark rift in Papua New Guinea develops within the shear zone between the Australian and southwest Pacific plates and is one of the youngest and most rapidly extending continental rifts in the world. In this work, we analyze teleseismic P wave arrivals to study both 3‐D velocity and radial anisotropy structures of the upper mantle, offering new evidence to understand rift initiation under a generally convergent setting. Slab remnants in the upper mantle bordering the rift zone are detected and sinking into the deeper mantle. Downwelling of these slab segments may induce small scale return flows in the mantle and contribute to exhumation of the ultra‐high pressure rocks and rift development. Significant low‐velocity anomalies are revealed beneath the rift zone and have consistently positive radial anisotropy, which indicates a dominant strain in the horizontal plane and supports a passive rifting model, where mantle material is brought to shallower depths simply as a result of the extension of the lithosphere and melt is produced due to the lowered melting point at reduced pressure (decompression melting). Tensional stresses transferred from slab pull of the northward Solomon subduction are probably driving the rifting.
    Description: Key Points: P wave radial anisotropic structure beneath the young and highly extended Woodlark rift is constrained from teleseismic tomography. Downwelling of slab relics bordering the rift zone may contribute to ultra‐high pressure rock exhumation and rift development. Slab‐pull drives rift initiation and induces decompression melting in the upper mantle under the rift zone by horizontal stress transfer.
    Description: National Natural Science Foundation of China (NSFC) http://dx.doi.org/10.13039/501100001809
    Description: National Science Foundation (NSF) http://dx.doi.org/10.13039/100000001
    Description: MEXT | Japan Society for the Promotion of Science (JSPS) http://dx.doi.org/10.13039/501100001691
    Description: Alexander von Humboldt‐Stiftung (Humboldt‐Stiftung) http://dx.doi.org/10.13039/100005156
    Description: https://doi.org/10.7914/SN/XD_1999
    Description: https://doi.org/10.7914/SN/ZN_2010
    Keywords: ddc:551 ; Woodlark rift ; radial anisotropy ; decompression melting ; slab‐pull ; slab downwelling ; ultra‐high pressure rock
    Language: English
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    The Synergy of Data From Profiling Floats, Machine Learning and Numerical Modeling: Case of the Black Sea Euphotic Zone (2022)
    Details
    Publication Date: 2022-12-05
    Description: Data from profiling floats in the Black Sea revealed complex temporal and spatial relationships between physical variables and oxygen, chlorophyll and the backscattering coefficient at 700 nm, as well as some limits in understanding the details of biogeochemistry dynamics. To account for different interdependences between physical and biogeochemical properties, a feedforward backpropagation neural network (NN) was used. This NN learns from data recorded by profiling floats and predicts biogeochemical states using physical measurements only. The performance was very high, particularly for oxygen, but it decreased when the NN was applied to older data because the interrelationships between the physical and biogeochemical properties have changed recently. The biogeochemical states reconstructed by the NN using physical data produced by a coupled physical–biogeochemical operational model were better than the biogeochemical outputs of the same coupled model. Therefore, the use of data from profiling floats, physical properties from numerical models and NNs appears to be a powerful approach for reconstructing the 4D dynamics of the euphotic zone. Basin‐wide patterns and temporal variabilities in oxygen, backscattering coefficient and chlorophyll were also analyzed. Of particular interest is the reconstruction of short‐lived biogeochemical features, particularly in coastal anticyclone areas, which are difficult to observe with available floats at the basin scale.
    Description: Plain Language Summary: This study addresses the biogeochemical dynamics of the euphotic layer in the Black Sea. Observations are provided from profiling floats, and the observed biogeochemical parameters include oxygen, the backscattering coefficient at 700 nm and chlorophyll‐a. Data analysis showed complex temporal and spatial relationships between physical and biogeochemical variables and some limits in understanding the details of biogeochemical dynamics. A feedforward backpropagation neural network was developed, which can be considered an input–output mapping in which the neurons combine the input data in such a way that the output can be considered a nonlinear combination of input data. When applied to older data, the reconstruction performance decreases, suggesting a change in the dependency of biogeochemical characteristics on physical drivers caused by known climate change. A comparison with simulations from a coupled operational biogeochemical model shows that the neural network outperforms the numerical model. The newly proposed method, combining data from profiling floats, physical properties from numerical models and a backpropagation neural network, allows us to reconstruct the 4D dynamics of the euphotic layer over the period 2013–2020.
    Description: Key Points: Machine learning helps identify fundamental biogeochemical mechanisms in the Black Sea. A feedforward backpropagation neural network performs better than a coupled physical‐biogeochemical model. Data from profiling floats, physical data from numerical models and machine learning enabled the analysis of 4D biogeochemical dynamics.
    Description: MASRI
    Description: National Roadmap for Scientific Infrastructure
    Description: European Horizon 2020 project DOORS
    Description: https://resources.marine.copernicus.eu/product-detail/BLKSEA_MULTIYEAR_PHY_007_004/INFORMATION
    Description: https://resources.marine.copernicus.eu/product-detail/BLKSEA_REANALYSIS_BIO_007_005/INFORMATION
    Description: http://www.coriolis.eu.org/Data-Products/Data-selection
    Description: https://zenodo.org/record/6860705
    Keywords: ddc:551 ; biogeochemistry ; neural networks ; profiling floats ; euphotic zone
    Language: English
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    Reversals in Temperature‐Precipitation Correlations in the Northern Hemisphere Extratropics During the Holocene (2022)
    Herzschuh, Ulrike ; Böhmer, Thomas ; Li, Chenzhi ; [et al.]
    Details
    Publication Date: 2022-12-07
    Description: Future precipitation levels remain uncertain because climate models have struggled to reproduce observed variations in temperature‐precipitation correlations. Our analyses of Holocene proxy‐based temperature‐precipitation correlations and hydrological sensitivities from 2,237 Northern Hemisphere extratropical pollen records reveal a significant latitudinal dependence and temporal variations among the early, middle, and late Holocene. These proxy‐based variations are largely consistent with patterns obtained from transient climate simulations (TraCE21k). While high latitudes and subtropical monsoon areas show mainly stable positive correlations throughout the Holocene, the mid‐latitude pattern is temporally and spatially more variable. In particular, we identified a reversal from positive to negative temperature‐precipitation correlations in the eastern North American and European mid‐latitudes from the early to mid‐Holocene that mainly related to slowed down westerlies and a switch to moisture‐limited convection under a warm climate. Our palaeoevidence of past temperature‐precipitation correlation shifts identifies those regions where simulating past and future precipitation levels might be particularly challenging.
    Description: Plain Language Summary: Predicting future precipitation levels reliably is more challenging than predicting temperature change. Accordingly, we need to understand the relationship between temperature and precipitation and its changes in space and time. We used climate proxy‐data derived from 2,237 pollen records from lake sediments and peats from the Northern Hemisphere extratropics for the early, middle, and late Holocene (i.e., 12,000–8,000, 8,000–4,000, 4,000–0 years before present, respectively). Our results reveal a significant latitudinal dependence and temporal variation of the temperature‐precipitation relationship. These proxy‐based variations are largely consistent with patterns obtained from simulations using climate models. While high latitudes and subtropical monsoon areas show mainly stable positive correlations throughout the Holocene (i.e., warm conditions co‐occur with wet conditions), the mid‐latitude pattern is temporally and spatially more variable. In particular, we identified a reversal to negative temperature‐precipitation correlations in the eastern North American and European mid‐latitudes from the early to middle Holocene. We hypothesize that weak westerly circulation, warm climate, and climate‐soil feedbacks limited evaporation and as such reduced convection during the middle Holocene which led to a negative relationship between temperature and precipitation. Our analysis of past temperature‐precipitation correlation shifts identifies regions where past changes in the temperature‐precipitation relationships are variable and thus where predicting precipitation might be particularly challenging in a warming climate.
    Description: Key Points: We analyzed Holocene temperature‐precipitation correlations and hydrological sensitivities using climate proxy (pollen) and model data from Northern Hemisphere extratropics. We found reversals to negative temperature‐precipitation correlations from the cold early Holocene to the warm mid‐Holocene likely related to moisture‐limited convection. Correlations and hydrological sensitivities were mostly stable positive in polar and extratropical monsoon‐areas.
    Description: EC European Research Council http://dx.doi.org/10.13039/501100000781
    Description: PALMOD
    Description: China Scholarship Council http://dx.doi.org/10.13039/501100004543
    Description: https://doi.pangaea.de/10.1594/PANGAEA.930512
    Description: https://doi.org/10.5281/zenodo.5910989
    Description: https://zenodo.org/record/7038402%23.YxBL1uzP3V8
    Keywords: ddc:551 ; ddc:561 ; Holocene ; pollen ; Northern Hemisphere ; temperature-precipation correlations
    Language: English
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    Stochastic Modeling Approach to Identify Uncertainties of Karst Conduit Networks in Carbonate Aquifers (2022)
    Details
    Publication Date: 2022-12-07
    Description: The characterization of the karst conduit network is an essential task to understand the complex flow system within karst aquifers. However, this task is challenging and often associated with uncertainty. Equivalent porous media approaches for modeling flow in karst aquifers fall short of capturing the hydraulic effect of individual karst features, while process‐oriented karst evolution models imply major computational efforts. In this study, we apply the Stochastic Karst Simulator (SKS) developed by Borghi et al. (2012) to generate karst conduit networks at a regional scale of a highly karstified carbonate aquifer located in the Eastern Mediterranean region and extensively used for water supply. The SKS generates conduit network geometries reasonably quick, using a mathematical proxy that mimics conduit evolution. The conduit simulation is based on a conceptual model of the genesis of the aquifer, consisting of different karstification phases. The stochastic approach of the algorithm enables us to generate an ensemble of conduit network realizations and to represent the uncertainties of these simulations in a Karst Probability Map. With only soft input information to constrain conduit evolution, multiple equivalent realizations yield similar resulting network geometries, indicating a robust approach. The presented methodology is numerically efficient, and its input can be easily adjusted. Subsequently, the resulting stochastic spatial distribution of conductivities can be employed for the parametrization of regional karst groundwater models.
    Description: Key Points: We statistically generate multiple sets of karst conduit network geometries using input data based on soft information. The resulting Karst Probability Map accounts for uncertainty in the spatial distribution of the karst conduit network. Our approach can assist in the integration of soft information into the parametrization of karst groundwater models.
    Description: Bundesministerium für Bildung und Forschung http://dx.doi.org/10.13039/501100002347
    Description: https://doi.org/10.14279/depositonce-16021
    Keywords: ddc:551 ; karst conduit modeling ; stochastic modeling ; structural uncertainty ; karst probability mapping ; groundwater modeling
    Language: English
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    On the Role of Rheological Memory for Convection‐Driven Plate Reorganizations (2022)
    Details
    Publication Date: 2022-12-10
    Description: Understanding the temporal variability of plate tectonics is key to unraveling how mantle convection transports heat, and one critical factor for the formation and evolution of plate boundaries is rheological “memory,” that is, the persistence of weak zones. Here, we analyze the impact of such damage memory in global, oceanic‐lithosphere‐only models of visco‐plastic mantle convection. Self‐consistently‐formed weak zones are found to be reactivated in distinct ways, and convection preferentially selects such damaged zones for new plate boundaries. Reactivation of damage zones increases the frequency of plate reorganizations, and hence reduces the dominant periods of surface heat loss. The inheritance of distributed lithospheric damage thus dominates global surface dynamics over any local boundary stabilizing effects of weakening. In nature, progressive generation of weak zones may thus counteract and perhaps overcome any effects of reduced convective vigor throughout planetary cooling, with implications for the frequency of orogeny and convective transport throughout Wilson cycles.
    Description: Plain Language Summary: Understanding how and why the motion of the lithosphere changes over time is important since this is telling us how planets with a plate tectonic style of heat transport evolve by thermo‐chemical mantle convection. One important factor for the evolution of plate boundaries is hysteresis, that is, memory of past deformation. Inherited weak zones, such as sutures, and progressive weakening are well documented in the geological record. Convection with damage shows dynamical behavior that is different from pure plastic failure without memory, or homogenous lithosphere that is being newly broken. We analyze the impact of damage with global, oceanic‐lithosphere‐only models of plate‐like mantle convection. Weak zones that are formed in an initially homogenous material are found to be reactivated subsequently in distinct ways. Within our tectonic system model, convection preferentially selects pre‐damaged zones for new, active plate boundaries. This reactivation increases the frequency of plate reorganizations compared to models without damage, and also changes the time‐dependence of cyclic surface heat loss. In nature, the progressive generation of weak zones over planetary history may counteract and perhaps overcome any effects of reduced convective vigor during cooling. This has implications for the frequency of mountain building and understanding Wilson cycles.
    Description: Key Points: Results from global, plate‐generating convection models with damage. Self‐consistently formed persistent weak zones lead to more frequent plate reorganizations. Accumulation of weak zones might counteract decrease in convective vigor for tectonic variability.
    Description: NSF EAR
    Description: Division of Earth Sciences http://dx.doi.org/10.13039/100000160
    Description: https://geodynamics.org/resources/citcoms
    Description: https://doi.org/10.5281/zenodo.6546322
    Keywords: ddc:551 ; plate tectonics ; visco-plastic convection models
    Language: English
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    Imaging the Absorbing Feeding and Eruptive Pathways of Deception Island, Antarctica (2022)
    Details
    Publication Date: 2022-12-10
    Description: Deception Island is one of the most active and best‐documented volcanoes in Antarctica. Since its last eruption in 1970, several geophysical surveys have targeted reconstructing its magmatic systems. However, geophysics fails to reconstruct the pathways magma and fluids follow from depth to erupt at the surface. Here, novel data selection strategies and multi‐frequency absorption inversions have been framed in a Geographical Information System, using all available geological (vents and faults distribution), geochemical and geophysical knowledge of the volcano. The result is the detection of these eruptive pathways. The model offers the first image of the magma and associated fluids pathways feed the 1967, 1969, and 1970 eruptions. Results suggest that future ascending paths might lead to active research bases and zones of planned helicopter rescue. The connection between seismic absorption, temperature, and fluid content makes it a promising attribute for detecting and monitoring eruptions at active calderas.
    Description: Plain Language Summary: Deception Island is the gateway for tourists to Antarctica and a laboratory to understand ice‐capped volcanoes and their eruptions. While the Island has been the target of many geophysical studies, no clear tomographic model shows how deep eruptive pathways of its last eruptions have reached the surface in the 1960s and 1970s. This is a recurrent topic in volcano geophysics: dikes and fluid migrations develop across structures considered too small to be detected by tomographic techniques. This paper demonstrates that seismic absorption has sufficient sensitivity to temperature and fluid content to detect these pathways. Once integrated within a Geographical Information System with all the information we have on the volcano, the models resolve the feeding systems of these eruptions, from a tectonically deformed deep magma chamber to shallow cold dyke intrusions and fluid migrations still feeding the volcano today. The correlation between seismic absorption, temperature, and fluid content offers a new tool for detecting and monitoring shallow volcanic hazards.
    Description: Key Points: High absorption detects deep eruptive pathways from the caldera center to its rim. Absorption imaging reconstructs shallow pathways of hazardous materials. Seismic absorption is sensitive to thermal anomalies at depth.
    Description: https://doi.org/10.5281/zenodo.6561124
    Description: https://zenodo.org/badge/latestdoi/493744216
    Keywords: ddc:551 ; seismic absorption ; seismic tomography ; Deception Island ; Volcanology ; remote sensing
    Language: English
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    Numerical Modeling of Structurally Controlled Ore Formation in Magmatic‐Hydrothermal Systems (2022)
    Details
    Publication Date: 2022-12-10
    Description: Faults and fractures can be permeable pathways for focused fluid flow in structurally controlled ore‐forming hydrothermal systems. However, quantifying their role in fluid flow on the scale of several kilometers with numerical models typically requires high‐resolution meshes. This study introduces a modified numerical representation of m‐scale fault zones using lower‐dimensional elements (here, one‐dimensional [1D] elements in a 2D domain) to resolve structurally controlled fluid flow with coarser mesh resolutions and apply the method to magmatic‐hydrothermal ore‐forming systems. We modeled horizontal and vertical structure‐controlled magmatic‐hydrothermal deposits to understand the role of permeability and structure connectivity on ore deposition. The simulation results of vertically extended porphyry copper systems show that ore deposition can occur along permeable vertical structures where ascending, overpressured magmatic fluids are cooled by downflowing ambient fluids. Structure permeability and fault location control the distribution of ore grades. In highly permeable structures, the mineralization can span up to 3 km vertically, resulting in heat‐pipe mechanisms that promote the ascent of a magmatic vapor phase to an overlying structurally controlled epithermal system. Simulations for the formation of subhorizontal vein‐type deposits suggest that the major control on fluid flow and metal deposition along horizontal structures is the absence of vertical structures above the injection location but their presence at greater distances. Using a dynamic permeability model mimicking crack‐seal mechanisms within the structures leads to a pulsating behavior of fracture‐controlled hydrothermal systems and prevents the inflow of ambient fluids under overpressured conditions.
