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  • Other Sources  (82)
  • AGU (American Geophysical Union)  (78)
  • Blackwell Publishing Ltd
  • Institute of Physics
  • 2020-2024  (78)
  • 2020-2023  (4)
  • 2005-2009
  • 1980-1984
  • 1925-1929
  • 2021  (82)
  • 2021  (82)
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  • 2020-2024  (78)
  • 2020-2023  (4)
  • 2005-2009
  • 1980-1984
  • 1925-1929
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  • 1
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    How to Find Aquifer Statistics Utilizing Pumping Tests? Two Field Studies Using welltestpy (2021)
    Blackwell Publishing Ltd | Malden, US
    Details
    Publication Date: 2022-04-01
    Description: We present a workflow to estimate geostatistical aquifer parameters from pumping test data using the Python package welltestpy. The procedure of pumping test analysis is exemplified for two data sets from the Horkheimer Insel site and from the Lauswiesen site, Germany. The analysis is based on a semi‐analytical drawdown solution from the upscaling approach Radial Coarse Graining, which enables to infer log‐transmissivity variance and horizontal correlation length, beside mean transmissivity, and storativity, from pumping test data. We estimate these parameters of aquifer heterogeneity from type‐curve analysis and determine their sensitivity. This procedure, implemented in welltestpy, is a template for analyzing any pumping test. It goes beyond the possibilities of standard methods, for example, based on Theis' equation, which are limited to mean transmissivity and storativity. A sensitivity study showed the impact of observation well positions on the parameter estimation quality. The insights of this study help to optimize future test setups for geostatistical aquifer analysis and provides guidance for investigating pumping tests with regard to aquifer statistics using the open‐source software package welltestpy.
    Description: Article impact statement: We present a workflow to infer parameters of subsurface heterogeneity from pumping test data exemplified at two sites using welltestpy.
    Description: German Federal Environmental Foundation (DBU) http://dx.doi.org/10.13039/100007636
    Keywords: ddc:551.49
    Language: English
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  • 2
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    Importance of sources of variability, scales and experimental design: A case study about the effects of biochar and slurry application on soil properties in agricultural silty loam soils (2021)
    Blackwell Publishing Ltd | Oxford, UK
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    Publication Date: 2022-04-01
    Description: In designed experiments, different sources of variability and an adequate scale of measurement need to be considered, but not all approaches in common usage are equally valid. In order to elucidate the importance of sources of variability and choice of scale, we conducted an experiment where the effects of biochar and slurry applications on soil properties related to soil fertility were studied for different designs: (a) for a field‐scale sampling design with either a model soil (without natural variability) as an internal control or with composited soils, (b) for a design with a focus on amendment variabilities, and (c) for three individual field‐scale designs with true field replication and a combined analysis representative of the population of loess‐derived soils. Three silty loam sites in Germany were sampled and the soil macroaggregates were crushed. For each design, six treatments (0, 0.15 and 0.30 g slurry‐N kg−1 with and without 30 g biochar kg−1) were applied before incubating the units under constant soil moisture conditions for 78 days. CO2 fluxes were monitored and soils were analysed for macroaggregate yields and associated organic carbon (C). Mixed‐effects models were used to describe the effects. For all soil properties, results for the loess sites differed with respect to significant contributions of fixed effects for at least one site, suggesting the need for a general inclusion of different sites. Analysis using a multilevel model allowed generalizations for loess soils to be made and showed that site:slurry:biochar and site:slurry interactions were not negligible for macroaggregate yields. The use of a model soil as an internal control enabled observation of variabilities other than those related to soils or amendments. Experiments incorporating natural variability in soils or amendments resulted in partially different outcomes, indicating the need to include all important sources of variability. Highlights Effects of biochar and slurry applications were studied for different designs and mixed‐effects models were used to describe the effects. Including an internal control allowed observation of, e.g., methodological and analytical variabilities. The results suggested the need for a general inclusion of different sites. Analysis using a multilevel model allowed generalizations for loess soils. The results indicated the need to include all important sources of variability.
    Keywords: ddc:631.4
    Language: English
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  • 3
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    Do tree species affect decadal changes in soil organic carbon and total nitrogen stocks in Danish common garden experiments? (2021)
    Blackwell Publishing Ltd | Oxford, UK
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    Publication Date: 2022-04-01
    Description: Temperate forest soils are often considered as an important sink for atmospheric carbon (C), thereby buffering anthropogenic CO2 emissions. However, the effect of tree species composition on the magnitude of this sink is unclear. We resampled a tree species common garden experiment (six sites) a decade after initial sampling to evaluate whether forest floor (FF) and topsoil organic carbon (Corg) and total nitrogen (Nt) stocks changed in dependence of tree species (Norway spruce—Picea abies L., European beech—Fagus sylvatica L., pedunculate oak—Quercus robur L., sycamore maple—Acer pseudoplatanus L., European ash—Fraxinus excelsior L. and small‐leaved lime—Tilia cordata L.). Two groups of species were identified in terms of Corg and Nt distribution: (1) Spruce with high Corg and Nt stocks in the FF developed as a mor humus layer which tended to have smaller Corg and Nt stocks and a wider Corg:Nt ratio in the mineral topsoil, and (2) the broadleaved species, of which ash and maple distinguished most clearly from spruce by very low Corg and Nt stocks in the FF developed as mull humus layer, had greater Corg and Nt stocks, and narrow Corg:Nt ratios in the mineral topsoil. Over 11 years, FF Corg and Nt stocks increased most under spruce, while small decreases in bulk mineral soil (esp. in 0–15 cm and 0–30 cm depth) Corg and Nt stocks dominated irrespective of species. Observed decadal changes were associated with site‐related and tree species‐mediated soil properties in a way that hinted towards short‐term accumulation and mineralisation dynamics of easily available organic substances. We found no indication for Corg stabilisation. However, results indicated increasing Nt stabilisation with increasing biomass of burrowing earthworms, which were highest under ash, lime and maple and lowest under spruce. Highlights We studied if tree species differences in topsoil Corg and Nt stocks substantiate after a decade. The study is unique in its repeated soil sampling in a multisite common garden experiment. Forest floors increased under spruce, but topsoil stocks decreased irrespective of species. Changes were of short‐term nature. Nitrogen was most stable under arbuscular mycorrhizal species.
    Description: Deutsche Forschungsgemeinschaff (DFG)
    Keywords: ddc:551.9 ; ddc:631.41
    Language: English
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  • 4
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    Urban pluvial flood adaptation: Results of a household survey across four German municipalities (2021)
    Blackwell Publishing Ltd | Oxford, UK
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    Publication Date: 2022-09-30
    Description: In recent years, German cities were heavily impacted by pluvial flooding and related damage is projected to increase due to climate change and urbanisation. It is important to ask how to improve urban pluvial flood risk management. To understand the current state of property level adaptation, a survey was conducted in four municipalities that had recently been impacted by pluvial flooding. A hybrid framework based on the Protection Motivation Theory (PMT) and the Protection Action Decision Model (PADM) was used to investigate drivers of adaptive behaviour through both descriptive and regression analyses. Descriptive statistics revealed that participants tended to instal more low‐ and medium‐cost measures than high‐cost measures. Regression analyses showed that coping appraisal increased protection motivation, but that the adaptive behaviour also depends on framing factors, particularly homeownership. We further found that, while threat appraisal solely affects protection motivation and responsibility appraisal affects solely maladaptive thinking, coping appraisal affects both. Our results indicate that PMT is a solid starting point to study adaptive behaviours in the context of pluvial flooding, but we need to go beyond that by, for instance, considering factors of the PADM, such as responsibility, ownership, or respondent age, to fully understand this complex decision‐making process.
    Description: Bundesministerium für Bildung und Forschung http://dx.doi.org/10.13039/501100002347
    Keywords: ddc:551.489 ; ddc:363.34
    Language: English
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  • 5
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    Decadal Disruption of the QBO by Tropical Volcanic Supereruptions (2021)
    AGU (American Geophysical Union) | Wiley
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    Publication Date: 2024-02-07
    Description: The Los Chocoyos (14.6°N, 91.2°W) supereruption happened ∼75,000 years ago in Guatemala and was one of the largest eruptions of the past 100,000 years. It emitted enormous amounts of sulfur, chlorine, and bromine, with multi‐decadal consequences for the global climate and environment. Here, we simulate the impact of a Los Chocoyos‐like eruption on the quasi‐biennial oscillation (QBO), an oscillation of zonal winds in the tropical stratosphere, with a comprehensive aerosol chemistry Earth System Model. We find a ∼10‐year disruption of the QBO starting 4 months post eruption, with anomalous easterly winds lasting ∼5 years, followed by westerlies, before returning to QBO conditions with a slightly prolonged periodicity. Volcanic aerosol heating and ozone depletion cooling leads to the QBO disruption and anomalous wind regimes through radiative changes and wave‐mean flow interactions. Different model ensembles, volcanic forcing scenarios and results of a second model back up the robustness of our results.
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  • 6
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    Basalt geochemistry and mantle flow during early backarc basin evolution: Havre Trough and Kermadec Arc, southwest Pacific (2021)
    AGU (American Geophysical Union) | Wiley
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    Publication Date: 2024-02-07
    Description: The Havre Trough backarc basin in the southwest Pacific is in the rifting stage of development. We distinguish five types of basalt there based on their amount and kind of slab component: backarc basalts (BAB) with little or no slab component; modified BAB (mBAB) with slight amounts; reararc (RA) with more; remnants of the pre‐existing arc (Colville Ridge horsts, CRH); and arc front volcanoes within the Havre Trough. Previous sub‐arc mantle is quickly removed and replaced by more fertile mantle with less slab component. The ambient mantle is “Pacific” isotopically, and more enriched in Nb/Yb and Nd and Hf isotope ratios north of the Central Kermadec Discontinuity at 32°S than to the south. The contrast may reflect inheritance in the south of mantle that was depleted during spreading that formed the southern South Fiji Basin, and a higher degree of melting because of a wetter slab‐derived flux. The slab component also differs along strike, more like a dry melt in the north and a super‐critical fluid in the south. The mass fraction of slab component increases southward in the backarc as well as the arc front. Reararc volcanoes have the most slab component (1‐2%) and form indistinct ridges at high angles to, and 〈50 km behind, frontal volcanoes. Backarc basalts have less and occur throughout the basin. Slab components are distributed further into the backarc, and more irregularly, during the rifting than spreading stage of backarc basin development. The rifting stage is disorganized geochemically as well as spatially.
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  • 7
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    A Hybrid Lister‐Outrigger Probe for Rapid Marine Geothermal Gradient Measurement (2021)
    AGU (American Geophysical Union) | Wiley
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    Publication Date: 2024-02-07
    Description: We have successfully constructed and tested a new, portable, Hybrid Lister‐Outrigger (HyLO) probe designed to measure geothermal gradients in submarine environments. The lightweight, low‐cost probe is 1‐3 m long, contains 4‐12 semiconductor temperature sensors that have a temperature resolution of 0.002 oC, a sample rate of 〈2 seconds, and a maximum working depth of ~2100 meters below sea level (mbsl). Probe endurance is continuous via ship‐power to water depths of ~700 mbsl, or up to ~1 week on batteries in depths 〉500 mbsl. Data are saved on solid‐state disks, transferred directly to the ship during deployment via a data cable, or transmitted via Bluetooth when the probe is at the sea surface. The probe contains an accelerometer to measure tilt, and internal pressure, temperature, and humidity gauges. Key advantages of this probe include (1) near‐real time temperature measurements and data transfer; (2) a low‐cost, transportable, and lightweight design; (3) easy and rapid two‐point attachment to a gravity corer, (4) short (3‐5 minute) thermal response times; (5) high temporal/spatial resolution and (6) longer deployment endurance compared to traditional methods. We successfully tested the probe both in lakes and during sea trials in May 2019 offshore Montserrat during the R/V Meteor Cruise 154/2. Probe‐measured thermal gradients were consistent with seafloor ocean‐drilling temperature measurements. Ongoing probe improvements include the addition of real‐time bottom‐camera feeds and long‐term (6‐12 month) deployment for monitoring. Key Points - We have designed, developed, and tested a low‐cost, portable hybrid Lister‐type probe to measure shallow thermal gradients - The probe consists of lightweight, quickly interchangeable/expendable components deployable to 2100 meters depth - The probe provides high vertical and temporal temperature resolution and rapid data transmission, reducing down‐time
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  • 8
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    The Alaska convergent margin backstop splay fault zone, a potential large tsunami generator between the frontal prism and continental framework (2021)
    AGU (American Geophysical Union) | Wiley
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    Publication Date: 2024-02-07
    Description: The giant tsunami that swept the Pacific from Alaska to Antarctica in 1946, was generated along one of three Alaska Trench instrumentally recorded aftershock areas following great and giant earthquakes. Aftershock areas were investigated during the past decade with multibeam bathymetry, OBS wide‐angle seismic, reprocessed legacy and new seismic reflection images. Summarized and updated here are previous papers and additional data. Tectonic structures collocated with aftershock area boundaries indicate possible lengths of rupture in future great earthquakes. NE aftershock area boundaries relate to subducted lower plate structures whereas the SW zone upper plate retains Beringian structural relicts. The lower to middle slope transition separating a stronger continental framework rock from a weaker accreted prism occurs along splay fault zones previously interpreted as backstops in seismic images. Damage zones along splay faults are generally 1 km wide dipping typically 21°. Splays form slip paths from the plate interface to the seafloor much shorter than the 3° to 4° dipping plate interface beneath the frontal prism. Associated seafloor vent structures indicate overpressured fluids at depth. Splay fault dip and its rigid hanging wall impart greater seafloor uplift than the accreted prism per unit of slip making them effective tsunami generators. Backstop splay fault zones run along the entire Alaska Trench. Beneath the frontal prism, active bend faults add rugosity to the plate interface and km high relief is commonly imaged in reprocessed legacy and new seismic data. The 1946 Unimak great (M8.6) earthquake epicenter is located near the backstop splay fault zone.
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  • 9
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    Does retrogression always account for the large volume of submarine megaslides? Evidence to the contrary from the Tampen Slide, offshore Norway (2021)
    AGU (American Geophysical Union) | Wiley
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    Publication Date: 2024-02-07
    Description: Submarine landslides can be several orders of magnitude larger than their terrestrial counterparts and can pose significant hazards across entire ocean basins. The landslide failure mechanism strongly controls the associated tsunami hazard. The Tampen Slide offshore Norway is one of the largest landslides on Earth but remains poorly understood due to its subsequent burial beneath up to 450 m of sediments. Here, we use laterally extensive (16,000 km2), high‐resolution processed 3D seismic reflection data to characterize the upper Tampen Slide. We identify longitudinal (downslope, movement‐parallel) chutes and ridges that are up‐to‐40 m high, as well as extensional and compressional (cross‐slope) ridges. This is the first time that longitudinal ridges of such size have been imaged in a deep marine setting. The first phase of the Tampen Slide involved the simultaneous translation of over 720 km3 of sediments along a single failure plane. This was followed by spreading along the head‐ and sidewall, and the formation of a retrogressive debris flow and slump, the volumes of which are insignificant compared to the first failure. The process responsible for movement of such a large sediment volume along a single glide plane differs significantly from that of other passive margin megaslides, which typically comprise numerous smaller landslides that fail retrogressively along multiple glide planes. The trigger mechanism (e.g. an earthquake), the presence of mechanically strong obstructions (e.g. igneous topographical high), and the number and location of weak layers may be key factors that determine whether megaslides develop along a single plane or retrogressively.
