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  • American Geophysical Union  (5,644)
  • 2005-2009  (5,644)
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  • 1
    Publication Date: 2017-04-04
    Description: Sulphur speciation in volcanic gases acts as a major redox buffer, and H2S/SO2 ratios represent a valuable indicator of magmatic conditions and interactions between magmatic and hydrothermal fluids. However, measurement of H2S/SO2 even by direct sampling techniques, is not straightforward. We report here on application of a small ultraviolet spectrometer for real-time field measurement of H2S and SO2 concentrations, using open-path and extractive configurations. The device was tested at fumaroles on Solfatara and Vulcano, Italy, in November 2002. H2S concentrations of up to 220ppmm(400 ppmv) were measured directly above the Bocca Grande fumarole at Solfatara, and H2S/SO2 molar ratios of 2 and 2.4, respectively, were determined for the ‘F11’ and ‘F0’ fumaroles at Vulcano. In comparison with other optical techniques capable of multiple volcanic gas measurements, such as laser and FTIR spectroscopy, this approach is considerably simpler and cheaper, with the potential for autonomous, sustained hightime resolution operation.
    Description: Published
    Description: 1652
    Description: partially_open
    Keywords: Remote monitoring ; Plume chemistry ; sulphur species ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 2
    Publication Date: 2017-04-04
    Description: Postseismic relaxation is modeled for the Irpinia earthquake, which struck southern Italy in 1980. Our goal is to understand the mechanism of surface deformation due to stress relaxation in the deep portion of the crust-lithosphere system for a shallow normal fault source and to infer the rheological properties of the lithosphere in the extensional environment of peninsular Italy. The modeling is carried out within the framework of our normal mode viscoelastic theory at high spatial resolution in order to accurately resolve the vertical surface displacements for a seismic source. The slip distribution over the faults is first inverted from coseismic leveling data, the misfit between observed and modeled vertical displacements being minimized by means of the L2 norm. Slip distribution is then used within the viscoelastic model to invert for the viscosities of the lower crust and generally of the lithosphere. Inversion is based on leveling data sampled along three lines crossing the epicentral area. Postseismic deformation in the Irpinia area is characterized by a broad region of crust upwarping in the footwall of the major fault and downwarping in the hanging wall that is responsible for the long-wavelength features of the vertical displacement pattern. The c2 analysis indicates that the Irpinia earthquake cannot constrain the rheology of the upper mantle but only of the crust; a full search in the viscosity spaces makes it possible to constrain the crustal viscosity to values of the order of 1019 Pa s, in agreement with previous studies carried out in different tectonic environments.
    Description: Published
    Description: 1-16
    Description: partially_open
    Keywords: Lithospheric rheology ; Irpinia earthquake ; 04. Solid Earth::04.01. Earth Interior::04.01.05. Rheology ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.05. Stress
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  • 3
    Publication Date: 2017-04-04
    Description: The northern Apennines of Italy are characterized by a complex Tertiary tectonic history, where superposed compressional and extensional deformation occurred. In such regions, characterized by low active extensional strain rate, the coseismic surface ruptures are rare and often a matter of much debate resulting in a difficult connection between ‘‘geological’’ faults (i.e., faults which can be mapped at the surface) and ‘‘seismological’’ faults (i.e., faults which actually generate earthquakes). The availability of detailed geological mapping and high-resolution seismological data for the Colfiorito area, struck in 1997 by a sequence of six 5 〈 Mw 6 normal faulting earthquakes, allow us to compare and verify the existence of geometric and kinematic correspondence between the mapped geological Quaternary faults and the activated structures. In map view, the earthquakes distribution reflects the fault pattern mapped at the surface, the length of activated and mapped faults is quite similar (7–10 km), the coseismic subsided region imaged by interferometric synthetic aperture radar data, is located in the hanging wall of the mapped normal faults that bound the Quaternary basins. In section view, there is a geometric connection between mapped normal faults and the aftershock alignments used to image fault geometry at depth. Comparison of striated fault planes and aftershock focal mechanism solutions show a strong kinematic consistency. This study points out that the Quaternary tectonosedimentary evolution and the present-day geological and geomorphologic setting of the Colfiorito area can be interpreted as the result of repeated, extensional earthquakes, similar to the 1997 events, occurring on NW-SE trending normal faults. Our data also show that the main shocks of the Colfiorito sequence nucleated close to the intersections between the normal faults and the preexisting compressional/transpressional structures, which in 1997 acted as lateral barriers to rupture propagation and consequently constrained the fault size.
    Description: Published
    Description: TC1002
    Description: reserved
    Keywords: faults ; colfiorito 1997 ; 04. Solid Earth::04.06. Seismology::04.06.01. Earthquake faults: properties and evolution
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  • 4
    Publication Date: 2017-04-04
    Description: The active tectonics at the front of the Southern Apennines and in the Adriatic foreland is characterized by E-W striking, right-lateral seismogenic faults, interpreted as reactivated inherited discontinuities. The best studied among these is the Molise-Gondola shear zone (MGsz). The interaction of these shear zones with the Apennines chain is not yet clear. To address this open question we developed a set of scaled analogue experiments, aimed at analyzing: 1) how dextral strike-slip motion along a pre-existing zone of weakness within the foreland propagates toward the surface and affects the orogenic wedge; 2) the propagation of deformation as a function of displacement; 3) any insights on the active tectonics of Southern Italy. Our results stress the primary role played by these inherited structures when reactivated, and confirm that regional E-W dextral shear zones are a plausible way of explaining the seismotectonic setting of the external areas of the Southern Apennines.
    Description: INGV, Università degli Studi di Pavia
    Description: Published
    Description: 21
    Description: open
    Keywords: Active strike-slip fault ; sandbox model ; southern Italy ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes ; 04. Solid Earth::04.03. Geodesy::04.03.01. Crustal deformations ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.06. Seismology::04.06.01. Earthquake faults: properties and evolution ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics
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  • 5
    Publication Date: 2017-04-04
    Description: Strong electrical signals that correspond to the Mw = 9.3 earthquake of 26 December 2004, which occurred at 0058:50.7 UTC off the west coast of northern Sumatra, Indonesia, were recorded by an electrostatic sensor (a device that detects short-term variations in Earth’s electrostatic fi eld) at a seismic station in Italy, which had been installed to study the infl uence of local earthquakes on a new landslide monitoring system. Electrical signals arrived at the station practically instantaneously and were detected up to several hours before the onset of the Sumatra earthquake (Figure 1) as well as before local quakes. The corresponding seismic signals (p-waves) arrived 740 seconds after the start of the earthquake. Because the electrical signals travel at the speed of light, electrical monitoring for the global detection of very strong earthquakes could be an important tool in signifi cantly increasing the hazard alert window.
    Description: Published
    Description: 445-460
    Description: open
    Keywords: Sumatra earthquake ; electrostatic signals ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics
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  • 6
    Publication Date: 2017-04-04
    Description: Combining tectonics, with seismological and geochemical data, we reconstruct the deformation history of the presently narrow Calabrian slab and the path of mantle circulation during the last 10 Ma. We show that during the slab deformation the mantle laterally flowed inside the back arc region permitting its retrograde motion and giving a seismological and volcanological record after 1–2 myr.
    Description: Published
    Description: 1-4
    Description: partially_open
    Keywords: mantle circulation ; Calabrian slab ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes ; 04. Solid Earth::04.01. Earth Interior::04.01.03. Mantle and Core dynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.04. Plate boundaries, motion, and tectonics ; 04. Solid Earth::04.07. Tectonophysics::04.07.06. Subduction related processes
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  • 7
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    American Geophysical Union
    Publication Date: 2017-04-04
    Description: A circular dome from Lipari Island consists of latitic enclaves hosted in a rhyolitic magma. A strain analysis of the enclaves has been carried out and the pure shear (a) and simple shear (g) deformation, the vorticity number Wk and flow kinematics are determined. The axial ratio Rf of the enclaves and the angle f between the long axis of the enclaves and the transport direction are measured in 131 sites concentrated in the axial zone (z1), upper-distal zone (z2) and basal zone (z3) of the flow. The f values depict a pattern suggesting endogenous growth. In z1, a/g 〉 1. In z2, 1 〈 a 〈 1.35 and 1.8 〈 g 〈 0.5. In z3, 1 〈 a 〈 1.5 and 0.3 〈 g 〈 2.8. In z1, Wk 〈 0.5. In z2 and z3, Wk 〉 0.8. Lateral stretching due to the upward motion of magma from the conduit prevails in z1. Here the increase of pure shear strain from the bottom to the top reflects strain accumulation due to endogenous growth. z2 and z3 suffer simple shear deformation. In z3, the sense of shear is consistent with the transport direction. An opposite sense of shear characterizes z2. This is due to velocity gradients located in the lower and upper portions of the flow. The kinematics is viscous spreading in z1 and viscous gliding (hyperbolic flow) in z2â z3.Possible rupturing of the exterior may be important in z1, where lateral stretching occurs, and in z3, where g is at a maximum. The effusion rate is 1.93 m3/s. Strain rates calculated using structural data span a range from 1.9 to 5.8.10 6 s 1.
    Description: Published
    Description: 1-10
    Description: partially_open
    Keywords: lava domes ; kinematics ; emplacement mechanism ; strain analysis ; enclaves ; viscous flows ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks
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  • 8
    Publication Date: 2017-04-04
    Description: In winter 1998 a small-aperture (~200 m), four-station array was operating in the middle of the Colfiorito plain. Waveforms of seven small magnitude (2.1 〈 M 〈 3.7) local earthquakes are analyzed in this study. The peculiarity of the array seismograms is a 2-min long duration of the horizontal ground motion. The predominant frequency in the plain is around 1 Hz. In this frequency band, earthquake-induced ground shaking is synchronous for a few seconds during direct S waves; after this time window, wave trains show an increasingly chaotic behavior within the array. The energy variation of the horizontal ground shaking between the array and a nearby rock outcrop exceeds a factor of 500 at 1 Hz. In order to help understanding of observations and construct models for future numerical simulations, the buried structure of the Colfiorito plain has been investigated through seismic refraction profiles and geoelectric measurements. A three-dimensional reconstruction of the basin structure reveals an extremely complex bedrock topography, which is probably a recurrent feature for intermontane basins in tectonically active regions. Apparent velocities and backazimuths in the frequency band 0.5–1.5 Hz indicate that a 180-m deep depression NW of the array is responsible for the generation of edge-diffracted surface (Love) waves. Their arrival to the array breaks the synchronism of vertically reverberating waves which predominate in the first seconds of the S-wave window
    Description: Published
    Description: reserved
    Keywords: site effects ; 3-D basin resonance ; seismic array ; diffraction ; Colfiorito Basin ; 04. Solid Earth::04.06. Seismology::04.06.04. Ground motion
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  • 9
    Publication Date: 2017-04-04
    Description: We integrate geologic, structural, leveling and Differential SAR Interferometry data to show that Vesuvius began to spread onto its sedimentary substratum about 3,600 years ago. Moreover, we model the detected deformation with a solution of the lubrication approximation of the Navier-Stokes equations to show that spreading may continue for about 7,200 years more. Correlation of volcanic spreading with phases of the eruptive activity suggests that Plinian eruptions, which are thought to pose the major hazard, are less likely to occur in the near future.
    Description: Published
    Description: 1-4
    Description: partially_open
    Keywords: Vesuvius ; volcanic activity ; 04. Solid Earth::04.03. Geodesy::04.03.01. Crustal deformations ; 04. Solid Earth::04.03. Geodesy::04.03.07. Satellite geodesy ; 04. Solid Earth::04.03. Geodesy::04.03.08. Theory and Models
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  • 10
    Publication Date: 2017-04-04
    Description: We show over 4 months of 3-component broadband seismometer data from the SN-1 seafloor multidisciplinary observatory, deployed offshore of Eastern Sicily (Italy) at 2105 m b.s.l. The SN-1 spectra show background noise levels above 0.1 Hz similar to levels at a nearby ground station. An important noise source below 0.1 Hz is caused by tilt of the sensor induced by sea currents. Seismic noise levels above 0.01 Hz are strongly dependent on Etna volcanic activity. In spite of these intense noise sources, SN-1 recorded many local, regional and global events. The quality of seismic recordings confirms the validity of the installation procedure and good ground coupling of the 3-component broadband sensor, suggesting that SN-1 can be proposed as permanent observatory in this high seismic and volcanic hazard area.
    Description: 2002-2003 Framework Program of the Italian National Group for the Defense against Earthquakes (GNDT)
    Description: Published
    Description: L07303
    Description: reserved
    Keywords: 04. Solid Earth::04.06. Seismology::04.06.99. General or miscellaneous
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  • 11
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2005. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 110 (2005): C07021, doi:10.1029/2004JC002293.
    Description: In order to simulate the large-scale structure and temporal variability of oceanic heat flux (F w) to the Arctic perennial ice pack, observations of heat in the mixed layer and ice dynamics are compared with parameterizations and climatologies. Long-term drifting platform observations of seawater temperature and salinity (primarily from automated buoys) are used to describe the annual cycle of temperature above freezing (ΔT f) in the mixed layer beneath the ice pack, which are modulated by ice-ocean friction velocities (u*) determined from the platform drifts to produce estimates of F w between 1975 and 1998. On average, ΔT f is not negligible in winter, especially in the Transpolar Drift, which implies a positive F w to the ice pack by means other than solar heating. A parameterization based solely on the solar zenith angle (with a 1 month lag) is found to largely describe the observed ΔT f (with root mean square error of 0.03°C), despite the lack of an albedo or open water term. A reconstruction of F w from 1979 to 2002 is produced by modulating parameterized ΔT f with u* on the basis of daily ice drift estimates from a composite satellite and in situ data set. The reconstructed estimates are corrected for regional variations and are compared to independent estimates of F w from ice mass balance measurements, indicating annual F w averages between 3 and 4 W m−2 depending on the selection of under-ice roughness length in the ice-ocean stress calculations. Although the interannual variations in ΔT f are fixed by the parameterization in the derived reconstruction, the dynamics indicate an overall positive trend (0.2 W m−2 decade−1) in Arctic F w, with the largest variations found in the southern Beaufort Gyre.
    Description: Portions of this work were prepared with funding provided by the International Arctic Research Center and National Science Foundation ARCSS program (grant OPP-0230184). Analysis of the IOEB data was accomplished as part of the IOEB program, which was supported by the Office of Naval Research, High Latitude Program, and Japan Marine Science and Technology Center.
    Keywords: Oceanic heat flux ; Arctic ice pack ; Ice-ocean interactions
    Repository Name: Woods Hole Open Access Server
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  • 12
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2005. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 6 (2005): Q08010, doi:10.1029/2005GC000911.
    Description: We used Secondary Ion Mass Spectrometry (SIMS) ion microprobe to analyze magnesium-to-calcium (Mg/Ca) and strontium-to-calcium (Sr/Ca) ratios of high-Mg calcite loculi within the skeleton of a shallow water gorgonian, Plexaurella dichotoma, from Bermuda. A cross-section of the gorgonian skeleton reveals loculi embedded within proteinaceous gorgonin arranged in concentric rings about the axial core. Viewed in cross-section, the loculi are fan-shaped, 10-140 μm in diameter, and composed of bundles of needle-shaped crystals that appear to radiate out from a calcification center. Discrete sample spots, each 20 μm diameter, were sputtered from successive loculi along a sample track 3 mm long. Over this distance, twenty-five bands of high-low density gorgonin couplets were encountered, estimated to represent the period 1963 to 1988. Mg/Ca ratios show an overall, positive correlation with annual sea surface temperatures (SSTs) that is strongest in the autumn months (October- December). High-resolution analyses along the growth axes of individual loculi reveal low variability and no trend, consistent with our interpretation of seasonal growth of these calcite inclusions. The sensitivity of Mg/Ca to interannual changes in average autumn temperatures is 0.47 mmol/mol per ºC. Conversely, interannual variability in calcite Sr/Ca does not follow the interannual variability in SST and may be influenced primarily by growth rate.
    Description: This study was supported by an Independent Study Award from the Woods Hole Oceanographic Institution No. 270051.81; NERC grant GR3/12800; a WHOI Ocean Life Institute grant to ALC; Bermuda Government, in support of the Benthic Ecology Research Programme at BBSR to SRS. Support for the WHOI Northeast National Ion Microprobe Facility was provided by NSF EAR-9628749.
    Keywords: Gorgonian ; Octocoral ; Mg/Ca ; Sr/Ca ; Sea surface temperature ; Biomineralization ; Growth bands ; SIMS ion microprobe ; Bermuda
    Repository Name: Woods Hole Open Access Server
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  • 13
    Publication Date: 2022-05-25
    Description: Author Posting. @ American Geophysical Union, 2005. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 32 (2005): L23610, doi:10.1029/2005GL024242.