    Description: Plain Language Summary: Faults and fractures can serve as permeable pathways for focused fluid flow in the subsurface and therefore be essential geological features for the formation of economic mineral deposits. However, quantifying their role in the hydrothermal systems on the scale of several kilometers with numerical models typically requires high‐resolution meshes. This study presents a modified numerical representation of m‐scale fault zones with variable orientations to understand the hydrology of magmatic‐hydrothermal ore‐forming systems. The vertically extended systems simulation results show that ore deposition can occur along permeable vertical structures where ascending magmatic fluids are cooled by downflowing ambient fluids. Structure permeability and fault location can directly control the distribution of ore grades. In contrast, mineralization in horizontal structures requires the absence of vertical structures above the injection location of metal‐bearing magmatic volatiles but their presence at greater distances. Our model also shows how dynamic opening and closing of the structures in response to magmatic degassing can lead to a pulsating behavior and prevent the downflow of ambient fluids.
    Description: Key Points: We describe structurally controlled fluid flow by representing faults and fractures as one‐dimensional line elements within a 2D modeling domain. Vertical structures are efficient pathways for focused fluid flow and formation of high‐grade mineralization. Ore formation in horizontal fractures requires a hydraulic connection to distal vertical fault zones.
    Description: German Federal Ministry of Education and Research
    Description: Deutsche Forschungsgemeinschaft, DFG http://dx.doi.org/10.13039/501100001659
    Description: Helmholtz Recruitment Initiative
    Keywords: ddc:551 ; magmatic‐hydrothermal systems ; ore deposits ; fluid flow ; numerical simulations ; faults and fractures
    Language: English
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    Groundwater Responses to Earth Tides: Evaluation of Analytical Solutions Using Numerical Simulation (2022)
    Details
    Publication Date: 2023-01-12
    Description: Harmonic Earth tide components in well water levels have been used to estimate hydraulic and geomechanical subsurface properties. However, the robustness of various methods based on analytical solutions has not been established. First, we review the theory and examine the latest analytical solution used to relate well water levels to Earth tides. Second, we develop and verify a novel numerical model coupling hydraulics and geomechanics to Earth tide strains. Third, we assess subsurface conditions over depth for a range of realistic properties. Fourth, we simulate the well water level response to Earth tide strains within a 2D poroelastic layered aquifer system confined by a 100 m thick aquitard. We find that the non‐linear inversion of analytical solutions to match two observations (amplitudes and phases) to multiple unknown parameters is sensible to the initial guess. We reveal that undrained, confined conditions are necessary for the analytical solution to be valid. This occurs for the dominant M2 frequency at depths 〉50 m and requires specific storage at constant strain of Sϵ ≥ 10−6 m−1, hydraulic conductivity of the aquitard of kl ≤ 5 ⋅ 10−5 ms−1 and aquifer of ka ≥ 10−4 ms−1. We further illustrate that the analytical solution is valid in unconsolidated systems, whereas consolidated systems require additional consideration of the Biot modulus. Overall, a priori knowledge of the subsurface system supports interpretation of the groundwater response. Our results improve understanding of the effect of Earth tides on groundwater systems and its interpretation for subsurface properties.
    Description: Plain Language Summary: Earth tide induced strains in the subsurface lead to well water level fluctuations in groundwater monitoring wells. This groundwater response has been interpreted with analytical solutions to estimate aquifer properties. However, analytical solutions are based on simplified assumptions whose accuracy have not yet been tested. We develop a new approach to simulate the influence of Earth tides on groundwater based on fundamental physical principles. We simulate realistic conditions and compare our results to those from analytical solution to determine the hydraulic and subsurface conditions under which simplified interpretations are valid. Our results improve understanding of the effects of Earth tides on groundwater systems and interpretation of subsurface properties from well water levels.
    Description: Key Points: We develop and verify a numerical model for the well water level response to Earth tides. Subsurface property estimation requires undrained and confined conditions occurring at depths 〉50 m. Amplitudes and phases from numerical and analytical solutions systematically diverge reflecting theory simplifications.
    Description: German Research Council
    Description: https://doi.org/10.5281/zenodo.6950492
    Keywords: ddc:551 ; tidal subsurface analysis ; numerical modeling ; Earth tides
    Language: English
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    Identifying Dominant Processes in Time and Space: Time‐Varying Spatial Sensitivity Analysis for a Grid‐Based Nitrate Model (2022)
    Details
    Publication Date: 2023-01-14
    Description: Distributed models have been increasingly applied at finer spatiotemporal resolution. However, most diagnostic analyses aggregate performance measures in space or time, which might bias subsequent inferences. Accordingly, this study explores an approach for quantifying the parameter sensitivity in a spatiotemporally explicit way. We applied the Morris method to screen key parameters within four different sampling spaces in a grid‐based model (mHM‐Nitrate) for NO3‐N simulation in a mixed landuse catchment using a 1‐year moving window for each grid. The results showed that an overly wide range of aquatic denitrification rates could mask the sensitivity of the other parameters, leading to their spatial patterns only related to the proximity to outlet. With adjusted parameter space, spatial sensitivity patterns were determined by NO3‐N inputs and hydrological transport capacity, while temporal dynamics were regulated by annual wetness conditions. The relative proportion of parameter sensitivity further indicated the shifts in dominant hydrological/NO3‐N processes between wet and dry years. By identifying not only which parameter(s) is(are) influential, but where and when such influences occur, spatial sensitivity analysis can help evaluate current model parameterization. Given the marked sensitivity in agricultural areas, we suggest that the current NO3‐N parameterization scheme (land use‐dependent) could be further disentangled in these regions (e.g., into croplands with different rotation strategies) but aggregated in non‐agricultural areas; while hydrological parameterization could be resolved into a finer level (from spatially constant to land use‐dependent especially in nutrient‐rich regions). The spatiotemporal sensitivity pattern also highlights NO3‐N transport within soil layers as a focus for future model development.
    Description: Key Points: A diagnostic analysis was conducted to disentangle the parameter sensitivity for NO3‐N simulations in catchment modeling in space and time. Sensitivity differed within sampling spaces, but was controlled spatially by NO3‐N supply/water fluxes while temporally by wetness condition. Analysis suggests finer‐level parameterization needs in arable land, and prioritizes NO3‐N transport in soils for improved conceptualization.
    Description: Chinese Scholarship Council
    Description: Leverhulme Trust http://dx.doi.org/10.13039/501100000275
    Description: Einstein Stiftung Berlin http://dx.doi.org/10.13039/501100006188
    Description: Berlin University Alliance http://dx.doi.org/10.13039/501100021727
    Description: https://doi.org/10.5281/zenodo.6497225
    Description: https://fred.igb-berlin.de/data/package/629
    Keywords: ddc:551 ; spatial time‐varying sensitivity analysis ; distributed nitrate modeling
    Language: English
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    Drought Conditions Enhance Groundwater Table Fluctuations Caused by Hydropower Plant Management (2022)
    Details
    Publication Date: 2023-01-13
    Description: Management of hydropower plants strongly influences streamflow dynamics and hence the interaction between surface water and groundwater. As dam operations cause variations in river stages, these can result in changes in the groundwater level at multiple temporal scales. In this work, we study the case of an Alpine aquifer, where weekly fluctuations are particularly pronounced. We consider an area with four river reaches differently impacted by reservoir operations and investigate the influence of these rivers on the common aquifer. Using continuous wavelet transform and wavelet coherence analysis, we show that weekly fluctuations in the groundwater table are particularly pronounced in dry years, in particular in the winter season, although the area of the aquifer impacted by dam operations remains almost unchanged. We thus observe that in Alpine catchments, surface water‐groundwater interaction is sensitive to the conditions determined by a specific hydrological year. We also investigate the influences of the river‐aquifer water fluxes and show that under dry conditions hydropeaking mainly affects their temporal dynamics. Our observations have significant consequences for predicting nutrient and temperature dynamics/regimes in river‐aquifer systems impacted by hydropower plant management.
    Description: Plain Language Summary: The operation of hydropower plants affects the water level in the downstream part of the river, which in turn can alter the groundwater level. In this work, we study an Alpine aquifer crossed by rivers differently impacted by hydropower production. We use statistical tools to analyze the interaction between the rivers and the groundwater, and observe that this interaction is sensitive to the conditions of the hydrological year, such as dry periods.
    Description: Key Points: Wavelet power spectrum and coherence analysis is used to study river‐aquifer interactions under dam operations in an Alpine catchment. The impact of reservoir operations on the aquifer is strongest under low flow conditions but the area impacted shows little variation. Under low flow conditions, dam operations considerably influence the frequency of the water exchange between rivers and aquifer.
    Description: Consejo Nacional de Ciencia y Tecnología http://dx.doi.org/10.13039/501100003141
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: Consejo Veracruzano de Investigación Científica y Desarrollo Tecnológico
    Description: https://doi.org/10.17632/97jchhz4s8.2
    Keywords: ddc:551 ; surface water‐groundwater interaction ; hydropower ; managed rivers ; groundwater modeling
    Language: English
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    Earthquake Rupture on Multiple Splay Faults and Its Effect on Tsunamis (2022)
    Details
    Publication Date: 2023-01-19
    Description: Detailed imaging of accretionary wedges reveals splay fault networks that could pose a significant tsunami hazard. However, the dynamics of multiple splay fault activation during megathrust earthquakes and the consequent effects on tsunami generation are not well understood. We use a 2‐D dynamic rupture model with complex topo‐bathymetry and six curved splay fault geometries constrained from realistic tectonic loading modeled by a geodynamic seismic cycle model with consistent initial stress and strength conditions. We find that all splay faults rupture coseismically. While the largest splay fault slips due to a complex rupture branching process from the megathrust, all other splay faults are activated either top down or bottom up by dynamic stress transfer induced by trapped seismic waves. We ascribe these differences to local non‐optimal fault orientations and variable along‐dip strength excess. Generally, rupture on splay faults is facilitated by their favorable stress orientations and low strength excess as a result of high pore‐fluid pressures. The ensuing tsunami modeled with non‐linear 1‐D shallow water equations consists of one high‐amplitude crest related to rupture on the longest splay fault and a second broader wave packet resulting from slip on the other faults. This results in two episodes of flooding and a larger run‐up distance than the single long‐wavelength (300 km) tsunami sourced by the megathrust‐only rupture. Since splay fault activation is determined by both variable stress and strength conditions and dynamic activation, considering both tectonic and earthquake processes is relevant for understanding tsunamigenesis.
    Description: Plain Language Summary: In subduction zones, where one tectonic plate moves beneath another, earthquakes can occur on many different faults. Splay faults are relatively steep faults that branch off the largest fault (the megathrust) in a subduction zone. As they are steeper than the megathrust, the same amount of movement on them could result in more vertical displacement of the seafloor. Therefore, splay faults are thought to play an important role in the generation of tsunamis. Here, we use computer simulations to study if an earthquake can break multiple splay faults at once and how this affects the resulting tsunami. We find that multiple splay faults can indeed fail during a single earthquake due to the stress changes from trapped seismic waves, which promote rupture on splay faults. Rupture on splay faults results in larger seafloor displacements with smaller wavelengths, so the ensuing tsunami is bigger and results in two main flooding episodes at the coast. Our results show that it is important to consider rupture on splay faults when assessing tsunami hazard.
    Description: Key Points: Multiple splay faults can be activated during a single earthquake by megathrust slip and dynamic stress transfer due to trapped waves. Splay fault activation is facilitated by their favorable orientation with respect to the local stress field and their closeness to failure. Long‐term geodynamic stresses and fault geometries affect dynamic splay fault rupture and the subsequent tsunami.
    Description: Volkswagen Foundation (VolkswagenStiftung) http://dx.doi.org/10.13039/501100001663
    Description: Royal Society (The Royal Society) http://dx.doi.org/10.13039/501100000288
    Description: EC | H2020 | H2020 Priority Excellent Science | H2020 European Research Council (ERC) http://dx.doi.org/10.13039/100010663
    Description: Deutsche Forschungsgemeinschaft (DFG) http://dx.doi.org/10.13039/501100001659
    Description: National Science Foundation (NSF) http://dx.doi.org/10.13039/100000001
    Description: https://github.com/TUM-I5/SWE
    Description: https://doi.org/10.5281/zenodo.6969455
    Keywords: ddc:551 ; earthquake ; tsunami ; subduction zone ; dynamic rupture ; splay fault ; numerical modeling
    Language: English
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    The Interconnected Magmatic Plumbing System of the Natron Rift (2022)
    Details
    Publication Date: 2023-01-20
    Description: Understanding the magmatic plumbing system of rift volcanoes is essential when examining the interplay between magmatic and tectonic forces. Recent seismicity, volcanic activity, magma emplacement, and volatile release make the Natron basin the ideal location to study these processes in the East African Rift System. Here, we present the first high‐resolution tomographic imaging of Oldoinyo Lengai volcano and surrounding volcanic systems using attenuation mapping. High scattering and absorption features reveal fluid‐filled fracture networks below regions of magmatic volatile release at the surface and a close spatial association between carbonatite volcanism and deeply penetrating, fluid‐filled faults. High‐absorption features appear sensitive to fluids and thermal gradients, revealing a central sill complex and connected plumbing system down to the mid‐crust, which links volcanoes and rift segments across the developing magmatic rift.
    Description: Plain Language Summary: The interplay between magmatic and tectonic forces during rifting is still debated. While they are a key component of rift development, the complex structures of rifts and melt storage systems scatter and absorb seismic waves passing through them: in turn, this deteriorates the quality of the subsurface images we obtain from them. In this study, we use the loss of energy suffered by seismic waves to image the Natron basin, which hosts extinct volcanoes and the only active natrocarbonatite volcano on Earth, Oldoinyo Lengai. The results identify areas of melt storage and fracture networks that feed volatiles and melt to this volcano. Results suggest that carbonatite melts may ascend through the crust efficiently along deep‐seated faults systems, while silicate melts in the region may be primarily sourced from a separate melt reservoir. This reservoir, which is elongate and oriented oblique to the general trend of the rift, may act as a magmatic transfer zone between two rift segments.
    Description: Key Points: First fine‐scale 3D images reveal an interconnected rift plumbing system using scattering and absorption mapping. High scattering and absorption mark fluid‐filled faults that degas magmatic fluids and act as potential conduits for carbonatite melts. A high absorption melt reservoir feeds eruptions at Oldoinyo Lengai and dike intrusions and acts as a transfer zone between rift segments.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: National Science Foundation http://dx.doi.org/10.13039/100000001
    Description: Terrestrial Magmatic Systems
    Description: https://github.com/LucaDeSiena/MuRAT
    Description: https://doi.org/10.14470/4W7564850022
    Description: http://doi.org/10.6084/m9.figshare.20101232
    Keywords: ddc:551 ; rift plumbing system ; attenuation imaging ; magma‐fault interactions ; Oldoinyo Lengai ; Natron Basin
    Language: English
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  • 40
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    Seamless Integration of the Coastal Ocean in Global Marine Carbon Cycle Modeling (2022)
    Details
    Publication Date: 2023-01-20
    Description: We present the first global ocean‐biogeochemistry model that uses a telescoping high resolution for an improved representation of coastal carbon dynamics: ICON‐Coast. Based on the unstructured triangular grid topology of the model, we globally apply a grid refinement in the land‐ocean transition zone to better resolve the complex circulation of shallow shelves and marginal seas as well as ocean‐shelf exchange. Moreover, we incorporate tidal currents including bottom drag effects, and extend the parameterizations of the model's biogeochemistry component to account explicitly for key shelf‐specific carbon transformation processes. These comprise sediment resuspension, temperature‐dependent remineralization in the water column and sediment, riverine matter fluxes from land including terrestrial organic carbon, and variable sinking speed of aggregated particulate matter. The combination of regional grid refinement and enhanced process representation enables for the first time a seamless incorporation of the global coastal ocean in model‐based Earth system research. In particular, ICON‐Coast encompasses all coastal areas around the globe within a single, consistent ocean‐biogeochemistry model, thus naturally accounting for two‐way coupling of ocean‐shelf feedback mechanisms at the global scale. The high quality of the model results as well as the efficiency in computational cost and storage requirements proves this strategy a pioneering approach for global high‐resolution modeling. We conclude that ICON‐Coast represents a new tool to deepen our mechanistic understanding of the role of the land‐ocean transition zone in the global carbon cycle, and to narrow related uncertainties in global future projections.
    Description: Plain Language Summary: The coastal ocean is an area hardly taken into account by current climate change assessment activities. Yet, its capacity in carbon dioxide (CO2) uptake and storage is crucial to be included in a science‐based development of sustainable climate change mitigation and adaptation strategies. Earth system models are powerful tools to investigate the marine carbon cycle of the open ocean. The coastal ocean, however, is poorly represented in global models to date, because of missing key processes controlling coastal carbon dynamics and too coarse spatial resolutions to adequately simulate coastal circulation features. Here, we introduce the first global ocean‐biogeochemistry model with a dedicated representation of the coastal ocean and associated marine carbon dynamics: ICON‐Coast. In this model, we globally apply a higher resolution in the coastal ocean and extend the accounted physical and biogeochemical processes. This approach enables for the first time a consistent, seamless incorporation of the global coastal ocean in model‐based Earth system research. In particular, ICON‐Coast represents a new tool to deepen our understanding about the role of the land‐ocean transition zone in the global climate system, and to narrow related uncertainties in possible and plausible climate futures.
    Description: Key Points: We introduce the first global ocean‐biogeochemistry model with a dedicated representation of coastal carbon dynamics. We globally apply a grid refinement in the coastal ocean to better resolve regional circulation features, including ocean‐shelf exchange. We explicitly incorporate key physical and biogeochemical processes controlling coastal carbon dynamics.
