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  • General Chemistry  (9,057)
  • 42.75
  • 2010-2014  (49)
  • 1995-1999  (6,878)
  • 1950-1954  (2,207)
Collection
Keywords
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Year
  • 1
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    Twee nieuwe tweestaarten in Nederland (Diplura) (2014)
    In:  Nederlandse Faunistische Mededelingen (0169-2453) vol.43 (2014) p.5
    Details
    Publication Date: 2017-03-16
    Description: Tweestaarten Diplura behoren met de springstaarten Collembola en beentasters Protura tot de Entognatha. Dat zijn kleine ongevleugelde bodemdieren met zes poten, die zich onderscheiden van de insecten door hun verzonken monddelen. Tot nu toe waren twee soorten voor Nederland gemeld, maar voor België 13. Tijdens een onderzoek naar in mierennesten levende organismen werden twee soorten gevonden die nog niet uit Nederland bekend waren. Verder onderzoek zal zeker nog meer nieuwe tweestaarten kunnen opleveren.
    Keywords: Diplura ; Nederland ; Campodea lubbocki ; Campodea plusiochaeta ; verspreiding ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
    Type: Article / Letter to the editor
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  • 2
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    De kriebelmuggen van Nederland en Vlaanderen (Diptera: Simuliidae) (2014)
    In:  Nederlandse Faunistische Mededelingen (0169-2453) vol.43 (2014) p.67
    Details
    Publication Date: 2017-03-16
    Description: Larven van kriebelmuggen komen uitsluitend voor in stromend water, waar ze met hun waaiervormige monddelen deeltjes filteren uit het voorbij stromende water. Het zijn goede indicatoren voor zuurstofrijk water. Tot nu toe was niet duidelijk welke soorten precies voorkomen in Nederland en België en de determinatie van kriebelmuggen wordt vaak als lastig beschouwd. Om dit te verhelpen, presenteren we hier determinatietabellen voor alle in Nederland en België voorkomende soorten, zowel voor larven van het laatste stadium als voor poppen.
    Keywords: Diptera ; Simuliidae ; Nederland ; België ; herkenning ; verspreiding ; ecologie ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
    Type: Article / Letter to the editor
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  • 3
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    Recente aanvullingen op de Nederlandse loopkevercatalogus (Coleoptera: Carabidae) (2014)
    In:  Nederlandse Faunistische Mededelingen (0169-2453) vol.43 (2014) p.17
    Details
    Publication Date: 2017-03-16
    Description: De catalogus van de Nederlandse kevers uit 2010 geeft het meest recente overzicht van de Nederlandse kevers. Er staan 372 soorten loopkevers op deze lijst. Per soort wordt een overzicht gegeven van de provincies waaruit waarnemingen bekend zijn. Voor elk zogenaamd provincierecord is een collectie-exemplaar aangeduid als bewijsexemplaar. Sinds 2010 is er veel nieuwe informatie over loopkevers bekend geworden. In dit artikel worden de wijzigingen in de lijst toegelicht.
    Keywords: Coleoptera ; Carabidae ; Nederland ; verspreiding ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
    Type: Article / Letter to the editor
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  • 4
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    De reuzenertswesp Leucospis dorsigera nieuw voor Nederland (Hymenoptera: Chalcidoidea) (2014)
    In:  Nederlandse Faunistische Mededelingen (0169-2453) vol.43 (2014) p.1
    Details
    Publication Date: 2017-03-16
    Description: Hoe een leek op het gebied van wespen en bijen toch een leuke vondst kan doen. Op zonnige dagen gaat de auteur regelmatig op ‘tuinsafari’. Een tuin waarin rekening wordt gehouden met vogels en insecten, door keuze van beplanting en het ophangen van insectenhotels. De inspanningen leverden op 23 juli 2014 een opvallende wesp op. In een bijna automatische reactie werden snel foto’s gemaakt, in de hoop ze later te kunnen determineren. De wesp vloog daarna weg en werd niet meer gezien. Na determinatie blijkt het reuzenertswesp Leucospis dorsigera te zijn, een nieuwe soort bronswesp voor Nederland.
    Keywords: Hymenoptera ; Chalcidoidea ; Leucospis dorsigera ; Nederland ; herkenning ; biologie ; verspreiding ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
    Type: Article / Letter to the editor
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  • 5
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    Twee nieuwe citroenzweefvliegen voor Nederland: Xanthogramma dives en X. stackelbergi (Diptera: Syrphidae) (2014)
    In:  Nederlandse Faunistische Mededelingen (0169-2453) vol.43 (2014) p.27
    Details
    Publication Date: 2017-03-16
    Description: De gewone citroenzweefvlieg Xanthogramma pedissequum is een eenvoudig te herkennen zweefvlieg. Tenminste, dat dachten we tot voor kort. Nu blijkt dat de bijna identieke X. dives en X. stackelbergi ook in Nederland rondvliegen. Gelukkig zijn er enkele kenmerken waarmee deze drie soorten citroenzweefvlieg in het veld redelijk herkenbaar blijken. In dit artikel bespreken we deze kenmerken en geven we informatie over verspreiding en vliegtijden van de drie soorten.
    Keywords: Diptera ; Syrphidae ; Xanthogramma dives ; Xanthogramma stackelbergi ; Nederland ; herkenning ; verspreiding ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
    Type: Article / Letter to the editor
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  • 6
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    Blaaskopvliegen van het genus Leopoldius in de Benelux (Diptera: Conopidae) (2014)
    In:  Nederlandse Faunistische Mededelingen (0169-2453) vol.43 (2014) p.55
    Details
    Publication Date: 2017-03-16
    Description: Wespblaaskoppen Leopoldius worden ondanks hun opvallende uiterlijk maar weinig waargenomen. De soorten zijn lastig van elkaar te onderscheiden en bovendien werden tot voor kort variabele kenmerken gebruikt, wat tot veel verwarring heeft geleid. Nu blijkt dat alleen vrouwtjes met zekerheid te herkennen zijn aan de vorm van het klampje. Dit is een lepelvormig uitsteeksel onder het vijfde achterlijfsegment. Het wordt gebruikt bij het afzetten van eieren op een gastheer. Waarschijnlijk zijn limonadewespen de belangrijkste gastheer van Leopoldius. In dit artikel wordt een nieuwe soort voor België en een nieuwe soort voor Luxemburg gemeld. Daarnaast wordt een overzicht geboden van waarnemingen in Nederland, België en Luxemburg en een sleutel tot de Noordwest-Europese soorten.
    Keywords: Diptera ; Conopidae ; Leopoldius ; Nederland ; België ; Luxemburg ; herkenning ; biologie ; verspreiding ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
    Type: Article / Letter to the editor
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  • 7
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    Eerste larvenvondst van de kokerjuffer Molanna albicans buiten Drenthe (Trichoptera: Molannidae) (2014)
    In:  Nederlandse Faunistische Mededelingen (0169-2453) vol.43 (2014) p.93
    Details
    Publication Date: 2017-03-16
    Description: Ondanks de fors toegenomen aandacht voor watermacrofauna sinds begin jaren 1980 is de schietmot Molanna albicans maar sporadisch aangetroffen. In dit artikel wordt de eerste larvenvondst van M. albicans buiten Drenthe beschreven. Samen met de vindplaatsen in Drenthe is de soort nu van vijf vennen in Nederland bekend. Aanvullend worden de determinatiekenmerken aan de hand van foto’s geïllustreerd.
    Keywords: Trichoptera ; Molannidae ; Molanna albicans ; Nederland ; verspreiding ; biologie ; herkenning ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
    Type: Article / Letter to the editor
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  • 8
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    Spatial and temporal distribution of caddisfly larvae in two lowland streams in The Netherlands (Trichoptera) (2014)
    In:  Nederlandse Faunistische Mededelingen (0169-2453) vol.42 (2014) p.81
    Details
    Publication Date: 2017-03-16
    Description: Caddisflies are a species rich insect order. The adults are moth-like, but their wings bear hairs instead of scales. The larvae are aquatic and live in self-constructed cases, made of plant material, sand or debris. The species are used as indicators of water quality, but much is still not known about their biology and ecology. In this paper the preferred substrates and phenology of the larvae of 13 species are described, using the data of a survey of two lowland streams in the east of the Netherlands.
    Keywords: Trichoptera ; ecology ; phenology ; Netherlands ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
    Type: Article / Letter to the editor
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  • 9
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    Slakkendodende vliegen van het genus Psacadina in Nederland en België (Diptera: Sciomyzidae) (2014)
    In:  Nederlandse Faunistische Mededelingen (0169-2453) vol.42 (2014) p.37
    Details
    Publication Date: 2017-03-16
    Description: Slakkendodende vliegen danken hun naam aan hun roofzuchtige, parasitaire larven, die het op slakken gemunt hebben. Uit België en Nederland zijn circa 60 soorten uit deze familie bekend, maar er zijn er zeker meer te ontdekken. Dit artikel meldt een nieuwe soort voor de Nederlandse fauna uit het genus Psacadina, dat in beide landen drie soorten telt. De herkenning en het voorkomen van de drie soorten wordt uitgebreid besproken.
    Keywords: Diptera ; Sciomyzidae ; Psacadina ; Nederland ; België ; biologie ; herkenning ; verspreiding ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
    Type: Article / Letter to the editor
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  • 10
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    De zwarte vlieg Bibio venosus nieuw voor de Nederlandse fauna (Diptera: Bibionidae) (2014)
    In:  Nederlandse Faunistische Mededelingen (0169-2453) vol.42 (2014) p.33
    Details
    Publication Date: 2017-03-16
    Description: Zwarte vliegen behoren tot de muggen, maar door hun korte antennen doen ze oppervlakkig aan vliegen denken. De mannetjes zien er met hun grote kop en grote ogen heel anders uit dan de vrouwtjes, die een kleine kop met kleine ogen hebben. In het voorjaar vormen sommige soorten opvallend grote zwermen op windluwe plekken. Aan de 17 soorten die reeds uit Nederland bekend waren, kan er nu één worden toegevoegd: Bibio venosus.
    Keywords: Diptera ; Bibionidae ; Bibio venosus ; herkenning ; biologie ; verspreiding ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
    Type: Article / Letter to the editor
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  • 11
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    Uitbreiding van de hooiwagen Astrobunus leavipes (Opiliones) (2014)
    In:  Nederlandse Faunistische Mededelingen (0169-2453) vol.42 (2014) p.11
    Details
    Publication Date: 2017-03-16
    Description: Astrobunus laevipes is een hooiwagen die via het Rijnbekken recentelijk ons land is binnengekomen. Er waren al vondsten langs de Waal en Nederrijn in Gelderland en het meest oostelijke puntje van de provincie Utrecht. Door gerichte inventarisaties kunnen wij de hooiwagen nu nieuw voor de provincies Zuid-Holland en Noord-Brabant melden. Daarnaast is er van A. laevipes nu ook een waarneming langs de IJssel en enkele westelijker in de provincie Utrecht. Allerlei rivierbegeleidende biotopen langs (uitlopers van) de Nederrijn en Waal worden al door deze opmerkelijke hooiwagen bevolkt, maar de noordelijke uitbreiding via de IJsselvallei lijkt veel trager te verlopen. De Maas lijkt nog niet bereikt.
    Keywords: Opiliones ; Astrobunus leavipes ; Nederland ; verspreiding ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
    Type: Article / Letter to the editor
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  • 12
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    Vierde aanvulling op de naamlijst van Nederlandse sluipvliegen (Diptera: Tachinidae) (2014)
    In:  Nederlandse Faunistische Mededelingen (0169-2453) vol.43 (2014) p.43
    Details
    Publication Date: 2017-03-16
    Description: De familie der sluipvliegen is één der soortenrijkste vliegenfamilies in ons land. De larven ontwikkelen zich inwendig in ongewervelden, veelal vlinderrupsen. De familie is in ons land relatief goed bestudeerd. In dit artikel wordt wederom een soort voor het eerst uit ons land vermeld. Hiermee komt het totaal aantal soorten dat in Nederland ooit vastgesteld is op 334.
    Keywords: Diptera ; Tachinidae ; Pexopsis aprica ; Nederland ; verspreiding ; biologie ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
    Type: Article / Letter to the editor
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  • 13
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    Bamboewormen in Nederland, met Micromaldane ornithochaeta nieuw voor Nederland (Polychaeta: Maldanidae) (2014)
    In:  Nederlandse Faunistische Mededelingen (0169-2453) vol.43 (2014) p.111
    Details
    Publication Date: 2017-03-16
    Description: Mariene borstelwormen vormen een ecologisch belangrijke, soortenrijke groep. Van diverse families is niet veel bekend over het voorkomen in Nederland en de bamboewormen (familie Maldanidae) behoren tot de slechtst bekende groepen. Bamboewormen danken hun naam aan de lange en aan het uiteinde verdikte segmenten. In dit artikel wordt een nieuwe bamboeworm voor Nederland besproken en een opsomming gegeven van de nu bekende inheemse soorten.
