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  • nitrogen  (123)
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  • Springer  (232)
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  • 1
    ISSN: 1572-882X
    Schlagwort(e): cellulose alkyl esters ; poly(∈-caprolactone) ; blends ; miscibility ; DSC
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Land- und Forstwirtschaft, Gartenbau, Fischereiwirtschaft, Hauswirtschaft , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Abstract Cellulose alkyl esters, CELL- OCOCnH2n+1(n = 1 ∼ 6), were synthesized by a homogeneous reaction of cotton cellulose with different acyl chlorides in N,N-dimethylacetamide--lithium chloride solution. The miscibility of the esterified celluloses with poly(∈-caprolactone) (PCL) was investigated, mainly through thermal analysis by differential scanning calorimetry (DSC). A polymer pair, cellulose butyrate (CB)/PCL, showed the highest miscibility of all the binary blends examined here; this is usual when relatively high-substituted esters (DS ≥ 2.0) are used as the respective component. The butyl ester derivatives with DS ≤ 1.5 showed poor miscibility with PCL
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  • 2
    ISSN: 1432-0789
    Schlagwort(e): Key words Microbial biomass C ; Water-soluble organic carbon ; Light fraction organic carbon ; Fertilizer ; nitrogen ; 13C nuclear magnetic resonance ; Infrared spectrophotometry
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie , Geologie und Paläontologie , Land- und Forstwirtschaft, Gartenbau, Fischereiwirtschaft, Hauswirtschaft
    Notizen: Abstract Soil samples taken from four experimental sites that had been cropped to continuous corn for 3–11 years in Ontario and Quebec were analyzed to evaluate changes in quantity and quality of labile soil organic carbon under different nitrogen (N) fertility and tillage treatments. Addition of fertilizer N above soil test recommendations tended to decrease amounts of water-soluble organic carbon (WSOC) and microbial biomass carbon (MBC). The quality of the WSOC was characterized by 13C nuclear magnetic resonance and infrared spectrophotometry and the results indicated that carbohydrates, long-chain aliphatics and proteins were the major components of all extracts. Similar types of C were present in all of the soils, but an influence of management was evident. The quantity of soil MBC was positively related to the quantities of WSOC, carbohydrate C, and organic C, and negatively related to quantities of long-chain aliphatic C in the soil. The quantity of WSOC was positively related to the quantities of protein C, carbohydrate C, and negatively related to the quantity of carboxylic C. The quantity of soil MBC was not only related to quantities of soil WSOC but also to the quality of soil WSOC.
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  • 3
    Digitale Medien
    Digitale Medien
    Springer
    Biology and fertility of soils 26 (1997), S. 31-34 
    ISSN: 1432-0789
    Schlagwort(e): Key words Microbial biomass ; Air-drying ; Extractable ; nitrogen ; Extractable phosphorus ; Tropical soil
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie , Geologie und Paläontologie , Land- und Forstwirtschaft, Gartenbau, Fischereiwirtschaft, Hauswirtschaft
    Notizen: Abstract The microbial contribution to extractable N and P after the air-drying of eight Indian dry tropical Ultisols was quantified. Air-drying of the soils decreased microbial biomass C by 25–53% but increased extractable N and P by 14–34% and 24–121%, respectively. This increase in the extractable N and P was accounted for, to some extent, by microbial biomass killed due to air-drying. Microbial biomass contributes 17–36% and 19–82% to the extractable N and P, respectively, possibly due to air-drying of the soils. I conclude that due to contamination of microbial biomass with the available nutrients in air-dried soils, measurements of extractable nutrients should be made on field-moist soils.
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  • 4
    Digitale Medien
    Digitale Medien
    Springer
    Nutrient cycling in agroecosystems 48 (1997), S. 241-246 
    ISSN: 1573-0867
    Schlagwort(e): barley ; denitrification ; fertilizerefficiency ; mineralization ; nitrogen ; sludge
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Land- und Forstwirtschaft, Gartenbau, Fischereiwirtschaft, Hauswirtschaft
    Notizen: Abstract Enhanced microbial activity following sewage sludge land application may affect soil N cycling and, therefore, plant available N. We studied the effect of anaerobically treated sewage sludge on N-fertilizer efficiency and on some aspects of the soil N cycling. Field plots (3 m × 9 m) sown with barley (Hordeum vulgare L.) in November were amended with a) sludge (80 mg ha-1) and ammonium nitrate (150 kg N ha-1), b) ammonium nitrate (150 kg ha-1) only, c) or left unamended. Monthly soil samples were taken from 0 to 20-and 20 to 50-cm depths to determine soil inorganic N (NH4 +, NO3-). Denitrification in the upper 20-cm horizon was estimated by measuring N2O+N2 emission from undisturbed soil samples by the acetylene-inhibition technique. Crop yield parameters were analysed before harvesting, and grain production was recorded. With respect to the control, the yield increase for the N-fertilizer treatment was 85% and 45% for the sludge + N-fertilizer treatment. The decrease of N-fertilizer efficiency in sludge amended plots was presumably due to a decrease in spring plant available N. Presumably, microbial immobilisation and denitrification in organic amended treatments were responsible for the decrease in N-fertilizer efficiency.
