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  • 04. Solid Earth::04.08. Volcanology::04.08.01. Gases  (51)
  • 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism  (31)
  • 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics  (22)
  • 05. General::05.02. Data dissemination::05.02.01. Geochemical data  (21)
  • Elsevier  (106)
  • Essen : Verl. Glückauf
  • Krefeld : Geologischer Dienst Nordhein-Westfalen
  • 2005-2009  (106)
Collection
Years
Year
  • 1
    Publication Date: 2021-07-14
    Description: A quantitative analysis of planktonic foraminifera, coupled with petrophysical and paleomagnetic measurements and 14C AMS calibrations, was carried out on a deep core recovered in the Sardinia Channel (Western Mediterranean Sea), during the CIESM Sub2 survey, providing an integrated stratigraphic time-framework over the last 80 kyr. Significant changes in the quantitative distribution of planktonic foraminifera allowed the identification of several eco-bioevents useful to accurately mark the boundaries of the eco-biozones widely recognised in the Western Mediterranean records and used for large scale correlations. Namely, 10 eco-biozones were identified based on the relative abundance of selected climate sensitive planktonic foraminiferal species. Sixteen codified eco-bioevents were correlated with the Alboran Sea planktonic foraminiferal data and four climatic global events (Sapropel S1, Younger Dryas, Greenland Isotope Interstadial 1, Greenland Isotope Stadial 2, Heinrich event H1-H6) were recognized. The eco-bioevents together with the 14C AMS calibrations allowed us to define an accurate age model, spanning between 2 and 83 kyr. The reliability of the age model was confirmed by comparing the colour reflectance (550 nm%) data of the studied record with the astronomically tuned record from the Ionian sea (ODP-Site 964). A mean sedimentation rate of about 7 cm/kyr included three turbidite event beds that were chronologically constrained within the relative low stand and lowering sea level phases of the MIS 4 and 3. The deep-sea sedimentary record includes a distinct tephra occurring at the base of the core which dates 78 ka cal. BP. The paleomagnetic data provide a well-defined record of the characteristic remanent magnetization that may be used to reconstruct the geomagnetic paleosecular variation for the Mediterranean back to 83 kyr.
    Description: Published
    Description: 725 - 737
    Description: 2.2. Laboratorio di paleomagnetismo
    Description: JCR Journal
    Description: reserved
    Keywords: Integrated stratigraphy ; Late Neogene marine record ; Eco-bio-events ; Reflectance 550 nm % ; Sardinia Channel ; Western Mediterranean ; 04. Solid Earth::04.04. Geology::04.04.04. Marine geology ; 04. Solid Earth::04.04. Geology::04.04.08. Sediments: dating, processes, transport ; 04. Solid Earth::04.04. Geology::04.04.10. Stratigraphy ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Publication Date: 2017-04-04
    Description: A remote sensing approach permits for the first time the derivation of a map of the carbon dioxide concentration in a volcanic plume. The airborne imaging remote sensing overcomes the typical difficulties associated with the ground measurements and permits rapid and large views of the volcanic processes together with the measurements of volatile components exolving from craters. Hyperspectral images in the infrared range (1900–2100 nm), where carbon dioxide absorption lines are present, have been used. These images were acquired during an airborne campaign by the Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) over the Pu`u` O`o Vent situated at the Kilauea East Rift zone, Hawaii. Using a radiative transfer model to simulate the measured up-welling spectral radiance and by applying the newly developed mapping technique, the carbon dioxide concentration map of the Pu`u` O`o Vent plume were obtained. The carbon dioxide integrated flux rate were calculated and a mean value of 396±138 t d−1 was obtained. This result is in agreement, within the measurements errors, with those of the ground measurements taken during the airborne campaign.
    Description: Published
    Description: 3192–3199
    Description: 1.10. TTC - Telerilevamento
    Description: JCR Journal
    Description: partially_open
    Keywords: Hyperspectral data ; Volcanic plume ; Carbon dioxide ; AVIRIS ; Kilauea ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 3
    Publication Date: 2017-04-04
    Description: Quantifying mercury (Hg) emissions from active volcanoes is of particular interest for better constraining the global cycle and environmental impact of this highly toxic element. Here we report on the abundance of total gaseous (TGM=Hg0 (g)+HgII (g)) and particulate (Hg(p)) mercury in the summit gas emissions of La Soufrière andesitic volcano (Guadeloupe island, Lesser Antilles), where enhanced degassing of mixed hydrothermalmagmatic volatiles has been occurring since 1992 from the Southern summit crater.We demonstrate that Hg in volcanic plume occurs predominantly as gaseous mercury, with a mean TGM/Hg(p) mass ratio of ~63. Combining the mean TGM/H2S mass ratio of the volcanic plume (~3.2×10−6), measured close to the source vent, with the H2S plume flux (~0.7 t d−1), determined simultaneously, allows us to estimate a gaseous mercury emission rate of 0.8 kg yr−1 from La Soufrière summit dome. Somewhat lower TGM/Stot mass ratio in fumarolic gases from the source vent (4.4×10−7) suggests that plume chemical composition is not well represented by the emission source (fumaroles) due to chemical processes prior to (or upon) discharge. Current mercury emission from La Soufrìere volcano represents a very small contribution to the estimated global volcanic budget for this element.
    Description: Published
    Description: 276-282
    Description: 4.3. TTC - Scenari di pericolosità vulcanica
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: Mercury ; Fumaroles ; Volcanic plume ; Trace metals ; Gaseous and particulate mercury ; Emission rate ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 4
    Publication Date: 2017-04-04
    Description: The transport, degassing and atmospheric release of halogens from active volcanism on Earth have been the focus of increasing interest over the last few decades, and have recently been the subject of the 1st workshop on “Halogens in volcanic systems and their environmental impacts” that was held in December of 2007 at Yosemite Lodge in Yosemite National Park, California. As an introduction to this Chemical Geology special issue, collecting contributions from many of the participants at the workshop, we review here recent advances in this field, including experimental and theoretical investigations of halogen behaviour in volcanic and related magmatic systems. We discuss previous research on several aspects of halogen geochemistry, including halogen abundances in the mantle and magmas on Earth; the effects of halogens on phase equilibria and melt viscosities; their partitioning between melt and fluid phase(s) upon decompression, cooling and crystallisation of magmas in the Earth's crust; and their final atmospheric release as volcanic gases. The role of halogens in the genesis of hydrothermal systems and in the transport of ore-forming metals is also reviewed, and we discuss our current understanding of atmospheric processing of volcanic halogens in both the troposphere and stratosphere, and their consequent impacts. In spite of these recent advancements, our current understanding of halogen geochemistry at active volcanoes is still far too fragmentary, and the key questions that require answers from future research are summarised in our conclusions.
    Description: Published
    Description: 1-18
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: Halogens ; Magmatic fluids ; Ore deposits ; Volcanic degassing ; Volcanic gas ; Atmospheric effects ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 5
    Publication Date: 2017-04-03
    Description: The currently available data set of S–Cl–F abundances in volcanic gas plumes and high-temperature fumarolic gas samples from basaltic volcanism is reviewed here in the attempt to derive constraints on the modes of halogen degassing from mafic silicate melts. Apart from large volcano-to-volcano variations, reflecting remarkable differences in volatile abundances in the source magmas, each of the explored volcanoes displays large changes of SO2/HCl and SO2/HF ratios with the style of volcanic activity, with HCl/HF staying fairly constant. Halogen abundances are low and SO2/HCl and SO2/HF are high when fresh (volatile-rich) magmas sustain degassing, as during explosive eruptions, at the onset of eruptive cycles, or shortly before paroxysmal events. Low SO2/HCl and SO2/HF ratios are instead characteristic of late stages of volcanic degassing, typically being observed in the concluding stages of basaltic eruptions, or during periods of reduced magma supply at persistently degassing volcanoes. These observations are taken as evidence of halogens being less keen to enter the gas phase (relative to S) during degassing of basaltic magmas; and quantitatively interpreted in light of a Rayleigh-type open-system degassing model. The model, though simple, quantitatively reproduces the range of volcanic gas compositions observed at basaltic volcanoes worldwide, and allows prediction of vapour/melt partitioning contrasts of factors ~9 and ~36 for the volatile couples S–Cl and S–F, respectively. These predictions require validation from appropriately designed experiments of halogen partitioning between magmatic vapours and silicate melts over a range of P–T–X conditions.
    Description: Published
    Description: 99-109
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: Volcanic degassing ; Halogens ; Volcanic gases ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 6
    Publication Date: 2017-04-04
    Description: Active volcanoes emit considerable amounts of contaminants such as As, Se and V. Mount Etna is the biggest volcano of Europe and an excellent geochemical site to study water-soil processes. Due to its volcanic activity, the rainwater has a strong compositional gradient, both in time and space. At present, the behaviour of trace elements in the soils around Mt Etna is poorly understood. To determine the influence of the rainwater pH on the potential mobilization of geogenic pollutants, batch experiments have been performed with synthetic rainwater for 25 soils collected along the flanks of the volcano. Our results show that: i) The maximum concentrations in the leaching solutions are higher for acid rain than for neutral rain (e.g. 7.7 vs 1.3 mg/L for Se). ii) With neutral rain conditions the soils upwind from the volcano have higher concentrations of Se than those downwind (up to 1.3 mg/L compared to ≤0.3 mg/L for the other samples). This trend is less clear for As and V. iii) For soils collected from 2 to 10 km downwind of the craters, Se concentrations in acid rain leachates decrease one order of magnitude with increasing distance. A similar pattern is also observed upwind from the volcano. For As and V no clear relationship between concentrations and location with respect to the volcanic craters is observed. Both i) and ii) result in a low pH dependence for samples upwind from the volcano. The biggest difference between acid and neutral leaching for As and V is observed for a sample 2 km downwind from the craters. The observed patterns are influenced by potential controlling factors, such as organic matter content, total concentrations, mineralogy, influence of the volcanic plume, etc. Our results have implications for the chemical composition of the Etnean aquifer, the only water resource to the one million inhabitants around Mt Etna, as well as for the bioavailability and potential toxicity through agricultural activities, essential to the local economy.
    Description: Published
    Description: Davos, Switzerland
    Description: 4.4. Scenari e mitigazione del rischio ambientale
    Description: open
    Keywords: volcanic soils ; selenium ; arsenic ; vanadium ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 03. Hydrosphere::03.03. Physical::03.03.01. Air/water/earth interactions ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.08. Risk::05.08.01. Environmental risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Oral presentation
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  • 7
    Publication Date: 2017-04-04
    Description: Dynamic accumulation chamber methods have been extensively used to estimate the total output of CO2 released from active volcanic area. In order to asses the performance and reliability of a closed dynamic system several tests were carried out with different soil permeabilities and soil CO2 fluxes. A special device was used to create a constant one-dimensional CO2 flux through a soil column with a known permeability. Three permeabilities were investigated, ranging between 3.6 × 10− 2 and 3.5 × 10 μm2, as were several CO2 fluxes (ranging between 1.1 × 10− 6 and 6.3 × 10− 5 kg m− 2 s− 1). The results highlight that the accuracy of soil CO2 flux measurements strictly depends on the soil gas permeability and the soil CO2 flux regimen. Generally chamber measurements underestimate CO2 fluxes at low soil permeability and low soil CO2 fluxes, whereas appreciable overestimations occur for high permeability soil, especially for high soil CO2 fluxes. Other tests carried out with different settings for the measurement device, such as the chamber volume and the flux of the pump used to recirculate air through the chamber and the gas analyzer (recirculation flux), revealed a strong dependence of the closed dynamic chamber measurements on the recirculation flux. Low recirculation fluxes (0.2–0.4 l min− 1) decreased the performance of the measurement system, causing underestimations of the actual soil CO2 flux, whereas higher values (0.6–1.0 l min− 1) resulted in overestimations, especially for elevated soil CO2 fluxes. An empirical equation was deduced to allow accumulation chamber fluxes to be calculated very accurately based on soil gas permeabilities measured in the field.
    Description: Published
    Description: 387-393
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: reserved
    Keywords: Soil CO2 flux measuraments ; Closed dynamic chamber ; soil gas permeability ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 8
    Publication Date: 2017-04-04
    Description: A quantitative analysis of planktonic foraminifera, coupled with petrophysical and paleomagnetic measurements and 14C AMS calibrations, was carried out on a deep core recovered in the Sardinia Channel (Western Mediterranean Sea), during the CIESM Sub2 survey, providing an integrated stratigraphic time-framework over the last 80 kyr. Significant changes in the quantitative distribution of planktonic foraminifera allowed the identification of several eco-bioevents useful to accurately mark the boundaries of the eco-biozones widely recognised in the Western Mediterranean records and used for large scale correlations. Namely, 10 eco-biozones were identified based on the relative abundance of selected climate sensitive planktonic foraminiferal species. Sixteen codified eco-bioevents were correlated with the Alboran Sea planktonic foraminiferal data and four climatic global events (Sapropel S1, Younger Dryas, Greenland Isotope Interstadial 1, Greenland Isotope Stadial 2, Heinrich event H1-H6) were recognized. The eco-bioevents together with the 14C AMS calibrations concurred to define an accurate age model, spanning between 2 and 83 kyr cal. BP. The reliability of the age model was confirmed by comparing the colour reflectance (550 nm%) data of the studied record with the astronomically tuned one of the Ionian sea (ODP-Site 964). A mean sedimentation rate of about 7 cm/kyr was evaluated including three turbidite event beds that were chronologically constrained within the relative low stand and lowering sea level phases of the MIS 4 and MIS 3. The deep sea sedimentary record includes a distinct tephra occurring at the base of the core which dates 79 ka. The paleomagnetic data provide a well-defined record of the characteristic remanent magnetization that may be used to reconstruct the geomagnetic paleosecular variation for the Mediterranean back to 83 kyr cal. BP.
    Description: In press
    Description: 2.2. Laboratorio di paleomagnetismo
    Description: JCR Journal
    Description: open
    Keywords: integrated stratigraphy, late Neogene marine record, eco-bio-events, reflectance 550 nm %, Sardinia ; 04. Solid Earth::04.04. Geology::04.04.04. Marine geology ; 04. Solid Earth::04.04. Geology::04.04.08. Sediments: dating, processes, transport ; 04. Solid Earth::04.04. Geology::04.04.10. Stratigraphy ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 9
    Publication Date: 2017-04-04
    Description: Methane, the most abundant hydrocarbon in the atmosphere, plays an important role in the Earth’s atmospheric chemistry and radiative balance being the second most important greenhouse gas after CO2. Methane is released to the atmosphere by a wide number of sources, both natural and anthropogenic, with the latter being twice as large as the former (Kvenvolden and Rogers, 2005). It has recently been established that significant amounts of geological methane, produced within the Earth’s crust, are currently released naturally into the atmosphere (Etiope, 2004). Among natural sources the volcanic/geothermal emissions are probably the least constrained. Recent estimations for volcanic and geothermal systems in Europe (Etiope et al. 2007) gave a rather large provisional range (4-16 kt/a) that claims for much more field measurements in order to widen the current database and decrease the present uncertainties. Pantelleria is an active volcanic complex, at present in quiescent status, hosting a high enthalpy geothermal system. Explorative geothermal wells tapped an exploitable water-dominated reservoir at 600-800 m depth with maximum measured temperatures of 250 °C. While some data are available on diffuse CO2 fluxes, data on CH4 are available only for fumarolic fluids. In the present study we measured CH4 fluxes in the area of Favara Grande characterized by intense diffuse degassing and widespread signs of geothermal activity (fumaroles, steaming grounds and large zones devoid of vegetation). Values range from negative (-43 to 0 mgCH4 m2 day), typical of soils with methanotrophic activity, up to 3500 mgCH4 m2 day in the most thermalized area. The preliminary estimate of the methane release from the area of Favara Grande is about 2.5 t/a. Extrapolation to the whole volcanic/geothermal system of Pantelleria gives about 10 t/a.
    Description: Published
    Description: Davos, Switzerland
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: open
    Keywords: soil gases ; methane output ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Poster session
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  • 10
    Publication Date: 2017-04-04
    Description: On February 27, 2007 a new eruption started at Stromboli that lasted until April 2 and included a paroxysmal explosion on March 15. Geochemical monitoring carried out over several years revealed some appreciable variations that preceded both the eruption onset and the explosion. The carbon dioxide (CO2) flux from the soil at Pizzo Sopra La Fossa markedly increased a few days before the eruption onset, and continued during lava effusion to reach its maximum value (at 90,000 g m−2 d−1) a few days before the paroxysm. Almost contemporarily, the δ13CCO2 of the SC5 fumarole located in the summit area increased markedly, peaking just before the explosion (δ13CCO2~−1.8‰). Following the paroxysm, helium (He) isotopes measured in the gases dissolved in the basal thermal aquifer sharply increased. Almost contemporarily, the automatic station of CO2 flux recorded an anomalous degassing rate. Also temperatures and the vertical thermal gradient, which had been measured since November 2006 in the soil at Pizzo Sopra La Fossa, showed appreciable variabilities that lasted until the end of the eruption. The geochemical variations indicated the degassing of a new batch of volatile-rich magma that preceded and probably fed the paroxysm. The anomalous 3He/4He ratio suggested that the ascent of a second batch of volatile-rich magma toward the surface was probably responsible of the resumption of the ordinary activity. A comparison with the geochemical variations observed during the 2002–2003 eruption indicated that the 2007 eruption was less energetic.
    Description: Published
    Description: 246-254
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: geochemistry ; eruption ; dissolved gases ; Stromboli ; volcanic activity ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 11
    Publication Date: 2017-04-04
    Description: Electric resistivity tomography (ERT), self-potential (SP), soil CO2 flux, and temperature are used to study the inner structure of La Fossa cone (Vulcano, Aeolian Islands). Nine profiles were performed across the cone with a measurement spacing of 20 m. The crater rims of La Fossa cone are underlined by sharp horizontal resistivity contrasts. SP, CO2 flux, and temperature anomalies underline these boundaries which we interpret as structural limits associated to preferential circulation of fluids. The Pietre Cotte crater and Gran Cratere crater enclose the main hydrothermal system, identified at the centre of the edifice on the base of low electrical resistivity values (b20 Ω m) and strong CO2 degassing, SP, and temperature anomalies. In the periphery, the hydrothermal activity is also visible along structural boundaries such as the Punte Nere, Forgia Vecchia, and Palizzi crater rims and at the base of the cone, on the southern side of the edifice, along a fault attributed to the NW main tectonic trend of the island. Inside the Punte Nere crater, the ERT sections show an electrical resistive body that we interpret as an intrusion or a dome. This magmatic body is reconstructed in 3D using the available ERT profiles. Its shape and position, with respect to the Pietre Cotte crater fault, allows replacing this structure in the chronology of the development of the volcano. It corresponds to a late phase of activity of the Punte Nere edifice. Considering the position of the SP, soil CO2 flux, and temperature maxima and the repartition of conductive zones related to hydrothermal circulation with respect to the main structural features, La Fossa cone could be considered as a relevant example of the strong influence of preexisting structures on hydrothermal fluid circulation at the scale of a volcanic edifice.
    Description: Published
    Description: 231-245
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: JCR Journal
    Description: partially_open
    Keywords: electrical resistivity ; self-potential ; soil CO2 degassing ; temperature ; fluid circulation ; hydrothermal system ; structural boundary ; Vulcano ; La Fossa cone ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring ; 03. Hydrosphere::03.03. Physical::03.03.02. General circulation ; 04. Solid Earth::04.01. Earth Interior::04.01.01. Composition and state ; 04. Solid Earth::04.02. Exploration geophysics::04.02.07. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 12
    Publication Date: 2017-04-04
    Description: The Pleistocene history of climate control on sedimentation in the Southern Alps-Po Plain system, northern Italy, was reconstructed using an integrated magnetostratigraphic, palynological, and petrographical approach on a 47-m-deep core. The core mainly consists of lacustrine sediments pertaining to the Bagaggera sequence, deposited at the foothills of the Southern Alps during the late Matuyama subchron (0.99–0.78 Ma). At that time, climate worsened globally and locally it caused the progradation of an alluvial fan unit onto the nearby Po Plain, triggering lake formation by damming of a tributary valley. These new data are used in conjunction with data from the literature to highlight and track the effects of climate forcing on sedimentation during the late Matuyama subchron in different orographic and geodynamic settings of the Southern Alps-Po Plain system as part of the greater Alpine area. We found that the episodes of alluvial fan and braidplain progradation observed in the southern foreland of the Alps during the late Matuyama global cooling seem broadly synchronous with the deposition of most of the so-called Günz and Älterer Deckenschotter deposits in the northern forelands of the Alps as well as with the first major waxing of the Alpine valley glaciers, possibly around the Marine Isotope Stage 22 (~0.87 Ma).
    Description: In press
    Description: 3.2. Tettonica attiva
    Description: JCR Journal
    Description: reserved
    Keywords: Pleistocene ; magnetostratigraphy ; pollen analysis ; sand petrography ; Alps ; Po Plain ; lacustrine sequence ; alluvial fan ; 02. Cryosphere::02.03. Ice cores::02.03.05. Paleoclimate ; 04. Solid Earth::04.04. Geology::04.04.02. Geochronology ; 04. Solid Earth::04.04. Geology::04.04.08. Sediments: dating, processes, transport ; 04. Solid Earth::04.04. Geology::04.04.10. Stratigraphy ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 13
    Publication Date: 2017-04-04
    Description: An infrared absorption spectroscopy remote sensing technique was used to determine the S02/HCl ratio in fumarolic plumes at Vulcano, Italy. The measurements were made from the southern crater rim of Fossa Grande Crater, about 400 m from the fumarolic area in the crater. Infrared absorption spectra of HCl and SO, were observed for four fumaroles a few tens of metres apart using the hot fumarolic surface as an infrared light source. The measured S02/HCl ratios in the FA, F47, FW and lower parti of the F21 fumaroles were 4.5-5.4, 3.5, 9.5-11.2 and 5.8 respectively. The S02/HCl ratio of the FA fumarole was higher than that of the gas collected directly in the fumarolic vent (S02/HCl ratio = 2.9), and was closer to the S~,,,,,,/HCl ratio (= 4.6) of the collected gas. Our results show that the SO,/HCl ratios of two fumaroles only a few tens of metres apart exhibits differences of about twofold. This suggests that this remote monitoring technique is capable of detecting spatial distribution in the S02/HCl ratios of volcanic plumes. Because temporal variations in S/Cl ratios can provide precursory signals for volcanic eruptions [l-31, this remote sensing technique can used efficiently for evaluation of volcanic activity.