    Keywords: Polychaeta ; Maldanidae ; Micromaldane ornithochaeta ; Nederland ; herkenning ; verspreiding ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
    Type: Article / Letter to the editor
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  • 14
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    Slakkendodende vliegen van het genus Anticheta in Nederland, met twee soorten nieuw voor de fauna (Diptera: Sciomyzidae) (2014)
    In:  Nederlandse Faunistische Mededelingen (0169-2453) vol.42 (2014) p.47
    Details
    Publication Date: 2017-03-16
    Description: Slakkendodende vliegen zijn nog relatief slecht onderzocht in ons land, zeker de kleine soorten. De vertegenwoordigers van het genus Anticheta zijn kleine vliegjes, waarvan slechts twee soorten uit ons land bekend waren. Uitgebreider onderzoek, zowel in collecties als in het veld, heeft twee nieuwe soorten voor de fauna aan het licht gebracht: Anticheta nigra en A. obliviosa. Van de eerste soort waren wereldwijd slechts acht exemplaren bekend.
    Keywords: Diptera ; Sciomyzidae ; Anticheta ; Nederland ; herkenning ; biologie ; verspreiding ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
    Type: Article / Letter to the editor
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  • 15
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    Het dotterbloemgitje Cheilosia frontalis nieuw voor Nederland (Diptera: Syrphidae) (2014)
    In:  Nederlandse Faunistische Mededelingen (0169-2453) vol.43 (2014) p.37
    Details
    Publication Date: 2017-03-16
    Description: Zelfs in een goed onderzochte insectengroep als de zweefvliegen zijn nog altijd nieuwe soorten voor de Nederlandse fauna te ontdekken. Ook in 2014 was het weer raak, dit keer in het fraaie natuurgebied rond de Drentsche Aa. Het lijkt niet toevallig dat deze aanvulling op de Nederlandse fauna juist hier werd gevonden. Deze vindplaats vult ecologische informatie uit het buitenland aan, waardoor langzamerhand een beeld begint te ontstaan van de levenswijze van deze zeldzame zweefvlieg, waarover tot voor kort weinig bekend was.
    Keywords: Diptera ; Syrphidae ; Cheilosia frontalis ; Nederland ; herkenning ; biologie ; verspreiding ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
    Type: Article / Letter to the editor
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  • 16
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    Nieuwe vondsten van de doornkaakzandbij Andrena trimmerana in Nederland (Hymenoptera: Apoidea: Andrenidae) (2014)
    In:  Nederlandse Faunistische Mededelingen (0169-2453) vol.42 (2014) p.75
    Details
    Publication Date: 2017-03-16
    Description: De doornkaakzandbij ziet er in het voorjaar een beetje anders uit dan in de zomer. Daarom worden de voorjaarsdieren door sommigen tot een andere soort beschouwd dan de zomerdieren. Uit Nederland zijn slechts drie exemplaren bekend: twee uit het voorjaar en één uit de zomer. Toevallig komen alle exemplaren uit hetzelfde gebied. Of is dit geen toeval?
    Keywords: Hymenoptera ; Apoidea ; Andrenidae ; Andrena trimmerana ; Nederland ; herkenning ; verspreiding ; biologie ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
    Type: Article / Letter to the editor
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  • 17
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    Het Sachalin-elfje Melangyna pavlovskyi nieuw voor Nederland (Diptera: Syrphidae) (2014)
    In:  Nederlandse Faunistische Mededelingen (0169-2453) vol.42 (2014) p.29
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    Publication Date: 2017-03-16
    Description: Elfjes behoren tot de vroegste zweefvliegen die in het voorjaar uit de pop kruipen. Rond bloeiende wilgen wemelt het vaak van wilgenelfjes Melangyna lasiophthalma, waardoor het zoeken naar de zeldzamere soorten soms lastig is. Toch zijn de meeste soorten relatief makkelijk van elkaar te onderscheiden. Met de vondst van het Sachalinelfje M. pavlovskyi wordt het echter weer iets lastiger.
    Keywords: Diptera ; Syrphidae ; Melangyna pavlovskyi ; Nederland ; herkenning ; verspreiding ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
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  • 18
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    Drie steltmuggen nieuw voor Nederland (Diptera: Limoniidae) (2014)
    In:  Nederlandse Faunistische Mededelingen (0169-2453) vol.42 (2014) p.19
    Details
    Publication Date: 2017-03-16
    Description: Steltmuggen lijken op langpootmuggen en zijn daar nauw aan verwant. Veel soorten zijn groot en karakteristiek gekleurd, maar toch zijn ze in Nederland nog weinig bestudeerd. Dit artikel bewijst dat er nog veel te ontdekken valt: in één jaar tijd zijn drie soorten gevonden die nog niet uit ons land bekend waren: Atypophthalmus inustus, Molophilus niger en Arctoconopa melampodia. Hiermee komt het totaal aantal soorten voor Nederland op 149. De nieuwe meldingen sluiten goed aan op het bekende verspreidingsgebied.
    Keywords: Diptera ; Limoniidae ; Nederland ; verspreiding ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
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  • 19
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    De wants Jalla dumosa na 45 jaar weer in Nederland waargenomen (Heteroptera: Pentatomidae) (2014)
    In:  Nederlandse Faunistische Mededelingen (0169-2453) vol.43 (2014) p.9
    Details
    Publication Date: 2017-03-16
    Description: Jalla dumosa is een in Nederland zeer zeldzame pentatomide, die in 1969 voor het laatst was waargenomen op Terschelling. Na 45 jaren zonder waarnemingen werd ze in 2014 weer in klein aantal waargenomen in de Kooiduinen op Ameland. Rupsen van onder andere de duinparelmoervlinder en de sint-jansvlinder stonden daar op het menu. In deze bijdrage wordt informatie samengevat over de vondsten in Nederland, de biologie en de verspreiding van de soort.
    Keywords: Heteroptera ; Pentatomidae ; Jalla dumosa ; Nederland ; verspreiding ; biologie ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
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  • 20
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    The exotic jellyfish Blackfordia virginica introduced into the Netherlands (Cnidaria: Hydrozoa) (2014)
    In:  Nederlandse Faunistische Mededelingen (0169-2453) vol.43 (2014) p.103
    Details
    Publication Date: 2017-03-16
    Description: In August 2014 the exotic jellyfish Blackfordia virginica was captured in the harbour of Amsterdam. This is the first confirmed record of this species in the Netherlands, although in October 2013 a possible specimen was filmed and released. This indicates that the species might be established in the Amsterdam area, although repeated introduction with ballast water cannot be ruled out. In September 2014 hydrozoan polyp colonies closely resembling those of B. virginica were collected near IJmuiden in the Noordzeekanaal, a canal connecting Amsterdam with the North Sea at IJmuiden.
    Keywords: Cnidaria ; Hydrozoa ; Blackfordia virginica ; Netherlands ; exotic species ; distribution ; identification ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
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  • 21
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    Het hooiwagengenus Trogulus in Nederland (Opiliones: Trogulidae) (2014)
    In:  Nederlandse Faunistische Mededelingen (0169-2453) vol.42 (2014) p.1
    Details
    Publication Date: 2017-03-16
    Description: Wie een steen of boomstronk omkeert en voor het eerst een Trogulus opmerkt, zal dit bizarre beest niet direct associëren met een hooiwagen. Met de korte, stevige poten, het afgeplatte achterlijf dat overdekt is met strooisel en zand, en een trage manier van voortbewegen is het een ongewone verschijning. De soorten van dit geslacht zijn bodembewoners die zich voornamelijk voeden met kleine huisjesslakken. Uit ons land waren tot nu toe twee soorten bekend. De identiteit van een van die twee was lang onzeker, maar door nieuwe inzichten is nu duidelijk om welke soort het werkelijk gaat. In Nederland blijkt bovendien nog een derde soort voor te komen, die hier voor het eerst gemeld wordt.
    Keywords: Opiliones ; Trogulidae ; Trogulus ; Nederland ; herkenning ; verspreiding ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
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  • 22
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    De gouden stamjager Choerades igneus nieuw voor Nederland (Diptera: Asilidae) (2014)
    In:  Nederlandse Faunistische Mededelingen (0169-2453) vol.43 (2014) p.47
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    Publication Date: 2017-03-16
    Description: Roofvliegen zijn met 40 Nederlandse soorten een vrij kleine groep, die behoorlijk goed is onderzocht. Het gebeurt dan ook niet vaak dat er een nieuwe soort voor de Nederlandse fauna kan worden opgetekend. De meeste roofvliegen zijn grijze vliegen, zo niet de stamjagers van het genus Choerades. Dit zijn juist vrij opvallend gekleurde vliegen. Zo heeft de rode dennenstamjager Choerades gilvus een rood gekleurd achterlijf. Opmerkelijk genoeg blijkt dat in Nederland juist onder deze opvallende verschijning twee soorten schuilgaan.
    Keywords: Diptera ; Asilidae ; Choerades igneus ; Nederland ; verspreiding ; biologie ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
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  • 23
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    Bruchus brachialis, een zaadkever nieuw voor de Nederlandse fauna (Coleoptera: Chrysomelidae) (2014)
    In:  Nederlandse Faunistische Mededelingen (0169-2453) vol.43 (2014) p.23
    Details
    Publication Date: 2017-03-16
    Description: Onlangs werd op een braakliggend terrein in Roermond de zaadkever Bruchus brachialis verzameld. Dit is de eerste Nederlandse vondst van deze zuidelijke soort. Een reeks recente waarnemingen uit de ons omringende landen laat zien dat deze soort al enige jaren in een noordwaartse areaaluitbreiding verwikkeld is. Met deze ontdekking komt het aantal Nederlandse Bruchus-soorten op zeven.
    Keywords: Coleoptera ; Chrysomelidae ; Nederland ; herkenning ; biologie ; verspreiding ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
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  • 24
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    De springstaart Entomobrya unostrigata nieuw voor noordwest Europa (Hexapoda: Collembola: Entomobryidae) (2014)
    In:  Nederlandse Faunistische Mededelingen (0169-2453) vol.42 (2014) p.63
    Details
    Publication Date: 2017-03-16
    Description: Nieuw gevormd landschap, zoals jonge duinvalleien, opgespoten polders en bedrijventerreinen in ontwikkeling vormen de habitat van gespecialiseerde soorten. Je moet tegen een stootje kunnen om in een dergelijke zandige, schaars begroeide omgeving te overleven. Vooral langdurig warme, droge perioden vormen een probleem voor vochtminnende bodemdieren. De springstaartsoorten die hier overleven zijn warmteminnend en droogteresistent, een bijzondere combinatie voor bodemdieren. Dit geldt ook voor Entomobrya unostrigata, een nieuwe aanwinst voor de fauna van Noordwest-Europa. Er is een aantal populaties van deze soort op de Tweede Maasvlakte gevonden. De dieren zaten hier onder stenen en hout op opgespoten zand.
    Keywords: Collembola ; Entomobryidae ; Entomobrya unostrigata ; Nederland ; herkenning ; verspreiding ; biologie ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
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  • 25
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    Sigalionide zeerupsen in Nederland, met Fimbriosthenelais minor nieuw voor Nederland (Polychaeta: Sigalionidae) (2014)
    In:  Nederlandse Faunistische Mededelingen (0169-2453) vol.42 (2014) p.71
    Details
    Publication Date: 2017-03-16
    Description: De Polychaeta vormen een groep van vrijwel uitsluitend mariene wormen, gekenmerkt door een geleed lichaam met aan de meeste leden een tamelijk groot aantal borstels. Het is een soortenrijke groep; ze spelen een belangrijke rol in de ecologie en diversiteit van vooral zachte, maar ook harde zeebodems. In vergelijking met de kreeftachtigen en weekdieren, eveneens soortenrijke groepen in dezelfde biotoop, zijn borstelwormen minder goed onderzocht. In dit artikel wordt de zeerups Fimbriosthenelais minor nieuw voor ons land gemeld. Met name op stenige en schelprijke bodems zijn nog meer nieuwe borstelwormen voor ons land te verwachten.
    Keywords: Polychaeta ; Sigalionidae ; Fimbriosthenelais minor ; Nederland ; herkenning ; verspreiding ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
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  • 26
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    Verspreiding en biotoop van het kalkdoorntje Tetrix tenuicornis in de Gelderse Poort (Orthoptera) (2014)
    In:  Nederlandse Faunistische Mededelingen (0169-2453) vol.42 (2014) p.55
    Details
    Publication Date: 2017-03-16
    Description: Het kalkdoorntje is een zeldzame sprinkhanensoort, die vooral bekend is uit Zuid-Limburg en van enkele locaties in het rivierengebied. Over het voorkomen van dit kleine sprinkhaantje binnen de Gelderse Poort was lange tijd weinig bekend. Pas vanaf 2007 worden regelmatig waarnemingen gedaan. Toevallige waarnemingen op, voor de auteur, onverwachte locaties vormden de aanleiding voor een grondige inventarisatie in de jaren 2011-2013. Hieruit komt naar voren dat het kalkdoorntje een ruime verspreiding heeft binnen de Gelderse Poort en een meer diverse biotoopkeuze heeft dan voorheen bekend was.
