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  • Polymer and Materials Science  (30,302)
  • 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous
  • 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology
  • Wiley-Blackwell  (30,306)
  • American Geophysical Union  (36)
  • Springer  (13)
  • Springer Berlin Heidelberg  (4)
  • COPERNICUS GESELLSCHAFT MBH, BAHNHOFSALLEE 1E, GOTTINGEN, 37081, GERMANY
  • 2010-2014  (40)
  • 2005-2009  (18)
  • 1995-1999  (14,995)
  • 1975-1979  (13,298)
  • 1950-1954  (2,009)
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  • 1
    Publication Date: 2020-11-16
    Description: Active volcanoes characterized by open conduit conditions generate sonic and infrasonic signals, whose investigation provides useful information for both monitoring purposes and studying the dynamics of explosive processes. In this work, we discuss the automatic procedures implemented for a real-time application to the data acquired by a permanent network of five infrasound stations running at Mt. Etna volcano. The infrasound signals at Mt. Etna consist in amplitude transients, called infrasound events. The adopted procedure uses a multi-algorithm approach for event detection, counting, characterization and location. It is designed for an efficient and accurate processing of infrasound records provided by single-site and array stations. Moreover, the source mechanism of these events can be investigated off-line or in near real-time by using three different models: i) Strombolian bubble; ii) resonating conduit and iii) Helmholtz resonator. The infrasound waveforms allow us to choose the most suitable model, to get quantitative information about the source and to follow the time evolution of the source parameters.
    Description: Published
    Description: 1215–1231
    Description: 6V. Pericolosità vulcanica e contributi alla stima del rischio
    Description: JCR Journal
    Description: open
    Keywords: infrasound ; monitoring system ; Mt. Etna ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Publication Date: 2020-12-15
    Description: Long continuous seismic data recorded at five broadband seismic stations during 2006 at Campi Flegrei caldera have been analyzed. Introducing a coarse-grained method, we evaluate the time evolution of amplitude and polarization of the seismic noise in the frequency band common to long-period events. The series are modulated on tidal time scales: the root-mean square is basically dominated by solar contribution, while the azimuth of the polarization vector shows lunar diurnal and semidiurnal constituents. In addition, we find that in the frequency band common to long-period events the azimuths are polarized toward a specific area, suggesting that these persistent oscillations can be induced by the activity of the shallow geothermal reservoir.
    Description: Published
    Description: 2628–2637
    Description: JCR Journal
    Description: restricted
    Keywords: sustained hydrothermal tremor ; Campi Flegrei Caldera ; polarization analysis ; tidal modulation ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 3
    Publication Date: 2020-12-21
    Description: We detail the Kamil crater (Egypt) structure and refine the impact scenario, based on the geological and geophysical data collected during our first expedition in February 2010. Kamil Crater is a model for terrestrial small-scale hypervelocity impact craters. It is an exceptionally well-preserved, simple crater with a diameter of 45 m, depth of 10 m, and rayed pattern of bright ejecta. It occurs in a simple geological context: flat, rocky desert surface, and target rocks comprising subhorizontally layered sandstones. The high depth-to-diameter ratio of the transient crater, its concave, yet asymmetric, bottom, and the fact that Kamil Crater is not part of a crater field confirm that it formed by the impact of a single iron mass (or a tight cluster of fragments) that fragmented upon hypervelocity impact with the ground. The circular crater shape and asymmetries in ejecta and shrapnel distributions coherently indicate a direction of incidence from the NW and an impact angle of approximately 30 to 45 . Newly identified asymmetries, including the off-center bottom of the transient crater floor downrange, maximum overturning of target rocks along the impact direction, and lower crater rim elevation downrange, may be diagnostic of oblique impacts in well-preserved craters. Geomagnetic data reveal no buried individual impactor masses 〉100 kg and suggest that the total mass of the buried shrapnel 〉100 g is approximately 1050–1700 kg. Based on this mass value plus that of shrapnel 〉10 g identified earlier on the surface during systematic search, the new estimate of the minimum projectile mass is approximately 5 t.
    Description: Published
    Description: 1842–1868
    Description: 3.8. Geofisica per l'ambiente
    Description: JCR Journal
    Description: restricted
    Keywords: Impact craters ; geophysical survey ; iron meteorite ; impact scenario ; 04. Solid Earth::04.02. Exploration geophysics::04.02.99. General or miscellaneous ; 04. Solid Earth::04.02. Exploration geophysics::04.02.07. Instruments and techniques ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 4
    Publication Date: 2021-07-14
    Description: From 25 November to 2 December 2006, the first active seismic tomography experiment at Stromboli volcano was carried out with the cooperation of four Italian research institutions. Researchers on board the R/V Urania of the Italian National Council of Research (CNR), which was equipped with a battery of four 210- cubic- inch generated injection air guns (GI guns), fired more than 1500 offshore shots along profiles and rings around the volcano.
    Description: DPC/INGV agreement 2004-2006
    Description: Published
    Description: 269-270
    Description: 1.4. TTC - Sorveglianza sismologica delle aree vulcaniche attive
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 3.6. Fisica del vulcanismo
    Description: N/A or not JCR
    Description: reserved
    Keywords: Stromboli ; seismic tomography ; air-gun ; 04. Solid Earth::04.06. Seismology::04.06.07. Tomography and anisotropy ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 04. Solid Earth::04.06. Seismology::04.06.10. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 5
    Publication Date: 2017-04-04
    Description: In this work we present seismological and ground deformation evidence for the phase preparing the July 18 to August 9, 2001 flank eruption at Etna. The analysis performed, through data from the permanent seismic and ground deformation networks, highlighted a strong relationship between seismic strain release at depth and surface deformation. This joint analysis provided strong constraints on the magma rising mechanisms. We show that in the last ten years, after the 1991–1993 eruption, an overall accumulation of tension has affected the volcano. Then we investigate the months preceding the 2001 eruption. In particular, we analyse the strong seismic swarm on April 20–24, 2001, comprising more than 200 events (Mmax = 3.6) with prevalent dextral shear fault mechanisms in the western flank. The swarm showed a ca. NE-SW earthquake alignment which, in agreement with previous cases, can be interpreted as the response of the medium to an intrusive process along the approximately NNW-SSE volcano-genetic trend. These mechanisms, leading to the July 18 to August 9, 2001 flank eruption, are analogous to ones observed some months before the 1991–1993 flank eruption and, more recently, in January 1998 before the February-November 1999 summit eruption.
    Description: Published
    Description: 1469-1487
    Description: partially_open
    Keywords: Ground deformation ; volcano seismology ; Mt. Etna Volcano ; intrusive mechanism ; 04. Solid Earth::04.03. Geodesy::04.03.01. Crustal deformations ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 6
    Publication Date: 2017-04-04
    Description: Volcanic tremor and low frequency events, together with infrasound signals, can represent important precursory phenomena of eruptive activity because of their strict relationship with eruptive mechanisms and with fluid flows through the volcano's feeding system. Important variations of these seismo-volcanic and infrasound signals, recorded at Mt. Etna volcano, occurred both in the medium- and short-term before the eruption, that took place on 13 May 2008. The most significant changes were observed in the frequency content and location of LP events, as well as in volcanic tremor location, that allowed us to track the magma pathway feeding the 2008 eruptive activity. The infrasound showed three different families of events linked to the activity of the three active vents: North-East crater, South-East crater and the eruptive fissure. The seismic and infrasonic variations reported, corroborated by ground deformations variations, help to develop a quantitative prediction and early-warning system for effusive and or explosive eruptions.
    Description: European Union VOLUME FP6-2004-Global-3
    Description: Published
    Description: L18307
    Description: 1.4. TTC - Sorveglianza sismologica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: Mt. Etna Eruption ; volcano seismology ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 7
    Publication Date: 2017-04-04
    Description: Active volcanoes produce inaudible infrasound due to the coupling between surface magmatic processes and the atmosphere. Monitoring techniques based on infrasound measurements have been proved capable of producing information during volcanic crises. We report observations collected from an infrasound network on Mt. Etna which enabled us to detect and locate a new summit eruption on May 13, 2008 when poor weather inhibited direct observations. Three families of signals were identified that allowed the evolution of the eruption to be accurately tracked in real-time. Each family is representative of a different active vent, producing different waveforms due to their varying geometry. Several competitive models have been developed to explain the source mechanisms of the infrasonic events, but according to our studies we demonstrate that two source models coexist at Mt. Etna during the investigated period. Such a monitoring system represents a breakthrough in the ability to monitor and understand volcanic phenomena.
    Description: Published
    Description: L05304
    Description: 1.4. TTC - Sorveglianza sismologica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: Mt. Etna ; infrasound ; eruption ; volcano monitoring ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 8
    Publication Date: 2012-02-03
    Description: Application of light detection and ranging (LIDAR) technology in volcanology has 7 developed rapidly over the past few years, being extremely useful for the generation 8 of high‐spatial‐resolution digital elevation models and for mapping eruption products. 9 However, LIDAR can also be used to yield detailed information about the dynamics of 10 lava movement, emplacement processes occuring across an active lava flow field, and the 11 volumes involved. Here we present the results of a multitemporal airborne LIDAR survey 12 flown to acquire data for an active flow field separated by time intervals ranging from 13 15 min to 25 h. Overflights were carried out over 2 d during the 2006 eruption of Mt. Etna, 14 Italy, coincident with lava emission from three ephemeral vent zones to feed lava flow in 15 six channels. In total 53 LIDAR images were collected, allowing us to track the volumetric 16 evolution of the entire flow field with temporal resolutions as low as ∼15 min and at a 17 spatial resolution of 〈1 m. This, together with accurate correction for systematic errors, 18 finely tuned DEM‐to‐DEM coregistration and an accurate residual error assessment, 19 permitted the quantification of the volumetric changes occuring across the flow field. We 20 record a characteristic flow emplacement mode, whereby flow front advance and channel 21 construction is fed by a series of volume pulses from the master vent. Volume pulses 22 have a characteristic morphology represented by a wave that moves down the channel 23 modifying existing channel‐levee constructs across the proximal‐medial zone and building 24 new ones in the distal zone. Our high‐resolution multitemporal LIDAR‐derived DEMs 25 allow calculation of the time‐averaged discharge rates associated with such a pulsed flow 26 emplacement regime, with errors under 1% for daily averaged values.
    Description: This work was partially funded by the Italian 930 Dipartimento della Protezione Civile in the frame of the 2007–2009 Agree- 931 ment with Istituto Nazionale di Geofisica e Vulcanologia–INGV. A.F. 932 benefited from the MIUR‐FIRB project “Piattaforma di ricerca multi‐disci- 933 plinare su terremoti e vulcani (AIRPLANE)” n. RBPR05B2ZJ. S.T. 934 benefited from the project FIRB “Sviluppo di nuove tecnologie per la prote- 935 zione e difesa del territorio dai rischi naturali (FUMO)” funded by the Italian 936 Ministero dell’Istruzione, dell’Università e della Ricerca.
    Description: Published
    Description: B11203
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 1.10. TTC - Telerilevamento
    Description: 3.6. Fisica del vulcanismo
    Description: JCR Journal
    Description: reserved
    Keywords: LIDAR ; lava flow ; Etna ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 9
    Publication Date: 2017-04-04
    Description: A new method for extracting dissolved gases in natural waters has been developed and tested, both in the laboratory and in the field. The sampling device consists of a polytetrafluroethylene (PTFE) tube (waterproof and gas permeable) sealed at one end and connected to a glass sample holder at the other end. The device is pre-evacuated and subsequently dipped in water, where the dissolved gases permeate through the PTFE tube until the pressure inside the system reaches equilibrium. A theoretical model describing the time variation in partial gas pressure inside a sampling device has been elaborated, combining the mass balance and ‘‘Solution-Diffusion Model’’ which describes the gas permeation process through a PTFE membrane). This theoretical model was used to predict the temporal evolution of the partial pressure of each gas species in the sampling device. The model was validated by numerous laboratory tests. The method was applied to the groundwater of Vulcano Island (southern Italy). The results suggest that the new sampling device could easily extract the dissolved gases from water in order to determine their chemical and isotopic composition.
    Description: - European Social Fund.
    Description: Published
    Description: Q09005
    Description: partially_open
    Keywords: dissolved gases ; helium isotope ; PTFE membrane ; Vulcano Island ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring ; 03. Hydrosphere::03.02. Hydrology::03.02.07. Instruments and techniques ; 04. Solid Earth::04.04. Geology::04.04.11. Instruments and techniques ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 10
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    American Geophysical Union
    Publication Date: 2017-04-04
    Description: Explosion-quake seismograms recorded at Stromboli show that seismic phases with a high-amplitude and high-frequency content propagate with a velocity of approximately 330 m/s - the sound speed. The analysis of seismograms, recorded at a distance of 500 m from one of the three active vents, shows for the first onset a low frequency and particle motion characteristics of a p-wave, which loses its longitudinal polarization with the onset of the air-wave. Recording the explosion-quake simultaneously with a microphonewe would ascertain that the high frequency onset coincides with the air-wave's. In order to better understand the seismic wavefield generated by the atmospheric pressure, we performed a controlled source experiment at Stromboli using a seismic gun. Seismograms with the same two phases and particle motions comparable with the volcanic seismic data were obtained. A second experiment demonstrated, that the air-wave propagates at least in the uppermost 1m of the gound. We suggest that the seismic source of the corresponding seismograms is an explosion at the top of the magma column and conclude that the p- and air-waves are both generated in the same point and at the same time.
    Description: Published
    Description: 65-68
    Description: 1.4. TTC - Sorveglianza sismologica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: volcano seismology ; Stromboli ; air wave ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 11
    Publication Date: 2017-04-04
    Description: The persistent occurrence of long period (LP) events at Mt Etna became apparent with the installation of the first fixed broad-band seismic network in late 2003. Repeating similar LP events from Nov. ‘03 to Sept. ‘04 indicate a non-destructive source process. We perform moment tensor (MT) inversions on a stacked high S/N ratio representative LP signal, conducting a grid search for the source geometry and L2-inversion for the source time function. Results indicate a NNW-SSE oriented resonating sub-vertical crack as the most probable source. This result is consistent with deformation and GPS observations. Crucial to this result are constraints imposed by detailed 3D full waveform numerical simulations in a heterogeneous tomographic model with topography, and in particular a detailed assessment of the influence of very near surface velocity structure on LP signals. Pulsating gas injection is hypothesised as the most likely LP trigger.
    Description: Published
    Description: L22316
    Description: 1.4. TTC - Sorveglianza sismologica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: Etna volcano ; moment tensor inversion ; LP activity ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 12
    Publication Date: 2017-04-04
    Description: Volcanoes deform as a consequence of the rise and storage of magma; once magma reaches a critical pressure, an eruption occurs. However, how the edifice deformation relates to its eruptive behavior is poorly known. Here, we produce a joint interpretation of spaceborne InSAR deformation measurements and volcanic activity at Mt. Etna (Italy), between 1992 and 2006. We distinguish two volcano-tectonic behaviors. Between 1993 and 2000, Etna inflated with a starting deformation rate of 1 cm yr 1 that progressively reduced with time, nearly vanishing between 1998 and 2000; moreover, low-eruptive rate summit eruptions occurred, punctuated by lava fountains. Between 2001 and 2005, Etna deflated, feeding higher-eruptive rate flank eruptions, along with large displacements of the entire East-flank. These two behaviors, we suggest, result from the higher rate of magma stored between 1993 and June 2001, which triggered the emplacement of the dike responsible for the 2001 and 2002–2003 eruptions. Our results clearly show that the joint interpretation of volcano deformation and stored magma rates may be crucial in identifying impending volcanic eruptions.
    Description: This work was partly funded by INGV and the Italian DPC and was supported by ASI, the Preview Project and CRdC-AMRA. DPC-INGV Flank project providing the funds for the publication fees.
    Description: Published
    Description: L02309
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 1.10. TTC - Telerilevamento
    Description: 3.6. Fisica del vulcanismo
    Description: 4.3. TTC - Scenari di pericolosità vulcanica
    Description: 4.5. Degassamento naturale
    Description: JCR Journal
    Description: partially_open
    Keywords: deformation ; eruptions ; Mt. Etna ; eruptive cycle ; InSAR ; 04. Solid Earth::04.01. Earth Interior::04.01.99. General or miscellaneous ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes ; 04. Solid Earth::04.03. Geodesy::04.03.99. General or miscellaneous ; 04. Solid Earth::04.03. Geodesy::04.03.06. Measurements and monitoring ; 04. Solid Earth::04.03. Geodesy::04.03.07. Satellite geodesy ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.07. Tectonophysics::04.07.99. General or miscellaneous ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 13
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    American Geophysical Union
    In:  “Accepted for publication in (Journal of Geophysical Research). Copyright (2009) American Geophysical Union. Further reproduction or electronic distribution is not permitted.”
