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  • Physics  (2,679)
  • AERODYNAMICS
  • Fisheries
  • 2000-2004  (48)
  • 1980-1984  (4,751)
  • 1
    Publication Date: 2004-11-13
    Description: The multibillion-dollar trade in bushmeat is among the most immediate threats to the persistence of tropical vertebrates, but our understanding of its underlying drivers and effects on human welfare is limited by a lack of empirical data. We used 30 years of data from Ghana to link mammal declines to the bushmeat trade and to spatial and temporal changes in the availability of fish. We show that years of poor fish supply coincided with increased hunting in nature reserves and sharp declines in biomass of 41 wildlife species. Local market data provide evidence of a direct link between fish supply and subsequent bushmeat demand in villages and show bushmeat's role as a dietary staple in the region. Our results emphasize the urgent need to develop cheap protein alternatives to bushmeat and to improve fisheries management by foreign and domestic fleets to avert extinctions of tropical wildlife.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Brashares, Justin S -- Arcese, Peter -- Sam, Moses K -- Coppolillo, Peter B -- Sinclair, A R E -- Balmford, Andrew -- New York, N.Y. -- Science. 2004 Nov 12;306(5699):1180-3.〈br /〉〈span class="detail_caption"〉Author address: 〈/span〉Conservation Biology Group, Department of Zoology, University of Cambridge, Cambridge CB2 3EJ, UK. brashares@nature.berkeley.edu〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/15539602" target="_blank"〉PubMed〈/a〉
    Keywords: Agriculture ; Animals ; *Animals, Wild ; Biodiversity ; Biomass ; Commerce ; Conservation of Natural Resources ; Fisheries ; *Fishes ; *Food Supply ; Ghana ; Humans ; *Mammals ; *Meat ; Population Density ; Population Dynamics
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 2
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    American Association for the Advancement of Science (AAAS)
    Publication Date: 2004-07-03
    Description: 〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Stec, Boguslaw -- New York, N.Y. -- Science. 2004 Jul 2;305(5680):41-4; author reply 41-4.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/15232089" target="_blank"〉PubMed〈/a〉
    Keywords: Adaptation, Biological ; *Cells ; *Life ; Physical Phenomena ; Physics ; Proteins/*chemistry ; Selection, Genetic ; Thermodynamics
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 3
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    American Association for the Advancement of Science (AAAS)
    Publication Date: 2004-08-31
    Description: 〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Grimm, David -- New York, N.Y. -- Science. 2004 Aug 27;305(5688):1235.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/15333821" target="_blank"〉PubMed〈/a〉
    Keywords: Animals ; Biodiversity ; *Ecosystem ; Fisheries ; *Fishes ; Humans ; Population Density ; *Recreation ; United States
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 4
    Publication Date: 2004-09-14
    Description: It is now widely accepted that global warming is occurring, yet its effects on the world's largest ecosystem, the marine pelagic realm, are largely unknown. We show that sea surface warming in the Northeast Atlantic is accompanied by increasing phytoplankton abundance in cooler regions and decreasing phytoplankton abundance in warmer regions. This impact propagates up the food web (bottom-up control) through copepod herbivores to zooplankton carnivores because of tight trophic coupling. Future warming is therefore likely to alter the spatial distribution of primary and secondary pelagic production, affecting ecosystem services and placing additional stress on already-depleted fish and mammal populations.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Richardson, Anthony J -- Schoeman, David S -- New York, N.Y. -- Science. 2004 Sep 10;305(5690):1609-12.〈br /〉〈span class="detail_caption"〉Author address: 〈/span〉Sir Alister Hardy Foundation for Ocean Science, The Laboratory, Citadel Hill, Plymouth, PL1 2PB, UK. anr@sahfos.ac.uk〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/15361622" target="_blank"〉PubMed〈/a〉
    Keywords: Animals ; Atlantic Ocean ; *Climate ; Copepoda/*growth & development ; *Ecosystem ; Fisheries ; Fishes ; *Food Chain ; Greenhouse Effect ; Meta-Analysis as Topic ; Phytoplankton/*growth & development ; Population Dynamics ; Seawater ; Temperature ; Zooplankton/*growth & development
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 5
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    American Association for the Advancement of Science (AAAS)
    Publication Date: 2004-10-09
    Description: Space used by animals increases with increasing body size. Energy requirements alone can explain how population density decreases, but not the steep rate at which home range area increases. We present a general mechanistic model that predicts the frequency of interaction, spatial overlap, and loss of resources to neighbors. Extensive empirical evidence supports the model, demonstrating that spatial constraints on defense cause exclusivity of home range use to decrease with increasing body size. In large mammals, over 90% of available resources may be lost to neighbors. Our model offers a general framework to understand animal space use and sociality.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Jetz, Walter -- Carbone, Chris -- Fulford, Jenny -- Brown, James H -- New York, N.Y. -- Science. 2004 Oct 8;306(5694):266-8.〈br /〉〈span class="detail_caption"〉Author address: 〈/span〉Department of Ecology and Evolutionary Biology, Princeton University, Princeton, NJ 08544-1003, USA. wjetz@princeton.edu〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/15472074" target="_blank"〉PubMed〈/a〉
    Keywords: Animals ; Body Constitution ; Body Weight ; Conservation of Natural Resources ; *Ecosystem ; Energy Metabolism ; Environment ; *Homing Behavior ; *Mammals/anatomy & histology/metabolism ; Mathematics ; *Models, Biological ; Physical Phenomena ; Physics ; Population Density
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 6
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    American Association for the Advancement of Science (AAAS)
    Publication Date: 2004-08-25
    Description: 〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Proffitt, Fiona -- New York, N.Y. -- Science. 2004 Aug 20;305(5687):1090.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/15326320" target="_blank"〉PubMed〈/a〉
    Keywords: Animals ; Birds/*physiology ; *Ecosystem ; *Eels ; Fisheries ; Food Chain ; North Sea ; Plankton ; Population Density ; *Reproduction ; Scotland ; Seawater ; Temperature
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 7
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    American Association for the Advancement of Science (AAAS)
    Publication Date: 2004-12-18
    Description: 〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉New York, N.Y. -- Science. 2004 Dec 17;306(5704):2012.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/15604367" target="_blank"〉PubMed〈/a〉
    Keywords: Access to Information ; Animals ; Biological Warfare ; Ecosystem ; Genome ; Information Dissemination ; Mars ; Physical Phenomena ; Physics ; Publishing ; *Science ; Security Measures
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 8
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    American Association for the Advancement of Science (AAAS)
    Publication Date: 2004-12-18
    Description: 〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉New York, N.Y. -- Science. 2004 Dec 17;306(5704):2013-7.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/15604368" target="_blank"〉PubMed〈/a〉
    Keywords: Animals ; Biodiversity ; Biological Evolution ; Cloning, Organism ; DNA, Intergenic ; Genome ; Hominidae/anatomy & histology ; Humans ; Physical Phenomena ; Physics ; Public Health ; *Science ; Water/chemistry
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 9
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    American Association for the Advancement of Science (AAAS)
    Publication Date: 2004-06-26
    Description: 〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Wright, Bruce A -- Okey, Thomas A -- New York, N.Y. -- Science. 2004 Jun 25;304(5679):1903.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/15218125" target="_blank"〉PubMed〈/a〉
    Keywords: Animals ; *Conservation of Natural Resources ; *Ecosystem ; *Environment ; Fisheries ; Humans ; Information Dissemination ; Population Growth ; Public Policy
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    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 10
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    American Association for the Advancement of Science (AAAS)
    Publication Date: 2004-08-25
    Description: 〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Allison, Edward H -- Seeley, Janet A -- New York, N.Y. -- Science. 2004 Aug 20;305(5687):1104.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/15326332" target="_blank"〉PubMed〈/a〉
    Keywords: Asia/epidemiology ; Female ; Fisheries ; HIV Infections/*epidemiology/transmission ; Humans ; Male ; Occupations ; Prevalence ; Sexual Partners ; *Transients and Migrants
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    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 11
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    American Association for the Advancement of Science (AAAS)
    Publication Date: 2004-08-03
    Description: 〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Cho, Adrian -- New York, N.Y. -- Science. 2004 Jul 30;305(5684):643-4.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/15286364" target="_blank"〉PubMed〈/a〉
    Keywords: *Biomechanical Phenomena ; *Engineering ; History, 20th Century ; History, 21st Century ; Humans ; Mathematics ; Mechanics ; Physics ; Research Support as Topic ; *Sports ; *Sports Equipment ; United States
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    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 12
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    American Association for the Advancement of Science (AAAS)
    Publication Date: 2004-05-29
    Description: 〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Malakoff, David -- New York, N.Y. -- Science. 2004 May 28;304(5675):1281.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/15166361" target="_blank"〉PubMed〈/a〉
    Keywords: Career Choice ; Emigration and Immigration ; History, 20th Century ; History, 21st Century ; India ; Physics ; Public Health ; United States
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    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 13
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    American Association for the Advancement of Science (AAAS)
    Publication Date: 2004-10-09
    Description: 〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Buskirk, Steven -- New York, N.Y. -- Science. 2004 Oct 8;306(5694):238-9.〈br /〉〈span class="detail_caption"〉Author address: 〈/span〉Department of Zoology and Physiology, University of Wyoming, Laramie, WY 82071, USA. marten@uwyo.edu〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/15472068" target="_blank"〉PubMed〈/a〉