    Keywords: Orthoptera ; Tetrigidae ; Tetrix tenuicornis ; verspreiding ; biologie ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
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  • 27
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    Sensitivities of marine macrozoobenthos to environmental pressures in the Netherlands (2013)
    In:  Nederlandse Faunistische Mededelingen (0169-2453) vol.41 (2013) p.79
    Details
    Publication Date: 2015-12-09
    Description: The relative sensitivities of 309 common invertebrate species in Dutch marine waters are presented for environmental and anthropogenic pressures like organic enrichment, sedimentation and fisheries. The species were furthermore appointed to trophic groups like suspension and deposit feeders. The Dutch Ministry of Infrastructure and the Environment uses these data when calculating the Benthic Ecosystem Quality Index 2 and the Infaunal Trophic Index. These metrics aid in the mandatory monitoring of ecological quality for example for the European Water Framework Directive. The common Dutch species were selected based on their abundance according to, 1. the mwtl dataset including results of on-going monitoring programs issued by the Ministry, 2. the monitoring by volunteer scuba-divers for the anemoon Foundation and 3. the monitoring of fouling plates for the project setl.
    Keywords: macrozoobenthos ; marine ; Netherlands ; environment ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
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  • 28
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    De zeepissebed Uromunna spec, de eerste waarneming van de familie Munnidae in Nederland (Isopoda) (2013)
    In:  Nederlandse Faunistische Mededelingen (0169-2453) vol.41 (2013) p.43
    Details
    Publication Date: 2015-12-09
    Description: Onze fauna verandert en de mariene fauna is daarop geen uitzondering. Zuidelijke soorten koloniseren onze kustwateren en exotische soorten worden door de mens aangevoerd. Voor sommige soorten is niet duidelijk waarom ze hier opduiken. De sterk veranderende kustbiotopen spelen ongetwijfeld eveneens een rol. Een niet-aflatende stroom onverwachte soorten, soms zelfs behorend tot nieuwe genera en zelfs families maken faunistisch onderzoek in de kustwateren verrassend en boeiend. In het kader van een inventarisatie van kreeftachtigen in het Deltagebied werden in de Oosterschelde bij Zierikzee verscheidene kleine monsters genomen van diverse substraten. De monsters van roodwieren bevatten een aantal opmerkelijke soorten. Dit artikel behandelt Uromunna spec., een zeepissebeddensoort van een familie die in ons land nog niet was aangetroffen.
    Keywords: Isopoda ; Munnidae ; Nederland ; Uromunna ; verspreiding ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
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  • 29
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    First record of a settled stomatopod Platysquilla eusebia in the North Sea (Malacostraca: Stomatopoda) (2013)
    In:  Nederlandse Faunistische Mededelingen (0169-2453) vol.41 (2013) p.31
    Details
    Publication Date: 2015-12-09
    Description: This paper describes the discovery of a settled juvenile specimen of the stomatopod Platysquilla eusebia on the Dutch part of the Dogger Bank in the central North Sea. This is the northernmost record in Europe. The species is native to the Mediterranean and to the Atlantic coast from Portugal up to France. Further investigations have to show if the species already forms populations this far north. As the planktonic stages of P. eusebia have already been recorded in prior years, the establishment of the species should not be a problem, providing the circumstances are favourable.
    Keywords: Malacostraca ; Stomatopoda ; Platysquilla eusebia ; distribution ; Netherlands ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
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  • 30
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    De springstaart Fasciosminthurus quinquefasciatus nieuw voor de Nederlandse fauna (Collembola: Bourletiellidae) (2013)
    In:  Nederlandse Faunistische Mededelingen (0169-2453) vol.40 (2013) p.1
    Details
    Publication Date: 2015-12-09
    Description: Met enige regelmaat duiken nieuwe springstaartsoorten op in ons land. Het vinden van een nieuwe soort is soms op toeval gebaseerd. Op een foto van een sprinkhaan was naast de linker voorpoot een klein, donker vlekje te zien. Uitvergroot bleek het om een klein springstaartje te gaan. Het zwart-wit gestreepte patroon liet geen ruimte voor twijfel over de determinatie: Fasciosminthurus quinquefasciatus, een nieuwe springstaart voor de Nederlandse fauna. In dit artikel wordt het genus en de soort voorgesteld, beschrijven we de habitat en geven we informatie over de verspreiding in de rest van Europa.
    Keywords: Collembola ; Bourletiellidae ; Fasciosminthurus quinquefasciatus ; Nederland ; verspreiding ; herkenning ; biologie ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
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  • 31
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    Duistere heiderouwzwever Exoprosopa cleomene duikt op in Nederlandse wolzwevercollectie (Diptera: Bombyliidae) (2013)
    In:  Nederlandse Faunistische Mededelingen (0169-2453) vol.39 (2013) p.49
    Details
    Publication Date: 2015-12-09
    Description: De roodbruine heiderouwzwever Exoprosopa capucina is een fraaie en karakteristieke koffiebruine verschijning op de Nederlandse heideterreinen. Zoals veel wolzwevers is deze te herkennen aan de vleugeltekening en de kleur van de lichaamsbeharing. Echter naarmate de dieren ouder worden verliezen ze deze beharing en wordt de determinatie lastiger. Vermoedelijk heeft het verfomfaaide uiterlijk van een vrouwtje Exoprosopa cleomene er voor gezorgd dat deze ruim 50 jaar onopgemerkt tussen de exemplaren van E. capucina heeft gestaan.
    Keywords: Diptera ; Bombyliidae ; Exoprosopa cleomene ; Nederland ; verspreiding ; herkenning ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
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  • 32
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    Sulcacis bidentulus, een nieuwe houtzwamkever voor de Nederlandse fauna (Coleoptera: Ciidae) (2013)
    In:  Nederlandse Faunistische Mededelingen (0169-2453) vol.39 (2013) p.7
    Details
    Publication Date: 2015-12-09
    Description: In de afgelopen jaren werd op verschillende plekken in Nederland een houtzwamkever gevonden die tot nu toe niet officieel gemeld werd: Sulcacis bidentulus. Deze soort valt binnen de zeer eenvormige familie Ciidae op door de kleur van de dekschilden, die duidelijk iets lichter bruin zijn dan de rest van het lichaam. De soort zou zich ontwikkelen in de bleke borstelkurkzwam, die voornamelijk op populieren groeit. Oudere vondsten ontbreken en de ontdekking van deze soort op meerdere locaties duidt op een recente vestiging in ons land. Dit sluit aan bij de geconstateerde uitbreiding in Midden-Europa.
    Keywords: Coleoptera ; Ciidae ; Sulcacis bidentulus ; Nederland ; verspreiding ; biologie ; herkenning ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
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  • 33
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    Vestiging van de boomkrekel Oecanthus pellucens in het rivierengebied (Orthoptera) (2013)
    In:  Nederlandse Faunistische Mededelingen (0169-2453) vol.39 (2013) p.35
    Details
    Publication Date: 2015-12-09
    Description: De boomkrekel is een slanke geelbruine krekel, die vooral opvalt door zijn melodieuze zang. Vroeger moest je naar Frankrijk om dit geluid te horen, maar tegenwoordig heerst ook in het rivierengebied bij Nijmegen een mediterrane sfeer. De boomkrekel is in 2004 voor het eerst langs de Waal gevonden en heeft zich daarna uitgebreid. In 2010 en 2011 heeft de Flora- en faunawerkgroep Gelderse Poort met vele vrijwilligers onderzoek gedaan naar de precieze verspreiding. In totaal werd de boomkrekel in 57 kilometerhokken gevonden en de verwachting is dat de soort zich de komende jaren verder zal uitbreiden.
    Keywords: Orthoptera ; Oecanthus pellucens ; Nederland ; verspreiding ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
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  • 34
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    De Nederlandse hongerwespen (Hymenoptera: Evanioidea: Gasteruptiidae) (2013)
    In:  Nederlandse Faunistische Mededelingen (0169-2453) vol.39 (2013) p.55
    Details
    Publication Date: 2015-12-09
    Description: Hongerwespen behoren tot de grote groep van de sluipwespen. Het zijn slanke wespjes die typisch met hangende pootjes vliegen, waarbij de verbrede achterschenen opvallen. Ze parasiteren bijen en mogelijk ook bepaalde angeldragende wespen en worden daarom vaak bij bijenhotels waargenomen. In het kader van dit artikel zijn de meldingen van Nederlandse hongerwespen kritisch beschouwd. In totaal zijn nu negen soorten uit ons land bekend, waarvan er hier maar liefst zes voor het eerst worden gemeld.
    Keywords: Hymenoptera ; Evanioidea ; Gasteruptiidae ; Nederland ; verspreiding ; herkenning ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
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  • 35
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    Marine fauna of hard substrata of the Cleaver bank and Dogger bank (2013)
    In:  Nederlandse Faunistische Mededelingen (0169-2453) vol.41 (2013) p.69
    Details
    Publication Date: 2015-12-09
    Description: As most of the sea bottom in the Dutch part of the North Sea consists of sand, marine fauna that live in association with hard substrates are rarely monitored. We report here on the results of a species inventory in June 2011 done by scuba-diving while focusing on a wreck on the Dogger Bank and on rocky bottoms on the Cleaver Bank. This resulted in various new records of species for the Dutch part of the North Sea. This result appeared for a large part linked to the added value of monitoring with scuba-divers. It is therefore concluded that scuba-divers should be used in addition to the more traditional monitoring methods in which dredges and grabs are used, if one aims at getting an accurate view of the biodiversity present in marine regions like the North Sea.
    Keywords: biodiversity ; hard substrata ; Netherlands ; marine ; scuba-diving ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
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  • 36
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    Benthic communities on hard substrates within the first Dutch offshore wind farm (OWEZ) (2013)
    In:  Nederlandse Faunistische Mededelingen (0169-2453) vol.41 (2013) p.59
    Details
    Publication Date: 2015-12-09
    Description: Five years after the commissioning of the offshore wind farm Egmond aan Zee, the monopiles and the rocks of the scour protection layers were covered by a wide variety of marine organisms. This paper describes the results of qualitative and quantitative assessments carried out in 2008 and 2011. The assessments were based on video footage, pictures and samples collected by divers at three different wind turbines. The ecological relevance of identified taxa is also discussed.
    Keywords: offshore wind farms ; Netherlands ; biodiversity ; benthic zone ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
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  • 37
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    De gouden kegelbij Coelioxys aurolimbata teruggevonden in het rivierengebied (Hymenoptera: Apoidea: Megachilidae) (2013)
    In:  Nederlandse Faunistische Mededelingen (0169-2453) vol.40 (2013) p.39
    Details
    Publication Date: 2015-12-09
    Description: De gouden kegelbij Coelioxys aurolimbata is uit ons land recent alleen bekend uit de zuidelijke helft van Limburg. Vóór 1960 kwam deze parasiet van de lathyrusbij Chalicodoma ericetorum ook in het rivierengebied voor. In juli van dit jaar werd de gouden kegelbij gevangen in Duiven. Mogelijk is dit de voorbode van een herovering van het rivierengebied door deze bedreigde soort.
    Keywords: Hymenoptera ; Apoidea ; Megachilidae ; Nederland ; Coelioxys aurolimbata ; verspreiding ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
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  • 38
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    The juwel anemone Corynactis viridis, a new order for the Netherlands (Cnidaria: Corallimorpharia) (2013)
    In:  Nederlandse Faunistische Mededelingen (0169-2453) vol.41 (2013) p.35
    Details
    Publication Date: 2015-12-09
    Description: During an expedition with scuba-divers to the Dutch part of the Brown Ridge in the central North Sea in June 2013, two colonies of the jewel anemone Corynactis viridis were found on the wreck Anna Graebe. With the jewel anemone both a new species and a new animal order, the Corallimorpharia, are added to the autochthonous fauna of the Netherlands. This species typically occurs in the Mediterranean and along the Atlantic coast from Portugal and the west British Isles up to Shetland. As other records of settled colonies of C. viridis in the North Sea were recently reported from Belgian, German and English waters, it is concluded that the jewel anemone, which used to be known as an occasional visitor, should now be considered autochthonous in the North Sea.