    Description: Published
    Description: 219-224
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: open
    Keywords: Gas chemistry ; FTIR ; Volcano ; fumaroles ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 14
    Publication Date: 2017-04-04
    Description: Methane (CH4) emanating from a continental volcanichydrothermal system in Nisyros, Greece, is processed through the abiogenic reduction of mantle- and marine limestonederived CO2 [1]. Evidence for the occurrence of abiogenic hydrothermal reduction of CO2 is from the chemical and carbon isotopic equilibrium patterns. We have further characterized this abiogenic methane (C1) source for the concentrations of ethane (C2) and propane (C3), as well as for the hydrogen isotopic composition of CH4, H2O, H2 and H2S. C1/C2+ ratios are significantly higher than those typically observed for purely thermogenic sources. Hydrocarbon distribution ratios for other continental-hydrothermal sources rich in CO2 are comparable to those of the Nisyros fumaroles implying that abiogenic methane might be significantly more widespread than previously assumed [2]. Relative concentrations of hydrocarbons in continental-hydrothermal discharges are even indistinguishable from those measured in ultramafic hydrothermal emissions. The fact that redox conditions do not seem to exert any control on the relative concentrations of hydrocarbons in hydrothermal emissions in general, implies that the same two sources account for hydrocarbon production in continental and ultramafic environments. One source generates methane exclusively through the selective abiogenic reduction of CO2 (Sabatierreaction). The other source produces minor amounts of methane, ethane and propane by a random process and represents either the thermal cracking of organic matter or the polymerization starting from methane. Hydrogen isotope partitioning between H2O, H2S, H2 and CH4 in Nisyros fumaroles reveals that isotopic exchange rates are highest for H2O-H2S followed by H2O-H2. In contrast to H2 and H2S, the hydrogen isotopic composition of methane exhibits almost no local variations. This is in agreement with its predominantly abiogenic hydrothermal origin and with the low temperature sensitivity of the hydrogen isotope fractionation factor between water vapor and methane.
    Description: Published
    Description: Davos, Switzerland
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: open
    Keywords: hydrothermal gases ; methane ; ethane ; propane ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Oral presentation
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  • 15
    Publication Date: 2017-04-04
    Description: The origin of forces driving the deformation of the continental crust near subduction zones and especially in backarc regions is debated. Thiswork is based on a compilation of SKS fast splitting directions that give an image of flowlines in themantle around theMediterranean subduction zones and a comparisonwith stretching and shear directions in metamorphic core complexes that show the pattern of deformation at the scale of the middle and lower crusts.We find that : (1) the two sets of directions are parallel in the three main backarc regions, namely the Alboran Sea, the Tyrrhenian Sea and the Aegean Sea showing that the lithosphere deformswith the samedirection of stretching in the crust and themantle, suggesting that (2) crustal deformation ismainly driven frombelowby slab retreat, and (3) the lithospheric fabric is reset within a few millions of years in backarc environments.
    Description: Published
    Description: 198–209
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: JCR Journal
    Description: reserved
    Keywords: subduction ; seismic anisotropy ; backarc extension ; slab retreat ; stretching lineation ; metamorphic core complexes ; Mediterranean ; Aegean ; Tyrrhenian ; Alboran ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 16
    Publication Date: 2017-04-04
    Description: The Early/Middle Eocene (Ypresian/Lutetian) transition is represented by a hiatus in many North European sections, including those in which the classic stratotypes were originally defined. However, the Global Stratotype Section and Point of the Lutetian Stage, which is still pending definition, should be placed at a globally correlatable event included within that unrepresented interval. The Pyrenean Eocene outcrops display sedimentary successions that offer the rare opportunity to analyse the Ypresian/Lutetian boundary interval in almost continuous sections and in very different settings. Seven reference stratigraphic sections were selected on the basis of their quality and correlated by means of biomagnetostratigraphic data. This correlation framework casts light on the sequence of chronostratigraphic events that characterize the Ypresian/Lutetian boundary interval, which may prove useful in defining the main correlation criterion of the base of the Lutetian. All of the Pyrenean sections show a similar sedimentary evolution, despite being up to 350 km apart from each other, containing deposits of different origins (intrabasinal carbonate sediments, siliciclastic sediments sourced from the Iberian plate, and terrigenous sediments sourced from the uplifting Pyrenees) and despite having been accumulated in different sedimentary environments (from continental to deep marine) and in different geodynamic settings (piggy-back basin, foreland basin and cratonic margin). This common evolution can be readily interpreted in terms of a sea-level driven depositional sequence whose lowstand and transgressive systems tracts are included within the Ypresian/Lutetian boundary interval. The Pyrenean Ypresian/Lutetian depositional sequence can reasonably be correlated with depositional sequences from classic North European areas, shedding light on the palaeoenvironmental history which in those areas has not been recorded. Furthermore, these depositional sequences may possibly correlate with others from the Antarctic Ocean and from New Jersey, as well as with oceanic temperature variations, suggesting that they might be the result of climatically-driven glacioeustatic sea-level changes. Should this hypothesis prove correct, it would confirm previous suggestions that the onset of Antarctic glaciations needs to be backshifted to the late Ypresian at least.
    Description: Published
    Description: 313-332
    Description: 2.2. Laboratorio di paleomagnetismo
    Description: JCR Journal
    Description: reserved
    Keywords: Eocene ; Lutetian ; Chronostratigraphy ; Sequence stratigraphy ; Climate ; Pyrenees ; 03. Hydrosphere::03.01. General::03.01.06. Paleoceanography and paleoclimatology ; 04. Solid Earth::04.04. Geology::04.04.10. Stratigraphy ; 04. Solid Earth::04.05. Geomagnetism::04.05.02. Geomagnetic field variations and reversals ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 17
    Publication Date: 2017-04-04
    Description: Nitrogen isotopes , N2/36Ar and 3He/4He were measured in volcanic fluids within different geodynamic settings. Subduction zones are represented by Aeolian archipelago, Mexican volcanic belt and Hellenic arc, spreading zones – by Socorro island in Mexico and Iceland and hot spots by Iceland and Islands of Cabo Verde. The δ15N values, corrected for air contamination of volcanic fluids, discharged from Vulcano Island (Italy), highlighted the presence of heavy nitrogen (around +4.3 ±0.5‰). Similar 15N values (around +5‰), have been measured for the fluids collected in the Jalisco Block, that is a geologically and tectonically complex forearc zone of the northwestern Mexico [1]. Positive values (15N around +3‰) have been also measured in the volcanic fluids discharged from Nysiros island located in the Ellenic Arc characterized by subduction processes. All uncorrected data for the Socorro island are in the range of -1 to -2‰. The results of raw nitrogen isotope data of Iceland samples reveal more negative isotope composition (about -4.4‰). On the basis of the non-atmospheric N2 fraction (around 50%) the corrected data of 15N for Iceland are around -16‰, very close to the values proposed by [2]. In a volcanic gas sample from Fogo volcano (Cabo Verde islands) we found a very negative value: -9.9‰ and -15‰ for raw and corrected values, respectively.
    Description: Geochimica et Cosmochimica Acta
    Description: Published
    Description: Davos, Switzerland
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: open
    Keywords: Nitrogen Isotopes ; Helium Isotopes ; Volcanic fluids ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Poster session
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  • 18
    Publication Date: 2017-04-04
    Description: Chemical and isotopic analyses of the main gas manifestations of the island of Pantelleria (Italy) were used to gain insight on the origin of the released methane. Results indicate that the most probable origin is through abiogenic reactions within the hydrothermal system. Methane and CO2 flux measurements from the soils were made with the accumulation chamber method in an area of about 0.015 km2 within the main fumarolic area of the island (Favara Grande). The 23 measurements range from –34 to 3550 mg m-2 d-1 for CH4 and from 0.6 to 379 g m-2 d-1 for CO2. The relationships between CH4 and CO2 fluxes and the CH4/CO2 ratios in the gases collected between 25 and 100 cm depth provide evidence for methanotrophic processes within the soils. Methane output for the surveyed area was calculated in 2.5 t a-1 and extrapolated to about 5-10 t a-1 for the entire volcanic/hydrothermal system of the island. Previous higher estimates of the CH4 output at Pantelleria (Etiope et al., 2007 - J. Volcanol. Geotherm. Res., 165, 76 – 86) were based on soil CO2 output and CH4/CO2 ratios in fumarolic gases; the present work provides the first direct CH4 flux data and it suggests that methanotrophic activity in the soil could be substantial in reducing the CH4 emission to the atmosphere.
    Description: Published
    Description: 147-157
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: reserved
    Keywords: hydrothermal systems ; gas geochemistry ; isotope composition ; methane output ; methanotrophic consumption ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 19
    Publication Date: 2017-04-04
    Description: Volcanic volatiles and aerosol emitted into the atmosphere ultimately fall on the Earth’s surface as wet or dry deposition, and they can influence the environment and the ecosystems at local and regional scales. Therefore, atmospheric deposition plays a key-role in the geochemical cycles, redistributing volcanogenic elements to the ground. For this reason, estimating the volcanogenic trace element fluxes from the atmosphere to the surface is necessary for a better knowledge of the environmental impact of the volcanic emissions. Nevertheless, from a literature review, we have recognized the scarcity of investigation on trace element deposition in the surroundings of active volcanoes. Here, we present a chemical characterization of bulk deposition around Mt. Etna, Italy, including both major and many trace elements. Bulk depositions were collected approximately fortnightly, from April 2006 to December 2007, using a network of five rain gauges, located at various altitudes on the upper flanks around the summit craters of the volcano. For most elements highest concentrations have been found close to the emission vent, confirming the prevailing volcanic contribution to rainwater composition close to the summit craters. Comparison with contemporaneously collected plume emissions shows that deposition processes produce no evident element-to-element fractionation. By contrast, comparison with whole rock composition indicates a contrasting behaviour between volatile elements, which are highly-enriched in rainwater, and refractory elements, which have low rainwater/whole rock concentration ratios. Chemical concentrations in bulk deposition were used to estimate the deposition rates of a large suite of elements. Deposition rates for volatile trace elements like Se, As, and Cd range from 1.7, 1.2 and 0.9 µg m-2 day-1 nearby to the summit vents, to 0.5, 0.3, and 0.1 µg m-2 day-1 at the local background site on the upwind western sector.
    Description: Published
    Description: Davos, Switzerland
    Description: 4.4. Scenari e mitigazione del rischio ambientale
    Description: open
    Keywords: trace metals ; atmospheric deposition ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.08. Risk::05.08.01. Environmental risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 20
    Publication Date: 2020-11-19
    Description: We report on structural and anisotropy of magnetic susceptibility (AMS) results from the Upper Miocene sediments of the Amantea basin, located on the Tyrrhenian coast of the Calabrian Arc (Southern Italy). The stratigraphic succession of the basin is organized in three depositional sequences, separated by two major angular unconformities. Detailed geologica1 mapping and structural analysis demonstrate that the stratigraphic evolution of the Amantea basin is strongly controlled by a synsedimentary extensional tectonic regime. Severa1 NNE-SSW-trending norma1 fault arrays with large scatter in inclination values have been interpreted as due to a domino faulting mechanism, consistent with a WNW-ESE stretching direction. AMS data have been obtained for 13 sites, both in the not constrained in age first depositional sequence (3 sites), and in the upper Tortonian-lower Messinian clays from the second depositional sequence (10 sites). Al1 the sites show a strong magnetic foliation parallel to the bedding planes, and a well defined magnetic lineation subparallel to the local bedding dip directions. The magnetic lineations cluster around a WNW-ESE trend and are parallel to the stretching directions inferred by fault-slip analysis and basin architecture. These new data then confirm the possibility to use the magnetic lineation to map the strain trajectory in weakly deformed extensional sedimentary basins. Paleomagnetic data (from previous studies) show that the whole Calabrian block underwent a 15°-20° clockwise rotation probably in the Pleistocene, postdating the extensional tectonic events which controlled the Amantea basin geometry. Therefore we suggest for the Amantea basin an original E-W-oriented stretching direction, which may be considered as the older extensional direction characterizing the Late Miocene evolution of the southern Tyrrhenian Sea domain.
    Description: Published
    Description: 33-49
    Description: JCR Journal
    Description: reserved
    Keywords: magnetic fabric ; extentional tectonics ; Miocene ; Calabrian Arc ; Italy ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 21
    Publication Date: 2020-11-26
    Description: During the July^August 2001 eruption of Mt. Etna development of extensional fractures/faults and grabens accompanied magma intrusion and subsequent volcanic activity. During the first days of the eruption, we performed an analysis of attitude, displacement and propagation of fractures and faults exposed on the ground surface in two sites, Torre del Filosofo and Valle del Leone, located along the same fracture system in the region surrounding the Valle del Bove depression on the eastern flank of Mt. Etna. Fractures and faults formed as the consequence of a shallow intruding dyke system that fed the several volcanic centres developed along the fracture system. The investigated sites differ in slope attitude and in geometrical relationships between fractures and slopes. In particular, the fracture system propagated parallel to the gentle slope (67‡ dip) in the Torre del Filosofo area, and perpendicular to the steep slope (V25‡ dip) in the Valle del Leone area. In the Torre del Filosofo area, slight graben subsidence and horizontal extension of the ground surface by about 3 m were recorded. In the Valle del Leone area, extensional faulting forming a larger and deeper graben with horizontal extension of the ground surface by about 10 m was recorded. For the Valle del Leone area, we assessed a downhill dip of 14‡ for the graben master fault at the structural level beneath the graben where the fault dip shallows. These results suggest that dyke intrusion at Mount Etna, and particularly in the region surrounding the Valle del Bove depression, may be at the origin of slope failure and subsequent slumps where boundary conditions, i.e. geometry of dyke, slope dip and initial shear stress, amongst others, favour incipient failures.
    Description: Published
    Description: 281-294
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 3.2. Tettonica attiva
    Description: 3.5. Geologia e storia dei sistemi vulcanici
    Description: 3.6. Fisica del vulcanismo
    Description: JCR Journal
    Description: reserved
    Keywords: dykes ; extensional fractures ; grabens ; slope failures ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.05. Stress ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
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  • 22
    Publication Date: 2021-01-07
    Description: The CO2 degassing process from a large area on the Tyrrhenian side of central Italy, probably related to the input into the upper crust of mantle fluids, was investigated in detail through the geochemical study of gas emissions and groundwater. Mass-balance calculations and carbon isotopes show that over 50% of the inorganic carbon in regional groundwater is derived from a deep source highlighting gas−liquid separation processes at depth. The deep carbonate−evaporite regional aquifer acts as the main CO2 reservoir and when total pressure of the reservoir fluid exceeds hydrostatic pressure, a free gas phase separates from the parent liquid and escapes toward the surface generating gas emissions which characterise the study area. The distribution of the CO2 flux anomalies and the location of high PCO2 springs and gas emissions suggest that the storage and the expulsion of the CO2 toward the atmosphere are controlled by the geological and structural setting of the shallow crust. The average CO2 flux and the total amount of CO2 discharged by the study area were computed using surface heat flow, enthalpy and CO2 molality of the liquid phase circulating in the deep carbonate−evaporite aquifer. The results show that the CO2 flux varies from 1×104 mol y−1 km−2 to 5×107 mol y−1 km−2, with an average value of 4.8×106 mol y−1 km−2, about five times higher than the value of 1×106 mol y−1 derived by Kerrick et al. [Kerrick, D.M., McKibben, M.A., Seward, T.M., Caldeira, K., 1995. Convective hydrothermal CO2 emission from high heat flow regions. Chem. Geol. 121, 285–293] as baseline for terrestrial CO2 emissions. The total CO2 discharged from the study area is 0.9×1011 mol y−1, confirming that Earth degassing from Tyrrhenian central Italy is a globally relevant carbon source
    Description: Published
    Description: 89–102
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Degassamento naturale
    Description: JCR Journal
    Description: reserved
    Keywords: Earth degassing ; carbon dioxide ; CO2 flux ; groundwater ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 23
    Publication Date: 2020-12-14
    Description: This paper presents a new methodology for studying the evolution of curved mountain belts by means of paleomagnetic analyses performed on analogue models. Eleven models were designed aimed at reproducing various tectonic settings in thin-skinned tectonics. Our models analyze in particular those features reported in the literature as possible causes for peculiar rotational patterns in the outermost as well as in the more internal fronts. In all the models the sedimentary cover was reproduced by frictional low-cohesion materials (sand and glass micro-beads), which detached either on frictional or on viscous layers. These latter were reproduced in the models by silicone. The sand forming the models has been previously mixed with magnetite-dominated powder. Before deformation, the models were magnetized by means of two permanent magnets generating within each model a quasi-linear magnetic field of intensity variable between 20 and 100 mT. After deformation, the models were cut into closely spaced vertical sections and sampled by means of 1x1-cm Plexiglas cylinders at several locations along curved fronts. Care was taken to collect paleomagnetic samples only within virtually undeformed thrust sheets, avoiding zones affected by pervasive shear. Afterwards, the natural remanent magnetization of these samples was measured, and alternating field demagnetization was used to isolate the principal components. The characteristic components of magnetization isolated were used to estimate the vertical-axis rotations occurring during model deformation. We find that indenters pushing into deforming belts from behind form non-rotational curved outer fronts. The more internal fronts show oroclinal-type rotations of a smaller magnitude than that expected for a perfect orocline. Lateral symmetrical obstacles in the foreland colliding with forward propagating belts produce non-rotational outer curved fronts as well, whereas in between and inside the obstacles a perfect orocline forms only when the ratio between obstacles’ distance and thickness of the cover is greater than 10. Finally, when a belt collides with an obstacle in the foreland oblique to the shortening direction the outer front displays rotations opposite in sign to oroclinal-type rotations, whereas the internal fronts seem to assume an "oroclinal type" rotational pattern. Furthermore rotation is easier in laterally unconfined models, i.e. when the wedge can "escape" laterally. The results from our models may be useful when compared to paleomagnetic rotations detected in natural arcs. In these cases, our results may allow for better understanding the tectonic setting controlling the genesis of curved mountain fronts, as is the case of the Gela Nappe of Sicily we compare with some of our models.
    Description: Published
    Description: 633-654
    Description: JCR Journal
    Description: reserved
    Keywords: paleomagnetism ; tectonic rotations ; physical models ; arcuate belts ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 24
    Publication Date: 2021-05-17
    Description: Papandayan is a stratovolcano situated in West Java, Indonesia. Since the last magmatic eruption in 1772,only few hydrothermal explosions have occurred. An explosive eruption occurred in November 2002 and ejected ash and altered rocks. The altered rocks show that an advanced argillic alteration took place in the hydrothermal system by interaction between acid fluids and rocks. Four zones of alteration have been defined and are limited in extension and shape along faults or across permeable structures at different levels beneath the active crater of the volcano. At the present time, the activity is centered in the northeast crater with discharge of low temperature fumaroles and acid hot springs. Two types of acid fluids are emitted in the crater of Papandayan volcano: (1) acid sulfate-chloride waters with pH between 1.6 and 4.6 and (2) acid sulfate waters with pH between 1.2 and 2.5. The water samples collected after the eruption on January 2003 reveal an increase in the SO4/Cl and Mg/Cl ratios. This evolution is likely explained by an increase in the neutralization of acid fluids and tends to show that water–rock interactions were more significant after the eruption. The evolution in the chemistry observed since 2003 is the consequence of the opening of new fractures at depth where unaltered (or less altered) volcanic rocks were in contact with the ascending acid waters. The high δ34S values (9–17‰) observed in acid sulfatechloride waters before the November 2002 eruption suggest that a significant fraction of dissolved sulfates was formed by the disproportionation of magmatic SO2. On the other hand, the low δ34S (−0.3–7‰) observed in hot spring waters sampled after the eruption suggest that the hydrothermal contribution (i.e. the surficial oxidation of hydrogen sulfide) has increased.
    Description: Published
    Description: 276-286
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: JCR Journal
    Description: reserved
    Keywords: Papandayan volcano ; Indonesia ; phreatic eruption ; hydrothermal system ; fluid geochemistry ; advanced argillic alteration ; gas geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
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  • 25
    Publication Date: 2020-11-17
    Description: TWODEE-2 is a FORTRAN 90 code based on previous code (TWODEE). It is designed to solve the shallow water equations for fluid depth, depth-averaged horizontal velocities and depth-averaged fluid density. The shallow layer approach used by TWODEE-2 is a compromise between the complexity of CFD models and the simpler integral models. It can be used for forecasting gas dispersion near the ground and/or for hazard assessment over complex terrains. The inputs to the model are topography, terrain roughness, wind measurements from meteorological stations and gas flow rate from the ground sources. Optionally the model can be coupled with the output of a meteorological processor which generates a zero-divergence wind field incorporating terrain effects. Model outputs are gas concentration, depth-averaged velocity, averaged cloud thickness and dose. The model can be a useful tool for gas hazard assessment by evaluating where and when lethal concentrations for humans and animals can be reached.
    Description: Published
    Description: 667-674
    Description: 6V. Pericolosità vulcanica e contributi alla stima del rischio
    Description: JCR Journal
    Description: reserved
    Keywords: Dense gas transport ; Fortran code ; Gas hazard ; Computational model ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 05. General::05.01. Computational geophysics::05.01.99. General or miscellaneous ; 05. General::05.08. Risk::05.08.01. Environmental risk
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  • 26
    Publication Date: 2017-04-04
    Description: Major and trace element and Sr–Nd–Hf–Pb isotopic data for the most primitive Tertiary lavas from the Veneto region (South-Eastern Alps, Italy) show the typical features of HIMU hotspot volcanism, variably diluted by a depleted asthenospheric mantle component (87Sr/86Sri=0.70306–0.70378; "Ndi=+3.9 to +6.8; "Hfi=+6.4 to +8.1, 206Pb/204Pbi=18.786–19.574). P-wave seismic tomography of the mantle below the Veneto region shows the presence of low-velocity anomalies at depth, which is consistent with possible upwellings of plume material. Between the depths of 100–250 km the velocity anomalies are approximately 2–2.5% slower than average, implying a temperature excess of about 220–280 K, in agreement with estimates for other mantle plumes in the world. In this context, the Veneto volcanics may represent the shallow expression of a mantle upflow. The presence of a HIMU-DM component in a collision environment has significant geodynamic implications. Slab detachment and ensuing rise of deep mantle material into the lithospheric gap is proposed to be a viable mechanism of hotspot magmatism in a subduction zone setting.
    Description: Published
    Description: 563–590
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: JCR Journal
    Description: reserved
    Keywords: trace-element ; isotopic composition ; alkali basalts ; central-Europe ; slab break-off ; plume ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 27
    Publication Date: 2017-04-04
    Description: One of the most challenging issues about the Tertiary–Quaternary alkaline magmatism spreading across the Euro-Mediterranean region is the assessment of both the nature of its mantle source and the mechanism responsible for the common HIMU-like (High μ=high 238U/204Pb) character of erupted lavas, enduring over about 100 million years in diverse tectonic environments. In this paper we try to reconcile geochemical and geophysical data through a multidisciplinary investigation on geochemistry, timing and locations of the main Na-rich alkaline volcanic centers, seismic tomographic images and plate kinematics. We propose that the common component of the Euro-Mediterranean mantle derives from a contamination episode triggered by the rise of the Central Atlantic Plume (CAP) head. Plate reconstruction shows that at late Cretaceous- Paleocene time the oldest magmatic centers of the Euro-Mediterranean region were located more than 2000 km SW of their present day position, in proximity of the CAP hot spot location, where seismic tomography detects a broad low seismic velocity region in the lower mantle. The northeastward migration of the Eurasian and African plates could have involved also part of the CAP contaminated mantle, which moved in the same direction being coupled to the lithospheric plates, thus explaining the presence of geochemically-uniform material spread in the sub-lithospheric Euro-Mediterranean mantle. During the Tertiary, regional-scale convection and related processes such as rifting, back-arc spreading, slab detachment/windows, may have favored upwelling and partial melting of the frayed plume head material via adiabatic decompression, shaping the spatial and temporal distribution of HIMU-like volcanics. The growing supply of subducted lithosphere may explain as well the increase of crustal isotopic signatures of alkaline magmas with time. In our opinion, the Euro-Mediterranean upper mantle contamination can be eventually related to a global event occurred during the Cretaceous as a consequence of a mantle avalanche caused by the Tethys closure.