    Description: The distribution of dimethylsulfide (DMS), dimethylsulfoniopropionate (DMSP) and dimethylsulfoxide (DMSO) was examined in lead water in pack ice of the Weddell Sea. Samples were taken by pulling water into a syringe from a series of depths from 0.002 m to 4 m and deeper. Concentrations of DMS, DMSP and DMSO remained low throughout the water column relative to surface water, which was highly enriched. Concentrations of the major sulfur compounds increased by over an order of magnitude during periods with smooth surface water conditions. This increase coincided with a profound stratification of the water column, caused by a decrease in salinity of near surface water. We estimate that the DMS emission from leads and open water in Antarctic sea ice could contribute significantly to the yearly DMS flux from the Southern Ocean.
    Description: This work was financially supported by the Marie Currie Training Site Fellowship (contract number HPMF-CT-2002-01865) and by Natural Environment Research Council, UK (award ref number NER/B/S/2003/00844).
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  • 14
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2005. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 6 (2005): Q08005, doi:10.1029/2005GC000912.
    Description: Submarine lava flows are the building blocks of young oceanic crust. Lava erupted at the ridge axis is transported across the ridge crest in a manner dictated by the rheology of the lava, the characteristics of the eruption, and the topography it encounters. The resulting lava flows can vary dramatically in form and consequently in their impact on the physical characteristics of the seafloor and the architecture of the upper 50–500 m of the oceanic crust. We have mapped and measured numerous submarine channelized lava flows at the East Pacific Rise (EPR) crest 9°–10°N that reflect the high-effusion-rate and high-flow-velocity end-member of lava eruption and transport at mid-ocean ridges. Channel systems composed of identifiable segments 50–1000 m in length extend up to 3 km from the axial summit trough (AST) and have widths of 10–50 m and depths of 2–3 m. Samples collected within the channels are N-MORB with Mg# indicating eruption from the AST. We produce detailed maps of lava surface morphology across the channel surface from mosaics of digital images that show lineated or flat sheets at the channel center bounded by brecciated lava at the channel margins. Modeled velocity profiles across the channel surface allow us to determine flux through the channels from 0.4 to 4.7 × 103 m3/s, and modeled shear rates help explain the surface morphology variation. We suggest that channelized lava flows are a primary mechanism by which lava accumulates in the off-axis region (1–3 km) and produces the layer 2A thickening that is observed at fast and superfast spreading ridges. In addition, the rapid, high-volume-flux eruptions necessary to produce channelized flows may act as an indicator of the local magma budget along the EPR. We find that high concentrations of channelized lava flows correlate with local, across-axis ridge morphology indicative of an elevated magma budget. Additionally, in locations where channelized flows are located dominantly to the east or west of the AST, the ridge crest is asymmetric, and layer 2A appears to thicken over a greater distance from the AST toward the side of the ridge crest where the channels are located.
    Description: This work was supported by NSF grant OCE-9819261 (to H.S., M.A.T., and D.J.F.) as well as the Postdoctoral Scholar Program at the Woods Hole Oceanographic Institution, with funding provided by the Penzance Endowed Discretionary Fund.
    Keywords: Channels ; Lava ; Lava morphology ; Ridge-crest ; Submarine
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  • 15
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2005. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 6 (2005): Q05007, doi:10.1029/2004GC000824.
    Description: The parameter μ describes the 238U/204Pb ratio of an Earth reservoir. Mantle domains labeled HIMU (high μ) originally defined reservoirs with highly radiogenic Pb isotope ratios observed in basalts from a select number of ocean islands, St. Helena in the Atlantic Ocean and the Cook-Austral islands in the South Pacific Ocean. While some authors use the term HIMU in this original sense, others refer to HIMU as a widespread component in many mid-ocean ridge and ocean island basalt (MORB and OIB) sources. Here we show that highly radiogenic Pb isotope signatures in MORB and OIB originate from two different sources. In addition to the classical HIMU component observed at St. Helena and the South Pacific (named HIMU in the following), we define a component with slightly less radiogenic Pb but significantly more radiogenic Sr isotope signatures. This component lies at the extension of the (Atlantic and Pacific) MORB array in a Sr-Pb isotope ratio diagram and is argued to be a ubiquitous component in MORB and many OIB sources. The inferred role of this component in the mantle and its inferred genetic origin closely resemble those originally suggested for a mantle component termed FOZO by Hart and coworkers. By redefining the composition, the origin, and the role of FOZO in the mantle, we establish a simple conceptual framework that explains the isotopic variability in both MORB and OIB with the lowest number of components. OIB are grouped into HIMU-type OIB and basalts from islands that diverge from the MORB-FOZO array toward various isotopically “enriched” compositions (EM). The apparent ubiquity of FOZO in the mantle and the calculated isotopic evolution of compositionally diverse MORB suggest that normal mantle melting and continuous subduction and aging of that crust during recycling through the mantle are the dominant causes of the MORB-FOZO array. In contrast to FOZO, HIMU-type OIB are quite rare, and if an origin by recycling of oceanic crust is also postulated, the production of HIMU sources has to be a special and rare combination of age and composition of subduction-modified recycled oceanic crust.
    Description: This work is partially supported by the Deutsche Forschungsgmeinschaft (DFG grant STR853/1 to A.S).
    Keywords: FOZO ; HIMU ; MORB ; Oceanic basalts ; OIB
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  • 16
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2004. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 5 (2004): Q01003, doi:10.1029/2003GC000607.
    Description: Several hydrographic stations in the vicinity of the Samoa Islands have 3He/4He above the regional background in the depth range of 1500–1800 m, indicating injection of mantle helium from a local hydrothermal source. The highest δ(3He) = 43.4% was detected at 1726-m depth at 15.0°S, 173.1°W in the bathymetric gap between the Samoa Islands and the northern end of the Tonga-Kermadec Arc. The δ(3He) profile at this station decreases to δ(3He) = 26% at 2500-m depth. The relatively shallow depth of the maximum hydrothermal signal suggests a source different from the conventional Pacific basin helium plume centered at 2500 m that is carried westward from the East Pacific Rise. Stations to the west of this locality show a progressive decrease in the maximum δ(3He) values in the depth range of 1480–1790 m out to 169°E. Stations east of the Tonga-Fiji region show lower 3He values (〈26%) at 1700 m and the profiles are dominated by a deeper maximum at 2500 m, presumably the distal traces of hydrothermal input from East Pacific Rise. This pattern in the 3He distribution suggests that the 1700-m deep helium plume is carried in a northwesterly direction some 2000 km from its source near the northern end of the Tonga-Kermadec Arc. At this time very little is known about the source of this hydrothermal plume or the details of its areal extent. Numerous seamounts and rift zones in the region are possible hydrothermal sources for the plume. The summit crater of Vailulu'u, a young seamount at the eastern end of the Samoa chain, was recently discovered to be hydrothermally active at ∼600 m depth [Hart et al., 2000]. However this shallow hydrothermal field on Vailulu'u is an unlikely source for the deeper 1700-m signal. The most likely source would appear to be the extensional zones of the northern Lau Basin system, such as the Mangatolo Triple Junction. Just as the helium plume emanating from Lo'ihi has helped our understanding of the circulation near the Hawaiian Islands [Lupton, 1996], this helium plume in the Tonga-Fiji region has great potential for delineating circulation in this area of the south Pacific.
    Description: This work was supported by the NOAA Vents Program and by Grants OCE91-05884, OCE92-96237, OCE92-96169, and OCE98-20132 of the Ocean Sciences Division of the National Science Foundation.
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    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2004. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 5 (2004): Q01B06, doi:10.1029/2003GC000619.
    Description: We quantitatively analyze the area-age distribution of sedimentary, igneous and metamorphic bedrock based on data from the most recent digital geologic maps of East and Southeast Asia (Coordinating Committee for Coastal and Offshore Geosciences Programmes in East and Southeast Asia (CCOP) and the Geologic Survey of Japan, 1997; 1:2,000,000), published as Digital Geoscience Map G-2 by the Geological Survey of Japan. Sedimentary rocks, volcanic rocks, plutonic rocks, ultramafic rocks and metamorphic rocks cover 73.3%, 8.5%, 8.8%, 0.9%, and 8.6% of the surface area, respectively. The average ages of major lithologic units, weighted according to bedrock area, are as follows: sedimentary rocks (average stratigraphic age of 123 Myr/median age of 26 Myr), volcanic rocks (84 Myr/20 Myr), intrusive rocks (278 Myr/195 Myr), ultramafic rocks (unknown) and metamorphic rocks (1465 Myr/1118 Myr). The variability in lithologic composition and age structure of individual countries reflects the complex tectonic makeup of this region that ranges from Precambrian cratons (e.g., northeast China and North Korea) to Mesozoic-Cenozoic active margins (e.g., Japan, the Philippines, Indonesia and New Guinea). The spatial resolution of the data varies from 44 km2 per polygon (Japan) to 1659 km2 per polygon (Taiwan) and is, on average (490 km2/polygon), similar to our previous analyses of the United States of America and Canada. The temporal and spatial resolution is sufficiently high to perform age-area analyses of individual river basins larger than ∼10,000 km2 and to quantitatively evaluate the relationship between bedrock geology and river chemistry. As many rivers draining tropical, mountainous islands of East and Southeast Asia have a disproportionate effect on the dissolved and particulate load delivered to the world oceans, bedrock geology in such river drainage basins disproportionately affect ocean chemistry.
    Description: Financial support was provided through the U.S. National Science Foundation (NSF-EAR-0125873) to BPE.
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  • 18
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2004. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 5 (2004): Q02003, doi:10.1029/2003GC000626.
    Description: The summit crater of Vailulu'u Seamount, the youngest volcano in the Samoan chain, hosts an active hydrothermal system with profound impact on the ocean water column inside and around its crater (2 km wide and 407 m deep at a 593 m summit depth). The turbidity of the ocean water reaches 1.4 NTU, values that are higher than in any other submarine hydrothermal system. The water is enriched in hydrothermal Mn (3.8 ppb) and 3He (1 × 10−11 cc/g) and we measured water temperature anomalies near the crater floor up to 0.2°C. The hydrothermal system shows complex interactions with the ocean currents around Vailulu'u that include tidally-modulated vertical motions of about 40–50 m, and replenishment of waters into the crater through breaches in the upper half of the crater wall. Inside and outside potential density gradients suggest that hydrothermal venting exports substantial amounts of water from the crater (1.3 ± 0.2 × 108 m3/day), which is in good agreement with fluxes obtained from a tracer release experiment inside the crater of Vailulu'u (0.8 × 108 m3/day [Hart et al., 2003]). This mass flux, in combination with the differences in the inside and outside crater temperature, yields a power output of around 760 megawatts, the equivalent of 20–100 MOR black smokers. The Mn output of 300 kg/day is approximately ten times the output of a single black smoker.
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  • 19
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2004. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 5 (2004): Q10006, doi:10.1029/2004GC000715.
    Description: New results from wide-angle seismic data collected parallel to the central Aleutian island arc require an intermediate to mafic composition for the middle crust and a mafic to ultramafic composition for the lower crust and yield lateral velocity variations that correspond to arc segmentation and trends in major element geochemistry. The 3-D ray tracing/2.5-D inversion of this sparse wide-angle data set, which incorporates independent phase interpretations and new constraints on shallow velocity structure, produces a faster and smoother result than a previously published velocity model. Middle-crustal velocities of 6.5–7.3 km/s over depths of ∼10–20 km indicate an andesitic to basaltic composition. High lower-crustal velocities of 7.3–7.7 km/s over depths of ∼20–35 km are interpreted as ultramafic-mafic cumulates and/or garnet granulites. The total crustal thickness is 35–37 km. This result indicates that the Aleutian island arc has higher velocities, and thus more mafic compositions, than average continental crust, implying that significant modifications would be required for this arc to be a suitable building block for continental crust. Lateral variations in average crustal velocity (below 10 km) roughly correspond to trends in major element geochemistry of primitive (Mg # 〉 0.6) lavas. The highest lower-crustal velocities (and presumably most mafic material) are detected in the center of an arc segment, between Unmak and Unalaska Islands, implying that arc segmentation exerts control over crustal composition.
    Description: Funding for this work was provided by the University of Wyoming Graduate School.
    Keywords: Continental crust ; Crustal geophysics ; Island arc ; Major element geochemistry
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  • 20
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2005. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 110 (2005): B12104, doi:10.1029/2005JB003630.
    Description: We use multichannel seismic reflection data to image the upper crustal structure of 0-620 ka crust along the southern Juan de Fuca Ridge (JdFR). The study area comprises two segments spreading at intermediate rate with an axial high morphology with narrow (Cleft) and wide (Vance) axial summit grabens (ASG). Along most of the axis of both segments we image the top of an axial magma chamber (AMC). The AMC along Cleft deepens from south to north, from 2.0 km beneath the RIDGE Cleft Observatory and hydrothermal vents near the southern end of the segment, to 2.3 km at the northern end near the site of the 1980’s eruptive event. Along the Vance segment, the AMC also deepens from south to north, from 2.4 km to 2.7 km. Seismic layer 2A, interpreted as the basaltic extrusive layer, is 250-300 m thick at the ridge axis along the Cleft segment, and 300-350 m thick along the axis of the Vance segment. However off-axis layer 2A is similar in both segments (500-600 m), indicating ~90% and ~60% off-axis thickening at the Cleft and Vance segments, respectively. Half of the thickening occurs sharply at the walls of the ASG, with the remaining thickening occurring within 3-4 km of the ASG. Along the full length of both segments, layer 2A is thinner within the ASG, compared to the ridge flanks. Previous studies argued that the ASG is a cyclic feature formed by alternating periods of magmatism and tectonic extension. Our observations agree with the evolving nature of the ASG. However, we suggest that its evolution is related to large changes in axial morphology produced by small fluctuations in magma supply. Thus the ASG, rather than being formed by excess volcanism, is a rifted flexural axial high. The changes in axial morphology affect the distribution of lava flows along the ridge flanks, as indicated by the pattern of layer 2A thickness. The fluctuations in magma supply may occur at all spreading rates, but its effects on crustal structure and axial morphology are most pronounced along intermediate spreading rate ridges.
    Description: This study was supported by the National Science Foundation grants OCE-0002551 to Woods Hole Oceanographic Institution, OCE-0002488 to Lamont-Doherty Earth Observatory, and OCE-0002600 to Scripps Institution of Oceanography.
    Keywords: Mid-ocean ridge ; Juan de Fuca ; Crustal structure
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  • 21
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2006. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 7 (2006): Q02005, doi:10.1029/2005GC001054.
    Description: In this paper, we compile the current surface seawater C37 alkenone unsaturation (UK′37) measurements (n=629, −1 to 30°C temperature range) to derive a global, field-based calibration of UK′37 with alkenone production temperature. A single nonlinear “global” surface water calibration of UK′37 accurately predicts alkenone production temperatures over the diversity of modern-day oceanic environments and alkenone-synthesizing populations (T=−0.957 + 54.293(UK′37) − 52.894(UK′37)2 + 28.321(UK′37)3, r2=0.97, n=567). The mean standard error of estimation is 1.2°C with insignificant bias in estimated production temperature among the different ocean regions sampled. An exception to these trends is regions characterized by strong lateral advection and extreme productivity and temperature gradients (e.g., the Brazil-Malvinas Confluence). In contrast to the surface water data, the calibration of UK′37 in surface sediments with overlying annual mean sea surface temperature (AnnO) is best fit by a linear model (AnnO=29.876(UK′37) − 1.334, r2=0.97, n=592). The standard error of estimation (1.1°C) is similar to that of the surface water production calibration, but a higher degree of bias is observed among the regional data sets. The sediment calibration differs significantly from the surface water calibration. UK′37 in surface sediments is consistently higher than that predicted from AnnO and the surface water production temperature calibration, and the magnitude of the offset increases as the surface water AnnO decreases. We apply the global production temperature calibration to the coretop UK′37 data to estimate the coretop alkenone integrated production temperature (coretop IPT) and compare this with the overlying annual mean sea surface temperature (AnnO). We use simple models to explore the possible causes of the deviation observed between the coretop temperature signal, as estimated by UK′37, and AnnO. Our results indicate that the deviation can best be explained if seasonality in production and/or thermocline production as well as differential degradation of 37:3 and 37:2 alkenones both affect the sedimentary alkenone signal.
    Description: C.R. acknowledges funding from the Deutsche Forschungsgemeinschaft (DFG).
    Keywords: Alkenones ; Paleoproxies ; Sea surface temperature ; UK′37
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  • 22
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2005. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 110 (2005): C02009, doi:10.1029/2004JC002311.
    Description: Observations from autumn, 2000, near the shelfbreak front in the Middle Atlantic Bight are used to describe the transition from stratified summer conditions to well-mixed winter conditions over the shelf. During the observational period, the front differed dramatically from climatological conditions, with buoyant Gulf Stream water found shoreward over the sub-surface shelfbreak front. Water mass analysis shows a large number of separate water masses with shelf, slope and Gulf Stream origins. The coolest shelf water was located at the shelfbreak and may be related to “cold pool” water masses observed to the north during summer. Shoreward of this shelfbreak water mass, a mid-shelf front was present which intersected the bottom at the 50 m isobath. High volume transports were associated with both the shelfbreak and mid-shelf fronts. Transport estimates from the cross-shelf sections were approximately 1 Sverdrup, which is large relative to previous estimates of shelf transport. The foot of the front was near the 130 m isobath, much deeper than the climatological position near the 75 m isobath, however this is consistent with a recent theory relating the magnitude of alongshelf transport to the depth at which the front intersects the bottom.