    Keywords: Cnidaria ; Corallimorpharia ; Netherlands ; Corynactis viridis ; distribution ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
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  • 39
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    De molkreeften Upogebia deltaura en U. stellata en geassocieerde soorten in de Noordzee (Decapoda: Upogebiidae) (2013)
    In:  Nederlandse Faunistische Mededelingen (0169-2453) vol.41 (2013) p.15
    Details
    Publication Date: 2015-12-09
    Description: In de bodem van de Noordzee leeft een bijzondere groep van kreeften. Zij brengen hun leven door in een ondergronds gangenstelsel: de molkreeften. Het zijn algemene bewoners van het Friese Front, de Oestergronden en de Klaverbank. In, op en bij deze kreeften leven verschillende andere diersoorten: parasitaire pissebedden, een mosdiertje en twee soorten tweekleppigen. Deze bijdrage gaat in op de ecologie van de molkreeften en hun symbionten.
    Keywords: Decapoda ; Upogebiidae ; Upogebia ; Nederland ; biology ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
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  • 40
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    Moss animals of the Dutch part of the North Sea and coastal waters of the Netherlands (Bryozoa) (2013)
    In:  Nederlandse Faunistische Mededelingen (0169-2453) vol.41 (2013) p.1
    Details
    Publication Date: 2015-12-09
    Description: Bryozoa or moss animals constitute a conspicuous and species-rich component of hardsubstrate benthic communities in marine and estuarine habitats. To gain insight into the biodiversity of these habitats, knowledge of bryozoan species is indispensable. Since the last comprehensive publication on Dutch species in 2004 much new information has become available. Particularly from the Dutch part of the Continental Flat of the North Sea, the largest natural area of the Netherlands, many new records have been collected. Other reasons to present an updated review are changes in nomenclature, the arrival of some exotic species and identification issues.
    Keywords: Bryozoa ; Netherlands ; checklist ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
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  • 41
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    Tephrochlaena oraria, een nieuwe afvalvlieg voor de Nederlandse fauna (Diptera: Heleomyzidae) (2013)
    In:  Nederlandse Faunistische Mededelingen (0169-2453) vol.40 (2013) p.35
    Details
    Publication Date: 2015-12-09
    Description: Heleomyzidae zijn kleine tot middelgrote vliegen. Ze krijgen niet veel aandacht, omdat de meeste soorten een nogal verborgen leven leiden en bovendien niet opvallend gekleurd of getekend zijn. De Nederlandse familienaam, afvalvliegen, is voor de meeste soorten niet echt passend, maar veel soorten van de subfamilie Heteromyzinae, waartoe Tephrochlaena oraria behoort, worden dan wel weer vaker rond afval aangetroffen. Tephrochlaena oraria is echter in meerdere opzichten een buitenbeentje. Met deze soort komt de lijst van Nederlandse Heleomyzidae op 49.
    Keywords: Diptera ; Heleomyzidae ; Tephrochlaena oraria ; Nederland ; verspreiding ; herkenning ; biologie ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
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  • 42
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    Komt de vermiljoenkever Cucujus cinnaberinus in azijnzuurvallen (Coleoptera: Cucujidae)? (2013)
    In:  Nederlandse Faunistische Mededelingen (0169-2453) vol.40 (2013) p.9
    Details
    Publication Date: 2015-12-09
    Description: Cucujus cinnaberinus is een recent voor Nederland ontdekte soort. De kever staat op de Habitatrichtlijn, wat onder meer betekent dat hij beschermd is en dat de populatie gemonitord dient te worden. Inventarisatie en monitoring gebeurt in het algemeen door het weghalen van schors van recent gestorven bomen. Hierdoor wordt het leefgebied van de kever echter flink aangetast. Wij voerden een klein onderzoek uit naar de mogelijkheden om C. cinnaberinus te vangen in azijnzuurvallen, zodat de habitat intact gelaten kan worden en de soort toch geïnventariseerd kan worden. Tijdens het voorjaar van 2013 werden vier vallen opgehangen op een locatie waar zich een populatie van deze soort bevindt. Er werden slechts twee individuen verzameld; de vangmethode lijkt dus niet bijzonder geschikt.
    Keywords: Coleoptera ; Cucujidae ; Cucujus cinnaberinus ; methode ; inventarisatie ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
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  • 43
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    Northward dispersal of the tanaid Zeuxo holdichi to the Netherlands (Crustacea: Tanaidae) (2013)
    In:  Nederlandse Faunistische Mededelingen (0169-2453) vol.39 (2013) p.95
    Details
    Publication Date: 2015-12-09
    Description: The tanaid Zeuxo holdichi, described in 1990 from Arcachon Bay in southwest France, has since then been recorded from west Portugal to northern Brittany and southwest England. The species is recorded here from the Netherlands, a further northward expansion of the range. It is hypothesised that Z. holdichi may be non-native to Europe.
    Keywords: Crustacea ; Tanaidae ; Zeuxo holdichi ; Netherlands ; distribution ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
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  • 44
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    Ecological relevance of shipwrecks in the North Sea (2013)
    In:  Nederlandse Faunistische Mededelingen (0169-2453) vol.41 (2013) p.49
    Details
    Publication Date: 2015-12-09
    Description: This paper reports on observations made during wreck dive expeditions in 2010-2012, in order to investigate the ecological relevance of shipwrecks on the Dutch Continental Shelf (dcs). Shipwrecks are biodiversity hotspots. The number of species recorded on shipwrecks is similar to the number of species found in soft bottoms of the entire dcs. The soft substrates, however, represent a vastly larger habitat on the dcs than the shipwrecks. Amongst many other taxa, juvenile and large Atlantic cod, linear skeleton shrimp, goldsinny wrasses and leopard spotted gobies were found in the shipwreck habitats. The presence of these important species and their absence from many other habitats, illustrate that shipwrecks function as key habitats, nurseries, and refugia that are rare or absent anywhere else in the Netherlands.
    Keywords: shipwrecks ; Netherlands ; biodiversity ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
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  • 45
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    De hottentottenvilla Villa hottentotta toch op de Nederlandse lijst (Diptera: Bombyliidae) (2013)
    In:  Nederlandse Faunistische Mededelingen (0169-2453) vol.40 (2013) p.23
    Details
    Publication Date: 2015-12-09
    Description: Wolzwevers zijn vliegen waarvan de larven parasitair leven bij andere insecten. Wolzwevers van het genus Villa veroorzaken vaak determinatieproblemen. Deze problemen lijken verleden tijd met recent gepubliceerde taxonomische inzichten. Eindelijk konden nu ook de Nederlandse exemplaren van dit genus op naam gebracht worden. Deze bleken te behoren tot vier soorten, waarvan er twee vermoedelijk reeds zijn verdwenen.
    Keywords: Diptera ; Bombyliidae ; Villa hottentotta ; Nederland ; verspreiding ; herkenning ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
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  • 46
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    De bijzondere levensloop van de sluipwesp Acrodactyla quadrisculpta op de schaduwstrekspin Tetragnatha montana (Hymenoptera: Ichneumonidae, Araneae: Tetragnathidae) (2013)
    In:  Nederlandse Faunistische Mededelingen (0169-2453) vol.39 (2013) p.1
    Details
    Publication Date: 2015-12-09
    Description: Sluipwespen van de groep van de Polysphinctini hebben een bijzondere levenswijze. Het vrouwtje van wesp legt een eitje op het achterlijf van een spin. Wanneer het eitje is uitgekomen brengt de larve haar hele leven op het achterlijf van de spin door. Ze maakt kleine wondjes in de huid en voedt zich met lichaamsvloeistof van de spin. Na verloop van tijd ontwikkelt de larve bulten op de rug, een teken dat ze bijna volgroeid is. Ze zuigt dan de spin leeg, de ‘grote slurp’ genaamd, en verpopt zich in het web. In dit artikel wordt de levenswijze van één van deze soorten, Acrodactyla quadrisculpta, voor het eerst beschreven en geïllustreerd.
    Keywords: Hymenoptera ; Ichneumonidae ; Araneae ; Tetragnathidae ; biologie ; Nederland ; Acrodactyla quadrisculpta ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
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  • 47
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    Galvormende bladwespen op wilg in Nederland (Hymenoptera: Tenthredinidae: Nematinae) (2013)
    In:  Nederlandse Faunistische Mededelingen (0169-2453) vol.39 (2013) p.15
    Details
    Publication Date: 2015-12-09
    Description: De bladwespgenera Phyllocolpa, Tubpontania, Pontania en Euura hebben gemeenschappelijk dat ze gallen vormen op wilg. Recentelijk is er veel vernieuwend taxonomisch werk verricht aan deze groepen. In dit artikel wordt de Nederlandse situatie samengevat. Uit oudere literatuur waren 18 soorten bekend en in het recent gepubliceerde gallenboek worden nog eens 11 soorten voor het eerst voor ons land vermeld. In dit artikel worden nog acht soorten aan de lijst toegevoegd en twee soorten worden van de lijst afgevoerd. In totaal zijn nu 35 soorten galvormende bladwespen van wilg uit Nederland bekend.
    Keywords: Hymenoptera ; Tenthredinidae ; Nematinae ; Nederland ; verspreiding ; herkenning ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
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  • 48
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    De rode snuitvlieg Rhingia rostrata terug in Nederland (Diptera: Syrphidae) (2013)
    In:  Nederlandse Faunistische Mededelingen (0169-2453) vol.40 (2013) p.15
    Details
    Publication Date: 2015-12-09
    Description: Snuitvliegen zijn rare snuiters onder de zweefvliegen. Ze hebben een verlengd gezicht en een lange tong. Hiermee kunnen ze foerageren op bloemen met diepliggende nectar, in tegenstelling tot de meeste andere zweefvliegen. Als genus zijn de vliegen makkelijk herkenbaar, maar de zeer zeldzame soorten tussen de zeer algemene gewone snuitvlieg uithalen was niet altijd even makkelijk. In dit artikel wordt de herontdekking van de rode snuitvlieg beschreven en een tabel gegeven voor de drie Noordwest-Europese soorten.
    Keywords: Diptera ; Syrphidae ; Rhingia rostrata ; Nederland ; verspreiding ; herkenning ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
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  • 49
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    Eerste waarneming van de schietmot Ecclisopteryx dalecarlica in Nederland en nieuwe vondsten in België (Trichoptera: Limnephilidae) (2013)
    In:  Nederlandse Faunistische Mededelingen (0169-2453) vol.39 (2013) p.89
    Details
    Publication Date: 2015-12-09
    Description: De larven van Trichoptera heten kokerjuffers en leven in het water. Veel soorten bouwen een kokertje van zand, takjes of ander materiaal, vandaar de Nederlandse naam. De volwassen dieren lijken wel wat op nachtvlinders en worden schietmotten genoemd. De laatste jaren heeft het onderzoek naar deze dieren een grote vlucht genomen. Enerzijds spelen ze een rol als indicator voor de waterkwaliteit. De larven worden dan ook veel verzameld tijdens macrofaunabemonsteringen door waterschappen. Anderzijds is er een groeiende groep entomologen die schietmotten bestudeert. In dit artikel wordt Ecclisopteryx dalecarlica voorgesteld, een nieuwe soort voor Nederland.
    Keywords: Trichoptera ; Limnephilidae ; Ecclisopteryx dalecarlica ; Nederland ; Belgie ; verspreiding ; herkenning ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
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  • 50
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    Notes on Menippus and Issikia from Sumatra and Java, Indonesia (Coleoptera: Chrysomelidae: Galerucinae) (1999)
    In:  Zoologische Mededelingen (00240672) vol.73, 1-11 (1999) p.187
    Details
    Publication Date: 2007-01-23
    Description: Menippus philippinensis Jacoby, 1894, is reported from Java, and Issikia clarki (Jacoby, 1884) comb. nov., from Sumatra.
    Keywords: Coleoptera ; Chrysomelidae ; Galerucinae ; Menippus ; Issikia ; Issikia clarki ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
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  • 51
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    Nieuwe en oude vindplaatsen van de roofvlieg Machimus cowini in Nederland (Diptera: Asilidae) (1999)
    In:  Nederlandse Faunistische Mededelingen (01692453) vol.9 (1999) p.143
    Details
    Publication Date: 2007-01-10
    Description: New and old records of the robberfly Machimus cowini in the Netherlands (Diptera: Asilidae) Until recently, Machimus cowini (Hobby, 1943) was known from just one record in the Netherlands. An examination of Dutch specimens of the similar M. cingulatus revealed specimens of M. cowini from five new localities. The records are concentrated on the island Ameland and along the rivers Waal and Maas. On Ameland, M. cowini probably occurs in coastal dunes. Near Nijmegen the species was found in grassy vegetation on floodplains and on riverdunes near the river.