    Description: German Research Foundation, Excellence Strategy EXC 2037 (CLICCS)
    Description: European Union, Horizon2020 Research and Innovation Program (ESM2025)
    Description: German Federal Ministry of Education
    Description: https://doi.org/10.5281/zenodo.6630352
    Keywords: ddc:551 ; coastal ocean ; global modeling ; marine carbon cycle ; variable‐resolution grid ; ocean‐biogiochemistry ; high‐resolution modeling
    Language: English
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  • 41
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    Particle‐Phase Uptake and Chemistry of Highly Oxygenated Organic Molecules (HOMs) From α‐Pinene OH Oxidation (2022)
    Poulain, L. ; Tilgner, A. ; Brüggemann, M. ; [et al.]
    Details
    Publication Date: 2023-06-16
    Description: Secondary organic aerosol (SOA) forms a major part of the tropospheric submicron particle mass. Still, the exact formation mechanisms of SOA have remained elusive. It is now admitted that highly oxygenated organic molecules (HOMs) can contribute to a large fraction of SOA formation. In this study, we performed a set of chamber experiments to investigate the SOA formation, and the HOMs uptake and processing directly formed by OH‐radical initiated oxidation of α‐pinene under two different aerosol seed conditions. Numerous HOM compounds were identified using advanced online and offline analytical techniques, and grouped into four classes according to their different uptake behaviors. For the first time, individual HOMs uptake coefficients ranging from 1.1 × 10−2 to 1.5 × 10−1 were experimentally determined and analyzed using a resistance model which considers uptake limitations by individual gas‐ and/or particle‐phase processes. This study demonstrates that the uptake coefficients of HOMs strongly depend on their molar mass and their respective O/C ratio. Results show that aerosol seed composition and phase state affect the initial uptake of HOMs. Furthermore, the study demonstrates that the acidity and/or different seed phase‐state can significantly enhance the subsequent uptake through occurring acidity‐driven reactions reflected in a reactive behavior, particularly under (NH4)HSO4 seed conditions, promoting up to 3 times a higher SOA mass formation including the formation of highly oxidized organosulfates (HOOS). Overall, the present study implies that HOMs and their subsequent chemical processing can play an important role in both the early growth of newly formed particles and SOA formation when particle acidity is high.
    Description: Plain Language Summary: Tropospheric organic aerosol (OA) compounds represent a large part of submicron particulate matter. A big fraction of OA is formed from oxidation of emitted gaseous volatile organic compounds such as α‐pinene. Oxidation products are less‐volatile compounds that tend to condense on aerosol particles. Recently identified “highly oxygenated organic molecules” (HOMs) are formed by gas‐phase autoxidation processes and exhibit very low vapor pressures. Therefore, HOMs are expected to efficiently contribute to secondary organic aerosol (SOA). However, up to now, SOA formation potential of HOMs is still not well described because of lacking experimental investigations and analysis. Consequently, this study aims to investigate the mentioned HOMs partitioning and subsequent SOA formation from the OH‐radical initiated oxidation of α‐pinene under both Na2SO4 and (NH4)HSO4 aerosol seed conditions through complex chamber experiments. For the first time, individual HOMs uptake coefficients were determined experimentally. Further investigations demonstrated that the uptake coefficients of HOMs strongly depend on their molar mass, as well as on their respective O/C ratio. Finally, the results show that aerosol acidity and/or phase state significantly enhances the HOMs uptake and promotes up to three times higher SOA mass formation under (NH4)HSO4 seed conditions compared to that under neutral seed conditions.
    Description: Key Points: Uptake coefficients of numerous highly oxygenated organic molecules (HOMs) were experimentally determined for the first time. HOMs uptake and secondary organic aerosol formation were significantly enhanced by acidic (NH4)HSO4 seed. Highly oxidized organosulfates formation were observed under acidic (NH4)HSO4 seed conditions.
    Description: European Commission http://dx.doi.org/10.13039/501100000780
    Description: National Natural Science Foundation of China http://dx.doi.org/10.13039/501100001809
    Description: https://doi.org/10.25326/FJNF-7224
    Description: https://doi.org/10.25326/KC8N-DY53
    Keywords: ddc:551 ; aerosol study ; highly oxygenated organic molecules
    Language: English
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  • 42
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    Early Eocene magnetostratigraphy and tectonic evolution of the Xining Basin, NE Tibet (2022)
    Meijer, Niels ; Dupont‐Nivet, Guillaume ; Licht, Alexis ; [et al.]
    Details
    Publication Date: 2023-06-14
    Description: The Cenozoic strata of the Xining Basin, NE Tibet, have provided crucial records for understanding the tectonic and palaeo‐environmental evolution of the region. Yet, the age of the lower part of the sedimentary stratigraphy and, consequently, the early tectonic evolution of the basin remain debated. Here, we present the litho‐ and magnetostratigraphy of various early Eocene sections throughout the Xining Basin independently constrained by the U–Pb radiometric age of a carbonate bed. Our study extends the dated stratigraphy down to 53.0 Ma (C24n.1r) and reveals highly variable accumulation rates during the early Eocene ranging from 0.5 to 8 cm/ka. This is in stark contrast to the low but stable accumulation rates (2–3 cm/ka) observed throughout the overlying Palaeogene and Neogene strata. Such a pattern of basin infill is not characteristic of flexural subsidence as previously proposed, but rather supports an extensional origin of the Xining Basin with multiple depocentres, which subsequently coalesced into a more stable and slowly subsiding basin. Whether this extension was related to the far‐field effects of the subducting Pacific Plate or the India–Asia collision remains to be confirmed by future studies.
    Description: European Research Council http://dx.doi.org/10.13039/501100000781
    Description: Hessisches Ministerium für Wissenschaft und Kunst http://dx.doi.org/10.13039/501100003495
    Keywords: ddc:551 ; Eocene ; geochronology ; northeast Tibet ; palaeomagnetism ; stratigraphy ; Xining Basin
    Language: English
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  • 43
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    The geodynamic and limnological evolution of Balkan Lake Ohrid, possibly the oldest extant lake in Europe (2022)
    Details
    Publication Date: 2023-12-04
    Description: Studies of the upper 447 m of the DEEP site sediment succession from central Lake Ohrid, Balkan Peninsula, North Macedonia and Albania provided important insights into the regional climate history and evolutionary dynamics since permanent lacustrine conditions established at 1.36 million years ago (Ma). This paper focuses on the entire 584‐m‐long DEEP sediment succession and a comparison to a 197‐m‐long sediment succession from the Pestani site ~5 km to the east in the lake, where drilling ended close to the bedrock, to unravel the earliest history of Lake Ohrid and its basin development. 26Al/10Be dating of clasts from the base of the DEEP sediment succession implies that the sedimentation in the modern basin started at c. 2 Ma. Geophysical, sedimentological and micropalaeontological data allow for chronological information to be transposed from the DEEP to the Pestani succession. Fluvial conditions, slack water conditions, peat formation and/or complete desiccation prevailed at the DEEP and Pestani sites until 1.36 and 1.21 Ma, respectively, before a larger lake extended over both sites. Activation of karst aquifers to the east probably by tectonic activity and a potential existence of neighbouring Lake Prespa supported filling of Lake Ohrid. The lake deepened gradually, with a relatively constant vertical displacement rate of ~0.2 mm a−1 between the central and the eastern lateral basin and with greater water depth presumably during interglacial periods. Although the dynamic environment characterized by local processes and the fragmentary chronology of the basal sediment successions from both sites hamper palaeoclimatic significance prior to the existence of a larger lake, the new data provide an unprecedented and detailed picture of the geodynamic evolution of the basin and lake that is Europe’s presumed oldest extant freshwater lake.
    Keywords: ddc:551 ; Balkan Peninsula ; Lake Ohrid ; DEEP sediment succession ; Pestani succession ; evolutionary dynamics ; regional climate history
    Language: English
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    Spatial and temporal dynamics of water isotopes in the riverine‐marine mixing zone along the German Baltic Sea coast (2022)
    John Wiley & Sons, Inc. | Hoboken, USA
    Details
    Publication Date: 2023-01-27
    Description: River estuaries are characterized by mixing processes between freshwater discharge and marine water masses. Since the first are depleted in heavier stable isotopes compared with the marine realm, estuaries often show a linear correlation between salinity and water stable isotopes (δ18O and δ2H values). In this study, we evaluated spatial and seasonal isotope dynamics along three estuarine lagoon transects, located at the northern German Baltic Sea coast. The data show strong seasonality of isotope values, even at locations located furthest from the river mouths. They further reveal a positive and linear salinity‐isotope correlation in spring, but ‐in two of the three studied transects‐ hyperbolic and partially reverse correlations in summers. We conclude that additional hydrological processes partially overprint the two‐phase mixing correlation during summers: aside from the isotope seasonality of the riverine inflows, the shallow inner lagoons in the studied estuaries are influenced by evaporation processes. In contrast the estuarine outflow regions are under impact of significant salinity and isotope fluctuations of the Baltic Sea. Deciphering those processes is crucial for the understanding of water isotope and salinity dynamics. This is also of relevance in context of ecological studies, for example, when interpreting oxygen and hydrogen isotope data in aquatic organisms that depend on ambient estuarine waters.
    Description: Spatial and seasonal water isotope dynamics were evaluated along three estuarine lagoon transects at the German Baltic Sea coast. Data reveal a positive and linear salinity‐isotope correlation in spring, but partially reverse correlations in summers. The results show that evaporation processes in the shallow inner lagoons and varying Baltic Sea influence in the outer estuary regions are able to overprint the two‐phase mixing correlation between riverine and marine water masses.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: https://doi.org/10.1594/PANGAEA.937990
    Keywords: ddc:551 ; δ2H ; δ18O ; Baltic Sea ; bodden ; Rügen ; salinity ; Schlei ; Zingst
    Language: English
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  • 45
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    Sediment Release in the Benguela Upwelling System Dominates Trace Metal Input to the Shelf and Eastern South Atlantic Ocean (2022)
    Details
    Publication Date: 2023-01-21
    Description: Upwelling of subsurface waters injects macronutrients (fixed N, P, and Si) and micronutrient trace metals (TMs) into surface waters supporting elevated primary production in Eastern Boundary Upwelling Regions. The eastern South Atlantic features a highly productive shelf sea transitioning to a low productivity N‐Fe (co)limited open ocean. Whilst a gradient in most TM concentrations is expected in any off‐shelf transect, the factors controlling the magnitude of cross‐shelf TM fluxes are poorly constrained. Here, we present dissolved TM concentrations of Fe, Co, Mn, Cd, Ni, and Cu within the Benguela Upwelling System from the coastal section of the GEOTRACES GA08 cruise. Elevated dissolved Fe, Co, Mn, Cd, Ni, Cu and macronutrient concentrations were observed near shelf sediments. Benthic sources supplied 2.22 ± 0.99 μmol Fe m−2 day−1, 0.05 ± 0.03 μmol Co m−2 day−1, 0.28 ± 0.11 μmol Mn m−2 day−1 and were found to be the dominant source to shallow shelf waters compared to atmospheric depositions. Similarly, off‐shelf transfer was a more important source of TMs to the eastern South Atlantic Ocean compared to atmospheric deposition. Assessment of surface (shelf, upper 200 m) and subsurface (shelf edge, 200–500 m) fluxes of Fe and Co indicated TM fluxes from subsurface were 2–5 times larger than those from surface into the eastern South Atlantic Ocean. Under future conditions of increasing ocean deoxygenation, these fluxes may increase further, potentially contributing to a shift toward more extensive regional limitation of primary production by fixed N availability.
    Description: Key Points: Shelf sediments release redox‐sensitive trace metals (TMs) to overlying oxygen‐depleted waters in the Benguela Upwelling System. Sediment‐derived TMs are upwelled and laterally transported constituting a major source to shelf waters and to the eastern South Atlantic. Subsurface fluxes of dissolved Fe and Co from the shelf edge play an important role in supplying Fe and Co to the eastern South Atlantic.
    Description: China Scholarship Council, CSC http://dx.doi.org/10.13039/501100004543
    Description: GEOMAR and German Research Foundation
    Description: German DFG
    Description: German Research Foundation
    Description: https://doi.pangaea.de/10.1594/PANGAEA.947275
    Keywords: ddc:551 ; dissolved trace metals ; Benguela Upwelling Systems ; fluxes ; Eastern Boundary Upwelling Systems Regions
    Language: English
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    Dynamics of Greenhouse Gases (CH4 and CO2) in Meromictic Lake Burgsee, Germany (2022)
    Details
    Publication Date: 2023-01-21
    Description: Extraordinary amounts of greenhouse gases can be stored within the monimolimnion of meromictic lakes, that is, in the water body which is excluded from mixing events. Lake Burgsee (Thuringia, Germany) is a shallow (depth 〈5 m) lake with a approximately 24 m deep sinkhole, which is fed by underground brine sources and has formed such a monimolimnion. We investigated the carbon dioxide and methane dynamics in this meromictic lake, from production potentials in the sediment via concentrations in the monimolimnion and mixolimnion to emissions to the atmosphere. In the monimolimnion, we found one of the highest methane concentrations (up to 〉5 mmol L−1) ever reported for a natural freshwater lake, while carbon dioxide concentrations in the water and methane production rates in the sediments were rather ordinary and within the range of holomictic eutrophic lakes. At the thermocline, gas concentrations accumulated to approximately 100 μmol L−1 CH4 and 80–230 μmol L−1 CO2. Estimated fluxes to the atmosphere reached considerable 3.5 mmol CH4 m−2 d−1 and 1.5 mmol CO2 m−2 d−1 above the sinkhole and 0.8 mmol CH4 m−2 d−1 and 0.4 mmol CO2 m−2 d−1 above the near‐by shallow lake center in 2018. Our results demonstrate that lakes in natural brine areas may provide significant storages and releases of greenhouse gases and require further investigation.
    Description: Plain Language Summary: In meromictic lakes, the deepest water layer, the monimolimnion, is stagnant and not included in seasonal water circulation. Organic matter continuously sinks down into the oxygen‐free monimolimnion, where it is decomposed into the final gaseous products carbon dioxide (CO2) and methane (CH4). Lake Burgsee is a meromictic shallow (depth 〈5 m), brine‐fed lake with a approximately 24 m deep sinkhole. At the bottom of the narrow sinkhole, salinities are as high as in brackish water and cause a chemical stratification of the water body—a monimolimnion—in approximately 18 m depth. CH4 concentrations above the sediment reach 〉5 mmol L−1, which is more than one order of magnitude higher than at the water surface and among the highest CH4 concentrations found in freshwater lakes worldwide. Further, emissions of CH4 and CO2 from the water to the atmosphere were considerable in 2018, and about four times higher above the sinkhole than above the shallow lake center. These results demonstrate, that lakes in natural brine areas may store and release significant amounts of greenhouse gases and require further investigation.
    Description: Key Points: In the urban meromictic Lake Burgsee, methane production potentials in the sediment are similar to eutrophic holomictic lakes. At its deepest site, it contains one of the highest methane concentrations (〉5 mmol L−1 CH4) ever reported for a natural freshwater lake. Lake Burgsee emits up to 〉3 mmol m−2 d−1 CH4 to the atmosphere above the sinkhole and 〈1 mmol m−2 d−1 CH4 at a near‐by shallow site.
    Keywords: ddc:551 ; meromictic lake ; sinkhole ; salinity ; greenhouse gases ; methane flux ; carbon dioxide
    Language: English
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  • 47
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    Evidence for Secondary Ice Production in Southern Ocean Maritime Boundary Layer Clouds (2022)
    Details
    Publication Date: 2023-01-25
    Description: Maritime boundary‐layer clouds over the Southern Ocean (SO) have a large shortwave radiative effect. Yet, climate models have difficulties in representing these clouds and, especially, their phase in this observationally sparse region. This study aims to increase the knowledge of SO cloud phase by presenting in‐situ cloud microphysical observations from the Southern Ocean Clouds, Radiation, Aerosol, Transport Experimental Study (SOCRATES). We investigate the occurrence of ice in summertime marine stratocumulus and cumulus clouds in the temperature range between 6 and −25°C. Our observations show that in ice‐containing clouds, maximum ice number concentrations of up to several hundreds per liter were found. The observed ice crystal concentrations were on average one to two orders of magnitude higher than the simultaneously measured ice nucleating particle (INP) concentrations in the temperature range below −10°C and up to five orders of magnitude higher than estimated INP concentrations in the temperature range above −10°C. These results highlight the importance of secondary ice production (SIP) in SO summertime marine boundary‐layer clouds. Evidence for rime splintering was found in the Hallett‐Mossop (HM) temperature range but the exact SIP mechanism active at lower temperatures remains unclear. Finally, instrument simulators were used to assess simulated co‐located cloud ice concentrations and the role of modeled HM rime‐splintering. We found that CAM6 is deficient in simulating number concentrations across the HM temperature range with little sensitivity to the model HM process, which is inconsistent with the aforementioned observational evidence of highly active SIP processes in SO low‐level clouds.
    Description: Plain Language Summary: Clouds in the Southern Ocean are important for climate but not well represented in climate models. Observations in this remote region have been rare. This study presents results from a recent airborne campaign that took place in the Southern Ocean where low‐ and mid‐level clouds were investigated by detecting individual cloud particles within the clouds. Although large fraction of the observed clouds did not contain ice crystals, occasionally high amounts of ice crystals were observed that cannot be explained by ice formation on aerosol particles but were result of multiplication of existing ice crystals. We tested the capability of a commonly used climate model to represent the observed ice concentrations and their sensitivity to one ice multiplication process parameterized in the model. These investigations revealed that the in the model the ice multiplication process was not responsible for generation of ice, which is in contradiction with the observations.
