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  • Books  (2)
  • Articles  (22,973)
  • 1980-1984  (22,975)
  • 1925-1929
  • 1983  (22,975)
  • Geosciences  (22,975)
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  • Books  (2)
  • Articles  (22,973)
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  • 1980-1984  (22,975)
  • 1925-1929
Year
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  • 1
    Unknown
    Oxford, London, Edinburgh, Boston, Melbourne : Blackwell Scientific Publications
    Keywords: Verwitterung
    Description / Table of Contents: Weathering Processes --- M. J. Wilson and D. Jones: Lichen weathering of minerals: implications for pedogenesis / Geological Society, London, Special Publications, 11:5-12, doi:10.1144/GSL.SP.1983.011.01.01 --- D. A. Spears: Porewater reactions in the unsaturated zone with special reference to groundwater quality in England / Geological Society, London, Special Publications, 11:13-18, doi:10.1144/GSL.SP.1983.011.01.02 --- David C. Cawsey and Paul Mellon: A review of experimental weathering of basic igneous rocks / Geological Society, London, Special Publications, 11:19-24, doi:10.1144/GSL.SP.1983.011.01.03 --- Kaolinites, Laterites and Bauxites --- H. Wopfner: Kaolinisation and the formation of silicified wood on late Jurassic Gondwana surfaces / Geological Society, London, Special Publications, 11:27-31, doi:10.1144/GSL.SP.1983.011.01.04 --- J. Esteoule-Choux: Kaolinitic weathering profiles in Brittany: genesis and economic importance / Geological Society, London, Special Publications, 11:33-38, doi:10.1144/GSL.SP.1983.011.01.05 --- A. Vincent: The origin and occurrence of Devon Ball Clays / Geological Society, London, Special Publications, 11:39-45, doi:10.1144/GSL.SP.1983.011.01.06 --- S. K. Monro, F. C. Loughnan, and M. C. Walker: The Ayrshire Bauxitic Clay: an allochthonous deposit? / Geological Society, London, Special Publications, 11:47-58, doi:10.1144/GSL.SP.1983.011.01.07 --- T. R. Marshall, B. J. Amos, and D. Stephenson: Base metal concentrations in kaolinised and silicified lavas of the Central Burma volcanics / Geological Society, London, Special Publications, 11:59-68, doi:10.1144/GSL.SP.1983.011.01.08 --- M. J. McFarlane: A low level laterite profile from Uganda and its relevance to the question of parent material influence on the chemical composition of laterites / Geological Society, London, Special Publications, 11:69-76, doi:10.1144/GSL.SP.1983.011.01.09 --- Ida Valeton: Palaeoenvironment of lateritic bauxites with vertical and lateral differentiation / Geological Society, London, Special Publications, 11:77-90, doi:10.1144/GSL.SP.1983.011.01.10 --- J. Esson: Geochemistry of a nickeliferous laterite profile, Liberdade, Brazil / Geological Society, London, Special Publications, 11:91-99, doi:10.1144/GSL.SP.1983.011.01.11 --- Red Beds --- R. Gardner: Reddening of tropical coastal dune sands / Geological Society, London, Special Publications, 11:103-115, doi:10.1144/GSL.SP.1983.011.01.12 --- K. Pye: Post-depositional reddening of late Quaternary coastal dune sands, north-eastern Australia / Geological Society, London, Special Publications, 11:117-129, doi:10.1144/GSL.SP.1983.011.01.13 --- B. M. Besly and P. Turner: Origin of red beds in a moist tropical climate (Etruria Formation, Upper Carboniferous, UK) / Geological Society, London, Special Publications, 11:131-147, doi:10.1144/GSL.SP.1983.011.01.14 --- Duricrusts: Calcretes, Silcretes and Gypcretes --- H. Wopfner: Environment of silcrete formation: a comparison of examples from Australia and the Cologne Embayment, West Germany / Geological Society, London, Special Publications, 11:151-158, doi:10.1144/GSL.SP.1983.011.01.15 --- W. J. E. van de Graaff: Silcrete in Western Australia: geomorphological settings, textures, structures, and their genetic implications / Geological Society, London, Special Publications, 11:159-166, doi:10.1144/GSL.SP.1983.011.01.16 --- M. A. Summerfield: Geochemistry of weathering profile silcretes, southern Cape Province, South Africa / Geological Society, London, Special Publications, 11:167-178, doi:10.1144/GSL.SP.1983.011.01.17 --- C. C. Reeves, Jr: Pliocene channel calcrete and suspenparallel drainage in West Texas and New Mexico / Geological Society, London, Special Publications, 11:179-183, doi:10.1144/GSL.SP.1983.011.01.18 --- Donald Carlisle: Concentration of uranium and vanadium in calcretes and gypcretes / Geological Society, London, Special Publications, 11:185-195, doi:10.1144/GSL.SP.1983.011.01.19 --- John Parnell: Ancient duricrusts and related rocks in perspective: a contribution from the Old Red Sandstone / Geological Society, London, Special Publications, 11:197-209, doi:10.1144/GSL.SP.1983.011.01.20 --- Colin F. Klappa: A process-response model for the formation of pedogenic calcretes / Geological Society, London, Special Publications, 11:211-220, doi:10.1144/GSL.SP.1983.011.01.21 --- A. S. Talma and F. Netterberg: Stable isotope abundances in calcretes / Geological Society, London, Special Publications, 11:221-233, doi:10.1144/GSL.SP.1983.011.01.22 --- F. Netterberg and J. H. Caiger: A Geotechnical classification of calcretes and other pedocretes / Geological Society, London, Special Publications, 11:235-243, doi:10.1144/GSL.SP.1983.011.01.23 --- R. P. Shaw: Karstic residual fluorite-baryte deposits at two localities in Derbyshire / Geological Society, London, Special Publications, 11:245-249, doi:10.1144/GSL.SP.1983.011.01.24 --- John A. Catt: Cenozoic pedogenesis and landform development in south-east England / Geological Society, London, Special Publications, 11:251-258, doi:10.1144/GSL.SP.1983.011.01.25
    Pages: Online-Ressource (258 Seiten) , Illustrationen, Diagramme, Karten
    ISBN: 063201072X
    Language: English
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  • 2
    Unknown
    Oxford, London, Edinburgh, Boston, Melbourne : Blackwell Scientific Publications
    Keywords: Erdöl ; Europa ; Geochemie
    Description / Table of Contents: J. Brooks: Introduction / Geological Society, London, Special Publications, 12:ix-xv, doi:10.1144/GSL.SP.1983.012.01.01 --- Geological and Geochemical Studies of Northwest European Continental Shelf --- P. J. Walmsley: The role of the Department of Energy in petroleum exploration of the United Kingdom / Geological Society, London, Special Publications, 12:3-10, doi:10.1144/GSL.SP.1983.012.01.02 --- A. Makourine: Gas Exploration and Reserves in Europe / Geological Society, London, Special Publications, 12:11-17, doi:10.1144/GSL.SP.1983.012.01.03 --- P. C. Barnard and B. S. Cooper: A Review of Geochemical Data Related to the Northwest European Gas Province / Geological Society, London, Special Publications, 12:19-33, doi:10.1144/GSL.SP.1983.012.01.04 --- J. L. Gevirtz, B. D. Carey, and S. R. Blanco: Surface Geochemical Exploration in the North Sea / Geological Society, London, Special Publications, 12:35-50, doi:10.1144/GSL.SP.1983.012.01.05 --- E. Faber and W. Stahl: Analytic Procedure and Results of an Isotope Geochemical Surface Survey in an Area of the British North Sea / Geological Society, London, Special Publications, 12:51-63, doi:10.1144/GSL.SP.1983.012.01.06 --- J. Sigalove: Petroleum Offshore Sniffer Exploration / Geological Society, London, Special Publications, 12:65, doi:10.1144/GSL.SP.1983.012.01.07 --- G. J. Candy: Petroleum Exploration Onshore U.K. / Geological Society, London, Special Publications, 12:67-68, doi:10.1144/GSL.SP.1983.012.01.08 --- T. P. Brennand: North Sea petroleum exploration / Geological Society, London, Special Publications, 12:69, doi:10.1144/GSL.SP.1983.012.01.09 --- Hans Rønnevik, Svein Eggen, and Jan Vollset: Exploration of the Norwegian Shelf / Geological Society, London, Special Publications, 12:71-93, doi:10.1144/GSL.SP.1983.012.01.10 --- D. C. Mudge and G. M. Bliss: Stratigraphy and Sedimentation of the Palaeocene Sands in the Northern North Sea / Geological Society, London, Special Publications, 12:95-111, doi:10.1144/GSL.SP.1983.012.01.11 --- C. D. Curtis: Geochemistry of Porosity Enhancement and Reduction in Clastic Sediments / Geological Society, London, Special Publications, 12:113-125, doi:10.1144/GSL.SP.1983.012.01.12 --- Hilary Irwin and Andrew Hurst: Applications of Geochemistry to Sandstone Reservoir Studies / Geological Society, London, Special Publications, 12:127-146, doi:10.1144/GSL.SP.1983.012.01.13 --- M. J. Pearson and D. Watkins: Organofacies and Early Maturation Effects in Upper Jurassic Sediments From the Inner Moray Firth Basin, North Sea / Geological Society, London, Special Publications, 12:147-160, doi:10.1144/GSL.SP.1983.012.01.14 --- M. J. Pearson, D. Watkins, J-L Pittion, D. Caston, and J. S. Small: Aspects of Burial Diagenesis, Organic Maturation and Palaeothermal History of an Area in the South Viking Graben, North Sea / Geological Society, London, Special Publications, 12:161-173, doi:10.1144/GSL.SP.1983.012.01.15 --- C. Cornford, J. A. Morrow, A. Turrington, J. A. Miles, and J. Brooks: Some Geological Controls on Oil Composition in the U.K. North Sea / Geological Society, London, Special Publications, 12:175-194, doi:10.1144/GSL.SP.1983.012.01.16 --- M. J. Fisher and Jennifer A. Miles: Kerogen Types, Organic Maturation and Hydrocarbon Occurrences in the Moray Firth and South Viking Graben, North Sea Basin / Geological Society, London, Special Publications, 12:195-201, doi:10.1144/GSL.SP.1983.012.01.17 --- R. H. Reitsema: Geochemistry of North and South Brae Areas, North Sea / Geological Society, London, Special Publications, 12:203-212, doi:10.1144/GSL.SP.1983.012.01.18 --- A. E. Griffith: The Search for Petroleum in Northern Ireland / Geological Society, London, Special Publications, 12:213-222, doi:10.1144/GSL.SP.1983.012.01.19 --- D. G. Roberts: Frontier exploration in Western and Northwest Europe / Geological Society, London, Special Publications, 12:223-224, doi:10.1144/GSL.SP.1983.012.01.20 --- Petroleum Exploration of Europe --- L. Mattavelli, T. Ricchiuto, D. Grighani, and M. Schoell: Origins of Natural Gas in the Po Valley, N. Italy / Geological Society, London, Special Publications, 12:227, doi:10.1144/GSL.SP.1983.012.01.21 --- M. Schoell and M. J. Whiticar: Isotope Geochemistry of Natural Gases in Central Europe / Geological Society, London, Special Publications, 12:229, doi:10.1144/GSL.SP.1983.012.01.22 --- K. Kuckelkorn, H. Wehner, and H. Hufnagel: Geochemical Observations and Oil Genesis in the German Alps and their foreland / Geological Society, London, Special Publications, 12:231-233, doi:10.1144/GSL.SP.1983.012.01.23 --- D. P. McKenzie: Basin Evolution and Hydrocarbon Generation / Geological Society, London, Special Publications, 12:253-254, doi:10.1144/GSL.SP.1983.012.01.25 --- B. Durand and M. Paratte: Oil Potential of Coals: A Geochemical Approach / Geological Society, London, Special Publications, 12:255-265, doi:10.1144/GSL.SP.1983.012.01.26 --- P. A. Schenck, J. W. de Leeuw, T. C. Viets, and J. Haverkamp: Pyrolysis-Mass Spectrometry in Coal Chemistry: a study of the coalification of vitrites and the typification of Australian Brown Coals / Geological Society, London, Special Publications, 12:267-274, doi:10.1144/GSL.SP.1983.012.01.27 --- D. J. Batten: Identification of Amorphous Sedimentary Organic Matter by Transmitted Light Microscopy / Geological Society, London, Special Publications, 12:275-287, doi:10.1144/GSL.SP.1983.012.01.28 --- P. M. R. Smith: Spectral Correlation of Spore Coloration Standards / Geological Society, London, Special Publications, 12:289-294, doi:10.1144/GSL.SP.1983.012.01.29 --- J. M. A. Buiskool Toxopeus: Selection Criteria for the Use of Vitrinite Reflectance as a Maturity Tool / Geological Society, London, Special Publications, 12:295-307, doi:10.1144/GSL.SP.1983.012.01.30 --- A. J. G. Barwise: Use of Porphyrins as a Maturity Parameter for Oils and Sediments / Geological Society, London, Special Publications, 12:309-315, doi:10.1144/GSL.SP.1983.012.01.31 --- Petroleum Geochemical Principles and Techniques --- D. H. Welte, M. A. Yükler, M. Radke, D. Leythaeuser, U. Mann, and U. Ritter: Organic Geochemistry and Basin Modelling — Important Tools in Petroleum Exploration / Geological Society, London, Special Publications, 12:237-252, doi:10.1144/GSL.SP.1983.012.01.24 --- Geological Information on Hydrocarbon Exploration on the U.K. Continental Shelf --- G. G. Baxter: Introduction / Geological Society, London, Special Publications, 12:319, doi:10.1144/GSL.SP.1983.012.01.32 --- D. J. McKay: The Compilation of an Earth Science Bibliography for the North Sea and Adjacent Areas / Geological Society, London, Special Publications, 12:321-328, doi:10.1144/GSL.SP.1983.012.01.33 --- P. Wigley: Commercially Available Geological Databanks—U.K.C.S. / Geological Society, London, Special Publications, 12:329-341, doi:10.1144/GSL.SP.1983.012.01.34 --- J. R. V. Brooks: Geological Information from Hydrocarbon Exploration on the United Kingdom Continental Shelf / Geological Society, London, Special Publications, 12:343-356, doi:10.1144/GSL.SP.1983.012.01.35 --- K. J. Chew and H. Stephenson: EXPHST—A Program to Analyse the History of Exploration Success within a Basin or Country / Geological Society, London, Special Publications, 12:357-371, doi:10.1144/GSL.SP.1983.012.01.36 --- G. G. Baxter: The Use of Computerized Information in Britoil, Exploration Division / Geological Society, London, Special Publications, 12:373, doi:10.1144/GSL.SP.1983.012.01.37
    Pages: Online-Ressource (XV, 379 Seiten)
    ISBN: 0632010762
    Language: English
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  • 3
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    Environmental geology 5 (1983), S. 1-8 
    ISSN: 1432-0495
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract The sorption of226Ra from oil-production brine by soils and sediments was investigated. Sorption was rapid, and the percentage sorbed increased with brine dilution. Greatest removals of226Ra from sediments in the laboratory occurred with alkaline DTPA, HCl, and BaCl2, with lesser removals using CaCl2 and NaCl solutions. Digestion of sediments with NaOCl indicates that most of the native and sorbed226Ra is associated with the mineral rather than organic fraction of the sediments. Correlation analysis based on 14 soils indicates that the retention of226Ra may involve precipitation reactions associated with sulfate-bearing minerals, as well as ion-exchange reactions with the clay mineral fractions of surficial earth materials.
