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  • 1
    Publication Date: 2020-02-12
    Type: info:eu-repo/semantics/book
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  • 2
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Physics Letters B 294 (1992), S. 466-478 
    ISSN: 0370-2693
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Physics
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Physics Letters B 317 (1993), S. 474-484 
    ISSN: 0370-2693
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Physics
    Type of Medium: Electronic Resource
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  • 4
    Publication Date: 2021-02-26
    Description: In this study we combine seismological and GOCE satellite gravity information by using a Bayesian-like technique, with the aim of inferring the density structure of the Pacific (90°N 90°S) (121°E 60°W) lithosphere and upper mantle. We recover a 1° × 1° 3-D density model, down to 300 km depth, which explains gravity observations with a variance reduction of 67.41%. The model, with an associated a posteriori standard deviation, provides a significant contribution to understanding the evolution of the Pacific lithosphere and answers to some debated geodynamic questions. Our methodology enables us to combine the recovery of density parameters with the optimum density-vSV scalings. The latter account for both seismological and gravity observations in order to identify the regions characterized by chemically-induced density heterogeneities which add to the thermally-induced anoma- lies. Chemically-modified structures are found west of the East Pacific Rise (EPR) and are of relevant amplitude both below the north-western side of the Pacific Plate, at the base of the lithosphere, and up to 100 km depth beneath the Hawaiian and Super Swell regions, thus explaining the anomalous shallow regions without invoking the thermal buoyancy as the sole justification. Coherently with the chemically modified structures, our results a) support a lighter and more buoyant lithosphere than that predicted by the cooling models and b) are in favor of the hypothesized crustal underplating beneath the Hawaiian chain and be- neath the volcanic units in the southern branch of the Super Swell region. The comparison between calculated mantle gravity residuals and residual topography a) suggests a lateral viscosity growth associated with the increasing thickness and density of the Plate and b) correlates well with sub-lithospheric mantle flow from the EPR towards west, up to the Kermadec and Tonga Trench in the south and the Kuril-Kamchatka Trench in the north.
    Description: Published
    Description: 101-115
    Description: 7T. Struttura della Terra e geodinamica
    Description: JCR Journal
    Keywords: Pacific lithosphere ; GOCE ; Satellite gravity ; Seismological observations ; Residual Topography ; 04.07. Tectonophysics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 5
    Publication Date: 2021-02-10
    Description: San Cristóbal volcano in northwest Nicaragua is one of the most active basaltic–andesitic stratovolcanoes of the Central American Volcanic Arc (CAVA). Here we provide novel constraints on the volcano's magmatic plumbing system, by presenting the first direct measurements of major volatile contents in mafic-to-intermediate glass inclusions from Holocene and historic-present volcanic activity. Olivine-hosted (forsterite [Fo] b80; Fob80) glass inclusions from Holocene tephra layers contain moderate amounts of H2O (0.1–3.3 wt%) and S and Cl up to 2500 μg/g, and define the mafic (basaltic) endmember component. Historic-present scoriae and tephra layers exhibit more-evolved olivines (Fo69–72) that contain distinctly lower volatile contents (0.1–2.2 wt% H2O, 760–1675 μg/g S, and 1021–1970 μg/g Cl), and represent a more-evolved basaltic–andesitic magma. All glass inclusions are relatively poor in CO2, with contents reaching 527 μg/g (as measured by nanoscale secondary ion mass spectrometry), suggesting pre- to postentrapment CO2 loss to a magmatic vapor. We use results of Raman spectroscopy obtained in a population of small (b50 μm) inclusions with CO2-bearing shrinkage bubbles (3–12 μm) to correct for postentrapment CO2 loss to bubbles, and to estimate the original minimumCO2 content in San Cristóbal parental melts at ~1889 μg/g, which is consistent with the less-CO2-degassed melt inclusions (MI) (N1500 μg/g) found in Nicaragua at Cerro Negro, Nejapa, and Granada. Models of H2O and CO2 solubilities constrain the degassing pathway of magmas up to 425 MPa (~16 km depth), which includes a deep CO2 degassing step (only partially preserved in the MI record), followed by coupled degassing of H2O and S plus crystal fractionation at magma volatile saturation pressures from ∼195 to b10 MPa. The variation in volatile contents from San Cristóbal MI is interpreted to reflect (1) Holocene eruptive cycles characterized by the rapid emplacement of basaltic magma batches, saturated in volatiles, at depths of 3.8–7.4 km, and (2) the ascent of more-differentiated and cogenetic volatile-poor basaltic andesites during historic-present eruptions, having longer residence times in the shallowest (b3.4 km) and hence coolest regions of the magmatic plumbing system. We also report the first measurements of the compositions of noble-gas isotopes (He, Ne, and Ar) in fluid inclusions in olivine and pyroxene crystals. While the measured 40Ar/36Ar ratios (300–304) and 4He/20Ne ratios (9–373) indicate some degree of air contamination, the 3He/4He ratios (7.01–7.20 Ra) support a common mantle source for Holocene basalts and historic-present basaltic andesites. The magmatic source is interpreted as generated by a primitive MORB-like mantle, that is influenced to variable extents by distinct slab fluid components for basalts (Ba/La ~ 76 and U/Th ~ 0.8) and basaltic andesites (Ba/La ~ 86 and U/Th ~ 1.0) in addition to effects of magma differentiation. These values for the geochemical markers are particularly high, and their correlation with strong plume CO2/S ratios from San Cristóbal is highly consistent with volatile recycling at the CAVA subduction zone, where sediment involvement in mantle fluids influences the typical relatively C-rich signature of volcanic gases in Nicaragua.
    Description: Published
    Description: 131-148
    Description: 1V. Storia eruttiva
    Description: JCR Journal
    Keywords: San Cristóbal, Volatiles, Melt inclusions, NanoSIMS, Multi-GAS, Noble gases ; Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 6
    Publication Date: 2021-05-12
    Description: Today, satellite remote sensing has reached a key role in Earth Sciences. In particular, Synthetic ApertureRadar (SAR) sensors and SAR Interferometry (InSAR) techniques are widely used for the study of dynamicprocesses occurring inside our living planet. Over the past 3 decades, InSAR has been applied for mappingtopography and deformation at the Earth’s surface. These maps are widely used in tectonics, seismology,geomorphology, and volcanology, in order to investigate the kinematics and dynamics of crustal faulting,the causes of postseismic and interseismic displacements, the dynamics of gravity driven slope failures,and the deformation associated with subsurface movement of water, hydrocarbons or magmatic fluids.
    Description: Published
    Description: 58-82
    Description: 1T. Geodinamica e interno della Terra
    Description: 4T. Fisica dei terremoti e scenari cosismici
    Description: 3V. Dinamiche e scenari eruttivi
    Description: JCR Journal
    Description: reserved
    Keywords: SAR ; InSAR ; Earth observation ; Surface displacements ; Satellite missions ; Advanced InSAR ; Earthquake studies ; Volcanic studies ; Tectonic process ; Coseismic studies ; Soil liquefaction ; Post-seismic studies ; Interseismic studies ; Volcanic unrest ; Pre-eruptive phase ; Eruptive phase ; 04. Solid Earth::04.03. Geodesy::04.03.01. Crustal deformations ; 04. Solid Earth::04.03. Geodesy::04.03.06. Measurements and monitoring ; 04. Solid Earth::04.03. Geodesy::04.03.07. Satellite geodesy ; 04. Solid Earth::04.03. Geodesy::04.03.09. Instruments and techniques ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics ; 04. Solid Earth::04.06. Seismology::04.06.11. Seismic risk ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 7
    Publication Date: 2021-07-14
    Description: We report the preliminary results from a project (GAPSS-Geothermal Area Passive Seismic Sources), aimed at testing the resolving capabilities of passive exploration methods on a well-known geothermal area, namely the Larderello-Travale Geothermal Field (LTGF). Located in the western part of Tuscany (Italy), LTGF is the most ancient geothermal power field of the world. GAPSS consisted of up to 20 seismic stations deployed over an area of about 50 x 50 Km. During the first 12 months of measurements, we located more than 2000 earthquakes, with a peak rate of up to 40 shocks/day. Preliminary results from analysis of these signals include: (i) analysis of Shear-Wave-Splitting from local earthquake data, from which we determined the areal distribution of the most anisotropic regions; (ii) local-earthquake travel-time tomography for both P- and S-wave velocities; (iii) telesismic receiver function aimed at determining the high-resolution (〈0.5km) S-velocity structure over the 0-20km depth range, and seismic anisotropy using the decomposition of the angular harmonics of the RF data-set; (iv) S-wave velocity profiling through inversion of the dispersive characteristics of Rayleigh waves from earthquakes recorded at regional distances. After presenting results from these different analyses, we eventually discuss their potential application to the characterisation and exploration of the investigated area.
    Description: Published
    Description: 227-234
    Description: 6T. Sismicità indotta e caratterizzazione sismica dei sistemi naturali
    Description: N/A or not JCR
    Description: restricted
    Keywords: Geothermal field; Local Earthquake Tomography; Shear Wave Splitting; Surface Wave Dispersion; Receiver Functions; Larderello- Travale geothermal field (Italy) ; 04. Solid Earth::04.06. Seismology::04.06.07. Tomography and anisotropy
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 8
    Publication Date: 2021-01-14
    Description: The Marsili Seamount (MS) is an about 3200 m high volcanic complex measuring 70 × 30 km with the top at ~500 m b.s.l. MS is interpreted as the ridge of the 2 Ma old Marsili back-arc basin belonging to the Calabrian Arc–Ionian Sea subduction system(Southern Tyrrhenian Sea, Italy). Previous studies indicate that theMS activity developed between 1 and 0.1 Ma through effusions of lava flows. Here, new stratigraphic, textural, geochemical, and 14C geochronological data from a 95 cm long gravity core (COR02) recovered at 839 m bsl in theMS central sector are presented. COR02 contains mud and two tephras consisting of 98 to 100 area% of volcanic ash. The thickness of the upper tephra (TEPH01) is 15 cm, and that of the lower tephra (TEPH02) is 60 cm. The tephras have poor to moderate sorting, loose to partly welded levels, and erosive contacts, which imply a short distance source of the pyroclastics. 14C dating on fossils above and below TEPH01 gives an age of 3 ka BP. Calculations of the sedimentation rates from the mud sediments above and between the tephras suggest that a formation of TEPH02 at 5 ka BP MS ashes has a high-K calcalkaline affinity with 53 wt.% b SiO2 b 68 wt.%, and their composition overlaps that of the MS lava flows. The trace element pattern is consistent with fractional crystallization from a common, OIB-like basalt. The source area of ashes is the central sector of MS and not a subaerial volcano of the Campanian and/or Aeolian Quaternary volcanic districts. Submarine, explosive eruptions occurred atMS in historical times: this is the first evidence of explosive volcanic activity at a significant (500–800 m bsl) water depth in the Mediterranean Sea.MS is still active, the monitoring and an evaluation of the different types of hazards are highly recommended.
    Description: Published
    Description: 764-774
    Description: 2IT. Laboratori sperimentali e analitici
    Description: JCR Journal
    Description: restricted
    Keywords: Submarine active volcanism ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 9
    Publication Date: 2021-05-12
    Description: An accelerating process of ground deformation that began 10 years ago is currently affecting the Campi Flegrei caldera. The deformation pattern is here explained with the overlapping of two processes: short time pulses that are caused by injection of magmatic fluids into the hydrothermal system; and a long time process of heating of the rock. The short pulses are highlighted by comparison of the residuals of ground deformation (fitted with an accelerating polynomial function) with the fumarolic CO2/CH4 and He/CH4 ratios (which are good geochemical indicators of the arrival of magmatic gases). The two independent datasets show the same sequence of five peaks, with a delay of ∼200 days of the geochemical signal with respect to the geodetic signal. The heating of the hydrothermal system, which parallels the long-period accelerating curve, is inferred by temperature–pressure gas geoindicators. Referring to a recent interpretation that relates variations in the fumarolic inert gas species to open system magma degassing, we infer that the heating is caused by enrichment in water of the magmatic fluids and by an increment in their flux. Heating of the rock caused by magmatic fluids can be a central factor in triggering unrest at calderas.
    Description: Published
    Description: 58-67
    Description: 2V. Dinamiche di unrest e scenari pre-eruttivi
    Description: JCR Journal
    Description: restricted
    Keywords: Campi Flegrei Caldera ; hydrothermal system ; ground deformation ; magmatic fluids ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 10
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    Elsevier
    In:  EPIC3Earth and Planetary Science Letters, Elsevier, 464, pp. 95-102
    Publication Date: 2017-04-18
    Description: Recent large-scale remote sensing studies have shown that glacier mass loss in south-eastern Tibet, specifically in the eastern Nyainqêntanglha Range exceeds the average in High Asia. However, detailed studies at individual glaciers are scarce and the drivers behind the observed changes are poorly constrained to date. Employing feature tracking techniques on TerraSAR-X data for the periods 2008/2009, 2012/2013 and 2013/2014 we found measurable surface velocities through to the glacier terminus positions of five debris-covered glacier tongues. This is contrary to debris-covered glaciers in other parts of High Asia, where stagnant glacier tongues are common. Our feature tracking results for the 2013/2014 period suggest an average deceleration of 51% when compared with published Landsat velocities for the period 1999/2003. Further, we estimated surface elevation changes for the five glaciers from recently released one arc second resolution elevation data obtained during the Shuttle Radar Topography Mission in 2000 and an interferometrical derived TanDEM-X elevation model for the year 2014. With an average rate of −0.83 ± 0.57 m a^-1 we confirm strong surface lowering in the region, despite the widely discussed insulation effect of debris cover. Beside the influence of thermokarst processes and delayed response times of debris-covered glaciers, we highlight that abundant monsoonal summer rainfall might contribute significantly to the pronounced negative mass balances in the study region.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
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  • 11
    Publication Date: 2017-04-10
    Description: Solid phase extraction (SPE) has become a widespread method for isolating dissolved organic matter (DOM) of diverse origin such as fresh and marine waters. This study investigated the DOM extraction selectivity of 24 commercially available SPE sorbents under identical conditions (pH = 2, methanol elution) on the example of Suwannee River (SR) water and North Sea (NS) water by using DOC analysis and Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS). Proton nuclear magnetic resonance (1H NMR) spectroscopy was employed to assess leaching behavior, and HLB sorbent was found to leach substantially, among others. Variable DOC recoveries observed for SR DOM and NS DOM were primarily caused by the respective molecular composition, with subordinated and heterogeneous contributions of relative salinity. Scatter of average H/C and O/C elemental ratios and gross alignment in mass-edited H/C ratios according to five established coarse SPE characteristics was near identical for SR DOM and NS DOM. FTMS-based principal component analysis (PCA) provided essentially analogous alignment of SR DOM and NS DOM molecular compositions according to the five established groups of SPE classification, and corroborated the sorption-mechanism-based selectivity of DOM extraction in both cases. Evaluation of structural blanks and leaching of SPE cartridges requires NMR spectroscopy because FT-ICR mass spectrometry alone will not reveal inconspicuous displacements of continual bulk signatures caused by leaching of SPE resin constituents.
    Repository Name: EPIC Alfred Wegener Institut
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  • 12
    Publication Date: 2018-12-19
    Description: The timing and geometry of the initial Gondwana break-up between Africa and East Antarctica is still poorly known due to missing information about the continent-ocean boundaries along the rifted margins. In this context, the Beira High off central Mozambique forms a critical geological feature of uncertain crustal fabric. Based on new wide-angle seismic and potential field data across Beira High a P-wave velocity model, supported by amplitude and gravity modelling, provides constraints on the crustal composition of this area. In the Mozambique Basin mainly normal oceanic crust of 5.5–7 km thickness with velocities of 6.5–7.0 km/s in the lower crust is present. A sharp transition towards Beira High marks the continent-ocean boundary. Here the crust thickens to 23 km at maximum. A small velocity-depth gradient and a constant increase in velocity with basal velocities of maximum 7.0 km/s are in good agreement with typical velocities of continental crust and continental fragments. The density model indicates the existence of felsicmaterial in greater depths and supports a fabric of stretched, but highly intruded continental crust below Beira High. A gradual decrease in crustal thickness characterizes the transition towards the Mozambican shelf area. Here, in the Zambezi Delta Depression 12 km of sediments cover the underlying 7 km thick crust. The presence of a high-velocity lower crustal body with velocities of 7.1–7.4 km/s indicates underplated, magmatic material in this part of the profile. However, the velocity structure in the shelf area allows no definite interpretation because of the experimental setup. Thus, the crustal nature below the Zambezi Delta and consequently the landward position of the continentocean boundary remains unknown. The difference in stretching below the margins of Beira High suggests the presence of different thinning directions and a rift jump during the early rifting stage.
    Repository Name: EPIC Alfred Wegener Institut
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  • 13
    Publication Date: 2016-07-06
    Description: This paper presents the results of measurements of aerosol physical and chemical properties during iAREA2014 campaign that took place on Svalbard between 15th of Mar and 4th of May 2014. With respect to field area, the experiment consisted of two sites: NyeÅlesund (78�550N, 11�560E) and Longyearbyen (78�130N, 15�330E) with further integration of Aerosol Robotic Network (AERONET) station in Hornsund (77�000N, 15�330E). The subject of this study is to investigate the inesitu, passive and active remote sensing observations as well as numerical simulations to describe the temporal variability of aerosol singleescattering properties during spring season on Spitsbergen. The retrieval of the data indicates several event days with enhanced singleescattering properties due to the existence of sulphate and additional seaesalt load in the atmosphere which is possibly caused by relatively high wind speed. Optical results were confirmed by numerical simulations made by the GEMeAQ model and by chemical observations that indicated up to 45% contribution of the seaesalt to a PM10 total aerosol mass concentration. An agreement between the in-situ optical and microphysical properties was found, namely: the positive correlation between aerosol scattering coefficient measured by the nephelometer and effective radius obtained from laser aerosol spectrometer as well as negative correlation between aerosol scattering coefficient and the Ångstrom exponent indicated that slightly larger particles dominated during special events. The inesitu surface observations do not show any significant enhancement of the absorption coefficient as well as the black carbon concentration which might occur during spring. All of extensive singleescattering properties indicate a diurnal cycle in Longyearbyen, where 21:00e5:00 data stays at the background level, however increasing during the day by the factor of 3e4. It is considered to be highly connected with local emissions originating in combustion, traffic and harbour activities. On the other hand, no daily fluctuations in NyeÅlesund are observed. Mean values in NyeÅlesund are equal to 8.2, 0.8 Mm�1 and 103 ng/m3 for scattering, absorption coefficients and black carbon concentration; however in Longyearbyen (only data from 21:00e05:00 UTC) they reach 7.9, 0.6 Mm�1 as well as 83 ng/ m3 respectively. Overall, the spring 2014 was considerably clean and seaesalt was the major aerosol component
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
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  • 14
    Publication Date: 2017-03-28
    Description: Particulate inorganic matter (PIM) is a key component in estuarine and coastal systems and plays a critical role in trace metal cycling. Better understanding of coastal dynamics and biogeochemistry requires improved quantification of PIM in terms of its concentration, size distribution, and mineral species composition. The angular pattern of light scattering contains detailed information about the size and composition of particles. These volume scattering functions(VSFs) were measured in Mobile Bay, Alabama, USA, a dynamic, PIM dominated coastal environment. From measured VSFs, we determined through inversion the particle size distributions (PSDs) of major components of PIM, amorphous silica and clay minerals. An innovation here is the extension of our reported PSDs significantly into the submicron range. The PSDs of autochthonous amorphous silica exhibit two unique features: a peak centered at about 0.8 μm between 0.2 and 4 μm and a very broad shoulder essentially extending from 4 μm to 〉100 μm. With an active and steady particle source from blooming diatoms, the shapes of amorphous silica PSDs for sizes 〈 10 μm varied little across the study area, but showed more particles of sizes 〉 10 μm inside the bay, likely due to wind-induced resuspension of larger frustules that have settled. Compared to autochthonous amorphous silica, the allochthonous clay minerals are denser and exhibit relatively narrower PSDs with peaks located between 1 and 4 μm. Preferential settling of larger mineral particles as well as the smaller but denser illite component further narrowed the size distributions of clay minerals as they were being transported outside the bay. The derived PSDs also indicated a very dynamic situation in Mobile Bay relative to the cold weather front that passed through during the experiment. With northerly winds of speeds up to 15 m s-1, both amorphous silica and clay minerals showed a dramatic increase in concentration and broadening in size distribution outside the exit of the barrier islands, indicative of wind-induced resuspension and subsequent advection of particles out of Mobile Bay. While collectively recognized as the PIM, amorphous silica and clay minerals, as shown in this study, possess very different size distributions. Considering how differences in PSDs and the associated particle areas will effect differences in sorption/desorption properties of these components, the results also demonstrate the potential of applying VSF-inversion in studying biogeochemistry in the estuarine-coastal ocean system.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , peerRev
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  • 15
    Publication Date: 2019-01-31
    Description: n the framework of atmospheric circulation regimes, we study whether the recent Arctic sea ice loss and Arctic Amplification are associated with changes in the frequency of occurrence of preferred atmospheric circulation patterns during the extended winter season from December to March. To determine regimes we applied a cluster analysis to sea-level pressure fields from reanalysis data and output from an atmospheric general circulation model. The specific set up of the two analyzed model simulations for low and high ice conditions allows for attributing differences between the simulations to the prescribed sea ice changes only. The reanalysis data revealed two circulation patterns that occur more frequently for low Arctic sea ice conditions: a Scandinavian blocking in December and January and a negative North Atlantic Oscillation pattern in February and March. An analysis of related patterns of synoptic-scale activity and 2 m temperatures provides a synoptic interpretation of the corresponding large-scale regimes. The regimes that occur more frequently for low sea ice conditions are resembled reasonably well by the model simulations. Based on those results we conclude that the detected changes in the frequency of occurrence of large-scale circulation patterns can be associated with changes in Arctic sea ice conditions.
