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  • Inorganic Chemistry  (3,066)
  • Aircraft Design, Testing and Performance  (85)
  • Aircraft Propulsion and Power  (40)
  • 1955-1959  (3,191)
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  • 1
    Publication Date: 2019-05-11
    Description: Three highly polished 15- included- angle cone- cylinders with hemispherical tips of several diameters ( 2, 3, and 4 in.) have been flown in order to obtain boundary- layer transition data at very low wall to local stream temperature ratios, and heat- transfer data. All surfaces had a 2-microinch average roughness height. Laminar flow existed over the entire hemispherical nose of the 2- and 3-inch-tip- diameter models throughout the complete flight history. Extreme cooling to wall to local stream temperature ratios at the sonic point as low as 0.20 did not cause transition on the nose for diameters as large as 3 inches. However, extreme cooling did cause early transition on the 4-inch model where it appears probable that transition occurred forward of the 45 station at a wall to local stream temperature ratio of about 0.26. Variations in tip diameter influenced transition downstream of the nose under conditions of extreme cooling. The 2-inch- tip model was laminar at all cone- cylinder stations at temperature ratios as low as 0.32 whereas the 3- and 4-inch-tip models were turbulent at the same local flow conditions but at higher wall to local temperature ratios. Transition on the cone and cylinder of the 3- and 4-inch- tip bodies appeared to be sensitive to local Mach number, and occurred at higher local temperature ratios when values of local Mach number were higher. Increasing the nose diameter from 2 to 3 inches significantly changed the local flow conditions for which laminar flow existed on the cone- cylinder afterbody. However, a further increase in tip size t o a 4-inch diameter had no discernable effect on the local flow conditions at transition. The transition results of the 3- and 4-inch-nose-diameter smooth bodies are similar to those observed on a 7/8-inch-nose-diameter body with roughened surfaces. Turbulent boundary layers resulted in both cases at very low wall to local stream temperature ratios. Both laminar and turbulent heat-transfer data were in good agreement with theoretical Stanton numbers when heat-transfer reduction due to tip blunting was considered.
    Keywords: Aircraft Propulsion and Power
    Type: NASA-MEMO-3-4-59E , GRC-E-DAA-TN65086
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  • 2
    Publication Date: 2019-05-11
    Description: A flight investigation was made of the lift and drag of a sweptwing fighter airplane in the basic configuration and in a slats-locked-closed configuration over a Mach number range from about 0.63 to about 1.44. At a nominal lift coefficient of 0.1 negligible drag-coefficient difference existed between the two configurations over a comparable Mach number and altitude range. For the basic configuration at zero lift the supersonic drag level was about three times as great as the subsonic drag level, which was about 0.01, whereas the drag-due-to-lift factor increased about 137 percent over the test Mach number range. At comparable Mach numbers the high-altitude data produced a larger lift-curve slope and showed a more pronounced variation of lift-curve slope in the transonic region than did the low-altitude data. For the high-altitude data the lift-curve slope at a Mach number of 1.44 was approximately 62 percent of the value at a Mach number of 0.9.
    Keywords: Aircraft Design, Testing and Performance
    Type: NASA-MEMO-10-1-58H , AFRC-E-DAA-TN47945
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  • 3
    Publication Date: 2019-06-28
    Description: No abstract available
    Keywords: Aircraft Design, Testing and Performance
    Type: NASA-TN-D-89
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  • 4
    Publication Date: 2019-07-13
    Description: Turbojet engine reliability has long been an intense interest to the military users of this type of aircraft propulsion. With the recent inauguration of commercial jet transport this subject has assumed a new dimension of importance. In January l96 the Lewis Research Center of the NASA (then the MACA) published the results of an extensive study on the factors that affect the opera- center dot tional reliability of turbojet engines (ref. 1). At that time the report was classified Confidential. In July l98 this report was declassified. It is thus appropriate at this time to present some of the highlights of the studies described in the NASA report. In no way is it intended to outline the complete contents of the report; rather it is hoped to direct attention to it among those who are center dot directly concerned with this problem. Since the publication of our study over three years ago, the NASA has completed a number of additional investigations that bear significantly on this center dot subject. A second object of this paper, therefore, is to summarize the results of these recent studies and to interpret their significance in relation to turbojet operational reliability.
    Keywords: Aircraft Design, Testing and Performance
    Type: SAE National Aeronautic Meeting; Mar 31, 1959 - Apr 03, 1959; New York, NY; United States
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  • 5
    Publication Date: 2019-08-17
    Description: An investigation of the low-subsonic stability and control characteristics of a model of a flat-bottom hypersonic boost-glide configuration having 78 deg sweep of the leading edge has been made in the Langley full-scale tunnel. The model was flown over an angle-of-attack range from 10 to 35 deg. Static and dynamic force tests were made in the Langley free-flight tunnel. The investigation showed that the longitudinal stability and control characteristics were generally satisfactory with neutral or positive static longitudinal stability. The addition of artificial pitch damping resulted in satisfactory longitudinal characteristics being obtained with large amounts of static instability. The most rearward center-of-gravity position for which sustained flights could be made either with or without pitch damper corresponded to the calculated maneuver point. The lateral stability and control characteristics were satisfactory up to about 15 deg angle of attack. The damping of the Dutch roll oscillation decreased with increasing angle of attack; the oscillation was about neutrally stable at 20 deg angle of attack and unstable at angles of attack of about 25 deg and above. Artificial damping in roll greatly improved the lateral characteristics and resulted in flights being made up to 35 deg angle of attack.
    Keywords: Aircraft Design, Testing and Performance
    Type: NASA-TM-X-201 , L-452
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  • 6
    Publication Date: 2019-08-17
    Description: Acceleration, airspeed, and altitude data obtained with an NACA VGH recorder from a four-engine commercial transport airplane operating over a northwestern United States-Alaska route were evaluated to determine the magnitude and frequency of occurrence of gust and maneuver accelerations., operating airspeeds, and gust velocities. The results obtained were then compared with the results previously reported in NACA Technical Note 3475 for two similar airplanes operating over transcontinental routes in the United States. No large variations in the gust experience for the three operations were noted. The results indicate that the gust-load experience of the present operation closely approximated that of the central transcontinental route in the United States with which it is compared and showed differences of about 4 to 1 when compared with that of the southern transcontinental route in the United States. In general, accelerations due to gusts occurred much more frequently than those due to operational maneuvers. At a measured normal-acceleration increment of 0.5g, accelerations due to gusts occurred roughly 35 times more frequently than those due to operational maneuvers.
    Keywords: Aircraft Design, Testing and Performance
    Type: NASA-MEMO-1-17-59L
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  • 7
    Publication Date: 2019-08-17
    Description: An analysis is made of wing deflection and streamwise twist measurements in rough-air flight of a large flexible swept-wing bomber. Random-process techniques are employed in analyzing the data in order to describe the magnitude and characteristics of the wing deflection and twist responses to rough air. Power spectra and frequency-response functions for the wing deflection and twist responses at several spanwise stations are presented. The frequency-response functions describe direct and absolute response characteristics to turbulence and provide a convenient basis for assessing analytic calculation techniques. The wing deformations in rough air are compared with the expected deformations for quasi-static loadings of the same magnitude, and the amplifications are determined. The results obtained indicate that generally the deflections are amplified by a small amount, while the streamwise twists are amplified by factors of the order of 2.0. The magnitudes of both the deflection velocities and the twist angles are shown to have significant effects on the local angles of attack at the various stations and provide the main source of aerodynamic loading, particularly at frequencies in the vicinity of the first wing-vibration mode.
    Keywords: Aircraft Design, Testing and Performance
    Type: NASA-MEMO-12-3-58L
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  • 8
    Publication Date: 2019-08-17
    Description: Analysis of the vortex model proposed by Kriebel, Seidel, and Schwind shows this representation of rotating stall satisfies, at least approximately, the requirements at the cascade. Cascade-parameter-variation effects on rotating stall were studied in a circular cascade and single-stage compressor. Modification of the single-stage compressor stopped the rotating-stall pattern and permitted observation of the pressure and velocity distribution around the annulus. Closer observation might be possible with proper flow-visualization techniques, such as a water pump.
    Keywords: Aircraft Design, Testing and Performance
    Type: NASA-MEMO-3-16-59W
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  • 9
    Publication Date: 2019-08-17
    Description: The effect of stator and rotor aspect ratio on transonic-turbine performance was experimentally investigated. The stator aspect ratios covered were 1.6. 0.8, and 0.4, while the rotor aspect ratios investigated were 1.46 and 0.73. It was found that the observed variation in turbine design-point efficiency was negligible. Thus, within the range of aspect ratio investigated, these results verify for turbines operating in the transonic flow range the finding of a reference report, which showed analytically that, if blade shape and solidity are held constant, the aspect ratio may be varied over a wide range without appreciable change in turbine efficiency.