    Keywords: Animals ; Body Constitution ; Body Weight ; *Ecosystem ; Energy Metabolism ; Environment ; *Homing Behavior ; *Mammals/anatomy & histology/metabolism ; Mathematics ; *Models, Biological ; Physical Phenomena ; Physics ; Population Density
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 14
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    American Association for the Advancement of Science (AAAS)
    Publication Date: 2004-07-27
    Description: 〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Rembold, Christopher M -- New York, N.Y. -- Science. 2004 Jul 23;305(5683):475; author reply 475.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/15273376" target="_blank"〉PubMed〈/a〉
    Keywords: Animals ; Coronary Artery Disease/mortality/*prevention & control ; *Diet ; Environmental Pollutants/toxicity ; Fatty Acids, Omega-3/*administration & dosage ; Fisheries ; *Food Contamination ; Humans ; Neoplasms/chemically induced/epidemiology ; Randomized Controlled Trials as Topic ; Risk Assessment ; *Salmon ; Toxicity Tests
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 15
    Publication Date: 2004-09-14
    Description: 〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Stokstad, Erik -- New York, N.Y. -- Science. 2004 Sep 10;305(5690):1548-9.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/15361593" target="_blank"〉PubMed〈/a〉
    Keywords: Animals ; Atlantic Ocean ; *Climate ; *Ecosystem ; Fisheries ; *Food Chain ; Phytoplankton/*growth & development ; Population Dynamics ; Seawater ; Temperature ; Zooplankton/*growth & development
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 16
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    American Association for the Advancement of Science (AAAS)
    Publication Date: 2004-01-01
    Description: 〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉New York, N.Y. -- Science. 2003 Dec 19;302(5653):2039-45.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/14700029" target="_blank"〉PubMed〈/a〉
    Keywords: Angiogenesis Inhibitors/therapeutic use ; Animals ; Astronomical Phenomena ; Astronomy ; Climate ; Germ Cells/cytology/physiology ; Humans ; Mental Disorders/etiology/genetics ; Neoplasms/blood supply/drug therapy ; Physical Phenomena ; Physics ; RNA, Antisense ; *Science/trends ; Stem Cells/physiology ; Y Chromosome/genetics
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 17
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    American Association for the Advancement of Science (AAAS)
    Publication Date: 2003-10-11
    Description: 〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Stone, Richard -- New York, N.Y. -- Science. 2003 Oct 10;302(5643):221-2.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/14551417" target="_blank"〉PubMed〈/a〉
    Keywords: Animals ; Ecosystem ; *Eels/growth & development/physiology ; Fisheries ; Fresh Water ; Oceans and Seas ; Population Density ; Reproduction ; Seawater
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 18
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    American Association for the Advancement of Science (AAAS)
    Publication Date: 2003-08-23
    Description: 〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Malakoff, David -- New York, N.Y. -- Science. 2003 Aug 22;301(5636):1034-7.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/12933987" target="_blank"〉PubMed〈/a〉
    Keywords: Animals ; *Anthozoa ; Atlantic Ocean ; Conservation of Natural Resources ; *Ecosystem ; Environment ; Fisheries ; *Fishes ; Geologic Sediments ; *Marine Biology ; Pacific Ocean ; *Seawater
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 19
    Publication Date: 2003-07-05
    Description: 〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Sanchirico, James N -- Stoffle, Richard -- Broad, Kenny -- Talaue-McManus, Liana -- New York, N.Y. -- Science. 2003 Jul 4;301(5629):47-9; author reply 47-9.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/12843376" target="_blank"〉PubMed〈/a〉
    Keywords: Animals ; California ; *Conservation of Natural Resources ; *Ecosystem ; Fisheries ; *Fishes ; Humans ; Seawater
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 20
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    American Association for the Advancement of Science (AAAS)
    Publication Date: 2003-07-12
    Description: 〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Vogel, Gretchen -- New York, N.Y. -- Science. 2003 Jul 11;301(5630):150.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/12855778" target="_blank"〉PubMed〈/a〉
    Keywords: *Biomedical Research ; Germany ; Neurosciences ; Physical Phenomena ; Physics ; Publishing ; Research/*standards ; Research Support as Topic ; *Scientific Misconduct
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    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 21
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    American Association for the Advancement of Science (AAAS)
    Publication Date: 2003-04-05
    Description: 〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Service, Robert F -- New York, N.Y. -- Science. 2003 Apr 4;300(5616):36-9.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/12677035" target="_blank"〉PubMed〈/a〉
    Keywords: Agriculture ; Animals ; California ; *Conservation of Natural Resources ; *Cypriniformes/physiology ; *Ecology ; Ecosystem ; Environment ; Fisheries ; *Fresh Water ; Government Agencies ; National Academy of Sciences (U.S.) ; *Oncorhynchus kisutch/physiology ; Oregon ; United States ; Water Movements
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    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 22
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    American Association for the Advancement of Science (AAAS)
    Publication Date: 2003-05-10
    Description: 〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Zimmer, Carl -- New York, N.Y. -- Science. 2003 May 9;300(5621):895.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/12738833" target="_blank"〉PubMed〈/a〉
    Keywords: Animals ; *Biological Evolution ; Breeding ; *Conservation of Natural Resources ; Environment ; Fisheries ; *Fishes/genetics/growth & development/physiology ; Plant Development ; Reproduction ; *Selection, Genetic ; Sexual Maturation
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    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 23
    Publication Date: 2003-11-15
    Description: 〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Malakoff, David -- Cho, Adrian -- New York, N.Y. -- Science. 2003 Nov 14;302(5648):1126-7.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/14615496" target="_blank"〉PubMed〈/a〉
    Keywords: Computers ; Facility Design and Construction ; Financing, Government ; Molecular Biology ; Nuclear Reactors ; Physical Phenomena ; Physics ; *Research Support as Topic ; United States ; *United States Government Agencies
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  • 24
    Publication Date: 2003-04-19
    Description: Using three-dimensional infrared high-speed video, we captured the wing and body kinematics of free-flying fruit flies as they performed rapid flight maneuvers. We then "replayed" the wing kinematics on a dynamically scaled robotic model to measure the aerodynamic forces produced by the wings. The results show that a fly generates rapid turns with surprisingly subtle modifications in wing motion, which nonetheless generate sufficient torque for the fly to rotate its body through each turn. The magnitude and time course of the torque and body motion during rapid turns indicate that inertia, not friction, dominates the flight dynamics of insects.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Fry, Steven N -- Sayaman, Rosalyn -- Dickinson, Michael H -- New York, N.Y. -- Science. 2003 Apr 18;300(5618):495-8.〈br /〉〈span class="detail_caption"〉Author address: 〈/span〉Institute of Neuroinformatics, University/ETH Zurich, Winterthurerstr. 190, CH-8057 Zurich, Switzerland.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/12702878" target="_blank"〉PubMed〈/a〉
    Keywords: Acceleration ; Animals ; Biomechanical Phenomena ; Body Constitution ; Drosophila melanogaster/anatomy & histology/*physiology ; Flight, Animal/*physiology ; Friction ; Mathematics ; Motion ; Movement ; Physical Phenomena ; Physics ; Robotics ; Rotation ; Torque ; Video Recording ; Wings, Animal/*physiology
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    American Association for the Advancement of Science (AAAS)
    Publication Date: 2003-07-26
    Description: 〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Couzin, Jennifer -- New York, N.Y. -- Science. 2003 Jul 25;301(5632):444.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/12881536" target="_blank"〉PubMed〈/a〉
    Keywords: *Biological Science Disciplines ; Budgets ; Financing, Government ; *National Institutes of Health (U.S.) ; *Natural Science Disciplines ; Physical Phenomena ; Physics ; *Research Support as Topic ; United States
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    Publication Date: 2003-08-30
    Description: 〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Webster, Paul -- New York, N.Y. -- Science. 2003 Aug 29;301(5637):1167.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/12947169" target="_blank"〉PubMed〈/a〉
    Keywords: Animals ; *Conservation of Natural Resources/economics ; *Ecosystem ; *Environment ; Financial Support ; Fisheries ; Fresh Water ; Pacific Ocean ; Russia ; *Salmon ; United Nations/economics
    Print ISSN: 0036-8075
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    In:  J. Geophys. Res., Amsterdam, Schweizerbart'sche Verlagsbuchhandlung, vol. 107, no. B10, pp. ECV 6-1-ECV 6-17, pp. 2223, (ISSN 0016-8548, ISBN 3-510-50045-8)
    Publication Date: 2002
    Description: We use laboratory experiments and numerical models to quantify the effects of dike interaction on the focusing of magma as it ascends in the upper mantle. Laboratory experiments involve injecting buoyant fluid into the base of a tank filled with solidified gelatin. When we initiate two dikes parallel to each other, but separated by a horizontal distance x, they tend to merge as they ascend. This behavior is also predicted by numerical models of two-dimensional dikes. The key parameters that control the maximum horizontal separation x c over which dikes will intersect are dike driving pressures, dike head lengths L (i.e., the length over which driving pressure is large), and the difference between the principal stresses of the remote stress field. When the remote differential stress is small compared to the dike driving pressure, two dikes of equal driving pressure and length will intersect over distances of x c ? L. This distance decreases with increasing remote differential stress. We quantify the effects on magma transport from a broad lateral distribution of magma using numerical simulations of multiple-dike interaction. When the average dike spacing prior to interaction is within ?3 L and remote differential stresses are insignificant, dike interaction can focus magma over horizontal distances many times L but at least ?6 L. Dike interaction can focus magma in the asthenosphere beneath mid-ocean ridges for low mantle viscosities (?10 19 Pa s) and if dikes initiate with average separations of a few hundred meters, or less. Such focusing is predicted to grow dikes of increasing magma flux approaching lateral separations of a kilometer.