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  • 10
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    Persistent Provenance of South Asian Monsoon‐Induced Silicate Weathering Over the Past 27 Million Years (2021)
    AGU (American Geophysical Union) | Wiley
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    Publication Date: 2024-02-07
    Description: The development of the South Asian monsoon (SAM) and Himalaya‐Tibetan Plateau uplift were closely intertwined with some studies suggesting that uplift initiated the monsoon whereas others link tectonics with monsoon‐controlled exhumation. Silicate weathering controls atmospheric CO2 on geological timescales resulting in a large potential for monsoon strength and the Himalayan orogeny to influence global climate but detailed records of SAM‐induced weathering on million year (Myr) timescales are lacking. Here, we present radiogenic Sr, Nd, and Pb isotope compositions of clay minerals produced by silicate weathering and transported to the central Bay of Bengal. The radiogenic isotope data exhibit a relatively small range and demonstrate a remarkably consistent mixture of sources dominated by Himalayan rocks and the Indo‐Burman ranges, which consist of sediments derived from the Himalayas. This suggests that the spatial pattern of regional weathering, which today is highest in the regions of strongest monsoon rains, has persisted in a similar form for the last 27 Myrs. A pronounced increase in primary clay mineral abundance (from 9% to 22%) coincident with global cooling 13.9 Myrs ago points to a shift in the weathering regime given that the clay provenance did not change dramatically. Relatively weaker chemical weathering intensity during the mid and late Miocene cooling suggests increased aridity and changes in the large scale atmospheric circulation in the SAM domain. The establishment of the dry winter monsoon season during the mid and late Miocene may have caused this shift in the weathering regime and can reconcile much of the contrasting evidence for SAM initiation.
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  • 11
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    Relationship between subduction erosion and the up‐dip limit of the 2014 Mw 8.1 Iquique earthquake (2021)
    AGU (American Geophysical Union) | Wiley
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    Publication Date: 2024-02-07
    Description: The aftershock distribution of the 2014 Mw 8.1 Iquique earthquake offshore northern Chile, identified from a long‐term deployment of ocean bottom seismometers installed eight months after the mainshock, in conjunction with seismic reflection imaging, provides insights into the processes regulating the up‐dip limit of coseismic rupture propagation. Aftershocks up‐dip of the mainshock hypocenter frequently occur in the upper plate and are associated with normal faults identified from seismic reflection data. We propose that aftershock seismicity near the plate boundary documents subduction erosion that removes mass from the base of the wedge and results in normal faulting in the upper plate. The combination of very little or no sediment accretion and subduction erosion over millions of years has resulted in a very weak and aseismic frontal wedge. Our observations thus link the shallow subduction zone seismicity to subduction erosion processes that control the evolution of the overriding plate. Key Points: - We investigate structure and seismicity at the up-dip end of the 2014 Iquique earthquake rupture using amphibious seismic data. - Seismicity up-dip of the 2014 Iquique earthquake occurs over a broad range likely interpreted to be related to the basal erosion processes. - Coseismic stress changes and aftershocks activate extensional faulting of the upper plate and subduction erosion.
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  • 12
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    Sedimentary Ancient DNA From the Subarctic North Pacific: How Sea Ice, Salinity, and Insolation Dynamics Have Shaped Diatom Composition and Richness Over the Past 20,000 Years (2021)
    AGU (American Geophysical Union) | Wiley
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    Publication Date: 2024-02-07
    Description: Key Points: • diatom sedaDNA composition is concordant with reconstructed sea-ice dynamics, SSTs and subsurface salinities over the past millenia • loss of diatom richness at ~11.1 cal kyr BP is possibly a consequence of increased freshwater input from Kamchatka • shifts of potential ecotypes of species from the genus Chaetoceros with changing environmental conditions We traced diatom composition and diversity through time using diatom derived sedimentary ancient DNA (sedaDNA) from eastern continental slope sediments off Kamchatka (North Pacific) by applying a short, diatom‐specific marker on 63 samples in a DNA metabarcoding approach. The sequences were assigned to diatoms that are common in the area and characteristic of cold water. SedaDNA allowed us to observe shifts of potential lineages from species of the genus Chaetoceros that can be related to different climatic phases, suggesting that pre‐adapted ecotypes might have played a role in the long‐term success of species in areas of changing environmental conditions. These sedaDNA results complement our understanding of the long‐term history of diatom assemblages and their general relationship to environmental conditions of the past. Sea‐ice diatoms (Pauliella taeniata (Grunow) Round & Basson, Attheya septentrionalis (Østrup) R.M.Crawford and Nitzschia frigida (Grunow)) detected during the late glacial and Younger Dryas are in agreement with previous sea‐ice reconstructions. A positive correlation between pennate diatom richness and the sea‐ice proxy IP25 suggests that sea ice fosters pennate diatom richness, whereas a negative correlation with June insolation and temperature points to unfavorable conditions during the Holocene. A sharp increase in proportions of freshwater diatoms at ∼11.1 cal kyr BP implies the influence of terrestrial runoff and coincides with the loss of 42% of diatom sequence variants. We assume that reduced salinity at this time stabilized vertical stratification which limited the replenishment of nutrients in the euphotic zone.
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  • 13
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    Recycling and burial of biogenic silica in an open margin oxygen minimum zone (2021)
    AGU (American Geophysical Union) | Wiley
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    Publication Date: 2024-02-07
    Description: An extensive data set of biogenic silica (BSi) fluxes is presented for the Peruvian oxygen minimum zone (OMZ) at 11ºS and 12ºS. Each transect extends from the shelf to the upper slope (∼1000 m) and dissects the permanently anoxic waters between ∼200 – 500m water depth. BSi burial (2100 mmol m‐2 yr‐1) and recycling fluxes (3300 mmol m‐2 yr‐1) were highest on the shelf with mean preservation efficiencies (34±15%) that exceed the global mean of 10 – 20%. BSi preservation was highest on the inner shelf (up to 56%), decreasing to 7% and 12% under anoxic waters and below the OMZ, respectively. The data suggest that the main control on BSi preservation is the rate at which reactive BSi is transported away from undersaturated surface sediments by burial and bioturbation to the underlying saturated sediment layers where BSi dissolution is thermodynamically and/or kinetically inhibited. BSi burial across the entire Peruvian margin between 3ºS to 15ºS and down to 1000m water depth is estimated to be 0.1 – 0.2 Tmol yr‐1; equivalent to 2 – 7% of total burial on continental margins. Existing global data permit a simple relationship between BSi rain rate to the seafloor and the accumulation of unaltered BSi, giving the possibility to reconstruct rain rates and primary production from the sediment archive in addition to benthic Si turnover in global models.
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  • 14
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    Deformation, CPO, and Elastic Anisotropy in Low‐Grade Metamorphic Serpentinites, Atlantis Massif Oceanic Core Complex (2021)
    AGU (American Geophysical Union) | Wiley
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    Publication Date: 2024-02-07
    Description: Crystallographic preferred orientation (CPO) and the associated seismic anisotropy of serpentinites are important factors for the understanding of tectonic settings involving hydrated Earth´s mantle, for example, at slow-spreading mid-ocean ridges. CPO of lizardite and magnetite in low-grade metamorphic serpentinites from the Atlantis Massif oceanic core complex (Mid-Atlantic Ridge, 30°N) were determined using synchrotron high energy X-ray diffraction in combination with Rietveld texture analysis. Serpentinite mesh structures show weak CPO while deformed samples show a single (0001) maximum perpendicular to the foliation. Seismic anisotropies calculated from CPO show up to 〉11% anisotropy for compressional waves (Vp) and shear wave splitting up to 0.38 km/s in the deformed samples. This indicates that deformation in shear zones controls elastic anisotropy and highlights its importance in defining the seismic signature of hydrated upper mantle.
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  • 15
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    Volcanic unrest at Taupō volcano in 2019: Causes, mechanisms and implications (2021)
    AGU (American Geophysical Union) | Wiley
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    Publication Date: 2024-02-07
    Description: Taupō volcano, New Zealand, is a large caldera volcano that has been highly active through the Holocene. It most recently erupted ∼1800 years ago but there have been multiple periods of historic volcanic unrest. We use seismological and geodetic analysis to show that in 2019 Taupō underwent a period of unrest characterised by increased seismic activity through multiple swarms and was accompanied by ground deformation within the caldera. The earthquakes, which include non-double-couple events, serve to outline an aseismic zone beneath the most recent eruptive vents. This aseismic zone is coincident with an inflating source, based on forward modelling of ground deformation data. We infer that this aseismic and deforming region delineates the location of the present day magma reservoir that is ≥250 km3 in volume and has a melt fraction of 〉 20–30%, inhibiting seismic activity. Our analysis shows that the 2019 unrest at Taupō was volcanic in nature and origin, demonstrating that this is an active and potentially hazardous volcano, and that improving our monitoring and understanding of its behaviour is important.
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  • 16
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    Dissolved Organic Matter in the Upwelling System off Peru: Imprints of Bacterial Activity and Water Mass Characteristics (2021)
    AGU (American Geophysical Union) | Wiley
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    Publication Date: 2024-02-07
    Description: Microbial degradation of dissolved organic matter (DOM) contributes to the formation and preservation of oxygen minimum zones (OMZs) in the ocean, but information on the spatial distribution and molecular composition of DOM in OMZ regions is scarce. We quantified molecular components of DOM that is, dissolved amino acids (DAA) and dissolved combined carbohydrates (DCCHO), in the upwelling region off Peru. We found the highest concentrations of DCCHO in fully oxygenated surface waters steeply declining at shallow depth. The highest DAA concentrations were observed close to the surface also, but attenuation of DAA concentration over depth was less pronounced. Compositional changes of DCCHO were strongest within more oxygenated waters. Compositional changes of DAA were also evident under suboxic conditions (〈5 µmol O2 kg−1) and indicated bacterial peptide degradation. Moreover, specific free amino acids (alanine and threonine) were enhanced within suboxic waters, pointing to a potential production of dissolved organic nitrogen under suboxic conditions. Our results therewith suggest that deoxygenation supports a spatial decoupling of DCCHO and DAA production and degradation dynamics and give new insights to carbon and nitrogen cycling in the OMZ off Peru.
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  • 17
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    A 30 ‐Year Time Series of Transient Tracer‐Based Estimates of Anthropogenic Carbon in the Central Labrador Sea (2021)
    AGU (American Geophysical Union) | Wiley
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    Publication Date: 2024-02-07
    Description: We use a 30-year time series (1986–2016) of dichlorodifluoromethane (CFC-12) concentrations with a refined transit time distribution (TTD) method, to estimate the temporal variation of anthropogenic carbon (Cant) in the Central Labrador Sea. We determined that the saturation of CFC-12 and sulfur hexafluroide (SF6) in newly-formed Labrador Sea Water had departed significantly from 100% and varied systematically with time. Multiple linear regression of the time-varying saturation, with the tracer's atmospheric growth rate and the wintertime mixed layer depth as independent variables, allowed reconstruction of the saturation history of CFC-12 and SF6 in wintertime surface waters, which was implemented in the TTD method. Use of the time-varying saturation for CFC-12 gave Cant concentrations ∼7 μmol kg−1 larger than estimates obtained assuming a constant saturation of 100%. The resulting Cant column inventories were ∼20% larger and displayed lower interannual variability compared to conventional TTD-based estimates. The column inventory of Cant increased at an average rate of 1.8 mol m−2 y−1 over the 30-year period. However, the accumulation rate of Cant was higher than this average in the early 1990s and since 2013, whereas inventories remained almost unchanged between 2003 and 2012. The variation in the Cant accumulation rate is shown to be linked to temporal variability in the relative layer thickness of the annually ventilated Labrador Sea Water and the underlying Deep Intermediate Water. The non-steady Cant accumulation highlights the importance of sampling frequency, especially in regions of variable deep mixing and high carbon inventories, and potential misinterpretation of Cant dynamics
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    Clouds and Radiation Processes in Regional Climate Models Evaluated Using Observations Over the Ice‐free Arctic Ocean (2021)
    AGU (American Geophysical Union) | Wiley
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    Publication Date: 2024-02-07
    Description: The presence of clouds in the Arctic regulates the surface energy budget (SEB) over the sea-ice surface and the ice-free ocean. Following several previous field campaigns, the cloud-radiation relationship, including cloud vertical structure and phase, has been elucidated; however, modeling of this relationship has matured slowly. In recognition of the recent decline in the Arctic sea-ice extent, representation of the cloud system in numerical models should consider the effects of areas covered by sea ice and ice-free areas. Using an in situ stationary meteorological observation data set obtained over the ice-free Arctic Ocean by the Japanese Research Vessel Mirai (September 2014), coordinated evaluation of six regional climate models (RCMs) with nine model runs was performed by focusing on clouds and the SEB. The most remarkable findings were as follows: (1) reduced occurrence of unstable stratification with low-level cloud water in all models in comparison to the observations, (2) significant differences in cloud water representations between single- and double-moment cloud schemes, (3) extensive differences in partitioning of hydrometeors including solid/liquid precipitation, and (4) pronounced lower-tropospheric air temperature biases. These issues are considered as the main sources of SEB uncertainty over ice-free areas of the Arctic Ocean. The results from a coupled RCM imply that the SEB is constrained by both the atmosphere and the ocean (and sea ice) with considerable feedback. Coordinated improvement of both stand-alone atmospheric and coupled RCMs would promote a more comprehensive and improved understanding of the Arctic air-ice-sea coupled system.