    Repository Name: EPIC Alfred Wegener Institut
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  • 16
    Publication Date: 2018-04-13
    Description: eddy located along the Antarctic Polar Front in the Atlantic sector of the Southern Ocean. Mixed layer (ML) waters were characterized by high nitrate (~20 μM), low dissolved iron (DFe ~0.2 nM) and low silicate concentrations (below 1 μM) restricting diatom growth. Upon initial fertilization, chlorophyll-a doubled during the first two weeks and stabilized thereafter, despite a second fertilization on day 21, due to an increase in grazing pressure. Biomass at the different trophic levels was mostly comprised of small autotrophic flagellates, the large copepod Calanus simillimus and the amphipod Themisto gaudichaudii. The downward flux of particulate material comprised mainly copepod fecal pellets that were remineralized in the upper 150 m of the water column with no significant deeper export. showed a greater variability (ranging from 0.3 to 1.3 nM) without a clear vertical pattern. Particulate iron concentrations (measured after 2 months at pH 1.4) decreased with time and showed a vertical pattern that indicated an important non-biogenic component at the bottom of the mixed layer. In order to assess the contribution of copepod grazing to iron cycling we used two different approaches: first, we measured for the first time in a field experiment copepod fecal pellet concentrations in the water column together with the iron content per pellet, and second, we devised a novel analytical scheme based on a two-step leaching protocol to estimate the contribution of copepod fecal pellets to particulate iron in the water column. Analysis of the iron content of isolated fecal pellets from C. simillimus showed that after the second fertilization, the iron content per fecal pellet was ~5 fold higher if the copepod had been captured in fertilized waters. We defined a new fraction termed leachable iron (pH 2.0) in 48 h (LFe48h) that, for the conditions during LOHAFEX, was shown to be an excellent proxy for the concentration of iron contained in copepod fecal pellets. We observed that, as a result of the second fertilization, iron accumulated in copepod fecal pellets and remained high at one third of the total iron stock in the upper 80 m. We hypothesize that our observations are due to a combination of two biological processes. First, phagotrophy of iron colloids freshly formed after the second fertilization by the predominant flagellate community resulted in higher Fe:C ratios per cell that, via grazing, lead to iron enrichment in copepod fecal pellets in fertilized waters. Second, copepod coprophagy could explain the rapid recycling of particulate iron in the upper 100–150 m, the accumulation of LFe48h in the upper 80 m after the second fertilization and provided the iron required for the maintenance of the LOHAFEX bloom for many weeks. Our results provide the first quantitative evidence of the major ecological relevance of copepods and their fecal products in the cycling of iron in silicate depleted areas of the Southern Ocean.
    Repository Name: EPIC Alfred Wegener Institut
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  • 17
    Publication Date: 2016-09-24
    Description: Thermokarst processes characterize a variety of ice-rich permafrost terrains and often lead to lake formation. The long-term evolution of thermokarst landscapes and the stability and longevity of lakes depend upon climate, vegetation and ground conditions, including the volume of excess ground ice and its distribution. The current lake status of thermokarst-lake landscapes and their future trajectories under climatewarming are better understood in the light of their long-term development. We studied the lake-rich southern marginal upland of the Yukon Flats (northern interior Alaska) using dated lake-sediment cores, observations of river-cut exposures, and remotely-sensed data. The region features thick (up to 40 m)Quaternary deposits (mainly loess) that contain massive ground ice. Two of three studied lakes formed ~11,000–12,000 cal yr BP through inferred thermokarst processes, and fire may have played a role in initiating thermokarst development. From ~9000 cal yr BP, all lakes exhibited steady sedimentation, and pollen stratigraphies are consistentwith regional patterns. The current lake expansion rates are low (0 to b7 cmyr−1 shoreline retreat) compared with other regions (~30 cm yr−1 or more). This thermokarst lake-rich region does not showevidence of extensive landscape lowering by lake drainage, nor of multiple lake generations within a basin. However, LiDAR images reveal linear “corrugations” (N5 m amplitude), deep thermo-erosional gullies, and features resembling lake drainage channels, suggesting that highly dynamic surface processes have previously shaped the landscape. Evidently, widespread early Holocene permafrost degradation and thermokarst lake initiation were followed by lake longevity and landscape stabilization, the latter possibly related to establishment of dense forest cover. Partial or complete drainage of three lakes in 2013 reveals that there is some contemporary landscape dynamism. Holocene landscape evolution in the study area differs from that described from other thermokarst-affected regions; regional responses to future environmental change may be equally individualistic.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev , info:eu-repo/semantics/article
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  • 18
    Publication Date: 2016-09-23
    Description: Thermokarst lakes develop as a result of the thaw and collapse of ice-rich, permanently frozen ground (permafrost). Of particular sedimentological importance are thermokarst lakes forming in late Pleistocene icy silt (yedoma),which dramatically alter the land surface by lowering surface elevation and redistributing upland sediment into lower basins. Our study provides the first description of yedoma thermokarst lake sedimentology based on the crossbasin sampling of an existing lake. We present lake sediment facies descriptions based on data from sediment cores from two thermokarst lakes of medium depth, Claudi and Jaeger (informal names), which formed in previously non thermokarst-affected upland yedoma on the northern Seward Peninsula, Alaska. We identify four prominent facies using sedimentological, biogeochemical, and macrofossil indicators: a massive silt lacking aquatic macrofossils and other aquatic indicators situated below a sub-lacustrine unconformity (Facies 1); two basal deposits: interbedded organic silt and chaotic silt (Facies 2–3); and a silt-rich mud (Facies 4). Facies 1 is interpreted as yedoma that has thawed during lake formation. Facies 3 formed adjacent to the margin due to thaw and collapse events from the lake shore. Material from Facies 3 was reworked by wave action to form Facies 2 in a medium energy margin environment. Facies 4 formed in a lower energy environment toward the lake basin center. This facies classification and description should enhance our ability (i) to interpret the spatial and temporal development of lakes and (ii) to reconstruct long-term patterns of landscape change.
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  • 19
    Publication Date: 2016-11-22
    Description: The hypothesis of this work was that exposure to diverse abiotic factors in two sites with different sediment and iron input (Peñón de Pesca: low impact; Island D: high impact, both areas in Potter Cove, King George Island, Antarctica) affects the physiological and oxidative profile of Gigartina skottsbergii and Himantothallus grandifolius. Daily metabolic carbon balance was significantly lower in both macroalgae from Island D compared to Peñón de Pesca. Lipid radical (LRradical dot) content was significantly higher in G. skottsbergii collected from Island D compared to Peñón de Pesca. In contrast, H. grandifolius showed significantly lower values in Island D compared to Peñón de Pesca. The β-carotene (β-C) content was significantly lower in G. skottsbergii from Island D compared to Peñón de Pesca, and the ratio LRradical dot/β-C showed a 6-fold increase in Island D samples compared to Peñón de Pesca. On the other hand, β-C content in H. grandifolius showed no significant differences between both areas. The LRradical dot/β-C content ratio in this alga was significantly lower (26%) in Island D as compared to Peñón de Pesca. Total iron content was significantly higher in both macroalgae from Island D compared to samples from Peñón de Pesca. Results with G. skottsbergii suggested changes in the oxidative cellular balance, probably related to the higher environmental iron in Island D as compared to Peñón de Pesca. The species H. grandifolius seems to be better adapted to the environmental conditions especially through a higher antioxidant capacity to cope with oxidative stress.
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  • 20
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    Elsevier
    In:  EPIC3Earth and Planetary Science Letters, Elsevier, 457, pp. 412-422, ISSN: 0012821X
    Publication Date: 2017-01-02
    Description: The Himalaya–Tibet orogen contains one of the largest modern topographic and climate gradients on Earth. Proxy data from the region provide a basis for understanding Tibetan Plateau paleo climate and paleo elevation reconstructions. Paleo climate model comparisons to proxy data compliment sparsely located data and can improve climate reconstructions. This study investigates temporal changes in precipitation, temperature and precipitation δ18O(δ18Op) over the Himalaya–Tibet from the Last Glacial Maximum (LGM) to present. We conduct a series of atmospheric General Circulation Model (GCM, ECHAM5-wiso) experiments at discrete time slices including a Pre-industrial (PI, Pre-1850 AD), Mid Holocene (MH, 6 ka BP) and LGM (21 ka BP) simulations. Model predictions are compared with existing proxy records. Model results show muted climate changes across the plateau during the MH and larger changes occurring during the LGM. During the LGM surface temperatures are ∼2.0–4.0◦C lower across the Himalaya and Tibet, and 〉5.0◦C lower at the northwest and northeast edge of the Tibetan Plateau. LGM mean annual precipitation is 200–600 mm/yr lower over on the Tibetan Plateau. Model and proxy data comparison shows a good agreement for the LGM, but large differences for the MH. Large differences are also present between MH proxy studies near each other. The precipitation weighted annual mean δ18Op lapse rate at the Himalaya is about 0.4h/km larger during the MH and 0.2h/km smaller during the LGM than during the PI. Finally, rainfall associated with the continental Indian monsoon (between 70◦E–110◦E and 10◦N–30◦N) is about 44% less in the LGM than during PI times. The LGM monsoon period is about one month shorter than in PI times. Taken together, these results document significant spatial and temporal changes in temperature, precipitation, and δ18Op over the last ∼21 ka. These changes are large enough to impact interpretations of proxy data and the intensity of the Indian monsoon.
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  • 21
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    Elsevier
    In:  EPIC3Fate and Impact of Microplastics in Marine Ecosystems, Fate and Impact of Microplastics in Marine Ecosystems, Elsevier, 1 p., pp. 162-163, ISBN: 978-0-12-812271-6
    Publication Date: 2017-06-21
    Description: Since the 1950s more than 6.1 billion tons of plastics have been produced. It has been estimated that about 10% of this amount will be deposited long-term in theOceans. The problem is highlighted by several currentstudies using different environmental sampling protocols and analytical methods. Effects of this anthropogenic litter on the environment and organisms are heavily on debate, emphasizing the need to transfer this knowledge to young educated people and to fuel educational programs. The school lab OPENSEA at the Alfred-Wegener-Institute on Helgoland started a joint high school project on marine plastic litter in cooperation with the experts of the marine microplastics group at AWI to link science and education more closely. Based on the OSPAR protocol for beach monitoring of marine litter we developed an experimental set up focusing on sampling and identification of plastic litter on beaches, shores and in sediments in the course of the OPENSEA science and education program for grammar and high school scholars. This monitoring provides environmental data on marine plastic litter and will be integrated in a long term data monitoring program in the course of a citizen science study. In addition we plan to integrate also smaller plastic particles into the project. Fractionated sediment samples will be screened for particles 〉 0.5mm, which then will be analyzed by ATR-FT-IR. These educational activities, with a strong link to the latest science and to sophisticated technology will raise the awareness of younger people for the marine litter problematic. We aim at increasingtheir concerns after taking part in this program. We will present background information, sampling strategies, identification efforts and results based on this scholar science project.
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  • 22
    Publication Date: 2017-01-20
    Description: Although the Arctic covers 6% of our planet’s surface and plays a key role in the Earth’s climate it remains one of the least explored ecosystems. The global change induced decline of sea ice has led to increasing anthropogenic presence in the Arctic Ocean. Exploitation of its resources is already underway, and Arctic waters are likely important future shipping lanes as indicated by already increasing numbers of fishing vessels, cruise liners and hydrocarbon prospecting in the area over the past decade. Global estimates of plastic entering the oceans currently exceed results based on empirical evidence by up to three orders of magnitude highlighting that we have not yet identified some of the major sinks of plastic in our oceans. Fragmentation into microplastics could explain part of the discrepancy. Indeed, microplastics were identified from numerous marine ecosystems globally, including the Arctic. Here, we analysed horizons of ice cores from the western and eastern Fram Strait by focal plane array based micro-Fourier transform infrared spectroscopy to assess if sea ice is a sink of microplastic. Ice cores were taken from land-locked and drifting sea ice to distinguish between local entrainment of microplastics vs long-distance transport. Mean concentrations of 2 x 106 particles m-3 in pack ice and 6 x 105 particles m-3 in land-locked ice were detected (numbers of fibers will soon be added). Eleven different polymer types were identified; polyethylene (PE) was the most abundant one. Preliminary results from four further ice cores from the central Arctic range in a similar order but the microplastics composition was very different. Calculation of drift trajectories by back-tracking of the ice floes sampled indicates multiple source areas, which explains the differences in the microplastic composition. Preliminary analysis of snow samples taken from ice floes in the Fram Strait showed numerous fibers of yet unknown but most likely anthropogenic origin indicating atmospheric fallout as a possible pathway. Our results exceed concentrations from the North Pacific by several orders of magnitudes. This can be explained partly by the process of ice formation, during which (organic) particles tend to concentrate by 1-2 orders of magnitude compared with ambient seawater. However, the magnitude of the difference indicates that Arctic sea ice is a temporal sink for microplastics. Increasing quantities of small plastic litter items on the seafloor nearby, which is located in the marginal ice zone corroborate the notion that melting sea ice releases entrained plastic particles and that sea ice acts as a vector of transport both horizontally and vertically to underlying ecosystem compartments.
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  • 23
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    Elsevier
    In:  EPIC3Fate and Impact of Microplastics in Marine Ecosystems, Elsevier
    Publication Date: 2017-05-29
    Description: The pollution of the oceans with plastic particles smaller than 5 mm, called microplastics is moving into the focus of science and governments. To determine the amount of microplastics several steps are necessary, starting with the sampling, work up and finally analysis. Each step has its own challenges due to small size of the particles. For analysis the imaging with µFTIR microscopy is a powerful tool allowing the analysis of complete filters. Systematic screening for optimal conditions and filter materials have already been performed. This method has a high time demand regarding the measurement and data interpretation. While the measurement is performed mostly by the spectrometer, the interpretation has to be made by hand on the basis of false color images. To overcome the manual part we developed a novel approach based on the Bruker OPUS© Software to decrease the high time demand for the analysis of microplastics. With this approach it was possible to analyze measurement files from focal plane array (FPA) FTIR mapping containing up to 1.8 million single spectra. These spectra were compared with a database of different synthetic and natural polymers by various methods. By benchmark tests their performance was monitored with the focus on accuracy and data quality. After optimization high quality data was generated, which allowed image analysis. Based on these results an approach for image analysis was developed, giving information for the particle size distribution for each polymer type, particle distribution on the filter and polymer distribution for the particles. It was possible to collect all data with relative ease even for complex sample matrices. This approach has significantly decreased the time demand for the interpretation of FTIR-imaging data and increased the generated data quality.
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  • 24
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    Elsevier
    In:  EPIC3SoftwareX, Elsevier, 6, pp. 69-80, ISSN: 2352-7110
    Publication Date: 2017-03-06
    Repository Name: EPIC Alfred Wegener Institut
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  • 25
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    Elsevier
    In:  EPIC3Remote Sensing of Environment, Elsevier, 187, pp. 30-48, ISSN: 0034-4257
    Publication Date: 2017-01-20
    Description: Research on processes leading to formation, maintenance, and disappearance of polynyas in the Polar Regions benefits significantly from the use of different types of remote sensing data. The Sentinels of the European Space Agency (ESA), together with other satellite missions, provide a variety of data from different parts of the electromagnetic spectrum, at different spatial scales, and with different temporal resolutions. In a case study we demonstrate the advantage of merging data from different spaceborne instruments for analysing ice conditions and ice dynamics in and around the frequently occurring Terra Nova Bay Polynya (TNBP) in the Ross Sea in the Antarctic. Starting with a list of polynya parameters that are typically retrieved from satellite images, we assess the usefulness of different sensor types. On regional scales (several 100 km), passive microwave radiometers provide a view on the mutual influence of the three Ross Sea polynyas on sea ice drift and deformation patterns. Optical sensors with meter-scale resolution, on the other hand, allow very localized analyses of different polynya zones. The combination of different ranges of the electromagnetic spectrum is essential for recognition and classification of ice types and structures. Radar images together with data from thermal infrared sensors, operated at tens to hundreds of meters resolution, improve the separation of the outlet zone of the polynya from the adjacent pack ice. The direct comparison of radar and passive microwave images reveals the visibility of deformed ice zone in the latter. A sequence of radar images was employed to retrieve ice drift around the TNB, which allows analysing the temporal changes of the polynya area and the extension and structure of the outlet zone as well as ice movements and deformation that are influenced by the katabatic winds.
