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  • 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry  (58)
  • 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics  (38)
  • Elsevier Science Limited  (47)
  • American Geophysical Union  (45)
  • Cell Press
  • Irkutsk : Ross. Akad. Nauk, Sibirskoe Otd., Inst. Zemnoj Kory
  • Krefeld : Geologischer Dienst Nordhein-Westfalen
  • Wiley
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Years
  • 1
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    Eruptive activity at Turrialba volcano (Costa Rica): Inferences from 3He/4He in fumarole gases and chemistry of the products ejected during 2014 and 2015 (2017)
    American Geophysical Union
    Details
    Publication Date: 2021-03-01
    Description: A new period of eruptive activity started at Turrialba volcano, Costa Rica, in 2010 after almost 150 years of quiescence. This activity has been characterized by sporadic explosions whose frequency clearly increased since October 2014. This study aimed to identify the mechanisms that triggered the resumption of this eruptive activity and characterize the evolution of the phenomena over the past 2 years. We integrate 3He/4He data available on fumarole gases collected in the summit area of Turrialba between 1999 and 2011 with new measurements made on samples collected between September 2014 and February 2016. The results of a petrological investigation of the products that erupted between October 2014 and May 2015 are also presented. We infer that the resumption of eruptive activity in 2010 was triggered by a replenishment of the plumbing system of Turrialba by a new batch of magma. This is supported by the increase in 3He/4He values observed since 2005 at the crater fumaroles and by comparable high values in September 2014, just before the onset of the new eruptive phase. The presence of a number of fresh and juvenile glassy shards in the erupted products increased between October 2014 and May 2015, suggesting the involvement of new magma with a composition similar to that erupted in 1864–1866. We conclude that the increase in 3He/4He at the summit fumaroles since October 2015 represents strong evidence of a new phase of magma replenishment, which implies that the level of activity remains high at the volcano.
    Description: Published
    Description: 3V. Proprietà dei magmi e dei prodotti vulcanici
    Description: 4V. Dinamica dei processi pre-eruttivi
    Description: 5V. Dinamica dei processi eruttivi e post-eruttivi
    Description: JCR Journal
    Keywords: Turrialba volcano ; eruptive activity ; 3He/4He ; fumarole gases ; glassy shards ; juvenile component ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.07. Tectonophysics::04.07.08. Volcanic arcs ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 2
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    Geochemistry of the mantle source and magma feeding system beneath Turrialba volcano, Costa Rica (2016)
    Elsevier Science Limited
    Details
    Publication Date: 2020-10-29
    Description: Turrialba volcano lies in the southern sector of the Central American Volcanic Front (CAVF) in Costa Rica. The geochemistry of major and trace elements, and Sr and Nd isotopes of a selected suite of volcanic rocks ranging in composition from basaltic andesite to dacite and belonging to the last 10 ka of activity of Turrialba volcano is described, together with the He-, Ne-, and Ar-isotope compositions of fluid inclusions hosted in olivine and pyroxene crystals. Most of the variability in the rock chemistry is consistentwith typical trends of fractional crystallization, but there is an outlying group of andesites that displays an adakite-like composition (with a consistent depletion in high-field-strength elements and a marked enrichment in Sr) and low 3He/4He ratios (7.0–7.2 Ra). The trace-element composition of these rocks is typical of subduction-related magmas influenced by an OIB-like component at the source associated with the subduction of the Galapagos seamounts. The 87Sr/86Sr (0.703612–0.703678) and 143Nd/144Nd (0.512960–0.512984) ratios of the bulk rocks vary within narrowranges, and are among the least-radiogenic isotope signatures of the CAVF volcanoes. The 3He/4He ratios measured in fluid inclusions hosted in olivine crystals (up to 8.1 Ra) are among the highest for the CAVF, and indicate that radiogenic 4He from fluids derived fromthe subducting slab contribute negligibly to the mantle wedge. The difference in He isotopes between most of studied rocks and those showing adakite-like features reasonably reflects two distinct components in the local mantle: (1) a MORB-like component, characterized by the highest He-isotope ratios (7.8–8.1 Ra), and (2) an OIB-like component, characterized by lower He-isotope ratios (7.0–7.2 Ra), coming from the subduction of the Galapagos seamounts. An overview at the regional scale indicates that high He-isotope ratios are peculiar to the two extreme sectors of the CAVF (Costa Rica to the south and Guatemala to the north), whereas in the central sector (Nicaragua) the magma source is probably contaminated by slab fluids. For the past few years Turrialba volcano has been in a volcanic unrest phase that has included a series of explosions, the most recent of which occurred between October 2014 and May 2015. The volcano is subject to an ongoing safety alert due to the possibility of a magmatic eruption. One of the crucial questions to be addressed is the kind of eruption that can be expected, and hence what type of magma is likely to be involved. The high 3He/4He ratios (7.8–8.0 Ra) measured during 2011 at high-temperature fumaroles of Turrialba craters are comparable to those measured in fluid inclusions of basaltic andesites that erupted in 1864–1866, suggesting that the magma currently feeding the shallow plumbing system has similar geochemical characteristics to the most recently erupted magma.
    Description: Published
    Description: 319-335
    Description: 1V. Storia e struttura dei sistemi vulcanici
    Description: 2V. Dinamiche di unrest e scenari pre-eruttivi
    Description: JCR Journal
    Description: restricted
    Keywords: Turrialba ; 3He/4He ratio ; Fluid inclusions ; Adakite ; MORB mantle ; OIB mantle ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology ; 04. Solid Earth::04.04. Geology::04.04.07. Rock geochemistry ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 3
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    New evidence of CO2 soil degassing anomalies on Piton de la Fournaise volcano and the link with volcano tectonic structures (2016)
    American Geophysical Union
    Details
    Publication Date: 2017-04-04
    Description: Piton de la Fournaise (PdF) is recognised as one of the world’s most active volcanoes in terms of eruptive frequency and the substantial quantity of lava produced. Yet, with the sole exception of rather modest intracrateric fumarole activity, this seems to be in contrast with an apparent absence of any type of natural fluid emission during periods of quiescence. Measurement campaigns were undertaken during a long-lasting quiescent period (2012-2014) and just after a short lived summit eruption (June 2014) in order to identify potential degassing areas in relation to the main structural features of the volcano (ex. rift zones) with the aim of developing a broader understanding of the geometry of the plumbing and degassing system. In order to assess the possible existence of anomalous soil CO2 flux, 513 measurements were taken along transects roughly orthogonal to the known tectonic lineaments crossing PdF edifice. In addition, 53 samples of gas for C isotope analysis were taken at measurement points that showed a relatively high CO2 concentration in the soil. CO2 flux values range from 10 to 1300 g m-2 d-1 while 13C are between -26.6 to -8‰. The results of our investigation clearly indicate that there is a strong spatial correlation between the anomalous high values of diffusive soil emissions and the main rift zones cutting the PdF massif and, moreover, that generally high soil CO2 fluxes show a d13C signature clearly related to a magmatic origin.
    Description: INSU (CNRS) and La Réunion Préfecture (Projet pour la quantification de l’aléa volcanique à La Réunion)
    Description: Published
    Description: 4388–4404
    Description: 2V. Dinamiche di unrest e scenari pre-eruttivi
    Description: JCR Journal
    Description: restricted
    Keywords: CO2 soil degassing anomalies at Piton de la Fournaise ; d13C magmatic signature ; Close link between anomalous CO2 degassing and the main seismotectonic structures ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 4
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    Asynchronous changes of CO2, H2 and He concentrations in soil gases: a theoretical model and experimental results (2016)
    American Geophysical Union
    Details
    Publication Date: 2017-04-04
    Description: This paper focuses on the chemical composition changes in soil gases through both a theoretical model and laboratory experiments. The model describes the one-dimensional mass transfer process, which is triggered by changes in the flux parameters of the system, and the time-dependent evolution of the composition of the soil gases as a function of i) the pristine gas mixture, ii) the diffusivity of the chemicals, and iii) the thickness of the transited medium. Carbon dioxide (CO2), hydrogen (H2), and helium (He) were used in a laboratory-scale flux simulator to investigate the evolution of the gas composition profile in an artificial soil of constant thickness. The agreement between the theoretical calculations and the experimental results supports the validity of the model. Our results indicate a good reproducibility of the transient changes in the concentrations of CO2, He, and H2 in CO2-rich gas mixtures that contain He and H2 as trace gases. Finally, the theoretical results were used to analyze the H2 and CO2 continuous monitoring data collected at Etna volcano in 2010
    Description: Published
    Description: 1565–1583
    Description: 2V. Dinamiche di unrest e scenari pre-eruttivi
    Description: 5V. Sorveglianza vulcanica ed emergenze
    Description: 1IT. Reti di monitoraggio e Osservazioni
    Description: JCR Journal
    Description: open
    Keywords: Soil gases ; Volcanic gas composition ; Hydrogen ; Carbon dioxide ; CO2 ; Helium ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 5
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    Dissolved inert gases (He, Ne and N2) as markers of groundwater flow and degassing areas at Mt Etna volcano (Italy) (2016)
    Elsevier Science Limited
    Details
    Publication Date: 2017-04-04
    Description: Fractions of the volatiles ascending from magma chambers meet groundwaters flowing away from the volcano summit and are carried to great distance as dissolved gases. The complex interactions between ascending magmatic volatiles, tectonic structures, heterogeneities in rock permeability and flow lines of aquifers deeply affect the dispersion of the dissolved species. Studying the spatial distribution of such species can therefore provide valuable information on the circulation of fluids inside volcanic edifices. Our study focussed on the composition of dissolved inert gases (He, Ne and N2) and He isotope ratio (3He/4He) in groundwaters circulating at Mt Etna volcano (Italy), because the concentrations of these species differ markedly between magmatic and shallow(crustal and atmospheric) sources, and they do not interact chemically with rocks. We identified groundwaters that flow through anomalously degassing areas associated with clearly evident or known tectonic structures. These waters show a typically magmatic He isotope composition (high 3He/4He ratios) and high proportions of dissolved magmatic gases (He and CO2) compared to the atmospheric ones (Ne and N2). Downstream of the degassing structures, along the hydrological outflows, we found groundwaters that are progressively enriched in atmospheric-derived gases (Ne and N2) and exhibited lower 3He/4He ratios. On this basis, we set up a model of unidimensional dispersion-advection of inert volatile solutes, coupled with a two-layer model for the dynamic exchange of volatiles through the aquifer–atmosphere interface. The model is able to quantitatively explain the progressive dilution of the magmatic signal over distances of several kilometres from the source location of the anomaly towards the final part of the flow lines at the coast. Typical hydrogeological parameters such as the flow velocity, rock permeability and rate of air–groundwater interaction can be constrained, and underground pathways of waters can be identified. Waters that are anomalously rich in magmatic tracers with respect to their peripheral position along the flowlines reflect arrival of deep gases frombelow, and they therefore offer a powerful tool for revealing hidden tectonic structures.
    Description: Published
    Description: 10-21
    Description: 1V. Storia e struttura dei sistemi vulcanici
    Description: JCR Journal
    Description: restricted
    Keywords: Dissolved gas in water ; Noble gas geochemistry ; Groundwater flow ; Nitrogen geochemistry ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 6
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    Active upper crust deformation pattern along the southern edge of the Tyrrhenian subduction zone (NE Sicily): Insights from a multidisciplinary approach (2016)
    Elsevier Science Limited
    Details
    Publication Date: 2017-04-04
    Description: Using a multidisciplinary dataset based on gravimetric, seismic, geodetic and geological observations,we provide an improved picture of the shallow structure and dynamics of the southern edge of the Tyrrhenian subduction zone.With a local earthquake tomographywe clearly identify twomain crustal domains in the upper 15 kmcharacterized by different P-wave velocity values: a high-velocity domain comprising southeasternmost Tyrrhenian Sea, NE Sicily and Messina Straits, and a low-velocity domain comprising Mt. Etna and eastern Sicily. The transition between the two domains shows a good spatial correspondence with a wider set of faults including the Taormina Fault System (TFS) and the Aeolian–Tindari–Letojanni Fault System (ATLFS), two nearly SE-striking fault systems crossing northeastern Sicily and ending on the Ionian shoreline of Sicily according to many investigators. Within this set of faults, most of the deformation/seismicity occurs along the northern and central segments of ATLFS, compared to lowactivity along TFS. A lack of seismicity (both recent and historical) is observed in the southern sector of ATLFS where, however, geodetic data reveal significant deformation. Ourmultidisciplinary dataset including offshore observations suggests the southeastward continuation of the ATLFS into the Ionian Sea until joiningwith the faults cutting the Ionian accretionarywedge described in the recent literature. Our findings imply the existence of a highly segmented crustal shear zone extending from the Aeolian Islands to the Ionian Abyssal plain, that we believe plays the role of accommodating differential motion between the Southern Tyrrhenian unit and the western compressional domain of Sicily. The ATLFS, which is a main part of the inferred shear zone, behaves similarly to what often observed at the edges of retreating subduction
    Description: Published
    Description: 205-218
    Description: 1T. Geodinamica e interno della Terra
    Description: 2T. Tettonica attiva
    Description: 3T. Pericolosità sismica e contributo alla definizione del rischio
    Description: 1A. Geomagnetismo e Paleomagnetismo
    Description: 6A. Monitoraggio ambientale, sicurezza e territorio
    Description: JCR Journal
    Description: restricted
    Keywords: subduction edge ; seismic velocity structure ; 04. Solid Earth::04.01. Earth Interior::04.01.99. General or miscellaneous ; 04. Solid Earth::04.02. Exploration geophysics::04.02.99. General or miscellaneous ; 04. Solid Earth::04.02. Exploration geophysics::04.02.02. Gravity methods ; 04. Solid Earth::04.02. Exploration geophysics::04.02.04. Magnetic and electrical methods ; 04. Solid Earth::04.02. Exploration geophysics::04.02.06. Seismic methods ; 04. Solid Earth::04.03. Geodesy::04.03.99. General or miscellaneous ; 04. Solid Earth::04.03. Geodesy::04.03.01. Crustal deformations ; 04. Solid Earth::04.03. Geodesy::04.03.03. Gravity and isostasy ; 04. Solid Earth::04.03. Geodesy::04.03.04. Gravity anomalies ; 04. Solid Earth::04.03. Geodesy::04.03.05. Gravity variations ; 04. Solid Earth::04.03. Geodesy::04.03.06. Measurements and monitoring ; 04. Solid Earth::04.03. Geodesy::04.03.07. Satellite geodesy ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.06. Rheology, friction, and structure of fault zones ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.05. Geomagnetism::04.05.99. General or miscellaneous ; 04. Solid Earth::04.05. Geomagnetism::04.05.03. Global and regional models ; 04. Solid Earth::04.05. Geomagnetism::04.05.04. Magnetic anomalies ; 04. Solid Earth::04.06. Seismology::04.06.99. General or miscellaneous ; 04. Solid Earth::04.06. Seismology::04.06.01. Earthquake faults: properties and evolution ; 04. Solid Earth::04.06. Seismology::04.06.07. Tomography and anisotropy ; 04. Solid Earth::04.07. Tectonophysics::04.07.99. General or miscellaneous ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.04. Plate boundaries, motion, and tectonics ; 04. Solid Earth::04.07. Tectonophysics::04.07.05. Stress ; 04. Solid Earth::04.07. Tectonophysics::04.07.06. Subduction related processes ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 7
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    Geochemical characterisation of gases along the dead sea rift: Evidences of mantle-CO2 degassing (2016)
    Elsevier Science Limited
    Details
    Publication Date: 2017-04-04
    Description: The Dead Sea Transform (DST) fault system,where a lateral displacement between the African and Arabian plates occurs, is characterised by anomalous heat flux in the Israeli area close to the border with Syria and Jordan. The concentration of He and CO2, and isotopic composition of He and total dissolved inorganic carbon were studied in cold and thermalwaters collected along the DST, in order to investigate the source of volatiles and their relationship with the tectonic framework of the DST. The waters with higher temperature (up to 57.2 °C) are characterised by higher amounts of CO2 and helium (up to 55.72 and 1.91 ∗ 10−2 cc l−1, respectively). Helium isotopic data (R/Ra from 0.11 to 2.14) and 4He/20Ne ratios (0.41–106.86) show the presence of deep-deriving fluids consisting of a variable mixture ofmantle and crust end-members,with the former reaching up to 35%. Carbon isotope signature of total dissolved carbon from hot waters falls within the range of magmatic values, suggesting the delivery of deep-seated CO2. The geographical distribution of helium isotopic data and isotopic carbon (CO2) values coupled with (CO2/3He ratios) indicate a larger contribution of mantle-derived fluids affecting the northern part of the investigated area, where the waters reach the highest temperature. These evidences suggest the occurrence of a favourable tectonic framework, including a Moho discontinuity up-rise and/or the presence of a deep fault system coupled with the recent magmatic activity recognised in the northern part of Israel.
    Description: Published
    Description: 50–57
    Description: 4V. Vulcani e ambiente
    Description: JCR Journal
    Description: restricted
    Keywords: Dead Sea Fault ; Fluid geochemistry ; Dissolved gases ; Helium isotopes ; Carbon isotopes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 8
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    Temporal and spatial correlations between soil CO2 flux and crustal stress (2016)
    American Geophysical Union
    Details
    Publication Date: 2017-04-04
    Description: In seismically active areas, tectonic stress deforms and breaks the rocks of the crust. Ongoing deformation produces detectable modifications in the shallower portions of the crust, resulting in a wide variety of changes in several parameters. In this paper, we report the results of a large-scale spatial (across an area of 15,000 km2) and temporal (up to 3 years) investigation of the relationship between active crustal stress and soil CO2 flux. We deployed a network of 10 automatic stations in most of the seismically active districts of southern Italy to monitor the soil CO2 fluxes, and we used seismicity data to track crustal stress. The results of the investigation show that the CO2 flux signals varied independently in the districts with low and sporadic seismicity. Conversely, in the only district with nearly continuous seismic activity, almost all of the CO2 flux signals were well correlated with each other, and we recorded a clear synchronous sharp increase of the seismicity and signals recorded by several stations. The high spatial and temporal correlation between seismicity and gas discharge evidenced in this study prove that the crustal stress associated with the seismogenic process is able to effectively modulate the gas release in a seismically active area.
    Description: Published
    Description: 7071–7085
    Description: 2T. Tettonica attiva
    Description: JCR Journal
    Description: reserved
    Keywords: Soil CO2 flux ; Crustal stress ; seismotectonic process ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.07. Tectonophysics::04.07.99. General or miscellaneous
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  • 9
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    Geological and geodetic constraints on the active deformation along the northern margin of the Hyblean Plateau (SE Sicily) (2016)
    Elsevier Science Limited
    Details
    Publication Date: 2021-09-08
    Description: A geologic and geodetic integrated analysis of the northern margin of the Hyblean Plateau (SE Sicily) has been carried out in order to test the relationship between the active deformation, recorded by GPS data, and the long-term tectonic evolution, reconstructed by the interpretation of structural and morphological data. Our study revealed the active growth of a large antiform, as a consequence of the positive tectonic inversion of the previous flexure, bordering the Hyblean Foreland. The deformation of Middle–Late Pleistocene marine terraces and the evolution of the drainage system are consistent with a progressive regional tilting of the entire eastern sector of the Hyblean Plateau (Siracusa Domain), representing the southern limb of the active antiform. The geometry of the Late Quaternarymarine strandlines, comparedwith the results of analoguemodels, is compatible with the effects of the NW-ward propagation of a detachment fault at depth. The active deformation of the Hyblean region, coherentwith the Nubia–Eurasia plate convergence, suggests to candidate the inverted tectonics at the northern border of the Hyblean Plateau as potential seismogenic sources of the area.
    Description: Published
    Description: 80-89
    Description: 1T. Geodinamica e interno della Terra
    Description: JCR Journal
    Description: restricted
    Keywords: Ground deformation ; Geological data ; GPS data ; Hyblean Plateau ; SE Sicily ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics
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  • 10
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    Chemical and isotopic features of cold and thermal fluids discharged in the Southern Volcanic Zone between 32.5°S and 36°S: Insights into the physical and chemical processes controlling fluid geochemistry in geothermal systems of Central Chile (2016)
    Elsevier Science Limited
    Details
    Publication Date: 2024-05-09
    Description: The Principal Cordillera of Central Chile is characterized by two belts of different ages and lithologies: (i) an eastern Mesozoic belt, consisting of limestone- and gypsum-rich sedimentary rocks at the border between Central Chile and Argentina, where the active volcanic arc occurs; and (ii) a western belt of Cenozoic age containing basaltic to andesitic volcanic and volcanoclastic sequences. This distinctive geological setting controls water chemistry of cold and thermal springs in the region, which are fed by meteoric water that circulates through deep regional structures. In the western sector of Principal Cordillera, water–rock interaction processes produce lowTDS, slightly alkaline HCO3 − dominatedwaters, although dissolution of underlyingMesozoic evaporitic rocks occasionally causes SO4 2− and Cl− enrichments. In this area, few Na+–HCO3 − and Na+–SO4 2− waters occurred, being likely produced by a Ca2+–Na+ exchange during water–rock interactions. Differently, the chemical features of Ca2+–Cl−waterswas likely related to an albitization–chloritization process affecting basaltic to andesitic rocks outcropping in this area. Addition of Na+–Cl− brines uprising from the eastern sector through the westverging thrust faults cannot be excluded, as suggested by the occurrence of mantle He (~19%) in dissolved gases. In contrast, in the eastern sector of the study region, mainly characterized by the occurrence of evaporitic sequences and relatively high heat flow,mature Na+–Cl− waters were recognized, the latter being likely related to promising geothermal reservoirs, as supported by the chemical composition of the associated bubbling and fumarolic gases. Their relatively low3He/4He ratios (up to 3.9 Ra)measured in the fumaroles on this area evidenced a significant crustal contamination by radiogenic 4He. The latter was likely due to (i) degassing from 4He-rich magma batches residing in the crust, and/or (ii) addition of fluids interacting with sedimentary rocks. This interpretation is consistent with the measured δ13C-CO2 values (from−13.2 to−5.72‰vs. V-PDB) and the CO2/3He ratios (up to 14.6 × 1010), which suggest that CO2 mostly originates from the limestone-rich basement and recycling of subducted sediments,with an important addition of sedimentary (organic-derived) carbon,whereas mantle degassing contributes at a minor extent. According to geothermometric estimations based on the Na+, K+, Mg2+ and Ca2+ contents, the mature Na+–Cl− rich waters approached a chemical equilibrium with calcite, dolomite, anhydrite, fluorite, albite, K-feldspar and Ca- andMg-saponites at a broad range of temperatures (up to ~300 °C) In the associated gas phase, equilibria of chemical reactions characterized by slowkinetics (e.g. sabatier reaction) suggested significant contributions from hot and oxidizing magmatic gases. This hypothesis is consistent with the δ13C-CO2, Rc/Ra, CO2/3He values of the fumarolic gases. Accordingly, the isotopic signatures of the fumarolic steam is similar to that of fluids discharged from the summit craters of the two active volcanoes in the study area (Tupungatito and Planchón–Peteroa). These results encourage the development of further geochemical and geophysical surveys aimed to provide an exhaustive evaluation of the geothermal potential of these volcanic–hydrothermal systems.