    Description: The authors gratefully acknowledge support from the Duke University - University of North Carolina Oceanographic Consortium for ship time aboard the R/V Cape Hatteras. MSL also gratefully acknowledges support from the Office of Naval Research (N00014-01-1-0260).
    Keywords: Shelfbreak front ; Mid-shelf front ; Shelf transport
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  • 23
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2006. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Paleoceanography 21 (2206): PA2002, doi:10.1029/2005PA001203.
    Description: We estimate tropical Atlantic upper ocean temperatures using oxygen isotope and Mg/Ca ratios in well-preserved planktonic foraminifera extracted from Albian through Santonian black shales recovered during Ocean Drilling Program Leg 207 (North Atlantic Demerara Rise). On the basis of a range of plausible assumptions regarding seawater composition at the time the data support temperatures between 33° and 42°C. In our low-resolution data set spanning ~84–100 Ma a local temperature maximum occurs in the late Turonian, and a possible minimum occurs in the mid to early late Cenomanian. The relation between single species foraminiferal δ18O and Mg/Ca suggests that the ratio of magnesium to calcium in the Turonian-Coniacian ocean may have been lower than in the Albian-Cenomanian ocean, perhaps coincident with an ocean 87Sr/86Sr minimum. The carbon isotopic compositions of distinct marine algal biomarkers were measured in the same sediment samples. The δ13C values of phytane, combined with foraminiferal δ13C and inferred temperatures, were used to estimate atmospheric carbon dioxide concentrations through this interval. Estimates of atmospheric CO2 concentrations range between 600 and 2400 ppmv. Within the uncertainty in the various proxies, there is only a weak overall correspondence between higher (lower) tropical temperatures and more (less) atmospheric CO2. The GENESIS climate model underpredicts tropical Atlantic temperatures inferred from ODP Leg 207 foraminiferal δ18O and Mg/Ca when we specify approximate CO2 concentrations estimated from the biomarker isotopes in the same samples. Possible errors in the temperature and CO2 estimates and possible deficiencies in the model are discussed. The potential for and effects of substantially higher atmospheric methane during Cretaceous anoxic events, perhaps derived from high fluxes from the oxygen minimum zone, are considered in light of recent work that shows a quadratic relation between increased methane flux and atmospheric CH4 concentrations. With 50 ppm CH4, GENESIS sea surface temperatures approximate the minimum upper ocean temperatures inferred from proxy data when CO2 concentrations specified to the model are near those inferred using the phytane δ13C proxy. However, atmospheric CO2 concentrations of 3500 ppm or more are still required in the model in order to reproduce inferred maximum temperatures.
    Description: Funding for this research was provided by the U.S. Science Support Program of the JOI, the Andrew W. Mellon Foundation Endowed Fund for Innovative Research, and Deutsche Forschungsgemeinschaft through the DFG-Research Center Ocean Margins.
    Keywords: Cretaceous ; Temperature ; Carbon dioxide
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  • 24
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2006. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 7 (2006): Q04012, doi:10.1029/2005GC001097.
    Description: We estimate the relative contribution of relict organic matter to the acid-insoluble organic carbon (AIOC) fraction of surface sediments from Ross Sea, Antarctica, on the basis of 14C abundance. The bulk isotopic characteristics of AIOC can largely be explained by simple two-source models of modern and relict organic carbon, when samples are grouped according to two geographical regions, namely, southwestern and south central Ross Sea. This spatial variability in relict organic carbon could be controlled by proximity to the edge of the Ross Ice Shelf and ice drainage areas. Radiocarbon abundance in the AIOC is potentially an excellent tool to estimate the contribution of relict organic carbon in the Antarctic margin sediments.
    Description: This work was partly supported by a grant from Japan Society for the Promotion of Science to N.O.
    Keywords: Ross Sea ; Radiocarbon ; Sediment ; Organic carbon
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  • 25
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2006. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 7 (2006): Q04003, doi:10.1029/2005GC001038.
    Description: The geology and structure of the Cleft Segment of the Southern Juan de Fuca Ridge (JdFR) have been examined using high-resolution mapping systems, observations by remotely operated vehicle (ROV), ROV-mounted magnetometer, and the geochemical analysis of recovered lavas. Bathymetric mapping using multibeam (EM300) coupled with in situ observations that focused on near-axis and flank regions provides a detailed picture of 0 to 400 ka upper crust created at the southern terminus of the JdFR. A total of 53 rock cores and 276 precisely located rock or glass samples were collected during three cruises that included sixteen ROV dives. Our observations of the seafloor during these dives suggest that many of the unfaulted and extensive lava flows that comprise and/or cap the prominent ridges that flank the axial valley emanate from ridge parallel faults and fissures that formed in the highly tectonized zone that forms the walls of the axial valley. The geochemically evolved and heterogeneous nature of these near-axis and flank eruptions is consistent with an origin within the cooler distal edges of a crustal magma chamber or mush zone. In contrast, the most recent axial eruptions are more primitive (higher MgO), chemically homogeneous lobate, sheet, and massive flows that generate a distinct magnetic high over the axial valley. We suggest that the syntectonic capping volcanics observed off-axis were erupted from near-axis and flank fissures and created a thickened extrusive layer as suggested by the magnetic and seismic data. This model suggests that many of the lavas that comprise the elevated ridges that bound the axial valley of the Cleft Segment were erupted during the collapse of a magmatic cycle not during the robust phase that established a new magmatic cycle.
    Description: This research has been partially supported by a NSF grant to M. Perfit (OCE-0221541). M. Tivey acknowledges support from WHOI’s Mellon grant for Independent Study. Support for D. Stakes, T. Ramirez, D. Caress, and N. Maher and for the entire field program was provided by funds to MBARI from the Lucille and David Packard Foundation.
    Keywords: Basalt ; Ridge
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  • 26
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2006. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 7 (2006): Q06016, doi:10.1029/2005GC001109.
    Description: Near-bottom investigations of the cross section of the Atlantis Massif exposed in a major tectonic escarpment provide an unprecedented view of the internal structure of the footwall domain of this oceanic core complex. Integrated direct observations, sampling, photogeology, and imaging define a mylonitic, low-angle detachment shear zone (DSZ) along the crest of the massif. The shear zone may project beneath the nearby, corrugated upper surface of the massif. The DSZ and related structures are inferred to be responsible for the unroofing of upper mantle peridotites and lower crustal gabbroic rocks by extreme, localized tectonic extension during seafloor spreading over the past 2 m.y. The DSZ is characterized by strongly foliated to mylonitic serpentinites and talc-amphibole schists. It is about 100 m thick and can be traced continuously for at least 3 km in the tectonic transport direction. The DSZ foliation arches over the top of the massif in a convex-upward trajectory mimicking the morphology of the top of the massif. Kinematic indicators show consistent top-to-east (toward the MAR axis) tectonic transport directions. Foliated DSZ rocks grade structurally downward into more massive basement rocks that lack a pervasive outcrop-scale foliation. The DSZ and underlying basement rocks are cut by discrete, anastomosing, normal-slip, shear zones. Widely spaced, steeply dipping, normal faults cut all the older structures and localize serpentinization-driven hydrothermal outflow at the Lost City Hydrothermal Field. A thin (few meters) sequence of sedimentary breccias grading upward into pelagic limestones directly overlies the DSZ and may record a history of progressive rotation of the shear zone from a moderately dipping attitude into its present, gently dipping orientation during lateral spreading and uplift.
    Description: This work was supported by NSF grants OCE-9712430 and 0136816 to Karson and Kelley and Swiss SNF grant 2100-068055 to Früh-Green.
    Keywords: Detachment faults ; Faults ; Oceanic core complex ; Seafloor spreading ; Serpentinite ; Shear zones
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  • 27
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2006. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 33 (2006): L13608, doi:10.1029/2006GL026311.
    Description: Austral winter oceanographic measurements from the northwest Australian continental shelf reveal salty water forming evaporatively inshore, moving across the wide shelf near the bottom and into the adjacent open ocean when the shelf edge alongshore flow is equatorward. The salt tongue is absent during more normal conditions, when the poleward Leeuwin Current is present. We hypothesize that the flow reversal enables shelf-wide bottom boundary layer (Ekman) transport and thus creates the shelf-edge convergence that accounts for the observed salt tongue. This flow is absent under sustained normal conditions because of buoyancy arrest in the bottom boundary layer.
    Description: This research was supported by the Processes and Prediction Division (Code 322 PO) of the U.S. Office of Naval Research through grant N00014-02-1-0767.
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  • 28
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2006. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 33 (2006): L14605, doi:10.1029/2006GL026316.
    Description: The Luzon Strait transport, as an index for the South China Sea throughflow, has attracted much attention. In this study the interannual variability of the Luzon Strait transport is examined, using the Island Rule and results from an ocean general circulation model. Transport variability obtained from these two approaches are consistent with each other. Assessment of contribution from each integral segment involved in the Island Rule indicates that wind stress in the western and central equatorial Pacific is the key factor regulating the interannual variability of the Luzon Strait transport, whereas the effect of local wind stress in the vicinity of the Luzon Strait is secondary. Analysis also shows that when the westerly (easterly) wind anomalies in the tropical Pacific break out, the Luzon Strait transport increases (decreases), consistent with the variations in the North Equatorial Current during El Niño (La Niña) events.
    Description: This research was supported by NSF of China (Grants Nos. 40136010 and 40406006). YD and TQ were supported by the National Aeronautics and Space Administration through grant NAG5-12756, and TQ also supported by Japan Agency for Marine-Earth Science and Technology through its sponsorship of the International Pacific Research Center.
    Keywords: Island Rule ; Wind stress ; South China Sea throughflow
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  • 29
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2006. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 7 (2006): Q07011, doi:10.1029/2005GC001178.
    Description: We report 157 closely spaced heat flow measurements along the Lucky Strike segment in the Mid-Atlantic Ridge (MAR) for ages of the ocean floor between 0 and 11 Ma. On the eastern flank of a volcanic plateau delimiting off-axis and axial domains, the magnitude of heat flow either conforms to the predictions of conductive lithospheric cooling models or is affected by localized anomalies. On the western flank it is uniformly lower than conductive model predictions. We interpret the observed patterns of heat flow by lateral fluid circulation in a highly permeable oceanic basement. The circulation geometries are probably 3-D rather than 2-D and are determined by the configuration of the basement/sediment interface and the distribution of effectively unsedimented seamounts where water recharge can occur. Two major hydrothermal circulation systems can possibly explain the observations off-axis: the first would involve lateral pore water flow from west to east, and the second would have a reverse flow direction. The wavelengths and magnitudes of heat flow anomalies require Darcy velocities of the order of 1–4 m/year, which are similar to those proposed for fast-accreted crust elsewhere. However, a large proportion of this MAR domain remains unaffected by hydrothermal cooling, which is a relatively unusual observation but confirms the validity of conductive thermal models for seafloor ages between 5 and 10 Ma. Closer to the ridge axis (〈5 Myr old crust), water circulation affects the overall axial domain, as larger proportions of basement are exposed. As much as 80–90% of the heat flux from the axial domain may be transferred to the Lucky Strike vent field, in agreement with the estimated discharge.
    Keywords: Heat flow ; Mid-Atlantic Ridge
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  • 30
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2006. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 7 (2006): Q11N07, doi:10.1029/2006GC001383.
    Description: The vertical profile of meridional transport in the South Atlantic is examined by combining paleoceanographic observations with a geostrophic circulation model using an inverse method. δ18Ocalcite observations along the margins of the South Atlantic show that upper-ocean cross-basin differences were weaker during the Last Glacial Maximum (LGM) than the Holocene. The δ18Ocalcite observations can be explained by a shift of water-mass properties without any change in the overturning circulation. Alternatively, they may indicate a reduced LGM cross-basin density difference and, via the thermal wind relation, a reduced vertical shear. Model inversions of δ18Ocalcite are found to require meridional transports different from the modern only after three assumptions are made: temperature and salinity distributions are spatially smooth, the relationship between salinity and δ18Owater is linear and spatially invariant, and LGM temperatures are known to within 1°C along the margins. The last assumption is necessary because an independent constraint on temperature or salinity is required to determine density from δ18Ocalcite observations. δ18Ocalcite observations are clearly useful, but before any firm constraints can be placed on LGM meridional transport, it appears necessary to better determine the relationship between δ18Ocalcite and density.
    Description: P.H. was funded by the NOAA postdoctoral program in climate and global change, and G.G. was partially funded by NSF paleoclimate program ATM-0502482.
    Keywords: Inverse modeling ; Last Glacial Maximum ; Meridional ocean circulation ; Geostrophy
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  • 31
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    American Geophysical Union
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2005. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 32 (2005): L18603, doi:10.1029/2005GL023568.
    Description: Strain variance from standard hydrographic profiles in the southern hemisphere oceans shows that turbulent mixing is vertically and spatially non-uniform. In the South Atlantic, Indian and South Pacific Oceans, enhanced diffusivities are found over rough topography. Consistent with internal tide generated mixing, the water column diffusivity returns to background levels 500 m to 1000 m off the sea floor. In the Southern Ocean, enhanced diffusivities throughout the entire water column below 1500 m are found in the Antarctic Circumpolar Current over complex topography. Differences in the vertical extent of enhanced diffusivity profiles in the Antarctic Circumpolar Current between the parameterizations based on tidal models and topography and of the present estimate of strain variance imply that elevated vertical diffusivity profiles in the Southern Ocean are due to the interaction between the mean geostrophic current and bottom topography.
    Description: BMS was supported by the Ocean and Climate Change Institute at the Woods Hole Oceanographic Institution.
    Keywords: Fine structure and microstructure ; Internal and inertial waves ; Turbulence, diffusion, and mixing processes
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  • 32
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2005. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 32 (2005): L08405, doi:10.1029/2005GL022583.
    Description: In this study, we demonstrate that mid-latitude surface measurements of diurnal temperature range (DTR) can be used to reconstruct decadal variability of regional-scale terrestrial photosynthetic activity 1) during and prior to the period with satellite retrievals of land greenness and 2) without the need for moisture data. While the two relative maxima present in the seasonal evolution of DTR can determine the beginning and the end of the growing season, the summertime average DTR can be used as a proxy of summertime terrestrial photosynthesis. In a case study in the eastern United States (1966–1997), the DTR reconstructions indicate significant natural decadal variability in photosynthetic activity, but no secular, long-term trend. The summertime photosynthesis was found to be controlled primarily by moisture availability. Also, contrary to existing model parameterizations, the timing of spring onset was found to depend on both temperature and moisture.
    Description: This work is supported by National Science Foundation grant ATM-9987457, NASA EOS-IDS grants NAG5-9514 and NNG04GK34G, NASA Carbon Cycle Program grant NAG5-11200, and the WHOI Ocean and Climate Change Institute.
    Keywords: Biogeochemical cycles, processes, and modeling ; Water cycles ; Evapotranspiration ; Land/atmosphere interactions ; North America
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  • 33
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2005. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 32 (2005): L10602, doi:10.1029/2005GL022834.
    Description: Ocean surface gravity waves with periods between 20 and 200 s were observed to reflect from a steep-walled submarine canyon. Observations of pressure and velocity on each side of the canyon were decomposed into incident waves arriving from distant sources, waves reflected by the canyon, and waves transmitted across the canyon. The observed reflection is consistent with longwave theory, and distinguishes between cases of normal and oblique angles of incidence. As much as 60% of the energy of waves approaching the canyon normal to its axis was reflected, except for waves twice as long as the canyon width, which were transmitted across with no reflection. Although waves approaching the canyon at oblique angles cannot propagate over the canyon, total reflection was observed only at frequencies higher than 20 mHz, with lower frequency energy partially transmitted across, analogous to the quantum tunneling of a free particle through a classically impenetrable barrier.
    Description: Funding was provided by the Office of Naval Research and the National Science Foundation.
    Keywords: Wave reflection ; Infragravity ; Submarine canyon
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  • 34
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2004. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 5 (2004): Q09F26, doi:10.1029/2004GC000744.