    Description: MIUR 2005-2007, prot. n. 2005055415_002, Poli G.
    Description: Published
    Description: 15–27
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: JCR Journal
    Description: partially_open
    Keywords: Cenozoic HIMU–OIB volcanism ; Euro-Mediterranean mantle ; geochemistry ; mantle tomography ; plate kinematics ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 28
    Publication Date: 2017-04-04
    Description: The controversial relationship between the orogenic segments of the Western Alps and the Northern Apennines is here explored integrating recently published 3D tomographic models of subduction with new and re-interpreted geological observations from the eclogitic domain of the Voltri Massif (Ligurian Alps, Italy), where the two belts joint each other. The Voltri Massif is here described as an extensional domain accommodating the opposing outward migration of the Alpine and Apennine thrust fronts, since about 30–35 Ma. Using tomographic images of the upper mantle and paleotectonic reconstructions, we propose that this extensional setting represents the surface manifestation of an along strike change in polarity of the subducted oceanic slab whose polarity changed laterally in space and in time. Our tectonic model suggests that the westward shift of the Alpine thrust front from the Oligocene onward was the consequence of the toroidal asthenospheric flow induced by the retreat of the Apenninic slab.
    Description: Published
    Description: 34–50
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: JCR Journal
    Description: reserved
    Keywords: Western Alps ; Northern Apennines ; Voltri Massif ; Tomography ; Kinematic reconstruction ; Extensional detachment ; Toroidal flow ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 29
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    Elsevier
    In:  Tanguy, J.C., Principe, C., Arrighi, S., 2005. Comment on “Historical measurements of the Earth’s magnetic field compared with remanence directions from lava flows in Italy over the last four centuries”. In: Lanza, R., Meloni, A., Tema, E. (Eds.), Phys Earth Planet. Inter. 152, 116–120.
    Publication Date: 2017-04-04
    Description: A comparison of the geomagnetic directions derived from lava flows of Italian volcanoes with those derived from direct historical measurements of the Earth’s magnetic field (Lanza et al., 2005) yielded two main results: (1) The general agreement between the two data sets already noted by previous authors (Rolph et al., 1987; Incoronato et al., 2002; Tanguy et al., 2003) was better substantiated. (2) The thermal remanent magnetization (TRM) direction of most flows was shown to deviate from the corresponding historical direction by a small angle θ. In most cases, this angle was larger than the experimental error on the TRM direction as given by the α95 semi-angle of confidence of Fisher’s statistics, i.e. θ 〉 α95. The conclusion drawn from these results was straightforward: a better understanding of the causes of the TRM deviation is required if we are to fully exploit the precision of TRM data from Italian volcanoes when their α95 value is less than 2.5–3.0◦.
    Description: Published
    Description: 121-124
    Description: 1.6. Osservazioni di geomagnetismo
    Description: 2.6. TTC - Laboratorio di gravimetria, magnetismo ed elettromagnetismo in aree attive
    Description: 3.4. Geomagnetismo
    Description: JCR Journal
    Description: reserved
    Keywords: Secular variation ; Historical magnetic measurements ; Thermal remanent magnetization ; Volcanic rocks ; 04. Solid Earth::04.05. Geomagnetism::04.05.02. Geomagnetic field variations and reversals ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism
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  • 30
    Publication Date: 2017-04-04
    Description: The age of spreading of the Liguro–Provençal Basin is still poorly constrained due to the lack of boreholes penetrating the whole sedimentary sequence above the oceanic crust and the lack of a clear magnetic anomaly pattern. In the past, a consensus developed over a fast (20.5–19 Ma) spreading event, relying on old paleomagnetic data from Oligo–Miocene Sardinian volcanics showing a drift-related 30° counterclockwise (CCW) rotation. Here we report new paleomagnetic data from a 10-mthick lower–middle Miocene marine sedimentary sequence from southwestern Sardinia. Ar/Ar dating of two volcanoclastic levels in the lower part of the sequence yields ages of 18.94±0.13 and 19.20±0.12 Ma (lower–mid Burdigalian). Sedimentary strata below the upper volcanic level document a 23.3±4.6° CCW rotation with respect to Europe, while younger strata rapidly evolve to null rotation values. A recent magnetic overprint can be excluded by several lines of evidence, particularly by the significant difference between the in situ paleomagnetic and geocentric axial dipole (GAD) field directions. In both the rotated and unrotated part of the section, only normal polarity directions were obtained. As the global magnetic polarity time scale (MPTS) documents several geomagnetic reversals in the Burdigalian, a continuous sedimentary record would imply that (unrealistically) the whole documented rotation occurred in few thousands years only. We conclude that the section contains one (or more) hiatus(es), and that the minimum age of the unrotated sediments above the volcanic levels is unconstrained. Typical back-arc basin spreading rates translate to a duration ≥3 Ma for the opening of the Liguro–Provençal Basin. Thus, spreading and rotation of Corsica–Sardinia ended no earlier than 16 Ma (early Langhian). A 16–19 Ma, spreading is corroborated by other evidences, such as the age of the breakup unconformity in Sardinia, the age of igneous rocks dredged west of Corsica, the heat flow in the Liguro–Provençal Basin, and recent paleomagnetic data from Sardinian sediments and volcanics. Since Corsica was still rotating/drifting eastward at 16 Ma, it presumably induced significant shortening to the east, in the Apennine belt. Therefore, the lower Miocene extensional basins in the northern Tyrrhenian Sea and margins can be interpreted as synorogenic "intra-wedge" basins due to the thickening and collapse of the northern Apennine wedge.
    Description: Published
    Description: 231-251
    Description: 2.2. Laboratorio di paleomagnetismo
    Description: JCR Journal
    Description: reserved
    Keywords: Paleomagnetism ; Corsica-Sardinia ; Liguro-Provençal Basin ; Back-arc spreading ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism
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  • 31
    Publication Date: 2017-04-04
    Description: We report on new paleomagnetic results obtained from 27 sites sampled in the Plio-Pleistocene sequences at the external front of the central-northern Apennines. Previous analyses of Miocene (Messinian) sediments indicated that the present shape of the northern Apenninic arc is due to the oroclinal bending of an originally straight belt oriented around N320° and that vertical axis rotations accompanied the migration of the thrust fronts toward the Adriatic foreland [F. Speranza et al., J. Geophys. Res. 102 (1997) 3153-3166]. We tried to provide new paleomagnetic constraints for the timing and rates of the oroclinal bending process during the Pliocene and the Pleistocene. The results suggest that CCW rotations observed in the northern part of the studied area are possibly younger than 3 Ma. No regional rotation is recorded in the Pliocene and Pleistocene sediments from the southern part of the study area, analogously to the Messinian sediments of the 'Acquasanta' domain of Speranza et al. [F. Speranza et al., J. Geophys. Res. 102 (1997) 3153-3166]. A local significant CCW rotation (23° ± 10°) is identified in the Early Pleistocene sediments that crop out along the Adriatic coast between Ascoli and Pescara, indicating differential motion of the thrust sheets. This rotation must be younger than 1.43 Ma.
    Description: Published
    Description: 243-257
    Description: 2.2. Laboratorio di paleomagnetismo
    Description: JCR Journal
    Description: open
    Keywords: paleomagnetism ; Apennines ; tectonics ; Pliocene ; Pleistocene ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics
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  • 32
    Publication Date: 2017-04-03
    Description: Ocean Drilling Program holes 744Aand 748B represent key sections for calibration of Southern Ocean Eocene-Oligocene biostratigraphic zonations. Sites 744 and 748 were above the carbonate compensation depth throughout this time interval and contain good planktonic foraminiferal, calcareous nannofossil, and diatom biostratigraphic records. In particular, the Southern Ocean diatom biostratigraphic zonation for the Oligocene critically hinges on calibration of these two holes. Previous low-resolution magnetostratigraphic studies at these sites were hampered by limited sampling and technical difficulties, which prompted our high-resolution reinvestigation of the magnetostratigraphy. Magnetic polarity zonations for holes 744Aand 748B were constructed after inspection of vector component plots at 1-cm stratigraphic intervals from continuous u-channel measurements. The magnetizations are generally stable and a robust polarity stratigraphy has been obtained for both holes. The increased resolution of our study and identification of persistent secondary overprints, which were not recognised in previous studies, suggests that the previously published interpretations need to be revised. Our magnetostratigraphic interpretations for both holes are constrained by foraminiferal and calcareous nannofossil datums, as well as by Sr isotope ages. We have calibrated four diatom datums, which are synchronous at the two studied sites, to the geomagnetic polarity timescale, including the first occurrence (FO) of Lisitzinia ornata (27.8 Ma), the FO of Rocella vigilans var. B (27.8 Ma), the FO of Cavitatus jouseanus (30.9 Ma) and the FO of Rhizosolenia oligocaenica (33.8 Ma). The synchroneity of these datums suggests that diatom biostratigraphy has considerable potential for Palaeogene biostratigraphic correlation in the Southern Ocean. Although the ages of some datums are obscured by an unconformity in Hole 744A, our age model from Hole 748B suggests age estimates for the last common occurrence of Rocella vigilans var. A(~29.0 Ma), the FO of Rocella vigilans var. A(30.0 Ma) and the FO of Rhizosolenia antarctica (33.2 Ma). It should also be noted that the last occurrence of the calcareous nannofossil Chiasmolithus altus occurs in Chron C8r rather than C8n in our revised magnetostratigraphic interpretation, which indicates that this datum is not diachronous between low and mid latitudes as had previously been suggested. Significant unconformities are documented in both holes, in the middle Oligocene and in the middle late Oligocene, respectively, which probably resulted from periods of enhanced circumpolar deep-water circulation.
    Description: Published
    Description: 145-168
    Description: 2.2. Laboratorio di paleomagnetismo
    Description: JCR Journal
    Description: reserved
    Keywords: Eocene ; Oligocene ; Ocean Drilling Program ; holes 744A and 748B ; Kerguelen Plateau ; Antarctica ; magnetostratigraphy ; biostratigraphy ; diatoms ; foraminifera ; calcareous nannofossils ; 03. Hydrosphere::03.01. General::03.01.06. Paleoceanography and paleoclimatology ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism
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  • 33
    Publication Date: 2017-04-04
    Description: The October 17 to November 5, 1999, eruption of Mount Etna’s Bocca Nuova crater emplaced a V15U106 m3 flow field. The eruption was characterized by 11 paroxysmal events during which intense Strombolian and lava fountain activity fed vigorous channelized PaPa flows at eruption rates of up to 120 m3 s31. Each paroxysm lasted between 75 and 450 min, and was separated by periods of less intense Strombolian activity and less vigorous (610 m3 s31) effusion. Ground-based, satellite- and model-derived volumetric data show that the eruption was characterized by two periods during which eruption rates and cumulative volume showed exponential decay. This is consistent with a scenario whereby the system was depressurized during the first eruptive period (October 17^23), repressurized during an October 24 pause, and then depressurized again during the second period (October 25^28). The imbalance between the erupted and supplied volumes mean that the two periods involved the collection of 1.5^5.7U106 m3 and 1.2^ 3.6U106 m3, respectively, or an increase in the time-averaged supply to 11.6^13.6 m3 s31 and 12.5^14.9 m3 s31. Two models are consistent with the observed episodic fountaining, derived volumetric trends and calculated volume imbalance: a magma collection model and a pulsed supply model. In the former case, depressurization of a shallow reservoir cause the observed volumetric trends and foam collapse at the reservoir roof powers fountaining. In the pulsing case, variations in magma flux account for pressurization^depressurization and supply the excess volume. Increases in rise rate and volatile flux, coupled with rapid exsolution during ascent, trigger fountaining. Limiting equations that define critical foam layer volumes and magma rise rates necessary for Hawaiian-style fountaining favor the latter model.
    Description: Published
    Description: 79-95
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 3.5. Geologia e storia dei sistemi vulcanici
    Description: 3.6. Fisica del vulcanismo
    Description: 4.3. TTC - Scenari di pericolosità vulcanica
    Description: JCR Journal
    Description: reserved
    Keywords: Etna ; lava fountaining ; eruption rates ; lava channel ; foam layers ; rise rates ; 04. Solid Earth::04.01. Earth Interior::04.01.99. General or miscellaneous ; 04. Solid Earth::04.01. Earth Interior::04.01.05. Rheology ; 04. Solid Earth::04.02. Exploration geophysics::04.02.99. General or miscellaneous ; 04. Solid Earth::04.02. Exploration geophysics::04.02.05. Downhole, radioactivity, remote sensing, and other methods ; 04. Solid Earth::04.02. Exploration geophysics::04.02.07. Instruments and techniques ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.11. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.02. Experimental volcanism ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.04. Thermodynamics ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
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  • 34
    Publication Date: 2017-04-04
    Description: The Piànico-Sèllere is a lacustrine succession from northern Italy that records a sequence of climatic transitions across two Pleistocene glacial stages. The intervening interglacial stage is represented by well-preserved varves with calcitic (summer) and clastic (winter) laminae. There is a tight coupling between climate-driven lithologic changes and magnetic susceptibility variations, and stable paleomagnetic components were retrieved from all investigated lithologies including the largely diamagnetic calcite varves. These components were used to delineate a sequence of magnetic polarity reversals that was interpreted as a record of excursions of the Earth’s magnetic field. Comparison of the magnetostratigraphic results with previously published data allows discussion of two possible models which have generated controversy regarding the age of the Piànico Formation. The data indicates that the Piànico Formation magnetostratigraphy correlates to geomagnetic field excursions across the Brunhes/Matuyama transition, and consequently the Piànico interglacial correlates to marine isotope stage 19. This correlation option is substantially consistent with K-Ar radiometric age estimates recently obtained from a tepha layer interbedded in the Piànico Formation. The alternative option, considering the Piànico interglacial correlative to marine isotope stage 11 within the Brunhes Chron as supported by tephrochronological dating reported in the literature, is not supported by the magnetostratigraphic results.
    Description: In press
    Description: 3.2. Tettonica attiva
    Description: JCR Journal
    Description: open
    Keywords: Piànico Formation ; Pleistocene ; magnetostratigraphy ; polarity excursions ; Brunhes Chron ; Southern Alps ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism
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  • 35
    Publication Date: 2017-04-04
    Description: El Chichón volcano (Chiapas, Mexico) erupted violently in March–April 1982, breaching through the former volcano–hydrothermal system. Since then, the 1982 crater has hosted a shallow (1–3.3 m, acidic (pH ∼ 2.2) and warm (∼ 30 °C) crater lake with a strongly varying chemistry (Cl/SO4=0–79 molar ratio). The changes in crater lake chemistry and volume are not systematically related to the seasonal variation of rainfall, but rather to the activity of near-neutral geyser-like springs in the crater (Soap Pool). These Soap Pool springs are the only sources of Cl for the lake. Their geyser-like behaviour with a long-term (months to years) periodicity is due to a specific geometry of the shallow boiling aquifer beneath the lake, which is the remnant of the 1983 Cl-rich (24,000 mg/l) crater lake water. The Soap Pool springs decreased in Cl content over time. The zero-time extrapolation (1982, year of the eruption) approaches the Cl content in the initial crater lake,meanwhile the extrapolation towards the future indicates a zero-Cl content by 2009±1. This particular situation offers the opportunity to calculate mass balance and Cl budget to quantify the lake–spring system in the El Chichón crater. These calculations show that the water balance without the input of SP springs is negative, implying that the lake should disappear during the dry season. The isotopic composition of lake waters (δD and δ18O) coincide with this crater lake-SP dynamics, reflecting evaporation processes and mixing with SP geyser and meteoric water. Future dome growth, not observed yet in the post-1982 El Chichón crater, may be anticipated by changes in lake chemistry and dynamics.
    Description: Published
    Description: 237–248
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: JCR Journal
    Description: reserved
    Keywords: El Chichón volcano ; crater lake–Spring dynamics ; fluid geochemistry ; stable isotopes ; monitoring ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
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  • 36
    Publication Date: 2017-04-04
    Description: In this paper we present a collection of good quality shear wave splitting measurements in Southern Italy. In addition to a large amount of previous splitting measurements, we present new data from 15 teleseisms recorded from 2003 to 2006 at the 40 stations of the CAT/SCAN temporary network. These new measurements provide additional constraints on the anisotropic behaviour of the study region and better define the fast directions in the southern part of the Apulian Platform. For our analysis we have selected wellrecorded SKS phases and we have used the method of Silver and Chan to obtain the splitting parameters: the azimuth of the fast polarized shear wave (φ) and delay time (δt). Shear wave splitting results reveal the presence of a strong seismic anisotropy in the subduction system below the region. Three different geological and geodynamic regions are characterized by different anisotropic parameters. The Calabrian Arc domain has fast directions oriented NNE–SSW and the Southern Apennines domain has fast directions oriented NNW–SSE. This rotation of fast axes, following the arcuate shape of the slab, is marked by a lack of resolved measurements which occurs at the transition zone between those two domains. The third domain is identified in the Apulian Platform: here fast directions are oriented almost N–S in the northern part and NNE–SSW to ENE–WSW in the southern one. The large number of splitting parameters evaluated for events coming from different back-azimuth allows us to hypothesize the presence of a depth-dependent anisotropic structure which should be more complicated than a simple 2 layer model below the Southern Apennines and the Calabrian Arc domains and to constrain at 50 km depth the upper limit of the anisotropic layer, at least at the edge of Southern Apennines and Apulian Platform. We interpret the variability in fast directions as related to the fragmented subduction system in the mantle of this region. The trench-parallel φ observed in Calabrian Arc and in Southern Apennines has its main source in the asthenospheric flow below the slab likely due to the pressure induced by the retrograde motion of the slab itself. The pattern of φ in the Apulian Platform does not appear to be the direct result of the rollback motion of the slab, whose influence is limited to about 100 km from the slab. The anisotropy in the Apulian Platform may be related to an asthenospheric flow deflected by the complicated structure of the Adriatic microplate or may also be explained as frozen-in lithospheric anisotropy.
    Description: Published
    Description: 49-67
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: JCR Journal
    Description: partially_open
    Keywords: Shear wave splitting ; Subduction ; Mantle flow ; Southern Italy ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes ; 04. Solid Earth::04.01. Earth Interior::04.01.03. Mantle and Core dynamics ; 04. Solid Earth::04.06. Seismology::04.06.07. Tomography and anisotropy ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.06. Subduction related processes
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  • 37
    Publication Date: 2017-04-04
    Description: El Chichón crater lake appeared immediately after the 1982 catastrophic eruption in a newly formed, 1-km wide, explosive crater. During the first 2 years after the eruption the lake transformed from hot and ultraacidic caused by dissolution of magmatic gases, to a warm and less acidic lake due to a rapid “magmatic-tohydrothermal transition” — input of hydrothermal fluids and oxidation of H2S to sulfate. Chemical composition of the lake water and other thermal fluids discharging in the crater, stable isotope composition (δD and δ18O) of lake water, gas condensates and thermal waters collected in 1995–2006 were used for the mass-balance calculations (Cl, SO4 and isotopic composition) of the thermal flux from the crater floor. The calculated fluxes of thermal fluid by different mass-balance approaches become of the same order of magnitude as those derived from the energy-budget model if values of 1.9 and 2 mmol/mol are taken for the catchment coefficient and the average H2S concentration in the hydrothermal vapors, respectively. The total heat power from the crater is estimated to be between 35 and 60 MW and the CO2 flux is not higher than 150 t/day or ~200 gm−2 day−1.
    Description: Published
    Description: 472-481
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: JCR Journal
    Description: reserved
    Keywords: El Chichón ; crater lake ; mass-energy budget ; CO2 flux ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.02. Data dissemination::05.02.04. Hydrogeological data
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  • 38
    Publication Date: 2017-04-04
    Description: Recent developments in paleomagnetism and environmental magnetism provide new tools for the detailed correlation of climatically induced magnetic mineralogy changes in sedimentary sequences. Studies of these changes contribute to the reconstruction of climate history for the glacial^interglacial cycles of the Late Pleistocene and to the delineation of the range of natural variability for global climate during the past hundred thousands years. Here we show that sharp coercivity minima observed in fine-grained sediments from the continental rise of the western Antarctic Peninsula correlate to the major rapid cooling events of the northern Atlantic (Heinrich layers). We interpret such an environmental magnetic signal in terms of variations in deep sea diagenetic processes of sulfide formation, which reflect changes in the input of detrital organic matter controlled by sea-ice extent. With the inherent uncertainties in age controls, the sedimentary paleoclimatic markers of the two hemispheres are almost contemporaneous, but interhemispheric time lags or leads of the order of 1-2 kyr (such as those recently reported from the Greenland and Antarctic ice cores) are also compatible with the data.
    Description: Published
    Description: 65-80
    Description: 2.2. Laboratorio di paleomagnetismo
    Description: JCR Journal
    Description: reserved
    Keywords: paleomagnetism ; paleointensity ; Antarctica ; Heinrich events ; climatic correlation ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism
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  • 39
    Publication Date: 2017-04-04
    Description: Many of the mountain belts displaying a curved shape are "oroclines", i.e. are produced after progressive bending of an originally straight fold and thrust belt. The bending process was previously explained as a consequence of several possible events taking place in the crustal orogenic wedge, such as occurrence of obstacles, non-coaxial deformation, and mouvements on wrench faults. Recent paleomagnetic results from the northern Apenninic Arc document that this belt is properly an orocline and results from Late Messinian-Early Pliocene bending of a Messinian straight belt-foredeep system. Tomographic images in turn show the presence of a high-velocity body, interpreted as subducted slab, in the upper mantle beneath the northern Apennines, between 35 and 670 km depth. Down to 100 km, this body displays an arcuate shape which closely mirrors the geological outlines, while it appears to be straight (and parallel to the Messinian pre-rotated belt) at depth. We explore here the possibility that the arcuate shape of the northern Apennines is a consequence, closely following in time, on much deeper processes than previously suggested, i.e. the lateral bending of the subducting Adriatic plate.
    Description: Published
    Description: 53-64
    Description: JCR Journal
    Description: reserved
    Keywords: paleomagnetism ; seismic tomography ; Northern Apennines ; orocline ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism ; 04. Solid Earth::04.06. Seismology::04.06.07. Tomography and anisotropy ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics
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  • 40
    Publication Date: 2017-04-04
    Description: We report on the anisotropy of magnetic susceptibility (AMS) analyses of fine-grained sediments deposited during the Messinian in foredeep basins at the front of the northern Apenninic chain. The data refer to 32 sampling sites, mostly distributed in the fine-grained intervals of the Laga and Colombacci formations, extending along the belt for a total length of about 300 km. Rock magnetism analyses indicate that the magnetic susceptibility and its anisotropy are in most cases dominated by the paramagnetic minerals of the clay matrix. In order to delineate the contribution of the ferrimagnetic fraction to the overall susceptibility fabric, the anisotropy of the anhysteretic remanent magnetisation was investigated at some representative sites. The magnetic fabric of the studied sediments mostly reflects the effects of compaction, showing a predominant magnetic foliation parallel to the bedding piane. At all the sites a well distinct magnetic lineation was also found, which is parallel to the fold axes and thrust fronts, both at local and regional scales. This feature is maintained in sequences that differ for sedimentological character and age, implying that the magnetic lineation was produced by a mild tectonic overprint of the primary sedimentary-compactional fabric. The relationship between the magnetic lineation trends and the vertical axis rotations detected by Speranza et al. [Speranza, F., Sagnotti, L.. Mattei, M., 1997. J. Geophys. Res. 102, 3153-3166] indicates that the magnetic lineation formed during the compressive phases of the Messinian-early Pliocene, when the Apenninic front was almost rectilinear and oriented N32O°.