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  • 5
    Digitale Medien
    Digitale Medien
    Springer
    Nutrient cycling in agroecosystems 48 (1997), S. 37-50 
    ISSN: 1573-0867
    Schlagwort(e): greenhouse gases ; nitrogen ; NOx ; nitrous oxide ; ozone precursors ; trace gases
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Land- und Forstwirtschaft, Gartenbau, Fischereiwirtschaft, Hauswirtschaft
    Notizen: Abstract Over 60 published papers reporting field measurements of emissions of nitric oxide (NO) from soil are reviewed, and over 100 annual estimates of NO emissions were made for various types of ecosystems, including agricultural fields. These data were stratified by biome and the mean of each stratum was multiplied by an estimate of the biome area. A few strata were identified as clearly having low NO emissions: montane forests, swamps and marshes, tundra, and temperate forests that are not heavily affected by N deposition. The largest emissions were observed in tropical savanna/woodland, chaparral, and cultivated agriculture, but variation in NO emissions within these strata was also large. Although the stratification scheme fails to partition this within-stratum variation, it does clearly identify these biomes as globally important sources of NO and as areas where more research is needed to investigate within-biome variation in NO emissions. It is too early to tell whether differences in NO emissions between temperate and tropical agriculture are significant, but it is clear that agriculture is an important source of NO and that management practices affect NO emissions. The best current estimate of the global soil source of NO is 21 Tg N yr-1. Adsorption of NOx onto plant canopy surfaces may reduce emissions to the atmosphere to as low as 13 Tg N yr-1, although the absorption effect is probably smaller than this. An error term for the global estimate is difficult to determine, but it is at least ±4 and perhaps as large at ±10 Tg N yr-1. Hence, only modest progress has been made in narrowing uncertainties in the estimate of the global soil source of NO, although some published lower estimates appear unlikely. This inventory reconfirms that the soil source of NO is similar in magnitude to fossil fuel emissions of NOx. Further narrowing of the uncertainty of the estimate of global soil NO emissions will require more sophisticated and carefully chosen stratification schemes to address variation within biomes based on soil fertility, soil texture, climate, and management and will require linking this type of inventory and stratification with mechanistic models.
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  • 6
    ISSN: 1572-9680
    Schlagwort(e): fibre ; intake ; nitrogen ; palatability ; tannin
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Land- und Forstwirtschaft, Gartenbau, Fischereiwirtschaft, Hauswirtschaft
    Notizen: Abstract The aim of this work was to assess whether degradability, gas production or chemical constituents could predict the preference of browses. Forty tropical browse species leaves with a crude protein (CP) content ranging from 79 to 307 g kg-1 DM were used for this study. The neutral detergent fibre (NDF) ranged from 220 to 694 g kg-1 DM, while acid detergent fibre (ADF) ranged from 146 to 523 g kg-1 DM. The NDF-bound nitrogen (NDFN) and ADF-bound nitrogen were particularly high in Calliandra calothyrsus, Acacia polyacantha, Sesbania sesban, Acacia venosa and Acacia hockii. High levels of tannins were observed in Acacia species especially A. dolichocephala, A. hockii, A. microbotrya and A. salicina. High levels were also observed in Flemingia macrophyla and Leucaena pallida. The browse species differed (P 〈 0.05) in DM in sacco degradability coefficients. High potential degradability (PD) and effective degradability (ED) were observed in Sesbania spp, Moringa stenopetala, Indigofera arrecta, Chamaecytisus palmensis and Atriplex spp. The browses differed (P 〈 0.05) in asymptotic gas (Ag) production (ml g-1 OM), but had similar (P 〉 0.05) times of incubation at which half of the asymptotic gas had been formed. Preference and DM intake were positively correlated (P 〈 0.01) to NDFN, but negatively correlated (P 〈 0.05) to NDF and ADF. The PD and Ag were negatively (P 〈 0.001) related to NDF, ADF and lignin. Total phenols (TP) and condensed tannins (CT) were negatively (P 〈 0.05) related to PD, ED and Ag. A positive correlation was observed between CT and NDF-bound condensed tannins (r = 0.55, P 〈 0.001) and, CT and TP (r = 0.40, P 〈 0.01). Prediction equations were poor for DM intake and preference, moderate for gas production and good for potential and effective degradabilities. The phenolic components were more related to dry matter degradation and gas production than to preference and dry matter intake. NDFN and Ag made a positive contribution to both preference and DM intake. It was concluded that chemical constitutes such as N, NDF, NDFN, ADF and lignin are essential to predict the nutritive value of browses.