    Description: We present first results of a petrographic study of hydrothermally altered peridotites drilled during Ocean Drilling Program (ODP) Leg 209 in the 15°20′N fracture Zone area on the Mid-Atlantic Ridge (MAR). We find that serpentinization is extensive at all drill sites. Where serpentinization is incomplete, phase relations indicate two major reaction pathways. One is reaction of pyroxene to talc and tremolite, and the other is reaction of olivine to serpentine, magnetite, and brucite. We interpret these reactions in the light of recent peridotite-seawater reaction experiments and compositions of fluids venting from peridotite massifs at a range of temperatures. We suggest that the replacement of pyroxene by talc and tremolite takes place at temperatures 〉350°–400°C, where olivine is stable. The breakdown of olivine to serpentine, magnetite, and brucite is favored at temperatures below 250°C, where olivine reacts faster then pyroxene. High-temperature hydrothermal fluids venting at the Logatchev and Rainbow sites are consistent with rapid reaction of pyroxene and little or no reaction of olivine. Moderate-temperature fluids venting at the Lost City site are consistent with ongoing reaction of olivine to serpentine and brucite. Many completely serpentinized peridotites lack brucite and talc because once the more rapidly reacting phase is exhausted, interaction with the residual phase will change fluid pH and silica activity such that brucite or talc react to serpentine. At two sites we see strong evidence for continued fluid flow and fluid-rock interaction after serpentinization was complete. At Site 1268, serpentinites underwent massive replacement by talc under static conditions. This reaction requires either removal of Mg from or addition of Si to the system. We propose that the talc-altered rocks are Si-metasomatized and that the source of Si is likely gabbro-seawater reaction or breakdown of pyroxene deeper in the basement. The basement at Site 1268 is heavily veined, with talc and talc-oxide-sulfide veins being the most common vein types. It appears that the systems evolved from reducing (oxygen fugacity buffered by magnetite-pyrrhotite-pyrite and lower) to oxidizing (dominantly hematite). We propose that this transition is indicative of high fluid flux under retrograde conditions and that the abundance of hematite may relate to the Ca-depleted nature of the basement that prevents near-quantitative removal of seawater sulfate by anhydrite precipitation. At site 1272 we find abundant iowaite partly replacing brucite. While this is the first report of iowaite from a mid-ocean ridge setting, its presence indicates, again, fairly oxidizing conditions. Our preliminary results indicate that peridotite-seawater and serpentinite-seawater interactions can take place under a wider range of temperature and redox conditions than previously appreciated.
    Description: This research used data and/or samples supplied by the Ocean Drilling Program (ODP). ODP is sponsored by the U.S. National Science Foundation (NSF) and participating countries under management of Joint Oceanographic Institutions (JOI), Inc.
    Keywords: Hydrothermal system ; Ocean Drilling Program ; Oceanic crust ; Serpentinite ; Water-rock interaction
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  • 35
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    American Geophysical Union
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2006. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 111 (2006): C02004, doi:10.1029/2004JC002689.
    Description: The first open ocean deployment of the Skin Depth Experimental Profiler (SkinDeEP) was from the R/V Melville in the Gulf of California during the Marine Optical Characterization Experiment (MOCE–5). SkinDeEP is an autonomous, vertical profiler for the upper few meters of the ocean. During MOCE–5, SkinDeEP was deployed on 10 separate occasions, and profiles were made at intervals of approximately one minute each. A total of 976 profiles were acquired during the cruise. The ocean skin temperatures were measured by the Marine Atmosphere Emitted Radiance Interferometer (M–AERI), an infrared spectroradiometer. Typical meteorological conditions were of low winds and high insolation. The dataset provided captures the near-surface temperature structure that decouples the skin layer from the conventional in–situ bulk sea surface temperature measurements made at a depth of a few meters. Data from SkinDeEP showed strong diurnal warming within the upper few meters, with one extreme case of 4.6 K. There were large discrepancies when computing the skin–bulk temperature difference with bulk temperatures at different depths. Results also show the strong dependency of estimating air–sea heat flux based on SST, with warm–layer errors of almost 60 Wm-2 associated with intense stratification. This indicates the importance of the inclusion of the skin temperature for accurate calculation of latent, sensible, and net longwave heat fluxes.
    Description: The development of SkinDeEP was funded through the Research Council of Norway (Prosjektnr. 127872/720). Support was provided by the European Commission under the Marie Curie Fellowship contract ERBFMBICT983162. Further supportwas provided by NSF grant OCE–0241834 and National Oceanographic Partnership Program Award No. NNG04GM56G.
    Keywords: Air-sea heat flux ; Cool skin ; Warm layer
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  • 36
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2006. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Water Resources Research 42 (2006): W03426, doi:10.1029/2005WR004131.
    Description: We assessed the effects of historical (1931-1998) changes in both land-use and climate on the water budget of a rapidly urbanizing watershed, Ipswich River basin (IRB), in northeastern Massachusetts. Water diversions and extremely low flow during summer are major issues in the IRB. Our study centers on a detailed analysis of diversions and a combined empirical/modeling treatment of evapotranspiration (ET) response to changes in climate and land-use. A detailed accounting of diversions showed that net diversions increased due to increases in water withdrawals (primarily ground water pumping) and export of sewage. Net diversions constitute a major component of runoff (20% of streamflow). Using a combination of empirical analysis and physically based modeling we related an increase in precipitation (2.7 mm/yr) and changes in other climate variables to an increase in ET (1.7 mm/yr). Simulations with a physically based water-balance model showed that the increase in ET could be attributed entirely to a change in climate, while the effect of land-use change was negligible. The land-use change effect was different from ET and runoff trends commonly associated with urbanization. We generalized these and other findings to predict future streamflow using climate change scenarios. Our study could serve as a framework for studying suburban watersheds, being the first study of a suburban watershed that addresses long-term effects of changes in both land-use and climate, and accounts for diversions and other unique aspects of suburban hydrology.
    Description: This research was partially supported by NSF grants (DEB-9726862, OCE-9726921 and OCE-0423565).
    Keywords: Water budgets ; Evapotranspiration ; Climate change ; Land-use change ; Urbanization ; Water-balance model ; Ipswich River
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  • 37
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2006. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 111 (2006): C03012, doi:10.1029/2005JC003290.
    Description: The Finite Volume Coastal Ocean Model (FVCOM) is used to estimate the onshore cross-frontal transport at the shelf break of the East China Sea. Boundary conditions of FVCOM are provided by the Princeton Ocean Model simulating ocean currents in the Yellow Sea and East China Sea realistically. One advantage of this study is that the unstructured triangular cell grid of FVCOM resolves complex bottom topography that may trigger Kuroshio frontal waves. It is anticipated that these nonlinear frontal waves enhance the exchange of seawater between the Kuroshio and shelf regions. Kuroshio frontal waves in the model are excited around the location where the bottom slope changes abruptly, and have the phase speed and amplitude consistent with those observed in the East China Sea. In addition, the model reproduces the onshore transport associated with growing frontal waves in the upper and lower layers. On the basis of passive tracer experiments, the annually averaged onshore-transport integrated along the shelf break is estimated to be 0.85 × 106 m3/s.
    Description: This study was carried out when A. I. stayed at WHOI with the grant of Overseas Advanced Educational Research Practice Support Program supported by the Ministry of Education, Science and Culture, Japan. In addition, the Japan Society for the Promotion of Science supported this study through Grant-in-Aid for Scientific Research.
    Keywords: East China Sea ; Kuroshio frontal wave ; Cross-frontal transport ; FVCOM
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  • 38
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2006. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 7 (2006): Q05022, doi:10.1029/2005GC001138.
    Description: In this study we use microsampling techniques to explore diagenetic processes in carbonates. These processes are important as they can affect the accuracy of U series chronometry. Fission track maps of deep-sea scleractinian corals show a threefold difference between the minimum and maximum [U] in modern corals, which is reduced to a factor of 2 in fossil corals. We use micromilling and MC-ICP-MS to make detailed analyses of the [U] and δ234Uinitial distributions in corals from 218 ka to modern. Within each fossil coral we observe a large range of δ234Uinitial values, with high δ234Uinitial values typically associated with low [U]. A simple model shows that this observation is best explained by preferential movement of alpha-decay produced 234U atoms (alpha-recoil diffusion). Open-system addition of 234U may occur when alpha-recoil diffusion is coupled with a high [U] surface layer, such as organic material. This process can result in large, whole-coral δ234Uinitial elevations with little effect on the final age. The diagenetic pathways that we model are relevant to both shallow-water and deep-sea scleractinian corals since both exhibit primary [U] heterogeneity and may be subject to U addition.
    Description: We gratefully acknowledge The Comer Foundation for Abrupt Climate Change.
    Keywords: Uranium ; Diagenesis ; Coral ; Dating
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  • 39
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2006. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 7 (2006): Q06006, doi:10.1029/2005GC001141.
    Description: Placing accurate age constraints on near-axis lava flows has become increasingly important given the structural and volcanic complexity of the neovolcanic zone at fast spreading ridges. Geomagnetic paleointensity of submarine basaltic glass (SBG) holds promise for placing quantitative age constraints on near-axis flows. In one of the first extensive tests of paleointensity as a dating tool or temporal marker we present the results of over 550 successful SBG paleointensity estimates from 189 near-axis (〈4 km) sites at the East Pacific Rise, 9°–10°N. Paleointensities range from 6 to 53 μT and spatially correspond to the pattern expected from known temporal variations in the geomagnetic field. Samples within and adjacent to the axial summit trough (AST) have values approximately equal to or slightly higher than the present-day. Samples out to 1–3 km from the AST have values higher than the present-day, and samples farther off axis have values lower than the present-day. The on-axis samples (〈500 m from the AST) provide a test case for using models of paleofield variation for the past few hundred years as an absolute dating technique. Results from samples collected near a well-documented eruption in 1991–1992 suggest there may be a small negative bias in the paleointensity estimates, limiting resolution of the dating technique. Possible explanations for such a bias include local field anomalies produced by preexisting magnetic terrain; anomalously high magnetic unblocking temperatures, leading to a small cooling rate bias; and/or the possibility of a chemical remanence produced by in situ alteration of samples likely to have complicated thermal histories. Paleointensity remains useful in approximating age differences in young flows, and a clear along-axis paleointensity contrast near 9°50′N is suggestive of a ∼150–200 year age difference. Paleointensity values of off-axis samples are generally consistent with rough age interpretations based on side scan data. Furthermore, spatial patterns in the paleointensity suggest extensive off-axis flow emplacement may occur infrequently, with recurrence intervals of 10–20 kyr. Results of a stochastic model of lava emplacement show that this can be achieved with a single distribution of flows, with flow size linked to time between eruptions.
    Description: This work was accomplished with support from NSF grants OCE-0095698 (J. S. G.), OCE-0095342 (D. V. K.), OCE-9912072 (M. R. P.), OCE-0138088 (M. R. P.), and OCE-9819261 (D. J. F.).
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  • 40
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2006. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 33 (2006): L06715, doi:10.1029/2006GL025753.
    Description: Several recent publications have documented changes in river discharge from arctic and subarctic watersheds. Comparison of these findings, however, has been hampered by differences in time periods and methods of analysis. Here we compare changes in discharge from different regions of the pan-arctic watershed using identical time periods and analytical methods. Discharge to the Arctic Ocean increased by 5.6 km3/y/y during 1964-2000, the net result of a large increase from Eurasia moderated by a small decrease from North America. In contrast, discharge to Hudson/James/Ungava Bays decreased by 2.5 km3/y/y during 1964-2000. While this evaluation identifies an overall increase in discharge (~120 km3/y greater discharge at the end of the time period as compared to the beginning for Hudson/James/Unvaga Bays and the Arctic Ocean combined), the contrasting regional trends also highlight the need to understand the consequences of adding/removing freshwater from particular regions of the arctic and subarctic oceans.
    Description: This work was supported by the Arctic System Science Program of the National Science Foundation (NSF-OPP-0229302, NSF-OPP-0230211, NSF-OPP-0519840) and by the National Oceanic and Atmospheric Administration (NA17RJ2612).
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  • 41
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2006. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Paleoceanography 21 (2006): PA1014, doi:10.1029/2005PA001162.
    Description: Sea surface temperature (SST) and seawater δ18O (δ18Ow) were reconstructed in a suite of sediment cores from throughout the Arabian Sea for four distinct time intervals (0 ka, 8 ka, 15 ka, and 20 ka) with the aim of understanding the history of the Indian Monsoon and the climate of the Arabian Sea region. This was accomplished through the use of paired Mg/Ca and δ18O measurements of the planktonic foraminifer Globigerinoides ruber. By analyzing basin-wide changes and changes in cross-basinal gradients, we assess both monsoonal and regional-scale climate changes. SST was colder than present for the majority of sites within all three paleotime slices. Furthermore, both the Indian Monsoon and the regional Arabian Sea mean climate have varied substantially over the past 20 kyr. The 20 ka and 15 ka time slices exhibit average negative temperature anomalies of 2.5°–3.5°C attributable, in part, to the influences of glacial atmospheric CO2 concentrations and large continental ice sheets. The elimination of the cross-basinal SST gradient during these two time slices likely reflects a decrease in summer monsoon and an increase in winter monsoon strength. Changes in δ18Ow that are smaller than the δ18O signal due to global ice volume reflect decreased evaporation and increased winter monsoon mixing. SSTs throughout the Arabian Sea were still cooler than present by an average of 1.4°C in the 8 ka time slice. These cool SSTs, along with lower δ18Ow throughout the basin, are attributed to stronger than modern summer and winter monsoons and increased runoff and precipitation. The results of this study underscore the importance of taking a spatial approach to the reconstruction of processes such as monsoon upwelling.
    Description: Analyses were funded by a SGER grant from the NSF (OCE03–34598). Funding was also provided by a Schlanger Ocean Drilling Program Fellowship (to K.A.D.) and NSF Grant OCE02–20776 (to D.W.O.). 16
    Keywords: Arabian Sea ; Mg/Ca ; Indian monsoon
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  • 42
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2006. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Paleoceanography 21 (2006): PA3012, doi:10.1029/2006PA001273.
    Description: Geochemical compositions and Sr and Nd isotopes were measured in two cores collected ~2 and 5 km from the Rainbow hydrothermal vent site on the Mid-Atlantic Ridge. Overall, the cores record enrichments in Fe and other metals from hydrothermal fallout, but sequential dissolution of the sediments allows discrimination between a leach phase (easily leachable) and a residue phase (refractory). The oxy-anion and transition metal distribution combined with rare earth element (REE) patterns suggest that 1) the leach fraction is a mixture of biogenic carbonate and hydrothermal Fe-Mn oxy-hydroxide with no significant contribution from detrital material, and 2) 〉99.5% of the REE content of the leach fraction is of seawater origin. In addition, the leach fraction has an average 87Sr/86Sr ratio indistinguishable from modern seawater at 0.70916. Although we lack the εNd value of present day deep water at the Rainbow vent site, we believe that the REE budget of the leach fraction is predominantly of seawater origin. We suggest, therefore, that the leach fraction provides a record of local seawater εNd values. Nd isotope data from these cores span the period of 4-14 ka (14C ages) and yield εNd values for North East Atlantic Deep Water (NEADW) that are higher (-9.3 to -11.1) than those observed in the nearby Madeira Abyssal Plain from the same depth (-12.4 ± 0.9). This observation suggests that either the Iceland-Scotland Overflow Water (ISOW) and Lower Deep Water (LDW) contributions to the formation of NEADW are higher along the Mid-Atlantic Ridge than in the surrounding basins, or that the relative proportion of ISOW was higher during this period than is observed today. This study indicates that hydrothermal sediments have the potential to provide a higher resolution record of deep water εNd values, and hence deep-water circulation patterns in the oceans, than is possible from other types of sediments.
    Description: VC is funded by the 2000 National Oceanography Centre, Southampton fellowship. Hydrothermal research at NOCS is funded through NERC core strategic science.
    Keywords: Nd isotope ; Hydrothermal ; Seawater
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  • 43
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2006. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 111 (2006): B09402, doi:10.1029/2005JB003981.
    Description: Prestack depth migrations of seismic reflection data collected around the Ocean Drilling Program (ODP) Leg 210 transect on the Newfoundland nonvolcanic margin delineate three domains: (1) extended continental crust, (2) transitional basement, and (3) apparent slow spreading oceanic basement beyond anomaly M3 and indicate first-order differences between this margin and its well-studied conjugate, the Iberia margin. Extended continental crust thins abruptly with few observed faults, in stark contrast with the system of seaward dipping normal faults and detachments imaged within continental crust off Iberia. Transition zone basement typically appears featureless in seismic reflection profiles, but where its character can be discerned, it does not resemble most images of exhumed peridotite off Iberia. Seismic observations allow three explanations for transitional basement: (1) slow spreading oceanic basement produced by unstable early seafloor spreading, (2) exhumed, serpentinized mantle with different properties from that off Iberia, and (3) thinned continental crust, likely emplaced by one or more detachment or rolling-hinge faults. Although we cannot definitively discriminate between these possibilities, seismic reflection profiles together with coincident wide-angle seismic refraction data tentatively suggest that the majority of transitional basement is thinned continental crust emplaced during the late stages of rifting. Finally, seismic profiles image abundant faults and significant basement topography in apparent oceanic basement. These observations, together with magnetic anomaly interpretations and the recovery of mantle peridotites at ODP Site 1277, appear to be best explained by the interplay of extension and magmatism during the transition from nonvolcanic rifting to a slow spreading oceanic accretion system.