    Keywords: Insecta ; Diptera ; Asilidae ; Machimus cowini ; Nederland ; Verspreiding ; Biotopen ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
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  • 52
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    The Palaearctic species of the genus Diachasmimorpha Viereck (Hymenoptera: Braconidae: Opiinae) (1999)
    In:  Zoologische Mededelingen (00240672) vol.73, 1-11 (1999) p.1
    Details
    Publication Date: 2007-01-23
    Description: Two new species of the genus Diachasmimorpha Viereck, 1913 (Braconidae: Opiinae) are described: D. feijeni spec. nov. from Bhutan (reared from Bactrocera minax (Enderlein) (Diptera: Tephritidae) in fruits of Citrus reticulata Blanco (mandarin)) and D. budrysi spec. nov. from Far East Russia. A key to the Palaearctic species is added, including two similar species (Fopius alternatae (Tobias, 1977), and F. myolejae (Tobias, 1977)).
    Keywords: Hymenoptera ; Braconidae ; Opiinae ; Diachasmimorpha ; Palaearctic ; Bhutan ; Russia ; key ; Diptera ; Citrus reticulata ; Bactrocera minax ; Tephritidae ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
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  • 53
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    Pemphredon montana, een nieuwe graafwesp voor Nederland (Hymenoptera: Specidae) (1999)
    In:  Nederlandse Faunistische Mededelingen (01692453) vol.9 (1999) p.142
    Details
    Publication Date: 2007-01-10
    Description: Pemphredon montana, new to The Netherlands (Hymenoptera: Sphecidae) In 1998 Pemphredon montana Dahlbom, 1845 was recorded for the first time in the Netherlands. The species was found nesting in the insulating material of a caravan in the northernmost part of the province of Overijssel.
    Keywords: Insecta ; Hymenoptera ; Sphecidae ; Crabronidae ; Pemphredon montana ; Nederland ; Verspreiding ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
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  • 54
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    Porcellium conspersum, een in Nederland zeer zeldzame landpissebed van vochtige bossen (Crustacea: Isopoda: Oniscoidea) (1999)
    In:  Nederlandse Faunistische Mededelingen (01692453) vol.9 (1999) p.140
    Details
    Publication Date: 2007-01-10
    Description: The influence of recent inundations on the distribution pattern of the isopod Eluma purpurascens in the province of Zeeland (Crustacea: Isopoda: Oniscoidea) Small scale mapping of Eluma purpurascens Budde-Lund, 1885 in the province of Zeeland revealed a remarkable distribution pattern. The species proved to be absent in parts which have been inundated during and after the second world war. This study shows that for the interpretation of distribution patterns the history of the study area should be considered.
    Keywords: Arthropoda ; Crustacea ; Isopoda ; Oniscoidea ; Nederland ; Verspreiding ; Biotopen ; Herkenning ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
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  • 55
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    Faunistiek en ecologie van het zweefvliegengenus Epistrophe in Nederland (Diptera: Syrphidae) (1999)
    In:  Nederlandse Faunistische Mededelingen (01692453) vol.8 (1999) p.33
    Details
    Publication Date: 2007-01-09
    Description: Faunistics and ecology of the syrphid genus Epistrophe in The Netherlands (Diptera: Syrphidae) Ten species of Epistrophe have been found in the Netherlands, two of which, E. cryptica and E. similis, are recorded here for the first time. The distribution, changes in distribution and ecology of the species were investigated and are illustrated by distribution maps and diagrams of the flight period. In all species, except E. eligans, females were observed more than males. Furthermore, females seem to be active later in the season than males. It is discussed that this is probably caused by the differences in behaviour between the males of the species.
    Keywords: Insecta ; Diptera ; Syrphidae ; Epistrophe ; Fenologie ; Verspreiding ; Biologie ; Nederland ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
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  • 56
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    De sneeuwspringer Boreus hyemalis in Nederland (Mecoptera: Boreidae) (1999)
    In:  Nederlandse Faunistische Mededelingen (01692453) vol.8 (1999) p.1
    Details
    Publication Date: 2007-01-26
    Description: Until recently Boreus hyemalis was considered to be a rare species in The Netherlands. It was only known from a few localities in The Netherlands in the provinces of Noord-Holland, Zuid- Holland, Utrecht, Gelderland and Drenthe. The last few years many new populations have been discovered. In this paper the first records for the provinces of Limburg, Noord-Brabant and Overijssel are presented. The species seems to prefer scarcely vegetated patches in sanddunes, dominated by greyhair grass Corynephorus canescens and the moss Polytrichum piliferum. It proved to be relatively easy to find, when the right places were searched in the right period (October until February).
    Keywords: Insecta ; Mecoptera ; Boreidae ; Boreus hyemalis ; Sneeuwspringer ; Verspreiding ; Nederland ; Biotopen ; Biologie ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
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  • 57
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    The genus Bryotropha in the Netherlands (Lepidoptera: Gelechiidae) (1999)
    In:  Nederlandse Faunistische Mededelingen (01692453) vol.9 (1999) p.79
    Details
    Publication Date: 2007-01-10
    Description: Het genus Bryotropha in Nederland (Lepidoptera: Gelechiidae) Het genus Bryotropha staat bekend als een notoir lastig geslacht van kleine bruine motjes. Die moeilijkheid komt door de variatie, maar vooral ook door gebrek aan bruikbare beschrijvingen. Met dit artikel zijn de negen Nederlandse soorten te determineren. Vanwege het gebrek aan determinatieliteratuur in heel Europa is het in het Engels geschreven. Behalve de maar één keer waargenomen B. domestica, zijn de meeste soorten vrij gewone verschijningen in ons land, zoals uit de kaarten blijkt.
    Keywords: Insecten ; Lepidoptera ; Gelechiidae ; Verspreiding ; Nederland ; Fenologie ; Waardplanten ; Biotopen ; Determinatiesleutel ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
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  • 58
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    De valkruidmineervlinder Digitivalva arnicella in Nederland: herontdekking en behoud (Lepidoptera: Plutellidae: Acrolepiinae) (1999)
    In:  Nederlandse Faunistische Mededelingen (01692453) vol.9 (1999) p.15
    Details
    Publication Date: 2007-08-06
    Description: The occurrence of Digitivalva arnicella in the Netherlands: rediscovery and conservation (Lepidoptera: Plutellidae: Acrolepiinae) Digitivalva arnicella (Heyden, 1863), previously only known from two localities before 1902, has been rediscovered in eight localities in the northern part of the Netherlands (province of Drenthe) on its host Arnica montana. On the basis of leafmines, found in old herbarium collections, it can be concluded that the species was once widespread within the range of its host in the northern and eastern parts of the Netherlands and has apparently been overlooked by entomologists since. D. arnicella is a much endangered species in the Netherlands, because of the dramatic decline of its host. Two of the eight discovered populations have been lost since their discovery in the first half of the 1990’s. Systematics and life history of the species are described and illustrated, the distribution is mapped and advise for management of its sites are given. The current management of some populations of Arnica, by mowing the site completely in August, is disastrous for the young caterpillars, mining the leaves.
    Keywords: Acrolepiinae ; Plutellidae ; Yponomeutoidea ; Digitivalva ; Netherlands ; conservation ; Arnica ; Digitivalva arnicella ( Plutellidae- ) ; Habitat management ; Endangered status ; effect of food plant shortage ; conservation proposals ; Food plants ; Arnica montana ; effect on decline to endangered status ; Decline-to-endangered-status ; influences-and-conservation ; Netherlands ; Distribution ; population dynamics and conservation ; endangered species ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
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  • 59
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    De boskrekel Nemobius sylvestris in de duinen bij Bergen (Noord-Holland) (Orthoptera) (1999)
    In:  Nederlandse Faunistische Mededelingen (01692453) vol.8 (1999) p.91-93
    Details
    Publication Date: 2007-01-09
    Description: Nemobius sylvestris in the dunes near Bergen (Orthoptera) A large population of Nemobius sylvestris (Bosc, 1792) has been found in the dunes near Bergen (Noord-Holland), 60 km northwest of the nearest known site in the Gooi-area. This discovery sheds new light on a specimen from Bergen found in a collection, which was thought to be mislabelled.
    Keywords: Insecta ; Orthoptera ; Gryllidae ; Nemobius sylvestris ; Nederland ; Verspreiding ; Biotopen ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
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  • 60
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    Interessante libellenwaarnemingen in 1998 (Odonata) (1999)
    In:  Nederlandse Faunistische Mededelingen (01692453) vol.8 (1999) p.85
    Details
    Publication Date: 2007-01-09
    Description: Interesting new records of Odonata in the Netherlands in 1998 A survey of the most interesting observations on Dutch Odonata is presented. During the Odonata Recording Scheme many new records of rare species have become available. Gomphus flavipes, G. vulgatissimus, Anax parthenope, Sympetrum pedemontanum and S. depressiusculum seem to become more common. The status of some threatened species is elucidated: Calopteryx virgo, Sympecma paedisca, Coenagrion hastulatum and Cordulegaster boltonii.
    Keywords: Insecta ; Odonata ; Verspreiding ; Nederland ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
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  • 61
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    The West Palaearctic species of the subfamily Paxylommatinae (Hymenoptera: Ichneumonidae), with special reference to the genus Hybrizon Fallén (1999)
    In:  Zoologische Mededelingen (00240672) vol.73, 1-11 (1999) p.11
    Details
    Publication Date: 2007-01-23
    Description: The West Palaearctic species of the subfamily Paxylommatinae are reviewed and the species of the genus Hybrizon Fallén, 1813, from the Palaearctic region are keyed. Hybrizon juncoi (Ceballos, 1957) is recognized as a valid species, a neotype is designated for Hybrizon latebricola Nees, 1834, and a lectotype is designated for Plancus apicalis Curtis, 1833. Paxylomma grandis Rudow, 1883, Ogkosoma schwarzi Haupt, 1913, and Eurypterna arakawae Matsumura, 1918, are new junior synonyms of Eurypterna cremieri (de Romand, 1838).
    Keywords: Ichneumonidae ; Paxylommatinae ; Hybrizon ; Ghilaromma ; Eurypterna ; keys ; distribution ; Palaearctic ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
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  • 62
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    The genus Scrobipalpa in the Netherlands (Lepidoptera: Gelechiidae) (1999)
    In:  Nederlandse Faunistische Mededelingen (01692453) vol.9 (1999) p.29
    Details
    Publication Date: 2007-01-10
    Description: Het genus Scrobipalpa in Nederland (Lepidoptera: Gelechiidae) Scrobipalpa is een geslacht van kleine, lastig uit elkaar te houden motjes. In heel Europa zijn ongeveer 70 soorten bekend. Doorgaans zijn de vleugels bruin- of grijsachtig met een tekening van stippels en strepen die bovendien erg kan variëren. Hierdoor kunnen de individuele soorten vaak moeilijk herkend worden. Aan de hand van de genitaliën kunnen soorten wel allemaal gedetermineerd worden. Omdat de literatuur over deze groep niet erg toegankelijk is en bestaande beschrijvingen soms erg onvolledig zijn, wordt dit artikel in het Engels geschreven. Met dit artikel zijn de elf Nederlandse soorten te determineren. De meeste hiervan zijn min of meer gebonden aan de kust. Van alle soorten worden naast beschrijvingen van de vleugeltekening en de genitaliën, ook de verspreiding, de biologie en de ecologie gegeven.
    Keywords: Insecta ; Lepidoptera ; Scrobipalpa ; Verspreiding ; Biotopen ; Fenologie ; Herkenning ; Determinatiesleutel ; Waardplanten ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
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  • 63
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    Cheilosia caerulescens in Nederland in 1998 (Diptera: Syprhidae) (1999)
    In:  Nederlandse Faunistische Mededelingen (01692453) vol.8 (1999) p.93
    Details
    Publication Date: 2007-01-09
    Description: New records of Cheilosia caerulescens in the Netherlands (Diptera: Syrphidae) Cheilosia caerulescens is a rare hoverfly in The Netherlands. Until 1998 only four records were known, the first in 1986. In 1998 the species was found on three new and one old locality. The record from Heemstede (province of Noord-Holland) is among the northernmost in the European distribution of this species. Three of the four records originate from gardens.
    Keywords: Insecta ; Diptera ; Syrphidae ; Cheilosia caerulescens ; Nederland ; Verspreiding ; Biotopen ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
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  • 64
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    Dansmuggen in natuurontwikkelingsgebieden (Chironomidae) (1999)
    In:  Nederlandse Faunistische Mededelingen (01692453) vol.8 (1999) p.89
    Details
    Publication Date: 2007-01-09
    Description: Chironomidae in newly created nature reserves In a newly created nature reserve near Eindhoven many interesting species of Chironomidae were found. Several new species to the Dutch fauna were identified and one species (of the genus Neozavrelia) proved to be new to science. The fauna of these young habitats is poorly known, but proves to be very interesting.