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  • 7
    ISSN: 1432-1017
    Schlagwort(e): Key words Phosphatidylcholine ; Phosphatidylglycerol ; DSC ; Phase diagrams ; Miscibility ; Nonideality parameter
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie , Physik
    Notizen: Abstract The miscibility of phosphatidylcholine (PC) and phosphatidylglycerol (PG) with different chain lengths (n = 14, 16) was examined by differential scanning calorimetry (DSC) at pH 2 and pH 7. The determination of the coexistence curves of the phase diagrams was performed using a new procedure, namely the direct simulation of the heat capacity curves as described recently (Johann et al. 1996, Garidel et al. 1997). From the simulations of the heat capacity curves first estimates for the nonideality parameters for nonideal mixing as a function of composition were obtained and phase diagrams were constructed using temperatures for the onset and offset of melting which were corrected for the broadening effect caused by a decrease in cooperativity of the transition. In most cases, the composition dependence of the nonideality parameters indicated nonsymmetric mixing behavior. The phase diagrams were further refined by simulations of the coexisting curves using a four-parameter model to account for nonideal and nonsymmetric mixing in the gel as well as in the liquid-crystalline phase. The mixing behavior of the systems was analyzed as a function of pH and chain length difference to elucidate the effect of these two parameters on the shape of the phase diagrams. At pH 7 the phase boundaries are much closer together and a narrower coexistence range is obtained compared to the corresponding phase diagrams at pH 2. For DPPC/DMPG at pH 2, the shape of the phase diagram and the strongly positive nonideality parameter ρ 1 for the liquid-crystalline phase indicates an upper azeotropic point. This indicates an unusual behavior of the system, namely more pronounced clustering of like molecules in the liquid-crystalline phase compared to the gel phase.
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  • 8
    ISSN: 1572-8943
    Schlagwort(e): DSC ; polyethylenes ; X-ray
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract In thermal analysis polyethylenes can be characterized by their melting temperature. With the polyethylene mixtures studied, we obtained the best results during solidification. Crystallization temperature decreased in the order: high density PE, low density PE linear, radical low density PE. Calorimetric measurement of crystallization enthalpies allowed the determination of the composition of each of the polyethylenes, in regenerated and recycled mixtures in relation with the frame of the plastic waste valorisation process. The rate of crystallization obtained from X-ray diffraction spectra of these polymers is function of their volumic mass. A good agreement has been observed between these two techniques.
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  • 9
    Digitale Medien
    Digitale Medien
    Springer
    Journal of thermal analysis and calorimetry 49 (1997), S. 79-85 
    ISSN: 1572-8943
    Schlagwort(e): cross-linking degree ; DSC ; enthalpy relaxation ; epoxy resins ; physical aging ; reactive diluent
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Structural relaxation in different epoxy-anhydride and epoxy-diamine resins has been investigated by differential scanning calorimetry using annealing and cooling rate experiments. The annealing experiments lead to the determination of enthalpy loss,δH, at an equivalent annealing temperatureT a=T g-20, and for periods of annealing time, ta, between 1 h and 4 months. The variation ofδH with logta, defines a relaxation rate per decade,rrpd, which is very sensitive to changes of the epoxy network. The cooling rate experiments allow the determination of the apparent activation energy,δh *. The effect of the degree of crosslinking, the addition of a reactive diluent, which acts as flexibilizer, and the length of cross-link onrrpd and δh* was studied.
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  • 10
    Digitale Medien
    Digitale Medien
    Springer
    Journal of thermal analysis and calorimetry 49 (1997), S. 149-154 
    ISSN: 1572-8943
    Schlagwort(e): DSC ; heterogeneity in polymer network ; poly(methacrylic acid)-net-poly(oxytetramethylene) ; thermogravimetry
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract TG and DSC were carried out on PMAA-net-POTM in order to elucidate the relation between the heterogeneity and the thermal changes; moreover, TG and DSC were carried out on PPOTMDM and PMAA to compare the results. The onset temperature in the last stage in the TG curve of PMAA-net-POTM increases as the concentrations of DMF and POTMDM in the polymerization decrease. This is explained in terms of plasticizers effects. A single peak due to fusion of POTM chains appears in the DSC curves of most copolymers. However, it is not seen in the DSC curves of copolymers with high heterogeneity. This is explained in terms of the freezing of POTM chains by frozen heterogeneous moieties.
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  • 11
    Digitale Medien
    Digitale Medien
    Springer
    Journal of thermal analysis and calorimetry 49 (1997), S. 177-182 
    ISSN: 1572-8943
    Schlagwort(e): bismaleimide resin ; CTBN ; curing behaviour ; DSC ; TG
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Bismaleimide resin (Compimide 353) was modified with the liquid elastomer carboxyl-terminated acrylonitrile butadiene (CTBN). The prereaction synthesis and curing of the CTBN-bismaleimide resin is discussed. The structure of the modified resin was identified by IR and NMR spectroscopy. The basic curing mechanism is also discussed. DSC and TG were used to study the curing behaviour and kinetic parameters, viz. the order of reaction, energy of activation and preexponential factor. Adhesive properties such as lap shear strength and peel strength at room temperature and elevated temperature were evaluated and are discussed.