    Publication Date: 2017-04-04
    Description: The eruptive episode of Mount Etna’s Southeast Crater (SEC) on 16 November 2006, which culminated with phreatomagmatic explosions and a peculiar volcaniclastic flowage event, is the subject of different interpretations. Behncke (2009) and Behncke et al. (2008, 2009), interpret the explosions as resulting from mixing of flowing lava with fluid-saturated, hydrothermally altered rock, and describe the resulting flow as a low-temperature (but potentially deadly) pyroclastic density current (PDC). Norini et al. (2009) speak of gravity-induced flank collapse affecting the SEC cone, leading to the emplacement of a landslide (or debris avalanche) deposit. Finally, Ferlito et al., commenting our recent work (Behncke et al., 2009), re-propose their earlier (2007) scenario of a shallow intrusion from the SEC conduit, caused by unloading and decompression when a part of the SEC cone flank was removed (“sector collapse”), leading to the explosive opening of an eruptive fissure, which discharged a pyroclastic flow. An outstanding feature of this event is that it was not accompanied by any significant change in the seismic signal, which led us (Behncke et al. 2009) to exclude the opening of an eruptive fissure. However, Ferlito et al. point out that seismic evidence alone does not rule out their scenario, and cite the lack of seismic signals accompanying the start of the (rather voluminous, in terms of lava discharge, but purely effusive) 2004-2005 Etna eruption as support for their hypothesis. Finally, they describe what they interpret as the source fissure for the phreatomagmatic explosions and PDCs, and was the site of minor lava extrusion toward the end of the 16 November 2006 event. On their website, Ferlito et al. host a short (〈2 min) clip excerpted from a 40:54 min long video recorded by G. Tomarchio, cameraman of the Italian public television RAI, featuring only the 1425 GMT explosion and PDC. The integral, original version of that video (which was made available to INGV-CT immediately after the event) documents, amongst others, the presence of Behncke and INGV colleagues on-site, and shows a number of extremely similar explosions and PDCs over several hours prior to 1425 GMT, only on a smaller scale. As for the 1425 GMT event, the video spectacularly shows explosive activity, but nothing proving the opening of an eruptive fissure, neither does it show any landsliding as surmised by Norini et al. (2009). Our careful viewing of 1500 still photographs taken of the activity on that day, including nearly 1000 taken by INGV staff, plus other videos taken from different viewpoints (e.g., Movie S3 in the auxiliary material to our article) leads us to analogous conclusions. Videos and photographs document dozens of minor explosive, PDC-generating events before the major phreatomagmatic explosions and PDCs at 1425 GMT. The mechanisms of these events were virtually the same throughout, differing only in their magnitude. All were caused by hot, flowing lava mixing with wet, hydrothermally altered rocks making up the SEC cone’s flank that the lava was burrowing through. The “eruptive fracture” that Ferlito et al. refer to is a secondary feature, formed at the toe of a lava flow, which had flowed down the ESE side of the cone early on 16 November 2006 and was severed around noon by the progressive enlargement of the large scar eroded into the cone’s flank. Draining of the lava within the active channel of the severed flow led to accumulation of lava at the cone’s base, developing into a sort of bubble. For reasons unknown, this bubble drained during the late afternoon, yielding an extremely small flow. The pocket evacuated by this outflow subsided to become what Ferlito et al. interpret as an eruptive fissure, a single slightly elongate collapse depression, lying approximately 150 m northeast of the locus of the 1425 GMT phreatomagmatic explosions, which is well visible in aerial photographs taken after the events under discussion (Figure 1). The lava flow that Ferlito et al. claim to have sampled is the secondary flow formed by the draining of the pocket. It has no whatsoever genetic relationship with the phreatomagmatic explosions and PDCs of 1425 GMT. Another fundamental argument lies in the seismic record, and it is here that Ferlito et al. miss two major points. Firstly, unlike the seismic scenario usually observed at Etna in more than three decades of monitoring (e.g., Patanè et al., 2004), the start of the 2004-2005 lava effusion was exceptionally silent as many authors noted (e.g., Burton et al., 2005; Di Grazia et al., 2006; Corsaro et al., 2009). The onset of lava emission was indeed completely and unusually aseismic (in terms of volcano-tectonic seismicity, volcanic tremor changes, etc.), but it was also totally non-explosive, due to the nearly complete depletion in gas of the magma. Therefore, this effusive episode stands in marked contrast with the 16 November 2006 activity. It should be noted that when new, gas-rich magma moved toward the surface at a later stage of the 2004-2005 lava effusion, the volcanic tremor amplitude markedly increased (Di Grazia et al., 2006). Secondly, Ferlito et al. refer to papers (e.g., Cardaci et al., 1993; Patanè et al., 2004) which deal with the relationship between volcano-tectonic (VT) seismicity and the triggering of eruptive activity at Etna. VT seismicity covers just a part of the information contained in a seismic record (e.g., McNutt, 2000), a detail which can be easily missed by non-experts in seismology. There is indeed a variety of signals (e.g., long-period events, hybrid events, volcanic tremor, explosion quakes) related to the movement of fluids and/or magma, which can herald and accompany the opening of eruptive fractures. We did extensive cross-checking of the seismic record of the entire 2006 eruptive sequence, paying particular attention to episodes of new eruptive fissures opening. Each single event marked by the opening of new vents displaying some sort of explosive activity (this occurred during at least four of the paroxysms during the August-December 2006 eruptive sequence) shows conspicuous changes not only in the amplitude of the seismic (tremor) signal, but also in the location of the centroid of the tremor source, and frequency content, features amply discussed in our paper (Behncke et al., 2009). The migration of subsurface magma can thus be well documented, if it is accompanied by degassing. We would also like to point out that the phreatomagmatic explosions and PDCs of 1425 GMT occurred shortly after a conspicuous drop in the volcanic tremor amplitude (see Fig. 8 in Behncke et al., 2009). The lack of changes in the seismic signals concurrent with the PDC is also evident in the spectrograms (in which the frequency content excludes the occurrence of any seismic signals associated with fracturing, see Fig. 9 in Behncke et al., 2009) and in the records of all the broadband stations considered by Behncke et al. (2009), notwithstanding their vicinity to the site of the PDC-generating explosions (EBEL and ECPN are located ~1 km from the SEC, at 2899 and 3050 m elevation above sea level, respectively). Finally, the hypothesis of magma uprise at the base of the SEC cone caused by unloading related to the removal of a major portion of the cone’s flank, has been vested by Ferlito et al. (2007) in a volcanic sector collapse scenario similar to the catastrophic 1980 debris avalanche at Mount St. Helens. Volcanic sector collapse commonly takes place instantaneously, which is the contrary of what happened at the SEC on 16 November 2006. Thanks to our presence on site from the early morning onward, we were able to document how the removal of a portion of the flank of the cone occurred extremely slowly, over at least 5 hours (cf. Fig. 5 in Behncke et al., 2008). The material involved in this displacement moved at best at 50-80 m per hour, which is rather unlike the speed of volcanic debris avalanches. There was no such thing as a major landslide, and no such thing as a new eruptive fissure opening; what did happen was a very hazardous sequence of events, including phreatomagmatic explosions and quite low-temperature but fast-moving, dense pyroclastic density currents. Such volcanic phenomena deserve in-depth multidisciplinary studies, and the ongoing discussion underscores how much work is still necessary to better understand the dynamics of a versatile volcano such as Mount Etna.
    Description: Published
    Description: B12205
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: JCR Journal
    Description: open
    Keywords: Volcano monitoring ; Mt. Etna ; Volcanic hazard ; instruments and techniques ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology
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  • 14
    Publication Date: 2017-04-04
    Description: Forecasting the time, nature, and impact of future eruptions is difficult at volcanoes such as Mount Etna, in Italy, where eruptions occur from the summit and on the flanks, affecting areas distant from each other. Nonetheless, the identification and quantification of areas at risk from new eruptions are fundamental for mitigating potential human casualties and material damage. Here, we present new results from the application of a methodology to define flexible high‐resolution lava invasion susceptibility maps based on a reliable computational model for simulating lava flows at Etna and on a validation procedure for assessing the correctness of susceptibility mapping in the study area. Furthermore, specific scenarios can be extracted at any time from the simulation database, for land use and civil defense planning in the long term, to quantify, in real time, the impact of an imminent eruption, and to assess the efficiency of protective measures.
    Description: This work was sponsored by the Italian Ministry for Education, University and Research, FIRB project RBAU01RMZ4 “Lava flow simulations by Cellular Automata,” and by the National Civil Defense Department and INGV (National Institute of Geophysics and Volcanology), project V3_6/09 “V3_6 – Etna.”
    Description: Published
    Description: B04203
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: 3.6. Fisica del vulcanismo
    Description: 4.3. TTC - Scenari di pericolosità vulcanica
    Description: 4.4. Scenari e mitigazione del rischio ambientale
    Description: JCR Journal
    Description: reserved
    Keywords: lava flows ; volcanic hazard ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.03. Geomorphology ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.01. Computational geophysics::05.01.02. Cellular automata, fuzzy logic, genetic alghoritms, neural networks ; 05. General::05.01. Computational geophysics::05.01.05. Algorithms and implementation ; 05. General::05.02. Data dissemination::05.02.99. General or miscellaneous ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions ; 05. General::05.08. Risk::05.08.99. General or miscellaneous ; 05. General::05.09. Miscellaneous::05.09.99. General or miscellaneous
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  • 15
    Publication Date: 2017-04-04
    Description: In the text
    Description: Published
    Description: 219-224
    Description: 1.4. TTC - Sorveglianza sismologica delle aree vulcaniche attive
    Description: JCR Journal
    Description: open
    Keywords: coda Q ; Phlegraean Fielsa ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology
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  • 16
    Publication Date: 2017-04-04
    Description: Repeated phenomena of flank instability accompanied the 28 December 2002 to 21 July 2003 eruption of Stromboli volcano. The major episodes were two tsunamigenic landslides on 30 December 2002, 2 d after the volcano unrest. After 30 December, sliding processes remodeled the area affected by slope instability.We propose analyses of 565 sliding episodes taking place from December 2002 to February 2003.We try to shed light on their main seismic features and links with the ongoing seismic and volcanic activity using variogram analysis as well. A characterization of the seismic signals in the time and frequency domains is presented for 185 sliding episodes. Their frequency content is between 1 Hz and 7 Hz. On the basis of the dominant peaks and shape of the spectrum, we identify three subclasses of signals, one of which has significant energy below 2 Hz. Low-frequency signatures were also found in the seismic records of the landslides of 30 December, which affected the aerial and submarine northwestern flank of the volcano. Accordingly, we surmise that spectral analysis might provide evidence of sliding phenomena with submarine runouts.We find no evidence of sliding processes induced by earthquakes. Additionally, a negative statistical correlation between sliding episodes and explosion quakes is highlighted by variogram analysis. Variograms indicate a persistent behavior, memory, of the flank instability from 5 to 10 d.We interpret the climax in the occurrence rate of the sliding processes between 24 and 29 January 2003 as the result of favorable conditions to slope instability due to the emplacement of NW-SE aligned, dike-fed vents located near the scarp of the landslide area. Afterward, the stabilizing effect of the lava flows over the northwestern flank of the volcano limited erosive phenomena to the unstable, loose slope not covered by lava.
    Description: This work was supported financially by Istituto Nazionale di Geofisica e Vulcanologia and Dipartimento per la Protezione Civile, project INGV-DPC V4/02.
    Description: Published
    Description: Q04022
    Description: 1.4. TTC - Sorveglianza sismologica delle aree vulcaniche attive
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 3.6. Fisica del vulcanismo
    Description: JCR Journal
    Description: reserved
    Keywords: rockfalls ; seismicity ; volcanoes ; volcano collapses ; Stromboli ; 04. Solid Earth::04.06. Seismology::04.06.99. General or miscellaneous ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 04. Solid Earth::04.07. Tectonophysics::04.07.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
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  • 17
    Publication Date: 2017-04-04
    Description: Geological surveys, tephrostratigraphic study, and 40Ar/39Ar age determinations have allowed us to chronologically constrain the geological evolution of the lower NW flank of Etna volcano and to reconstruct the eruptive style of the Mt Barca flank eruption. This peripheral sector of the Mt Etna edifice, corresponding to the upper Simeto valley, was invaded by the Ellittico volcano lava flows between 41 and 29 ka ago when the Mt Barca eruption occurred. The vent of this flank eruption is located at about 15 km away from the summit craters, close to the town of Bronte. The Mt Barca eruption was characterized by a vigorous explosive activity that produced pyroclastic deposits dispersed eastward and minor effusive activity with the emission of a 1.1-km-long lava flow. Explosive activity was characterized by a phreatomagmatic phase followed by a magmatic one. The geological setting of this peripheral sector of the volcano favors the interaction between the rising magma and the shallow groundwater hosted in the volcanic pile resting on the impermeable sedimentary basement. This process produced phreatomagmatic activity in the first phase of the eruption, forming a pyroclastic fall deposit made of high-density, poorly vesicular scoria lapilli and lithic clasts. Conversely, during the second phase, a typical strombolian fall deposit formed. In terms of hazard assessment, the possible occurrence of this type of highly explosive flank eruption, at lower elevation in the densely inhabited areas, increases the volcanic risk in the Etnean region and widens the already known hazard scenario.
    Description: INGV-DPC V3_6 project UR V3_6/07
    Description: In press
    Description: on line first
    Description: 3.5. Geologia e storia dei sistemi vulcanici
    Description: JCR Journal
    Description: reserved
    Keywords: Etna volcano ; unconformity ; tephostratigraphy ; 40Ar/39Ar age determination ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 18
    Publication Date: 2017-04-04
    Description: Kostrov's (1974) algorithm for seismic-strain tensor computations, in the version implemented by Wyss et al. (1992a) for error estimates, has been applied to shear-type earthquakes occurring beneath the Etna volcano during 1990-1996. Space-time variations of strain orientations and amplitudes have been examined jointly with ground-deformation and gravimetric data collected in the same period and reported in the literature. Taking also into account the information available from volcanological observations and structural geology, we propose a model assuming that hydraulic pressure by magma emplaced in nearly north-south vertical structures produces the E-W orientation of the maximum compressive strain found in the upper 10 km beneath the crater area. In contrast, regional tectonics deriving from the slow, north-south convergence between the African and European plates appear to play a dominant role in the generation of stress and strain fields at crustal depths deeper than 10 km below the volcano. According to our interpretation, the progressive ascent of magma through the upper crust prior to eruption produces the observed gravity changes, cone inflation and unusual seismic strain rate in the upper 10 km associated with a more sharply defined seismic deformation regime (i.e. very small confidence limits of the epsilon 1 orientation). In agreement with this model, deflation revealed by ground-deformation data during the course of the major 1991-1993 eruption was accompanied by a practically nil level of shallow seismicity.
    Description: Published
    Description: 318-330
    Description: JCR Journal
    Description: open
    Keywords: Mt. Etna ; Italy ; Earthquakes ; Seismic strain ; Stress inversion ; Volcanic processes ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 19
    Publication Date: 2017-04-04
    Description: The period September–November 2007 was characterized at Mount Etna by explosive activity and intense degassing. During this time interval, infrasonic signals were recorded by an infrasonic network. By a triggering procedure, about 1000 infrasonic events were found, characterized by very high signal-to-noise ratio and grouped into nine families. Successively, the spectral analysis allowed subdividing these nine families into three clusters based on the peak frequency and the quality factor of the events. Finally, by the location analysis a cluster (cluster 1) was related to the degassing activity of the northeast crater (NEC), while the other two (clusters 2 and 3) to the explosive activity of the southeast crater (SEC). The comparison between the stacked infrasonic waveforms, interpreted as generated by the vibration of large gas bubbles, and the synthetic ones, permitted to calculate radius, length of the bubble, and initial overpressure, by a genetic algorithm method. The higher overpressure values of cluster 3 compared to the cluster 2 values were in good agreement with the stronger intensity of the explosions accompanying the infrasonic events of cluster 3. The variation of both intensities and waveforms is tentatively attributed to the occasional accumulation of lithic clasts (due to moderate landslides?) on the explosive vent. Indeed, events belonging to cluster 3 were no longer observed once the landslides had ended. Finally, the daily emitted gas volume, related to the active degassing, was estimated for NEC and SEC by using the infrasonic data during the studied period.
    Description: Published
    Description: B08308
    Description: 1.4. TTC - Sorveglianza sismologica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: Mt. Etna ; Infrasound ; volcano monitoring ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 20
    Publication Date: 2012-02-03
    Description: An edited version of this paper was published by AGU. Copyright (2010) American Geophysical Union
    Description: Seismic, deformation, and volcanic gas observations offer independent and complementary information on the activity state and dynamics of quiescent and eruptive volcanoes and thus all contribute to volcanic risk assessment. In spite of their wide use, there have been only a few efforts to systematically integrate and compare the results of these different monitoring techniques. Here we combine seismic (volcanic tremor and long‐period seismicity), deformation (GPS), and geochemical (volcanic gas plume CO2/SO2 ratios) measurements in an attempt to interpret trends in the recent (2007–2008) activity of Etna volcano. We show that each eruptive episode occurring at the Southeast Crater (SEC) was preceded by a cyclic phase of increase‐decrease of plume CO2/SO2 ratios and by inflation of the volcano’s summit captured by the GPS network. These observations are interpreted as reflecting the persistent supply of CO2‐rich gas bubbles (and eventually more primitive magmas) to a shallow (depth of 1–2.8 km asl) magma storage zone below the volcano’s central craters (CCs). Overpressuring of the resident magma stored in the upper CCs’ conduit triggers further magma ascent and finally eruption at SEC, a process which we capture as an abrupt increase in tremor amplitude, an upward (〉2800 m asl) and eastward migration of the source location of seismic tremor, and a rapid contraction of the volcano’s summit. Resumption of volcanic activity at SEC was also systematically anticipated by declining plume CO2/SO2 ratios, consistent with magma degassing being diverted from the central conduit area (toward SEC).
    Description: Published
    Description: Q09008
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 1.3. TTC - Sorveglianza geodetica delle aree vulcaniche attive
    Description: 1.4. TTC - Sorveglianza sismologica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: volcano monitoring ; Mt. Etna volcano ; geochemistry and geophysics ; volcanic tremor ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
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  • 21
    Publication Date: 2012-02-03
    Description: Influences of distant earthquakes on volcanic systems by dynamic stress transfer are well documented. We analyzed seismic signals and volcanic activity at Mount Etna during two periods, January 2006 and May 2008, that clearly showed variations coincident with distant earthquakes. In the first period, characterized by mild volcano activity, the effect of the dynamic stress transfer, caused by an earthquake in Greece (M = 6.8), was twofold: (1) banded tremor activity changed its features and almost disappeared; (2) a swarm of volcano‐tectonic (VT) earthquakes took place. The changes of the banded tremor were likely due to variations in rock permeability, caused by fluid flows driven by dynamic strain. The VT earthquake swarm probably developed as a secondary process, promoted by the dynamically triggered activation of magmatic fluids. The second period, May 2008, showed an intense explosive activity. During this interval, the dynamic stress transfer, associated with the arrival of the seismic waves of the Sichuan earthquake (M = 7.9), affected the character of the seismo‐volcanic signals and on the following day triggered an eruption. In particular, we observed changes in volcanic tremor and increases of both occurrence rate and energy of long period events. In this case, we suggest that dynamic stress transfer caused nucleation of new bubbles in volatile‐rich magma bodies with consequent buildup of pressure, highlighted by the increase of long period activity, followed by the occurrence of an eruption. We conclude that stresses from distant earthquakes are capable of modifying the state of the volcano.
    Description: Published
    Description: B12304
    Description: 1.4. TTC - Sorveglianza sismologica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: Mt. Etna volcano ; dynamic stress transfer ; triggered eruption ; triggered seismicity ; volcano seismology ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 22
    Publication Date: 2012-02-03
    Description: An edited version of this paper was published by AGU. Copyright (2010) American Geophysical Union.
    Description: Volcano deformation may occur under different conditions. To understand how a volcano deforms, as well as relations with magmatic activity, we studied Mt. Etna in detail using interferometric synthetic aperture radar (InSAR) data from 1994 to 2008. From 1994 to 2000, the volcano inflated with a linear behavior. The inflation was accompanied by eastward and westward slip on the eastern and western flanks, respectively. The portions proximal to the summit showed higher inflation rates, whereas the distal portions showed several sectors bounded by faults, in some cases behaving as rigid blocks. From 2000 to 2003, the deformation became nonlinear, especially on the proximal eastern and western flanks, showing marked eastward and westward displacements, respectively. This behavior resulted from the deformation induced by the emplacement of feeder dikes during the 2001 and 2002–2003 eruptions. From 2003 to 2008, the deformation approached linearity again, even though the overall pattern continued to be influenced by the emplacement of the dikes from 2001 to 2002. The eastward velocity on the eastern flank showed a marked asymmetry between the faster sectors to the north and those (largely inactive) to the south. In addition, from 1994 to 2008 part of the volcano base (south, west, and north lower slopes) experienced a consistent trend of uplift on the order of ∼0.5 cm/yr. This study reveals that the flanks of Etna have undergone a complex instability resulting from three main processes. In the long term (103–104 years), the load of the volcano is responsible for the development of a peripheral bulge. In the intermediate term (≤101 years, observed from 1994 to 2000), inflation due to the accumulation of magma induces a moderate and linear uplift and outward slip of the flanks. In the short term (≤1 year, observed from 2001 to 2002), the emplacement of feeder dikes along the NE and south rifts results in a nonlinear, focused, and asymmetric deformation on the eastern and western flanks. Deformation due to flank instability is widespread at Mt. Etna, regardless of volcanic activity, and remains by far the predominant type of deformation on the volcano.
    Description: ESA provided the SAR data (Cat‐1 no. 4532 and GEO Supersite initiative). The DEM was obtained from the SRTM archive, while the ERS‐1/2 orbits are courtesy of the TU‐Delft, The Netherlands. This work was partially funded by INGV and the Italian DPC (DPCINGV project V4 “Flank”), the Italian DPC (under special agreement with IREA‐CNR), and the Italian Space Agency under contract “sistema rischio vulcanico (SRV).” The authors thank Francesco Casu, Paolo Berardino, and Riccardo Lanari for their support and Geoff Wadge and Michael Poland for their helpful and constructive review of the manuscript.
    Description: Published
    Description: B10405
    Description: 1.3. TTC - Sorveglianza geodetica delle aree vulcaniche attive
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 1.10. TTC - Telerilevamento
    Description: 3.2. Tettonica attiva
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: 3.6. Fisica del vulcanismo
    Description: 4.3. TTC - Scenari di pericolosità vulcanica
    Description: JCR Journal
    Description: reserved
    Keywords: Flank instability ; InSAR ; volcanoes ; Etna ; 04. Solid Earth::04.01. Earth Interior::04.01.99. General or miscellaneous ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes ; 04. Solid Earth::04.02. Exploration geophysics::04.02.99. General or miscellaneous ; 04. Solid Earth::04.03. Geodesy::04.03.99. General or miscellaneous ; 04. Solid Earth::04.03. Geodesy::04.03.06. Measurements and monitoring ; 04. Solid Earth::04.03. Geodesy::04.03.07. Satellite geodesy ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.06. Rheology, friction, and structure of fault zones ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.07. Tectonophysics::04.07.99. General or miscellaneous ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.05. Stress ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions ; 05. General::05.04. Instrumentation and techniques of general interest::05.04.99. General or miscellaneous ; 05. General::05.08. Risk::05.08.99. General or miscellaneous
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  • 23
    Publication Date: 2017-04-04
    Description: During 1991−93 at Mount Etna, long-period (LP) events occurring in swarms characterized the evolution of the eruption. The presence of multiplets i.e. groups of events with similar waveform signatures, has been recognized within this activity. Traditional techniques for locating LP events do not allow obtaining reliable hypocenters, which have only succeeded in placing earthquakes in a roughly 1 km2 area slightly east of the Mt. Etna Northeast Crater. Hypocenters have been relocated in two steps: the absolute location has been improved using Thurber’s code and a complex 3D velocity model; a highly precise relative location has been applied on multiplets to define the source geometry. 3D locations and high precision analysis suggest that during the 1991−93 eruption the resonator producing LP events was a part of the uppermost Northeast Crater conduit, measuring 210 meters in height and 45−50 meters in diameter.