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  • 26
    Publication Date: 2016-10-10
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  • 27
    Publication Date: 2017-05-03
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  • 28
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    Elsevier
    In:  EPIC3Climate Change, Ocean Current Changes, Amsterdam, Elsevier, pp. 253-269
    Publication Date: 2016-12-05
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  • 29
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    Elsevier
    In:  EPIC3Reference Module in Earth Systems and Environmental Sciences, Elsevier
    Publication Date: 2017-02-14
    Description: Vast quantities of plastics are accumulating in the oceans. At sea, plastics interact with marine biota often with deleterious consequences for organisms and habitats. As users of marine food resources and ecosystem services humans are also affected by marine plastic litter. Economic, social and health implications necessitate decisive action to manage this growing environmental problem at a global scale. Accordingly, legislative and technological instruments have been implemented to reduce the amounts of marine plastic debris. Promising strategies to reduce the human plastic footprint in the oceans must involve the minimization of plastic discharges into the marine environment.
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  • 30
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    Elsevier
    In:  EPIC3Fate and Impact of Microplastics in Marine Ecosystems, MICRO 2016, Amsterdam, Elsevier, 2 p., pp. 106-107
    Publication Date: 2017-01-20
    Description: For many years, the pollution of the oceans with marine litter received only little attention from the public although the global plastic production has grown steadily. However, since the “discovery” of the oceanic garbage patches and microplastics the littering of the oceans has become a hot topic, which is reflected in strong recent increases in the number of publications. Despite growing research efforts many questions remain unanswered and the new wealth of information does not readily transpire to the general public, which is left unsettled. For example, it is still unclear what the overall extent of ocean pollution is, or how the enormous amounts of oceanic plastics affect marine life and ecosystems. To overcome this uncertainty and make best use of the existing knowledge, we currently develop an online portal for marine litter and microplastic pollution named LITTERBASE. As of early 2017, LITTERBASE will provide access to the current state of understanding of marine litter and microplastics to the general public and stakeholders. Published records of marine litter and microplastics and their impact on marine life will be compiled in a database. The regularly updated information will be displayed in distribution maps and other graphs in an interactive online portal. In the long run, data from citizen scientists may also be integrated into these infographs.
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  • 31
    Publication Date: 2018-02-16
    Description: Global and regional change clearly affects the structure and functioning of ecosystems in shelf seas. However, complex interactions within the shelf seas hinder the identification and unambiguous attribution of observed changes to drivers. These include variability in the climate system, in ocean dynamics, in biogeochemistry, and in shelf sea resource exploitation in the widest sense by societies. Observational time series are commonly too short, and resolution, integration time, and complexity of models are often insufficient to unravel natural variability from anthropogenic perturbation. The North Sea is a shelf sea of the North Atlantic and is impacted by virtually all global and regional developments. Natural variability (from interannual to multidecadal time scales) as response to forcing in the North Atlantic is overlain by global trends (sea level, temperature, acidification) and alternating phases of direct human impacts and attempts to remedy those. Human intervention started some 1000 years ago (diking and associated loss of wetlands), expanded to near-coastal parts in the industrial revolution of the mid-19th century (river management, waste disposal in rivers), and greatly accelerated in the mid-1950s (eutrophication, pollution, fisheries). The North Sea is now a heavily regulated shelf sea, yet societal goals (good environmental status versus increased uses), demands for benefits and policies diverge increasingly. Likely, the southern North Sea will be re-zoned as riparian countries dedicate increasing sea space for offshore wind energy generation with uncertain consequences for the system's environmental status. We review available observational and model data (predominantly from the southeastern North Sea region) to identify and describe effects of natural variability, of secular changes, and of human impacts on the North Sea ecosystem, and outline developments in the next decades in response to environmental legislation, and in response to increased use of shelf sea space.
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  • 32
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    Elsevier
    In:  EPIC3Deep Sea Research Part I: Oceanographic Research Papers, Elsevier, 107, pp. 70-81
    Publication Date: 2019-08-19
    Description: The Weddell Sea plays an important role for the global oceans and climate by being one of the biggest production and export areas of Antarctic Bottom Water (AABW). Circumpolar Deep Water (CDW) enters the Weddell Gyre (WG) at its eastern boundary. Then called Warm Deep Water (WDW), it is a major contributor to the formation of deep and bottom waters due to ocean-ice shelf interactions in the southern and soutwestern Weddell Sea. Hydrographic data collected between 0 and 30°E on the RV Polarstern cruise ANT XX/2 reveals a two-core structure for the eastern inflow of warm water at roughly 20°E but not further downstream at the Greenwich meridian (GM). Model results and climatological fields suggest that the two cores represent two separate modes of warm inflow. One mode is driven by eddy mixing in the northeastern corner of the WG and the other one is an advective mode, forming the southern branch of the inflow which extends beyond 30°E before turning westward. Both pathways are likely to carry waters from different origins within the Antarctic Circumpolar Current (ACC), where more ventilated CDW is found at the Southern Boundary (SB) compared to the centre. The southern route shows considerable interannual variability in the model. A variable inflow of two types of CDW together with admixed recirculated and cooler waters from the Weddell Sea can potentially contribute to the observed variability and warming trend of WDW over the last decade at the GM.
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  • 33
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    Elsevier
    In:  EPIC3Earth and Planetary Science Letters, Elsevier, 409, pp. 15-22, ISSN: 0012-821X
    Publication Date: 2017-02-08
    Description: Knowledge of the magnitude of the Last Glacial Maximum (LGM) cooling is a useful constraint for estimating the climate sensitivity used in projecting future climate change. Proxy comparison, especially that between the alkenone-based UK′37 and the archaeal tetraether-based TEX86, has been increasingly applied in paleoceanographic studies as a measure to better constrain proxy-derived temperature estimates. In this study, we compile and compare published multiproxy (UK′37 and TEXH86) records of glacial cooling measured on the same sediment cores. In spite of the diversity in oceanographic and sedimentation settings spanned by the study sites, we find that the TEXH86-derived mean tropical LGM cooling is approximately twice as strong as that suggested by the UK′37 and MARGO estimates. The extent of proxy discrepancy varies with the application of various regional calibrations, but the mean TEXH86-inferred cooling remains stronger than that inferred from UK′37. To understand the discrepancy between proxies, we examine the seasonal and water column structure of LGM cooling simulated by state-of-the-art climate models. We find that the dissimilar magnitudes of proxy-derived glacial cooling cannot be fully explained by proxies reflecting temperature of different seasons or different water depths, if the recording season and depth are assumed to stay constant through time. A hypothetical shift in recording season and/or depth between the Holocene and the LGM could in theory cause the proxy discrepancy, but this hypothesis cannot be constrained due to a lack of information on lipid production and export in the water column during the LGM. Alternatively, the systematic proxy discrepancy, which persists across diverse oceanographic settings, may imply that the commonly applied proxy calibrations for reconstructing past temperatures are fundamentally biased. As evidenced by the improved consistency between UK′37 and TEXH86-based estimates of LGM cooling after we applied a global subsurface (0–200 m) temperature calibration for TEXH86, it is plausible that the TEXH86 signal originates from deeper in the water column than typically assumed for the proxy calibration.
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  • 34
    Publication Date: 2018-02-11
    Description: Arctic sea ice is a critical component of the climate system as it influences the albedo, heat, moisture and gas exchange between ocean and atmosphere as well as the ocean's salinity. An ideal location to study natural sea ice variability during pre-industrial times is the East Greenland Shelf that underlies the East Greenland Current (EGC), the main route of Arctic sea ice and freshwaters from the Arctic Ocean into the northern North Atlantic. Here, we present a new high-resolution biomarker record from the East Greenland Shelf (73°N), which provides new insights into the sea ice variability and accompanying phytoplankton productivity over the past 5.2 kyr. Our IP25 based sea ice reconstructions and the inferred PIP25 index do not reflect the wide-spread late Holocene Neoglacial cooling trend that follows the decreasing solar insolation pattern, which we relate to the strong influence of the polar EGC on the East Greenland Shelf and interactions with the adjacent fjord throughout the studied time interval. However, our reconstructions reveal several oscillations with increasing/decreasing sea ice concentrations that are linked to the known late Holocene climate cold/warm phases, i.e. the Roman Warm Period, Dark Ages Cold Period, Medieval Climate Anomaly and Little Ice Age. The observed changes seem to be connected to general ocean atmosphere circulation changes, possibly related to North Atlantic Oscillation and Atlantic Multidecadal Oscillation regimes. Furthermore, we identify a cyclicity of 73–74 years in sea ice algae and phytoplankton productivity over the last 1.2 kyr, which may indicate a connection to Atlantic Multidecadal Oscillation mechanisms.
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  • 35
    Publication Date: 2017-12-17
    Description: The bio-essential trace metal iron (Fe) has poor inorganic solubility in seawater, and therefore dissolution is dependent on organic complexation. The Arctic Ocean is subject to strong terrestrial influences which contribute to organic solubility of Fe, particularly in the surface. These influences are subject to rapid changes in the catchments of the main contributing rivers. Here we report concentrations and binding strengths of Fe-binding organic ligands in relation to spectral properties of Dissolved Organic Matter (DOM) and concentrations of humic substances. Full-depth profiles of Fe and Fe-binding organic ligands were measured for 11 stations, good agreement to previous studies was found with ligand concentrations between 0.9 and 2.2 equivalent nM of Fe (Eq. nM Fe) at depths 〉 200 m. We found nutrient-like profiles of Fe in the Atlantic-influenced Nansen basin, surface enrichment in the surface over the Amundsen and Makarov basins and scavenging effects in the deep Makarov basin. A highly detailed surface transect consisting of two sections crossing the surface flow from the Siberian continental shelf to the Fram Strait, the TransPolar Drift (TPD), clearly indicates the flow path of the riverine contribution to Fe and Fe-binding organic ligands with concentrations of 0.7 to 4.4 nM and 1.6 to 4.1 Eq. nM Fe, respectively. This is on average 4.5 times higher in DFe and 1.7 times higher in Fe-binding organic ligands than outside the TPD flow path. Conditional binding strengths of ligands in the entire dataset were remarkably similar at 11.45 ≤ LogK′ ≤ 12.63. Increased organic Fe-binding organic ligand concentrations were evident in the Arctic Ocean surface. To better identify the organic substances responsible for Fe complexation in the Arctic Ocean, diverse analytical approaches and a standard other than Suwannee River Fulvic Acid are recommended.
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  • 36
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    In:  EPIC3Comparative Biochemistry and Physiology, Part A, Elsevier, 211, pp. 61-68
    Publication Date: 2018-02-05
    Description: Effects of hypoxia on the osmorespiratory functions of the posterior gills of the shore crab Carcinus maenas acclimated to 12 ppt seawater (DSW) were studied. Short-circuit current (Isc) across the hemilamella (one epithelium layer supported by cuticle) was substantially reduced under exposure to 1.6, 2.0, or 2.5 mg O2/L hypoxic saline (both sides of epithelium) and fully recovered after reoxygenation. Isc was reduced equally in the epithelium exposed to 1.6 mg O2/L on both sides and when the apical side was oxygenated and the basolateral side solely exposed to hypoxia. Under 1.6 mg O2/L, at the level of maximum inhibition of Isc, conductance was decreased from 40.0 mS cm−2 to 34.7 mS cm−2 and fully recovered after reoxygenation. Isc inhibition under hypoxia and reduced 86Rb+ (K+) fluxes across apically located K+ channels were caused preferentially by reversible inhibition of basolaterally located and ouabain sensitive Na+,K+-ATPase mediated electrogenic transport. Reversible inhibition of Isc is discussed as decline in active transport energy supply down regulating metabolic processes and saving energy during oxygen deprivation. In response to a 4 day exposure of Carcinus to 2.0 mg O2/L, hemolymph Na+ and Cl− concentration decreased, i.e. hyperosmoregulation was weakened. Variations of the oxygen concentration level and exposure time to hypoxia lead to an increase of the surface of mitochondria per epithelium area and might in part compensate for the decrease in oxygen availability under hypoxic conditions.
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  • 37
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    Elsevier
    In:  EPIC3Fate and Impact of Microplastics in Marine Ecosystems, MICRO 2016: Fate and Impact of Microplastics in Marine Ecosystems, Elsevier, pp. 92-93
    Publication Date: 2018-02-11
    Description: As the plastic production has been rising since the last five decades, so does the concern for the occurrence of microplastic particles (〈5 mm)in the marine environment during the past years. But still by now the extent of this microplastic pollution of coastal waters and the open ocean remains unclear. Since monitoring the abundance of microplastics in the marine environment is requested by the Marine Strategy Framework Directive (MSFD) standardized and reliable methods forthe detection of microplastics are urgently needed. Studies differ mainly in their purification methods, aiming to reduce biogenic material in environmental samples without altering the plastic polymers to facilitate a clear assignment of the microplastics. In the present and ongoing study the purification method consists of a treatment with technical enzymes and detergents to reduce the use of oxidants and avoid the use of strong acids as well as the subsequent identification and quantification of microplastics applying Focal Plane Array (FPA)-based μFourier Transform Infrared (μFT-IR) spectroscopy.
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  • 38
    Publication Date: 2019-07-17
    Description: Microcystis are known for their potential ability to synthesize toxins, mainly microcystins (MCs). In order to evaluate the effects of temperature on chlorophyll a (Chl a), growth, physiological responses and toxin production of a native Microcystis aeruginosa, we exposed the cells to low (23 °C) and high (29 °C) temperature in addition to a 26 °C control treatment. Exponential growth rate was significantly higher at 29 °C compared to 23 °C and control, reaching 0.43, 0.32 and 0.33 day−1 respectively. In addition, there was a delay of the start of exponential growth at 23 °C. However, the intracellular concentration of Chl a decreased significantly due to temperature change. A significant increase in intracellular ROS was observed in coincidence with the activation of enzymatic antioxidant catalase (CAT) during the first two days of exposure to 23° and 29 °C in comparison to the control experiment, decreasing thereafter to nearly initial values. Five MCs were determined by LC-MS/MS analysis. In the experiments, the highest MC concentration, 205 fg [Leu1] MC-LR.cell− 1 expressed as MC-LR equivalent was measured in the beginning of the experiment and subsequently declined to 160 fg.cell− 1 on day 2 and 70 fg.cell− 1 on day 4 in cells exposed to 29 °C. The same trend was observed for all other MCs except for the least abundant MC-LR which showed a continuous increase during exposure time. Our results suggest a high ability of M. aeruginosa to perceive ROS and to rapidly initiate antioxidant defenses with a differential response on MC production.
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  • 39
    Publication Date: 2016-10-01
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  • 40
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    In:  EPIC3MICRO 2016. Fate and Impact of Microplastics in Marine Ecosystems, MICRO 2016. Fate and Impact of Microplastics in Marine Ecosystems, Elsevier, 1 p., pp. 120-120, ISBN: 9780128122716
    Publication Date: 2016-12-12
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  • 41
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    Elsevier
    In:  EPIC3Fate and Impact of Microplastics in Marine Ecosystems, MICRO 2016, Amsterdam, Elsevier, pp. 177-181
    Publication Date: 2017-04-25
    Repository Name: EPIC Alfred Wegener Institut
    Type: Inbook , peerRev
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  • 42
    Publication Date: 2017-06-07
    Description: Over the past ~ 5000 years, amplified dust generation and deposition in the American West has been linked to human activity. In recent decades, intensified rates of agriculture and livestock grazing have been correlated with greater dust production detected on seasonal to annual timescales. The combination of land use intensification and climate change (i.e. increased drought frequency) in North America highlights the importance of characterizing the sources of dust both before and after the influence of anthropogenic activity. We apply high-precision geochemical and isotopic (Sr and Nd isotopes) techniques to an ice core from the Upper Fremont Glacier (Wyoming, USA) to produce the first glacial dataset from the American West. Our Sr-Nd isotopic composition data indicates the evolving dust provenance to the Upper Fremont Glacier (UFG) from a long-range transport of mineral dust to a local source. This increasing input of dust from a local source is supported by a rise in average dust particle diameter combined with greater average dust concentration throughout the record. The greater presence of dust particles smaller than 2.5 μm in the most recent samples from UFG ice core record support existing satellite and sediment core data regarding the effects of anthropogenic activity upon dust sources and pathways in the American West. Although the Sr-Nd isotope database in North America needs be expanded, our results provide a survey of windborne dust through the past 270 years.
    Repository Name: EPIC Alfred Wegener Institut
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  • 43
    Publication Date: 2017-06-16
    Description: This study analyzed multi-channel seismic reflection data from Lake Van, Eastern Anatolia, to provide key information on the structural elements, deformational patterns and overall tectonic structure of the Lake Van basin. The seismic data reveal three subbasins (the Tatvan, northern and Ahlat subbasins) separated by structural ridges (the northern and Ahlat ridges). The Tatvan basin is a tilted wedge-block in the west, it is a relatively undeformed and flat-lying deep basin, forming a typical example of strike-slip sedimentation. Seismic sections reveal that the deeper sedimentary sections of the Tatvan basin are locally folded, gently in the south and more intensely further north, suggesting a probable gravitational “wedge-block” instability, oblique to the northern margin. The northern subbasin, bounded by normal oblique faults, forms a basin-margin graben structure that is elongated in a northeast-southwest direction. The east-west trending Ahlat ridge forms a fault-wedged sedimentary ridge and appears to offset by reverse oblique faults forming as a push-up rhomb horst structure. The Ahlat subbasin is a fault-wedged trough fill that is elongated in the west-east direction and appears as a horst-foot graben formed by the normal oblique faults. The northeast-southwest directed northern ridge is a faulted crestal terrace of a sublacustrine basement block. Its step-like morphology, in response to the downfaulting of the Tatvan basin, as well as its backthrusted appearance, indicates the normal oblique nature of the bounding faults. The lacustrine shelf and slope show distinctive stratigraphic features; progradational deltas, submerged fluvial channels, distorted and collapsed beddings and soft sediment deformation structures, characterizing a highly unstable nature of shelf caused by strong oblique faulting and related earthquakes. The faulting caused uplift of the Çarpanak spur zone, together with the northeastern Erek delta, deformation of deltaic structures and subsequently exposing the shelf and slope areas. The exposed areas are evident in the angular unconformity surface of the Çarpanak basement block with the northeastern Erek delta and thinned sediments. The uplift resulted in the asymmetric depositional emplacement of the southeastern delta that is controlled by a series of ramp anticlines/low angle reverse faults. The Deveboynu subbasin and Varis spur zone form wide fault-controlled depressions with thick sediments that are elongated in the north-south direction. These subbasins appear as a small pull-apart boundary formed by normal oblique faults at the western end of the southeastern delta.
    Repository Name: EPIC Alfred Wegener Institut
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  • 44
    facet.materialart.
    Unknown
    Elsevier
    In:  EPIC3Graphical Models, Elsevier, 82, pp. 123-136, ISSN: 15240703
    Publication Date: 2017-06-14
    Description: Local curvature characterizes every point of a surface and measures its deviation from a plane, locally. One application of local curvature measures within the field of image and geometry processing is object segmentation. Here, we present and evaluate a novel algorithm based on the fundamental forms to calculate the curvature on surfaces of objects discretized with respect to a regular three-dimensional grid. Thus, our new algorithm is applicable to voxel data, which are created e.g. from computed tomography (CT). Existing algorithms for binary data used the Gauss map, rather than fundamental forms. For the calculation of the fundamental forms, derivatives of a surface in tangent directions in every point of the surface have to be computed. Since the surfaces exist on grids with restricted resolution, these derivatives have to be discretized. In the presented method, this is realized by projecting the tangent plane onto the discrete object surface. The most important parameter of the proposed algorithm is the size of the chosen window for the calculation of the gradient. The size of this window has to be selected according to object size as well as with respect to distances between objects. In our experiments, an algorithm based on the Gauss map provided inconsistent values for simple test objects, whereas our method provides consistent values. We report quantitative results on various test geometries, compare our method to two algorithms working on gray value data and demonstrate the practical applicability of our novel algorithm to CT-reconstructions of Greenlandic firn.