    Description: Key Points: Ice concentrations several orders of magnitude higher than ice nucleating particle concentrations were observed. Secondary ice production was believed to be responsible for the observed high ice number concentrations. Comparison with climate model indicated that secondary ice processes are still inadequately represented in the model.
    Description: National Science Foundation http://dx.doi.org/10.13039/100000001
    Description: U.S. Department of Energy http://dx.doi.org/10.13039/100000015
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: NSF Polar Programs
    Keywords: ddc:551 ; southern ocean ; mixed‐phase clouds ; in‐situ observations ; ice crystals ; secondary ice ; ice nucleating particles
    Language: English
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  • 48
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    Do Emergent Constraints on Carbon Cycle Feedbacks Hold in CMIP6? (2022)
    Details
    Publication Date: 2024-02-21
    Description: Emergent constraints on carbon cycle feedbacks in response to warming and increasing atmospheric CO〈sub〉2 〈/sub〉 concentration have previously been identified in Earth system models participating in the Coupled Model Intercomparison Project (CMIP) Phase 5. Here, we examine whether two of these emergent constraints also hold for CMIP6. The spread of the sensitivity of tropical land carbon uptake to tropical warming in an idealized simulation with a 1% per year increase of atmospheric CO〈sub〉2 〈/sub〉 shows only a slight decrease in CMIP6 (−52 ± 35 GtC/K) compared to CMIP5 (−49 ± 40 GtC/K). For both model generations, the observed interannual variability in the growth rate of atmospheric CO〈sub〉2 〈/sub〉 yields a consistent emergent constraint on the sensitivity of tropical land carbon uptake with a constrained range of −37 ± 14 GtC/K for the combined ensemble (i.e., a reduction of ∼30% in the best estimate and 60% in the uncertainty range relative to the multimodel mean of the combined ensemble). A further emergent constraint is based on a relationship between CO〈sub〉2 〈/sub〉 fertilization and the historical increase in the CO〈sub〉2 〈/sub〉 seasonal cycle amplitude in high latitudes. However, this emergent constraint is not evident in CMIP6. This is in part because the historical increase in the amplitude of the CO〈sub〉2 〈/sub〉 seasonal cycle is more accurately simulated in CMIP6, such that the models are all now close to the observational constraint.
    Description: Plain Language Summary: The statistical model of so‐called emergent constraints help to better understand the sensitivity of Earth system processes in a changing climate. Here, we analyze the robustness of two previously found emergent constraints on carbon cycle feedbacks, using models from the Coupled Model Intercomparison Project (CMIP) of Phases 5 and 6. First the decrease of carbon storage in the tropics due to increasing near‐surface air temperatures, which is found to be robust on the choise of model ensemble. Giving a constraint estimate of −52 ± 35 GtC/K for CMIP6 models, being within the range of uncertainty for the previously estimated result for CMIP5. Second, the increase of carbon storage in high latitudes due to CO〈sub〉2 〈/sub〉 fertilization effect, which is found to be not evident among CMIP6 models. This is in part because the historical increase in the amplitude of the CO〈sub〉2 〈/sub〉 seasonal cycle is more accurately simulated in CMIP6, such that the models are all now close to the observational constraint.
    Description: Key Points: An emergent constraint on the sensitivity of tropical land carbon to global warming, originally derived from Coupled Model Intercomparison Project Phase 5 (CMIP5), also holds for CMIP6. The combined CMIP5 + CMIP6 ensemble gives an emergent constraint on the sensitivity of tropical land carbon to global warming of −37 ± 14 GtC/K. An emergent constraint on the fertilization feedback due to rising CO〈sub〉2 〈/sub〉 levels, previously derived, is not evident in CMIP6.
    Description: Horizon 2020 Framework Programme http://dx.doi.org/10.13039/100010661
    Description: ERC
    Description: https://doi.org/10.5281/zenodo.6900341
    Description: https://doi.org/10.5281/zenodo.3387139
    Description: https://github.com/ESMValGroup
    Description: https://docs.esmvaltool.org/
    Keywords: ddc:551 ; carbon cycle ; emergent constraint ; CMIP5 ; CMIP6 ; fertilization effect ; temperature warming
    Language: English
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  • 49
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    Particulate Organic Matter Mobilization and Transformation Along a Himalayan River Revealed by ESI‐FT‐ICR‐MS (2022)
    Details
    Publication Date: 2024-02-09
    Description: Tracing pathways and transformations of particulate organic carbon from landscape sources to oceanic sinks is commonly done using the isotopic composition or biomarker content of particulate organic matter (POM). However, similarity of source characteristics and complex mixing in rivers often preclude a robust deconvolution of individual contributions. Moreover, these approaches are limited in detecting organic matter transformations. This impedes understanding of carbon cycling. Fourier Transform Ion Cyclotron Resonance Mass Spectrometry (FT‐ICR‐MS) can simultaneously identify many molecular formulas from mixtures of organic matter, and provide direct information on its compositional variability. Here, we investigate how FT‐ICR‐MS can give insight into POM dynamics on a landscape scale, focusing on the trans‐Himalayan Kali Gandaki River, Nepal. Using molecular information, we identify source tracers in the solvent extractable lipid fraction of riverine POM, finding up to 102 indicative molecular formulas for individual sources. Further, we assess molecular transformations of the lipid fraction of POM during its transfer from litter into topsoil, and onwards into the river. A large number of shared mass formulas and a well‐preserved isoprenoidal patterns suggest efficient incorporation of litter into topsoil. In contrast, we observe a selective loss of mass formulas and a preferential export of formulas with low double bond equivalents and a low nominal oxidation state of carbon after organic matter entrainment in the river. Our results demonstrate the potential of FT‐ICR‐MS for source‐to‐sink studies, allowing detailed organic matter source characterization and discrimination, and tracking of molecular transformations along organic matter pathways spanning different spatial and temporal scales.
    Description: Plain Language Summary: The transfer of organic matter (OM) by rivers from landscape sources into the ocean followed by its burial in marine sediments is an important carbon sink. Therefore, OM is often traced along this journey using its isotopic or biomarker composition. But contributions of OM sources to river sediments can be difficult to estimate because of similar source characteristics, mixing of many sources and changes of the molecular composition along the way. Fourier Transform Ion Cyclotron Resonance Mass Spectrometry (FT‐ICR‐MS) is a novel method able to identify many molecular formulas from OM mixtures at once providing direct information about their molecular composition. Here, we investigate how FT‐ICR‐MS contributes to understanding the transport and transformation of particulate OM focusing on a Himalayan river in Nepal. We use the molecular information to identify tracers for individual OM sources in the landscape. We then assess molecular transformations during the transfer of litter into topsoil, and onwards into the river. Our data suggest efficient incorporation of litter into topsoil, but we observe a selective loss of molecular formulas upon entrainment of sources into the river. Our results reveal that FT‐ICR‐MS is useful for detailed source characterization and tracking of molecular transformations along OM pathways.
    Description: Key Points: Organic matter sourcing and transformations in a Himalayan river studied by FT‐ICR‐MS measurements of solvent extractable lipids. Identification of up to 102 indicator mass formulas for different organic matter sources in the landscape using indicator species analysis. Mass formulas preserved during incorporation of litter into topsoil but selectively lost during entrainment of sources into the river.
    Description: Helmholtz Impuls und Vernetzungsfond
    Description: GFZ expedition funding
    Description: http://doi.org/10.5880/GFZ.4.6.2022.002
    Keywords: ddc:551 ; particulate organic carbon ; solvent extractable lipids ; FT‐ICR‐MS ; Himalaya ; carbon cycling ; indicator species analysis
    Language: English
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    Fluvial and permafrost history of the lower Lena River, north‐eastern Siberia, over late Quaternary time (2022)
    Schwamborn, Georg ; Schirrmeister, Lutz ; Mohammadi, Ali ; [et al.]
    Details
    Publication Date: 2023-11-18
    Description: Arctic warming and permafrost thaw visibly expose changes in the landscape of the Lena River delta, the largest Arctic delta. Determining the past and modern river regime of thick deltaic deposits shaping the Lena River mouth in north‐eastern Siberia is critical for understanding the history of delta formation and carbon sequestration. Using a 65 m long sediment core from the delta apex a set of sedimentological techniques is applied to aid in reconstructing the Lena River history. The analysis includes: (i) grain‐size measurements and the determination of the bedload composition; (ii) X‐ray fluorescence, X‐ray diffractometry, and magnetic susceptibility measurements and heavy mineral analysis for tracking mineral change; (iii) pH, electrical conductivity, ionic concentrations, and the δ〈sub〉18〈/sub〉O and δD stable isotope composition from ground ice for reconstructing permafrost formation. In addition; (iv) total and dissolved organic carbon is assessed. Chronology is based on; (vi) radiocarbon dating of organic material (accelerator mass spectrometry and conventional) and is complemented by two infrared – optically stimulated luminescence dates. The record stretches back approximately to Marine Isotope Stage 7. It holds periods from traction, over saltation, to suspension load sedimentation. Minerogenic signals do not indicate provenance change over time. They rather reflect the change from high energy to a lower energy regime after Last Glacial Maximum time parallel to the fining‐up grain‐size trend. A prominent minimum in the ground ice stable isotope record at early Holocene highlights that a river arm migration and an associated refreeze of the underlying river talik has altered the isotopic composition at that time. Fluvial re‐routing might be explained by internal dynamics in the Lena River lowland or due to a tectonic movement, since the study area is placed in a zone of seismic activity. At the southern Laptev Sea margin, onshore continental compressional patterns are bordering offshore extensional normal faults.
    Description: Alfred Wegener Institute, Helmholtz Centre for Polar and Marine Research
    Description: https://doi.org/10.1594/PANGAEA.945355
    Keywords: ddc:551 ; Lena River ; north‐eastern Siberia ; palaeoenvironment ; permafrost ; Quaternary
    Language: English
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    Quantifying Ice‐Sheet Derived Lead (Pb) Fluxes to the Ocean; A Case Study at Nioghalvfjerdsbræ (2022)
    Details
    Publication Date: 2023-11-17
    Description: Concentrations of the toxic element lead (Pb) are elevated in seawater due to historical emissions. While anthropogenic atmospheric emissions are the dominant source of dissolved Pb (dPb) to the Atlantic Ocean, evidence is emerging of a natural source associated with subglacial discharge into the ocean but this has yet to be constrained around Greenland. Here, we show subglacial discharge from the cavity underneath Nioghalvfjerdsbræ floating ice tongue, is a previously unrecognized source of dPb to the NE Greenland Shelf. Contrasting cavity‐inflowing and cavity‐outflowing waters, we constrain the associated net‐dPb flux as 2.2 ± 1.4 Mg·yr−1, of which ∼90% originates from dissolution of glacial bedrock and cavity sediments. We propose that the retreat of the floating ice tongue, the ongoing retreat of many glaciers on Greenland, associated shifts in sediment dynamics, and enhanced meltwater discharges into shelf waters may result in pronounced changes, possibly increases, in net‐dPb fluxes to coastal waters.
    Description: Plain Language Summary: Lead (Pb) is a toxic element. Hundreds of thousands of tons have historically been emitted into the atmosphere through use of leaded gasoline, ore‐smelting and coal‐combustion which led to large‐scale deposition of Pb into the ocean and onto the Greenland Ice Sheet. Since the phase‐out of leaded gasoline, concentrations of dissolved Pb in the surface ocean have declined, increasing the relative importance of other, natural sources of Pb to the marine environment. In 2016, we conducted a survey near Nioghalvfjerdsbræ, one of Greenland’s largest marine‐terminating glaciers, to investigate if Greenland Ice Sheet discharge is a source of Pb to the Northeast Greenland Shelf. We observed elevated dissolved Pb concentrations at intermediate depths within a ⁓60 km radius downstream of the Nioghalvfjerdsbræ terminus. The Pb enrichment originates from underneath the glacier’s floating ice tongue. Lead sources underneath Nioghalvfjerdsbræ likely include Pb from eroded bedrock and exchange with fjord sediments. Our calculations suggest that Nioghalvfjerdsbræ dissolved Pb discharge is comparable to that from small Arctic rivers. Given the widespread occurance of Pb‐rich minerals across Greenland, observed increases in meltwater discharge and the retreat of marine‐terminating glaciers could increase dPb supply to Greenlandic shelf regions.
    Description: Key Points: Helium and neon show strong evidence for a subglacial source of Pb discharging onto the NE Greenland Shelf. Contrasting inflowing and outflowing waters beneath the floating ice tongue of Nioghalvfjerdsbræ shows a 2‐3‐fold dPb enrichment. The dissolved Pb flux from Nioghalvfjerdsbræ (2.2 ± 1.4 Mg·yr−1) is comparable to small Arctic rivers, with ∼90% of a sedimentary origin.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: Bundesministerium für Bildung und Forschung http://dx.doi.org/10.13039/501100002347
    Description: Kuwait Institute for Scientific Research http://dx.doi.org/10.13039/501100005074
    Description: Swiss Polar Foundation
    Description: https://doi.pangaea.de/10.1594/PANGAEA.871028
    Description: https://doi.pangaea.de/10.1594/PANGAEA.871030
    Description: https://doi.pangaea.de/10.1594/PANGAEA.879197
    Description: https://doi.pangaea.de/10.1594/PANGAEA.905347
    Description: https://doi.pangaea.de/10.1594/PANGAEA.933431
    Description: https://doi.pangaea.de/10.1594/PANGAEA.931336
    Description: https://doi.org/10.5194/essd-8-543-2016
    Keywords: ddc:551 ; Greenland ice sheet ; Arctic ; marine‐terminating glacier ; Nioghalvfjerdsbrae ; lead fluxes ; GEOTRACES
    Language: English
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    Rinikerfeld Palaeolake (Northern Switzerland) – a sedimentary archive of landscape and climate change during the penultimate glacial cycle (2022)
    Gegg, Lukas ; Anselmetti, Flavio S. ; Deplazes, Gaudenz ; [et al.]
    Details
    Publication Date: 2024-01-19
    Description: While timing and ice extent of the last glacial maximum are generally well known, the courses of earlier glaciations have remained poorly constrained, with one of the main reasons being the scarcity of sedimentary archives. This study introduces a new palaeolake record from a Mid‐Pleistocene glaciofluvial channel system in the Lower Aare Valley (Northern Switzerland). The record of Rinikerfeld comprises a 〉40 m long succession of Quaternary deposits that are targeted by multi‐method sedimentological analysis. Sedimentary facies together with geochemical and geotechnical parameters, pollen content, as well as luminescence ages allow the reconstruction of the establishment, evolution and infilling of the early Marine Isotope Stage 6‐aged Rinikerfeld Palaeolake. A drastic change in lake sediment composition and structure indicates cessation of the initial glacially derived input, which is explained by landscape modification and drainage rerouting during the Penultimate (Beringen) Glaciation. Geochemical and palynological data further reveal cold, initially periglacial but slightly ameliorating, climate conditions, while the lake was progressively filled up by local runoff, before being buried by periglacial colluvial diamicts, and potentially overridden by ice. It is therefore concluded that the onset of the Beringen Glaciation was an environmentally as well as geomorphically dynamic time period in the Northern Alpine Foreland.
    Description: NATIONALE GENOSSENSCHAFT FÜR DIE LAGERUNG RADIOAKTIVER ABFÄLLE
    Keywords: ddc:551 ; Northern Alpine foreland ; palaeolake ; penultimate glaciation ; periglacial lake ; sedimentary archive
    Language: English
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    Riparian Microtopography Affects Event‐Driven Stream DOC Concentrations and DOM Quality in a Forested Headwater Catchment (2022)
    Blaurock, Katharina ; Garthen, Phil ; da Silva, Maria P. ; [et al.]
    Details
    Publication Date: 2024-01-19
    Description: The transport of dissolved organic carbon (DOC) from the soils to inland waters plays an important role in the global carbon cycle. Widespread increases in DOC concentrations have been observed in surface waters over the last few decades, affecting carbon balances, ecosystem functioning and drinking water treatment. However, the primary hydrological controls on DOC mobilization are still uncertain. The aim of this study was to investigate the role of microtopography in the riparian zone for DOC export and DOM quality. DOC concentration and DOM quality in the shallow groundwater of a riparian zone and in streamflow in a forested headwater catchment was investigated using fluorescence and absorbance characteristics. We found higher DOC concentrations with a higher aromaticity in the microtopographical depressions, which were influenced by highly dynamic shallow groundwater levels, than in the flat forest soil. As a result of the frequent wet‐dry cycles in the upper soil layers, aromatic DOC accumulated in the shallow groundwater within and below the microtopographical depressions. Rising groundwater levels during precipitation events led to the connection of the microtopographical depressions to the stream, resulting in a change toward more aromatic DOC in the stream. Increasing stream DOC concentrations were accompanied by increasing concentrations of iron and aluminum, suggesting the coupled release of these metals with DOC from the riparian zone. Our results highlight the importance of the interplay between microtopography and groundwater level dynamics in the riparian zone for DOC export from headwater catchments.
    Description: Plain Language Summary: Dissolved organic carbon (DOC) is the result of the continuous breakdown of organic material, such as leaves. It accumulates in the soil and is transported to streams mainly during precipitation events. In this study, we analyzed the shallow groundwater of two differing sites in the Bavarian Forest National Park. Both sites were located close to the stream, but one was characterized by typical forest soil and one by small ponds, which were occasionally filled with water. The site with ponds showed much higher DOC concentrations and the DOC was chemically different from the other site. During a precipitation event, we observed a shift in chemical composition of stream water parameters toward the chemical characteristics found at the site with ponds. Therefore, we conclude that the ponds contribute substantially to DOC mobilization, once they fill with water and get connected to the stream.
