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  • 1
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Analytica Chimica Acta 82 (1976), S. 415-420 
    ISSN: 0003-2670
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1365-3091
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: Geological and volcanological studies were performed in the Herculaneum excavations, 7 km west of Vesuvius, Italy, to reconstruct the main features of the pyroclastic density currents and the temporal sequence of the ad 79 eruptive events that destroyed and buried the town. The identification of two distinctive marker beds allows correlation of these deposits with the better-known sequences to the south of Vesuvius, along the dispersal axis of the Plinian fall deposit. Detailed observations from stratigraphic sections show that the pyroclastic density current deposits are characterized by several sedimentary facies, each recording different depositional and emplacement mechanisms. Facies analysis reveals both lateral and vertical variations from massive to stratified deposits, which can be related to the combined effects of flow dynamics and local irregularities of the substratum at centimetre or metre scales. These topographic irregularities enhanced turbulence and allowed rapid transition from non-turbulent to turbulent transport within the flow. Fabric data from these deposits, both from roof tile orientations and anisotropy magnetic susceptibility (AMS) analyses carried out on some of the pyroclastic deposits, suggest that the pyroclastic density currents were strongly affected by the presence of buildings. These obstacles probably caused deflection and separation of flows into multiple lobes that moved in different directions.
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    International journal of earth sciences 67 (1978), S. 598-614 
    ISSN: 1437-3262
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Description / Table of Contents: Abstract The Secca Fawn-1 hole, drilled in 1968 by Gulf Oil Co. on the western margin of Southern Red Sea, crossed at 1400 m depth a sequence of late Miocene-early Pliocene submarine basaltic flows, at least 600 m thick. This paper reports the results of the study of these basalts. Homogenous basaltic fragments were separated from 22 cuttings and analyzed for major elements; several trace elements were determined on 11 of these samples. All basalts have the composition of transitional olivine-tholeiites and a primary vertical variation, with a tendency towards a slightly more alkalic composition, was recognized in spite of the chemical changes induced by sea-water alteration which has affected rather deeply these rocks. Secca Fawn-1 basalts appear to be geochemically intermediate between typical low-K oceanic tholeiites as those erupted at Red Sea central trough and the transitional olivine-tholeiites of the spreading axes of the neighbouring Afar rift. K-Ar age results of 5.8 and 8.2 m. y. were obtained on two selected samples; these dates are however subject to caution because of the state of alteration of the samples. The structural implications of these data are discussed and it is thought that Secca Fawn-l basalts are related either to a localized spreading episode avorted in early Pliocene, or to extensional tectonics on the attenuated continental lithosphere of the Red Sea margin.
    Abstract: Résumé Le sondage Secca Fawn-l, foré en 1968 par la Gulf Oil Co. sur le bord occidental de la Mer Rouge méridionale, a traversé, à la profondeur de 1400 mètres, une série épaisse de 600 mètres, faite de coulées basaltiques sous-marines d'âge Miocène supérieur à Pliocène inférieur. On en a analysé 22 fragments homogènes provenant de cuttings, et on en a déterminé les éléments majeurs ainsi que quelques éléments en traces dans 11 de ces échantillons. Tous les basaltes sont des tholéiites à olivine transitionnelles; une variation verticale primaire montrant dans les basaltes plus récents une tendance plus alcaline a été reconnue, ce qui peut être attribué à une altération chimique due à l'eau marine. — Du point de vue géochimique, les basaltes de Secca Fawn-1 sont intermédiaires entre des tholéiites océaniques pauvres en K, typiques, comme celles du Fossé central de la Mer Rouge, et les tholéiites à olivine transitionelles des axes d'expansion de la zone voisine du Rift de l'Afar. Des âges K-Ar de 5,8 et 8,2 m. a. ont été obtenus sur des échantillons provenant de la partie centrale de la série; mais ces datations doivent etre regardées avec précaution, car ces échantillons ont subi une altération secondaire. Les implications structurelles sont discutées; on envisage 2 possibilités: les basaltes de Secca Fawn-1 peuvent être liés soit à un épisode d'expansion localisée au début du Pliocène, ou bien à une tectonique disjonctive atténuée dans la lithosphère continentale du bord de la Mer Rouge.