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    Electrical resistivity anomalies offshore a carbonate coastline: Evidence for freshened groundwater? (2021)
    AGU (American Geophysical Union) | Wiley
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    Publication Date: 2024-02-07
    Description: Carbonate lithologies host considerable quantities of the Earth’s freshwater resources and partially supply a quarter of the global population with drinkable water. Carbonates constitute substantial amounts of the global coastlines, yet it is not known if and how they can sustain freshened groundwater offshore. Here, we use controlled source electromagnetic, seismic reflection, and core sample data to derive a lithological model for the eastern margin of the Maltese Islands and identify four distinct resistivity anomalies within the Upper Coralline Limestone, Globigerina Limestone, and Blue Clay formations. The anomalies hosted in the former are likely associated to low porosities, whereas the anomaly within the latter is indicative of pore fluid freshening. Hydrogeological modeling suggests that freshened pore fluids, emplaced during sea-level lowstands and preserved in low permeability units, are potentially still found within carbonate shelves. However, resource potential is low due to its relict nature and low permeability host environment. Key points ● Geophysical data and hydrogeological modeling are applied to detect offshore freshened groundwater in a semi-arid carbonate setting ● Globigerina Limestone and Blue Clay located offshore SE Malta likely host a disconnected offshore freshened groundwater body ● The resistive anomalies within the Upper Coralline Limestone are interpreted as localized porosity variations.Accepted Article This article is protected by copyright. All rights reserved. ● This OFG was emplaced during sea-level lowstands and preserved in low permeability units
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    Insights into Water Mass Origins in the Central Arctic Ocean from in‐situ Dissolved Organic Matter Fluorescence (2021)
    AGU (American Geophysical Union) | Wiley
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    Publication Date: 2024-02-07
    Description: The Arctic Ocean receives a large supply of dissolved organic matter (DOM) from its catchment and shelf sediments, which can be traced across much of the basin’s upper waters. This signature can potentially be used as a tracer. On the shelf, the combination of river discharge and sea-ice formation, modifies water densities and mixing considerably. These waters are a source of the halocline layer that covers much of the Arctic Ocean, but also contain elevated levels of DOM. Here we demonstrate how this can be used as a supplementary tracer and contribute to evaluating ocean circulation in the Arctic. A fraction of the organic compounds that DOM consists of fluoresce and can be measured using in-situ fluorometers. When deployed on autonomous platforms these provide high temporal and spatial resolution measurements over long periods. The results of an analysis of data derived from several Ice Tethered Profilers (ITPs) offer a unique spatial coverage of the distribution of DOM in the surface 800m below Arctic sea-ice. Water mass analysis using temperature, salinity and DOM fluorescence, can clearly distinguish between the contribution of Siberian terrestrial DOM and marine DOM from the Chukchi shelf to the waters of the halocline. The findings offer a new approach to trace the distribution of Pacific waters and its export from the Arctic Ocean. Our results indicate the potential to extend the approach to separate freshwater contributions from, sea-ice melt, riverine discharge and the Pacific Ocean. Key Points: Arctic surface waters with comparable temperature and salinity have contrasting in situ dissolved organic matter fluorescence. Organic matter fluorescence can tracklow salinity waters feeding into the Transpolar Drift and haloclinelayers. Siberian and Chukchishelf waters can be separated based on their fluorescence to salinity relationship
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    Assessment of C, N, and Si Isotopes as Tracers of Past Ocean Nutrient and Carbon Cycling (2021)
    AGU (American Geophysical Union) | Wiley
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    Publication Date: 2024-02-07
    Description: Biological productivity in the ocean directly influences the partitioning of carbon between the atmosphere and ocean interior. Through this carbon cycle feedback, changing ocean productivity has long been hypothesized as a key pathway for modulating past atmospheric carbon dioxide levels and hence global climate. Because phytoplankton preferentially assimilate the light isotopes of carbon and the major nutrients nitrate and silicic acid, stable isotopes of carbon (C), nitrogen (N), and silicon (Si) in seawater and marine sediments can inform on ocean carbon and nutrient cycling, and by extension the relationship with biological productivity and global climate. Here, we compile water column C, N, and Si stable isotopes from GEOTRACES-era data in four key ocean regions to review geochemical proxies of oceanic carbon and nutrient cycling based on the C, N, and Si isotopic composition of marine sediments. External sources and sinks as well as internal cycling (including assimilation, particulate matter export, and regeneration) are discussed as likely drivers of observed C, N, and Si isotope distributions in the ocean. The potential for C, N, and Si isotope measurements in sedimentary archives to record aspects of past ocean C and nutrient cycling is evaluated, along with key uncertainties and limitations associated with each proxy. Constraints on ocean C and nutrient cycling during late Quaternary glacial-interglacial cycles and over the Cenozoic are examined. This review highlights opportunities for future research using multielement stable isotope proxy applications and emphasizes the importance of such applications to reconstructing past changes in the oceans and climate system.
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    Upward‐Doming Zones of Gas Hydrate and Free Gas at the Bases of Gas Chimneys, New Zealand's Hikurangi Margin (2021)
    AGU (American Geophysical Union) | Wiley
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    Publication Date: 2024-02-07
    Description: Focused gas migration through the gas hydrate stability zone in vertical gas conduits is a global phenomenon. The process can lead to concentrated gas hydrate formation and seafloor gas seepage, which influences seafloor biodiversity and ocean biogeochemistry. However, much is unknown about how gas and gas hydrate co-exist within and around gas conduits. We present seismic imaging of the gas hydrate system beneath a four-way closure anticlinal ridge at New Zealand's southern Hikurangi subduction margin. Gas has accumulated beneath the base of gas hydrate stability to a thickness of up to ∼240 m, which has ultimately led to hydraulic fracturing and propagation of a vertical gas conduit to the seafloor. Despite the existence of an array of normal faults beneath the ridge, these structures are not exploited as long-range gas flow conduits. Directly beneath the conduit, and extending upward from the regional base of gas hydrate stability, is a broad zone characterized by both negative- and positive-polarity reflections. We interpret this zone as a volume of sediment hosting both gas hydrate and free gas, that developed due to partial gas trapping beneath a mass transport deposit. Similar highly reflective zones have been identified at the bases of other gas conduits, but they are not intrinsic to all gas conduits through gas hydrate systems. We suggest that pronounced intervening sealing units within the gas hydrate stability zone determine whether or not they form.
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    Iron regulation of North Atlantic eddy phytoplankton productivity (2021)
    AGU (American Geophysical Union) | Wiley
    Details
    Publication Date: 2024-02-07
    Description: Cyclonic ocean eddies drive upwelling of deep waters enhanced in nutrients, which can elevate phytoplankton productivity. At mid‐latitudes in the North Atlantic, satellite images show enhanced chlorophyll‐a associated with eddies. However, surface macronutrient concentrations are often not fully depleted in this region, implying enhanced macronutrient supply is not the primary control. We conducted high resolution sampling through two mid‐latitude Atlantic eddies in late spring, located 800 and 350 km east of the Newfoundland Grand Banks. Waters outside of both eddies had unused residual macronutrients, low dissolved iron, and iron‐stressed phytoplankton. Inside both eddies, plankton biomass was higher and macronutrient concentrations lower. However, full macronutrient drawdown and an absence of iron stress were only present in the eddy nearer the continental shelf. From these two examples, iron supply and proximity to shelf iron sources appear to be important factors regulating productivity and macronutrient utilization in mid‐latitude North Atlantic cyclonic eddies.
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    Deep‐Sea Electric and Magnetic Surveys Over Active and Inactive Basalt‐Hosted Hydrothermal Sites of the TAG Segment (26°, MAR): An Optimal Combination for Seafloor Massive Sulfide Exploration (2021)
    AGU (American Geophysical Union) | Wiley
    Details
    Publication Date: 2024-02-07
    Description: A GEOMAR (Kiel, Germany) research team has developed a passive electric field acquisition system for Autonomous Underwater Vehicles (AUVs) to optimize seafloor massive sulfides exploration. This sensor was made of two perpendicular and horizontal pairs of electrodes, and was successfully tested over active basalt-hosted hydrothermal site TAG (26°N, Mid-Atlantic Ridge) and several inactive sites in its vicinity. The resulting data underline the efficiency of combining deep-sea electric and magnetic measurements for searching for active and inactive hydrothermal vent fields. With these datasets, it becomes possible to determine the geological nature of the targets and to constrain the characteristics of fluid circulation at depth without involving costly and invasive underwater tools such as Remotely Operated Vehicles or even manned submersibles to collect samples. Data analysis also revealed that AUV attitude variations induce distortions of the electric signal. These distortions start prevailing for dives at altitudes higher than 90 m above the seafloor, as the distance between the AUV becomes too important to guarantee that the signal produced by the geological target still dominates. To improve the acquisition system and reduce the overall noise, we discuss solutions that limit the impact of such attitude variations. These solutions consist of minor adjustments, such as masts at AUVs stern to tow damping electrodes arrays. In such configurations, we believe that deep-sea passive electric measurements combined with high-resolution magnetic measurements can become a highly efficient seafloor exploration tool, including for sulfide deposits associated with inactive hydrothermal systems.
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    The medial offshore record of explosive volcanism along the central to eastern Aegean Volcanic Arc, part 1: Tephrostratigraphic correlations (2021)
    AGU (American Geophysical Union) | Wiley
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    Publication Date: 2024-02-07
    Description: The Milos, Christiana-Santorini-Kolumbo (CSK) and Kos-Yali-Nisyros (KYN) volcanic complexes of the Aegean Volcanic Arc have repeatedly produced highly explosive eruptions from at least ∼360 ka into historic times and still show recent unrest. We present the marine tephra record from an array of 50, up to 7.4 m long, sediment cores along the arc collected in 2017 during RV Poseidon cruise POS513, which complements earlier work on distal to ultra-distal eastern Mediterranean sediment cores. A unique set of glass-shard trace element (LA-ICPMS) compositions complements our major element (EMP) data on 220 primary ash layers and 40 terrestrial samples to support geochemical fingerprinting for correlations with 19 known tephras from all three volcanic complexes and with the 39 ka Campanian Ignimbrite from the Campi Flegrei, Italy. The correlations include eleven eruptions from CSK (Kameni, Kolumbo 1650, Minoan, Cape Riva, Cape Tripiti, Upper Scoriae 1 and 2, Middle Pumice, Cape Thera, Lower Pumice, Cape Therma 3). We identify a previously unknown widespread tephra from a plinian eruption on Milos (Firiplaka Tephra). Near the KYN we correlate marine tephras with the Kos Plateau Tuff, the Yali 1 and Yali 2 tephras, and the Upper and Lower Pumice on Nisyros. Between these two major tephras, we found two tephras from Nisyros not yet observed on land. The four Nisyros tephras form a systematic trend toward more evolved magma compositions. In the companion paper we use the tephrostratigraphic framework established here to constrain new eruption ages and magnitudes as a contribution to volcanic hazard assessment.
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    The Rift and Continent‐Ocean Transition Structure Under the Tagus Abyssal Plain West of the Iberia (2021)
    AGU (American Geophysical Union) | Wiley
    Details
    Publication Date: 2024-02-07
    Description: The West Iberia margin is the focus of intense research since the 1980s, with some of the most exemplary geophysical cross-sections and drilling expeditions. Those data sets have been used to create conceptual models of rifting used as a template to interpret margins worldwide. We present two collocated ∼350 km long lines of multi-channel seismic (MCS) streamer data and wide-angle seismic (WAS) data collected across the Tagus Abyssal Plain (TAP). We use travel-times of first arrivals identified at WAS and reflected seismic phases identified at both WAS and MCS records to jointly invert for the P wave velocity (Vp) distribution and the geometry of a sediment unconformity, the top of the basement, and the Moho boundary. The Vp model shows that the TAP basement is more complex than previously inferred, presenting abrupt boundaries between five domains. Domain I under the foot of the slope and Domain III under the abyssal plain display Vp values and gradients of thin continental crust. In between, Domain II displays a steep Vp gradient and high Vp values at shallow depth that support that basement is made of exhumed partly serpentinized mantle. Domain IV and Domain V, further oceanward, have oceanic crust Vp structure. The new results support an unanticipated complex rift history during the initial separation of Iberia and America. We propose a geodynamic scenario characterized by two phases of extension separated by a jump of the locus of extension, caused by the northward propagation of the oceanic spreading center during the J-anomaly formation, which terminated continental rifting.
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    Stable Barium Isotope Dynamics During Estuarine Mixing (2021)
    AGU (American Geophysical Union) | Wiley
    Details
    Publication Date: 2024-02-07
    Description: Stable barium isotopes are a potential proxy for riverine inputs into the ocean that reflect monsoon variability and climate change. However, dissolved Ba isotope (δ138BaDBa) geochemistry in river estuaries, a dynamic land to ocean transition zone, has rarely been systematically examined to date. Here, we show that significant Ba isotope fractionation occurs at near-zero salinities in the Yangtze and Pearl River Estuary, whereas conservative mixing dominates δ138BaDBa distributions beyond low salinities, which are well predicted by an ion exchange model. Elevated δ138BaDBa in the river endmember results from preferential removal of light Ba isotopes by adsorption to fluvial particles. Subsequently, δ138BaDBa rapidly drops to minimum signatures at increased salinities indicating particle desorption of isotopically light Ba. Nevertheless, the apparently conservative δ138BaDBa-salinity relationship beyond the low-salinity minimum in both estuaries provides a modern calibration for using Ba isotopes as a proxy for paleosalinity and river water inputs into the ocean.
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    Sensitivity of Tsunami Scenarios to Complex Fault Geometry and Heterogeneous Slip Distribution: Case‐Studies for SW Iberia and NW Morocco (2021)
    AGU (American Geophysical Union) | Wiley
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    Publication Date: 2024-02-07
    Description: The SW Iberian margin is one of the most seismogenic and tsunamigenic areas in W-Europe, where large historical and instrumental destructive events occurred. To evaluate the sensitivity of the tsunami impact on the coast of SW Iberia and NW Morocco to the fault geometry and slip distribution for local earthquakes, we carried out a set of tsunami simulations considering some of the main known active crustal faults in the region: the Gorringe Bank (GBF), Marquês de Pombal (MPF), Horseshoe (HF), North Coral Patch (NCPF) and South Coral Patch (SCPF) thrust faults, and the Lineament South (LSF) strike-slip fault. We started by considering for all of them relatively simple planar faults featuring with uniform slip distribution; we then used a more complex 3D fault geometry for the faults constrained with a large 2D multichannel seismic dataset (MPF, HF, NCPF, and SCPF); and finally, we used various heterogeneous slip distributions for the HF. Our results show that using more complex 3D fault geometries and slip distributions, the peak wave height at the coastline can double compared to simpler tsunami source scenarios from planar fault geometries. Existing tsunami hazard models in the region use homogeneous slip distributions on planar faults as initial conditions for tsunami simulations and therefore underestimate tsunami hazard. Complex 3D fault geometries and non-uniform slip distribution should be considered in future tsunami hazard updates. The tsunami simulations also support the finding that submarine canyons attenuate the wave height reaching the coastline, while submarine ridges and shallow shelves have the opposite effect.
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    Seismic Velocity Structure Along and Across the Ultraslow‐Spreading Southwest Indian Ridge at 64°30′E Showcases Flipping Detachment Faults (2021)
    AGU (American Geophysical Union) | Wiley
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    Publication Date: 2024-02-07
    Description: We present two ∼150-km-long orthogonal 2D P-wave tomographic velocity models across and along the ridge axis of the ultraslow-spreading Southwest Indian Ridge at 64°30′E. Here, detachment faults largely accommodate seafloor accretion by mantle exhumation. The velocity models are constructed by inverting first arrival traveltimes recorded by 32 ocean bottom seismometers placed on the two profiles. The velocities increase rapidly with depth, from 3 to 3.5 km/s at the seafloor to 7 km/s at depths ranging from 1.5 to 6 km below the seafloor. The vertical gradient decreases for velocities 〉7 km/s. We suggest that changes in velocity with depth are related to changes in the degree of serpentinization and interpret the lithosphere to be composed of highly fractured and fully serpentinized peridotites at the top with a gradual downward decrease in serpentinization and pore space to unaltered peridotites. One active and five abandoned detachment faults are identified on the ridge-perpendicular profile. The active axial detachment fault (D1) shows the sharpest lateral change (horizontal gradient of ∼1 s–1) and highest vertical gradient (∼2 s–1) in the velocities. In the western section of the ridge-parallel profile, the lithosphere transitions from non-volcanic to volcanic over a distance of ∼10 km. The depth extent of serpentinization on the ridge-perpendicular profile ranges from ∼2 to 5 km, with the deepest penetration at the D1 hanging wall. On the ridge-parallel profile, this depth (∼2.5–4 km) varies less as the profile crosses the D1 hanging wall at ∼5–9 km south of the ridge axis.