    Description: Key Points: This study found small‐scale differences in dissolved organic carbon (DOC) concentrations and dissolved organic matter (DOM) quality in the riparian zone. Microtopographical depressions were characterized by high DOC concentrations and aromatic DOC. In‐stream DOC concentrations and DOM quality during a precipitation event resembled shallow groundwater below microtopographical depressions.
    Description: Stifterverband http://dx.doi.org/10.13039/501100008384
    Description: Helmholtz Association http://dx.doi.org/10.13039/501100009318
    Description: Rudolf and Helene Glaser Foundation
    Description: European Regional Development Funds
    Description: https://doi.org/10.6084/m9.figshare.19086455
    Description: https://doi.org/10.48758/ufz.12908
    Keywords: ddc:551 ; dissolved organic carbon ; hydrology ; microtopography ; DOM quality
    Language: English
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    Focused methane migration formed pipe structures in permeable sandstones: Insights from uncrewed aerial vehicle‐based digital outcrop analysis in Varna, Bulgaria (2021)
    Details
    Publication Date: 2022-04-04
    Description: Focused fluid flow shapes the evolution of marine sedimentary basins by transferring fluids and pressure across geological formations. Vertical fluid conduits may form where localized overpressure breaches a cap rock (permeability barrier) and thereby transports overpressured fluids towards shallower reservoirs or the surface. Field outcrops of an Eocene fluid flow system at Pobiti Kamani and Beloslav Quarry (ca 15 km west of Varna, Bulgaria) reveal large carbonate‐cemented conduits, which formed in highly permeable, unconsolidated, marine sands of the northern Tethys Margin. An uncrewed aerial vehicle with an RGB sensor camera produces ortho‐rectified image mosaics, digital elevation models and point clouds of the two kilometre‐scale outcrop areas. Based on these data, geological field observations and petrological analysis of rock/core samples, fractures and vertical fluid conduits were mapped and analyzed with centimetre accuracy. The results show that both outcrops comprise several hundred carbonate‐cemented fluid conduits (pipes), oriented perpendicular to bedding, and at least seven bedding‐parallel calcite cemented interbeds which differ from the hosting sand formation only by their increased amount of cementation. The observations show that carbonate precipitation likely initiated around areas of focused fluid flow, where methane entered the formation from the underlying fractured subsurface. These first carbonates formed the outer walls of the pipes and continued to grow inward, leading to self‐sustaining and self‐reinforcing focused fluid flow. The results, supported by literature‐based carbon and oxygen isotope analyses of the carbonates, indicate that ambient seawater and advected fresh/brackish water were involved in the carbonate precipitation by microbial methane oxidation. Similar structures may also form in modern settings where focused fluid flow advects fluids into overlying sand‐dominated formations, which has wide implications for the understanding of how focusing of fluids works in sedimentary basins with broad consequences for the migration of water, oil and gas.
    Description: Integrated School of Ocean Sciences (ISOS) Kiel
    Description: European Union’s Horizon 2020 http://dx.doi.org/10.13039/100010661
    Description: Bulgarian Science Fund
    Keywords: ddc:551
    Language: English
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    Carbon Dioxide and Methane Release Following Abrupt Thaw of Pleistocene Permafrost Deposits in Arctic Siberia (2021)
    Details
    Publication Date: 2022-04-07
    Description: The decomposition of thawing permafrost organic matter (OM) to the greenhouse gases (GHG) carbon dioxide (CO2) and methane forms a positive feedback to global climate change. Data on in situ GHG fluxes from thawing permafrost OM are scarce and OM degradability is largely unknown, causing high uncertainties in the permafrost‐carbon climate feedback. We combined in situ CO2 and methane flux measurements at an abrupt permafrost thaw feature with laboratory incubations and dynamic modeling to quantify annual CO2 release from thawing permafrost OM, estimate its in situ degradability and evaluate the explanatory power of incubation experiments. In July 2016 and 2019, CO2 fluxes ranged between 0.24 and 2.6 g CO2‐C m−2 d−1. Methane fluxes were low, which coincided with the absence of active methanogens in the Pleistocene permafrost. CO2 fluxes were lower three years after initial thaw after normalizing these fluxes to thawed carbon, indicating the depletion of labile carbon. Higher CO2 fluxes from thawing Pleistocene permafrost than from Holocene permafrost indicate OM preservation for millennia and give evidence that microbial activity in the permafrost was not substantial. Short‐term incubations overestimated in situ CO2 fluxes but underestimated methane fluxes. Two independent models simulated median annual CO2 fluxes of 160 and 184 g CO2‐C m−2 from the thaw slump, which include 25%–31% CO2 emissions during winter. Annual CO2 fluxes represent 0.8% of the carbon pool thawed in the surface soil. Our results demonstrate the potential of abrupt thaw processes to transform the tundra from carbon neutral into a substantial GHG source.
    Description: Plain Language Summary: Thawing of permanently frozen soils (permafrost) in the northern hemisphere forms a threat to global climate since these soils contain large amounts of frozen organic carbon, which might be decomposed to the greenhouse gases (GHGs) carbon dioxide (CO2) and methane upon thaw. How fast these GHGs are produced is largely unknown, since field observations of greenhouse gas fluxes from thawing permafrost are too sparse. Consequently, simulations on the effect of thawing permafrost soils on future climate are highly uncertain. We measured CO2 and methane fluxes from soils affected by abrupt permafrost thaw in Siberia during two summer seasons. We used these field observations and long‐term incubation data to calibrate two models that simulate the CO2 release over a whole year. We found that greenhouse gas fluxes were dominated by CO2 and that the minor importance of methane was due to the absence of methane producing microorganisms in the Pleistocene permafrost. The CO2 release in the first year accounted for 0.8% of thawed permafrost carbon but decomposition rates decreased after the depletion of the rapidly decomposable organic matter. Abrupt permafrost thaw turned the tundra into a substantial source of CO2, of which 25%–31% was released in the non‐growing season.
    Description: Key Points: Abrupt permafrost thaw turned the tundra into a substantial annual source of CO2 of which 25%–31% were released in the non‐growing season. About 0.8% of thawed permafrost carbon was decomposed to CO2 in one year but decomposition rates declined after the loss of labile carbon. Methane contributed a minor fraction to total greenhouse gas fluxes also because of a low methanogen abundance in Pleistocene permafrost.
    Description: German Ministry for Education and Research
    Description: German Research Foundation
    Description: https://doi.org/10.5281/zenodo.5584710
    Keywords: ddc:551
    Language: English
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    Leaf Wax Hydrogen Isotopes as a Hydroclimate Proxy in the Tropical Pacific (2021)
    Details
    Publication Date: 2022-04-07
    Description: Hydrogen isotope ratios of sedimentary leaf waxes (δ2HWax values) are increasingly used to reconstruct past hydroclimate. Here, we add δ2HWax values from 19 lakes and four swamps on 15 tropical Pacific islands to an updated global compilation of published data from surface sediments and soils. Globally, there is a strong positive linear correlation between δ2H values of mean annual precipitation (δ2HP values) and the leaf waxes n‐C29‐alkane (R2 = 0.74, n = 665) and n‐C28‐acid (R2 = 0.74, n = 242). Tropical Pacific δ2HWax values fall within the predicted range of values based on the global calibration, and the largest residuals from the global regression line are no greater than those observed elsewhere, despite large uncertainties in δ2HP values at some Pacific sites. However, tropical Pacific δ2HWax values in isolation are not correlated with estimated δ2HP values from isoscapes or from isotope‐enabled general circulation models. Palynological analyses from these same Pacific sediment samples suggest no systematic relationship between any particular type of pollen distribution and deviations from the global calibration line. Rather, the poor correlations observed in the tropical Pacific are likely a function of the small range of δ2HP values relative to the typical residuals around the global calibration line. Our results suggest that δ2HWax values are currently most suitable for use in detecting large changes in precipitation in the tropical Pacific and elsewhere, but that ample room for improving this threshold exits in both improved understanding of δ2H variability in plants, as well as in precipitation.
    Description: Plain Language Summary: Past precipitation patterns are difficult to reconstruct, limiting our ability to understand Earth’s climate system. Geochemists reconstruct past precipitation by measuring the amount of heavy hydrogen naturally incorporated into the waxy coating of leaves, which is preserved in mud that accumulates in lakes, soils, and oceans. Heavy hydrogen in leaf waxes is strongly correlated with local precipitation, allowing us to learn about rainfall intensity, temperature, and cloud movement. However, no existing calibration studies include sites from the tropical Pacific, home to the most intense rainfall on the planet and populations that rely on rain for drinking water and farming. We measured heavy hydrogen in leaf waxes from tropical Pacific islands and show that although values are within the global calibration error, no precipitation relationship exists within the region. Plant type distributions do not explain the lack of correlation, which is best attributed to poorly constrained estimates of heavy hydrogen in local rain and the relatively small range of variability within the region. At present, heavy hydrogen from ancient leaf waxes can show large changes in past precipitation, but improved process‐level understanding is needed to use this tool to understand smaller changes in the tropical Pacific and elsewhere.
    Description: Key Points: Leaf wax 2H/1H ratios are correlated with mean annual precipitation 2H/1H ratios globally, but not in the tropical Pacific. Deviations from the global relationship between precipitation leaf wax 2H/1H ratios cannot be predicted from palynological assemblages. Small range and large uncertainties in estimates of tropical Pacific precipitation 2H/1H ratios likely account for poor correlations.
    Description: Swiss National Science Foundation
    Description: National Science Foundation (NSF) http://dx.doi.org/10.13039/100000001
    Description: Natural Environment Research Council (NERC) http://dx.doi.org/10.13039/501100000270
    Description: Department of Education and Training, Australian Research Council (ARC) http://dx.doi.org/10.13039/501100000923
    Description: http://10.0.15.89/ethz-b-000412154
    Keywords: ddc:551 ; ddc:577.7
    Language: English
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    Long‐Term Nitrate Trajectories Vary by Season in Western European Catchments (2021)
    Details
    Publication Date: 2022-04-05
    Description: Human alteration of nutrient cycles has caused persistent and widespread degradation of water quality around the globe. In many regions, including Western Europe, elevated nitrate (NO3−) concentration in surface waters contributes to eutrophication and noncompliance with environmental legislation. Discharge, NO3− concentrations and the vulnerability of the aquatic ecosystems to eutrophication often exhibit a distinct seasonality. Understanding spatial patterns and long‐term trends in this seasonality is crucial to improve water quality management. Here, we hypothesized that NO3− concentrations during high‐flow periods would respond faster to changes in nutrient inputs than low‐flow concentrations because of greater connectivity of shallow diffuse NO3− sources with the river network. To test this hypothesis, we compiled long‐term NO3− and discharge time series from 290 Western European catchments. To characterize the long‐term trajectories of seasonal NO3− concentration, we propose a novel hysteresis approach comparing low‐ and high‐flow NO3− concentration in the context of multi‐decadal N input changes. We found synchronous winter maxima of NO3− and discharge in 84% of the study catchments. However, contrary to our hypothesis, there were surprisingly diverse long‐term trajectories of seasonal NO3− concentration. Both clockwise (faster high‐flow NO3− response) and counterclockwise hysteresis (faster low‐flow NO3− response) occurred in similar proportions, potentially due to a high complexity in the underlying processes. Spatial variability of seasonality in NO3− concentration across the catchments was more pronounced and better predictable than its long‐term variability. This work demonstrates the value of seasonal and inter‐annual hydrochemical analysis and provides new tools for water quality monitoring and management.
    Description: Plain Language Summary: Nitrogen is an essential element of all living organisms and has thus often been used excessively as fertilizer to secure food production. However, surface waters can suffer from elevated nutrients inputs, causing toxic algal blooms and impairing drinking water quality, especially during summer low flows. To manage water quality, it is crucial to understand these seasonal variations of nitrogen and discharge and the underlying processes. We used data from 290 catchments in France and Germany to characterize average seasonality patterns and their long‐term evolution across the variety of landscapes and human influences. This allowed classifying catchment behavior and linking them to controls. As expected, both nitrogen and discharge peak during winter in most catchments (84%). However, there are well explainable deviations, for example, in mountainous regions. The long‐term evolution of seasonality was more diverse than expected suggesting a complex interplay of various processes with the long input history from fertilization and wastewater being part of the controls. We found that the differences among catchments were greater than the long‐term changes of seasonality within most catchments. By identifying catchment typologies, our study increases the understanding of nitrate seasonality patterns across a large extent and thus supports ecological water quality management.
    Description: Key Points: Spatial patterns of nitrate and discharge seasonality are linked to topography and hydroclimate with winter maxima dominating for both. After decreasing nutrient inputs, cases with decreases in river nitrate preceding during low‐ and high‐flow seasons occurred equally often. Spatial variability of nitrate seasonality is greater and more predictable from catchment characteristics than its long‐term variability.
    Description: Deutsche Forschungsgemeinschaft (DFG) http://dx.doi.org/10.13039/501100001659
    Description: Helmholtz Association http://dx.doi.org/10.13039/501100009318
    Description: US National Science Foundation (NSF)
    Keywords: ddc:551
    Language: English
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    The terrestrial impact crater record: A statistical analysis of morphologies, structures, ages, lithologies, and more (2021)
    Details
    Publication Date: 2022-03-30
    Description: Abstract The number of newly discovered and confirmed impact structures on earth is growing continuously. In this review paper, the main attributes of 198 confirmed impact structures and 10 further structures, for which final confirmation based on the identification of shock features is not yet entirely satisfying, are presented. The impact craters are compared statistically, with regard to their morphology, structure, and status of erosion or burial. The size– and age–frequency distributions of terrestrial impact structures are presented. Additional aspects concern target petrography and shock effects found in the craters. Based on the discovery statistics of presently known crater structures, an estimate can be made of the number of craters that await discovery. The paper is complementary to the recently published atlas of terrestrial impact structures by Gottwald et al. (2020).
    Keywords: ddc:551
    Language: English
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    Eemian landscape response to climatic shifts and evidence for northerly Neanderthal occupation at a palaeolake margin in northern Germany (2021)
    Details
    Publication Date: 2022-03-30
    Description: The prevailing view suggests that the Eemian interglacial on the European Plain was characterized by largely negligible geomorphic activity beyond the coastal areas. However, systematic geomorphological studies are sparse. Here we present a detailed reconstruction of Eemian to Early Weichselian landscape evolution in the vicinity of a small fingerlake on the northern margin of the Salzwedel Palaeolake in Lower Saxony (Germany). We apply a combination of seismics, sediment coring, pollen analysis and luminescence dating on a complex sequence of colluvial, paludal and lacustrine sediments. Results suggest two pronounced phases of geomorphic activity, directly before the onset and at the end of the Eemian period, with an intermediate period of pronounced landscape stability. The dynamic phases were largely driven by incomplete vegetation cover, but likely accentuated by fluvial incision in the neighbouring Elbe Valley. Furthermore, we discovered Neanderthal occupation at the lakeshore during Eemian pollen zone (PZ) E IV, which is chronologically in line with other known Eemian sites of central Europe. Our highly‐resolved spatio‐temporal data substantially contribute to the understanding of climate‐induced geomorphic processes throughout and directly after the last interglacial period. It helps unraveling the landscape dynamics between the coastal areas to the north and the loess belt to the south.
    Description: Two phases of channel incision at the Saalian‐Eemian transition and in the late Eemian. Incisions closely followed by rising water tables. Long‐lasting phase of geomorphic stability in the mid‐Eemian, characterized by: very dense forest cover. the formation of a fingerlake within the paleochannel with gradually sinking water table. no influx of clastic sediments, but deposition of peat and lake‐marl deposits.
    Description: Max‐Planck‐Gesellschaft http://dx.doi.org/10.13039/501100004189
    Keywords: ddc:554.3 ; ddc:551
    Language: English
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    Papanin Ridge and Ojin Rise Seamounts (Northwest Pacific): Dual Hotspot Tracks Formed by the Shatsky Plume (2021)
    Details
    Publication Date: 2022-03-31
    Description: Although previous findings support an origin of the Shatsky Rise igneous plateau (Northwest Pacific) through interaction of a mantle plume with a mid‐ocean ridge triple junction, the evidence for the involvement of a mantle plume is equivocal. The identification of an intraplate hotspot track emanating from the plateau could solve this controversy. Here we present major and trace element geochemical data from two different bathymetric features that emanate from the youngest end of Shatsky Rise: Papanin Ridge and the Ojin Rise Seamount province. Combining our results with plate tectonic reconstructions, we conclude that Papanin Ridge represents a hotspot track formed by plume‐ridge interaction. Whereas the southwestern part was formed along the path of the retreating Pacific‐Farallon‐Izanagi triple junction, the northeastern part was built by preferential drainage into its Pacific‐Farallon branch. In contrast, the Ojin Rise Seamounts formed as a true intraplate hotspot track of the Shatsky plume tail. Our wide‐ranging study reveals systematic spatial geochemical variations, consistent with a lithospheric thickness control on magma composition derived from melting a heterogeneous plume source. The recognition of two hotspot tracks and in particular of the Ojin Rise Seamounts as an intraplate hotspot track that is directly linked to Shatsky plateau volcanism both in terms of geochemistry and plate tectonic reconstructions confirms the long‐disputed involvement of a mantle plume for the formation of Shatsky Rise.