    Description: Published
    Description: 663-674
    Description: reserved
    Keywords: waveform correlation ; stacked events ; 1991−93 eruption ; conduct geometry ; Mt. Etna Northeast Crater ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous
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  • 24
    Publication Date: 2017-04-04
    Description: We present an updated geological evolution of Mount Etna volcano based on new 40Ar/39Ar age determinations and stratigraphic data integrating the previous K/Ar ages. Volcanism began at about 500 ka ago through submarine eruptions on the Gela–Catania Foredeep basin. About 300 ka ago fissure-type eruptions occurred on the ancient alluvial plain of the Simeto River forming a lava plateau. From about 220 ka ago the eruptive activity was localised mainly along the Ionian coast where fissure-type eruptions built a shield volcano. Between 129 and 126 ka ago volcanism shifted westward toward the central portion of the present volcano (Val Calanna–Moscarello area). Furthermore, scattered effusive eruptions on the southern periphery of Etna edifice occurred until about 121 ka ago. The stabilization of the plumbing system on the Valle del Bove area is marked by the building of two small polygenic edifices, Tarderia and Rocche volcanoes. Their eruptive activity was rather coeval ending 106 and 102 ka ago, respectively. During the investigated time-span volcanism in Etna region was controlled by a main E–W extensional tectonic related to the reactivation of Malta Escarpment fault system in eastern Sicily.
    Description: Published
    Description: On line First
    Description: 3.5. Geologia e storia dei sistemi vulcanici
    Description: JCR Journal
    Description: reserved
    Keywords: Mount Etna ; 40Ar/39Ar dating ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous
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  • 25
    Publication Date: 2017-04-04
    Description: The 2002–2003 Etna eruption is studied through earthquake distributions and surface fracturing. In September 2002, earthquake-induced surface rupture (sinistral offset 0.48 m) occurred along the E-W striking Pernicana Fault (PF), on the NE flank. In late October, a flank eruption accompanied further ( 0.77 m) surface rupturing, reaching a total sinistral offset of 1.25 m; the deformation then propagated for 18 km eastwards to the coastline (sinistral offset 0.03 m) and southwards, along the NW-SE striking Timpe (dextral offset 0.04 m) and, later, Trecastagni faults (dextral offset 0.035 m). Seismicity (〈4 km bsl) on the E flank accompanied surface fracturing: fault plane solutions indicate an overall ESEWNWextension direction, consistent with ESE slip of the E flank also revealed by ground fractures. A three-stage model of flank slip is proposed: inception (September earthquake), climax (accelerated slip and eruption) and propagation (E and S migration of the deformation).
    Description: Published
    Description: 2286
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 3.2. Tettonica attiva
    Description: 3.5. Geologia e storia dei sistemi vulcanici
    Description: 3.6. Fisica del vulcanismo
    Description: 4.3. TTC - Scenari di pericolosità vulcanica
    Description: JCR Journal
    Description: reserved
    Keywords: volcano seismology ; surface fracturing ; flank slip ; eruption ; Etna ; 04. Solid Earth::04.01. Earth Interior::04.01.99. General or miscellaneous ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes ; 04. Solid Earth::04.02. Exploration geophysics::04.02.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.06. Seismology::04.06.99. General or miscellaneous ; 04. Solid Earth::04.06. Seismology::04.06.01. Earthquake faults: properties and evolution ; 04. Solid Earth::04.06. Seismology::04.06.02. Earthquake interactions and probability ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 04. Solid Earth::04.06. Seismology::04.06.11. Seismic risk ; 04. Solid Earth::04.07. Tectonophysics::04.07.99. General or miscellaneous ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.05. Stress ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 26
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    American Geophysical Union
    In:  An edited version of this paper was published by AGU. Copyright (2009) American Geophysical Union
    Publication Date: 2017-04-04
    Description: Three eruptive episodes during the 2006 summit eruptions of Mount Etna were exceptionally well documented by visual, seismic and thermal monitoring. The first (16 November) was strongly explosive, with vigorous Strombolian activity and ash emission from multiple vents, lava emission, and phreatomagmatic explosions generating pyroclastic density currents (PDCs). The second episode (19 November) had a rather weakly explosive component, with mild Strombolian activity but more voluminous lava emission. The third (24 November) was a moderately explosive paroxysm, with intermittent lava fountaining and generation of a tephra column as well as lava emission and PDCs. Data recorded by a thermal monitoring camera clearly document the different phases of each paroxysm, weather clouds occasionally hampering thermal monitoring. The images show a rapid onset of the volcanic activity, which during each of the paroxysms reached a peak in eruptive and thermal intensity, and then decreased gradually. The stronger phreatomagmatic explosions and PDCs on 16 and 24 November did not yield any seismic signature linked to the opening of new vents, nor were they associated with peculiar characteristics of the seismic signal. Nevertheless, eruptive styles (Strombolian activity, lava emission) and different levels in the intensity of explosive activity were generally well reflected in the amplitude and frequency content of the seismic signal, and in the source location of the volcanic tremor centroid throughout the three eruptive episodes. This multidisciplinary study, therefore, not only provides a key to distinguish between endogenous and exogenous origins of the phenomena observed, but also documents the complex magma dynamics within the volcano.
    Description: Published
    Description: B03211
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: JCR Journal
    Description: reserved
    Keywords: Volcano monitoring ; Mt Etna ; volcanic hazard ; instruments and techniques ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 27
    Publication Date: 2017-04-04
    Description: Forecasting the time, nature and impact of future eruptions is difficult at volcanoes such as Mount Etna, in Italy, where eruptions occur from the summit and on the flanks, affecting areas distant from each other. Nonetheless, the identification and quantification of areas at risk from new eruptions is fundamental for mitigating potential human casualties and material damage. Here, we present new results from the application of a methodology to define flexible high-resolution lava invasion susceptibility maps based on a reliable computational model for simulating lava flows at Etna and on a validation procedure for assessing the correctness of susceptibility mapping in the study area. Furthermore, specific scenarios can be extracted at any time from the simulation database, for land-use and civil defence planning in the long-term, to quantify, in real-time, the impact of an imminent eruption, and to assess the efficiency of protective measures.
    Description: This work was sponsored by the Italian Ministry for Education, University and Research, FIRB project n° RBAU01RMZ4 “Lava flow simulations by Cellular Automata”, and by the National Civil Defence Department and INGV (National Institute of Geophysics and Volcanology), project V3_6/09 “V3_6 – Etna”.
    Description: In press
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: 3.6. Fisica del vulcanismo
    Description: 4.3. TTC - Scenari di pericolosità vulcanica
    Description: 4.4. Scenari e mitigazione del rischio ambientale
    Description: JCR Journal
    Description: open
    Keywords: lava flows ; Etna ; hazard evaluation ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.01. Computational geophysics::05.01.99. General or miscellaneous ; 05. General::05.01. Computational geophysics::05.01.02. Cellular automata, fuzzy logic, genetic alghoritms, neural networks ; 05. General::05.02. Data dissemination::05.02.99. General or miscellaneous ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions ; 05. General::05.08. Risk::05.08.99. General or miscellaneous ; 05. General::05.09. Miscellaneous::05.09.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 28
    Publication Date: 2017-04-04
    Description: We have found experimental evidence which shows that the volcanic tremor recorded at Deception Island (South Shetland Islands, Antarctica) is a superposition in time of overlapping hybrid events.
    Description: Published
    Description: 3069-3072
    Description: 3.1. Fisica dei terremoti
    Description: JCR Journal
    Description: reserved
    Keywords: Arrays ; volcanictremor ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 29
    Publication Date: 2017-04-04
    Description: In this work, waveform variations in repeating volcanotectonic earthquakes occurring from 2001–2009 in the northeastern flank of Mt. Etna were studied. Changes in waveform were found mainly during 2002–2003; and consisted of a decreasing similarity in the coda of events in earthquake families, as revealed by cross-correlation analysis, and delays, increasing proportionally to the lapse time, detected by coda wave interferometry. Such variations, mainly evident at stations located in the north-eastern flank of the volcano, were likely due to medium changes taking place within this region. Localized medium velocity decreases were inferred to occur in 2002–2003, followed by successive increases. The velocity decrease was interpreted as being caused by the opening or enlargement of cracks, produced by intruding magma bodies, intense ground deformation, and/ or VT earthquake activity that accompanied the 2002–2003 Mt. Etna eruption. On the other hand, subsequent velocity increases were interpreted as resulting from healing processes.
    Description: Published
    Description: L18311
    Description: 1.4. TTC - Sorveglianza sismologica delle aree vulcaniche attive
    Description: JCR Journal
    Description: restricted
    Keywords: coda wave interferometry ; Etna ; VT earthquakes ; Pernicana fault ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 30
    Publication Date: 2017-04-04
    Description: Since the second half of the 1990s, the eruptive activity of Mount Etna has provided evidence that both explosive and effusive eruptions display periodic variations in discharge and eruption style. In this work, a multiparametric approach, consisting of comparing volcanological, geophysical, and geochemical data, was applied to explore the volcano's dynamics during 2009–2011. In particular, temporal and/or spatial variations of seismicity (volcano-tectonic earthquakes, volcanic tremor, and long-period and very long period events), ground deformation (GPS and tiltmeter data), and geochemistry (SO2 flux, CO2 flux, CO2/SO2 ratio) were studied to understand the volcanic activity, as well as to investigate magma movement in both deep and shallow portions of the plumbing system, feeding the 2011 eruptive period. After the volcano deflation, accompanying the onset of the 2008–2009 eruption, a new recharging phase began in August 2008. This new volcanic cycle evolved from an initial recharge phase of the intermediate-shallower plumbing system and inflation, followed by (i) accelerated displacement in the volcano's eastern flank since April 2009 and (ii) renewal of summit volcanic activity during the second half of 2010, culminating in 2011 in a cyclic eruptive behavior with 18 lava fountains from New Southeast Crater (NSEC). Furthermore, supported by the geochemical data, the inversion of ground deformation GPS data and the locations of the tremor sources are used here to constrain both the area and the depth range of magma degassing, allowing reconstructing the intermediate and shallow storage zones feeding the 2011 cyclic fountaining NSEC activity.
    Description: Published
    Description: 3519–3539
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: JCR Journal
    Description: restricted
    Keywords: Mt Etna ; seismology ; ground deformation ; geochemistry ; volcanology ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 31
    Publication Date: 2017-04-04
    Description: Active volcanoes characterized by open conduit conditions generate sonic and infrasonic signals, whose investigation provides useful information for both monitoring purposes and studying the dynamics of explosive processes. In this work, we discuss the automatic procedures implemented for a real-time application to the data acquired by a permanent network of five infrasound stations running at Mt. Etna volcano. The infrasound signals at Mt. Etna consist in amplitude transients, called infrasound events. The adopted procedure uses a multi-algorithm approach for event detection, counting, characterization and location. It is designed for an efficient and accurate processing of infrasound records provided by single-site and array stations. Moreover, the source mechanism of these events can be investigated off-line or in near real-time by using three different models: (1) Strombolian bubble; (2) resonating conduit and (3) Helmholtz resonator. The infrasound waveforms allow us to choose the most suitable model, to get quantitative information about the source and to follow the time evolution of the source parameters.
    Description: Published
    Description: 1215–1231
    Description: 1.4. TTC - Sorveglianza sismologica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: Infrasound ; monitoring system ; Mt. Etna volcano ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 32
    Publication Date: 2017-04-04
    Description: We investigated the banded tremor activity occurring at Mt. Etna volcano between August-October 2008 during the 2008-2009 eruption. The banded tremor occurred in episodes lasting 25-30 minutes with intervals in between the episodes of about 25 minutes. Seismic signal analyses showed that the banded tremor was characterised by spectral contents, wavefields and source locations that differed from the “ordinary” volcanic tremor. The infrasound recordings exhibited an intermittent infrasonic tremor alternating with the banded tremor episodes. Finally, nonlinear analyses suggested that banded tremor system can be considered chaotic, implying: i) sensitive dependence on initial conditions, suggesting not only that a banded tremor system requires particular conditions to generate, but also that slight variations of these conditions are able to greatly change the features of the banded tremor or even to stop it; ii) long-term unpredictability, that is, the impossibility to forecast the long-term evolution of the banded tremor. On the basis of all these results and analogies with geyser models, we suggest a model of banded tremor that invokes alternating recharge-discharge phases. Banded tremor is due to “perturbations” in shallow aquifers, such as fluid movement and bubble growth or collapse due to hydrothermal boiling, triggered by the heat and hot fluid transfer from the underlying magma bodies. This heat-fluid transfer also causes an increasing pressure in the aquifer leading to fluid-discharge. During this process the seismic radiation decreases and, if the fluid-discharge is well coupled with the atmosphere, acoustic signals are generated.
    Description: Published
    Description: 1.4. TTC - Sorveglianza sismologica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: Banded tremor ; Mt. Etna volcano ; volcano seismology ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 33
    Publication Date: 2017-04-04
    Description: This paper presents a magnetotelluric (MT) survey of the unstable eastern flank of Mt. Etna. We take thirty soundings along two profiles oriented in the N-S and NW-SE directions, and from these data recover two 2D resistivity models of the subsurface. Both models reveal three major layers in a resistive-conductive-resistive sequence, the deepest extending to 14 km bsl. The shallow layer corresponds to the volcanic cover, and the intermediate conductive layer corresponds to underlying sediments segmented by faults. These two electrical units are cut by E-W-striking faults. The third layer (basement) is interpreted as mainly pertinent to the Apennine-Maghrebian Chain associated with SW-NE-striking regional faults. The detailed shapes of the resistivity profiles clearly show that the NE Rift is shallow-rooted ( 0–1 km bsl), thus presumably fed by lateral dikes from the central volcano conduit. The NW-SE profile suggests by a series of listric faults reaching up to 3 km bsl, then becoming almost horizontal. Toward the SE, the resistive basement dramatically dips (from 3 km to 10 km bsl), in correspondence with the Timpe Fault System. Several high-conductivity zones close to the main faults suggest the presence of hydrothermal activity and fluid circulation that could enhance flank instability. Our results provide new findings about the geometry of the unstable Etna flank and its relation to faults and subsurface structures.
    Description: This paper presents a magnetotelluric (MT) survey of the unstable eastern flank of Mt. Etna. We take thirty soundings along two profiles oriented in the N-S and NW-SE directions, and from these data recover two 2D resistivity models of the subsurface. Both models reveal three major layers in a resistive-conductive-resistive sequence, the deepest extending to 14 km bsl. The shallow layer corresponds to the volcanic cover, and the intermediate conductive layer corresponds to underlying sediments segmented by faults. These two electrical units are cut by E-W-striking faults. The third layer (basement) is interpreted as mainly pertinent to the Apennine-Maghrebian Chain associated with SW-NE-striking regional faults. The detailed shapes of the resistivity profiles clearly show that the NE Rift is shallow-rooted ( 0–1 km bsl), thus presumably fed by lateral dikes from the central volcano conduit. The NW-SE profile suggests by a series of listric faults reaching up to 3 km bsl, then becoming almost horizontal. Toward the SE, the resistive basement dramatically dips (from 3 km to 10 km bsl), in correspondence with the Timpe Fault System. Several high-conductivity zones close to the main faults suggest the presence of hydrothermal activity and fluid circulation that could enhance flank instability. Our results provide new findings about the geometry of the unstable Etna flank and its relation to faults and subsurface structures.
    Description: Published
    Description: B03216
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 3.2. Tettonica attiva
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: JCR Journal
    Description: restricted
    Keywords: Etna ; magnetotelluric ; flank instability ; volcano ; 04. Solid Earth::04.01. Earth Interior::04.01.99. General or miscellaneous ; 04. Solid Earth::04.02. Exploration geophysics::04.02.99. General or miscellaneous ; 04. Solid Earth::04.02. Exploration geophysics::04.02.04. Magnetic and electrical methods ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.05. Geomagnetism::04.05.99. General or miscellaneous ; 04. Solid Earth::04.07. Tectonophysics::04.07.99. General or miscellaneous ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous
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  • 34
    Publication Date: 2017-04-04
    Description: We produce a spatial probability map of vent opening (susceptibility map) at Etna, using a statistical analysis of structural features of flank eruptions of the last 2 ky. We exploit a detailed knowledge of the volcano structures, including the modalities of shallow magma transfer deriving from dike and dike-fed fissure eruptions analysis on historical eruptions. Assuming the location of future vents will have the same causal factors as the past eruptions, we converted the geological and structural data in distinct and weighted probability density functions, which were included in a non-homogeneous Poisson process to obtain the susceptibility map. The highest probability of new eruptive vents opening falls within a N-S aligned area passing through the Summit Craters down to about 2,000 ma.s.l. on the southern flank. Other zones of high probability follow the North-East, East-North-East, West, and South Rifts, the latter reaching low altitudes (∼400 m). Less susceptible areas are found around the faults cutting the upper portions of Etna, including the western portion of the Pernicana fault and the northern extent of the Ragalna fault. This structuralbased susceptibility map is a crucial step in forecasting lava flow hazards at Etna, providing a support tool for decision makers.
    Description: This study was performed with the financial support from the V3-LAVA project (DPC-INGV 2007–2009 contract).
    Description: Published
    Description: 2083–2094
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 3.2. Tettonica attiva
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: 3.6. Fisica del vulcanismo
    Description: 4.3. TTC - Scenari di pericolosità vulcanica
    Description: JCR Journal
    Description: restricted
    Keywords: Flank eruption ; Dike ; Volcano structure ; Susceptibility map ; Spatial clustering ; Back analysis ; 04. Solid Earth::04.01. Earth Interior::04.01.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.07. Tectonophysics::04.07.99. General or miscellaneous ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.01. Computational geophysics::05.01.99. General or miscellaneous ; 05. General::05.01. Computational geophysics::05.01.04. Statistical analysis ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions ; 05. General::05.08. Risk::05.08.99. General or miscellaneous
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  • 35
    Publication Date: 2017-04-04
    Description: Volcanic rift zones, characterized by repeated dike emplacements, are expected to delimit the upper portion of unstable flanks at basaltic edifices. We use nearly two decades of InSAR observations excluding wintertime acquisitions, to analyze the relationships between rift zones, dike emplacement and flank instability at Etna. The results highlight a general eastward shift of the volcano summit, including the northeast and south rifts. This steadystate eastward movement (1-2 cm/yr) is interrupted or even reversed during transient dike injections. Detailed analysis of the northeast rift shows that only during phases of dike injection, as in 2002, does the rift transiently becomes the upper border of the unstable flank. The flank's steady-state eastward movement is inferred to result from the interplay between magmatic activity, asymmetric topographic unbuttressing, and east-dipping detachment geometry at its base. This study documents the first evidence of steady-state volcano rift instability interrupted by transient dike injection at basaltic edifices.
    Description: Partially funded by INGV and the Italian DPC (DPC-INGV project V4 “Flank”). ERS and ENVISAT SAR data were provided by ESA through the Cat-1 project no. 4532 and the GEO Supersite initiative. The DEM was obtained from the SRTM archive. ERS-1/2 orbits are courtesy of the TU-Delft, The Netherlands. SAR data processing has been done at IREACNR, partially carried out under contract “Volcanic Risk System (SRV)” funded by the Italian Space Agency (ASI).