    Keywords: Aircraft Propulsion and Power
    Type: NASA-MEMO-2-11-59E , E-177
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  • 10
    Publication Date: 2019-08-17
    Description: The suitability of cermets for turbine stator blades of a modified turbojet engine was determined at an average turbine-inlet-gas temperature of 2000 F. Such an increase in temperature would yield a premium in thrust from a service engine. Because the cermet blades require no cooling, all the available compressor bleed air could be used to cool a turbine made from conventional ductile alloys. Cermet blades were first run in 100-hour endurance tests at normal gas temperatures in order to evaluate two methods for mounting them. The elevated gas-temperature test was then run using the method of support considered best for high-temperature operation. After 52 hours at 2000 F, one of the group of four cermet blades fractured probably because of end loads resulting from thermal distortion of the spacer band of the nozzle diaphragm. Improved design of a service engine would preclude this cause of premature failure.
    Keywords: Aircraft Propulsion and Power
    Type: NASA-MEMO-2-13-59E , E-147
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  • 11
    Publication Date: 2019-08-17
    Description: In an attempt to find an aerodynamic means of counteracting the transonic trim change of a fighter airplane, lower surface spoilers were tested on a 0.055-scale wind-tunnel model. The Mach number range of the tests was 0.8 to 1.2 at Reynolds numbers of approximately 4 million. Although the spoilers produced a moderate decrease in the trim change at low altitudes, they also produced a large increase in drag. Pressure-distribution tests with external fuel tanks showed large pressure changes on the lower surface of the wing due to the tanks.
    Keywords: Aircraft Design, Testing and Performance
    Type: NASA-MEMO-12-27-58A
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  • 12
    Publication Date: 2019-08-17
    Description: An investigation was conducted in a modified turbojet engine to determine the cooling characteristics of the semistrut corrugated air- cooled turbine blade and to compare and evaluate a leading-edge tip cap as a means for improving the leading-edge cooling characteristics of cooled turbine blades. Temperature data were obtained from uncapped air-cooled blades (blade A), cooled blades with the leading-edge tip area capped (blade B), and blades with slanted corrugations in addition to leading-edge tip caps (blade C). All data are for rated engine speed and turbine-inlet temperature (1660 F). A comparison of temperature data from blades A and B showed a leading-edge temperature reduction of about 130 F that could be attributed to the use of tip caps. Even better leading-edge cooling was obtained with blade C. Blade C also operated with the smallest chordwise temperature gradients of the blades tested, but tip-capped blade B operated with the lowest average chordwise temperature. According to a correlation of the experimental data, all three blade types 0 could operate satisfactorily with a turbine-inlet temperature of 2000 F and a coolant flow of 3 percent of engine mass flow or less, with an average chordwise temperature limit of 1400 F. Within the range of coolant flows investigated, however, only blade C could maintain a leading-edge temperature of 1400 F for a turbine-inlet temperature of 2000 F.
    Keywords: Aircraft Propulsion and Power
    Type: NASA-MEMO-2-9-59E
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  • 13
    Publication Date: 2019-08-17
    Description: The Levy method which deals with an idealized structure was used to obtain the natural modes and frequencies of a large-scale built-up 45 deg. delta wing. The results from this approach, both with and without the effects of transverse shear, were compared with the results obtained experimentally and also with those calculated by the Stein-Sanders method. From these comparisons it was concluded that the method as proposed by Levy gives excellent results for thin-skin delta wings, provided that corrections are made for the effect of transverse shear.
    Keywords: Aircraft Design, Testing and Performance
    Type: NASA-MEMO-2-2-59L , L-153
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  • 14
    Publication Date: 2019-08-17
    Description: A cambered and twisted triangular wing of aspect ratio 2 in combination with a cambered body was investigated experimentally to determine the effectiveness of the camber in reducing the drag due to lift at trim at supersonic speeds. Four arrangements were tested comprising all combinations of a symmetrical and a cambered wing with a symmetrical and a cambered body. The camber shape investigated was derived by linearized lifting surface theory for triangular wings with sonic leading edges and satisfied the requirement that the wing be trimmed at the design Mach number and lift coefficient. The experimental results for the cambered wing and cambered body showed that the drag coefficient at trim was always greater, at the same lift coefficient, than that for the untrimmed symmetrical wing and body. The trim lift coefficient was positive and decreased with increasing Mach number. At the design Mach number of 2.24, the trim lift coefficient was somewhat lower and the drag coefficient was higher than values predicted by linearized lifting surface theory for the wing alone. A comparison of the trim lift-drag ratio of the cambered wing and cambered body with values obtained by trimming the symmetrical wing and symmetrical body either with a canard or a trailing-edge flap showed that, at approximately the design Mach number the cambered configuration developed a somewhat higher value than the trailing-edge flap configuration but a lower value than the canard configuration.
    Keywords: Aircraft Design, Testing and Performance
    Type: NASA-MEMO-2-3-59A
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  • 15
    Publication Date: 2019-08-17
    Description: The maximum Mach number and altitude capabilities of the Bell X-2 research airplane were achieved during a program conducted by the U.S. Air Force with Bell Aircraft Corp. providing operational support and the National Aeronautics and Space Administration providing instrumentation and advisory engineering assistance. A maximum geometric altitude of 126,200 feet was attained at a static pressure of 9.4 pounds per square foot and a dynamic pressure of 19.1 pounds per square foot. During the last flight of the airplane, a maximum Mach number of 3.20 was reached. The directionally divergent maneuver which terminated the final high Mach number flight was precipitated by the loss in directional stability that resulted from increasing the angle of attack. The yawing moment from the lateral control was sufficient to initiate the divergence and also to cause,, indirectly, rolling moments that were greater than the aileron capabilities of the airplane. The ensuing violent motions-resulting from inertial roll coupling caused the loss of the aircraft.
    Keywords: Aircraft Design, Testing and Performance
    Type: NASA-TM-X-137
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  • 16
    Publication Date: 2019-08-16
    Description: The first flight of the North American X-15 research airplane was made on June 8, 1959. This was accomplished after completion of a series of captive flights with the X-15 attached to the B-52 carrier airplane to demonstrate the aerodynamic and systems compatibility of the X-15//B-52 combination and the X-15 subsystem operation. This flight was planned as a glide flight so that the pilot need not be concerned with the propulsion system. Discussions of the launch, low-speed maneuvering, and landing characteristics are presented, and the results are compared with predictions from preflight studies. The launch characteristics were generally satisfactory, and the X-15 vertical tail adequately cleared the B-52 wing cutout. The actual landing pattern and landing characteristics compared favorably with predictions, and the recommended landing technique of lowering the flaps and landing gear at a low altitude appears to be a satisfactory method of landing the X-15 airplane. There was a quantitative correlation between flight-measured and predicted lift-drag-ratio characteristics in the clean configuration and a qualitative correlation in the landing configuration. A longitudinal-controllability problem, which became severe in the landing configuration, was evident throughout the flight and, apparently, was aggravated by the sensitivity of the side-located control stick. In the low-to-moderate angle-of-attack range covered, the longitudinal and directional stability were indicated to be adequate.
    Keywords: Aircraft Design, Testing and Performance
    Type: NASA-TM-X-195
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  • 17
    Publication Date: 2019-08-16
    Description: A study has been made of the subsonic pressure distributions and loadings for a 45 deg sweptback-wing and body combination at angles of attack up to 36 deg. The wing had an aspect ratio of 5.5, a taper ratio of 0.53, and NACA 64A010 sections normal to the quarter-chord line and was mounted on a slender body of fineness ratio 12.5. Test results are presented for Mach numbers of 0.30 and 0.50 with corresponding Reynolds numbers of 1.5 and 2.0 million, respectively. The stall patterns and spanwise loadings at high angles of attack for the present model are correlated with those for other 45 deg sweptback wing and body combinations having aspect ratios between 4.0 and 8.0. A tentative approach is presented for extrapolating the Weissinger span-loading method to higher angles of attack, and for deriving the spanwise-load distributions for 45 deg sweptback wings at angles of attack above 20 deg. The investigation also included tests of the body in combination with only one panel of the swept wing. The problem of estimating the normal-force coefficient for the single panel at high angles of attack is considered.
    Keywords: Aircraft Design, Testing and Performance
    Type: NASA-MEMO-1-18-59A
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  • 18
    Publication Date: 2019-08-16
    Description: Results of a cyclic load test made by NASA on an EB-47E airplane are given. The test reported on is for one of three B-47 airplanes in a test program set up by the U. S. Air Force to evaluate the effect of wing structural reinforcements on fatigue life. As a result of crack development in the upper fuselage longerons of the other two airplanes in the program, a longeron and fuselage skin modification was incorporated early in the test. Fuselage strain-gage measurements made before and after the longeron modification and wing strain-gage measurements made only after wing reinforcement are summarized. The history of crack development and repair is given in detail. Testing was terminated one sequence short of the planned end of the program with the occurrence of a major crack in the lower right wing skin.