    Description: Plain Language Summary: The origin of Shatsky Rise, a large igneous plateau in the NW Pacific, has long been debated. It could have either formed by shallow mantle melting due to its confirmed creation along a mid‐ocean ridge or with additional contribution of deeper mantle material that upwelled as so‐called mantle plume beneath the spreading ridge (“plume‐ridge interaction”). The identification of an intraplate hotspot track emanating from Shatsky Rise and related to the plateau could answer this question. Here we present major and trace element geochemical data from lava samples dredged from two different structures that arise from the youngest end of the Shatsky Rise plateau: Papanin Ridge and the Ojin Rise Seamount province. By combining our results with plate tectonic reconstructions, we conclude that Papanin Ridge formed, like the main Shatsky Rise, by continued plume‐ridge interaction. In contrast, the Ojin Rise Seamounts formed as a true intraplate hotspot track by the drift of the Pacific Plate over the stationary Shatsky hotspot (plume tail). The recognition of an intraplate hotspot track that is directly linked to the Shatsky plateau volcanism both in terms of geochemistry and plate tectonic reconstructions also confirms the involvement of a mantle plume for the formation of Shatsky Rise.
    Description: Key Points: The Ojin Rise Seamounts are identified as intraplate hotspot track of the same mantle plume that formed the Shatsky Rise oceanic plateau. Papanin Ridge formed by plume‐ridge interaction and represents the northeastern continuation of the Shatsky plateau. Linking an intraplate hotspot track to the Shatsky plateau confirms the involvement of a mantle plume for its formation.
    Description: Bundesministerium für Bildung und Forschung (BMBF) http://dx.doi.org/10.13039/501100002347
    Description: GEOMAR Helmholtz Centre for Ocean Research Kiel
    Description: https://doi.org/10.26022/IEDA/111976
    Keywords: ddc:551 ; ddc:552.2
    Language: English
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    The Heligoland Glacitectonic Complex in the southeastern North Sea: indicators of a pre‐ or early‐Elsterian ice margin (2021)
    Details
    Publication Date: 2022-03-28
    Description: Glacial landforms are abundant in the North Sea basin and are often used to reconstruct the impact and dynamics of ice sheets during the Pleistocene. Geophysical methods have allowed the mapping and structural analysis of glacial landforms at the surface and in the subsurface to estimate the position of former ice margins in the North Sea. However, the glacial history of the southeastern North Sea remains underexplored. In this study, we present a structural analysis of Late Pliocene to Late Pleistocene sediments based on a dense grid of 2D high‐resolution multi‐channel reflection seismic data from the German sector of the southeastern North Sea. We show that the Heligoland Glacitectonic Complex (HGC) is larger than previously assumed (700 km2, 32×22 km) and characterized by three distinct zones of thrusting and deformation on two décollements. The kinematic restoration of seismic cross‐sections and dip measurements of thrust faults demonstrate that the HGC was formed by an ice lobe advancing from the southeast. To explain the origin of the HGC, we provide alternative models for its formation during a single ice advance or two ice advances in the study area. Furthermore, we validate the early or pre‐Elsterian age of the HGC based on nearby Elsterian tunnel valleys, and conclude that salt structures in the subsurface may have influenced its location.
    Description: Schleswig‐Holstein Agency for Coastal Defence, National Park and Marine Conservation (LKN.SH) and the State Agency for Agriculture, Environment and Rural Areas of Schleswig‐Holstein (LLUR)
    Keywords: ddc:551
    Language: English
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    Late Holocene Climate Changes in the Altai Region Based on a First High‐Resolution Biomarker Isotope Record From Lake Khar Nuur (2021)
    Details
    Publication Date: 2022-03-29
    Description: The Late Holocene marks a substantial cultural and economic transition in the eastern Eurasian Steppe and Altai Region with the dispersal of nomadic pastoralism. So far, paleoclimate conditions during this time remain unclear and controversial. Here, we present a high‐resolution 4.2 ka paleoclimate record from Lake Khar Nuur in the Mongolian Altai that is based on lake sediment proxies and biomarker compound‐specific δ2H analyses. Our results document increased aridity before ∼3.7 cal. ka BP, followed by two pronounced phases of warm and wet conditions from ∼3.5–2.8 to ∼2.3–1.5 cal. ka BP, and a strong increase in aridity since ∼1.5 cal. ka BP. Phases of warmer and wetter conditions coincide with a negative North Atlantic Oscillation, which has been responsible for advecting moisture into the region by more southerly‐displaced Westerlies and possibly favored the expansion of mobile nomadic pastoralism in the region.
    Description: Plain Language Summary: Nomadic pastoralism is the dominant subsistence practice in the eastern Eurasian Steppe and Altai Region since the Late Bronze Age. Whether this had climatic reasons is one of the most intriguing question, because former climatic conditions are poorly understood in this important but understudied region. To address this issue, we established a hydrological record for the last ∼4.2 ka from a high‐altitude lake in the Mongolian Altai. Our findings provide evidence of exceptionally warm and wet conditions from ∼3.5–2.8 and ∼2.3–1.5 cal. ka BP. Those favorable climate conditions likely favored productive grasslands and the widespread dispersal of nomadic pastoralism in the eastern Eurasian Steppe and Altai Region.
    Description: Key Points: A high‐resolution 4.2 ka paleoclimate record from Lake Khar Nuur in the Mongolian Altai, based on biomarker compound‐specific δ2H analyses. Our hydrological proxies record distinct changes in warm/wet and cold/dry conditions during the Late Holocene in the Altai Region: Pronounced warm/wet conditions from ∼3.5 to 2.8 cal. ka BP probably favored the widespread dispersal of nomadic pastoralism in the region.
    Description: Ernst Abbe Stiftung
    Description: https://doi.org/10.1594/PANGAEA.936512
    Keywords: ddc:551
    Language: English
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    Cyclostratigraphy and paleoenvironmental inference from downhole logging of sediments in tropical Lake Towuti, Indonesia (2021)
    Springer Netherlands
    Details
    Publication Date: 2023-06-14
    Description: Lake Towuti is located on central Sulawesi/Indonesia, within the Indo Pacific Warm Pool, a globally important region for atmospheric heat and moisture budgets. In 2015 the Towuti Drilling Project recovered more than 1000 m of drill core from the lake, along with downhole geophysical logging data from two drilling sites. The cores constitute the longest continuous lacustrine sediment succession from the Indo Pacific Warm Pool. We combined lithological descriptions with borehole logging data and used multivariate statistics to better understand the cyclic sequence, paleoenvironments, and geochronology of these sediments. Accurate chronologies are crucial to analyze and interpret paleoclimate records. Astronomical tuning can help build age-depth models and fill gaps between age control points. Cyclostratigraphic investigations were conducted on a downhole magnetic susceptibility log from the lacustrine facies (10–98 m below lake floor) from a continuous record of sediments in Lake Towuti. This study provides insights into the sedimentary history of the basin between radiometric ages derived from dating a tephra layer (~ 797 ka) and C14-ages (~ 45 ka) in the cores. We derived an age model that spans from late marine isotope stage (MIS) 23 to late MIS 6 (903 ± 11 to 131 ± 67 ka). Although uncertainties caused by the relatively short record and the small differences in the physical properties of sediments limited the efficacy of our approach, we suggest that eccentricity cycles and/or global glacial-interglacial climate variability were the main drivers of local variations in hydroclimate in central Indonesia. We generated the first nearly complete age-depth model for the lacustrine facies of Lake Towuti and examined the potential of geophysical downhole logging for time estimation and lithological description. Future lake drilling projects will benefit from this approach, since logging data are available just after the drilling campaign, whereas core descriptions, though more resolved, only become available months to years later.
    Description: Deutsche Forschungsgemeinschaft (DE)
    Description: Projekt DEAL
    Keywords: ddc:551 ; Paleoclimate ; Geophysical downhole logging ; Cyclostratigraphy ; Lake Towuti ; Indo Pacific Warm Pool
    Language: English
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    Holocene paleoenvironmental change inferred from two sediment cores collected in the Tibetan lake Taro Co (2021)
    Springer Netherlands
    Details
    Publication Date: 2023-07-06
    Description: The Tibetan Plateau, also known as the “Water Tower of Asia” because of its function as a water storage and supply region, responds dramatically to modern climate changes. Paleoecological shifts inferred from lake sediment archives provide essential insights into past climate changes, and the processes that drove those shifts. This is especially true for studies of lakes in endorheic basins on the Tibetan Plateau, where lake level is regulated predominantly by Monsoon intensity. Such water bodies provide excellent opportunities to reconstruct past changes in humidity. Most paleolimnological investigations of lakes on the Tibetan Plateau, however, have involved the study of a single sediment core, making it difficult to discern between changes caused by local events and those caused by lake-wide or regional processes. Here we present results from a paleolimnological study of Lake Taro Co, a currently closed-basin lake in Central Tibet. We compared a sediment record from the central part of the lake to a record from the near-shore area, and present results of sedimentological and bioindicator (chironomid, diatom, pollen) analyses from both records. Results show three periods of lake-wide ecosystem change (〉 ca. 5250, 5250–2250 and 〈 since about 2250 cal year BP), which reflect a continuous drying trend throughout the Middle and Late Holocene. In addition to this lake-wide trend, we identified two local events in the sediment core from the southeastern, nearshore site. These include (1) a hiatus between 12,400 and 5400 cal year BP and (2) an 1800-year period of distinct paleoenvironmental conditions (5400–3600 cal year BP). We hypothesize that both events were caused by relocation of a river in the southeast sector of the lake’s catchment. We propose that the first relocation caused an erosion event that removed sediment, thereby producing the hiatus. During the following 1800 years, the core site may have been located on the river delta, before another river relocation at 3600 cal year BP established the modern prodelta situation. Our study demonstrates the value of using multiple sediment cores from a lake, to better identify processes that control widespread versus local events.
    Description: Bundesministerium für Bildung und Forschung http://dx.doi.org/10.13039/501100002347
    Description: Fellowships for Young International Scientists http://dx.doi.org/10.13039/501100010895
    Description: NSFC Research Fund for International Young Scientists (CN)
    Description: Deutsche Forschungsgemeinschaft (DFG) (DE)
    Description: National Natural Science Foundation of China http://dx.doi.org/10.13039/501100001809
    Description: Technische Universität Braunschweig (1042)
    Keywords: ddc:551 ; Monsoon ; Chironomidae ; Diatoms ; Geochemistry ; XRF ; Paleolimnology
    Language: English
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    The Late Carboniferous deeply eroded Tharandt Forest caldera–Niederbobritzsch granite complex: a post-Variscan long-lived magmatic system in central Europe (2021)
    Springer Berlin Heidelberg
    Details
    Publication Date: 2023-08-17
    Description: Samples and documentation of outcrops and drillings, facies analysis, whole rock geochemistry and radiometric ages have been employed to re-evaluate the Late Carboniferous Tharandt Forest caldera (TFC) and the co-genetic Niederbobritzsch granite (NBG) in the eastern Erzgebirge near Dresden, Germany. The c. 52 km2 TFC harbours strongly welded ignimbrites with a preserved minimum thickness of 550 m. Composition of initial fallout tephra at the base of the TFC fill, comprising lithics of rhyolitic and basic lava, and of silica-rich pyroclastic rocks, suggests a bimodal volcanic activity in the area prior to the climactic TFC eruption. The lower part of the TFC fill comprises quartz-poor ignimbrites, overlain by quartz-rich ignimbrites, apparently without a depositional break. Landslides originating from the collapse collar of the caldera plunged into the still hot TFC fill producing monolithic gneiss mesobreccia with clasts ≤ 1 m in a pyroclastic matrix. Aphanitic and porphyritic rhyolitic magma formed ring- and radial dykes, and subvolcanic bodies in the centre of TFC. Whole rock geochemical data indicate a high silica (most samples have 〉 73 wt% SiO2) rhyolitic composition of the TFC magma, and a similar granodiorite–granitic composition for the NBG. Based on drillings and caldera extent, a minimum volume of 22 km3 of TFC fill is preserved, the original fill is assumed at about 33 km3. This estimate translates into a denudation of at least c. 210 m during Late Paleozoic to pre-Cenomanian. Telescopic subsidence of the TFC took place in two, perhaps three stages. A possible TFC outflow facies has been completely eroded and distal TFC tuff has not been recognized in neighboring basins. New CA-ID-TIMS measurements on two TFC samples gave mean zircon ages of 313.4 ± 0.4 Ma and 311.9 ± 0.4 Ma; two samples from NBG resulted in 318.2 ± 0.5 Ma and 319.5 ± 0.4 Ma. In addition, for one sample of the ring dyke an age of ca. 314.5 ± 0.5 Ma has been obtained. These ages, together with field relations, allow for a model of a long-standing evolution of an upper crustal magmatic system (~ 5 Ma?), where pulses of magmatic injection and crustal doming alternate with magmatic quietness and erosion. Together with the Altenberg–Teplice Volcanic Complex, located some 10 km to the southeast, the TFC–NBG Complex represents an early post-Variscan magmatic activity in central Europe.
    Description: Technische Universität Bergakademie Freiberg (3135)
    Keywords: ddc:551 ; Single phase caldera evolution ; Caldera wall landslides ; Freiberg gneiss dome ; CA-ID-TIMS zircon dating
    Language: English
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    Local radon flux maxima in the quaternary sediments of Schleswig–Holstein (Germany) (2021)
    Springer Berlin Heidelberg
    Details
    Publication Date: 2023-08-17
    Description: This paper presents radon flux profiles from four regions in Schleswig–Holstein (Northern Germany). Three of these regions are located over deep-rooted tectonic faults or salt diapirs and one is in an area without any tectonic or halokinetic activity, but with steep topography. Contrary to recently published studies on spatial patterns of soil radon gas concentration we measured flux of radon from soil into the atmosphere. All radon devices of each profile were deployed simultaneously to avoid inconsistencies due to strong diurnal variations of radon exhalation. To compare data from different seasons, values had to be normalized. Observed radon flux patterns are apparently related to the mineralogical composition of the Quaternary strata (particularly to the abundance of reddish granite and porphyry), and its grain size (with a flux maximum in well-sorted sand/silt). Minimum radon flux occurs above non-permeable, clay-rich soil layers. Small amounts of water content in the pore space increase radon flux, whereas excessive water content lessens it. Peak flux values, however, are observed over a deep-rooted fault system on the eastern side of Lake Plön, i.e., at the boundary of the Eastholstein Platform and the Eastholstein Trough. Furthermore, high radon flux values are observed in two regions associated with salt diapirism and near-surface halokinetic faults. These regions show frequent local radon flux maxima, which indicate that the uppermost strata above salt diapirs are very inhomogeneous. Deep-rooted increased permeability (effective radon flux depth) or just the boundaries between permeable and impermeable strata appear to concentrate radon flux. In summary, our radon flux profiles are in accordance with the published evidence of low radon concentrations in the “normal” soils of Schleswig–Holstein. However, very high values of radon flux are likely to occur at distinct locations near salt diapirism at depth, boundaries between permeable and impermeable strata, and finally at the tectonically active flanks of the North German Basin.
    Description: Bundesministerium für Wirtschaft und Energie http://dx.doi.org/10.13039/501100006360
    Description: Johannes Gutenberg-Universität Mainz (1030)
    Keywords: ddc:551 ; Radon flux ; Local radon flux maxima ; Permeability ; Quaternary sediments ; Salt tectonics ; Schleswig–Holstein
    Language: English
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    The Toba supervolcano eruption caused severe tropical stratospheric ozone depletion (2021)
    Nature Publishing Group UK
    Details
    Publication Date: 2023-09-12
    Description: Supervolcano eruptions have occurred throughout Earth’s history and have major environmental impacts. These impacts are mostly associated with the attenuation of visible sunlight by stratospheric sulfate aerosols, which causes cooling and deceleration of the water cycle. Supereruptions have been assumed to cause so-called volcanic winters that act as primary evolutionary factors through ecosystem disruption and famine, however, winter conditions alone may not be sufficient to cause such disruption. Here we use Earth system model simulations to show that stratospheric sulfur emissions from the Toba supereruption 74,000 years ago caused severe stratospheric ozone loss through a radiation attenuation mechanism that only moderately depends on the emission magnitude. The Toba plume strongly inhibited oxygen photolysis, suppressing ozone formation in the tropics, where exceptionally depleted ozone conditions persisted for over a year. This effect, when combined with volcanic winter in the extra-tropics, can account for the impacts of supereruptions on ecosystems and humanity.
    Description: Stratospheric sulfur emissions from the Toba supereruption about 74,000 years ago suppressed ozone formation which caused severe tropical ozone layer depletion and enhanced solar ultraviolet radiation stress, according to Earth system model simulations.