    Description: Published
    Description: L20311
    Description: 1.3. TTC - Sorveglianza geodetica delle aree vulcaniche attive
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 1.10. TTC - Telerilevamento
    Description: 3.2. Tettonica attiva
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: 3.6. Fisica del vulcanismo
    Description: 4.3. TTC - Scenari di pericolosità vulcanica
    Description: JCR Journal
    Description: restricted
    Keywords: flank instability ; rift zones ; 04. Solid Earth::04.03. Geodesy::04.03.99. General or miscellaneous ; 04. Solid Earth::04.03. Geodesy::04.03.01. Crustal deformations ; 04. Solid Earth::04.03. Geodesy::04.03.06. Measurements and monitoring ; 04. Solid Earth::04.03. Geodesy::04.03.07. Satellite geodesy ; 04. Solid Earth::04.03. Geodesy::04.03.09. Instruments and techniques ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.06. Rheology, friction, and structure of fault zones ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.07. Tectonophysics::04.07.99. General or miscellaneous ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.05. Stress ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.08. Risk::05.08.99. General or miscellaneous
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  • 36
    Publication Date: 2017-04-04
    Description: In this work, we present regional maps of the inverse intrinsic quality factor (Qi −1), the inverse scattering quality factor (Qs −1) and total inverse quality factor (Qt −1) for the volcanic environment of Deception Island (Antarctica). Our attenuation study is based on diffusion approximation, which permits us to obtain the attenuation coefficients for every single couple source-receiver separately. The data set used in this research is derived from an active seismic experiment using more than 5200 offshore shots (air guns) recorded at 32 onshore seismic stations and four ocean bottom seismometers. To arrive at a regional distribution of these values, we used a new mapping technique based on a Gaussian space probability function. This approach led us to create ‘2-D probabilistic maps’ of values of intrinsic and scattering seismic attenuation. The 2-D tomographic images confirm the existence of a high attenuation body below an inner bay of Deception Island. This structure, previously observed in 2-D and 3-D velocity tomography of the region, is associated with a massive magma reservoir. Magnetotelluric studies reach a similar interpretation of this strong anomaly. Additionally, we observed areas with lower attenuation effects that bear correlation with consolidated structures described in other studies and associated with the crystalline basement of the area. Our calculations of the transport mean-free path and absorption length for intrinsic attenuation gave respective values of ≈950 m and 5 km, which are lower than the values obtained in tectonic regions or volcanic areas such as Tenerife Island. However, as observed in other volcanic regions, our results indicate that scattering effects dominate strongly over the intrinsic attenuation.
    Description: This work has been partially supported by the Spanish project Ephestos, CGL2011–29499-C02–01, by the EU project EC-FP7 MEDiterranean SUpersite Volcanoes (MED-SUV), by the Basque Government researcher training program BFI09.277 and by the Regional project ‘Grupo de Investigaci´on en Geof´ısica y Sismolog´ıa de la Junta de Andaluc´ıa, RNM104.’ Edoardo del Pezzo was partly supported by DPC-INGV projects UNREST SPEED and V2 (Precursori).
    Description: Published
    Description: 1957-1969
    Description: 3.1. Fisica dei terremoti
    Description: 3.6. Fisica del vulcanismo
    Description: JCR Journal
    Description: restricted
    Keywords: Seismic attenuation; ; Seismic tomography ; Volcano seismology ; Wave scattering and diffraction ; Wave propagation ; 04. Solid Earth::04.06. Seismology::04.06.07. Tomography and anisotropy ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 04. Solid Earth::04.06. Seismology::04.06.09. Waves and wave analysis
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  • 37
    Publication Date: 2017-04-04
    Description: Hazard mapping in poorly known volcanic areas is complex since much evidence of volcanic and non-volcanic hazards is often hidden by vegetation and alteration. In this paper, we propose a semi-quantitative method based on hazard event tree and multi-hazard map constructions developed in the frame of the FP7 MIAVITA project. We applied this method to the Kanlaon volcano (Philippines), which is characterized by poor geologic and historical records. We combine updated geological (long-term) and historical (short-term) data, building an event tree for the main types of hazardous events at Kanlaon and their potential frequencies. We then propose an updated multi-hazard map for Kanlaon, which may serve as a working base map in the case of future unrest. The obtained results extend the information already contained in previous volcanic hazard maps of Kanlaon, highlighting (i) an extensive, potentially active ~5 km long summit area striking north–south, (ii) new morphological features on the eastern flank of the volcano, prone to receiving volcanic products expanding from the summit, and (iii) important riverbeds that may potentially accumulate devastating mudflows. This preliminary study constitutes a basis that may help local civil defence authorities in making more informed land use planning decisions and in anticipating future risk/hazards at Kanlaon. This multi-hazard mapping method may also be applied to other poorly known active volcanoes.
    Description: This work was undertaken under the MIAVITA project, financed by the European Commission under the 7th Framework Programme for Research and Technological Development, Area “Environment”, Activity 6.1 “Climate Change, Pollution and Risks”.
    Description: Published
    Description: 1929-1943
    Description: 1V. Storia e struttura dei sistemi vulcanici
    Description: 2V. Dinamiche di unrest e scenari pre-eruttivi
    Description: 3V. Dinamiche e scenari eruttivi
    Description: 4V. Vulcani e ambiente
    Description: 6A. Monitoraggio ambientale, sicurezza e territorio
    Description: JCR Journal
    Description: open
    Keywords: RISK ASSESSMENTS ; Mount Kanlaon ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous ; 04. Solid Earth::04.07. Tectonophysics::04.07.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous
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  • 38
    Publication Date: 2020-02-24
    Description: Recent laboratory experiments on Etna basalt have permitted the generation of an extensive catalogue of acoustic emissions (AE) during two key experimental phases. Firstly, AE have been generated during triaxial compressional tests and formation of a complex fracture/damage zone. Secondly, rapid fluid decompression through the damage/shear zone after failure. We report new results from an advanced analysis method using AE spectrograms, allowing us to qualitatively identify high and low frequency events; essentially comparable to seismicity in volcanic areas. Our analysis, for the first time, quantitatively classifies ‘families’ of AE events belonging to the same experimental stage without prior knowledge. We then test the method using the AE catalogue for verification, which is not possible with field data. FFT spectra, obtained from AE, are subdivided into equal log intervals for which a local slope is calculated. Factor analysis has been then applied, in which we use a data matrix of columns representing the variables considered (frequency data averaged in bins) vs. rows indicating each AE data set. Factor analysis shows that the method is very effective and suitable for reducing data complexity, allowing distinct factors to be obtained. We conclude that most of the data variance (information content) can be well represented by three factors only, each one representing a well defined frequency range. Through the factor scores it is possible to represent data in a lower dimension factor space. Classification is then possible by identifying clusters of AE belonging to the same experimental stage. This allows us to propose a deformation/decompression interpretation based solely on the AE frequency analysis and to identify a third type of AE related to fluid movements in the deformation stage.
    Description: Published
    Description: 201-211
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: open
    Keywords: acoustic emissions ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 05. General::05.01. Computational geophysics::05.01.04. Statistical analysis
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: book chapter
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  • 39
    Publication Date: 2017-04-04
    Description: 129 Long Period (LP) events, divided in two families were recorded by 50 stations deployed on Mount Etna within an eruptive context in the second half of June 2008. In order to understand the mechanisms of these events, we perform moment tensor inversion. Numerical tests show that unconstrained inversion leads to reliable moment tensor solutions because of the close proximity of numerous stations to the source positions. However, single forces cannot be accurately determined as they are very sensitive to uncertainities in the velocity model. These tests emphasize the importance of using stations located as close as possible to the source in the inversion of LP events. Inversion of LP signals is initially unconstrained, in order to estimate the most likely mechanism. Constrained inversions then allow us to accurately determine the structural orientations of the mechanisms. Inversions for both families show mechanisms with strong volumetric components. These events are generated by cracks striking SW-NE for both families and dipping 70± SE (fam. 1) and 50± NW (fam. 2). The geometries of the cracks are different from the structures obtained by the location of these events. The orientation of the cracks is consistent with the local tectonic context on Mount Etna. The LP events seem to be a response to the lava fountain occuring on the 10th of May, 2008.
    Description: In press
    Description: (38)
    Description: 1.4. TTC - Sorveglianza sismologica delle aree vulcaniche attive
    Description: 3.1. Fisica dei terremoti
    Description: JCR Journal
    Description: open
    Keywords: Long-Period events ; earthquake source mechanism ; Etna Volcano ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 40
    Publication Date: 2017-04-04
    Description: This paper presents an analysis of seismicity associated with the volcanic activity of Volcàn de Colima (México) and recorded in the period November 2005–April 2006 during a field survey by the Istituto Nazionale di Geofisica e Vulcanologia (INGV)–Osservatorio Vesuviano, the Observatorio Vulcanologico de Colima of Colima University and the Instituto Andaluz de Geofisica, University of Granada. Three different types of volcanic earthquakes have been identified on the basis of their spectral properties: Type A (0.3–1 Hz), Type B (1–5 Hz) and Type C (3–4 Hz). Results of polarization analysis applied to Type A events show a predominance of radial motion, indicating that the wavefield comprises compressional waves (P) and shear waves polarized in the vertical plane (SV), while the signal always begins with a negative polarity. Type A, B and C earthquakes have been located using both a flat layered model and a 3D model including topography. Hypocentre distributions indicate that the source of Type A signals is very shallow and confined to a small volume lying about 1 km below the crater. In contrast, the source of Type B and C events is significantly deeper, with most hypocentres located in a volume of about 1 km3 centred at 2.5–3 km depth. A cluster analysis based on the crosscorrelation among the waveforms of different events recorded at the same station was applied to Type A earthquakes. Only two clusters, which include only a small percentage of events were found, indicating that earthquake families were uncommon during the period of our survey.
    Description: Published
    Description: 887-898
    Description: 3.1. Fisica dei terremoti
    Description: JCR Journal
    Description: reserved
    Keywords: Colima Volcano ; Long Period Events ; Earthquake location ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 41
    Publication Date: 2017-04-04
    Description: On 16 November 2006, a 1 day long paroxysmal eruption occurred at the summit craters of Mt. Etna volcano. A multiparametric approach, consisting of analyzing infrasonic, seismic, and video camera recordings, was carried out to follow its evolution. Volcanological and geophysical observations identified three eruptive phases. In the first phase, infrasonic and seismic characteristics reflected the highly explosive nature of the activity. Waveform characterization of infrasound events confirmed the activity of the several explosive vents at the summit of Southeast Crater (SEC). During the second phase, results highlighted the decoupling between seismic and infrasonic sources, which was due to the decrease in explosive activity and the reactivation of effusive vents located south of Bocca Nuova and on the saddle between Bocca Nuova and SEC. The third phase was the most intense and was characterized by various volcanic phenomena (pyroclastic flows, jets of dark ash, and white steam). The very high radiated infrasonic energy, together with infrasound event features, led us to infer a gas enrichment of the shallow magma column, preceding by a few minutes and likely related to the pyroclastic flows in the SEC area. After the eruption at SEC, variations in infrasound events related to the activity of Northeast Crater (NEC) were found. The observed spectral changes and the source mechanism modeling of the NEC infrasound events suggest the existence of a link in the plumbing system feeding the two craters.
    Description: Published
    Description: B09301
    Description: 1.4. TTC - Sorveglianza sismologica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: Etna ; Infrasound ; volcanic tremor ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 42
    Publication Date: 2017-04-04
    Description: One hundred twenty-nine long-period (LP) events, divided into two families of similar events, were recorded by the 50 stations deployed on Mount Etna in the second half of June 2008. During this period lava was flowing from a lateral fracture after a summit Strombolian eruption. In order to understand the mechanisms of these events, we perform moment tensor inversions. Inversions are initially kept unconstrained to estimate the most likely mechanism. Numerical tests show that unconstrained inversion leads to reliable moment tensor solutions because of the close proximity of numerous stations to the source positions. However, single forces cannot be accurately determined as they are very sensitive to uncertainties in the velocity model. Constrained inversions for a crack, a pipe or an explosion then allow us to accurately determine the structural orientations of the source mechanisms. Both numerical tests and LP event inversions emphasise the importance of using stations located as close as possible to the source. Inversions for both families show mechanisms with a strong volumetric component. These events are most likely generated by cracks striking SW–NE for both families and dipping 70° SE (family 1) and 50° NW (family 2). For family 1 events, the crack geometry is nearly orthogonal to the dikelike structure along which events are located, while for family 2 the location gave two pipelike bodies that belong to the same plane as the crack mechanism. The orientations of the cracks are consistent with local tectonics, which shows a SW–NE weakness direction. The LP events appear to be a response to the lava fountain occurring on 10 May 2008 as opposed to the flank lava flow.
    Description: Published
    Description: B01304
    Description: 1.4. TTC - Sorveglianza sismologica delle aree vulcaniche attive
    Description: 3.1. Fisica dei terremoti
    Description: JCR Journal
    Description: reserved
    Keywords: Etna Volcano ; long-period events ; source mechanism ; location ; plumbing systems ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 43
    Publication Date: 2017-04-04
    Description: The peculiar source characteristics of long-period seismic events (time persistency of the source, low-frequency peaks in the source spectrum, absence of high-frequency radiation) prevent the formation of a definite high-frequency coda in the seismograms. In contrast, this is well formed in volcano–tectonic quakes. For this reason, the widely used duration magnitude scale that is based on the proportionality between the energy and the coda duration cannot be used for long-period estimation. In observatory practice, the long-period magnitude is sometimes estimated using the same duration magnitude scale, leading to confusing results. In this report, we show a new method to estimate the magnitude of long-period events that generally occur for volcanoes, with some application examples from data for Mt Etna (Italy), Colima Volcano (Mexico) and Campi Flegrei (Italy).
    Description: Published
    Description: 911-919
    Description: 3.1. Fisica dei terremoti
    Description: JCR Journal
    Description: restricted
    Keywords: Earthquake source observations; ; Volcano monitoring ; Volcano seismology ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 04. Solid Earth::04.06. Seismology::04.06.09. Waves and wave analysis
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 44
    Publication Date: 2017-04-04
    Description: Between 1994 and 2010, we completed 16 thermal surveys of Vulcano’s Fossa fumarole field (Aeolian Islands, Italy). In each survey, between 400 and 1,200 vent temperatures were collected using a thermal infrared thermometer from distances of ∼1 m. The results show a general decrease in average vent temperature during 1994–2003, with the average for the entire field falling from ∼220°C in 1994 to ∼150°C by 2003. However, between 2004 and 2010, we witnessed heating, with the average increasing to ∼190°C by 2010. Alongside these annual-scale field-wide trends, we record a spatial re-organisation of the fumarole field, characterised by shut down of vent zones towards the crater floor, matched by rejuvenation of zones located towards the crater rim. Heating may be expected to be associated with deflation because increased amounts of vaporisation will remove volume from the hydrothermal system Gambino and Guglielmino (J Geophys Res 113: B07402, 2008). However, over the 2004–2010 heating period, no ground deformation was observed. Instead, the number of seismic events increased from a typical rate of 37 events per month during 1994–2000 to 195 events per month during 2004–2010. As part of this increase, we noticed a much greater number of high-frequency events associated with rock fracturing. We thus suggest that the heating event of 2004–2010 was the result of changed permeability conditions, rather than change in the heat supply from the deeper magmatic source. Within this scenario, cooling causes shut down of lower sectors and re-establishment of pathways located towards the crater rim, causing fracturing, increased seismicity and heat flow in these regions. This is consistent with the zone of rejuvenation (which lies towards and at the rim) being the most favourable location for fracturing given the stress field of the Fossa cone Schöpa et al. (J Volcanol Geotherm Res 203:133–145, 2011); it is also the most established zone, having been active at least since the early twentieth century. Our data show the value of deploying multi-disciplinary geophysical campaigns at degassing (fumarolic) hydrothermal systems. This allows more complete and constrained understanding of the true heat loss dynamics of the system. In the case study presented here, it allows us to distinguish true heating from apparent heating phases. While the former are triggered from the bottom-up, i.e. they are driven by increases in heat supply from the magmatic source, the latter are triggered from the top-down, i.e. by changing permeability conditions in the uppermost portion of the system to allow more efficient heat flow over zones predisposed to fracturing.
    Description: Published
    Description: 1293-1311
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 1.3. TTC - Sorveglianza geodetica delle aree vulcaniche attive
    Description: 1.4. TTC - Sorveglianza sismologica delle aree vulcaniche attive
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 3.6. Fisica del vulcanismo
    Description: JCR Journal
    Description: restricted
    Keywords: Fumaroles ; Vulcano ; Vent temperature ; Seismicity ; Ground Deformation ; Permeability ; 04. Solid Earth::04.03. Geodesy::04.03.01. Crustal deformations ; 04. Solid Earth::04.03. Geodesy::04.03.06. Measurements and monitoring ; 04. Solid Earth::04.06. Seismology::04.06.06. Surveys, measurements, and monitoring ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 45
    Publication Date: 2017-04-04
    Description: Strong changes in seismic radiation, comparable to those preceding and/or accompanying eruptive activity in recent years, were recorded at Mt. Etna volcano, Italy, from November 2005 to January 2006. The amplitude of volcanic tremor peaked in mid-December 2005 after a continuous, slow increase from August 2005 onwards, during which neither effusive nor paroxysmal activity was observed by volcanologists and alpine guides. During this time span, the centroid locations of volcanic tremor moved towards the surface, more and more clustered below the summit craters. The application of pattern classification analysis based on Self-Organizing Maps and fuzzy clustering to volcanic tremor data highlighted variations in the frequency domain as well. These changes were temporally associated with ground deformation variations, as indicative of a mild inflation of the summit of the volcano, and with a conspicuous increase in the SO2 plume-flux emission. Overall, we interpret this evidence as the result of recharging of the volcanic feeder at depth (〉 3 km below sea level) during which magma did not reach the shallow plumbing system.
    Description: Published
    Description: 4989–5005
    Description: 2V. Dinamiche di unrest e scenari pre-eruttivi
    Description: JCR Journal
    Description: embargoed_20140606
    Keywords: time series analysis ; volcano seismology ; volcano monitoring ; neural network and fuzzy logic ; seismic tomography ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 46
    Publication Date: 2017-04-04
    Description: The statistical analysis of volcanic activity at Mt Etna was conducted with the twofold aim of (1) constructing a probability map for vent opening of future flank eruptions and (2) forecasting the expected number of eruptive events at the summit craters. The spatiotemporal map of new vent opening at Etna volcano is based on the analysis of spatial locations and frequency of flank eruptions starting from 1610. Thanks to the completeness and accuracy of historical data over the last four centuries, we examined in detail the spatial and temporal distribution of flank eruptions showing that effusive events follow a nonhomogenous Poisson process with space-time varying intensities. After demonstrating the spatial nonhomogeneity and the temporal nonstationarity of flank eruptions at Etna, we calculated the recurrence rates (events expected per unit area per unit time) and produced different spatiotemporal probability maps of new vent opening in the next 1, 10 and 50 years. These probabilistic maps have an immediate use in evaluating the future timing and areas of Etna prone to volcanic hazards. Finally, the results of the analysis of the persistent summit activity during the last 110 years indicate that the hazard rate for eruptive events is not constant with time, differs for each summit crater of Mt Etna, highlighting a general increase in the eruptive frequency starting from the middle of last century and particularly from 1971, when the SE crater was formed.
    Description: This work was developed in the frame of the TecnoLab, the Laboratory for the Technological Advance in Volcano Geophysics organized by INGV-CT, DIEES-UNICT, and DMI-UNICT.