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    Microseismicity and lava flows hint at magmato‐tectonic processes near the southern tip of the Fonualei Rift and Spreading Center in the Lau Basin (2021)
    AGU (American Geophysical Union) | Wiley
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    Publication Date: 2024-02-07
    Description: Spreading centers in the proximity of back‐rolling subduction zones constitute an ideal natural laboratory to investigate the interaction of magmatism and tectonism during the early evolution of back‐arc basins. Using 32 days of ocean bottom seismometer data, we located 697 microeathquakes at the southern Fonualei Rift and Spreading Center (S‐FRSC). The majority of epicenters concentrate along the central region of the axial valley, marking the active ridge axis. Only odd events were associated with the prominent faults bounding the axial valley. About 450 events are spatially clustered around 17°42’S and their waveforms show a pronounced similarity. Most of these events are associated with a 138 hours lasting earthquake swarm. The tectonic structure of the ridge axis in the S‐FRSC resembles a series of left‐stepping en echelon segments, expressed at the seafloor by numerous volcanic ridges. The recorded earthquake swarm is located at the stepover of two en echelon segments suggesting that the earthquake swarm is mainly tectonically driven. The events directly beneath our seismic network indicate a maximum depth of brittle faulting down to about 14 km below the seafloor. This is within the maximum depth range of brittle faulting at ultraslow mid‐ocean ridges. Since the thickness of the brittle lithosphere is mainly controlled by temperature, our results suggest a sub‐axial thermal structure similar to that of ultraslow mid‐ocean ridges of similar opening rates.
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    Plume‐Induced Sinking of Intracontinental Lithospheric Mantle: An Overlooked Mechanism of Subduction Initiation? (2021)
    AGU (American Geophysical Union) | Wiley
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    Publication Date: 2024-02-07
    Description: Although many different mechanisms for subduction initiation have been proposed, only few of them are viable in terms of consistency with observations and reproducibility in numerical experiments. In particular, it has recently been demonstrated that intra‐oceanic subduction triggered by an upwelling mantle plume could greatly contribute to the onset and operation of plate tectonics in the early and, to a lesser degree, modern Earth. On the contrary, the initiation of intra‐continental subduction still remains underappreciated. Here we provide an overview of 1) observational evidence for upwelling of hot mantle material flanked by downgoing proto‐slabs of sinking continental mantle lithosphere, and 2) previously published and new numerical models of plume‐induced subduction initiation. Numerical modeling shows that under the condition of a sufficiently thick (〉100 km) continental plate, incipient downthrusting at the level of the lowermost lithospheric mantle can be triggered by plume anomalies of moderate temperatures and without significant strain‐ and/or melt‐related weakening of overlying rocks. This finding is in contrast with the requirements for plume‐induced subduction initiation within oceanic or thinner continental lithosphere. As a result, plume‐lithosphere interactions within continental interiors of Paleozoic‐Proterozoic‐(Archean) platforms are the least demanding (and thus potentially very common) mechanism for initiation of subduction‐like foundering in the Phanerozoic Earth. Our findings are supported by a growing body of new geophysical data collected in various intra‐continental areas. A better understanding of the role of intra‐continental mantle downthrusting and foundering in global plate tectonics and, particularly, in the initiation of “classic” ocean‐continent subduction will benefit from more detailed follow‐up investigations.
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    Ventilation History of the Nordic Seas Deduced From Pelagic‐Benthic Radiocarbon Age Offsets (2021)
    AGU (American Geophysical Union) | Wiley
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    Publication Date: 2024-02-07
    Description: Changes in ocean circulation are considered a major driver of centennial‐to‐millennial scale climate variability during the last deglaciation. Using four sediment records from the Nordic Seas, we studied radiocarbon ventilation ages in subsurface and bottom waters to reconstruct past variations in watermass overturning. Planktic foraminiferal ages show significant spatial variability over most of the studied period. These differences suggest that the ventilation of the shallower subsurface waters is strongly influenced by local conditions such as sea‐ice and meltwater input, changes in mixed‐layer depth, and/or variable contributions of water masses with different 14C signatures. Despite covering a significant water depth range, the benthic foraminiferal records show common long‐term patterns, with generally weaker ventilation during stadials and stronger during interstadials. The Greenland Sea record differs the most from the other records, which can be explained by the greater depth and the geographical distance of this site. The benthic records reflect regional shifts in deep convection and suggest that the deep Nordic Seas have been generally bathed by a single, though changing, deep‐water mass analogous to the present‐day Greenland Sea Deep Water. Since significant offsets in ventilation ages are yielded by different taxonomic or ecological groups of benthic foraminifera, the use of uniform material seems a prerequisite to reconstruct bottom water ventilation histories.
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    On the Variability of the DWBC Transport Between 26.5°N and 16°N in an Eddy‐Rich Ocean Model (2021)
    Wiley | AGU (American Geophysical Union)
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    Publication Date: 2024-02-07
    Description: The southward flow of North Atlantic Deep Water makes up the major component of the deepwater limb of the Atlantic Meridional Overturning Circulation (AMOC). In the subtropical North Atlantic, it's flow is concentrated along the continental slope, forming a coherent Deep Western Boundary Current (DWBC). Both, observations and models show a high variability of the flow in this region. Here we use an eddy-rich ocean model to show that this variability is mainly caused by eddies and meanders. Their formation process involves an important contribution from energy transfer by barotropic instability. They occur along the entire DWBC pathway and introduce several recirculation gyres that result in a decorrelation of the DWBC transport at 26.5°N and 16°N, despite the fact that a considerable mean transport of 20 Sv connects the two latitudes. Water in the DWBC at 26.5°N is partly returned northward. Because the amount of water returned depends on the DWBC transport itself, a stronger DWBC does not necessarily lead to an increased amount of water that reaches 16°N. Along the pathway to 16°N, the transport signal is altered by a broad and temporally variable transit time distribution. Thus, advection in the DWBC cannot account for coherent AMOC changes on interannual timescales seen in the model.
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    Magnetic and Gravity Surface Geometry Inverse Modelling of the TAG Active Mound (2021)
    AGU (American Geophysical Union) | Wiley
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    Publication Date: 2024-02-07
    Description: Seafloor massive sulfide deposits form in remote environments, and the assessment of deposit size and composition through drilling is technically challenging and expensive. To aid the evaluation of the resource potential of seafloor massive sulfide deposits, three-dimensional inverse modelling of geophysical potential field data (magnetic and gravity) collected near the seafloor can be carried out to further enhance geologic models interpolated from sparse drilling. Here, we present inverse modelling results of magnetic and gravity data collected from the active mound at the Trans-Atlantic Geotraverse hydrothermal vent field, located at 26o08'N on the Mid-Atlantic Ridge, using autonomous underwater vehicle (AUV) and submersible surveying. Both minimum-structure and surface geometry inverse modelling methods were utilized. Through deposit-scale magnetic modelling, the outer extent of a chloritized alteration zone within the basalt host rock below the mound was resolved, providing an indication of the angle of the rising hydrothermal fluid and the depth and volume of seawater/hydrothermal mixing zone. The thickness of the massive sulfide mound was determined by modelling the gravity data, enabling the tonnage of the mound to be estimated at 2.17 +/- 0.44 Mt through this geophysics-based, non-invasive approach.
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    Zircon and Melt Extraction From a Long‐Lived and Vertically Extensive Magma System Underneath Ilopango Caldera (El Salvador) (2021)
    AGU (American Geophysical Union) | Wiley
    Details
    Publication Date: 2024-02-07
    Description: The Tierra Blanca (TB) eruptive suite comprises the last four major eruptions of Ilopango caldera in El Salvador (≤45 ka), including the youngest Tierra Blanca Joven eruption (TBJ; ∼106 km3): the most voluminous event during the Holocene in Central America. Despite the protracted and productive history of explosive silicic eruptions at Ilopango caldera, many aspects regarding the longevity and the prevailing physicochemical conditions of the underlying magmatic system remain unknown. Zircon 238U-230Th geochronology of the TB suite (TBJ, TB2, TB3, and TB4) reveals a continuous and overlapping crystallization history among individual eruptions, suggesting persistent melt presence in thermally and compositionally distinct magma reservoirs over the last ca. 80 kyr. The longevity of zircon is in contrast to previously determined crystallization timescales of 〈10 kyr for major mineral phases in TBJ. This dichotomy is explained by a process of rhyolitic melt segregation from a crystal-rich refractory residue that incorporates zircon, whereas a new generation of major mineral phases crystallized shortly before eruption. Ti-in-zircon temperatures and amphibole geothermobarometry suggest that rhyolitic melt was extracted from different storage zones of the magma reservoir as indicated by distinct but synchronous thermochemical zircon histories among the TB suite eruptions. Zircon from TBJ and TB2 suggests magma differentiation within deeper and hotter parts of the reservoir, whereas zircon from TB3 and TB4 instead hints at crystallization in comparatively shallower and cooler domains. The assembly of the voluminous TBJ magma reservoir was also likely enhanced by cannibalization of hydrothermally altered components as suggested by low-δ18O values in zircon (+4.5 ± 0.3‰).
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    Unravelling Surface Seawater DMS Concentration and Sea‐To‐Air Flux Changes After Sea Ice Retreat in the Western Arctic Ocean (2021)
    AGU (American Geophysical Union) | Wiley
    Details
    Publication Date: 2024-02-07
    Description: Key Points: • Surface seawater dimethylsulfide (DMS) concentrations remain unchanged after sea ice retreat in the western Canada Basin • Increased wind speed is a critical factor driving the enhancement of dimethylsulfide (DMS) flux after sea ice retreat at high latitudes in the Arctic Ocean • Nutrient supply is hypothesized to significantly impact dimethylsulfide (DMS) distribution in the western Arctic Ocean Abstract: The receding of the seasonal ice cover in the Arctic due to climate change has been predicted by models to increase climate-active biogenic trace gas emissions, specifically those of dimethylsulfide (DMS). However, insufficient DMS measurements are currently available to either support or refute this hypothesis and to fully understand the various responses of oceanic DMS in a rapidly changing Arctic Ocean environment. Here, we present high-resolution surface water DMS data collected in the summer of 2014 in combination with a suite of ancillary variables including sea ice cover, salinity, and nutrients. We show that surface seawater DMS concentrations, generally below 0.5 nmol L−1, remained unchanged in the Canada Basin after sea ice retreat probably due to insufficient nutrients supply to the upper mixed layer and resulting low primary production. Moreover, in the Chukchi shelf region, DMS concentrations decreased following a phytoplankton bloom due to the rapid depletion and slow resupply of nutrients. Although the DMS sea-to-air fluxes were not high from a global perspective, they increased by a factor of 4-fold after sea ice retreat in the Arctic Ocean high latitudes. This increase in DMS flux was mainly driven by increased wind speed. This work provides unique observations and insights on how surface seawater DMS and flux to the atmosphere may change in the future Arctic Ocean.
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    On the Along‐Slope Heat Loss of the Boundary Current in the Eastern Arctic Ocean (2021)
    AGU (American Geophysical Union) | Wiley
    Details
    Publication Date: 2024-02-07
    Description: This study presents recent observations to quantify oceanic heat fluxes along the continental slope of the Eurasian part of the Arctic Ocean, in order to understand the dominant processes leading to the observed along-track heat loss of the Arctic Boundary Current (ABC). We investigate the fate of warm Atlantic Water (AW) along the Arctic Ocean continental margin of the Siberian Seas based on 11 cross-slope conductivity, temperature, depth transects and direct heat flux estimates from microstructure profiles obtained in summer 2018. The ABC loses on average urn:x-wiley:21699275:media:jgrc24332:jgrc24332-math-0006(108) J m−2 per 100 km during its propagation along the Siberian shelves, corresponding to an average heat flux of 47 W m−2 out of the AW layer. The measured vertical heat flux on the upper AW interface of on average 10 W m−2 in the deep basin, and 3.7 W m−2 above the continental slope is larger than previously reported values. Still, these heat fluxes explain less than 20% of the observed heat loss within the boundary current. Heat fluxes are significantly increased in the turbulent near-bottom layer, where AW intersects the continental slope, and at the lee side of a topographic irregularity. This indicates that mixing with ambient colder water along the continental margins is an important contribution to AW heat loss. Furthermore, the cold halocline layer receives approximately the same amount of heat due to upward mixing from the AW, compared to heat input from the summer-warmed surface layer above. This underlines the importance of both surface warming and increased vertical mixing in a future ice-free Arctic Ocean in summer.
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    Southern Ocean ecosystem response to Last Glacial Maximum boundary conditions (2021)
    AGU (American Geophysical Union)
    Details
    Publication Date: 2024-02-07
    Description: Phytoplankton exert a significant control on the marine carbon cycle and can thus impact atmospheric CO2 concentration. Here we use a new ecosystem model to analyse the response of diatoms and coccolithophores in the Southern Ocean to Last Glacial Maximum (LGM) climate conditions, and changes in aeolian iron (Fe) input in the Southern Ocean. We find that LGM climate conditions without changes in Fe input lead to a large increase in diatoms north of the winter sea ice edge in the South Atlantic (19%) and the South Pacific (26%), and a 31% and 9% increase within the seasonal sea-ice zone in the South Atlantic and Indian oceans, respectively, while diatoms decrease in the Ross and Weddell Seas, and in the South Pacific (62%) south of the winter sea ice edge. Coccolithophores increase by 11% in the South West Atlantic near 45°S but are outcompeted by diatoms within the seasonal sea-ice zone, where they decrease by 21%. Overall, this results in a 11% decrease in Southern Ocean net primary productivity (NPP) and a 2.4% decrease in export production (EP). A series of sensitivity experiments with different aeolian Fe input are compared to available paleo-proxy records. The best fit is obtained for a simulation forced with dust fluxes from Lambert et al. (2015) and reduced Antarctic Bottom Water formation in the Weddell Sea. The 78% increase in aeolian Fe input in the Southern Ocean in this simulation increases the Southern Ocean EP by 4.4%, while NPP remains 8.7% weaker compared to preindustrial.
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    Changing Spatial Patterns of Deep Convection in the Subpolar North Atlantic (2021)
    AGU (American Geophysical Union) | Wiley
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    Publication Date: 2024-02-07
    Description: Deep convection and associated deep water formation are key processes for climate variability, since they impact the oceanic uptake of heat and trace gases and alter the structure and strength of the global overturning circulation. For long, deep convection in the subpolar North Atlantic was thought to be confined to the central Labrador Sea in the western subpolar gyre (SPG). However, there is increasing observational evidence that deep convection also has occurred in the eastern SPG south of Cape Farewell and in the Irminger Sea, in particular, in 2015–2018. Here we assess this recent event in the context of the temporal evolution of spatial deep convection patterns in the SPG since the mid-twentieth century, using realistic eddy-rich ocean model simulations. These reveal a large interannual variability with changing contributions of the eastern SPG to the total deep convection volume. Notably, in the late 1980s to early 1990s, the period with highest deep convection intensity in the Labrador Sea related to a persistent positive phase of the North Atlantic Oscillation, the relative contribution of the eastern SPG was small. In contrast, in 2015–2018, deep convection occurred with an unprecedented large relative contribution of the eastern SPG. This is partly linked to a smaller north-westward extent of deep convection in the Labrador Sea compared to previous periods of intensified deep convection, and may be a first fingerprint of freshening trends in the Labrador Sea potentially associated with enhanced Greenland melting and the oceanic advection of the 2012–2016 eastern North Atlantic fresh anomaly.