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  • 4
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    Environmental geology 5 (1983), S. 11-18 
    ISSN: 1432-0495
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract The potential of certain agricultural activities for groundwater pollution has long been recognized. Intensification of agriculture, increases in land area devoted to arable crops, intensification of animal husbandry, and a move away from arable rotations toward monoculture have affected groundwater nitrate content and necessitate continued close monitoring of groundwater. Investigative techniques vary, and have included systematic collection of water quality data from the saturated zone of aquifers, determining solute concentrations in pore waters present in unsaturated zones overlying unconfined aquifers, and deep profiling of consolidated aquifers. Pore water has been analyzed for both chemical components and thermonuclear tritium. Studies continue throughout the world. The results of several of these from various countries are included in the Symposium.
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    Environmental geology 5 (1983), S. 19-25 
    ISSN: 1432-0495
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract Organic and inorganic materials brought into the soil by intensive agricultural activities are decomposed in the soil zone by chemical and biochemical effects and redox processes and will enter into the infiltration process in the form of dissolved ions. Water movement in the unsaturated and saturated infiltration zone is subject to the laws of hydrology, but the changes of dissolved material content are controlled by chemical and biochemical effects also subject to changes in the transport processes.
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    Environmental geology 5 (1983), S. 27-32 
    ISSN: 1432-0495
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract The state of the art of mathematical modelling of groundwater pollution by agricultural activities is well advanced at the present time and a large number of models are available for a wide variety of water pollution problems. Also a variety of computational methods are available from very simple ones to the most advanced. In general, there are two ways of obtaining a water quality model: “from below,” when water quality data based on actual observation or measurement are explicitly analyzed by the calculus; and “from above,” when the calculus is available in advance as a theory and the user tries to find its interpretation for a given case and from rather limited data. Classifications may be based on the type of modelled processes, the mathematical approach, or on the purpose of the models. Eleven papers were presented in the Symposium on this topic, with most of the models being of the dynamic type.
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  • 7
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    Environmental geology 5 (1983), S. 35-38 
    ISSN: 1432-0495
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract In recent years, considerable interest has been expressed in the nitrate content of water supplies. The most notable toxic effect of nitrate is infant methemoglobinemia. The risk of this disease increases significantly at nitrate-nitrogen levels exceeding 10 mg/l. For this reason, this concentration has been established as a limit for drinking water in many countries. In natural waters, nitrate is a minor ionic constituent and seldom accounts for more than a few percent of the total anions. However, nitrate in a significant concentration may occur in the vicinity of some point sources such as septic tanks, manure pits, and waste-disposal sites. Non-point sources contributing to groundwater pollution are numerous and a majority of them are related to agricultural activities. The largest single anthropogenic input of nitrate into the groundwater is fertilizer. Even though it has not been proven that nitrogen fertilizers are responsible for much of nitrate pollution, they are generally recognized as the main threat to groundwater quality, especially when inefficiently applied to irrigated fields on sandy soils. The biggest challenge facing today's agriculture is to maintain the balance between the enhancement of crop productivity and the risk of groundwater pollution.
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  • 8
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    Environmental geology 5 (1983), S. 39-48 
    ISSN: 1432-0495
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract Ireland has large water resources. Only 5.3% of developable waters are as yet developed, to supply some 650 I/day/per capita to the population of some 3.37 million people. State of development varies in each of the seven water resources regions. Precipitation is fairly evenly distributed over the year, but the percentage infiltrating to form groundwater varies quite sharply. Some 61% of infiltration occurs in the four winter months November to February, when agricultural activities are low. Only 10% infiltrates in the four summer months, May to August, when agricultural activities are high. In all, annual groundwater amounts to some 24.8 km3, of which 50% is considered to be recoverable. Capital groundwater reserves must be large, but are unquantified. Under these conditions, the impact of agriculture on groundwater quantities is negligible. Of the annual extraction of some 170 × 106m3 of groundwater, some 66 × 106m3/year are used in different agricultural activities. Drainage operations, however, have effects on Irish groundwater. Such lands may overlie impermeable strata or pans, or may receive concealed or visible groundwater discharge. Their drainage will affect the groundwater in various ways. There has been a considerable impact of agriculture on groundwater quality. The effects on the atmosphere and on precipitation are not identifiable. Effects of diffuse infiltration are treated with respect to: (a) application of ground limestone (lime); (b) application of K.N.P. inorganic fertilizer; (c) spreading of organic slurries; (d) development of organic nitrogen in soils, mainly after ploughing of grasslands; and (e) residues from herbicides, fungicides, and pesticides. The infiltration of these substances spread on the land is closely related to the interaction between times of ground-water recharge and times of fertilizer application. Effects of concentrated infiltration are treated under seven sub-heads: (a) infiltration of polluted surface waters; (b) localized farm infiltration; (c) concentrated waste disposal from feedlots; (d) concentrated waste disposal from silage; (e) concentrated waste disposal from agro-industries; (f) disposal through sinkholes and quarries; and (g) disposal by deep well injection. These operations are deliberate, and not related to times of groundwater recharge. They are often into the limestone aquifers, and so doubly dangerous.
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    Environmental geology 5 (1983), S. 61-64 
    ISSN: 1432-0495
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract High contents of nitrate in groundwater, ranging up to 1,500 mg/l, have been found. High concentrations are more common in village wells than in irrigation wells situated in the fields. The losses of nitrogen from the soil zone through deep leaching into the groundwater are small (260 kg N/km2); however, due to a small net infiltration (29 mm/year), the median content in groundwater still approaches the permissible limit of 50 mg/l NO 3 − . In villages about 10–20% of the nitrogen from excreta are leached into the groundwater. Mineralization of soil nitrogen during a dry period, followed by heavy rains, caused extremely high contents of nitrate in groundwater.
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    Environmental geology 5 (1983), S. 79-82 
    ISSN: 1432-0495
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract Lake Chicot is an oxbow lake located along the western side of the Mississippi River in southeastern Arkansas. A major flood in 1927, levee construction, land use changes from bottomland hardwood to agriculture, a large increase in drainage area, and stream channelization have altered the appearance of contributing watersheds and the lake. The lake often has high suspended sediment concentrations making it undesirable for recreation and aquatic production. As part of a coordinated study to determine changes in the lake, sediment accumulation patterns and rates were determined in Lake Chicot using the137Cs technique. Major sediment accumulation is occurring near the major inlet and along the thalweg of the oxbow. Average sediment accumulation of 1.8 cm/yr since 1963 was measured for twelve samples. Calculations show sediment accumulation is decreasing. This study has shown that the137Cs technique can provide useful planning information for the environmental geologist or reservoir manager. Results of the current study will be used to develop better sediment and water management strategies for Lake Chicot.
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    Environmental geology 5 (1983), S. 93-99 
    ISSN: 1432-0495
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    Topics: Geosciences
    Notes: Abstract Landslide risk can be assessed by evaluating geological conditions associated with past events. A sample of 2,4 16 slides from urban areas in West Virginia, each with 12 associated geological factors, has been analyzed using SAS computer methods. In addition, selected data have been normalized to account for areal distribution of rock formations, soil series, and slope percents. Final calculations yield landslide risk assessments of 〈0.50=low risk, 0.50 to 1.50=moderate risk, and 〉1.50=high risk. The simplicity of the method provides for a rapid, initial assessment prior to financial investment. However, it does not replace on-site investigations, nor excuse poor construction.
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    Environmental geology 5 (1983), S. 127-131 
    ISSN: 1432-0495
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    Topics: Geosciences
    Notes: Abstract The nematocide DBCP has been an effective chemical for the control of nematodes but, because of contamination of groundwaters and for health reasons, its use has been curtailed. To evaluate the tendency of DBCP to leach, adsorption and transport characteristics were examined on laboratory samples of a field soil through which the chemical was also leached. Adsorption of DBCP on Panoche clay loam was small, and displacement experiments in soil columns demonstrated that loading rate and flux of water were significant for the dissipation of the chemical by microbial degradation and/or volatilization. Dissipation rate constants were estimated by optimizing the fit to experimental BTCs of the convective-dispersion equation with linear adsorption and a first-order degradation rate. Although field measurements did not establish conclusively that leaching to groundwater would occur in a fine-textured soil, evidence was obtained that leaching below the root zone could occur in many soils.
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    Environmental geology 5 (1983), S. 103-113 
    ISSN: 1432-0495
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    Topics: Geosciences
    Notes: Abstract Eighty surface sediment samples taken in 1978 from Lake Geneva, together with two cores sampled in 1976 and 1980, and 30 samples (1978) from the Rhone River were analyzed for organochlorine compounds. DDT, its metabolites (DDE, TDE), HCB, and PCB were found. No other organochlorine compound was identified at the detection level of 0.5 ppb. DDT metabolites were widespread and indicated residual DDT sources in the Rhone watershed and other minor lake tributaries, particularly on the Swiss coast. DDT levels have declined since an apparent peak usage in 1957. HCB was found in almost all samples. It first appeared about 1962 with consistent usage to the present. Use is widespread with the major source being the Rhône River. PCB was found in all samples at levels comparable to levels in the North American Great Lakes. Sources appear to be diffuse urban/industrial, with major inputs on the Swiss shore between Vevey and Morges. Peak use of PCB occurred in 1972 and was followed by a decline to 1978, with some evidence for a second increase to 1980, the latest sample available. Both HCB and PCB were found at high levels in the most upstream samples of the Rhône River which may be indicative of substantial atmospheric loadings of these two compounds to the Lake Geneva Basin.