    Keywords: Aircraft Design, Testing and Performance
    Type: NASA-MEMO-3-15-59L , AF-AM-171
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  • 19
    Publication Date: 2019-08-16
    Description: Flight tests were made to determine the capability of positioning a gliding airplane for a landing on a 5,000-foot runway with special reference to the gliding flight of a satellite vehicle of fixed configuration upon reentry into the earth's atmosphere. The lift-drag ratio and speed of the airplane in the glides were varied through as large a range as possible. The results showed a marked tendency to undershoot the runway when the lift-drag ratios were below certain values, depending upon the speed in the glide. A straight line dividing the successful approaches from the undershoots could be drawn through a lift-drag ratio of about 3 at 100 knots and through a lift-drag ratio of about 7 at 185 knots. Provision of a drag device would be very beneficial, particularly in reducing the tendency toward undershooting at the higher speeds.
    Keywords: Aircraft Design, Testing and Performance
    Type: NASA-MEMO-3-12-59L , L-406
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  • 20
    Publication Date: 2019-08-16
    Description: Several approximate procedures for calculating the bending-moment response of flexible airplanes to continuous isotropic turbulence are presented and evaluated. The modal methods (the mode-displacement and force-summation methods) and a matrix method (segmented-wing method) are considered. These approximate procedures are applied to a simplified airplane for which an exact solution to the equation of motion can be obtained. The simplified airplane consists of a uniform beam with a concentrated fuselage mass at the center. Airplane motions are limited to vertical rigid-body translation and symmetrical wing bending deflections. Output power spectra of wing bending moments based on the exact transfer-function solutions are used as a basis for the evaluation of the approximate methods. It is shown that the force-summation and the matrix methods give satisfactory accuracy and that the mode-displacement method gives unsatisfactory accuracy.
    Keywords: Aircraft Design, Testing and Performance
    Type: NASA-MEMO-2-18-59L , L-143
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  • 21
    Publication Date: 2019-08-16
    Description: The design and experimental investigation of a 4.5-inch-mean-diameter two-stage turbine are presented herein and used to study the effect of size on the efficiency of turbines in the auxiliary power drive class. The results of the experimental investigation indicated that design specific work was obtained at design speed at a total-to-static efficiency of 0.639. At design pressure ratio, design static-pressure distribution through the turbine was obtained with an equivalent specific work output of 33.2 Btu per pound and an efficiency of 0.656. It was found that, in the design of turbines in the auxiliary power drive class, Reynolds number plays an important part in the selection of the design efficiency. Comparison with theoretical efficiencies based on a loss coefficient and velocity diagrams are presented. Close agreement was obtained between theory and experiment when the loss coefficient was adjusted for changes in Reynolds number to the -1/5 power.
    Keywords: Aircraft Propulsion and Power
    Type: NASA-MEMO-4-6-59E
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  • 22
    Publication Date: 2019-08-15
    Description: The performance of turbine-engine combustors usually is given in terms of operating limits and combustion efficiency. The latter property is determined most often by measuring the increase in enthalpy across the combustor through the use of thermocouples. This investigation was conducted to determine the ability of gas-analytical techniques to provide additional information about combustor performance. Gas samples were taken at the outlet and two upstream stations and their compositions determined. In addition to over-all combustion efficiency, estimates of local fuel-air ratios, local combustion efficiencies, and heat-release rates can be made. Conclusions can be drawn concerning the causes of combustion inefficiency and may permit corrective design changes to be made more intelligently. The purpose of this investigation was not to present data for a given combustor but rather to show the types and value of additional information that can be gained from gas-analytical data.
    Keywords: Aircraft Propulsion and Power
    Type: NASA-MEMO-1-26-59E , E-245
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  • 23
    Publication Date: 2019-08-15
    Description: The Bell D-188A VTOL airplane is a horizontal-attitude VTOL fighter with tilting engine nacelles at the tips of a low-aspect-ratio unswept wing and additional engines in the fuselage. The model could be flown smoothly in hovering and transition flight. In forward flight the model could be flown smoothly at the lower angles of attack but experienced an uncontrollable directional divergence at angles of attack above about 16 deg.
    Keywords: Aircraft Design, Testing and Performance
    Type: NASA-MEMO-3-16-59L , TED-AD-3147 , L-241
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  • 24
    Publication Date: 2019-08-15
    Description: Flapwise bending moments were calculated for a teetering rotor blade using a reasonably rapid theoretical method in which airloads obtained from wind-tunnel tests were employed. The calculated moments agreed reasonably well with those measured with strain gages under the same test conditions. The range of the tests included one hovering and two forward-flight conditions. The rotor speed for the test was very near blade resonance, and difficult-to-calculate resonance effects apparently were responsible for the largest differences between the calculated and measured harmonic components of blade bending moments. These differences, moreover, were largely nullified when the harmonic components were combined to give a comparison of the calculated and measured blade total- moment time histories. The degree of agreement shown is therefore considered adequate to warrant the use of the theoretical method in establishing and applying methods of prediction of rotor-blade fatigue loads. At the same time, the validity of the experimental methods of obtaining both airload and blade stress measurement is also indicated to be adequate for use in establishing improved methods for prediction of rotor-blade fatigue loads during the design stage. The blade stiffnesses and natural frequencies were measured and found to be in close agreement with calculated values; however, for a condition of blade resonance the use of the experimental stiffness values resulted in better agreement between calculated and measured blade stresses.
    Keywords: Aircraft Design, Testing and Performance
    Type: NASA-MEMO-2-28-59L , L-140
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  • 25
    Publication Date: 2019-08-15
    Description: As a continuation of an investigation of the release characteristics of an MB-1 rocket carried internally by the Convair F-106A airplane, six missile-bay baffle configurations and a rocket end plate have been investigated in the 27- by 27-inch preflight jet of the NASA Wallops Station. The MB-1 rocket used had retractable fins and was ejected from a missile bay modified by the addition of six different baffle configurations. For some tests a rocket end plate was added to the model. Dynamically scaled models (0.04956 scale) were tested at a simulated altitude of 22,450 feet and Mach numbers of 0.86, 1.59, and 1.98, and at a simulated altitude of 29,450 feet and a Mach number of 1.98. The results of this investigation indicate that the missile-bay baffle configurations and the rocket end plate may be used to reduce the positive pitch amplitude of the MB-1 rocket after release. The initial negative pitching velocity applied to the MB-1 rocket might then be reduced in order to maintain a near-level-flight attitude after release. As the fuselage angle of attack is increased, the negative pitch amplitude of the rocket is decreased.
    Keywords: Aircraft Design, Testing and Performance
    Type: NASA-MEMO-4-29-59L , AF-AM-57 , L-361
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  • 26
    Publication Date: 2019-08-15
    Description: A series of landings was performed with a straight-wing airplane to evaluate the effect of low lift-drag ratios on approach and landing characteristics. Landings with a peak lift-drag ratio as low as 3 were performed by altering the airplane configuration (extending speed brakes, flaps, and gear and reducing throttle setting). As lift-drag ratio was reduced, it was necessary either to make the landing pattern tighter or to increase initial altitude, or both. At the lowest lift-drag ratio the pilots believed a 270 deg overhead pattern was advisable because of the greater ease afforded in visually positioning the airplane. The values of the pertinent flare parameters increased with the reduction of lift-drag ratio. These parameters included time required for final flare; speed change during final flare; and altitude, glide slope, indicated airspeed, and vertical velocity at initiation of final flare. The pilots believed that the tolerable limit was reached with this airplane in the present configuration, and that if, because of a further reduction in lift-drag ratio, more severe approaches than those experienced in this program were attempted, additional aids would be required to determine the flare-initiation point.
    Keywords: Aircraft Design, Testing and Performance
    Type: NASA-TM-X-31
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  • 27
    Publication Date: 2019-08-15
    Description: Values of the normal component of induced velocity throughout the entire field of a uniformly loaded r(rotor at high high speed are presented in the form of charts and tables. Many points were found by an electromagnetic analog, details of which are given. Comparisons of computed and analog values for the induced velocity indicate that the latter are sufficiently accurate for engineering purposes.
    Keywords: Aircraft Design, Testing and Performance
    Type: NASA-TR-R-41
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  • 28
    Publication Date: 2019-08-15
    Description: This paper briefly summarizes available statistical data on airplane taxi operations, examines the profiles and power spectra of four selected runways and taxiways covering a wide range of surface roughness, considers (on the basis of theoretical and experimental results) the loads resulting from taxiing on such runways over a range of speeds and, by synthesis of the aforementioned results, proposes new criteria for runway and taxiway smoothness which are applicable to new construction and may also be used as a guide for determining when repairs are necessary.