    Keywords: Fluids ; Plate tectonics ; ascent ; sheeted ; dykes ; Modelling ; JGR ; 8434 ; Volcanology: ; Magma ; migration ; 8145 ; Tectonophysics: ; Physics ; of ; magma ; and ; magma ; bodies ; 8120 ; Dynamics ; of ; lithosphere ; and ; mantle--general ; 3035 ; Marine ; Geology ; and ; Geophysics: ; Midocean ; ridge ; processes
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    American Association for the Advancement of Science (AAAS)
    Publication Date: 2002-10-09
    Description: 〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Radny, Marian W -- New York, N.Y. -- Science. 2002 Oct 4;298(5591):59; author reply 59.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/12365438" target="_blank"〉PubMed〈/a〉
    Keywords: Animals ; Body Constitution ; Body Weight ; *Carnivora/anatomy & histology/metabolism ; *Ecosystem ; *Food ; Physical Phenomena ; Physics ; Population Density
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    American Association for the Advancement of Science (AAAS)
    Publication Date: 2002-08-07
    Description: 〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Ajayi, Thomas -- Sherman, Kenneth -- Tang, Qisheng -- New York, N.Y. -- Science. 2002 Aug 2;297(5582):772.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/12162321" target="_blank"〉PubMed〈/a〉
    Keywords: Biomass ; Conservation of Natural Resources/*economics/*methods/trends ; *Ecosystem ; Europe ; Fisheries ; International Cooperation ; *Marine Biology/economics/trends ; North America ; Water Pollution/prevention & control
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    American Association for the Advancement of Science (AAAS)
    Publication Date: 2002-03-30
    Description: Beyond molecular chemistry based on the covalent bond, supramolecular chemistry aims at developing highly complex chemical systems from components interacting through noncovalent intermolecular forces. Over the past quarter century, supramolecular chemistry has grown into a major field and has fueled numerous developments at the interfaces with biology and physics. Some of the conceptual advances and future challenges are profiled here.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Lehn, Jean-Marie -- New York, N.Y. -- Science. 2002 Mar 29;295(5564):2400-3.〈br /〉〈span class="detail_caption"〉Author address: 〈/span〉Institut de Science et d'Ingenierie Supramoleculaires (ISIS), Universite Louis Pasteur, 67000 Strasbourg, and College de France, 75005 Paris, France. lehn@chimie.u-strasbg.fr〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/11923524" target="_blank"〉PubMed〈/a〉
    Keywords: Biology ; Chemical Phenomena ; *Chemistry ; Chemistry, Physical ; Molecular Structure ; Nanotechnology ; Physical Phenomena ; Physicochemical Phenomena ; Physics ; *Polymers/chemistry
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  • 31
    Publication Date: 2002-12-10
    Description: There is debate concerning the most effective conservation of marine biodiversity, especially regarding the appropriate location, size, and connectivity of marine reserves. We describe a means of establishing marine reserve networks by using optimization algorithms and multiple levels of information on biodiversity, ecological processes (spawning, recruitment, and larval connectivity), and socioeconomic factors in the Gulf of California. A network covering 40% of rocky reef habitat can fulfill many conservation goals while reducing social conflict. This quantitative approach provides a powerful tool for decision-makers tasked with siting marine reserves.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Sala, Enric -- Aburto-Oropeza, Octavio -- Paredes, Gustavo -- Parra, Ivan -- Barrera, Juan C -- Dayton, Paul K -- New York, N.Y. -- Science. 2002 Dec 6;298(5600):1991-3.〈br /〉〈span class="detail_caption"〉Author address: 〈/span〉Center for Marine Biodiversity and Conservation, Scripps Institution of Oceanography, La Jolla, CA 92093, USA. esala@ucsd.edu〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/12471258" target="_blank"〉PubMed〈/a〉
    Keywords: Animals ; California ; Computer Simulation ; *Conservation of Natural Resources ; *Ecosystem ; Environment ; Fisheries ; Fishes ; Invertebrates ; *Models, Biological ; *Seawater
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    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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    Publication Date: 2001-08-18
    Description: 〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Magnuson, J J -- Safina, C -- Sissenwine, M P -- New York, N.Y. -- Science. 2001 Aug 17;293(5533):1267-8.〈br /〉〈span class="detail_caption"〉Author address: 〈/span〉Center for Limnology, University of Wisconsin, Madison, WI 53706, USA. jmagnuson@mhub.limnology.wisc.edu〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/11509715" target="_blank"〉PubMed〈/a〉
    Keywords: Animal Identification Systems ; Animals ; Atlantic Ocean ; *Behavior, Animal ; Body Temperature ; *Conservation of Natural Resources ; Diving ; *Ecosystem ; Fisheries ; Population Dynamics ; Reproduction ; Swimming ; Tuna/genetics/*physiology
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    American Association for the Advancement of Science (AAAS)
    Publication Date: 2001-03-20
    Description: 〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Malakoff, D -- New York, N.Y. -- Science. 2001 Jan 12;291(5502):227-9.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/11253825" target="_blank"〉PubMed〈/a〉
    Keywords: Animals ; Fisheries ; *Homing Behavior ; Isotopes ; Otolithic Membrane/*chemistry ; Perciformes/*physiology ; Population Dynamics ; Reproduction ; United States
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    American Association for the Advancement of Science (AAAS)
    Publication Date: 2001-02-24
    Description: 〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Collie, J -- Saila, S -- Walters, C -- Carpenter, S -- New York, N.Y. -- Science. 2000 Nov 3;290(5493):933-4.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/11184733" target="_blank"〉PubMed〈/a〉
    Keywords: Animals ; Conservation of Natural Resources ; *Ecosystem ; Fisheries ; Fresh Water ; Government Agencies ; Models, Biological ; Northwestern United States ; Population Dynamics ; *Salmon/physiology
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    American Association for the Advancement of Science (AAAS)
    Publication Date: 2001-06-09
    Description: A free-electron laser consists of an electron beam propagating through a periodic magnetic field. Today such lasers are used for research in materials science, chemical technology, biophysical science, medical applications, surface studies, and solid-state physics. Free-electron lasers with higher average power and shorter wavelengths are under development. Future applications range from industrial processing of materials to light sources for soft and hard x-rays.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉O'Shea, P G -- Freund, H P -- New York, N.Y. -- Science. 2001 Jun 8;292(5523):1853-8.〈br /〉〈span class="detail_caption"〉Author address: 〈/span〉Department of Electrical and Computer Engineering and Institute for Plasma Research, University of Maryland, College Park, MD 20742, USA.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/11397938" target="_blank"〉PubMed〈/a〉
    Keywords: Biochemical Phenomena ; Biochemistry ; Biological Science Disciplines ; Electromagnetic Fields ; Electrons ; Laser Therapy ; *Lasers ; Physical Phenomena ; Physics ; *Research
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    American Association for the Advancement of Science (AAAS)
    Publication Date: 2001-12-26
    Description: 〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉New York, N.Y. -- Science. 2001 Dec 21;294(5551):2443-7.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/11752538" target="_blank"〉PubMed〈/a〉
    Keywords: Animals ; Antineoplastic Agents/therapeutic use ; Axons/physiology ; Benzamides ; Carbon ; Climate ; Ecosystem ; Electronics ; Genome, Human ; Humans ; Imatinib Mesylate ; Leukemia, Myelogenous, Chronic, BCR-ABL Positive/drug therapy ; Physical Phenomena ; Physics ; Piperazines/therapeutic use ; Pyrimidines/therapeutic use ; Rna ; *Research ; *Science
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    American Association for the Advancement of Science (AAAS)
    Publication Date: 2001-07-28
    Description: 〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Zimmer, C -- New York, N.Y. -- Science. 2001 Jul 27;293(5530):627-8.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/11474097" target="_blank"〉PubMed〈/a〉
    Keywords: Animals ; *Cnidaria ; *Ecosystem ; Eutrophication ; Fisheries ; International Cooperation ; Israel ; Jordan ; Marine Biology ; Oceans and Seas ; Time Factors ; United States
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    American Association for the Advancement of Science (AAAS)
    Publication Date: 2001-06-16
    Description: 〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Malakoff, D -- New York, N.Y. -- Science. 2001 Jun 15;292(5524):1979.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/11408626" target="_blank"〉PubMed〈/a〉
    Keywords: *Bacterial Physiological Phenomena ; Financing, Government ; Geological Phenomena ; Geology ; Gold ; *Laboratories ; *Mining ; *Natural Science Disciplines ; Physical Phenomena ; Physics ; Research ; United States
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    American Association for the Advancement of Science (AAAS)
    Publication Date: 2001-02-24
    Description: Using a novel technique, described on page 795, paleoceanographers have been able to chart the abundance of sockeye salmon in the Bristol Bay and Kodiak Island regions of Alaska over the past 300 years--by far the most complete record yet. Through time, they found, sockeye populations have alternately soared and slipped, following natural climate variations--well before commercial fishers began throwing nets over the sides of boats.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Brown, K -- New York, N.Y. -- Science. 2000 Oct 27;290(5492):685-6.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/11184190" target="_blank"〉PubMed〈/a〉
    Keywords: Alaska ; Animals ; *Climate ; *Ecosystem ; Fisheries ; Fresh Water ; Geologic Sediments/chemistry ; Nitrogen Isotopes/analysis ; Pacific Ocean ; Salmon/*physiology ; Temperature
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    Publication Date: 2001-08-18
    Description: The deployment of electronic data storage tags that are surgically implanted or satellite-linked provides marine researchers with new ways to examine the movements, environmental preferences, and physiology of pelagic vertebrates. We report the results obtained from tagging of Atlantic bluefin tuna with implantable archival and pop-up satellite archival tags. The electronic tagging data provide insights into the seasonal movements and environmental preferences of this species. Bluefin tuna dive to depths of 〉1000 meters and maintain a warm body temperature. Western-tagged bluefin tuna make trans-Atlantic migrations and they frequent spawning grounds in the Gulf of Mexico and eastern Mediterranean. These data are critical for the future management and conservation of bluefin tuna in the Atlantic.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Block, B A -- Dewar, H -- Blackwell, S B -- Williams, T D -- Prince, E D -- Farwell, C J -- Boustany, A -- Teo, S L -- Seitz, A -- Walli, A -- Fudge, D -- New York, N.Y. -- Science. 2001 Aug 17;293(5533):1310-4.〈br /〉〈span class="detail_caption"〉Author address: 〈/span〉Tuna Research and Conservation Center, Stanford University, Hopkins Marine Station, Oceanview Boulevard, Pacific Grove, CA 93950, USA. bblock@stanford.edu〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/11509729" target="_blank"〉PubMed〈/a〉
    Keywords: Animal Identification Systems ; Animals ; Atlantic Ocean ; *Behavior, Animal ; Body Temperature ; Conservation of Natural Resources ; Diving ; *Ecosystem ; Female ; Fisheries ; Male ; Reproduction ; Seasons ; Swimming ; Temperature ; Tuna/*physiology
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    Publication Date: 2001-09-15
    Description: Recent advances in machine learning methods, along with successful applications across a wide variety of fields such as planetary science and bioinformatics, promise powerful new tools for practicing scientists. This viewpoint highlights some useful characteristics of modern machine learning methods and their relevance to scientific applications. We conclude with some speculations on near-term progress and promising directions.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Mjolsness, E -- DeCoste, D -- New York, N.Y. -- Science. 2001 Sep 14;293(5537):2051-5.〈br /〉〈span class="detail_caption"〉Author address: 〈/span〉Machine Learning Systems Group, Jet Propulsion Laboratory/California Institute of Technology, Pasadena, CA, 91109, USA. mjolsness@jpl.nasa.gov〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/11557883" target="_blank"〉PubMed〈/a〉
    Keywords: Algorithms ; Animals ; *Artificial Intelligence ; Astronomical Phenomena ; Astronomy ; Cluster Analysis ; *Computational Biology ; Computer Simulation ; Gene Expression Profiling ; Gene Expression Regulation ; Image Processing, Computer-Assisted ; Neural Networks (Computer) ; Physical Phenomena ; Physics ; Robotics
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    Electronic Resource
    Electronic Resource
    Springer
    Agriculture and human values 17 (2000), S. 125-139 
    ISSN: 1572-8366
    Keywords: Environment ; Fisheries ; Fordism ; Nation-State ; Regulation ; Supranational State ; Transnational corporations ; Transnational State
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract This analysis uses an analytical frameworkgrounded in political economy perspectives of theglobalization of the agro-food sector combined with acase study approach focusing on the Marine StewardshipCouncil (MSC) to inform discussions regarding thecharacteristics of societal regulation in thepost-Fordist era. More specifically, this analysisuses the case of the emergence of the MSC toinvestigate propositions regarding the existence of,and location of, nascent forms of a transnationalState. The MSC proposes to regulate the certificationof sustainable fisheries at the global level throughan eco-labeling program. The MSC was created in 1996by the transnational environmental organization theWorld Wildlife Fund and the transnational corporationUnilever. The emergence of the MSC has generatedheated discussion in fisheries management circles thatis in general divided along North/South lines. Thisanalysis indicates that the case of the MSC providesvaluable insights into the possible characteristics ofsupranational regulatory mechanisms that might emulatethe role of the nation-State in the post-Fordist era.