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  • 12
    Digitale Medien
    Digitale Medien
    Springer
    Journal of thermal analysis and calorimetry 49 (1997), S. 343-349 
    ISSN: 1572-8943
    Schlagwort(e): double melting peak ; DSC ; fiber ; polyethylene
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The multiple melting peaks observed on differential scanning calorimetry (DSC) of ultrahigh molar-mass polyethylene fibers (UHMMPE) are analyzed as a function of sample mass. Using modern DSC capable of recognizing single fibers of microgram size, it is shown that the multiple peaks are in part or completely due to sample packing. Loosely packed fibers fill the entire volume of the pan with rather large thermal resistance to heat flow. On melting, the fibers contract and flow to collect ultimately at the bottom of the pan. This process seems to be able to cause an artifact of multistage melting dependent on the properties of the fibers. A method is proposed to greatly reduce, or even eliminate, errors of this type. The crucial elements of the analysis of melting behavior and melting temperature are decreasing the sample size and packing the individual fibers in a proper geometry, or to introduce inert media to enhance heat transport.
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  • 13
    Digitale Medien
    Digitale Medien
    Springer
    Journal of thermal analysis and calorimetry 49 (1997), S. 399-405 
    ISSN: 1572-8943
    Schlagwort(e): DSC ; polyimide fiber ; TMA ; TG
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract A commercially available polyimide fiber was investigated as a possible precursor for the formation of carbon fibers. The thermal response of the fiber was thoroughly investigated using DSC, TMA and TG. These responses were dependent on the atmosphere and tension during scanning. The fiber was stabilized at high temperatures both in inert and oxidative environments and the effect of these stabilization treatments on the structure and properties of the fiber was carefully followed. During heating, the fiber showed shrinkage tendency at small tensions, but at higher tensions the fibers could be stretched. Among the two environments investigated, air was more effective than nitrogen in getting a more stable fiber.
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  • 14
    Digitale Medien
    Digitale Medien
    Springer
    Journal of thermal analysis and calorimetry 49 (1997), S. 407-415 
    ISSN: 1572-8943
    Schlagwort(e): compatibility ; covulcanization ; derivative heat flow (δW/δT) ; DSC ; microheterogeneous
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Derivative heat flow curves give much more information about the phase heterogeneity of binary blends composed of NR, SBR and BR elastomers thanT g. In blend compositions, the areas under the derivative heat flow curves appear to be an additive function of the concentration of elastomers in the case of incompatible blends (NR/BR, NR/SBR). They are less than additive for either a partially compatible blend (uncured SBR/BR) or a compatible blend (covulcanized SBR/BR). In the case of 60/40 SBR/BR blends, a DSC (T 0.5) reveals a singleT g, in conformity with the earlier investigators, whereas the derivative heat flow curve shows two peaks (T p) indicating incomplete homogenization of the phases. This is a new observation not mentioned in the published literature. Thus, derivative heat flow traces are likely to provide a unique tool to determine compatibility of elastomers. The study also reveals the importance of sample contact with the DSC pan in quantitative determinations.
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  • 15
    Digitale Medien
    Digitale Medien
    Springer
    Journal of thermal analysis and calorimetry 49 (1997), S. 449-454 
    ISSN: 1572-8943
    Schlagwort(e): DSC ; network ; polyethylene ; turbidimetry
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Semicrystalline polymers are made of a crystalline phase and of an amorphous phase. Recently, NMR, Raman and FTIR experiments have identified a third phase comprised of defects such as tie-molecules, in the organization of chains. Our investigation of physical gels has led us to believe that by following the heat flow in a very slow temperature ramp (0.05 K min−1), phasechanges, unnoticed in the usual fast ramp, could be detected. These are associated to a physical network strained in the temperature ramp. In order to obtain more information on the network phase, the polymer has been crosslinked The characteristics obtained by slow calorimetry and turbidimetry of the original and modified materials are compared.
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  • 16
    Digitale Medien
    Digitale Medien
    Springer
    Journal of thermal analysis and calorimetry 49 (1997), S. 483-490 
    ISSN: 1572-8943
    Schlagwort(e): carboxyterminated polybutadiene ; DSC ; DMA ; SEM ; toughened epoxy
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract A new type of toughened epoxy polymer based on epoxy cresol novolac resin (ECN) and carboxy terminated polybutadiene (CTPB) liquid functional rubber has been studied. ECN has been synthesized in the laboratory and CTPB used was also of indigenised origin. Rubber modified epoxies were characterized with the help of differential scanning calorimetry (DSC), dynamic mechanical analysis (DMA) and scanning electron microscopy (SEM) techniques.