    Keywords: Aircraft Design, Testing and Performance
    Type: NASA-MEMO-2-21-59L
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  • 29
    Publication Date: 2019-08-15
    Description: An investigation was conducted to determine the flameholding capabilities of aerodynamic jets at afterburner operating conditions. Stability data for a number of aerodynamic flameholders were obtained in a 5- by 5-inch test section at inlet-air reference velocities up to 600 feet per second, an inlet-air temperature of 1250 F, and a combustor-inlet pressure of 15 inches of mercury absolute. Combustion efficiency and stability data of the more promising combinations were then obtained in a 10- by 12-inch test section at the same test conditions. Both air and stoichiometric mixtures of fuel and air were used in the jets; mixture flow rates were approximately 1 percent by weight of the total air-flow rate. Injection pressures were limited to values that might be available from compressor-bleed air. At a reference velocity of 600 feet per second, aerodynamic flame-holders alone were unable to maintain a stable flame at injection pressures up to 70 pounds per square inches large reductions in velocity were required to achieve flame stabilization. When the aerodynamic jets were used in combination with a V-gutter flameholder with approximately a 30 percent blocked area, flame stabilization was attained at a velocity of 600 feet per second; however, the combustion efficiencies of the various combinations were no greater than that obtained with the V-gutter alone.
    Keywords: Aircraft Propulsion and Power
    Type: NASA-MEMO-4-9-59E
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  • 30
    Publication Date: 2019-08-15
    Description: Incompressible-flow calculations were performed to determine the effects of combustor geometric and operating variables on pressure loss and airflow distribution in a tubular combustor with a tapered liner. The calculations include the effects of momentum transfer between annulus and liner gas streams, annulus wall friction, heat release, and discharge coefficients of liner air-entry holes. Generalized curves are presented which show the effects of liner-wall inclination, liner open hole area, and temperature rise across the combustor on pressure loss and airflow distribution for a representative parabolic liner hole distribution. A comparison of the experimental data from 12 tapered liners with the theoretical calculations indicates that reasonable design estimates can be made from the generalized curves. The calculated pressure losses of the tapered liners are compared with those previously reported for tubular liners.
    Keywords: Aircraft Propulsion and Power
    Type: NASA-MEMO-11-26-58E , E-126
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  • 31
    Publication Date: 2019-08-15
    Description: A comparison of the performance of a single-stage rotor run at three different blade setting angles is presented. The rotor was of a design typical for a last stage of a multistage compressor. At each setting angle, the rotor blade row was operated from 53 to 100 percent of equivalent maximum speed (850 ft/sec tip speed) at constant inlet pressure. Hot-wire anemometry was used to observe rotating-stall and surge patterns in time unsteady flow. Results indicated that an increase in peak pressure ratio and an increase in maximum equivalent weight flow were obtained at each speed investigated when the blade setting angle was decreased. An increase in peak efficiency was achieved with decrease in blade setting angle for part of the range of speeds investigated. However, the peak efficiencies for the three blade setting angles were approximately the same at the maximum speed investigated. The flow ranges for all three configurations were about the same at minimum speed and decreased at almost the same rate when the rotative speed was increased through part of the range of speeds investigated. At maximum speed, the flow range for the smallest setting angle was considerably less than the flow range for the other two configurations. A decrease in efficiency and flow range for the smallest blade setting angle at maximum speed can be attributed primarily to a Mach number effect. In addition, because of the difference in projected axial chord lengths at the casing wall, some effect on performance could be expected from the change in three-dimensional flow occurring at the tip. Rotating-stall characteristics for the two smaller blade setting angles were essentially the same. Only surge could be detected for the largest blade setting angle in the unstable-flow region of operation.
    Keywords: Aircraft Propulsion and Power
    Type: NASA-MEMO-11-27-58E , E-117
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  • 32
    Publication Date: 2019-08-15
    Description: Flight tests have been conducted with a single-rotor helicopter, one blade of which was equipped at 14 percent and 40 percent of the blade radius with strain gages calibrated to measure moments rather than stresses, to determine the effects of transition, landing approaches, and partial-power vertical descents on the rotor-blade bending and torsional moments. In addition, ground tests were conducted to determine the effects of static droop-stop pounding on the rotor-blade moments. The results indicate that partial-power vertical descents and landing approaches produce rotor-blade moments that are higher than the moments encountered in any other flight condition investigated to date with this equipment. Decelerating through the transition region in level flight was found to result in higher vibratory moments than accelerating through this region. Deliberately induced static droop-stop pounding produced flapwise bending moments at the 14-percent-radius station which were as high as the moments experienced in landing approaches and partial-power vertical descents.
    Keywords: Aircraft Design, Testing and Performance
    Type: NASA-MEMO-5-7-59L
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  • 33
    Publication Date: 2019-08-15
    Description: Generalized influence coefficients are calculated by the method of NACA TN 3640 for a large-scale, built-up, 450 delta-wing specimen. These are used together with appropriate generalized masses to obtain the natural modes and frequencies in symmetric and antisymmetric free-free vibration. The resulting frequencies are compared with those obtained experimentally and are found to be consistently high. Possible sources of the disparities are discussed.
    Keywords: Aircraft Design, Testing and Performance
    Type: NASA-MEMO-2-1-59L
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  • 34
    Publication Date: 2019-08-15
    Description: Some blunt-body shapes considered suitable for entry into the earth's atmosphere were tested by both static and oscillatory methods in the Langley stability tunnel. In addition, free-fall tests of some similar models were made in the Langley 20-foot free-spinning tunnel. The results of the tests show that increasing the flare of the body shape increased the dynamic stability and that for flat-faced shapes increasing the corner radius increased the stability. The test data from the Langley stability tunnel were used to compute the damping factor for the models tested in the langley 20-foot free-spinning tunnel. For these cases in which the damping factor was low, -1/2 or less, the stability was critical and sensitive to disturbance. When the damping factor was about -2, damping was generally obtained.
    Keywords: Aircraft Design, Testing and Performance
    Type: NASA-MEMO-2-22-59L , L-157
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  • 35
    Publication Date: 2019-08-15
    Description: High-altitude turbojet performance is adversely affected by the effects of low air density. This performance loss is evaluated as a Reynolds number effect, which represents the increased significance of high fluid viscous forces in relation to dynamic fluid forces as the Reynolds number is decreased. An analytical and experimental investigation of the effects of low Reynolds number operation on a single-stage, high-work-output turbine with a downstream stator was carried out at Reynolds numbers of 182,500, 39,600, and 23,000, based on average rotor-design flow conditions. At low Reynolds numbers and turbulent flow conditions, increased viscous losses caused decreased effective flow area, and thus decreased weight flow, torque, and over-all efficiency at a given equivalent speed and pressure ratio. Decreasing the Reynolds number from 182,500 to 23,000 at design equivalent speed resulted in a 5.00-point loss in peak over-all turbine efficiency for both theory and experiment. The choking equivalent weight flow decreased 2.30 percent for these conditions. Limiting loading work output was reached at design equivalent speed for all three Reynolds numbers. The value of limiting loading work output at design speed decreased 4.00 percent as Reynolds number was decreased from 182,500 to 23,000. A theoretical performance-prediction method using basic boundary-layer relations gave good agreement with experimental results over most of the performance range at a given Reynolds number if the experimental and analytical design operating conditions were carefully matched at the highest Reynolds number with regard to design performance parameters. High viscous losses in the inlet stator and rotor prevented the attainment of design equivalent work output at the lowest Reynolds number of 23,000.
    Keywords: Aircraft Propulsion and Power
    Type: NASA-TM-X-9
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  • 36
    Publication Date: 2019-08-16
    Description: A preliminary investigation was conducted to determine whether a warhead stage of an antimissile missile could be placed within an arbitrary 2-nautical-mile-radius maneuver cylinder around an intercontinental-ballistic-missile (ICBM) flight path above an altitude of 140,000 feet, a horizontal range of 40 nautical miles, at a flight-path angle of approximately 20 deg, and within 50 seconds after take-off using only aerodynamic forces to turn the antimissile missile. The preliminary investigation indicated that an antimissile missile using aerodynamic forces for turning was capable of intercepting the ICBM for the stated conditions of this study although the turning must be completed below an altitude of approximately 70,000 feet to insure that the antimissile missile will be at the desired flight-path angle. Trim lift coefficients on the order of 2 to 3 and a maximum normal-acceleration force of from 25g to 35g were necessary to place the warhead stage in intercept position. The preliminary investigation indicated that for the two boosters investigated the booster having a burning time of 10 seconds gave greater range up the ICBM flight path than did the booster having a burning time of 15 seconds for the same trim lift coefficient and required the least trim lift coefficient for the same range.