    Description: Published
    Description: 1925-1935
    Description: 1V. Storia e struttura dei sistemi vulcanici
    Description: 2V. Dinamiche di unrest e scenari pre-eruttivi
    Description: 3V. Dinamiche e scenari eruttivi
    Description: 4V. Vulcani e ambiente
    Description: 3IT. Calcolo scientifico e sistemi informatici
    Description: JCR Journal
    Description: restricted
    Keywords: Etna ; probabilistic modeling ; eruption ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous ; 04. Solid Earth::04.07. Tectonophysics::04.07.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 05. General::05.01. Computational geophysics::05.01.02. Cellular automata, fuzzy logic, genetic alghoritms, neural networks ; 05. General::05.01. Computational geophysics::05.01.04. Statistical analysis ; 05. General::05.01. Computational geophysics::05.01.05. Algorithms and implementation ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 47
    Publication Date: 2017-04-04
    Description: Flank instability at basaltic volcanoes is often related to repeated dike intrusions along rift zones and accompanied by surface fracturing and seismicity. These processes have been mostly studied during specific events, and the lack of longer-term observations hinders their better understanding. Here we analyze ~20 years of deformation of the Pernicana Fault System (PFS), the key structure controlling the instability of the eastern flank of Mt. Etna. We exploit East-West and vertical components of mean deformation velocity, as well as corresponding time series, computed from ERS/ENVISAT (1992–2010) and COSMO-SkyMed (2009–2011) satellite radar sensors via Synthetic Aperture Radar Interferometry techniques. We then integrate and compare this information with field, seismic, and leveling data, collected between 1980 and 2012. We observe transient displacements accompanied by seismicity, overprinted on a long-term background eastward motion (~2 cm/yr). In the last decades, these transient events were preceded by a constant amount of accumulated strain near the PFS. The time of strain accumulation varies between a few years and a few decades, also depending on magma emplacement within the nearby North East Rift, which may increase the strain along the PFS. These results suggest that the amount of deformation near the PFS may be used as a gauge to forecast the occurrence of instability transients on the eastern flank of Etna. In this context, the PFS may provide an ideal, small-scale structure to test the relations between strain accumulation, stress loading, and seismic energy release.
    Description: This work has been partially supported by the Italian Space Agency (ASI) within the SAR4Volcanoes project, agreement I/ 034/11/0.
    Description: Published
    Description: 4398-4409
    Description: 1T. Geodinamica e interno della Terra
    Description: 2T. Tettonica attiva
    Description: 3T. Pericolosità sismica e contributo alla definizione del rischio
    Description: 4T. Fisica dei terremoti e scenari cosismici
    Description: 5T. Sorveglianza sismica e operatività post-terremoto
    Description: 1V. Storia e struttura dei sistemi vulcanici
    Description: 2V. Dinamiche di unrest e scenari pre-eruttivi
    Description: 3V. Dinamiche e scenari eruttivi
    Description: 4V. Vulcani e ambiente
    Description: 6A. Monitoraggio ambientale, sicurezza e territorio
    Description: JCR Journal
    Description: restricted
    Keywords: Volcano flank instability ; Pernicana fault ; Etna ; 04. Solid Earth::04.01. Earth Interior::04.01.99. General or miscellaneous ; 04. Solid Earth::04.03. Geodesy::04.03.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.06. Seismology::04.06.99. General or miscellaneous ; 04. Solid Earth::04.07. Tectonophysics::04.07.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 05. General::05.01. Computational geophysics::05.01.99. General or miscellaneous ; 05. General::05.02. Data dissemination::05.02.99. General or miscellaneous ; 05. General::05.08. Risk::05.08.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 48
    Publication Date: 2017-04-04
    Description: From December 2005 to January 2006, an anomalous degassing episode was observed at Mount Etna, well-correlated with an increase in volcanic tremor, and in the almost complete absence of eruptive activity. In the same period, more than 10,000 very long period (VLP) events were detected. Through moment tensor inversion analyses of the VLP pulses, we obtained quantitative estimates of the volumetric variations associated with these events. This allowed a quantitative investigation of the relationship between VLP seismic activity, volcanic tremor, and gas emission rate at Mount Etna. We found a statistically significant positive correlation between SO2 gas flux and volcanic tremor, suggesting that tremor amplitude can be used as a first-order proxy for the background degassing activity of the volcano. VLP volumetric changes and SO2 gas flux are correlated only for the last part of our observations, following a slight change in the VLP source depth. We calculate that the gas associated with VLP signal genesis contributed less than 5% of the total gas emission. The existence of a linear correlation between VLP and degassing activities indicates a general relationship between these two processes. The effectiveness of such coupling appears to depend upon the particular location of the VLP source, suggesting that conduit geometry might play a significant role in the VLP-generating process. These results are the first report on Mount Etna of a quantitative relationship between the amounts of gas emissions directly estimated through instrumental flux measurements and the quantities of gas mass inferred in the VLP source inversion.
    Description: Published
    Description: 4910-4921
    Description: 2V. Dinamiche di unrest e scenari pre-eruttivi
    Description: JCR Journal
    Description: restricted
    Keywords: Very Long Period seismicity ; UV scanners network ; Etna Volcano ; volcano monitoring ; 04. Solid Earth::04.02. Exploration geophysics::04.02.06. Seismic methods ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 49
    Publication Date: 2017-04-03
    Description: Among the eruptive styles, the Strombolian activity is one of the more easy to study because of its repetitive behavior. For this reason large amount of data can be comfortably collected. Strombolian volcanoes are like natural laborato- ries repeating the same experiment (individual explosions) many times each day. The development of quantitative models of eruptive dynamics is driven by the comparison of experimental ob- servations and synthetic data obtained through mathemat- ical, numerical or analogue modeling. Since Strombolian activity offers a profuse amount of interesting seismic signals, during the last decades there has been growing attention on seismological techniques aimed at retrieving the conduit geometry and the eruption dynamics from the seismological recordings. One of these techniques, the source function inversion, is able to re- trieve a summary of the forces acting on the volcanic con- duit during the VLP event generation [5]. The comparison of observed source functions with synthetic ones, obtained through numerical modeling, allow us to put constraints on the proposed models. Quantitative models, able to fit seismological observa- tions, are a powerful tool for interpreting seismic record- ings and therefor the seismological monitoring of active volcanoes.
    Description: Published
    Description: 1.4. TTC - Sorveglianza sismologica delle aree vulcaniche attive
    Description: restricted
    Keywords: Strombolian activity ; Slug flow ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.01. Computational geophysics::05.01.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: book chapter
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  • 50
    Publication Date: 2017-04-04
    Description: Seismic activity, ground deformation, and soil and fumarole temperatures acquired during 2004–2007 at Vulcano (Aeolian Islands) are analysed and the time relations among the different time series are discussed. Changes in temperature of fumarolic gases took place during four ‘‘anomalous’’ periods (November 2004–March 2005; October 2005–February 2006; August–October 2006; July–December 2007) at the same time as an increasing number of volcano-seismic events. In particular, the temperatures at high temperature vents and at steam heated soil ranged in time from 180 to 440 C and from 20 to 90 C, respectively. The maximum daily number of volcano-seismic events was 57, reached during the second anomalous period. This seismicity, characterised by focal depth generally lower than 1 km below sea level (b.s.l.) and composed of different kinds of events associated to both resonance and shear failure processes, is related to the shallow dynamics of the hydrothermal system. During the analysed period, very few volcano-tectonic earthquakes took place and tilt recordings showed no sharp or important changes. In light of such observations, the increases in both temperature and volcano-seismic events number were associated to increases in the release of gas from a deep and stable magma body, without magma intrusions within the shallow hydrothermal system. Indeed, a greater release of gas from depth leads to increased fluid circulation, that can promote increases in volcano-seismic events number by both fracturing processes and resonance and vibration in cracks and conduits. The different trends observed in the measured geochemical and geophysical series during the anomalous periods can be due to either time changes in the medium permeability or a changing speed of gas release from a deep magma body. Finally, all the observed variations, together with the changing temporal distribution of the different seismic event kinds, suggest that the hydrothermal system at Vulcano can be considered unsteady and dynamic.
    Description: Published
    Description: 167–182
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: JCR Journal
    Description: reserved
    Keywords: Volcano seismolog ; soil and fumarole temperatures ; tilt data ; hydrothermal system ; Vulcano Island ; volcanic unrest ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 51
    Publication Date: 2017-04-04
    Description: In the present paper, we analyse long-period (LP) events and seismic noise recorded at Campi Flegrei during the uplift episode of 2004–2006. The results of a detailed polarization analysis indicate that the large number of LPs detected during the seismic crisis were accompanied by a sustained activity consisting of very low-energy volcanic signals. These weak volcanic signals, which are usually absent in ambient noise recorded in the studied area, and LP events have similar properties, namely they are radially polarized towards the same LP source. The large dataset analysed allows us to study the statistics of the polarization, leading to the extraction of the average properties of the volcanic signals. An estimate of the complexity of the system can be provided by the degrees of freedom necessary to describe the asymptotic dynamics in a reconstructed phase space. This analysis shows that both LPs and low-energy signals can be described by a low-dimensional dynamical system, while ambient noise unrelated to volcanic activity is higher dimensional. Based on these observations, we interpret the phenomena observed during the seismic crisis in the framework of the theory of self-oscillating systems, in which LPs and low-energy signals represent self-oscillations generated by a persistent hydrothermal source.
    Description: Published
    Description: 1537-1551
    Description: 1.4. TTC - Sorveglianza sismologica delle aree vulcaniche attive
    Description: JCR Journal
    Description: restricted
    Keywords: Campi Flegrei, Long-period events, Self-sustained oscillations ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology
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  • 52
    Publication Date: 2017-04-04
    Description: The complex volcanic system of Tenerife Island is known to have a highly heterogeneous character, as recently confirmed by velocity tomography.We present new information derived from intrinsic quality factor inverse maps (Qi −1), scattering quality factor inverse maps (Qs −1) and total quality factor inverse maps (Qt −1) obtained for the same region. The data set used in this work is the result of the analysis of an active seismic experiment carried out, using offshore shots (air guns) recorded at over 85 onshore seismic stations. The estimates of the attenuation parameters are based on the assumption that the seismogram energy envelopes are determined by seismic energy diffusion processes occurring inside the island. Diffusion model parameters, proportional to Qi −1 and to Qs −1, are estimated from the inversion of the energy envelopes for any source–receiver couple. They are then weighted with a new graphical approach based on a Gaussian space probability function, which allowed us to create ‘2-D probabilistic maps’ representing the space distribution of the attenuation parameters. The 2-D images obtained reveal the existence of a zone in the centre of the island characterized by the lowest attenuation effects. This effect is interpreted as highly rigid and cooled rocks. This low-attenuation region is bordered by zones of high attenuation, associated with the recent historical volcanic activity. We calculate the transport mean free path obtaining a value of around 4 km for the frequency range 6–12 Hz. This result is two orders of magnitude smaller than values calculated for the crust of the Earth. An absorption length between 10 and 14 km is associated with the average intrinsic attenuation parameter. These values, while small in the context of tectonic regions, are greater than those obtained in volcanic regions such as Vesuvius or Merapi. Such differences may be explained by the magnitude of the region of study, over three times larger than the aforementioned study areas. This also implies deeper sampling of the crust, which is evidenced by a change in the values of seismic attenuation. One important observation is that scattering attenuation dominates over the intrinsic effects, Qi being at least twice the value of Qs.
    Description: This work has been partially supported by the Spanish project Ephestos, CGL2011-29499-C02-01, by the EU project EC-FP7 MEDiterranean SUpersite Volcanoes (MED-SUV), by the Basque Government researcher training program BFI09.277 and by the Regional project ‘Grupo de Investigaci´on en Geof´ısica y Sismolog´ıa de la Junta de Andaluc´ıa, RNM104’. EdP has been partly supported by DPC-INGV projects UNREST SPEED and V2 (Precursori).
    Description: Published
    Description: 1942-1956
    Description: 3.1. Fisica dei terremoti
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: JCR Journal
    Description: restricted
    Keywords: Seismic attenuation ; ; Seismic tomography; ; Volcano seismology ; Wave propagation. ; 04. Solid Earth::04.06. Seismology::04.06.07. Tomography and anisotropy ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 04. Solid Earth::04.06. Seismology::04.06.09. Waves and wave analysis
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 53
    Publication Date: 2017-10-06
    Description: Although the oldest volcanic rocks exposed at Pantelleria (Strait of Sicily) are older than 300 ka, most of the island is covered by the 45–50 ka Green Tuff ignimbrite, thought to be related to the Cinque Denti caldera, and younger lavas and scoria cones. Pre-50 ka rocks (predominantly rheomorphic ignimbrites) are exposed at isolated sea cliffs, and their stratigraphy and chronology are not completely resolved. Based on volcanic stratigraphy and K/Ar dating, it has been proposed that the older La Vecchia caldera is related to ignimbrite Q (114 ka), and that ignimbrites F, D, and Z (106, 94, and 79 ka, respectively) were erupted after caldera formation. We report here the paleomagnetic directions obtained from 23 sites in ignimbrite P (133 ka) and four younger ignimbrites, and from an uncorrelated (and loosely dated) welded lithic breccia thought to record a caldera-forming eruption. The paleosecular variation of the geomagnetic field recorded by ignimbrites is used as correlative tool, with an estimated time resolution in the order of 100 years. We find that ignimbrites D and Z correspond, in good agreement with recent Ar/Ar ages constraining the D/Z eruption to 87 ka. The welded lithic breccia correlates with a thinner breccia lying just below ignimbrite P at another locality, implying that collapse of the La Vecchia caldera took place at ~130–160 ka. This caldera was subsequently buried by ignimbrites P, Q, F, and D/Z. Paleomagnetic data also show that the northern caldera margin underwent a ~10° west–northwest (outwards) tilting after emplacement of ignimbrite P, possibly recording magma resurgence in the crust.
    Description: Published
    Description: 341-357
    Description: 1V. Storia eruttiva
    Description: JCR Journal
    Description: restricted
    Keywords: Pantelleria ; Ignimbrite ; Caldera formation ; Paleomagnetism ; Paleosecular variation of the geomagnetic field ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.08. Sediments: dating, processes, transport ; 04. Solid Earth::04.04. Geology::04.04.10. Stratigraphy ; 04. Solid Earth::04.04. Geology::04.04.11. Instruments and techniques ; 04. Solid Earth::04.05. Geomagnetism::04.05.99. General or miscellaneous ; 04. Solid Earth::04.05. Geomagnetism::04.05.02. Geomagnetic field variations and reversals ; 04. Solid Earth::04.05. Geomagnetism::04.05.03. Global and regional models ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism ; 04. Solid Earth::04.05. Geomagnetism::04.05.07. Rock magnetism ; 04. Solid Earth::04.05. Geomagnetism::04.05.08. Instruments and techniques
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 54
    Publication Date: 2017-11-17
    Description: Island (Antarctica), recorded during three Antarctic summers (1994- 1995, 1995-1996 and 1996-1997), are analyzed using a dense small-aperture (500 m) seismic array. The visual and spectral classification of the seismic events shows the existence of long-period and hybrid isolated seismic events, and of low-frequency, quasi-monochromatic and spasmodic continuous tremors, All spectra have the highest amplitudes in the frequency band between 1 and 4 Hz, while hybrids and spasmodic tremors have also significant amplitudes in the high-frequency band (4-10 Hz). The array analysis indicates that almost all the well-correlated low-frequency signals share similar array parameters (slowness and back azimuth) and have the same source area, close to the array site. The polarization analysis shows that phases at high-frequency are mostly composed of P waves, and those phases dominated by low frequencies can be interpreted as surface waves. No clear shear waves are evidenced. From the energy evaluation, we have found that the reduced displacement values for surface and body waves are confined in a narrow interval. Volcano-tectonic seismicity is located close to the array, at a depth shallower than 1 km. The wave-field properties of the seismovolcanic signals allow us to assume a unique source model, a shallow resonating fluid-filled crack system at a depth of some hundreds of meters. All of the seismic activity is interpreted as the response of a reasonably stable stationary geothermal process. The differences observed in the back azimuth between low and high frequencies are a near-field effect. A few episodes of the degassification process in an open conduit were observed and modeled with a simple organ pipe.
    Description: Published
    Description: 13905-13931
    Description: 3.1. Fisica dei terremoti
    Description: JCR Journal
    Description: reserved
    Keywords: Long Period Events ; Deception Island ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 55
    Publication Date: 2020-02-24
    Description: We investigated the relationship between volcano-seismic events, recorded at La Fossa crater of Vulcano (Aeolian Islands, Italy) during 2004-2006, and the dynamics of the hydrothermal system. During the period of study, three episodes of increasing numbers of volcano-seismic events took place at the same time as geothermal and geochemical anomalies were observed. These geothermal and geochemical anomalies have been interpreted as resulting from an increasing deep magmatic component of the hydrothermal fluids. Three classes of seismic events (long period, high frequency and monochromatic events), characterised by different spectral content and various similarity of the waveforms, have been recognised. These events, clustered mainly below La Fossa crater area at depths of 0.5–1.1 km b.s.l., were space-distributed according to the classes. Based on their features, we can infer that such events at Vulcano are related to two different source mechanisms: (1) fracturing processes of rocks and (2) resonance of cracks (or conduits) filled with hydrothermal fluid. In the light of these source mechanisms, the increase in the number of events, at the same time as geochemical and geothermal anomalies were observed, was interpreted as the result of an increasing magmatic component of the hydrothermal fluids, implying an increase of their flux. Indeed, such variation caused an increase of both the pore pressure within the rocks of the volcanic system and the amount of ascending fluids. Increased pore pressures gave rise to fracturing processes, while the increased fluid flux favoured resonance and vibration processes in cracks and conduits. Finally, a gradual temporal variation of the waveform of the hybrid events (one of the subclasses of long period events) was observed, likely caused by heating and drying of the hydrothermal system.
    Description: Published
    Description: 803-816
    Description: 1.4. TTC - Sorveglianza sismologica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: Volcano seismology ; Vulcano Island ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 56
    Publication Date: 2017-04-04
    Description: We analyze the distribution of volcanic earthquake recurrence intervals in the Vesuvio, Campi Flegrei, and Hawaii regions and compare it with tectonic recurrence rates in California. We find that the distribution behavior is similar for volcanic and tectonic seismic events. In both cases, the recurrence interval distributions collapse onto the same master curve if time is rescaled by the average occurrence rate. This implies that both phenomena have the same temporal organization, and it is possible to adopt for volcanic areas that the same occurrence models used for tectonic regions.
    Description: Published
    Description: B10309
    Description: 1.4. TTC - Sorveglianza sismologica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: volcanic earthquake ; recurrence intervals ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 05. General::05.01. Computational geophysics::05.01.04. Statistical analysis
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 57
    Publication Date: 2017-04-04
    Description: Flank instability is common at volcanoes, even though the subsurface structures, including the depth to a detachment fault, remain poorly constrained. Here, we use a multidisciplinary approach, applicable to most volcanoes, to evaluate the detachment depth of the unstable NE flank of Mt. Etna. InSAR observations of Mount Etna during 1995–2008 show a trapdoor subsidence of the upper NE flank, with a maximum deformation against the NE Rift. The trapdoor tilt was highest in magnitude in 2002–2004, contemporaneous with the maximum rates of eastward slip along the east flank. We explain this deformation as due to a general eastward displacement of the flank, activating a rotational detachment and forming a rollover anticline, the head of which is against the NE Rift. Established 2D rollover construction models, constrained by morphological and structural data, suggest that the east‐dipping detachment below the upper NE flank lies at around 4 km below the surface. This depth is consistent with seismicity that clusters above 2–3 km below sea level. Therefore, the episodically unstable NE flank lies above an east‐dipping rotational detachment confined by the NE Rift and Pernicana Fault. Our approach, which combines short‐term (InSAR) and long‐term (geological) observations, constrains the 3D geometry and kinematics of part of the unstable flank of Etna and may be applicable and effective to understand the deeper structure of volcanoes undergoing flank instability or unrest.
    Description: This work was partially funded by INGV and the DPC‐INGV project “Flank”, and partially by the ASI (SRV project).