    Keywords: Insecta ; Chironomidae ; Verspreiding ; Biotopen ; Nederland ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
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  • 65
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    Four new species of Pteromalus Swederus (Hymenoptera: Chalcidoidea: Pteromalidae) and redescriptions of three other species (1999)
    In:  Zoologische Mededelingen (00240672) vol.73, 1-11 (1999) p.165
    Details
    Publication Date: 2007-01-23
    Description: A key to the European species of the Pteromalus altus group is presented. The relationship between this group and species of the genus Euphorbia (Euphorbiaceae) is confirmed. One new species: P. villosae, associated with Euphorbia villosa Waldst. & Kit.is presented. Two new species of the albipennis group: Pteromalus almeriensis and P. costulata are presented. In addition one species of the P. vibulenus group: P. tethys is added. Information on P. sylveni Hedqvist, P. osmiae Hedqvist and P. discors Graham is given.
    Keywords: Chalcidoidea ; Pteromalidae ; Pteromalus ; new species ; redescriptions ; Spain ; Portugal ; France ; Greece ; Euphorbia ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
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  • 66
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    The Egyptian species of Encarsia (Hymenoptera: Aphelinidae): a preliminary review (1999)
    In:  Zoologische Mededelingen (00240672) vol.73, 1-10 (1999) p.131
    Details
    Publication Date: 2007-01-23
    Description: The species of Encarsia Foerster (Hymenoptera: Aphelinidae) known from Egypt are revised. A total of 14 species are treated, including one new species. E. indifferentis Mercet, 1929, is synonymised with E. inaron (Walker, 1839). All species are fully described or diagnosed, and illustrated. Host records, and species-distributions outside Egypt, are given.
    Keywords: Egypt ; Encarsia ; Aleyrodidae ; Aphelinidae ; Diaspididae ; parasitoids ; biological control ; natural enemies ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
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  • 67
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    Bijzondere kevervondsten in Nederland (Coleoptera: Staphylinidae, Nitidulidae, Dermestidae) (1999)
    In:  Nederlandse Faunistische Mededelingen (01692453) vol.9 (1999) p.133
    Details
    Publication Date: 2007-01-10
    Description: Interesting records of beetles in The Netherlands (Coleoptera: Staphylinidae, Nitidulidae, Dermestidae) Tachyporus quadriscopulatus Pandellé, 1869 has been recorded for the second time in the Netherlands at Arcen and Velden, province of Limburg. After 27 years, a third record of Carpophilus marginellus Motschulsky, 1858 can be reported from St. Geertruid, in the southern part of the province of Limburg. One specimen was found outdoors, in a wood. One specimen of Anthrenocerus australis Hope, 1843 was also found outdoors, in Oost- Maarland also in southern Limburg, sitting on a flower in a meadow.
    Keywords: Insecta ; Coleoptera ; Staphylinidae ; Nitidulidae ; Dermestidae ; Nederland ; Verspreiding ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
    Type: Article / Letter to the editor
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  • 68
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    Dagvlinders in 1998: nog steeds onder druk (Lepidoptera: Rhopalocera) (1999)
    In:  Nederlandse Faunistische Mededelingen (01692453) vol.9 (1999) p.127
    Details
    Publication Date: 2007-01-10
    Description: Butterflies in the Netherlands still under pressure (Lepidoptera: Rhopalocera) New information on the Dutch Rhopalocera fauna since the distribution atlas of Tax (1989) is presented. Coenonympha pamphilus was common in large parts of the Netherlands, but has declined dramatically. C. arcania is now formally extinct in our country. An extensive research showed that Maculinea alcon ericae has dissappeared from many sites. Furthermore the smallest of the two remaining populations of Heteropterus morpheus seems to have gone extinct. On the other hand, Callophrys rubi, has colonized new territory. Lampidus boeticus, was observed once as an adult and once a caterpillar was found between snow peas from Egypt. Colias croceus was very abundant in 1998. The reintroductions of Maculinea teleius and M. nausithous in 1990 appear to have been successful.
    Keywords: Insecta ; Lepidoptera ; Rhopalocera ; Verspreiding ; Bedreiging ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
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  • 69
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    De edelherthorzel Cephenemyia auribarbis gekweekt (Diptera: Oestridae) (1999)
    In:  Nederlandse Faunistische Mededelingen (01692453) vol.9 (1999) p.109
    Details
    Publication Date: 2007-01-10
    Description: The rearing of the botfly Cephenemyia auribarbis (Diptera: Oestridae) After several failures we finally succeeded in rearing botflies Cephenemyia from third-instar larvae. From a red deer shot at 13 March 1998 about one hundred larvae of Cephenemyia auribarbis (Meigen, 1824) were collected. Ten individuals reached the pupal stage. After 22 days, one fullgrown male died in the pupa, and two males emerged and lived for 17 and 18 days respectively. This is one of the few recorded succesful attempts to rear botflies.
    Keywords: Insecta ; Diptera ; Oestridae ; Cephenemyia auribarbis ; Nederland ; Verspreiding ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
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  • 70
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    Een nieuwe vondst van het locomotiefje Chorthippus apricarius in Nederland (Orthoptera) (1999)
    In:  Nederlandse Faunistische Mededelingen (01692453) vol.8 (1999) p.90
    Details
    Publication Date: 2007-01-09
    Description: A new record of Chorthippus apricarius in the Netherlands (Orthoptera) Chorthippus apricarius is a very rare grasshopper in The Netherlands. Only three, very widely separated sites are known. In 1998 a small new population has been found in a roadside verge, 2 km southwest of the southernmost site in the south of the province of Limburg.
    Keywords: Insecta ; Orthoptera ; Acrididae ; Chorthippus apricarius ; Locomotiefje ; Verspreiding ; Biotopen ; Nederland ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
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  • 71
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    Naamlijst van de glanskevers van Nederland en het omliggende gebied (Coleoptera: Nitidulidae & Brachypteridae) (1999)
    In:  Nederlandse Faunistische Mededelingen (01692453) vol.8 (1999) p.11
    Details
    Publication Date: 2007-01-09
    Description: Checklist of the Nitidulidae and Brachypteridae (Coleoptera) of the Netherlands and surrounding regions An annotated checklist of the Nitidulidae and Brachypteridae of the Netherlands and surrounding regions is presented, based mainly on literature research. Since the list of Brakman seven new species to the Netherlands have been published. One of these species, Pocadius adustus, is listed here for the first time. Major nomenclatorial changes, published elsewhere, have been implemented. The list contributes to the faunistic work of the European Invertebrate Survey - The Netherlands. A separate list of hostplants of the Nitidulidae and Brachypteridae is presented.
    Keywords: Insecta ; Coleoptera ; Nitidulidae ; Brachypteridae ; Glanskevers ; Verspreiding ; Waardplanten ; Biologie ; Naamlijst ; Nederland ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
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  • 72
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    Photochemistry of 9,10-Dicarbonyl-9,10-dihydroanthracene - A Source of 9,10-Dehydroanthracene? (1999)
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1999 (1999), S. 57-60 
    Details
    ISSN: 1434-193X
    Keywords: Benzyne ; Dehydroanthracene ; Matrix isolation ; Photochemistry ; Bergman reaction ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: -9,10-Didehydroanthracene (1) is an interesting derivative of p-benzyne that has been subject of several studies. In contrast to an earlier report, the photochemical decarbonylation of 9,10-dicarbonyl-9,10-dihydroanthracene (2) does not lead to 1 but rather to the ring-opened ene-diyne 4. The key intermediate for this reaction is keto carbene 7 which is formed by monodecarbonylation of 2. Carbene 7 is labile towards visible-light irradiation and easily looses the second CO molecule to give 4. Carbene 7 and diyne 4 are characterized by IR and UV/Vis spectra, the IR spectra are compared to calculations at the B3LYP/6-31G(d,p) level of theory.
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    Reversal Diastereofacial Selectivity in the n-Butyllithium Addition to O-Protected N-Trimethylsilylimines of (2S)-Lactal: Enthalpic versus Entropic Contributions (1999)
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1999 (1999), S. 61-65 
    Details
    ISSN: 1434-193X
    Keywords: Nucleophilic addition ; Solvent effect ; Reversal of diastereoselectivity ; Temperature effect ; Imines ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: -Commonly observed, but rarely explored, is the possibility of modifying the diastereomeric excess (de%) by means of temperature. A complete reversal in the diastereofacial selectivity could be obtained whenever the diastereoisomers concerned are differentially favored by enthalpy and entropy. The enthalpic or entropic dominance of a diastereoisomer depends greatly on the reaction solvent used.
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  • 74
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    Syntheses of Donor-Acceptor-Substituted 2,6-Stellanes (1999)
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1999 (1999), S. 73-81 
    Details
    ISSN: 1434-193X
    Keywords: Donor-acceptor systems ; Cage compounds ; Stelladione ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: -A number of condensations could be carried out using tricyclo[3.3.0.03,7]octane-2-one (stellanone, 4) and tricyclo[3.3.0.03,7]octane-2,6-dione (2,6-stelladione, 5) as starting materials. The components for condensations were 2-trimethylsilyl-1,3-dithiane (6), 1,1-bis(trimethylsilyl)-1H-cyclopropa[b]naphthalene (7), its 3,6-dimethoxy-substituted analogue 8, fluorene (12), xanthene (13), diethyl malonate (14), and malononitrile (15). The condensation reactions with 5 yielded mono- and disubstituted products, among them were the donor-acceptor-substituted 2,6-stellanes 33-35. The structures of 18 (prepared from stellanone and fluorene), 19, 24, 27, 31 and 32 (synthesized by condensation of 2,6-stelladione and 2-trimethylsilyl-1,3-dithiane and malononitrile, respectively) were determined by X-ray crystallography.
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  • 75
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    Synthesis of ω-Nitro Acids and ω-Amino Acids by Ring Cleavage of α-Nitrocycloalkanones (1999)
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1999 (1999), S. 87-90 
    Details
    ISSN: 1434-193X
    Keywords: Water ; α-Nitrocycloalkanones ; ω-Nitro acids ; Surfactant ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: -The reaction of various α-nitrocycloalkanones 1 with aqueous 0.05 M NaOH, at 80 °C, in the presence of cetyltrimethylammonium chloride (CTACl) as a cationic surfactant, produces ω-nitro acids 2 in good yields. Reduction of the latter with HCOONH4/Pd-C, in methanol, at 80 °C affords ω-amino acids 3. The synthesis of methyl 9-oxodecanoate (8) is also reported.
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  • 76
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    On the Selective O-Alkylation of Ambident Nucleophiles - The Synthesis of Thiohydroxamic Acid O-Esters by Phase-Transfer Reactions (1999)
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1999 (1999), S. 97-106 
    Details
    ISSN: 1434-193X
    Keywords: O-Alkylation ; Ambident nucleophile ; Thiazolethione ; Thiohydroxamic acid ; Phase-transfer reaction ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: -O-Alkylation of cyclic thiohydroxamic acids 1 and 3-5 has been studied with a view to developing an efficient method for the synthesis of N-(alkoxy)pyridine-2(1H)-thiones and N-(alkoxy)thiazole-2(3H)-thiones. Four issues have been addressed and the following conclusions can be drawn: (i) Thiones 1 and 5 exist as O-H acids in the solid state. (ii) According to NMR investigations (1H, 13C), the thione structures should be largely retained in CDCl3, [D6]DMSO, and CD3OD solutions of acids 1, 3-5, as is also the case for pyridinethione salts 2a-h. (iii) O-Alkylation of pyridinethione salts occurs in competition with S-alkylation. Selective O-alkylation is however possible, if thiohydroxamate salts with large countercations, such as M = NBu4, are treated with hard alkylating reagents in polar aprotic media. (iv) As tetrabutylammonium thiohydroxamates, such as 2f, are highly useful in the synthesis of cyclic thiohydroxamic acid O-esters, we have developed an efficient protocol for the preparation of N-(alkoxy)pyridine-2(1H)-thiones directly from acid 1 using phase-transfer conditions (alkyl halide or sulfonic acid ester, CH3CN, K2CO3, Bu4NHSO4). This method has proved particularly successful for the synthesis of N-(alkoxy)thiazole-2(3H)-thiones 11, 20-28, which were obtained in yields of up to 87%.
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  • 77
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    Palladium(0)-Catalyzed Asymmetric Synthesis of 1,2,3,4-Tetrahydro-2-vinylquinoxalines (1999)
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1999 (1999), S. 129-134 
    Details
    ISSN: 1434-193X
    Keywords: Tetrahydro-2-vinylquinoxaline ; Cyclization ; Palladium ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: -Reaction of (Z)-1,2-bis(methoxycarbonyloxy)but-2-ene (2) with various N,N-bis(arylsulfonyl)-o-phenylenediamines 1 was catalyzed by a palladium complex associated with chiral ligands to give optically active 1,4-bis(arylsulfonyl)-1,2,3,4-tetrahydro-2-vinylquinoxalines 3 with up to 62% ee. The use of (S)-MeOBIPHEP as the chiral ligand and N,N-bis(p-tolylsulfonyl)-o-phenylenediamine (1i) as the nucleophile led to the highest ee at 25 °C, regardless of the solvent used. The enantioselectivity of the cyclization is strongly affected by the nature of the substituents at the nitrogen atom.