    Notes: Zusammenfassung Die Secca-Fawn-l-Bohrung, die 1968 von der Gulf Oil Company am westlichen Rand des südlichen Roten Meeres abgeteuft wurde, erreichte in 1400 m Tiefe eine Folge von jungmiozänen bis altpliozänen submarinen Basaltlagen, die mindestens 600 m mächtig sind. Es wurden homogene Basaltfragmente aus den Cuttings auf ihren Hauptelementgehalt hin analysiert; zahlreiche Spurenelemente wurden in einer Reihe dieser Proben bestimmt. Alle Basalte haben die Zusammensetzung von Übergangs-Olivin-Tholeiiten. Die primäre vertikale Veränderung zeigt eine zunehmende Tendenz zu mehr alkalischer Zusammensetzung, was auf eine chemische Veränderung durch Seewassereinfluß in diesen Gesteinen zurückgeführt werden kann. Die Secca-Fawn-1-Basalte erscheinen geochemisch zwischen typischen ozeanischen Tholeiiten mit niedrigen K-Werten, wie sie im Roten Meer im zentralen Graben auftreten, und Übergangs-Olivin-Tholeiiten entlang der spreading-Achse in der benachbarten Afar-Rift-Zone. Die K-Ar-Alter ergeben 5,8 und 8,2 m. y. Diese Alter sind jedoch mit Vorsicht zu betrachten, da die Proben einer sekundären Veränderung unterworfen waren. Als Folgerungen für die Strukturgeologie ergeben sich Zusammenhänge für eine frühe spreading-Episode im Altpliozän oder eine Dehnungstektonik in der kontinentalen Lithosphäre des Rotmeerrandes.
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  • 4
    ISSN: 1432-0819
    Keywords: Key words Sulphur isotopes ; alkaline magmas magma degassing ; magma contamination ; Vulture Volcano ; Italy
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract Both the δ34S value and the total S content of products from Vulture Volcano, Italy are mainly controlled by the separation of S gases, predominantly SO2, from high f O2 magmas containing S predominantly as SO2– 4. The addition of evaporites to such magmas appears to be a relatively uncommon and limited phenomenon. The total S content of the most primitive product of Vulture Volcano (5600 mg/kg) is very high. The high δ34S value of 4ö indicates an origin through the partial melting of a mantle containing high S, enriched in 34S of unknown origin.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Bulletin of volcanology 57 (1995), S. 99-110 
    ISSN: 1432-0819
    Keywords: Fumaroles ; Fluid chemistry ; δD value ; δ18O value ; Volcanic surveillance ; Vulcano Island
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract Variations in δD and δ18O values with H2O contents and outlet temperatures indicate that the fumaroles of La Fossa crater have discharged mixtures of magmatic water and marine hydrothermal water, since 1979. The contribution of meteoric water was low in the period 1979–1982 and very low afterwards. The δ18O values of the marine-hydrothermal component of +5 to +7.2‰ are due to isotopic exchange with the 18O-rich silicates of the rocks under high-temperature and low-permeability conditions. The δ18O value of the magmatic end-member is generally +3.5 to +4.3‰, although values as high as +5.5 to +6.5‰ were reached in the summer of 1988, when magma degassing appears to have extended into the core of the magma body. The δD values of the end-member were close to -20‰, typical of andesitic waters. Both the isotopic values and chemical data strongly support a ‘dry’ model, consisting of a central magmatic gas column and a surrounding hydrothermal envelope, in which marine hydrothermal brines move along limited fracture zones to undergo total evaporation on approaching the conduits of magmatic fluids. The vents at the eastern and western boundaries of the fumarolic field are fed by fluids whose pressure is governed by the coexistence of vapor, liquid and halite, giving rise to a high risk of phreato magmatic explosions, should magma penetrate into these wet environments. Most La Fossa eruptions were triggered by an initial hydrothermal blast and continued with a series of phreatomagmatic explosions. The fluids discharged by the Forgia Vecchia fumaroles are mixed with meteoric water, which is largely evaporated, although subordinate loss of condensed steam may be responsible for scrubbing most of the acidic gas species. The temperatures and pressures, and the risk of a sudden pressure increase, are low. A boiling hydrothermal aquifer at 230° C is present underneath the Baia di Levante beach. This area has a minor risk of hydrothermal explosions.