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  • 17
    Digitale Medien
    Digitale Medien
    Springer
    Journal of thermal analysis and calorimetry 49 (1997), S. 477-481 
    ISSN: 1572-8943
    Schlagwort(e): DSC ; EVA blends ; phenolic resin ; TG-DTG
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The properties of polymeric blends originate from the synergistic association of their components. In this investigation, phenolic resins obtained by the reaction of cashew-nut shell liquid (CNSL) and aldehyde are used in several applications. Mixtures of CNSL with industrial reject ethylene-co-vinyl acetate (EVA reject) were prepared with an EVA reject content up to 70%. The thermal compatibility and stability were evaluated by means of thermogravimetry (TG), derivative thermogravimetry (DTG) and differential scanning calorimetry (DSC). For blends containing a high percentage of EVA reject, the TG curves clearly show two decomposition stages, one at 350
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  • 18
    Digitale Medien
    Digitale Medien
    Springer
    Journal of thermal analysis and calorimetry 49 (1997), S. 513-520 
    ISSN: 1572-8943
    Schlagwort(e): DSC ; glass transition ; heat capacity ; melting transition ; nanophases ; polymers
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Polymer molecules have contour lengths which may exceed the dimension of microphases. Especially in semicrystalline samples a single molecule may traverse several phase areas, giving rise to structures in the nanometer region. While microphases have properties that are dominated by surface effects, nanometer-size domains are dominated by interaction between opposing surfaces. Calorimetry can identify such size effects by shifts in the phase-transition temperatures and shapes, as well as changes in heat capacity. Specially restrictive phase structures exist in drawn fibers and in mesophase structures of polymers with alternating rigid and flexible segments. On several samples shifts in glass and melting temperatures will be documented. The proof of rigid amorphous sections at crystal interfaces will be given by comparison with structure analyses by X-ray diffraction and detection of motion by solid state NMR. Finally, it will be pointed out that nanophases need special attention if they are to be studied by thermal analysis since traditional ‘phase’ properties may not exist.
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  • 19
    ISSN: 1572-8943
    Schlagwort(e): dielectric spectroscopy (DETA) ; DSC ; dynamic mechanical (DMA) spectroscopy ; glass transition ; PET ; polymers ; relaxation ; rigid amorphous ; temperature modulated DSC
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The relaxation strength at the glass transition for semi-crystalline polymers observed by different experimental methods shows significant deviations from a simple two-phase model. Introduction of a rigid amorphous fraction, which is non-crystalline but does not participate in the glass transition, allows a description of the relaxation behavior of such systems. The question arises when does this amorphous material vitrify. Our measurements on PET identify no separate glass transition and no devitrification over a broad temperature range. Measurements on a low molecular weight compound which partly crystallizes supports the idea that vitrification of the rigid amorphous material occurs during formation of crystallites. The reason for vitrification is the immobilization of co-operative motions due to the fixation of parts of the molecules in the crystallites. Local movements (Β-relaxation) are only slightly influenced by the crystallites and occur in the whole non-crystalline fraction.
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  • 20
    Digitale Medien
    Digitale Medien
    Springer
    Journal of thermal analysis and calorimetry 49 (1997), S. 745-753 
    ISSN: 1572-8943
    Schlagwort(e): DSC ; kerogen ; oxidation ; pyrolysis ; type determination
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The rate of pyrolysis and oxidation of 8 different samples of oil shale kerogen concentrate (KC) were investigated using DSC analysis. Recently performed thermogravimetric studies (TG and DTG) with the same samples of KC indicated that the activation energy of the pyrolysis of specific KCs increases with increasing paraffinic structure in the KC. An opposite effect, i.e. a decrease of the activation energy with an increase of paraffinic structure was determined in the case of KC oxidation. In this study, using the standard ASTM E-698 method based on the determined temperature at which the maximum heat effect could be observed (exo in the case of oxidation and endo in the case of pyrolysis), an activation energy for the pyrolysis, as well as for the oxidation process was determined and also successfully correlated with the content of paraffinic structure of KC. Thus, the higher content of paraffinic structure in KCs indicates that higher values of the activation energy could be determined either in the case of pyrolysis or oxidation followed by DSC analysis.
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  • 21
    Digitale Medien
    Digitale Medien
    Springer
    Journal of thermal analysis and calorimetry 49 (1997), S. 795-799 
    ISSN: 1572-8943
    Schlagwort(e): butter ; butter oil ; DSC ; recombined butter
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract DSC can be used to quickly determine if a product labeled as butter is actually a recombined butter made without milk. Recombined butter is manufactured from anhydrous milk fat, skim milk powder, water, salt, and lecithin. Melting profiles of tempered samples of natural butter and recombined butter were alike, but DSC curves from 5 to 25°C of untempered refrigerated samples revealed that the enthalpy of the melting transition around 17–20°C was much higher for natural butter than for recombined butter. The procedure for differentiating the two products can be completed in less than 20 min.