    Description: Published
    Description: 97-113
    Description: 1V. Storia e struttura dei sistemi vulcanici
    Description: JCR Journal
    Description: restricted
    Keywords: Fluid geochemistry ; Central Chile ; Water–gas–rock interaction ; Hydrothermal reservoir ; Geothermal resource ; Volcanoes ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
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  • 11
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    Intense magmatic degassing through the lake of Copahue volcano, 2013-2014 (2016)
    American Geophysical Union
    Details
    Publication Date: 2024-05-09
    Description: Here we report on the first assessment of volatile fluxes from the hyperacid crater lake hosted within the summit crater of Copahue, a very active volcano on the Argentina-Chile border. Our observations were performed using a variety of in situ and remote sensing techniques during field campaigns in March 2013, when the crater hosted an active fumarole field, and in March 2014, when an acidic volcanic lake covered the fumarole field. In the latter campaign, we found that 566 to 1373 t d−1 of SO2 were being emitted from the lake in a plume that appeared largely invisible. This, combined with our derived bulk plume composition, was converted into flux of other volcanic species (H2O ~ 10989 t d−1, CO2 ~ 638 t d−1, HCl ~ 66 t d−1, H2 ~ 3.3 t d−1, and HBr ~ 0.05 t d−1). These levels of degassing, comparable to those seen at many open-vent degassing arc volcanoes, were surprisingly high for a volcano hosting a crater lake. Copahue's unusual degassing regime was also confirmed by the chemical composition of the plume that, although issuing from a hot (65°C) lake, preserves a close-to-magmatic signature. EQ3/6 models of gas-water-rock interaction in the lake were able to match observed compositions and demonstrated that magmatic gases emitted to the atmosphere were virtually unaffected by scrubbing of soluble (S and Cl) species. Finally, the derived large H2O flux (10,988 t d−1) suggested a mechanism in which magmatic gas stripping drove enhanced lake water evaporation, a process likely common to many degassing volcanic lakes worldwide.
    Description: Published
    Description: 6071–6084
    Description: 3V. Dinamiche e scenari eruttivi
    Description: JCR Journal
    Description: restricted
    Keywords: water/rock interaction ; volcanic lakes ; volcanic/hydrothermal gases ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration ; 04. Solid Earth::04.02. Exploration geophysics::04.02.07. Instruments and techniques ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 12
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    The origin of along-rift variations in faulting and magmatism in the Ethiopian Rift (2015)
    American Geophysical Union
    Details
    Publication Date: 2021-06-25
    Description: The geological record at rifts and margins worldwide often reveals considerable along-strike variations in volumes of extruded and intruded igneous rocks. These variations may be the result of asthenospheric heterogeneity, variations in rate, and timing of extension; alternatively, preexisting plate architecture and/or the evolving kinematics of extension during breakup may exert first-order control on magmatism. The Main Ethiopian Rift (MER) in East Africa provides an excellent opportunity to address this dichotomy: it exposes, along strike, several sectors of asynchronous rift development from continental rifting in the south to incipient oceanic spreading in the north. Here we perform studies of volcanic cone density and rift obliquity along strike in the MER. By synthesizing these new data in light of existing geophysical, geochemical, and petrological constraints on magma generation and emplacement, we are able to discriminate between tectonic and mantle geodynamic controls on the geological record of a newly forming magmatic rifted margin. The timing of rift sector development, the three-dimensional focusing of melt, and the ponding of plume material where the rift dramatically narrows each influence igneous intrusion and volcanism along the MER. However, rifting obliquity plays an important role in localizing intrusion into the crust beneath en echelon volcanic segments. Along-strike variations in volumes and types of igneous rocks found at rifted margins thus likely carry information about the development of strain during rifting, as well as the physical state of the convecting mantle at the time of breakup.
    Description: Published
    Description: 467-477
    Description: 1T. Geodinamica e interno della Terra
    Description: JCR Journal
    Description: restricted
    Keywords: Variationsinmeltproductioncausedby asynchronous rift sector development • Where the rift narrows, ponding of plume material may enhance melting • Three-dimensional migration of melt along the LAB focuses magma supply ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 13
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    Neotectonics and long-term seismicity in Europe and the Mediterranean region (2015)
    American Geophysical Union
    Details
    Publication Date: 2021-01-04
    Description: We present a neotectonic model of ongoing lithosphere deformation and a corresponding estimate of long-term shallow seismicity across the Africa-Eurasia plate boundary, including the eastern Atlantic, Mediterranean region, and continental Europe. GPS and stress data are absent or inadequate for the part of the study area covered by water. Thus, we opt for a dynamic model based on the stress-equilibrium equation; this approach allows us to estimate the long-term behavior of the lithosphere (given certain assumptions about its structure and physics) for both land and sea areas. We first update the existing plate model by adding five quasi-rigid plates (the Ionian Sea, Adria, Northern Greece, Central Greece, and Marmara) to constrain the deformation pattern of the study area. We use the most recent datasets to estimate the lithospheric structure. The models are evaluated in comparison with updated datasets of geodetic velocities and the most compressive horizontal principal stress azimuths. We find that the side and basal strengths drive the present-day motion of the Adria and Aegean Sea plates, whereas lithostatic pressure plays a key role in driving Anatolia. These findings provide new insights into the neotectonics of the greater Mediterranean region. Finally, the preferred model is used to estimate long-term shallow seismicity, which we retrospectively test against historical seismicity. As an alternative to reliance on incomplete geologic data or historical seismic catalogs, these neotectonic models help to forecast long-term seismicity, although requiring additional tuning before seismicity rates are used for seismic hazard purposes.
    Description: Published
    Description: 5311–5342
    Description: 1T. Geodinamica e interno della Terra
    Description: 2T. Tettonica attiva
    Description: 3T. Pericolosità sismica e contributo alla definizione del rischio
    Description: JCR Journal
    Description: open
    Keywords: Tectonics ; Earthquake rates ; 04. Solid Earth::04.02. Exploration geophysics::04.02.03. Heat flow ; 04. Solid Earth::04.03. Geodesy::04.03.01. Crustal deformations ; 04. Solid Earth::04.04. Geology::04.04.01. Earthquake geology and paleoseismology ; 04. Solid Earth::04.04. Geology::04.04.06. Rheology, friction, and structure of fault zones ; 04. Solid Earth::04.06. Seismology::04.06.01. Earthquake faults: properties and evolution ; 04. Solid Earth::04.06. Seismology::04.06.02. Earthquake interactions and probability ; 04. Solid Earth::04.07. Tectonophysics::04.07.01. Continents ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.04. Plate boundaries, motion, and tectonics ; 04. Solid Earth::04.07. Tectonophysics::04.07.05. Stress ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics
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  • 14
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    Gas blowout from shallow boreholes near Fiumicino International Airport (Rome): Gas origin and hazard assessment (2015)
    Elsevier Science Limited
    Details
    Publication Date: 2021-03-05
    Description: In summer 2013 a toxic and polluting gas blowout (19 tonnes day−1 CO2, 95 kg day−1 CH4) occurred from two shallow boreholes drilled at only 50 m from the International Airport of Rome (Italy), in the town of Fiumicino. Another gas blowout occurred in the same period from a borehole located offshore, 2 km away, also generating sea-water acidification; it lasted only a couple of days. Onshore, CO2was also diffusing fromholes within the soil, particularly toward the airport, generating a soil flux up to 1.8 tonnes day−1. In 3.5 months ~1500 tonnes of CO2 and 5.4 tonnes of CH4 were emitted in the atmosphere. Temporal monitoring of gas geochemistry indicates that in this area a mixing occurs between shallow and pressurized gas pockets, CO2-dominated, but with different chemical (i.e., He/CH4 ratio) and isotopic (3He/4He, δ13C-δDCH4) characteristics. Numerical simulation of CO2 dispersion in the atmosphere showed that dangerous air CO2 concentrations, up to lethal values, were only found near the vents at a height of 0.2 m. Fiumicino is a high blowout risk area, as CO2 rising through deep reaching faults pressurizes the shallowaquifer contained in gravels confined underneath shales of the Tiber delta deposits. The Fiumicino blowout is a typical example of dangerous phenomenon that may occur in urban context lying nearby active or recent volcanoes and requires quick response on hazard assessment by scientists to be addressed to civil protection and administrators.
    Description: Published
    Description: 54-65
    Description: 4V. Vulcani e ambiente
    Description: JCR Journal
    Description: restricted
    Keywords: Endogenous gas blowout from shallow wells ; Chemical and isotopic composition of gas and water ; Viscous flux and diffuse soil gas flux measurements ; Simulation andmonitoring of air CO2 dispersion ; Hazard assessment ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 05. General::05.08. Risk::05.08.01. Environmental risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 15
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    Subsurface hydrothermal processes and the bioenergetics of chemolithoautotrophy at the shallow-sea vents off Panarea Island (Italy) (2015)
    Elsevier Science Limited
    Details
    Publication Date: 2021-05-12
    Description: The subsurface evolution of shallow-sea hydrothermal fluids is a function ofmany factors including fluid–mineral equilibria, phase separation, magmatic inputs, and mineral precipitation, all of which influence discharging fluid chemistry and consequently associated seafloor microbial communities. Shallow-sea vent systems, however, are understudied in this regard. In order to investigate subsurface processes in a shallow-sea hydrothermal vent, and determine how these physical and chemical parameters influence the metabolic potential of the microbial communities, three shallow-sea hydrothermal vents associated with Panarea Island (Italy) were characterized. Vent fluids, pore fluids and gases at the three sites were sampled and analyzed for major and minor elements, redoxsensitive compounds, free gas compositions, and strontiumisotopes. The corresponding data were used to 1) describe the subsurface geochemical evolution of the fluids and 2) to evaluate the catabolic potential of 61 inorganic redox reactions for in situ microbial communities. Generally, the vent fluids can be hot (up to 135 °C), acidic (pH 1.9–5.7), and sulfidic (up to 2.5 mM H2S). Three distinct types of hydrothermal fluids were identified, each with higher temperatures and lower pH,Mg and SO4, relative to seawater. Type 1 was consistently more saline than Type 2, and both were more saline than seawater. Type 3 fluids were similar to or slightly depleted in mostmajor ions relative to seawater. End-member calculations of conservative elements indicate that Type 1 and Type 2 fluids are derived from two different sources, most likely 1) a deeper, higher salinity reservoir and 2) a shallower, lower salinity reservoir, respectively, in a layered hydrothermal system. The deeper reservoir records some of the highest end-member Cl concentrations to date, and developed as a result of recirculation of brine fluids with long term loss of steam and volatiles due to past phase separation. No strong evidence for ongoing phase separation is observed. Type 3 fluids are suggested to be mostly influenced by degassing of volatiles and subsequently dissolution of CO2, H2S, and other gases into the aqueous phase. Gibbs energies (ΔGr) of redox reactions that couple potential terminal electron acceptors (O2, NO3 −, MnIV, FeIII, SO4 2−, S0, CO2) with potential electron donors (H2, NH4 +, Fe2+, Mn2+, H2S, CH4) were evaluated at in situ temperatures and compositions for each site and by fluid type.When Gibbs energies of reaction are normalized per kilogram of hydrothermal fluid, sulfur oxidation reactions are the most exergonic, while the oxidation of Fe2+, NH4 +, CH4, and Mn2+ is moderately energy yielding. The energetic calculations indicate that the most robust microbial communities in the Panarea hot springs combineH2S fromdeepwater–rock–gas interactions with O2 that is entrained via seawater mixing to fuel their activities, regardless of site location or fluid type.
    Description: Published
    Description: 21-45
    Description: 4A. Clima e Oceani
    Description: JCR Journal
    Description: restricted
    Keywords: submarine hydrothermal systems ; subsurface processes ; thermodynamics ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 16
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    Spatial relationship between earthquakes and volcanic vents in the central-northern Main Ethiopian Rift (2015)
    Elsevier Science Limited
    Details
    Publication Date: 2021-06-25
    Description: During the breakup of continents extension is commonly accommodated by connected networks of fluid filled fractures (dykes) and by faults. Despite the importance of these two extension mechanisms their spatial relationship in three dimensions is poorly understood primarily because it is difficult to quantify the subsur- face distribution of faulting and intrusion. In order to address this problem, we conduct a quantitative anal- ysis of the spatial distribution and clustering of earthquakes and volcanic vents in the Main Ethiopian Rift in East Africa in order to understand how extension by faulting and intrusion is distributed throughout the vol- canic rift. We use fractal analysis of earthquake epicentres in order to infer the 2D characteristics of the sub- surface fault network, and directly test our model results against the 3D distribution of earthquake hypocentres. Our results show that fractal analysis of these features is a reliable means to characterise the 3D properties of the fault network. In addition, the strong similarity between the properties of the fault net- work derived from earthquakes and properties of the magma-filled fracture network derived from fractal analysis of volcanic vents strongly suggests that these are genetically linked. We then explore their spatial link using computation of earthquake and vent density, which shows that the zone of seismicity is generally around 20–30-km-wide, while the zone of vents is narrower and centred within the zone of seismicity. This spatial relationship suggests that the faults, which form rift axial grabens, are induced above a narrower and central zone of diking. We also demonstrate significant along-rift variation in degree of magmatism and faulting with regions of increased degree of diking inferred from a higher cone density characterised by reduced degree of faulting.
    Description: Published
    Description: 123-133
    Description: 1T. Geodinamica e interno della Terra
    Description: JCR Journal
    Description: restricted
    Keywords: Volcanic vent Earthquake Spatial distribution Self-similar clustering Ethiopian Rift ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 17
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    Mercury Degassing on Africa-Adriatic Tectonic Plate Margin (2015)
    American Geophysical Union
    Details
    Publication Date: 2021-06-25
    Description: Beside anthropogenic influences, mercury in the environment can also be of natural origin. Among geologic sources, volcanic activity has been of main interest so far. Modern estimations of global natural emissions are between 2000 and 5200 tonnes per year. However, these estimates are very uncertain, thus more detailed and systematic research on natural sources of mercury is necessary. Tectonic activity is connected to certain phenomena such as degassing of Hg and other gases from active faults, geothermal activity, volcanoes, etc., especially on tectonic plate margins. Elemental mercury concentrations in air, soil gases and fluxes, as well as its speciation, in connection to tectonic activity, were studied in different environments such are karst cave (Postojna Cave), active volcano areas (Mt. Etna, Italy), and active tectonic areas in the Mediterranean Basin on Africa-Adriatic tectonic plate margin. Postojna Cave is characterized by elevated Hg (up to 150 ng m-3) air concentrations at certain areas in vicinity of active faults; however the concentrations showed also strong seasonal variations. Mt. Etna on Sicily is the largest and most active Mediterranean volcano. Concentrations of mercury in air in the vicinity of the volcano are relatively high (between 4 and 30 ng m-3) and rise towards the summit crater (65 to 130 ng m-3). Concentrations in sulphatare and fumaroles gases on the summit of the volcano can reach very high values (even up to 60 μg m-3). The Mediterranean Basin is characterized by strong tectonic activity as a consequence of subduction of African plate under the Eurasian plate. A possible source of DGM (dissolved gaseous mercury in sea water) in deeper and bottom waters could be intensive tectonic activity of the seafloor, since higher concentrations and portions of DGM were found near the bottom at locations with strong tectonic activity (Alboran Sea, Strait of Sicily, Tyrrhenian Sea, Ionian Sea). Distribution of different mercury species in sediment and water of the Mediterranean Sea showed that the main source of mercury is geotectonic activity and its accompanying phenomena.
    Description: Published
    Description: San Francisco
    Description: 6A. Monitoraggio ambientale, sicurezza e territorio
    Description: restricted
    Keywords: Mercury ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Conference paper
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  • 18
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    The protracted development of focused magmatic intrusion during continental rifting (2015)
    American Geophysical Union
    Details
    Publication Date: 2021-06-25
    Description: The transition from mechanical thinning toward focused magmatic intrusion during continental rifting is poorly constrained; the tectonically active Main Ethiopian Rift (MER) provides an ideal study locale to address this issue. The presence of linear magmatic-tectonic belts in the relatively immature central MER may indicate that the transition from mechanical to magmatic rifting is more spatially distributed and temporally protracted than has previously been assumed. Here we examine lava geochemistry and vent distribution of a Pliocene-Quaternary linear magmatic chain along the western margin of the central MER—the Akaki Magmatic Zone. Our results show limited variability in parental magma that evolve in a complex polybaric fractionation system that has not changed significantly over the past 3 Ma. Our results suggest the following: (1) channeling of plume material and the localization of shear- or topography-induced porosity modulates melt intrusion into the continental lithosphere. (2) Pre-existing lithospheric structures may act as catalysts for intrusion of magmas into the lithospheric mantle. (3) The midcrustal to upper crustal strain regime dictates the surface orientation of volcanic vents. Therefore, although linear magmatic belts like those in the central MER may young progressively toward the rift axis and superficially resemble oceanic style magmatism, they actually represent prebreakup magmatism on continental crust. The oldest linear magmatic belts observed seismically and magnetically at the edge of the ocean basins thus may not, as is often assumed, actually mark the onset of seafloor spreading.
    Description: Published
    Description: 875–897
    Description: 1T. Geodinamica e interno della Terra
    Description: JCR Journal
    Description: restricted
    Keywords: Precambrian lineaments control off-axis melt • Magmatic extension in Ethiopian rift is not ocean like • Magmatic belts at basins margins may not be seafloor spreading ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 19
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    The intimate relationship between strain and magmatism: A numerical treatment of clustered monogenetic fields in the Main Ethiopian Rift (2015)
    American Geophysical Union
    Details
    Publication Date: 2017-04-04
    Description: The spatial distribution of monogenetic vents and the geochemistry of their erupted products can be used to probe heterogeneity in lithospheric strain across a rift. We show that Quaternary volcanic belts in the central Main Ethiopian Rift (MER) exhibit differences in vent fractal clustering with an exponent indicative of more clustering and a shallower magma reservoir for the Wonji Fault Belt (WFB), in comparison to the Silti-Debre Zeyit Fault Zone (SDFZ). The range of lengths that exhibit vent fractal clustering is bounded by (1) a lower cutoff of few hundreds of meters that correlates with the depth of emplacement of intrusive material and is likely linked to evolving silicic magma systems and (2) an upper cutoff which we interpret to scale with the depth from which dikes originate just prior to eruption: ~10 km for WFB and ~7 km for SDFZ. We attribute this difference to strain partitioning within the MER, which favors dike formation at greater depths beneath the more highly strained eastern margin of the MER (below the WFB), in comparison to the western rift margin (below the SDFZ). Statistical analysis of monogenetic fields in the MER show, when reviewed in light of a priori geophysical and geodetic data, that the plumbing system of monogenetic volcanism style is strongly controlled by crustal strain state. Such statistical techniques may have application in probing the magma systems of other environments where less geophysical or geochemical controls exist.
    Description: Published
    Description: 49-64
    Description: 1T. Geodinamica e interno della Terra
    Description: JCR Journal
    Description: restricted
    Keywords: Ethiopian RIft, Volcanism, crustal strain state ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 20
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    The carbon-isotope signature of ultramafic xenoliths from the Hyblean Plateau (southeast Sicily, Italy): Evidence of mantle heterogeneity (2015)
    American Geophysical Union
    Details
    Publication Date: 2017-04-04
    Description: We investigated the carbon isotope composition of mantle source beneath the Hyblean Plateau (southeast Sicily, Italy) by studying CO2 in fluid inclusions from ultramafic xenoliths recovered in some Miocene diatremes. In order to constrain the processes influencing the isotopic marker of carbon we combined d13CCO2 results with information about noble gases (He and Ar) obtained in a previous investigation of the same products. Although Ar/CO2 and He/Ar ratios provide evidence of Rayleigh-type fractional degassing, the isotopic geochemistry of carbon is poorly influenced by this process. Mixing related to metasomatic processes where MORB-type pyroxenitic melts permeate a peridotite mantle probably contaminated by crustal fluids inherited from a fossil subduction can explain the measured d13C and CO2/3He variations, ranging from 24&to 22& and from 109 to 1010, respectively. Simple mass-balance calculations highlighted that the Hyblean peridotite source was mainly contaminated by the carbonate source, being carbonate and organic matter present at a ratio that varied within the range from 7:1 to 4:1.