    Description: Published
    Description: L16304
    Description: 1.3. TTC - Sorveglianza geodetica delle aree vulcaniche attive
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 1.10. TTC - Telerilevamento
    Description: 3.2. Tettonica attiva
    Description: 4.3. TTC - Scenari di pericolosità vulcanica
    Description: JCR Journal
    Description: reserved
    Keywords: flank instability ; fault ; InSAR ; Etna ; rollover ; 04. Solid Earth::04.01. Earth Interior::04.01.99. General or miscellaneous ; 04. Solid Earth::04.02. Exploration geophysics::04.02.99. General or miscellaneous ; 04. Solid Earth::04.03. Geodesy::04.03.99. General or miscellaneous ; 04. Solid Earth::04.03. Geodesy::04.03.06. Measurements and monitoring ; 04. Solid Earth::04.03. Geodesy::04.03.07. Satellite geodesy ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.06. Rheology, friction, and structure of fault zones ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.04. Geology::04.04.11. Instruments and techniques ; 04. Solid Earth::04.06. Seismology::04.06.99. General or miscellaneous ; 04. Solid Earth::04.07. Tectonophysics::04.07.99. General or miscellaneous ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.05. Stress ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.08. Risk::05.08.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 58
    Publication Date: 2022-05-04
    Description: Mediterranean tectonics has been characterized by an irregular, complex temporal evolution with episodic rollback and retreat of the subducted plate followed by period of slow trench-migration. To provide insight into the geodynamics of the Calabrian arc, we image the characteristics and lithospheric structure of the convergent, Apulian and Hyblean forelands at the cusps of the arc. Specifically we investigate the crustal and lithospheric thicknesses using teleseismic S-to-p converted phases, applied to the Adria-Africa plate margin for the first time. We find that the Moho in the Apulian foreland is nearly flat at ∼30 km depth, consistent with previous P receiver functions results, and that the Hyblean crustal thickness is more complex, which can be understood in terms of the nature of the individual pieces of carbonate platform and pelagic sediments that make up the Hyblean platform. The lithospheric thicknesses range between 70–120 km beneath Apulia and 70–90 km beneath Sicily. The lithosphere of the forelands at each end of the Calabrian arc are continental in nature, buoyant compared to the subducting oceanic lithosphere and have previously been interpreted as mostly undeformed carbonate platforms. Our receiver function images also show evidence of lithospheric erosion and thinning close to Mt. Etna and Mt. Vulture, two volcanoes which have been associated with asthenospheric upwelling and mantle flow around of the sides the slab. We suggest that as the continental lithosphere resists being subducted it is being thermo-mechanically modified by toroidal flow around the edges of the subducting oceanic lithosphere of the Calabrian arc.
    Description: Published
    Description: L23301
    Description: JCR Journal
    Description: restricted
    Keywords: continental lithosphere ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous
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  • 59
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Der Einfluß von 3-Phenylenbismaleimid auf die Werkstoffeigenschaften von CaCO3 gefüllten Polypropylen-Verbundstoffen wurde untersucht. Die Verarbeitungstemperatur spielte eine entscheidende Rolle bei der Herstellung der Verbundwerkstoffe. Bei Verarbeitungstemperaturen oberhalb der Bismaleimid-Zersetzungstemperatur zeigte die Bismaleimid-Verbindung einen positiven Effekt. Die chemische Zusammensetzung der modifizierten Verbunde wurde mit den mechanischen Eigenschaften korreliert. Basierend auf ESCA-Analysen werden Wechselwirkungen zwischen dem Polymeren und CaCO, diskutiert.
    Notes: The effect of 3-phenylene bismaleimide on the mechanical performance of an inorganic filler-based polypropylene composite was studied. The selection of processing temperature played a significant role in the preparation of such composites. A positive effect of the bismaleimide compound was obtained for a processing temperature above the decomposition temperature of bismaleimide. The chemical composition of the modified composite was correlated to its mechanical strength by experimentation involving a rotatable design. An interaction between polymer and CaCO3 has been proposed based on ESCA analysis.
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  • 60
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    Angewandte Makromolekulare Chemie 224 (1995), S. 33-48 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Chemische und mechanische Eigenschaften von Zwischenprodukten der PE-Schrumpfschlauch-Produktion wurden bei unterschiedlichen Compound-Zusammensetzungen (PE, ein aromatisches Amin oder Phenolderivat als Antioxidans und in einigen Fällen ein Flammschutzmittel und/oder eine Elastomerkomponente) untersucht.Während der Herstellung, besonders während der durch Elektronenstrahlung initiierten Vernetzung, nimmt die thermooxidative Stabilität des Materials gegenüber der des compoundierten Granulats ab. Das aromatische Amin scheint bei gleicher Zusammensetzung das wirksamere und strahlungsbeständigere Antioxidans im Vergleich zum Phenolderivat zu sein. Die Oxidationsstabilität der hergestellten Schrumpfschläuche wird nicht von der Qualität des eingesetzten PE-Ausgangsgranulats beeinflußt.Durch die Alterung des Materials ändern sich die mechanischen Eigenschaften geringfügig. Die Elastomerzugabe bewirkt keine Änderung von Zugfestigkeit und Reißdehnung. Die Stabilität des Endprodukts ist bei weitem ausreichend, um den Spannungen, die beim Schrumpfen während des Gebrauchs auftreten, standzuhalten. Die gute Zugfestigkeit des Materials wird durch die Alterung ebenfalls nicht beeinträchtigt.Bei der Extrusion des Granulats tritt keine nennenswerte Änderung des Molekulargewichts bzw. der Molekulargewichtsverteilung auf. Durch die Bestrahlung wird das Material vernetzt und zu mehr als 50% unlöslich, und seine thermooxidativen Eigenschaften ändern sich deutlich gegenüber dem ursprünglichen PE und dem daraus compoundierten Material.
    Notes: Some chemical and mechanical properties of intermediate products obtained in the production of PE heat-shrinkable tubes were studied at different compositions of the material containing PE, antioxidant (aromatic amime or phenol) and, in some cases, flame retardant and/or an elastomer.In the course of the production phase, the thermooxidative stability decreases compared to that of compounded granulate. The greatest decrease is caused by irradiation. The aromatic amine seems to be a more effective antioxidant at similar compositions than the phenol derivative, and it shows a better resistance against irradiation. The oxidative stability of the finished shrinkable tubes is not affected by the quality of commercial granulate (initial polyethylene).Mechanical properties change slightly upon ageing, and the introduction of the elastomer did not alter the tensile strength and elongation at break. The remaining stability of the end product was still high enough to bear the stress of shrinking in use, and the good tensile strength of the material did not decrease upon thermal ageing either.In the extrusion of the granulated compound no significant change in the distribution and average molecular weight took place. Irradiation produced more than 50% insoluble fraction and the thermooxidative properties of the crosslinked sample changed significantly compared to the original PE and to the compound prepared from it.
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  • 61
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    Angewandte Makromolekulare Chemie 224 (1995), S. 89-96 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: In the present work oxygen index (OI) measurements and thermogravimetric analysis (TG) for a series of polyurethanes based on diols and isocyanate were conducted. It was found that a correlation exists between some of the thermal degradation parameters obtained from TG and OI-values. Analysis of experimental results confirms that the amount of mass loss at 250°C is directly proportional to the OI-value. It was also found that the logarithmic temperatures of maximal decomposition rates are directly proportional to the OI-values.
    Notes: In der vorliegenden Arbeit wurden für eine Serie von Polyurethanen auf der Basis von Diol und Isocyanat der Sauerstoffindex (SI) gemessen und die thermische Zersetzung mittels thermogravimetrischer Analyse (TG) untersucht. Dabei wurde ein Zusammenhang zwischen einigen Parametern der thermischen Zersetzung und den SI-Werten gefunden. Die Auswertung der experimentellen Ergebnisse zeigte, daß die Höhe des Massenverlustes bei 250°C und die SI-Werte direkt proportional zueinander sind. Derselbe Zusammenhang besteht auch zwischen dem Logarithmus der Temperatur bei der maximalen Zersetzungsgeschwindigkeit und den SI-Werten.
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  • 62
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    Angewandte Makromolekulare Chemie 224 (1995), S. 109-114 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Poly(acrylsäre-co-acrylamid) wurde mit Zinkoxid und Kryolith (Na3AlF6) in unterschiedlichen Verhältnissen gemischt und bei Raumtemperatur zu Zahnzementen ausgehärtet. IPDT, Temperaturen bei maximaler Abbaugeschwindigkeit, Aktivierungsenergien und Frequenzfaktoren des thermischen Abbaus der Proben wurden aus thermogravimetrischen Messungen ermittelt. Die Probe mit 20 Gew.-% Kryolith in der Füllstoffmischung ist thermisch sehr stabil.
    Notes: Dental cement compositions made by mixing poly(acrylic acid-co-acrylamide) and mixtures of zinc oxide and cryolite (Na3AIF6) in various proportions of 10-50 wt.-% (w/w) were cured at room temperature. From thermogravimetric analyses of the samples, the integral procedural decomposition temperatures (IPDT), maximum decomposition temperatures, activation energies and frequency factors were evaluated. The cured cement sample containing 20 wt.-% cryolite in the filler mixture is thermally very stable.
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  • 63
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    Angewandte Makromolekulare Chemie 224 (1995), S. 133-144 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Die wasserlöslichen aromatischen Diazonium-Doppelsalze p-Diazodiphenylaminchlorid/Zinkchlorid (DZS-1) und p-Diazoanisolchlorid/Zinkchlorid (DZS-2) wurden auf ihre Verwendbarkeit als photobleichbare Farbstoffe in der Kontrastverstärkungslithographie untersucht. Nach Untersuchung der Bleicheigenschaften der hergestellten Salze wurde DZS-1 in wäßrigen Lösungen mit Poly(vinylalkohol) als Kontrastverstärkungssystem eingesetzt. Die thermische Stabilität, der Resistkontrast, die Bestrahlungsparameter und andere Bleicheigenschaften wurden untersucht. Im Vergleich zu einem handelsüblichen i-Linien-Photoresist beträgt das Kontrastverhältnis der DZS-1/PVA CEL-Schicht 1,67.
    Notes: Water soluble aromatic diazonium double salts, p-diazodiphenylamine chloride zinc chloride (DZS-1) and p-diazoanisol chloride zinc chloride (DZS-2), have been evaluated as photobleachable dyes for contrast enhancement lithography. After testing the bleaching characteristics, aqueous solutions of DZS-1 and poly(vinyl alcohol) were used as a contrast enhancement material. Thermal stability, resist contrast, exposure parameters and other bleaching characteristics of the photobleachable membranes were investigated. A. commercial i-line photoresist was used to evaluate the contrast ratio of the DZS-1/PVA CEL layer. The contrast ratio obtained in this investigation is 1.67.
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  • 64
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    Angewandte Makromolekulare Chemie 224 (1995), S. 167-178 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Methylen-4,4′-diphenyldiisocyanat und zwei unterschiedliche Bisoxazoline wurden für Kopplungsreaktionen in mit Carboxygruppen terminierten flüssigkristallinen Poly(ethylenterephthalat-co-oxybenzoat)en eingesetzt. Um definierte Bedingungen zu gewährleisten, erfolgte die Synthese von Copolyestern mit unterschiedlichen Carboxygruppenkonzentrationen. Die Bestimmung des Carboxygruppengehalts wird beschrieben.Es erfolgt ein Vergleich des Kopplungsverhaltens beider Arten von Kettenverlängerern. Es konnte nachgewiesen werde, daß die Bisoxazoline bedeutend schneller reagieren als das Diisocyanat. Durch einen geringen Überschuß and Bisoxazolin in der Reaktionsmischung konnte einer thermischen Schädigung vorgebeugt werden. Abhängig von der Menge an zugegebenem Koppler wurden bei den modifizierten Copolyestern Oxazolinendgruppen beobachtet. Außerdem werden mögliche Vernetzungsreaktionen und die thermische Stabilität diskutiert.
    Notes: Methylene-4,4′-diphenyldiisocyanate and two different bisoxazolines were used for coupling reactions in carboxy-terminated liquid crystalline poly(ethylene terephthalate-co-oxybenzoate). In order to guarantee defined conditions, copolyesters with different carboxylic group concentrations were synthesized. The determination of the carboxylic group content is described.The coupling behaviour of both types of chain extenders has been compared. It was evidenced that the bisoxazolines reacted significantly faster than the diisocyanate. A slight excess of bisoxazoline in the reaction mixture prevented thermomechanical degradation. Depending on the amount of coupling agent added, an oxazoline termination of the copolyester was observed. Additionally, probable crosslinking reactions and the thermal stability have been discussed.
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  • 65
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    Angewandte Makromolekulare Chemie 224 (1995), S. 201-201 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
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  • 66
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    Angewandte Makromolekulare Chemie 225 (1995), S. 11-20 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Der Einfluß von 3-Phenylenbismaleimid auf die Werkstoffeigenschaften von mit Talkum und Zeolith gefüllten Polypropylen-Verbundstoffen wurde untersucht. Durch geeignete Planung des Aufbaus kann die Produkteigenschaft optimiert werden. Die Kapazität zur Füllstoffaufnahme schwankt bei Polypropylen je nach Art des Füllstoffs. Ein hochbelastbarer Verbundstoff kann aus einem geeignet modifizierten, mit Zeolith gefüllten Polypropylen hergestellt werden, auch wenn der Füllstoff in der Verbundmatrix dominiert. Als Ursache dieser Verstärkung wird eine verbesserte Wechselwirkung zwischen dem Polymeren und dem Füllstoff angenommen.
    Notes: The effect of 3-phenylene bismaleimide as a modifier for talc and zeolite-filled polypropylene composites has been studied. The usefulness of the experimental design to assure best product properties has also been illustrated. Polypropylene shows a variable degree of filling capacity depending on the type of filler. A high-strength composite can be prepared with suitably modified zeolite-filled polypropylene even if filler is the dominant phase in the composite matrix. An improved interfacial interaction between polypropylene and filler is proposed to be the reason for this improvement of strength.
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  • 67
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    Angewandte Makromolekulare Chemie 225 (1995), S. 51-61 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Die katalytische Oligomerisation von 1-Decen wurde mit Komplexverbindungen mehrerer Übergangsmetalle (Co(II), Co(III), Zr(IV), Ti(IV), Cr(III), V(V)) und Alkyl-aluminiumhalogeniden als Cokatalysatoren durchgeführt. Mit einem Chrom(III)-Et3Al2Cl3-Katalysatorsystem konnten Dimere (C20), Trimere (C30) und Tetramere (C40) von 1-Decen erhalten werden. Die kinematischen Viskositäten und Fließpunkte der hydrierten Oligomere wurden bestimmt und mit den Werten handelsüblicher Proben verglichen. Ein Mechanismus für die Oligomerisation von 1-Decen mit diesem Katalysatorsystem wird vorgeschlagen.
    Notes: The catalytic oligomerization of 1-decene has been carried out employing several transition metal complexes of Co(II), Co(III), Zr(IV), Ti(IV), Cr(III), V(V) in combination with alkyl aluminum halides as cocatalysts. The chromium(III)-Et3Al2Cl3 system exhibits good oligomerizing activity yielding dimers (C20), trimers (C30) and tetramers (C40) of 1-decene. The kinematic viscosities and pour points of hydrogenated oligomers have been determined and compared with those of commercial samples. The probable mechanism of oligomerization of 1-decene on this catalyst is described.
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  • 68
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    Angewandte Makromolekulare Chemie 225 (1995), S. 99-107 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Single-component formulations of epoxy resins with reactive accelerators must be storable. The preparation of several blocked accelerators is described. The basicity of tertiary amines, which correlates with accelerating effects, as well as acidity and structure of polyphenols and modified novolacs influences the extend of blocking. The curing process was investigated by measurements of gel time and viscosity.
    Notes: Einkomponentige Epoxidharzsysteme mit effizienten Reaktionsbeschleunigern müssen lagerstabil sein. Daher wurden Versuche unternommen, Beschleuniger auf Basis von tertiären Aminen mit modifizierten Phenolnovolaken zu blockieren. Das Ausmaß der Blockierung ist sowohl von der Basizität der Amine, die mit der beschleunigenden Wirkung korreliert, als auch von der Acidität und dem strukturellen Aufbau der modifizierten Phenole abhängig. Die Bewertung der Härtungseigenschaften erfolgte über Gelzeitbestimmungen und Viskositätsmessungen.
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  • 69
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Die Bruchzähigkeit von Phenolphthalein-Poly(etherketon) bei 190°C wurde mit zwei verschiedenen Methoden bestimmt, der konventionellen Rißwachstumsmethode und der „stress whitening zone“-Methode. Die gute Übereinstimmung der Ergebnisse zeigt, daß letztere Methode zur Bestimmung der Rißinitiierung einiger Polymerer herangezogen werden kann, für die das „blunting line concept“ nicht geeeignet ist.
    Notes: Fracture toughness values of phenolphthalein poly(ether ketone) (PEK-C) at 190°C were determined by two different methods, i.e. the conventional crack growth method and the crack stress whitening zone method, which show consistent results. This indicates that the crack stress whitening zone method can be used to determine the crack initiation of some polymers for which the blunting line concept is unsuitable.
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  • 70
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    Angewandte Makromolekulare Chemie 226 (1995), S. 13-22 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Stabilitätskonstanten und zugehörige thermodynamische Parameter (ΔH°, ΔS°) eines intermakromolekularen Komplexes aus Poly(acrylsäure-co-acrylamid), Poly(methacrylsäure-co-acrylamide) und Poly(N-vinylpyrrolidon) wurden mit bekannten Methoden bei verschiedenen Temperaturen bestimmt. Dabei wurde eine stufenweise Auflösung des Komplexes in Abhängigkeit von der Temperatur beobachtet, die mit den Stabilitätskonstanten und den thermodynamischen Parametern korreliert wurde.
    Notes: Stability constant and related thermodynamic parameters (ΔH° and ΔS°) of a multicomponent intermacromolecular complex consisting of poly(acrylic acid-coacrylamide), poly(methacrylic acid-co-acrylamide) and poly(N-vinylpyrrolidone) have been determined using known methods. A distinct stepwise disintegration of the complex at different temperatures has been observed, and this could be correlated with the stability constant and thermodynamic parameters calculated at various temperatures.
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  • 71
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    Angewandte Makromolekulare Chemie 226 (1995), S. 53-57 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Der Einfluß von Ultraschall auf die Polymerisation und Depolymerisation von Ethylmethacrylat und der Mechanismus des Kettenabbruchs wurden untersucht. Der Polymerisationsumsatz war unabhängig von den verwendeten Ultraschallbedingungen (800 W, 35 kHz). Depolymerisationsversuche mit Ultraschall bei 20°C zeigten, daß Kettenabbruch im wesentlichen durch Disproportionierung stattfindet; dabei werden Molekulargewichte nicht unter ca. 500000 erreicht.
    Notes: The effect of ultrasound in ethyl methacrylate polymerization and depolymerization and the chain termination mechanism for ethyl methacrylate have been studied. Polymerization conversion at 60°C did not depend on energy (80 W) and frequency (35 kHz) of ultrasound applied. In ultrasound depolymerization studies at 20°C the governing termination mechanism was found to be disproportionation and the lower limiting molecular weight was Mn = 500 000.
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  • 72
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    Angewandte Makromolekulare Chemie 226 (1995), S. 71-87 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: The copolymerization of acrylonitrile with maleic anhydride was investigated to synthesize acylic reactive polymers for manufacture of membranes that serve as support for covalent enzyme immobilization. The free-radical copolymer synthesis was carried out in solution (N,N-dimethylformamide (DMF), dimethylacetamide (DMAC), γ-butyrolactone, ethylene carbonate), by precipitation polymerization (dioxane) as well as bulk polymerization. The polymers were characterized using IR spectroscopy, elementary analysis, NMR spectroscopy, gel permeation chromatography, viscosity measurements, osmometry and potentiometry.The kinetic parameters were followed by dilatometric measurements up to high conversions. The anhydride content in the monomer mixtures showed a significant influence on the rate of polymerization and the molecular weight. With raised concentration of anhydride the polymerization rate and molecular weights decreased. Film forming polymers (M̄η 〉 30 000 g/mol) can be obtained by all copolymerization procedures with exception of solution polymerization in DMF and DMAC, respectively. The content of maleic anhydride in the membrane polymers did not exceed 5 mol-%, even though the maleic anhydride content in the monomer mixtures was raised up to the equimolar mixture. Nevertheless, such low maleic anhydride content of prepared membranes is enough for successful enzyme immobilization with amyloglucosidase (copolymer was prepared in γ-butyrolactone, M̄η = 49 000 g/mol, cPMSA = 0,3 mol-%).