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  • 22
    Digitale Medien
    Digitale Medien
    Springer
    Journal of thermal analysis and calorimetry 49 (1997), S. 809-816 
    ISSN: 1572-8943
    Schlagwort(e): dehydration ; drying method ; DSC ; lactitol ; lactitol monohydrate ; TG ; X-ray powder diffraction
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The purpose of this study is to find out the effect of the crystal water content on the crystal structure of lactitol monohydrate. Crystal water was removed by drying over silicagel at 40°C and by using phosphorus pentoxide as drying agent at 20°C. The amouts of water removals were identified by thermogravimetry, the melting points and the heat of fusions were calculated from the results of differential scanning calorimetry measurements and the structure of samples were identified by X-ray powder diffraction method. Over 23 w/w% of total water content could removed by gently drying until significant structural changes could be detected. The melting point of anhydrous lactitol obtained by drying lactitol monohydrate was 120°C and the melting enthalpy was 102 J g−1 when measured with heating rate 10°C min−1 by DSC.
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  • 23
    Digitale Medien
    Digitale Medien
    Springer
    Journal of thermal analysis and calorimetry 49 (1997), S. 831-837 
    ISSN: 1572-8943
    Schlagwort(e): DSC ; enzymatic hydrolysis ; functional properties ; hemisphaericin ; mexicain
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract DSC was used to study the extent of denaturation of hemisphaericin and mexicain hydrolysates from corn gluten, soybean and sunflower meals. It was observed that the defatted meals studied exhibited only one broad peak transition. The data obtained demonstrated that the partial protein denaturation found with hemisphaericin or mexicain is correlated to modifications of functional properties. The two enzymes display different modes of action, according to the protein source.
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  • 24
    Digitale Medien
    Digitale Medien
    Springer
    Journal of thermal analysis and calorimetry 49 (1997), S. 913-927 
    ISSN: 1572-8943
    Schlagwort(e): anesthetic drugs ; bupivacaine hydrochloride ; dibucaine hydrochloride ; DSC ; polymorphism ; prilocaine hydrochloride ; procaine hydrochloride ; solvent mediated transitions ; temperature resolved X-ray diffraction ; tetracaine base ; tetracaine hydrochloride ; thermodynamic relationships
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The local anesthetic drug tetracaine hydrochloride is described in the Europ. Pharmacopea with a melting point of 148°C or with a range of 134 to 147°C due to the melting points of two other forms. The polymorphic behaviour of tetracaine hydrochloride has been studied by using thermal treatments, storage at 92% r.h., crystallizations and equilibrations with saturated solutions. Samples were characterized by X-ray diffraction, IR, thermal analysis and elemental analysis. Since some findings were difficult to interpret, temperature resolved X-ray diffraction was used additionally for the understanding of the thermal behaviour of tetracaine hydrochloride. In this study the polymorphic behaviour of some other local anesthetic drugs is compared. Ten different forms of tetracaine hydrochloride: six anhydrous crystalline forms, an amorphous form, a hemihydrate, a monohydrate and a tetrahydrate were identified. The relationships between all forms are given. The heating curve of the commercial form 1 is very dependent on the heating rate. This anhydrous form 1 is the thermodynamic stable modification at ambient temperature. The form 2 is reversibly enantiotrope to form 1. The four other modifications called 3, 4, 5 and 6 are monotropes of form 1. Only forms 1 and 5 are stable at ambient temperature. Form 1 is hygroscopic only at high humidity level of 92% r.h., form 5 is hygroscopic at 61% r.h. Both transform into the monohy-drate. No polymorphic forms of tetracaine base, dibucaine hydrochloride, procaine hydrochloride or prilocaine hydrochloride were found. The commercial form of bupivacaine hydrochloride is a monohydrate. Thermal treatment at 200°C gives one anhydrous form. As demonstrated by temperature resolved X-ray diffraction two other forms are detected by heating and cooling processes between 100 and 170°C. Equilibrations and crystallization experiments show that solvates are easily obtained in different solvents. Temperature resolved X-ray diffraction is a very efficient tool as a support to DSC for the identification of the transition processes and interpretation of thermal events and thermodynamic relationships. Equilibration experiments are very adequate to find out the thermodynamically stable form at ambient temperature (solvent mediated transitions).
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  • 25
    Digitale Medien
    Digitale Medien
    Springer
    Journal of thermal analysis and calorimetry 49 (1997), S. 961-970 
    ISSN: 1572-8943
    Schlagwort(e): distribution constant ; DSC ; powder compact ; Rosin-Rammler particle size distribution ; thermal resistance
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract How a DSC result is influenced by the particle size distribution of a powder sample is shown, and a simple and optimal method to be included in a routine DSC analysis (e.g., purity determination) to improve the reliability of the analysis is proposed. In case ofα-Al2O3 powder, most reliable heat capacity data can be obtained by preparing a powder with a self-similar particle size distribution with a distribution constant of 0.7, and by compressing it under a pressure of 1.5 MPa for a duration of 5 min or longer.