    Keywords: Aircraft Design, Testing and Performance
    Type: NASA-MEMO-2-14-59L
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  • 37
    Publication Date: 2019-08-16
    Description: As a means of evaluating the roll utilization of a fighter airplane capable of supersonic speeds, an instrumented North American F-100A fighter airplane was flown by U.S. Air Force pilots at Nellis Air Force Base, NV, during 20 hours of service operational flying. Mach numbers up to 1.22 and altitudes up to 50,000 feet were realized in this investigation. Results of the study showed that except for high g barrel rolls performed as evasive maneuvers and rolls performed in acrobatic flying, rolling was utilized primarily as a means of changing heading. Acrobatic and air combat maneuvering produced the largest bank angles (1,200 deg), roll velocities (3.3 radians/sec), rolling accelerations (8 radians/sq sec) and sideslip angles (10.8 deg). Full aileron deflections were utilized on numerous occasions. Although high rolling velocities and accelerations also were experienced during several air-to-air gunnery missions, generally, air-to-air gunnery and air-to-ground gunnery and bombing required only two-thirds of maximum aileron deflection. The air-to-air gunnery and air combat maneuvers initiated from supersonic speeds utilized up to two-thirds aileron deflection and bank angles of less than 18 deg and resulted in rolling velocities and accelerations of 2 radians per second and 4.6 radians/sq sec, respectively. Rolling maneuvers were often initiated from high levels of normal acceleration, but from levels of negative normal acceleration only once.
    Keywords: Aircraft Design, Testing and Performance
    Type: NASA-MEMO-12-1-58H
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  • 38
    Publication Date: 2019-08-16
    Description: A flight investigation was undertaken to determine the effect of a fully controllable thrust reverser on the flight characteristics of a single-engine jet airplane. Tests were made using a cylindrical target-type reverser actuated by a hydraulic cylinder through a "beep-type" cockpit control mounted at the base of the throttle. The thrust reverser was evaluated as an in-flight decelerating device, as a flight path control and airspeed control in landing approach, and as a braking device during the ground roll. Full deflection of the reverser for one reverser configuration resulted in a reverse thrust ratio of as much as 85 percent, which at maximum engine power corresponded to a reversed thrust of 5100 pounds. Use of the reverser in landing approach made possible a wide selection of approach angles, a large reduction in approach speed at steep approach angles, improved control of flight path angle, and more accuracy in hitting a given touchdown point. The use of the reverser as a speed brake at lower airspeeds was compromised by a longitudinal trim change. At the lower airspeeds and higher engine powers there was insufficient elevator power to overcome the nose-down trim change at full reverser deflection.
    Keywords: Aircraft Design, Testing and Performance
    Type: NASA-MEMO-4-26-59A , A-135
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  • 39
    Publication Date: 2019-08-16
    Description: Five engine tests were conducted to definitely establish the failure mechanism of leading-edge cracking and to determine which conditions of engine operation cause the failures. Five groups of S-616 and M-252 buckets from master lots were run consecutively in the same J47-25 engine. The tests included a steady-state run at full-power conditions, rapid cycling between idle and rated speed, and three different start-stop tests. The first start-stop test consisted of cycles of start and stop with 5 minutes of idle speed before each stop; the second included cycles of start and stop but with 15 minutes of rated speed before each stop; the third consisted of cycles of gradual starts and normal stops with 5 minutes at idle speed before each stop. The test results demonstrated that the primary cause of leading-edge cracking was thermal fatigue produced by repeated engine starts. The leading edge of the bucket experiences plastic flow in compression during starts and consequently is subjected to a tensile stress when the remainder of the bucket becomes heated and expands. Crack initiation was accelerated when rated-speed operation was added to each normal start-stop cycle. This acceleration of crack formation was attributed to localized creep damage and perhaps to embrittlement resulting from overaging. It was demonstrated that leading-edge cracking can be prevented simply by starting the engine gradually.
    Keywords: Aircraft Propulsion and Power
    Type: NASA-MEMO-4-7-59E , E-281
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  • 40
    Publication Date: 2019-08-16
    Description: In order to determine the effect of a low design diffusion factor on the performance of a transonic axial-flow compressor rotor, a high-specific-flow rotor with a 0.35 hub-tip radius ratio was designed, fabricated and tested. This rotor used a design tip diffusion factor of 0.20 with a design corrected specific weight flow of 40 pounds per second per square foot of frontal area, a total-pressure ratio of 1.27, and an adiabatic efficiency of 0.96. The design, rotor performance, and blade element performance are presented with a discussion on rotor shock losses and a comparison with a similarly designed rotor with a tip diffusion factor of 0.35. At the design corrected tip speed of 1100 feet per second, a peak rotor adiabatic efficiency of 0.88 was attained at a corrected specific weight flow of 39 pounds per second per square foot of frontal area with a mass-averaged total-pressure ratio of 1.27. The blade element tip diffusion factor was 0.281, which is 0.08 higher than the design value of 0.20. Peak efficiencies of 0.95, 0.91, 0.89, and 0.85 were obtained at 70, 80, 90, and 110 percent of design speed, respectively. Comparison of the performance of the rotor reported herein and a similarly designed rotor with increased blade loading indicates that higher blade loading results in a more desirable rotor because of a higher pressure ratio and equivalent efficiency. Computed values of shock losses at the rotor tip section indicate that the losses at peak efficiency are primarily a function of shock losses since the profile losses are only a small percentage of the total loss.
    Keywords: Aircraft Propulsion and Power
    Type: NASA-TM-X-86
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  • 41
    Publication Date: 2019-08-16
    Description: The first landing of the X-15 airplane was made at 8:43 a.m., June 8, 1959, on the hard surface of Rogers Dry Lake. One purpose of the first-glide flight was to evaluate the effectiveness of the landing-gear system. Some results are presented of the landing-approach characteristics, the impact period, and the runout phase of the landing maneuver. The results indicate that the touchdown was accomplished at a vertical velocity of 2.0 feet per second for the main gear and 13.5 feet per second for the nose gear. These vertical velocities were within the values of sinking speeds established by structural design limitations. However, permanent structural deformation occurred in the main-landing-gear system as a result of the landing, and a reevaluation of the gear is being made by the manufacturer. The landing occurred at a true ground speed of 158 knots for main-gear touchdown at an angle of attack of 8.50. The incremental acceleration at the main gear was 2.7g and 7.39 at the nose gear as a result of the landing. The incremental acceleration at the center of gravity of the airplane was 0.6g for the main-gear impact and 2.4g for the nose-gear impact. The incremental acceleration at the main gear as a result of the nose-gear impact was 4.8g. The extreme rearward location of the main-gear skids appears to offer satisfactory directional stability characteristics during the run- out phase of the landing. No evidence of nosewheel shimmy was indicated during the impact and runout phase of the landing despite the absence of a shimmy damper on the nose gear. The maximum amount of skid wear as a result of the landing was on the order of 0.005 inch. No appreciable amount of tire wear was indicated for the dual, corotating nosewheels.
    Keywords: Aircraft Design, Testing and Performance
    Type: NASA-TM-X-207
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  • 42
    Electronic Resource
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    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 10-17 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Bei gelinder Erwärmung der Phenylalkane (R · C6H5; R ≧ C3) mit durch Wasser aktiviertem Aluminiumchlorid findet eine Umlagerung der Seitenkette statt. Es entstehen: aus Isopropylbenzol n-Propylbenzol, aus sek.-Butylbenzol Isobutylbenzol, aus tert.-Amylbenzol 2-Methyl-3-phenyl-butan und aus letzterem, bei längerer Einwirkung des Katalysators, Neopentylbenzol.  -  Die stabilen Produkte dieser Umlagerungen enthalten an primäre Kohlenstoffatome gebundene Phenylgruppen, im Gegensatz zu den Produkten der Friedel-Crafts-Alkylierungsreaktion, in welchen eine tertiäre bzw. eine sekundäre Stellung der Phenylgruppen bevorzugt wird.
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  • 43
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    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 40-46 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Darstellung des Naphthyl-(2)-tellurjodids wird beschrieben und der Beweis für seine Konstitution erbracht.
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  • 44
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    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 36-39 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Lewis-Säuren sowie Silicagel bewirken bei Anilen bestimmter Konstitution eine Polarisierung in Richtung der dipolaren Grenzformel. Dieser Effekt ist mit einer bedeutenden Farbvertiefung verbunden. Es werden die konstitutionellen Voraussetzungen der Erscheinung erörtert.