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    Nitrite Cycle Indicated by Dual Isotopes in the Northern South China Sea (2021)
    AGU (American Geophysical Union) | Wiley
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    Publication Date: 2024-02-07
    Description: As the world's largest marginal sea, biogeochemical cycling of nitrite (NO2-) in the South China Sea (SCS) is still unclear. NO2- concentration generally shows a peak at or near the base of the sunlit euphotic zone, which is called primary NO2- maximum (PNM). The PNM appears widely in the SCS, but its formation mechanism has not yet been realized. In this study, the dual isotopes of NO2- are used for the first time to explore the NO2- cycle and PNM formation in the northern SCS (NSCS). We propose that the formation of the PNM in the NSCS is mainly driven by ammonia (NH3) oxidation. A steady-state model is used to estimate the biogeochemical cycling rates of NO2- in the NSCS. Our results show that both the oxidation rate of NH3 and the assimilation rate of NO2- are significantly reduced from the shelf to the basin. Notably, the role of NO2- oxidation in the basin is not negligible, although the assimilation of NO2- mainly represents the fate of NO2- in the NSCS. The residence time of NO2- implies that the cycle of NO2- is dynamic and the PNM is an active signal in the NSCS. Our results further demonstrate the importance of NH3 oxidation in the formation of PNM in the marginal sea, which can be applied in global marginal seas to gain a deeper understanding of marine nitrogen (N) cycle.
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    Papanin Ridge and Ojin Rise Seamounts (Northwest Pacific): Dual Hotspot Tracks Formed by the Shatsky Plume (2021)
    AGU (American Geophysical Union) | Wiley
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    Publication Date: 2024-02-07
    Description: Although previous findings support an origin of the Shatsky Rise igneous plateau (Northwest Pacific) through interaction of a mantle plume with a mid-ocean ridge triple junction, the evidence for the involvement of a mantle plume is equivocal. The identification of an intraplate hotspot track emanating from the plateau could solve this controversy. Here we present major and trace element geochemical data from two different bathymetric features that emanate from the youngest end of Shatsky Rise: Papanin Ridge and the Ojin Rise Seamount province. Combining our results with plate tectonic reconstructions, we conclude that Papanin Ridge represents a hotspot track formed by plume-ridge interaction. Whereas the southwestern part was formed along the path of the retreating Pacific-Farallon-Izanagi triple junction, the northeastern part was built by preferential drainage into its Pacific-Farallon branch. In contrast, the Ojin Rise Seamounts formed as a true intraplate hotspot track of the Shatsky plume tail. Our wide-ranging study reveals systematic spatial geochemical variations, consistent with a lithospheric thickness control on magma composition derived from melting a heterogeneous plume source. The recognition of two hotspot tracks and in particular of the Ojin Rise Seamounts as an intraplate hotspot track that is directly linked to Shatsky plateau volcanism both in terms of geochemistry and plate tectonic reconstructions confirms the long-disputed involvement of a mantle plume for the formation of Shatsky Rise.
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    The role of fluid seepage in the erosion of Mesozoic carbonate escarpments (2021)
    AGU (American Geophysical Union) | Wiley
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    Publication Date: 2024-02-07
    Description: Mesozoic submarine carbonate escarpments are erosional features that host box canyons, the formation of which had been attributed to seepage erosion in view of their similarity to subaerial box canyons. The latter had been cited as diagnostic of groundwater activity, although the efficacy of fluid seepage as an erosive agent in bedrock remains controversial. Here we use multibeam echosounder data from the Blake, Campeche, Malta and Florida Escarpments to demonstrate that box canyon formation is, in general, a significant process eroding carbonate escarpments. Numerical modelling based on parameters from the Florida Escarpment shows that box canyons can initiate and retrogressively evolve by fluid seeping via joints, which causes a reduction in rock strength due to fluid pressure and dissolution, resulting in periodic block failure at the canyon head. Box canyon elongation is promoted by an exponential distribution of joint density, an increase in joint density, joints oriented perpendicular and parallel to the escarpment, or an increase in the thickness of the flowing groundwater zone and slope gradient of the escarpment. The angularity of the canyon head decreases with a decrease in joint density and when joint density is uniform, whereas the canyon width is regulated by the extent of the joint set zone. Since the key factors contributing to box canyon formation along the Florida Escarpment appear to characterise the Blake, Campeche and Malta Escarpments, the groundwater model for box canyon formation should be applicable to these escarpments as well.
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    Where and How the East Madagascar Current Retroflection Originates? (2021)
    AGU (American Geophysical Union) | Wiley
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    Publication Date: 2024-02-07
    Description: The East Madagascar Current (EMC) is one of the western boundary currents of the South Indian Ocean. As such, it plays an important role in the climate system by transporting water and heat toward the pole and recirculating to the large-scale Indian Ocean through retroflection modes of its southern extension. Five cruise data sets and remote sensing data from different sensors are used to identify three states of the southern extension of the EMC: early retroflection, canonical retroflection, and no retroflection. Retroflections occur 47% of the time. EMC strength regulates the retroflection state, although impinged mesoscale eddies also contribute to retroflection formation. Early retroflection is linked with EMC volume transport. Anticyclonic eddies drifting from the central Indian Ocean to the coast favor early retroflection formation, anticyclonic eddies near the southern tip of Madagascar promote the generation of canonical retroflection, and no retroflection appears to be associated with a lower eddy kinetic energy (EKE). Knowledge of the EMC retroflection state could help predict (a) coastal upwelling south of Madagascar, (b) the southeastern Madagascar phytoplankton bloom, and (c) the formation of the South Indian Ocean Counter Current (SICC).
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    Efficient extraction of past seawater Pb and Nd isotope signatures from Southern Ocean sediments (2021)
    AGU (American Geophysical Union) | Wiley
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    Publication Date: 2024-02-07
    Description: Radiogenic lead (Pb) and neodymium (Nd) isotope compositions extracted from authigenic phases in marine sediments are sensitive tracers to reconstruct past ocean circulation and water mass mixing. Chemical reductive leaching of hydrogenetic ferromanganese oxyhydroxides from bulk sediments is the most practical way to recover past seawater Pb and Nd isotope signatures in the Southern Ocean, due to the scarcity of alternative archives. However, the leached signal could be compromised if substantial quantities of Pb and Nd were released from non‐hydrogenetic sediment fractions during chemical extraction. Here we developed a very short 10‐seconds leaching method to extract reliable seawater Pb and Nd isotope signals from sediments in the Atlantic sector of Southern Ocean. The effect of a previously recommended MgCl2 pre‐wash, the role of chelate ligands in the leaching solution and length of leaching time were investigated. The results show that 10‐seconds exposure time of sediments to reductive leaching extracted sufficient and more reliable hydrogenetic Pb and Nd compared with the commonly used 30‐minute leaching approaches. The robustness of our improved leaching method was validated via direct comparison of Pb and Nd isotope signatures with actual seawater, porewater and corresponding sediment leachates from three stations in front of the Antarctic Filchner‐Rønne Ice Shelf. Our findings also indicate that in contrast previously studied sites on the West Antarctic continental shelf, the bottom seawater Nd concentration is less elevated through benthic fluxes in the area of the southern Weddell Sea shelf.
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    Provenance and weathering of clays delivered to the Bay of Bengal during the middle Miocene: Linkages to tectonics and monsoonal climate (2021)
    AGU (American Geophysical Union) | Wiley
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    Publication Date: 2024-02-07
    Description: Tectonics and regional monsoon strength control weathering and erosion regimes of the watersheds feeding into the Bay of Bengal, which are important contributors to global climate evolution via carbon cycle feedbacks. The detailed mechanisms controlling the input of terrigenous clay to the Bay of Bengal on tectonic to orbital timescales are, however, not yet well understood. We produced orbital‐scale resolution geochemical records for International Ocean Discovery Program Site U1443 (southern Bay of Bengal) across five key climatic intervals of the middle to late Miocene (15.8 – 9.5 Ma). Our new radiogenic Sr, Nd, and Pb isotope time series of clays transported to the Ninetyeast Ridge suggest that the individual contributions from different erosional sources overall remained remarkably consistent during the Miocene despite major tectonic reorganizations in the Himalayas. On orbital timescales, however, high‐resolution data from the five investigated intervals show marked fluctuations of all three isotope systems. Interestingly, the variability was much higher within the Miocene Climatic Optimum (around 16‐15 Ma) and across the major global cooling (~13.9‐13.8 Ma) until ~13.5 Ma, than during younger time intervals. This change is attributed to a major restriction on the supply of High Himalayan erosion products due to migration of the peak precipitation area towards the frontal domains of the Himalayas and the Indo‐Burman Ranges. The transient excursions of the radiogenic isotope signals on orbital timescales most likely reflect climatically driven shifts in monsoon strength.
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    Tropical Cyclone Integrated Kinetic Energy in an Ensemble of HighResMIP Simulations (2021)
    AGU (American Geophysical Union) | Wiley
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    Publication Date: 2024-02-07
    Description: This study investigates tropical cyclone integrated kinetic energy, a measure which takes into account the intensity and the size of the storms and which is closely associated with their damage potential, in three different global climate models integrated following the HighResMIP protocol. In particular, the impact of horizontal resolution and of the ocean coupling are assessed. We find that, while the increase in resolution results in smaller and more intense storms, the integrated kinetic energy of individual cyclones remains relatively similar between the two configurations. On the other hand, atmosphere-ocean coupling tends to reduce the size and the intensity of the storms, resulting in lower integrated kinetic energy in that configuration. Comparing cyclone integrated kinetic energy between a present and a future scenario did not reveal significant differences between the two periods.
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    New Magnetostratigraphic Insights From Iceberg Alley on the Rhythms of Antarctic Climate During the Plio‐Pleistocene (2021)
    AGU (American Geophysical Union) | Wiley
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    Publication Date: 2024-02-07
    Description: International Ocean Discovery Program (IODP) Expedition 382 in the Scotia Sea’s Iceberg Alley recovered among the most continuous and highest resolution stratigraphic records in the Southern Ocean near Antarctica spanning the last 3.3 Myr. Sites drilled in Dove Basin (U1536/U1537) have well‐resolved magnetostratigraphy and a strong imprint of orbital forcing in their lithostratigraphy. All magnetic reversals of the last 3.3 Myr are identified, providing a robust age model independent of orbital tuning. During the Pleistocene, alternation of terrigenous versus diatomaceous facies shows power in the eccentricity and obliquity frequencies comparable to the amplitude modulation of benthic δ18O records. This suggests that variations in Dove Basin lithostratigraphy during the Pleistocene reflect a similar history as globally integrated ice volume at these frequencies. However, power in the precession frequencies over the entire ∼3.3 Myr record does not match the amplitude modulation of benthic δ18O records, suggesting Dove Basin contains a unique record at these frequencies. Comparing the position of magnetic reversals relative to local facies changes in Dove Basin and the same magnetic reversals relative to benthic δ18O at North Atlantic IODP Site U1308, we demonstrate Dove Basin facies change at different times than benthic δ18O during intervals between ∼3 and 1 Ma. These differences are consistent with precession phase shifts and suggest climate signals with a Southern Hemisphere summer insolation phase were recorded around Antarctica. If Dove Basin lithology reflects local Antarctic ice volume changes, these signals could represent ice sheet precession‐paced variations not captured in benthic δ18O during the 41‐kyr world.
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    Offshore freshened groundwater in continental margins (2021)
    AGU (American Geophysical Union) | Wiley
    Details
    Publication Date: 2024-02-07
    Description: First reported in the 1960s, offshore freshened groundwater (OFG) has now been documented in most continental margins around the world. In this review we compile a database documenting OFG occurrences and analyse it to establish the general characteristics and controlling factors. We also assess methods used to map and characterise OFG, identify major knowledge gaps and propose strategies to address them. OFG has a global volume of 1 million km3; it predominantly occurs within 55 km of the coast and down to a water depth of 100 m. OFG is mainly hosted within siliciclastic aquifers on passive margins and recharged by meteoric water during Pleistocene sea‐level lowstands. Key factors influencing OFG distribution are topography‐driven flow, salinisation via haline convection, permeability contrasts, and the continuity/connectivity of permeable and confining strata. Geochemical and stable isotope measurements of pore waters from boreholes have provided insights into OFG emplacement mechanisms, while recent advances in seismic reflection, electromagnetic surveys and mathematical models have improved our understanding of OFG geometry and controls. Key knowledge gaps, such as the extent and function of OFG, and the timing of their emplacement, can be addressed by the application of isotopic age tracers, joint inversion of electromagnetic and seismic reflection data, and development of three‐dimensional hydrological models. We show that such advances, combined with site‐specific modelling, are necessary to assess the potential use of OFG as an unconventional source of water and its role in sub‐seafloor geomicrobiology.
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    Comparison of Different Coupling Methods for Joint Inversion of Geophysical data: A case study for the Namibian Continental Margin (2021)
    AGU (American Geophysical Union) | Wiley
    Details
    Publication Date: 2024-02-07
    Description: Integration of multiple geophysical data is a key practice to reduce model uncertainties and enhance geological interpretations. Electrical resistivity models resulting from inversion of marine magnetotelluric (MT) data, often lack depth resolution of lithological boundaries and distinct information for shallow model parts. This is due to the diffusive nature of electromagnetic fields, enhanced by deficient data sampling and model regularization during inversion. Thus, integrating data or models to constrain layer thicknesses or structural boundaries is an effective approach to derive better constrained and more detailed resistivity models. We investigate the different impacts of three cross-gradient coupled constraints on 3D MT inversion of data from the Namibian passive continental margin. The three constraints are a) coupling with a fixed structural density model; b) coupling with satellite gravity data; c) coupling with a fixed gradient velocity model. Here we show that coupling with a fixed model (a and c) improves the resistivity model the most. Shallow conductors imaging sediment cover are confined to a thinner layer in the resulting resistivity models compared to the MT-only model. Additionally, these constraints help to suppress vertical smearing of a conductive anomaly attributed to a fracture zone, and clearly show that the seismically imaged Moho is not accompanied by a change in electrical resistivity. All of these observations help to derive an Earth model, which will form the basis for future interpretation of the processes that lead to continental break-up during the early Cretaceous.
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    Impact of Intraseasonal Waves on Angolan Warm and Cold Events (2021)
    Wiley | AGU (American Geophysical Union)
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    Publication Date: 2024-02-07
    Description: The intraseasonal variability of the tropical eastern boundary upwelling region in the Atlantic Ocean is investigated using multiyear mooring and satellite data. Pronounced oscillations of alongshore velocity and sea level off Angola at periods of about 90 and 120 days are observed. Similar spectral peaks are detected along the equator suggesting an equatorial forcing via equatorial and coastally trapped waves. Equatorial variability at 90 days is enhanced only in the eastern Atlantic likely forced by local zonal wind fluctuations. Variability at 120 days is generally stronger and linked to a second equatorial basin mode covering the whole equatorial basin. Besides forcing of the 120‐day variability by equatorial zonal winds, additional forcing of the resonant basin mode likely originates in the central and western tropical North Atlantic. The coastally trapped waves generated at the eastern boundary by the impinging equatorial Kelvin waves that are detected through their variations in sea level anomaly are associated with corresponding sea surface temperature anomalies delayed by about 14 days. Off Angola, those intraseasonal waves interfere with major coastal warm and cold events that occur every few years by either enhancing them as for the Benguela Niño in 1995 or damping them as for the warm event in 2001.