    Description: Published
    Description: 600-611
    Description: 2V. Dinamiche di unrest e scenari pre-eruttivi
    Description: JCR Journal
    Description: restricted
    Keywords: xenoliths ; mantle heterogeneity ; Hyblean Plateau ; fluid inclusions ; isotopic carbon ; 04. Solid Earth::04.01. Earth Interior::04.01.03. Mantle and Core dynamics ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 21
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    Radiogenic helium degassing and rock fracturing: a case study of the southern Apennines active tectonic region (2015)
    American Geophysical Union
    Details
    Publication Date: 2017-04-04
    Description: Gas from mud volcanoes, dry mofettes, springs, and wells were sampled in a region of active tectonics and high seismicity in the southern Apennines (Italy), where there is a long history of disastrous earthquakes, with the latest (Ms = 6.9) occurring in 1980. The fluids consist of a mixture of mantle-derived and crust-derived volatiles, with a low atmosphere-derived contribution, as identified by the He isotope signature and He/Ne ratio measurements. One year of monthly monitoring of the He concentrations and He isotopes revealed no seasonal modifications or variations induced by low seismicity. There are extraordinary high outputs of 4He produced in the crust in the area (up to 2.5 × 1028 atoms yr 1). These outputs cannot be solely due to the whole-rock production rate and a long-lasting diffusion degassing through the crust of the produced 4He. This study explored the relation between the volume of fractured rock and the related release of He. The results support that crustal degassing can be controlled by tectonic events resulting in earthquakes. The high seismicity in this sector of the Apennines provides the conditions necessary for a massive release of He that has accumulated in the rock over a long time period. We identified that the assessed high crustal 4He output can be attributed to an intense fracturing of a calculable volume of rock, which gives new constraints on the volume of rock involved in high-magnitude earthquakes in the region.
    Description: Published
    Description: 2200-2211
    Description: 2T. Tettonica attiva
    Description: JCR Journal
    Description: reserved
    Keywords: xtraordinary high radiogenic helium flux in continental region ; Release of crustal 4He due to rock fracturing ; Relationship between rock involved in earthquake and radiogenic He flux ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 22
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    Boron, lithium and methane isotope composition of hyperalkaline waters (Northern Apennines, Italy): terrestrial serpentinization or mixing with brine? (2015)
    Elsevier Science Limited
    Details
    Publication Date: 2020-02-24
    Description: Spring waters issuing from serpentinized ultramafic rocks of the Taro-Ceno Valleys (Northern Apennine, Emilia-Romagna region, Italy) were analyzed for major element, trace element and dissolved gas concentrations and d11B, d7Li, d18O(H2O), d2H(H2O), d13C(CH4) and d2H(CH4) isotope compositions. Similar to other springs worldwide that issue from serpentinites, the chemical composition of the waters evolves with water–rock interaction from Ca-HCO3, through Mg-HCO3 and ultimately to a hyperalkaline Na- (Ca)-OH composition. Most of the Ca- and Mg-HCO3 springs have d11B ranging between +16.3‰ and +23.7‰, consistent with the range of low P–T serpentinites. Very high d11B in two springs from Mt. Prinzera (PR10: +39‰; PR01: +43‰) can be related to isotopic fractionation during secondary phase precipitation, as also inferred from d7Li values. In contrast to typical abiogenic isotope signatures of CH4 from serpentinized rocks, dissolved CH4 from the Taro-Ceno hyperalkaline springs has an apparent biotic (thermogenic and/or mixed thermogenic-microbial) signature with d13C(CH4) ranging from 57.5‰ to 40.8‰, which is similar to that of hydrocarbons from production wells and natural seeps in adjacent hydrocarbon systems. The data suggest that CH4 in the hyperalkaline springs investigated in this study may derive from organic matter of the sedimentary (flysch and arenaceous) formations underlying the ophiolite unit. However, small amounts of H2 were detected in one hyperalkaline spring (PR10), but for two springs with very low CH4 concentrations (PR01 and UM15) the d2H value could not be measured, so the occurrence of some abiotic CH4 cannot be excluded. The occurrence of thermogenic CH4 in ophiolites may be a widespread phenomenon, and thus the characterization of serpentinization-related gases requires accurate evaluation of the regional context including a careful knowledge of the relationships with surrounding sedimentary rocks and their hydrocarbon potential.
    Description: Published
    Description: 17-25
    Description: 7A. Geofisica di esplorazione
    Description: JCR Journal
    Description: restricted
    Keywords: Serpentinization, methane ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 23
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    Mantle CO2 degassing at Mt. Vulture volcano (Italy): Relationship between CO2 outgassing of volcanoes and the time of their last eruption (2015)
    Elsevier Science Limited
    Details
    Publication Date: 2017-04-04
    Description: Mantle volatiles are mainly lost from the Earth to the atmosphere through subaerial and submarine volcanism. Recent studies have shown that degassing of mantle volatiles also occurs from inactive volcanic areas and in tectonically active areas. A new challenge in Earth science is to quantify the mantle-derived flux of volatiles (e.g., CO2) which is important for understanding such diverse issues as the evolution of the atmosphere, the relationships between magma degassing and volcanic activity, gas pressure and seismogenic processes, and the hazards posed by volcanic lakes. Here we present a detailed study of mantle-derived CO2 budget from Mt. Vulture volcano in the Apennines, Italy, whose latest eruption occurred 141 ± 11 kyr ago. The relationship between δ13CCO2 and total dissolved carbon at Mt. Vulture volcano indicates that the emitted CO2 is a mixture of a biogenic end-member with an average δ13CCO2 of about −17h and a mantle-derived CO2 end-member with δ13CCO2 values from −3h to +2h. These values of mantle- derived δ13CCO2 are in the range of those for gas emitted from active volcanoes in the Mediterranean. We calculated the contribution of individual components (CO2 in groundwater, in lakes and from main pools) to the total CO2 budget in the area. We used new measurements of water flow, combined with literature data, to calculate the CO2 flux associated with groundwater, and measured the gas flux from the main pools on the volcanic edifice. Finally, we calculated the CO2 flow in the lakes based on the gradient concentration and eddy diffusivity. The total mantle-derived CO2 budget in the area is 4.85×108 molyr−1, which is more than double previous estimates. This is higher than those observed in younger volcanic systems elsewhere, thereby supporting the existence of actively degassing mantle melts below Mt. Vulture volcano. A structural map highlights the tectonic control on CO2 flow across the Mt. Vulture volcanic edifice. Indeed, the tectonic discontinuities that controlled the magma upwelling during the most recent volcanic activity are still the main active degassing structures. The new estimate of CO2 budget in the Mt. Vulture area, together with literature data on CO2 budget from historically active and inactive Italian volcanoes, suggests a power-law functional relationship between the age of the most recent volcanic eruption and both total discharged CO2 (R2 = 0.73) and volcano size-normalized CO2 flux (R2 =0.66). This relation is also valid by using data from worldwide volcanoes highlighting that deep degassing can occur over very long time too. In turn, the highlighted relation provides also an important tool to better evaluate the state of activity of a volcano, whose last activity occurred far in time. Finally, our study highlights that in the southern Apennines, an active degassing of mantle-derived volatiles (i.e., He, CO2) occurs indiscriminately from west to east. This is in contrast to the central– northern Apennine, which is characterized by a crustal radiogenic volatile contribution, which increases eastward, coupled to a decrease in deep CO2 flux. This difference between the two regions is probably due to lithospheric tears which control the upwelling of mantle melts, their degassing and the transport of volatiles through the crust.
    Description: Published
    Description: 268-280
    Description: 4V. Vulcani e ambiente
    Description: JCR Journal
    Description: reserved
    Keywords: deep CO2 budget ; groundwater ; carbon isotopes ; CO2 degassing ; lithospheric fault systems ; Mt. Vulture volcano ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 24
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    New insights into crustal structure, Cenozoic magmatism, CO2 degassing and seismogenesis in the southern Apennines and Irpinia region from local earthquake tomography (2015)
    American Geophysical Union
    Details
    Publication Date: 2017-04-04
    Description: We present high-resolution Vp and Vp/Vs models of the southern Apennines (Italy) computed using local earthquakes recorded from 2006 to 2011 with a graded inversion scheme that progressively resolves the crustal structure, from the large scale of the Apennines belt to the local scale of the normal-fault system. High-Vp bodies defined in the upper and mid crust under the external Apennines are interpreted as extensive mafic intrusions revealing anorogenic magmatism episodes that broadened on the Adriatic domain during Paleogene. Under the mountain belt, a low-Vp region, annular to the Neapolitan volcanic district, indicates the existence of a thermal/fluid anomaly in the mid crust, coinciding with a shallow Moho and diffuse degassing of deeply derived CO2. In the belt axial zone, low Vp/Vs gas-pressurized rock volumes under the Apulian carbonates correlate to high heat flow, strong CO2-dominated gas emissions of mantle origin and shallow carbonate reservoirs with pressurized CO2 gas caps. We hypothesize that the pressurized fluid volumes located at the base of the active fault system influence the rupture process of large normal-faulting earthquakes, like the 1980 Mw6.9 Irpinia event, and that major asperities are confined within the high-Vp Apulian carbonates. This study confirms once more that pre-existing structures of the Pliocene Apulian belt controlled the rupture propagation during the Irpinia earthquake. The main shock broke a 30 km long, NE-dipping seismogenic structure, whereas delayed ruptures (both the 20 s and the 40 s sub-events) developed on antithetic faults, reactivating thrust faults located at the eastern edge of the Apulian belt.
    Description: Published
    Description: 8283–8311
    Description: 1T. Geodinamica e interno della Terra
    Description: 2T. Tettonica attiva
    Description: 4T. Fisica dei terremoti e scenari cosismici
    Description: JCR Journal
    Description: embargoed_20150609
    Keywords: The velocity structure of the southern Apennines is determined by a multi-scale tomography ; Large Cenozoic mafic intrusions are identified in the Apulian crust ; Pressurized CO2 reservoirs identified under the axial belt can affect crustal seismicity ; 04. Solid Earth::04.02. Exploration geophysics::04.02.99. General or miscellaneous ; 04. Solid Earth::04.06. Seismology::04.06.01. Earthquake faults: properties and evolution ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics ; 04. Solid Earth::04.06. Seismology::04.06.07. Tomography and anisotropy ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.02. Data dissemination::05.02.02. Seismological data
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  • 25
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    Distribution, composition and origin of coalbed gases in excavation fields from the Preloge and Pesje mining areas, Velenje Basin, Slovenia (2015)
    Elsevier Science Limited
    Details
    Publication Date: 2017-04-04
    Description: Coal gas outbursts (especially CO2) present a high risk in mining of lignite in the Velenje Coal Mine, located in the Velenje Basin in northern Slovenia. A programme of monitoring geochemical parameters was set up to help understand the behaviour of the coalbed gas distribution in advance of the working face using mass spectrometric methods to study its molecular and isotopic compositions and origin. Coalbed gas samples from four different excavation fields (G2/C and K.-130/A from the north and south Preloge mining area and K.-5/A and K.-50/C from the Pesje mining area), which were operational between the years 2010 and 2011 were investigated. The major gas components are CO2 and methane. Temporal changes in the chemical and isotopic composition of free seamgaseswere observedwithin boreholes as a function of the advancement of theworking face. The study also revealed that at a distance of around 120 m from the working face, the influence of coal exploitation by the Velenje Longwall Mining Method causes coalbed gas to migrate. At a distance of 70 m the lignite structure is crushed causing desorption of fixed CO2 from the coal. Differences in coalbed gas composition at the longwall panels which underlie the unmined area or under previously mined areas were found. A high CDMI {=[CO2/(CO2+CH4)]100 (%)} indexwith values up to 95.6% was typical for areas of pre-mined excavation fields (South Preloge K.-130/A and Pesje area K.-5/A), while in excavation fieldswith no previous mining activity (North Preloge G2/C and Pesje area K.-50/C) up to 61.9 vol % of CH4 was detected. The concentration measurements and isotopic studies revealed endogenic CO2 (including CO2 originating from dissolution of carbonates) with δ13CCO2 values ranging from −7.0‰ to 5.5‰, microbial methane and CO2 with values ranging from −70.4 to −50‰ and from −11.0 to −7.0‰, respectively. Higher δ13CCH4 values ranging from −50 to −19.8‰ could be attributed to so-called secondary processes influencing the δ13CCH4 value, such as migration due to lignite excavation (escape of isotopically lighter methane). In excavation fields (G2/C and K.-50/C) with no-premining activity higher δ13CCH4 values could also be explained by migration of methane fromdeeper strata. The δ13CCH4 value also depended on the depth of the excavation field; at shallower levels of the excavation field (K.-5/A) a lower δ13CCH4 value was traced indicating microbial gas, while at deeper levels higher δ13CCH4 values were found.
    Description: Slovenian Research Agency (L2-4066 and L1-5451)
    Description: Published
    Description: 363-377
    Description: 5A. Energia e georisorse
    Description: JCR Journal
    Description: restricted
    Keywords: Excavation fields Advancement of the working face Coalbed gas composition Stable isotopes Coalbed gas origin Velenje Basin ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 26
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    Hydrogen isotope fractionation in land-based serpentinization systems. Comment on “Origin of methane in serpentinite-hosted hydrothermal systems: The CH4–H2–H2O hydrogen isotope systematics of the Hakuba Happo hot spring” by Suda et al. [Earth Planet. Sci. Lett. 386 (2014) 112–125] (2015)
    Elsevier Science Limited
    Details
    Publication Date: 2020-02-24
    Description: no abstract available
    Description: Published
    Description: 373-375
    Description: 7A. Geofisica di esplorazione
    Description: JCR Journal
    Description: restricted
    Keywords: Abiotic methane, serpentinization ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 27
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    New geochemical investigations in Platanares and Azacualpa geothermal sites (Honduras) (2015)
    Elsevier Science Limited
    Details
    Publication Date: 2017-04-04
    Description: Platanares and Azacualpa geothermal sites of Honduras are located in an inner part of the Caribbean Plate far from the active volcanic front of Central America. Here geology indicates that there are not the conditions for the occurrence of shallow magmatic heat sources for high-enthalpy geothermal resources. Geothermal perspectives are related to the possibility of a deep circulation of meteoric water along faults and the storage of the heated fluid in fractured permeable reservoirs. Geochemical geothermometers indicate a temperature for the deeper part of the geothermal reservoir close to 200 °C for Platanares and of 150–170 °C for Azacualpa. Calcite scaling, with subordinate silica deposition has to be expected in both sites. CO2 soil flux investigations have been carried out in both areas and reveal the presence of positive anomalies likely corresponding to the presence at depth of fractured degassing geothermal reservoirs. Compared with the geothermal areas of Central Italy whose reservoirs are hosted in carbonate rocks, e.g. Latera (Chiodini et al., 2007), the CO2 soil flux measured in Honduras is significantly lower (mean of 17 g/m2day at Platanares and of 163 g/m2day at Azacualpa) probably because of the dominant silicate nature of the deep reservoirs.
    Description: Published
    Description: 113-134
    Description: 4V. Vulcani e ambiente
    Description: JCR Journal
    Description: reserved
    Keywords: Geothermal perspectives of Honduras, Water and gas geochemistry, Geothermometric estimations, CO2 soil flux investigation for the assessment of permeability at depth ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 28
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    Geostatistical techniques application to dissolved radon hazard mapping: an example from the western sector of the Sabatini Volcanic District and the Tolfa Mountains (central Italy) (2015)
    Elsevier Science Limited
    Details
    Publication Date: 2023-03-13
    Description: Dissolved Rn was determined in 192 samples collected from cold shallow volcanic and sedimentary aquifers, deep thermal aquifers and from waters associated with bubbling gases in the western sector of the Sabatini Volcanic District and the Tolfa Mountains (central Italy). Shallow aquifers hosted in the Quaternary volcanic complexes show values ranging from 1.0 to 352 Bq/L (median value 55 and inter-quartile distance 62 Bq/L), while waters circulating within the permeable horizons of the sandy-to-clayey sediments of the Tolfa flysch have values from 1.0 to 44 Bq/L (median value 6.9 and inter-quartile distance 8.1 Bq/L). Thermal waters are hosted in the Mesozoic carbonate formations and move towards the surface along faults. Here, dissolved Rn values range from 0 to 37 Bq/L (median value 3.0 and inter-quartile distance 9.5 Bq/L). Waters associated with bubbling gases show dissolved Rn contents ranging from 2.0 to 48 Bq/L (median value 6.2 and inter-quartile distance 23 Bq/L). Those results suggest that lithology is the main factor affecting the Rn contents in shallow aquifers, due to the high levels of Rn progenitors U and Ra in the volcanic rocks relative to sedimentary units. The influence of other factors such as the presence of a fracture network, seasonal flow variations, type of discharge (from well or spring) was also investigated. Radon contents of thermal waters result from mixing with shallow waters (from both volcanic and sedimentary rock aquifers) and decrease of Rn solubility with temperature, while for bubbling pools the effects of strong degassing were also considered. In terms of health hazard from direct ingestion of Rn-rich waters, 20.8% of those circulating within the volcanic aquifer show values higher than the recommended value of 100 Bq/L, while none of those circulating within the sedimentary aquifers exceed the threshold value. Geostatistical techniques were used for the elaboration of contour maps by using variogram models and kriging estimation aimed at defining the areas where a potential health hazard due to the direct ingestion of Rn-rich waters and to inhalation of air following degassing of Rn from waters may be expected.
    Description: Published
    Description: 312-324
    Description: 5A. Energia e georisorse
    Description: JCR Journal
    Description: restricted
    Keywords: radon ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 29
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    Isotopic patterns of hydrothermal hydrocarbons emitted from Mediterranean volcanoes (2015)
    Elsevier Science Limited
    Details
    Publication Date: 2024-05-09
    Description: We have analyzed the carbon isotopic composition of CO2, methane, ethane, propane and n-butane, the hydrogen isotopic composition of methane as well as total concentrations of gas constituents contained in theMediterranean volcanic–hydrothermal discharges of Nisyros (Greece), Vesuvio, La Solfatara, Ischia and Pantelleria (all Italy) to determine the origin of the hydrocarbons. Isotopic criteria conventionally used for hydrocarbon classification suggest thermogenic origins, except for Pantelleria, for which an abiogenic origin is indicated. These findings would imply that thermogenic sources can provide methane/(ethane + propane) concentration ratios as high as those usually observed for microbial hydrocarbons. However, additional consideration of gas concentration data challenges the suitability of conventional criteria for the classification of hydrocarbons emanating from hydrothermal environments. Methane seems to be in close equilibrium with co-occurring CO2, whereas its higher chain homologues are not. Therefore, it cannot be excluded that methane on the one hand and ethane, propane and n-butane on the other hand have distinct origins. The carbon isotopic composition of methane might be controlled by the carbon isotopic composition of co-occurring inorganic CO2 and by hydrothermal temperatures whereas the carbon isotopic composition of the higher n-alkanes could correspond to the maturity of organic matter and/or to the residence time of the gasses in the source system
    Description: Published
    Description: 152–163
    Description: 2V. Dinamiche di unrest e scenari pre-eruttivi
    Description: JCR Journal
    Description: restricted
    Keywords: Hydrocarbons ; Abiogenic ; Thermogenic ; Stable isotopes ; Fumaroles ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
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  • 30
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    Mapping Moho depth variations in central Italy from PsMoho-P delay times: Evidence of an E-W transition in the Adriatic Moho at 42°N latitude (2014)
    American Geophysical Union
    Details
    Publication Date: 2020-12-18
    Description: Along the Italian peninsula adjoin two crustal domains, peri-Tyrrhenian and Adriatic, whose boundary is not univocal in central Italy. In this area, we attempt to map the extent of the Moho in the two terrains from variations of the travel time difference between the direct P wave and the P-to-S wave converted at the crust-mantle boundary, called PsMoho. We use teleseismic receiver functions computed at 38 broad-band stations in this and previous studies, and assigned each of the recording sites to the Adriatic or peri-Tyrrhenian terrains based on station location, geologic and geophysical data and interpretation, and consistency of delays with the regional Moho trend. The results of the present study show that the PsMoho arrival time varies from 2.3 to 4.1 s in the peri-Tyrrhenian domain and from 3.7 to 5.5 s in the Adriatic domain. As expected, the lowest time difference is observed along the Tyrrhenian coastline and the largest values are observed in the axial zone of the Apennine chain. A key new result of this study is a sharp E-W boundary in the Adriatic domain that separates a deeper Moho north of about 42 N latitude from a shallower Moho to the south. This feature is constrained for a length of about 40 km by the observations available in this study. The E-W boundary requires a revision of prior mapping of the Moho in central Italy and supports previous hypotheses of lithosphere segmentation.
    Description: Published
    Description: 3929–3938
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: JCR Journal
    Description: open
    Keywords: teleseismic receiver functions ; Moho discontinuity ; central Italy ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics
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    Sudden deep gas eruption nearby Rome's airport of Fiumicino (2014)
    American Geophysical Union
    Details
    Publication Date: 2021-03-24
    Description: On 24 August 2013 a sudden gas eruption from the ground occurred in the Tiber river delta, nearby Rome's international airport of Fiumicino. We assessed that this gas, analogous to other minor vents in the area, is dominantly composed of deep, partially mantle-derived CO2, as in the geothermal gas of the surrounding Roman Comagmatic Province. Increased amounts of thermogenic CH4 are likely sourced from Meso-Cenozoic petroleum systems, overlying the deep magmatic fluids. We hypothesize that the intersection of NE-SW and N-S fault systems, which at regional scale controls the location of the Roman volcanic edifices, favors gas uprising through the impermeable Pliocene and deltaic Holocene covers. Pressurized gas may temporarily be stored below these covers or within shallower sandy, permeable layers. The eruption, regardless the triggering cause—natural or man-made, reveals the potential hazard of gas-charged sediments in the delta, even at distances far from the volcanic edifices.
