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  • 1
    Publication Date: 2022-05-25
    Description: This paper is not subject to U.S. copyright. The definitive version was published in Marine and Petroleum Geology 58A (2014): 99-116, doi:10.1016/j.marpetgeo.2014.04.009.
    Description: In addition to well established properties that control the presence or absence of the hydrate stability zone, such as pressure, temperature, and salinity, additional parameters appear to influence the concentration of gas hydrate in host sediments. The stratigraphic record at Site 17A in the Andaman Sea, eastern Indian Ocean, illustrates the need to better understand the role pore-scale phenomena play in the distribution and presence of marine gas hydrates in a variety of subsurface settings. In this paper we integrate field-generated datasets with newly acquired sedimentology, physical property, imaging and geochemical data with mineral saturation and ion activity products of key mineral phases such as amorphous silica and calcite, to document the presence and nature of secondary precipitates that contributed to anomalous porosity preservation at Site 17A in the Andaman Sea. This study demonstrates the importance of grain-scale subsurface heterogeneities in controlling the occurrence and distribution of concentrated gas hydrate accumulations in marine sediments, and document the importance that increased permeability and enhanced porosity play in supporting gas concentrations sufficient to support gas hydrate formation. The grain scale relationships between porosity, permeability, and gas hydrate saturation documented at Site 17A likely offer insights into what may control the occurrence and distribution of gas hydrate in other sedimentary settings.
    Description: The financial support for the NGHP01, from the Oil Industry Development Board, Oil and Natural Gas Corporation Ltd., GAIL (India) Ltd. and Oil India Ltd. is gratefully acknowledged. We also acknowledge the support extended by all the participating organizations of the NGHP: MoP&NG, DGH, ONGC, GAIL, OIL, NIO, NIOT, and RIL.
    Keywords: Porosity ; Permeability ; Grain size ; Indian Ocean ; Gas hydrate ; Saturation ; Volcanic ash ; Carbonate
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 2
    Publication Date: 2022-05-26
    Description: This paper is not subject to U.S. copyright. The definitive version was published in Marine and Petroleum Geology 28 (2011): 589-607, doi:10.1016/j.marpetgeo.2009.12.004.
    Description: Data acquired at the BPXA-DOE-USGS Mount Elbert Gas Hydrate Stratigraphic Test Well, drilled in the Milne Point area of the Alaska North Slope in February, 2007, indicates two zones of high gas hydrate saturation within the Eocene Sagavanirktok Formation. Gas hydrate is observed in two separate sand reservoirs (the D and C units), in the stratigraphically highest portions of those sands, and is not detected in non-sand lithologies. In the younger D unit, gas hydrate appears to fill much of the available reservoir space at the top of the unit. The degree of vertical fill with the D unit is closely related to the unit reservoir quality. A thick, low-permeability clay-dominated unit serves as an upper seal, whereas a subtle transition to more clay-rich, and interbedded sand, silt, and clay units is associated with the base of gas hydrate occurrence. In the underlying C unit, the reservoir is similarly capped by a clay-dominated section, with gas hydrate filling the relatively lower-quality sands at the top of the unit leaving an underlying thick section of high-reservoir quality sands devoid of gas hydrate. Evaluation of well log, core, and seismic data indicate that the gas hydrate occurs within complex combination stratigraphic/structural traps. Structural trapping is provided by a four-way fold closure augmented by a large western bounding fault. Lithologic variation is also a likely strong control on lateral extent of the reservoirs, particularly in the D unit accumulation, where gas hydrate appears to extend beyond the limits of the structural closure. Porous and permeable zones within the C unit sand are only partially charged due most likely to limited structural trapping in the reservoir lithofacies during the period of primary charging. The occurrence of the gas hydrate within the sands in the upper portions of both the C and D units and along the crest of the fold is consistent with an interpretation that these deposits are converted free gas accumulations formed prior to the imposition of gas hydrate stability conditions.
    Keywords: Mount Elbert well ; Gas hydrate ; Alaska North Slope ; Milne Point ; Sagavanirktok formation
    Repository Name: Woods Hole Open Access Server
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  • 3
    Publication Date: 2022-05-26
    Description: This paper is not subject to U.S. copyright. The definitive version was published in Marine and Petroleum Geology 28 (2011): 561-577, doi:10.1016/j.marpetgeo.2010.03.016.
    Description: The BPXA-DOE-USGS Mount Elbert Gas Hydrate Stratigraphic Test Well was an integral part of an ongoing project to determine the future energy resource potential of gas hydrates on the Alaska North Slope. As part of this effort, the Mount Elbert well included an advanced downhole geophysical logging program. Because gas hydrate is unstable at ground surface pressure and temperature conditions, a major emphasis was placed on the downhole-logging program to determine the occurrence of gas hydrates and the in-situ physical properties of the sediments. In support of this effort, well-log and core data montages have been compiled which include downhole log and core-data obtained from the gas-hydrate-bearing sedimentary section in the Mount Elbert well. Also shown are numerous reservoir parameters, including gas-hydrate saturation and sediment porosity log traces calculated from available downhole well log and core data.