    Description: The SCREECH program was funded by U.S. National Science Foundation grant OCE-9819053 to Woods Hole Oceanographic Institution, by the Danish Research Foundation (Danmarks Grundforskningsfond), and by the Natural Science and Engineering Council of Canada. D. Shillington was also supported by NSF grant OCE-0241940 and by the University of Wyoming Graduate School. B. Tucholke acknowledges additional support from NSF grant OCE-0326714 and the Henry Bryant Bigelow Chair in Oceanography at Woods Hole Oceanographic Institution.
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  • 44
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2006. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 111 (2006): C09023, doi:10.1029/2005JC003268.
    Description: Using 14 year-long instrumented moorings deployed south of St. Lawrence Island, along with oceanographic drifters, we investigate the circulation over the central Bering shelf and the role of polynyas in forming and disseminating saline waters over the shelf. We focus also on evaluating the Gawarkiewicz and Chapman [1995] model of eddy production within coastal polynyas. Principal results include: 1) The northern central shelf near-surface waters exhibit westward flow carrying low-salinity waters from the Alaskan coast in fall and early winter, with consequences for water mass formation and biological production. 2) Within the St. Lawrence polynya, the freshening effect of winter advection is about half as large as the salting effect of surface brine flux resulting from freezing. 3) Brine production over the Bering shelf occurs primarily offshore, rather than within coastal polynyas, even though ice production per unit area is much larger within the polynyas. 4) We find little evidence for the geostrophic flow adjustment predicted by recent polynya models. 5) In contrast to the theoretical prediction that dense water from the polynya is carried offshore by eddies, we find negligible cross-shelf eddy density fluxes within and surrounding the polynya and very low levels of eddy energy that decreased from fall to winter, even though dense water accumulated within the polynya and large cross-shore density gradients developed. 6) It is possible that dense polynya water was advected downstream of our array before appreciable eddy fluxes materialized.
    Description: This work was supported by National Science Foundation grant OCE9730697 to the University of Alaska and grant OCE9730823 to the University of Washington. S. M. acknowledges the support of the National Science Foundation under OCE9811097 and of NASA under grant NNG04GM69G. The University of Hamburg contributions were funded by the Bundesminister für Bildung und Wissenschaft. Funding for the drifter deployment was made possible by the North Pacific Research Board, grant NPMRI T2130. Manuscript preparation was additionally supported by Office of Naval Research grants N00014-99-1-0345 and N00014-02-1-0305 to the University of Washington.
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  • 45
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2005. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 110 (2005): G02013, doi:10.1029/2005JG000031.
    Description: Concentrations of dissolved organic carbon (DOC) and δ18O values have been determined following sampling of runoff from a number of major arctic rivers, including the Ob, Yenisey, Lena, Kolyma, Mackenzie and Yukon in 2003-2004. These data are considered in conjunction with marine data for DOC, δ18O values, nutrients, salinity, and fluorometric indicators of DOC that were obtained as part of the Shelf-Basin Interactions program at the continental shelf-basin boundary of the Chukchi and Beaufort Seas. These marine data indicate that the freshwater component is most likely derived from regional sources, such as the Mackenzie, the Bering Strait inflow and possibly eastern Siberian rivers, including the Kolyma, or the Lena but not rivers further west in the Eurasian arctic. Contributions of freshwater from melted sea ice to marine surface waters appeared to be insignificant over annual cycles compared to runoff, although on a seasonal basis, freshwater from melted sea ice was locally dominant following a major sea-ice retreat into the Canada Basin in 2002. DOC concentrations were correlated with the runoff fraction, with an apparent meteoric water DOC concentration of 174 ± 1 μM (standard error). This concentration is lower than the flow-weighted concentrations measured at river mouths of the five largest Arctic rivers (358 to 917 μM), indicating that removal of terrigenous DOC during transport through estuaries, shelves and in the deep basin. DOC data indicate that flow-weighted concentrations in the two largest North American arctic rivers, the Yukon (625μM) and the Mackenzie (382 μM), are lower than in the three largest Eurasian arctic rivers, the Ob (825 μM), the Yenesey (858 μM) and the Lena (917 μM). A fluorometric indicator of chromophoric dissolved organic matter (CDOM) that has provided estimates of terrigenous DOC concentrations in the Eurasian Arctic was not correlated with DOC concentrations in the Amerasian marine waters studied, except below the upper Arctic Ocean halocline. Nutrient distributions and concentrations as well as derived nutrient ratios suggest the CDOM fluorometer may be responding to the release of chromophoric materials from continental shelf sediments. Shipboard incubation experiments with undisturbed sediment cores indicate that continental shelf sediments on the Bering and Chukchi Sea shelves are likely to be a net source of DOC to the Arctic Ocean.
    Description: The PARTNERS and SBI projects have been supported by the Office of Polar Programs of the U.S. National Science Foundation.
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  • 46
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2006. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 7 (2006): Q10N03, doi:10.1029/2005GC001226.
    Description: The geostrophic shear associated with the meridional overturning circulation is reflected in the difference in density between the eastern and western margins of the ocean basin. Here we examine how the density difference across 30°S in the upper 2 km of the Atlantic Ocean (and thus the magnitude of the shear associated with the overturning circulation) has changed between the last glacial maximum and the present. We use oxygen isotope measurements on benthic foraminifera to reconstruct density. Today, the density in upper and intermediate waters along the eastern margin in the South Atlantic is greater than along the western margin, reflecting the vertical shear associated with the northward flow of surface and intermediate waters and the southward flowing North Atlantic Deep Waters below. The greater density along the eastern margin is reflected in the higher δ 18O values for surface sediment benthic foraminifera than those found on the western margin for the upper 2 km. For the last glacial maximum the available data indicate that the eastern margin foraminifera had similar δ 18O to those on the western margin between 1 and 2 km and that the gradient was reversed relative to today with the higher δ 18O values in the western margin benthic foraminifera above 1 km. If this reversal in benthic foraminifera δ 18O gradient reflects a reversal in seawater density gradient, these data are not consistent with a vigorous but shallower overturning cell in which surface waters entering the Atlantic basin are balanced by the southward export of Glacial North Atlantic Intermediate Water.
    Description: This work was supported by NSF award OCE-9984989/OCE-0428803 to J.L.-S., NSF award OCE-9986748 to D.W.O. and W.B.C., NSF OCE-0222111 to C.D.C., and SEGRF fellowship at LLNL to J.M.
    Keywords: Last Glacial Maximum ; South Atlantic ; Meridional overturning circulation ; Oxygen isotopes ; Benthic foraminifera
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  • 47
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2006. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 111 (2006): B11404, doi:10.1029/2005JB004156.
    Description: We present a compressional seismic velocity profile of the crust of the eastern margin of the Grand Banks of Newfoundland, Canada. This velocity model was obtained by a tomographic inversion of wide-angle data recorded on a linear array of 24 ocean-bottom seismometers (OBSs). At the landward side, we imaged a crustal thickness of 27 km in Flemish Pass and beneath Beothuk Knoll, which is thinner than the 35-km-thick crust of the central Grand Banks. We therefore assume that the eastern rim of the Grand Banks stretched uniformly by 25%. Farther seaward, the continental crust tapers rapidly beneath the continental slope to ~6 km thickness. In the distal margin we find a 60-km-wide zone with seismic velocities between 5.0 and 6.5 km/s that thins to the southeast from 6 km to 2 km, which we interpret as highly extended continental crust. Contrary to other seismic studies of the margins of the Grand Banks, we find seismic velocities of 8 km/s and higher beneath this thin crustal layer in the continent-ocean transition. We conclude that mantle was locally emplaced at shallow levels without significant hydration from seawater, or serpentinized mantle was removed along a décollement in the final stages of continental rifting. The outer edge of highly extended continental crust borders a 25-km-wide zone where seismic velocities increase gradually from 6.3 km/s just below the top of acoustic basement to 7.7 km/s at 5 km below basement. We interpret this area as a relatively narrow zone of exhumed and serpentinized continental mantle. Seawards, we imaged a thin and laterally heterogeneous layer with a seismic velocity that increases sharply from 5.0 km/s in basement ridges to 7.0 km/s at its base, overlying mantle velocities between 7.8 and 8.2 km/s. We interpret this area as unroofed mantle and very thin oceanic crust that formed at an incipient, magmastarved, ultraslow spreading ridge. A comparison of the conjugate rifted margins of the eastern Grand Banks and the Iberia Abyssal Plain show that they exhibit a similar seaward progression from continental crust to mantle to oceanic crust. This indicates that before continental breakup, rifting exhumed progressively deeper sections of the continental lithosphere on both conjugate margins. A comparison between the continent-ocean transition of the Grand Banks and Flemish Cap shows that the final phase of continental rifting and the formation of the first oceanic crust required more time at the Grand Banks margin than at the southeastern margin of Flemish Cap.
    Description: The SCREECH program was funded by the U.S. National Science Foundation grant OCE-9819053 to Woods Hole Oceanographic Institution, by the Danish Research Foundation (Danmarks Grundforskningsfond), and by the Natural Science and Engineering Council of Canada. HVA received support from the University of Texas Institute for Geophysics and a Jackson School of Geosciences Fellow award. BET acknowledges additional support from NSF grant OCE-0326714 and the Henry Bryant Bigelow Chair in Oceanography at Woods Hole Oceanographic Institution.
    Keywords: Continental rifting ; Marine geophysics ; Passive margin
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  • 48
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2005. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Paleoceanography 20 (2005): PA1016, doi:10.1029/2004PA001103.
    Description: Radiocarbon age relationships between co-occurring planktic foraminifera, alkenones and total organic carbon in sediments from the continental margins of Southern Chile, Northwest Africa and the South China Sea were compared with published results from the Namibian margin. Age relationships between the sediment components are site-specific and relatively constant over time. Similar to the Namibian slope, where alkenones have been reported to be 1000 to 4500 years older than co-occurring foraminifera, alkenones were significantly (~1000 yrs) older than co-occurring foraminifera in the Chilean margin sediments. In contrast, alkenones and foraminifera were of similar age (within 2σ error or better) in the NW African and South China Sea sediments. Total-organic-matter and alkenone ages were similar off Namibia (age difference TOC-alkenones: 200-700 years), Chile (100-450 years), and NW Africa (360-770 years), suggesting minor contributions of pre-aged terrigenous material. In the South China Sea total organic carbon is significantly (2000-3000 yrs) older due to greater inputs of pre-aged terrigenous material. Age offsets between alkenones and planktic foraminifera are attributed to lateral advection of organic matter. Physical characteristics of the depositional setting, such as sea-floor morphology, shelf width, and sediment composition, may control the age of co-occurring 2 sediment components. In particular, offsets between alkenones and foraminifera appear to be greatest in deposition centers in morphologic depressions. Aging of organic matter is promoted by transport. Age offsets are correlated with organic richness, suggesting that formation of organic aggregate is a key process.
    Description: GM and MK acknowledge financial support from the WHOI postdoctoral scholarship program. This work was funded by NSF grant OCE-0327405.
    Keywords: Compound-specific radiocarbon dating ; Alkenones ; High accumulation rate sediments
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  • 49
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2005. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 6 (2005): Q05006, doi:10.1029/2004GC000881.
    Description: We analyzed in detail the geology of the median valley floor of the Mariana Basin slow-spreading ridge using sea surface geophysical data and a high-resolution deep-tow side-scan sonar survey over one spreading segment. Analysis of surface magnetic data indicates highly asymmetric accretion, with the half-spreading rate on the western side of the basin being two to three times larger than on the eastern side. Surface magnetic and reflectivity data together suggest that asymmetric spreading is accomplished through eastward ridge jumps of ∼10 km of amplitude. Deep-tow backscatter data indicate along-axis variations of the volcanic processes with the emplacement of smooth and hummocky flows at the segment center and end, respectively. This variation likely relates to changes in the effusion rate due to the deepening or even disappearance of the magma chamber toward the segment end. Concerning tectonic processes, we find a power law distribution of the fractures, with an exponent of 1.74. This suggests that within the inner valley floor, fracture growth prevails over fracture nucleation and coalescence and that fractures accommodate less than 8% of the strain. According to our calculation based on a ratio of 0.02 to 0.03 between the vertical displacement and the length of faults, the amount of tectonic strain accommodated in the inner valley floor would consistently be ∼1.1–3.4%. Data also show two distinct sets of fractures. One trend is parallel to the rift direction at the segment center (∼N160°E) and perpendicular to the plate separation direction. Another set trends ∼17° oblique to this direction (∼N175°E) and is located over the eastern part of the valley, in the vicinity of a major bounding fault also trending ∼N175°E, that is, obliquely to the direction of plate motion. We modeled the stress field near a major fault that is oblique to the regional stress field associated with plate separation using a three-dimensional boundary element approach. We found that the orientation of the predicted fissuring near the oblique fault is locally rotated by ∼15° due to a flexure of the bending plate close to this fault.
    Description: The KR03-12 cruise was funded by both JAMSTEC and ORI. This research was supported by the Postdoctoral Scholar Program at the Woods Hole Oceanographic Institution, with funding provided by the United States Geological Survey.
    Keywords: Back arc ; Deep tow ; Faulting ; Ridge ; Side-scan sonar ; Volcanism
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  • 50
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2005. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 6 (2005): Q09016, doi:10.1029/2005GC000963.
    Description: Tephra layers recovered by Ocean Drilling Program from the forearc and trench regions offshore the Nicoya Peninsula of Costa Rica allow the temporal evolution of the volcanic arc to be reconstructed since 2.5 Ma. Major and trace element analyses by microprobe methods reveal a dominant tholeiitic character and a provenance in the Costa Rican area. The tephra show long-term coherent variability in geochemistry. One tephra dated at 1.45 Ma shows minimum values in ɛ Nd and maximum Li/Y consistent with very high degrees of sediment recycling at this time. However, overall Li/Y and δ7Li increase with SiO2 content, suggesting addition of heavy Li through forearc tectonic erosion and crustal assimilation. Peak values in δ7Li starting at 1.45 Ma and lasting ∼0.5 m.y. indicate enhanced tectonic erosion of the forearc possibly caused by subduction of a seamount at 1.45 Ma. The tephra record indicates significant temporal variability in terms of sediment subduction, reconciling the geologic evidence for long-term tectonic erosion and geochemical evidence for recent sediment accretion in the modern Central American arc.
    Description: Financial support for the analytical work was gratefully received from JOI-USSAC. The lithium isotope work was supported in part by National Science Foundation grant OCE-990554 to L.H.C.
    Keywords: Costa Rica ; Subduction ; Geochemistry ; Tephra
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  • 51
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2005. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 6 (2005): Q11001, doi:10.1029/2005GC001013.
    Description: Heat flow measurements colocated with seismic data across 106 Ma seafloor of the Madeira Abyssal Plain (MAP) reveal variations in seafloor heat flow of ±10–20% that are positively correlated with basement relief buried below thick sediments. Conductive finite element models of sediments and upper basement using reasonable thermal properties are capable of generating the observed positive correlation between basement relief and seafloor heat flow, but with variability of just ±4–8%. Conductive simulations using a high Nusselt number (Nu) proxy for vigorous local convection suggest that Nu = 2–10 within the upper 600–100 m of basement, respectively, is sufficient to achieve a reasonable match to observations. These Nu values are much lower than those inferred on younger ridge flanks where greater thermal homogeneity is achieved in upper basement. Fully coupled simulations suggest that permeability below the MAP is on the order of 10−12–10−10 m2 within the upper 300–600 m of basement. This permeability range is broadly consistent with values determined by single-hole experiments and from modeling studies at other (mostly younger) sites. We infer that the reduction in basement permeability with age that is thought to occur within younger seafloor may slow considerably within older seafloor, helping hydrothermal convection to continue as plates age.
    Description: Funding in support of this work was provided by the U.S. National Science Foundation (OCE-0001892), the U.S. Science Support Program for IODP (T301A7), and the Institute for Geophysics and Planetary Physics/Los Alamos National Laboratory (1317).
    Keywords: Crustal evolution ; Hydrothermal processes ; Numerical modeling
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  • 52
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2005. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 110 (2005): C05001, doi:10.1029/2004JC002691.
    Description: Numerical simulations of the Hudson River estuary using a terrain-following, three-dimensional model (Regional Ocean Modeling System, ROMS) are compared with an extensive set of timeseries and spatially resolved measurements over a 43-day period with large variations in tidal forcing and river discharge. The model is particularly effective at reproducing the observed temporal variations in both the salinity and current structure, including tidal, spring-neap, and river discharge induced variability. Large observed variations in stratification between neap and spring tides are captured qualitatively and quantitatively by the model. The observed structure and variations of the longitudinal salinity gradient are also well reproduced. The most notable discrepancy between the model and the data is in the vertical salinity structure. While the surface-to-bottom salinity difference is well reproduced, the stratification in the model tends to extend all the way to the water surface, whereas the observations indicate a distinct pycnocline and a surface mixed layer. Because the southern boundary condition is located near the mouth the estuary, the salinity within the domain is particularly sensitive to the specification of salinity at the boundary. A boundary condition for the horizontal salinity gradient, based on the local value of salinity, is developed to incorporate physical processes beyond the open boundary not resolved by the model. Model results are sensitive to the specification of the bottom roughness length and vertical stability functions, insofar as they influence the intensity of vertical mixing. The results only varied slightly between different turbulence closure methods of k-ε, k-ω, and k-kl.