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  • 78
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    Stereoselective Synthesis of Enantiomerically Pure β-Fluoroalkyl γ-Butyrolactones by Sulfoxide-Directed Lactonization (1999)
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1999 (1999), S. 111-115 
    Details
    ISSN: 1434-193X
    Keywords: Fluorine ; Lactones ; Annulation ; Ketene ; Sulfoxides ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: -Enantiomerically pure α,α-dichloro β-fluoroalkyl γ-p-tolylthio γ-butyrolactones trans-6a-c have been obtained with excellent stereocontrol (〉 98:2) and enantiomeric purity (〉 98:2) by sulfoxide-directed lactonization (Marino's annu-lation reaction) of β-fluoroalkyl vinyl sulfoxides (R)-(E)-5a-c with dichloroketene. Highly chemoselective dechlorination and desulfurization reactions performed on trans-6c efficiently provided the β-chlorodifluoromethyl γ-butyrolactone (S)-8c, the absolute stereochemistry of which was determined by X-ray diffraction analysis of its γ-p-tolylthio precursor (2R,3S)-7c.
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    Reaction of Nitrosobenzene with 4-Methoxy-N-methyleneaniline (1999)
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1999 (1999), S. 141-143 
    Details
    ISSN: 1434-193X
    Keywords: Nitrosobenzene ; 4-Methoxy-N-methyleneaniline ; 1,3,5-Tris(4-methoxyphenyl)-1,3,5-triazinane ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: -A 1:1 adduct produced in the reaction of nitrosobenzene (2) with 1,3,5-tris(4-methoxyphenyl)-1,3,5-triazinane (3) has been shown by X-ray diffraction structure analysis to be the N′-(4-methoxyphenyl)-N-phenyl-N-oxyformamidinium species 5.
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  • 80
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    A New Diastereoselective Synthesis of anti-α-Alkyl α-Hydroxy β-Amino Acids (1999)
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1999 (1999), S. 155-161 
    Details
    ISSN: 1434-193X
    Keywords: Alkylation ; Oxazolines ; anti-α-Alkyl α-hydroxy β-amino acids ; Lithium dianion ; Penicillin G acylase ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: -As part of an ongoing project concerning the synthesis of enantiomerically pure α-hydroxy β-amino acids, we have now developed a general strategy allowing the synthesis of anti-α-alkyl α-hydroxy β-amino acids. Our procedure involves the intermediate formation of trans-oxazolines, which are alkylated at C-5 with good to high diastereoselectivity and then hydrolysed under mildly acidic conditions, affording in quantitative yield the corresponding hydroxy amides. The starting (R)-3-amino-3-phenylpropanoic acid and (S)-3-aminobutanoic acid were obtained in enantiomerically pure form by selective enzymatic hydrolysis of the corresponding phenylacetylamides with penicillin G acylase.
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  • 81
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    Palladium(0)-Catalyzed Reaction of Acidic Anilines with (Z)-2-Butene-1,4-diyl Dicarbonate - Preparation of N-Aryl-4-vinyloxazolidin-2-ones (1999)
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1999 (1999), S. 181-186 
    Details
    ISSN: 1434-193X
    Keywords: Palladium catalysis ; Homogeneous catalysis ; Anilines ; Alkylation ; Oxazolidinones ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: -Palladium-catalyzed reaction of acidic anilines with (Z)-2-butene-1,4-diyl dicarbonate affords N-aryl-4-vinyloxazolidin-2-ones. The success of the reaction depends on the acidity of the aniline and requires in situ conversion of the dicarbonate into carbamate carbonate by nucleophilic attack of the aniline conjugate base followed by palladium-catalyzed intramolecular cyclization.
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  • 82
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    Substituent Effects on the Vinylcyclopropane-Cyclopentene Rearrangement - A Theoretical Study by Restricted and Unrestricted Density Functional Theory (1999)
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1999 (1999), S. 215-220 
    Details
    ISSN: 1434-193X
    Keywords: Density functional calculations ; Vinylcyclopropane-cyclopentene rearrangement ; [1,3]-Sigmatropic shift ; Biradical-like transition structure ; Substituent effects ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: -The effect of donor substitution by the hydroxy group and of acceptor substitution by the cyano group on the activation energies of the vinylcyclopropane-cyclopentene rearrangement was calculated by the spin-restricted RB3LYP/6-31G* method for reactant structures and by the spin-unrestricted UB3LYP/6-31G* method for transition structures. The activation energies of the rearrangement of hydroxy- and cyano-substituted vinylcyclopropanes are very similar for substitution in the same position. In agreement with earlier findings the substituent effects on the activation energies are closely connected with the radical stabilizing properties of the substituents. As indicated by singlet/triplet splitting energies, the transition structures are essentially biradicaloid. In spite of spin pairing in the transition structure the substituent effects on bond lengths and on stabilization energies are very similar to those of the free radicals corresponding to the two radical substructures. Thus, the transition structures may be considered, in good approximation, as structures consisting of two weakly interacting radicals.Supporting information for this article is available on the WWW under -http://www.wileY-Vch.de/contents/jc_2046/1999/98349_s.pdf or from the author.
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    Syntheses and Reactions of 1-Amino-2,2-dialkylcyclopropane-1-carbonitriles and -carboxamides - Potential Precursors of ACC Derivatives (1999)
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1999 (1999), S. 239-250 
    Details
    ISSN: 1434-193X
    Keywords: Cyclopropanes ; Rearrangements ; Cyanohydrins ; Schiff bases ; Small ring systems ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: -The direct cyclization of 2-amino-4-chloro-3,3-dimethylbutanenitrile with potassium tert-butoxide in THF afforded 1-amino-2,2-dimethylcyclopropane-1-carbonitrile and a dimerization product. Various new cis- and trans-1-(tert-butylamino)-2-benzyl-2-methylcyclopropane-carbonitriles and© the corresponding cyclopropanecarboxamides have been synthesized, with focus on the isolation of the pure stereoisomeric cyclopropanecarboxamides. The relative configuration of the stereoisomers was established by X-ray crystallographic analysis of one of the model compounds. A new route to the latter functionalized cyclopropanes was developed by reaction of 1-methoxycyclopropylamines with potassium cyanide. Some remarkable rearrangements of 1-aminocyclopropane-1-carbonitriles into azetidine and oxazine derivatives via Favorskii-derived intermediates are reported. Various aspects of the chemistry of geminally functionalized cyclopropanes are discussed.
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    Regio- and Stereoselective Synthesis of Vinylallenes by 1,5-(SN′′)-Substitution of Enyne Acetates and Oxiranes with Organocuprates (1999)
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1999 (1999), S. 267-275 
    Details
    ISSN: 1434-193X
    Keywords: Vinylallenes ; Organocuprates ; Substitution ; Stereoselective synthesis ; Copper catalysis ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: -Enyne acetates 2, 4, 6, and 8, as well as enyne oxiranes 10, with different substitution patterns react with organocuprates regioselectively under 1,5-(SN2′′)-substitution to provide vinylallenes 11 and 12. With lithium dimethylcuprate, reduced vinylallenes originating from a (formal) transfer of a hydride ion to the substrate are formed in some cases. The products are usually obtained as mixtures of (E/Z)isomers; however, pure (E)-vinylallenes are formed occasionally. The 1,5-substitutions can also be carried out with catalytic amounts of copper reagents. The reaction of chiral enyne acetate (S)-2a with tBu2CuLi · LiCN proceeds enantioselectively, so that this transformation constitutes a new case of remote stereocontrol.
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    Reactions of the Hydrofluoroborate Salts of Open-Chain Analogues of Reissert Compounds with Some α,β-Ethylenic Esters (1999)
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1999 (1999), S. 297-303 
    Details
    ISSN: 1434-193X
    Keywords: Nitrogen heterocycles ; Open-chain analogue of Reissert compound ; Hydrofluoroborate salts ; α,β-Ethylenic esters ; 1,3-Dipolar cycloaddition ; Azomethine ylide ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: -The reaction of the hydrofluoroborate salt of an open-chain analogue of a Reissert compound with some α,β-ethylenic esters does not give a [4 + 2] cycloadduct, as previously described in the case of ethyl acrylate. The reaction starts with a 1,3-dipolar cycloaddition of a münchnone imine 5c, d. The [3 + 2] cycloadducts 13 evolve via a rearrangement-condensation sequence to give a substituted 2-pyridone derivative 18 or 19. The proposed mechanism has been verified by the isolation and structural X-ray analysis of some compounds of the reaction sequence.
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    EPC-Synthesis of β-Amino Acid Derivatives through Lithiated Hydropyrimidines (1999)
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1999 (1999), S. 335-360 
    Details
    ISSN: 1434-193X
    Keywords: 2-tert-Butylhydropyrimidinones ; 3-Aminocarboxylic acid derivatives ; Cyclic imino esters ; Lithium enaminates ; Alkylations ; β-Amino acids ; Asymmetric synthesis ; Kinetic resolution ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: -Racemic and enantiopure 2-tert-butyltetrahydropyrimidinones (from pivalaldehyde and 3-aminocarboxylic acids) are converted to Alloc-, Boc-, and Z-protected cyclic imino esters (7-10, Schemes 2-4). These are deprotonated to Li enaminates (K, L). Reactions with electrophiles (prim., sec. alkyl, allyl, benzyl, propargyl halides, aldehydes, imines, enoates) give good yields and are highly diastereoselective (products 11-42, Schemes 5-10). A two-step cleavage (removal of protecting group and hydrolysis) under very mild conditions converts the heterocyclic products to α-branched β-amino acid methyl esters (43-61, Schemes 11-13). The structure of the products is determined by NMR spectroscopy (Figure 1), by chemical correlation (Scheme 14), and by X-ray analysis (Figure 2, 3, 7, Table 1). A structure of the Li enaminates is proposed (Figure 4). Mechanistic models are derived for the reactions occurring with formation of two stereogenic centers with relative topicity like (Figures 5, 6).
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    A Unified Synthetic Strategy for the Indolopyridine Alkaloid Group (1999)
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1999 (1999), S. 373-378 
    Details
    ISSN: 1434-193X
    Keywords: Alkaloids ; Cross-coupling ; N-Heterocycles ; Palladium ; Synthesis design ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: -Thermal or acetyl chloride induced cyclization of bromoenamide 10 affords the pentacyclic derivative 12 with high yield and regioselectivity. From this common synthetic intermediate, palladium-catalyzed reactions allow the total synthesis of indolopyridine alkaloids 1-6.Supporting information for this article is available on the WWW under -http://www.wileY-Vch.de/contents/jc_2046/1999/98332_s.pdf or from the author.
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    Conformational Preferences of Peptides Containing Reverse-Turn Mimetic Bicyclic Lactams: Inverse γ-Turns versus Type-II′ β-Turns - Insights into β-Hairpin Stability (1999)
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1999 (1999), S. 389-400 
    Details
    ISSN: 1434-193X
    Keywords: Reverse-turn mimics ; γ-Turns ; β-Turns ; β-Hairpins ; NMR spectroscopy ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: -The solid-phase synthesis and characterization of a series of peptides (3-9), containing reverse-turn mimetic bicyclic lactams (1a, 1b), was reported in the preceding paper. The bicyclic lactams (1a, 1b) possess high structural similarity to the two central residues of a β-turn. The conformational preferences of the constrained peptides have been investigated by NMR spectroscopy and IR spectroscopy. Our experimental results have been complemented by computer modelling studies and show that the constrained peptides (3-9) form an inverse γ-turn or a type-II′ β-turn through intramolecular hydrogen bonding, depending on the nature of the reverse-turn mimic. In N-acetylated tetrapeptide mimics incorporating the two different bicyclic lactams (a series and b series), H5 is available for either a γ-turn (7-membered ring with the carbonyl group of the bicyclic lactam) or a β-turn (10-membered ring with the carbonyl group of residue 2), as shown in Figures 7 and 9. The a series incorporating the (5,7)-bicyclic lactam predominantly induces the γ-turn conformation, while the b series incorporating the (5,6)-bicyclic lactam can promote either a γ-turn or a β-turn conformation, with the β-turn usually being preferred and with varying degrees of β-hairpin formation.
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  • 89
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    Deprotonation of Oxazolinyloxiranes: Formation of Substituted Acyloxiranes (1999)
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1999 (1999), S. 409-417 
    Details
    ISSN: 1434-193X
    Keywords: Deprotonation ; Oxiranyloxazolines ; Oxazolinyloxiranyllithium compounds ; Oxazolidines ; Acyloxiranes ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: -Deprotonation of oxazolinyloxiranes 1a, 1h, and 1k with sBuLi/TMEDA at -100 °C in Et2O furnishes oxazolinyloxiranyllithium compounds[1]1b, 1i, and 1l which are stable at low temperature and can be trapped with electrophiles to give substituted oxiranes 1c-1g and 1j. The reaction of 1b with aldehydes produced diastereomers syn (2a-d) and anti (3a-d). Oxiranyllithium 1i from trans-1-(4,4-dimethyl-2-oxazolinyl)-2-p-tolylepoxyethane (1h) was found to be configurationally stable while oxiranyllithium 1l, generated from the cis isomer 1k, was not. Oxazolinylepoxides 1d, 1j, and 1m could be deblocked to acyloxiranes 5a-e through oxazolidines 4a-e.