    Description: King Abdullah University of Science and Technology (KAUST) https://doi.org/10.13039/501100004052
    Description: http://hdl.handle.net/10754/667404
    Description: https://github.com/SeregaOsipov/NASA-GISS-ModelE/releases/tag/toba_o3
    Description: https://simplex.giss.nasa.gov/snapshots/
    Keywords: ddc:551 ; Atmospheric chemistry ; Natural hazards ; Palaeoclimate ; Volcanology
    Language: English
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    Late Oligocene—Early Miocene shortening in the Thrace Basin, northern Aegean (2021)
    Springer Berlin Heidelberg
    Details
    Publication Date: 2023-07-20
    Description: Late Cenozoic was a period of large-scale extension in the Aegean. The extension is mainly recorded in the metamorphic core complexes with little data from the sedimentary sequences. The exception is the Thrace Basin in the northern Aegean, which has a continuous record of Middle Eocene to Oligocene marine sedimentation. In the Thrace Basin, the Late Oligocene–Early Miocene was characterized by north-northwest (N25°W) shortening leading to the termination of sedimentation and formation of large-scale folds. We studied the stratigraphy and structure of one of these folds, the Korudağ anticline. The Korudağ anticline has formed in the uppermost Eocene–Lower Oligocene siliciclastic turbidites with Early Oligocene (31.6 Ma zircon U–Pb age) acidic tuff beds. The turbidites are underlain by a thin sequence of Upper Eocene pelagic limestone. The Korudağ anticline is an east-northeast (N65°E) trending fault-propagation fold, 9 km wide and 22 km long and with a subhorizontal fold axis. It is asymmetric with shallowly-dipping northern and steeply-dipping southern limbs. Its geometry indicates about 1 km of shortening in a N25°W direction. The folded strata are unconformably overlain by Middle Miocene continental sandstones, which constrain the age of folding. The Korudağ anticline and other large folds in the Thrace Basin predate the inception of the North Anatolian Fault (NAF) by at least 12 myr. The Late Oligocene–Early Miocene (28–17 Ma) shortening in the Thrace Basin and elsewhere in the Balkans forms an interlude between two extensional periods, and is probably linked to changes in the subduction dynamics along the Hellenic trench.
    Description: TÜBİTAK
    Description: İTÜ-BAP
    Description: TÜBA
    Description: Freie Universität Berlin (1008)
    Keywords: ddc:551 ; Thrace Basin ; Shortening ; Oligocene ; Miocene ; Aegean
    Language: English
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    The birth of the Alps: Ediacaran to Paleozoic accretionary processes and crustal growth along the northern Gondwana margin (2021)
    Siegesmund, S. ; Oriolo, S. ; Schulz, B. ; [et al.]
    Springer Berlin Heidelberg
    Details
    Publication Date: 2023-07-20
    Description: New whole-rock geochemical and coupled U–Pb and Lu–Hf LA-ICP-MS zircon data of metasedimentary rocks of the Austroalpine, South Alpine and Penninic basement domains are presented, to disentangle the pre-Variscan tectonic evolution of the proto-Alps. The studied units seem to record distinct stages of protracted Late Ediacaran to Carboniferous tectonosedimentary processes prior to the Variscan collision. In the case of Austroalpine and South Alpine units, nevertheless, no major differences in terms of provenance are observed, since most detrital zircon samples are characterized by a major Pan-African peak. Their detrital zircon spectra record a provenance from the northeastern Saharan Metacraton and the Sinai basement at the northern Arabian-Nubian Shield, being thus located along the eastern Early Paleozoic northern Gondwana margin, whereas sources located further west are inferred for the Penninic Unit, which might have been placed close to the Moldanubian Unit of the Bohemian Massif. In any case, it is thus clear that the Alpine basement remained in a close position to the Gondwana mainland at least during the Early Paleozoic. The Late Ediacaran to Silurian tectonic evolution, which includes Cadomian and Cenerian tectonometamorphic and magmatic processes, seem thus to record a continuum related to a retreating-mode accretionary orogen, with diachronous back-arc basin opening and possibly discrete compressional/transpressional pulses linked to changes in subduction zone dynamics. On the other hand, it is inferred that the Alpine basement essentially comprises Pan-African metasedimentary and subordinate metaigneous rocks, possibly with very few Early Neoproterozoic relics. This basement was significantly reworked during the protracted Paleozoic orogenic evolution, due to anatexis and/or assimilation by mantle-derived juvenile magmatism.
    Description: Georg-August-Universität Göttingen (1018)
    Keywords: ddc:551 ; Alpine basement ; Cadomian orogeny ; Cenerian orogeny ; Retreating-mode accretionary orogen ; Sedimentary provenance ; Detrital zircons
    Language: English
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    Age and origin of groundwater resources in the Ararat Valley, Armenia: a baseline study applying hydrogeochemistry and environmental tracers (2021)
    Schubert, Michael ; Michelsen, Nils ; Schmidt, Axel ; [et al.]
    Springer Berlin Heidelberg
    Details
    Publication Date: 2023-08-08
    Description: Within the Ararat Valley (Armenia), a continuously growing water demand (for irrigation and fish farming) and a simultaneous decline in groundwater recharge (due to climate change) result in increasing stress on the local groundwater resources. This detrimental development is reflected by groundwater-level drops and an associated reduction of the area with artesian conditions in the valley centre. This situation calls for increasing efforts aimed at more sustainable water resources management. The aim of this baseline study was the collection of data that allows for study on the origin and age distribution of the Ararat Valley groundwater based on environmental tracers, namely stable (δ〈sup〉2〈/sup〉H, δ〈sup〉18〈/sup〉O) and radioactive (〈sup〉35〈/sup〉S, 〈sup〉3〈/sup〉H) isotopes, as well as physical-chemical indicators. The results show that the Ararat Valley receives modern recharge, despite its (semi-)arid climate. While subannual groundwater residence times could be disproved (〈sup〉35〈/sup〉S), the detected 〈sup〉3〈/sup〉H pattern suggests groundwater ages of several decades, with the oldest waters being recharged around 60 years ago. The differing groundwater ages are reflected by varying scatter of stable isotope and hydrochemical signatures. The presence of young groundwater (i.e., younger that the 1970s), some containing nitrate, indicates groundwater vulnerability and underscores the importance of increased efforts to achieve sustainable management of this natural resource. Since stable isotope signatures indicate the recharge areas to be located in the mountains surrounding the valley, these efforts must not be limited to the central part of the valley where most of the abstraction wells are located.
    Description: Technische Universität Darmstadt (3139)
    Keywords: ddc:551 ; Groundwater residence time ; Tritium ; Radiosulphur ; Stable isotopes ; Armenia
    Language: English
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    Implications for sedimentary transport processes in southwestern Africa: a combined zircon morphology and age study including extensive geochronology databases (2021)
    Gärtner, Andreas ; Hofmann, Mandy ; Zieger, Johannes ; [et al.]
    Springer Berlin Heidelberg
    Details
    Publication Date: 2023-07-27
    Description: Extensive morphological and age studies on more than 4600 detrital zircon grains recovered from modern sands of Namibia reveal complex mechanisms of sediment transport. These data are further supplemented by a zircon age database containing more than 100,000 single grain analyses from the entire southern Africa and allow for hypothesising of a large Southern Namibian Sediment Vortex located between the Damara Orogen and the Orange River in southern Namibia. The results of this study also allow assuming a modified model of the Orange River sand highway, whose origin is likely located further south than previously expected. Moreover, studied samples from other parts of Namibia give first insights into sediment movements towards the interior of the continent and highlight the potential impact of very little spatial variations of erosion rates. Finally, this study points out the huge potential of detrital zircon morphology and large geo-databases as an easy-to-use additional tool for provenance analysis.
    Description: deutsche forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: Senckenberg Naturhistorische Sammlungen Dresden (3507)
    Keywords: ddc:551 ; Namibia ; Zircon ; Mineral morphology ; Sediment transport ; Geochronology ; Database
    Language: English
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    New constraints on the exhumation history of the western Tauern Window (European Alps) from thermochronology, thermokinematic modeling, and topographic analysis (2021)
    Springer Berlin Heidelberg
    Details
    Publication Date: 2023-07-27
    Description: The Brenner normal fault bounds the Tauern Window to the west and accommodated a significant portion of the orogen-parallel extension in the Eastern Alps. Here, we use zircon (U–Th)/He, apatite fission track, and apatite (U–Th)/He dating, thermokinematic modeling, and a topographic analysis to constrain the exhumation history of the western Tauern Window in the footwall of the Brenner fault. ZHe ages from an E–W profile (parallel to the slip direction of the fault) decrease westwards from ~ 11 to ~ 8 Ma and suggest a fault-slip rate of 3.9 ± 0.9 km/Myr, whereas AFT and AHe ages show no spatial trends. ZHe and AFT ages from an elevation profile indicate apparent exhumation rates of 1.1 ± 0.7 and 1.0 ± 1.3 km/Myr, respectively, whereas the AHe ages are again spatially invariant. Most of the thermochronological ages are well predicted by a thermokinematic model with a normal fault that slips at a rate of 4.2 km/Myr between ~ 19 and ~ 9 Ma and produces 35 ± 10 km of extension. The modeling reveals that the spatially invariant AHe ages are caused by heat advection due to faulting and posttectonic thermal relaxation. The enigmatic increase of K–Ar phengite and biotite ages towards the Brenner fault is caused by heat conduction from the hot footwall to the cooler hanging wall. Topographic profiles across an N–S valley in the fault footwall indicate 1000 ± 300 m of erosion after faulting ceased, which agrees with the results of our thermokinematic model. Valley incision explains why the Brenner fault is located on the western valley shoulder and not at the valley bottom. We conclude that the ability of thermokinematic models to quantify heat transfer by rock advection and conduction is crucial for interpreting cooling ages from extensional fault systems.
    Description: Westfälische Wilhelms-Universität Münster (1056)
    Description: https://github.com/jeanbraun
    Keywords: ddc:551 ; European Alps ; Tauern Window ; Thermochronology ; Thermokinematic modeling
    Language: English
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    Two-phase late Paleozoic magmatism (~ 313–312 and ~ 299–298 Ma) in the Lusatian Block and its relation to large scale NW striking fault zones: evidence from zircon U–Pb CA–ID–TIMS geochronology, bulk rock- and zircon chemistry (2021)
    Springer Berlin Heidelberg
    Details
    Publication Date: 2023-07-21
    Description: Late Paleozoic (Variscan) magmatism is widespread in Central Europe. The Lusatian Block is located in the NE Bohemian Massif and it is part of the Saxothuringian Zone of the Variscan orogen. It is bordered by two major NW-trending shear zones, the Intra-Sudetic Fault Zone towards NE and the Elbe Fault Zone towards SW. The scarce Variscan igneous rocks of the Lusatian Block are situated close to these faults. We investigated 19 samples from Variscan plutonic and volcanic rocks of the Lusatian Block, considering all petrological varieties (biotite-bearing granites from the Koenigshain and Stolpen plutons, amphibole-bearing granites from three boreholes, several volcanic dykes, and two volcanites from the intramontane Weissig basin). We applied whole-rock geochemistry (18 samples) and zircon evaporation dating (19 samples). From the evaporation data, we selected six representative samples for additional zircon SHRIMP and CA–ID–TIMS dating. For the Koenigshain pluton, possible protoliths were identified using whole-rock Nd-isotopes, and zircon Hf- and O-isotopes. The new age data allow a subdivision of Variscan igneous rocks in the Lusatian Block into two distinct magmatic episodes. The spatial relation of the two age groups to either the Elbe Fault Zone (298–299 Ma) or the Intra-Sudetic Fault Zone (312–313 Ma) together with reports on the fault-bound character of the dated intrusions suggests an interpretation as two major post-collisional faulting episodes. This assumption of two distinct magmatic periods is confirmed by a compilation of recently published zircon U–Pb CA–ID–TIMS data on further Variscan igneous rocks from the Saxothuringian Zone. New geochemical data allow us to exclude a dominant sedimentary protolith for the Koenigshain pluton as supposed by previous investigations. This conclusion is mainly based on new O- and Hf-isotope data on zircon and the scarcity of inherited zircons. Instead, acid or intermediate igneous rocks are supposed as the main source for these I-type granitoids from the Koenigshain pluton.
    Description: Technische Universität Bergakademie Freiberg (3135)
    Keywords: ddc:551 ; Geochronology ; Zircon ; Variscan granites ; Lusatian block
    Language: English
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    Soil erosion and sediment transport modelling using hydrological models and remote sensing techniques in Wadi Billi, Egypt (2021)
    Springer International Publishing
    Details
    Publication Date: 2024-02-14
    Description: Modelling soil erosion and sediment transport are vital to assess the impact of the flash floods. However, limited research works have studied sediment transport, especially in Egypt. This paper employs the HEC-HMS lumped hydrological model to predict the sediment load due to the flood event of 9th March 2014 in Wadi Billi, Egypt. The Modified USLE model has been used to calculate the total upland erosion, while Laursen-Copeland has been used to simulate load streams’ sediment transport potential. The Normalized Difference Vegetation Index (NDVI) has been applied over Landsat 8 image captured on 20th February 2014 using ArcMap 10.5 to determine the vegetation cover based on its spectral footprint. The resulted sedigraph showed accumulation of more than five thousand tons of sediments at the Wadi’s outlet. The results are crucial to design a suitable stormwater management system to protect the downstream urban area and to use flood water for groundwater recharge.
    Description: Technische Universität Berlin (3136)
    Description: https://www.hec.usace.army.mil/software/hec-hms/
    Keywords: ddc:551 ; MUSLE model ; HEC-HMS ; Wadi system ; Remote sensing ; Sedigraph ; Egypt
    Language: English
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    Black Sea hydroclimate and coupled hydrology was strongly controlled by high-latitude glacial climate dynamics (2021)
    Nature Publishing Group UK
    Details
    Publication Date: 2023-09-14
    Description: Abstract The Black Sea experienced pronounced millennial-scale changes in temperature and rainfall during the last glacial coinciding with Dansgaard-Oeschger cycles. However, little is known regarding the amount and sources of freshwater reaching this inland basin. Here, we present detailed ostracod δ〈sup〉18〈/sup〉O data from the glacial Black Sea showing subdued Dansgaard-Oeschger cyclicity and four prominent longer-term saw-tooth shaped Bond-like cycles. We propose that the δ〈sup〉18〈/sup〉Oostracods signature primarily reflects changes in the atmospheric circulation in response to the waxing and waning Eurasian Ice Sheet. The millennial-scale ice sheet variations likely resulted not only in latitudinal migrations of atmospheric frontal systems but also in shifts of dominant moisture sources for the Black Sea. Heavier isotopic precipitation arrived from the North Atlantic-Mediterranean realm during the warmer interstadials and lighter isotopic precipitation from the Eurasian continental interior during the colder stadials. The subdued Dansgaard-Oeschger variability likely reflects an integrated precipitation signal additionally affected by the long mixing times of the large Black Sea volume up to 1,500 years as suggested from hydrologic-isotope-balance modelling.
    Description: Moisture sources to the Black Sea changed in response to atmospheric frontal displacements driven by Eurasian Ice Sheet dynamics during the last glacial period, according to analyses of ostracod oxygen and strontium isotope data from Black Sea sediments.
    Description: Deutsche Forschungsgemeinschaft (German Research Foundation) https://doi.org/10.13039/501100001659
    Description: https://doi.org/10.5281/zenodo.4545579
    Keywords: ddc:551 ; paleohydrology ; palaeoclimate ; Black Sea ; Archangelsky Ridge ; isotope geochemistry ; Dansgaard-Oeschger cycles
    Language: English
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    Geological development of the Limpopo Shelf (southern Mozambique) during the last sealevel cycle (2020)
    Springer Berlin Heidelberg
    Details
    Publication Date: 2023-06-17
    Description: Paleo-shorelines on continental shelves give insights into the complex development of coastlines during sealevel cycles. This study investigates the geologic development of the Limpopo Shelf during the last sealevel cycle using multichannel seismic and acoustic datasets acquired on the shelf in front of the Limpopo River mouth. A detailed investigation of seismic facies, shelf bathymetry, and a correlation to sea level revealed the presence of numerous submerged shorelines on the shelf. These shorelines are characterized by distinct topographic ridges and are interpreted as coastal dune ridges that formed in periods of intermittent sealevel still-/slowstand during transgression. The shorelines are preserved due to periods of rapid sealevel rise (melt water pulses) that led to the overstepping of the dune ridges as well as due to early cementation of accumulated sediments that increased the erosive resistance of the ridges. The high along-shelf variability of the submerged dune ridges is interpreted as a result of pre-existing topography affecting shoreline positions during transgression. The pre-existing topography is controlled by the underlying sedimentary deposits that are linked to varying fluvial sediment input at different points on the shelf. The numerous prominent submerged dune ridges form barriers for the modern fluvial sediment from the Limpopo River and dam sediment on the inner shelf. They may also facilitate along-shelf current-induced sediment transport.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Keywords: ddc:551 ; Limpopo Shelf ; Geology
    Language: English
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    Slab break-offs in the Alpine subduction zone (2020)
    Springer Berlin Heidelberg
    Details
    Publication Date: 2023-06-17
    Description: After the onset of plate collision in the Alps, at 32–34 Ma, the deep structure of the orogen is inferred to have changed dramatically: European plate break-offs in various places of the Alpine arc, as well as a possible reversal of subduction polarity in the eastern Alps have been proposed. We review different high-resolution tomographic studies of the upper mantle and combine shear- and body-wave models to assess the most reliable geometries of the slabs. Several hypotheses for the tectonic evolution are presented and tested against the tomographic model interpretations and constraints from geologic and geodetic observations. We favor the interpretation of a recent European slab break-off under the western Alps. In the eastern Alps, we review three published scenarios for the subduction structure and propose a fourth one to reconcile the results from tomography and geology. We suggest that the fast slab anomalies are mainly due to European subduction; Adriatic subduction plays no or only a minor role along the Tauern window sections, possibly increasing towards the Dinarides. The apparent northward dip of the slab under the eastern Alps may be caused by imaging a combination of Adriatic slab, from the Dinaric subduction system, and a deeper lying European one, as well as by an overturned, retreating European slab.