    Description: We gratefully acknowledge support from the U.S. Geological Survey Mendenhall Post-doctoral Research Program for support of J. C. Warner. J. A. Lerczak and W. R. Geyer were supported by the Hudson River Foundation.
    Keywords: Estuary ; Model skill assessment ; Hudson River
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  • 53
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    American Geophysical Union
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2006. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 111 (2006): C01002, doi:10.1029/2005JC003139.
    Description: This study examines water property distributions in the deep South China Sea and adjoining Pacific Ocean using all available hydrographic data. Our analysis reveals that below about 1500 m there is a persistent baroclinic pressure gradient driving flow from the Pacific into the South China Sea through Luzon Strait. Applying hydraulic theory with assumptions of zero potential vorticity and flat bottom to the Luzon Strait yields a transport estimate of 2.5 Sv (1 Sv=106 m3 s-1). Some implications of this result include: (i) a residence time of less than 30 years in the deep South China Sea, (ii) a mean diapycnal diffusivity as large as 10-3 m2 s-1, and (iii) an abyssal upwelling rate of about 3×10-6 m s-1. These quantities are consistent with residence times based on oxygen consumption rates. The fact that all of the inflowing water must warm up before leaving the basin implies that this marginal sea contributes to the water mass transformations that drive the meridional overturning circulation in the North Pacific. Density distributions within the South China Sea basin suggest a cyclonic deep boundary current system, as might be expected for an overflow-driven abyssal circulation.
    Description: This study was supported by National Science Foundation (NSF) through Grant OCE00-95906 and by Japan Marine Science and Technology Center through its sponsorship of the International Pacific Research center (IPRRC). Support is also from NSF grant OCE-0325102.
    Keywords: Deepwater overflow ; South China Sea ; Pacific Ocean ; Luzon Strait
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  • 54
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2006. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 33 (2006): L05601, doi:10.1029/2005GL025514.
    Description: The strong tidal modulation of infragravity (200 to 20 s period) waves observed on the southern California shelf is shown to be the result of nonlinear transfers of energy from these low-frequency long waves to higher-frequency motions. The energy loss occurs in the surfzone, and is stronger as waves propagate over the convex low-tide beach profile than over the concave high-tide profile, resulting in a tidal modulation of seaward-radiated infragravity energy. Although previous studies have attributed infragravity energy losses in the surfzone to bottom drag and turbulence, theoretical estimates using both observations and numerical simulations suggest nonlinear transfers dominate. The observed beach profiles and energy transfers are similar along several km of the southern California coast, providing a mechanism for the tidal modulation of infragravity waves observed in bottom-pressure and seismic records on the continental shelf and in the deep ocean.
    Description: Support was provided by ONR and NSF.
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  • 55
    facet.materialart.
    Unknown
    American Geophysical Union
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2006. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 7 (2006): Q11004, doi:10.1029/2005GC001216.
    Description: The Sr/Ca ratio of biogenic carbonate is widely used as a proxy for paleotemperature. This application is supported by empirical calibrations of Sr/Ca as a function of temperature, but it is also known that Sr uptake in calcite gauged by KdSr=(Sr/Ca)calcite/(Sr/Ca)solution is affected by other variables, including bulk precipitation rate (Kd Sr increases with increasing precipitation rate). There are no data from controlled experiments specifically addressing the effect of radial growth rate of individual crystals on Kd Sr. For this reason, we conducted two series of experiments to explore Sr partitioning at varying growth rates: (1) growth from a CaCl2–NH4Cl–SrCl2 solution by diffusion of CO2 from an ammonium carbonate source (“drift” experiments) and (2) “drip” precipitation of calcite on a substrate, using a steady flow of CaCl2–SrCl2 and Na2CO3 solutions, mixed just before passage through a tube and dripped onto a glass slide precoated with calcite (“cave-type” experiments). The growth rates of individual crystals were determined by periodic monitoring of crystal size through time or, roughly, by comparison of the final size with the duration of the experiment. Electron microprobe analyses across sectioned crystals grown in the drift experiments show that the concentration of Sr is high in the center (where radial growth rates are highest) and decreases systematically toward the edge. The center-to-edge drop in Sr concentration is a consequence of the slowing radial growth rate as individual crystals become larger. In general, high crystal growth rate (V) enhances Sr uptake in calcite due to a type of kinetic disequilibrium we refer to as “growth entrapment.” The apparent Kd Sr ranges from 0.12 to 0.35 as V increases from 0.01 nm/s to 1 μm/s at 25°C.
    Description: This work was supported by the National Science Foundation through grants EAR-9804794 and EAR-0337481 to E. B. Watson.
    Keywords: Calcite ; Partitioning ; Fluid ; Growth rate ; Strontium ; Temperature
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  • 56
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2006. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Paleoceanography 21 (2006): PA3008, doi:10.1029/2005PA001208.
    Description: Multi-proxy geologic records of δ18O and Mg/Ca in fossil foraminifera from sediments under the Eastern Pacific Warm Pool (EPWP) region west of Central America document variations in upper ocean temperature, pycnocline strength, and salinity (i.e., net precipitation) over the past 30 ky. Although evident in the paleotemperature record, there is no glacial-interglacial difference in paleosalinity, suggesting that tropical hydrologic changes do not respond passively to high-latitude ice sheets and oceans. Millennial variations in paleosalinity with amplitudes as high as ~4 PSU occur with a dominant period of ~3-5 ky during the glacial/deglacial interval and ~1.0-1.5 ky during the Holocene. The amplitude of the EPWP paleosalinity changes greatly exceeds that of published Caribbean and western tropical Pacific paleosalinity records. EPWP paleosalinity changes correspond to millennial-scale climate changes in the surface and deep Atlantic and the high northern latitudes, with generally higher (lower) paleosalinity during cold (warm) events. In addition to Intertropical Convergence Zone (ITCZ) dynamics, which play an important role in tropical hydrologic variability, changes in Atlantic-Pacific moisture transport, which is closely linked to ITCZ dynamics, may also contribute to hydrologic variations in the EPWP. Calculations of interbasin salinity average and interbasin salinity contrast between the EPWP and the Caribbean help differentiate long-term changes in mean ITCZ position and Atlantic-Pacific moisture transport, respectively.
    Description: Support for this research was provided by the U.S. National Science Foundation.
    Keywords: Water vapor ; Eastern tropical Pacific ; Paleoceanography
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  • 57
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2005. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 6 (2005): Q11009, doi:10.1029/2005GC001026.
    Description: The northern scarp of the western Blanco Transform (BT) fault zone provides a "tectonic window" into crust generated at an intermediate-rate spreading center, exposing a ~2000 m vertical section of lavas and dikes. The lava unit was sampled by submersible during the Blancovin dive program in 1995, recovering a total of 61 samples over vertical distances of ~1000 m and a lateral extent of ~13 km. Major elements analyses of 40 whole rock samples exhibit typical tholeiitic fractionation trends of increasing FeO*, Na2O, and TiO2 and decreasing Al2O3 and CaO with decreasing MgO. The lava suite shows a considerable range in extent of crystallization, including primitive samples (Mg# 64) and evolved FeTi basalts (FeO〉12%;TiO2〉2%). Based on rare earth element and trace element data, all of the lavas are incompatible-element depleted normal mid-ocean ridge basalts (N-MORB;La/SmN〈1). The geochemical systematics suggest that the lavas were derived from a slightly heterogeneous mantle source, and crystallization occurred in a magmatic regime of relatively low magma flux and/or high cooling rate, consistent with magmatic processes occurring along the present-day southern Cleft Segment. The BT scarp reveals the oceanic crust in two-dimensional space, allowing us to explore temporal and spatial relationships in the horizontal and vertical directions. As a whole, the data do not appear to form regular spatial trends; rather, primitive lavas tend to cluster shallower and toward the center of the study area, while more evolved lavas are present deeper and toward the west and east. Considered within a model for construction of the upper crust, these findings suggest that the upper lavas along the BT scarp may have been emplaced off-axis, either by extensive off-axis flow or off-axis eruption, while the lower lavas represent axial flows that have subsided with time. A calculation based on an isochron model for construction of the upper crust suggests that the Cleft Segment requires at least ~50 ka to build the lower extrusive section, consistent to first order with independent estimates for the construction of intermediate-spreading rate crust.
    Description: This work was supported by the US National Science Foundation (OCE 02- 22154 to E.K. and J.K. and OCE 9400623 to M.T.).
    Keywords: Accretion ; Isochron ; MORB
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  • 58
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2005. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 5 (2005): Q04008, doi:10.1029/2003GC000623.
    Description: An in-depth Sr-Nd-Pb-He-Os isotope and trace element study of the EMII-defining Samoan hot spot lavas leads to a new working hypothesis for the origin of this high 87Sr/86Sr mantle end-member. Systematics of the Samoan fingerprint include (1) increasing 206Pb/204Pb with time - from 18.6 at the older, western volcanoes to 19.4 at the present-day hot spot center, Vailulu'u Seamount, (2) en-echelon arrays in 206Pb/204Pb – 208Pb/204Pb space which correspond to the two topographic lineaments of the 375 km long volcanic chain – this is much like the Kea and Loa Trends in Hawai'i, (3) the highest 87Sr/86Sr (0.7089) of all oceanic basalts, (4) an asymptotic decrease in 3He/4He from 24 RA [Farley et al., 1992] to the MORB value of 8 RA with increasing 87Sr/86Sr, and (5) mixing among four components which are best described as the “enriched mantle”, the depleted FOZO mantle, the (even more depleted) MORB Mantle, and a mild HIMU (high 238U/204Pb) mantle component. A theoretical, “pure” EMII lava composition has been calculated and indicates an extremely smooth trace element pattern of this end-member mantle reservoir. The standard recycling model (of ocean crust/sediment) fails as an explanation for producing Samoan EM2, due to these smooth spidergrams for EM2 lavas, low 187Os/188Os ratios and high 3He/4He (〉8 RA). Instead, the origin of EM2 has been modeled with the ancient formation of metasomatised oceanic lithosphere, followed by storage in the deep mantle and return to the surface in the Samoan plume.
    Description: We acknowledge NSF support, through grant OCE-9819038 (SRH and HS), and EAR-0125917 (SRH).
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  • 59
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2006. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Paleoceanography, 21 (2006): PA2009, doi:10.1029/2005PA001218.
    Description: The salinity and temperature of the Florida Current are key parameters affecting the transport of heat into the North Atlantic, yet little is known about their variability on centennial time scales. Here we report replicated, high-resolution foraminiferal records of Florida Current surface hydrography for the last millennium from two coring sites, Dry Tortugas and the Great Bahama Bank. The oxygen isotopic composition of Florida Current surface water (δ18Ow) near Dry Tortugas increased 0.4‰ during the course of the Little Ice Age (LIA: ~1200-1850 A. D.), equivalent to a salinity increase of 0.8-1.5 psu. On the Great Bahama Bank, where surface waters are influenced by the North Atlantic subtropical gyre, δ18Ow increased by 0.3‰ during the last 200 years. Although a portion (~0.1‰) of this shift may be an artifact of anthropogenically-driven changes in surface water ΣCO2, the remaining δ18Ow signal implies a 0.4 to 1 psu increase in salinity after 200 yr BP. The simplest explanation of the δ18Ow data is southward migration of the Atlantic Hadley circulation during the LIA. Scaling of the δ18Ow records to salinity using the modern low-latitude δ18Ow-S slope produces an unrealistic reversal in the salinity gradient between the two sites. Only if δ18Ow is scaled to salinity using a high-latitude δ18Ow-S slope can the records be reconciled. Changes in atmospheric 14C paralleled shifts in Dry Tortugas δ18Ow, suggesting that variable solar irradiance paced centennialscale ITCZ migration and changes in Florida Current salinity during the last millennium.
    Description: This work was supported by NSF grant OCE-0096469.
    Keywords: Gulf Stream ; Salinity ; Little Ice Age
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  • 60
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2006. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 7 (2006): Q05001, doi:10.1029/2005GC001086.
    Description: A 2002 multibeam sonar survey of Mauna Loa’s western flank revealed ten submarine radial vents and three submarine lava flows. Only one submarine radial vent was known previously. The ages of these vents are constrained by eyewitness accounts, geologic relationships, Mn-Fe coatings, and geochemical stratigraphy; they range from 128 years B.P. to possibly 47 ka. Eight of the radial vents produced degassed lavas despite eruption in water depths sufficient to inhibit sulfur degassing. These vents formed truncated cones and short lava flows. Two vents produced undegassed lavas that created ‘‘irregular’’ cones and longer lava flows. Compositionally and isotopically, the submarine radial vent lavas are typical of Mauna Loa lavas, except two cones that erupted alkalic lavas. He-Sr isotopes for the radial vent lavas follow Mauna Loa’s evolutionary trend. The compositional and isotopic heterogeneity of these lavas indicates most had distinct parental magmas. Bathymetry and acoustic backscatter results, along with photography and sampling during four JASON2 dives, are used to produce a detailed geologic map to evaluate Mauna Loa’s submarine geologic history. The new map shows that the 1877 submarine eruption was much larger than previously thought, resulting in a 10% increase for recent volcanism. Furthermore, although alkalic lavas were found at two radial vents, there is no systematic increase in alkalinity among these or other Mauna Loa lavas as expected for a dying volcano. These results refute an interpretation that Mauna Loa’s volcanism is waning. The submarine radial vents and flows cover 29 km2 of seafloor and comprise a total volume of ~2 x 109 m3 of lava, reinforcing the idea that submarine lava eruptions are important in the growth of oceanic island volcanoes even after they emerged above sea level.
    Description: This project was funded by NSF grants OCE-97-29894 to M.G. and OCE-9818744 to J.M.R.
    Keywords: Hawaii ; Mauna Loa ; Submarine volcanism ; Radial vents ; Bathymetry ; Igneous petrology
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  • 61
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2006. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 7 (2006): Q05023, doi:10.1029/2005GC001204.
    Description: The Deep Ocean Raman In Situ Spectrometer (DORISS) instrument was deployed at the Sea Cliff Hydrothermal Field and Hydrate Ridge in July 2004. The first in situ Raman spectra of hydrothermal minerals, fluids, and bacterial mats were obtained. These spectra were analyzed and compared to laboratory Raman measurements of standards and samples collected from the site. Spectra of vent fluid (∼294°C at the orifice) at ∼2700 m depth were collected with noncontact and immersion sampling optics. Compared to spectra of ambient (∼2°C) seawater, the vent fluid spectra show changes in the intensity and positions of the water O-H stretch bands due to the elevated temperature. The sulfate band observed in seawater spectra is reduced in vent fluid spectra as sulfate is removed from vent fluid in the subseafloor. Additional components of hydrothermal fluid are present in concentrations too low to be detected with the current Raman system. A precision underwater positioner (PUP) was used to focus the laser spot on opaque samples such as minerals and bacterial mats. Spectra were obtained of anhydrite from actively venting chimneys, and of barite deposits in hydrothermal crusts. Laboratory analysis of rock samples collected in the vent field also detected the presence of gypsum. Spectra of bacterial mats revealed the presence of elemental sulfur (S8) and the carotenoid beta-carotene. Challenges encountered include strong fluorescence from minerals and organics and insufficient sensitivity of the instrument. The next generation DORISS instrument addresses some of these challenges and holds great potential for use in deep-sea vent environments.
    Description: Funding was provided by the David & Lucile Packard Foundation.
    Keywords: Cold seeps ; Hydrothermal vents ; Raman spectroscopy
    Repository Name: Woods Hole Open Access Server
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  • 62
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2006. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 111 (2006): C06026, doi:10.1029/2005JC003289.
    Description: Satellite remote sensing estimates of surface chlorophyll, temperature, wind speed, and sea ice cover are examined in the region of the Southern Ocean Iron Experiment (SOFeX). Our objectives are to place SOFeX into a regional context and highlight regional mesoscale spatial and monthly temporal variability. SOFeX fertilized two patches with iron, one south of the Antarctic Polar front (PF) and one north of the PF but south of the Subantarctic Front (SAF). Satellite observable phytoplankton blooms developed in both patches. The spring sea-ice retreat near the south patch site was delayed in the 2001-2002 season, in turn delaying the naturally occurring, modest spring bloom in this region. Ambient surface chlorophyll concentrations for the area surrounding the southern patch during January 2002 are low (mean 0.26 mg/m3) compared with climatological January values (0.42 mg/m3). Regions east and west at similar latitudes exhibited higher mean chlorophyll concentrations (0.79 and 0.74 mg/m3, respectively). These modest phytoplankton blooms were likely stimulated by melting sea-ice via changes in the light-mixing regime and release of iron, and were smaller in magnitude than the iron-induced bloom within the SOFeX southern patch (〉 3 mg/m3). Iron inputs from melting ice may drive much of the natural spatial and temporal variability within the seasonal ice zone. Mean chlorophyll concentrations surrounding the SOFeX northern patch site were similar to climatological values during the SOFeX season. The northern patch was stretched into a long, thin filament along the southern boundary of the SAF, likely increasing the mixing/dilution rate with surrounding waters.