    Keywords: Gas hydrate ; Alaska ; Resources ; Logs ; Core ; North Slope ; Drilling
    Repository Name: Woods Hole Open Access Server
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  • 4
    Publication Date: 2022-05-26
    Description: This paper is not subject to U.S. copyright. The definitive version was published in Marine and Petroleum Geology 28 (2011): 361-380, doi:10.1016/j.marpetgeo.2010.01.008.
    Description: This study characterizes cored and logged sedimentary strata from the February 2007 BP Exploration Alaska, Department of Energy, U.S. Geological Survey (BPXA-DOE-USGS) Mount Elbert Gas Hydrate Stratigraphic Test Well on the Alaska North Slope (ANS). The physical-properties program analyzed core samples recovered from the well, and in conjunction with downhole geophysical logs, produced an extensive dataset including grain size, water content, porosity, grain density, bulk density, permeability, X-ray diffraction (XRD) mineralogy, nuclear magnetic resonance (NMR), and petrography. This study documents the physical property interrelationships in the well and demonstrates their correlation with the occurrence of gas hydrate. Gas hydrate (GH) occurs in three unconsolidated, coarse silt to fine sand intervals within the Paleocene and Eocene beds of the Sagavanirktok Formation: Unit D-GH (614.4 m–627.9 m); unit C-GH1 (649.8 m–660.8 m); and unit C-GH2 (663.2 m–666.3 m). These intervals are overlain by fine to coarse silt intervals with greater clay content. A deeper interval (unit B) is similar lithologically to the gas-hydrate-bearing strata; however, it is water-saturated and contains no hydrate. In this system it appears that high sediment permeability (k) is critical to the formation of concentrated hydrate deposits. Intervals D-GH and C-GH1 have average “plug” intrinsic permeability to nitrogen values of 1700 mD and 675 mD, respectively. These values are in strong contrast with those of the overlying, gas-hydrate-free sediments, which have k values of 5.7 mD and 49 mD, respectively, and thus would have provided effective seals to trap free gas. The relation between permeability and porosity critically influences the occurrence of GH. For example, an average increase of 4% in porosity increases permeability by an order of magnitude, but the presence of a second fluid (e.g., methane from dissociating gas hydrate) in the reservoir reduces permeability by more than an order of magnitude.
    Description: This work was supported by the Coastal and Marine Geology, and Energy Programs of the U.S. Geological Survey and funding was provided by the Gas Hydrate Program of the U.S. Department of Energy.
    Keywords: Gas hydrate ; Sagavanirktok Formation ; Milne Point ; Physical properties ; Grain size ; Mineralogy ; Porosity ; Permeability
    Repository Name: Woods Hole Open Access Server
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  • 7
    Publication Date: 1997-01-01
    Print ISSN: 0149-1423
    Electronic ISSN: 1943-2674
    Topics: Geosciences
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  • 8
    Publication Date: 2017-10-05
    Description: Total organic carbon (TOC) content of marine sediments represents residual carbon, originally derived from terrestrial and marine sources, which has survived seafloor and shallow subseafloor diagenesis. Ultimately, its preservation below the sulfate reduction zone in marine sediments drives methanogenesis. Within the gas hydrate stability zone (GHSZ), methane production along continental margins can supersaturate pore fluids and lead to the formation of gas hydrate. In this paper we examine the inventory and sources of TOC in sediments collected from four regions within the GHSZ along the Indian continental margins. The recovered sediments vary in age from Oligocene to recent. Mean TOC abundance is greatest in the Krishna-Godavari (K-G) Basin and decreases progressively to the Mahanadi basin, Andaman wedge, and Kerala-Konkan (K-K) Basin. This decrease in TOC is matched by a progressive increase in biogenic CaCO3 and increasing distance from terrestrial sources of organic matter and lithogenic materials. Organic carbon sources inferred from C/N and delta C-13(TOC) range from terrestrial (K-G Basin) to mixed marine and terrestrial (Mahanadi Basin), to marine dominant (Andaman wedge and K-K Basin). In the K-G Basin, variation in the bulk delta C-13(TOC) is consistent with changes in C-3 and C-4 vegetation driven by monsoon variability on glacial-interglacial timescales, whereas in the Mahanadi Basin a shift in the delta C-13(TOC) likely reflects the onset of C-4 plant deposition in the Late Miocene. A large shift the delta C-13(TOC) in the K-K basin is consistent with a change from C-3 to C-4 dominated plants during the middle Miocene. We observe a close relationship between TOC content and gas hydrate saturation, but consider the role of sedimentation rates on the preservation of TOC in the zone of methanogenesis and advective flow of methane from depth. Although TOC contents are sufficient for in situ methanogenesis at all the sites where gas hydrates were observed or inferred from proxy data, seismic, borehole log, pressure core, and gas composition data coupled with relatively high observed gas hydrate saturations suggest that advective gas transport may also play a role in the saturation of methane and the formation of gas hydrates in these regions. Although TOC content may be a first order indicator for gas hydrate potential, the structural and stratigraphic geologic environment along a margin will most likely dictate where the greatest gas hydrate saturations will occur.
    Type: Article , PeerReviewed
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