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    Environmental geology 5 (1983), S. 133-141 
    ISSN: 1432-0495
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract An iterative least-squares optimization technique is utilized in conjunction with a one-dimensional representation of the mass transport equation to generate theoretical210Pb concentration/depth profiles beneath the water-sediment interface that are best-fit approximations to directly measured210Pb concentration/depth profiles at various locations within the Great Lakes system. The outputs of such an optimization analysis are the diffusion coefficientsD M (molecular) andD B (bioturbation) associated with the transport of210Pb radionuclides in lake bed sediments. For all stations studied, the estimated values ofD B are consistently larger than the estimated values ofD M , emphasizing the importance of accounting for the effects of bioturbation in the modelling of contaminant transport through lake bed sediments.
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    Environmental geology 5 (1983), S. 143-149 
    ISSN: 1432-0495
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    Notes: Abstract Thirty two cores were collected from Lake Geneva sediments along one longitudinal and eight transverse profiles. Rates of sedimentation determined by137Cs vary from 0.01 to 1.86 g cm−2 y−1. The average deposition rates in coastal and slope areas amounts to 0.37 g cm−2 y−1 in the Upper Lake (Grand Lac) and 0.12 g cm−2 y−1 in the Lower Lake (Petit Lac). In the deep basins, average rates of 0.13 and 0.05 g cm−2 y−1 were found for the Grand Lac and Petit Lac, respectively. The estimated mass of sediment deposited yearly outside of the principal deltas and turbidity current depositional areas is about 1.0 million tons (about 13% of the estimated total river load). One turbidite is clearly identified in the deepest, central lake area. There is little variation of surface sediment texture (mean grain size about 8–9µm) with the exception of delta areas. Since the beginning of the twentieth century, both carbonate and organic matter have increased as a result of lake eutrophication.
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    Environmental geology 5 (1983), S. 169-176 
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    Notes: Abstract Analysis of well logs of Lake Baldeney, a reservoir of the Ruhr River, yields four facies factors that reflect the effect of anthropogenic processes on the sediment. First, the sedimentation rate is directly related to the subsidence caused by mining. The extent of the subsidence was such that the sediment load of the river could not compensate for the sinking of the lake bottom. Discharged sediment filled about one-fifth of the basin within 40 years. In certain areas of the basin the sedimentation rate reached up to 10 cm per year. Second, the grain-size distribution of the sediment was influenced by long-term and short-term events. During the subsidence, grain-size distribution remained relatively constant. The destruction of the Möhne River dam during World War II resulted in the presence of an extremely large grain size as evidenced by the so-calledMöhnelage. The filling of the lake after 1961 was accompanied by a continual increase in medium grain size. Third, until 1975, the mode of the lake sediment reflects the effect of mining in the vicinity of the lake. High coal content can be traced to its origin. The introduction of modern production processes, modernization of coal dressing, and hydraulic hauling is documented in the sediment. Finally, the heavy metal content of the sediment corresponds to the industrial development in the drainage area the Ruhr River. The accumulation of Cd reached an extreme concentration, exceeding the natural content by a thousand times. Variation in concentration reflects an increase in industrial production, as well as measures undertaken to restore water quality.
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    Notes: Abstract Lake Zürich occupies a glacially overdeepened perialpine trough in the northern Middlelands of Switzerland. A total of 154.4 m of Quaternary sediments and 47.3 m of Tertiary Molasse bedrock has been cored from the deepest part of the lake, some 10 km south of the city of Zürich. Some 16.8 m of gravels and sands directly overlying the bedrock include basal till and probably earliest subglacial fluvial and lacustrine deposits. These are overlain by 98.6 m of fine-grained, glacial-aged sediments comprising completely deformed proglacial and/or subglacial lacustrine muds, separated by four basal mud tills. The lack of interglacial sediments, fossils, and other datable material, and the presence of severe sediment deformation and unknown amounts of erosion prevent the establishment of an exact chronostratigraphy for sediments older than the upper mud till. Above it some 8.6 m of lacustrine muds were deposited, folded, faulted, and tilted during the final opening of the lake at about 17,500–17,000 years ago. Superimposed are 30.4 m of final Würm and post-glacial sediments comprising (from oldest): cyclic proglacial mud, thick-bedded and laminated mud, a complex transition zone, laminated carbonate, laminated marl, and diatom-calcite varves. These sediments reflect changing catchment and lacustrine conditions including: glacial proximity, catchment stability, lake inflow characteristics, thermal structure, chemistry, and bed stability. Average sedimentation rates ranged from 11 cm yr−1 immediately after glacier withdrawal, to as low as 0.4 mm yr−1 as the environment stabilized. The lack of coarse outwash deposits separating the fine-grained glaciolacustrine sediments from a corresponding underlying basal till suggests that deglaciation of the deep northern basin of Lake Zürich was by stagnation-zone retreat rather than by retreat of an active ice-front.
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    Environmental geology 5 (1983), S. 219-224 
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    Notes: Abstract The construction of reservoirs on large rivers in the USSR greatly influences the nature of adjacent areas. The water percolating into reservoir shores replenishes existing aquifers and creates new ones. The water volume formed in this way may be sometimes compared to the storage of the reservoirs. So seepage water is not lost; it remains in an artifically saturated zone and may be used for water supply and irrigation. The negative aspects are the waterlogging of adjacent areas, in topographic depressions, in particular, and soil salinization, especially in southern regions. The analysis and generalization of data on the groundwater regime formation in reservoir shore areas are useful for various branches of the national economy. The Ivankovo Reservoir on the Volga River having a long record of observations has been selected for the studies, which are discussed in this paper.
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    Environmental geology 5 (1983), S. 49-52 
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    Notes: Abstract The underground transport of pathogenic bacteria and viruses may be described by the general transport equation considering dispersion, adsorption, and biological elimination. The survival time of bacteria and viruses in groundwater is different for the specific species and for the specific groundwater environment. Dispersion causes a distribution of pollutants in time and space, thus their concentration decreases over time and with transport distance. Microorganisms are reversibly adsorbed on underground particles, which causes a retardation of their transport velocity with respect to groundwater flow velocity. An additional approach is provided by the filter theory.
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    Environmental geology 5 (1983), S. 53-59 
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    Notes: Abstract In Europe the Chalk constitutes a major source of potable water supply. Its outcrop forms extensive tracts of agricultural land, where the groundwater resources largely originate as infiltrating excess rainfall. Research on the unsaturated zone of the aquifer beneath such cultivated land should allow an assessment of nutrient leaching losses from the associated highly permeable soils and the prediction of future groundwater quality trends. Pore-water profiles for nitrate and numerous other constituents from a site of exceptionally detailed study are presented and compared to results from sites elsewhere in eastern England to demonstrate the impact of modern arable agriculture. Environmental isotopes have also been investigated in depth to aid the study. The problems in evaluating the evolution of the unsaturated zone profiles are discussed.
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    Environmental geology 5 (1983), S. 65-71 
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    Notes: Abstract The agricultural influence on the quality of the groundwater in Sweden is mostly associated with infiltration areas. The local conditions here determine the extent of the nitrate leakage. It is evident that certain combinations of factors in normal cropping can give unduly high nitrate concentrations in the groundwater.
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    Environmental geology 5 (1983), S. 73-78 
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    Notes: Abstract In a reconnaissance study, trace amounts of Cd, Cu, Pb, and Zn were determined in “A-zone” soil from 22 locations in the Dayton, Ohio, area. Soil samples were collected at high-volume air monitoring sites in urban, suburban, and rural areas. Measurable amounts of the elements were found in all of the samples. Positive correlations occur between each metal and particulate matter, with correlation coefficients of aboutr=0.70, at the 99% confidence level. Natural background values for the elements were measured in soil from rural areas. Theoretical background values, which are very close to those measured, were calculated from the individual regression equations. Natural background levels do not exceed 1.00 ppm Cd, 15 ppm Cu, 25 ppm Pb, and 55 ppm Zn. The heavy metal contents of most soils in the area exceed background by factors of up to 3.0 for Cd, up to 4.5 for Cu, up to 11 for Pb, and up to 4.5 for Zn. Significant positive correlations among the metals suggest a common source (or sources) for at least some, if not most, of the heavy metals. For the most part, the highest metal values are found in soils near coal-burning plants. Fly ash from a local plant contains substantial amounts of the elements. The high lead values are largely due to vehicular exhaust. However, there is evidence that the metals can also come from the normal deterioration of vehicles. It appears that airborne pollution is an important source of heavy metals in Dayton area soils.
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    Environmental geology 5 (1983), S. 167-168 
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    Environmental geology 5 (1983), S. 151-157 
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    Notes: Abstract Sedimentation rates were determined by210Pb in three sediment cores from the main basin of Lake Constance. Rates vary from 0.094 to 0.133 g cm−2y−1, in agreement with previous determinations. A constant radionuclide flux (CR) model reveals long-term, quasi-synchronous fluctuations of sedimentation rate on the basin-wide scale. On average, the rate of sedimentation remains much the same from the beginning of this century indicating little effect of human activity in the watershed on fine-silt sediment supply. The anthropogenic fluxes of Zn, Pb, and Cd in the three cores are compared and the application of210Pb as a heavy metal tracer in Lake Constance is examined. It seems to be a very good tracer for Pb, moderately good for Zn and Cu, and not useful for Cd.
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    Environmental geology 5 (1983), S. 177-190 
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    Notes: Abstract Lake Manitoba, North America's thirteenth largest lake, occupies a glacier-scoured basin in south-central Manitoba. Despite its large size, the lake is extremely shallow with a mean depth of 4.5 m. The lake can be subdivided into two connected but distinctly different basins: a small, irregular-shaped North Basin and a much larger and smoother South Basin. Most of the water inflow is from the Waterhen River (42% of the inflow) and from precipitation directly on the lake's surface (40%), while nearly 60% of the outflow is by evaporation. Lake Manitoba water is alkaline and brackish with the salinity dominated by sodium and chloride ions. The surficial offshore deposits of the main South Basin of the lake consist mainly of silt and clay-sized sediments composed of detrital components (clay minerals, quartz, carbonates, and feldspars) and endogenic/authigenic components (carbonates, sulfides, and organic matter). In addition to these modern sediments, several areas of relict fluvial-shoreline sand and till deposits occur in the South Basin. The lacustrine processes presently operating in Lake Manitoba reflect the influence of (1) the extreme shallow depth of the lake, (2) the basin morphology, and (3) the water chemistry. In addition, land clearing and increased watershed drainage have resulted in substantially increased sedimentation rates in the South Basin during the past century.
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    Notes: Abstract Two numerical models, one for the vadose zone and the other for the aquifer system, are utilized to predict nitrate pollution potential in groundwater. Transport by dispersion and convection of mobile species of nitrogen, ammonium ion exchange, first order nitrogen transformations, and nitrogen plant uptake are included in the formulation for the vadose zone. Transport of nitrate in the aquifer is assumed to be affected only by dispersion-convection phenomena. Justifications for one-dimensional conceptualization of flow in the vadose zone and two-dimensional representation for the aquifer, under various field conditions, are presented. To illustrate the concept, a simple hypothetical problem is solved. The approach presented here provides an efficient means of long-term simulation of large-scale field problems.
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    Environmental geology 5 (1983), S. 225-231 
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    Notes: Abstract Agriculture is a basic economic activity in the Canary Islands, a Spanish region in the Atlantic Ocean, facing the Sahara. The main crops are bananas, tomatoes, and other special ones suitable for exportation. Fertilizers are applied in high quantities on the scarce land available. The relatively good vertical permeability of the soils favors the deep infiltration of irrigation return flows. Water is obtained by an extraordinary net of shaft wells and water galleries, supplemented when possible by surface reservoirs in the deep gullies. Water is distributed by an extensive network of pipes and canals, allowing the transportation of water to virtually any point from any water source. Water quality is widely variable, from almost rain water to brackish, with a high frequency of sodium bicarbonate types. Return flows, especially when water is applied with good irrigation techniques and the original quality is poor, are saline and contain chemicals leached from the fertilizers. On Tenerife Island, most of the return flows go to coastal aquifers, while most of the water comes from high-altitude water galleries. Agricultural pollution is not generally appraised, but it exists. It can be masked by the frequent, high natural nitrate content in groundwater. On Gran Canaria Island, since water comes mainly from deep shaft wells near the irrigated areas, the nitrate pollution is much more clear. On La Palma Island, besides the nitrate pollution, a potassium pollution of agricultural origin has been mentioned. Other situations on the remaining islands are also discussed. It can be concluded that agriculture is a big concern for the water quality in many areas and impairs its suitability for other uses. Because of the great depth of the water table, the nitrate pollution may not become obvious for many years, especially for the deep-water galleries.