    Description: S. Doney and K. Moore were supported by NASA grant NAG5-12520 from the NASA Ocean Biogeochemistry Program.
    Keywords: SeaWiFS ; Iron ; Marginal ice zone
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  • 63
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2006. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Paleoceanography 21 (2006): PA3010, doi:10.1029/2005PA001257.
    Description: Ocean circulation and global climate are strongly influenced by seawater density, which is itself controlled by salinity and temperature. Although adequate instrumental sea-surface temperature (SST) records exist for most of the surface oceans over the past 100-150 years, records of salinity really only exist for the last 40-50 years. Here we show that longer proxy records from corals (Siderastrea radians) in the eastern tropical North Atlantic are dominated by multi-decadal variations in salinity which are correlated with the relationship between SST and the North Atlantic Oscillation (NAO) over the course of the 20th century. The data reveal an increase in eastern tropical North Atlantic salinity of +0.5 psu between about 1950-1990. Rather than a monotonic secular increase, as indicated by some instrumental records, the pre-instrumental coral proxy records presented here suggest that salinity in the tropical North Atlantic is periodic on a decadal to multi-decadal scale.
    Keywords: Salinity ; Tropical North Atlantic ; North Atlantic Oscillation
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  • 64
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2006. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 111 (2006): G03002, doi:10.1029/2005JG000158.
    Description: Our current understanding of paleoecology and paleoceanography is largely based on the superb Phanerozoic fossil record of foraminiferan protists. The early history of the group is unresolved, however, because basal foraminiferans (allogromiids) are unmineralized and thus fossilize poorly. Molecular-clock studies date foraminiferal origins to the Neoproterozoic, but the deep sea – one of Earth’s most extensive habitats and presently a significant fraction of basal foraminiferal diversity— was probably anoxic at that time and, until now, anaerobic allogromiids were unknown. Molecular, cell and ecological analyses reveal the presence of a previously unknown allogromiid inhabiting anoxic, sulfidic deep-sea sediments (Santa Barbara Basin, California, USA). The fact that the new foraminifer harbors prokaryotic endobionts implicates symbiogenesis as a driving force in early foraminiferal diversification.
    Description: The Wadsworth Center’s Electron Microscopy, Biochemistry, and Molecular Genetics Core facilities, as well as its National Biotechnology Resource for the Visualization of Biological Complexity (supported by a NIH BRTP/NCRR grant) are gratefully acknowledged. Funded by NASA Exobiology NRA-01-01-EXB-057 (to J.M.B.); W. Storrs Cole Memorial Research Award (Geological Society of America, to J.M.B.); NSF DEB0445181 (to S.S.B.).
    Keywords: Foraminifera ; Santa Barbara Basin ; Symbiosis
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  • 65
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2006. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 33 (2006): L17403, doi:10.1029/2006GL026972.
    Description: Terrestrial ecosystems of the northern high latitudes (above 50oN) exchange large amounts of CO2 and CH4 with the atmosphere each year. Here we use a process-based model to estimate the budget of CO2 and CH4 of the region for current climate conditions and for future scenarios by considering effects of permafrost dynamics, CO2 fertilization of photosynthesis and fire. We find that currently the region is a net source of carbon to the atmosphere at 276 Tg C yr-1. We project that throughout the 21st century, the region will most likely continue as a net source of carbon and the source will increase by up to 473 Tg C yr-1 by the end of the century compared to the current emissions. However our coupled carbon and climate model simulations show that these emissions will exert relatively small radiative forcing on global climate system compared to large amounts of anthropogenic emissions.
    Description: This study was supported by a NSF Biocomplexity (ATM-0120468) and ARCSS programs; the NASA Land Cover and Land Use Change and EOS Interdisciplinary Science (NNG04GJ80G) programs; and by funding from MIT Joint Program on the Science and Policy of Global Change, which is supported by a consortium of government, industry and foundation sponsors.
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  • 66
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2006. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 111 (2006): B11207, doi:10.1029/2006JB004327.
    Description: One process for the formation of continental crust is the accretion of arc terranes at continental margins. A longstanding problem with this model is that although the composition of the continental crust is andesitic, the majority of arc lavas are basaltic. Moreover, those arc lavas that are andesitic tend to be evolved (lower Mg #) compared to the continental crust. Continental crust can be produced through mixing of basaltic and silicic arc lava compositions, assuming that mafic cumulates formed during generation of the silicic component are removed. If these cumulates are denser than the underlying mantle, removal can occur via foundering of lower arc crust. Indeed, field observations of the Talkeetna arc section in south-central Alaska, combined with modeling of fractionation in primitive arc magmas, suggest that large amounts of primitive gabbronorite and pyroxenite are missing from the lower crust. Using rock compositions from the Talkeetna section and the free energy minimization program Perple_X, we calculated equilibrium mineral assemblages for a range of gabbroic and ultramafic compositions at P, T, oxygen fugacity (fO2), and H2O contents appropriate for arc lower crust. The quartz-olivine-garnet-free mineral assemblage found in the Talkeetna gabbronorites (and in the similar Kohistan section in Pakistan) defines a narrow range of fO2 centered on NNO+2 (±1 log unit). Predicted mineral assemblages calculated under these conditions were used to estimate the density and seismic structure of the arc lower crust. We find that the missing gabbroic and ultramafic rocks from the Talkeetna section were likely denser than the underlying mantle, while the gabbronorites that remain are either neutrally or slightly positively buoyant. Generalizing, we show that lower crustal Vp 〉 7.4 km/s in modern arcs is indicative of lower crust that is convectively unstable relative to the underlying mantle. However, most lower crust in modern arcs is observed to have Vp 〈 7.4 km/s, implying that gravitationally unstable material must founder rapidly on geologic time-scales, or high Vp plutonic rocks crystallize beneath the Moho.
    Description: This research was funded in part by NSF Grants OCE-0426160, EAR-0409092, OCE-0242233, EAR-0125919, and EAR-9910899.
    Keywords: Arc lower crust ; Crustal foundering ; Thermodynamic modeling
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  • 67
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2006. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 111 (2006): C02006, doi:10.1029/2005JC003011.
    Description: Net northward transport below γn 〉 28.1 kgm−3 (≈3200 m) into the Perth Basin of between 4.4 and 5.8 Sv is estimated from a year-long current meter mooring array between the Broken and Naturaliste Plateaus. Northward transport of between 2.0 and 2.5 Sv of Antarctic Bottom Water (γn 〉28.2 kgm−3), that must upwell within the southern region of the Perth Basin, results in an area-averaged diapycnal velocity and diffusivity of w*=2.5− 3.1× 10−6 ms−1 and κ = 13−15×10−4 m2s−1, respectively. Diffusivity estimates for the Perth Basin are several times larger than area averaged mixing estimates for the abyssal subtropical South Atlantic and Pacific Oceans. However, the dissipation of turbulent kinetic energy required to maintain the abyssal mixing in the Perth basin, ε=O(10−9 Wkg−1), is similar to that required in the South Atlantic Ocean. The area-averaged diffusivity in the Perth Basin does not require unreasonable energy dissipation rates as this ocean basin is only weakly stratified. The abyssal diffuvisity of the Perth Basin results from intense mixing at the basin boundary and in the basin interior over rough topography. The complex bathymetry and low abyssal stratification suggests that the Indian Ocean, for a given energy dissipation, may support a larger meridional overturning circulation than other subtropical basins.
    Description: BMS was supported by funds from the Ocean and Climate Change Institute at the Woods Hole Oceanographic Institution, and The James S. Cole and Cecily C. Selby Endowed Fund and The Penzance Endowed Fund in support of Assistant Scientists. The mooring array was funded by Australia’s CSIRO Marine Research.
    Keywords: Water masses ; Deep recirculation and transport ; Turbulence ; Diffusion ; Indian Ocean
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  • 68
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2006. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 111 (2006): C06028, doi:10.1029/2004JC002821.
    Description: This paper describes a simple “multibox” model of the Arctic atmosphere-ice-ocean system. The model consists of two major modules (an Arctic module and a Greenland Sea module) and several sub-modules. The Arctic module includes a shelf box model coupled with a thermodynamic sea ice model, and an Arctic Ocean model coupled with a sea ice model and an atmospheric box model. The Greenland Sea module includes an oceanic model coupled with a sea ice model and a statistical model of surface air temperature over the Greenland Sea. The full model is forced by daily solar radiation, wind stress, river runoff, and Pacific Water inflow through Bering Strait. For validation purposes, results from model experiments reproducing seasonal variability of the major system parameters are analyzed and compared with observations and other models. The model reproduces the seasonal variability of the Arctic system reasonably well and is used to investigate decadal Arctic climate variability in Part 2 of this publication.
    Description: This publication is the result of research sponsored by Alaska Sea Grant with funds from the National Oceanic and Atmospheric Administration Office of Sea Grant, Department of Commerce, under grant no. NA 86RG0050 (project no. GC/01-02), and from the University of Alaska with funds appropriated by the state. This research has also been supported by the National Science Foundation and by the International Arctic Research Center, University of Alaska Fairbanks, under auspices of the United States National Science Foundation.
    Keywords: Arctic decadal oscillations ; Idealized Arctic model ; Arctic–Greenland Sea interaction
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  • 69
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2005. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 6 (2005): Q03001, doi:10.1029/2004GC000849.
    Description: The Zagros mountains of southern Iran are marked by a zone of high seismicity and accommodate a significant portion of the convergence between Arabia and Eurasia. Due to the lack of dense local seismic or geodetic networks, the inferred kinematics of the collision in Iran is mainly based on catalogs of teleseismically determined earthquake locations. We surveyed all M w 〉 4.5 earthquakes in the Harvard Centroid Moment Tensor (HCMT) and International Seismological Centre (ISC) catalogs that occurred in the Zagros mountains during the period 1992–2002 and that were spanned by Interferometric Synthetic Aperture Radar (InSAR) images from the ERS 1 and 2 satellites. We invert the observed deformation for the best fitting point source, single fault plane, and distributed fault slip for four earthquakes and one unexplained deformation event. We find that we can precisely locate earthquakes that are too small to be well-located by either the HCMT or ISC catalogs, allowing us to tie specific earthquakes to active geologic structures.
    Description: ERS 1 and 2 data were acquired through an ESA category-1 proposal. R. Lohman is partially supported by a NASA New Investigator Program grant award to M. Simons.
    Keywords: DOAS ; SO2 emissions
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  • 70
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2004. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 5 (2004): Q10004, doi:10.1029/2004GC000772.
    Description: Long-chain, odd-carbon-numbered C25 to C35 n-alkanes are characteristic components of epicuticular waxes produced by terrestrial higher plants. They are delivered to aquatic systems via eolian and fluvial transport and are preserved in underlying sediments. The isotopic compositions of these products can serve as records of past vegetation. We have developed a rapid method for stable carbon isotopic analyses of total plant-wax n-alkanes using a novel, moving-wire system coupled to an isotope-ratio mass spectrometer (MW-irMS). The n-alkane fractions are prepared from sediment samples by (1) saponification and extraction with organic solvents, (2) chromatographic separation using silica gel, (3) isolation of straight-chain carbon skeletons using a zeolite molecular sieve, and (4) oxidation and removal of unsaturated hydrocarbons with RuO4. Short-chain n-alkanes of nonvascular plant origin (〈C25) are removed by evaporation on the moving wire. Test samples processed using this procedure yielded n-alkane fractions essentially free of interfering components. The δ13C values obtained by MW-irMS did not differ significantly from weighted averages of individual n-alkane δ13C values obtained by irmGC-MS. Isotopic variations in compound-class n-alkane fractions from a latitudinal transect of core-top sediments from the Southwest African margin (3°N–28°S) were congruent with those measured by compound-specific isotopic analyses of plant-wax n-alkanes. The amplitude of the variations was smaller, indicating contributions from non-plant-wax hydrocarbons, but the measurements revealed variations in carbon isotopic composition that are consistent with vegetation zones on the adjacent continent.
    Description: We thank the WHOI Summer Student Fellow program and NSF (BCS-0218511) for funding.
    Keywords: Moving wire ; Plant-wax n-alkanes ; Stable carbon isotopes
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  • 71
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2006. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 111 (2006): C05015, doi:10.1029/2005JC002989.
    Description: New in situ observations from 10°N, 125°W during 1997–1998 show strong intraseasonal variability in meridional velocity and sea surface temperature. The 50- to 100-day oscillations in sea surface height (SSH) have long been recognized as a prominent aspect of oceanic variability in the region of 9–13°N in the eastern Pacific Ocean. We use in situ and satellite data to more fully characterize this variability. The oscillations have zonal wavelengths of 550–1650 km and propagate westward in a manner consistent with the dispersion relation for first baroclinic mode, free Rossby waves in the presence of a mean westward flow. Analysis of 9 years of altimetry data shows that the amplitude of the 50- to 100-day SSH variability at 10°N is largest on 90–115°W, with peak amplitudes occurring around April. Some eddies traveling westward at 10–13°N emanate from near the gulfs of Tehuantepec and Papagayo, but eddies sometimes also appear to intensify well away from the coast while in the North Equatorial Current (NEC). The hypothesis that the intraseasonal variability and its annual cycle are associated with baroclinic instability of the NEC is supported by a spatiotemporal correlation between the amplitude of 50- to 100-day variability and the occurrence of westward zonal flows meeting an approximate necessary condition for baroclinic instability. The notion that baroclinic instability may be involved is further corroborated by the tendency of the NEC to weaken while the eddies intensify, even as the wind works to strengthen the current.
    Description: The authors gratefully acknowledge support for the fieldwork under the NOAA Office of Global Programs Pan American Climate Studies program (grants NA66GPO130 and NA96GPO428) and for analysis and publication (grants NA87RJ0445 and NA17RJ1223).
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  • 72
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2006. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 111 (2006): C07S06, doi:10.1029/2005JC003173.
    Description: Climate variability drives significant changes in the physical state of the North Pacific, and thus there may be important impacts of climate variability on the upper ocean carbon balance across the basin. We address this issue by considering the response of seven biogeochemical ocean models to climate variability in the North Pacific. The models’ upper ocean pCO2 and air-sea CO2 flux respond similarly to climate variability on seasonal to decadal timescales. Modeled seasonal cycles of pCO2 and its temperature and non-temperature driven components at three contrasting oceanographic sites capture the basic features found in observations [Takahashi et al., 2002, 2006; Keeling et al., 2004; Brix et al., 2004]. However, particularly in the Western Subarctic Gyre, the models have difficulty representing the temporal structure of the total pCO2 cycle because it results from the difference of these two large and opposing components. In all but one model, the airsea CO2 flux interannual variability (1σ) in the North Pacific is smaller (ranges across models from 0.03 to 0.11 PgC/yr) than in the Tropical Pacific (ranges across models from 0.08 to 0.19 PgC/yr), and the timeseries of the first or second EOF of the air-sea CO2 flux has a significant correlation with the Pacific Decadal Oscillation (PDO). Though air-sea CO2 flux anomalies are correlated with the PDO, their magnitudes are small (up to ±0.025 PgC/yr (1σ)). Flux anomalies are damped because anomalies in the key drivers of pCO2 (temperature, dissolved inorganic carbon (DIC) and alkalinity) are all of similar magnitude and have strongly opposing effects that damp total pCO2 anomalies.
    Description: F. Chai and L. Shi acknowledge grant support from NSF (OCE 0137272) and NASA (NAG5-9348; S. Doney and I. Lima from NSF/ONR NOPP (N000140210370) and NASA (NNG05GG30G); G. McKinley from NASA (NNG05GF94G); and T. Takahashi from NOAA (NA16GP2001).
    Keywords: Ocean carbon cycle ; Ocean models ; PDO
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  • 73
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    American Geophysical Union
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2006. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 33 (2006): L14614, doi:10.1029/2006GL026769.
    Description: Potential temperature differences are computed from hydrographic sections transiting the western basins of the South Atlantic Ocean from 60°S to the equator in 2005/2003 and 1989/1995. While warming is observed throughout much of the water column, the most statistically significant warming is about +0.04°C in the bottom 1500 dbar of the Brazil Basin, with similar (but less statistically significant) warming signals in the abyssal Argentine Basin and Scotia Sea. These abyssal waters of Antarctic origin spread northward in the South Atlantic. The observed abyssal Argentine Basin warming is of a similar magnitude to that previously reported between 1980 and 1989. The Brazil Basin abyssal warming is similar in size to and consistent in timing with previously reported changes in abyssal southern inflow and northern outflow. The temperature changes reported here, if they were to hold throughout the abyssal world ocean, would contribute substantially to global ocean heat budgets.
    Description: The 2005 and 2003 cruises on the NOAA Ship Ronald Brown are part of the NOAA/NSF funded U.S. CLIVAR/CO2 Repeat Hydrography Program. The NOAA Office of Oceanic and Atmospheric Research and the NOAA Climate Program Office further supported GCJ.