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Bulletin of volcanology 58 (1996), S. 380-392 
    ISSN: 1432-0819
    Keywords: Key words Montserrat Island ; Soufrière Hills Volcano ; Fluid geochemistry ; Hydrothermal fluids ; Magmatic fluids
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract  Two geochemical surveys carried out in March 1991 and September 1992 revealed the existence of a hydrothermal system in the southern portion of Montserrat Island, below Soufrière Hills Volcano. This conclusion is supported by the presence of: (a) the thermal springs of Plymouth which are fed by deep Na–Cl waters (Cl concentration ∼25 000 mg/kg, temperature ca. 250  °C) mixed with shallow steam-heated waters; (b) the four fumarolic fields of Galway's Soufrière, Gages Upper Soufrière, Gages Lower Soufrière, and Tar River Soufrière, where acid to neutral, steam-heated waters are present together with several fumarolic vents, discharging vapors formed through boiling of hydrothermal aqueous solutions. Involvement of magmatic fluids in the recharge of the hydrothermal aquifers is suggested by: (a) the high 3He/4He ratios of fumarolic fluids, i.e., 8.2 RA at Galway's Soufrière and 5.9 RA at Gages Lower Soufrière; (b) the δD and δ18O values of Na–Cl thermal springs and steam condensates, indicating the involvement of arc-type magmatic water in the formation of deep geothermal liquids; and (c) the CH4/CO2 ratios of fumarolic fluids, which are lower than expected for equilibrium with the FeO–FeO1.5 hydrothermal rock buffer, but being shifted towards the SO2–H2S magmatic gas buffer.
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Bulletin of volcanology 47 (1984), S. 295-302 
    ISSN: 1432-0819
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract A simple geochemical model of Solfatara, Phlegraean Fields (Italy), is proposed on the basis of gas composition and temperature at the surface. Data on the Solfatara fumaroles have been collected since 1979 within the framework of a geochemical monitoring for the surveillance of the Phlegraean volcanic system. Surface manifestations of Solfatara are likely to be fed through isoenthalpic expansion of dry steam, which separates from a geothermal liquid in an intensively fractured zone at about 236°C. This value is consistent both with gas composition and surface temperature. The gas/steam ratio appears to be the most effective parameter to detect changes of heat flow at depth. Actually a remarkable decrease in the gas/steam ratio has been observed since 1981, while the gas composition and the temperature did not change significantly. These facts suggest increased heat flow at depth.
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  • 8
    ISSN: 1432-0819
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract Physical, chemical and isotopic parameters were measured in fumaroles at the Vulcano crater and in drowned fumaroles near the beach. The data were used to define boundary conditions for possible conceptual models of the system.Crater fumaroles: time variations of CO2 and SO2 concentrations indicate mixing of saline gas-rich water with local fresh water. Cl/Br ratios of 300– 400 favour sea-water as a major source for Cl, Brand part of the water in the fumaroles. Cl concentrations and δD values revealed, independently, amixing of 0.75 sea-water with 0.25 local freshwaterin furmarole F-5 during September 1982.Patterns of parameter correlation and mass balances reveal that CO2, S, NH3 and B originate from sources other than sea water. The CO2 value of δ13C = − 2%o favours, at least partial, origin from decomposition of sedimentary rocks rather than mantle-derived material. Radiogenic4He(1.3 × lO−3 ccSTP/g water) and radiogenic40Ar(10.6 × 10−4 ccSTP/g water) are observed, (4He/40Ar)radiogenic = 1.2, well in the range of values observed in geothermal systems.Drowned fumaroles: strongly bubbling gas at a pond and at the beachappears to have the same origin and initial compositionas the crater fumaroles (2 km away). The fumarolic gas is modified by depletion of the reactive gases, caused by dissolution in shallow-water. Atmospheric Ne, Ar, Kr and Xe are addeden route, some radiogenic He and Ar are maintained. The Vulcano system seems to be strongly influenced by the contribution of sea-water and decomposition of sedimentary rocks. Evidence of magmatic contributions is mainly derived from heat.