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    Earth’s magnetic field strength and the Cretaceous Normal Superchron: New data from Costa Rica (2021)
    AGU (American Geophysical Union) | Wiley
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    Publication Date: 2024-02-07
    Description: Constraining the long‐term variability and average of the Earth’s magnetic field strength is fundamental to understanding the characteristics and behavior of the geomagnetic field. Questions remain about the strength of the average field, and the relationship between strength and reversal frequency, due to the dispersion of data from key time intervals. Here, we focus on the Cretaceous Normal Superchron (CNS; 121‐84 Ma), during which there were no reversals. We present new intensity results from 41 submarine basaltic glass (SBG) sites collected on the Nicoya Peninsula and Murcièlago Islands, Costa Rica. New and revised 40Ar/39Ar and biostratigraphic age constraints from previous studies indicate ages from 141 to 65 Ma. One site with an age of 135.1 ± 1.5 Ma (2σ) gave a reliable intensity result of 34 ± 8 µT (equivalent to a virtual axial dipole moment, VADM, value of 88 ± 20 ZAm2), three sites from 121 to 112 Ma, spanning the onset of the CNS, vary from 21 ± 1 to 34 ± 4 µT (53 ± 3 to 87 ± 10 ZAm2). These results from the CNS are all higher than the long‐term average of ∼42 ZAm2 and data from Suhongtu, Mongolia (46‐53 ZAm2) and are similar to the Troodos Ophiolite, Cyprus (81 ZAm2, reinterpreted in this study). Together with the reinterpreted data, the new Costa Rica results suggest that the strength of the geomagnetic field was approximately the same both before and after the onset of the CNS. Therefore, the data do not support a strict correlation between polarity interval length and the strength of the magnetic field.
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    Evolution of the Crustal and upper Mantle seismic structure from 0 – 27 Ma in the equatorial Atlantic Ocean at 2º 43´S (2021)
    AGU (American Geophysical Union) | Wiley
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    Publication Date: 2024-02-07
    Description: We present seismic tomographic results from a unique seismic refraction and wide-angle survey along a 600-km long flow-line corridor of oceanic lithosphere ranging in age from 0 to 27 Ma in the equatorial Atlantic Ocean at 2º 43´S. The velocities in the crust near the ridge axis rapidly increase in the first 6 Myr and then change gradually with age. The upper crust (Layer 2) thickness varies between 2 – 2.4 km with an average thickness of 2.2 km and the crustal thickness varies from 5.6 – 6 km along the profile with an average crustal thickness of 5.8 km. At some locations, we observe negative velocity anomalies (∼ -0.3 km/s) in the lower crust which could be either due to chemical heterogeneity in gabbroic rocks and/or the effects of fault related deformation zones leading to an increase in porosities up to 1.6% depending on the pore/crack geometry. The existence of a low velocity anomaly beneath the ridge axis suggests the presence of partial melt (∼1.3%) in the lower crust. Upper mantle velocities also remain low (∼7.8 km/s) from ridge axis up to 5 Ma, indicating a high temperature regime associated with mantle melting zone underneath. These results suggest that the evolution of the crust and uppermost mantle at this location occur in the first 10 Ma of its formation and then remains unchanged. Most of the structures in the older crust and upper mantle are fossilized structures and could provide information about past processes at ocean spreading centers.
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    A rapid numerical method to constrain 2D focused fluid flow rates along convergent margins using dense BSR‐based temperature field data (2021)
    AGU (American Geophysical Union) | Wiley
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    Publication Date: 2024-02-07
    Description: Estimates of the sub-seabed fluid flow rates are important for understanding hydrological budgets, biogeochemical cycles, and physical properties of the sediments. Fluid flow rates and directions, however, are difficult to measure, particularly beneath the seafloor. We developed a rapid method to estimate regional fluid migration rates using an extensive database of seismic reflection profiles taken offshore SW Taiwan. We observe bottom-simulating reflector (BSR) that deflect towards the seafloor near thrust faults that indicate localized heat flow variations. At these sites, advecting warm pore fluids transport heat to shallower depths and force the BSR shallower. Our 2-D steady-state numerical method quantifies the fluid flow rates required to cause such thermal anomalies. We found that fluid flow rates near the trench of the accretionary wedge range between 0.1 to 16 m3 yr-1 m-1, with slower and faster rates generally associated with slope basin discontinuities and faults, respectively. To evaluate the fluid pattern evolution from subduction to collision, we studied three transects: one along the Manila subduction zone in the south and two in Taiwan’s initial collision zone in the north. We quantified the fluid budget and partitioning of fluid flow between focused discharge through faults and diffusive flow through the wedge. Faults in Taiwan’s accretionary wedge capture on average 25% of the total dewatering flux in the younger subduction zone and 38.5% in the tectonically mature collision zone. Our method provides estimates of fluid migration rates along convergent plate boundaries, and contributes to our understanding of focused fluid flow processes in many other regions.
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    Core-log-seismic integration in metamorphic rocks and its implication for the regional geology: A case study for the ICDP drilling project COSC-1, Sweden (2021)
    AGU (American Geophysical Union) | Wiley
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    Publication Date: 2024-02-07
    Description: Continental collision causes deformation in the crust along shear zones. However, the physical and chemical conditions at which these zones operate and the deformation processes that enable up to hundreds of km of tectonic transport are still unclear because of the depth at which they occur and the challenges in imaging them. Ancient exhumed collision zones allow us to investigate these processes much better, for example at the COSC‐1 borehole in the central Scandinavian Caledonides. This study combines data from the COSC‐1 borehole with different seismic measurements to provide constraints on the spatial lithological and textural configuration of the Seve Nappe Complex. This is one of the few studies that shows that core‐log‐seismic integration in metamorphic rocks allows to identify the spatial distribution of major lithological units. Especially gamma ray logs in combination with density data are powerful tools to distinguish between mafic and felsic lithologies in log‐core correlation. Our results indicate that reflections along the borehole are primarily caused by compositional rather than textural changes. Reflections in the Seve Nappe Complex are not as distinct as in greater depths but continuous and several of them can be linked to magmatic intrusions, which have been metamorphically overprinted. Their setting indicates that the Seve Nappe Complex consists of the remnants of a volcanic continental margin. Our results suggest that ductile‐deformed middle crustal reflectivity is primarily a function of pre‐orogenic lithological variations which has to be considered when deciphering mountain building processes.
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    Constraining global marine iron sources and ligand-mediated scavenging fluxes with GEOTRACES dissolved iron measurements in an ocean biogeochemical model (2021)
    AGU (American Geophysical Union) | Wiley
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    Publication Date: 2024-02-07
    Description: Iron is a key micronutrient controlling phytoplankton growth in vast regions of the global ocean. Despite its importance, uncertainties remain high regarding external iron source fluxes and internal cycling on a global scale. In this study, we used a global dissolved iron dataset, including GEOTRACES measurements, to constrain source and scavenging fluxes in the marine iron component of a global ocean biogeochemical model. Our model simulations tested three key uncertainties: source inputs of atmospheric soluble iron deposition (varying from 1.4–3.4 Gmol/yr), reductive sedimentary iron release (14–117 Gmol/yr), and compared a variable ligand parameterization to a constant distribution. In each simulation, scavenging rates were tuned to reproduce the observed global mean iron inventory for consistency. The variable ligand parameterization improved the global model-data misfit the most, suggesting that heterotrophic bacteria are an important source of ligands to the ocean. Model simulations containing high source fluxes of atmospheric soluble iron deposition (3.4 Gmol/yr) and reductive sedimentary iron release (114 Gmol/yr) further improved the model most notably in the surface ocean. High scavenging rates were then required to maintain the iron inventory resulting in relatively short surface and global ocean residence times of 0.83 and 7.5 years, respectively. The model simulates a tight spatial coupling between source inputs and scavenging rates, which may be too strong due to underrepresented ligands near source inputs, contributing to large uncertainties when constraining individual fluxes with dissolved iron concentrations. Model biases remain high and are discussed to help improve global marine iron cycle models.
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    Enhanced late Miocene chemical weathering and altered precipitation patterns in the watersheds of the Bay of Bengal recorded by detrital clay radiogenic isotopes (2021)
    AGU (American Geophysical Union) | Wiley
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    Publication Date: 2024-02-07
    Description: The late Miocene was a period of declining CO2 levels and extensive environmental changes, which likely had a large impact on monsoon strength as well as on the weathering and erosion intensity in the South Asian Monsoon domain. To improve our understanding of these feedback systems, detrital clays from the southern Bay of Bengal (International Ocean Discovery Program Site U1443) were analysed for the radiogenic isotope compositions of Sr, Nd, and Pb to reconstruct changes in sediment provenance and weathering regime related to South Asian Monsoon rainfall from 9 to 5 Ma. The 100 kyr resolution late Miocene to earliest Pliocene record suggests overall low variability in the provenance of clays deposited on the Ninetyeast Ridge. However, at 7.3 Ma, Nd and Pb isotope compositions indicate a switch to an increased relative contribution from the Irrawaddy River (by ∼10 %). This shift occurred during the global benthic δ13C decline and we suggest that global cooling and increasing aridity resulted in an eastward shift of precipitation patterns leading to a more focussed erosion of the Indo-Burman Ranges. Sr isotope compositions were decoupled from Nd and Pb isotope signatures and became more radiogenic between 6 and 5 Ma. Grassland expansion generating thick, easily weatherable soils may have led to an environment supporting intense chemical weathering which is likely responsible for the elevated detrital clay 87Sr/86Sr ratios during this time. This change in Sr isotope signatures may also have contributed to the late Miocene increase of the global seawater Sr isotope composition.
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    Three‐Dimensional Numerical Simulations of Internal Tides in the Angolan Upwelling Region (2021)
    AGU (American Geophysical Union) | Wiley
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    Publication Date: 2024-02-07
    Description: In austral winter, biological productivity at the Angolan shelf reaches its maximum. The alongshore winds, however, reach their seasonal minimum suggesting that processes other than local wind‐driven upwelling contribute to near‐coastal cooling and upward nutrient supply, one possibility being mixing induced by internal tides (ITs). Here, we apply a three‐dimensional ocean model to simulate the generation, propagation, and dissipation of ITs at the Angolan continental slope and shelf. Model results are validated against moored acoustic Doppler current profiler and other observations. Simulated ITs are mainly generated in regions with a critical/supercritical slope typically between the 200‐ and 500‐m isobaths. Mixing induced by ITs is found to be strongest close to the coast and gradually decreases offshore thereby contributing to the establishment of cross‐shore temperature gradients. The available seasonal coverage of hydrographic data is used to design simulations to investigate the influence of seasonally varying stratification characterized by low stratification in austral winter and high stratification in austral summer. The results show that IT characteristics, such as their wavelengths, sea surface convergence patterns, and baroclinic structure, have substantial seasonal variations and additionally strong spatial inhomogeneities. However, seasonal variations in the spatially averaged generation, onshore flux, and dissipation of IT energy are weak. By evaluating the change of potential energy, it is shown, nevertheless, that mixing due to ITs is more effective during austral winter. We argue that this is because the weaker background stratification in austral winter than in austral summer acts as a preconditioning for IT mixing.
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    Warming Trend in Antarctic Bottom Water in the Vema Channel in the South Atlantic (2021)
    AGU (American Geophysical Union) | Wiley
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    Publication Date: 2024-02-07
    Description: The excess heat absorbed from the atmosphere has increased the temperature in the upper layers of the ocean (〈2,000 m). In the abyss, infrequently repeated ship sections, deep Argo float measurements, and sparse moored observations have found signs of warming in the Southwest Atlantic, possibly linked to changes in the Weddell Sea. We present a new moored temperature time series sampled near the bottom in the Vema Channel, from February 2019 to August 2020. Together with historical data, the combined record confirms the warming of the abyssal waters, with an increase of 0.059°C in potential temperature between January 1991 and August 2020, embedded within intense high-frequency variability. Moreover, the data suggest the possibility of an accelerated warming, with a change in the temperature trend from 0.0016°C yr−1, between the early 1990s and 2005, to 0.0026°C yr−1 afterwards.
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    Trace element biogeochemistry in the high latitude North Atlantic Ocean: seasonal variations and volcanic inputs (2021)
    AGU (American Geophysical Union) | Wiley
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    Publication Date: 2024-02-07
    Description: Key Points: - Bio-essential element concentrations in surface waters decreased from spring to summer with removal ratios reflecting biological uptake - Effects of volcanic inputs from Eyjafjallajökull in spring 2010 were pronounced for Al, Mn and Zn but returned to typical levels in summer - Deep winter convection dominated trace element supply to surface waters with minor contributions from atmospheric and diffusive mixing We present dissolved and total dissolvable trace elements for spring and summer cruises in 2010 in the high latitude North Atlantic. Surface and full depth data are provided for Al, Cd, Co, Cu, Mn, Ni, Pb, Zn in the Iceland and Irminger Basins, and consequences of biological uptake and inputs by the spring Eyjafjallajökull volcanic eruption are assessed. Ash from Eyjafjallajökull resulted in pronounced increases in Al, Mn and Zn in surface waters in close proximity to Iceland during the eruption, whilst 3 months later during the summer cruise levels had returned to more typical values for the region. The apparent seasonal removal ratios of surface trace elements were consistent with biological export. Assessment of supply of trace elements to the surface mixed layer for the region, excluding volcanic inputs, indicated that deep winter mixing was the dominant source, with diffusive mixing being a minor source (between 13.5% (dissolved Cd (DCd)) and ‐2.43% (DZn) of deep winter flux), and atmospheric inputs being an important source only for DAl and DZn (DAl up to 42% and DZn up to 4.2% of deep winter+diffusive fluxes) and typically less than 1% for the other elements. Elemental supply ratios to the surface mixed layer through convection were comparable to apparent removal ratios we calculated between spring and summer. Given that deep mixing dominated nutrient and trace element supply to surface waters, predicted increases in water column stratification in this region may reduce supply, with potential consequences for primary production and the biological carbon pump.
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    Imaging the P‐Wave Velocity Structure of Arctic Subsea Permafrost Using Laplace‐Domain Full‐Waveform Inversion (2021)
    AGU (American Geophysical Union) | Wiley
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    Publication Date: 2024-02-07
    Description: Climate change in the Arctic has recently become a major scientific issue, and detailed information on the degradation of subsea permafrost on continental shelves in the Arctic is critical for understanding the major cause and effects of global warming, especially the release of greenhouse gases. The subsea permafrost at shallow depths beneath the Arctic continental shelves has significantly higher P‐wave velocities than the surrounding sediments. The distribution of subsea permafrost on Arctic continental shelves has been studied since the 1970s using seismic refraction methods. With seismic refraction data, the seismic velocity and the depth of the upper boundary of subsea permafrost can be determined. However, it is difficult to identify the lower boundary and the internal shape of permafrost. Here, we present two‐dimensional P‐wave velocity models of the continental shelf in the Beaufort Sea by applying the Laplace‐domain full‐waveform inversion method to acquired multichannel seismic reflection data. With the inverted P‐wave velocity model, we identify anomalous high seismic velocities that originated from the subsea permafrost. Information on the two‐dimensional distribution of subsea permafrost on the Arctic continental shelf area, including the upper and lower bounds of subsea permafrost, are presented. Also, the two‐dimensional P‐wave velocity model allows us to estimate the thawing pattern and the shape of subsea permafrost structures. Our proposed P‐wave velocity models were verified by comparison with the previous distribution map of subsea permafrost from seismic refraction analyses, geothermal modeling, and well‐log data.