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    Environmental geology 5 (1983), S. 9-9 
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    Environmental geology 5 (1983), S. 33-34 
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    Notes: Abstract By the twenty-first century, the world population will be 9 billion, double its present total. This raises significant questions regarding the ability to feed, clothe, and shelter this population and at what cost to the earth, especially to groundwater quality. Various studies continue on the effects of drainage works and irrigation on groundwater, some of the results of which are reported in this Symposium.
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    Environmental geology 5 (1983), S. 83-92 
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    Notes: Abstract Recent field studies of postglacial volcanic deposits at Glacier Peak indicate the volcano has erupted more often, more voluminously, and more recently than previously thought. These past eruptions produced pyroclastic flows, extensive lahars, and widely distributed tephra falls. Analysis of the magnitude of past eruptions and the distribution of volcanic sediments indicates that future eruptions at Glacier Peak as large as those of the last several thousand years would dramatically affect people and property downstream and downwind from the volcano. Pyroclastic flows and lateral blasts would primarily affect uninhabited valleys within a few tens of kilometers of the volcano. Lahars and floods constitute the major hazard to populated areas from future eruptions, and could affect areas at low elevation along valley floors and in the Puget lowland as far as 100 km downvalley west of the volcano. Air-fall tephra from future eruptions will probably be deposited primarily east of Glacier Peak because of prevailing westerly winds.
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    Environmental geology 5 (1983), S. 101-102 
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    Environmental geology 5 (1983), S. 115-126 
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    Notes: Abstract Rates of shoreline change and overwash penetration distances were calculated for barrier islands along the Louisiana, Mississippi, and Alabama coasts with the orthogonal grid mapping system (OGMS). Average rates of shoreline change are exceptionally high in Louisiana, being of the order −4.7 to −7.4 m yr−1. Mississippi and Alabama recession rates are lower and range from −2.0 to −3.1 m yr−1 over the period of record. Erosion rates along the shorelines of these islands have remained relatively constant over the period of study with five exceptions in coastal Louisiana and the Chandeleur-Breton Islands Arc, and two exceptions along the Mississippi-Alabama barrier islands where they have accelerated. Mean overwash penetration is greatest along Dauphin Island, Alabama, and Cat Island, Mississippi: 207.6 and 197.9 m, respectively. The Chandeleur-Brenton Islands Arc range from 88.1 m at the central barrier to 180.4 along the flanks. The Mississippi islands range from 105.2 m on Ship Island to 200.5 m along central Horn Island. Mean overwash penetration along the Louisiana barriers is highly variable: 46.3 to 211.4 m.
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    Environmental geology 5 (1983), S. 159-165 
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    Notes: Abstract Industrial expansion in the harbor areas of Antwerp has altered environmental conditions to a great extent. This study examines the relation between the water economy of the port of Antwerp docks and the composition of dock waters, sediments, and interstitial waters, with emphasis on trace metals and chlorides. Some conclusions are reached as to the possible use of the dredged deposits in agriculture.
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    Environmental geology 5 (1983), S. 207-212 
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    Notes: Abstract The content and distribution of nitrate in groundwater and surface water in the Karup Basin area have been investigated and analyzed. In addition to existing analyses, chemical profiles of the groundwater of the upper part of the water table sand aquifer were measured at a number of sites. The profiles indicate, in general, an upper oxidation zone with nitrate and a lower reduction zone free of nitrate. However, below plantation areas, the nitrate content in the oxidation zone is significantly low as well. The eight profiles are graphed separately, and all results are finally plotted on a single map by a graphic method that takes into consideration both the concentration and the level of the sampled water. The great variation in the nitrate content of the water from one water-supply well to another can easily be explained by plotting the values on maps using this graphing procedure, in conjunction with an examination of the nitrate zonation found in the profiles. The influence of agricultural activities is significantly related to the concentration of nitrate in surface water and groundwater under such water table conditions and circumstances as are found in the Karup Basin.
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    Mineralium deposita 18 (1983), S. 133-133 
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    Mineralium deposita 18 (1983), S. 173-190 
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    Notes: Abstract Whole-rock samples of the Merensky Unit were analysed for major elements, Cu, Ni, Cr, Co, Eu, Th, U, Cs, and the platinum-group elements Pt, Pd, Rh, Ir and Au. There is a sympathetic variation of Cu, Ni, Co, and S throughout the sequence. Th and U abundances are highest around the Merensky Reef, and their distribution in the rest of the unit reflects the amount of mesostasis. Eu distribution is governed by primary plagioclase. Pt, Pd, Rh, Ir and Au (PM) are concentrated in the Merensky Reef. The relative proportions throughout the unit are Ir〈Rh〈Pd⪕Au〈Pt. Au, Pd, Pt are depleted upwards in the plagioclase-rich part of the unit. Except for Ir, the PM correlate with Th and U at lower PM levels. The PM are highly intercorrelated and there is considerable variation in the individual ratios. The distribution of trace elements in the Merensky Unit was governed by the growth rates of the primary silicates. At low abundances the PM behave as incompatible elements, together with late S. At higher concentrations the primary S content controls PM abundances. Residual liquid compositions computed from a marginal-facies analysis show parallel FeO and SiO2 enrichment trends; interaction of these trends resulted in the Merensky Reef and its attendant mineralization.
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    Description / Table of Contents: Abstract Granodioritic rocks from the stock of Quellaveco, their surrounding rhyolites and a subvolcanic dyke give K-Ar ages between Paleocene and lower Eocene, with an “mean age” of 53.7 M.Y. These results agree with those of other porphyry-copper deposits in the South-Western USA, in Northern Chile, and, which have been generated during Laramian orogenesis. Furthermore, no significant age difference between the pluton and the basement, have been observed, is interpreted as indicative of a consanguineous origin for both rock types.
    Notes: Résumé Les âges K-Ar des roches granodioritiques du stock de Quellaveco, des rhyolites encaissantes et d'un dyke subvolcanique sont compris entre le Paléocène et le début de l'Eocène, avec un “âge moyen” de 53.7 M.A. Ces résultats concordent avec ceux obtenus pour bon nombre d'autres porphyres cuprifères du Sud-Ouest des Etats Unis et du Nord du Chili qui ont été formés au cours de l'orogenèse Laramienne. De plus, il n'y a quasiment pas de différence entre l'âge du substratum et celui de l'intrusif, ce qui semble indiquer que ces roches sont cogénétiques.
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    Notes: Abstract Platinum-group minerals (PGM) have been identified as inclusions in chromite from the Bird River Sill, Manitoba. The inclusions are small (〈20 microns) and are commonly euhedral. The PGM inclusions are (Ru, Os, Ir) S2, laurite, and (Os, Ir, Ru alloy), rutheniridosmine: Laurites contain up to 2.99 wt. % palladium. Arsenic content is negligible and no platinum or rhodium has been detected. One platinum-group element alloy contains 0.96 wt. % rhodium but neither platinum nor palladium has been detected. Laurite inclusions in chromite from the ultramafic zone record two compositional trends; first increasing and then decreasing Ru/(Ru+Os+Ir) up section. PGM inclusions and other solid inclusions occur as discrete phases in chromite and are part of the chromite precipitation event. Increasing oxygen fugacity by wall rock assimilation or new magma injection initiates chromite precipitation, locally increasing the sulphur content of the magma to convert PGE alloys to sulphides.
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    Mineralium deposita 18 (1983), S. 27-38 
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    Notes: Abstract Samples of a brecciated sulphide vein (marcasite, sphalerite and scarce galena, in a calcite gangue), and its gossan, were collectet from bore holes. The gossan consists dominantly of goethite alternating with lepidocrocite and hydrohematite in a type of boxwork structure. Lead and manganese oxides are present. The gossan contains about 0.6% zinc and 0.2% lead. Sequential selective extractions and electron microprobe analyses were carried out. Soils with anomalous values in lead and zinc lying adjacent to the gossan contain fragments of ferruginous material which possess dimensions ranging from hundreds of microns to several centimeters. The textures, mineralogy and trace element contents of the fragments resemble those of limonites from the gossan. Mineralogical and selective analyses on the gossan and the soil materials show mineralogical and geochemical analogies. Lead and zinc anomalies can be explained partly by the occurrence of limonitic microfragments in the anomalous soils. The origin of these fragments is related to the disaggregation of the gossan. Already evoked by others authors for mainly non-carbonate environments, the results weight to the hypothesis that the dispersion of lead and zinc is partly mechanical.
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    Notes: Abstract At least seven different types of ore bodies, with an ore stock of Ba, F, Fe, Pb, Zn, Cu and Sb occur in Paleozoic rocks (Lower-Middle Cambrian and Ordovician) in an ≃15 km2 area north of the Narcao village (SW Sardinia, Italy). The ore bodies are related both to syngenetic accumulations, and later epigenetic recirculation of the primary ores. In the Lower Cambrian the area studied shows evidence of synsedimentary tectonic instability, probably related to carbonate shelf margin features. The Upper Cambrian is lacking and the transgressive Ordovician sediments cover large areas of the previously gently folded Cambrian rocks (Sardic phase of Caledonian orogenesis). The main Hercynian tectonic phases had a much stronger compressive folding that is mirrored in a sequence of tight folds and upthrusts. The geometric setting resulting from the tectonic frame of the Cambrian and Ordovician sediments must be taken into account to understand the distribution and the genesis of most of the ore bodies.
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    Description / Table of Contents: Résumé Les indices manganésifères des collines Blafo et Guéto sont rencontrés dans les quartzites et les schistes sériciteux associés aux épanchements rhyolitiques d'une série volcano-sédimentaire birrimienne. La minéralisation, épigénétique, est une imprégnation d'oxydes de fer (goethite) et de manganèse (essentiellement MnO2-cryptomélane et nsutite), surimposée à une paragénèse initiale à magnétite, pyrophanite et localement ottrélite et grenat. L'altération météorique n'a provoqué de transformations notables que dans les matériaux associés à deux surfaces d'aplanissement. L'une est conservée sous forme de petits témoins bauxitisés au sommet des collines et des minerais enrichis sont associés à la gibbsite et la kaolinite. L'autre est un glacis de piémont et le manganèse s'y disperse dans une cuirasse ferrugineuse.
    Notes: Abstract Manganese-bearing occurrences of the Blafo-Guéto hills are present in quartzites and sericite schists with associated rhyolites, belonging to a Birrimian volcanic-sedimentary series. An initial assemblage made up of magnetite, pyrophanite and locally ottrelite and garnet is affected by a subsequent epigenetic mineralization in form of an impregnation of iron and manganese oxides (mainly goethite, cryptomelane and nsutite). Only in the materials associated with two different landsurfaces, the weathering produced important and significant alterations. The first surface is represented by small bauxitised remnants at the top of the hills; enriched ore is then associated with kaolinite and gibbsite. The second surface is a piedmont pediment where a ferruginous crust contains low-grade manganese mineralization.