    Description: Published
    Description: 73-93
    Description: JCR Journal
    Description: reserved
    Keywords: magnetic anisotropy ; rock strain ; northern Apennines ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism
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  • 41
    Publication Date: 2017-04-04
    Description: A transect of three sites was drilled during Leg 188 of the Ocean Drilling Program (ODP), proximal to the East Antarctic Ice Sheet (EAIS) across the Prydz Bay continental shelf (Site 1166), slope (Site 1167), and rise (Site 1165). We present results of a palaeomagnetic and rock magnetic study of sediments recovered at sites 1165 and 1166. Magnetostratigraphic interpretations are presented for both holes and are mainly constrained by diatom and radiolarian biostratigraphies, interpreted in the light of recent refinements to Southern Ocean zonal schemes and datum calibrations for these microfossil groups. Site 1165 records a history of sedimentation on the continental rise extending back to earliest Miocene times (about 22 Ma). Several long-term changes characterise this record, including an overall trend of decreasing sedimentation rates from the bottom to the top of the hole. There is a progressive decrease in the sedimentation rate above about 308 mbsf (meters below sea floor), which is marked by a transition from dark-grey fissile claystones to greenish-grey diatom-bearing clays. At this transition, ice-rafted debris, sand grains, and total clay content also increase. The chronology presented here indicates a middle Miocene age (~14.3 Ma) for the lithological transition. Correlation to ODP Hole 747A from the Kerguelen Plateau suggests that this lithological transition coincides with the base of the Mi-3/3a δ18O event, which suggests palaeoclimatic control on middle Miocene sedimentation changes at Site 1165. Core recovery was poor at Site 1166. Consequently, the magnetostratigraphic data are of limited value. The deepest cores recovered at Site 1166 record brief intervals in the early history of the EAIS for the Prydz Bay region, extending back through the early stage of glaciation to pre-glacial times. An Early Cretaceous fluvio-lacustrine unit, lagoonal deposits and sandy fluvio-deltaic units of mid-late Eocene age contain a sporadic record of the transition from humid and mild conditions to cool temperate conditions.
    Description: Published
    Description: 69-100
    Description: 2.2. Laboratorio di paleomagnetismo
    Description: JCR Journal
    Description: reserved
    Keywords: magnetostratigraphy ; biostratigraphy ; Prydz Bay ; Antarctica ; Ocean Drilling Program ; sites 1165 and 1166 ; 03. Hydrosphere::03.01. General::03.01.06. Paleoceanography and paleoclimatology ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 42
    Publication Date: 2017-04-04
    Description: The 2001 eruption represents one of the most studied events both from volcanological and geophysical point of view on Mt. Etna. This eruption was a crucial event in the recent dynamic of the volcano, marking the passage from a period (March 1993 – June 2001) of moderate stability with slow, continuous flank sliding and contemporaneous summit eruptions, to a period (July 2001 to present) of dramatically increased flank deformations and flank eruptions. We show new GPS data and high precision relocation of seismicity in order to demonstrate the role of the 2001 intrusive phase in this change of the dynamic regime of the volcano. GPS data consist of two kinematic surveys carried out on 12 July, a few hours before the beginning of the seismic swarm, and on 17 July, just after the onset of eruptive activity. A picture of the spatial distribution of the sin-eruptive seismicity has been obtained using the HypoDD relocation algorithm based on the double-difference (DD) technique. Modeling of GPS measurements reveal a southward motion of the upper southern part of the volcano, driven by a NNW-SSE structure showing mainly left-lateral kinematics. Precise hypocenter location evidences an aseismic zone at about sea level, where the magma upraise was characterized by a much higher velocity and an abrupt westward shift, revealing the existence of a weakened or ductile zone. These results reveal how an intrusion of a dike can severely modify the shallow stress field, triggering significant flank failure. In 2001, the intrusion was driven by a weakened surface, which might correspond to a decollement plane of the portion of the volcano affected by flank instability, inducing an additional stress testified by GPS measurements and seismic data, which led to an acceleration of the sliding flanks.
    Description: In press
    Description: 1.1. TTC - Monitoraggio sismico del territorio nazionale
    Description: 1.3. TTC - Sorveglianza geodetica delle aree vulcaniche attive
    Description: 1.4. TTC - Sorveglianza sismologica delle aree vulcaniche attive
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 3.2. Tettonica attiva
    Description: 3.5. Geologia e storia dei sistemi vulcanici
    Description: 3.6. Fisica del vulcanismo
    Description: 4.2. TTC - Scenari e mappe di pericolosità sismica
    Description: 4.3. TTC - Scenari di pericolosità vulcanica
    Description: 4.4. Scenari e mitigazione del rischio ambientale
    Description: JCR Journal
    Description: reserved
    Keywords: Stress release ; Dike ; Volcano-tectonics ; Flank instability ; Mount Etna ; Instrumental monitoring ; 04. Solid Earth::04.01. Earth Interior::04.01.99. General or miscellaneous ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes ; 04. Solid Earth::04.02. Exploration geophysics::04.02.99. General or miscellaneous ; 04. Solid Earth::04.03. Geodesy::04.03.99. General or miscellaneous ; 04. Solid Earth::04.03. Geodesy::04.03.06. Measurements and monitoring ; 04. Solid Earth::04.03. Geodesy::04.03.07. Satellite geodesy ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.01. Earthquake geology and paleoseismology ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.06. Seismology::04.06.99. General or miscellaneous ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics ; 04. Solid Earth::04.06. Seismology::04.06.04. Ground motion ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 04. Solid Earth::04.07. Tectonophysics::04.07.99. General or miscellaneous ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.05. Stress ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
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  • 43
    Publication Date: 2017-04-04
    Description: Four groups of thermal springs with temperatures from 50 to 80 °C are located on the S–SW–W slopes of El Chichón volcano, a composite dome-tephra edifice, which exploded in 1982 with a 1 km wide, 160 m deep crater left. Very dynamic thermal activity inside the crater (variations in chemistry and migration of pools and fumaroles, drastic changes in the crater lake volume and chemistry) contrasts with the stable behavior of the flank hot springs during the time of observations (1974–2005). All known groups of hot springs are located on the contact of the basement and volcanic edifice, and only on the W–SW–S slopes of the volcano at almost same elevations 600–650 m asl and less than 3 km of direct distance from the crater. Three groups of near-neutral (pH≈6) springs at SW–S slopes have the total thermal water outflow rate higher than 300 l/s and are similar in composition. The fourth and farthest group on the western slope discharges acidic (pH≈2) saline (10 g/kg of Cl) water with a much lower outflow rate (b10 l/s). Water–rock interaction modeling of main types of the El Chichón thermal waters using regular log Q/K graphs (saturation indices vs temperature) showed maximum equilibrium temperature slightly higher than 200 °C. Acidic waters are equilibrated with some clay minerals at about 120 °C. Three main sources of the salinity of thermal water are suggested on the basis of mixing plots and isotopic data: a magmatic source for CO2, boron, sulfur and a limited part of Cl; volcanic rock source for the major cations and trace elements; the oil-bearing evaporitic basement source (oil-field brine?) for NaCl, Br, a part of Ca and some trace elements. All flank thermal springs end up in the river Rio Magdalena that has a variable seasonal flow rates from 4 to 20 m3/s. Any changes in the chemistry of springs must notably change the composition of the streams draining hot springs and eventually, Rio Magdalena. A monthly geochemical monitoring of Rio Magdalena and streams draining main hot springs would be a useful tool for surveying the activity of the volcano.
    Description: Published
    Description: 224–236
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: JCR Journal
    Description: reserved
    Keywords: volcano–hydrothermal system ; crater lake ; acidic water ; trace elements ; thermochemical modeling ; El Chichón volcano ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 44
    Publication Date: 2017-04-04
    Description: In this paper we will discuss a simplified thermodynamic description for the saturation of FeS, either liquid or solid, in magmatic melts. The Conjugated-Toop–Samis–Flood–Grjotheim model [Moretti R. and Ottonello G., 2005. Solubility and speciation of sulfur in silicate melts, the Conjugated-Toop–Samis–Flood–Grjotheim (CTSFG) model. Geochimica et Cosmochimica Acta, 69, 801–823] has furnished the theoretical reference frame, since it already accounts for the solubility of gaseous sulfur and the speciation and oxidation state of sulfur in silicate melts. We provide a new model to predict the saturation of magmatic silicate melts with an FeS phase that is internally consistent with these previous parameterizations. The derived model provides an effective sulfogeobarometer, which is superior with respect to previous models. For magmas rising from depth to surface, our appraisal of molar volumes of sulfur-bearing species in silicate melts allows us to model oxidation–reduction processes at different pressures, and sulfur concentrations for saturationwith either liquid or solid phases. In this respect, the nature of the oxygen fugacity buffer is critical. On the basis of model results on some typical compositions of volcanological interest, the sulfur contents at sulfide saturation (SCSS) have been calculated and the results duplicate the experimental observations that the SCSS is positively correlatedwith pressure forwatersaturated acidic melts and negatively correlated with pressure for water-poor basaltic melts. This new model provides fO2–fS2 pairs of FeS saturation of natural silicatemelts. In caseswhere the redox constraint is lacking, the model can be used to investigate whether the dissolved sulfur content approaches SCSS or not, and if so, to estimate at which fO2 value the silicate melt is saturated with a sulfide phase
    Description: Published
    Description: 286–298
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: 3.6. Fisica del vulcanismo
    Description: JCR Journal
    Description: reserved
    Keywords: Sulfur ; Silicate melt ; Iron sulfide ; Chemical thermodynamics ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.04. Thermodynamics ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks
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  • 45
    Publication Date: 2017-04-04
    Description: Using constraints from literature data on the petrology and texture of erupted material from Stromboli and geochemical measurements of gas emissions together with a model of gas solubility we construct a conceptual model of quiescent degassing for this volcano. We find that within a pressure range between 100 MPa and 50 MPa (∼3.6 km and ∼1.8 km depth respectively) vesiculating magma ascending within the conduit becomes permeable to gas flow and a transition from closed- to open-system degassing takes place. Above the transition, gas, rich in the most insoluble gases, flows up through degassing magma, and thereby becomes enriched in more soluble gases during ascent to the surface. The final gas emission is therefore a superposition of gases released from magma above the percolation transition and gas that has evolved in closed-system below the transition. Steady-state gas release from Stromboli can only be sustained via magma circulation, driven by the density variation between ascending vesiculating magma and descending degassed magma. By balancing the buoyant force of ascending vesiculating magma against the viscous resistance produced by travelling through descending, degassed magma in a simple flow model we determine that a cylindrical conduit diameter of 2.5–2.9 m produces the magma mass flow rate of 575 kg s−1, required to account for the observed quiescent SO2 gas flux on Stromboli of ∼2.3 kg s−1 (200 td−1).
    Description: Published
    Description: 46–60
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: JCR Journal
    Description: reserved
    Keywords: Stromboli ; gas ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 46
    Publication Date: 2017-04-03
    Description: Direct measurements of the Earth’s magnetic field in Italy since 1640 a.d. have been used to check the remanence directions derived from historically dated volcanic rocks of Etna and Vesuvius. Direct measurements consist of the records of L’Aquila and Pola geomagnetic observatories, the repeat stations of the Italian Magnetic Network and the data base of the Historical Italian Geomagnetic Data Catalogue. All have been relocated to the same reference site (Viterbo — lat. 42.45◦N, long. 12.03◦E) in order to draw a reference secular variation (SV) curve. The direction of the Earth’s field at Viterbo has also been calculated from the historical records (2000–1600) of ref. [Jackson, A., Jonkers, A.R.T., Walker, M.R., 2000. Four centuries of geomagnetic secular variation from historical records. Phil. Trans. R. Soc. London, Ser. A 358, 957–990] database. The remanence directions from Etna show a general agreement with the trend of the SV curve, although their inclination is usually lower than that from the direct measurement. The directions from Vesuvius are more scattered. Large discrepancies occur at both volcanoes and in some cases have been ascribed in the literature to poor geographic information, making it difficult to identify the flows actually emplaced during the eruptions reported in the chronicles. Closer examination shows that the great majority of the best-defined remanence directions (semi-angle of confidence α95 〈 2.5◦) deviate significantly from the geomagnetic direction measured at the time of the emplacement, the angle between the two directions being larger than the α95 value. The value of 2.5–3.0◦ can thus be regarded as a conservative evaluation of the error when dealing with dating Etna and Vesuvius lava flows older than 17th century, even when the accuracy attained in remanence measurements is higher. In default of a SV curve for Italy derived from archaeological artefacts, a further error in dating is introduced when reference is made to SV curves of other countries, even if well-established, as these are from regions too far from Italy (〉600 km) to confidently relocate magnetic directions.
    Description: Published
    Description: 97-107
    Description: 1.6. Osservazioni di geomagnetismo
    Description: 2.6. TTC - Laboratorio di gravimetria, magnetismo ed elettromagnetismo in aree attive
    Description: 3.4. Geomagnetismo
    Description: JCR Journal
    Description: reserved
    Keywords: Secular variation ; Historical magnetic measurements ; Thermal remanent magnetization ; Volcanic rocks ; 04. Solid Earth::04.02. Exploration geophysics::04.02.04. Magnetic and electrical methods ; 04. Solid Earth::04.05. Geomagnetism::04.05.02. Geomagnetic field variations and reversals ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism
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  • 47
    Publication Date: 2017-04-04
    Description: The analysis of the Messinian and Pliocene stratigraphy of the southern Bajo Segura Basin (Betic Cordillera, Spain) has revealed three highstand sedimentary phases (Messinian I, Messinian II, and Pliocene) bounded by two lowstand erosional surfaces (intra-Messinian and end-Messinian unconformities). The Messinian I highstand phase is characterized by the progradation of coastal and shallow marine sandstones (La Virgen Fm) over slope and pelagic-basin marls (Torremendo Fm). After this first phase, a fall in sea level brought about the intra-Messinian unconformity, a subaerial erosional surface with local accumulations of karstic breccias and caliche-like carbonate crusts. The Messinian II highstand phase is represented by sandy beaches and muddy lagoons (Garruchal Fm) correlative with shallow marine evaporites (San Miguel Fm); this second phase records the intra-Messinian reflooding of the basin, which characterizes the salinity crisis in the marginal basins of the Mediterranean. A new sea-level fall resulted in the end-Messinian unconformity, of which the most significant feature is the presence of a broad palaeovalley, c. 200 m deep, which, along its course, completely eroded the deposits of the Messinian II phase and part of the deposits of the Messinian I phase. The Pliocene highstand phase begins with coastal and shallow marine conglomerates and sandstones (La Pedrera Fm) which fill the deep part of the above-mentioned palaeovalley. These bottom deposits evolved gradually upwards towards pelagic marls (Hurchillo Fm), over which shallow marine and coastal sandstones prograded (Rojales Fm). This third phase records the flooding of the basin at the beginning of the Pliocene, when the salinity crisis ended in the marginal basins of the Mediterranean. The combination of calcareous nannoplankton biostratigraphy and magnetostratigraphy has confirmed that both the end of the sedimentation of the Messinian I phase, as well as the two lowstand erosional surfaces (intra- and end-Messinian unconformities) and also the onset of the Pliocene phase occurred in the chron C3r (c. 5.9–5.2 Ma). Under the assumption of the classical model of a desiccated deep basin, either of the two aforementioned erosional surfaces, or even both, could be correlative with the evaporites deposited in the abyssal parts of the Mediterranean.
    Description: Published
    Description: 267-288
    Description: 2.2. Laboratorio di paleomagnetismo
    Description: JCR Journal
    Description: reserved
    Keywords: Stratigraphy ; Magnetobiostratigraphy ; Messinian ; Pliocene ; Salinity crisis ; Mediterranean region ; 04. Solid Earth::04.04. Geology::04.04.08. Sediments: dating, processes, transport ; 04. Solid Earth::04.04. Geology::04.04.10. Stratigraphy ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism ; 04. Solid Earth::04.05. Geomagnetism::04.05.07. Rock magnetism
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  • 48
    Publication Date: 2017-04-04
    Description: We analyze the 1997–2006 seismicity of the transition zone between Southern and Central Apennines, which is one of the most active seismic areas of Italy. Our aim is to add information on the seismotectonic picture of this area. Seismic activity is characterized by single events with Mb3.0 and low magnitude (Mb4.0) seismic sequences (1997–98 and 2005) and swarms (1999, 2000 and 2001). Hypocenters are within the upper 15 km of the crust. The epicentral distribution of the relocated seismicity shows that single events prevalently align NW–SE along the Apennine chain axis. This seismicity is related to the main, NE–SW extension affecting the chain. Single events concentrate also: at the south of the seismogenetic source responsible for the 1915 earthquake, where the 2000 swarm occurred; between the faults of the 1984 and 1805 events, where the 2001 sequence developed; between the faults of the 1805 and 1688 events, where the 1997–1998 seismic sequence concentrated. The seismic swarms occurred in 1999, 2000 and 2005 are located inside the Ortona– Roccamonfina structural line, which strikes NNE–SSW and separates the Central Apennines from the Southern ones. The epicentral distribution of these swarms and focal mechanisms suggest the presence of active NE–SW faults moving in response to a NW–SE extension. The results of the strain analysis on 52 wellconstrained focal mechanisms evidence a prevailing NE–SW extension, corresponding to the large scale stress field acting in the Apennine Chain, and a second-order NW–SE extension. This last direction of extension was already observed in the 1997–98 and 2001 seismic sequences. The location of the NE–SW striking faults responsible for the seismic swarms suggest that some segments of the Ortona–Roccamonfina line are still active and move in response to both the NE–SW regional extension of Southern Apennines, and to a NW–SE striking longitudinal extension.
    Description: Published
    Description: 102-110
    Description: 1.1. TTC - Monitoraggio sismico del territorio nazionale
    Description: 3.1. Fisica dei terremoti
    Description: 3.2. Tettonica attiva
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: JCR Journal
    Description: reserved
    Keywords: Apennines ; seismicity ; 04. Solid Earth::04.04. Geology::04.04.01. Earthquake geology and paleoseismology ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.06. Seismology::04.06.99. General or miscellaneous ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.05. Stress ; 05. General::05.02. Data dissemination::05.02.02. Seismological data
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  • 49
    Publication Date: 2017-04-04
    Description: This work represents the first attempt to use anisotropy of magnetic susceptibility (AMS) analysis for the characterization of the magnetic fabric of Plio-Pleistocene sediments in the southern Apennines of Italy. The area examined, the Sant’Arcangelo basin, has undergone mild deformation during the Pleistocene. Analysis was carried out on 182 cores sampled at 15 sites in unmetamorphosed, weakly deformed clays and marly clays. The data identify a magnetic fabric of clearly depositional—compactional origin even though a partial contribution of tectonic deformation to the AMS is also recognizable at many sites. The results presented here are compared with the existing structural and sedimentary data. In particular, a close consistency is found between the overall orientation of magnetic lineations and the compressional directions indicated by previous meso-structural analysis. We suggest that the magnetic fabric detected here arises from a limited overprint of strain effects related to compressional episodes on a primary, sedimentary, fabric. This interpretation allowed us to resolve the bedding attitude where the clayey units appear homogeneous in the field, and hence to suggest the appropriate bedding correction in concomitant paleomagnetic analysis, and to estimate the orientation and the relative degree of deformation at each sampling site.
    Description: Published
    Description: 165-176
    Description: JCR Journal
    Description: reserved
    Keywords: magnetic anisotropy ; rock strain ; Sant'Arcangelo basin ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism
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  • 50
    Publication Date: 2017-04-04
    Description: Piston core LC07, located west of the Sicily Strait in the Mediterranean Sea, unambiguously records the Matuyama/ Brunhes (M/B) and the upper Jaramillo polarity reversals, with similar average sediment accumulation rates (SARs) for the Brunhes Chron (2.29 cm/kyr) and late Matuyama Chron C1r.1r (2.19 cm/kyr). We report a relative paleointensity record for the interval spanning the M/B boundary down into the Jaramillo Subchron, which is unique in the Mediterranean because existing records from this basin cover only the last 80 kyr. The average SAR in core LC07 is used to translate the depth-related paleointensity record to the time domain; the ratio of anhysteretic remanent magnetization to low-field magnetic susceptibility is climatically sensitive and is used to tune the age model. This correlation produces a good fit to the global ice volume model derived for summer insolation at 65°N. With this age model, a paleointensity minimum in association with the M/B boundary has a duration of about 4-5 kyr, while the directional change has a duration of 〈3 kyr. A second paleointensity minimum of similar duration is found about 16 kyr below the M/B boundary. This feature (precursor or 'dip' in the literature) has previously been recognized at the same time interval in many marine records, which reinforces the validity of our age model. Other relative paleointensity minima are found within chron C1r.1r, and, within the uncertainties of the respective age models, these minima coincide with those observed from the few published coeval paleointensity records. In particular, there is good correspondence between the ages of minima at about 0.92 and 0.89 Ma, which probably correlate with two geomagnetic excursions (Santa Rosa and Kamikatsura, respectively) that have been recorded in lava flows and dated using the 40Ar/39Ar technique. In contrast, a recently dated excursion at 0.83 Ma from La Palma seems to correspond to a paleointensity maximum. This observation is opposite to that expected and this excursion needs to be confirmed. In contrast to some recently published paleointensity records, spectral analysis of the LC07 record does not reveal identification of significant power at the orbital obliquity frequency.
    Description: Published
    Description: 327-341
    Description: 2.2. Laboratorio di paleomagnetismo
    Description: JCR Journal
    Description: reserved
    Keywords: paleointensity ; magnetic field ; Matuyama Chron ; Jaramillo Subchron ; Brunhes Chron ; Mediterranean Sea ; 04. Solid Earth::04.05. Geomagnetism::04.05.02. Geomagnetic field variations and reversals ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism
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  • 51
    Publication Date: 2017-04-04
    Description: Drilling offshore from Cape Roberts, Antarctica, has enabled recovery of a 1472-m cumulative record of late Eocene–early Miocene history of sedimentary basin development and climate change in the Western Ross Sea. In this paper, we synthesize the results of palaeomagnetic analyses carried out on the CRP-1, CRP-2 and CRP-3 sediment cores, and present a chronology for the recovered Eocene–Miocene succession. Stepwise demagnetization data demonstrate that secondary overprints have been successfully removed and that characteristic remanent magnetizations (ChRMs) have been clearly identified in most of the samples. A close sampling interval has allowed a detailed magnetic polarity stratigraphy to be established for the composite succession. Correlation with the geomagnetic polarity time scale (GPTS) has been constrained by a number of 40Ar/39Ar and 87Sr/86Sr ages, as well as by a recently developed Antarctic siliceous microfossil zonation, and by calcareous nannoplankton biostratigraphy. The basal sediments of the Eocene–Miocene succession rest unconformably on Devonian sandstones of the Beacon Supergroup. A basal sandstone breccia, which probably represents the onset of rifting in the Victoria Land Basin (VLB), is overlain by a succession of sandstones that are interbedded with thin conglomerate beds. These sediments give way to more clearly glacially influenced mudstones and diamictite facies in the mid Oligocene, and, by the Oligocene–Miocene boundary, coincident with the Mi-1 glaciation, a permanent glacial dominance was imprinted on the sedimentary record. Average sediment accumulation rates were initially rapid in the late Eocene–early Oligocene (up to 60 cm/k.y.), but reduced to only a few cm/k.y. in the early Miocene as basin subsidence slowed.