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    Stable Atlantic Deep Water Mass Sourcing on Glacial‐Interglacial Timescales (2021)
    AGU (American Geophysical Union) | Wiley
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    Publication Date: 2024-02-07
    Description: Increased deep ocean carbon storage is often invoked as the major sink for lower atmospheric CO2 concentrations during past ice ages. In order to improve the understanding of the changes in ocean dynamics facilitating such increased oceanic carbon storage, we assess the variability of deep water provenance in the Atlantic by reconstructing authigenic Nd isotopes from North Atlantic site U1313 over the past ∼100 kyr. Under consideration of these new constraints for the northern Nd isotope end-member, we find only limited long-term variations in the meridional and intra-basin water-mass gradients suggesting a prevalence of northern-sourced water (NSW) throughout the past 100 kyr. Tentative results suggest that during the glacial period of Marine Isotope Stage 4 NSW proportions even increased by additional ∼15% in the equatorial and Northeast Atlantic, calling into question the notion that cold climates promote the expansion of southern-sourced water.
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    Seismic Constraint From Vp/Vs Ratios on the Structure and Composition Across the Continent‐Ocean Transition Zone, South China Sea (2021)
    AGU (American Geophysical Union) | Wiley
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    Publication Date: 2024-02-07
    Description: At non-volcanic passive continental margins, seismic techniques often failed to uniquely define the nature of crustal domains. Here, we overcome this problem by studying the structure and composition of the continent-ocean transition (COT) in the Southwest Sub-basin of the South China Sea, using P and S wave seismic tomography and Vp/Vs ratios, providing unique constraints on lithology. Throughout the image domain, we can rule out large areas of exhumed mantle as Vp/Vs ratios are always 〈1.9 in the shallow basement layer. Instead, the COT is characterized by extended and fragmented continental crust, and possibly mafic aggregation at the bottom of the crust. In concert with observations from multichannel seismic reflection data, seismic velocities and Vp/Vs ratios suggest that the oldest oceanic crust was formed by starved magmatism, causing rugged basement, thin crust, nearly absent lower crust, and moderately serpentinized mantle below. Our results reveal that rifting occurred without un-roofing continental mantle.
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    Meridional and Cross‐Shelf Variability of N2O and CH4 in the Eastern‐South Atlantic (2021)
    AGU (American Geophysical Union) | Wiley
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    Publication Date: 2024-02-07
    Description: Upward transport and/or mixing of trace gas-enriched subsurface waters fosters the exchange of nitrous oxide (N2O) and methane (CH4) with the atmosphere in the Eastern-South Atlantic (ESA). To date, it is, however, unclear whether this source is maintained by local production or advection of trace gas-enriched water masses. The meridional and zonal variability of N2O and CH4 in the ESA were investigated to identify the contributions of the major regional water masses to the overall budget of N2O and CH4. The maximal sea surface N2O and CH4 concentrations and the main ESA upwelling cells co-occurred with a strong negative correlation with the sea surface temperature (SST) (p 〈 0.05). The dominance of the central water masses in the winter and spring seasons and the interplay between shelf topography and wind regime are suggested to determine enhanced gas transfer toward the sea-air interface or “capping” at midwater depth. These parameters are supposed to be critical in the local budget of N2O and CH4 in the ESA. Our findings also show that the shape of N2O and CH4 gradients is very similar both meridionally and zonally; however, the extent of the differences between the high-end and low-end members of the concentrations/saturations range is different. This suggests a more pronounced effect of local sources on CH4 than N2O distribution, in particular in the Walvis Bay area. With respect to N2O, however, low-oxygen waters from the poleward undercurrent impinge in the shelf close to Cape Frio and often result in N2O concentrations significantly higher than off Lüderitz (p 〈 0.05)
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    Altitude of the East Asian Coastal Mountains and Their Influence on Asian Climate During Early Late Cretaceous (2021)
    AGU (American Geophysical Union) | Wiley
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    Publication Date: 2024-02-07
    Description: The East Asian coastal mountains have been in place during the Late Cretaceous times, thus substantially influencing the Asian climate. So far, their altitude is uncertain. Here we investigate the influence of such mountains on Asian climate using an atmosphere-ocean general circulation model, Community Earth System Model version 1.2.2. Simulation results show that extensive deserts would develop over the eastern part of the East Asia if the altitude of the coastal mountains was greater than 2 km. This is due to the pumping effect of the coastal mountains which deprives the moisture from the East Asian interior during summer and autumn, leading to less precipitation and greater potential evapotranspiration. The existence of extensive desert areas would be more consistent with the presented Asian paleoenvironmental reconstructions. Therefore, our results independently indicate that the altitude of the coastal mountains had attained 2 km or more by the early Late Cretaceous.
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    The Climate Response to Emissions Reductions Due to COVID‐19: Initial Results From CovidMIP (2021)
    AGU (American Geophysical Union) | Wiley
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    Publication Date: 2024-02-07
    Description: Many nations responded to the corona virus disease-2019 (COVID-19) pandemic by restricting travel and other activities during 2020, resulting in temporarily reduced emissions of CO2, other greenhouse gases and ozone and aerosol precursors. We present the initial results from a coordinated Intercomparison, CovidMIP, of Earth system model simulations which assess the impact on climate of these emissions reductions. 12 models performed multiple initial-condition ensembles to produce over 300 simulations spanning both initial condition and model structural uncertainty. We find model consensus on reduced aerosol amounts (particularly over southern and eastern Asia) and associated increases in surface shortwave radiation levels. However, any impact on near-surface temperature or rainfall during 2020–2024 is extremely small and is not detectable in this initial analysis. Regional analyses on a finer scale, and closer attention to extremes (especially linked to changes in atmospheric composition and air quality) are required to test the impact of COVID-19-related emission reductions on near-term climate. Key Points: - Lockdown restrictions during COVID-19 have reduced emissions of aerosols and greenhouse gases - 12 CMIP6 Earth system models have performed coordinated experiments to assess the impact of this on climate - Aerosol amounts are reduced over southern and eastern Asia but there is no detectable change in annually averaged temperature or precipitation
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    The Transpolar Drift Influence on the Arctic Ocean Silicon Cycle (2021)
    AGU (American Geophysical Union) | Wiley
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    Publication Date: 2024-02-07
    Description: During most of the year, diatom production in the ice-covered Central Arctic Ocean (CAO) is limited by light availability and nutrient supply. Therefore, biological production is thought to be generally low, with higher biological production at the sea ice edge and over partially ice-free shelf areas. The major surface ocean current in the CAO is the Transpolar Drift (TPD), which transports sea ice and water from the rivers and shelves of the Laptev and the East Siberian Seas across the CAO toward the Fram Strait, carrying high amounts of terrestrial-derived material over long distances. We used Si isotopes (δ30Si) to better understand the difference between lower and higher biological production areas and how the TPD potentially affects the Si cycle in the CAO. Our data show low dissolved Si concentrations ([DSi]) paired with high values of δ30Si-DSi in all surface samples indicating fractionation by diatoms. Specifically, outside the TPD influence, all nutrients were depleted and supply was limited due to stratified conditions, thus preventing further phytoplankton growth in the area during the sampling time in late summer-early fall. In contrast, under the TPD influence, diatom primary production was limited by low nitrate and strongly limited by light due to the presence of sea ice, even though [DSi] values were much higher than outside the TPD. Based on δ30Si, we could identify low but measurable DSi utilization in the TPD, potentially highlighting the importance of sea ice-attached diatoms transported to the CAO via the TPD for the Si cycle in this region. Key Points - Primary production and silicon utilization outside the Transpolar Drift are higher than under its influence due to more light availability - Primary production and lateral water transport under the Transpolar Drift influence were identified from silicon isotope composition - The Transpolar Drift delivers high dissolved silicon to the surface Arctic Ocean, a unique feature not seen in any other open ocean
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    Cross‐scale seismic anisotropy analysis in metamorphic rocks from the COSC‐1 borehole in the Scandinavian Caledonides (2021)
    AGU (American Geophysical Union) | Wiley
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    Publication Date: 2024-02-07
    Description: Metamorphic and deformed rocks in thrust zones show particularly high seismic anisotropy causing challenges for seismic imaging and interpretation. A good example is the Seve Nappe Complex in central Sweden, an old exhumed orogenic thrust zone that is characterized by a strong but incoherent seismic reflectivity and considerable seismic anisotropy. However, only little is known about their origin in relation to composition and structural influences on measurements at different seismic scales. Here, we present a new integrative study of cross‐scale seismic anisotropy analyses combining mineralogical composition, microstructural analyses and seismic laboratory experiments from the COSC‐1 borehole, which sampled a 2.5 km‐deep section of metamorphic rocks deformed in an orogenic root now preserved in the Lower Seve Nappe. While there is strong crystallographic preferred orientation in most samples in general, variations in anisotropy depend mostly on bulk mineral composition and dominant core lithology as shown by a strong correlation between these. This relationship enables to identify three distinct seismic anisotropy facies providing a continuous anisotropy profile along the borehole. Moreover, comparison of laboratory seismic measurements and electron‐backscatter diffraction data reveals a strong scale‐dependence, which is more pronounced in the highly deformed, heterogeneous samples. This highlights the need for comprehensive cross‐validation of microscale anisotropy analyses with additional lithological data when integrating seismic anisotropy over seismic scales.
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    Retreat of Humboldt Gletscher, North Greenland, Driven by Undercutting From a Warmer Ocean (2021)
    AGU (American Geophysical Union) | Wiley
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    Publication Date: 2024-02-07
    Description: Humboldt Gletscher is a 100‐km wide, slow‐moving glacier in north Greenland which holds a 19‐cm global sea level equivalent. Humboldt has been the fourth largest contributor to sea level rise since 1972 but the cause of its mass loss has not been elucidated. Multi‐beam echo sounding data collected in 2019 indicate a seabed 200 m deeper than previously known. Conductivity temperature depth data reveal the presence of warm water of Atlantic origin at 0°C at the glacier front and a warming of the ocean waters by 0.9 ± 0.1°C since 1962. Using an ocean model, we reconstruct grounded ice undercutting by the ocean, combine it with calculated retreat caused by ice thinning to floatation, and are able to fully explain the observed retreat. Two thirds of the retreat are caused by undercutting of grounded ice, which is a physical process not included in most ice sheet models.
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    The South Atlantic Meridional Overturning Circulation and Mesoscale Eddies in the First GO‐SHIP Section at 34.5ºS (2021)
    AGU (American Geophysical Union) | Wiley
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    Publication Date: 2024-02-07
    Description: The variability of the Atlantic Meridional Overturning Circulation (AMOC) has considerable impacts on the global climate system. Past studies have shown that changes in the South Atlantic control the stability of the AMOC and drive an important part of its variability. That is why significant resources have been invested in a South (S)AMOC observing system. In January 2017, the RV Maria S. Merian conducted the first GO‐SHIP hydrographic transect along the SAMOC‐Basin Wide Array (SAMBA) line at 34.5°S in the South Atlantic. This paper presents estimates of meridional volume, freshwater (MFT), and heat (MHT) transports through the line using the slow varying geostrophic density field and direct velocity observations. An upper and an abyssal overturning cell are identified with a strength of 15.64 ± 1.39 Sv and 2.4 ± 1.6 Sv, respectively. The net northward MHT is 0.27 ± 0.10 PW, increasing by 0.12 PW when we remove the observed mesoscale eddies with a climatology derived from the Argo floats data set. We attribute this change to an anomalous predominance of cold core eddies during the cruise period. The highest velocities are observed in the western boundary, within the Brazil and the Deep Western Boundary currents. These currents appear as a continuous deep jet located 150 km off the slope squeezed between two cyclonic eddies. The zonal changes in water masses properties and velocity denote the imprint of exchange pathways with both the Southern and the Indian oceans. Key Points: ● Overturning maximum is 15.64 ± 1.39 Sv; Meridional heat and freshwater transport are 0.27 ± 0.10 PW and 0.23 ± 0.02 Sv, respectively ● Excluding the mesoscale eddies from the section increased the meridional heat transport by 0.12 PW ● The distribution of water masses and currents reflects the favorable position of the section for observing
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    Seismic structure of the St. Paul Fracture Zone and Late Cretaceous to Mid Eocene oceanic crust in the equatorial Atlantic Ocean near 18°W (2021)
    AGU (American Geophysical Union) | Wiley
    Details
    Publication Date: 2024-02-07
    Description: Plate tectonics characterize transform faults as conservative plate boundaries where the lithosphere is neither created nor destroyed. In the Atlantic, both transform faults and their inactive traces, fracture zones, are interpreted to be structurally heterogeneous, representing thin, intensely fractured, and hydrothermally altered basaltic crust overlying serpentinized mantle. This view, however, has recently been challenged. Instead, transform zone crust might be magmatically augmented at ridge-transform intersections before becoming a fracture zone. Here, we present constraints on the structure of oceanic crust from seismic refraction and wide-angle data obtained along and across the St. Paul fracture zone near 18°W in the equatorial Atlantic Ocean. Most notably, both crust along the fracture zone and away from it shows an almost uniform thickness of 5-6 km, closely resembling normal oceanic crust. Further, a well-defined upper mantle refraction branch supports a normal mantle velocity of 8 km/s along the fracture zone valley. Therefore, the St. Paul fracture zone reflects magmatically accreted crust instead of the anomalous hydrated lithosphere. Little variation in crustal thickness and velocity structure along a 200 km long section across the fracture zone suggests that distance to a transform fault had negligible impact on crustal accretion. Alternatively, it could also indicate that a second phase of magmatic accretion at the proximal ridge-transform intersection overprinted features of starved magma supply occurring along transform faults. Key Points: - Seismic structure along the St. Paul fracture zone reflects magmatically accreted oceanic crust - Oceanic crust across St. Paul shows only small thickness variations, lacking evidence for regional crustal thinning near fracture zones - Magmatic nature of crust supports a mechanism where transform crust is augmented before being turned into a fracture zone
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    Mean‐state dependence of CO 2 ‐forced tropical Atlantic sector climate change (2021)
    AGU (American Geophysical Union) | Wiley
    Details
    Publication Date: 2024-02-07
    Description: Twenty-first-century climate change projections are uncertain, especially on regional scales. An important source of uncertainty is that climate models exhibit biases, which limits their ability to predict climate. One of the largest biases is the too warm sea surface temperature (SST) in the eastern tropical Atlantic (TA), reflecting deficient atmospheric and oceanic circulation. Here, we show that CO2-forced TA-sector climate changes simulated by state-of-the-art climate models exhibit a strong mean-state dependence. In particular, models simulating largest SST warming in the eastern TA, consistent with the warming observed since the mid-20th century, typically exhibit a more realistic mean state than models simulating largest warming in the western TA. The former models exhibit a larger climate sensitivity, and predict stronger and in part qualitatively different climate changes over the TA sector, for example in precipitation. These findings may help to reducing uncertainty in TA-climate change projections.
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    Impact of Chlorophyll Shading on the Peruvian Upwelling System (2021)
    AGU (American Geophysical Union) | Wiley
    Details
    Publication Date: 2024-02-07
    Description: The influence of chlorophyll shading on ocean dynamics has been usually disregarded in eastern boundary upwelling systems modeling studies in spite of their very high primary productivity. Here, we study how this effect impacts on the Peru upwelling system using a regional mesoscale-resolving physical biogeochemical coupled model. We show that the shading effect leads to a surface cooling of up to 1°C on the shelf due to subsurface cooling of the source waters during their transit toward the shelf. The shading effect leads to a more realistic subsurface stratification, a slowdown of the alongshore currents, and a shoaling of the oxycline. Impacts on the regional model biases show that the shading effect needs to be taken into account in both physical and coupled physical-biogeochemical regional models of upwelling systems.