    Repository Name: EPIC Alfred Wegener Institut
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  • 45
    Publication Date: 2017-04-04
    Description: A potential CO2 storage site located offshore the west coast of Italy, has been modelled using PFLOTRAN assuming an injection rate of 1.5 Mtons/year for 20 years. The model predicts a CO2 footprint characterised by a diameter of about 3.5 km and a maximum pressure build up of 38 bars. The solubility trapping has been quantified, predicting a dissolution in brine of 69% and 79% of the total amount of CO2 injected after 1000 and 2000 years respectively. The residual trapping has also been found to play an important role, with 9% and 6% of the injected CO2 being locked into the hosting matrix pores after 1000 and 2000 years respectively. Considering a worst-case scenario for leakages, where zero critical capillarity pressure has been assumed, minor CO2 leakages through the caprock have been identified, caused by the combined effects of the long-term structural trapping and the large and lasting overpressure caused by the CO2 injection in an ideally closed system. Finally, some preliminary work undertaken as part of an ongoing effort to couple a geochemical model to the multi-phase flow simulations reveals i) small changes in mineral volume fraction and porosity during and after the injection (~5% after 1000 years), and ii) a not negligible self-sealing effect due to precipitation of calcite in the lower layer of the caprock. Further investigations and longer physical time runs are needed to confirm this assumption, but also to gain more confidence on the geochemical model built so far and to estimate the mineral trapping potential for this site.
    Description: Published
    Description: 334-343
    Description: 5A. Energia e georisorse
    Description: N/A or not JCR
    Description: restricted
    Keywords: CO2 geological storage modelling ; geochemistry ; PFLOTRAN ; PFLOTRAN case study ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 46
    Publication Date: 2017-04-04
    Description: We present a method to minimize the error of temperature estimate when multiple discrete populations of glass and clinopyroxene occur in a single heterogeneous eruptive unit. As test data we have used ~1100 clinopyroxene–melt pairs from isothermal and thermal gradient experiments. These latter are characterized by the crystallization of multiple modes of clinopyroxene as frequently documented for chemically and thermally zoned magma chambers. Equilibrium clinopyroxene–melt pairs are identified through the difference between predicted and measured components in clinopyroxene. The use of these equilibrium compositions as input data for one of the most recent clinopyroxene-based thermometers demonstrates that the error of temperature estimate is minimized and approaches to the calibration error of the thermometric model. To emphasize the paramount importance of this method for predicting the crystallization temperature of heterogeneousmagmas, we have tested for equilibrium~480 and ~150 clinopyroxene–melt pairs fromthe explosive eruptions of the Sabatini Volcanic District (Latium Region, Central Italy) and the Campi Flegrei Volcanic Field (Campanian Region, Southern Italy), respectively. These eruptions were fed by zoned magma chambers, as indicated by the occurrence ofmultiple modes of clinopyroxene in the eruptive units. Results fromcalculations demonstrate that clinopyroxene–melt pairs in equilibrium at the time of eruption are effectively captured by our method and, consequently, the error of temperature estimate is significantly reduced.
    Description: Published
    Description: 97-103
    Description: 2IT. Laboratori sperimentali e analitici
    Description: JCR Journal
    Description: open
    Keywords: Equilibrium model ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 47
    Publication Date: 2017-04-04
    Description: There have been limited studies to date targeting gaseous elemental mercury (GEM) flux from soil emission in enriched volcanic substrates and its relation with CO2 release and tectonic structures. In order to evaluate and understand the processes of soil–air exchanges involved at Solfatara of Pozzuoli volcano, the most active zone of Campi Flegrei caldera (Italy), an intensive field measurement survey has been achieved in September 2013 by using high-time resolution techniques. Soil–air exchange fluxes of GEM and CO2 have been measured simultaneously at 116 points, widely distributed within the crater. Quantification of gas flux has been assessed by using field accumulation chamber method in conjunction with a Lumex®-RA 915 + portable mercury vapor analyzer and a LICOR for CO2 determination, respectively. The spatial distribution of GEM and CO2 emissions correlated quite closely with the hydrothermal and geological features of the studied area. The highest GEM fluxes (from 4.04 to 5.9 × 10− 5 g m− 2 d− 1) were encountered close to the southern part of the crater interested by an intense fumarolic activity and along the SE–SW tectonic fracture (1.26 × 10− 6–6.91 × 10− 5 g GEM m− 2 d− 1). Conversely, the lowest values have been detected all along the western rim of the crater, characterized by a weak gas flux and a lush vegetation on a very sealed clay soil, which likely inhibited mercury emission (range: 1.5 × 10− 7–7.18 × 10− 6 g GEM m− 2 d− 1). Results indicate that the GEM exchange between soil and air inside the Solfatara crater is about 2–3 orders of magnitude stronger than that in the background areas (10− 8–10− 7 g m− 2 d− 1). CO2 soil diffuse degassing exhibited an analogous spatial pattern to the GEM fluxes, with emission rates ranging from about 15 to ~ 20,000 g CO2 m− 2 d− 1, from the outermost western zones to the south-eastern sector of the crater. The observed significant correlation between GEM and CO2 suggested that in volcanic system GEM volatilizes from substrate in a similar manner to the release of CO2. The quantitative estimation of the total amount of CO2 and GEM released from the Solfatara crater gave values of about 304 ± 13 and 3.7 ± 0.2 × 10− 6 t d− 1, respectively. Finally, based on our dataset and previous work, we propose that an average GEM/CO2 molar ratio of ~ 2 × 10− 8 (n = 9) is best representative of hydrothermal degassing. Taking into account the uncertainty in global hydrothermal CO2 emissions from sub-aerial environments (~ 1012 Mol yr− 1), we infer a global volcanic GEM flux from hydrothermal environments of ~ about 8.5 t yr− 1. Although this value has to be considered as a lower limit for the global emission of GEM from these sources, we suggest that on a local scale hydrothermal activity can be regarded as a significant source of GEM than previously recognized to the atmospheric pool.
    Description: Published
    Description: 26-40
    Description: 4V. Vulcani e ambiente
    Description: JCR Journal
    Description: restricted
    Keywords: Flux Chamber Survey ; Mercury ; CO2 emissions ; Solfatara ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 48
    Publication Date: 2017-04-04
    Description: Geological, geodetic and seismological data have been analyzed in order to frame the Lipari–Vulcano complex (Aeolian archipelago, southern Italy) into the geodynamic context of the southeastern Tyrrhenian Sea. It is located at the northern end of a major NNW–SSE trending right-lateral strike-slip fault system named “Aeolian–Tindari–Letojanni” which has been interpreted as a lithospheric discontinuity extending from the Aeolian Islands to the Ionian coast of Sicily and separating two different tectonic domains: a contractional one to the west and an extensional one to the north-east. Structural field data consist of structural measurements performed on well-exposed fault planes and fractures. The mesostructures are mostly represented by NW–SE striking normal faults with a dextral-oblique component of motion. Minor structures are represented by N–S oriented joints and tension gashes widespread over the whole analyzed area and particularly along fumarolized sectors. The analyzed seismological dataset (from 1994 to 2013) is based on earthquakes with magnitude ranging between 1.0 and 4.8. The hypocenter distribution depicts two major alignments corresponding to the NNW–SSE trending Aeolian–Tindari–Letojanni fault system and to the WNW–ESE oriented Sisifo–Alicudi fault system. GPS data analysis displays ∼3.0 mm/yr of active shortening between the two islands, with a maximum shortening rate of about 1.0 × 10−13 s−1, between La Fossa Caldera and south of Vulcanello. This region is bounded to the north by an area where the maximum values of shear strain rates, of about 0.7 × 10−13 s−1 are observed. This major change occurs in the area south of Vulcanello that is also characterized by a transition in the way of the vertical axis rotation. Moreover, both the islands show a clear subsidence process, as suggested by negative vertical velocities of all GPS stations which exhibit a decrease from about −15 to −7 mm/yr from north to south. New data suggest that the current kinematics of the Lipari–Vulcano complex can be framed in the tectonic context of the eastward migrating Sisifo–Alicudi fault system. This is dominated by transpressive tectonics in which contractional and minor extensional structures can coexist with strike-slip motion.
    Description: Published
    Description: 150-167
    Description: 1T. Geodinamica e interno della Terra
    Description: 2T. Tettonica attiva
    Description: JCR Journal
    Description: restricted
    Keywords: Southern Tyrrhenian sea ; Aeolian Archipelago ; Lipari–Vulcano complex ; Structural analysis ; GPS ; Seismological data ; 04. Solid Earth::04.03. Geodesy::04.03.01. Crustal deformations ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 49
    Publication Date: 2020-02-24
    Description: In June–July 2001 a series of 16 discrete lava fountain paroxysms occurred at the Southeast summit crater (SEC) of Mount Etna, preceding a 28-day long violent flank eruption. Each paroxysm was preceded by lava effusion, growing seismic tremor and a crescendo of Strombolian explosive activity culminating into powerful lava fountaining up to 500m in height. During 8 of these 16 events we could measure the chemical composition of the magmatic gas phase (H2O, CO2, SO2, HCl, HF and CO), using open-path Fourier transform infrared (OP-FTIR) spectrometry at ∼1–2km distance from SEC and absorption spectra of the radiation emitted by hot lava fragments. We show that each fountaining episode was characterized by increasingly CO2-rich gas release, with CO2/SO2and CO2/HCl ratios peaking in coincidence with maxima in seismic tremor and fountain height, whilst the SO2/HCl ratio showed a weak inverse relationship with respect to eruption intensity. Moreover, peak values in both CO2/SO2ratio and seismic tremor amplitude for each paroxysm were found to increase linearly in proportion with the repose interval (2–6 days) between lava fountains. These observations, together with a model of volatile degassing at Etna, support the following driving process. Prior to and during the June–July 2001 lava fountain sequence, the shallow (∼2km) magma reservoir feeding SEC received an increasing influx of deeply derived carbon dioxide, likely promoted by the deep ascent of volatile-rich primitive basalt that produced the subsequent flank eruption. This CO2-rich gas supply led to gas accumulation and overpressure in SEC reservoir, generating a bubble foam layer whose periodical collapse powered the successive fountaining events. The anti-correlation between SO2/HCl and eruption intensity is best explained by enhanced syn-eruptive degassing of chlorine from finer particles produced during more intense magma fragmentation.
    Description: Published
    Description: 123-134
    Description: 3V. Dinamiche e scenari eruttivi
    Description: JCR Journal
    Description: restricted
    Keywords: FTIR remote sensing ; lava fountains ; gas composition ; magma degassing ; separate CO2transfer ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 50
    Publication Date: 2020-02-24
    Description: The time for a first book on Geoethics has come. The faster, greedier pace of society and globalization demands it. The comfortable life of scholars in the ivory tower is coming to a rude awakening. People demand understandable information on geohazards, judges condemn scientist and engineers for lack of communication, indigenous people rise in anger accusing experts of misleading them, attempts to avoid transparency in developments still exist, the helplessness of technology to deal with nuclear waste becomes more evident everyday and nature exposes shortcuts in constructing critical facilities with her own awesome force.....
    Description: Published
    Description: XXI-XXII
    Description: 3T. Pericolosità sismica e contributo alla definizione del rischio
    Description: 4V. Vulcani e ambiente
    Description: 4A. Clima e Oceani
    Description: 5A. Energia e georisorse
    Description: 6A. Monitoraggio ambientale, sicurezza e territorio
    Description: reserved
    Keywords: Geoethics ; Philosophy ; Geosciences ; Geoscientists ; Ethics ; Earth Sciences ; Sustainability ; Research Integrity ; Professional Ethics ; Geoscience communication ; Responsibility ; Stewardship ; Planet ; Earth ; 05. General::05.03. Educational, History of Science, Public Issues::05.03.99. General or miscellaneous ; 05. General::05.08. Risk::05.08.99. General or miscellaneous ; 05. General::05.09. Miscellaneous::05.09.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: book chapter
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  • 51
    Publication Date: 2017-04-04
    Description: Key Features. Written by a global group of contributors with backgrounds ranging from philosopher to geo-practitioner, providing a balance of voices. Includes case studies, showing where experts have gone wrong and where key organizations have ignored facts, wanting assessments favorable to their agendas. Provides a much needed basis for discussion to guide scientists to consider their responsibilities and to improve communication with the public. Description. Edited by two experts in the area, Geoethics: Ethical Challenges and Case Studies in Earth Sciences addresses a range of topics surrounding the concept of ethics in geoscience, making it an important reference for any Earth scientist with a growing concern for sustainable development and social responsibility. This book will provide the reader with some obvious and some hidden information you need for understanding where experts have not served the public, what more could have been done to reach and serve the public and the ethical issues surrounding the Earth Sciences, from a global perspective. Table of contents. Section 1: Introduction Section 2: Philosophical reflections Section 3: The ethics of practice Section 4: Man made hazards Section 5: Natural hazards Section 6: Exploitation of resources Section 7: Low income and indigenous communities Section 8: Geoscience community
    Description: Published
    Description: 3T. Pericolosità sismica e contributo alla definizione del rischio
    Description: 5T. Sorveglianza sismica e operatività post-terremoto
    Description: 4V. Vulcani e ambiente
    Description: 5V. Sorveglianza vulcanica ed emergenze
    Description: 4A. Clima e Oceani
    Description: 6A. Monitoraggio ambientale, sicurezza e territorio
    Description: open
    Keywords: Geoethics ; Philosophy ; Natural hazards ; Man made hazards ; Georesources ; Low income countries ; Geoscience community ; Communication ; Geoeducation ; Natural risks ; 04. Solid Earth::04.06. Seismology::04.06.11. Seismic risk ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.03. Educational, History of Science, Public Issues::05.03.99. General or miscellaneous ; 05. General::05.08. Risk::05.08.99. General or miscellaneous ; 05. General::05.09. Miscellaneous::05.09.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: book
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  • 52
    facet.materialart.
    Unknown
    Elsevier
    Publication Date: 2017-04-04
    Description: This chapter outlines a framework of the issues addressed by geoethics. Starting from an etymological analysis of the word “geoethics,” we identify the cultural basis on which to expand the debate on geoethics, while also proposing for consideration by the scientific community some questions that may guide the development of future research and practice in geosciences. We attempt to define some fundamental points that, in our opinion, will strengthen geoethics and help its development. The goal of geoethics is to suggest practical solutions and provide useful techniques, and also to promote cultural renewal in how humans perceive and relate to the planet, through greater attention to the protection of life and the richness of the Earth, in all its forms. As each science does, geoethics should also be able to present an image of the world, pointing out the manner in which it can be understood, investigated, designed, and experienced.
    Description: Published
    Description: 3-14
    Description: 3T. Pericolosità sismica e contributo alla definizione del rischio
    Description: 4V. Vulcani e ambiente
    Description: 4A. Clima e Oceani
    Description: 5A. Energia e georisorse
    Description: 6A. Monitoraggio ambientale, sicurezza e territorio
    Description: reserved
    Keywords: Etymological analysis ; Geoethics ; Geoscientists oath ; Responsibility ; Society ; 05. General::05.03. Educational, History of Science, Public Issues::05.03.99. General or miscellaneous ; 05. General::05.09. Miscellaneous::05.09.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: book chapter
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  • 53
    facet.materialart.
    Unknown
    Elsevier | Elsevier Science Limited
    Publication Date: 2017-04-04
    Description: Campi Flegrei caldera, within the Neapolitan area of Italy, is potentially one of the most dangerous volcanoes in the world, and during the last decade it has shown clear signs of reactivation, marked by the onset of uplift and changes in the geochemistry of gas emissions. We describe a 30-year-long data set of the CO2–He–Ar–N2 compositions of fumarolic emissions from La Solfatara crater, which is located in the center of the caldera. The data display continuous decreases in both the N2/He and N2/CO2 ratios since 1985, paralleled by an increase in He/CO2. These variations cannot be explained by either processes of boiling/condensation in the local hydrothermal system or with changes in the mixing proportions between a magmatic vapor and hydrothermal fluids. We applied the magma degassing model of Nuccio and Paonita (2001, Earth Planet. Sci. Lett. 193, 467–481) using the most recent inert-gas solubilities in order to interpret these peculiar features in accordance with petrologic constraints derived from the ranges of the melt compositions and reservoir pressures at Campi Flegrei. The model simulations for mafic melts (trachybasalt and shoshonite) show a remarkably good agreement with the measured data. Both decompressive degassing of an ascending magma and mixing between magmatic fluids exsolved at various levels along the ascent path can explain the long-term geochemical changes. Recalling that (i) a sill-like reservoir of gases at a depth of 3–4 km seems to be the main source of ground inflation and (ii) there is petrologic and geophysical evidence for a reservoir of magma at about 8 km below Campi Flegrei, we suggest that the most-intense episodes of inflation occur when the gas supply to the sill-like reservoir comes from the 8 km-deep magma, although fluids exsolved by magma bodies at shallower depths also contribute to the gas budget. Our work highlights that, in caldera systems where the presence of hydrothermal aquifers commonly masks the magmatic signature of reactive volatiles, inert gases are the preferred species to use when seeking information on the melt composition, dynamics, and structure of the plumbing systems.
    Description: Published
    Description: 1-15
    Description: 2V. Dinamiche di unrest e scenari pre-eruttivi
    Description: JCR Journal
    Description: restricted
    Keywords: Geochemical Evidences ; Magmas ; Campi Flegrei caldera ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 54
    Publication Date: 2017-04-04
    Description: The present study is focused on the emergence of dynamical complexity in the Earth's magnetospheric dynamics during magnetic storms as monitored by SYM-H index. A long time series of SYM-H index covering the period from January 2000 to December 2004 is analyzed using a quite novel technique, the permutation entropy analysis. We show that the normalized permutation entropy values of the SYM-H time series decrease during geomagnetic disturbed periods revealing a gradual increase in the temporal correlation of the fluctuations which generates a gradual increase in the complexity degree of the magnetosphere response to the solar wind magnetic field and plasma parameter changes. These large changes in the normalized permutation entropy values and complexity degree observed during the disturbed periods can be interpreted as the signature of dynamical phase transitions happening in proximity to the occurrence of geomagnetic storms and substorms confirming results previously found using different methods. The dependence of the degree of complexity on both the magnitude of the geomagnetic disturbance and the IMF ByGSM and BzGSM components is investigated and discussed.