    Keywords: Antarctic bottom water ; Brazil Basin ; Atlantic Ocean
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  • 74
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2005. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 6 (2005): Q09008, doi:10.1029/2005GC000954.
    Description: We reconstruct the volcanic and tectonic evolution over the last 250,000 years of the median valley floor in the spreading segment of the Mid-Atlantic Ridge centered at 25°N. In the center of the segment, multibeam bathymetry and deep-towed side-scan images show a large area of smooth-textured lava flows more like those of the East Pacific Rise than those of the Mid-Atlantic Ridge. Hummocky flows more typical of the Mid-Atlantic Ridge are found toward the southern end of the segment. The presence of the abundant smooth-textured flows allows us to interpret the volcanic and tectonic relationships in the segment. We construct a geological map using (1) multibeam bathymetry to identify the key volcanic structures and fault scarps and (2) high-resolution TOBI side-scan sonar images to interpret age relationships between features on the basis of overall sediment cover as shown by backscatter brightness. Bottom photographs across key features on the median valley floor yield detailed information on stratigraphic relationships between volcanic features and faults and allow us to calibrate backscatter brightness in terms of sediment cover and hence of age. In this way we derive a history of volcanic activity and deformation in a detailed survey area at the segment center, with the most recent flows erupted about 5000 years ago, and the youngest smooth flows about 10,000 years ago, separated by an episode of faulting. Using bathymetry and side-scan surveys, we extrapolate this to the whole of the median valley floor. The volcanic activity giving rise to the smooth flows has been continuous for about a quarter of a million years at the segment center. Over the same period, hummocky flows have been continuously erupted at the southern end of the segment. Electron probe analyses of dredged basalt glasses show that there is a systematic variation in composition with position in the segment. Basalts from the segment center are all more evolved than those at the southern end of the segment. There is, however, no relation of chemistry with lava type. The basalts from the segment center have very nearly the same composition whether they come from hummocky flows or smooth flows. The boundary between the smooth flows and hummocky flows has fluctuated with time and migrated rapidly northward over the last few thousand years, so that shortly the eruption of smooth flows will probably have ceased. The survey shows that flows that are smooth on side-scan images are not necessarily sheet flows. In this study they uniformly show pillow morphology. We conclude that smooth flows were probably erupted at faster eruption rates than hummocky flows.
    Description: This project was funded by an NERC grant that enabled Charles Darwin cruise 65 and by NSF grant OCE-9811575.
    Keywords: Mid-Atlantic Ridge ; Volcanism ; Faulting ; Tectonic history ; Smooth-textured flows ; Hummocky flows
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    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2004. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 5 (2004): Q04G14, doi:10.1029/2002GC000439.
    Description: This paper presents new magmatic helium isotopic compositions in a suite of lavas from phase II of the Hawaiian Scientific Drilling Project (HSDP2) core, which sampled Mauna Kea volcano to a maximum depth of 3098 m below sea level. Most of the measurements were performed by in vacuo crushing of olivine phenocrysts, but include submarine pillow glasses from the 2200 to 2500 meter depth interval, and orthopyroxene phenocrysts from an intrusive at 1880 m. The magmatic 3He/4He ratios range from 6 to 24.7 times atmospheric (Ra), which significantly extends the range of values for Mauna Kea volcano. The 3He/4He ratios are lowest (i.e., close to MORB values of ∼8 Ra) near the top of the Mauna Kea section and rise slowly, to 10–12 Ra, at 1000 m below sea level, consistent with results from the HSDP1 core. At depths greater than 1000 m in the core, primarily in the submarine lavas, there are brief periods when the 3He/4He ratios are higher than 14.5 Ra, always returning to a baseline value. Twelve such excursions were identified in the core; all but one are in the submarine section, and most (7) are in the deepest section, at depths of 1950 to 3070 m. The baseline 3He/4He value rises from 10–12 Ra near 1000 m depth to 12–14 Ra at 3000 m. The helium spikes are found only in lavas that are older than 380 Ka in age, based on an age model derived from Ar-Ar data (W. D. Sharp et al., manuscript in preparation, 2003). Excluding the excursions defined by single lava flows (3) and intrusive units (3), the average spike duration is approximately 15 (±9) Ka (n = 6). The high 3He/4He spikes are interpreted as pulses of magma from the center of the actively upwelling Hawaiian hot spot. The short duration of the high 3He/4He excursions suggests that Mauna Kea was never directly over high the 3He/4He component of the plume (during the HSDP2 eruptive period), presumed to be the plume center. Assuming that the Mauna Kea helium spikes result from melting of heterogeneities within the plume, their short duration implies that the length scales of heterogeneities in the solid upwelling mantle are between 60 m and 12 km (for upwelling rates of 2 to 40 cm/yr). The high 3He/4He are associated with high 208Pb/204Pb, and relatively low 143Nd/144Nd, Zr/Nb, and SiO2. The correlations with major elements, trace elements and isotopes demonstrate that helium is coupled to the other geochemical variations, and that the Mauna Kea isotopic variability is caused by heterogeneities within the upwelling plume.
    Description: This work was supported by EAR/NSF through the Continental Dynamics and Instrumentation and Facilities programs.
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    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2004. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 5 (2004): Q06007, doi:10.1029/2004GC000702.
    Description: We deployed five ocean bottom hydrophones (OBHs) for a 1-year seismic monitoring study of Vailulu'u Seamount, the youngest and easternmost volcano in the Samoan Archipelago. Four instruments were placed on the summit crater rim at 600–700 m water depth, and one was placed inside the crater at 1000 m water depth. An analysis of the first 45 days of records shows a very large number of seismic events, 211 of them local. These events define a steady background activity of about four seismic events per day, increasing to about 10 events per day during a week of heightened seismic activity, which peaked at 40 events during 1 day. We identified 107 earthquakes, whose arrivals could be picked on all five stations and that are likely located within the seamount, based on their similar waveforms. Two linear trends are defined by 21 of these events. These are extremely well correlated and located, first downward then upward on a steeply inclined plane that is close to the axial plane of the southeast rift as it emerges from the main summit of Vailulu'u. These events resemble volcanotectonic earthquakes from subaerial volcanoes in displaying very coherent seismic waveforms and by showing systematic, narrowly defined progressions in hypocenter locations. We propose that these events reflect brittle rock failure due to magma redistribution in or near a central magma reservoir.
    Description: The bulk of this work was funded by NSF-OCE, in grants to HS and SRH and the OBSIP facility at Scripps.
    Keywords: Samoa ; Vailulu'u ; Volcano ; Seismic monitoring ; Volcanic activity ; Submarine
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  • 77
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2004. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 5 (2004): Q01007, doi:10.1029/2002GC000408.
    Description: Volcanic glasses contained in distal fallout tephras from the Izu arc volcanic front (Izu VF) provide unique perspectives on general problems of arc volcanism. Unlike cogenetic lavas, these glasses are liquid compositions where element concentrations as well as ratios have significance. Isotopic evidence and previous work show that there is no sediment melt contribution to the sources of the Izu VF tephras, and hence their trace element characteristics permit determination of the trace element contents of slab fluids. The slab fluid is a composite of metasediment (∼5% of total fluid) and metabasalt (∼95%) component fluids, and carries large ion lithophile elements (LILE) with high LILE/Th and LILE/U, and low Th and U relative to source. Except for Sr and K, the metabasalt fluid is much less enriched than the metasediment fluid, but its large relative proportions make it an important carrier of many trace elements. The metabasalt fluid has the characteristics of the arc trace element signature, obviating the need for ubiquitous involvement of sediment in arc magma genesis. The fluid component in the tephras is remarkably constant in composition over fifteen million years, and hence appears to be a robust composition that may be applicable to other convergent margins. Assuming that the metabasalt fluid is a common component, and that distribution coefficients between sediment and fluid are similar from one arc to another, composite fluid compositions can be estimated for other arcs. Differences from this composition then would likely result from a sediment melt component. Comparison to arcs with sediment melt components in their source (Marianas, eastern Aleutians) shows that partial sediment melts may be so enriched, that they can completely mask the signature of the comingling slab fluids. Hence sediment melts can easily dominate the trace element and isotopic signature of many convergent margins. Since sediment melts inherit the LILE/LILE ratios of the trench sediment, Earth's surface processes must eventually influence the compositional diversity of arcs.
    Description: This study was funded by the “Deutsche Forschungsgemeinschaft” (grants Str 441/3 and 441/4). The Northeast National Ion Microprobe Facility at WHOI was supported by grants EAR-9628749 and EAR-990440 from the National Science Foundation.
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  • 78
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2005. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 6 (2005): Q12P07, doi:10.1029/2005GC000974.
    Description: Secondary ion mass spectrometry (SIMS) is useful for measuring Mg/Ca in both primary calcite and diagenetic minerals in planktonic foraminifera. The excellent spatial resolution (〈10 μm) and small amount of material removed (〈2 ng) makes it easy to avoid targets that include obvious embedding material and encrusting or infilling minerals such as secondary calcite and authigenic clays in diagenetically altered samples. Because analyses can be performed on individuals, SIMS is also a viable technique for generating Mg/Ca values from sediment samples in which foraminifera are rare or have low mass. For clean primary calcite samples, Mg/Ca ratios from SIMS compare well to those obtained using inductively coupled plasma mass spectrometry (ICP-MS), while maintaining information regarding the true variability of elemental ratios within individual tests. For samples with secondary calcite or stubbornly adhering clays, SIMS enables us to accurately measure primary calcite compositions and to assess and reconcile contamination problems in bulk samples analyzed by solution-based ICP-MS. We have observed that SIMS is an invaluable and reliable tool for the identification and avoidance of problems of diagenesis and the analysis of rare or delicate planktonic foraminifera. However, because of operator time required to properly target delicate (thin-walled) or contaminated planktonic foraminifera, SIMS may not be feasible for Mg/Ca studies where large numbers (hundreds) of samples must be processed and bulk measurements on multiple individuals will suffice.
    Description: Funding for this research was provided by The Andrew W. Mellon Foundation Endowed Fund for Innovative Research and by the U.S. Science Support Program of the Joint Oceanographic Institutions. This material is also based on work supported by the National Science Foundation under grant OCE-0334598. Partial support for the Northeast National Ion Microprobe Facility was provided by NSF (EAR-0115433). This research used samples and data provided by the Ocean Drilling Program (ODP). ODP is sponsored by the U.S. National Science Foundation and participating countries under management of Joint Oceanographic Institutions, Inc.
    Keywords: Cenomanian ; Eocene ; Holocene ; Mg/Ca ; Paleoceanography ; Paleocene
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  • 79
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2005. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 6 (2005): Q01007, doi:10.1029/2004GC000841.
    Description: Repeat-pass Interferometric Synthetic Aperture Radar (InSAR) provides spatially dense maps of surface deformation with potentially tens of millions of data points. Here we estimate the actual covariance structure of noise in InSAR data. We compare the results for several independent interferograms with a large ensemble of GPS observations of tropospheric delay and discuss how the common approaches used during processing of InSAR data affects the inferred covariance structure. Motivated by computational concerns associated with numerical modeling of deformation sources, we then combine the data-covariance information with the inherent resolution of an assumed source model to develop an efficient algorithm for spatially variable data resampling (or averaging). We illustrate these technical developments with two earthquake scenarios at different ends of the earthquake magnitude spectrum. For the larger events, our goal is to invert for the coseismic fault slip distribution. For smaller events, we infer the hypocenter location and moment. We compare the results of inversions using several different resampling algorithms, and we assess the importance of using the full noise covariance matrix.
    Description: R. Lohman is partially supported by a NASA New Investigator Program grant award to M. Simons.
    Keywords: Correlated noise ; InSAR ; Little Skull Mountain
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  • 80
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2004. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 5 (2004): Q08002, doi:10.1029/2004GC000712.
    Description: Detailed hydrothermal surveys over ridges with spreading rates of 50–150 mm/yr have found a linear relation between spreading rate and the spatial frequency of hydrothermal venting, but the validity of this relation at slow and ultraslow ridges is unproved. Here we compare hydrothermal plume surveys along three sections of the Gakkel Ridge (Arctic Ocean) and the Southwest Indian Ridge (SWIR) to determine if hydrothermal activity is similarly distributed among these ultraslow ridge sections and if these distributions follow the hypothesized linear trend derived from surveys along fast ridges. Along the Gakkel Ridge, most apparent vent sites occur on volcanic highs, and the extraordinarily weak vertical density gradient of the deep Arctic permits plumes to rise above the axial bathymetry. Individual plumes can thus be extensively dispersed along axis, to distances 〉200 km, and ∼75% of the total axial length surveyed is overlain by plumes. Detailed mapping of these plumes points to only 9–10 active sites in 850 km, however, yielding a site frequency F s , sites/100 km of ridge length, of 1.1–1.2. Plumes detected along the SWIR are considerably less extensive for two reasons: an apparent paucity of active vent fields on volcanic highs and a normal deep-ocean density gradient that prevents extended plume rise. Along a western SWIR section (10°–23°E) we identify 3–8 sites, so F s = 0.3–0.8; along a previously surveyed 440 km section of the eastern SWIR (58°–66°E), 6 sites yield F s = 1.3. Plotting spreading rate (us) versus F s, the ultraslow ridges and eight other ridge sections, spanning the global range of spreading rate, establish a robust linear trend (F s = 0.98 + 0.015us), implying that the long-term heat supply is the first-order control on the global distribution of hydrothermal activity. Normalizing F s to the delivery rate of basaltic magma suggests that ultraslow ridges are several times more efficient than faster-spreading ridges in supporting active vent fields. This increased efficiency could derive from some combination of three-dimensional magma focusing at volcanic centers, deep mining of heat from gabbroic intrusions and direct cooling of the upper mantle, and nonmagmatic heat supplied by exothermic serpentinization.
    Description: This research was partially supported the NOAA VENTS Program. P.J.M. and H.J.B.D. gratefully acknowledge NSF grant OPP 9911795 for support of the AMORE Expedition; P.J.M. and E.T.B. acknowledge NSF grant OPP 0107767 and the VENTS Program for development and construction of MAPRs for use in ice-covered seas. H.J.B.D. acknowledges NSF grant OCE-9907630 for support of SWIR studies. J.E.S. was supported by Deutsche Forschungsgemeinschaft grant SN15/2.
    Keywords: Gakkel Ridge ; Hydrothermal venting ; Magmatic budget ; Southwest Indian Ridge ; Ultraslow ridges
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  • 81
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2006. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 7 (2006): Q03002, doi:10.1029/2005GC001094.
    Description: In the decade following documented volcanic activity on the East Pacific Rise near 9°50′N, we monitored hydrothermal vent fluid temperature variations in conjunction with approximately yearly vent fluid sampling to better understand the processes and physical conditions that govern the evolution of seafloor hydrothermal systems. The temperature of both diffuse flow (low-temperature) and focused flow (high-temperature) vent fluids decreased significantly within several years of eruptions in 1991 and 1992. After mid-1994, focused flow vents generally exhibited periods of relatively stable, slowly varying temperatures, with occasional high- and low-temperature excursions lasting days to weeks. One such positive temperature excursion was associated with a crustal cracking event. Another with both positive and negative excursions demonstrated a subsurface connection between adjacent focused flow and diffuse flow vents. Diffuse flow vents exhibit much greater temperature variability than adjacent higher-temperature vents. On timescales of a week or less, temperatures at a given position within a diffuse flow field often varied by 5°–10°C, synchronous with near-bottom currents dominated by tidal and inertial forcing. On timescales of a week and longer, diffuse flow temperatures varied slowly and incoherently among different vent fields. At diffuse flow vent sites, the conceptual model of a thermal boundary layer immediately above the seafloor explains many of the temporal and spatial temperature variations observed within a single vent field. The thermal boundary layer is a lens of warm water injected from beneath the seafloor that is mixed and distended by lateral near-bottom currents. The volume of the boundary layer is delineated by the position of mature communities of sessile (e.g., tubeworms) and relatively slow-moving organisms (e.g., mussels). Vertical flow rates of hydrothermal fluids exiting the seafloor at diffuse vents are less than lateral flow rates of near-bottom currents (5–10 cm/s). The presence of a subsurface, shallow reservoir of warm hydrothermal fluids can explain differing temperature behaviors of adjacent diffuse flow and focused flow vents at 9°50′N. Different average temperatures and daily temperature ranges are explained by variable amounts of mixing of hydrothermal fluids with ambient seawater through subsurface conduits that have varying lateral permeability.
    Description: Field and shore-based analyses have been supported by the National Science Foundation (OCE-0096468, OCE-8917311, OCE-9217026, OCE-9302205, OCE-0327261), the Woods Hole Oceanographic Institution's Vetlesen Fund and W. A. Clark Senior Scientist Chair (DJF), and the Devonshire Foundation (TMS).
    Keywords: Hydrothermal systems ; East Pacific Rise ; Vent fluids ; Seafloor eruptions
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    Publication Date: 2006-12-01
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    Electronic ISSN: 1944-7973
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