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  • 9
    ISSN: 1432-0819
    Keywords: Sulphur isotopes ; alkaline magmas magma degassing ; magma contamination ; Vulture Volcano, Italy
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract Both the δ34 value and the total S content of products from Vulture Volcano, Italy are mainly controlled by the separation of S gases, predominantly SO2, from high f O2magmas containing S predominantly as SO 2- 4 . The addition of evaporites to such magmas appears to be a relatively uncommon and limited phenomenon. The total S content of the most primitive product of Vulture Volcano (5600 mg/kg) is very high. The high δ34S value of 4‰ indicates an origin through the partial melting of a mantle containing high S, enriched in 34S of unknown origin.
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  • 10
    Publication Date: 2014-11-05
    Description: Two mafic eruptive products from Vesuvius, a tephrite and a trachybasalt, have been crystallized in the laboratory to constrain the nature of primitive Vesuvius magmas and their crustal evolution. Experiments were performed at high temperatures (from 1000 to ≥1200°C) and both at 0·1 MPa and at high pressures (from 50 to 200 MPa) under H 2 O-bearing fluid-absent and H 2 O- and CO 2 -bearing fluid-present conditions. Experiments started from glass except for a few that started from glass plus San Carlos olivine crystals to force olivine saturation. Melt H 2 O concentrations reached a maximum of 6·0 wt % and experimental f O 2 ranged from NNO – 0·1 to NNO + 3·4 (where NNO is nickel–nickel oxide buffer). Clinopyroxene (Mg# up to 93) is the liquidus phase for the two investigated samples; it is followed by leucite for H 2 O in melt 〈3 wt %, and by phlogopite (Mg# up to 81) for H 2 O in melt 〉3 wt %. Olivine (Fo 85 ) crystallized spontaneously in only one experimental charge. Plagioclase was not found. Upon progressive crystallization of clinopyroxene, glass K 2 O and Al 2 O 3 contents strongly increase whereas MgO, CaO and CaO/Al 2 O 3 decrease; the residual melts follow the evolution of Vesuvius whole-rocks from trachybasalt to tephrite, phonotephrite and to tephriphonolite. Concentrations of H 2 O and CO 2 in near-liquidus 200 MPa glasses and primitive melt inclusions from the literature overlap. The earliest evolutionary stage, corresponding to the crystallization of Fo-rich olivine, was reconstructed by the olivine-added experiments. They show that the primitive Vesuvius melts are trachybasalts (K 2 O ~ 4·5–5·5 wt %, MgO = 8–9 wt %, Mg# = 75–80, CaO/Al 2 O 3 = 0·9–0·95) that crystallize Fo-rich olivine (90–91) as the liquidus phase between 1150 and 1200°C and from 300 to 〈200 MPa. Primitive Vesuvius melts are volatile-rich (1·5–4·5 wt % H 2 O and 600–4500 ppm CO 2 in primitive melt inclusions) and oxidized (from NNO + 0·4 to NNO + 1·2). Assimilation of carbonate wall-rocks by ascending primitive magmas can account for the disappearance of olivine from crystallization sequences and explains the lack of rocks representative of olivine-crystallizing magmas. A correlation between carbonate assimilation and the type of feeding system is proposed: carbonate assimilation is promoted for primitive magma batches of small volumes. In contrast, for longer-lived, large-volume, less frequently recharged, hence more evolved, cooler reservoirs, magma–carbonate interaction is limited. Primitive magmas from Vesuvius and other Campanian volcanoes have similar redox states. However, the Cr# of Vesuvius spinels is distinctive and therefore the peridotitic component in the mantle source of Vesuvius differs from that of the other Campanian magmas.
    Print ISSN: 0022-3530
    Electronic ISSN: 1460-2415
    Topics: Geosciences
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