    Description: Published
    Description: 207-236
    Description: 2.2. Laboratorio di paleomagnetismo
    Description: 3.8. Geofisica per l'ambiente
    Description: JCR Journal
    Description: reserved
    Keywords: Antarctica ; Cape Roberts Project ; Cenozoic ; Chronology ; Magnetostratigraphy ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism
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  • 52
    Publication Date: 2017-04-04
    Description: During 2001–2005, Mount Etna was characterized by intense eruptive activity involving the emission of petrologically different products from several vents, which involved at least two types of magma with different degrees of evolution. We investigated the ratios and abundances for noble-gas isotopes in fluid inclusions trapped in olivines and pyroxenes in the erupted products. We confirm that olivine has the most efficient crystalline structure for preserving the pristine composition of entrapped gases, while pyroxene can suffer diffusive He loss. Both the minerals also experience noble gas air contamination after eruption. Helium isotopes of the products genetically linked to the two different magmas fall in the isotopic range typical of the Etnean volcanism. This result is compatible with the metasomatic process that the Etnean mantle is undergoing by fluids from the Ionian slab during the last ten kyr, as previously inferred by isotope and trace element geochemistry. Significant differences were also observed among olivines of the same parental magma that erupted throughout 2001–2005, with 3He/4He ratios moving from about 7.0 Ra in 2001 volcanites, to 6.6 Ra in 2004–2005 products. Changes in He abundances and isotope ratios were attributed to variations in protracted degassing of the same magma bodies from the 2001 to the 2004–2005 events, with the latter lacking any contribution of undegassed magma. The decrease in 3He/4He is similar to that found from measurements carried out every fifteen days during the same period in gases discharged at the periphery of the volcano. To our knowledge this is the first time that such a comparison has been performed so in detail, and provides strong evidence of the real-time feeding of peripheral emissions by magmatic degassing.
    Description: Published
    Description: 683-690
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: open
    Keywords: fluid inclusions ; noble gases ; helium isotopes ; magma degassing ; olivine ; pyroxene ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 53
    Publication Date: 2017-04-04
    Description: An extensive geochemical survey of the fluids released by the volcanic/geothermal system of Methana was undertaken. Gases were characterized based on the chemical and isotopic [helium (He) and carbon (C)] analysis of 27 samples. Carbon dioxide soil gas concentration and fluxes were measured at 179 sampling sites throughout the peninsula. Forty samples of thermal and cold groundwaters were also sampled and analysed to characterize the geochemistry of the aquifers. Gases of hydrothermal origin gave a preliminary geothermometric estimate of about 210 °C. The He-isotope composition indicated mantle contributions of up to 40%, and the C-isotope composition of CO2 indicated that it predominantly (〉90%) originated from limestone decomposition. The groundwater composition was suggestive of mixing between meteoric and hydrothermally modified sea-water endmembers and water–rock interaction processes limited to simple rock dissolution driven by an increased endogenous CO2 content. All of the thermal manifestations and anomalous degassing areas, although of limited extent, were spatially correlated with the main active tectonic system of the area. The total CO2 output of the volcanic system has been preliminary estimated to be less than 0.05 kg s–1. Although this value is very low compared to those of other volcanic systems, anomalous CO2 degassing at Methana – which is currently restricted to limited areas and at present is the only volcanic risk of the peninsula – is a potential gas hazard that warrants further assessment in future studies.
    Description: Published
    Description: 818-828
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: Methana ; south Aegean volcanic arc ; fluids geochemistry ; soil gases ; groundwaters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 54
    Publication Date: 2017-04-04
    Description: Tomographical results are commonly presented in the form of color images and not much statistical quantification has been carried out on the derived models. Correlation between different depths can shed important light concerning the dynamics. We have generalized the application of multidimensional wavelets to investigate the products of two field variables, such as the cross-spectrum, which is of paramount importance for quantifying the correlation between two depth levels of seismic tomography with a multiple-scale character. For two multidimensional fields A and B, we calculate the correlation C by projecting this as an Hermitian inner product in physical space with a two-dimensional (2D), fourth derivative of the Gaussian wavelet as the weighting function. The correlation function C becomes now a multi-scaled function, a map cast in terms of both the scale and location of the wavelet transform. Having calculated C, we can delineate the locations and length-scales of the prominent features in the landscape of the correlation function. This wavelet formulation is very general and can be extended to other types of statistical analysis, for example in a Kalman filter system. We have used a high-resolution (finer than 1◦) seismic tomographical model for analyzing the extent of mantle layering under Europe by focussing on the different length-scales in the correlation function involving the 3D seismic anomalies lying between 400 and 600 km depth. Between the depths of 500 and 600 km under Europe, the wavelet correlation analysis shows that an ellipse-shaped object exists with an area of 2000 km × 4000 km having a strong correlation for length-scales of around 400 km, and weaker correlation for shorter length scales of around 150 km. On the other hand, between depths of 400 and 600 km, the correlation deteriorates on the long length scales and becomes even worse at the short length scales. From the wavelet correlation spectra, we can extract an horizontal characteristic length scale of around 100 km, which may be related to the boundary interaction between the slab and the ambient mantle. The correlation results suggest that the thickness of the recumbent fast (cold) material in the transition zone is between 100 and 150 km. This large elliptical pattern of presumably cold material would act to inhibit the vigor of mantle convection locally beneath Europe today.
    Description: Published
    Description: 125–139
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: JCR Journal
    Description: reserved
    Keywords: wavelets ; correlation ; tomography ; transition zone ; Mediterranean ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics
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  • 55
    Publication Date: 2017-04-04
    Description: Subduction zones appear primarily controlled by the polarity of their direction, i.e., W-directed or E- to NNE-directed, probably due to the westward drift of the lithosphere relative to the asthenosphere. The decollement planes behave differently in the two end-members. In the W-directed subduction zone, the decollement of the plate to the east is warped and subducted, whereas in the E- to NNE-directed, it is ramping upward at the surface. There are W-directed subduction zones that work also in absence of active convergence like the Carpathians or the Apennines. W-directed subduction zones have shorter life 30–40 Ma.than E- or NE-directed subduction zones even longer than 100 Ma.. The different decollements in the two end-members of subduction should control different PTt paths and, therefore, generate variable metamorphic assemblages in the associated accretionary wedges and orogens. These asymmetries also determine different topographic and structural evolutions that are marked by low topography and a fast ‘eastward’ migrating structural wave along W-directed subduction zones, whereas the topography and the structure are rapidly growing upward and expanding laterally along the opposite subduction zones. The magmatic pair calc-alkaline and alkaline–tholeiitic volcanic products of the island arc and the back-arc basin characterise the W-directed subduction zones. Magmatic rocks associated with E- or NE-directed subduction zones have higher abundances of incompatible elements, and mainly consist of calc-alkaline– shoshonitic suites, with large volumes of batholithic intrusions and porphyry copper ore deposits. The subduction zones surrounding the Adriatic plate in the central Mediterranean confirm the differences among subduction zones as primarily controlled by the geographic polarity of the main direction of the slab. The western margin of the Adriatic plate contemporaneously overridden and underthrust Europe toward the ‘west’ to generate, respectively, the Alps and the Apennines, while the eastern margin subducted under the Dinarides–Hellenides. These belts confirm the characters of the end-members of subduction zones as a function of their geographic polarity similarly to the Pacific subduction zones.
    Description: Published
    Description: 167–208
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: JCR Journal
    Description: reserved
    Keywords: tectonics ; subduction zones ; orogens ; Mediterranean geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 56
    Publication Date: 2017-04-04
    Description: We present a high-resolution paleomagnetic record from 682 discrete samples from Eltanin 27–21 (69.03°S 179.83°E), a 16-meter long piston core recovered in 1968 at a water depth of 3456 m by the USNS Eltanin as part of Operation Deep Freeze. After removal of a low-coercivity overprint, most samples yield stable characteristic remanent magnetization directions. The downhole variation in the magnetic inclination provides a well-resolved magnetostratigraphy from the Brunhes Chron (0–0.781 Ma), through the Reunion Subchron (2.128–2.148 Ma), and into Chron C2r.2r. The sedimentation rates are sufficiently high that even short-term geomagnetic features, like the Cobb Mountain excursion, are resolved. The record from Eltanin 27–21 provides new insights into the behavior of the geomagnetic field at high latitudes, about which very little is currently known. Using the variability in the inclinations during stable polarity intervals, we estimate that the dispersion in the paleomagnetic pole position over the past ~2 Myr is 30.3°±4.3°, which is significantly greater than observed at low to mid latitude sites. The higher dispersion observed at Eltanin 27–21 is consistent with numerical modeling of the geodynamo. That modeling has shown that polar vortices can develop in the Earth's core within the tangent cylinder, defined as the cylinder coaxial with the Earth's rotation axis and tangent to the inner core/outer core boundary. The polar vortices produce vigorous fluid motion in the core, which creates greater geomagnetic field variability above the tangent cylinder at the surface of the Earth. The tangent cylinder intersects the Earth's surface in the polar regions at 79.1° latitude, which is relatively close to the latitude of Eltanin 27–21.
    Description: Published
    Description: 435-443
    Description: 2.2. Laboratorio di paleomagnetismo
    Description: JCR Journal
    Description: reserved
    Keywords: paleomagnetism ; geomagnetism ; magnetostratigraphy ; Eltanin ; Ross Sea ; Antarctica ; tangent cylinder ; geodynamo ; Cobb Mountain Subchron ; Reunion Subchron ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism ; 04. Solid Earth::04.05. Geomagnetism::04.05.07. Rock magnetism
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 57
    Publication Date: 2017-04-04
    Description: We report on a high-resolution Vp, Vp/Vs and Qp model of the southern Tyrrhenian subduction zone, obtained by the inversion of P- and S wave arrival times and t* values from intraslab seismicity. The arcuate shape of the southern Apennines–Calabrian arc-Sicilian Maghrebides is perfectly mirrored by two rather continuous low and high Vp bands lying beneath the belt system at ca. 25 and 100 km, respectively. Between 100 and 300 km, two independent high Vp slabs lie beneath the Neapolitan region and the southern Tyrrhenian Sea, separated by unperturbed mantle. We suggest that the ca. 150 km-wide slab window beneath the southern Apennines opened after a tear occurring within a composite subduction system, formed by the Apulian continental lithosphere and the Ionian oceanic slab. The abrupt slab rupture induced ultrafast southeastward retreat of the Ionian slab, and the 19 cm/yr spreading of the back-arc oceanic Marsili basin between ca. 2.1 and 1.6 Ma ago. The 25 km low Vp zone beneath the arc denotes continental upper crustal rocks below the chain. Its striking continuity requires a unique orogenic wedge at 25 km depth below the southern Apennines, the Calabrian arc, and the Sicilian Maghrebides. The alternative explanation would imply the ubiquitous occurrence of autochthonous lower plate rocks at 25 km depth, i.e. a puzzling autochthonous continental Calabria. The Ionian slab beneath Calabria shows high Vp, high Qp and low Vp/Vs anomalies, typical of old oceanic lithosphere. Intermediate depth seismicity is concentrated within its thin oceanic crust, suggesting the occurrence of vigorous metamorphism. The slab dehydration promotes the melting of the overlying mantle, as testified by high Vp/Vs and low Qp anomalies between the slab and the Aeolian magmatic arc.
    Description: Published
    Description: 408-423
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: JCR Journal
    Description: reserved
    Keywords: seismic tomography ; recent evolution of the Ionian slab ; deep earthquakes slab dehydration and magmatism ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.06. Subduction related processes ; 04. Solid Earth::04.07. Tectonophysics::04.07.08. Volcanic arcs
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  • 58
    Publication Date: 2017-04-04
    Description: The Neogene Fortuna and Bajo Segura basins are located on the northeastern end of the Trans-Alborán Shear Zone (TASZ), on the eastern Betic cordillera. The stratigraphic study of the infilling of these basins has shown two major sedimentary discontinuities. The first one, represented by an erosive surface separating open marine marls from an overlying coastal conglomeratic unit, is linked to the onset of the activity along the TASZ, which in this area indicates the beginning of the Abanilla Thrust emplacement. In the Fortuna Basin, the Tortonian salinity crisis, registered over this older first discontinuity, was therefore related to tectonic processes of the eastern portion of the cordillera and consequently would not have an expression in the western basins. The age of the Tortonian Salinity Crisis has been established with nannofossil biostratigraphy as Latest Tortonian at a somewhat lower stratigraphic position than previously recognized. The second sedimentary discontinuity was developed in relation with the known Mediterranean-wide Messinian salinity crisis.
    Description: Published
    Description: 474-481
    Description: 2.2. Laboratorio di paleomagnetismo
    Description: JCR Journal
    Description: reserved
    Keywords: Betic Cordillera ; Tortonian Salinity Crisis ; Messinian Salinity Crisis ; Trans-Alboran Shear Zone ; Fortuna Basin ; Spain ; 04. Solid Earth::04.04. Geology::04.04.10. Stratigraphy ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 59
    Publication Date: 2017-04-04
    Description: A new magnetic polarity stratigraphy is reported from 214 sampling sites representing 265 m of fluviatile red beds of the Buntsandstein facies succession from the Catalan Coastal Ranges (Riera de Sant Jaume, RSJ section). The Buntsandstein constitutes the lowermost of the six lithostratigraphic units in which the Triassic from the CCR is subdivided (also grouped into the typical three-fold subdivision of the Germanic Facies from the Tethys Realm: Buntsandstein, Muschelkalk and Keuper). Magnetostratigraphic data from four sections though the uppermost Buntsandstein facies located in the Molina de Aragón area in the Iberian Ranges (Rey, D., Turner, P., Ramos, A., 1996. Palaeomagnetism and Magnetostratigraphy of the Middle Triassic in the Iberian Ranges (Central Spain). In: Morris, A., Tarling, D.R. (Eds.), Palaeomagnetism and Tectonics of the Mediterranean Region, Geol. Soc. Sp. Pub. 105, 59–82) are also discussed in the light of a new biostratigraphic reappraisal of the palynoflora content presented herein. Characteristic magnetizations are carried mostly by hematite with minor contributions by magnetite for the Buntsandstein red beds. The magnetic polarity sequence at the RSJ section consists of 9 magnetozones (and one additional less reliable magnetozone) that are represented by more than two samples. A detailed study along a magnetic reversal indicates that the nature of the remanence in the studied red beds is partially controlled by a chemical magnetization process (delayed remanence acquisition), in addition to a detrital signature (the characteristic primary direction). Chronostratigraphic constraints are provided by conodont fauna from the overlying Muschelkalk facies that indicates a middle–late Pelsonian to late Illyrian age (middle–late Anisian) (Marquez-Aliaga, A., Valenzuela-Rios, J.I., Calvet, F., Budurov, K., 2000. Middle Triassic conodonts from northeastern Spain; biostratigraphic implications. Terra Nova 12, 77–83) and a few palynostratigraphic determinations in the Buntsandstein red beds. These biostratigraphic constraints and the magnetic polarity pattern allow an unambiguous correlation of the RSJ magnetostratigraphy to the conodont-ammonoid-calibrated magnetostratigraphy from the Tethys realm (Muttoni, G., Kent, D.V., Meco, S., Balini, M., Nicora, A., Rettori, R. Gaetani, M., Krystine, L., 1998. Towards a better definition of the Middle Triassic magnetostratigraphy and biostratigraphy of the Tethyan realm. Earth Planet. Sci. Lett. 164, 285–302; Muttoni, G., Gaetani, M., Budurov, K., Zagorchev, I., Trifonova, E., Ivanova, D., Petrounova, L., Lowrie, W., 2000. Middle Triassic paleomagnetic data from northern Bulgaria; constraints on Tethyan magnetostratigraphy and paleogeography. Palaeogeogr. Palaeoclimatol. Palaeoecol. 160, 223–237; Muttoni, G., Nicora, A., Brack, P., Kent, D.V., 2004a. Integrated Anisian–Ladinian boundary chronology. Palaeogeogr. Palaeoclimatol. Palaeoecol. 208, 85–102; Muttoni, G., Kent, D.V., Olsen, P.E., Di Stefano, P., Lowrie, W., Bernasconi, S., Hernandez, F.M., 2004b. Tethyan magnetostratigraphy from Pizzo Mondello (Sicily) and correlation to the Late Triassic Newark astrochronological polarity time scale. Geol. Soc. Amer. Bull. 116, 1043–1058). The proposed correlation identifies for the first time in the Triassic from Iberia the Olenekian (Scythian)–Anisian stage boundary (245 Ma) within magnetozone N3 in the Riera de Sant Jaume units. Likewise, the new palynostratigraphic reconsideration allows the identification of the Anisian–Ladian stage (Illyrian–Fassanian substage) boundary (taken the option at the base of the Curionii ammonoid Zone favored by Muttoni et al. (2004a) [Muttoni, G., Nicora, A., Brack, P., Kent, D.V., 2004. Integrated Anisian–Ladinian boundary chronology. Palaeogeogr. Palaeoclimatol. Palaeoecol. 208, 85–102] for this boundary within the upper part of the Rillo Mudstone and Sandstones Formation (RMS Formation) and the Fassanian–Longobardian substage boundary (Ladinian) within the Torete Multicoloured Mudstone and Sandstone Formation (TMMS Formation). Our data are consistent with the notion that the lower Muschelkalk transgression progressed from east to west (i.e., the Buntsandstein/Muschelkalk boundary is younger in the Iberian Ranges with respect to the Catalan Coastal Ranges). The Early/Middle Triassic paleopole for the Catalan Coastal Ranges is located at 55.18N 172.4E (Dp=1.4, Dm=2.7).and the Middle/Late Triassic paleopole for the Iberian Ranges is 558N 201E (Dp=1.7, Dm=3.1). These paleopoles are compatible with the general trend of the Iberian apparent polar wander path which indicates a northward motion during the Triassic related to the general northward translation of Pangea.
    Description: Published
    Description: 158-177
    Description: 2.2. Laboratorio di paleomagnetismo
    Description: JCR Journal
    Description: reserved
    Keywords: Buntsandstein ; Olenekian–Anisian boundary ; Anisian–Ladinian boundary ; Palynostratigraphy ; Conodonts ; Catalan Coastal Ranges ; Iberian Ranges ; 04. Solid Earth::04.04. Geology::04.04.10. Stratigraphy ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism
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  • 60
    Publication Date: 2017-04-04
    Description: In curved orogenic systems where thrusting and vertical-axis rotations have been documented, it is possible to determine whether the curvature is secondary or progressive based on the timing between the two motions. The South-Central Unit of the Southern Pyrenees provides an opportunity to investigate relationships between thrusting, folding, and vertical-axis rotation because of unusual preservation of Tertiary synorogenic sedimentary strata. Paleomagnetic samples were collected from 51 sites in the upper Eocene-lower Oligocene continental synorogenic strata of the Oliana anticline, a foreland fold along the eastern margin of the South-Central Unit. Site-mean characteristic remanent magnetization directions were determined from 17 sites through thermal demagnetization and principal component analysis. In addition, 72 samples were collected from 39 stratigraphic levels spanning the Upper Eocene marine marls and treated with thermal and alternating field demagnetization techniques. Of these, 53 samples yielded demagnetization trajectories that further constrained the rotation. Comparison of the observed mean paleomagnetic direction from the Oliana anticline with the expected direction indicates a counterclockwise rotation (R ± ΔR) of 20.3° ± 10.9°. Based on the stratigraphic horizons recording the rotation, the age of the rotation is younger than ~34 Ma (after deposition of Unit 3). Data covering the Upper Eocene-Lower Oligocene time interval indicate a similar magnitude of rotation, suggesting that late stage emplacement of thrust sheets hinterlandward of the Oliana anticline controlled the rotation, with rotation accommodated along regionally extensive evaporites. The well-constrained timing relationships between thrusting and rotation and the regional and local transport directions, suggest that the South-Central Unit is a progressive curve that formed through distributed shortening.
    Description: Published
    Description: 435-449
    Description: 2.2. Laboratorio di paleomagnetismo
    Description: JCR Journal
    Description: reserved
    Keywords: Pyrenees ; Oliana anticline ; synorogenic strata ; paleomagnetism ; salients ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics
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  • 61
    Publication Date: 2017-04-04
    Description: Neogene intermontane basins in Almería Province, SE Spain, display excellent exposures of Messinian (Late Miocene) sequences. The Sorbas, Almería-Níjar and Vera basins maintained connection with the Mediterranean throughout the Messinian, except during the major desiccation phase leading to the formation of salt in the deep centre of the Western Mediterranean. These basins were part of the Western Mediterranean with no separate link to the Atlantic Ocean. The presence of normal marine sediments in these basins reflects the Western Mediterranean watermass. Messinian pre-evaporitic sediments in the basins of southeastern Almería do not show gradual change towards evaporite deposits. Instead they contain stenohaline invertebrates right up to a major erosion surface that separates them from overlying gypsum deposits. This contradicts suggestion of progressive salinity increase in this part of the Western Mediterranean prior to the Messinian Salinity Crisis (MSC); it also indicates that initiation of evaporite precipitation was not synchronous throughout the Mediterranean Basin. There is no major erosion surface within or at the top of the evaporites in these Almería basins, and the gypsum beds exhibit upward transition to siliciclastic and carbonate deposits. This is inconsistent with a model of Messinian Mediterranean evaporite formation whereby deposition of marginal evaporites was followed by their erosion during drawdown that resulted in formation of evaporites in the centre of the Western Mediterranean. The presence of stenohaline biotas in siliciclastic deposits interbedded with the gypsum and in the Messinian post-evaporitic sediments, challenges the view that a long-standing large body of brackish water (the Lago Mare) filled the Western Mediterranean following the MSC and prior to Early Pliocene flooding. It also contradicts the concept of many relatively small brackish basins spread across an otherwise desiccated Western Mediterranean basin. The basins of southeastern Almería record normal marine Early Messinian sedimentation that was abruptly interrupted by sealevel fall. This drawdown most likely resulted in precipitation of evaporites in the central deep Western Mediterranean basin. Following this episode, final marine reflooding of the Western Mediterranean took place during the Late Messinian, and the Mediterranean Sea rose to a level similar to, or higher than, that preceding the Salinity Crisis.