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    Mineralium deposita 18 (1983), S. 113-125 
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    Notes: Abstract The mineralogy and chemistry of oxidate facies sediments associated with a Solomon Island cupriferous pyrite deposit are described. Systematic variations in sediment composition are consistent with the gradual imposition of an oxidising environment on a pool of exhaled solution lying in a topographic depression on the sea floor. Manganese is first precipitated in the Mn2+ oxidation state as pyrochroite, γMn(OH)2. With later seafloor weathering and diagenesis, this oxidises initially to the Mn3+ intermediate minerals manganite (γMnO.OH) or, in the presence of iron hydroxides, to groutite (αMnO.OH). Subsequently, these oxidise further to Mn4+ as the βMnO2 dimorphs pyrolusite or ramsdellite, respectively. Todorokite (δMnO2) is indicative of more oxidising conditions and is found in the upper horizons of the manganiferous sediment. It is invariably non-stoichiometric in composition and its Mn2+/Mn4+ ratio is a direct function of the Eh prevailing during its precipitation. Adsorption of Na+, K+, Ca2+ and Ba2+ions at the time of formation stabilises the todorokite structure and provides an explanation for its persistence (with its Mn2+ions) in association with the completely oxidised Mn4+ mineral, βMnO2, pyrolusite. The enrichment of Cu, Zn and Pb in manganiferous sediments from both pelagic and exhalative environments is associated with the occurrence of goethite. The enrichment of K, Ba and Ca in manganiferous sediments from a similar range in environments is associated with the occurrence of todorokite. Both the mineralogy and trace element characteristics of a manganiferous sediment are thus a function of the environment of deposition rather than the ultimate source of the metals concerned. The trace element contents of manganiferous “floaters” should therefore only be used as an indicator of related sulphide mineralisation in the presence of other favourable factors.
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    Notes: Abstract Continental red beds are the host rocks of a characteristic style of mineralization which suggests a genetic link between red bed formation and ore formation. Samples of unmineralized and mineralized Triassic sediments from Central England have been studied sedimentologically, petrographically and geochemically with the aim of clarifying this link which may provide valuable guides for exploration. On the basis of sedimentological and petrographic observations it is suggested that these red beds were formed as a result of diagenetic alteration whereby detrital silicates and oxides are progressively dissolved and the iron released is deposited as hematite. A model for mineralization is proposed involving the release of trace metals from detrital minerals during diagenesis, their retention in saline interstitial solutions, migration to suitable sites of precipitation and deposition by reaction with trapped hydrocarbons or reduced sulphur.
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    Mineralium deposita 18 (1983), S. 379-386 
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    Description / Table of Contents: Abstract Fluid inclusions in calcites sampled in a Pb-Zn mineralized vein in East Belgium are characterized by a large dispersion of filling temperatures Th (30°C to more than 360°C) and by two groups of freezing points Tf2 (−14°C and −21°C). Boiling has not been proved. According to the still unexplained dispersion of the filling temperatures, this study does not permit an estimation of the depth of the ore formation. Nevertheless, fluid inclusions thermometric properties make possible the distinction between calcites associated with a mineralization (from the fertile locality of Poppelsberg) and calcites from sterile area (Belle Roche, Th=150°C, Tf2 variable around a mode of −8°C).
    Notes: Résumé Les inclusions fluides des calcites prélevées dans un filon plombo-zincifère dans l'Est de la Belgique montrent une grande dispersion des températures d'homogénéisation Th (30°C à plus de 360°C) et sont caractérisées par deux types de températures de fin de fusion Tf2(−14°C et −21°C). L'ébullition n'a pu être démontrée. En raison de la dispersion des températures d'homogénéisation non expliquée à ce jour, la profondeur de mise en place du gisement reste difficile à estimer. Toutefois, les propriétés thermométriques des inclusions fluides permettent de distinguer les calcites issues d'un site fertile (Poppelsberg) des calcites provenant d'un site stérile (Belle Roche, Th=150°C, Tf2 variable avec un mode à −8°C):
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    Mineralium deposita 18 (1983), S. 411-421 
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    Notes: Abstract In the western part of the Rheinisches Schiefergebirge geochemical investigations were carried out on Paleozoic black shales and carbonates in the Aachen region. Primary and secondary metal distributions were determined in selected units of sedimentary rocks by XRF-analysis and in stream sediments by AAS-analysis. The primary geochemical pattern and the results of geological studies reveal that Frasnian (Upper Devonian) black shales and nodular limestones were deposited in a restricted environment under euxinic conditions of a swell and basin facies. Black shales and nodular limestones are enriched in Zn and Cu resp., possibly indicating stratiform sulphide mineralization. Geochemical anomalies in stream sediments with increased values of Pb, Zn, Cd, Cu, Co, and Ni were found in areas of Lower Paleozoic sedimentary rocks and associated acid intrusives which are known to contain low grade sulphide mineralization of the “porphyry copper-type”.
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    Mineralium deposita 18 (1983), S. 1-1 
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    Mineralium deposita 18 (1983), S. 39-55 
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    Notes: Abstract The genesis of the Sullivan orebody is reviewed in terms of current concepts of stratiform ore formation. The source of metals and sulfur, the environment and time of ore formation, and the imprint of subsequent metamorphic events are explained in terms of a model which views the ore as one component of a chemical and clastic sequence formed within a rift basin above a thermal anomaly. Classic primary sedimentary structures are displayed in both the chemical (sulfide) and the clastic (silicate) rocks. Fractures and breccia zones beneath the western section of the mine provided passage-ways for boron and metal-rich sulfur-poor brines. Sulfides formed when the metals combined with reduced marine sulfur. The pattern of metal zoning is a reflection of the location of brine vents. The boron-rich solutions produced the tourmaline alteration zone. The sodium-rich brine produced albite within the ore sequence and in the hanging wall perhaps by the modification of analcite. The manganese variation of sulfide minerals between ore bands and laminations reflect changes in the chemistry of solutions during sedimentation and some degree of partitioning during metamorphism. The metamorphism has modified both the sulfide and silicate assemblages.
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    Mineralium deposita 18 (1983), S. 3-15 
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    Notes: Abstract The Deer Lake Complex, located in north-central Minnesota, consists of a series of layered peridotite-pyroxenite-gabbro sills. Sulfide minerals occur as fine disseminations throughout pyroxenite and gabbro units, and occur more sporadically in peridotite and basal chilled margin units. Sulfide volume percentage rarely exceeds 0.5. A distinct zonation in sulfide mineralogy and sulfur isotopic composition characterizes the sills. Cobaltian pentlandite is the dominant sulfide mineral in peridotite (pd) units, with Ni-enrichment most likely linked to the serpentinization process. δ34Spd values are variable, ranging from −3.5 to +2.8‰. Sulfide assemblages in pyroxenite (px) and lower gabbro units consist of chalcopyrite, pyrrhotite, and minor pentlandite. δ34Spx values range from −1 to +1 ‰. Pyrite is the principal sulfide mineral in upper gabbro (μg) units. Its origin may be related to increased f02 conditions of the remaining melt and to reaction between a S-bearing volatile phase and mafic silicates. δ34Sug values range from 1 to 3.5 ‰. Sulfur isotopic values of chilled margin (2–9 ‰) and peridotite units, together with the erratic spatial distribution of sulfide minerals in these zones, suggests that the parent magma was not initially saturated with sulfur, and that local sulfide concentrations are the result of incorporation of sulfur derived from metasedimentary country rocks. Sulfide saturation was more uniformly reached during pyroxenite formation, with contained sulfur being of magmatic origin. Enrichment in 34S of pyrite from upper gabbro may be explained by buildup of isotopically heavy sulfur following a Rayleigh process, coupled with possible involvement of a SO2-rich fluid phase during hydrothermal alteration.
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    Mineralium deposita 18 (1983), S. 89-97 
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    Notes: Abstract A comprehensive study of alteration minerals, especially clays, developed around or within French hydrothermal uranium ore bodies (Vendée and Margeride), generally associated with leucogranitic rocks, using optical examinations, classical methods of clay mineralogy and electron microprobe determinations, demonstrates the general feature of potassic minerals as products of reaction between ore forming fluids and host rocks. Six stages of alteration follow the typical metallogenic sequence established for numerous deposits: early stages and uranium stages 1) 2) 3) with phengites, illite, mixed layered illite and K-montmorillonites; 4), early reworking of pitchblende 1 to pitchblende 2 with complex zoning around ores: illite, illite-K-montmorillonites; 5) then to coffinite-smectites; 6) sooty pitchblende, during supergene weathering, with smectites and kaolinite. Potassic metasomatism by fluids in desequillibrium with the minerals of the granitic host rocks, essentially albite, explains the complex alterations in K-smectites, mixed layered minerals and adularia. Variety of alteration products in each alteration zone indicate incomplete reactions of the solids and chemical potential gradients on a small scale.
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    Mineralium deposita 18 (1983), S. 129-130 
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    Mineralium deposita 18 (1983), S. 134-134 
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    Mineralium deposita 18 (1983), S. 161-171 
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    Description / Table of Contents: Résumé Des minéralisations epigénétiques à plomb-zinc cuivre d'age tertiaire existent dans la couverture carbonatic mesozoïque du Haut-Atlas oriental (Maroc) tandis que les minéralisations à stibine, barytine et cuivre sont localisés dans le socle d'age précambrien à paleozoique. Les mesures du rapport isotopique du carbone dans les roches carbonatées encaissantes varie de +3‰ à -1‰ PDB. Les resultats sont caracteristiques d'un carbone d'origine marine. Il n'y a pas de differences entre les dolomies encaissantes et les veines dolomitiques plus récents. Dans les mêmes échantillons la composition isotopique de l'oxygène est enrichie en isotope O16 (variant de -3‰ à -11‰ PDB) par rapport à cette des carbonates en equilibre avec l'eau de mer. On suppose que la composition isotopique a changé au cours de la minéralisation ces phénomènes étant lié à la migration d'eaux connèes de la formation en partie diluis par des eaux météoriques. On estime que la soufre des sulfures syngénétiques reduits bacteriologiquement et des sulfates marins du Mesozoïque remobilisés durant l'orogénèse tertiaire sont les sources de H2S et SO4. On estime que des sulfates du Cambro-Ordovicien constituent la source pour les gîtes des Jebel Zelmou dans le socle. La composition isotopique du plomb des galènes dans les gîtes tertiaires de la couverture mesozoique est rigoureusement homogéne. Les ages varient de 230 à 180 Ma. On considére que des processus de remobilisation importants sont à l'origine de la metallogénèse tertiaire au Maroc.
    Notes: Abstract Tertiary epigenetic lead ± zinc and copper mineralizations occur in the Mesozoic carbonate cover and stibnite, barite and copper mineralization in the Precambrian to Palaezoic basement in the Eastern High Atlas, Morocco. The carbon isotope data from host carbonates range from +3 to -1‰ PDB. The data are typical for marine carbon. There is no difference between surrounding dolomites and younger vein dolomites. The oxygen isotopic composition of the samples is enriched in 16O; the range is from -3 to -11‰ PDB with respect to that of carbonates in equilibrium with marine water. It is postulated that the isotopic composition was changed during dolomitization being caused by transition of connate formation waters diluted to some degree by meteoritic water. The bacteriogenically reduced sulphur from syngenetic sulphides and Mesozoic marine sulphate mobilized during Tertiary orogenesis are thought to be the source of H2S and SO4. Cambro-Ordovicien sulphate is also supposed to be the source of sulphur in the Jebel Zelmou barite deposit in the basement. Isotopic composition of lead from galenas in the Tertiary deposits from the Mesozoic cover are strikingly homogenous. Model ages vary between 230–180 Ma. It is suggested that important mobilization processes are responsible for Tertiary metallogeny in Morocco.
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    Mineralium deposita 18 (1983), S. 215-233 
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    Notes: Abstract Bedded marine sedimentary phosphate rocks of Campanian-Maastrichtian age are exposed in the Western Desert of Iraq, forming part of the Tethyan phosphate province. The studied phosphorites are found in three horizons within carbonate rocks; they are mostly pelletal in texture, associated with bone fragments and detrital quartz grains, and cemented by calcite or chert. The mineralogy of the phosphate is dominated by carbonate-fluorapatite. The phosphate and the associated carbonate rocks are relatively enriched with Cr, Ni, Cu, Zn, V, and organic matter. The apatite is enriched with isotopically light carbon and heavy sulfur. The mode of phosphorite formation seems to have included syngenetic deposition of phosphate under reducing, slightly alkaline conditions in shallow marine environment. Decomposition of organic phosphatic remnants appear to have been the local source of phosphorus enrichment. However, the major tectonic and paleogeographic development of the Tethys Sea during Upper Cretaceous have probably played an important role in providing suitable setting for large scale formation of phosphorite.