    Description: Published
    Description: 5632–5636
    Description: 2.2. Laboratorio di paleomagnetismo
    Description: JCR Journal
    Description: restricted
    Keywords: geothermal gas ; deep CO2 ; Tiber river delta ; thermogenic CH4 ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 32
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    Origin and interactions of fluids circulating over the Amik Basin (Hatay, Turkey) and relationships with the hydrologic, geologic and tectonic settings (2014)
    Elsevier Science Limited
    Details
    Publication Date: 2021-06-15
    Description: We investigated the geochemical features of the fluids circulating over the Amik Basin (SE Turkey–Syria border), which is crossed by the Northern extension of theDSF (Dead Sea Fault) and represents the boundary area of three tectonic plates (Anatolian, Arabian and African plates). We collected 34 water samples (thermal and cold from natural springs and boreholes) as well as 8 gas samples (bubbling and gas seepage) besides the gases dissolved in the sampled waters. The results show that the dissolved gas phase is a mixture of shallow (atmospheric) and deep components either of mantle and crustal origin. Coherently the sampled waters are variable mixtures of shallow and deep ground waters, the latter being characterised by higher salinity and longer residence times. The deep groundwaters (fromboreholes deeper than 1000 m)have a CH4-dominated dissolved gas phase related to the presence of hydrocarbon reservoirs. The very unique tectonic setting of the area includes the presence of an ophiolitic block outcropping in the westernmost area on the African Plate, as well as basalts located to the North and East on the Arabic Plate. The diffuse presence of CO2-enriched gases, although diluted by the huge groundwater circulation, testifies a regional degassing activity. Fluids circulating over the ophiolitic block are marked by H2-dominated gases with abiogenic methane and high-pH waters. The measured 3He/4He isotopic ratios display contributions from both crustal and mantle-derived sources over both sides of the DSF. Although the serpentinization process is generally independent from mantle-type contribution, the recorded helium isotopic ratios highlight variable contents of mantle-derived fluids. Due to the absence of recent volcanism over the western side of the basin (African Plate), we argue that CO2-rich volatiles carrying mantle-type helium and enriched in heavy carbon, are degassed by deep-rooted regional faults rather than from volcanic sources.
    Description: Published
    Description: 23–39
    Description: 2T. Tettonica attiva
    Description: JCR Journal
    Description: restricted
    Keywords: Dead Sea Fault ; Hydrogeochemistry ; Gas geochemistry ; He isotopes ; C isotopes ; Ophiolites ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.02. Carbon cycling ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 33
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    Paleomagnetism and magnetic fabric of the Eastern Cordillera of Colombia: Evidence for oblique convergence and non rotational reactivation of a Mesozoic intracontinental rift (2014)
    American Geophysical Union
    Details
    Publication Date: 2017-04-04
    Description: We report the paleomagnetic and magnetic fabric results of 58 sites from Cretaceous-Miocene marine and continental strata from the Eastern Cordillera (EC) and the Cucuta zone, at the junction between the Santander Massif and the Merida Andes of Colombia. The EC is an intracontinental doubly vergent range inverting a Triassic to Early Cretaceous rift zone. Twenty-three sites reveal nonsystematic tectonic rotations, including unrotated areas of the EC range with respect to stable South America. Our data show that the EC inverted a NNE oriented rift zone and that the orientation of the Mesozoic rift and the mountain chain roughly correspond. Interestingly, magnetic lineations from anisotropy of magnetic susceptibility analysis do not trend parallel to the chain but rather are oblique to the main orogenic trend. By also considering GPS evidence of a ~1 cm/yr ENE displacement of central western Colombia accommodated by the EC, we suggest that the Miocene-Recent deformation event of this belt arises from ENE oblique convergence reactivating a NNE oriented rift zone. Oblique shortening was likely partitioned into pure dip-slip shear characterizing thick-skinned frontal thrust sheets (well known along both chain fronts) and by range-parallel right-lateral strike-slip faults, which have not been identified yet, but likely exist in the axial part of the EC. Finally, the 35° ± 9° clockwise rotation observed in four post-Miocene magnetically overprinted sites from the Cucuta zone reflects late Cenozoic and ongoing right-lateral strike-slip displacement occurring along faults parallel to the Boconó fault system, possibly connected with the right-lateral faults inferred to exist along the axial part of the EC.
    Description: Published
    Description: 2233–2260
    Description: 1A. Geomagnetismo e Paleomagnetismo
    Description: JCR Journal
    Description: restricted
    Keywords: Paleomagnetism, magnetic fabric, Eastern Cordillera ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.04. Plate boundaries, motion, and tectonics ; 04. Solid Earth::04.07. Tectonophysics::04.07.06. Subduction related processes ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics
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  • 34
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    Foreland segmentation along an active convergent margin: New constraints in southeastern Sicily (Italy) from seismic and geodetic observations (2014)
    Elsevier Science Limited
    Details
    Publication Date: 2017-04-04
    Description: We performed an in-depth analysis of the ongoing tectonics of a large sector of southern Sicily, including the Hyblean Foreland and the front of the Maghrebian Chain, as well as the Ionian Sea offshore, through the integration of seismic and GPS observations collected in the nearly two decades. In particular, a dataset consisting of more than 1100 small-to moderate-magnitude earthquakes (1.0 ≤ ML ≤ 4.6) has been used for local earthquake tomography in order to trace the characteristics of the faulting systems, and for focal mechanisms computation to resolve the current local stress field and to characterise the faulting regime of the investigated area. In addition, GPS measurements, carried out on both episodic and continuous stations, allowed us to infer the main features of the current crustal deformation pattern. Main results evidence that the Hyblean Plateau is subject to a general strike–slip faulting regime, with a maximum horizontal stress axis NW–SE to NNW–SSE oriented, in agreement with the Eurasia–Nubia direction of convergence. The Plateau is separated into two different tectonic crustal blocks by the left-lateral strike–slip Scicli–Ragusa Fault System. The western block moves in agreement with central Sicily while the eastern one accommodates part of the contraction arising from the main Eurasia–Nubia convergence. Furthermore, we provided evidences leading to consider the Hyblean–Maltese Escarpment Fault System as an active boundary characterised by a left-lateral strike–slip motion, separating the eastern block of the Plateau from the Ionian basin. All these evidences lend credit to a crustal segmentation of the southeastern Sicily.
    Description: Published
    Description: 137-149
    Description: 1T. Geodinamica e interno della Terra
    Description: JCR Journal
    Description: open
    Keywords: Southeastern Sicily ; Seismotectonics ; Tomography ; Focal mechanisms ; Crustal stress ; Geodetic strain rate ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics
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    Real-time measurements of the concentration and isotope composition of atmospheric and volcanic CO2 at Mount Etna (Italy) (2014)
    American Geophysical Union
    Details
    Publication Date: 2020-02-24
    Description: We present unprecedented data of real-time measurements of the concentration and isotope composition of CO2 in air and in fumarole-plume gases collected in 2013 during two campaigns at Mount Etna volcano, which were made using a laser-based isotope ratio infrared spectrometer. We performed approximately 360 measurements/h, which allowed calculation of the δ13C values of volcanic CO2. The fumarole gases of Torre del Filosofo (2900mabove sea level) range from 3.24 ± 0.06‰to 3.71 ± 0.09‰, comparable to isotope ratio mass spectrometry (IRMS) measurements of discrete samples collected on the same dates. Plume gases sampled more than 1 km from the craters show a δ13C= 2.2 ± 0.4‰, in agreement with the crater fumarole gases analyzed by IRMS. Measurements performed along ~17km driving track from Catania to Mount Etna show more negative δ13C values when passing through populated centers due to anthropogenic-derived CO2 inputs (e.g., car exhaust). The reported results demonstrate that this technique may represent an important advancement for volcanic and environmental monitoring.
    Description: Published
    Description: 2382–2389
    Description: 2V. Dinamiche di unrest e scenari pre-eruttivi
    Description: JCR Journal
    Description: restricted
    Keywords: Real-time data of CO2 content and δ13C in atmospheric/volcanic gases ; This study opens new perspective for the community for volcanic surveillance ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 36
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    Advective heat transport associated with regional Earth degassing in central Apennine (Italy) (2014)
    Elsevier Science Limited
    Details
    Publication Date: 2017-04-04
    Description: In this work we show that the main springs of the central Apennine transport a total amount of heat of ∼2.2 109 J s−1. Most of this heat (57%) is the result of geothermal warming while the remaining 43% is due to gravitational potential energy dissipation. This result indicates that a large area of the central Apennines is very hot with heat flux values 4300 mWm−2. These values are higher than those measured in the magmatic and famously geothermal provinces of Tuscany and Latium and about 1/3 of the total heat discharged at Yellowstone. This finding is surprising because the central Apennines have been thought to be a relatively cold area. Translated by CO2 rich fluids, this heat anomaly suggests the existence of a thermal source such as a large magmatic intrusion at depth. Recent tomographic images of the area support the presence of such an intrusion visible as a broad negative velocity anomaly in seismic waves. Our results indicate that the thermal regime of tectonically active areas of the Earth, where meteoric waters infiltrate and deeply circulate, should be revised on the basis of mass and energy balances of the groundwater systems.
    Description: Published
    Description: 65–74
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: heat flux ; CO2 Earth degassing ; central Apennine ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
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  • 37
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    Vertical GPS ground motion rates in the Euro-Mediterranean region: New evidence of velocity gradients at different spatial scales along the Nubia-Eurasia plate boundary (2014)
    American Geophysical Union
    Details
    Publication Date: 2017-04-04
    Description: We use 2.5 to 14 years long position time series from 〉800 continuous Global Positioning System (GPS) stations to study vertical deformation rates in the Euro-Mediterranean region. We estimate and remove common mode errors in position time series using a principal component analysis, obtaining a significant gain in the signal-to-noise ratio of the displacements data. Following the results of a maximum likelihood estimation analysis, which gives a mean spectral index ~ 0.7, we adopt a power law + white noise stochastic model in estimating the final vertical rates and find 95% of the velocities within ±2 mm/yr, with uncertainties from filtered time series ~40% smaller than from the unfiltered ones. We highlight the presence of statistically significant velocity gradients where the stations density is higher. We find undulations of the vertical velocity field at different spatial scales both in tectonically active regions, like eastern Alps, Apennines, and eastern Mediterranean, and in regions characterized by a low or negligible tectonic activity, like central Iberia and western Alps. A correlation between smooth vertical velocities and topographic features is apparent in many sectors of the study area. Glacial isostatic adjustment and weathering processes do not completely explain the measured rates, and a combination of active tectonics and deep-seated geodynamic processes must be invoked. Excluding areas where localized processes are likely, or where subduction processes may be active, mantle dynamics is the most likely process, but regional mantle modeling is required for a better understanding.
    Description: Published
    Description: 6003–6024
    Description: 1T. Geodinamica e interno della Terra
    Description: 2T. Tettonica attiva
    Description: 1R. Reti di monitoraggio e Osservazioni
    Description: JCR Journal
    Description: restricted
    Keywords: GPS ; Geodynamics ; Mediterranean ; Vertical deformation ; 04. Solid Earth::04.03. Geodesy::04.03.01. Crustal deformations ; 04. Solid Earth::04.03. Geodesy::04.03.06. Measurements and monitoring ; 04. Solid Earth::04.03. Geodesy::04.03.07. Satellite geodesy ; 04. Solid Earth::04.07. Tectonophysics::04.07.01. Continents ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.04. Plate boundaries, motion, and tectonics ; 04. Solid Earth::04.07. Tectonophysics::04.07.06. Subduction related processes
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  • 38
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    Distinguishing contributions to diffuse CO2 emissions in volcanic areas from magmatic degassing and thermal decarbonation using soil gas 222Rn–δ13 C systematics: Applicationto Santorini volcano,Greece (2014)
    Elsevier Science Limited
    Details
    Publication Date: 2022-06-10
    Description: Between January 2011 and April 2012, Santorini volcano (Greece) experienced a period of unrest characterised by the onset of detectable seismicity and caldera-wide uplift. This episode of inflation represented the first sizeable intrusion of magma beneath Santorini in the past 50 years. We employ a new approach using 222 Rn– δ 13 C systematics to identify and quantify the source of diffuse degassing at Santorini during the period of renewed activity. Soil CO 2 flux measurements were made across a network of sites on Nea Kameni between September 2010 and January 2012. Gas samples were collected in April and September 2011 for isotopic analysis of CO 2 ( δ 13 C), and radon detectors were deployed during September 2011 to measure ( 222 Rn). Our results reveal a change in the pattern of degassing from the summit of the volcano (Nea Kameni) and suggest an increase in diffuse CO 2 emissions between September 2010 and January 2012. High-CO 2 -flux soil gas samples have δ 13 C ∼ 0 .Using this value and other evidence from the literature we conclude that these CO 2 emissions from Santorini were a mixture between CO 2 sourced from magma, and CO 2 released by the thermal or metamorphic breakdown of crustal limestone. We suggest that this mixing of magmatic and crustal carbonate sources may account more broadly for the typical range of δ 13 CvaluesofCO 2 (from ∼− 4 to ∼+ 1 )in diffuse volcanic and fumarole gas emissions around the Mediterranean, without the need to invoke unusual mantle source compositions. At Santorini a mixing model involving magmatic CO 2 (with δ 13 C of − 3 ± 2 and elevated ( 222 Rn)/CO 2 ratios ∼ 10 5 –10 6 Bqkg − 1 )andCO 2 released from decarbonation of crustal limestone (with ( 222 Rn)/CO 2 ∼ 30–300 Bqkg − 1 ,and δ 13 Cof + 5 ) can account for the δ 13 C and ( 222 Rn)/CO 2 characteristics of the ‘high flux’ gas source. This model suggests ∼ 60% of the carbon in the high flux deep CO 2 end member is of magmatic origin. This combination of δ 13 Cand( 222 Rn) measurements has potential to quantify magmatic and crustal contributions to the diffuse outgassing of CO 2 in volcanic areas, especially those where breakdown of crustal limestone is likely to contribute significantly to the CO 2 flux
    Description: Published
    Description: 180-190
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: volcanic unrest ; soil gas measurements ; carbon isotopic analysis ; magmatic degassing ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
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  • 39
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    Gas geochemistry of the magmatic-hydrothermal fluid reservoir in the Copahue–Caviahue Volcanic Complex (Argentina) (2014)
    Elsevier Science Limited
    Details
    Publication Date: 2024-05-09
    Description: Copahue volcano is part of the Caviahue–Copahue Volcanic Complex (CCVC),which is located in the southwestern sector of the Caviahue volcano-tectonic depression (Argentina–Chile). This depression is a pull-apart basin accommodating stresses between the southern Liquiñe–Ofqui strike slip and the northern Copahue–Antiñir compressive fault systems, in a back-arc setting with respect to the Southern Andean Volcanic Zone. In this study, we present chemical (inorganic and organic) and isotope compositions (δ13C-CO2, δ15N, 3He/4He, 40Ar/36Ar, δ13C-CH4, δD-CH4, and δD-H2O and δ18O-H2O) of fumaroles and bubbling gases of thermal springs located at the foot of Copahue volcano sampled in 2006, 2007 and 2012. Helium isotope ratios, the highest observed for a Southern American volcano (R/Ra up to 7.94), indicate a non-classic arc-like setting, but rather an extensional regime subdued to asthenospheric thinning. δ13C-CO2 values (from −8.8‰ to −6.8‰ vs. V-PDB), δ15N values (+5.3‰ to +5.5‰ vs. Air) and CO2/3He ratios (from 1.4 to 8.8 × 109) suggest that the magmatic source is significantly affected by contamination of subducted sediments. Gases discharged from the northern sector of the CCVC show contribution of 3He-poor fluids likely permeating through local fault systems. Despite the clear mantle isotope signature in the CCVC gases, the acidic gas species have suffered scrubbing processes by a hydrothermal system mainly recharged by meteoric water. Gas geothermometry in the H2O-CO2-CH4-CO-H2 system suggests that CO and H2 re-equilibrate in a separated vapor phase at 200°–220 °C. On the contrary, rock–fluid interactions controlling CO2, CH4 production from Sabatier reaction and C3H8 dehydrogenation seem to occur within the hydrothermal reservoir at temperatures ranging from 250° to 300 °C. Fumarole gases sampled in 2006–2007 show relatively low N2/He and N2/Ar ratios and high R/Ra values with respect to those measured in 2012. Such compositional and isotope variations were likely related to injection of mafic magma that likely triggered the 2000 eruption. Therefore, changes affecting the magmatic systemhad a delayed effect on the chemistry of the CCVC gases due to the presence of the hydrothermal reservoir. However, geochemical monitoring activities mainly focused on the behavior of inert gas compounds (N2 and He), should be increased to investigate the mechanism at the origin of the unrest started in 2011.
    Description: Published
    Description: 44–56
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: Fluid geochemistry ; Copahue volcano ; Fumarolic fluid ; Hydrothermal reservoir ; Volcanic unrest ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
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  • 40
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    Diffuse soil emission of hydrothermal gases (CO2, CH4, and C6H6) at Solfatara crater (Campi Flegrei, southern Italy) (2014)
    Elsevier Science Limited
    Details
    Publication Date: 2024-05-09
    Description: Measurements of soil fluxes of hydrothermal gases, with special emphasis on C6H6, as well as chemical composition of mono-aromatic compounds in fumaroles and air, were carried out in April 2012 at the Solfatara crater (Campi Flegrei, Southern Italy) to investigate the distribution and behavior of these species as they migrate through the soil from their deep source to the atmosphere. Soil fluxes of CO2, CH4 and C6H6 exhibit good spatial correlation, suggesting that diffuse degassing is mainly controlled by local fractures. The calculated total output of diffuse C6H6 from Solfatara is 0.10 kg day 1, whereas fluxes of CO2 and CH4 are 79 103 and 1.04 kg day 1, respectively. A comparison between soil gas fluxes and fumarole composition reveals that within the crater soil CH4 is significantly affected by oxidation processes, which are more efficient for low gas fluxes, being dependent on the residence time of the uprising hydrothermal gases at shallow depth. Benzene degradation, mainly proceeding through oxidation via benzoate, seems to be strongly controlled by the presence of a shallow SO2 4 -rich aquifer located in the central and southwestern sectors of the crater, suggesting that the process is particularly efficient when SO2 4 acts as terminal electron acceptor (SO4 reduction). Relatively high C6H6/C7H8 ratios, typical of hydrothermal fluids, were measured in air close to the main fumarolic field of Solfatara crater. Here, C6H6 concentrations, whose detection limit is 0.1 lgm 3, are more than one order of magnitude higher than the limit value for ambient air (5 lgm 3). This suggests that hydrothermal fluids have a strong impact on air quality in the immediate surroundings of the fumarolic vents. Significant concentrations of endogenous mono-aromatics were also detected in air samples collected from the northern and western sides of the crater, where these gas compounds are mostly fed by diffuse degassing through the crater bottom soil.
    Description: Published
    Description: 142–153
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: hydrothermal gases ; Solfatara crater ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
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  • 41
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    Multidisciplinary study of the Tindari Fault (Sicily, Italy) separating ongoing contractional and extensional compartments along the active Africa–Eurasia convergent boundary (2013)
    Elsevier Science Limited
    Details
    Publication Date: 2020-12-15
    Description: The Africa–Eurasia convergence in Sicily and southern Calabria is currently expressed by two different tectonic and geodynamic domains: thewestern region, governed by a roughlyN–S compression generated by a continental collision; the eastern one, controlled by a NW–SE extension related to the south-east-directed expansion of the Calabro–Peloritan Arc. The different deformation pattern of these two domains is accommodated by a right-lateral shear zone (Aeolian–Tindari–Letojanni fault system) which, from the Ionian Sea, north of Mt. Etna, extends across the Peloritani chain to the Aeolian Islands. In this work, we study the evidence of active tectonics characterizing this shear zone, through the analysis of seismic and geodetic data acquired by the INGV networks in the last 15 years. The study is completed by structural and morphological surveys carried out between Capo Tindari and the watershed of the chain. The results allowed defining a clear structural picture depicting the tectonic interferences between the two different geodynamic domains. The results indicate that, besides the regional ~N130°E horizontal extensional stress field, another one, NE–SW-oriented, is active in the investigated area. Both tension axes are mutually independent and have been active up to the present at different times. The coexistence of these different active horizontal extensions is the result of complex interactions between several induced stresses: 1) the regional extension (NW–SE) related to the slab rollback and back-arc extension; 2) the strong uplift of the chain; 3) the accommodation between compressional and extensional tectonic regimes along the Aeolian– Tindari–Letojanni faults, through a SSE–NNW right-lateral transtensional displacement. In these conditions, the greater and recurring uplift activity is not able to induce a radial extensional dynamics, but, under the “directing” action of the shear system, it can only act on the regional extension (NW–SE) and produce the second system of extension (NE–SW).
    Description: Published
    Description: 1-17
    Description: 3.2. Tettonica attiva
    Description: JCR Journal
    Description: open
    Keywords: Africa–Eurasia convergence ; Aeolian–Tindari fault system ; Transform activity ; Stress and strain fields ; Multidisciplinary approach ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics
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  • 42
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    Offshore and onshore seepage of thermogenic gas at Katakolo Bay (Western Greece) (2013)
    Elsevier Science Limited
    Details
    Publication Date: 2017-04-04
    Description: Considerable seepage of natural gas occurs throughout the Katakolo Bay, both at sea and on land, along the Ionian coast of Peloponnesus (Western Greece). Explosive levels of CH4 and toxic concentrations of H2S accumulating in the ground, pose a severe hazard for humans and tourist infrastructures. A wide offshore and onshore gas survey, including marine remote sensing, underwater exploration by a towed instrumented system, compositional and isotopic analyses, and flux measurements of gas, allowed us to assess that: (a) gas seepage takes place along two main normal faults; (b) offshore side-scan sonographs recorded at least 823 gas bubble plumes over an area of 94,200 m2, at depths ranging from 5.5 to 16 m; (c) offshore and onshore seeps release the same type of thermogenic gas (δ13CCH4~−34 to −36‰); (d) offshore gas showed increased stable carbon isotopic ratio of CO2 and propane, which suggests enhanced biodegradation of hydrocarbons; (e) isotopic data combined with thermogenic gas generation modeling and maturity plots, suggest that the gas is related to a deep Petroleum System with Jurassic carbonate reservoirs, Triassic source rocks, and Triassic evaporites; (f) H2S (δ34S: +2.4‰) is produced by thermochemical sulfate reduction in deep anhydrites, in contact with hydrocarbon-rich carbonates; (g) due to the shallow depth, more than 90% of CH4 released at the seabed enters the atmosphere, consistent with theoretical bubble dissolution models, with a mean plume output of 0.12 kg d−1; total offshore CH4 output was estimated in the range of 33 to 120 t y−1; and (h) in the onshore area at least 50 gas vents in the harbor and a large seep on the adjacent Faros hill, emit in total about 89 t CH4 y−1. Katakolo results to be one of the biggest thermogenic gas seepage zones in Europe.