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    Electronic Resource
    Electronic Resource
    Springer
    Environment, development and sustainability 2 (2000), S. 277-304 
    ISSN: 1573-2975
    Keywords: Systems of Knowledge ; Local Knowledge ; Fisheries ; Resource Management
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Sociology
    Notes: Abstract During the last 20 years, the existence of rich systems of local knowledge, and their vital support to resource use and management regimes, has been demonstrated in a wide range of biological, physical and geographical domains, such as agriculture, animal husbandry, forestry and agroforestry, medicine, and marine science and fisheries. Local knowledge includes empirical and practical components that are fundamental to sustainable resource management. Among coastal-marine fishers, for example, regular catches and, often, long-term resource sustainment are ensured through the application of knowledge that encompasses empirical information on fish behaviour, marine physical environments, fish habitats and the interactions among ecosystem components, as well as complex fish taxonomies. Local knowledge is therefore an important cultural resource that guides and sustains the operation of customary management systems. The sets of rules that compose a fisheries management system derive directly from local concepts and knowledge of the resources on which the fishery is based. Beyond the practical and the empirical, it is essential to recognise the fundamental socio-cultural importance of local knowledge to any society. It is through knowledge transmission and socialisation that worldviews are constructed, social institutions perpetuated, customary practices established, and social roles defined. In this manner, local knowledge and its transmission, shape society and culture, and culture and society shape knowledge. Local knowledge is of great potential practical value. It can provide an important information base for local resources management, especially in the tropics, where conventionally-used data are usually scarce to non-existent, as well as providing a shortcut to pinpoint essential scientific research needs. To be useful for resources management, however, it must be systematically collected and scientifically verified, before being blended with complementary information derived from Western-based sciences. But local knowledge should not be looked on with only a short-term utilitarian eye. Arguments widely accepted for conserving biodiversity, for example, are also applicable to the intellectual cultural diversity encompassed in local knowledge systems: they should be conserved because their utility may only be revealed at some later date or owing to their intrinsic value as part of the world's global heritage. At least in cultures with a Western liberal tradition, more than lip-service is now being paid to alternative systems of knowledge. The denigration of alternative knowledge systems as backward, inefficient, inferior, and founded on myth and ignorance has recently begun to change. Many such practices are a logical, sophisticated and often still-evolving adaptation to risk, based on generations of empirical experience and arranged according to principles, philosophies and institutions that are radically different from those prevailing in Western scientific circles, and hence all-but incomprehensible to them. But steadfastly held prejudices remain powerful. In this presentation I describe the 'design principles' of local knowledge systems, with particular reference to coastal-marine fishing communities, and their social and practical usefulness. I then examine the economic, ideological and institutional factors that combine to perpetuate the marginalisation and neglect of local knowledge, and discuss some of the requirements for applying local knowledge in modern management.
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    In:  J. Geophys. Res., Hannover, Dt. Geophys. Ges. e. V., vol. 105, no. B4, pp. 8103-8120, pp. 1058, (ISSN: 1340-4202)
    Publication Date: 2000
    Keywords: Crustal deformation (cf. Earthquake precursor: deformation or strain) ; InSAR ; Geodesy ; Modelling ; JGR ; 1243 ; Geodesy ; and ; gravity ; Space ; geodetic ; surveys ; 3210 ; Mathematical ; geophysics ; (new ; field) ; Modeling ; 8145 ; Tectonophysics ; Physics ; of ; magma ; and ; magma ; bodies ; 8499 ; Volcanology
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    American Association for the Advancement of Science (AAAS)
    Publication Date: 2000-06-08
    Description: 〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Normile, D -- New York, N.Y. -- Science. 2000 May 19;288(5469):1165.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/10841732" target="_blank"〉PubMed〈/a〉
    Keywords: *Academies and Institutes/economics ; Animals ; Astronomical Phenomena ; Astronomy ; Chloroplasts/genetics ; Drosophila/genetics ; Interferometry ; *Molecular Biology/economics ; Physical Phenomena ; Physics ; *Research/economics ; Research Support as Topic ; Taiwan
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    American Association for the Advancement of Science (AAAS)
    Publication Date: 2000-08-19
    Description: At a press conference on 27 July, the National Marine Fisheries Service (NMFS) released a long-awaited plan to save the Columbia River's endangered salmon by restoring fish habitat, overhauling hatcheries, limiting harvest, and improving river flow. What the plan did not do, however, was call for immediate breaching of four dams on the Snake River, the Columbia's major tributary--an option that has been the subject of a nationwide environmental crusade. The NMFS will hold that option in abeyance while it sees whether the less drastic measures will do the trick. Responses from both sides were immediate and outraged.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Mann, C C -- Plummer, M L -- New York, N.Y. -- Science. 2000 Aug 4;289(5480):716-9.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/10950712" target="_blank"〉PubMed〈/a〉
    Keywords: Animals ; *Conservation of Natural Resources ; *Ecosystem ; Fisheries ; Fresh Water ; Government Agencies ; Northwestern United States ; *Salmon
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    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 47
    Publication Date: 2000-10-29
    Description: The effects of climate variability on Pacific salmon abundance are uncertain because historical records are short and are complicated by commercial harvesting and habitat alteration. We use lake sediment records of delta15N and biological indicators to reconstruct sockeye salmon abundance in the Bristol Bay and Kodiak Island regions of Alaska over the past 300 years. Marked shifts in populations occurred over decades during this period, and some pronounced changes appear to be related to climatic change. Variations in salmon returns due to climate or harvesting can have strong impacts on sockeye nursery lake productivity in systems where adult salmon carcasses are important nutrient sources.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Finney, B P -- Gregory-Eaves, I -- Sweetman, J -- Douglas, M S -- Smol, J P -- New York, N.Y. -- Science. 2000 Oct 27;290(5492):795-9.〈br /〉〈span class="detail_caption"〉Author address: 〈/span〉Institute of Marine Science, University of Alaska Fairbanks, Fairbanks, AK 99775, USA. finney@ims.uaf.edu〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/11052941" target="_blank"〉PubMed〈/a〉
    Keywords: Alaska ; Animals ; *Climate ; Diatoms ; *Ecosystem ; Fisheries ; Fresh Water ; Geologic Sediments/chemistry ; Industry ; Nitrogen Isotopes/analysis ; Pacific Ocean ; Plankton ; Salmon/*physiology ; Temperature
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 48
    facet.materialart.
    Unknown
    American Association for the Advancement of Science (AAAS)
    Publication Date: 2000-05-08
    Description: Fish faunas across the continental United States have become more similar through time because of widespread introductions of a group of cosmopolitan species intended to enhance food and sport fisheries. On average, pairs of states have 15.4 more species in common now than before European settlement of North America. The 89 pairs of states that formerly had no species in common now share an average of 25.2 species. Introductions have played a larger role than extirpations in homogenizing fish faunas. Western and New England states have received the most introductions, which is a reflection of the small number of native fishes in these areas considered desirable gamefish by settlers.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Rahel, F J -- New York, N.Y. -- Science. 2000 May 5;288(5467):854-6.〈br /〉〈span class="detail_caption"〉Author address: 〈/span〉Department of Zoology and Physiology, University of Wyoming, Laramie, WY 82071, USA. frahel@uwyo.edu〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/10797007" target="_blank"〉PubMed〈/a〉
    Keywords: Animals ; *Ecosystem ; Fisheries ; *Fishes ; Species Specificity ; United States
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 49
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    Journal of Polymer Science: Polymer Chemistry Edition 22 (1984), S. 1065-1076 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Various phosphorus-containing polyimides were prepared by the reaction of 1-[(dialkoxyphosphinyl)methyl]-2,4- and -2,6-diaminobenzenes (1) with a tetracarboxylic dianhydride like pyromellitic dianhydride (PMDA) and benzophenone tetracarboxylic dianhydride (BTDA). In addition, copolyimides that contained approximately 3% phosphorus were prepared by the reaction of 1 and m-phenylenediamine (MPD) with the aforementioned tetracarboxylic dianhydrides. Elemental analysis, inherent viscosity, infrared (IR) spectroscopy, differential scanning calorimetry (DSC), and thermogravimetric analysis (TGA) studies were performed to characterize the polymers. Their thermal properties were compared with those of the corresponding common polyimides. It was shown that the molecular weight and thermal stability of the polymers were reduced as the concentration of the phosphorus moieties increased. The fire-resistance of the copolyimides was evaluated by determining their limiting oxygen index (LOI) value. Copolyimides that contained about 3% phosphorus showed an LOI value approximately 30% higher, than the value of the corresponding common polyimides. In addition, a model diamic acid and diimide was synthesized by the reaction of 1-[di(2-chloroethoxyphosphinyl)methyl]-2,4- and - 2,6-diaminobenzene (DCEPD) with phthalic anhydride and characterized by elemental analysis, IR, proton nuclear magnetic (1H-NMR) spectroscopy, DSC, and TGA. The pyrolysis behavior of the model compounds was investigated by gas chromatography-mass spectrometry (GC-MS). A direct cleavage of the P—C bond and a possible rearrangement to diisocyanates occurred during their pyrolysis.
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  • 50
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    Journal of Polymer Science: Polymer Chemistry Edition 22 (1984), S. 1123-1130 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Thin film coatings were prepared by polymerizing trifluoromethyl-substituted aromatic compounds in a glow discharge with low power levels and medium pressures. Smooth, continuous films which are adherent and insoluble in conventional solvents were produced. A significant amount of the fluorine content from the monomer was retained in the polymer. The trifluoromethyl group was not removed by the plasma conditions and appeared in the film as trifluoromethyl and difluoromethylene groups. The films were slightly less wettable than those of the unfluorinated films.