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  • 90
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    N-Substituted 1-Aminoindoles from Electrogenerated N-Substituted 2-(ortho-Nitrosophenyl)ethylamines (1999)
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1999 (1999), S. 419-430 
    Details
    ISSN: 1434-193X
    Keywords: Electrochemistry ; Electrosynthesis ; Nitrosobenzenes ; Nitrogen heterocycles ; 1-Aminoindoles ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: -An electrochemical methodology offering efficient access to N-alkyl- and N-aryl-substituted 1-aminoindoles has been developed. N-Substituted 2-(ortho-nitrosophenyl)ethylamines, electrogenerated in a “redox” flow cell, undergo intramolecular cyclization to hydrocinnoline-type intermediates. Under slightly basic conditions, these undergo spontaneous ring-contraction to produce the N-substituted heterocycles in good yields. The reactions have been studied in slightly acidic and slightly basic aqueous alcoholic media.
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  • 91
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    Synthesis of Enantiopure β- and γ-Amino Alcohols from Homochiral α- and β-Aminoacylsilanes as Stable Synthetic Equivalents of α- and β-Amino Aldehydes (1999)
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1999 (1999), S. 437-445 
    Details
    ISSN: 1434-193X
    Keywords: Aminoacylsilanes ; Amino aldehydes ; Amino alcohols ; Allylation ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: -A practical route is described for the synthesis of enantiopure β- and γ-amino alcohols with two stereocenters, starting from homochiral α- (1 and 5) and β- (13 and 16) -aminoacylsilanes, and involving stereoselective addition of allylmetal compounds and subsequent stereospecific protiodesilylation of the adducts. The degree of diastereoselectivity achieved in the nucleophilic addition step depends on both the nitrogen-protecting group and the reagents used. Diastereomeric excess (de) values equal to or higher than 98% were obtained in the TiCl4-promoted allylation of the N-Pht-aminoacylsilanes 1 and 13 and of the N-Ts-aminoacylsilane 5 with allyltrimethylsilane. Lower de values were obtained in the Sc(OTf)3-catalyzed allylation of 5 with tetraallyltin and in the additions of both allyltrimethylsilane and tetraallyltin to the N-Ts-β-aminoacylsilane 16. Protiodesilylation of the adducts, leading to the β- and γ-amino alcohols, was accomplished with TBAF, except in the case of the adducts obtained from 5. For these, a preliminary removal of the tosyl group was necessary, which was accomplished with simultaneous desilylation by treatment with Na in liquid ammonia.Supporting information for this article is available on the WWW under -http://www.wileY-Vch.de/contents/jc_2046/1999/98342_s.pdf or from the author.
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  • 92
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    Diastereoselective Intramolecular meta Photocycloaddition of Side-Chain-Substituted 5-(2-Methoxyphenyl)pent-1-enes (1999)
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1999 (1999), S. 463-470 
    Details
    ISSN: 1434-193X
    Keywords: meta Photocycloaddition ; Photochemistry ; Steric hindrance ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: -Irradiation of a series of 5-(2-methoxyphenyl)pent-1-enes substituted with a hydroxy or trimethylsilyloxy group at the α-, β-, or γ-position of the side-chain yields in all cases meta photocycloadducts, in which the configuration at the substituted carbon atom is mainly endo. This indicates that the diastereoselectivity originates from minimization of steric interactions between the side-chain substituent and the ortho-methoxy group at the arene unit. Hydrogen bonding does not seem to be involved. The introduction of the side-chain substituents also influences the regioselectivity of the addition: The linear to angular adduct ratios are significantly increased compared to the case of the parent compound.
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  • 93
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    5-Aza-7-deaza-2′-deoxyguanosine: Oligonucleotide Duplexes with Novel Base Pairs, Parallel Chain Orientation and Protonation Sites in the Core of a Double Helix (1999)
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1999 (1999), S. 485-496 
    Details
    ISSN: 1434-193X
    Keywords: 5-Aza-7-deaza-2′-deoxyguanosine ; Oligonucleotides ; Parallel DNA ; Protonated base pairs ; Tm values ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: -Oligonucleotides containing 5-aza-7-deaza-2′-deoxyguanosine (1) were synthesized. Solid-phase synthesis was performed with the phosphonate 15 or the phosphoramidite 5. The amino-unprotected phosphonate 4 was also employed. Hybridization studies of oligonucleotides containing 1 resulted in new base pairs leading to duplexes with parallel (ps) or antiparallel (aps) chain orientation. Among those with parallel chains a stable “purine-purine” base pair was observed between 5-aza-7-deazaguanine and guanine or 7-deazaguanine. Antiparallel stranded duplexes are formed when 5-aza-7-deazaguanine pairs with cytosine. This base pair has only two hydrogen bonds under neutral conditions but is stabilized by a third one in acidic medium. A new base pair is also detected between the base of 1 and isoguanine (neutral medium).
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  • 94
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    Polar and Steric Substituent Effects in 5-exo-trig Cyclizations of 1-Aryl-4-penten-1-oxyl Radicals (1999)
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1999 (1999), S. 523-523 
    Details
    ISSN: 1434-193X
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: -By mistake wrong concentrations were given in the footnote of Table 1 and in the Discussion. Instead of c0 = 1.2 M read c0 = 0.12 M if 2-naphthalenethiol was used as hydrogen donor and instead of c0 = 1.8 M read c0 = 0.18 M if Bu3SnH was used to trap photoproducts. In Table 2 relative rate constants of radical 2d refer to radical 2e and vice versa as correctly stated in the Discussion. In the Experimental Section (Iodocyclization) read 2.25 g (8.86 mmol) of iodine instead of 2.25 g (1.10 mmol) of iodine.
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  • 95
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    Arylboron Compounds as Acid Catalysts in Organic Synthetic Transformations (1999)
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1999 (1999), S. 527-538 
    Details
    ISSN: 1434-193X
    Keywords: Tris(pentafluorophenyl)borane ; Diarylborinic acid ; Arylboronic acid ; Chiral arylboron catalyst ; Lewis acid ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: -Arylboron compounds, ArnB(OH)3-n (n = 1-3), bearing electron-withdrawing aromatic groups such as triarylboranes, diarylborinic acids, and arylboronic acids represent a new class of air-stable and water-tolerant Lewis acid or Brønsted acid catalysts in organic synthesis. In particular, while tris(pentafluorophenyl)borane has primarily been used as a co-catalyst in metallocene-mediated olefin polymerization, its potential as a Lewis acid catalyst for organic transformation is now much more extensive. Diarylborinic acids and arylboronic acids have shown themselves to be powerful tools in the design of chiral boron catalysts. This article provides a comprehensive summary of the organic transformations catalyzed by arylboron compounds as acids.
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    2D-NMR-Guided Constitutional Analysis of Organic Compounds Employing the Computer Program COCON[#] (1999)
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1999 (1999), S. 573-577 
    Details
    ISSN: 1434-193X
    Keywords: Structure elucidation ; Constitutional analysis ; Natural products ; HMBC ; Computational chemistry ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: -The computer program COCON is introduced as a tool for the comprehensive structure elucidation of unknown organic compounds. In particular, structural proposals made on the basis of the molecular formula and of 2D-NMR experiments can be analyzed for the existence of alternative constitutions being in agreement with the same data set. The computational speed grounds on the evaluation of ambiguous long-range connectivity information during the process of structure generation. The data set experimentally obtained for the marine natural product oroidin (1) was selected, because proton-poor compounds usually cause uncertainties in NMR-based structure determinations. The calculation results encourage to move from the experience-based analysis of NMR chemical shifts or of MS fragmentations to the automated evaluation of routinely available connectivity information.Supporting information for this article is available on the WWW under -http://www.wileY-Vch.de/contents/jc_2046/1999/98241_s.pdf or from the author.
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  • 97
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    3,5-Dimesityl-1,2,4-oxadiphosphole - Synthesis and Reactivity of a Novel Heterocycle (1999)
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1999 (1999), S. 587-595 
    Details
    ISSN: 1434-193X
    Keywords: Phosphaalkenes ; Heterodiphospholes ; Cycloadditions ; Phosphaalkyne cyclooligomers ; Phosphorus-carbon cage compounds ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: -The first synthesis of a 1,2,4-oxadiphosphole 6 has been achieved by vacuum thermolysis of mesitylphosphaalkene 5. The novel heterocycle 6 exhibits an enormous potential for cycloaddition reactions, which predominantly proceed selectively at low temperatures. Compound 6 undergoes addition with two equivalents of phosphaalkynes 10 by a [4+2] cycloaddition/homo Diels-Alder reaction sequence to form novel oxatetraphosphadeltacyclenes 12 and 13. Tetrachloro-o-benzoquinone (14) undergoes a selective [4+1] cycloaddition with 12 and 13 leading to the spirocyclic products 15 and 16 containing λ5-phosphorus atoms. Treatment of the oxadiphosphole 6 with dimethyl acetylenedicarboxylate (17) provides the first access to a 1,2-oxaphosphole 18, which is formed after an initial [4+2] cycloaddition followed by a retro Diels-Alder reaction. An unexpected reaction of 6 is observed with tri-tert-butylazete (20) furnishing a new polycyclic system (→ 21).
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    Synthesis of 1β-Methylcarbapenem Antibiotic Precursors by Cyclization Using π-Allylpalladium Complexes (1999)
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1999 (1999), S. 621-626 
    Details
    ISSN: 1434-193X
    Keywords: 1β-Methylcarbapenems ; Palladium ; Ruthenium ; Catalysis ; Cyclizations ; Stereoselective hydrogenation ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: -An efficient diastereoselective multi-step synthesis of bicyclic 1β-methylcarbapenem antibiotic precursors has been developed, starting from the commercially available 4-acetoxyazetidin-2-one 4. Chiral ruthenium catalysts are used in the hydrogenation step to control the β-stereochemistry at the 1-position, and a π-allylpalladium ring-closure strategy is used to form the functionalized carbapenem skeleton.
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  • 99
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    Oligo-2,6-naphthylenevinylenes - New Building Blocks for the Preparation of Photoluminescent Polymeric Materials (1999)
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1999 (1999), S. 643-651 
    Details
    ISSN: 1434-193X
    Keywords: Oligomers ; Synthesis design ; Substituent effects ; Luminescence ; Cyclic voltammetry ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: -Synthetic strategies towards appropriate symmetric and unsymmetric functionalization of the naphthalene ring are presented. By means of Knoevenagel and Wittig condensation reactions new fluorescent, differently functionalized oligo(2,6-naphthylenevinylene)s have been synthesized, the presence of terminal aldehyde or bromine substitution opening the way to the incorporation of the fluorescent trimers in a variety of polymeric materials. The effect of substituting the phenylene ring by the more bulky dialkoxynaphthalene system in arylenevinylene-type materials is studied from the structural point of view and the possibility to tune the emission color and the electron affinity through the introduction of naphthylenevinylene and cyano-substituted naphthylenevinylene units is also investigated.
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  • 100
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    New Type of Skipped Oligoaziridines: Synthesis of New Fatty AcidDerivatives Containing Aziridine Functions (1999)
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1999 (1999), S. 661-664 
    Details
    ISSN: 1434-193X
    Keywords: Aziridines ; N-Heterocycles ; Fatty acids ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: -The first successful preparation of the aziridines methyl cis-9,10;cis-12,13-diepiminooctadecanoate (3) derived from linoleic acid, and methyl cis-9,10;cis-12,13;cis-15,16-triepiminooctadecanoate (6) derived from linolenic acid, is reported. Remarkably, the bis- and trisaziridine were obtained in a reaction sequence that consists of only two steps, using technically pure methyl esters of epoxidized sunflower and linseed oil. The conversion of methyl 9,10;12,13-diepoxyoctadecanoate (1), with sodium azide and ammonium chloride in ethanol in the presence of water, yielded the new diazidodihydroxy compound methyl 9(10),12(13)-diazido-10(9),13(12)-dihydroxyoctadecanoate (2) in the first step. 2 was obtained as a regioisomeric mixture. The reaction of 2 with triphenylphosphane led to the bisaziridine 3. The analogous conversion of methyl 9,10;12,13;15,16-triepoxyoctadecanoate (4), via the new triazidotrihydroxy compound methyl 9(10),12(13),15(16)-triazido-10(9),13(12),16(15)-trihydroxyoctadecanoate (5), afforded trisaziridine 6.
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