    Description: Published
    Description: 115–126
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: Gas seeps ; Thermogenic methane ; Bubble plumes ; Hydrocarbon biodegradation ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 43
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    Continuous monitoring of hydrogen and carbon dioxide at Mt Etna (2013)
    Elsevier Science Limited
    Details
    Publication Date: 2017-04-04
    Description: This study assessed the use of a H2 fuel cell as an H2-selective sensor for volcano monitoring. The resolution, repeatability, and cross-sensitivity of the sensor were investigated and evaluated under known laboratory conditions. A tailor-made device was developed and used for continuously monitoring H2 and CO2 at Mt Etna throughout 2009 and 2010. The temporal variations of both parameters were strongly correlated with the evolution of the volcanic activity during the monitoring period. In particular, the CO2 flux exhibited long-term variations, while H2 exhibited pulses immediately before the explosive activity that occurred at Mt Etna during 2010.
    Description: Published
    Description: 41–51
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: Soil CO2 flux ; H2 monitoring ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.06. Seismology::04.06.10. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 44
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    Methane flux from miniseepage in mud volcanoes of SW Taiwan: Comparison with the data from Italy, Romania, and Azerbaijan (2013)
    Elsevier Science Limited
    Details
    Publication Date: 2017-04-04
    Description: Mud volcanoes (MVs) are considered important methane (CH4) sources for the atmosphere; gas is not only released from macro-seepage, i.e., from craters and visible gas bubbling manifestations, but also from invisible and pervasive exhalation from the ground, named miniseepage. CH4 flux related to miniseepage was measured only in a few MVs, in Azerbaijan, Italy, Japan, Romania and Taiwan. This study examines in detail the flux data acquired in 5 MVs and 1 ‘‘dry’’ seep in SW Taiwan, and further compares with other 23 MVs in Italy, Romania and Azerbaijan. Miniseepage from the six manifestations in SW Taiwan MVs and seeps annually contribute at least 110 tons of methane directly to the atmosphere, and represents about 80% of total degassing during a quiescent period. Combining miniseepage flux and geo-electrical data from the Wu-shan-ding MV revealed a possible link between gas flux and electrical resistivity of the vadose zone. This suggests that unsaturated subsoil is a preferential zone for shallow gas accumulation and seepage to the atmosphere. Besides, miniseepage flux in Chu-huo everlasting fire decreases by increasing the distance from the main gas channeling zone and molecular fractionation (methane/ethane ratio) is higher for lower flux seepage, consistently with what observed in other MVs worldwide. Measurements from Azerbaijan, Italy, Romania, and Taiwan converge to indicate that miniseepage is directly proportional to the vent output and it is a significant component of the total methane budget of a MV. A miniseepage vs. macro-seepage flux equation has been statistically assessed and it can be used to estimate theoretically at least the order of magnitude of the flux of miniseepage for MVs of which only the flux from vents was evaluated, or will be evaluated in future. This will allow a more complete and objective quantification of gas emission in MVs, thus also refining the estimate of the global methane emission from geological sources.
    Description: Published
    Description: 3–12
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: Mud volcano ; Miniseepage ; Macro-seepage ; Global methane emission ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 45
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    Chemical and isotopic characterisation of bulk deposition in the Louros basin (Epirus, Greece) (2013)
    Elsevier Science Limited
    Details
    Publication Date: 2017-04-04
    Description: About 120 rainwater samples were collected through a network of five bulk collectors in the area of the Louros basin (Epirus, Greece) during the wet season from October 2008 to August 2009. They were analysed for their isotopic (δD and δ18O) and chemical (H+, Na+, K+, Mg2+, Ca2+, NH4 +, F−, Cl−, Br−, NO3 −, SO4 2 −) composition. A local meteoric water line (δD‰ = 5.80 ± 0.02 δ18O‰ + 0.02 ± 0.12) and a local isotopic lapse rate (−0.18 δ18O‰/100 m) were obtained considering the volume-weighted means of the five sampling sites. These results agree well with those obtained in nearby areas. The chemical composition of the samples allows to identify an almost entirely marine origin for chloride and sodium with decreasing deposition values at increasing distance from the coast. Nitrate and ammonium are almost completely of anthropogenic origin, calcium and potassium are overwhelmingly geogenic, sulphate has a prevailingly anthropogenic origin with a significant marine contribution and magnesium has a mixedmarine and soil dust origin. Finally, as for most of the Mediterranean area, rainwater acidity is buffered by the dissolution of the abundant geogenic carbonate aerosol.
    Description: Published
    Description: 399-410
    Description: 4.4. Scenari e mitigazione del rischio ambientale
    Description: JCR Journal
    Description: restricted
    Keywords: Precipitation ; Neutralization ; Stable isotopes ; Chemical composition ; Bulk deposition ; 01. Atmosphere::01.01. Atmosphere::01.01.02. Climate ; 01. Atmosphere::01.01. Atmosphere::01.01.03. Pollution ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 02. Cryosphere::02.03. Ice cores::02.03.06. Precipitation ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 46
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    The episodic and abrupt geochemical changes at La Fossa fumaroles (Vulcano Island, Italy) and related constraints on the dynamics, structure, and compositions of the magmatic system (2013)
    Elsevier Science Limited
    Details
    Publication Date: 2017-04-04
    Description: Herein we report on the chemical and isotopic (C, H, O, and He) compositions of the fluids from La Fossa crater fumaroles of Vulcano from 1999 to 2010. Consistent with records obtained since the end of the 1980s, our data show that the geochemical features of the fumarole system have experienced several episodes of remarkable change, each lasting no more than a few months. Typical signatures of these short-term anomalies are large increments in CO2, N2, and He concentrations, coupled to increased 13C/12C isotopic ratios, but their meaning remains widely debated. Within a model of fumarolic fluids based on mixing between hydrothermal and magmatic endmembers, we have developed a novel approach to constrain chemical (He/ CO2 and N2/He) and isotopic (13C/12C, D/H, and 3He/4He) ratios of the magmatic endmember during the short-term anomalies. Although much of the geochemical variability in fumaroles results from changes in mixing proportions, the magmatic fluid unquestionably shows significant variations in time. The magmatic He/CO2, N2/He, 13C/12C, and 3He/4He values throughout 1988–1996 differed from those feeding the anomaly at the end of 2004. Early clues of the new magmatic fluid appeared in 1998–1999, far from any short-term anomaly, whereas new and old magmatic fluids coexisted after 2004. We quantitatively prove that the detected geochemical changes are consistent with the degassing path of a magma having a latitic composition, and suggest the presence of two magma ponding levels at slightly different pressures, where bubble–melt decoupling can occur. The different He-isotope compositions at these levels suggest low hydraulic connectivity typical of a complex reservoir with dike and sill structures. In this framework, the short-term geochemical anomalies are probably due to gas accumulation at the top of magma bodies followed by massive escape, or activation of new degassing levels in the reservoir, for which the stress field almost certainly plays a key role. Such a scenario explains the observed increases in both fumarole output and shallow high-frequency seismicity (due to increased pore pressure) during the anomalies, while being consistent with the concomitant absence of any deep seismicity or ground deformation, eventually related to magma movement.
    Description: Published
    Description: 158-178
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: restricted
    Keywords: fumarole geochemistry ; magma degassing ; thermodynamic modeling ; noble gas geochemistry ; carbon isotopes ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.04. Thermodynamics ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 47
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    An innovative method for continuous measurement of soil CO2 flux (2013)
    Elsevier Science Limited
    Details
    Publication Date: 2017-04-04
    Description: Herein, we present a method for continuous measurement of soil CO2 flux that is completely new and distinct from existing instruments. The foremost difference is that instead of using an infrared gas analyser (IRGA), the new device measures soil CO2 flux by means of a simple pressure sensor, measuring pressure transients inside a closed polymeric tube inserted into the soil. This allows continuous measurements even in soil placed in environments that could potentially damage IRGA. In addition, due to the innovative operating principle, measurements of soil CO2 flux can be effortlessly performed also in strongly harsh weather conditions. Theoretical equations were derived for calculating soil CO2 flux solely using measured transient values. The reliability of the equations was rigorously tested with a variety of experiments. Continuous measurements over four months, acquired in a high-emission area on the Island of Vulcano, compared favourably with the data obtained using an established method.
    Description: Published
    Description: 102-109
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: JCR Journal
    Description: restricted
    Keywords: Soil CO2 flux measurements ; Continuous monitoring ; Methods of measurement ; Polymeric membranes ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
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  • 48
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    Defining a 3D physical model for the hydrothermal circulation at Campi Flegrei caldera (Italy) (2013)
    Elsevier Science Limited
    Details
    Publication Date: 2017-04-04
    Description: Our study is aimed to develop a 3D physical model of the Campi Flegrei geothermal system, in order to achieve a more accurate and comprehensive representation of the hydrothermal processes occurring in the caldera. The new model, developed by using the TOUGH2 code simulator, accounts for the caldera rocks' physical properties, bathymetry and water table topography. In particular, the computational domain is constrained by density values obtained by tomographic inversion of gravity data collected during several surveys at CF both onshore and offshore the caldera. Empirical relations between density and porosity and between porosity and permeability, derived by published data on samples cored in deep wells or collected in outcrops, allowed us to characterize the main rocks physical parameters controlling the dynamic of the CF geothermal system. We have performed and compared several simulations investigating the effects of the injection at depth, underneath Solfatara crater, of a hot gaseous mixture rich in CO2. We show that, with respect to the available literature on 2D axisymmetric models, the effects of the water table topography together with the bathymetry and the heterogeneous distribution of the rocks' physical properties, lead to important differences in the hydrothermal circulation of fluids at CF. These constraints allow the activation of convective cells with different behaviors, which produce variable patterns of temperature inside the hydrothermal system. As a consequence, the predominant effect is again represented by a central plume below the Solfatara crater, but with a non-axisymmetric structure and a wider extension. Additionally, high temperature zones are present near the coastline and in the middle part of the submerged area of the caldera with a SE–NW alignment. Moreover, our results indicate that, the submerged part of the CF caldera would deserve a more accurate study and survey, being affected by phenomenon of heating and degassing. This information could be very useful in terms of hazard assessment and volcanic risk mitigation in such an active and densely inhabited volcanic and geothermal area.
    Description: Published
    Description: 172-182
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: Campi Flegrei ; Geothermal system ; 3D model ; Water table topography ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
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  • 49
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    The cuticle micromorphology of in situ Erica arborea L. exposed to long-term volcanic gases (2013)
    Elsevier Science Limited
    Details
    Publication Date: 2017-04-04
    Description: Epidermis micromorphology of in situ Erica arborea L. exposed for generations to long-term effect of volcanic gases in Pisciarelli and Solfatara di Pozzuoli areas have been studied by X-ray analyses, SEM and TEM observations. In particular, the aim of this study is to investigate the effects of volcanic gases on extant and possibly fossil plants. Plants of the same species living in a nearby control site were also studied for comparison. SEM coupled with EDX analysis was used to localize different elements within the leaves (mesophyll, cell wall and cuticle). After conventional and cryo preparation, SEM of mature leaves ascertained that the abaxial side is more serrate in fumigated leaves and hairs, epicuticular wax alterations have also been noted. Leaves experiencing chronic fumigation display stomata more sunken with respect to the epidermal surface. TEM of transverse and longitudinal sections of cuticle showed an outer A2 granular amorphous layer and external to a B1 fibrillous layer. Significant statistical variations of ultrastructural components of the cuticle revealed a response of E. arborea to this extreme environment. At the ultrastructural level, significant variations in thickness of the cell wall plus cuticle, cell wall and A2 layer among fumigated and non-fumigated leaves have been found. In the studied localities a positive correlation between atmospheric CO2 concentration and the thickness of A2 layer also exists. The results are of interest being applicable in the understanding of plant cuticle responses during periods of normal vs. volcanic activity.
    Description: Published
    Description: 197– 206
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: Phlegrean Fields ; Erica arborea ; Volcanic gases ; Epidermis ; Cuticle ultrastructure ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring ; 03. Hydrosphere::03.04. Chemical and biological::03.04.04. Ecosystems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
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  • 50
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    Chlorine isotope composition of volcanic gases and rocks at Mount Etna (Italy) and inferences on the local mantle source (2013)
    Elsevier Science Limited
    Details
    Publication Date: 2017-04-04
    Description: We present the first chlorine isotope compositional data for gases and lavas from Mount Etna (Italy), and to our knowledge, of active Mediterranean volcanism. We investigated lavas erupted and gases discharged during 2008-2011 from a high-temperature fumarole (HT; 〉300°C) and plume gases from both North East and Central Craters. Most of the samples vary in a narrow range of chlorine isotope composition (37Cl values ≈ 0 ± 0.7‰) with gases partially overlapping with rocks. Only HT gases sampled in 2009 have been clearly affected by secondary processes (37Cl values 〉 15.9‰), resulting in partial removal of chlorine and isotopic fractionation producing a 37Cl enrichment in the residual gaseous HCl. These secondary processes also affect, although to a lesser extent, plume gases from North East Crater (NEC). Although post-magmatic processes are able to modify the chlorine isotope composition, 37Cl values are not affected by magma degassing for residual fractions ≥ 0.3 in the melt, or any effect is within our data variability. Finally, 37Cl values and Cl/K ratios of magmatic chlorine constrain the Etnean source to be compatible with depleted mantle (DMM) contaminated by altered oceanic crust (AOC), in agreement with indications from more common isotopic tracers of mantle processes.
    Description: Published
    Description: 134-142
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: restricted
    Keywords: Mount Etna ; chlorine isotope ; plume ; fumarole ; degassing ; mantle source ; 04. Solid Earth::04.04. Geology::04.04.07. Rock geochemistry ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks
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  • 51
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    The attenuation mechanism of S-waves in the source zone of the 1999 Chamoli earthquake (2013)
    Elsevier Science Limited
    Details
    Publication Date: 2017-04-04
    Description: In the present study the attenuation mechanism of seismic wave energy in and around the source area of the Chamoli earthquake of 29th March 1999 is estimated using the aftershock data. Most of the analyzed events are from the vicinity of the Main Central Thrust (MCT), which is a well-defined tectonic discontinuity in the Himalayas. Separation of intrinsic (Q 1 i ) and scattering (Q 1 s ) attenuation coefficient is done over the frequencies 1, 2, 4, 8 and 16 Hz using Multiple Lapse Time Window Analysis (MLTWA) method. It is observed that S-waves and their coda are primarily attenuated due to scattering attenuation and seismic albedo is very high at all the frequencies. A comparison of attenuation characteristics obtained using these aftershock data with those obtained using data of general seismicity of this region reveal that at lower frequencies both intrinsic and scattering attenuation for Chamoli was much higher compared to those for Garwhal-Kumaun region using general seismicity data. At higher frequencies intrinsic attenuation for Chamoli is lower than and scattering attenuation is comparable to those obtained using general seismicity data of Garwhal-Kumaun region.
    Description: A partial support has been given by Italy INGV-DPC (Istituto Nazionale di Geofisica e Vulcanologia and Dipartimento di Protezione Civile) Projects UNREST and SPEED, and by Italy’s Ministry of Education PRIN project (Seismic Hazard in Central Apennines, UR Del Pezzo).
    Description: Published
    Description: 446-454
    Description: 1T. Geodinamica e interno della Terra
    Description: 4T. Fisica dei terremoti e scenari cosismici
    Description: JCR Journal
    Description: restricted
    Keywords: MLTWA ; Intrinsic attenuation ; Scattering attenuation ; Chamoli Himalayas ; Himalayas ; 04. Solid Earth::04.06. Seismology::04.06.07. Tomography and anisotropy ; 04. Solid Earth::04.06. Seismology::04.06.09. Waves and wave analysis ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics
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  • 52
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    Sulphur-gas concentrations in volcanic and geothermal areas in Italy and Greece: Characterising potential human exposures and risks (2013)
    Elsevier Science Limited
    Details
    Publication Date: 2017-04-04
    Description: Passive samplers were used to measure the atmospheric concentrations of SO2 naturally emitted at three volcanoes in Italy (Etna, Vulcano and Stromboli) and of H2S naturally emitted at three volcanic/geothermal areas in Greece (Milos, Santorini and Nisyros). The measured concentrations and dispersion patterns varied with the strength of the source (open conduits or fumaroles), the meteorological conditions and the area topography. At Etna, Vulcano and Stromboli, SO2 concentrations reach values that are dangerous to people affected by bronchial asthma or lung diseases (〉1000 μg m−3). H2S values measured at Nisyros also exceed the limit considered safe for the same group of people (〉3000 μg m−3). The data obtained using passive samplers represent time-averaged values over periods from a few days up to 1 month, and hence concentrations probably reached much higher peak values that were potentially also dangerous to healthy people. The present study provides evidence of a peculiar volcanic risk associated with tourist exploitation of active volcanic areas. This risk is particularly high at Mt. Etna, where the elderly and people in less-than-perfect health can easily reach areas with dangerous SO2 concentrations via a cableway and off-road vehicles
    Description: Published
    Description: 1-13
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: Sulphur dioxide ; Hydrogen sulphide ; Volcanic risks ; Gas hazard ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
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  • 53
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    Geochemical insight into differences in the physical structures and dynamics of two adjacent maar lakes at Mt. Vulture volcano (southern Italy) (2013)
    American Geophysical Union
    Details
    Publication Date: 2017-04-04
    Description: We report on the first geochemical investigation of the Monticchio maar lakes (Mt. Vulture volcano, southern Italy) covering an annual cycle that aimed at understanding the characteristic features of the physical structures and dynamics of the two lakes. We provide the first detailed description of the lakes based on high-resolution CTD profiles, chemical and isotopic (H and O) compositions of the water, and the amounts of dissolved gases (e.g., He, Ar, CH4 and CO2). The combined data set reveals that the two lakes, which are separated by less than 200 m, exhibit different dynamics: one is a meromictic lake, where the waters are rich in biogenic and mantle-derived gases, while the other is a monomictic lake, which exhibits complete turnover of the water in winter and the release of dissolved gases. Our data strongly suggest that the differences in the dynamics of the two lakes are due to different density profiles affected by dissolved solutes, mainly Fe, which is strongly enriched in the deep water of the meromictic lake. A conceptual model of water balance was constructed based on the correlation between the chemical composition of the water and the hydrogen isotopic signature. Gas-rich groundwaters that feed both of the lakes and evaporation processes subsequently modify the water chemistry of the lakes. Our data highlight that no further potential hazardous accumulation of lethal gases is expected at the Monticchio lakes. Nevertheless, geochemical monitoring is needed to prevent the possibility of vigorous gas releases that have previously occurred in historical time.
    Description: Published
    Description: 1411–1434
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: restricted
    Keywords: geochemistry ; noble gases ; maar lake ; lake dynamics ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 54
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    Active degassing of mantle-derived fluid: A geochemical study along the Vulture line, southern Apennines (Italy (2013)
    Elsevier Science Limited
    Details
    Publication Date: 2017-04-04
    Description: We report the results of a geochemical study of gas emissions along a NE–SW transect in southern Italy in order to test the hypothesis that the region around Monte Vulture is affected by degassing of mantle-derived fluids through a lithospheric discontinuity. We also investigated lavas from the Monte Vulture volcano displaying 3He/4He (up to ~6.0 Ra) and Sr isotopes that are consistent with an origin inmantle that has hadminimal pollution from subducted Adriatic slab. Similar 3He/4He in fluids from around Mt. Vulture indicate that the deep volcanic systemis still degassing. Mantle-derived He occurs in fluids along the length of the Vulture line, reinforcing the hypothesis that it is a deep tectonic discontinuity along which mantle fluids and/or melts advect to the surface. The CO2/3He ratios are highly variable (2.7×108–2.15×1011) in response to processes such as gas dissolution into aquifers, addition of crustal gases and degassing fractionation.
    Description: Published
    Description: 65-74
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: restricted
    Keywords: nonle gases ; mantle degassing ; tectonics ; Mt. Vulture ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 55
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    Comment on “CO2 variability in mid-ocean ridge basalts from syn-emplacement degassing: Constraints on eruption dynamics ” by Soule et al. [Earth Planet. Sci. Lett. (2012) 327–328, 39–49] (2013)
    Elsevier Science Limited
    Details
    Publication Date: 2017-04-04
    Description: Commenton “CO2 variabilityinmid-oceanridge basalts fromsyn-emplacementdegassing: Constraintsoneruptiondynamics”
    Description: Published
    Description: 251-253
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: restricted
    Keywords: non-equilibrium degassing, modeling, CO2, bubble growth, MORB, gas geochemistry ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.04. Thermodynamics
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  • 56
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    A two-component mantle source feeding Mt. Etna magmatism: Insights from the geochemistry of primitive magmas (2013)
    Elsevier Science Limited
    Details
    Publication Date: 2017-10-06
    Description: Themajor elements, trace elements and Sr and Nd isotopes of selected Etnean primitive rocks (b15 ky BP) were studied in order to characterize their mantle source. The noble-gas geochemistry of fluid inclusions in minerals fromthe same lavaswas also investigated. Themajor element compositions ofwhole rocks and minerals showed that these products are among the most primitive atMt. Etna, comprising 6.3–17.5 wt.% MgO. The variable LREE (Light Rare Earth Elements) enrichment relative to MORB (Mid-Ocean Ridge Basalt) (Lan/Ybn = 11–26), togetherwith the patterns of certain trace-element ratios (i.e., Ce/Yb versus Zr/Nb and Th/Y versus La/Yb), can be attributed to varying degrees of melting of a common mantle source. Numerical simulations performed with the MELTS program allowed the melting percentages associated with each product to be estimated. This led us to recalculate the hypothetical parental trace-element content of the Etneanmantle source, whichwas common to all of the investigated rocks. The characteristics of the Sr, Nd and He isotopes confirmed the primitive nature of the rocks,with themost-depleted and primitive lava being that ofMt. Spagnolo (SPA; 143Nd/144Nd = 0.512908 87Sr/ 86Sr = 0.703317–0.703325 and 3He/4He = 7.6 Ra), and highlighted the similarity of the mantle sources feeding the volcanic activity of Mt. Etna and the Hyblean Plateau (a region to the south of Mt. Etna and characterized by oldermagmatismthan Mt. Etna). The coupling of noble gases and trace elements suggests an origin for the investigated Etnean lavas from melting of a Hyblean-like mantle, consisting of a two-component source where a peridotitic matrix is veined by 10% pyroxenite. A variable degree of mantle contamination by crustal-like fluids, probably related to subduction, is proposed to explain the higher Sr-isotope and lowerNd-isotope values in some rocks (143Nd/144Nd up to 0.512865 and 87Sr/86Sr up to 0.703707). This process probably occurred in the source prior tomagma generation, refertilizing some portions of themantle. Accordingly, the estimated degree of melting responsible for each magma appears to be related to its 87Sr/86Sr enrichment. In contrast, the decoupling between 3He/4He and 87Sr/86Sr ratios requires the occurrence in the crustal reservoirs of further processes capable of shifting the He isotope ratio towards slightly more radiogenic values, such as magma aging or a contribution of shallow fluid. Therefore, different residence times in the Etnean reservoir and/or various rates of magma ascent could be key parameters for preserving the original He isotope marker of the Etnean mantle source.