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  • 51
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    Journal of Polymer Science: Polymer Chemistry Edition 22 (1984), S. 1153-1177 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Asymmetric polyamides from the reaction of either optically active trans-1,2-cyclopropanedicarboxylic acid (C3) or trans-1,2-cyclohexanedicarboxylic acid (C6) with 2,7-diazaspiro[4,4]nonane(DSN) were synthesized. The possible conformations of these polymers and their model compounds in 2,2,2-trifluoroethanol (TFE), water, methanesulfonic acid (MSA), and sulfuric acid were examined by circular dichroism (CD), NMR, viscosity, and dipole moment measurements. The racemic polyamides (±)C3·(±)DSN and (±)C6·(±)DSN exist in extended forms. No intrinsic viscosity changes were observed for these two polymers in TFE and MSA. Certain viscosity and spectral changes have been observed for the optically active polyamides, although no specific ordered conformations can be assigned. The optically active diacid units incorporated into the polymer give a conformation unique from the totally extended chain. CD studies seem to evidence some conformational differences among the polyamide derived from (+)C6 diacid and the optically active DSN. By changing the solvent from TFE to MSA a blue shift of the trough was observed for (+)C6·(±)DSN, a red shift for (+)C6·(-)DSN, and an inversion of the CD spectrum for (+)C6·(+)DSN polyamides. The results of the work with (+)C6·(-)DSN in dilute acid solution suggest that the rotation around the C-N bond is a relatively low-energy process. The spectral and intrinsic viscosity data are consistent with this suggestion. No drastic spectral changes have been observed for the C3·DSN polyamides by changing the solvent from TFE to MSA. The amide group in the C3·DSN polyamide and the corresponding model compound prefer a similar conformation with the carbonyl group bisecting the cyclopropane ring. The C3·DSN polyamide seems to exist in an extended form.
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  • 52
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    Journal of Polymer Science: Polymer Chemistry Edition 22 (1984), S. 1515-1524 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The cationic grafting of polystyrene initiated by carbon black containing the CO+ClO-4 group was investigated. The introduction of CO+ClO-4 groups onto a carbon black surface was achieved by the reaction of AgClO4 with carbon black that contained a COCI group. The latter was introduced by the reaction of carboxyl groups with SOCl2. It was found that polystyrene chains could be grown from CO+ClO-4 groups on the surface of carbon black. Moreover, polystyrene was effectively grafted from carbon black: the grafting ratio at 20°C increased to 58% as conversion increased. Furthermore, the grafting ratio and molecular weight of ungrafted polystyrene decreased with an increase in polymerization temperature. These results were explained by the fact that the increasing temperature of the polymerization caused an increase in the rate of chain transfer reaction of the growing polymer chain to the monomer. The carbon black obtained from the reaction produced a stable colloidal dispersion in a good solvent for polystyrene.
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  • 53
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    Journal of Polymer Science: Polymer Chemistry Edition 22 (1984), S. 1541-1550 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Radical polymerization of several alkyl allyl oxalates, including methyl allyl oxalate (MAO), ethyl allyl oxalate, propyl allyl oxalate, butyl allyl oxalate, and octyl allyl oxalate, was conducted in the evolution of carbon dioxide at elevated temperatures, and was compared with the anomalous polymerization behavior of diallyl oxalate (DAO) discussed in our earlier articleA. Matsumoto, I. Tamura, M. Yamawaki, and M. Oiwa, J. Polym. Sci. Polym. Chem. Ed., 17, 1419 (1979).. The kinetic equations for the polymerization of alkyl allyl oxalate were derived following the kinetic treatment of the DAO polymerization by further consideration of the absence of cyclization of the growing polymer radical and the effective reinitiation by alkyl radical, and were then satisfactorily applied to the polymerization of MAO, as a representative alkyl allyl oxalate. The evolution of carbon dioxide in the polymerization of alkyl allyl oxalates was enhanced with the increase of bulkiness of the alkyl substituent, as a result of steric suppression of the propagation of the growing polymer radical.
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  • 54
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    Journal of Polymer Science: Polymer Chemistry Edition 22 (1984), S. 17-28 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Plasma polymers synthesized by inductively coupled RF techniques have been investigated as a function of operating parameters for the isomeric perfluorinated diazines (pyrazine, pyrimidine, and pyridazine). A combination of ESCA and microanalytical studies shows that plasma polymers are produced by rearrangement mechanisms: the C/F and C/N stoichiometric ratios are similar to those of the starting monomers over a range of operating parameters. A comparison of rates of formation of plasma polymer films reveals distinctive differences between the isomeric diazines that suggest that equilibration of valence isomers occurs on a substantially slower time scale than for isomeric fluorinated benzenes5-9 which, in general, polymerize at essentially the same rates. In contrast to the remarkably low critical surface tension of plasma polymers based on perfluorobenzenes (ca. 20 dynes cm-2), the plasma polymer films from the perfluorinated diazines which are initially hydrophobic become hydrophilic in contact with water droplets. This is attributed to the hydrolytic instability of films associated with the labilizing influence of nitrogen on nucleophilic displacement of fluoride which is a feature of the chemistry of monomers.
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  • 55
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    Journal of Polymer Science: Polymer Chemistry Edition 22 (1984), S. 49-60 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Studies were conducted on grafting of acrylamide (AM) and sodium-2-acrylamido-2-methylpropane sulfonate (NaAMPS) comonomers onto dextran utilizing Ce(IV) induced initiation. The effects of reaction temperature, the Ce(IV)/dextran ratio, and the AM/NaAMPS ratio on grafting yield were investigated. The graft copolymerization behavior can be explained by exchange of the AMPS anion with one of the ligands on the Ce(IV) initiator. Oxidative modification of the dextran substrate improved the yield of graft copolymer. The dextran-g-poly(acrylamido-co-sodium-2-acrylamido-2-methylpropane sulfonate) samples prepared by this method were characterized as to copolymer composition and molecular weight utilizing elemental analysis, dilute solution viscometry, and aqueous size exclusion chromatography. Relationships of molecular weight and charge density to kinematic viscosity and salt sensitivity are discussed.
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  • 56
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    Journal of Polymer Science: Polymer Chemistry Edition 22 (1984), S. 77-84 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Photoinitiated cationic polymerization by photosensitization of diphenyliodonium and triphenylsulfonium salts is shown to proceed by two distinct electron transfer process: (1) direct electron transfer from excited-state photosensitizers and (2) indirect electron transfer from photogenerated radicals. The efficiency of the former process is attributed to the instability of the reduction products (from diphenyliodonium and triphenylsulfonium salts), which dissociate in competition with undergoing energy-wastage reverse electron transfer. Amplification of photons in the production of protons (or other reactive cations) is postulated to account for the high quantum yields observed in the latter process. Potential advantages of utilizing the indirect redox process in the design of UV curable hybrid systems, which contain functionality for both radical and cationic polymerization, are noted. The results also provide evidence against the importance of triplet states of the onium salts in photoinitiator activity.
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  • 57
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    Journal of Polymer Science: Polymer Chemistry Edition 22 (1984), S. 107-120 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Racemic and optically active N-carboxyanhydrides (NCA)s of 2-methyl- and cis-6-methylpipecolic acid, when subjected to polymerization conditions in solution or in bulk whether with “weak” or “strong” base initiators, resisted polymerization under all conditions tried. Instead, the NCA of 2-methylpipecolic acid gave the corresponding cyclic dipeptide and the NCA of cis-6-methylpipecolic acid formed the cyclic dipeptide derived from trans-6-methylpipecolic acid. The mechanism of dimerization of these NCA's was investigated. Evidence was provided for the proposed mechanism in which the active moiety is not a carbamate ion but an amino group. Methyl 2-methylpipecolate underwent an intermolecular SN2-type reaction upon heating, yielding equimolar quantities of methyl N-methyl-2-methylpipecolate and 2-methylpipecolic acid.
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  • 58
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    Journal of Polymer Science: Polymer Chemistry Edition 22 (1984), S. 135-144 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The effect of a range of 10 organic nitriles on the radiation-induced polymerization of styrene was studied. A dose rate of 4.4 rad s-1 was used. A rate of polymerization of styrene (1.744 mol L-1 of toluene solution) of 5.0 × 10-7 mol L-1 s-1 was found. With organic nitriles present (styrene:nitrile ratio of 1:0.28) the rate of polymerization increased. Rates in the range of 5.5 × 10-7 -5.2 × 10-6 mol L-1 s-1, depending on the nitrile present, were obtained. The polymers were partially characterized and evidence of involvement of each of the nitriles in the polymer chains was revealed. The increase in rate of polymerization has been attributed to the part played by nitrile radicals in the initiation of styrene polymerization. Radical yield values [as G(nitrile radical)] were derived from the relevant rate expressions. Values ranged from 2.7 to 49.5, depending on the particular nitrile. Corresponding values of G(nitrile radical) in the range of 5.1-129.4 were obtained by the manipulation of number-average molar mass data. Values of kpkt of approximately 2 × 10-5 L mol-1 s-1 were found. Trommsdorff types of effect are absent from these systems.
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  • 59
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    Journal of Polymer Science: Polymer Chemistry Edition 22 (1984), S. 213-223 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The effect of parasubstituents on the radiation chemistry of poly(α-methylstyrene) (PMS) was compared for the fluoro (PFMS), chloro (PCMS), bromo (PBMS), isopropyl (PiPMS), and methoxy (PMeOM) derivatives. Radiolysis yields, ESR spectra, and GC—MS analysis of products were obtained. PMS and PFMS have similar low radiolysis yields, products, and product distributions. Only main-chain radicals which persist to 200° were observed. PCMS has increased values of Gs, Gx, and Gr. The product analysis results suggest that the presence of chlorine contributes to the primary process by dissociative electron capture and enhances the cleavage of α-methyl group. Irradiation of PBMS caused crosslinking and yielded few volatile products. PMeOMS and PiPMS gel readily by γ-irradiation and may be useful as negative radiation resists.
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  • 60
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    Journal of Polymer Science: Polymer Chemistry Edition 22 (1984), S. 225-238 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: High molecular weight polysilane copolymers which contain the units in the title were prepared in high yield by sodium coupling the corresponding organodichlorosilanes in toluene. These copolymers are highly soluble in common solvents and can be drawn into fibers or formed into films by molding or casting. They are also photoactive.