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  • 45
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    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 203-213 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die optimalen Reaktionsbedingungen für die Cyclisierung der N-Lithium-Derivate der sekundären Amine I, II, IX und X mit m- bzw. o-ständigem Chlor zu den in der Überschrift genannten Heterocyclen werden ermittelt. Im Gegensatz zur stets intramolekularen Basen-Addition an die intermediären Arine sind für die Freisetzung der Arine, also für den geschwindigkeitsbestimmenden Teilschritt, inter- und intramolekulare Chemismen zu diskutieren. Die experimentellen Daten weisen für N-Lithium-I und -II auf eine Hilfestellung zugesetzten, komplex-gebundenen Lithiumdiäthylamids bei der Arin-Bildung.
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  • 46
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    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 338-343 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Benzil und substituierte Benzile lassen sich mit Formamid und Aldehyden, ebenso mit Formamid in Gegenwart von Ameisensäure und reduzierenden Schwefelverbindungen, in substituierte Imidazole überführen.
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  • 47
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die bei der direkten Nitrierung von n-Hexatriacontan nach drei verschiedenen Verfahren entstehenden Mononitrohexatriacontane sind identische Gemische sämtlicher theoretisch möglicher Stellungsisomeren. Ausschließliche Bildung von 2-Nitro-hexatriacontan findet entgegen den Befunden von NAMETKIN und Mitarbb. nicht statt.
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  • 48
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    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 320-328 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Aus den Blättern von Crataegus oxyacantha L. wurden zwei neue Triterpencarbonsäuren, Acantholsäure, C30H48O5, und Neotaegolsäure, C30H48O4, isoliert. Crataegolsäure wurde als ein Derivat der β-Amyrin-Reihe erkannt. Ein papierchromatographisches Verfahren zur Trennung von Triterpensäuregemischen wird beschrieben; das angegebene Lösungsmittelgemisch ließ sich erfolgreich auch für eine Verteilungschromatographie an der Cellulosesäure verwenden.
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  • 49
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Chloramin T läßt sich mit Sulfenamiden und besonders glatt mit Sulfenyl-amidinen und verwandten Verbindungen kondensieren. Die Reaktionsprodukte werden als Derivate von Sulfinsäureamid-imiden aufgefaßt.
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  • 50
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    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 22-36 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: CH-Acide Verbindungen wie Chinaldin, Lepidin, 9-Methyl-acridin, die drei Acetylpyridine, Aceton, 2.4-Dinitro-toluol und ein Phenacyl-thioäther werden nach KING mit Jod/Pyridin, teilweise auch mit Jod/Thioharnstoff umgesetzt; mit einigen der so erhaltenen Salze werden Ringschluß-Reaktionen vollzogen. Mit Brom/Pyridin gelingt die King-Reaktion nur in wenigen Fällen. Mittels der Umsetzung mit p-Nitroso-dimethylanilin sowie der nach King wird gezeigt und begründet, daß die Reaktivität der Methylgruppe in der Reihe α- und γ-Picolin → Chinolin/Lepidin → 9-Methyl-acridin zu-, daß sie aber in deren Halogenalkylaten in der gleichen Reihenfolge abnimmt. Es werden Benzologe eines von BERSON und COHEN bei ihrer Pyridonsynthese angenommenen Zwischenproduktes in kristallisierter Form gefaßt.
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  • 51
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 407-414 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Nitro-benzoxazolone reagieren mit Diazomethan, Carbonsäure- und Sulfonsäurechloriden nur in der Lactamform. Durch die Nitrogruppe in verschiedenen Stellungen des Benzolringes werden die NH-Acidität und die Spaltbarkeit des Heteroringes beeinflußt. Im 4-Nitro-benzoxazolon ist die 3-Stellung durch die Nitrogruppe sterisch behindert.
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  • 52
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    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 429-441 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Das am N-Methyl-indolin und N-Methyl-tetrahydrochinolin ausgearbeitete Syntheseprinzip läßt sich auf andere Heterocyclen übertragen. Chlor- oder Brombenzol-Derivate mit o- oder m-ständiger basisch-substituierter Seitenkette werden inter- oder intramolekular in das Arin übergeführt; die anschließende intramolekulare Basen-Addition liefert unter Ringschluß tertiäre Amine: N-Phenyl-tetrahydrochinolin, N-Methyl-phenmorpholin, N.N′-Dimethyl-tetrahydrochinoxalin und N.N′-Dimethyl-indazolin. Auch die erfolgreiche Schließung eines 8 gliedrigen Ringes wird beschrieben.
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  • 53
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    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 468-471 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die unter verschiedenen Bedingungen durchgeführte Cyclisierung des im Titel genannten Esters wird beschrieben.
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  • 54
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    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 474-482 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Darstellung sowie physikalische und chemische Eigenschaften eines neuen stabilen Aroxyls. des 4-Phenyl-2.6-di-tert.-butyl-phenoxyls-(1) werden beschrieben. Die 4-ständige Phenylgruppe dieses Aroxyls bedingt, verglichen mit 2.4.6-Tri-tert.-butyl-phenoxyl-(1) und ähnlichen Verbindungen, einige Besonderheiten im reaktiven Verhalten dieses freien Radikals.
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  • 55
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 213-218 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die durch Hydrierung von Dihydrogallussäure erhältliche 3.4.5-Trihydroxy-cyclohexan-carbonsäure-(1) vom Schmp. 203〉 erweist sich durch Lactonbildung und Abbau zum γ-Pyrogallit als all-cis-Isomeres.
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  • 56
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    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 535-540 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Kohlenstoffkette der (+)-Weinsäure wird an dem einen Ende über das Diazoketon verlängert. Die neue Ketogruppe liefert durch nochmalige Reaktion mit Diazomethan eine Kettenverzweigung, worauf durch Abbau nach RUFF an dem anderen Ende der Weinsäure L-Apiose entsteht.
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  • 57
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    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 606-615 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 1- bzw. 3-Cyan-azulene lassen sich aus Azulenaldoximen durch Wasserabspaltung mit Acetanhydrid darstellen. Verschiedentlich tritt daneben eine Umlagerung des Oxims zur Acetaminoverbindung ein. Bei Umsetzung von Azulenen mit Bromcyan entstehen Nitrile durch direkte Substitution. Die Nitrile sind sehr reaktionsträge Verbindungen. Ihre Inaktivität wird durch eine polare Struktur erklärt. Die spektralen Verschiebungen gegenüber den zugrundeliegenden Azulenen und die Halbstufenpotentiale werden angegeben.