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    Mineralium deposita 18 (1983), S. 285-297 
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    Notes: Abstract The S-isotope composition (δ34SCDT) of 213 samples of sulfides, sulfates and native sulfur from the pyrite mineralizations of southern Tuscany and associated country rocks were determined. The sulfur isotopic composition of pyrite is quite homogeneous and similar for all studied ore bodies, with an average δ34S value near +9,5‰. Pyrite disseminated within the Filladi di Boccheggiano formation, and thought to be authigenic, shows a much larger range of δ34S values (-13.1 to +14.5‰). The isotopic compositions of other sulfides associated with pyrite in the deposits show that isotopic equilibrium among sulfides was approached on a regional scale, but seldom fully attained. Isotopic data suggest that sedimentary marine sulfate was the ultimate source of sulfur in ores. Sulfates (mostly anhydrite) from the sulfate-carbonate lenses associated with both the Filladi di Boccheggiano and the Calcare Cavernoso formations also have similar and homogeneous compositions (average δ34S=+15–16‰). Coexisting sulfates and sulfides are not in isotopic equilibrium. In the light of the isotopic data, among the many proposed genetic models for the largest stratabound pyrite bodies the two following alternatives appear the most likely: 1) in agreement with recently suggested hypotheses, the ore bodies are older than the emplacement of the Mio-Pliocenic granitoids in the area, and are probably hydrothermal-sedimentary in origin, coeval with associated country rocks; 2) the ore bodies were formed as a consequence of bacterial reduction of anhydrite in low-temperature convection systems related to the early stages of the Mio-Pliocenic thermal anomaly. In both cases, the emplacement of the Mio-Pliocenic granitoids caused metamorphism and remobilization of the pre-existing ores, producing smaller discordant mineralized bodies.
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    Mineralium deposita 18 (1983), S. 437-442 
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    Description / Table of Contents: Abstract Microprobe analysis of mineralisations from the district of Hualgayoc, Peru, shows a zonation of sphalerite compositions all around a rhyodacitic body. The differences in the iron content of sphalerites in veins inside the rhyodacite and in sedimentary strata may be explained by a contamination of the hydrothermal solutions by those strata.
    Notes: Résumé L'étude analytique ponctuelle à la microsonde électronique des minéralisations du district de Hualgayoc, Pérou, montre une zonalité de composition des sphalérites autour d'un pluton rhyodacitique. Les différences de teneur en fer entre les filons internes au pluton et les filons liés aux couches sédimentaires voisines sont interprétées comme un phénomène de contamination du fluide hydrothermal par ces couches.
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    Mineralium deposita 18 (1983), S. 543-543 
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    Notes: Abstract The Blazna-Guset mining area is located in the Rodna Mountains, Eastern Carpathians, North Romania. It is mostly covered by the metamorphic rocks of the Rebra Series (Upper Precambrian; K/Ar dating gave 800 m.y.). The middle part of this series — called the Carbonate Formation — contains lead-zinc pyrite ores hosted by prevailingly carbonate rocks. The ores form flat and thin lenses occurring together with fine intercalations of silicate-, graphite- and quartz-bearing rocks within the calcite-dominated limestones. Pyrite, ironpoor sphalerite and galena are the main ore minerals. Chalcopyrite, pyrrhotite and magnetite also occur in small amounts. Within the highly deformed and partly recrystallized parts of the ore bodies bournonite, arsenopyrite and pearceitepolybasite were locally encountered. Ba, Ti and Mn are the most significant ore-accompanying elements.
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    Mineralium deposita 18 (1983), S. 529-534 
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    Notes: Abstract The contents of silver and mercury in 323 spots on gold grains from seven localities of the Witwatersrand palaeo-placer and Archaean vein deposits from Barberton were measured using an electron microprobe. The objective was to obtain information on the extent of gold alteration during fluvial transport and post-depositional geological processes. The results, however, show that Ag and Hg are distributed homogeneously in the gold grains studied. No indications were found that the gold was transported in solution nor that leaching took place in an oxidizing fluvial environment. This strongly suggests that the Ag and Hg contents in Witwatersrand gold grains represent geochemical ‘fingerprints’ inherited from their eroded primary sources. Combined analysis for Ag and Hg in Witwatersrand gold grains by electron microprobe can therefore be a valuable tool in establishing the types of primary sources for the gold.
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    Mineralium deposita 18 (1983), S. 535-541 
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    Notes: Abstract On the basis of the Cu:Zn:Pb ratios, the Tsunokakezawa no. 1 orebody is classified as a ‘B’ (black) Kuroko ore sub-type. With the exception of zirconium the distribution of base metals and certain trace elements through the stratigraphy of the orebody is as expected in Kuroko deposits. Zirconium shows its highest concentration in the barite zone, which can be accounted for by lower flow rates of hydrothermal fluid during barite formation compared to those during massive sulfide ore formation.
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    Mineralium deposita 18 (1983), S. 315-333 
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    Notes: Abstract Numerous scheelite-mineralized areas have been located in the Caledonian fold belt of Central East Greenland (70° – 74 1/2° N). The fold belt comprises Archaean and Proterozoic metamorphic complexes flanked by Late Proterozoic and Lower Palaeozoic sediments, and intruded by Upper Proterozoic and Caledonian granitic rocks. Scheelite mineralization occurs in: marble-skarns in Upper Proterozoic metasediments often spatially associated with Caledonian or older granitic intrusives; skarns and quartz veins in Late Proterozoic sediments (Lower EBG quartzite) up to 7 km from outcropping Caledonian granites; veins in fault zones cutting late Proterozoic sediments (Upper EBG limestones). In this paper, the three types are described with emphasis on structural setting, mineralogy and trace-element chemistry. It is concluded that most scheelite mineralization is associated with Caledonian igneous activity, either at or near granite contacts or as mineralization distal to granites at depth. Of the various types described, the scheelite veins in Late Proterozoic limestone are considered to be of the best economic potential.
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    Mineralium deposita 18 (1983), S. 423-434 
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    Notes: Abstract The idealized prototype of a southern Tuscan antimony deposit can be described as follows: The irregular mineralization is situated in the upper part of the highly porous Calcare Cavernoso, overlain by an impermeable unit, normally a flysch-type rock. The deposits are bound to the edge of horst positions and also to areas of elevated geothermal gradient and resulting hydrothermal activity. These observations were used as variables for statistical probability calculations for antimony-deposit formation. Within the areas determined to be of high probability, 47 target areas were selected for geochemical soil sampling. Positive correlation of antimony with barium, strontium and lead, corresponding to gangue and accessory ore minerals in the deposit was found. Local distribution of Sb of 3 representative areas are discussed in detail. Although no high anomalies so far unknown were identified, known mineralizations were extended or neighbouring anomalies found. Regional correlation with horst structures and especially their fault margins (e.g. eastern margin of the ridge of Monticiano) was confirmed. The high density of mineralizations in the Tafone area is also reflected in the geochemical results of the soil sample prospection. A possible explanation for this accumulation may be seen in the large outcrops of pre-Carboniferous rocks, which generally are expected to be the primary source of antimony. From these pre-Variscan units antimony was remobilized and transported hydrothermally to its present position.
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    Mineralium deposita 18 (1983), S. 235-243 
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    Notes: Abstract The isotopic ratios of Pb have been determined from 33 galena samples collected from a variety of occurrences in the north Eifel and north Sauerland. On the basis of the data presented, it is not possible to distinguish between the isotopic characteristics of galena-Pb from veins, carbonate cavity-filling and sandstone-hosted disseminated mineralisation in the north Eifel. In the north Sauerland, Saxonian (late Mesozoic-Tertiary) disseminated Pb mineralisation in Cretaceous-Tertiary sediments is generally more radiogenic than Saxonian vein mineralisation in Paleozoic country rocks. Variscan vein-type mineralisation (Ramsbeck, Ebbe Mountains) proved to have the least radiogenic Pb. The results are discussed in terms of potential sources of the Pb, and are compared to other data reported from European deposits.
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    Mineralium deposita 18 (1983), S. 267-283 
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    Description / Table of Contents: Abstract Since its formation in earliest Cambrian time, the St-Honoré alkaline complex has fractured into large subhorizontal slabs under the effect of magmatic pulsations and thermal contraction. These slabs were rapidly segmented and cracked by the same stresses. The secondary permeability resulting from these fractures first aided the circulation of the rare earth mineralizing hydrothermal fluids in the center of the complex, and then, after the unroofing of the complex, instigated the development of a karstic drainage system within the carbonatites of the complex. The accumulated sediments in the karstic caverns derive from the periodic inwashing of the insoluble residues built up on the surface of erosion, were indurated after the sealing of the karstic openings with calcareous muds during the Ordovician transgression, and were faulted with their cover when the Saguenay graben formed. The last event, marked by low temperature regional mineralizating circulation (barite and calcite crystals coating geodes at NIOBEC), permitted the establishment of a new subterrean drainage system.
    Notes: Résumé Dès sa formation au tout début du Cambrien, le complexe alcalin de St-Honoré s'est fracturé en grandes plaquettes subhorizontales sous l'effet des pulsations magmatiques et de la contraction thermique. Ces plaquettes se sont ensuite rapidement segmentées et fendillées suite aux mêmes contraintes. La perméabilité secondaire résultant de toutes ces fractures a d'abord favorisé la circulation hydrothermale minéralisatrice en terres rares au centre du complexe puis, après la dénudation du complexe, le développement d'un drainage karstique dans les carbonatites du complexe. Les sédiments accumulés dans les cavernes karstiques proviennent du lessivage périodique des résidus d'altération météoritique concentrés à la surface d'érosion, se sont indurés après que la transgression ordovicienne eut recouvert les ouvertures karstiques de boues calcaires, et ont été faillés avec leur couverture lors de la formation du graben du Saguenay. Ce dernier événement, marqué par une circulation minéralisante de basse température (barytine et calcite dans les géodes de la mine NIOBEC), a permis la naissance d'un nouveau drainage souterrain.
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    Mineralium deposita 18 (1983), S. 17-25 
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    Description / Table of Contents: Abstract The sulphur isotope composition of 233 sulphides and 40 sulphates has been investigated and evaluated in combination with 29 earlier published data. The total variation of δ34S values for the sulphides and the sulphates ranges from −40 up to −1 ‰ and from +7 up to +20 ‰, respectively. For the mineral species the variations are (with number of samples in brackets): galena (96) −32 up to −2 ‰, sphalerite (141) −30 up to −4 ‰, marcasite (16) −27 up to −1 ‰, pyrite (10) −26 up to −13 ‰, molybedenite (3) −40 up to −29 ‰, anhydrite and gypsum (8) +15 up to +20 ‰, coelestine (1) +19 ‰, and barite (33) +7 up to +18 ‰. The frequency distribution of the δ34S values corresponds with the complexity of the ore forming processes which resulted in six strata-bound ore mineralizations. The sulphate values clearly show that the sulphate sulphur originates from sea water sulphate. The sulphides are formed by bacteriogeneric processes from seawater sulphate, and their sulphur isotope composition depends on the lithofacies of the sediments as well as on the following diagenetic processes.
    Notes: Zusammenfassung Von der Blei-Zinklagerstätte Bleiberg (Kärnten, Österreich) wurden 233 Sulfide und 40 Sulfate auf ihre Schwefelisotopenzus ammensetzung untersucht und zusammen mit 29 bereits bekannten Daten ausgewertet. Die δ34S-Werte der Sulfide liegen im Bereich von −40 bis −1 ‰. Für die einzelnen Mineralarten wurde gefunden (jeweilige Probenanzahl in Klammern): Galenit (96) −32 bis −2 ‰, Sphalerit (141) −30 bis −4 ‰, Markasit (16) −27 bis −1 ‰, Pyrit (10) −26 bis −13 ‰, Molybdänit (3) −40 bis −29 ‰, Anhydrit und Gips (8) +15 bis +20 ‰, Cölestin (1) +19 ‰ und Baryt (33) +7 bis +18 ‰. Die Häufigkeitsverteilung der δ34S-Werte charakterisiert die Komplexität des Vererzungsvorganges. Sechs schichtgebundene Vererzungsabläufe vom Unterkarn bis zur Basis des Nor zeigen bei den Sulfaten nur geringe Variation. Die Herkunft des Sulfatschwefels aus dem Meerwasser ist daraus ableitbar. Die Sulfide sind durch bakteriogene Prozesse abgeschieden worden und ihre Schwefelisotopenzusammensetzung erscheint sowohl von der Lithofazies der Karbonatsedimente als auch von späteren diagenetischen Prozessen abhängig.