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  • 61
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    Journal of Polymer Science: Polymer Chemistry Edition 22 (1984), S. 277-281 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 62
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    Journal of Polymer Science: Polymer Chemistry Edition 22 (1984), S. 303-318 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Iron-ion-containing polymers were prepared by reacting atactic polyvinylpyridine with ferric chloride or ferric nitrate in methanol solution. Molar ratios of Fe3+ to 4-vinylpyridine (Fe:PVP) were 1:2, 1:6, and 1:20. Three kinds of iron center were characterized from 57Fe Mössbauer spectra recorded over a temperature range of 4.2-290 K. Infrared (IR) spectra of the samples were measured also. All samples contained amorphous hydrated ferric-oxide particles that exhibited superparamagnetic behavior at low temperatures. The size of the clusters (102-103 iron atoms per particle) was estimated from the average blocking temperatures TBav, which is sensitive to the Fe:PVP ratio. For FeCl3:PVP preparations with Fe:PVP of 1:2, 1:6, and 1:20 TBav was 37, 10, and 〈4 K, respectively. A small proportion (〈10%) of high-spin ferrous iron centers was found in most samples. A third type of signal attributable to oxygen-bridged ferric dimers was found in FeCl3-PVP preparations with Fe:PVP of 1:2 or 1:6 but not in Fe(No3)3-PVP samples. This species is probably [Cl3Fe—O—FeCl3]2-. Interactions between the polymer and the various iron centers were weak.
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  • 63
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    Journal of Polymer Science: Polymer Chemistry Edition 22 (1984), S. 341-352 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Five general routes for the preparation of polyoxyethylene [generally referred to as poly(ethylene glycol) or PEG] derivatives are described. These routes are (1) nucleophilic displacements with the alkoxide of PEG, (2) nucleophilic displacement on PEG-tosylate, -mesylate, or -bromide, (3) reductive amination of PEG-aldehyde, (4) reductive amination of PEG-amine, and (5) nucleophilic displacements on the s-triazine derivatives prepared from s-triazine trichloride (cyanuric chloride) and PEG. Eighteen derivatives are prepared and potential applications to catalysis, cell purifications, and other areas are discussed briefly.
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  • 64
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    Journal of Polymer Science: Polymer Chemistry Edition 22 (1984), S. 391-406 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The polymerization of 6-amino-2,4-trans,trans-hexadienoic acid and various of its salts was studied in the solid state. Crystals of the hydrochloride and organic inorganic double halides with cadmium chloride, manganese (II) chloride, and iron(II) chloride were found to polymerize rapidly upon UV or γ irradiation. An erythro-diisotactic polymer is obtained in the form of extended chain crystals. The polymer behaves as an amphoteric polyelectrolyte. The kinetics and the mechanism of the polymerization as well as morphological changes during the solid state reaction are discussed.
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  • 65
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    Journal of Polymer Science: Polymer Chemistry Edition 22 (1984), S. 419-428 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: ESCA and contact-angle (H2O and CH2I2) measurements are used to follow changes in the surface of poly(ethylene terephthalate) film photooxidized (254 nm radiation in O2) for varying times, followed by aging for as many as three weeks or washing with water. Photooxidation occurs uniformly throughout the outermost 50 Å of the film to give a surface stoichiometry that corresponds to C10O6.6. Oxidation produces mainly carboxyl (acid) and alcohol/phenol groups, carbonyls form after extensive treatment. Low molecular weight products formed by chain scission and oxidation are removed by washing and diffuse into the bulk when aged. Oxidized products in higher molecular weight chains are not removed by washing, but can diffuse into the polymer bulk or reorient because of their chain mobility; therefore they are directed toward the polymer bulk rather than the surface. Extended photooxidation produces a stable oxidized surface more resistant to aging changes. The results are compared with those obtained for poly(ethylene terephthalate) film oxidized in an electrical discharge.
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  • 66
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    Journal of Polymer Science: Polymer Chemistry Edition 22 (1984), S. 463-473 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The absolute rate constants of propagation (kp) and of termination (kt) of N-acryloylpiperidine (NAPi) were determined by the rotating sector method in bulk; kp = 273 and kt = 1.79 × 107 L/mol s at 30°C. It was noted that kp for NAPi was 100 times smaller than that for N,N-dimethylacrylamide (DMAcAm). The absolute rate constants of cross-propagations for copolymerizations with common monomers were evaluated by combination of the kp value and the monomer reactivity ratios. Quantitative comparison of the rate constants with those of DMAcAm and poly(DMAcAm) radical shows that NAPi is as reactive as DMAcAm and the smaller kp value for NAPi is ascribable to much the lower reactivity of the poly(NAPi) radical. The large difference in reactivity of the polymer radicals is discussed in relation to the steric factor of the piperadino and the dimethylamino groups which seems to affect the capability of the carboxamide group to stabilize the polymer radical.
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  • 67
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    Journal of Polymer Science: Polymer Chemistry Edition 22 (1984), S. 493-502 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Preirradiation grafting of N-vinylpyrrolidone (NVP) onto poly(tetrafluoroethylene) (PTFE) and poly(tetrafluoroethylene-hexafluoropropylene) (FEP) films was investigated. The influence of grafting parameters such as preirradiation dose, monomer concentration, and grafting temperature on the rate and grafting yield was studied. Different solvents were used for diluting the monomer and it was found that the aqueous monomer solution at a concentration of 80 wt% was suitable for this grafting system. However, the graft polymerization of NVP in benzene terminated within a short time without significant grafting yield. The dependence of the grafting rate on preirradiation dose and monomer concentration was 1.2 and 1.07 order, respectively, for grafting onto PTFE films and 1.1 and 1.2 order, respectively, for grafting onto FEP films. Arrhenius plots for grafting onto PTFE films showed a breaking point at ca. 35°C and the overall activation energies were calculated as 23.6 and 9.0 Kcal/mol below and above 35°C, respectively. For grafting onto FEP films, however, no break was observed in the Arrhenius plots; the overall activation energy was 11.9 Kcal/mol. The swelling behavior and electric resistance of the grafted materials were investigated.
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  • 68
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    Topics: Chemistry and Pharmacology
    Notes: Several polythioesters by interfacial polycondensation of 1,4-di(mercaptomethyl)-2,3,5,6-tetramethylbenzene with oxalyl, succinyl, adipoyl, suberoyl, and sebacoyl chlorides were obtained. To determine the optimal conditions for interfacial polycondensation, the influence of the following factors on yield and value of reduced viscosity were studied: type of organic phase, concentration of hydrogen chloride acceptor, the quantitative ratio of aqueous to organic phase, molar ratio of reagents; temperature of reaction, rate of acid chloride addition, and contribution of catalyst. Thorough studies were carried out only for polycondensation of the dithiol with adipoyl and sebacoyl chlorides. The structure of all polythioesters obtained under the model conditions was determined by elementary analysis and infrared spectra. Initial decomposition temperature, mass loss in percentage at the same temperature, maximum rate of decomposition, and mass loss percentage at 100-400°C were defined by thermogravimetric analyses. Chemical resistance of the polythioesters was determined by treatment with some organic solvents, mineral acids (concentrated and 10%), and sodium hydroxide (10 and 50%). Some mechanical and electrical properties of the polythioesters obtained from dithiol and adipoyl and sebacoyl chlorides were determined. The molecular weight was not measured because of the low solubility of the polythioesters.
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    Topics: Chemistry and Pharmacology
    Notes: The anionic polymerization of norbornene trisulfide initiated with sodium thiophenoxide (sodium cation solvated with dibenzo-18-crown-6 ether) was studied. Polymers with high molecular weights were obtained (Mn up to 105, osmometrically). Molecular weights calculated for living polymerization conditions (i.e., one molecule of initiator yields one macromolecule) agree well with Mn measured by osmometry. 1H-NMR, 13C-{1H}-NMR, and Raman spectra of the polymer are given. Thermodynamics of polymerization in toluene solvent is described. Enthalpy ΔHss = -(1.39 ± 0.17) kcal mol-1 and entropy ΔSss = -(7.52 ± 0.55) cal mol-1 deg-1 coefficients of polymerization were evaluated from the temperature dependence of the equilibrium monomer concentration determined dilatometrically.
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  • 70
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    Journal of Polymer Science: Polymer Chemistry Edition 22 (1984), S. 1141-1151 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A fire- and heat-resistant polymer was obtained by the thermal polymerization of bismaleimido-substituted 2,2-bis(anilino)-4,4,6,6-tetrakis-(4-Aminophenoxy)-cyclotriphosphazene. The thermal stabilities of the polymer were evaluated in nitrogen and in air by thermogravimetric analysis. This polymer was stable to 345°C and had char yields of 78% at 800°C in nitrogen and of 71% at 700°C in air. The structures of cyclotriphosphazene precursors and the polymer were characterized using Fourier-transform infrared and proton nuclear magnetic resonance spectroscopy.
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  • 71
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    Journal of Polymer Science: Polymer Chemistry Edition 22 (1984), S. 1187-1190 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 72
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    Journal of Polymer Science: Polymer Chemistry Edition 22 (1984), S. 1197-1200 
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    Keywords: Physics ; Polymer and Materials Science
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    Topics: Chemistry and Pharmacology
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  • 73
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    Journal of Polymer Science: Polymer Chemistry Edition 22 (1984), S. 1243-1250 
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    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The rate of reaction of alkyl halides with aqueous sodium acetate or cyanide catalyzed by phosphonium salts supported on insoluble polystyrene resins, and rates of ion-exchange of the chloride ion in the catalysts against the acetate ion, were studied as a function of catalyst particle size, the percentage of ring substitution, the morphology of polymer support, and distance between active site and polymer backbone. Rates of 1-bromooctane or benzyl chloride with macroporous, 7-25% ring-substituted catalysts increased with increasing ring substitution. Rates with macroporous catalysts increased as a heptamethylene spacer was introduced between the active site and the polymer backbone. Rates of ion-exchange with macroporous catalysts were facilitated with increasing ring substitution or by the introduction of the spacer chain. A relation between the catalytic activity of macroporous or microporous catalysts and ion-exchange rates under triphase conditions was discussed.