    Description: Published
    Description: 25-31
    Description: 1A. Geomagnetismo e Paleomagnetismo
    Description: JCR Journal
    Description: restricted
    Keywords: Geomagnetic storms ; Permutation entropy ; Complexity ; 05. General::05.07. Space and Planetary sciences::05.07.01. Solar-terrestrial interaction
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 55
    Publication Date: 2017-04-04
    Description: Detailed surveys of diffuse CO2 flux, soil temperature, thermal gradients, and sampling of high-T fumaroles were carried out in the Favare area and Lake Specchio di Venere on Pantelleria Island. Spatial patterns of diffuse CO2 emissions in the Favare area reflect structural discontinuities (faults, fractures or cracks in the soil) associated with the volcano-tectonic structures of the young Monastero Caldera (NNE–SSW to NE–SW trending). The estimated diffuse CO2 output from two adjacent sites in the Favare area (~ 93,000 m2) is 7.8 t d− 1 (equivalent to 2.62 kt a− 1), whereas that from the west shore of the lake (450 m2) is 0.041 t d− 1 (or 0.015 kt a− 1). The extrapolation of diffuse CO2 fluxes across the entire altered area of Favare suggests that CO2 emissions are ~ 19.3 t d− 1. The diffuse CO2 flux correlates with shallow soil temperatures, indicating a similar source for both the heat and volatiles from the underlying geothermal reservoir. Gas equilibria applied to fumarolic effluents define P–T conditions for this reservoir at 2–6 bar and 120–160 °C, in good agreement with measurements from exploratory wells in these areas (e.g., 135 °C at a depth of 290 m). Using the CO2 flux as a tracer for steam output, and consequently for heat flow, the calculated thermal energy for the shallow reservoir is 10–12 MW; this represents the minimum geothermal potential of the reservoir on Pantelleria island.
    Description: Published
    Description: 22-33
    Description: 4V. Vulcani e ambiente
    Description: JCR Journal
    Description: restricted
    Keywords: CO2 soil degassing; ; Geothermal potential; ; Geothermal aquifers; ; Pantelleria Island ; 04. Solid Earth::04.08. Volcanology::04.08.04. Thermodynamics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 56
    Publication Date: 2017-09-11
    Description: Telica volcano, in north-west Nicaragua, is a young stratovolcano of intermediate magma composition producing frequent Vulcanian to phreatic explosive eruptions. The Telica stratigraphic record also includes examples of (pre)historic sub-Plinian activity. To refine our knowledge of this very active volcano, weanalyzedmajor element composition and volatile content of melt inclusions fromsomestratigraphically significant Telica tephra deposits. These include: (1) the Scoria Telica Superior (STS) deposit (2000 to 200 years Before Present; Volcanic Explosive Index, VEI, of 2–3) and (2) pyroclasts from the post-1970s eruptive cycle (1982; 2011). Based on measurements with nanoscale secondary ion mass spectrometry, olivine-hosted (forsterite [Fo] N 80) glass inclusions fall into 2 distinct clusters: a group of H2O-rich (1.8–5.2 wt%) inclusions, similar to those of nearby Cerro Negro volcano, and a second group of CO2-rich (360–1700 μg/g CO2) inclusions (Nejapa, Granada). Model calculations show that CO2 dominates the equilibrium magmatic vapor phase in the majority of the primitive inclusions (XCO2 N 0.62–0.95). CO2, sulfur (generally b2000 μg/g) and H2O are lost to the vapor phase during deep decompression (P N 400 MPa) and early crystallization of magmas. Chlorine exhibits a wide concentration range (400–2300 μg/g) in primitive olivine-entrapped melts (likely suggesting variable source heterogeneity) and is typically enriched in the most differentiated melts (1000–3000 μg/g). Primitive, volatile-rich olivine-hosted melt inclusions (entrapment pressures, 5–15 km depth) are exclusively found in the largest-scale Telica eruptions (exemplified by STS in our study). These eruptions are thus tentatively explained as due to injection of deep CO2-rich mafic magma into the shallow crustal plumbing system. More recent (post-1970), milder (VEI 1–2) eruptions, instead, do only exhibit evidence for low-pressure (P b 50–60 MPa), volatile-poor (H2O b 0.3–1.7 wt%; CO2 b 23–308 μg/g) magmatic conditions. These are manifested as andesitic magmas, recording multiple magma mixing events, in pyroxene inclusions.Wepropose that post-1970s eruptions are possibly related to the high viscosity of resident magma in shallow plumbing system (b2.4 km), due to crystallization and degassing
    Description: Published
    Description: 131-148
    Description: 1V. Storia eruttiva
    Description: JCR Journal
    Keywords: Telica, Nicaragua ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 57
    Publication Date: 2017-09-11
    Description: characterization of ultra-calcic arc melts, equilibrium phase relations have been determined experimentally for the La Sommata basalt (Som-1, Vulcano, Aeolian arc). Som-1 (Na2O + K2O = 4.46 wt.%, CaO = 12.97 wt.%, MgO = 8.78 wt.%, CaO/Al2O3 = 1.03) is a reference primitive ne-normative arc basalt with a strong ultra-calcic affinity. The experiments have been performed between 44 and 154 MPa, 1050 and 1150 °C and from NNO + 0.2 to NNO + 1.9. Fluid-present conditions were imposed with H2O–CO2 mixtures yielding melt H2O concentrations from0.7 to 3.5wt.%. Phases encountered include clinopyroxene, olivine, plagioclase and Fe-oxide. Clinopyroxene is slightly earlier than olivine in the crystallization sequence. It is the liquidus phase at 150 MPa, being joined by olivine on the liquidus between 44 and 88MPa. Plagioclase is the third phase to appear in the crystallization sequence and orthopyroxene was not found. Experimental clinopyroxenes (Fs7–16) and olivines (Fo78–92) partially reproduce the natural phenocryst compositions (respectively Fs5–7 and Fo87–91). Upon progressive crystallization, experimental liquids shift towards higher SiO2 (up to ~55 wt.%), Al2O3 (up to ~18 wt.%) and K2O (up to ~5.5wt.%) and lower CaO,MgO and CaO/Al2O3. Experimental glasses and natural whole-rock compositions overlap, indicating that progressive crystallization of Som-1 type melts can generate differentiated compositions such as those encountered at Vulcano. The lowpressure cotectic experimental glasses reproduce glass inclusions in La Sommata clinopyroxene but contrast with glass inclusions in olivine which preserve basaltic melts more primitive than Som-1. Phase relations for the La Sommata basalt are identical in all critical aspects to those obtained previously on a synthetic ultra-calcic arc composition. In particular, clinopyroxene+olivine co-saturation occurs at very low pressures (≤100 MPa). Ultra-calcic arc compositions do not represent primary mantle melts but result from the interaction between a primary mantle melt and clinopyroxene-bearing rocks in the arc crust. At Vulcano, primitive ultra-calcic end-member melts were generated between 250 and 350 MPa in the lower magma accumulation zone by reaction between hot primitive melts and wehrlitic or gabbroic lithologies. At Stromboli, golden pumices and glass inclusions with an ultra-calcic affinity were also generated at shallow pressures, between 150 and 250 MPa, suggesting that the interaction model is of general significance in the Aeolian arc.
    Description: Published
    Description: 85-101
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: JCR Journal
    Keywords: Primitive arc magmas, Ultra-calcic Experiments, Phase equilibria, Vulcano, Aeolian arc ; Petrology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 58
    Publication Date: 2017-12-13
    Description: This study focuses on the interaction among deep volcanic/hydrothermal gases, groundwater and soil gases at Vulcano Island (Aeolian Archipelago, Italy). The chemical-physical parameters of the groundwater, the total dissolved inorganic carbon (TDIC) and the isotopic composition of the CO2 dissolved in groundwater are reported and discussed. Furthermore, a comparison between soil gases and groundwater indicates that groundwater and soil gases show the same qualitative information, giving a good overall picture of the main degassing zones of a volcanic system, whereas the soil gas discharge provides an evaluation of the mass released by the deep feeding system. This approach can be a useful tool both to characterize mixing and/or interaction processes among different sources and for a monitoring of degassing activity of a volcanic system.
    Description: Published
    Description: 116-119
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: 4V. Dinamica dei processi pre-eruttivi
    Description: N/A or not JCR
    Keywords: Soil CO2 flux ; Dissolved gases ; Isotope composition of CO2 ; Groundwaters ; Vulcano Island ; 03.02. Hydrology ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 59
    Publication Date: 2020-02-24
    Description: We formulate a mathematical model for a geothermal basin with an idealized geometry characterized by: (1) radial symmetry around an extracting well (or a cluster of wells), (2) a relatively thin horizontal fractured layer lying underneath a low permeability, low porosity rock layer, saturated with water. Vaporization is allowed only at the boundary of the extracting well (or well cluster). The model is based on the assumption that the flow from the reservoir to the well is fed by a gravity driven flow through the overstanding rocks. Despite the various simplifying assumptions, the resulting mathematical problem is considerably difficult also because we consider the effect of thermal expansion and thermal variation of viscosity. Though there is no evidence that the assumed configuration of the basin approaches the structure of a known geothermal field, the results obtained match with surprising accuracy the data of a specific field in the Mt. Amiata area (data kindly provided by ENEL Green Power through Tuscany Region).
    Description: Published
    Description: 37-54
    Description: 5A. Energia e georisorse
    Description: 6A. Monitoraggio ambientale, sicurezza e territorio
    Description: 7A. Geofisica di esplorazione
    Description: 3IT. Calcolo scientifico e sistemi informatici
    Description: JCR Journal
    Description: restricted
    Keywords: Geothermal reservoirs ; Porous media ; Permeability estimation ; Fractured media ; 01. Atmosphere::01.02. Ionosphere::01.02.01. Ion chemistry and composition ; 03. Hydrosphere::03.02. Hydrology::03.02.02. Hydrological processes: interaction, transport, dynamics ; 03. Hydrosphere::03.02. Hydrology::03.02.05. Models and Forecasts ; 05. General::05.01. Computational geophysics::05.01.03. Inverse methods ; 05. General::05.01. Computational geophysics::05.01.04. Statistical analysis ; 05. General::05.05. Mathematical geophysics::05.05.99. General or miscellaneous
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  • 60
    Publication Date: 2020-02-24
    Description: Serpentinization of ultramafic rocks is considered a major process of production of abiotic methane (CH4) and hydrogen (H2) on Earth, and it may be responsible for CH4 occurrence on other planets. While serpentinization and CH4 synthesis have been widely studied and modeled in high temperature hydrothermal conditions, such as on submarine mid-ocean ridges, the increasing number of discoveries of abiotic CH4 in ophiolites on continents shows the importance of present-day (meteoric water driven) serpentinization in low temperature (〈100 °C) gas synthesis. As a new case, we report compositional, isotopic, and flux data of gas dissolved in hyperalkaline Ca-OH waters issuing from serpentinized peridotites at Genova (Italy). CH4 is dominantly abiotic (δ13C: -9 ‰ VPDB; δ2H: -168 to - 225 ‰ VSMOW), similar to that released by ophiolites in Oman, Turkey, the Philippines, and by the submarine Lost City serpentinization system. While the absence of CO2 was expected in this kind of fluids, the absence of H2 is unusual. This could be due to hydration of olivine and pyroxene by CO2-rich fluids, eventually associated with high silica activity, which inhibits H2 formation and produces CH4 directly. Thermodynamic modeling and H2O-CH4 isotope equilibrium confirm the low temperatures (〈60°C) of the serpentinization system, and thus the abiotic methane synthesis.
    Description: Published
    Description: 248-251
    Description: 7A. Geofisica di esplorazione
    Description: N/A or not JCR
    Description: restricted
    Keywords: methane, ophiolites, serpentinization ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 61
    Publication Date: 2020-05-29
    Description: The structural integrity of pipelines undergone seismic waves is crucial for industrial installation and for the distributed transportation networks of gaseous and liquid fluids. However, it is nowadays proved that the definition of seismic vulnerability based on purely, structural-derived limit states or on return-to-service or even on the purely economic repair rate indications, is not sufficient for the holistic analysis of risks. On the other hand, detailed numerical studies based on full analyses (including fluid/soil/structure interaction) are too expensive for the aims of risk assessment and simplified methodologies are still needed.In this paper, a large database of earthquake-induced damage for steel and non-steel pipelines is presented. Each case was analyzed and collected from post-earthquake reconnaissance, seismic engineering reports and technical papers. The database may be adopted for the definition of specific vulnerability function (fragility curves), which are commonly implemented in multi-hazard analyses, and more in general for the assessment of Na-Tech risks (Natural events triggering Technological disasters). Seismic damage to pipelines in the framework of Na-Tech risk assessment. Available from: https://www.researchgate.net/publication/271673585_Seismic_damage_to_pipelines_in_the_framework_of_Na-Tech_risk_assessment [accessed Jun 12, 2015].
    Description: Published
    Description: 159-162
    Description: 3T. Pericolosità sismica e contributo alla definizione del rischio
    Description: JCR Journal
    Description: restricted
    Keywords: Earthquake ; Na-Tech ; Ground failure ; Lifeline ; Fragility curve ; Pipelines ; 04. Solid Earth::04.06. Seismology::04.06.11. Seismic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 62
    Publication Date: 2017-02-02
    Repository Name: EPIC Alfred Wegener Institut
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  • 63
    Publication Date: 2015-12-01
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev , info:eu-repo/semantics/article
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  • 64
    Publication Date: 2019-07-17
    Description: Reactive iron (oxyhydr)oxide minerals preferentially undergo early diagenetic redox cycling which can result in the production of dissolved Fe(II), the adsorption of Fe(II) onto particle surfaces, and the formation of authigenic Fe minerals. The partitioning of iron in sediments has traditionally been studied by applying sequential extractions that target operationally-defined iron phases. Here, we complement an existing sequential leaching method by developing a sample processing protocol for δ56Fe analysis, which we subsequently use to study Fe phase-specific fractionation related to dissimilatory iron reduction in a modern marine sediment. Carbonate-Fe was extracted by acetate, easily reducible oxides (e.g. ferrihydrite and lepidocrocite) by hydroxylamine–HCl, reducible oxides (e.g. goethite and hematite) by dithionite–citrate, and magnetite by ammonium oxalate. Subsequently, the samples were repeatedly oxidized, heated and purified via Fe precipitation and column chromatography. The method was applied to surface sediments collected from the North Sea, south of the island of Helgoland. The acetate-soluble fraction (targeting siderite and ankerite) showed a pronounced downcore δ56Fe trend. This iron pool was most depleted in 56Fe close to the sediment–water interface, similar to trends observed for pore-water Fe(II). We interpret this pool as surface-reduced Fe(II), rather than siderite or ankerite, that was open to electron and atom exchange with the oxide surface. Common extractions using 0.5 M HCl or Na-dithionite alone may not resolve such trends, as they dissolve iron from isotopically distinct pools leading to a mixed signal. Na-dithionite leaching alone, for example, targets the sum of reducible Fe oxides that potentially differ in their isotopic fingerprint. Hence, the development of a sequential extraction Fe isotope protocol provides a new opportunity for detailed study of the behavior of iron in a wide range of environmental settings.
    Repository Name: EPIC Alfred Wegener Institut
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  • 65
    Publication Date: 2016-02-12
    Description: The focus of this research has been on detecting changes in lake areas, vegetation, land surface temperatures, and the area covered by snow, using data from remote sensing. The study area covers the main (central) part of the Lena River catchment in the Yakutia region of Siberia (Russia), extending from east of Yakutsk to the central Siberian Plateau, and from the southern Lena River to north of the Vilyui River. Approximately 90% of the area is underlain by continuous permafrost. Remote sensing products were used to analyze changes in water bodies, land surface temperature (LST), and leaf area index (LAI), as well as the occurrence and extent of forest fires, and the area and duration of snow cover. The remote sensing analyses (for LST, snow cover, LAI, and fire) were based on MODIS–derived NASA products (250–1000 m) for 2000 to 2011. Changes in water bodies were calculated from two mosaics of (USGS) Landsat (30 m) satellite images from 2002 and 2009. Within the study area's 315,000 km2 the total area covered by lakes increased by 17.9% between 2002 and 2009, but this increase varied in different parts of the study area, ranging between 11% and 42%. The land surface temperatures showed a consistent warming trend, with an average increase of about 0.12 °C/year. The average rate of warming during the April–May transition period was 0.17 °C/year and 0.19 °C/year in the September–October period, but ranged up to 0.49 °C/year during September–October. Regional differences in the rates of land surface temperature change, and possible reasons for the temperature changes, are discussed with respect to changes in the land cover. Our analysis of a broad spectrum of variables over the study area suggests that the spring warming trend is very likely to be due to changes in the area covered by snow. The warming trend observed in fall does not, however, appear to be directly related to any changes in the area of snow cover, or to the atmospheric conditions, or to the proportion of the land surface that is covered by water (i.e., to wetting and drying). Supplementary data (original data, digitized version of the maps, metadata) are archived under PANGAEA (http://dx.doi.org/10.1594/PANGAEA.855124).
    Repository Name: EPIC Alfred Wegener Institut
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  • 66
    Publication Date: 2016-06-23
    Description: The Southern Ocean (SO) is a major sink for anthropogenic atmospheric carbon dioxide (CO2), potentially harbouring even greater potential for additional sequestration of CO2 through enhanced phytoplankton productivity. In the SO, primary productivity is primarily driven by bottom up processes (physical and chemical conditions) which are spatially and temporally heterogeneous. Due to a paucity of trace metals (such as iron) and high variability in light, much of the SO is characterised by an ecological paradox of high macronutrient concentrations yet uncharacteristically low chlorophyll concentrations. It is expected that with increased anthropogenic CO2 emissions and the coincident warming, the major physical and chemical process that govern the SO will alter, influencing the biological capacity and functioning of the ecosystem. This review focuses on the SO primary producers and the bottom up processes that underpin their health and productivity. It looks at the major physico-chemical drivers of change in the SO, and based on current physiological knowledge, explores how these changes will likely manifest in phytoplankton, specifically, what are the physiological changes and floristic shifts that are likely to ensue and how this may translate into changes in the carbon sink capacity, net primary productivity and functionality of the SO.
    Repository Name: EPIC Alfred Wegener Institut
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  • 67
    Publication Date: 2018-02-16
    Description: We analyze inter-annual changes of marine observations at Helgoland Roads (nitrate, phosphate, salinity, Secchi depth) in relation to hydro-climatic conditions and Elbe River discharge as potential drivers. Focusing on mean spring conditions we explore graphical covariance selection modeling as a means to both identify and represent the structure of parameter interactions. While river discharge is able to modify spatial distributions and related gradients in the station's vicinity, atmospherically forced regional transport patterns govern the time dependent local conditions the station is actually exposed to. A model consistent with the data confirms the interplay of the two forcing factors for observations at station Helgoland Roads. Introducing water temperature as a third predictor of inter-annual variability does not much improve the model. Comparing a Helgoland Roads dependence graph with corresponding graphs for other stations or related model simulations, for instance, could help identify differences in underlying mechanisms without referring to specific realizations of external forcing. With regard to prediction, supplementary numerical experiments reveal that imposing constraints on parameter interactions can reduce the chance of fitting regression models to noise.
    Repository Name: EPIC Alfred Wegener Institut
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  • 68
    Publication Date: 2017-10-17
    Description: A new airborne remote sensing approach to estimate an upper limit of the direct sea-air methane emission flux was applied over the 22/4b blowout site located at N57.92°, E1.63° in the North Sea. Passive remote sensing data using sunglint/sunglitter geometry were collected during instrumental tests with the Methane Airborne MAPper \u2013 MAMAP \u2013 instrument installed aboard the Alfred Wegener Institute (AWI) Polar-5 aircraft on 3. June 2011. MAMAP is a passive short wave infrared (SWIR) remote sensing spectrometer for airborne measurements and retrieval of the atmospheric column-averaged dry air mole fractions of methane (XCH4) and carbon dioxide (XCO2). In addition to MAMAP a fast CH4 in-situ analyzer (Los-Gatos Research Inc. RMT-200), two 5-hole turbulence probes and the Polar-5 basic sensor suite comprising different temperature, pressure, humidity and camera sensors were installed aboard the aircraft. The collected MAMAP remote sensing data acquired in the vicinity of the 22/4b blowout site showed no detectable increase in the derived XCH4 (with respect to the atmospheric background). Based on the absence of a detectable XCH4 column increase, an approximate top-down upper-limit for the direct atmospheric 22/4b blowout CH4 emissions from the main bubble plume of less than 10 ktCH4/yr has been derived. The constraint has been determined by comparing XCH4 information derived by the remote sensing measurements with results obtained from a Gaussian plume forward model simulation taking into account the actual flight track, the instrument sensitivity and measurement geometry, as well as the prevailing atmospheric conditions.