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    Notes: Abstract Studies of the compositions of coexisting sulphide assemblages from certain Zambian Copperbelt deposits and of their textural relations and host rock environments have been undertaken by routine microscopy and using electron microprobe analysis. Special attention has been paid to sulphide assemblages containing cobalt. Using experimental data on the systems Cu-Co-S, Cu-Fe-Co-S and on sulphidation equilibria, together with the available information on equilibria involving gangue minerals and some new calculations, an attempt has been made to define the chemical conditions of ore formation and/or re-equilibration in several deposits (Baluba, Chibuluma West and Chibuluma, Chambeshi S.E.). If a re-equilibration temperature of 300°C is assumed the range of aS2 prevailing during final formation of the assemblages was of the order 10−7 – 10−9 atm, more rarely dropping to 10−11 – 10−12 atm. If magnetite is present, and this is considered very unlikely in most cases, aO2 may have reached as high as 10−35 atm but it is generally likely to have been around 10−50 atm or even lower. Values of aCO2 are assumed to have been of the order of 10−0.5 atm. Detailed studies of drill hole samples from the Chambeshi S.E. deposit suggest an important link between the petrology of the host rocks and the sulphide mineral chemistry. In particular, the control exerted on sulphide composition by aS2 may have been related to the availability of sulphate in the form of diagenetic anhydrite or in sulphate-rich interstitial waters. The distinctive distribution of cobalt in the ores appears related to the distribution of amphibolite bodies and in turn to rift fault systems in the Basement which allowed upward movement of fluids enriched in magmatically derived cobalt.
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    Mineralium deposita 18 (1983), S. 131-133 
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    Mineralium deposita 18 (1983), S. 299-299 
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    Mineralium deposita 18 (1983), S. 257-265 
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    Description / Table of Contents: Abstract The main manganese oxides of oceanic nodules: todorokite and birnessite, are considered as regular solutions of MnO2 and MnO. Thermodynamic properties of regular solutions are used for the calculation of Gibbs energies ΔG° of these oxides and of their equilibrium constants of precipitation by oxidation from Mn2+ of sea water. From equilibrium diagram representation it is possible to distinguish the different manganese oxide forms, when looking at Mn2+ activity and pE: Mn2+ variations in sea water originates mainly from hydrothermal springs and diagenetic fluxes, while pE variations reflects the transient states during oxide rehandling. This solid state transformations defines a pE-buffer.
    Notes: Résumé Les principaux oxydes de manganèse des nodules océaniques: todorokite et birnessite, sont envisagés comme des solutions simples de MnO2 et MnO. Les propriétés thermodynamiques de celles-ci sont utilisées pour calculer les énergies standard de Gibbs ΔG° de ces oxydes et les constantes d'équilibre de leur réaction de précipitation par oxydation du Mn2+ de l'eau de mer. L'interprétation des diagrammes d'équilibre conduit à penser que la formation d'un de ces oxydes sera déterminé par deux facteurs: l'activité du Mn2+ et le pE. Les variations des teneurs en Mn2+ seront la conséquence d'un apport tel que source hydrothermale ou flux diagénétique par exemple. Les variations de pE seront dues à une réaction d'équilibration entre les différents oxydes; ces transformations à l'état solide agissent comme un tampon pE.
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    Mineralium deposita 18 (1983), S. 299-300 
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    Mineralium deposita 18 (1983), S. 477-485 
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    Topics: Geosciences
    Notes: Abstract The Tyndrum Pb+Zn veins, hosted by late Proterozoic quartzites, were probably generated in the Tournaisian (360 Ma). By determination of sulphur isotopic ratios of vein minerals three aspects of the Tyndrum mineralization were addressed, (i) sulphate sulphur sources; (ii) reduced sulphur source; (iii) isotopic equilibrium in the vein system including geothermometry. Twelve galenas have δ34S values ranging from +3.55 ‰ to +6.38 ‰ (this excludes one value of +11.21 ‰ from a large but nearly barren quartz vein). Other sulphides are enriched or depleted in 34S in the sense expected for isotopic equilibrium although there is no evidence for isotopic equilibrium between the vein minerals. The sulphide sulphur source was probably in the Dalradian metasediments where disseminated pyrite averages +6 ‰. Baryte had δ34S values averaging 14 ‰ and was therefore not in isotopic equilibrium with sulphides: a continental groundwater source is most likely.
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  • 72
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    Notes: Abstract Fe-sulfides associated with Belgian Pb-Zn vein deposits have been analysed by DC arc spectrometry and XRF for Tl, Ni, Co, Mn, Zn, Pb, Ge, Cd, and As. They show high Tl contents (from 〉30 ppm upt to 6800 ppm) and Co:Ni ratios 〈1. These features permit to distinguish them from Fe-sulfides of sedimentary and high temperature occurrences. The Tl distribution in a botryoidal marcasite of Vedrin (average Tl content of 0.68%) has been investigated by ion microprobe. It displays a pattern similar to colloform texture. Principal component analysis shows that the behaviour of Tl is partly controlled by a factor opposing Tl to all other elements. This is interpreted as reflecting the influence of sorption mechanisms by contrast with direct precipitation. Tl and the other elements are not considered of magmatic origin because no acidic magmatism is known during or after Variscan times. Extraction from sedimentary rocks by hydrothermal brines is favoured.
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  • 73
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    Description / Table of Contents: Résumé De nombreux indices et anciennes exploitations de faible tonnage pour Pb-Zn-Ba-F s'observent dans les séries carbonatées du Dévonien moyen et supérieur du SW du Synclinorium de Dinant où elles délimitent un district métallifère. Une étude lithogéochimique régionale des calcaires givétiens montre le faible potentiel métallifère de ces sédiments de plateforme. Ces résultats sont confirmés par l'étude de la distribution de 13 éléments présents dans un filon et son encaissant immédiat. Enfin la comparaison des compositions isotopiques du Pb des galènes du filon et du Pb en trace dans les calcaires encaissants apporte des arguments décisifs. Ces résultats sont suffisants pour rejeter l'hypothèse de l'origine des métaux par sécrétion latérale et militent en faveur du caractère “épigénétique-étranger” de ces minéralisations.
    Notes: Abstract Numerous vein mineralizations occur in the carbonate series of the Middle and Upper Devonian located in the Pb-Zn (F-Ba) metalliferous district of the South border of the Dinant Synclinorium. A regional lithogeochemical study (major and trace elements) of the Givetian limestones reveal the low potential of heavy metals in these platform sediments. These results are confirmed by the distribution of 13 elements present in a vein mineralization and its close surrounding. Finally, the comparison of the isotopic composition of the lead in the galenas of the vein mineralization and the traces of lead in the host rocks add decisive important arguments. These results seem to be sufficient to reject the hypothesis of the origin of the metals by lateral secretion and are in favor of an “epigenetic-foreign” character for these mineralizations.
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    Mineralium deposita 18 (1983), S. 135-160 
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    Notes: Abstract Copper mineralisation is associated with rocks of basic/intermediate composition which occur as a widespread swarm of relatively small irregularly-shaped bodies within the gneissic terrain of the Okiep District. These basic rocks comprise the so-called Koperberg noritoid suite of Namaqualand and constitute one of the three major copper producers in South Africa. While a metasomatic origin was briefly favoured for the noritoids, most researchers have emphasized the cross-cutting nature of the noritoids relative to their host rocks and prefer an origin involving magmatic injection. High noritoid 87Sr/86Sr initial ratio values indicated to some workers that mobilisation of suitable crustal materials was more attractive than intrusion of mantle-derived melts to account for the origin of the noritoid suite. The present study has shown that the structure, texture and mineralogy of the noritoids do not lend themselves to interpretation of the noritoids as pristine intrusive rocks, and indicate that the noritoids have undergone high-grade metamorphism after emplacement. The geochemistry of the noritoid suite reveals a pronounced alkaline affinity and mineralogical control of the chemistry characterises the rocks as cumulates. The dimensions of the noritoids appear unfavourable for development of cumulate rocks and it is considered possible that the present configuration of the noritoids results from dismemberment of larger intrusive bodies as a result of shear deformation during high-grade metamorphism. It has not been possible to identify a magma parent to the noritoid suite, but we believe the parent to have been an alkaline mantle-derived magma which suffered contamination by granitic anatects in the lower crust. Recognition of the metamorphic history of the Namaqualand noritoids renders a comparison between them and the Caraiba noritoids of interest.
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    Mineralium deposita 18 (1983), S. 191-206 
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    Description / Table of Contents: Abstract The physico-chemical parameters (pH, Eh, T, conductivity, alkalinity) of thirty one water samples have been measured within the Yeelirrie uraniferous calcrete channel (46000 tons of estimated U3O8). The major element (Ca++, Mg++, Na+, K+, SO 4 -- , Cl-) and some trace element (Cr, Co, Ni, Pb, Ti, Cu, Si, Zn, Ba, Sr, F, V, U) concentrations of nineteen water samples have been also measured. The results of the Wateq program traitment of most of this datas are in general in agreement with the channel mineralogy. Most dissolved elements, and in particular the necessary elements to the ore deposit formation, barring vanadium, are concentrated by a fast maturation waters process in relating to arid climate. In some time, the water pH increase and the Eh decrease. The V4+ is removed dating probable vanadiferous concentrations near the ore body by slightly oxydising waters. The installation of a redox front between a supersaturated ground water upstream a barrier structure and more oxidizing waters penetrating in a primary palustrine limestone provoke the V4+ to V5+ oxidation. The dolomitization of this limestone have for consequence the CO 3 -- ion activity decreasing who induce the decomplexation of uranyle carbonate ions and thus the U6+ supply. Then, the carnotite may precipitate. Thus, the climate, the hydrology and the morphology appear like the controls of Yeelirrie type ore deposit.
    Notes: Résumé Les paramètres physico-chimiques (pH, Eh, T, conductivité, alcalinité) des eaux de 31 puits ont été mesurés dans le chenal du calcrete uranifère de Yeelirrie (46000 tonnes d'U3O8 estimées). Les concentrations en éléments majeurs (Ca++, Mg++, Na+, K+, SO 4 -- , Cl-) et en certains éléments traces (Cr, Co, Ni, Pb, Ti, Cu, Si, Zn, Ba, Sr, F, V, U) ont été dosées dans les eaux de 19 puits. Les résultats du traitement par le programme Wateq, de la plupart de ces données, sont dans l'ensemble en accord avec la minéralogie du chenal. La plupart des éléments dissous et en particulier les éléments nécessaires à la formation du gîte, à l'exception du vanadium, se concentre par un processus rapide de maturation des eaux lié au climat aride. Parallèlement, le pH des eaux augmente et l'Eh diminue. Le V4+ est mis en solution à partir, vraisemblablement, de préconcentrations vanadifères proches du gîte par des eaux peu oxydantes. L'installation d'un front d'oxydo-réduction entre une nappe sursaturée en sels dissous, peu oxydante en amont d'une structure verrou et des eaux plus oxydantes arrivant dans un calcaire palustre primaire provoque l'oxydation du V4+ en V5+. La dolomitisation de ce calcaire amène la baisse de l'activité de l'ion CO 3 -- qui induit la décomplexation des ions uranyles carbonatés et ainsi l'apport de l'uranium 6+. La carnotite peut alors précipiter. Ainsi, le climat, l'hydrologie et la morphologie apparaissent-ils comme les contrôles des minéralisations de type Yeelirrie.
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    Mineralium deposita 18 (1983), S. 443-455 
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    Notes: Abstract Analyses of platinum-group elements (PGE) in rocks collected from the Voikar-Syninsky ophiolite in the Polar Urals suggest that the distribution and geochemistry of PGE in this Paleozoic ophiolite are similar to those in Mesozoic ophiolites from elsewhere. Chondrite-normalized PGE patterns for chromitite, the tectonite unit, and ultramafic and mafic cumulate unit have negative slopes. These results are similar to those found for chromitites from other ophiolites; stratiform chromities show positive slopes. If the magmas that form both types of chromitite originate from similar mantle source material with respect to PGE content, the processes involved must be quite different. However, the distinct chondrite-normalized PGE patterns may reflect differing source materials.