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  • 74
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    Journal of Polymer Science: Polymer Chemistry Edition 22 (1984), S. 1251-1258 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Polymerization of the cyclic amide of PIII is described for the first time. The N,N-diethylamine-1,3,2-dioxaphosphorinan was shown to give living reversible polymerization with anionic initiators. Lithium and sodium derivatives were found to be inactive. 1H-, 13C-, and 31P-NMR indicated that the polymer strictly reflects the monomer structure and is formed without any isomerization, the polymer chain being $\rlap{--} ({\rm OP}\left( {{\rm NR}_{\rm 2} } \right){\rm O(CH}_{\rm 2} \rlap{--} )_3 )_n $. Initiation involves attack of the anion on the P atom. From the dependence of the equilibrium monomer concentration on temeprature ΔH1s = 1.5 ± 0.2 kcal·mol-1 and ΔS1s = 4.6 ± 0.6 cal·mol-1·°K-1.
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  • 75
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    Topics: Chemistry and Pharmacology
    Notes: The interaction of α-poly-L-lysine and ε-poly-L-lysine with methyl and ethyl orange was studied by equilibrium dialysis and spectroscopic methods. The results of the dialysis measurements indicated that the extent of binding by ε-polypeptide is substantially higher than that by α-polypeptide, despite the much greater molecular weight of the latter. This difference in binding affinity was interpreted in terms of the increased conformational adaptability of ε-polypeptide because of its highly flexible structure. Furthermore, ε-polypeptide exhibited strong cooperative binding. In addition, the effect of the successive addition of α- and ε-polypeptides on the absorption spectra of methyl and ethyl orange was investigated. The addition of α-polypeptide with a molecular weight of 400,000 produced a new absorption peak at a shorter wavelength, due to the stacked dye molecules on the polypeptide chain, whereas that of ε-polypeptide did not. From the results of spectroscopic measurements a possible mode of interaction between these two polypeptides and the small molecule is discussed.
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  • 76
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    Journal of Polymer Science: Polymer Chemistry Edition 22 (1984), S. 1327-1333 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Grafted PMMA was isolated by the acid hydrolysis method. Weight-average and number-average molecular weights were determined by gel permeation chromatography. The number-average molecular weight of the grafted chains was about 475,000 for amylopectin and 403,000 for amylose. The number of grafted chains (mmol) ranged from 2.4 × 10-3 to 4.6 × 10-3 for amylopectin graft copolymers and from 2.9 × 10-3 to 6.8 × 10-3 for those of amylose. These results were related to others obtained from ceric ion consumption studies. The values suggest that amylopectin, because of its complex structure, favors a higher consumption of ceric ion in homopolymerization reactions and inhibits the initiation reactions of the copolymerization.
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  • 77
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    Journal of Polymer Science: Polymer Chemistry Edition 22 (1984), S. 1365-1372 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The progressive dissolution of carboxylated latex particles with increasing pH was utilized to investigate the internal structure of core-shell latex particles, in comparison with that of copolymeric latex particles formed from the same monomers. The results indicated that in those latex particles which are formed when ethyl acrylate (EA) -methacrylic acid (MAA) or methyl acrylate (MA) -MAA mixture is polymerized in the presence of poly(MA-MAA) or poly(EA-MAA) seeds the shell is composed of the more hydrophilic poly(MA-MAA) molecules relatively high in MAA content and the core is composed of both poly(MA-MAA) and poly(EA-MAA) molecules, regardless of the order of the stage feed, while the copolymeric latex particles are relatively uniform from surface to center in distribution of all components except MAA. Examination of the distribution of the carboxylic groups in all of the latex particles showed their concentration to be highest at the surface and to decrease with proximity to the center in accordance with other findings reported in the literature.
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  • 78
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    Journal of Polymer Science: Polymer Chemistry Edition 22 (1984), S. 1409-1417 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The emulsion polymerization of styrene initiated by potassium persulfate catalyzed by Ti+3 ions was studied. Two sources of Ti+3 ions were used: the titanium trichloride and titanium sulfate. It was found that the titanium ions used in conjunction with potassium persulfate decrease both the reaction rate and the average molecular weight. An even greater drop of reaction rate was noted when chlorine anions (TiCl3) were present. The presence of these ions had a stabilizing effect on the polydispersity.
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    Journal of Polymer Science: Polymer Chemistry Edition 22 (1984), S. 1471-1479 
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    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Mass spectroscopy was done at different temperatures on epoxylated novolac resin DEN 438 (Dow Chemical Co.) alone, and after curing with various metal(II) phthalocyanine tetraamines (MPTA). Possible modes of fragmentation are given to explain the experimental results. Gas-chromatographic/mass-spectroscopic (GC-MS) analyses of MPTA derivatives indicated the presence of only trace quantities of benzene, aniline, cyanobenzene, and orthodicyanobenzene. The GC-MS studies of the cured DEN 438 epoxy resins indicated that the mechanisms of thermal degradation are qualitatively similar, and some common features were observed in their fragmentation in an electron beam and by thermal degradation. This study is a further assessment of the utility of these phthalocyanine derivatives for curing epoxy resins to produce heat-resistant polymer systems.
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  • 80
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    Journal of Polymer Science: Polymer Chemistry Edition 22 (1984), S. 1507-1514 
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    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The initiation mechanism on the radical polymerization of vinyl monomers by polyethyleneglycol (PEG-300) in aqueous solution was studied. The initiating radical species were determined by means of the spin trapping technique. They were concluded to be generated by the hydrogen atom transfer from the monomer adsorbed at the ether group of PEG-300 to the free monomer.
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    Journal of Polymer Science: Polymer Chemistry Edition 22 (1984), S. 1535-1540 
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    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The stereospecificity of benzyl derivatives of trivalent titanium (Rn TiX3-n, where X = Cl, I, n = 1-3) in butadiene polymerization was studied. It was found that dibenzyltitaniumiodide is an efficient catalyst of the 1,4-cis-polymerization of butadiene and that tribenzyltitanium forms 1,2-units. In both cases all the titanium-benzyl bonds participated in the initiation reaction and the active sites were polymeric analogues of crotyl derivatives of Ti(III); namely, bis-π-oligobutadienyltitaniumiodide and tris-π-oligobutadienyltitanium. These sites are stable at room temperature. The nature of the active sites in the polymerization of butadiene with Ziegler's 1,4-stereo-specific systems Til4 (or Til2Cl2) + AIR3 are described.
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  • 82
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    Journal of Polymer Science: Polymer Chemistry Edition 22 (1984), S. 1573-1578 
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    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: When 4-hydroxy-2,2,6,6-tetramethyl piperidinoxyl (HTMPO) is processed in polypropylene in a closed mixer, almost 50% is converted to other products during the first few minutes whilst the applied torque in the mixer is high. There is associated formation of unsaturation and this fact, in conjunction with the almost complete regeneration of nitroxyl within five minutes, suggests that the corresponding hydroxylamine (HTMPOH), which can be qualitatively identified, is the major transformation product. A study of the UV stability of PP films fabricated from polymer processed for varying times shows that UV stability is related to the quantity of the redox couple (HTMPO + HTMPOH) remaining in the polymer. This is considerably reduced by severe processing. The redox capable has almost no thermal antioxidant (oven aging) activity.
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  • 83
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    Journal of Polymer Science: Polymer Chemistry Edition 22 (1984), S. 1611-1621 
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    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Polyamides 6.10 and 6.6 (PA* 6.10 and 6.6) containing small amounts of —N=N— units in the main chains were prepared by interfacial polycondensation between hexamethylenediamine and sebacoyl chloride or adipoyl chloride with addition of azobiscyanopentanoyl chloride. Polyamide-polystyrene block copolymers (PA-b-PSt) were then prepared by decomposition of the —N=N— units of PA*, initiating radical polymerization of styrene in m-cresol. The average PA block length of PA-b-PSt thus formed was longer than that expected from the initially present PA segments between the —N=N— units. This is probably due to recombination of PA radicals whose initiation efficiency is as low as 15%. The PSt blocks also had higher molecular weight (7000-79,000) in comparison with homopolystyrene produced from monomeric azobiscyanopentanoic acid used as an initiator due to higher viscosity of polymerization system. Variation of intrinsic viscosity and turbidimetric titration behavior along with the change in composition were also discussed.
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  • 84
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    Journal of Polymer Science: Polymer Chemistry Edition 22 (1984), S. 1603-1610 
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    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The polymerization of trimethylsilylacetylene was investigated by using W and Mo catalysts. Mixtures of WCl6 with appropriate organometallic cocatalysts such as n-Bu4Sn and Et3SiH at 1:1 molar ratio provided poly(trimethylsilylacetylene) in high yields. On the other hand, MoCI5 gave mainly methanol-soluble oligomers even in the presence of these cocatalysts. The polymer formed was a partly insoluble yellow powder, and the molecular weight of the soluble fraction was about 7000. The IR, 1H-NMR, and 13C-NMR spectra supported the polymer structure, (CH = CSiMe3)n. Protodesilylation of poly(trimethylsilylacetylene) afforded a new polymer containing both acetylene and trimethylsilylacetylene units.
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    Journal of Polymer Science: Polymer Chemistry Edition 22 (1984), S. 1733-1742 
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    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Cationic oligomerization of bicyclic oxalactam, 8-oxa-6-azabicyclo[3.2.1]octan-7-one [abbreviated as BOL (1)], was carried out at 0-60°C with trifluoromethanesulfonic acid and borontrifluoride etherate as catalysts to obtain the oligomer mixture at high yield. From the structural analysis of the isolated dimer, a N-(2(e)-carbamoyltetrahydropyran-6(e)-yl)-8-oxa-6-azabicyclo[3.2.1]octan-7-one, the oligomerization proceeded through the 5C-6N scission in (1) but not through the 6N-7C (amide group) scission as generally observed in common lactams. This peculiar oligomerization must result from the protonation to the oxamide unit in the BOL molecule.
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    Journal of Polymer Science: Polymer Chemistry Edition 22 (1984), S. 1775-1782 
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    Keywords: Physics ; Polymer and Materials Science
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    Topics: Chemistry and Pharmacology
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    Journal of Polymer Science: Polymer Chemistry Edition 22 (1984), S. 1803-1815 
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    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The kinetics of aqueous polymerization of acrylamide with KMnO4/glycine redox pair was studied in an atmosphere of nitrogen at 35 ± 0.2°C. The rate of polymerization was found to be first power on monomer, activator, and catalyst concentration. The overall energy of activation was calculated to be 15.66 kcal/deg mol (65.54 kJ/mol) between 30 and 50°C. The effects of various additives (alcohols, neutral salts, complexing agents, addition of catalyst) were studied. The dependence of the polymerization rate on the activator and catalyst concentration was studied in DMF-water mixture also. The molecular weight of polymer was determined at various temperatures of the reaction medium.