    Notes: Die Copolymerisation des Acrylnitrils mit Maleinsäureanhydrid (MSA) wurde mit dem Ziel untersucht, acylfunktionalisierte Reaktivpolymere mit Filmbildungseigenschaften herzustellen, um diese in der Anwendung als Membran für kovalente Enzymfixierungen zu nutzen. Die radikalinitiierte Synthese der Copolymeren wurde in Lösung (Dimethylformamid (DMF), Dimethylacetamid (DMAC), γ-Butyrolacton, Ethylencarbonat), durch Fällungscopolymerisation (Dioxan) sowie in Substanz durchgeführt.Die Polymercharakterisierung erfolgte durch IR-Spektroskopie, Elementaranalyse, Kernresonanzspektroskopie, Gelpermeationschromatographie, Viskosimetrie, Osmometrie und Potentiometrie.Die Kinetik wurde durch dilatometrische Untersuchungen bis zu hohen Umsätzen verfolgt. Danach weist der Anhydridgehalt im Monomergemisch einen signifikanten Einfluß auf die Bruttopolymerisationsgeschwindigkeit und die Molmasse der Polymeren auf. Mit steigendem Anhydridanteil wird die Bruttopolymerisationsgeschwindigkeit herabgesetzt und eine Verringerung der Molmasse herbeigeführt. Die Copolymerisation von Acrylnitril und Maleinsäureanhydrid führt mit Ausnahme der Lösungspolymerisation in DMF bzw. DMAC zu Polymeren mit Molmassen oberhalb 30 000 g/mol, was ihre Anwendung als Membran ermöglicht. Die Einbaurate an Maleinsäureanhydrid in den Membranpolymeren ist bis einschließlich einer äquimolaren Zusammensetzung des Monomergemischs nicht größer als 5 mol-%. Derartig niedrige MSA-Reaktivgruppenanteile erweisen sich jedoch als ausreichend, um an einer aus einem Lösungspolymerisat (γ-Butyrolacton, M̄η = 49 000 g/mol, cPMSA = 0,3 mol-%) formierten Membran eine Enzymimmobilisierung mit Amyloglucosidase nachzuweisen.
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  • 73
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    Angewandte Makromolekulare Chemie 226 (1995), S. 143-160 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Die Synthesen einer Aryl-alkyl-azodiisocyanat-Verbindung und einer Azoharnstoff-Modellsubstanz werden beschrieben. Aus dem Azodiisocyanat wurden durch Grenzflächen-Polyaddition neuartige Azoharnstoff-Polymer hergestellt. Die zahlenmittleren Molekulargewichte, bestimmt mit der Gelpermeationschromatographie (GPC), lagen zwischen 6000 und 9000. Die Photolyse- und Thermolysereaktionen der Modellsubstanzen und der Polymeren wurden mittels UV-Spektroskopie und Differentialkalorimetrie (DSC) verfolgt und mit den Ergebnissen von ähnlichen Azoamiden verglichen. Der photochemische Polymerabbau wurde mittels GPC untersucht.
    Notes: The synthesis of an aryl alkyl azo diisocyanate and a model azo urea is described. From the azo diisocyanate new azo polyureas were created by interfacial polyaddition. Molecular weights Mn in the range of 6000 to 9000 were determined by gel permeation chromatography (GPC). Photolysis and thermolysis of both, model compounds and polymers, were studied by UV-spectroscopy and differential scanning calorimetry (DSC), respectively, and the results were compared with those of similar azo amides. Photochemical polymer degradation was followed by GPC.
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  • 74
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    Angewandte Makromolekulare Chemie 226 (1995), S. 219-219 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 75
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    Angewandte Makromolekulare Chemie 227 (1995), S. 69-85 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Thermotrop flüssigkristalline Copolyester aus Vanillinsäure (V), 4-Hydroxybenzoesäure (B) und Polyethylenterephthalat (E) wurden mittels 1H-NMR-Spektroskopie und Gelpermeationschromatographie (GPC) untersucht. Die neun möglichen Diaden konnten detektiert und zugeordnet werden. Die Abfolge der Grundeinheiten der V/B/E-Copolyester ändert sich mit zunehmendem B-Anteil von statistischer Verteilung zur Blockbildung und ist außerdem geringfügig von der Katalysatorkonzentration und der Polykondensationsdauer abhängig. Die GPC-Ergebnisse deuten darauf hin, daß die V/B/E-Copolyester engere Molekulargewichtsverteilungen aufweisen als die B/E-Copolyester. Mit von 0 bis 5 mol-% steigendem V-Anteil verengt sich die Molekulargewichtsverteilung. Die Gelpermeationschromatogramme der meisten V/B/E-Copolyester weisen im Unterschied zu den Einzelsignalen der B/E-Copolyester Dublett-Peaks auf.
    Notes: Thermotropic liquid-crystalline copolyesters made from vanillic acid (V), 4-hydroxybenzoic acid (B) and poly(ethylene terephthalate) (E) were examined by 1H-NMR and GPC investigations. Nine possible diads could be identified and assigned. The sequence distribution of V/B/E copolyesters tends to change from random to block with an increase of B content in the copolyesters. The sequence distribution also varies slightly with catalyst concentration and polycondensation time. GPC results suggest that the V/B/E copolyesters have narrower molecular weight distribution (MWD) than B/E copolyesters. The MWD of the copolyesters narrows gradually with increasing V content from zero to 5 mol-%. The GPC chromatograms of the most V/B/E copolyesters show double peaks, which is different from the single peak of the GPC chromatograms of the B/E copolyesters.
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  • 76
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    Angewandte Makromolekulare Chemie 227 (1995), S. 111-120 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Die Strahlungsbeständigkeit von vorbestrahltem Polypropylen mit 2,5 Gew.-% Ethylenanteil wurde mitr einem Copolymeren aus Polypropylen und einem nukleierenden Agens im Hinblick auf die Strahlungssterilisation von medizinischen Geräten verglichen. Die Transparenz des Propylen-Ethylen-Copolymeren wurde durch die Vorbehandlung verbessert. Im Vergleich mit der ebenfalls verbesserten Transparenz des Copolymeren aus Polypropylen und dem nukleierenden Agens wurde durch die Vorbestrahlung die Strahlungsbeständigkeit während der Bestrahlung und bei der Lagerung des bestrahlten Materials verbessert. Dies wird auf die geringere Kristallinität des vorbestrahlten Polypropylens aufgrund von bei der Bestrahlung gebildeten Verzweigungen zurückgeführt.
    Notes: The radiation stability of the pre-irradiated copolymer of polypropylene containing 2.5 wt.-% ethylene units is compared with a copolymer of polypropylene with a nucleating agent with regard to radiation sterilization of medical devices. It is found that transparency property of the propylene-ethylene copolymer is improved through pre-irradiation processes. This finding was compared with the co-polypropylene with nucleating agent which also gives a better transparency property. In comparison, it is found that pre-irradiated copolymer exhibits better radiation stability during irradiation and during storage after irradiation. The radiation stability of the pre-irradiated copolymer is due to its lower crystallinity caused by the formation of branches during the pre-irradiation process.
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  • 77
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    Angewandte Makromolekulare Chemie 227 (1995), S. 193-193 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 78
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Polydiaryldiazosulfide wurden durch Grenzflächenpolykondensation aus aromatischen Bisdiazoniumionen und Benzol-1,3-dithiol erhalten. Auf diese Weise wurden Molekulargewichte Mn von 3400 bis 11700 erreicht (GPC).Die neue Polymerklasse zeichnet sich durch hohe Photolabilität und relativ geringe Thermostabilität aus. Mittels UV-Spektroskopie wurde die Photolyse von Modellver-bindungen und Polymeren verfolgt, wobei in nahezu allen Fällen ein Zerfall 1. Ordnung beobachtet wurde. Der photochemische Kettenabbau konnte durch GPC-Untersuchungen verfolgt werden. Die thermische Stabilität der polymeren Diazosulfide wurde durch DSC-Messungen untersucht.
    Notes: Poly(diaryl diazosulfide)s were synthesized from aromatic bisdiazonium ions and benzene-1,3-dithiol via interfacial polycondensation. Number-average molecular weights Mn in the range of 3400 to 11700 were determined by gel permeation chromatography (GPC).The new polymer class is distinguished by high photosensitivity and low thermostability. First order kinetics during photolysis of nearly all polymers and model compounds under investigation was observed by means of UV spectroscopy. Polymer degradation upon irradiation was verified by GPC measurements. Thermal decay was followed by differential scanning calorimetry (DSC).
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  • 79
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Three different titration methods were proved with respect to accuracy, reproducibility and handling for the determination of maleic anhydride (MSA) content in acrylonitrile (AN) copolymers in form of poly(AN-co-MSA) and poly(AN-co-styrene-co-MSA). The comparison comprises (i) the combined method A/H characterized by the reaction of anhydride groups (AG) with aniline and titration of the formed monoacid with methanolic KOH (A) and the complete hydrolysis of AG and titration of acid groups (SG) with aqueous NaOH (H), (ii) method B based on the conversion of AG with n-butylamine (BA) and back-titration of unreacted amine with HClO4 in glacial acetic acid and (iii) method C consisting of the reaction of AG with p-chloroaniline (pCA) followed by Cl-determination after the Schöniger-decomposition. Whereas all mentioned methods are suitable for the determination of AG in the presence of initial SG, the combination of A/H additionally allows the simultaneous determination of AG and SG. In comparison with the other methods the combination of A/H is to be favoured due to the possibility to obtain additional information about SG and because of the better results in accuracy, reproducibility and handling. By means of FTIR spectroscopy the content of AG and SG was estimated qualitatively and a correlation between the spectroscopic and potentiometric data of AG was discovered.
    Notes: Zur Bestimmung des Maleinsäreanhydrid(MSA)-Gehaltes in Acrylnitril(AN)-Copolymeren des Typs Poly(AN-co-MSA) bzw. Poly(AN-co-Styrol-co-MSA) wurden drei verschiedene Titrationsmethoden hinsichtlich ihrer Richtigkeit, Reproduzierbarkeit sowie ihres Zeitaufwandes geprüft. Miteinander verglichen wurden (i) eine Methodenkombination A/H bestehend aus dem Teilschritt A, einer Umsetzung der Anhydridgruppen (AG) mit Anilin einschließlich der Titration der Monosäuregruppen mit methanolischer KOH, und dem Teilschritt H, einer vollständigen Hydrolyse der AG und Titration der Säuregruppen (SG) mit wäßriger NaOH, (ii) Methode B basierend auf der Reaktion der AG mit n-Butylamin (BA) und der Rücktitration des nicht umgesetzten Amins mit Perchlorsäure (HClO4) in Eisessig und (iii) Methode C, beruhend auf der Umsetzung der AG mit p-Chloranilin (pCA) und nachfolgender Chlorbestimmung durch Schöniger-Aufschluß. Während sich alle genannten Methoden prinzipiell für die AG-Bestimmung in Gegenwart initialer SG empfehlen, ist darüber hinaus über A/H eine simultane Bestimmung von AG und SG möglich. Wegen dieses zusätzlichen Informationsgewinns, ihrer besseren Reproduzierbarkeit, der erhöhten Richtigkeit sowie des geringeren zeitlichen und apparativen Aufwandes ist die Kombination A/H zu favorisieren. Mit Hilfe der FTIR-Spektroskopie wurde der Gehalt an AG und SG qualitativ verfolgt und eine Korrelation zwischen den Bandenintensitäten der AG und den potentiometrisch erhaltenen Werten gefunden.
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  • 80
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    Angewandte Makromolekulare Chemie 229 (1995), S. 15-27 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Die Härtung eines ungesättigten Polyesterharzes mit niedrigem Exotherm-Peak wurde mit der Standardmethodik und der Differential-Kalorimetrie (DSC) untersucht. Ein Kupfersalz und α-Methylstyrol wurden als Polymerisationsverzögerer benutzt. Der Einfluß der Verzögerer auf die Temperatur des exothermen Peaks, die Gelzeit, die Härtungsenthalpie und die Polymerisationskinetik wurden untersucht.
    Notes: The curing behavior of an unsaturated polyester resin with low exotherm peak was studied by a standard procedure and by differential scanning calorimetry (DSC). A copper salt and α-methylstyrene were used as the polymerization retarders. The influence of the retarders on the exotherm peak temperature, gelation time, exothermic heat and the polymerization kinetics was investigated.
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    Angewandte Makromolekulare Chemie 229 (1995), S. 93-112 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Propen und 1-Octen wurden mit dem syndiospezifischen Metallocen-Katalysator Me2C(Cp)(Flu)ZrCl2/MAO copolymerisiert. Es wurde ein hoher, statistischer Octeneinbau beobachtet. Niedrige Octenkonzentrationen beeinflußten die Aktivität des Katalysators nur wenig; Molekulargewicht, Kristallinität, E-Modul und Glastemperatur wurden dagegen mit ansteigendem Octengehalt erniedrigt. Blends aus ataktischem Oligopropen und syndiotaktischem Polypropen bzw. Poly(propen-co-octen) wurden aus einer Toluol-Lösung hergestellt. Diese Lösungsblends wurden mit einem Reaktorblend verglichen, der mit einem Hybrid-Katalysator bestehend aus einer Mischung von syndiospezifischem Me2C(Cp)(Flu)ZrCl2/MAO und unspezifischem Cp2ZrCl2/MAO hergestellt wurde. Das ataktische Oligopropen wirkte als Weichmacher, der E-Modul und Glastemperatur der Blends erniedrigte.
    Notes: Propene and 1-octene were copolymerized with the syndiospecific homogeneous metallocene catalyst Me2C(Cp)(Flu)ZrCl2/MAO. Large amounts of octene were incorporated randomly. While catalyst activity was not affected markedly by low octene content, molecular weight, crystallinity, Young's modulus, and glass transition temperature were reduced with increasing octene content. Blends of atactic oligopropene with syndiotactic polypropene and poly(propene-co-octene) were prepared from toluene solution and compared with a reactor blend prepared with a hybrid catalyst containing a mixture of syndiospecific Me2C(Cp)(Flu)ZrCl2/MAO and non-specific Cp2ZrCl2/MAO. Atactic oligopropene acted as plasticizer reducing Young's modulus and glass transition temperature of the blends.
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    Angewandte Makromolekulare Chemie 229 (1995), S. 175-184 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Die innere Oberfläche und das Hohlraumsystem von verschiedenartigen Celluloseregeneratfasern werden mit Röntgenkleinwinkelstreuung untersucht. Dabei wird gefunden, daß alle Fasern ein Hohlraumsystem von 0,01 bis 0,1% (Volumenanteil 10-4-10-3) aufweisen. Es zeigt sich jedoch, daß die Größe des Hohlraumsystems für die mechanischen Eigenschaften wenig Bedeutung hat. Es ist vielmehr die Gestalt der Hohlräume und ihre Orientierung, die hier wesentlich sind. Es wird gefunden, daß langgestreckte Hohlräume, vermutlich orientiert, für gute mechanische Eigenschaften verantwortlich sind. Damit können auch verbesserte textile Eigenschaften von Lyocellfasern des NMMO-Typs erklärt werden.
    Notes: Both the inner surface and the void system of different cellulose regenerate fibers are investigated with X-ray small angle scattering. Thereby it turns out that all fibers have a void system of 0.01 to 0.1% (volume fraction 10-4-10-3). However, the amount of the void system has little influence on the mechanical properties. Rather, it is the shape of the voids and their orientation which proves essential. It is found that elongated voids, probably well oriented, are responsible for superior mechanical properties. This explains also improved textile properties of lyocell fibers of the NMMO type.
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    Angewandte Makromolekulare Chemie 230 (1995), S. 1-12 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Die mit γ-Strahlen induzierte Polymerisation von Methacrylsäure (MA) und Acrylsäure (AA) mit Acrylamid (AAm) (M2) in Substanz wurde untersucht. Die nach Kelen-Tüdős berechneten Copolymerisationsparameter betragen r1 = 1.35 und r2 = 0.22 für MA-AAm bzw. r1 = 1.75 und r2 = 0.10 für AA-AAm. Die Polymerisationsgeschwindigkeit hängt sowohl von der Temperatur als auch von der Comonomerzusammensetzung ab. Die differentialkinetischen Kurven sind unimodal, was darauf hinweist, daß nur der Copolymerisationsprozeß abläuft. Ein zweites Maximum in diesen Kurven wird mit Vernetzung und der Bildung wasserunlöslicher Bestandteile erklärt. Die Copolymeren sind weiße Pulver; die wasserlöslichen Fraktionen sind im Gegensatz zu den wasserunlöslichen nicht giftig, aber als Immunmodulatoren weniger aktiv.
    Notes: A study was made of the γ-radiation-induced bulk copolymerization of the methacrylic acid-acrylamide (M2) (MA-AAm) and acrylic acid-acrylamide (M2) (AA-AAm) monomeric pairs. The copolymerization reactivity ratios deterined according to the Kelen-Tüdő method were: r1 = 1.35, r2 = 0.22 for the MA-AAm pair, and r1 = 1.75, r2 = 0.10 for the AA-AAm pair. It has been established that the polymerization rate depends both on the composition of the starting reaction mixture and on the reaction temperature. The differential kinetic curves obtained are unimodal ones, suggesting the occurrence of only one process, i.e. copolymerization. A second maximum in these curves, appearing at elevated temperature, is explained by crosslinking and formation of a water-insoluble fraction. The copolymers obtained are white powders; in contrast to their water-insoluble fractions, the water-soluble ones are not toxic but they are less active as immunomodulators.
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  • 84
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    Angewandte Makromolekulare Chemie 228 (1995), S. 201-219 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Die Hydrolyse von Poly(ester-urethan-harnstoffen) (PURUs) wurde untersucht. Es handelt sich dabei um einen komplexen Vorgang, der die Analyse der Beziehung zwischen der Zusammensetzung der PURUs und ihrer Hydrolysebeständigkeit erschwert. Es wurde gefunden, daß die Hydrolysebeständigkeit mit Zunahme (i) der Polyol-Acidität, (ii) des Estergruppen-Gehaltes, (iii) der Beweglichkeit der Hauptketten und (iv) deren Hydrophilie abnimmt; die Molmasse des Polyols scheint keinen merklichen Einfluß darauf zu haben. Der negative Einfluß von Ethergruppen (obwohl hydrolysebeständiger als Estergruppen) ist möglicherweise auf eine Zunahme der Hauptkettenbeweglichkeit und den dadurch leichteren Zugang von Wassermolekülen zu Estergruppen zurückzuführen. Der positive Effekt von aromatischen Ringen in Polyolen kann einer erhöhten Steifigkeit der Hauptkette als auch einer ansteigenden Hydrolysebeständig-keit benachbarter Estergruppen durch Resonanzeffekte zugeschrieben werden. Insgesamt kann angenommen werden, daß die beschriebenen Effekte sich überlagern und gleichzeitig die resultierende Hydrolysebeständigkeit vorherbestimmen. Es sollte daher möglich sein, qualitative Vorhersagen bezüglich der Hydrolysebeständigkeit in Abhängigkeit von der Zusammensetzung der PURUs zu treffen.
    Notes: Hydrolysis of poly(ester urethane ureas) (PURUs) is a complex phenomenon which impedes the analysis of the relationships between their composition and hydrolytic stability. Hydrolytic stability of PURUs decreases due to rising (i) polyol acidity, (ii) content of ester groups, (iii) flexibility and (iv) hydrophilicity of the backbones; molar mass of polyols does not seem to have any appreciable effect on it. Negative influence of ether groups (which have better hydrolytic stability than ester groups) is probably linked to the increase in the backbone flexibility and, consequently, to easier access of water molecules to ester groups. Positive effect of aromatic rings in polyols can be ascribed to enhanced rigidity of the backbones as well as to increased hydrolytic stability of adjacent ester groups due to the resonance effect. It can be presumed that the mentioned effects will superpose and simultaneously predestine the resulting hydrolytic resistance. Considering the observed tendencies, it is possible to qualitatively predict the trends how the hydrolytic stability will respond to changes in PURUs composition.
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  • 85
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    Angewandte Makromolekulare Chemie 229 (1995), S. 63-72 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Eine neuartige lichtempfindliche Naphthochinondiazid-Verbindung (NQD) wurde aus 2,6-Bis(hydroxymethyl)-3,4-dimethylphenol und Toluoldiisocyanat synthetisiert und mit IR-, NMR- und Elementaranalyse identifiziert. Die Bleicheigenschaften unter Lichteinwirkung wurden mit UV-Spektrophotometrie bestimmt. Die Anwendung von NQD in der Photolithographie als positiver Photoresist sowie einer wäßrigen Lösung von NQD, Novolak, Cellosolve-Acetat und DMF als lichtempfindliches Material wurde untersucht. Das hergestellte NQD erwies sich als effektive Komponente in positiven Photoresists. Die optimalen Bedingungen der UV-Dosis, Schichtdicke und Resistzusammensetzung wurden abgeschätzt. Die Auflösung des positiven Photoresists wurde durch Rasterelektronenmikroskopie bestimmt. Außerdem wurde der Einfluß von UV-Dosis und -Wellenlänge, Einwirkungsdauer und Entwicklungszeit auf die Empfindlichkeit und die Auflösung des Photoresists untersucht.