    Description: Published
    Description: 243-258
    Description: 5V. Sorveglianza vulcanica ed emergenze
    Description: JCR Journal
    Description: restricted
    Keywords: Mt. Etna ; Hyblean Plateaux ; Primitive magma ; Mantle metasomatism ; Peridotite ; Pyroxenite ; 04. Solid Earth::04.01. Earth Interior::04.01.03. Mantle and Core dynamics ; 04. Solid Earth::04.04. Geology::04.04.07. Rock geochemistry ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 57
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    Role of the brittle–ductile transition on fault activation (2012)
    Elsevier Science Limited
    Details
    Publication Date: 2021-01-27
    Description: We model a fault cross-cutting the brittle upper crust and the ductile lower crust. In the brittle layer the fault is assumed to have stick–slip behaviour, whereas the lower ductile crust is inferred to deform in a steady-state shear. Therefore, the brittle–ductile transition (BDT) separates two layers with different strain rates and structural styles. This contrasting behaviour determines a stress gradient at the BDT that is eventually dissipated during the earthquake. During the interseismic period, along a normal fault it should form a dilated hinge at and above the BDT. Conversely, an over-compressed volume should rather develop above a thrust plane at the BDT. On a normal fault the earthquake is associated with the coseismic closure of the dilated fractures generated in the stretched hangingwall during the interseismic period. In addition to the shear stress overcoming the friction of the fault, the brittle fault moves when the weight of the hangingwall exceeds the strength of the dilated band above the BDT. On a thrust fault, the seismic event is instead associated with the sudden dilation of the previously over-compressed volume in the hangingwall above the BDT, a mechanism requiring much more energy because it acts against gravity. In both cases, the deeper the BDT, the larger the involved volume, and the bigger the related magnitude. We tested two scenarios with two examples from L’Aquila 2009 (Italy) and Chi-Chi 1999 (Taiwan) events. GPS data, energy dissipation and strain rate analysis support these contrasting evolutions. Our model also predicts, consistently with data, that the interseismic strain rate is lower along the fault segment more prone to seismic activation.
    Description: Published
    Description: 160-161
    Description: JCR Journal
    Description: open
    Keywords: faul activation ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics
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  • 58
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    Three-dimensional Moho topography in Italy: New constraints from receiver functions and controlled source seismology (2012)
    American Geophysical Union
    Details
    Publication Date: 2020-10-26
    Description: In complex tectonics regions, seismological, geophysical, and geodynamic modeling require accurate definition of the Moho geometry. Various active and passive seismic experiments performed in the central Mediterranean region revealed local information on the Moho depth, in some cases used to produce interpolated maps. In this paper, we present a new and original map of the 3-D Moho geometry obtained by integrating selected high-quality controlled source seismic and teleseismic receiver function data. The very small cell size makes the retrieved model suitable for detailed regional studies, crustal corrections in teleseismic tomography, advanced 3-D ray tracing in regional earthquake location, and local earthquake tomography. Our results show the geometry of three different Moho interfaces: the European, Adriatic-Ionian, and Tyrrhenian. The three distinct Moho are fashioned following the Alpine and Apennines subduction, collision, and back-arc spreading and show medium- to high-frequency topographic undulations reflecting the complexity of the geodynamic evolution.
    Description: Published
    Description: Q09006
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: JCR Journal
    Description: reserved
    Keywords: Italy; controlled source seismology; crust; receiver function ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics
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  • 59
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    Sulfur isotopic compositions of fumarolic and plume gases at Mount Etna (Italy) and inferences on their magmatic source (2012)
    American Geophysical Union
    Details
    Publication Date: 2017-04-03
    Description: Here we report new data on the sulfur isotopic compositions (d34S) of fumarolic and plume gases collected at Mount Etna volcano during 2008–2009. While low-temperature fumaroles are affected by postmagmatic processes that modify the pristine isotopic signature, high-temperature and plume gases allow establishment of a d34S range of 0 1‰ for magmatic SO2. We compared our data with those from S dissolved in primitive melt inclusions from 2002 lava and in whole rocks that erupted during the past two thousand years. Such a comparison revealed that d34S is systematically lower for magmatic gases than for sulfur dissolved in the melt. We modeled how isotopic fractionation due to magma degassing process may vary d34S value in both the melt and gaseous phases. This modeling required assessment of the fractionation factor (agas-melt). The most recent measurements on the oxidation state of sulfur in basaltic melt inclusions indicate that nearly all S is dissolved as sulfate (S6+), which would be possible in oxidized magmatic systems (DNNO ≥ 1). Under these conditions the exsolved gaseous phase is depleted with respect to the melt and the proposed model fits both gas and melt data, and constrains the Etnean magmatic d34S to 1.0 1.5‰. It is remarkable that the assessed redox conditions—which are significantly more oxidizing than previously thought—are able to explain why the dominant sulfur species measured in the Etnean plume is SO2.
    Description: Published
    Description: Q05015
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: restricted
    Keywords: Mount Etna ; SO2 ; degassing ; fumarole ; plume ; sulfur isotope ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 60
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    A pilot GIS database of active faults of Mt. Etna (Sicily): A tool for integrated hazard evaluation (2012)
    Elsevier Science Limited
    In:  Supplementary data associated with this article can be found in the online version, at http://dx.doi.org/10.1016/j.jvolgeores.2012.08. 013.
    Details
    Publication Date: 2017-04-04
    Description: A pilot GIS-based system has been implemented for the assessment and analysis of hazard related to active faults affecting the eastern and southern flanks of Mt. Etna. The system structure was developed in ArcGis® environment and consists of different thematic datasets that include spatially-referenced arc-features and associated database. Arc-type features, georeferenced into WGS84 Ellipsoid UTM zone 33 Projection, represent the five main fault systems that develop in the analysed region. The backbone of the GIS-based system is constituted by the large amount of information which was collected from the literature and then stored and properly geocoded in a digital database. This consists of thirty five alpha-numeric fields which include all fault parameters available from literature such us location, kinematics, landform, slip rate, etc. Although the system has been implemented according to the most common procedures used by GIS developer, the architecture and content of the database represent a pilot backbone for digital storing of fault parameters, providing a powerful tool in modelling hazard related to the active tectonics of Mt. Etna. The database collects, organises and shares all scientific currently available information about the active faults of the volcano. Furthermore, thanks to the strong effort spent on defining the fields of the database, the structure proposed in this paper is open to the collection of further data coming from future improvements in the knowledge of the fault systems. By layering additional user-specific geographic information and managing the proposed database (topological querying) a great diversity of hazard and vulnerability maps can be produced by the user. This is a proposal of a backbone for a comprehensive geographical database of fault systems, universally applicable to other sites.
    Description: Published
    Description: 170-186
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 3.2. Tettonica attiva
    Description: 4.3. TTC - Scenari di pericolosità vulcanica
    Description: 5.5. TTC - Sistema Informativo Territoriale
    Description: JCR Journal
    Description: reserved
    Keywords: GIS-based system ; Hazard assessment ; Volcano-tectonics ; Flank dynamics ; Georeferenced arc-features ; Active fault database ; 04. Solid Earth::04.01. Earth Interior::04.01.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.06. Rheology, friction, and structure of fault zones ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.06. Seismology::04.06.99. General or miscellaneous ; 04. Solid Earth::04.07. Tectonophysics::04.07.99. General or miscellaneous ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.05. Stress ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 05. General::05.08. Risk::05.08.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 61
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    An alternative model for the recent evolution of the Northern–Central Apennines (Italy) (2012)
    Elsevier Science Limited
    Details
    Publication Date: 2017-04-04
    Description: The aim of this paper is to propose an alternative model for the Pliocene-Quaternary to present evolution of the Northern–Central Apennines by combining geometrical requirements (Riedel shear system) with existing structural and geological geometries (fault systems and their tectonic associations). We define three sectors characterized by different geological, seismological, geodetic and geothermal signatures: the North-Western Sector (NWS), the Western Central Sector (WCS) and the Eastern Central Sector (ECS). According to GPS data derived from literature the three blocks move independently. In particular, the NWS is bound between the ECS/WCS and the Alps; this constraint leads to a stress accumulation responsible for a fragmentation into further several blocks, which move either to the NE or SW. The WCS is relatively stable; the ECS moves towards NE and is characterized by the presence of numerous releasing and restraining bends, which can be related to the action of a main NNW–SSE left-lateral shear zone. Accordingly, the recent and active tectonic setting of the Northern–Central Apennines is rather related to the dynamics of the introduced blocks, caused by the push of the African plate against Europe, than to subduction processes.
    Description: Published
    Description: 55-63
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: JCR Journal
    Description: restricted
    Keywords: Northern-Central Apennines ; Riedel shear system ; Strike slip ; Restraining and releasing bends ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 62
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    Soil gases and SAR measurements reveal hidden faults on the sliding flank of Mt. Etna (Italy) (2012)
    Elsevier Science Limited
    Details
    Publication Date: 2017-04-04
    Description: From October 2008 to November 2009, soil CO2, radon and structural field surveys were performed on Mt. Etna, in order to acquire insights into active tectonic structures in a densely populated sector of the south-eastern flank of the volcano, which is involved in the flank dynamics, as highlighted by satellite data (InSAR). The studied area extends about 150 km2, in a sector of the volcano where InSAR results detected several lineaments that were not well-defined from previous geological surveys. In order to validate and better constrain these features with ground data evidences, soil CO2 and soil radon measurements were performed along transects roughly orthogonal to the newly detected faults, with measurement points spaced about 100 m. In each transect, the highest CO2 values were found very close to the lineaments evidenced by InSAR observations. Anomalous soil CO2 and radon values were also measured at old eruptive fractures. In some portions of the investigated area soil gas anomalies were rather broad over transects, probably suggesting a complex structural framework consisting of several parallel volcano-tectonic structures, instead of a single one. Soil gas measurements proved particularly useful in areas at higher altitude on Mt. Etna (i.e. above 900 m asl), where InSAR results are not very informative/ are fairly limited, and allowed recognizing the prolongation of some tectonic lineaments towards the summit of the volcano. At a lower altitude on the volcanic edifice, soil gas anomalies define the active structures indicated by InSAR results prominently, down to almost the coastline and through the northern periphery of the city of Catania. Coupling InSARwith soil gas prospectingmethods has thus proved to be a powerful tool in detecting hidden active structures that do not show significant field evidences.
    Description: This work was funded by the DPC-INGV project “Flank”
    Description: Published
    Description: 27-40
    Description: 3.2. Tettonica attiva
    Description: JCR Journal
    Description: reserved
    Keywords: CO2 ; Radon ; InSAR ; Faults ; Etna ; Volcano-tectonics ; 04. Solid Earth::04.03. Geodesy::04.03.01. Crustal deformations ; 04. Solid Earth::04.03. Geodesy::04.03.07. Satellite geodesy ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 63
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    How do volcanic rift zones relate to flank instability? Evidence from collapsing rifts at Etna (2012)
    American Geophysical Union
    Details
    Publication Date: 2017-04-04
    Description: Volcanic rift zones, characterized by repeated dike emplacements, are expected to delimit the upper portion of unstable flanks at basaltic edifices. We use nearly two decades of InSAR observations excluding wintertime acquisitions, to analyze the relationships between rift zones, dike emplacement and flank instability at Etna. The results highlight a general eastward shift of the volcano summit, including the northeast and south rifts. This steadystate eastward movement (1-2 cm/yr) is interrupted or even reversed during transient dike injections. Detailed analysis of the northeast rift shows that only during phases of dike injection, as in 2002, does the rift transiently becomes the upper border of the unstable flank. The flank's steady-state eastward movement is inferred to result from the interplay between magmatic activity, asymmetric topographic unbuttressing, and east-dipping detachment geometry at its base. This study documents the first evidence of steady-state volcano rift instability interrupted by transient dike injection at basaltic edifices.
    Description: Partially funded by INGV and the Italian DPC (DPC-INGV project V4 “Flank”). ERS and ENVISAT SAR data were provided by ESA through the Cat-1 project no. 4532 and the GEO Supersite initiative. The DEM was obtained from the SRTM archive. ERS-1/2 orbits are courtesy of the TU-Delft, The Netherlands. SAR data processing has been done at IREACNR, partially carried out under contract “Volcanic Risk System (SRV)” funded by the Italian Space Agency (ASI).
    Description: Published
    Description: L20311
    Description: 1.3. TTC - Sorveglianza geodetica delle aree vulcaniche attive
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 1.10. TTC - Telerilevamento
    Description: 3.2. Tettonica attiva
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: 3.6. Fisica del vulcanismo
    Description: 4.3. TTC - Scenari di pericolosità vulcanica
    Description: JCR Journal
    Description: restricted
    Keywords: flank instability ; rift zones ; 04. Solid Earth::04.03. Geodesy::04.03.99. General or miscellaneous ; 04. Solid Earth::04.03. Geodesy::04.03.01. Crustal deformations ; 04. Solid Earth::04.03. Geodesy::04.03.06. Measurements and monitoring ; 04. Solid Earth::04.03. Geodesy::04.03.07. Satellite geodesy ; 04. Solid Earth::04.03. Geodesy::04.03.09. Instruments and techniques ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.06. Rheology, friction, and structure of fault zones ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.07. Tectonophysics::04.07.99. General or miscellaneous ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.05. Stress ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.08. Risk::05.08.99. General or miscellaneous
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  • 64
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    Upper mantle structure below the European continent: Constraints from surface-wave tomography and GRACE satellite gravity data (2012)
    American Geophysical Union
    Details
    Publication Date: 2017-04-04
    Description: We here exploit fundamental mode Rayleigh and Love seismic wave information and the high resolution satellite global gravity model GGM02C to obtain a 1° × 1° 3-D image of: (a) upper-mantle isotropic shear-wave speeds; (b) densities; and (c) density-vS coupling below the European plate (20°N–90°N) (40°W–70°E). The 3-D image of the density-vS coupling provides unprecedented detail of information on the compositional and thermal contributions to density structures. The accurate and high-resolution crustal model allows us to compute a reliable residual topography to understand the dynamic implications of our models. The correlation between residual topography and mantle residual gravity anomalies defines three large-scale regions where upper mantle dynamics produce surface expression: the East European Craton; the eastern side of the Arabian Plate; and the Mediterranean Basin. The effects of mantle convection are also clearly visible at: (1) the Eastern Sirt Embayment; (2) the West African Craton northern margins; (3) the volcanically active region of the Canarian Archipelago; (4) the northern edge of the Central European Volcanic Province; and (5) the Northeastern part of the Atlantic Ocean, between Greenland and Iceland. Strong connections are observed among areas of weak radial anisotropy and areas where the mantle dynamics show surface expression. Although both thermal and additional dependencies have been incorporated into the density model, convective down-welling in the mantle below the East European Craton is required to explain the strong correlation between the estimated negative mantle residual anomalies and the negative residual topography.
    Description: DATEC MERG-CT-2007-046522 and NERIES INFRAST-2.1-026130
    Description: Published
    Description: B09401
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: JCR Journal
    Description: restricted
    Keywords: Europe ; GRACE ; density-velocity scaling relationship ; dynamic topography ; surface waves ; upper mantle density ; 04. Solid Earth::04.01. Earth Interior::04.01.01. Composition and state ; 04. Solid Earth::04.03. Geodesy::04.03.03. Gravity and isostasy ; 04. Solid Earth::04.06. Seismology::04.06.07. Tomography and anisotropy ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 05. General::05.01. Computational geophysics::05.01.03. Inverse methods
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  • 65
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    An overview of experimental models to understand a complex volcanic instability: Application to Mount Etna, Italy (2012)
    Elsevier Science Limited
    Details
    Publication Date: 2017-04-04
    Description: Volcanic edifices are often unable to support their own load, triggering the instability of their flanks. Many analogue models have been aimed, especially in the last decade, at understanding the processes leading to volcano flank instability; general behaviors were defined and the experimental results were compared to nature. However, available data at well-studied unstable volcanoes may allow a deeper understanding of the specific processes leading to instability, providing insights also at the local scale. Etna (Italy) constitutes a suitable example for such a possibility, because of its well-monitored flank instability, for which different triggering factors have been proposed in the last two decades. Among these factors, recent InSAR data highlight the role played by magmatic intrusions and a weak basement, under a differential unbuttressing at the volcano base. This study considers original and recently published experimental data to test these factors possibly responsible for flank instability, with the final aim to better understand and summarize the conditions leading to flank instability at Etna. In particular, we simulate the following processes: a) the longterm activity of a lithospheric boundary, as the Malta Escarpment, separating the Ionian oceanic lithosphere from the continental Sicilian lithosphere, below the most unstable east flank of the volcano; b) spreading due to a weak basement, with different boundary conditions; c) the pressurization of a magmatic reservoir, as that active during the 1994–2001 inflation period; d) dike emplacement, as observed during the major 2001 and 2002–2003 eruptions. The experimental results suggest that: 1) the long-term activity of a lithospheric tectonic boundary may create a topographic slope which provides a differential buttressing at the volcano base, a preparing factor to drive longer-term (〉105 years) instability on the east flank of the volcano; 2) volcano spreading (b104 years) has limited effect on flank instability at Etna; 3) magmatic intrusions (b101 years), both in the form of Mogi-like sources or dikes, provide the most important conditions to trigger flank instability on the shorter-term.
    Description: Thisworkwas partially funded by INGV and the Italian DPC (DPC-INGV project V4 “Flank”).
    Description: Published
    Description: 98-111
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 3.2. Tettonica attiva
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: 3.6. Fisica del vulcanismo
    Description: JCR Journal
    Description: reserved
    Keywords: volcano instability ; analogue modeling ; Etna ; unbuttressing ; 04. Solid Earth::04.01. Earth Interior::04.01.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.06. Rheology, friction, and structure of fault zones ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.07. Tectonophysics::04.07.99. General or miscellaneous ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.05. Stress ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.02. Experimental volcanism ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 66
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    Evidence for a recent change in the shallow plumbing system of Mt. Etna (Italy): Gas geochemistry and structural data during 2001–2005 (2012)
    Elsevier Science Limited
    Details
    Publication Date: 2017-04-04
    Description: We analyzed crater SO2 fluxes from Mt Etna, together with soil CO2 effluxes from the volcano's flanks, in the period from 2001 to 2005. Between the 2001 and 2002–2003 eruptions, persistently low values of both parameters suggest that no new gas-rich magma was accumulating at shallow depth (b5 km) within Etna's central conduit, whereas very high SO2 sin-eruptive fluxes during the two eruptions indicated sudden decompression of an un-degassed magma rising along newly-formed eccentric conduits. In November 2003, soil CO2 data indicate migration of gas-rich magma from deep (〉10 km) to shallow (b5 km) portions of the feeding conduits, preceded by an increase in crater SO2 fluxes. A similar behavior was observed also during and after the following 2004–2005 eruption. This degassing style matches a period of increased structural instability of the volcanic edifice caused by acceleration of spreading that affected both its eastern and southern flanks. Spreading could have triggered progressively deeper depressurization in the central conduit, inducing release of the more soluble gas (SO2) first, and then of CO2, contrary to what was observed before the 2001 eruption. This suggests that the edifice has depressurized, promoting ascent of fresh-magma and increasing permeability favouring release of CO2 flux. By integrating geochemical and structural data, previous degassing models developed at Mt. Etna have been updated to advance the understanding of eruptive events that occurred in recent years.
    Description: This work was funded by grants from the Istituto Nazionale di Geofisica e Vulcanologia (INGV) and from the Dipartimento per la Protezione Civile (Italy).
    Description: Published
    Description: 90-97
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: 3.6. Fisica del vulcanismo
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: reserved
    Keywords: Geochemical modeling ; volcano monitoring ; volcanic gases ; Tectonics and magmatism ; flank collapse ; 04. Solid Earth::04.01. Earth Interior::04.01.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.07. Tectonophysics::04.07.99. General or miscellaneous ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.05. Stress ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.04. Thermodynamics ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 05. General::05.08. Risk::05.08.99. General or miscellaneous
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  • 67
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    Influence of volcanic gases on the epidermis of Pinus halepensis Mill. in Campi Flegrei, Southern Italy: A possible tool for detecting volcanism in present and past floras (2012)
    Elsevier Science Limited
    Details
    Publication Date: 2017-04-04
    Description: Cuticle micromorphology together with epidermal and epistomatal wax, in both current- and first-year-old needles of conifer Pinus halepensis (Aleppo pine) trees growing under volcanic gas fumigation was analysed in Pisciarelli area, Campi Flegrei, Southern Italy. As a control, current- and first-year-old needles growing far from volcanic gas emission were also sampled. Using a multidisciplinary approach with SEM, TEM and X-ray, volcanic gases were shown to cause degradation on epicuticular and epistomatal waxes. Significant statistical variations of ultrastructural components of the cuticle, with 30 measurements, including total thickness of the cuticle, and details and proportions of all different layers, and use of confidence interval, revealed a high degree of sensitivity of Aleppo pine to this extreme environment. In the present study, non-significant thickness variations of the cell wall plus cuticle among current- and first-year-old needles of both fumigated and non fumigated trees have been found. However, at the ultrastructural level, significant variations in cell wall and total cuticle thickness, especially within the three zones of B1 fibrillar layer, revealed different equilibria for each of the four types of material. Using energy dispersive X-ray microanalysis, no sulphur was found in either cuticle or epidermal cells, but the presence of H2S in the fumarole gas is suspected to cause indirect and/or direct cuticle alterations of wax structure. Ultrastructural characters of plant cuticles related to emission of volcanic gases during the geological past are also discussed. Among these considerations, an identification key enabling distinction between non fumigated and fumigated materials with 9 characters, provides a good tool detecting the influence of volcanism for extant and fossil plants.