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  • 77
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    Description / Table of Contents: Résumé Les intrusions de rhyolites et de microgranites de la région d'Ain-Barbar (massif de l'Edough — Cap de Fer, Algérie) sont recoupées par des veines à minéralisation polymétallique (Fe-Cu-Zn-Pb) et ont subi des altérations hydrothermales corrélables à cet épisode de métallisation. Leur datation par la méthode K-Ar a été entreprise pour préciser l'âge de cet événement. Les mesures effectuées donnent des “âges” conventionnels compris entre 15 et 16 M.A., avec deux “âges isochrones” à 15.1 et 16.0 M.A. L'âge le plus ancien pourrait correspondre à la mise en place des intrusions microgranitiques, ainsi qu'à celle de l'un des filons rhyolitiques. L'âge le plus jeune, obtenu sur deux autres filons rhyolitiques est à la fois celui de leur mise en place intrusive et des altérations hydrothermales qui les affectent; c'est aussi celui des altérations hydrothermales subies par les intrusions plus anciennes. Ces mesures confirment que le magmatisme du massif de l'Edough — Cap de Fer s'est produit à la fin du Burdigalien et au Langhien, et montrent que les phénomènes hydrothermaux ont suivi immédiatement les épisodes d'intrusion. Elles permettent en outre de préciser l'âge de la dernière phase de plissements importants dans cette région.
    Notes: Abstract The Ain-Barbar district (Edough — Cap de Fer massif, northeastern Algeria) displays numerous microgranitic plugs and several rhyolitic dykes. These intrusives are cross-cut by polymetallic ore veins (Fe-Cu-Zn-Pb), and are hydrothermally altered in association with the mineralization. K-Ar measurements were carried out in order to determine the age of this event. Measurements gave conventional “ages” in the interval 15 to 16 M.Y., as well as two “isochron ages”, respectively at 15.1 and 16.0 M.Y. The 16.0 M.Y. age could be representative for the intrusion of microgranites, and one of the rhyolitic dykes. The 15.1 M.Y. one is clearly the age of the intrusion for two other rhyolitic dykes, and is coeval with the age of their hydrothermal alteration. The 15.1 M.Y. age is equally the one for the hydrothermal alteration affecting previous intrusive rocks. These results are compatible with previous data concerning magmatic events within the Edough — Cap de Fer massif. They show that hydrothermal process occurred very close after the end of intrusion in the Ain-Barbar district. They give also indirect evidence for the age of the last folding event in the area.
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    Mineralium deposita 18 (1983), S. 435-435 
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    Acta crystallographica 39 (1983), S. 269-269 
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    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Notes: All exp (-i2πζ, exp(-iπζ/2), exp(-iπζ and exp(-i3πζ/2) in equations (21) in Onoda, Saeki & Kawada [Acta Cryst. (1980). A36, 952-957] are mis-expressed and to be replaced respectively by exp(i2πζ), exp (iπζ/2), exp (iπζ) and exp (i3πζ/2).
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    Acta crystallographica 39 (1983), S. 282-286 
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    Notes: A partially analytic technique for the calculation of electron transmission functions used in multislice calculations is developed. This development utilizes the fact that atomic scattering amplitudes are generally available as fitting parameters to four Gaussians. The result is especially applicable to calculations with a large or infinite repeat distance in the incident-beam direction and initial test calculations give a time saving of a factor of four. Sample results are given for the calculation of images from an inclined stacking fault in gold.
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    Acta crystallographica 39 (1983), S. 326-332 
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    Notes: A comparison is made of the treatments of absorption in the theories of secondary extinction by Werner [J. Appl. Phys. (1974), 45, 3246-3254] and by Becker & Coppens [Acta Cryst. (1974), A30, 129-147]. The Werner approach treats absorption and extinction together, whereas Becker & Coppens assume a prior correction for absorption, and make an approximate allowance for the effect of absorption on the extinction by modifying the parameter representing the effective crystal dimension. By consideration of the form of the corrections for a specially simple crystal shape, it is shown that the Becker & Coppens method predicts slightly greater extinction than does the unified treatment of Werner. However, the difference is small, and likely to be unimportant in practice The Werner solution of the Hamilton-Zachariasen transfer equations is exact, but not easy to use. The Becker & Coppens results are approximate, but they are presented in a form convenient for computation.
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    Acta crystallographica 39 (1983), S. 377-387 
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    Notes: Generalized relations relating multipole population parameters to d-orbital occupancies of transition-metal atoms are presented. The relations are cast in the form of a 15 × 15 matrix which reduces to smaller size for site symmetries higher than {\bar 1}. The matrix takes into account differences in normalization of density functions and atomic orbitals. The expressions are applied to diffraction data on Cr(CO)6, Mn2(CO)10, Co2(CO)8, Co3(CO)9CH, Co(NH3)6Cr(CN)6 and Co(NH3)6- Co(CN)6. In all cases crystal-field destabilized orbitals are depopulated relative to stabilized orbitals. Results are in almost quantitative agreement with theoretical populations; small remaining discrepancies are to be analyzed further for their possible significance. Occupancy of e'g orbitals in the last two compounds indicates a degree of covalency of the metal-ligand interaction in these low-spin complexes which is larger for the cyano ligand than for the ammonia molecule in agreement with generally accepted conclusions based on spectroscopic data. Very little difference is observed between the relative orbital occupancies of the Cr(CN)3-6 and Cr(CO)6 species.
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    Acta crystallographica 39 (1983), S. 422-422 
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    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Notes: As a result of a printer's error, Figs. 9(a) and 9(b) in Smith & O'Keefe [Acta Cryst. (1983), A39, 139-148] have been transposed, so that (a) is labelled (b) and (b) is labelled (a).
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    Acta crystallographica 39 (1983), S. 481-499 
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    Acta crystallographica 39 (1983), S. 503-503 
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    Acta crystallographica 39 (1983), S. 512-515 
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    Notes: Statistical methodology originally introduced by French & Wilson [Acta Cryst. (1978). A34, 517-525] for the treatment of negative-intensity observations is shown to be useful for the estimation of anomalous-scattering differences. The general principles of this method are described, along with applications to data from a lead derivative of the enzyme carboxypeptidase A.
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    Acta crystallographica 39 (1983), S. 533-538 
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    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Notes: A discussion is given on simple grounds, not explicitly involving the dynamical deformation formalism, of the implications of having the outer part of the electron distribution vibrating significantly differently from the core. The use of a lattice dynamical shell model to represent this effect is examined in some detail, with particular reference to the framework within which such a model gives meaningful results. Predictions are given from the 14-parameter shell models and the 11-parameter valence-shell models for the difference between Debye-Waller B values of the shells and cores and also for the effective Debye-Waller factors for the deforming ions in 14 zinc-blende-structure compounds. It is concluded that the effective X-ray Debye-Waller B at very small sin θ/λ is typically several percent smaller than the core B value, owing to a very substantial reduction in the mean-square displacements of shells compared with cores. Results are also given for the 15-parameter deformation-dipole models for eight materials. These show effects broadly comparable in magnitude to the shell models but more varied in detail. Notably, some models show for the first time a larger rather than smaller Debye-Waller factor for the deforming ion.
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    Acta crystallographica 39 (1983), S. 562-565 
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    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Notes: With the help of conditional probabilities formulas are derived for the first and second moment of R2 as a function of the size of the model. The formulas are valid in the space group P{\bar 1} for two extreme cases, viz completely correct and completely incorrect models. Incorporation of the observed intensities enables one to obtain accurate a priori estimates of (R2) and σ(R2). The theory agrees very well with simulated experiments.
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  • 90
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    [S.l.] : International Union of Crystallography (IUCr)
    Acta crystallographica 39 (1983), S. 597-597 
    ISSN: 1600-5724
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Chemistry and Pharmacology , Geosciences , Physics
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  • 91
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    [S.l.] : International Union of Crystallography (IUCr)
    Acta crystallographica 39 (1983), S. 191-191 
    ISSN: 1600-5724
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Chemistry and Pharmacology , Geosciences , Physics
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  • 92
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    [S.l.] : International Union of Crystallography (IUCr)
    Acta crystallographica 39 (1983), S. 202-207 
    ISSN: 1600-5724
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Notes: The importance of carrying out TDS corrections is emphasized. Their relative effect on the derived temperature parameter values is discussed and shown to rely primarily on the experimental conditions and not on the softness of the crystal.
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  • 93
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    [S.l.] : International Union of Crystallography (IUCr)
    Acta crystallographica 39 (1983), S. 245-251 
    ISSN: 1600-5724
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Notes: 'Symmetrized' components are introduced in place of the standard ones to improve the method presented in paper I [Fumi & Ripamonti (1980). Acta Cryst. A36, 535-551]. These components, which are simply related to the standard ones, allow a further reduction of the computational task and also a further simplification of the results and of their use. This is illustrated by application to general two-dimensional tensors of ranks 6 and 8 and by particularization of the results to the cases of the third- and fourth-order elastic tensors.
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  • 94
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    [S.l.] : International Union of Crystallography (IUCr)
    Acta crystallographica 39 (1983), S. 269-269 
    ISSN: 1600-5724
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Notes: Mis-expressed terms in equations (13) in Onoda & Kawada [Acta Cryst. (1980), A36, 134-139] should be corrected. All exp(--i2πζ, exp(-iπζ/2), exp(-iπζ and exp(-i3πζ/2) on page 137 are to be replaced respectively by exp(i2πζ), exp (iπζ/2), exp (iπζ) and exp (i3πζ/2).
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  • 95
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    [S.l.] : International Union of Crystallography (IUCr)
    Acta crystallographica 39 (1983), S. 270-271 
    ISSN: 1600-5724
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Chemistry and Pharmacology , Geosciences , Physics
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  • 96
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    [S.l.] : International Union of Crystallography (IUCr)
    Acta crystallographica 39 (1983), S. 272-272 
    ISSN: 1600-5724
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Chemistry and Pharmacology , Geosciences , Physics
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  • 97
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    [S.l.] : International Union of Crystallography (IUCr)
    Acta crystallographica 39 (1983), S. 693-697 
    ISSN: 1600-5724
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Notes: A correct calculation of the scale factor between the diffraction data of isomorphous crystals is shown on the basis of a statistics criterion. This scale factor requires no additional refinement, improves the signal-to-noise ratio of difference Patterson maps and Wilson's statistics and allows an estimation of the degree of non-isomorphism. The method has been tested for the 3 Å data sets of protein γ-crystallin crystals and a few of its heavy-atom isomorphous derivatives.
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  • 98
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    [S.l.] : International Union of Crystallography (IUCr)
    Acta crystallographica 39 (1983), S. 740-746 
    ISSN: 1600-5724
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Notes: High-angle X-ray diffuse scattering has been measured in a volume element in reciprocal space for a Ni-12.7 at.% Al alloy single crystal quenched from 1323 K. The Cowley-Warren order parameters were determined after separation of the first- and second-order size effects, using a procedure based on the Borie-Sparks quadratic approximation of atomic displacements. The experimental order coefficients were used to reconstruct the real-space locally ordered distribution of atoms, from which the spectrum of nearest-neighbor atomic configurations was determined. Some 61% of the Al atoms were found to be in a planar ordered configuration consisting of a nickel atom and four nearest-neighbor aluminum atoms, the basic structural unit of Ni3Al. These planar elementary ordered units were, of course, distributed on the three equivalent {100} planes. While most of the ordered 'domains' consisted of from one to three Ni3Al rings, a few domains were found to contain on the order of a hundred such elementary ordered units. The larger ordered domains may be thought of as embryos of the ordered Ni3Al phase which have formed during quenching of the bulk alloy single crystal. There is evidence that the spatial distribution of ordered domains is not random.
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  • 99
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    [S.l.] : International Union of Crystallography (IUCr)
    Acta crystallographica 39 (1983), S. 767-772 
    ISSN: 1600-5724
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Notes: Experimental topographs may be simulated by addition of simulations where one point source is lit on the surface of the crystal. The accuracy of a varying-step integration of Takagi equations is good enough to allow such computations. It is shown that all parts of the contrast are sensitive to the width of the entrance slit and that accurate characterization of defects must take this parameter into account.
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  • 100
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    [S.l.] : International Union of Crystallography (IUCr)
    Acta crystallographica 39 (1983), S. 548-552 
    ISSN: 1600-5724
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Notes: X-ray intensity measurements from an extended-face single crystal of cubic zinc selenide obtained by Mcintyre, Moss & Barnea [Acta Cryst. (1980), A36, 482-490] have been reanalysed with a view to explaining the unresolved discrepancies between theory and experiment present in the original analysis of the most severely extinguished reflections. The results obtained are shown to complement the recent findings of a wavelength-dependent study using the same crystal specimen [Stevenson & Barnea (1983). Acta Cryst. A39, 538-547] and foreshadow the need to allow for the presence of the Borrmann effect.
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