    Description: Published
    Description: 131-154
    Description: 2.2. Laboratorio di paleomagnetismo
    Description: JCR Journal
    Description: reserved
    Keywords: Almería ; Evaporites ; Messinian Salinity Crisis ; Palaeoenvironments ; Western Mediterranean ; Spain ; 03. Hydrosphere::03.01. General::03.01.06. Paleoceanography and paleoclimatology ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism
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  • 62
    Publication Date: 2017-04-04
    Description: The tectonic escarpments locally known as ‘Timpe’ cut a large sector of the eastern flank of Etna, and allow an ancient volcanic succession dating back to 225 ka to be exposed. Geological and volcanological investigations carried out on this succession have allowed us to recognize relevant angular unconformities and volcanic features which are the remnants of eruptive fissures, as well as important changes in the nature, composition and magmatic affinity of the exposed volcanics. In particular, the recognition in the lower part of the succession of important and unequivocal evidence of ancient eruptive fissures led us to propose a local origin for these volcanics and to revise previous interpretations which attributed their westward-dipping to the progressive tectonic tilting of strata. These elements led us to reinterpret the main features of the volcanic activity occurring since 250 ka BP and their relationship with tectonic structures active in the eastern flank of Etna. We propose a complex paleo-environmental and volcanotectonic evolution of the southeastern flank of Mt. Etna, in which the Timpe fault system played the role of the crustal structure that allowed the rise and eruption of magmas in the above considered time span.
    Description: Published
    Description: 289-306
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 3.5. Geologia e storia dei sistemi vulcanici
    Description: 3.6. Fisica del vulcanismo
    Description: JCR Journal
    Description: reserved
    Keywords: Mount Etna ; tectonics ; fisssure eruptions ; columnar basalt ; fault escarpment ; xenoliths ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.03. Geomorphology ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology ; 04. Solid Earth::04.04. Geology::04.04.06. Rheology, friction, and structure of fault zones ; 04. Solid Earth::04.04. Geology::04.04.07. Rock geochemistry ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.04. Geology::04.04.10. Stratigraphy ; 04. Solid Earth::04.04. Geology::04.04.11. Instruments and techniques ; 04. Solid Earth::04.07. Tectonophysics::04.07.99. General or miscellaneous ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.04. Plate boundaries, motion, and tectonics ; 04. Solid Earth::04.07. Tectonophysics::04.07.05. Stress ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
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  • 63
    Publication Date: 2017-04-04
    Description: A new method combining measurements of soil CO2 flux and determinations of the carbon isotopic composition of soil CO2 efflux was developed in order to qualitatively and quantitatively characterise the CO2 source feeding the soil CO2 diffuse degassing. The method was tested in March 2007 at the Solfatara of Pozzuoli volcano degassing area (Naples, Italy) where more than 300 measurements of soil CO2 flux and determinations of the carbon isotopic composition of soil CO2 efflux were performed, surveying Solfatara crater and its surroundings. The wide range of CO2 flux and CO2 isotopic composition values (from 8.4 g m−2 d−1 to 28,834 g m−2 d−1, and from 0.73‰ to −33.54‰, respectively), together with their statistical distributions suggests the occurrence of multiple CO2 sources feeding soil degassing. The combined interpretation of flux and isotopic data allows us to identify and characterise two distinct gas sources: a hydrothermal and a biogenic source. The soil CO2 from the hydrothermal source is characterised by a mean δ13CCO2 of −2.3‰±0.9‰, hence close to the isotopic composition of the fumarolic CO2 (δ13CCO2=−1.48‰± 0.22‰) and by a mean CO2 flux of 2875 g m−2 d−1. The CO2 from the biogenic source is characterised by a mean δ13CCO2 of −19.4‰±2.1‰, and by a mean CO2 flux of 26 g m−2 d−1, which are both in the range of the typical values for biologic CO2 soil degassing. This reliable characterisation of the biogenic CO2 flux would not have been possible by solely applying a statistical analysis of the CO2 flux values, which is commonly applied in volcanological studies for the partitioning between background fluxes and anomalous CO2 fluxes. A map of the Solfatara diffuse degassing structure was derived from the estimated threshold for the biogenic CO2 flux, highlighting that soil degassing of hydrothermal CO2 mixed in different proportion with biogenic CO2 occurs over a large area (~0.8 km2), which extends over the inner part of the Solfatara crater as well as the eastern periphery, corresponding with a NW–SE fault system. The presented method and data analysis are important means of surveillance of the volcanic activity.
    Description: Published
    Description: 372–379
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Degassamento naturale
    Description: JCR Journal
    Description: reserved
    Keywords: CO2 soil degassing ; CO2 flux ; carbon dioxide ; carbon isotopes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 64
    Publication Date: 2017-04-04
    Description: The recent eruption of Stromboli in February–April 2007 offered a unique chance to test our current understanding of processes driving the transition from ordinary (persistent Strombolian) to effusive activity, and the ability of instrumental geophysical and geochemical networks to interpret and predict these events. Here, we report on the results of two years of in-situ sensing of the CO2/SO2 ratio in Stromboli's volcanic gas plume, in the attempt to put constraints on the trigger mechanisms and dynamics of the eruption. We show that large variations of the plume CO2/SO2 ratio (range, 0.9–26) preceded the onset of the eruption (since December 2007), interrupting a period of relatively-steady and low ratios (time-averaged ratio, 4.3) lasting from at least May to November 2006. By contrasting our observations with numerical simulations of volcanic degassing at Stromboli, derived by use of an equilibrium saturation model, we suggest that the pre-eruptive increase of the ratio reflected an enhanced supply of deeply-derived CO2-rich gas bubbles to the shallowplumbing system. This larger-than-normal ascent of gas bubbles was likely sourced by a 1–3 km deep gas– melt separation region (probably a magma storage zone), and caused faster convective overturning of magmas in the shallow conduit; an increase in the explosive rate and in seismic tremor, and finally the collapse of the la Sciara del Fuoco sector triggering the effusive phase. The high CO2/SO2 ratios (up to 21) observed during the effusive phase, and particularly in the days and hours before a paroxysmal explosion on March 15, 2007, indicate the persistence of the same gas source; and suggest that de-pressurization of the same 1–3 km deep magma storage zone could have been the trigger mechanism for the paroxysm itself
    Description: In press
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 3.6. Fisica del vulcanismo
    Description: JCR Journal
    Description: reserved
    Keywords: Stromboli ; plume chemistry ; magma degassing ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.04. Thermodynamics ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 65
    Publication Date: 2021-09-08
    Description: The Gran Sasso range is a striking salient formed by two roughly rectilinear E–W and N–S limbs. In the past ∼90° counterclockwise (CCW) rotations from the eastern Gran Sasso were reported [Tectonophysics 215 (1992) 335], suggesting west–east increase of rotation-related northward shortening along the E–W limb. In this paper, we report on paleomagnetic data from Meso-Cenozoic sedimentary dykes and strata cropping out at Corno Grande (central part of the E–W Gran Sasso limb), the highest summit of the Apennine belt. Predominant northwestward paleomagnetic declinations (in the normal polarity state) from both sedimentary dykes and strata are observed. When compared to the expected declination values for the Adriatic foreland, our data document no thrusting-related rotation at Corno Grande. The overall paleomagnetic data set coupled with the available geological information shows that the Gran Sasso arc is in fact a composite structure, formed by an unrotated-low shortening western (E–W trending) limb and a strongly CCW rotated eastern salient. Late Messinian and post-early Pliocene shortening episodes documented along the Gran Sasso front indicate that belt building and arc formation occurred during two distinct episodes. We suggest that the southern part of a late Messinian N–S front was reactivated during early–middle Pliocene time, forming a tight range salient due to CCW rotations and differential along-front shortening rates. The formation of a northward displacing bulge in an overall NW–SE chain is likely a consequence of the collision between the Latium-Abruzzi and Apulian carbonate platforms during northeastward propagation of the Apennine wedge, inducing lateral northward extrusion of Latium-Abruzzi carbonates towards ductile basinal sediment areas.
    Description: Published
    Description: 183-197
    Description: 2.2. Laboratorio di paleomagnetismo
    Description: JCR Journal
    Description: reserved
    Keywords: Gran Sasso range ; Mountain front ; Central Apennines ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 66
    Publication Date: 2022-05-30
    Description: We report on new palaeomagnetic and magnetic fabric analyses of mainly Upper Miocene sedimentary sequences from the external central Apennine fold and thrust belt (Molise area), where the principal compressive structures are clearly non-coaxial. The sampling was carried out on the E–W-oriented Matese–Frosolone thrust sheet, that for its geographical position and structural setting (superposition of thrusting, strike-slip and extensional tectonics since Late Miocene to present-day) represents a key structure for the comprehension of the Neogene–Quaternary evolution of the entire Molise area. Palaeomagnetic results suggest that the Matese–Frosolone thrust sheet counterclockwise rotated at least 35° after Messinian times. These data confirm that the present-day trend variability observed in the main compressional structures in the Apennine chain can be related to rotations about vertical axes rather than to changes in the stress field orientation, at least since Late Miocene times. Magnetic fabric analyses indicate that the studied sediments were subjected to very mild deformation, suggesting that the surface emergence of the thrust front of the Matese–Frosolone unit is located farther north, far from the studied area. Well-defined magnetic lineations of tectonic origin were only observed in sites close to localised belts of strike-slip deformation.
    Description: Published
    Description: 143-157
    Description: JCR Journal
    Description: reserved
    Keywords: Apennines ; palaeomagnetism ; anisotropy of magnetic susceptibility ; structural geology ; Neogene ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 67
    Publication Date: 2017-04-04
    Description: The development of the 2004–2005 eruption at Etna (Italy) is investigated by means of field surveys to define the current structural state of the volcano. In 2004–2005, a fracture swarm, associated with three effusive vents, propagated downslope from the SE summit crater towards the SE. Such a scenario is commonly observed at Etna, as a pressure increase within the central conduits induces the lateral propagation of most of the dikes downslope. Nevertheless, some unusual features of this eruption (slower propagation of fractures, lack of explosive activity and seismicity, oblique shear along the fractures) suggest a more complex triggering mechanism. A detailed review of the recent activity at Etna enables us to better define this possible mechanism. In fact, the NW–SE-trending fractures formed in 2004–2005 constitute the southeastern continuation of a N–S-trending fracture system which started to develop in early 1998 to the east of the summit craters. The overall 1998–2005 deformation pattern therefore forms an arcuate feature, whose geometry and kinematics are consistent with the head of a shallow flank deformation on the E summit of Etna. Similar deformation patterns have also been observed in analogue models of deforming volcanic cones. In this framework, the 2004–2005 eruption was possibly induced by a dike resulting from the intersection of this incipient fracture system with the SE Crater. A significant acceleration of this flank deformation may be induced by any magmatic involvement. The central conduit of the volcano is presently open, constantly buffering any increase in magmatic pressure and any hazardous consequence can be expected to be limited. A more hazardous scenario may be considered with a partial or total closing of the central conduit. In this case, magmatic overpressure within the central conduit may enhance the collapse of the upper eastern flank, triggering an explosive eruption associated with a landslide reaching the eastern lower slope of the volcano.
    Description: Published
    Description: 195–206
    Description: reserved
    Keywords: eruption triggering ; volcano-tectonics ; fracture fields ; flank spreading ; Mt. Etna ; 04. Solid Earth::04.04. Geology::04.04.01. Earthquake geology and paleoseismology ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics
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  • 68
    Publication Date: 2017-04-04
    Description: New major and trace element analyses and Sr-isotope determinations of rocks from Mt. Somma–Vesuvius volcano produced from 25 ky BP to 1944 AD are part of an extensive database documenting the geochemical evolution of this classic region. Volcanic rocks include silica undersaturated, potassic and ultrapotassic lavas and tephras characterized by variable mineralogy and different crystal abundance, as well as by wide ranges of trace element contents and a wide span of initial Sr-isotopic compositions. Both the degree of undersaturation in silica and the crystal content increase through time, being higher in rocks produced after the eruption at 472 AD (Pollena eruption). Compositional variations have been generally thought to reflect contributions from diverse types of mantle and crust. Magma mixing is commonly invoked as a fundamental process affecting the magmas, in addition to crystal fractionation. Our assessment of geochemical and Srisotopic data indicates that compositional variability also reflects the influence of crustal contamination during magma evolution during upward migration to shallow crustal levels and/or by entrapment of crystal mush generated during previous magma storage in the crust. Using a variant of the assimilation fractional crystallization model (Energy Conservation– Assimilation Fractional Crystallization; [Spera and Bohrson, 2001. Energy-constrained open-system magmatic processes I: General model and energy-constrained assimilation and fractional crystallization (EC–AFC) formulation. J. Petrol. 999– 1018]; [Bohrson, W.A. and Spera, F.J., 2001. Energy-constrained open-system magmatic process II: application of energyconstrained assimilation–fractional crystallization (EC–AFC) model to magmatic systems. J. Petrol. 1019–1041]) we estimated the contributions from the crust and suggest that contamination by carbonate rocks that underlie the volcano (2 km down to 9–10 km) is a fundamental process controlling magma compositions at Mt. Somma–Vesuvius in the last 8 ky BP. Contamination in the mid- to upper crust occurred repeatedly, after the magma chamber waxed with influx of new mantle- and crustal-derived magmas and fluids, and waned as a result of magma withdrawal and production of large and energetic plinian and subplinian eruptions.
    Description: Published
    Description: 303– 329
    Description: reserved
    Keywords: Mt. Somma–Vesuvius volcano ; Sr isotopes ; Geochemistry ; Crustal contamination ; Mantle source ; Phenocryst entrapment ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
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  • 69
    Publication Date: 2017-04-04
    Description: In this paper, we discuss the possibility that the North Anatolian fault (NAF) results from the deep deformation of the slab beneath the Bitlis–Hellenic subduction zone. We described the tectonic evolution of the Anatolia–Aegean area in three main steps, before, during and after the formation of the NAF. We remark that the tectonic conditions that are assumed to have triggered the formation of the NAF, i.e. collision to the east and extension to the west, was already achieved before the onset of that strike-slip fault system. We also highlight that the formation of the NAF was accompanied by the uplift of the Turkish–Iranian plateau and by a surge of volcanism in the eastern Anatolia collisional area and probably by the acceleration of the Aegean trench retreat. We show tomographic images from global P-wave model of Piromallo and Morelli [C. Piromallo, A. Morelli, P wave tomography of the mantle under the Alpine–Mediterranean area, J. Geophys. Res. 108 (2003) doi: 10.1029/2002JB001757.] showing that the slab beneath the Bitlis collisional belt is not continuous and that its possible rupture pursues to the west at least up to Cyprus and possibly up to the eastern end of the Hellenic trench. All these observations suggest that the plate tectonic re-organization occurred in the Late Miocene–Early Pliocene in the region results from slab break-off in the Bitlis area and from its lateral propagation to the West. This idea is tested in analogue laboratory experiments, which confirm that the break of the slab under the collisional belt may trigger, (1) the acceleration of slab retreat to the west due to the increase in slab pull force, (2) the indentation of the continent in the collisional area and (3) produce the conditions that permit the lateral escape of material towards the west and the formation of the NAF.
    Description: Published
    Description: 85-97
    Description: JCR Journal
    Description: reserved
    Keywords: Mediterranean ; subduction ; collision ; analogue experiments ; seismic tomography ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics
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  • 70
    Publication Date: 2017-04-04
    Description: The Deep Western Boundary Current (DWBC) inflow to the SW Pacific is one of the largest, transporting ~40% of the total input of deep water to the world’s oceans. Here we use a sedimentary record from the giant piston core MD97-2114 collected on the northern flank of the Chatham Rise located at 1935 m water depth, east of New Zealand, to investigate DWBC variability during the Pleistocene epoch when the period of glacial cycles changed progressively from a 41 kyr to 100 kyr rhythm. Magnetic grain-size may be directly related to orbitally forced fluctuations in the strength of the upper circumpolar deep water (UCDW) through its interaction with terrigenous sediments supplied from the south and west. The long-term trends in magnetic properties are characterized by two main perturbations centered at 870 ka (Marine Isotope Stage, MIS 22) 450 ka (MIS 12), which is broadly consistent with the inferred perturbation during the mid-Pleistocene climate transition based on sedimentological paleocurrent reconstruction from Ocean Drilling Program Site 1123 located at 3290 m water depth in the main core of the DWBC flow on the North Chatham Drift. This similarity suggests that both the upper and middle CDW are modulated by similar processes and fluctuations of Antarctic Bottom Water production could be directly responsible for this deep Pacific Ocean inflow variability over the past 1.2 Ma.
    Description: Published
    Description: 107-118
    Description: 2.2. Laboratorio di paleomagnetismo
    Description: JCR Journal
    Description: reserved
    Keywords: DWBC ; Chatham Rise ; New Zealand; ; Pleistocene; ; magnetostratigraphy; ; environmental magnetism ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism
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  • 71
    Publication Date: 2017-04-04
    Description: The Lower Paleozoic assemblages in the E. Meditterranean comprise a Southern (Tauride-Anatolide,SE Anatolia and Central Iranian terranes) and a Northern (Carpathian-Balkan, Istanbul, Zonguldak and the Main Range terranes) Zone. A detailed stratigrapic account is given for these terranes for the Early Paleozoic and their paleogeographical settings are discussed to evaluate the Early Paleozoic geodynamic interpretation of this critical area between Gondwana-Perigondwana and Laurussia..
    Description: Published
    Description: 315-323
    Description: JCR Journal
    Description: open
    Keywords: Palaeozoic, evolution, Turkey ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics
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  • 72
    Publication Date: 2017-04-04
    Description: Several sites with anomalous emissions of carbon dioxide were investigated in the region south of Mt. Etna volcano in order to assess the types of emission (focused and/or diffuse), their surface extension and the total output of CO2. Most of the studied emissions are located on the southwest boundary of Mt. Etna, near the town of Paternò. They consist of three mud volcanoes (known as Salinelle), one spring with bubbling gas (Acqua Grassa) and one area of diffuse degassing (Peschería). Another site (Naftía Lake) with remarkable gas emissions (bubbling gas into a lake as well as adjacent areas of diffuse soil degassing) is located further southwest of Mt. Etna in an area of extinct Quaternary volcanism on the northwest margin of Hyblean Mts. In all of these areas the origin of the highest CO2 emissions is clearly magmatic, and degassing to the atmosphere occurs mostly through tectonic structures, probably at a regional scale. The magmatic source that feeds anomalous degassing in the above areas is likely to be the same that feeds volcanic activity at Mt. Etna. Focused degassing was measured at each emission vent using devices that measure the air speed, whereas diffuse soil degassing was measured using the accumulation chamber method. In total, 712 measurements were carried out (146 in focused degassing vents, 566 on diffuse degassing areas). Single CO2 output values ranged from 1.8 10−5 to 1.68 kg s−1. In the case of diffuse degassing areas, statistical analyses allowed to discriminate between biogenic CO2 and CO2 deriving from a magmatichydrothermal source. Only the efflux values from the latter source were considered in the output estimates. The total estimated output thus obtained was about 2.61 kg s−1, relevant to a total surface of about 146,500 m2 (which includes only the magmatic CO2 emissions). This value is comparable with that of most non-volcanic emissions from geothermal and/or faulted areas of centralsouthern Italy, as well with the CO2 output from some of the volcanic areas of Italy.
    Description: Istituto Nazionale di Geofisica e Vulcanologia; Dipartimento per la Protezione Civile.
    Description: Published
    Description: 46–63
    Description: 4.5. Degassamento naturale
    Description: JCR Journal
    Description: reserved
    Keywords: Mt. Etna ; mud volcanoes ; soil CO2 effluxes ; magmatic degassing ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
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  • 73
    Publication Date: 2017-04-04
    Description: The sustained and uninterrupted plume degassing at Mount Etna volcano, Southern Italy, represents the troposphere’s most prominent natural source of fluorine. Of the ~ 200 Mg of fluorine (as HFg) emitted daily by the volcano, 1.6±2.7 Mg are deposited by wet and dry deposition. Fluorine-deposition via volcanic ash, here characterised for the first time, can be quite significant during volcanic eruptions (i.e. 60 Mg of fluorine were deposited during the 2001 eruption through volcanic ash, corresponding to ~ 85% of the total fluorine deposition). Despite the fact that these depositions are huge, the fate of the deposited fluorine and its impact on the environment are poorly understood. We herein present original data on fluorine abundance in vegetation (Castanea Sativa and Pinus Nigra) and andosoils from the volcano’s flank, in the attempt to reveal the potential impact of volcanogenic fluorine emissions. Fluorine contents in chestnut leaves and pine needles are in the range 1.8-35 µg/g and 2.1-74 µg/g respectively; they exceed the typical background concentrations in plants growing in rural areas, but fall within the lower range of typical concentrations in plants growing near high fluorine anthropogenic emission sources. The rare plume fumigations on the lower flanks of Mt Etna (distance 〉 4 km from summit craters) are probably the cause of the “undisturbed” nature of Etnean vegetation: climatic conditions, which limit the growth of vegetation on the upper regione deserta, are a natural limit to the development of more severe impacts. High fluorine contents, associated with visible symptoms, were only measured in pine needles at three sites, located near recently-active (2001 to 2003) lateral eruptive fractures. Total fluorine contents (FTOT) in the Etnean soils have a range of 112-341 µg/g, and fall within the typical range of undisturbed soils; fluorine extracted with distilled water (FH2O) have a range of 5.1 to 61 µg/g and accounts for 2-40 % of FTOT. FH2O is higher in topsoils from the eastern flank (downwind), while it decreases with depth in soil profiles and on increasing soil grain size (thereby testifying to its association with clay-mineral-rich, fine soil fractions). The fluorine adsorption capacity of the andosoils acts as a natural barrier that protects the groundwater system.
    Description: Published
    Description: 87-101
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 4.5. Degassamento naturale
    Description: JCR Journal
    Description: reserved
    Keywords: Mt. Etna ; Fluorine ; environmental volcanology ; impact of volcanic F ; soils ; vegetation ; volcanic ash ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 03. Hydrosphere::03.03. Physical::03.03.01. Air/water/earth interactions ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 05. General::05.08. Risk::05.08.01. Environmental risk
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  • 74
    Publication Date: 2017-04-04
    Description: Introduction of a special issue of the journal
    Description: no abstract
    Description: Published
    Description: 1-4
    Description: 4.5. Degassamento naturale
    Description: JCR Journal
    Description: reserved
    Keywords: Earth's degassing ; volcanic areas ; seismic areas ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
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  • 75
    Publication Date: 2017-04-04
    Description: We report on a high-resolution magnetostratigraphic analysis of a continuous 97.5 m thick upper Sinemurian–Pliensbachian pelagic limestone section (“Corniola” formation) exposed at Bosso Stirpeto (Marche, Italy), where detailed ammonite and calcareous nannofossil biozonation is available. The early Pliensbachian (Carixian) is notably expanded (74.35 m excluding few slumps), implying an average sedimentation rate of 28.6 m/Myr. Both the Carixian boundaries and three additional intra-Carixian ammonite zone boundaries are tied up with polarity magnetozones. We find that a normal polarity characterizes the latest Sinemurian and Sinemurian/Carixian boundary, while a reverse polarity (punctuated by three short normal polarity magnetozones) dominates the Carixian. In the lower Carixian sediments, two 3.39–4.65 m thick (excluding the slumps) intervals are characterized by persistent transitional (between 45°N and 45°S) virtual geomagnetic pole (VGP) latitudes, but this seems not to be the result of mineral magnetic artefacts, antipodal polarity averaging, or sedimentary layer disturbance. Thus we suggest that in two ∼120 and 160 kyr-long time intervals during the early Carixian, the VGPs were predominantly confined at tropical–equatorial latitudes of the Earth. Such geomagnetic feature has never been documented before elsewhere in other time intervals, and requires further paleomagnetic investigation of other expanded Carixian section to be confirmed. The magnetic polarity profile (including the transitional direction intervals) of Bosso Stirpeto may compare with that from similarly expanded Carixian sections (Breggia, Switzerland), and cores (Montcornet, Paris basin). However, the matching of magnetic polarity zones requires a significant aging of some parts of the magnetostratigraphic profile at both Breggia and Montcornet.