    Description: Published
    Description: 1–17
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: Campi Flegrei ; Volcanic gases ; Pinus halepensis ; Hydrogen sulphide (H2S) ; 04. Solid Earth::04.03. Geodesy::04.03.06. Measurements and monitoring ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
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  • 68
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    Insights from fumarole gas geochemistry on the origin of hydrothermal fluids on the Yellowstone Plateau (2012)
    Elsevier Science Limited
    Details
    Publication Date: 2017-04-04
    Description: The chemistry of Yellowstone fumarole gases shows the existence of two component waters, type MC, influenced by the addition of deep mantle fluid, and type CC, influenced by crustal interactions (CC). MC is high in 3He/4He (22 Ra) and low in 4He/40Ar ( 1), reflecting input of deep mantle components. The other water is characterized by 4He concentrations 3–4 orders of magnitude higher than air-saturated meteoric water (ASW). These high He concentrations originate through circulation in Pleistocene volcanic rocks, as well as outgassing of Tertiary and older (including Archean) basement, some of which could be particularly rich in uranium, a major 4He source. Consideration of CO2–CH4–CO–H2O–H2 gas equilibrium reactions indicates equilibration temperatures from 170 C to 310 C. The estimated temperatures highly correlate with noble-gas variations, suggesting that the two waters differ in temperature. Type CC is 170 C whereas the MC is hotter, at 340 C. This result is similar to models proposed by previous studies of thermal water chemistry. However, instead of mixing the deep hot component simply with cold, meteoric waters we argue that addition of a 4He-rich component, equilibrated at temperatures around 170 C, is necessary to explain the range in fumarole gas chemistry.
    Description: Published
    Description: 265–278
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: hydrothermal fluids ; Yellowstone Plateau ; 04. Solid Earth::04.03. Geodesy::04.03.06. Measurements and monitoring ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
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  • 69
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    Evidence of a recent rapid subsidence in the S–E Cyclades (Greece): An effect of the 1956 Amorgos earthquake? (2012)
    Elsevier Science Limited
    Details
    Publication Date: 2022-11-23
    Description: An underwater geomorphological survey along the coasts of six Cycladic islands (Sifnos, Antiparos, Paros, Naxos, Iraklia and Keros) revealed widespread evidence of a recent 30–40 cm submergence, part of which may have seismic origin. Comparison with information reported from earthquakes having affected the area suggests that at least part of the recent submergence might be an effect of the 1956 Amorgos earthquake. Modelling of the co-seismic and short-term post-seismic effects of the earthquake revealed that part of the observed subsidence may be explained in some of the islands by a fast post-seismic relaxation of a low-viscosity layer underlying the seismogenic zone. However far-field observations are underestimated by our model, and may be affected by a wider deformation field induced by the largest aftershock of the Amorgos sequence, or by other earthquakes.
    Description: Published
    Description: 27-40
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: JCR Journal
    Description: restricted
    Keywords: tidal notch ; sea level change ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics
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  • 70
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    Topography of the Calabria subduction zone (southern Italy): Clues for the origin of Mt. Etna (2011)
    American Geophysical Union
    Details
    Publication Date: 2012-02-03
    Description: Calabria represents an ideal site to analyze the topography of a subduction zone as it is located on top of a narrow active Wadati-Benioff zone and shows evidence of rapid uplift. We analyzed a pattern of surface deformation using elevation data with different filters and showed the existence of a long wavelength (〉100 km) relatively positive topographic signal at the slab edges. The elevation of MIS 5.5 stage marine terraces supports this pattern, although the record is incomplete and partly masked by the variable denudation rate. We performed structural analyses along the major active or recently reactivated normal faults showing that the extensional direction varies along the Calabrian Arc and laterally switches from arc-normal, within the active portion of the slab, to arc-oblique or even arc-parallel, along the northern and southern slab edges. This surface deformation pattern was compared with a recent high resolution P wave tomographic model showing that the high seismic velocity anomaly is continuous only within the active Wadati-Benioff zone, whereas the northern and southwestern sides are marked by low velocity anomalies, suggesting that large-scale topographic bulges, volcanism, and uplift could have been produced by mantle upwelling. We present numerical simulations to visualize the three-dimensional mantle circulation around a narrow retreating slab, ideally similar to the one presently subducting beneath Calabria. We emphasize that mantle upwelling and surface deformation are expected at the edges of the slab, where return flows may eventually drive decompression melting and the Mount Etna volcanism.
    Description: Published
    Description: TC1003
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: JCR Journal
    Description: reserved
    Keywords: topography ; Calabrian Arc ; subduction ; tomography ; mantle flow ; uplift ; retreat ; anisotropy ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 71
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    Seismotectonic features from accurate hypocentre locations in southern central Andes (western Argentina) (2011)
    Elsevier Science Limited
    Details
    Publication Date: 2017-04-04
    Description: A local seismic network, over a five-year period, recorded about 450 earthquakes in western Argentina. In this region, the geodynamics is controlled by the subduction of the Nazca plate beneath the South American lithosphere, which is characterised here by a sub-horizontal path before reassuming its downward descent. As accurate earthquake locations are of primary importance when studying the seismicity of a given area, events recorded by the local seismic network enable in-depth investigations into seismo-tectonic patterns, allowing to improve the earthquake source characterization and knowledge on the ongoing seismo-tectonics of the region. To this end, we performed a simultaneous 1-D inversion of both the velocity structure and the hypocentre location. The minimum 1-D model obtained is complemented by station corrections which lead to a first insight into the deeper 3-D structure. In addition, stability tests were performed to verify the robustness of our earthquake location results. They reveal a fairly stable hypocentre determination, demonstrating that the locations obtained by the inversion process are not systematically biased. The results show that Sierra Pie de Palo is characterised by a crustal seismogenic structure, dipping west and extending from its eastern boundary to about 30 km of depth. The study also provided new constraints on the geometry of the subducted slab. We noted a great concentration of shallower seismicity compared to that of the surrounding areas of the Wadati-Benioff zone, at the expected position of the Juan Fernandez Ridge (JFR). Our hypocentres indicate that JFR certainly influences the subduction style along its strike, leading to the formation of a bend in the slab geometry.
    Description: Published
    Description: 44-54
    Description: 3.2. Tettonica attiva
    Description: JCR Journal
    Description: restricted
    Keywords: Minimum 1-D velocity model ; high precision earthquake location ; seismogenic structure ; flat-slab subduction ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 72
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    U-Pb and 40Ar-39Ar geochronology of Palaeozoic units in the northern Apennines: determining protolith age and alpine evolution using the Calamita Schist and Ortano Porphyroid (2011)
    Wiley
    Details
    Publication Date: 2017-04-04
    Description: In the northern Apennines, the Palaeozoic basement involved in the Late Oligocene–Middle Miocene nappe stack contains metamorphic units for which hypothetical ages have been assigned on the basis of lithological correlations with the Palaeozoic formations of the Variscan chain in Sardinia. This uncertainty concerning the age poses limitations to reconstructing the Palaeozoic stratigraphy, defining the Alpine and pre-Alpine histories and correlations with other domains of the Variscan chain. We present the U-Pb age of detrital zircon and the 40Ar-39Ar age of metamorphic muscovite for the Calamita Schist and Ortano Porphyroid, two metamorphic units of undetermined Palaeozoic age cropping out in the eastern Elba Island. The radioisotopic data allows us to: (i) define the Early Carboniferous and Middle Ordovician ages for the Calamita Schist and Ortano Porphyroid, respectively, as well as their derivation (flysch deposit and magmatic rocks); (ii) pose some constraints concerning their alpine tectonic and metamorphic histories. These new data generate a more precise reconstruction of the Palaeozoic sequence in the northern Apennines, and they document that the Palaeozoic basement involved in the alpine deformation underwent internal stacking with an inversion of the original sequence.
    Description: In press
    Description: 3.2. Tettonica attiva
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: JCR Journal
    Description: reserved
    Keywords: northern Apennines ; Palaeozoic basement ; U-Pb zircon ; 40Ar-39Ar muscovite ; 04. Solid Earth::04.04. Geology::04.04.02. Geochronology ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 73
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    Long term variations of the Campi Flegrei (Italy) volcanic system as revealed by the monitoring of hydrothermal activity (2010)
    American Geophysical Union
    Details
    Publication Date: 2017-04-04
    Description: Long duration time-series of the chemical composition of fumaroles and of soil CO2 flux reveal that important variations in the activity of the Solfatara fumarolic field, the most important hydrothermal site of Campi Flegrei, occurred in the 2000-2008 period. A continuous increase of the CO2 concentrations, and a general decrease of the CH4 concentrations are interpreted as the consequence of the increment of the relative amount of magmatic fluids, rich in CO2 and poor in CH4, hosted by the hydrothermal system. Contemporaneously, the H2O-CO2-He-N2 gas system shows remarkable compositional variations in the samples collected after July 2000 with respect to the previous ones, indicating the progressive arrival at the surface of a magmatic component different from that involved in the 1983-84 episode of volcanic unrest (1983-1984 bradyseism). The change starts in 2000 concurrently with the occurrence of relatively deep, long-period seismic events which were the indicator of the opening of an easy-ascent pathway for the transfer of magmatic fluids towards the shallower, brittle domain hosting the hydrothermal system. Since 2000, this magmatic gas source is active and causes ground deformations, seismicity as well as the expansion of the area affected by soil degassing of deeply derived CO2. Even though the activity will most probably be limited to the expulsion of large amounts of gases and thermal energy, as observed in other volcanoes and in the past activity of Campi Flegrei, the behavior of the system in the future is, at the moment, unpredictable.
    Description: Published
    Description: B03205
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: reserved
    Keywords: Campi Flegrei ; CO2 ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
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  • 74
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    Anatomy of an unstable volcano from InSAR: Multiple processes affecting flank instability at Mt. Etna, 1994–2008 (2010)
    American Geophysical Union
    Details
    Publication Date: 2012-02-03
    Description: An edited version of this paper was published by AGU. Copyright (2010) American Geophysical Union.
    Description: Volcano deformation may occur under different conditions. To understand how a volcano deforms, as well as relations with magmatic activity, we studied Mt. Etna in detail using interferometric synthetic aperture radar (InSAR) data from 1994 to 2008. From 1994 to 2000, the volcano inflated with a linear behavior. The inflation was accompanied by eastward and westward slip on the eastern and western flanks, respectively. The portions proximal to the summit showed higher inflation rates, whereas the distal portions showed several sectors bounded by faults, in some cases behaving as rigid blocks. From 2000 to 2003, the deformation became nonlinear, especially on the proximal eastern and western flanks, showing marked eastward and westward displacements, respectively. This behavior resulted from the deformation induced by the emplacement of feeder dikes during the 2001 and 2002–2003 eruptions. From 2003 to 2008, the deformation approached linearity again, even though the overall pattern continued to be influenced by the emplacement of the dikes from 2001 to 2002. The eastward velocity on the eastern flank showed a marked asymmetry between the faster sectors to the north and those (largely inactive) to the south. In addition, from 1994 to 2008 part of the volcano base (south, west, and north lower slopes) experienced a consistent trend of uplift on the order of ∼0.5 cm/yr. This study reveals that the flanks of Etna have undergone a complex instability resulting from three main processes. In the long term (103–104 years), the load of the volcano is responsible for the development of a peripheral bulge. In the intermediate term (≤101 years, observed from 1994 to 2000), inflation due to the accumulation of magma induces a moderate and linear uplift and outward slip of the flanks. In the short term (≤1 year, observed from 2001 to 2002), the emplacement of feeder dikes along the NE and south rifts results in a nonlinear, focused, and asymmetric deformation on the eastern and western flanks. Deformation due to flank instability is widespread at Mt. Etna, regardless of volcanic activity, and remains by far the predominant type of deformation on the volcano.
    Description: ESA provided the SAR data (Cat‐1 no. 4532 and GEO Supersite initiative). The DEM was obtained from the SRTM archive, while the ERS‐1/2 orbits are courtesy of the TU‐Delft, The Netherlands. This work was partially funded by INGV and the Italian DPC (DPCINGV project V4 “Flank”), the Italian DPC (under special agreement with IREA‐CNR), and the Italian Space Agency under contract “sistema rischio vulcanico (SRV).” The authors thank Francesco Casu, Paolo Berardino, and Riccardo Lanari for their support and Geoff Wadge and Michael Poland for their helpful and constructive review of the manuscript.
    Description: Published
    Description: B10405
    Description: 1.3. TTC - Sorveglianza geodetica delle aree vulcaniche attive
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 1.10. TTC - Telerilevamento
    Description: 3.2. Tettonica attiva
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: 3.6. Fisica del vulcanismo
    Description: 4.3. TTC - Scenari di pericolosità vulcanica
    Description: JCR Journal
    Description: reserved
    Keywords: Flank instability ; InSAR ; volcanoes ; Etna ; 04. Solid Earth::04.01. Earth Interior::04.01.99. General or miscellaneous ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes ; 04. Solid Earth::04.02. Exploration geophysics::04.02.99. General or miscellaneous ; 04. Solid Earth::04.03. Geodesy::04.03.99. General or miscellaneous ; 04. Solid Earth::04.03. Geodesy::04.03.06. Measurements and monitoring ; 04. Solid Earth::04.03. Geodesy::04.03.07. Satellite geodesy ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.06. Rheology, friction, and structure of fault zones ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.07. Tectonophysics::04.07.99. General or miscellaneous ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.05. Stress ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions ; 05. General::05.04. Instrumentation and techniques of general interest::05.04.99. General or miscellaneous ; 05. General::05.08. Risk::05.08.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 75
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    CO2/CH4 ratio in fumaroles a powerful tool to detect magma degassing episodes at quiescent Volcanoes (2010)
    American Geophysical Union
    Details
    Publication Date: 2017-04-04
    Description: Long time series of fumarolic compositions at Campi Flegrei (Italy), Mammoth Mountain (California), Panarea (Italy) and Nisyros (Greece) show rapid increases, up to orders of magnitude, of the CO2/CH4 ratio systematically with the occurrence of volcanic unrest periods. These easily detected anomalies originate with the arrival of CH4-poor magmatic fluids in the shallower levels of the volcanoes. The data suggest that volcanoes are characterized by magmatic activity at depth also in periods of apparent quiescence. The activity is constituted by the pulsing release of large amount of fluids which either cause unrest periods (seismicity and ground deformation) or possibly could precede volcanic eruption. This type of volcanic activity can be monitored trough the classical geophysical techniques together with the systematic sampling and analysis of fumaroles.
    Description: Published
    Description: L02302
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: reserved
    Keywords: CO2/CH4 ; magma degassing ; quiescent volcanoes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 76
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    Unknown
    Active tectonics in Northern Victoria Land (Antarctica) inferred from the integration of GPS data and geologic setting. (2010)
    American Geophysical Union
    Details
    Publication Date: 2017-04-04
    Description: Accepted for publication in Journal of Geophysical Research. Copyright (2010) American Geophysical Union.
    Description: A semi-permanent global positioning system (GPS) network of 30 vertices known as the Victoria Land Network for Deformation Control (VLNDEF) was set-up in the Austral summer of 1998 in Northern Victoria Land (NVL), including Terra Nova Bay (TNB), Antarctica. The locations were selected according to the known Cenozoic fault framework that is characterized by a system of NW-SE regional faults with right-lateral, strike-slip kinematics. The TNB1 permanent GPS station is within the VLNDEF, and following its installation on a bedrock monument in October 1998 it has been recording almost continuously. The GPS network has been surveyed routinely every two summers, using high-quality, dual-frequency GPS receivers. In this study, we present the results of a distributed session approach applied to the processing of the GPS data of the VLNDEF. An improved reference frame definition was implemented, including a new Euler pole, to compute the Antarctic intra-plate residual velocities. The projection of the residual velocities on the main faults in NVL show present-day activities for some faults, including the Tucker, Leap Year, Lanterman, Aviator, and David faults, with rightlateral strike-slip kinematics and local extensional/ compressional components. This active fault pattern divides NVL into eight rigid blocks, each characterized by their relative movements and rigid rotations. These show velocities of up to several mm/yr, which are comparable to those predicted by plate tectonic theory at active plate margins.
    Description: All researches were carried out in the framework of the Programma Nazionale di Ricerche in Antartide (PNRA) and financially supported by PNRA S.C.r.l.
    Description: Published
    Description: B12421
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: JCR Journal
    Description: reserved
    Keywords: ANTARCTICA ; GEODESY ; MONITORING NETWORKS ; CRUSTAL DEFORMATION ; CONTINENTAL NEOTECTONICS ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics
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  • 77
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    Unknown
    Tectonic evidence for the ongoing Africa-Eurasia convergence in central Mediterranean foreland areas: A journey among long-lived shear zones, large earthquakes, and elusive fault motions. (2010)
    American Geophysical Union
    Details
    Publication Date: 2017-04-04
    Description: An edited version of this paper was published by AGU. Copyright (2010) American Geophysical Union
    Description: We investigate the role of the Africa-Eurasia convergence in the recent tectonic evolution of the central Mediterranean. To this end we focused on two sectors of the Adriatic-Hyblean foreland of the Apennine-Maghrebian chain as they allow tectonic evidence for relative plate motions to be analyzed aside from the masking effect of other more local tectonic phenomena (e.g., subduction, chain building, etc.). We present a thorough review of data and interpretations on two major shear zones cutting these foreland sectors: the E-W Molise-Gondola in central Adriatic and the N-S Vizzini-Scicli in southern Sicily. The selected foreland areas exhibit remarkable similarities, including an unexpectedly high level of seismicity and the presence of the investigated shear zones since the Mesozoic. We analyze the tectonic framework, active tectonics, and seismicity of each of the foreland areas, highlighting the evolution of the tectonic understanding. In both areas, we find that current strains at midcrustal levels seem to respond to the same far-field force oriented NNW-SSE to NW-SE, similar to the orientation of the Africa-Eurasia convergence. We conclude that this convergence plays a primary role in the seismotectonics of the central Mediterranean and is partly accommodated by the reactivation of large Mesozoic shear zones.
    Description: The work has been funded by project “Sviluppo Nuove Tecnologie per la Protezione e Difesa del Territorio dai Rischi Naturali,” by the Italian Ministry of Education and Research (MIUR), and by the Italian Presidenza del Consiglio dei Ministri – Dipartimento della Protezione Civile (DPC).
    Description: Published
    Description: B12404
    Description: 3.2. Tettonica attiva
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: JCR Journal
    Description: partially_open
    Keywords: Molise-Gondola shear zone ; Vizzini-Scicli shear zone ; Gargano Promontory ; Hyblean Plateau ; slip reversal ; 1627 earthquake ; 1693 earthquake ; 04. Solid Earth::04.03. Geodesy::04.03.01. Crustal deformations ; 04. Solid Earth::04.04. Geology::04.04.01. Earthquake geology and paleoseismology ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.04. Plate boundaries, motion, and tectonics ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 78
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    Detachment depth revealed by rollover deformation: An integrated approach at Mount Etna (2010)
    American Geophysical Union
    Details
    Publication Date: 2017-04-04
    Description: Flank instability is common at volcanoes, even though the subsurface structures, including the depth to a detachment fault, remain poorly constrained. Here, we use a multidisciplinary approach, applicable to most volcanoes, to evaluate the detachment depth of the unstable NE flank of Mt. Etna. InSAR observations of Mount Etna during 1995–2008 show a trapdoor subsidence of the upper NE flank, with a maximum deformation against the NE Rift. The trapdoor tilt was highest in magnitude in 2002–2004, contemporaneous with the maximum rates of eastward slip along the east flank. We explain this deformation as due to a general eastward displacement of the flank, activating a rotational detachment and forming a rollover anticline, the head of which is against the NE Rift. Established 2D rollover construction models, constrained by morphological and structural data, suggest that the east‐dipping detachment below the upper NE flank lies at around 4 km below the surface. This depth is consistent with seismicity that clusters above 2–3 km below sea level. Therefore, the episodically unstable NE flank lies above an east‐dipping rotational detachment confined by the NE Rift and Pernicana Fault. Our approach, which combines short‐term (InSAR) and long‐term (geological) observations, constrains the 3D geometry and kinematics of part of the unstable flank of Etna and may be applicable and effective to understand the deeper structure of volcanoes undergoing flank instability or unrest.
    Description: This work was partially funded by INGV and the DPC‐INGV project “Flank”, and partially by the ASI (SRV project).