    Description: GRNE graduate school
    Description: Deutsche Forschungsgemeinschaft (DE)
    Description: H2020 Marie Skłodowska-Curie Actions ()
    Description: http://www.orfeus-eu.org/eida
    Keywords: ddc:551 ; Seismic tomography ; Subduction slabs ; Alpine subduction system ; Slab break-off ; Slab polarity reversal
    Language: English
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    Mesozoic deposits of SW Gondwana (Namibia): unravelling Gondwanan sedimentary dispersion drivers by detrital zircon (2020)
    Zieger, J. ; Harazim, S. ; Hofmann, M. ; [et al.]
    Springer Berlin Heidelberg
    Details
    Publication Date: 2023-06-17
    Description: The Namibian Mesozoic successions may be remnant of a high dynamic sedimentary system that is characterized by multiple stages of sediment accumulation and erosion with contemporaneous homogenization starting with the deposition of the Permo-Carboniferous Dwyka Group strata and continues at least until the Lower Cretaceous. The Lower Cretaceous sedimentary system is interpreted to have involved at least an area covering the whole SW Gondwana, documenting the sedimentary history during the evolution from an ice house environment to an arid desert. To test the sediment homogenization hypothesis, we applied a combination of isotopic and morphometric data on detrital zircon grains, as well as whole-rock geochemical data of selected Mesozoic sandstones from Namibia. As a base for the interpretation of the detrital zircon age data we compiled a zircon age dataset with c. 44,000 analyses for the southern African region. All samples reveal a major detrital pan-African zircon age peak of c. 0.5–0.7 Ga sourced from the pan-African magmatic events occurring around the Kalahari Craton margin. The lowermost Triassic is characterized by the occurrence of additional Mesoproterozoic and Paleoproterozoic age peaks of c. 1.0–1.2 Ga and 1.8–2.0 Ga with a majority of zircon grains showing angular shapes. The protosource of these grains is interpreted to possibly be the Namaqua Metamorphic Complex and other Paleoproterozoic structural units deformed in course of the Namaqua orogeny. In contrast, other samples show a prominent Permo-Triassic age peak and completely rounded zircon grains, putatively derived from within the Gondwanides volcanic arc. The disparity in the zircon age pattern may point towards a change in provenance and also a change in the whole system of zircon recycling during the Mesozoic southern Gondwana. The Lower Triassic Neu Loore fm. are constrained to more local bedrock sources and short zircon transport distance. In contrast, zircon grains of the Middle Triassic Omingonde, the Jurassic Etjo und the Cretaceous Twyfelfontein formations are an expression for a major recycling and sediment homogenization system. The system was facilitated by an interplay between fluvial and eolian sedimentary transport systems.
    Keywords: ddc:551 ; Zircon U–pb ; Mesozoic ; Gondwana ; Karoo ; Namibia
    Language: English
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    Revisiting afro-alpine Lake Garba Guracha in the Bale Mountains of Ethiopia: rationale, chronology, geochemistry, and paleoenvironmental implications (2020)
    Springer Netherlands
    Details
    Publication Date: 2023-06-08
    Description: Previous paleolimnological studies demonstrated that the sediments of Garba Guracha, situated at 3950 m asl in the afro-alpine zone of the Bale Mountains of Ethiopia, provide a complete Late Glacial and Holocene paleoclimate and environmental archive. We revisited Garba Guracha in order to retrieve new sediment cores and to apply new environmental proxies, e.g. charcoal, diatoms, biomarkers, and stable isotopes. Our chronology is established using 210Pb dating and radiocarbon dating of bulk sedimentary organic matter, bulk n-alkanes, and charcoal. Although bedrock was not reached during coring, basal ages confirm that sedimentation started at the earliest ~ 16 cal kyr BP. The absence of a systematic age offset for the n-alkanes suggests that “pre-aging” is not a prominent issue in this lake, which is characterised by a very small afro-alpine catchment. X-ray fluorescence scans and total organic carbon contents show a prominent transition from minerogenic to organic-rich sediments around 11 cal kyr BP coinciding with the Holocene onset. While an unambiguous terrestrial versus aquatic source identification seems challenging, the n-alkane-based Paq proxy, TOC/N ratios, δ13C values, and the sugar biomarker patterns suggest a predominantly autochthonous organic matter source. Supraregional climate events, such as the African Humid Period, the Younger Dryas (YD), a 6.5 cal kyr BP short drying event, and the 4.2 cal kyr BP transition to overall drier climate are recorded in our archive. The Garba Guracha record suggests that northern hemisphere forcings played a role in the Eastern African highland paleoclimate.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Keywords: ddc:551 ; Paleolimnology ; Afro-alpine ; Radiocarbon dating ; XRF scanning ; Sedimentation rate ; Biomarkers
    Language: English
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    The 1994 Piedmont flood: an archetype of extreme precipitation events in Northern Italy (2020)
    Springer International Publishing
    Details
    Publication Date: 2023-06-08
    Description: Extreme precipitation events (EPEs) are meteorological phenomena of major concern for the densely populated regions of northern and central Italy. Although statistically rare, they tend to be recurrent in autumn and share common characteristics in the large-scale dynamical evolution responsible for their generation. Past studies on EPEs have reported, as the main triggering factor, a meridionally elongated upper-level trough embedded in an incoming Rossby wave packet. In this respect, we show how the meteorological conditions leading to the devastating 1994 Piedmont flood represent a typical flow evolution for this type of extreme events. Exploiting the systematic classification of EPEs recently published by the authors and taking advantage of a new observational dataset, this article revisits the role of the large-scale flow on this and similar cases of past EPEs.
    Description: Ludwig-Maximilians-Universität, Meteorologisches Institut, München, Germany
    Keywords: ddc:551 ; Extreme precipitation ; Floods ; Po river ; Atmospheric rivers ; Rossby wave packets ; Downstream development
    Language: English
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    Deglacial to Holocene variability in surface water characteristics and major floods in the Beaufort Sea (2020)
    Wu, Junjie ; Stein, Ruediger ; Fahl, Kirsten ; [et al.]
    Nature Publishing Group UK
    Details
    Publication Date: 2023-06-05
    Description: Surface water characteristics of the Beaufort Sea have global climate implications during the last deglaciation and the Holocene, as (1) sea ice is a critical component of the climate system and (2) Laurentide Ice Sheet meltwater discharges via the Mackenzie River to the Arctic Ocean and further, to its outflow near the deep-water source area of the Atlantic Meridional Overturning Circulation. Here we present high-resolution biomarker records from the southern Beaufort Sea. Multi-proxy biomarker reconstruction suggests that the southern Beaufort Sea was nearly ice-free during the deglacial to Holocene transition, and a seasonal sea-ice cover developed during the mid-late Holocene. Superimposed on the long-term change, two events of high sediment flux were documented at ca. 13 and 11 kyr BP, respectively. The first event can be attributed to the Younger Dryas flood and the second event is likely related to a second flood and/or coastal erosion.
    Description: The Beaufort Sea was nearly ice-free during the transition from the last deglacial to the Holocene, a period in which two episodes of high sediment flux suggest major glacial flood events, according to high-resolution multi-proxy biomarker records.
    Description: Alfred Wegener Institute Helmholtz Centre for Polar and Marine Research (Alfred-Wegener- Institute, Helmholtz Centre for Polar and Marine Research) https://doi.org/10.13039/501100003207
    Description: China Scholarship Council (CSC) https://doi.org/10.13039/501100004543
    Description: National Research Foundation of Korea (NRF) https://doi.org/10.13039/501100003725
    Keywords: ddc:551 ; Biogeochemistry ; Cryospheric science ; Palaeoceanography
    Language: English
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    Higher than present global mean sea level recorded by an Early Pliocene intertidal unit in Patagonia (Argentina) (2020)
    Rovere, Alessio ; Pappalardo, Marta ; Richiano, Sebastian ; [et al.]
    Nature Publishing Group UK
    Details
    Publication Date: 2023-06-05
    Description: Reconstructions of global mean sea level from earlier warm periods in Earth’s history can help constrain future projections of sea level rise. Here we report on the sedimentology and age of a geological unit in central Patagonia, Argentina, that we dated to the Early Pliocene (4.69–5.23 Ma, 2σ) with strontium isotope stratigraphy. The unit was interpreted as representative of an intertidal environment, and its elevation was measured with differential GPS at ca. 36 m above present-day sea level. Considering modern tidal ranges, it was possible to constrain paleo relative sea level within  ±2.7 m (1σ). We use glacial isostatic adjustment models and estimates of vertical land movement to calculate that, when the Camarones intertidal sequence was deposited, global mean sea level was 28.4 ± 11.7 m (1σ) above present. This estimate matches those derived from analogous Early Pliocene sea level proxies in the Mediterranean Sea and South Africa. Evidence from these three locations indicates that Early Pliocene sea level may have exceeded 20m above its present level. Such high global mean sea level values imply an ice-free Greenland, a significant melting of West Antarctica, and a contribution of marine-based sectors of East Antarctica to global mean sea level.
    Description: Global mean sea level was 28.4 ± 11.7 m higher than at present during the Early Pliocene, at atmospheric CO2 levels of no more than 450 ppm and temperatures of 2–3 ∘C above preindustrial levels, suggests a reconstruction from Patagonia.
    Description: National Science Foundation (NSF) https://doi.org/10.13039/100000001
    Keywords: ddc:551 ; Geomorphology ; Palaeoclimate
    Language: English
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    Return to rapid ice loss in Greenland and record loss in 2019 detected by the GRACE-FO satellites (2020)
    Sasgen, Ingo ; Wouters, Bert ; Gardner, Alex S. ; [et al.]
    Nature Publishing Group UK
    Details
    Publication Date: 2023-11-16
    Description: Between 2003-2016, the Greenland ice sheet (GrIS) was one of the largest contributors to sea level rise, as it lost about 255 Gt of ice per year. This mass loss slowed in 2017 and 2018 to about 100 Gt yr〈sup〉−1〈/sup〉. Here we examine further changes in rate of GrIS mass loss, by analyzing data from the GRACE-FO (Gravity Recovery and Climate Experiment – Follow On) satellite mission, launched in May 2018. Using simulations with regional climate models we show that the mass losses observed in 2017 and 2018 by the GRACE and GRACE-FO missions are lower than in any other two year period between 2003 and 2019, the combined period of the two missions. We find that this reduced ice loss results from two anomalous cold summers in western Greenland, compounded by snow-rich autumn and winter conditions in the east. For 2019, GRACE-FO reveals a return to high melt rates leading to a mass loss of 223 ± 12 Gt month〈sup〉−1〈/sup〉 during the month of July alone, and a record annual mass loss of 532 ± 58 Gt yr〈sup〉−1〈/sup〉.
    Description: Mass loss from the Greenland ice sheet returned to record levels in 2019, following unusually small loss in 2017-18, according to an analysis of satellite data from GRACE and its follow-on mission GRACE-FO.
    Description: Alfred Wegener Institute Helmholtz Centre for Polar and Marine Research (Alfred-Wegener- Institute, Helmholtz Centre for Polar and Marine Research) https://doi.org/10.13039/501100003207
    Description: Helmholtz Association https://doi.org/10.13039/501100009318
    Description: http://geoweb.princeton.edu/people/simons/software.html
    Keywords: ddc:551 ; Climate change ; Cryospheric science ; Greenland ; ice loss
    Language: English
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    The 12 December 2017 Baumgarten Gas Hub Explosion: A Case Study on Understanding the Occurrence of a Large Infrasound Azimuth Residual and a Lack of Seismic Observations (2020)
    Springer International Publishing
    Details
    Publication Date: 2023-11-27
    Description: The Baumgarten explosion occurred on 12 December 2017 at a gas storage site about 30 km east of Vienna, Austria. Acoustic arrivals from this accidental surface explosion were detected at dozens of stations of the AlpArray seismic network to distances up to 150 km, mainly in easterly directions. Thus it was expected that the Hungarian infrasound array PSZI located about 230 km to the east-southeast of Baumgarten would detect this acoustic wave as well. Standard progressive multichannel correlation processing and frequency-wavenumber analysis identified a signal emerging at 7:57:55 UTC from an azimuth of 296°–300° and with trace-velocity 〉 400 m/s. The extraordinarily high trace-velocity and excessive backazimuth residual, relative to the explosion site direction of 282°, however cast strong doubts on the arrival’s connection to the Baumgarten event. Accounting for the effect of non-planar geometry of the infrasound array results in a reduction of the azimuth residual by half. Additionally, 2D and 3D raytracing methods are used including the European Centre for Medium-Range Weather Forecasts (ECMWF) atmospheric model to further explain the remaining azimuth residual as well as to elucidate the large trace velocity estimates. The prevailing stratospheric winds in excess of 150 m/s are identified as the underlying cause. Including both factors the initial azimuth residual of up to 18° decreases to ~ 4°, allowing to associate the infrasound signal at PSZI with the Baumgarten event. Finally, the data from a seismic station at 30 km range is re-investigated for magnitude estimation. The local magnitude of ML 〈 1.0 explains well the scarcity of seismic observations within 50 km range, where three or four stations show signals, mainly consisting of Rg-type surface waves, but no body waves.
    Description: https://www.geofon.gfz-potsdam.de/doi/network/HN
    Description: https://doi.org/10.14470/UA114590
    Description: https://www.geofon.gfz-potsdam.de/doi/network/SK
    Description: https://www.ecmwf.int/
    Description: https://www.github.com/LANL-Seismoacoustics/GeoAc
    Keywords: ddc:551 ; Infrasound ; Baumgarten explosion ; array data processing ; backazimuth residual ; atmospheric sound propagation ; detection threshold
    Language: English
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    Geochemical/hydrochemical evaluation of the geothermal potential of the Lamongan volcanic field (Eastern Java, Indonesia) (2015)
    Details
    Publication Date: 2022-10-07
    Description: Magmatic settings involving active volcanism are potential locations for economic geothermal systems due to the occurrence of high temperature and steam pressures. Indonesia, located along active plate margins, hosts more than 100 volcanoes and, therefore, belongs to the regions with the greatest geothermal potential worldwide. However, tropical conditions and steep terrain reduce the spectrum of applicable exploration methods, in particular in remote areas. In a case study from the Lamongan volcanic field in East Java, we combine field-based data on the regional structural geology, elemental and isotopic composition of thermal waters, and the mineralogical and geochemical signatures of volcanic rocks in exploring hidden geothermal systems. Results suggest infiltration of groundwater at the volcanoes and faults. After infiltration, water is heated and reacts with rocks before rising to the surface. The existence of a potential heat source is petrologically and geophysically constrained to be an active shallow mafic-magma chamber, but its occurrence is not properly reflected in the composition of the collected warmed spring waters that are predominantly meteoric in origin. In conclusion, spring temperature and hydrochemistry alone may not always correctly reflect the deep geothermal potential of an area.
    Keywords: ddc:551
    Language: English
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    Thermal properties of gas hydrate bearing sediments and effects of phase transitions on the transport of heat deduced from temperature logging at Mallik, NWT, Canada (2005)
    GFZ, Helmholtz-Zentrum
    Details
    Publication Date: 2023-08-29
    Description: Detailed knowledge about the thermal properties of rocks containing gas hydrate is required in order to quantify processes involving the formation and decomposition of gas hydrate in nature. This work investigates the influence of methane hydrate on the transport of heat in hydrate-bearing rocks. Both the thermal conductivity of gashydrate bearing sediments and the thermal effects of phase transitions are analyzed. In the framework of the Mallik 2002 program three wells penetrating a continental gas hydrate occurrence under permafrost were successfully equipped with permanent fiberoptic distributed temperature sensing cables. Temperature data were collected over a period of 21 months after completion of the wells. The analysis of the disturbed well temperatures after drilling revealed a strong effect of phase transitions on temperature changes. For the first time, the effects of induced temperature changes within a gas hydrate deposit were monitored in-situ. The resulting temperature gradient anomalies could be successfully utilized to determine the base of the gas hydrate occurrences and the permafrost layer at about 1103-1104±3.5 m and 599-604±3.5 m below ground level respectively. At the end of the 21-month observation period, the well temperature returned close to equilibrium with the formation temperature. At the base of the gas hydrate occurrences a temperature of 12.3 ◦C was measured, which is about 0.7 K below the stability temperature predicted by thermodynamic calculations considering a pressure gradient of 10.12 kPa m〈sup〉−1〈/sup〉 and a sea-water salinity of 35 ppt. Under the stated conditions, the base of the stability zone of methane hydrate at Mallik would lie at about 1140 m below ground level. Thermal conductivity profiles were calculated from the geothermal data as well as from a petrophysical model derived from the available logging data and application of mixing-law models. The results indicate, that variations of thermal conductivity are mainly lithologically controlled with a minor influence from hydrate saturation. The results of the geometric mean model showed the best agreement to the thermal conductivity profiles derived from geothermal data. Average thermal conductivity values of the hydrate-bearing intervals range between 2.35 W m〈sup〉−1〈/sup〉 K〈sup〉−1〈/sup〉 and 2.77 W m〈sup〉−1〈/sup〉 K〈sup〉−1〈/sup〉 . A simplified numerical model of conductive heat flow was set up in order to assess the temperature effect of phase transitions within the gas hydrate bearing strata. Within the model the mobilization of latent heat during the phase transition was considered (enthalpy method), taking into account the stability conditions for methane hydrate at Mallik (pressure, temperature, pore fluid and gas phase composition) as well as effects of hydrate decomposition on the thermal rock properties. The modelling results indicate, that the regeneration of hydrate after the recovery of stability conditions is inhibited.
    Description: thesis
    Keywords: ddc:551 ; gas hydrate
    Language: English
    Type: doc-type:book , publishedVersion
    Format: application/pdf
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