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  • 88
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    Journal of Polymer Science: Polymer Chemistry Edition 22 (1984), S. 1743-1756 
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    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Several polyamides of p-phenylenedioxydiacetic acid (PDDA) were synthesized by the low-temperature solution polycondensation techniques. Six different diamines were condensed independently with p-phenylenedioxydiacetyl chloride (PDC) in a mixture of N-methyl pyrolidone (NMP) and hexamethyl phosphoramide (HMPA). The polymers were obtained in 80-95% yield and possessed inherent viscosities in the range 0.32-0.81 dL/g. The polymers were characterized by infrared (IR) and H1-NMR spectra. The solubility, density, crystallinity, and thermal stability of the polyamides were also determined. A model diamide (MDA-1) was also synthesized from aniline and PDC to confirm the formation of polyamides from diamines.
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    Journal of Polymer Science: Polymer Chemistry Edition 22 (1984), S. 1797-1801 
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    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The radiation degradation of viscoelastic solutions of a dialkyl monohydroxy aluminum polymer compound (AIR2OH)x is investigated. Radioactive cobalt-60 is chosen for irradiation experiments. The viscosity of the polymer in six different solvents is measured after irradiation using a capillary viscometer at room temperature (25°C). The degradation effects on both the radiation dose and the solvent used.
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  • 90
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    Topics: Chemistry and Pharmacology
    Notes: Asymmetric selective (or stereoelective) polymerization of racemic 1,2-diphenylethyl methacrylate (DPEMA) with ethylmagnesium bromide (EtMgBr)-(-)-sparteine catalyst was studied in toluene at -78°C. In the polymerization (S) enantiomer was consumed preferentially and the enantiomeric excess of initially polymerized (S) enantiomer was consumed preferentially and the enantiomeric excess of initially polymerized DPEMA was greater than 90%. Optically pure (R) monomer was recovered at about 70% polymer yield. Poly(DPEMA) obtained with EtMgBr-(-)-sparteine complex was highly isotactic. It was found in the polymerization of optically active DPEMA that optical rotation of poly(DPEMA) was dependent on the tacticity and that isotactic and syndiotactic poly(DPEMA)s showed opposite optical rotations. Circular dichroism spectra of the optically active polymers were measured.
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  • 91
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    Journal of Polymer Science: Polymer Chemistry Edition 22 (1984), S. 1865-1873 
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    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The laser-initiated polymerization of a thiol-ene photopolymerizable system was studied. The laser was operated in single- and multiple-pulse modes to generate exotherms, which were measured in a modified differential scanning calorimeter. Arrhenius plots of the polymerization, obtained by measuring polymerization exotherms at various temperatures, showed positive and negative portions. Pseudoactivation energies for the thiol-ene polymerization increased rapidly at low conversions (〈50%) of the thiol and ene chromophores. The results were comparable to those obtained from photopolymerization of multifunctional acrylate monomers.
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    Journal of Polymer Science: Polymer Chemistry Edition 22 (1984), S. 1909-1921 
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    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: By exposure to ultraviolet and gamma radiation and by the usual methods of thermal polymerization, the stereospecific polymerization of methyl aryloxymethacrylates was carried out at different temperatures in several solvents. Triad tacticity values of the polymers obtained by free-radical and ionic routes were computed from nuclear magnetic resonance spectral data. Results of this investigation support our earlier observationSee: K. Saunders, T. Balakrishnan, R. W. Lenz, and K. Hatada, Macromolecules, 12, 392 (1979). that, under the conditions used, heterotactic content is the maximum in most of these polymers, thereby justifying the high steric effect of the bulky and polar aryloxy side chain which offers equal isotactic and syndiotactic placements.
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    Journal of Polymer Science: Polymer Chemistry Edition 22 (1984), S. 1987-1996 
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    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The cationic, ring-opening polymerization of 1,6-anhydro-3,4-di-O-benzyl-2-deoxy-β-D-arabino-hexopyranose (ABDA) (=1,6-anhydro-3,4-di-O-benzyl-2-deoxy-β-D-glucopyranose) was investigated with Lewis acid as catalyst. Phosphorus pentafluoride at -78°C caused polymerization to a highly stereoregular (1 → 6)-α-linked polysaccharide. Effects of C-2 substituent on the polymerization of 1,6-anhydro sugar are discussed. In addition, copolymerization of ABDA (M1) with 1,6-anhydro-2,3,4-tri-O-benzyl-β-D-glucopyranose (LGTBE, M2) was studied. The monomer reactivity ratios calculated by the Kelen-Tüdös method were r1 = 4.46 and r2 = 1.66. Debenzylation of the polymer produced 2-deoxy-(1 → 6)-α-D-arabino-hexopyranan in which every repeating unit contained two free hydroxyl groups.
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    Journal of Polymer Science: Polymer Chemistry Edition 22 (1984), S. 2381-2393 
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    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The absolute rate constants for propagation (kp) and for termination (kt) of ethyl α-fluoroacrylate (EFA) were determined by means of the rotating sector method; kp = 1120 and kt = 4.8 × 108 L/mol.s at 30°C. The monomer reactivity ratios for the copolymerizations with various monomers were obtained. By combining the kp values for EFA from the present study and those for common monomers with the monomer reactivity ratios, the absolute values of the rate constants for cross-propagations were also evaluated. Reactivities of EFA and poly(EFA) radical, being compared with those of methyl acrylate and its polymer radical, were found to be little affected by the α-fluoro substitution. Poly(EFA) prepared with the radical initiator was characterized by differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). Although the glass transition temperature obtained by DSC for poly(EFA) resembled that of poly(ethyl α-chloroacrylate), its TGA thermogram showed fast chain de polymerization to EFA that was distinct from complicated degradation of poly(ethyl α-chloroacrylate).
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  • 95
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    Topics: Chemistry and Pharmacology
    Notes: A polymethacrylate derivative containing uracil bases was methylated by using methyl iodide or dimethyl sulfate to give polymers containing 3-methyluracil derivatives. In the case of methylation with dimethyl sulfate, sulfonation at 5-position of the bases occurred in addition to the methylation at N-3 position. The methylated polymers thus obtained were used further for the study of polymer complex formation with polymethacrylate containing adenine base.
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    Journal of Polymer Science: Polymer Chemistry Edition 22 (1984), S. 2523-2531 
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    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Polyelectrolyte submicron microcapsules were prepared by interfacial crosslinking of an aqueous salt solution of poly(ethyleneimine) and a toluene solution of brominated poly-(2,6-dimethylphenylene oxide). The two solutions were brought together and mixed by sonication. As a result, a stable emulsion was obtained, which was subsequently cast into a membrane in which the microcapsules were embedded. The salt solution contained in the microcapsules could be released under controlled conditions. The rates of release were measured. They could be controlled by applying osmotic pressures, by additional quaternization of the membrane, or by modification of the structure of the capsule wall by introduction of a surfactant.
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    Journal of Polymer Science: Polymer Chemistry Edition 22 (1984), S. 2539-2550 
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    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A combined (chemical and infrared (IR) spectrophotometric) method is discussed for the simultaneous determination of concentrations of carboxyl (A), ketone (K), and ester (E) groups formed in the oxidation of polyethylene (PE). The IR absorptivities of these functional groups were determined by using model compounds [stearic acid, stearone, poly-(1,4-butylene sebacate)]. The integral absorption of the C=O band of polymer samples which contained several oxo groups of different types was found to be additive. This method was applied to the determination of the carboxyl, ester, and ketone content of samples oxidized at different oxygen pressures.
    Additional Material: 7 Ill.
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  • 98
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 22 (1984), S. 2579-2599 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Polyamides and related model compounds were prepared from carboxy acids and primary amines by reacting them with triphenylphosphite in an appropriate solvent at 100°C. The reactions proceeded in the absence of organic base but were accelerated by the addition of bases such as pyridine. Nevertheless, even the powerful combination of 13C and 31P NMR failed to indicate the presence of pyridinium phosphite in the reaction mixture. In the reaction of a primary amine and carboxyl groups a detectable amount of the diphenoxy aminophosphine intermediate was observed. The end products are the amides, phenol, and diphenyl phosphite. When primary amine was not present a slow formation of a phenyl ester of the carboxylic acid was evident. All the intermediate species and the end products were formed with or without added pyridine. A mixed anhydride of carboxylic acid and phosphite was never seen. The results in this article are fundamentally the same as those in the companion article (I) for which the data were obtained at 280°C in the absence of solvent and base. However, because the reaction went quickly to completion at 280°C, the diphenoxy aminophosphine intermediate was not observed. A mechanism for the amidation in which the diphenoxy aminophosphine is an initial reaction intermediate is proposed. This species reacts with the carboxylic acid through an intramolecular substitution to give an amide. This mechanism may be valid for the high-temperature reactions as well. Several minor unclear points are indicated.
    Additional Material: 4 Ill.
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  • 99
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 22 (1984), S. 2661-2666 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: ESCA has been used to investigate the composition and structural features of plasma-polymerized 2,4,6-trifluoro-1,3,5-triazine. Polymer formation was studied as a function of power and post-polymerisation treatment. All the polymer films revealed an intense peak at a binding energy of ∼290.2 eV probably arising from groups. A high sensitivity towards hydrolysis was observed resulting in substantial loss of fluorine and increase in oxygen content of the plasma polymers.
    Additional Material: 2 Ill.
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  • 100
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 22 (1984), S. 2685-2697 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The kinetics of chain transfer to the bifunctional initiating and transfer agents (binifers) 1,4-di(2-chloro-2-propyl)benzene (p-DCC), 1,3-di(2-chloro-2-propyl)-5-tert-butylbenzene (m-tBuDCC), and 1,3-di(2-chloro-2-propyl)-4,6-dimethylbenzene (m-DMeDCC) in the polymerization of isobutylene has been investigated. Chain transfer to monomer was shown to be absent up to -20°C in CH3Cl/n-hexane and CH2Cl2/n-hexane mixtures using the m-tBuDCC/BCl3 binifer system. Chain transfer constants (Ci) to m-tBuDCC and kt/kp ratios determined in the range from -30°C to -80°C in CH3Cl/n-hexane mixtures and pure CH3Cl solvent are reported, and the activation energy differences Etr,l - Ep and Et - Ep were calculated. Chain transfer constants to p-DCC and m-DMeDCC were determined by the use of pure CH3Cl diluent at -50°C. The chain transfer reactivity of five different inifers is discussed and compared based on CI values obtained under identical conditions, with special regard to the new, sterically hindered binifer m-DMeDCC of extraordinary reactivity.
    Additional Material: 7 Ill.
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