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    Seismic Structure, Gravity Anomalies and Flexure Along the Emperor Seamount Chain (2021)
    AGU (American Geophysical Union) | Wiley
    Details
    Publication Date: 2024-02-07
    Description: The Hawaiian-Emperor seamount chain in the Pacific Ocean has provided fundamental insights into hotspot generated intraplate volcanism and the long-term strength of oceanic lithosphere. However, only a few seismic experiments to determine crustal and upper mantle structure have been carried out on the Hawaiian Ridge, and no deep imaging has ever been carried out along the Emperor seamounts. Here, we present the results of an active source seismic experiment using 29 Ocean-Bottom Seismometers (OBS) carried out along a strike profile of the seamounts in the region of Jimmu and Suiko guyots. Joint reflection and refraction tomographic inversion of the OBS data show the upper crust is highly heterogeneous with P wave velocities 〈4–5 km s−1, which are attributed to extrusive lavas and clastics. In contrast, the lower crust is remarkably homogeneous with velocities of 6.5–7.2 km s−1, which we attribute to oceanic crust and mafic intrusions. Moho is identified by a strong PmP arrival at offsets of 20–80 km, yielding depths of 13–16 km. The underlying mantle is generally homogeneous with velocities in the range 7.9–8.0 km s−1. The crust and mantle velocity structure has been verified by gravity modeling. While top of oceanic crust prior to volcano loading is not recognized as a seismic or gravity discontinuity, flexural modeling reveals a ∼5.0–5.5 km thick preexisting oceanic crust that is overlain by a ∼8 km thick volcanic edifice. Unlike at the Hawaiian Ridge, we find no evidence of magmatic underplating.
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    Foraminifera Iodine to Calcium Ratios: Approach and Cleaning (2021)
    AGU (American Geophysical Union) | Wiley
    Details
    Publication Date: 2024-02-07
    Description: Planktic and benthic foraminiferal iodine (I) to calcium (Ca) molar ratios have been proposed as an exciting new proxy to assess subsurface and bottom water oxygenation in the past. Compared to trace metals, the analysis of iodine in foraminiferal calcite is more challenging, as iodine is volatile in acid solution. Here, we compare previous analyses that use tertiary amine with alternative analyses using tetramethylammonium hydroxide (TMAH) and ammonium hydroxide (NH4OH) to stabilize iodine in solution. In addition, we assess the effect of sample size and cleaning on planktic and benthic foraminiferal I/Ca. Our stabilization experiments with TMAH and NH4OH show similar trends as those using tertiary amine, giving relatively low I/Ca ratios for planktic and benthic foraminifera samples from poorly oxygenated waters, and high ratios for well-oxygenated waters. This suggests that both alternative methods are suitable to stabilize iodine initially dissolved in acid. Samples that contain 5–10 specimens show a wide spread in I/Ca. Samples containing 20 specimens or more show more centered I/Ca values, indicating that a larger sample size is more representative of the average planktic foraminifera community. The impact of cleaning on planktic and benthic foraminifera I/Ca ratios is very similar to Mg/Ca, with the largest effect occurring during the clay removal step. The largest iodine contaminations were recorded at locations characterized by moderate to high organic carbon contents. In those circumstances, we recommend doubling the oxidative cleaning steps (4 instead of 2 repetitions) to ensure that all organic material is removed.
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    The medial offshore record of explosive volcanism along the central to eastern Aegean Volcanic Arc, part 2: Tephra ages and volumes, eruption magnitudes and marine sedimentation rate variations (2021)
    AGU (American Geophysical Union) | Wiley
    Details
    Publication Date: 2024-02-07
    Description: We use the tephrostratigraphic framework along the Aegean Volcanic Arc established in part 1 of this contribution to determine hemipelagic sedimentation rates, calculate new tephra ages, and constrain the minimum magnitudes of (sub)plinian eruptions of the last 200 kyrs. Hemipelagic sedimentation rates range from ∼0.5 cm/kyr up to ∼40 cm/kyr and vary laterally as well as over time. Interpolation between dated tephras yields an eruption age of ∼37 ka for the Firiplaka tephra, showing that explosive volcanism on Milos is ∼24 kyrs younger than previously thought. The four marine Nisyros tephras (N1 to N4) identified in part 1 (including the Upper (N1) and Lower (N4) Pumice) have ages of ∼57 ka, ∼63 ka, ∼69 ka, and ∼76 ka, respectively. Eruption ages for the Yali-1 and Yali-2 tephras are ∼55 ka and ∼34 ka, respectively. The Yali-2 tephra comprises two geochemically and laterally distinct marine facies. The southern facies is identical to the Yali-2 fall deposit on land but the western facies has slightly less evolved glass compositions. Overall, erupted plinian and co-ignimbrite fall tephra volumes range from 〈1 to 56 km3 (excluding possible caldera fillings and ignimbite volumes), and 80% of the eruptions had magnitude 5.5〈M≤7.2 (M=log(m)-7; m = erupted magma mass in kg). Twenty percent of the tephras represent 3.2〈M〈5.5 eruptions. The long-term average tephra magma mass flux through highly explosive eruptions of Santorini is estimated at ∼40 kg/s. The analogous data for the Kos-Yali-Nisyros volcanic complex is less-well constrained but similar to Santorini.
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    Crustal Thinning From Orogen to Back-Arc Basin: The Structure of the Pannonian Basin Region Revealed by P-to-S Converted Seismic Waves (2021)
    AGU (American Geophysical Union) | Wiley
    Details
    Publication Date: 2024-02-07
    Description: We present the results of P-to-S receiver function analysis to improve the 3D image of the sedimentary layer, the upper crust, and lower crust in the Pannonian Basin area. The Pannonian Basin hosts deep sedimentary depocentres superimposed on a complex basement structure and it is surrounded by mountain belts. We processed waveforms from 221 three-component broadband seismological stations. As a result of the dense station coverage, we were able to achieve so far unprecedented spatial resolution in determining the velocity structure of the crust. We applied a three-fold quality control process; the first two being applied to the observed waveforms and the third to the calculated radial receiver functions. This work is the first comprehensive receiver function study of the entire region. To prepare the inversions, we performed station-wise H-Vp/Vs grid search, as well as Common Conversion Point migration. Our main focus was then the S-wave velocity structure of the area, which we determined by the Neighborhood Algorithm inversion method at each station, where data were sub-divided into back-azimuthal bundles based on similar Ps delay times. The 1D, nonlinear inversions provided the depth of the discontinuities, shear-wave velocities and Vp/Vs ratios of each layer per bundle, and we calculated uncertainty values for each of these parameters. We then developed a 3D interpolation method based on natural neighbor interpolation to obtain the 3D crustal structure from the local inversion results. We present the sedimentary thickness map, the first Conrad depth map and an improved, detailed Moho map, as well as the first upper and lower crustal thickness maps obtained from receiver function analysis. The velocity jump across the Conrad discontinuity is estimated at less than 0.2 km/s over most of the investigated area. We also compare the new Moho map from our approach to simple grid search results and prior knowledge from other techniques. Our Moho depth map presents local variations in the investigated area: the crust-mantle boundary is at 20–26 km beneath the sedimentary basins, while it is situated deeper below the Apuseni Mountains, Transdanubian and North Hungarian Ranges (28–33 km), and it is the deepest beneath the Eastern Alps and the Southern Carpathians (40–45 km). These values reflect well the Neogene evolution of the region, such as crustal thinning of the Pannonian Basin and orogenic thickening in the neighboring mountain belts.
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    Dissolved Cd, Co, Cu, Fe, Mn, Ni and Zn in the Arctic Ocean (2021)
    AGU (American Geophysical Union) | Wiley
    Details
    Publication Date: 2024-02-07
    Description: During the Polarstern (PS94) expedition, summer 2015, part of the international GEOTRACES program, sources and sinks of dissolved (D) Cd, Co, Cu, Fe, Mn, Ni and Zn were studied in the central Arctic Ocean. In the Polar Surface Water in which the TransPolar Drift (TPD) is situated, salinity and δ18O derived fractions indicated a distinct riverine source for silicate DCo, DCu, DFe, DMn and DNi. Linear relationships between DMn and the meteoric fraction depended on source distance, likely due to Mn-precipitation during transport. In the upper 50 m of the Makarov Basin, outside the TPD core, DCo, DMn, DNi, DCd and DCu were enriched by Pacific waters, whereas DFe seemed diluted. DCo, DFe, DMn and DZn were relatively high in the Barents Sea and led to enrichment of Atlantic water flowing into the Nansen Basin. Deep concentrations of all metals were significantly lower in the Makarov Basin compared to the Nansen and Amundsen, the Eurasian, Basins. The Gakkel ridge hydrothermal input and higher continental slope convection are explanations for higher metal concentrations in the Eurasian Basins. Although scavenging rates are lower in the Makarov Basin compared to the Eurasian Basins, the residence time is longer and therefore scavenging can decrease the dissolved concentrations with time. This study provides a baseline to assess future change, and additionally identifies processes driving trace metal distributions. Our results underline the importance of fluvial input as well as shelf sources and internal cycling, notably scavenging, for the distribution of bio-active metals in the Arctic Ocean.
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    How Does the North Atlantic SST Pattern Respond to Anthropogenic Aerosols in the 1970s and 2000s? (2021)
    AGU (American Geophysical Union) | Wiley
    Details
    Publication Date: 2024-02-07
    Description: We show how changes in the global distribution of anthropogenic aerosols favor different spatial patterns in the North Atlantic sea-surface temperature (NASST). The NASSTs largely show the expected decrease associated with the anthropogenic aerosols in the 1970s, but also an unusual warming response in the eastern sub-polar gyre, the region of the North Atlantic warming hole. The NASST response reversed for the anthropogenic aerosols in the 2000s against 1970s. The regional reduction in anthropogenic aerosols favored as follows: (1) a strengthening of the warming hole and (2) a NASST increase at high latitudes associated with changes in the coupled atmosphere-ocean dynamics. We found that the gyre component of the northward Atlantic heat transport in mid-to high latitudes is an important driver for the heat convergence associated with the NASST patterns. At least two-thirds of the NASST response in MPI-ESM1.2 is associated with aerosol-cloud interactions, highlighting the need to better understand them. Key Points: - Anthropogenic aerosol patterns affect the coupled atmosphere-ocean dynamical response - 1970s to 2000s aerosol pattern change enhances North Atlantic warming hole through ocean meridional heat convergence by the sub-polar gyre - Most of the response to anthropogenic aerosols is associated with aerosol-cloud interactions
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    Glacial‐Isostatic Adjustment Models Using Geodynamically Constrained 3D Earth Structures (2021)
    AGU (American Geophysical Union) | Wiley
    Details
    Publication Date: 2024-02-08
    Description: Glacial-isostatic adjustment (GIA) is the key process controlling relative sea-level (RSL) and paleo-topography. The viscoelastic response of the solid Earth is controlled by its viscosity structure. Therefore, the appropriate choice of Earth structure for GIA models is still an important area of research in geodynamics. We construct 18 3D Earth structures that are derived from seismic tomography models and are geodynamically constrained. We consider uncertainties in 3D viscosity structures that arise from variations in the conversion from seismic velocity to temperature variations (factor r) and radial viscosity profiles (RVP). We apply these Earth models to a 3D GIA model, VILMA, to investigate the influence of such structure on RSL predictions. The variabilities in 3D Earth structures and RSL predictions are investigated for globally distributed sites and applied for comparisons with regional 1D models for ice center (North America, Antarctica) and peripheral regions (Central Oregon Coast, San Jorge Gulf). The results from 1D and 3D models reveal substantial influence of lateral viscosity variations on RSL. Depending on time and location, the influence of factor r and/or RVP can be reverse, for example, the same RVP causes lowest RSL in Churchill and largest RSL in Oregon. Regional 1D models representing the structure beneath the ice and 3D models show similar influence of factor r and RVP on RSL prediction. This is not the case for regional 1D models representing the structure beneath peripheral regions indicating the dependence on the 3D Earth structure. The 3D Earth structures of this study are made available.
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    Isoscape Models of the Southern Ocean: Predicting Spatial and Temporal Variability in Carbon and Nitrogen Isotope Compositions of Particulate Organic Matter (2021)
    AGU (American Geophysical Union) | Wiley
    Details
    Publication Date: 2024-02-14
    Description: Polar marine ecosystems are particularly vulnerable to the effects of climate change. Warming temperatures, freshening seawater, and disruption to sea-ice formation potentially all have cascading effects on food webs. New approaches are needed to better understand spatiotemporal interactions among biogeochemical processes at the base of Southern Ocean food webs. In marine systems, isoscapes (models of the spatial variation in the stable isotopic composition) of carbon and nitrogen have proven useful in identifying spatial variation in a range of biogeochemical processes, such as nutrient utilization by phytoplankton. Isoscapes provide a baseline for interpreting stable isotope compositions of higher trophic level animals in movement, migration, and diet research. Here, we produce carbon and nitrogen isoscapes across the entire Southern Ocean (〉40°S) using surface particulate organic matter isotope data, collected over the past 50 years. We use Integrated Nested Laplace Approximation-based approaches to predict mean annual isoscapes and four seasonal isoscapes using a suite of environmental data as predictor variables. Clear spatial gradients in δ13C and δ15N values were predicted across the Southern Ocean, consistent with previous statistical and mechanistic views of isotopic variability in this region. We identify strong seasonal variability in both carbon and nitrogen isoscapes, with key implications for the use of static or annual average isoscape baselines in animal studies attempting to document seasonal migratory or foraging behaviors.
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    Geochemical and Isotopic Evolution of Late Oligocene Magmatism in Quchan, NE Iran (2021)
    AGU (American Geophysical Union) | Wiley
    Details
    Publication Date: 2024-02-14
    Description: Magmatic activity that accompanied the collision between Arabia and Eurasia at ∼27 Ma, provides unique opportunities for understanding the triggers and magma reservoirs for collisional magmatism and its different styles in magmatic fronts and back-arcs. We present new ages and geochemical-isotopic results for magmatic rocks that formed during the collision between Arabia and Eurasia in NE Iran, which was a back-arc region to the main magmatic arcs of Iran. Our new zircon U-Pb ages indicate that collisional magmatism began at ∼24 Ma in the NE Iran back-arc, although magmatism in this area started in the Late Cretaceous time and continued until the Pleistocene. The collisional igneous rocks are characteristically bimodal, and basaltic-andesitic and dacitic-rhyolitic components show significant isotopic differences; εNd(t) = +4.4 to +7.4 and εHf(t) = +5.4 to +9.5 for mafic rocks and εNd(t) = +0.2 to +8.4 and εHf(t) = +3.4 to +12.3 for silicic rocks. The isotopic values and modeling suggest that fractional crystallization and assimilation-fractional crystallization played important roles in the genesis of felsic rocks in the NE Iran collisional zone. Trace element and isotopic modeling further emphasize that the main triggers of the magmatism in NE Iran comprise a depleted to the enriched mantle and the Cadomian continental crust of Iran. Our results also emphasize the temporal magmatic variations in the NE Iran back-arc from Late Cretaceous to Pleistocene.
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    Freshened Groundwater in the Sub-seafloor (2021)
    AGU (American Geophysical Union)
    Details
    Publication Date: 2024-06-12
    Description: Scientists are using a variety of geochemical, geophysical, and numerical methods to study offshore freshened groundwater and better understand its role in the global water cycle.
    Type: Article , NonPeerReviewed
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