    Description: Published
    Description: 344-359
    Description: 3.4. Geomagnetismo
    Description: JCR Journal
    Description: reserved
    Keywords: magnetostratigraphy ; Pliensbachian ; Carixian ; Corniola formation ; geomagnetic field ; Bosso valley ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism
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  • 76
    Publication Date: 2017-04-04
    Description: We provide new data on relative sea-level change from the late Holocene for two locations in the central Mediterranean: Sardinia and NE Adriatico. They are based on precise measures of submerged archaeological and tide notch markers that are good indicators of past sea-level elevation. Twelve submerged archaeological sites were studied: six, aged between 2.5 and 1.6 ka BP, located along the Sardinia coast, and a further six, dated 2.0 ka BP, located along the NE Adriatic coast (Italy, Slovenia and Croatia). For Sardinia, we also use beach rock and core data that can be related to Holocene sea level. The elevations of selected significant archaeological markers were measured with respect to the present sea level, applying corrections for tide and atmospheric pressure values at the time of surveys. The interpretation of the functional heights related to sea level at the time of their construction provides data on the relative changes between land and sea; these data are compared with predictions derived from a new glacio–hydro-isostatic model associated with the Last Glacial cycle. Sardinia is tectonically relatively stable and we use the sea-level data from this island to calibrate our models for eustatic and glacio–hydro-isostatic change. The results are consistent with those from another tectonically stable site, the Versilia Plain of Italy. The northeast Adriatic (Italy, Slovenia and Croatia) is an area of subsidence and we use the calibrated model results to separate out the isostatic from the tectonic contributions. This indicates that the Adriatic coast from the Gulf of Trieste to the southern end of Istria has Q1 tectonically subsided by 1.5m since Roman times.
    Description: Published
    Description: 2463-2486
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: JCR Journal
    Description: reserved
    Keywords: sea level, archaeology, tectonics ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics
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  • 77
    Publication Date: 2017-04-04
    Description: A large database of major, trace and isotope (Sr, Nd, Pb, O) data exists for rocks produced by the volcanic activity of Somma-Vesuvius volcano. Variation diagrams strongly suggest a major role for evolutionary processes such as fractional crystallization, contamination, crystal trapping and magma mixing, occurring after magma genesis in the mantle. Most mafic magmas are enriched in LILE (K, Rb, Ba), REE (Ce, Sm) and Y, show small Nb–Ta negative anomalies, and have values of Nb/Zr at about 0.15. Enrichments in LILE, REE, Nb and Ta do not correlate with Sr isotope values or degree of both K enrichment and silica undersaturation. The results indicate mantle source heterogeneity produced by slab-derived components beneath the volcano. However, the Sr isotope values of Somma-Vesuvius increase from 0.7071 up to 0.7081 with transport through the uppermost 11–12 km of the crust. The Sr isotope variation suggests that the crustal component affected the magmas during ascent through the lithosphere to the surface. Our new geochemical assessment based on chemical, isotopic and fluid inclusion data points to the existence of three main levels of magma storage. Two of the levels are deep and may represent long-lived reservoirs, and an uppermost crustal level that probably coincides with the volcanic conduit. The deeper level of magma storage is deeper than 12 km and fed the 1944 AD eruption. The intermediate level coincides with the seismic discontinuity detected by Zollo et al. (1996) at about 8 km. This intermediate level supplies magmas with 87Sr/86Sr values between 0.7071 and 0.7074, and δO18 8‰ that typically erupted both during interplinian (i.e. 1906 AD) and sub-plinian (472 AD, 1631 AD) events. The shallowest level of magma storage at about 5 km was the site of magma chambers for the Pompei and Avellino eruptions. New investigations are necessary to verify the proposed magma feeding system.
    Description: Published
    Description: 183-204
    Description: open
    Keywords: NONE ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
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    Type: book chapter
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  • 78
    Publication Date: 2017-04-04
    Description: A physical model based on the advective–diffusion theory was developed in order to describe the mixing between a deep gas source and the atmosphere. The model was used to predict the isotopic fractionation of carbon in soil CO2. Gas samples were collected at different depths in areas characterized by different geological settings and CO2 fluxes. The relative theoretical and experimental isotopic profiles were compared and a good agreement was found. These profiles show how the isotopic composition of CO2 changes through the upper few decimeters of soil and how the amount of the isotopic fractionation is strongly influenced by soil CO2 flux. Finally, the model was used to derive the carbon isotopic composition of unfractioned deep CO2 source for all the investigated sites
    Description: Published
    Description: 3016–3027
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Degassamento naturale
    Description: JCR Journal
    Description: reserved
    Keywords: Carbon isotope fractionation ; soil degassing ; gas transport ; D13C(CO2) ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
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  • 79
    Publication Date: 2017-04-04
    Description: Our knowledge of the degassing pattern of sulphur, chlorine and fluorine during ascent and eruption of basaltic magmas is still fragmental and mainly limited to water-poor basalts. Here we model and discuss the pressure-related degassing behaviour of S, Cl and F during ascent, differentiation and extrusion of H2O–CO2-rich alkali basalt on Mount Etna (Sicily) as a function of eruptive styles. Our modelling is based on published and new melt inclusion data for dissolved volatiles (CO2, H2O, S, Cl, F) in quenched explosive products from both central conduit (1989–2001) and lateral dyke (2001 and 2002) eruptions. Pressures are obtained from the dissolved H2O and CO2 concentrations, and vapour–melt partition coefficients of S, Cl and F are derived from best fitting of melt inclusion data for each step of magma evolution. This allows us to compute the compositional evolution of the gas phase during either open or closed system degassing and to compare it with the measured composition of emitted gases. We find that sulphur, chlorine and fluorine begin to exsolve at respective pressures of ∼140 MPa, ∼100 MPa and ≤10 MPa during Etna basalt ascent and are respectively degassed at 〉95%, 22–55%, and ∼15% upon eruption. Pure open system degassing fails to explain gas compositions measured during either lateral dyke or central conduit eruptions. Instead, closed-system ascent and eruption of the volatile-rich basaltic melt well accounts for the time-averaged gas composition measured during 2002-type lateral dyke eruptions (S/Cl molar ratio of 5±1, 35% bulk Cl loss). Extensive magma fragmentation during the most energetic fountaining phases enhances Cl release (55%) and produces a lower S/Cl ratio of 3.7, as actually measured. Comparatively slower magma rise in the central conduits of Etna favours both sulphide saturation of the melt and greater chlorine release (55%), resulting in a distinct S/Cl evolution path and final ratio in eruptive gas. In both eruption types, any previous bubble–melt separation at depth leads to increased S/Cl and S/F ratios in emitted gas. High S/Cl ratios measured during some discrete eruptive events can thus be explained by transitions from closed (deep) to open (shallow) system degassing, with differential gas transfer extending down to ∼2 km depth below the vents. This depth coincides with the base of the volcanic pile where structural discontinuities and the high magma vesicularity (60%) may favour separate gas flow. Finally, the excess S–Cl–F gas discharge through Etna summit craters during non-eruptive periods requires a mixed supply from shallow magma degassing in the volcanic conduits and deeper-derived SO2-rich bubbles from the sub-volcano plumbing system. Our modelling provides a useful reference framework for interpreting the monitored variations of S, Cl and F in Mount Etna gas emissions as a function of volcanic activity. More broadly, the observations made for S, Cl and F degassing on Etna may apply to other basaltic volcanoes with water-rich magmas, such as in arcs.
    Description: Published
    Description: 772-786
    Description: reserved
    Keywords: Mt Etna ; volatiles ; magma degassing ; eruptive mechanisms ; modelling ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas
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  • 80
    Publication Date: 2017-04-04
    Description: Knowledge of the physical, chemical and thermodynamic properties of silicate melts and glasses is required to understand magma formation and evolution at all scales of observation. As is illustrated by the papers published in this special issue of Chemical Geology, there is a complex interplay between microscopic and macroscopic features. Whereas determining the microscopic structure of glasses and melts is useful to understand how macroscopic properties vary with pressure, temperature and composition, studies of macroscopic properties in turn put strong constraints on which microscopic aspects are actually relevant to a given problem. In this issue this approach is successfully applied to a variety of topics which range from melt rheology to volatile solubility or from spectroscopic investigations of silicate speciation to computer simulation studies of melt/glass structure. These papers were originally presented and discussed in April 2005 at the Vienna meeting of the European Union of Geosciences. They represent an up-to-date overview of current research in the field, ranging from classical approaches to new science and technology solutions which will help expand our research possibilities. We thank the Chemical Geology staff and all contributors and colleagues who made this volume possible.
    Description: Published
    Description: 1
    Description: open
    Keywords: NONE ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
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  • 81
    Publication Date: 2017-04-04
    Description: It has recently been demonstrated that methane emission from lithosphere degassing is an important component of the natural greenhouse-gas atmospheric budget. Globally, the geological sources are mainly due to seepage from hydrocarbon-prone sedimentary basins, and subordinately from geothermal/volcanic fluxes. This work provides a first estimate of methane emission from the geothermal/volcanic component at European level. In Europe, 28 countries have geothermal systems and at least 10 countries host surface geothermal manifestations (hot springs, mofettes, gas vents). Even if direct methane flux measurements are available only for a few small areas in Italy, a fair number of data on CO2, CH4 and steam composition and flux from geothermal manifestations are today available for 6 countries (Czech Republic, Germany, Greece, Iceland, Italy, Spain). Following the emission factor and area-based approach, the available data have been analyzed and have led to an early and conservative estimate of methane emission into the atmosphere around 10,000 ton/yr (4000–16,000 ton/yr), basically from an area smaller than 4000 km2, with a speculative upper limit in the order of 105 ton/yr. Only 4–18% of the conservative estimate (about 720 ton/yr) is due to 12 European volcanoes, where methane concentration in volcanic gases is generally in the order of a few tens of ppmv. Volcanoes are thus not a significant methane source. While the largest emission is due to geothermal areas, which may be situated next to volcanoes or independent. Here inorganic synthesis, thermometamorphism and thermal breakdown of organic matter are substantial. Methane flux can reach hundreds of ton/yr from small individual vents. Geothermal methane is mainly released in three countries located in the main high heat flow regions: Italy, Greece, and Iceland. Turkey is likely a fourth important contributor but the absolute lack of data prevents any emission estimate. Therefore, the actual European geothermal–volcanic methane emission could be easily projected to the 105 ton/yr levels, reaching the magnitude of some other natural sources such as forest fires or wild animals.
    Description: Published
    Description: 76-86
    Description: 4.5. Degassamento naturale
    Description: JCR Journal
    Description: reserved
    Keywords: Methane ; volcanoes ; Geothermal vents ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
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  • 82
    Publication Date: 2017-04-04
    Description: Northern Apulia is an emerged portion of the Adriatic microplate, representing the foreland–foredeep area of a stretch of the Apennine chain in southern Italy. The interaction between the relatively rigid microplate and the contiguous more deformable domains is responsible for the intense seismicity affecting the chain area. However strong, sometimes even disastrous, earthquakes have also hit northern Apulia on several occasions. The identification of the causative faults of such events is still unclear and different hypotheses have been reported in literature. In order to provide guidelines and constraints in the search for these structures, a comprehensive re-examination and reprocessing of all the available seismic data has been carried out taking into consideration 1) the characteristics of historical events, 2) the accurate relocation of events instrumentally recorded in the last 20 years, 3) the determination of focal mechanisms and of the regional stress tensor. The results obtained bring to light a distinction between the foreland and foredeep areas. In the first region there is evidence of a regional stress combining NWcompression and NE extension, thus structures responsible for major earthquakes should be searched for among strike–slip faults, possibly with a slight transpressive character. These structures could be either approximately N–S oriented sinistral or E–Wdextral faults. In the foredeep region there is a transition toward transtensive mechanisms,with strikes similar to those of the previous zone, or maybe also towardsNWoriented normal faults,more similar to those prevailing in the southern Apennine chain in relation to a dominant NE extension; this appears to be the effect of a reduction of the NW compression, probably due to a decrease in efficiency of stress transmission along the more tectonised border of the Adriatic microplate.
    Description: Published
    Description: 9 - 35
    Description: 3.2. Tettonica attiva
    Description: JCR Journal
    Description: reserved
    Keywords: Northern Apulia ; Historical earthquakes ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics
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  • 83
    Publication Date: 2017-04-04
    Description: A new high-resolution Apparent Polar Wander Path (APWP) segment has been obtained from the magnetostratigraphy of four Kimmeridgian to Lower Aptian sections in the Northern Apennines (Italy). The use of paleomagnetic data for determination of the Adria APWP was hampered by the large local rotations linked to Apennine tectonics, characterized by folds and thrusts developed during the Neogene. To overcome this problem, we have computed relative rotations between time overlapping sections and realigned them in a common declination reference frame (namely the Bosso section). We synthesized a new high-resolution 150 to 125 Ma APWP for Adria, which has a similar shape to the time-equivalent segment of the synthetic APWP of Africa of Besse and Courtillot [J., Besse, V., Courtillot, Apparent and true polar wander and the geometry of the geomagnetic field over the last 200 Myr, J. Geophys. Res. 107(B11) (2002), doi:10.1029/200JB000050]. A 26° clockwise rotation of our combined Adria APWP places it in almost perfect overlap with African data of same age, confirming that the Adria promontory moved coherently with Africa during this time span, whereas the counterclockwise rotation of Adria with respect to Africa was introduced later, most probably during Apennines orogenesis. Finally, we discuss in relation with worldwide plate evolution the peculiar shape of our APWP, which displays a hairpin turn during Berriasian time, and dates the main Late Jurassic/Early Cretaceous change in plate motion at around anomaly M16.
    Description: Published
    Description: 329-342
    Description: 3.4. Geomagnetismo
    Description: JCR Journal
    Description: reserved
    Keywords: paleomagnetism ; Apparent Polar Wander Path ; magnetostratigraphy ; Adria ; Italy ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism
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  • 84
    Publication Date: 2017-04-04
    Description: Recent studies suggested that Alban Hills (Rome) is a quiescent and not an extinct volcano, as it produced Holocene eruptions and several lahars until Roman times by water overflow fromthe Albano crater lake. Alban Hills are presently characterized by high PCO2 in groundwaters and by several cold gas emissions usually in sites where excavations removed the superficial impervious cover. Gas consists mostly of CO2 with minor H2S and the diffuse CO2 soil flux is locally very high. Accidental gas blowouts, occurred during shallow well drillings (tens to hundreds m depth) in zones with no surface gas manifestations, indicate the presence of gas pressurized aquifers confined underneath impermeable layers, within both the volcanic rock pile and the underlying Pleistocene loose sediments. Degassing mostly occurs in correspondence of bordering faults of buried horsts cut in the Mesozoic carbonate basement, hosting the main aquifer. Carbon isotopic composition (δ13CCO2) suggests that CO2 is at least partly originated by thermal decarbonation of these limestones. 3He/4He isotopic ratio of the gas (up to 1.9 Ra) is the same or even slightly higher than that of olivine and clinopyroxene fluid inclusions of the Alban Hills volcanic products, indicating a possible magmatic source for the gas. Low R/Ra values, compared to MORB and island arc magmas, are characteristic of the potassic Roman Comagmatic Province and reflect a deep involvement of crustal material in the magma genesis. The lack of high temperature fumaroles can be explained by an efficient meteoric cold water penetration and circulation in the volcano permeable terrains.
    Description: Published
    Description: 5-16
    Description: 4.5. Degassamento naturale
    Description: JCR Journal
    Description: reserved
    Keywords: Alban Hills ; magma degassing ; CO2 fluxes ; gas blowouts ; C and He isotopes ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
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  • 85
    Publication Date: 2022-06-08
    Description: An integrated sedimentological, magnetostratigraphic, and paleontological study of the Vallcebre section (south eastern Pyrenees, Spain) is carried out in order to define and portray the transition from the Cretaceous to the Tertiary in a continental setting. A robust magnetostratigraphy is correlated to the standard polarity scale in light of known biochronological constraints (charophyte, marine invertebrates, eggshells and other dinosaur remains). Our results show that this section is among the thickest stratigraphic records for the continental Maastrichtian in the Old World. Sedimentology indicates a progressive regression from marine through lagoonal to entirely continental environments. The section is dominated by mudstones deposited under low energy conditions. Exceptionally, a basin-wide regression maximum is recorded some time before the Cretaceous–Tertiary boundary (K/T). This regression maximum is marked by the input of coarse-grained (alluvial) sediments that record a dramatic change in the landscape (quiet mud plains changed to sandy floodplains deposited by high-energy currents). After a period of renewed quiescence following the regression maximum, a Cenozoic flooding took place. Such terminal Cretaceous sequence of events has been recorded in shorter sections in several other basins from southwestern Europe. This energetic sediment input suggests that some time before the K/T event, a sudden paleoenvironmental reorganization took place in the continental basins of south western Europe.
    Description: Published
    Description: 35-47
    Description: 2.2. Laboratorio di paleomagnetismo
    Description: JCR Journal
    Description: reserved
    Keywords: K/T boundary ; magnetostratigraphy ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism
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  • 86
    Publication Date: 2017-04-04
    Description: A Conjugated Toop-Samis-Flood-Grjotheim (CTSFG) model is developed by combining the framework of the Toop-Samis polymeric approach with the Flood-Grjotheim theoretical treatment of silicate melts and slags. Electrically equivalent ion fractions are computed over the appropriate matrixes (anionic and cationic) in a Temkin notation for fused salts, and are used to weigh the contribution of the various disproportionation reactions of type: M2/pO(melt)+ 1/2S(gas)+M2/pS(melt)+1/2O2(gas) M2/po(melt)+1/2S2(gas)+3/2O2(gas)-M2/pSO4(melt)v being the charge of the generic Mp-1 cation. The extension of the anionic matrix is calculated in the framework of a previously developed polymeric model (Ottonello et al., 2001), based on a parameterization of Lux-Flood acid-base properties of melt components. Model activities follow the Raoultian behavior implicit in the Temkin notation, without the needs of introducing adjustable parameters. The CTSFG model is based on a large amount of data available in literature and exhibits a satisfactory heuristic capability, with virtually no compositional limits, as long as the structural role given to each oxide holds. The model may be employed to compute gas-melt equilibria involving sulfur and allows computing sulfide and sulfate contents of silicate melts whenever the fugacity of a gaseous sulfur species and oxygen are known. Alternatively, the model calculates the oxidation state of the system (i.e., oxygen fugacity), whenever an analytical determination of either sulfide/sulfate or ferrous/ferric ratios in the melt is provided. Calculated sulfide and sulfate capacities allow the estimates of sulfur abundance in various melts of geological interest, both under anhydrous and hydrous conditions or, alternatively, of fS2, given fO2 and the bulk sulfur content. In this case, fSO2 and fH2S may be eventually computed along the water-sulfur-melt boundary provided fH2O is known.
    Description: Published
    Description: 801-823
    Description: partially_open
    Keywords: sulfur ; silicate melts ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.04. Thermodynamics
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  • 87
    Publication Date: 2017-04-04
    Description: Despite its impact in understanding oceanic crust formation and eruptive styles of related volcanism, magma dynamics at midocean ridges are poorly known. Here, we propose a new method to assess ascent rates of mid-ocean ridge basalt (MORB) magmas,as well as their pre- and sin-eruptive dynamics. It is based on the idea that a rising magma can reach a variable degree of both CO2 supersaturation in melt and kinetic fractionation among noble gases in vesicles in relation to its ascent rate through the crust. To quantify the relationship, we have used a model of multicomponent bubble growth in MORB melts, developed by extending the single-component model of Proussevitch and Sahagian [A.A. Proussevitch, D.L. Sahagian, Dynamics and energetics of bubble growth in magmas: analytical formulation and numerical modeling, J. Geophys. Res. 103 (1998), 18223–18251.] to CO2–He–Ar gas mixtures. After proper parameterization, we have applied it to published suites of data having the required features (glasses from Pito Seamount and mid-Atlantic ridges). Our results highlight that the investigated MORB magmas display very different ranges of ascent rates: slow rises of popping rock forming-magmas that cross the crust (0.01–0.5 m/s), slightly faster rates of energetic effusions (0.1–1 m/s), up to rates of 1–10 m/s which fall on the edge between lava effusion and Hawaiian activity. Inside a single plumbing system, very dissimilar magma dynamics highlight the large differences in compressive stress of the oceanic crust on a small scale. Constraints on how the systems of ridges work, as well as the characteristics of the magmatic source, can also be obtained. Our model shows how measurements of both the dissolved gas concentration in melt and the volatile composition of vesicles in the same sample are crucial in recognizing the kinetic effects and definitively assessing magma dynamics. An effort should be made to correctly set the studied samples in the sequence of volcanic submarine deposits where they are collected. Enhanced knowledge of a number of physical properties of gas-bearing MOR magmas is also required, mainly noble gas diffusivities, to describe multicomponent bubble growth at a higher confidence level.
    Description: Published
    Description: 138-158
    Description: partially_open
    Keywords: Bubble growth ; MORB ; Noble gas ; Kinetic fractionation ; Modeling ; 04. Solid Earth::04.04. Geology::04.04.07. Rock geochemistry ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.04. Thermodynamics
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  • 88
    Publication Date: 2017-04-04
    Description: Thermal springs with a maximum measured temperature of 89°C discharge hot water and gas from a depth of 11 m, 400 m offshore of Punta Pantoque, located in the northern part of Bahìa de Banderas, near Puerto Vallarta, Mexico. The composition of all water samples collected from the sea bottom is close to that of sea water. Nevertheless, it was possible to estimate the thermal endmember composition by extrapolating the sulfate concentration to zero. This endmember is similar in chemical composition both to waters of the Rio Purificacion and La Tuna thermal springs, located to the South along the Pacific coast of the Jalisco Block, and to pore waters from the deep-sea drilling cores from some accretionary complexes. Gas composition as well as isotopic composition of He and carbon from CO2, CH4 and C2H6 suggests an essentially thermo-biogenic origin for the gas and the presence of a high proportion of radiogenic, crustal helium. Isotopic composition of He in the Punta de Mita gas (0.4 Ra) is the lowest ever measured in Mexican hydrothermal gases. These findings do not support the idea that there exists a direct connection between the Punta de Mita springs and the last volcanic events which occurred in this area at V3 Ma. Rather, this hydrothermal activity is related to deep active faulting and the existence of a deep regional aquifer or local aquifers of connate waters underlying the granites of the Jalisco Block.