    Description: Published
    Description: L16304
    Description: 1.3. TTC - Sorveglianza geodetica delle aree vulcaniche attive
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 1.10. TTC - Telerilevamento
    Description: 3.2. Tettonica attiva
    Description: 4.3. TTC - Scenari di pericolosità vulcanica
    Description: JCR Journal
    Description: reserved
    Keywords: flank instability ; fault ; InSAR ; Etna ; rollover ; 04. Solid Earth::04.01. Earth Interior::04.01.99. General or miscellaneous ; 04. Solid Earth::04.02. Exploration geophysics::04.02.99. General or miscellaneous ; 04. Solid Earth::04.03. Geodesy::04.03.99. General or miscellaneous ; 04. Solid Earth::04.03. Geodesy::04.03.06. Measurements and monitoring ; 04. Solid Earth::04.03. Geodesy::04.03.07. Satellite geodesy ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.06. Rheology, friction, and structure of fault zones ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.04. Geology::04.04.11. Instruments and techniques ; 04. Solid Earth::04.06. Seismology::04.06.99. General or miscellaneous ; 04. Solid Earth::04.07. Tectonophysics::04.07.99. General or miscellaneous ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.05. Stress ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.08. Risk::05.08.99. General or miscellaneous
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  • 79
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    Deformation and eruptions at Mt. Etna (Italy): A lesson from 15 years of observations (2009)
    American Geophysical Union
    Details
    Publication Date: 2017-04-04
    Description: Volcanoes deform as a consequence of the rise and storage of magma; once magma reaches a critical pressure, an eruption occurs. However, how the edifice deformation relates to its eruptive behavior is poorly known. Here, we produce a joint interpretation of spaceborne InSAR deformation measurements and volcanic activity at Mt. Etna (Italy), between 1992 and 2006. We distinguish two volcano-tectonic behaviors. Between 1993 and 2000, Etna inflated with a starting deformation rate of 1 cm yr 1 that progressively reduced with time, nearly vanishing between 1998 and 2000; moreover, low-eruptive rate summit eruptions occurred, punctuated by lava fountains. Between 2001 and 2005, Etna deflated, feeding higher-eruptive rate flank eruptions, along with large displacements of the entire East-flank. These two behaviors, we suggest, result from the higher rate of magma stored between 1993 and June 2001, which triggered the emplacement of the dike responsible for the 2001 and 2002–2003 eruptions. Our results clearly show that the joint interpretation of volcano deformation and stored magma rates may be crucial in identifying impending volcanic eruptions.
    Description: This work was partly funded by INGV and the Italian DPC and was supported by ASI, the Preview Project and CRdC-AMRA. DPC-INGV Flank project providing the funds for the publication fees.
    Description: Published
    Description: L02309
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 1.10. TTC - Telerilevamento
    Description: 3.6. Fisica del vulcanismo
    Description: 4.3. TTC - Scenari di pericolosità vulcanica
    Description: 4.5. Degassamento naturale
    Description: JCR Journal
    Description: partially_open
    Keywords: deformation ; eruptions ; Mt. Etna ; eruptive cycle ; InSAR ; 04. Solid Earth::04.01. Earth Interior::04.01.99. General or miscellaneous ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes ; 04. Solid Earth::04.03. Geodesy::04.03.99. General or miscellaneous ; 04. Solid Earth::04.03. Geodesy::04.03.06. Measurements and monitoring ; 04. Solid Earth::04.03. Geodesy::04.03.07. Satellite geodesy ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.07. Tectonophysics::04.07.99. General or miscellaneous ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 80
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    Recent extension driven by mantle upwelling beneath the Admiralty Mountains (East Antarctica) (2008)
    American Geophysical Union
    Details
    Publication Date: 2021-01-27
    Description: Northern Victoria Land is located at the boundary between an extended, presumably hot, region (West Antarctic Rift System) and the thick, possibly cold, East Antarctic craton. The style and timing of Tertiary deformation along with relationships with the magmatic activity are still unclear, and contrasting models have been proposed. We performed structural and morphotectonic analyses at the NE termination of northern Victoria Land in the Admiralty Mountains area, where the relationship between topography, tectonics, and magmatism is expected to be well pronounced. We found evidence of two subsequent episodes of faulting, occurring concurrently with the Neogene McMurdo volcanism. The first episode is associated with dextral transtension, and it is overprinted by extensional tectonics during the emplacement of large shield alkaline volcanoes. Upper mantle seismic tomography shows that the extensional regime is limited to regions overlying a low-velocity anomaly. We interpret this anomaly to be of thermal origin, and have tested the role of largescale upwelling on lithosphere deformation in the area. The results of this integrated analysis suggest that the morphotectonic setting of the region and the magmatism is likely the result of upwelling flow at the boundary between the cold cratonic and the hot stretched province (WARS), at work until recent time in this portion of the northern Victoria Land.
    Description: Published
    Description: TC4015
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: JCR Journal
    Description: partially_open
    Keywords: Antarctica ; Admiralty Mountains ; Extensional Tectonics ; Mantle Upwelling ; Seismic Tomography ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 81
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    Continuous monitoring of soil CO2 flux on Mt. Etna:The 2004–2005 eruption and the role of regional tectonics and volcano tectonics. (2008)
    American Geophysical Union
    Details
    Publication Date: 2017-04-04
    Description: The soil CO2 flux on Mt. Etna as recorded by the ETNAGAS network (an automatic system for measuring soil CO2 flux and meteorological parameters) started to increase strongly about 5 months prior to the onset of the 2004–2005 eruption and decreased a few months before the end of the eruption. Time delays in the occurrences of anomalies in soil CO2 flux at different sites in the geochemical network constrain the relationship between soil CO2 flux distributions and the tectonic framework of Etna volcano. The anomalies observed before the 2004–2005 eruption support the intrusion of new undegassed magma into the upper feeding system of the volcano (〈20 km below sea level). Magma subsequently rose slowly in the volcano conduits, thereby triggering the onset of the 2004–2005 eruption. The time delays in the occurrences of anomalies in combination with spectral analysis indicate the importance of tectonic and volcanotectonic structures in driving the ascent of deep gases within the crust. Moreover, greatest amplitude pulsations of the low-frequency components of the CO2 flux signals were correlated with the paroxystic activities of the 2004–2005 eruption. This study confirms that CO2 flux variation is a useful indicator for volcanic activity in the surveillance of the Mt. Etna and similar basaltic volcanoes.
    Description: Dipartimento Protezione Civile Ministero degli Interni
    Description: Published
    Description: B09206
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: JCR Journal
    Description: reserved
    Keywords: CO2 flux ; Continuous monitoring of soil CO2 flux ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
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    Unmanned aerial vehicle measurements of volcanic carbon dioxide fluxes (2008)
    American Geophysical Union
    Details
    Publication Date: 2017-04-04
    Description: We report the first measurements of volcanic gases with an unmanned aerial vehicle (UAV). The data were collected at La Fossa crater, Vulcano, Italy, during April 2007, with a helicopter UAV of 3 kg payload, carrying an ultraviolet spectrometer for remotely sensing the SO2 flux (8.5 Mg d 1), and an infrared spectrometer, and electrochemical sensor assembly for measuring the plume CO2/SO2 ratio; by multiplying these data we compute a CO2 flux of 170 Mg d 1. Given the deeper exsolution of carbon dioxide from magma, and its lower solubility in hydro-thermal systems, relative to SO2, the ability to remotely measure CO2 fluxes is significant, with promise to provide more profound geochemical insights, and earlier eruption forecasts, than possible with SO2 fluxes alone: the most ubiquitous current source of remotely sensed volcanic gas data.
    Description: Published
    Description: L06303
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: Plume measurements ; carbon dioxide fluxes ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
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  • 83
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    CO2/CH4 ratio in fumaroles a powerful tool to detect magma degassing episodes at quiescent volcanoes (2008)
    American Geophysical Union
    Details
    Publication Date: 2017-04-04
    Description: Long time series of fumarolic compositions at Campi Flegrei (Italy), Mammoth Mountain (California), Panarea (Italy) and Nisyros (Greece) show rapid increases, up to orders of magnitude, of the CO2/CH4 ratio systematically with the occurrence of volcanic unrest periods. These easily detected anomalies originate with the arrival of CH4-poor magmatic fluids in the shallower levels of the volcanoes. The data suggest that volcanoes are characterized by magmatic activity at depth also in periods of apparent quiescence. The activity is constituted by the pulsing release of large amount of fluids which either cause unrest periods (seismicity and ground deformation) or possibly could precede volcanic eruption. This type of volcanic activity can be monitored trough the classical geophysical techniques together with the systematic sampling and analysis of fumaroles.
    Description: In press
    Description: 4.5. Degassamento naturale
    Description: JCR Journal
    Description: reserved
    Keywords: fumarole ; magma degassing ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 84
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    Link between major flank slip and 2002–2003 eruption at Mt. Etna (Italy) (2008)
    American Geophysical Union
    Details
    Publication Date: 2017-04-04
    Description: The 2002–2003 Etna eruption is studied through earthquake distributions and surface fracturing. In September 2002, earthquake-induced surface rupture (sinistral offset 0.48 m) occurred along the E-W striking Pernicana Fault (PF), on the NE flank. In late October, a flank eruption accompanied further ( 0.77 m) surface rupturing, reaching a total sinistral offset of 1.25 m; the deformation then propagated for 18 km eastwards to the coastline (sinistral offset 0.03 m) and southwards, along the NW-SE striking Timpe (dextral offset 0.04 m) and, later, Trecastagni faults (dextral offset 0.035 m). Seismicity (〈4 km bsl) on the E flank accompanied surface fracturing: fault plane solutions indicate an overall ESEWNWextension direction, consistent with ESE slip of the E flank also revealed by ground fractures. A three-stage model of flank slip is proposed: inception (September earthquake), climax (accelerated slip and eruption) and propagation (E and S migration of the deformation).
    Description: Published
    Description: 2286
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 3.2. Tettonica attiva
    Description: 3.5. Geologia e storia dei sistemi vulcanici
    Description: 3.6. Fisica del vulcanismo
    Description: 4.3. TTC - Scenari di pericolosità vulcanica
    Description: JCR Journal
    Description: reserved
    Keywords: volcano seismology ; surface fracturing ; flank slip ; eruption ; Etna ; 04. Solid Earth::04.01. Earth Interior::04.01.99. General or miscellaneous ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes ; 04. Solid Earth::04.02. Exploration geophysics::04.02.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.06. Seismology::04.06.99. General or miscellaneous ; 04. Solid Earth::04.06. Seismology::04.06.01. Earthquake faults: properties and evolution ; 04. Solid Earth::04.06. Seismology::04.06.02. Earthquake interactions and probability ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 04. Solid Earth::04.06. Seismology::04.06.11. Seismic risk ; 04. Solid Earth::04.07. Tectonophysics::04.07.99. General or miscellaneous ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.05. Stress ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
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  • 85
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    Lithospheric rheology in southern Italy inferred from postseismic viscoelastic relaxation following the 1980 Irpinia earthquake (2006)
    American Geophysical Union
    Details
    Publication Date: 2017-04-04
    Description: Postseismic relaxation is modeled for the Irpinia earthquake, which struck southern Italy in 1980. Our goal is to understand the mechanism of surface deformation due to stress relaxation in the deep portion of the crust-lithosphere system for a shallow normal fault source and to infer the rheological properties of the lithosphere in the extensional environment of peninsular Italy. The modeling is carried out within the framework of our normal mode viscoelastic theory at high spatial resolution in order to accurately resolve the vertical surface displacements for a seismic source. The slip distribution over the faults is first inverted from coseismic leveling data, the misfit between observed and modeled vertical displacements being minimized by means of the L2 norm. Slip distribution is then used within the viscoelastic model to invert for the viscosities of the lower crust and generally of the lithosphere. Inversion is based on leveling data sampled along three lines crossing the epicentral area. Postseismic deformation in the Irpinia area is characterized by a broad region of crust upwarping in the footwall of the major fault and downwarping in the hanging wall that is responsible for the long-wavelength features of the vertical displacement pattern. The c2 analysis indicates that the Irpinia earthquake cannot constrain the rheology of the upper mantle but only of the crust; a full search in the viscosity spaces makes it possible to constrain the crustal viscosity to values of the order of 1019 Pa s, in agreement with previous studies carried out in different tectonic environments.
    Description: Published
    Description: 1-16
    Description: partially_open
    Keywords: Lithospheric rheology ; Irpinia earthquake ; 04. Solid Earth::04.01. Earth Interior::04.01.05. Rheology ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.05. Stress
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  • 86
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    Constraints on mantle circulation around the deforming Calabrian slab (2006)
    American Geophysical Union
    Details
    Publication Date: 2017-04-04
    Description: Combining tectonics, with seismological and geochemical data, we reconstruct the deformation history of the presently narrow Calabrian slab and the path of mantle circulation during the last 10 Ma. We show that during the slab deformation the mantle laterally flowed inside the back arc region permitting its retrograde motion and giving a seismological and volcanological record after 1–2 myr.
    Description: Published
    Description: 1-4
    Description: partially_open
    Keywords: mantle circulation ; Calabrian slab ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes ; 04. Solid Earth::04.01. Earth Interior::04.01.03. Mantle and Core dynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.04. Plate boundaries, motion, and tectonics ; 04. Solid Earth::04.07. Tectonophysics::04.07.06. Subduction related processes
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  • 87
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    Lateral slab deformation and the origin of the western Mediterranean arcs (2005)
    American Geophysical Union
    Details
    Publication Date: 2017-04-04
    Description: The western Mediterranean subduction zone (WMSZ) extends from the northern Apennine to southern Spain and turns around forming the narrow and tight Calabrian and Gibraltar Arcs. The evolution of the WMSZ is characterized by a first phase of orogenic wedging followed, from 30 Ma on, by trench retreat and back-arc extension. Combining new and previous geological data, new tomographic images of the western Mediterranean mantle, and plate kinematics, we describe the evolution of the WMSZ during the last 35 Myr. Our reconstruction shows that the two arcs form by fragmentation of the 1500 km long WMSZ in small, narrow slabs. Once formed, these two narrow slabs retreat outward, producing back-arc extension and large scale rotation of the flanks, shaping the arcs. The Gibraltar Arc first formed during the middle Miocene, while the Calabrian Arc formed later, during the late Miocene-Pliocene. Despite the different paleogeographic settings, the mechanism of rupture and backward migration of the narrow slabs presents similarities on both sides of the western Mediterranean, suggesting that the slab deformation is also driven by lateral mantle flow that is particularly efficient in a restricted (upper mantle) style of mantle convection.
    Description: Published
    Description: 1-21
    Description: reserved
    Keywords: Mediterranean ; subduction ; arcuate belt ; tomography ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics
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  • 88
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    S, Cl and F degassing as an indicator of volcanic dynamics: The 2001 eruption of Mount Etna (2005)
    American Geophysical Union
    Details
    Publication Date: 2017-04-04
    Description: The recent eruption of Mount Etna (July 2001) offered the opportunity to analyze magma-derived volatiles emitted during preand syn-eruptive phases, and to verify whether their composition is affected by changes in volcanic dynamics. This paper presents the results of analyses of F, Cl and S in the volcanic plume collected by filter-packs, and interprets variations in the composition based on contrasting solubility in magmas. A Rayleigh-type degassing mechanism was used to fit the acquired data and to estimate Henryâ s solubility constant ratios in Etnean basalt. This model provided insights into the dynamics of the volcano. Abundances of sulfur and halogens in eruptive plumes may help predict the temporal evolution of an ongoing effusive eruption.
    Description: -Gruppo Nazionale per la Vulcanologia.
    Description: Published
    Description: 1559
    Description: partially_open
    Keywords: magmatic degassing ; acidic gases ; plume chemistry ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 89
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    A PTFE membrane for the in situ extraction of dissolved gases in natural waters: Theory and applications (2005)
    American Geophysical Union
    Details
    Publication Date: 2017-04-04
    Description: A new method for extracting dissolved gases in natural waters has been developed and tested, both in the laboratory and in the field. The sampling device consists of a polytetrafluroethylene (PTFE) tube (waterproof and gas permeable) sealed at one end and connected to a glass sample holder at the other end. The device is pre-evacuated and subsequently dipped in water, where the dissolved gases permeate through the PTFE tube until the pressure inside the system reaches equilibrium. A theoretical model describing the time variation in partial gas pressure inside a sampling device has been elaborated, combining the mass balance and ‘‘Solution-Diffusion Model’’ which describes the gas permeation process through a PTFE membrane). This theoretical model was used to predict the temporal evolution of the partial pressure of each gas species in the sampling device. The model was validated by numerous laboratory tests. The method was applied to the groundwater of Vulcano Island (southern Italy). The results suggest that the new sampling device could easily extract the dissolved gases from water in order to determine their chemical and isotopic composition.
    Description: - European Social Fund.
    Description: Published
    Description: Q09005
    Description: partially_open
    Keywords: dissolved gases ; helium isotope ; PTFE membrane ; Vulcano Island ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring ; 03. Hydrosphere::03.02. Hydrology::03.02.07. Instruments and techniques ; 04. Solid Earth::04.04. Geology::04.04.11. Instruments and techniques ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
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  • 90
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    Relative roles of rifting tectonics and magma ascent processes: Inferences from geophysical, structural, volcanological, and geochemical data for the Neapolitan volcanic region (southern Italy) (2005)
    American Geophysical Union
    Details
    Publication Date: 2017-04-04
    Description: The Neapolitan volcanic region is located within the graben structure of the Campanian Plain (CP), which developed between the western sector of the Appenine Chain and the eastern margin of the Tyrrhenian Sea. Two volcanic areas, spaced less than 10 km apart, are situated within the CP: the Somma-Vesuvius Volcano (SVV) and the Phlegraean Volcanic District (PVD). SVV is a typical stratovolcano, whereas PVD, including Campi Flegrei, Procida, and Ischia, is composed mostly of monogenetic centers. This contrast is due to different magma supply systems: a widespread fissure-type system beneath the PVD and a central-type magma supply system for the SVV. Volcanological, geophysical, and geochemical data show that magma viscosity, magma supply rate, and depth of magma storage are comparable at PVD and SVV, whereas different structural arrangements characterize the two areas. On the basis of geophysical data and magma geochemistry, an oblique-extensional tectonic regime is proposed within the PVD, whereas in the SVVarea a compressive stress regime dominates over extension. Geophysical data suggest that the area with the maximum deformation rate extends between the EW-running 41st parallel and the NE-running Magnaghi-Sebeto fault systems. The PVD extensional area is a consequence of the Tyrrhenian Sea opening and is decoupled from the surrounding areas (Roccamonfina and Somma-Vesuvius) which are still dominated by Adriatic slab dynamics. Spatially, we argue that the contribution of the asthenospheric wedge become much less important from W-NW to E-SE in the CP. The development of the two styles of volcanism in the CP reflects the different tectonic regimes acting in the area.
    Description: Published
    Description: 1-25
    Description: partially_open
    Keywords: Volcanic styles ; Tectonic setting ; Neapolitan volcanic region ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.05. Stress ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics
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  • 91
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    Carbon dioxide Earth degassing and seismogenesis in central and southern Italy (2005)
    American Geophysical Union
    Details
    Publication Date: 2017-04-04
    Description: We present the first regional map of CO2 Earth degassing from a large area (most of central and south Italy) derived from the carbon of deep provenance dissolved in the main springs of the region. The investigation shows that a globally significant amount of deeply derived CO2 (10% of the estimated global CO2 emitted from subaerial volcanoes) is released by two large areas located in western Italy. The anomalous flux of CO2 suddenly disappears in the Apennine in correspondence to a narrow band where most of seismicity concentrates. Here, at depth, the gas accumulates in crustal traps generating CO2 overpressurized reservoirs which induce seismicity.
    Description: Published
    Description: 1-4
    Description: partially_open
    Keywords: Carbon dioxide ; Central Italy ; Southern Italy ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 03. Hydrosphere::03.04. Chemical and biological::03.04.02. Carbon cycling ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics
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    Type: article
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  • 92
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    Evidence of deep magma degassing and ascent by geochemistry of peripheral gas emissions at Mount Etna (Italy): Assessment of the magmatic reservoir pressure (2005)
    American Geophysical Union
    Details
    Publication Date: 2017-04-04
    Description: Five gas discharges in the area of Mount Etna volcano (Italy) and in the near Hyblean plateau have been monitored since 1996. All the emissions displayed low contributions from crustal fluids, whereas magmatic gases were the main component. Selective dissolution of these gases into hydrothermal aquifers has been recognized and modeled, allowing us to calculate the original composition of the magma-released gases. The inferred composition of the magmatic gases exhibits synchronous variations of He/Ne and He/CO2 ratios, which are coherent with the magma degassing process. On the basis of numerical simulations of volatile degassing from Etnean basalts we have computed the initial and final pressures of the magma batches feeding the emissions. We thus can define the levels of the Etna plumbing system where magmas are stored. Pressure values were around 360 and 160 MPa for initial and final stages, respectively, meaning related depths of about 10 and 3 km below sea level, matching those obtained by geophysical investigations for the deep and shallow magma reservoirs. In addition, we have been able to recognize episodes of magma migration from the deeper reservoir toward the shallow one. An important magma injection into the shallow storage volume was detected during the onset of the 2001 eruption (17 July). No further injection had taken place during this period until September 2001, providing a possible reason for the quick exhaustion of the eruption. In view of this we suggest that the sampled emissions are a powerful geochemical tool to investigate the Etna’s plumbing system and its magma dynamics, as well as the development of eruptive events.
    Description: Published
    Description: 2463
    Description: partially_open
    Keywords: gas geochemistry ; magma degassing ; modeling ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.04. Thermodynamics ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 93
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    Active geodynamics of the central Mediterranean Sea: Tensional tectonic evidences in western Sicily from mantle-derived helium (2005)
    American Geophysical Union
    Details
    Publication Date: 2017-04-04
    Description: We report results on the measured high 3He/4He isotope ratio in western Sicily, interpreted together with the heat data. The study of this sector of the Europe-Africa interaction is crucial to a better understanding of the tectonics and the geodynamical evolution of the central Mediterranean area. The estimated mantle-derived helium fluxes in the investigated areas are up to 2–3 orders of magnitude greater than those of a stable continental area. The highest flux, found in the southernmost area near the Sicily Channel, where recent eruptions of the Ferdinandea Island occurred 20 miles out to sea off Sciacca, has been associated with a clear excess of heat flow. Our results indicate that there is an accumulation of magma below the continental crust of western Sicily that is possibly intruding and out-gassing through roughly N-S trending deep fault systems linked to the mantle, that have an extensional component. Although the identification of these faults is not sufficiently constrained by our data, they could possibly be linked to the pre-existing faults that originated during the Mesozoic extensional-transtensional tectonic phases.
    Description: Published
    Description: L04312
    Description: partially_open
    Keywords: helium isotopes ; heat production ; tectonics ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 03. Hydrosphere::03.04. Chemical and biological::03.04.07. Radioactivity and isotopes ; 04. Solid Earth::04.02. Exploration geophysics::04.02.03. Heat flow ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.07. Tectonophysics::04.07.03. Heat generation and transport ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics
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