    Repository Name: EPIC Alfred Wegener Institut
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  • 69
    Publication Date: 2016-04-15
    Description: In this study, we describe a de novo sequencing and assembly of the spleen transcriptome of Lepidonotothen nudifrons, a notothenioid fish widely distributed around the Antarctic Peninsula and the Scotia Arc. Sequences were generated on an Illumina MiSeq system and assembled to a total of 112,477 transcripts. Putative functional annotation was possible for more than 34% of the transcripts. This data will be relevant for future studies targeting the erythrocyte turnover, oxygen transport mechanism and immune system, which are key functional traits to investigate cold adaptation and thermal sensitivity of Antarctic notothenioids.
    Repository Name: EPIC Alfred Wegener Institut
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  • 70
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    Unknown
    Elsevier
    In:  EPIC3Chemical Geology, Elsevier, 392, pp. 32-42, ISSN: 0009-2541
    Publication Date: 2014-12-03
    Description: In this study we introduce a new in situ technique which allows the determination of the boron isotopic composition and B/Ca ratios simultaneously at the nanogram level using a combination of optical emission spectroscopy and multiple ion counting MC ICP-MS with laser ablation. This technique offers a new application in the paleo-field of oceanography and climatology since small samples like e.g. single foraminiferal shells can be analyzed. The simultaneous determination of the boron isotopic composition and B/Ca ratios provides two independent proxies which allow the reconstruction of the full carbonate system. To test the new technique we performed measurements on the cultured, benthic foraminifer Amphistegina lessonii. Our results yielded an average boron isotopic composition δ11B = 18.0 ± 0.83‰ (SD) with an average internal precision of 0.52‰ (RSE). The boron concentration was 53 ± 7 μg/g (SD). These results agree with the range reported in the literature. The reconstructed mean pH value is in excellent agreement with the measured pH of the seawater in which the foraminifers grew. The analysis of a foraminifer consumed approximately 1200 ng calcium carbonate containing ca. 0.06 ng boron. Compared to bulk analytical methods, this new technique requires less material and reduces the time for sample preparation.
    Repository Name: EPIC Alfred Wegener Institut
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  • 71
    Publication Date: 2015-01-30
    Description: Particles determine the residence time of many dissolved elements in seawater. Although a substantial number of field studies were conducted in the framework of major oceanographic programs as GEOSECS and JGOFS, knowledge about particle dynamics is still scarce. Moreover, the particulate trace metal behavior remains largely unknown. The GEOSECS sampling strategy during the 1970s focused on large sections across oceanic basins, where particles were collected by membrane filtration after Niskin bottle sampling, biasing the sampling toward the small particle pool. Late in this period, the first in situ pumps allowing large volume sampling were also developed. During the 1990s, JGOFS focused on the quantifi- cation of the ‘‘exported carbon flux’’ and its seasonal variability in representative biogeochemical prov- inces of the ocean, mostly using sediment trap deployments. Although scarce and discrete in time and space, these pioneering studies allowed an understanding of the basic fate of marine particles. This understanding improved considerably, especially when the analysis of oceanic tracers such as natural radionuclides allowed the first quantification of processes such as dissolved-particle exchange and par- ticle settling velocities. Because the GEOTRACES program emphasizes the importance of collecting, char- acterizing and analyzing marine particles, this paper reflects our present understanding of the sources, fate and sinks of oceanic particles at the early stages of the program.
    Repository Name: EPIC Alfred Wegener Institut
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  • 72
    Publication Date: 2015-10-12
    Description: The comparative analysis of marine litter in different marine compartments has rarely been attempted. In this study, long-term time series of marine litter abundance on the seafloor and on the coast, both from the southeastern North Sea, were analyzed for temporal trends and correlations. On four beach sections of 100 m length, mean abundances of total beach litter collected four times a year from 2002 to 2008 varied between 105 and 435 items. Mean densities of total inorganic litter on the seafloor amounted to 10.6 ± 9.7 kg km−2 in the offshore region (2001–2010) and 13.7 ± 12.6 kg km−2 in the Wadden Sea (1998–2007), respectively. In the offshore region, there was no significant long-term trend, while in the Wadden Sea, densities of marine litter declined significantly. Correlations between time series were weak, indicating different sources and transport processes responsible for compositions of beach litter and litter on the seafloor. Decreases in inputs from fisheries and substantial export due to resuspension are discussed as reasons for the decrease in litter on the seafloor in the Wadden Sea.
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  • 73
    Publication Date: 2015-04-21
    Repository Name: EPIC Alfred Wegener Institut
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  • 74
    Publication Date: 2017-06-02
    Description: Ecological systems depend on both constraints and historical contingencies, both of which shape their present observable system state. In contrast to ahistorical systems, which are governed solely by constraints (i.e. laws), historical systems and their dynamics can be understood only if properly described, in the course of time. Describing these dynamics and understanding long-term variability can be seen as the mission of long time series measuring not only simple abiotic features but also complex biological variables, such as species diversity and abundances, allowing deep insights in the functioning of food webs and ecosystems in general. Long time-series are irreplaceable for understanding change, and cruicially inherent system variability and thus envisaging future scenarios. This nonewithstanding, current policies in funding and evaluating scientific research discourage the maintenance of long termseries, despite a clear need for long-term strategies to cope with climate change. Timeseries are cruicial for a pursuit of the much invoked Ecosystem Approach and to the passage from simple monitoring programmes large-scale and long-term Earth observatories – thus promoting a better understanding of the causes and effects of change in ecosystems. The few ongoing long timeseries in European waters must be integrated and networked so as to facilitate the formation of nodes of a series of observatories which, together, should allow the long-term management of the features and characteristics of European waters. Human capacity building in this region of expertise and a stronger societal involvement are also urgently needed, since the expertise in recognizing and describing species and therefore recording them reliably in the context of timeseries is rapidly vanishing from the European Scientific community.
    Repository Name: EPIC Alfred Wegener Institut
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  • 75
    facet.materialart.
    Unknown
    Elsevier
    In:  EPIC3Journal of Plant Physiology, Elsevier, 173, pp. 41-50, ISSN: 01761617
    Publication Date: 2017-06-05
    Description: The combined effects of ocean acidification and ultraviolet radiation (UVR) have been studied in the kelps Alaria esculenta and Saccharina latissima from Kongsfjorden (Svalbard), two major components of the Arctic macroalgal community, in order to assess their potential to thrive in a changing environment. Overall results revealed synergistic effects, however with a different amplitude in the respective species. Changes in growth, internal N, C:N ratio, pigments, optimum quantum yield (Fv/Fm) and electron transport rates (ETR) following CO2 enrichment and/or UVR were generally more pronounced in S. latissima than in A. esculenta. The highest growth rates were recorded under simultaneous CO2 enrichment and UVR in both species. UVR-mediated changes in pigment content were partially prevented under elevated CO2 in both species. Similarly, UVR led to increased photosynthetic efficiency (α) and ETR only if CO2 was not elevated in A. esculenta and even under high CO2 in S. latissima. Increased CO2 did not inhibit external carbonic anhydrase (eCA) activity in the short-term but in the mid-term, indicating a control through acclimation of photosynthesis rather than a direct inhibition of eCA by CO2. The higher benefit of simultaneous CO2 enrichment and UVR for S. latissima respect to A. esculenta seems to involve higher C and N assimilation efficiency, as well as higher ETR, despite a more sensitive Fv/Fm. The differential responses shown by these two species indicate that ongoing ocean acidification and UVR could potentially change the dominance at lower depths (4–6 m), which will eventually drive changes at the community level in the Arctic coastal ecosystem. These results support an existing consideration of S. latissima as a winner species in the global change scenario.
    Repository Name: EPIC Alfred Wegener Institut
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  • 76
    Publication Date: 2014-12-09
    Description: Steinthorsdottir et al. (2014) used a previously published stomata-based CO2 record (Steinthorsdottir et al., 2013) to argue for a large, abrupt change in atmospheric carbon dioxide at the onset of the Younger Dryas (YD) cold interval. Their record implies a 50 ppm CO2 rise followed by a decline by 100 ppm. They compare their results to a hypothetical and highly unlikely simulation sce- nario in which vertical mixing in the ocean is increased by a factor of 100 and wind strength by a factor of 7. They furthermore compare their stomata-based CO2 record with the ice core CO2 re- cord derived from EPICA Dome C (EDC). We here question their interpretation.
    Repository Name: EPIC Alfred Wegener Institut
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  • 77
    Publication Date: 2017-06-14
    Description: We compare and contrast the ecological impacts of atmospheric and oceanic circulation patterns on polar and sub-polar marine ecosystems. Circulation patterns differ strikingly between the north and south. Meridional circulation in the north provides connections between the sub-Arctic and Arctic despite the presence of encircling continental landmasses, whereas annular circulation patterns in the south tend to isolate Antarctic surface waters from those in the north. These differences influence fundamental aspects of the polar ecosystems from the amount, thickness and duration of sea ice, to the types of organisms, and the ecology of zooplankton, fish, seabirds and marine mammals. Meridional flows in both the North Pacific and the North Atlantic oceans transport heat, nutrients, and plankton northward into the Chukchi Sea, the Barents Sea, and the seas off the west coast of Greenland. In the North Atlantic, the advected heat warms the waters of the southern Barents Sea and, with advected nutrients and plankton, supports immense biomasses of fish, seabirds and marine mammals. On the Pacific side of the Arctic, cold waters flowing northward across the northern Bering and Chukchi seas during winter and spring limit the ability of boreal fish species to take advantage of high seasonal production there. Southward flow of cold Arctic waters into sub-Arctic regions of the North Atlantic occurs mainly through Fram Strait with less through the Barents Sea and the Canadian Archipelago. In the Pacific, the transport of Arctic waters and plankton southward through Bering Strait is minimal. In the Southern Ocean, the Antarctic Circumpolar Current and its associated fronts are barriers to the southward dispersal of plankton and pelagic fishes from sub-Antarctic waters, with the consequent evolution of Antarctic zooplankton and fish species largely occurring in isolation from those to the north. The Antarctic Circumpolar Current also disperses biota throughout the Southern Ocean, and as a result, the biota tends to be similar within a given broad latitudinal band. South of the Southern Boundary of the ACC, there is a large-scale divergence that brings nutrient-rich water to the surface. This divergence, along with more localized upwelling regions and deep vertical convection in winter, generates elevated nutrient levels throughout the Antarctic at the end of austral winter. However, such elevated nutrient levels do not support elevated phytoplankton productivity through the entire Southern Ocean, as iron concentrations are rapidly removed to limiting levels by spring blooms in deep waters. However, coastal regions, with the upward mixing of iron, maintain greatly enhanced rates of production, especially in coastal polynyas. In these coastal areas, elevated primary production supports large biomasses of zooplankton, fish, seabirds, and mammals. As climate warming affects these advective processes and their heat content, there will likely be major changes in the distribution and abundance of polar biota, in particular the biota dependent on sea ice.
    Repository Name: EPIC Alfred Wegener Institut
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  • 78
    Publication Date: 2015-09-28
    Description: Abstract The northern Antarctic Peninsula is one of the fastest changing regions on Earth. The disintegration of the Larsen-A Ice Shelf in 1995 caused tributary glaciers to adjust by speeding up, surface lowering, and overall increased ice-mass discharge. In this study, we investigate the temporal variation of these changes at the Dinsmoor–Bombardier–Edgeworth glacier system by analyzing dense time series from various spaceborne and airborne Earth observation missions. Precollapse ice shelf conditions and subsequent adjustments through 2014 were covered. Our results show a response of the glacier system some months after the breakup, reaching maximum surface velocities at the glacier front of up to 8.8 m/d in 1999 and a subsequent decrease to ∼1.5 m/d in 2014. Using a dense time series of interferometrically derived TanDEM-X digital elevation models and photogrammetric data, an exponential function was fitted for the decrease in surface elevation. Elevation changes in areas below 1000 m a.s.l. amounted to at least 130 ± 15 m between 1995 and 2014, with change rates of ∼3.15 m/a between 2003 and 2008. Current change rates (2010–2014) are in the range of 1.7 m/a. Mass imbalances were computed with different scenarios of boundary conditions. The most plausible results amount to − 40.7 ± 3.9 Gt . The contribution to sea level rise was estimated to be 18.8 ± 1.8 Gt , corresponding to a 0.052 ± 0.005 mm sea level equivalent, for the period 1995–2014. Our analysis and scenario considerations revealed that major uncertainties still exist due to insufficiently accurate ice-thickness information. The second largest uncertainty in the computations was the glacier surface mass balance, which is still poorly known. Our time series analysis facilitates an improved comparison with {GRACE} data and as input to modeling of glacio-isostatic uplift in this region. The study contributed to a better understanding of how glacier systems adjust to ice shelf disintegration.
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  • 79
    Publication Date: 2020-02-17
    Description: The accelerated warming of the Arctic climate may alter the local and regional surface energy balances, for which changing land surface temperatures (LSTs) are a key indicator. Modeling current and anticipated changes in the surface energy balance requires an understanding of the spatio-temporal interactions between LSTs and land cover, both of which can be monitored globally by measurements from space. This paper investigates the accuracy of the MODIS LST/Emissivity Daily L3 Global 1 km V005 product and its spatio-temporal sensitivity to land surface properties in a Canadian High Arctic permafrost landscape. The land cover ranged from fully vegetated wet sedge tundra to barren rock. MODIS LSTs were compared with in situ radiometer measurements from wet tundra areas collected over a 2-year period from July 2008 to July 2010 including both summer and winter conditions. The accuracy of the MODIS LSTs was − 1.1 °C with a root mean square error of 3.9 °C over the entire observation period. Agreement was lowest during the freeze-back periods where MODIS LST showed a cold bias likely due to the overrepresentation of clear-sky conditions. A multi-year analysis of LST spatial anomalies, i.e., the difference between MODIS LSTs and the MODIS LST regional mean, revealed a robust spatio-temporal pattern. Highest variability in LST anomalies was found during freeze-up and thaw periods as well as for open water surface in early summer due to the presence or absence of snow or ice. The summer anomaly pattern was similar for all three years despite strong differences in precipitation, air temperature and net radiation. Summer periods with regional mean LSTs above 5.0 °C showed the greatest spatial diversity with four distinct 2.0 °C classes. Summer anomalies ranged from − 4.5 °C to 2.6 °C with an average standard deviation of 1.8 °C. Dry ridge areas heated up the most, while wetland areas and dry areas of sparsely vegetated bedrock with a high albedo remained coolest. The observed summer LST anomalies can be used as a baseline against which to evaluate both past and future changes in land surface properties that relate to the surface energy balance. Summer anomaly classes mainly reflected a combination of albedo and surface wetness. The potential to use this tool to monitor surface drying and wetting in the Arctic should therefore be further explored. A multi-sensor approach combining thermal satellite measurements with optical and radar imagery promises to be an effective tool for a dynamic, process-based ecosystem monitoring scheme.
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  • 80
    Publication Date: 2016-03-17
    Description: Forests worldwide are threatened by various environmental and anthropogenic hazards, especially tropical forests. Knowledge on the impacts of these hazards on forest structure and dynamics has been compiled in empirical studies. However, the results of these studies are often not sufficient for long-term projections and extrapolations to large spatial scales especially for unprecedented environmental conditions, which require both the identification and understanding of key underlying processes. Forest models bridge this gap by incorporating multiple ecological processes in a dynamic framework (i.e. including a realistic model structure) and addressing the complexity of forest ecosystems. Here, we describe the evolution of the individual-based and process-based forest gap model FORMIND and its application to tropical forests. At its core, the model includes physiological processes on tree level (photosynthesis, respiration, tree growth, mortality, regeneration, competition). During the past two decades, FORMIND has been used to address various scientific questions arising from different forest types by continuously extending the model structure. The model applications thus provided understanding in three main aspects: (1) the grouping of single tree species into plant functional types is a successful approach to reduce complexity in vegetation models, (2) structural realism was necessary to analyze impacts of natural and anthropogenic disturbances such as logging, fragmentation, or drought, and (3) complex ecological processes such as carbon fluxes in tropical forests – starting from the individual tree level up to the entire forest ecosystem – can be explored as a function of forest structure, species composition and disturbance regime. Overall, this review shows how the evolution of long-term modelling projects not only provides scientific understanding of forest ecosystems, but also provides benefits for ecological theory and empirical study design.
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  • 81
    Publication Date: 2016-05-02
    Description: Recent declines in ice shelf and sea ice extent experienced in polar regions highlight the importance of evaluating variations in local weather patterns in response to climate change. Airborne mineral particles (dust) transported through the atmosphere and deposited on ice sheets and glaciers in Antarctica and Greenland can provide a robust set of tools for resolving the evolution of climatic systems through time. Here we present the first high time resolution radiogenic isotope (strontium and neodymium) data for Holocene dust in a coastal East Antarctic ice core, accompanied by rare earth element composition, dust concentration, and particle size distribution during the last deglaciation. We aim to use these combined ice core data to determine dust provenance, with variations indicative of shifts in either dust production, sources, and/or transport pathways. We analyzed a series of 17 samples from the Taylor Dome (77◦47'47''S, 158◦43'26''E) ice core, 113–391m in depth from 1.1–31.4ka. Radiogenic isotopic and rare earth element compositions of dust during the last glacial period are in good agreement with previously measured East Antarctic ice core dust records. In contrast, the Holocene dust dataset displays a broad range in isotopic and rare earth element compositions, suggesting a shift from long-range transported dust to a more variable, local input that may be linked to the retreat of the Ross Ice Shelf during the last deglaciation. Observed changes in the dust cycle inferred from a coastal East Antarctic ice core can thus be used to infer an evolving local climate.
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  • 82
    Publication Date: 2021-08-16
    Description: Estimation of high-resolution terrestrial evapotranspiration (ET) from Landsat data is important in many climatic, hydrologic, and agricultural applications, as it can help bridging the gap between existing coarse-resolution ET products and point-based field measurements. However, there is large uncertainty among existing ET products from Landsat that limit their application. This study presents a simple Taylor skill fusion (STS) method that merges five Landsat-based ET products and directly measured ET from eddy covariance (EC) to improve the global estimation of terrestrial ET. The STS method uses a weighted average of the individual ET products and weights are determined by their Taylor skill scores (S). The validation with site-scale measurements at 206 EC flux towers showed large differences and uncertainties among the five ET products. The merged ET product exhibited the best performance with a decrease in the averaged root-mean-square error (RMSE) by 2–5 W/m2 when compared to the individual products. To evaluate the reliability of the STS method at the regional scale, the weights of the STS method for these five ET products were determined using EC ground-measurements. An example of regional ET mapping demonstrates that the STS-merged ET can effectively integrate the individual Landsat ET products. Our proposed method provides an improved high-resolution ET product for identifying agricultural crop water consumption and providing a diagnostic assessment for global land surface models.