    Notes: A new photosensitive naphthoquinonediazide (NQD) was synthesized from 2,6-bis-(hydroxymethyl)-3,4-dimethylphenol and toluene diisocyante. NQD was identified by using IR, NMR and elemental analyses. Photobleachable characteristics were evaluated by UV spectrophotometry. Applications of the NQD on the photolithography as a positive working photoresist were investigated. The aqueous solution of NQD, novolak, cellosolve acetate, and DMF was used as a photosensitive material. It was found that NQD synthesized in this investigation can be used as an effective component in a positive photoresist. Optimal conditions of the UV dose, coating thickness, and development of the resist system were estimated. Resolution of the positive resist was evaluated by SEM technique. Effects of UV dose, exposure time, development time, and exposure UV wave length on the sensitivity and resolution of the photoresist were investigated.
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  • 86
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    Angewandte Makromolekulare Chemie 229 (1995), S. 123-132 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Die radikalinduzierte Polymerisation von phenlysubstituierten 2-Methylen-1,3-dioxanen wurde untersucht. Es kann gezeigt werden, daß die grundlegende Polymerisationstendenz derartiger Ketenacetale darin besteht, über die Doppelbindung zu hochmolekularen Polyacetalen ohne eine nennenswerte Ringöffnung zu polymerisieren. Einflußfaktoren, wie z. B. resonanzstabilisierte Kettenenden oder sterische Hinderungen während des Wachstumsschrittes sind nicht in der Lage, die Polymerisation in die Richtung der gewünschten Ringöffnung zu lenken.Mittels Dichtemessungen wurden Informationen über das Schrumpfungsverhalten gewonnen. Es konnte gezeigt werden, daß raumerfüllende Substituenten am 2-Methylen-1,3-dioxansystem bei der Homopolymerisation grundsätzlich eine geringe Volumenschrumpfung bewirken und die Schrumpfung von herkömmlichen Monomeren bei der Copolymerisation herabsetzen können.
    Notes: We have investigated the free radical polymerization of phenyl-substituted 2-methylene-1,3-dioxanes. It was shown that there is a basic tendency of such ketenacetals to undergo exclusively a vinyl polymerization forming high-molecular polyacetals without any detectable ring opening. The polymerization with the desirable ring opening reaction cannot be controlled by factors like resonance stabilized chain ends or steric hindrance in the growing step.From densitometric measurements we got new information about the shrinkage behaviour. It was demonstrated that bulky substituents attached to the 2-methylene-1,3-dioxane system result in a significant low shrinkage in homopolymerization and the shrinkage of common comonomers can be decreased by copolymerization.
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  • 87
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    Angewandte Makromolekulare Chemie 229 (1995), S. 133-143 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Die Polymerisation von Acrylamid (AAM) in einer konzentrierten bikontinuierlichen Mikroemulsion wurde studiert. Die Initiierungsstelle bei Verwendung von radikalischen Initiatoren mit verschiedener Wasserlöslichkeit wurde untersucht. Es wurde festgestellt, daß ein vollständig oder teilweise wasserlöslicher radikalischer Initiator die Acrylamidpolymerisation in der untersuchten Mikroemulsion effektiv initiieren kann. Die dadurch entstandenen Polymeren weisen eine Spezialstruktur auf, die von der Zusammensetzung der ursprünglichen Mikroemulsion abhängig ist.
    Notes: The polymerization of acrylamide (AAM) in concentrated bicontinuous microemulsion systems was studied. The locus of initiation using radical initiators with various water-solubility was investigated. It was found that water-soluble and partially water-soluble initiators initiate the AAM polymerization in the reaction systems under investigation very effectively. The polymers thus formed have special structures dependent on the composition of the original concentrated bicontinuous microemulsion.
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  • 88
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    Angewandte Makromolekulare Chemie 229 (1995), S. 209-209 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 89
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    Angewandte Makromolekulare Chemie 229 (1995), S. 185-198 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Bacteriorhodopsin is a component of the purple membrane of Halobacterium halobium. It shows photochemical activity and undergoes a series of photocyclic-associated conformational changes. Incorporated in a matrix it is suitable as a light energy/electrical current transducer. Very important is an orientation of purple membrane fragments.The reaction between solutions of a polyelectrolyte and multivalent ions leads to a ionotropic gel, that is a gel with an ordered structure. If the gel formation was carried out in the presence of purple membrane fragments, the Bacteriorhodopsin is highly oriented and produces a photoelectrical signal. It consists a correlation between the light direction and the orientation of the purple membrane due to the gel formation.
    Notes: Bacteriorhodopsin ist Bestandteil der sogenannten Purpurmembran des Mikroorganismus Halobacterium halobium. Es zeigt photochemische Aktivität und kann als biologischer Lichtwandler fungieren. Voraussetzung hierfür ist eine orientierte Anordnung der Purpurmembran in einer Matrix.Das Prinzip der ionotropen Gelbildung, d. h. die geordnete Strukturbildung einer Polyelektrolytlösung infolge eines gerichteten Diffusionsstromes von mehrwertigen Ionen gestattet die orientierte Anordnung der Purpurmembran. Durch Lichteinwirkung werden elektrische Signale induziert. Es besteht ein Zusammenhang zwischen der Richtung des Strahlungseinfalls und der durch die Gelwachstumsrichtung festgelegten Orientierung der Purpurmembran.
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  • 90
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The thermal oxidation of β ray-crosslinked polyethylene (XLPE) was studied in temperatures ranging from 90 to 180°C. Various analytical methods were used for determination of an end of the induction period on bulk samples: gravimetry, ultimate tensile properties, density and color change. On microtome slices of ∼30 μm thickness the depth distribution of oxidation products, phenolic antioxidant, density and tensile ultimate properties were followed as a function of exposure time by respectively IR and UV spectrophotometry, densitometry and Microfoil Tensile Testing.Depending on the testing method different durations of induction period (DIP) were obtained. They increase in following order:Phenol depletion 〈 Ultimate elongation 〈 Density 〈 Carbonyl build-up ≤ Color change 〈 Weight loss.The difference between phenol depletion DIP and carbonyl build-up DIP can be considered as negligible at temperatures higher than the melting point (about 30%) but it reachs more than 100% at T〈 Tm.Different kinetic regimes of phenol consumption were observed depending on the exposure temperature. A mechanistic interpretation is proposed explaining the role of the stabilizer system in initially homogeneous and later heterogeneous oxidation of the bulk material.The Arrhenius law was applied to different durations of induction period. A discontinuity appeared in the melting point region (120-130°C) which is tentatively interpreted in terms of different stabilizer concentration in amorphous phase of semicrystalline material (T 〈 Tm) and in melt material (T 〉 Tm). On the basis of the presented complex study of polyethylene thermo-oxidation, different aspects of lifetime predictions are discussed.
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  • 91
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Most plastics are produced from oil and have a high potential as hydrocarbon sources for the chemical industry. Pyrolysis is a practicable way to pyrolyze mixed plastics. The fluidized bed pyrolysis has turned out to be particularly advantageous. 25 to 45 percent of product gas with a high heating value and 30 to 50 percent of an oil rich in aromatics, could be recovered. The oil is comparable to that of a mixture of light benzene and bituminous coal tar. Up to 60 percent of ethene and propene are produced by using mixed polyolefins as feedstock. Under appropriate conditions the pyrolysis could be successful on the market.
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  • 92
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: When poly(methyl methacrylate) films containing UV absorbers are exposed to UV light, the absorbers undergo photodegradation resulting in loss of absorbance. If the data extend for less than one half-life, both zero and first order kinetic treatment give fairly linear fits, but the rate constants so derived are dependent on the initial absorbance of the films. When the zero order rate constants are corrected to account for the higher rate of degradation near the surface compared with the bulk that occurs in highly absorbing films, consistent “infinite absorption” zero order rate constants are derived. The inhomogeneous degradation is due to only the highly absorbed, higher energy light contributing significantly to the degradation. For the benzophenone and benzotriazole classes of absorber, at least 65% of the degradation is due to light with wavelengths 〈 350 nm. Structural variations generally caused only small differences in the rates of degradation of these classes of absorbers unless the substitutions disrupted the intramolecular hydrogen bonds that are critical for stability. If the hydrogen bond is weakened, the absorber is less stable.
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  • 93
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Aus Cardanol, einem Bestandteil der Schale der Cashewnuß, wurde durch Kondensation mit Formaldehyd und substituierten aromatischen Verbindungen unter saurer oder basischer Katalyse eine Reihe von Harzen hergestellt und anhand ihrer IR-Spektren charakterisiert. Sie lassen sich als selektive Ionenaustauscher für bestimmte Ionen verwenden, was mittels einer Gleichgewichtsmethode geprüft wurde. Das thermische Verhalten der Harze wurde untersucht, und ein plausibler Abbaumechanismus wird vorgeschlagen.
    Notes: A large number of resins have been synthesized by reacting cardanol, a constituent of cashewnut shell liquid, with formaldehyde and substituted aromatic compounds in the presence of acidic and basic catalysts. The resins have been characterized by IR spectra. They were shown to be selective ion exchangers for certain metal ions. A batch equilibrium method was used for studying the selectivity of the metal ions. The thermal behaviour of the resins has been studied and a plausible degradation mechanism has been suggested.
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  • 94
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Bisphenol A polycarbonate (BPA-PC) is an important high performance engineering thermoplastic well known for its outstanding combination of toughness, transparency and heat resistance. These properties make it an idel material for demanding applications where it is exposed to external stresses such as elevated temperatures, ultraviolet light and γ-ray sterilization. However, on extended exposure to these conditions, BPA-PC slowly degrades, turning progressively more yellow, eventually leading to a decrease in its physical properties. Over the years, there has been numerous studies made to understand these degradative processes so as to better design more stable BPA-PC formulations. In this paper, this chemistry is briefly reviewed along with more recent work in this area with a special emphasis on the efforts made to identifying the actual chemical species responsible for the observed yellow color and the chemistry responsible for their formation.
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  • 95
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Hindered Amine Light Stabilizers (HALS) are know to inhibit the photo-oxidation of polymers. A key reaction in their stabilization mechanism is believed to be the conversion of a hindered aminoether into a nitroxyl radical. Several different possible mechanisms for this conversion were explored. One, the elimination of the aminoether to form an olefin and hydroxylamine (an intermediate in the formation of a nitroxyl), while possible at high temperatures, cannot account for the inhibitory activity we observed for secondary and primary aminoethers. Direct radical displacement by peroxy radicals was also considered. However, the products predicted by this reaction pathway were not observed. Finally, oxidation of the nitrogen by a peroxy radical, by either electron transfer or a radical attack on the nitrogen, was investigated. While electron transfer was shown to be unlikely, direct oxidation of the aminoether nitrogen was supported by our results. A detailed mechanism for the reaction of both alkyl- and acyl-peroxy radicals with aminoethers is proposed.
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  • 96
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Die thermischen und dynamisch-mechanischen Eigenschaften einiger linearer kautschukelastischer Polyurethane mit chemisch unterschiedlichen starren Segmenten wurden untersucht und zur chemischen Zusammensetzung in Beziehung gesetzt. Interessante Zusammenhänge wurden zwischen der Kristallinität der elastischen Polyurethanharnstoffe und der aromatischen oder cycloaliphatischen Natur der Diisocyanat-Komponenten gefunden. Darüber hinaus scheinen die Ergebnisse bei einem bestimmten Verhältnis zwischen starren und flexiblen Segmenten und bei gegebener Zusammensetzung der flexiblen Gruppen auf eine bessere Phasenseparation bei den Polyurethanharnstoffen mit cycloaliphatischen starren Segmenten als bei solchen mit aromatischen, starren Einheiten hinzuweisen.
    Notes: Experimental batches of linear rubber-like polyurethanes characterized by the presence of chemically different hard segments are studied and their thermal and dynamic-mechanical properties are related to the differences in chemical compositions. Interesting correlations are found between the development of crystallinity in such elastomeric poly(urethaneurea)s and the aromatic or alicyclic nature of the diisocyanate. Moreover, for a fixed ratio between hard and soft segments, and for a given composition of the soft segment, the results seem to indicate a better degree of phase separation in cycloaliphatic-based hard segment poly(urethaneurea)s than in aromatic-based hard segment poly(urethaneurea)s.
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  • 97
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    Angewandte Makromolekulare Chemie 231 (1995), S. 135-144 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Makromonomere Polyethylenoxid-Azoinitiatoren (Makroinimere) MIM-400 und MIM-1500 wurden synthetisiert und IR- und NMR-spektroskopisch sowie mit Hilfe der DSC-Analyse charakterisiert. Die mit diesen Makroinimeren initiierte Dispersions-polymerisation von Styrol bzw. Methylmethacrylat (MMA) in Ethanol/Wasser bei 60°C wurde untersucht. Dabei wurde gefunden, daß die Polymerisationsgeschwindig-keit mit zunehmender MIM-Konzentration ansteigt, wobei der Anstieg im Styrolsystem ausgeprägter war. Im Bereich von mittleren Umsätzen konnte gezeigt werden, daß die Polymerisationsgeschwindigkeit von MMA proportional der Potenz 1,7 bzw. 1,6 von [MIM-400] bzw. [MIM-1500] ist, während für Styrol eine Potenz von 2,5 bezüglich [MIM-400] gefunden wurde.
    Notes: Macromonomeric poly(oxyethylene) azoinitiators (macroinimers) MIM-400 and MIM-1500 were synthesized and characterized by IR and NMR spectroscopy and DSC techniques. The dispersion polymerizations of styrene and methyl methacrylate (MMA) initiated by poly(oxyethylene) macroinimers (MIM-400 and MIM-1500) in water/ethanol were investigated at 60°C. The rate of polymerization was found to increase with increasing concentration of MIM and the increase was more pronounced in the styrene system. In the range of medium conversions the rate of polymerization was found to be proportional to the 1.7th and 1.6th power of [MIM-400] and [MIM-1500] for MMA and to the 2.5th power of [MIM-400] for styrene, respectively.
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  • 98
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    Angewandte Makromolekulare Chemie 231 (1995), S. 187-198 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Glass transition temperatures of binary and ternary blends of chemically uniform poly(styrene-co-n-butyl methacrylate)s with a mean content of 30.8 wt.-% of n-butyl methacrylate and number-average molar masses in the range of 4900 and 67000 g/mol have been investigated in relation to their composition. The blends showed significant deviations from an ideal behaviour with reference to a linearity between glass transition temperature and composition.This phenomenon is described by a mathematical model where polynoms are particularly well suited to represent the glass transition temperatures of the blends, partly exceeding those of the pure components. Finally, various reasons of these deviations were discussed. Here, energetical interactions seem to be of considerable importance combined with a nonadditivity of volumes.
    Notes: Die Glasübergangstemperaturen binärer und ternärer Mischungen chemisch einheitlicher Poly(styrol-co-n-butylmethacrylat)e mit einem mittleren n-Butylmethacrylat-Anteil von 30,8 Gew.-% und unterschiedlichen zahlenmittleren Molmassen im Bereich von 4900 bis 67000 g/mol wurden in Abhängigkeit von der Zusammensetzung untersucht. Es wurden wesentliche Abweichungen vom idealen Verhalten bezüglich einer linearen Abhängigkeit zwischen Glasübergangstemperatur und Zusammensetzung festgestellt.Dieses Verhalten konnte mit einem mathematischen Modell dargestellt werden, wobei sich insbesondere Polynome zur Beschreibung der teilweise über den Werten der Ausgangskomponenten liegenden Glasübergangstemperaturen der Mischungen als geeignet erwiesen. Schließlich wurden verschiedene Ursachen für diese Abweichungen diskutiert, wobei offensichtlich energetische Wechselwirkungen verbunden mit einer Nichtadditivität der Volumina von wesentlicher Bedeutung sind.
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  • 99
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    Angewandte Makromolekulare Chemie 233 (1995), S. 133-148 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: ε-Caprolactam (CL) and phenyl glycidyl ether (PGE) were homopolymerized using the initiator/accelerator-systems Na-caprolactam/N-acetyl-caprolactam (NaCL/AcCL) and Na-caprolactam/N-acetyl imidazole (NaCL/AcImi). In a one-pot reaction both monomers gave different oligomeric reaction products depending on the reaction temperature (100°C to 140°C, max. 240°C) but no regular copolymers. Soluble products were separated by HPLC and identified by means of spectroscopic methods. In acetone insoluble products were investigated by IR- and NMR-spectroscopy, mass spectrometry and elemental analysis.
    Notes: Es wurden Versuche zur Homopolymerisation von ε-Caprolactam (CL) und Phenylglycidether (PGE) mit den Initiator/Beschleuniger-Systemen Na-Caprolactam/N-Acetylcaprolactam (NaCL/AcCL) und Na-Caprolactam/N-Acetylimidazol (NaCL/AcImi) durchgeführt, um die für eine mögliche Copolymerisation von CL und PGE geeigneten Reaktionsbedingungen zu ermitteln. CL und PGE wurden in unterschiedlichen molaren Verhältnissen (CL : PGE = 1 : 5 bis 1 : 0,05) und bei Temperaturen zwischen 100°C und 140°C (max. 240°C) in einer Eintopfreaktion polymerisiert.Die löslichen Produkte wurden mittels HPLC getrennt und spektroskopisch identifiziert. Die in Aceton unlöslichen Produkte wurden mit IR- und NMR-Spektroskopie, Massenspektrometrie (MS) und Elementaranalyse untersucht.
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  • 100
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    Angewandte Makromolekulare Chemie 236 (1996), S. 111-127 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Neuartige Fluoropolyether-Polyol-Harze, die mit konventionellen Härtern wie Polyisocyanaten oder Melaminen aushärtbar sind, wurden hergestellt. Zunächst wurden oligomere NCO-terminierte Prepolymere durch Addition von Fluorpolyether-Makrodiolen unterschiedlicher Molekulargewichte an Isophorondiisocyanate erhalten. Durch die Reaktion dieser Prepolymeren mit Trimethylolpropan wurden endständige Hydroxygruppen eingeführt. Die Viskosität von Lösungen dieser Harze wurde bei unterschiedlichen Konzentrationen (Massenbruch 0,4-0,8) und Temperaturen (25°C-65°C) gemessen. Die erhaltenen Werte wurden auf der Basis der Erickson-Gleichung (Konzentrationsabhängigkeit von η) und unter Berücksichtigung des WLF-und des Arrhenius-Modells (Temperaturabhängigkeit von η) diskutiert. Das thermische Verhalten der Harze und von ausgehärteten Filmen wurde mit DSC bestimmt. Dabei wurden zwei Glasübergange beobachtet, die den separierten fluorhaltigen und nicht-fluorhaltigen Phasen zugeordnet werden können. Die Analyse des Zugverhaltens der Filme zeigte besonders bei den mit Isocyanat gehärteten Proben ein ausgeprägtes hart-plastisches Verhalten. Diese Werkstoffe erscheinen für die Anwendung als hoch-wertige, dauerfeste und klare Beschichtungen geeignet.
    Notes: New fluoropolyether polyolic resins are presented suitable to be cured with conventional hardeners as polyisocyanates or melamines. These resins are prepared by addition of fluoropolyether macrodiols (Fomblin® ZDOLTX) of various molecular weights to isophorone diisocyanate (IPDI) to give oligomeric NCO-terminated prepolymers. The final hydroxy functionality is obtained by the reaction of those prepolymers with trimethylolpropane (TMP). The viscosity of the resins is measured at various concentrations (weight fraction 0.8 - 0.4) and temperatures (T = 25-65°C). The results are discussed in terms of the Erickson equation (η vs. concentration) and using the WLF and Arrhenius models (η vs. T). The thermal behavior is studied by DSC for both the resins and cured films indicating the presence of two Tgs, corresponding to the segregated fluorinated and hydrogenated phases, the former particularly evident with the highest molecular weights of the fluorinated macromer. Tensile curves of selfsupported films are then analyzed showing an evident tough-plastic behavior especially for the isocyanate-cured films. The application of such materials as high-durability clear coats is finally proposed.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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