    Description: Published
    Description: 329-338
    Description: partially_open
    Keywords: submarine springs ; hydrothermal systems ; geothermometry ; He-isotopes ; formation waters ; Jalisco Block ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 89
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    Elsevier
    In:  Taran Y. A., Inguaggiato S., Marin M., and Yurova L. M. (2002) Geochemistry of fluids from submarine hot springs at Punta de Mita, Nayarit, Mexico. J. Volcanol. Geoth. Res. 115, 329-338.
    Publication Date: 2017-04-04
    Description: We thank R.M. Prol-Ledesma for her comment on the paper by Taran et al. (2002a) and the new data presented on the water composition of the Punta de Mita (PM) submarine springs. Prol-Ledesma (2003) comments refer to a supposedly wrong citation, superficial description of the geological background, incorrect method of water sampling, wrong approach for the estimation of the end-member composition, irrelevant discussion on the origin of fluids and, lastly, the using of someone else’s ideas and conclusions. In addition, she claims that our data on the fluid chemistry of the springs are not the first (original)ones. The Comment is supported by numerous references to publications by Prol-Ledesma et al. The text below follows the rubrics in the Comment.
    Description: Published
    Description: 319-322
    Description: partially_open
    Keywords: submarine springs ; hydrothermal systems ; geothermometry ; He-isotopes ; formation waters ; Jalisco Block ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 90
    Publication Date: 2020-12-03
    Description: A study of the He isotopic ratios of fluid inclusions in olivine and pyroxene from the Roman Comagmatic Province (RCP),Italy, is presented together with 87Sr/86Sr isotope compositions of the whole rock or pyroxene phenocrysts. A clear covariation in He and Sr isotopes is apparent, with a strong northward increase in radiogenic He and Sr being evident. He and Sr isotopes ratios range from 3He/4He = 5.2 Ra and 87Sr/86Sr = 0.7056 in south Campania, to 3He/4He = 0.44 Ra and 87Sr/86Sr = 0.715905 in the northernmost Latium. Helium isotope ratios are significantly lower than MORB values and are among the lowest yet measured in subduction zone volcanism. The 3He/4He of olivine and pyroxene phenocryst-hosted volatiles appear to be little influenced by posteruptive processes and magma–crust interaction. The 3He/4He–87Sr/86Sr covariation is consistent with binary mixing between an asthenospheric mantle similar to HIMU ocean island basalts, and an enriched (radiogenic) mantle end member generated from subduction of the Ionian/Adriatic plate. The contribution of radiogenic He from metasomatic fluids and postmetasomatism radiogenic ingrowth in the wedge is strongly dependent on the initial He concentration of the mantle. Only when asthenosphere He concentrations are substantially lower than the MORB source mantle, and metasomatism occurred at the beginning of the subduction (f30 Ma), can ingrowth in the mantle wedge account for the 3He/4He of the most radiogenic basalts.
    Description: - European Social Fund - Scottish Universities - Carnegie Trust for the Universities of Scotland.
    Description: Published
    Description: 295–308
    Description: partially_open
    Keywords: Roman Comagmatic Province ; fluid inclusions ; helium ; strontium ; 04. Solid Earth::04.01. Earth Interior::04.01.03. Mantle and Core dynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.06. Subduction related processes ; 04. Solid Earth::04.07. Tectonophysics::04.07.08. Volcanic arcs ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks
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  • 91
    Publication Date: 2021-06-25
    Description: We report in this paper a systematic investigation of the chemical and isotopic composition of groundwaters flowing in the volcanic aquifer of Mt. Vesuvius during its current phase of dormancy, including the first data on dissolved helium isotope composition and tritium content. The relevant results on dissolved He and C presented in this paper reveal that an extensive interaction between rising magmatic volatiles and groundwaters currently takes place at Vesuvius. Vesuvius groundwaters are dilute (mean TDS 2800 mg/L) hypothermal fluids (mean T 17.7°C) with a prevalent alkaline-bicarbonate composition. Calcium-bicarbonate groundwaters normally occur on the surrounding Campanian Plain, likely recharged from the Apennines. D and 18O data evidence an essentially meteoric origin of Vesuvius groundwaters, the contribution from either Tyrrhenian seawater or 18O-enriched thermal water appearing to be small or negligible. However, the dissolution of CO2-rich gases at depth promotes acid alteration and isochemical leaching of the permeable volcanic rocks, which explains the generally low pH and high total carbon content of waters. Attainment of chemical equilibrium between the rock and the weathering solutions is prevented by commonly low temperature (10 to 28°C) and acid-reducing conditions. The chemical and isotope (C and He) composition of dissolved gases highlights the magmatic origin of the gas phase feeding the aquifer. We show that although the pristine magmatic composition may vary upon gas ascent because of either dilution by a soil-atmospheric component or fractionation processes during interaction with the aquifer, both 13C/12C and 3He/4He measurements indicate the contribution of a magmatic component with a 13C 0‰ and R/Ra of 2.7, which is consistent with data from Vesuvius fumaroles and phenocryst melt inclusions in olivine phenocrysts. A main control of tectonics on gas ascent is revealed by data presented in this paper. For example, two areas of high CO2 release and enhanced rock leaching are recognized on the western (Torre del Greco) and southwestern (Torre Annunziata–Pompeii) flanks of Vesuvius, where important NE-SW and NW-SE tectonic structures are recognized. In contrast, waters flowing through the northern sector of the volcano are generally colder, less saline, and CO2 depleted, despite in some cases containing significant concentrations of magmaderived helium. The remarkable differences among the various sectors of the volcano are reconciled in a geochemical interpretative model, which is consistent with recent structural and geophysical evidences on the structure of Somma-Vesuvius volcanic complex.
    Description: -European Union, -Ministero dell’Universita’ e della Ricerca Scientifica e Tecnologica; -CNR–Gruppo Nazionale per la Vulcanologia.
    Description: Published
    Description: 963–981
    Description: partially_open
    Keywords: isotopes ; water chemistry ; dissolved gases ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 03. Hydrosphere::03.04. Chemical and biological::03.04.07. Radioactivity and isotopes ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 92
    Publication Date: 2017-04-04
    Description: The chemical and isotopic composition of fumarolic gases emitted from Nisyros Volcano, Greece,and of a single gas sample from Vesuvio, Italy, was investigated in order to determine the origin of methane (CH4) within two subduction-related magmatic-hydrothermal environments. Apparent temperatures derived from carbon isotope partitioning between CH4 and CO2 of around 340°C for Nisyros and 470°C for Vesuvio correlate well with aquifer temperatures as measured directly and/or inferred from compositional data using the H2O-H2-CO2-CO-CH4 geothermometer. Thermodynamic modeling reveals chemical equilibrium between CH4, CO2 and H2O implying that carbon isotope partitioning between CO2 and CH4 in both systems is controlled by aquifer temperature. N2/3He and CH4/3He ratios of Nisyros fumarolic gases are unusually low for subduction zone gases and correspond to those of midoceanic ridge environments. Accordingly, CH4 may have been primarily generated through the reduction of CO2 by H2 in the absence of any organic matter following a Fischer-Tropsch-type reaction. However, primary occurrence of minor amounts of thermogenic CH4 and subsequent re-equilibration with co-existing CO2 cannot be ruled out entirely. CO2/3He ratios and 13CCO2 values imply that the evolved CO2 either derives from a metasomatized mantle or is a mixture between two components, one outgassing from an unaltered mantle and the other released by thermal breakdown of marine carbonates. The latter may contain traces of organic matter possibly decomposing to CH4 during thermometamorphism.
    Description: European community
    Description: Published
    Description: 2321–2334
    Description: partially_open
    Keywords: fumarolic gases ; hydrothermal systems ; chemical and isotopic equilibrium ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 93
    Publication Date: 2017-04-04
    Description: We present here new measurements of sulfur dioxide and hydrogen sulfide emissions from Vulcano, Etna, and Stromboli (Italy), made by direct sampling at vents and by filter pack and ultraviolet spectroscopy in downwind plumes. Measurements at the F0 and FA fumaroles on Vulcano yielded SO2/H2S molar ratios of 0.38 and 1.4, respectively, from which we estimate an H2S flux of 6 to 9 for the summit crater. For Mt. Etna and Stromboli, we found SO2/H2S molar ratios of 20 and 15, respectively, which combined with SO2 flux measurements, suggest H2S emission rates of 50 to 113 and 4 to 8, respectively. We observe that source and plume SO2/H2S ratios at Vulcano are similar, suggesting that hydrogen sulfide is essentially inert on timescales of seconds to minutes. This finding has important implications for estimates of volcanic total sulfur budget at volcanoes since most existing measurements do not account for H2S emission.
    Description: Published
    Description: 1861–1871
    Description: partially_open
    Keywords: H2S atmospheric budget ; volcanic degassing ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
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  • 94
    Publication Date: 2017-04-04
    Description: Hydrothermal systems and related vents can exhibit dramatic changes in their physico-chemical conditions over time as a response to varying activity in the feeding magmatic systems. Massive steam condensation and gas scrubbing processes of thermal fluids during their ascent and cooling cause further compositional changes that mask information regarding the conditions evolving at depth in the hydrothermal system. Here we propose a new stability diagram based on the CO2-CH4-CO-H2 concentrations in vapor, which aims at calculating the temperatures and pressures in hydrothermal reservoirs. To filter gas scrubbing effects, we have also developed a model for selective dissolution of CO2-H2S-N2-CH4-He-Ne mixtures in fresh and/or air-saturated seawater. This methodology has been applied to the recent (November 2002) crisis that affected the geothermal field off the island of Panarea (Italy), where the fluid composition and fluxes have been monitored for the past two decades. The chemical and isotopic compositions of the gases suggest that the volatile elements originate from an active magma, which feeds a boiling saline solution having temperatures of up to 350 C and containing 12 mol CO2 in vapor. The thermal fluids undergo cooling and re-equilibration processes on account of gas-water-rock interactions during their ascent along fracture networks. Furthermore, steam condensation and removal of acidic species, partial dissolution in cold air-saturated seawater and stripping of atmospheric components, affect the composition of the geothermal gases at shallow levels. The observed geochemical variations are consistent with a new input of magmatic fluids that perturbed the geothermal system and caused the unrest event. The present-state evolution shows that this dramatic input of fluids is probably over, and that the system is now tending towards steady-state conditions on a time scale of months.
    Description: Published
    Description: 3045-3059
    Description: partially_open
    Keywords: Submarine degassing ; geothermal system ; gas-water interaction ; gas geothermometry ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.04. Thermodynamics ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
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  • 95
    Publication Date: 2017-04-04
    Description: The northwestern flank of the Colli Albani, a Quaternary volcanic complex near Rome, is characterised by high CO2 values and Rn activities in the groundwater and by the presence of zones with strong emission of gas from the soil. The most significant of these zones is Cava dei Selci where many houses are located very near to the gas emission site. The emitted gas consists mainly of CO2 (up to 98 vol) with an appreciable content of H2S (0.8). The He and C isotopic composition indicates, as for all fluids associated with the Quaternary Roman and Tuscany volcanic provinces, the presence of an upper mantle component contaminated by crustal fluids associated with subducted sediments and carbonates. An advective CO2 flux of 37 tons/day has been estimated from the gas bubbles rising to the surface in a small drainage ditch and through a stagnant water pool, present in the rainy season in a topographically low central part of the area. A CO2 soil flux survey with an accumulation chamber, carried out in February-March 2000 over a 12 000 m2 surface with 242 measurement points, gave a total (mostly conductive) flux of 61 tons/day. CO2 soil flux values vary by four orders of magnitude over a 160-m distance and by one order of magnitude over several metres. A fixed network of 114 points over 6350 m2 has been installed in order to investigate temporal flux variations. Six surveys carried out from May 2000 to June 2001 have shown large variations of the total CO2 soil flux (8/25 tons/day). The strong emission of CO2 and H2S, which are gases denser than air, produces dangerous accumulations in low areas which have caused a series of lethal accidents to animals and one to a man. The gas hazard near the houses has been assessed by continuously monitoring the CO2 and H2S concentration in the air at 75 cm from the ground by means of two automatic stations. Certain environmental parameters (wind direction and speed; atm P, T, humidity and rainfall) were also continuously recorded. At both stations, H2S and CO2 exceeded by several times the recommended concentration thresholds. The highest CO2 and H2S values were recorded always with wind speeds less than 1.5 m/s, mostly in the night hours. Our results indicate that there is a severe gas hazard for people living near the gas emission site of Cava dei Selci, and appropriate precautionary and prevention measures have been recommended both to residents and local authorities.
    Description: - GNV funded research project Gas Hazard of Colli Albani
    Description: Published
    Description: 81^94
    Description: partially_open
    Keywords: Colli Albani ; CO2 flux ; H2S ; gas hazard ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes ; 04. Solid Earth::04.03. Geodesy::04.03.06. Measurements and monitoring ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.02. Experimental volcanism ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
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  • 96
    Publication Date: 2017-04-04
    Description: A systematic survey of soil CO2 concentrations was carried out on the flanks of Somma^Vesuvius volcano in order to constrain possible pathways responsible of carbon dioxide diffuse degassing taking place during the present state of quiescence. Measurements were performed at 1162 sites in late winter^spring 2000,highlighting that soil CO2 concentrations range from 50 to 10500 ppmV. A statistical analysis was developed in order to define the threshold value of anomaly and separate the biogenic CO2 component,produced by soil respiration,from the inorganic component of deep provenance. A computer routine was also elaborated to interpret the grid of CO2 anomalous concentration values and define the actual location,orientation and length of degassing structures. The results obtained by this procedure reveal a main control of the regional stress field on the patterns of gas migration. The identified degassing lineaments are typically oriented along the Apenninic (NW^SE) and anti-Apenninic (NE^SW)trends,which are known to govern the past geological and structural evolution of the Campanian Plain and present seismicity and deformation pattern of Mount Vesuvius. A main degassing area was recognized on the eastern and southern flanks of the volcano,which likely relates to the geometry of the underlying carbonate basement,reaching its top (500 m depth) in this sector of the volcano.
    Description: Published
    Description: 55-79
    Description: partially_open
    Keywords: Somma-Vesuvius ; CO2 degassing ; Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 97
    Publication Date: 2017-04-04
    Description: Since the early 1970s enhanced eruptive activity of Mount Etna has been accompanied by selective geochemical changes in erupted lavas, among which a gradual increase of alkalis whose origin is still debated. Here we provide further insight into the origin of this recent evolution, based on a detailed study of the chemistry and dissolved volatile content of melt inclusions trapped in olivine crystals of unusual plagioclase-poor primitive basalt that was extruded during a highly explosive flank eruption in July–August 2001. Two types of lava were erupted simultaneously along a N–S fracture system. Trachybasalts from the upper vents (2950–2700 m) were simply drained out by fracturing of the central volcanic conduit. They are identical to summit crater lavas and contain Mg-poor olivines (Fo70–72) with evolved and volatile-poor melt inclusions that represent late-stage crystallisation during shallow open conduit degassing. In contrast, plagioclase-poor basalt (80% of total) extruded through the lower vents (2550–2100 m) derived from lateral dyke intrusion of a more primitive and volatile-rich magma across the sedimentary basement. This primitive melt is best preserved in rare Fo82.4–80.5 skeletal olivines present in lapilli deposits from the most powerful activities at the 2550 m vent. Its high dissolved contents of H2 O (3.4 wt.%), CO2 (0.11 to 0.41 wt.%), S (0.32 wt.%), Cl (0.16 wt.%) and F (0.094 wt.%) point to its closed system ascent from ∼400 to 250 MPa (∼12 to 6.5 km depth b.s.l.). However, the predominance of euhedral olivine phenocrysts with common reverse zoning (cores Fo76–78 and rims Fo78–80) and decrepited inclusions shows that most of the erupted basalt derived from a slightly more evolved, crystallizing body of the same magma that was invaded by the uprising primitive melt prior to erupting. The few preserved inclusions in these olivines indicate pre-eruptive storage of that magma body at about 5 km depth b.s.l., in coherence with seismic data. We propose that the 2001 flank eruption resulted from gradual overpressuring of Etna's shallow plumbing system due to the influx of volatile-rich primitive basalt that may have begun several months in advance. We find that this basalt is much richer in alkalis (2.0 wt.% K2 O) and has higher S/Cl (2.0) but lower Cl/K and Cl/F ratios than all pre-1970s Etnean lavas (1.4 wt.% K2 O, S/Cl=1.5), as further exemplified by melt inclusions in entrained olivine xenocrysts. Combining these new observations with previously published data, we argue that the 2001 basalt represents a new alkali-rich basic end-member feeding Mt. Etna, only few amount of which had previously been extruded during a 1974 peripheral eruption and, more recently, during brief paroxysmal summit events. Over the last three decades this new magma has progressively mixed with and replaced the former K-poorer trachybasalts filling the plumbing system, leading to extrusion of gradually more primitive and alkali-richer lavas. Its geochemical singularities cannot result from shallow crustal contaminations. Instead, they suggest the involvement of an alkali-richer but Cl-poorer arc-type component during recent magma genesis beneath Etna.
    Description: Published
    Description: 1-17
    Description: partially_open
    Keywords: Mt. Etna ; volatiles ; degassing ; eruptive mechanism ; magma geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
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  • 98
    Publication Date: 2017-04-04
    Description: Chlorine- and sulphur-bearing compounds in fumarole discharges of the La Fossa crater at Vulcano Island (Italy) can be modelled by a mixing process between magmatic gases and vapour from a boiling hydrothermal system. This allows estimating the compounds in both endmembers. Magma degassing cannot explain the time variation of sulphur and HCl concentrations in the deep endmember, which are more probably linked to reactions of solid phases at depth, before mixing with the hydrothermal vapours. Based on the P^T conditions and speciation of the boiling hydrothermal system below La Fossa, the HCl and Stot contents in the hydrothermal vapours were used to compute the redox conditions and pH of the aqueous solution. The results suggest that the haematite magnetite buffer controls the hydrothermal fO2 values, while the pH has increased since the end of the 1970s. The main processes affecting pH values may be linked to Na^Ca exchanges between evolved seawater, feeding the boiling hydrothermal system, and local rocks. While Na is removed from water, calcium enters the solution, undergoes hydrolysis and produces HCl,lowering the pH of the water. The increasing water^rock ratio within the hydrothermal system lowers the Ca availability, so the aqueous solution becomes less acidic. Seawater flowing towards the boiling hydrothermal brine dissolves a large quantity of pyrite along its path. In the boiling hydrothermal system, dissolved sulphur precipitates as pyrite and anhydrite, and becomes partitioned in vapour phase as H2S and SO2. These results are in agreement with the paragenesis of hydrothermal alteration minerals recovered in drilled wells at Vulcano and are also in agreement with the isotopic composition of sulphur emitted by the crater fumaroles.
    Description: Published
    Description: 137-150
    Description: partially_open
    Keywords: chlorine ; sulphur ; hydrothermal system ; genetic processes ; Vulcano Island ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.04. Thermodynamics ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
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  • 99
    Publication Date: 2017-04-04
    Description: This work addresses the study of fluid circulation of the Stromboli island using a dense coverage of self-potential (SP) and soil CO2 data. A marked difference exists between the northern flank and the other flanks of the island. The northern flank exhibits (1) a typical negative SP/altitude gradient not observed on the other flanks, and (2) higher levels of CO2. The general SP pattern suggests that the northern flank is composed of porous layers through which vadose water flows down to a basal water table, in contrast to the other flanks where impermeable layers impede the vertical flow of vadose water. In the Sciara del Fuoco and Rina Grande-Le Schicciole landslide complexes, breccias of shallow gliding planes may constitute such impermeable layers whereas elsewhere, poorly permeable, fine-grained pyroclastites or altered lava flows may be present. This general model of the flanks also explains the main CO2 patterns: concentration of CO2 at the surface is high on the porous north flank and lower on the other flanks where impermeable layers can block the upward CO2 flux. The active upper part of the island is underlain by a well-defined hydrothermal system bounded by short-wavelength negative SP anomalies and high peaks of CO2. These boundaries coincide with faults limiting ancient collapses of calderas, craters and flank landslides. The hydrothermal system is not homogeneous but composed of three main subsystems and of a fourth minor one and is not centered on the active craters. The latter are located near its border. This divergence between the location of the active craters and the extent of the hydrothermal system suggests that the internal heat sources may not be limited to sources below the active craters. If the heat source strictly corresponds to intrusions at depth around the active conduits, the geometry of the hydrothermal subsystems must be strongly controlled by heterogeneities within the edifice such as craters, caldera walls or gliding planes of flank collapse, as suggested by the correspondence between SP^CO2 anomalies and structural limits. The inner zone of the hydrothermal subsystems is characterized by positive SP anomalies, indicating upward movements of fluids, and by very low values of CO2 emanation. This pattern suggests that the hydrothermal zone becomes self-sealed at depth, thus creating a barrier to the CO2 flux. In this hypothesis, the observed hydrothermal system is a shallow one and it involves mostly convection of infiltrated meteoric water above the sealed zone. Finally, on the base of CO2 degassing measurements, we present evidence for the presence of two regional faults, oriented N41‡ and N64‡, and decoupled from the volcanic structures.
    Description: Published
    Description: 1^18
    Description: partially_open
    Keywords: Stromboli ; hydrothermal system ; self-potential ; soil gas ; carbon dioxide ; Aeolian islands ; 03. Hydrosphere::03.02. Hydrology::03.02.02. Hydrological processes: interaction, transport, dynamics ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
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  • 100
    Publication Date: 2017-04-04
    Description: One of the seven potentially active andesite stratovolcanoes in southern Peru, Misti (5822 m), located 17 km northeast and 3.5 km above Arequipa, represents a major threat to the population (f900,000 inhabitants). Our recent geophysical and geochemical research comprises an extensive self-potential (SP) data set, an audioâ magnetotelluric (AMT) profile across the volcano and CO2 concentrations in the soil along a radial profile. The SP survey is the first of its kind in providing a complete mapping of a large andesitic stratovolcano 20 km in diameter. The SP mapping enables us to analyze the SP signature associated with a subduction-related active volcano. The general SP pattern of Misti is similar to that of most volcanoes with a hydrogeologic zone in the lower flanks and a hydrothermal zone in the upper central area. A quasi-systematic relationship exists between SP and elevation. Zones with constant SP/altitude gradients (Ce) are observed in both hydrogeologic (negative Ce) and hydrothermal (positive Ce) zones. Transition zones between the different Ce zones, which form a concentric pattern around the summit, have been interpreted in terms of lateral heterogeneities in the lithology. The highest amplitudes of SP anomalies seem to coincide with highly resistive zones. The hydrothermal system 6 km in diameter, which extends over an area much larger than the summit caldera, may be constrained by an older, concealed collapse caldera. A sealed zone has apparently developed through alteration in the hydrothermal system, blocking the migration of CO2 upward. Significant CO2 emanations are thus observed on the lower flanks but are absent above the hydrothermal zone.
    Description: - Institut de Recherche pour le Developpement (IRD) - Instituto Geofısico del Peru´ (IGP)
    Description: Published
    Description: 343-360
    Description: partially_open
    Keywords: Misti volcano ; self-potential ; audioâ magnetotelluric ; electrical resistivity ; structural discontinuity ; hydrothermal system ; Peru ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
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