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  • 58
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    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 637-644 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Darstellung des 3-Aza-chinolizidins und des von diesem sich ableitenden tricyclischen Systems mit zwei Brückenstickstoffatomen, des Perhydro-dipyrido-[1.2-a, 1′.2′-c]pyrimidins (4a.8a-Diaza-perhydrophenanthrens) wird beschrieben.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 667-673 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Am Beispiel der Bildung von 3-Carbäthoxy-2-methyl-6.7-benzo-indolchinon-(4.5) (VI) aus 5-Hydroxy-3-carbäthoxy-2-methyl-6.7-benzo-indol (II) wird gezeigt, daß die Zwischenstufe eines Substitutionsprodukts (III) durchlaufen wird, das als solches isoliert und zum erwarteten Chinon zerlegt werden kann.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 693-699 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die UV-Absorption der Jodkomplexe von Cycloolefinen wird gemessen und nach der von LONG und NEUZIL für Olefine entwickelten Methode zur Analyse von Δ1.9- und Δ9.10-Octalingemischen verwendet.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 699-704 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Der Ersatz von organisch gebundenem Chlor und Brom durch den Hydroperoxy-Rest des Wasserstoffperoxyds ist immer dann möglich, wenn das Alkylhalogenid genügend reaktionsfähig im Sinne des SNl-Schemas ist. Komplexbildner können die Reaktion erleichtern.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 732-735 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Ausgehend von Methantriessigsäure wurde ein Tris diazoketon hergestellt. Die hieraus mit Halogenwasserstoffsäuren primär gebildeten Halogenketone erleiden eine „intramolekulare Trimerisierung“ der Carbonylgruppen unter Bildung von 1.3.5-Tris-chlormethyl- und 1.3.5-Tris-brommethyl-2.4.9-trioxa-adamantan. Dagegen zeigt das durch Friedel-Crafts-Acylierung des Säurechlorides der Methantriessigsäure mit Benzol erhaltene Triketon der gleichen Struktur keine Tendenz zur Bildung des 2.4.9-Trioxa-adamantan-Ringsystems. Die Trimerisierung der Carbonylgruppen unterbleibt hier wegen der Mesomeriebeteiligung der Carbonylgruppen am aromatischen System.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 776-779 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Aus Anona reticulata Linn. wurde ein neues Alkaloid, Reticulin, isoliert. Reticulin ist ein 2-Methyl-7-hydroxy-6-methoxy-1-[3-hydroxy-4-methoxy-benzyl]-1.2.3.4-tetrahydro-isochinolin, wie durch oxydativen Abbau gezeigt werden konnte.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 791-793 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: α.β-Dibrom-β-[benzthiazolyl-(2)]-propionsäure spaltet unter der Einwirkung von Alkalien keinen Bromwasserstoff, sondern Brom ab. N-Methyl-chinolon, N-Methyl-chinoliniumjodid und N.N′-Dimethyl-benzimidazolon reagieren mit den Monometallverbindungen des Acetylens nicht. Dagegen gelang die Umsetzung von 2-Chlor-benzoxazol mit Acetylen-natrium zum 2-Äthinylbenzoxazol.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 793-806 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Brenztraubensäure besitzt in komplexer Bindung eine Reihe von Eigenschaften, die von der freien Säure nicht bekannt sind. So nimmt das Substitutionsvermögen gegenüber Halogen namentlich bei Gegenwart von guten Komplexbildnern beträchtlich zu. Im Falle der Jodsubstitution konnte die Abhängigkeit der Substitutionsgeschwindigkeit von der Komplexstabilität bewiesen und damit ein Einblick in die Struktur der als Liganden fixierten Brenztraubensäuremoleküle gewonnen werden.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 855-857 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Durch Umsetzung von SCl2 bzw. S2Cl2 mit S7NH konnten die Schwefelnitride S15N2 und S16N2 als kristallisierte Substanzen gewonnen werden. Von diesen ist besonders S15N2 resonanzstabilisiert.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 869-871 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Chlorierung des 2-Mercapto-thiazolo[4.5-b]- und -[5.4-b]chinolins in Essigsäure führt zu den entsprechenden 2-Chlorderivaten. Die Chloratome erwiesen sich als sehr labil und lassen sich leicht durch verschiedene nucleophile Substituenten ersetzen.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 982-986 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Am Triacetsäurelacton werden Substitutionsreaktionen in 3-Stellung durchgeführt. Bei der Einwirkung von Benzoldiazoniumchlorid entsteht das 3-Phenyl-Derivat; Aryl-bzw. Aryl-alkyl-carbinole und Aralkylhalogenide reagieren beim Zusammenschmelzen mit Triacetsäurelacton zu den entsprechenden 3-Substitutionsprodukten. Die C-3-Acylierung gelingt in Gegenwart von wasser-freiem Aluminiumtrichlorid.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 998-999 
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 977-981 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die 2-[α-Amino-alkyl]-benzimidazole Ia bis IVa lassen sich mit guten Ausbeuten durch Kondensation von o-Phenylendiamin mit den N-p-Tosyl- oder N-Carbobenzoxy-Derivaten von Amino-iminoäther-hydrochloriden und nach-folgende Abspaltung der Tosyl- bzw. der Carbobenzoxy-Gruppe darstellen. Bei Verbindungen mit verzweigtem Alkyl-Rest tritt als Konkurrenz-Reaktion zum Benzimidazol-Ringschluß die Zersetzung des Iminoäther-hydrochlorids zum Säureamid ein.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. XXIX 
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    Keywords: Chemistry ; Inorganic Chemistry
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 986-988 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Bei der Einwirkung von Phosgen auf Arylacetyl-acetessigester in Gegenwart von Pyridin entstehen nicht die erwarteten 3-substituierten 4-Hydroxypyrone-(2), sondern die cyclischen Kohlensäureester der Dienolformen der Arylacetyl-acetessigester.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 988-998 
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 2.2-Dimethyl-chinuclidon-(6) wird durch eine 12 stufige Synthese in racemischer und optisch aktiver Form dargestellt. Dieses „Lactam“ ist aus sterischen Gründen keiner Säureamidmesomerie fähig. Die sich daraus ergebenden Eigenschaften  -  Basizität, Reaktivität und spektrales Verhalten  -  werden untersucht und diskutiert.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1012-1018 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die kontinuierliche Dampfphasen-Dehydrochlorierung von Halogenalkyl-chlorsilanen zur Darstellung von Vinyl-trichlorsilan (VII) und Methyl-vinyl-dichlorsilan (XIII) wird auf Chlorpropyl-trichlorsilane übertragen. Es wird ferner über ein sehr einfaches Verfahren zur Gewinnung von Allyl- (I), Propenyl- (II), sowie Crotyl-trichlorsilan (IV) aus den entsprechenden Chloralkyl-trichlorsilanen berichtet. Sie entstehen aus den Chloralkyl-chlorsilanen durch Behandeln mit „großoberflächigen“ Stoffen, wie Silicium-, Kupfer- oder Eisenpulver bei oder unterhalb ihrer Siedetemperaturen.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1042-1048 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Dipolmomente und UV-Spektren von Thionylanilinen weisen darauf hin, daß die NS-Bindung in diesen Substanzen als Vierelektronenbindung aufgefaßt werden kann, die mit benachbarten π-Elektronensystemen in Wechselwirkung tritt.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1092-1101 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Substituierte Ammoniumsalze vom Typ I liefern mit Abkömmlingen des Phenylglyoxals in Methanol in glatter Reaktion Lactolid-Basen vom Typ II. Aus diesen lassen sich verschiedene Octa- bzw. Decahydroisochinolin-Derivate darstellen, die in 1-Stellung einen substituierten Benzylrest tragen.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1105-1112 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es werden 2-[p-Aminosulfonyl-phenylhydrazino]-thiazole beschrieben, die durch Kondensation von 1-[p-Aminosulfonyl-phenyl]-thiosemicarbazid mit α-Halogen-carbonylverbindungen in äthanol. Lösung zugänglich sind. Führt man die gleichen Umsetzungen mit Chloraceton bzw. ω-Chlor-acetophenon in konz. Salzsäure durch, so entsteht das 3-[p-Aminosulfonyl-anilino]-4-methyl-thiazolon-(2)-imid bzw. das 2-Amino-4-[p-aminosulfonyl-phenyl]-5-phenyl-1.3.4-thiodiazin. Ersteres sowie das 3-[p-Aminosulfonyl-anilino]-4.5-dimethyl-thiazolon-(2)-imid lassen sich auch aus Rhodanaceton bzw. 3-Rhodan-butanon-(2) und p-Aminosulfonyl-phenylhydrazin-hydrochlorid darstellen. Dagegen erhält man aus ω-Rhodan-acetophenon und p-Aminosulfonyl-phenylhydrazin-hydrochlorid das Phenylglyoxal-bis-[p-aminosulfonyl-phenylhydrazon].
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1126-1129 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Tachysterin2 wurde mit durch Glas gefiltertem Quecksilberdampflicht in Präcalciferol2 umgewandelt.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1149-1152 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Durch Anwendung des Verdünnungsprinzipes gelang es, aus primären Aminen und S2Cl2 N.N′-Dialkyl-cyclotetraschwefeldiimide(1) in guter Ausbeute herzustellen. 5 Vertreter dieser Verbindungsklasse wurden als farblose, wohlkristallisierte Verbindungen gewonnen.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1158-1163 
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Von den sechs möglichen Isomeren des Decalindiols-(1.4) wurden zwei der Reihe des cis-Decalins und zwei der Reihe des trans-Decalins angehörende Diole durch Reduktion von cis- und trans-Decalindion-(1.4) sowie durch katalyt. Hydrierung von Naphthohydrochinon-(1.4) und ar-Tetralindiol-(5.8) mit Raney-Nickel im Autoklaven erhalten, eindeutig der cis- und trans-Reihe zugeordnet und durch Derivate charakterisiert.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1177-1184 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Anlagerung von Adipinsäure-äthylester-chlorid an Acetylen, Umsetzung mit alkoholischer Lauge und Hydrieren des β-Dicarbonylderivates lieferte 6-Hydroxy-8-methoxy-octansäure-(1)-äthylester (XIII) (Syntheseweg A).  -  Umsetzung von Äthyl-vinyl-äther mit dem Acetal des Adipinaldehydsäure-äthylesters und folgende Hydrierung führte zu 6.8-Diäthoxy-octansäure-(1)-ester (XXIV) (Syntheseweg B).  -  XIII und XXIV wurden über das 6.8-Bisisothiuroniumsalz in d,l-α-Liponsäure umgewandelt. Die guten Ausbeuten beim Einsatz von in 6-Stellung acetylierten 6.8-Dihydroxy-octansäure-Derivaten gestatteten Rückschlüsse auf den Chemismus der Solvolyse sekundärer Ester.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1212-1215 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Aus cyclischen Ketonen und sekundären Aminen erhältliche α.β-ungesättigte Amine addieren Wasserstoffperoxyd an der Doppelbindung und geben kristalline Peroxyde.