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  • 26
    Digitale Medien
    Digitale Medien
    Springer
    Journal of thermal analysis and calorimetry 49 (1997), S. 999-1005 
    ISSN: 1572-8943
    Schlagwort(e): DSC ; finite element method ; temperature gradients ; polymer
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Differential Scanning Calorimetry is frequently used for measurements of thermal properties on all kinds of substances. The temperature lag in the samples depend on the thermal properties and the thermal contact between sample and sample holder. In the paper, we discuss the temperature distribution in samples of comparatively low thermal conductivity, such as polymers. The purpose of this study is to pinpoint the substantial temperature differences that may occur in such bad conducting samples under different conditions. The calculations of the temperature gradients have been carried out by using a finite element software package.
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  • 27
    Digitale Medien
    Digitale Medien
    Springer
    Journal of thermal analysis and calorimetry 49 (1997), S. 991-998 
    ISSN: 1572-8943
    Schlagwort(e): cryo-microscopy ; crystallization ; DSC ; ICE ; microscopy
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract A simultaneous differential scanning calorimeter (DSC)-optical video microscope instrument has been developed. The instrument development included slight modifications to the sample head of a Perkin-Elmer DSC-7, along with the use of a CCD camera and magnifying lenses. The instrument permitted simultaneous following of optical and thermal events during isothermal and non-isothermal DSC experiments. The DSC curves were almost identical to those given by a standard DSC-7. The operational temperature range of the instrument is between −160 to 600°C. The capabilities of the DSC-video microscope are illustrated by examples of ice crystallization data in aqueous solutions of glycerol and dimethyl sulphoxide.
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  • 28
    Digitale Medien
    Digitale Medien
    Springer
    Journal of thermal analysis and calorimetry 48 (1997), S. 19-38 
    ISSN: 1572-8943
    Schlagwort(e): chalcedony ; crystalline disorder ; DSC ; DTA ; high-low quartz inversion ; silcretes
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The paper reviews studies on possible applications of the high-low quartz inversion in petrology. Since the first suggestions of Fenner and Tuttle, nearly fifty papers have dealt with the subject, including ten by the present authors. The detailed discussion of the preparative and instrumental factors which may influence the quartz inversion behaviour reveals that the DTA (DSC) runs have to be made under highly standardized conditions to permit measurement of the ‘material inherent factors’ (mainly crystal physical factors) which cause variations in shape and temperatures. The most striking variations in shape and temperatures of the inversion effect (e.g. including temperatures more than 70°C lower than the ‘textbook value’ of 573°C for the quartz inversion) are observed for microcrystalline quartz crystals. The literature and the authors' own investigation demonstrate that the most interesting field of application of the method is that of authigenic quartz formation in sediments and soils. The characterization of metamorphic quartz is more complicated. Four fields of study are chosen to demonstrate the possible application of the quartz inversion characterization for petrogenetic interpretations: (1) the differentiation between authigenic and inherited quartz crystals in sediments, (2) the characterization of the contact-metamorphic aureoles around granites, (3) special regional-metamorphic terrains and (4) (from a few so far unpublished studies) the differentiation between sedimentary and soil silcretes.
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  • 29
    Digitale Medien
    Digitale Medien
    Springer
    Journal of thermal analysis and calorimetry 48 (1997), S. 259-266 
    ISSN: 1572-8943
    Schlagwort(e): DSC ; freezable water ; muscle water
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The freezable water contents of samples obtained from previously chilled semimembranous muscle of middle-aged beef carcasses after a 24 h cooling period a room at in 5±1
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  • 30
    Digitale Medien
    Digitale Medien
    Springer
    Journal of thermal analysis and calorimetry 48 (1997), S. 473-483 
    ISSN: 1572-8943
    Schlagwort(e): dosage form ; drug products ; DSC ; identification ; quantitation ; TG
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Thermal analysis techniques, DSC and TG can advantageously be used in quality control of drug products. The methods are commonly used in preformulation for the study of polymorphism and for the study of the interactions drug substance-excipients, since these physical interactions can be the basis of the dosage form performance. For routine control of the drug products, DSC and TG methods which are quick, which require only few mg of the samples and which are automated, are very attractive for routine analysis of drug products. A single scan can give several qualitative and quantitative informations. DSC offer analytical possibilities only if the drug substance and the excipients do not have physical interactions or limited interactions (e.g. eutectic behaviour). About twenty marketed products have been analyzed by DSC and TG. In most of them identification of drug substance is easy. Several excipients could be identified in a tablet. Quantitations are demonstrated for some drug substances and excipients. DSC purity calculations have been applied to acetyl salicylic acid, paracetamol, cimetidine, pindolol, ibuprofen.