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  • 83
    Publication Date: 2022-05-25
    Description: © The Author(s), 2014. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Methods in Oceanography 10 (2015): 21–43, doi:10.1016/j.mio.2014.05.001.
    Description: We present an integrated framework for joint estimation and pursuit of dynamic features in the ocean, over large spatial scales and with multiple collaborating vehicles relying on limited communications. Our approach uses ocean model predictions to design closed-loop networked control at short time scales, and the primary innovation is to represent model uncertainty via a projection of ensemble forecasts into local linearized vehicle coordinates. Based on this projection, we identify a stochastic linear time-invariant model for estimation and control design. The methodology accurately decomposes spatial and temporal variations, exploits coupling between sites along the feature, and allows for advanced methods in communication-constrained control. Simulations with three example datasets successfully demonstrate the proof-of-concept.
    Description: The work is supported by the Office of Naval Research, Grant N00014-09-1-0700 and the National Science Foundation, Contract CNS-1212597.
    Keywords: Autonomous underwater vehicles ; Collaborative control ; Feature tracking ; Ensemble forecasts ; Linearization ; System identification
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  • 84
    Publication Date: 2022-05-25
    Description: © The Author(s), 2014. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Ecological Modelling 276 (2014): 38–50, doi:10.1016/j.ecolmodel.2014.01.005.
    Description: Sea-level rise and human development pose significant threats to shorebirds, particularly for species that utilize barrier island habitat. The piping plover (Charadrius melodus) is a federally-listed shorebird that nests on barrier islands and rapidly responds to changes in its physical environment, making it an excellent species with which to model how shorebird species may respond to habitat change related to sea-level rise and human development. The uncertainty and complexity in predicting sea-level rise, the responses of barrier island habitats to sea-level rise, and the responses of species to sea-level rise and human development necessitate a modeling approach that can link species to the physical habitat features that will be altered by changes in sea level and human development. We used a Bayesian network framework to develop a model that links piping plover nest presence to the physical features of their nesting habitat on a barrier island that is impacted by sea-level rise and human development, using three years of data (1999, 2002, and 2008) from Assateague Island National Seashore in Maryland. Our model performance results showed that we were able to successfully predict nest presence given a wide range of physical conditions within the model's dataset. We found that model predictions were more successful when the ranges of physical conditions included in model development were varied rather than when those physical conditions were narrow. We also found that all model predictions had fewer false negatives (nests predicted to be absent when they were actually present in the dataset) than false positives (nests predicted to be present when they were actually absent in the dataset), indicating that our model correctly predicted nest presence better than nest absence. These results indicated that our approach of using a Bayesian network to link specific physical features to nest presence will be useful for modeling impacts of sea-level rise or human-related habitat change on barrier islands. We recommend that potential users of this method utilize multiple years of data that represent a wide range of physical conditions in model development, because the model performed less well when constructed using a narrow range of physical conditions. Further, given that there will always be some uncertainty in predictions of future physical habitat conditions related to sea-level rise and/or human development, predictive models will perform best when developed using multiple, varied years of data input.
    Description: Funding for the research presented in this paper was provided by the North Atlantic Landscape Conservation Cooperative and the U.S. Geological Survey.
    Keywords: Bayesian network ; Development ; Habitat ; Piping plover ; Sea-level rise ; Shorebird
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  • 85
    Publication Date: 2022-05-25
    Description: © The Author(s), 2015. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Deep Sea Research Part I: Oceanographic Research Papers 100 (2015): 21-33, doi:10.1016/j.dsr.2015.01.010.
    Description: Most of our knowledge about deep-sea habitats is limited to bathyal (200–3000 m) and abyssal depths (3000–6000 m), while relatively little is known about the hadal zone (6000–11,000 m). The basic paradigm for the distribution of deep seafloor biomass suggests that the reduction in biomass and average body size of benthic animals along depth gradients is mainly related to surface productivity and remineralisation of sinking particulate organic carbon with depth. However, there is evidence that this pattern is somewhat reversed in hadal trenches by the funnelling of organic sediments, which would result in increased food availability along the axis of the trenches and towards their deeper regions. Therefore, despite the extreme hydrostatic pressure and remoteness from the pelagic food supply, it is hypothesized that biomass can increase with depth in hadal trenches. We developed a numerical model of gravitational lateral sediment transport along the seafloor as a function of slope, using the Kermadec Trench, near New Zealand, as a test environment. We propose that local topography (at a scale of tens of kilometres) and trench shape can be used to provide useful estimates of local accumulation of food and, therefore, patterns of benthic biomass. Orientation and steepness of local slopes are the drivers of organic sediment accumulation in the model, which result in higher biomass along the axis of the trench, especially in the deepest spots, and lower biomass on the slopes, from which most sediment is removed. The model outputs for the Kermadec Trench are in agreement with observations suggesting the occurrence of a funnelling effect and substantial spatial variability in biomass inside a trench. Further trench surveys will be needed to determine the degree to which seafloor currents are important compared with the gravity-driven transport modelled here. These outputs can also benefit future hadal investigations by highlighting areas of potential biological interest, on which to focus sampling effort. Comprehensive exploration of hadal trenches will, in turn, provide datasets for improving the model parameters and increasing predictive power.
    Description: MCI would also like to thank the University of Southampton, the Natural Environment Research Council (NERC, grant number NEW332003) and the Institute of Marine Engineering, Science & Technology (IMarEST), for supporting his research towards a PhD. We are grateful for the support provided by the National Science Foundation (OCE-1131620 to TMS, JCD, and PHY) to the Hadal Ecosystem Studies (HADES) project to which this paper forms a contribution. Support also came from the Natural Environment Research Council (NERC) and its Marine Environmental Mapping Programme (MAREMAP).
    Keywords: Hadal ecology ; Sediment ; Gravitational transport ; Topography ; Benthic biomass ; Kermadec Trench
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  • 86
    Publication Date: 2022-05-25
    Description: © The Author(s), 2013. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Journal of King Saud University - Science 25 (2013): 217–228, doi:10.1016/j.jksus.2013.02.006.
    Description: The degradation of natural fish habitat in the ocean implies lost economic benefits. These value losses often are not measured or anticipated fully, and therefore they are mainly ignored in decisions to develop the coast for industrial or residential purposes. In such circumstances, the ocean habitat and its associated ecosystem are treated as if they are worthless. Measures of actual or potential economic values generated by fisheries in commercial markets can be used to assess a conservative (lower-bound) value of ocean habitat. With this information, one can begin to compare the values of coastal developments to the values of foregone ocean habitat in order to help understand whether development would be justified economically. In this paper, we focus on the economic value associated with the harvesting of commercial fish stocks as a relevant case for the Saudi Arabian portion of the Red Sea. We describe first the conceptual basis behind supply-side approaches to economic valuation. Next we review the literature on the use of these methods for valuing ocean habitat. We provide an example based on recent research assessing the bioeconomic status of the traditional fisheries of the Red Sea in the Kingdom of Saudi Arabia (KSA). We estimate the economic value of ecosystem services provided by the KSA Red Sea coral reefs, finding that annual per-unit values supporting the traditional fisheries only are on the order of $7000/km2. Finally, we develop some recommendations for refining future applications of these methods to the Red Sea environment and for further research.
    Description: This research is based on work supported by Award Nos. USA 00002 and KSA 00011 made by the King Abdullah University of Science and Technology (KAUST).
    Keywords: Ecosystem service ; Supply-side valuation ; Traditional fishery ; Red Sea ; Coral reef ; Bio-economics
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  • 87
    Publication Date: 2022-05-25
    Description: © The Author(s), 2013. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Ecological Modelling 261-262 (2013): 43–57, doi:10.1016/j.ecolmodel.2013.04.006.
    Description: Dynamic Green Ocean Models (DGOMs) include different sets of Plankton Functional Types (PFTs) and equations, thus different interactions and food webs. Using four DGOMs (CCSM-BEC, PISCES, NEMURO and PlankTOM5) we explore how predator–prey interactions influence food web dynamics. Using each model's equations and biomass output, interaction strengths (direct and specific) were calculated and the role of zooplankton in modeled food webs examined. In CCSM-BEC the single size-class adaptive zooplankton preys on different phytoplankton groups according to prey availability and food preferences, resulting in a strong top-down control. In PISCES the micro- and meso-zooplankton groups compete for food resources, grazing phytoplankton depending on their availability in a mixture of bottom-up and top-down control. In NEMURO macrozooplankton controls the biomass of other zooplankton PFTs and defines the structure of the food web with a strong top-down control within the zooplankton. In PlankTOM5, competition and predation between micro- and meso-zooplankton along with strong preferences for nanophytoplankton and diatoms, respectively, leads to their mutual exclusion with a mixture of bottom-up and top-down control of the plankton community composition. In each model, the grazing pressure of the zooplankton PFTs and the way it is exerted on their preys may result in the food web dynamics and structure of the model to diverge from the one that was intended when designing the model. Our approach shows that the food web dynamics, in particular the strength of the predator–prey interactions, are driven by the choice of parameters and more specifically the food preferences. Consequently, our findings stress the importance of equation and parameter choice as they define interactions between PFTs and overall food web dynamics (competition, bottom-up or top-down effects). Also, the differences in the simulated food-webs between different models highlight the gap of knowledge for zooplankton rates and predator–prey interactions. In particular, concerted effort is needed to identify the key growth and loss parameters and interactions and quantify them with targeted laboratory experiments in order to bring our understanding of zooplankton at a similar level to phytoplankton.
    Description: This work was supported with funding from Palmer LTER (NSF OPP-0823101) and C-MORE (NSF EF-0424599).
    Keywords: Dynamic Green Ocean Model ; Plankton Functional Types ; Zooplankton ; Food web dynamic ; Predator–prey interactions
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  • 88
    Publication Date: 2022-05-25
    Description: © The Author(s), 2013. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Remote Sensing of Environment 135 (2013): 77-91, doi:10.1016/j.rse.2013.03.025.
    Description: Photosynthetic production of organic matter by microscopic oceanic phytoplankton fuels ocean ecosystems and contributes roughly half of the Earth's net primary production. For 13 years, the Sea-viewing Wide Field-of-view Sensor (SeaWiFS) mission provided the first consistent, synoptic observations of global ocean ecosystems. Changes in the surface chlorophyll concentration, the primary biological property retrieved from SeaWiFS, have traditionally been used as a metric for phytoplankton abundance and its distribution largely reflects patterns in vertical nutrient transport. On regional to global scales, chlorophyll concentrations covary with sea surface temperature (SST) because SST changes reflect light and nutrient conditions. However, the ocean may be too complex to be well characterized using a single index such as the chlorophyll concentration. A semi-analytical bio-optical algorithm is used to help interpret regional to global SeaWiFS chlorophyll observations from using three independent, well-validated ocean color data products; the chlorophyll a concentration, absorption by CDM and particulate backscattering. First, we show that observed long-term, global-scale trends in standard chlorophyll retrievals are likely compromised by coincident changes in CDM. Second, we partition the chlorophyll signal into a component due to phytoplankton biomass changes and a component caused by physiological adjustments in intracellular chlorophyll concentrations to changes in mixed layer light levels. We show that biomass changes dominate chlorophyll signals for the high latitude seas and where persistent vertical upwelling is known to occur, while physiological processes dominate chlorophyll variability over much of the tropical and subtropical oceans. The SeaWiFS data set demonstrates complexity in the interpretation of changes in regional to global phytoplankton distributions and illustrates limitations for the assessment of phytoplankton dynamics using chlorophyll retrievals alone.
    Description: The authors would like to acknowledge the NASA Ocean Biology and Biogeochemistry program for its long-term support of satellite ocean color research and the Orbital Sciences Corporation and GeoEye who were responsible for the launch, satellite integration and on-orbit management the SeaWiFS mission.
    Keywords: Ocean color ; SeaWiFS ; Phytoplankton ; Colored dissolved organic matter ; Decadal trends
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  • 89
    Publication Date: 2022-05-25
    Description: © The Author(s), 2015. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Agriculture, Ecosystems & Environment 212 (2015): 127-133, doi:10.1016/j.agee.2015.07.005.
    Description: Climate change is causing the intensification of both rainfall and droughts in temperate climatic zones, which will affect soil drying and rewetting cycles and associated processes such as soil greenhouse gas (GHG) fluxes. We investigated the effect of soil rewetting following a prolonged natural drought on soil emissions of nitrous oxide (N2O) and carbon dioxide (CO2) in an agricultural field recently converted from 22 years in the USDA Conservation Reserve Program (CRP). We compared responses to those in a similarly managed field with no CRP history and to a CRP reference field. We additionally compared soil GHG emissions measured by static flux chambers with off-site laboratory analysis versus in situ analysis using a portable quantum cascade laser and infrared gas analyzer. Under growing season drought conditions, average soil N2O fluxes ranged between 0.2 and 0.8 μg N m−2 min−1 and were higher in former CRP soils and unaffected by nitrogen (N) fertilization. After 18 days of drought, a 50 mm rewetting event increased N2O fluxes by 34 and 24 fold respectively in the former CRP and non-CRP soils. Average soil CO2 emissions during drought ranged from 1.1 to 3.1 mg C m−2 min−1 for the three systems. CO2 emissions increased ∼2 fold after the rewetting and were higher from soils with higher C contents. Observations are consistent with the hypothesis that during drought soil N2O emissions are controlled by available C and following rewetting additionally influenced by N availability, whereas soil CO2 emissions are independent of short-term N availability. Finally, soil GHG emissions estimated by off-site and in situ methods were statistically identical.
    Description: Financial support for this work was provided by the DOE Office of Science (DE-FC02-07ER64494) and Office of Energy Efficiency and Renewable Energy (DE-AC05-76RL01830), the US National Science Foundation LTER program (DEB 1027253), and MSU AgBioResearch. J. Tang and M. Cui were supported additionally by NSF/DBI-959333, Brown University seed funding, and the Brown University–Marine Biological Laboratory graduate program in Biological and Environmental Sciences.
    Keywords: Soil carbon ; Conservation reserve program ; N2O methodology ; Corn ; No-till
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  • 90
    Publication Date: 2022-05-25
    Description: © The Author(s), 2015. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Deep Sea Research Part II: Topical Studies in Oceanography 118 (2015): 122-135, doi:10.1016/j.dsr2.2015.02.008.
    Description: A coupled biophysical model is used to examine the impact of changes in sea ice and snow cover and nutrient availability on the formation of massive under-ice phytoplankton blooms (MUPBs) in the Chukchi Sea of the Arctic Ocean over the period 1988–2013. The model is able to reproduce the basic features of the ICESCAPE (Impacts of Climate on EcoSystems and Chemistry of the Arctic Pacific Environment) observed MUPB during July 2011. The simulated MUPBs occur every year during 1988–2013, mainly in between mid-June and mid-July. While the simulated under-ice blooms of moderate magnitude are widespread in the Chukchi Sea, MUPBs are less so. On average, the area fraction of MUPBs in the ice-covered areas of the Chukchi Sea during June and July is about 8%, which has been increasing at a rate of 2% yr–1 over 1988–2013. The simulated increase in the area fraction as well as primary productivity and chlorophyll a biomass is linked to an increase in light availability, in response to a decrease in sea ice and snow cover, and an increase in nutrient availability in the upper 100 m of the ocean, in conjunction with an intensification of ocean circulation. Simulated MUPBs are temporally sporadic and spatially patchy because of strong spatiotemporal variations of light and nutrient availability. However, as observed during ICESCAPE, there is a high likelihood that MUPBs may form at the shelf break, where the model simulates enhanced nutrient concentration that is seldom depleted between mid-June and mid-July because of generally robust shelf-break upwelling and other dynamic ocean processes. The occurrence of MUPBs at the shelf break is more frequent in the past decade than in the earlier period because of elevated light availability there. It may be even more frequent in the future if the sea ice and snow cover continues to decline such that light is more available at the shelf break to further boost the formation of MUPBs there.
    Description: This work is supported by the NASA Cryosphere Program and Climate and Biological Response Program and the NSF Office of Polar Programs (Grant Nos. NNX12AB31G; NNX11AO91G; ARC-0901987).
    Keywords: Arctic Ocean ; Chukchi Sea ; Phytoplankton ; Blooms ; Sea ice ; Snow depth ; Light availability ; Nutrient availability
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  • 91
    Publication Date: 2022-05-25
    Description: © The Author(s), 2015. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Deep Sea Research Part I: Oceanographic Research Papers 104 (2015): 72-91, doi:10.1016/j.dsr.2015.06.012.
    Description: Nitrogen fixation is an important yet still incompletely constrained component of the marine nitrogen cycle, particularly in the subsurface. A Video Plankton Recorder (VPR) survey in the subtropical North Atlantic found higher than expected Trichodesmium colony abundances at depth, leading to the hypothesis that deep nitrogen fixation in the North Atlantic may have been previously underestimated. Here, Trichodesmium colony abundances and modeled nitrogen fixation from VPR transects completed on two cruises in the tropical and subtropical North Atlantic in fall 2010 and spring 2011 were used to evaluate that hypothesis. A bio-optical model was developed based on carbon-normalized nitrogen fixation rates measured on those cruises. Estimates of colony abundance and nitrogen fixation were similar in magnitude and vertical and geographical distribution to conventional estimates in a recently compiled climatology. Thus, in the mean, VPR-based estimates of volume-specific nitrogen fixation rates at depth in the tropical North Atlantic were not inconsistent with estimates derived from conventional sampling methods. Based on this analysis, if Trichodesmium nitrogen fixation by colonies is underestimated, it is unlikely that it is due to underestimation of deep abundances by conventional sampling methods.
    Description: We gratefully acknowledge support of this research by NSF and NASA. A NASA Earth and Space Science Fellowship supported E. Olson's graduate studies.
    Keywords: Nitrogen fixation ; Trichodesmium spp. ; North Atlantic ; Video Plankton Recorder
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  • 92
    Publication Date: 2022-05-25
    Description: This paper is not subject to U.S. copyright. The definitive version was published in Marine and Petroleum Geology 66 (2015): 434-450, doi:10.1016/j.marpetgeo.2015.02.033.
    Description: Natural hydrate-bearing sediments from the Nankai Trough, offshore Japan, were studied using the Pressure Core Characterization Tools (PCCTs) to obtain geomechanical, hydrological, electrical, and biological properties under in situ pressure, temperature, and restored effective stress conditions. Measurement results, combined with index-property data and analytical physics-based models, provide unique insight into hydrate-bearing sediments in situ. Tested cores contain some silty-sands, but are predominantly sandy- and clayey-silts. Hydrate saturations Sh range from 0.15 to 0.74, with significant concentrations in the silty-sands. Wave velocity and flexible-wall permeameter measurements on never-depressurized pressure-core sediments suggest hydrates in the coarser-grained zones, the silty-sands where Sh exceeds 0.4, contribute to soil-skeletal stability and are load-bearing. In the sandy- and clayey-silts, where Sh 〈 0.4, the state of effective stress and stress history are significant factors determining sediment stiffness. Controlled depressurization tests show that hydrate dissociation occurs too quickly to maintain thermodynamic equilibrium, and pressure–temperature conditions track the hydrate stability boundary in pure-water, rather than that in seawater, in spite of both the in situ pore water and the water used to maintain specimen pore pressure prior to dissociation being saline. Hydrate dissociation accompanied with fines migration caused up to 2.4% vertical strain contraction. The first-ever direct shear measurements on never-depressurized pressure-core specimens show hydrate-bearing sediments have higher sediment strength and peak friction angle than post-dissociation sediments, but the residual friction angle remains the same in both cases. Permeability measurements made before and after hydrate dissociation demonstrate that water permeability increases after dissociation, but the gain is limited by the transition from hydrate saturation before dissociation to gas saturation after dissociation. In a proof-of-concept study, sediment microbial communities were successfully extracted and stored under high-pressure, anoxic conditions. Depressurized samples of these extractions were incubated in air, where microbes exhibited temperature-dependent growth rates.