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    Keywords: Chemistry ; Inorganic Chemistry
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    Topics: Chemistry and Pharmacology
    Notes: Als weiteres Beispiel für die präparative Überlegenheit der säurekatalysierten Aldolreaktionen des Formaldehyds gegenüber den OH⊖-katalysierten wird über die Synthese der bisher unbekannten Bisanhydro-ennea-heptose, die das Ringsystem des 3.7-Dioxa-bicyclo-[1.3.3]-nonans enthält, berichtet.  -  Bei der Untersuchung des Verhaltens der Bisanhydro-ennea-heptose gegen Alkalien machten sich in der Abspaltbarkeit der Hydroxymethylgruppen charakteristische Unterschiede geltend, deren Erklärung in den konstitutionell-konstellativen Gegebenheiten zu suchen ist.  -  Bei dem Versuch einer Ringerweiterung an der Anhydro-ennea-heptose mit Diazomethan bildet sich eine Verbindung C9H16O5, die wahrscheinlich kein Derivat des Oxa-cycloheptanons-(4), sondern ein Derivat des Tetrahydro-γ-pyrons ist.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1112-1114 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Autoxydation des N-Benzyl-dihydro-nicotinamids wird in Gegenwart von Flavinen durch einige Metall-Chelate des Sulfosalicylaldehyd-äthylendiimins erheblich beschleunigt.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1258-1262 
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: In der Methylengruppe monosubstituierte β-Dicarbonylverbindungen können durch Umsetzung mit Diacylimido-chlormethanen amidomethyliert werden.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1313-1319 
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Methylphenylhydrazone der Monobenzoyl-aldosen liegen im kristallisierten und gelösten Zustand nur als Schiffsche Basen vor, sie zeigen keine Mutarotation und lassen sich zu 5-Benzoyl-2.3.4-triacetyl-pentose- bzw. 6-Benzoyl-2.3.4.5-tetraacetyl-hexose-methylphenylhydrazonen acetylieren, deren Struktur durch Synthese bewiesen wird. Die aus Monobenzoyl-aldose-phenylhydrazonen mit Phenylhydrazin darstellbaren Monobenzoyl-aldose-phenylhydrazonen werden sehr leicht zu Aldose-phenylosazonen und Benzoesäure hydrolysiert.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1329-1335 
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Darstellung des Monobrom-, Monojod- und Trimethoxy-pivalophenons werden beschrieben. Die Halogenverbindungen erleiden bei der Einwirkung wäßriger Alkalien eine hydrolytische Spaltung. Die Methoxyverbindung ist gegen Alkalien stabil.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1366-1375 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Zur Darstellung der 8-Methyl-acenaphthen-essigsäure-(3) (X) eignet sich die aus 7-Methyl-tetralon-(1) erhaltene 7-Methyl-tetralon-(1)-essigsäure-(2) nicht. X ist aber aus 7-Methyl-naphthalin-dicarbonsäure-(1.2)-anhydrid in einer 6 stufigen Reaktionsfolge zugänglich. Seine Überführung in das Methyl-cholanthren (XII) gelingt analog der Pschorrschen Phenanthrensynthese. Eine andere Synthese von XII führt über die Kondensation des 8-Methyl-3-[β-brom-äthyl]-acenaphthens mit Cyclohexanon-(1)-carbonsäure-(2)-äthylester zum Ziel.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1386-1397 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Durch Oxydation von Tetralol-(6) und Östradiol-17-monoacetat mit Bleitetraacetat werden Tetralin-p-chinolacetat und 17β-Acetoxy-östra-p-chinol-(10ζ)-acetat dargestellt. Aus den Chinolacetaten lassen sich die Chinole durch basenkatalysierte Umesterung in Freiheit setzen. Dem aufgezeigten Weg kommt allgemeine Bedeutung zur Darstellung von p-Chinolen zu.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1427-1437 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Umsetzung von Methylestern ungesättigter Fettsäuren mit Quecksilber(II)-acetat in Methanol führt zu relativ beständigen Addukten. Der geschwindigkeitsbestimmende Schritt der Reaktion folgt dem Gesetz der 2. Ordnung. Diskontinuierliche Gegenstromverteilung ermöglicht nach der Adduktbildung ungesättigter Fettsäuremethylester deren nahezu quantitative Abtrennung aus Gemischen mit gesättigten Fettsäureestern. Die Trennung cis-trans-isomerer ungesättigter Fettsäuren über ihre Quecksilberaddukte gelingt ebenfalls mit hohem Reinheitsgrad und befriedigender Ausbeute auf Grund ihrer unterschiedlichen RG. cis-trans-Isomerisierung wurde hierbei bisher nur in sehr geringem Ausmaß beobachtet.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1478-1480 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Umsetzung von Chlorameisensäure-benzylester mit überschüssigem Hydrazinhydrat in absol. Chloroform ergibt Carbobenzoxy-hydrazin. In wäßrigem Medium entsteht vorwiegend N.N′-Dicarbobenzoxy-hydrazin (I), das von rauchender Salpetersäure leicht zu Azodicarbonsäure-dibenzylester (II) dehydriert wird.
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  • 92
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: α-Methylmercapto-acrylsäure-methylester läßt sich bei Temperaturen von 100-150° in ein Dimeres umwandeln, dem auf Grund der sauren Hydrolyse zu α-Keto-α′-methylmercapto-adipinsäure, der alkalischen Hydrolyse zu α-Methylmercapto-muconsäure und der entschwefelnden Hydrierung zu Adipinsäure-diester die Struktur eines α.α′-Bis-methylmercapto-dihydromuconsäureesters zukommt. Ein neues Isomeres des Methionins, α-Methylmercapto-β-amino-buttersäure, wird durch Addition von Ammoniak an α-Methylmercapto-crotonsäuremethylester dargestellt.
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  • 93
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1517-1523 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Umsetzung von 1.3.5-Trinitro-benzol mit Nitrophloroglucin sowie diejenige von Pikrinsäure mit Phloroglucin führt zu polycyclischen Verbindungen. Deren adamantanartige Konstitution wird auf Grund UV-spektroskopischer Vergleiche diskutiert.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1526-1538 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Umsetzung von Schwefelwasserstoff mit Schwefeltrioxyd ohne Lösungsmittel oder in Frigen liefert bei -78° nur ein weißes Addukt, das im Vakuum wieder quantitativ in seine Bestandteile zerfällt.  -  Reaktion von Schwefelwasserstoff mit Chlorsulfonsäure bei -78° ergibt solvatfreie Thioschwefelsäure H2S2O3, die dabei als in flüssiger Luft glasig erstarrendes öl anfällt.  -  Die gleiche Verbindung kann durch Umsetzung von Chlorwasserstoff mit Natriumthiosulfat in Methylenchlorid, Methylbromid und Aceton dargestellt werden. Sie ist thermisch unbeständiger als das durch Oxoniumsalzbildung stabilisierte ätherat H2S2O3·2R2O.  -  Die Ursachen der Bildung von Trithionsäure neben Thioschwefelsäure aus Na2S2O3 und HCl bei Feuchtigkeitsausschluß in Äther werden unter Annahme der Mitwirkung saurer Thiosulfate diskutiert.
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  • 95
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1573-1578 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Der durch Säuren katalysierte Isochinolin-Ringschluß ist unter bestimmten Bedingungen auch mit Substanzen durchführbar, die eine säureempfindliche Gruppe enthalten. Auf diese Weise lassen sich Enoläther bzw. Acetale des Decahydroisochinolons herstellen (XII bzw. XIII), die durch nachfolgende Hydrolyse das freie α.β-ungesättigte Ringketon (XVI) liefern, das man durch direkten Ringschluß nicht erhalten kann.
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  • 96
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1587-1593 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Bei der Anlagerung von Ammoniak an Shikimisäure (I) entstehen vorwiegend zwei stereoisomere Aminosäuren der Konstitution III und IV.
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  • 97
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: α-Halogenierte Amine des Typs R—CHCl—NR2 entstehen durch Spaltung von Aminalen (1) aliphatischer oder aromatischer Aldehyde mit Halogenwasserstoff oder durch Umsetzung von Enaminen (XIII) mit Halogenwasserstoff.
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  • 98
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1614-1617 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Durch Knoevenagel-Kondensation von 2.3;4.5-Diisopropyliden-al-D-arabinose mit Acetessigester, Malonester, Cyanessigester und Benzoylaceton werden Zuckerderivate mit verlängerter und verzweigter Kohlenstoffkette gewonnen, die teilweise mit Lithiumaluminiumhydrid reduziert werden.
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  • 99
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1635-1637 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Beim fraktionierten Umkristallisieren von Mannose-[1-T]-phenylhydrazon und Glucose-[1-T] werden Isotopeneffekte beobachtet, die durch die in den Lösungen ablaufenden Isomerisierungen erklärt werden.
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  • 100
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1654-1657 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: (±)-Corypalmin und (±)-Isocorypalmin wurden nach einer vereinfachten Methode zur Darstellung von Tetrahydro-protoberberinen synthetisiert.
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