    Description: PCCTs were developed with funding to Georgia Tech from the DOE/Chevron Joint Industry Project (JIP), with additional funds from the Joint Oceanographic Institutions, Inc. The JIP also funded the Georgia Tech participation in Sapporo. USGS participation in Sapporo was funded through a technical assistance agreement with Chevron (TAA-12-2135/CW928359). Some USGS developments on the IPTC were funded under Interagency Agreement DE-FE0002911 with the U.S. Department of Energy, with additional support from the U.S. Geological Survey. Core acquisition and Japanese participation in this study was supported by the Research Consortium for Methane Hydrate Resources in Japan (MH21 Research Consortium) to carry out Japan's Methane Hydrate R&D Program conducted by the Ministry of Economy, Trade and Industry (METI).
    Keywords: Methane hydrate ; Hydrate-bearing sediment ; Nankai Trough ; Physical properties ; Pressure core
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  • 93
    Publication Date: 2022-05-25
    Description: © The Author(s), 2016. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Continental Shelf Research 124 (2016): 165-181, doi:10.1016/j.csr.2016.06.005.
    Description: A new hydrographic climatology has been created for the continental shelf region, extending from the Labrador shelf to the Mid-Atlantic Bight. The 0.2-degree climatology combines all available observations of surface and bottom temperature and salinity collected between 1950 and 2010 along with the location, depth and date of these measurements. While climatological studies of surface and bottom temperature and salinity have been presented previously for various regions along the Canadian and U.S. shelves, studies also suggest that all these regions are part of one coherent system. This study focuses on the coherent structure of the mean seasonal cycle of surface and bottom temperature and salinity and its variation along the shelf and upper slope. The seasonal cycle of surface temperature is mainly driven by the surface heat flux and exhibits strong dependency on latitude (r≈−0.9). The amplitude of the seasonal cycle of bottom temperature is rather dependent on the depth, while the spatial distribution of bottom temperature is correlated with latitude. The seasonal cycle of surface salinity is influenced by several components, such as sea-ice on the northern shelves and river discharge in the Gulf of St. Lawrence. The bottom salinity exhibits no clear seasonal cycle, but its spatial distribution is highly correlated with bathymetry, thus Slope Water and its intrusion on the shelf can be identified by its relatively high salinity compared to shallow, fresher shelf water. Two different regimes can be identified, especially on the shelf, separated by the Laurentian Channel: advection influences the phasing of the seasonal cycle of surface salinity and bottom temperature to the north, while in the southern region, river runoff and air-sea heat flux forcing are dominant, especially over the shallower bathymetry.
    Description: Support from NSF OCE PO to Y-OK (OCE-1242989 and OCE-1435602) and SJL (OCE-1332666).
    Keywords: Seasonal climatology ; Temperature ; Salinity ; Dataset ; Shelf
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  • 94
    Publication Date: 2022-05-25
    Description: © The Author(s), 2016. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Progress in Oceanography 151 (2017): 261–274, doi:10.1016/j.pocean.2016.12.007.
    Description: The southeast subtropical Pacific Ocean was sampled along a zonal transect between the coasts of Chile and Easter Island. This remote area of the world’s ocean presents strong gradients in physical (e.g., temperature, density and light), chemical (e.g., salinity and nutrient concentrations) and microbiological (e.g., cell abundances, biomass and specific growth rates) properties. The goal of this study was to describe the phosphorus (P) dynamics in three main ecosystems along this transect: the upwelling regime off the northern Chilean coast, the oligotrophic area associated with the southeast subtropical Pacific gyre and the transitional area in between these two biomes. We found that inorganic phosphate (Pi) concentrations were high and turnover times were long (〉210 nmol l−1 and 〉31 d, respectively) in the upper water column, along the entire transect. Pi uptake rates in the gyre were low (euphotic layer integrated rates were 0.26 mmol m−2 d−1 in the gyre and 1.28 mmol m−2 d−1 in the upwelling region), yet not only driven by decreases in particle mass or cell abundance (particulate P- and cell- normalized Pi uptake rates in the euphotic layer were ∼1–4 times and ∼3–15 times lower in the gyre than in the upwelling, respectively). However these Pi uptake rates were at or near the maximum Pi uptake velocity (i.e., uptake rates in Pi amended samples were not significantly different from those at ambient concentration: 1.5 and 23.7 nmol l−1 d−1 at 50% PAR in the gyre and upwelling, respectively). Despite the apparent Pi replete conditions, selected dissolved organic P (DOP) compounds were readily hydrolyzed. Nucleotides were the most bioavailable of the DOP substrates tested. Microbes actively assimilated adenosine-5′-triphosphate (ATP) leading to Pi and adenosine incorporation as well as Pi release to the environment. The southeast subtropical Pacific Ocean is a Pi-sufficient environment, yet DOP hydrolytic processes are maintained and contribute to P-cycling across the wide range of environmental conditions present in this ecosystem.
    Description: Funds for this work were provided by the Gordon and Betty Moore Foundation’s Marine Microbiology Initiative (D.M.K., 3794) and the Center for Microbial Oceanography: Research and Education (C-MORE, National Science Foundation, D.M.K., EF0424599).
    Keywords: Phosphorus dynamics ; Microbes ; Stocks ; Fluxes ; Southeast subtropical Pacific Ocean
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  • 95
    Publication Date: 2022-05-25
    Description: © The Author(s), 2017. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Chemical Geology 453 (2017): 146–168, doi:10.1016/j.chemgeo.2017.01.022.
    Description: Cold-water corals (CWCs) are unique archives of mid-depth ocean chemistry and have been used successfully to reconstruct the neodymium (Nd) isotopic composition of seawater from a number of species. High and variable Nd concentrations in fossil corals however pose the question as to how Nd is incorporated into their skeletons. We here present new results on modern specimens of Desmophyllum dianthus, Balanophyllia malouinensis, and Flabellum curvatum, collected from the Drake Passage, and Madrepora oculata, collected from the North Atlantic. All modern individuals were either collected alive or uranium-series dated to be 〈 500 years old for comparison with local surface sediments and seawater profiles. Modern coral Nd isotopic compositions generally agree with ambient seawater values, which in turn are consistent with previously published seawater analyses, supporting small vertical and lateral Nd isotope gradients in modern Drake Passage waters. Two Balanophyllia malouinensis specimens collected live however deviate by up to 0.6 epsilon units from ambient seawater. We therefore recommend that this species should be treated with caution for the reconstruction of past seawater Nd isotopic compositions. Seventy fossil Drake Passage CWCs were furthermore analysed for their Nd concentrations, revealing a large range from 7.3 to 964.5 ng/g. Samples of the species D. dianthus and Caryophyllia spp. show minor covariation of Nd with 232Th content, utilised to monitor contaminant phases in cleaned coral aragonite. Strong covariations between Nd and Th concentrations are however observed in the species B. malouinensis and G. antarctica. In order to better constrain the source and nature of Nd in the cleaned aragonitic skeletons, a subset of sixteen corals was investigated for its rare earth element (REE) content, as well as major and trace element geochemistry. Our new data provide supporting evidence that the applied cleaning protocol efficiently removes contaminant lithogenic and ferromanganese oxyhydroxide phases. Mass balance calculations and seawater-like REE patterns rule out lithogenic and ferromanganese oxyhydroxide phases as a major contributor to elevated Nd concentrations in coral aragonite. Based on mass balance considerations, geochemical evidence, and previously published independent work by solid-state nuclear magnetic resonance (NMR) spectroscopy, we suggest authigenic phosphate phases as a significant carrier of skeletal Nd. Such a carrier phase could explain sporadic appearance of high Nd concentrations in corals and would be coupled with seawater-derived Nd isotopic compositions, lending further confidence to the application of Nd isotopes as a water mass proxy in CWCs.
    Description: TvdF and TS acknowledge financial support for a bursary by the Grantham Institute of Climate Change and the Environment and a Marie Curie Reintegration grant (IRG 230828), as well as funding from the Leverhulme Trust (RPG-398) and the NERC (NE/N001141/1). Additional financial support was provided to LFR by the USGS-WHOI Co-operative agreement, NSF-ANT grants 0636787 and 80295700, The European Research Council, the Leverhulme Trust and a Marie Curie Reintegration grant. LB was supported by a NOAA/UCAR Climate and Global Change Postdoctoral Fellowship and KJM acknowledges funding from a Marie Curie International Outgoing fellowship (IOF 236962).
    Keywords: Neodymium isotopes ; Rare earth elements ; Cold-water corals ; Seawater ; Sediments ; Drake Passage
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  • 96
    Publication Date: 2022-05-25
    Description: This paper is not subject to U.S. copyright. The definitive version was published in Continental Shelf Research 138 (2017): 1-18, doi:10.1016/j.csr.2017.02.003.
    Description: Hurricane Sandy was one of the most destructive hurricanes in US history, making landfall on the New Jersey coast on October 30, 2012. Storm impacts included several barrier island breaches, massive coastal erosion, and flooding. While changes to the subaerial landscape are relatively easily observed, storm-induced changes to the adjacent shoreface and inner continental shelf are more difficult to evaluate. These regions provide a framework for the coastal zone, are important for navigation, aggregate resources, marine ecosystems, and coastal evolution. Here we provide unprecedented perspective regarding regional inner continental shelf sediment dynamics based on both observations and numerical modeling over time scales associated with these types of large storm events. Oceanographic conditions and seafloor morphologic changes are evaluated using both a coupled atmospheric-ocean-wave-sediment numerical modeling system that covered spatial scales ranging from the entire US east coast (1000 s of km) to local domains (10 s of km). Additionally, the modeled response for the region offshore of Fire Island, NY was compared to observational analysis from a series of geologic surveys from that location. The geologic investigations conducted in 2011 and 2014 revealed lateral movement of sedimentary structures of distances up to 450 m and in water depths up to 30 m, and vertical changes in sediment thickness greater than 1 m in some locations. The modeling investigations utilize a system with grid refinement designed to simulate oceanographic conditions with progressively increasing resolutions for the entire US East Coast (5-km grid), the New York Bight (700-m grid), and offshore of Fire Island, NY (100-m grid), allowing larger scale dynamics to drive smaller scale coastal changes. Model results in the New York Bight identify maximum storm surge of up to 3 m, surface currents on the order of 2 ms−1 along the New Jersey coast, waves up to 8 m in height, and bottom stresses exceeding 10 Pa. Flow down the Hudson Shelf Valley is shown to result in convergent sediment transport and deposition along its axis. Modeled sediment redistribution along Fire Island showed erosion across the crests of inner shelf sand ridges and sedimentation in adjacent troughs, consistent with the geologic observations.
    Description: This research was funded by the U.S. Geological Survey (USGS), Coastal and Marine Geology Program, and conducted by the Coastal Change Processes Project. This research was supported in part by the Department of the Interior Hurricane Sandy Recovery program.
    Keywords: Shoreface connected sand ridges ; Sediment transport ; Fire Island, NY ; Hurricane Sandy ; Inner shelf ; Numerical modeling
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  • 97
    Publication Date: 2022-05-25
    Description: © The Author(s), 2016. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Journal of Hydrology: Regional Studies 11 (2017): 219-233, doi:10.1016/j.ejrh.2016.08.003.
    Description: Hydrogeologic controls on seasonal land/sea exchange are investigated in Malibu, California, USA. An assessment of regional groundwater/surface water exchange and associated biogeochemical transport in an intermittently open, coastal lagoon in California is developed using naturally occurring U/Th-series tracers. Nearshore lagoons that are seasonally disconnected from the coastal ocean occupy about 10% of coastal areas worldwide. Lagoon systems often are poorly flushed and thus sensitive to nutrient over-enrichment that can lead to eutrophication, oxygen depletion, and/or pervasive algal blooms. This sensitivity is exacerbated in lagoons that are intermittently closed to surface water exchange with the sea and occur in populous coastal areas. Such estuarine systems are disconnected from the sea during most of the year by wave-built barriers, but during the rainy season these berms can breach, enabling direct water exchange. Using naturally-occurring 222Rn as groundwater tracer, we estimate that groundwater discharge to Malibu Lagoon during open berm conditions was one order of magnitude higher (21 ± 17 cm/day) than during closed berm conditions (1.8 ± 1.4 cm/day). The SGD (submarine groundwater discharge) into nearshore coastal waters at the SurferRider and Colony Malibu was 4.2 cm/day on average. The exported total dissolved nitrogen (TDN) through the berm during closed berm was 1.6 × 10−3 mol/day, whereas during open berm (exported by the Creek) was 3.5 × 103 mol/day. Although these evaluations are specific to the collection campaigns the 2009 and 2010 hydro years, these two distinct hydrologic scenarios play an important role in the seasonality and geochemical impact of land/sea exchange, and highlight the sensitivity of such systems to future impacts such as sea level rise and increasing coastal populations.
    Description: This work was co-funded by the City of Malibu and the U.S. Geological Survey.
    Keywords: Regional groundwater flow ; Submarine groundwater discharge ; Radon ; Hydrologic time series
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  • 98
    Publication Date: 2022-05-25
    Description: This paper is not subject to U.S. copyright. The definitive version was published in Marine and Petroleum Geology 58A (2014): 99-116, doi:10.1016/j.marpetgeo.2014.04.009.
    Description: In addition to well established properties that control the presence or absence of the hydrate stability zone, such as pressure, temperature, and salinity, additional parameters appear to influence the concentration of gas hydrate in host sediments. The stratigraphic record at Site 17A in the Andaman Sea, eastern Indian Ocean, illustrates the need to better understand the role pore-scale phenomena play in the distribution and presence of marine gas hydrates in a variety of subsurface settings. In this paper we integrate field-generated datasets with newly acquired sedimentology, physical property, imaging and geochemical data with mineral saturation and ion activity products of key mineral phases such as amorphous silica and calcite, to document the presence and nature of secondary precipitates that contributed to anomalous porosity preservation at Site 17A in the Andaman Sea. This study demonstrates the importance of grain-scale subsurface heterogeneities in controlling the occurrence and distribution of concentrated gas hydrate accumulations in marine sediments, and document the importance that increased permeability and enhanced porosity play in supporting gas concentrations sufficient to support gas hydrate formation. The grain scale relationships between porosity, permeability, and gas hydrate saturation documented at Site 17A likely offer insights into what may control the occurrence and distribution of gas hydrate in other sedimentary settings.
    Description: The financial support for the NGHP01, from the Oil Industry Development Board, Oil and Natural Gas Corporation Ltd., GAIL (India) Ltd. and Oil India Ltd. is gratefully acknowledged. We also acknowledge the support extended by all the participating organizations of the NGHP: MoP&NG, DGH, ONGC, GAIL, OIL, NIO, NIOT, and RIL.
    Keywords: Porosity ; Permeability ; Grain size ; Indian Ocean ; Gas hydrate ; Saturation ; Volcanic ash ; Carbonate
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  • 99
    Publication Date: 2022-05-25
    Description: © The Author(s), 2015. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Remote Sensing of Environment 160 (2015): 222-234, doi:10.1016/j.rse.2015.01.019.
    Description: Phytoplankton, at the base of the marine food web, represent a fundamental food source in coral reef ecosystems. The timing (phenology) and magnitude of the phytoplankton biomass are major determinants of trophic interactions. The Red Sea is one of the warmest and most saline basins in the world, characterized by an arid tropical climate regulated by the monsoon. These extreme conditions are particularly challenging for marine life. Phytoplankton phenological indices provide objective and quantitative metrics to characterize phytoplankton seasonality. The indices i.e. timings of initiation, peak, termination and duration are estimated here using 15 years (1997–2012) of remote sensing ocean-color data from the European Space Agency (ESA) Climate Change Initiative project (OC-CCI) in the entire Red Sea basin. The OC-CCI product, comprising merged and bias-corrected observations from three independent ocean-color sensors (SeaWiFS, MODIS and MERIS), and processed using the POLYMER algorithm (MERIS period), shows a significant increase in chlorophyll data coverage, especially in the southern Red Sea during the months of summer NW monsoon. In open and reef-bound coastal waters, the performance of OC-CCI chlorophyll data is shown to be comparable with the performance of other standard chlorophyll products for the global oceans. These features have permitted us to investigate phytoplankton phenology in the entire Red Sea basin, and during both winter SE monsoon and summer NW monsoon periods. The phenological indices are estimated in the four open water provinces of the basin, and further examined at six coral reef complexes of particular socio-economic importance in the Red Sea, including Siyal Islands, Sharm El Sheikh, Al Wajh bank, Thuwal reefs, Al Lith reefs and Farasan Islands. Most of the open and deeper waters of the basin show an apparent higher chlorophyll concentration and longer duration of phytoplankton growth during the winter period (relative to the summer phytoplankton growth period). In contrast, most of the reef-bound coastal waters display equal or higher peak chlorophyll concentrations and equal or longer duration of phytoplankton growth during the summer period (relative to the winter phytoplankton growth period). The ecological and biological significance of the phytoplankton seasonal characteristics are discussed in context of ecosystem state assessment, and particularly to support further understanding of the structure and functioning of coral reef ecosystems in the Red Sea.
    Keywords: Phytoplankton phenology ; Ocean-color remote sensing ; ESA OC-CCI ; Coral reef ecosystems ; Monsoon ; Ecological indicators ; Red Sea
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  • 100
    Publication Date: 2022-05-25
    Description: © The Author(s), 2014. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Cold Regions Science and Technology 109 (2015): 9-17, doi:10.1016/j.coldregions.2014.08.004.
    Description: Traditional measures for detecting oil spills in the open-ocean are both difficult to apply and less effective in ice-covered seas. In view of the increasing levels of commercial activity in the Arctic, there is a growing gap between the potential need to respond to an oil spill in Arctic ice-covered waters and the capability to do so. In particular, there is no robust operational capability to remotely locate oil spilt under or encapsulated within sea ice. To date, most research approaches the problem from on or above the sea ice, and thus they suffer from the need to ‘see’ through the ice and overlying snow. Here we present results from a large-scale tank experiment which demonstrate the detection of oil beneath sea ice, and the quantification of the oil layer thickness is achievable through the combined use of an upward-looking camera and sonar deployed in the water column below a covering of sea ice. This approach using acoustic and visible measurements from below is simple and effective, and potentially transformative with respect to the operational response to oil spills in the Arctic marine environment. These results open up a new direction of research into oil detection in ice-covered seas, as well as describing a new and important role for underwater vehicles as platforms for oil-detecting sensors under Arctic sea ice.
    Description: This work was funded through a competitive grant for the detection of oil under ice obtained from Prince William Sound Oil Spill Recovery Institute (OSRI) (11-10-09). Additional funding/resources was obtained through the EU FP7 funded ACCESS programme (Grant Agreement n°. 265863).
    Keywords: Arctic ; Oil spill ; Sea ice ; Oil detection ; Sonar ; Camera
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