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  • 31
    Digitale Medien
    Digitale Medien
    Springer
    Journal of thermal analysis and calorimetry 48 (1997), S. 437-445 
    ISSN: 1572-8943
    Schlagwort(e): cardiac glycoside binding ; DSC ; membrane protein ; membrane receptor binding ; Na+ ; K+-ATPase ; thermal unfolding ; titration calorimetry
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract DSC studies are carried out to characterize Na+,K+-ATPase isolated from pig kidney in its natural membrane environment as well as in its purified state upon detergent treatment. The transition temperatures of the investigated thermal protein unfolding process, observed between 43 and 64.5° C, depend on the local membrane environment as well as onpH. In addition, the transition temperature is significantly increased upon binding of different cations and ligands which are known to interact with the enzyme. Evidence for a lipid phase transition around 23 °C in the original biological membrane is reported. The application of a calorimeter equipped with removable cells appears to be more suitable for the investigation of this type of membrane sample than an instrument with fixed capillary cells. Filling the sample capillary cell with an usual syringe, consisting of a long and thin needle, can influence the experimental results. Na+, K+ -ATPase acts as the receptor for cardiac glycoside binding. The thermodynamic parameters of this binding process are determined by titration calorimetry. The binding of ouabain, as a typical example, is unusually slow and is enthalpy driven. The enthalpy change upon binding enthalpy is −75 kJ mol−1 at 25 °C. The surprisingly low stoichiometric coefficient, resulting from an evaluation based on a simple one step binding model, is interpreted in terms of a dimeric receptor unit.
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  • 32
    Digitale Medien
    Digitale Medien
    Springer
    Journal of thermal analysis and calorimetry 48 (1997), S. 647-656 
    ISSN: 1572-8943
    Schlagwort(e): aluminate sodalite ceramics ; ceramics ; dielectric properties ; DSC ; ferroelectric transitions
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Aluminate sodalite ceramics, (Sr8Al12O24)(CrO4)2) — SACR, have been prepared from solution spray-dried precursors. The spray drying of a mixed aqueous nitrate solution gave an anhydrous powder which was thermally decomposed in air at 1350 °C to give a crystalline SACR powder with a median volume diameter of 4–6 μm. The SACR powder was dry pressed and sintered to 〉90% density. The yellow SACR powder showed two phase transitions between 10 and 45 °C with a 25 ° intermediate phase region indicative of a low defect concentration in the crystalline structure. A colour change observed in the sintered ceramic (changing to a mixed green/yellow) and a narrowing of the phase transition region (15–40 °C) are discussed. Dielectric measurements were consistent with the presence of two extrinsic ferroelectric transitions at 17 and 35 °C.
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  • 33
    Digitale Medien
    Digitale Medien
    Springer
    Journal of thermal analysis and calorimetry 48 (1997), S. 691-696 
    ISSN: 1572-8943
    Schlagwort(e): conglomerate ; DSC ; melting phase diagram ; recemic compound
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The phenomena of conglomerate formation-racemic compound formation were investigated in a series of five (N-alkyl)-2′,6′-pipecoloxylidides. The optically active enantiomers were prepared by optical resolution of the racemates using 2R,3R-tartaric acid and 0,0′-dibenzoyl-2R,3R-tartaric acid as resolving agent. By DSC measurement of the racemates and the enantiomer the binary phase diagrams were determined. Among the four racemic molecular compounds the N-methyl derivative is the more stable. By increasing the length of the alkyl chain the stability of the racemic compound decreased, and in case of the longest -butyl-chain conglomerate formation was observed.
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  • 34
    Digitale Medien
    Digitale Medien
    Springer
    Journal of thermal analysis and calorimetry 48 (1997), S. 727-734 
    ISSN: 1572-8943
    Schlagwort(e): DSC ; monosulfide solid solution ; system Fe-Ni-S
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The decay of a monosulphide solid solution (mss) with the composition (Fe1−1Nix)0.96S was investigated by means of differential scanning calorimetry in the temperature range, from 20 to 305
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  • 35
    Digitale Medien
    Digitale Medien
    Springer
    Journal of thermal analysis and calorimetry 49 (1997), S. 1305-1314 
    ISSN: 1572-8943
    Schlagwort(e): DSC ; electrolytic capacitors ; etched Al foils ; thermal resistance ; transient state
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract A DSC method for evaluating the surface area of etched Al foils for use in high performance electrolytic capacitors is presented. A linear relationship between the etching degree (effective surface area) and the thermal resistance of the sample is obtained by means of DSC, based on the transient phenomenon. This method using the transient state in DSC measurement is not only novel, but also rapid and simple in evaluating the surface area of an etched aluminum foil. The method is effective even when the Al foil has a naturally oxidized surface.
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  • 36
    Digitale Medien
    Digitale Medien
    Springer
    Journal of thermal analysis and calorimetry 49 (1997), S. 1357-1364 
    ISSN: 1572-8943
    Schlagwort(e): chemisorption ; desorption ; DSC ; dynamic FT-IR silver powder ; XPS
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The mechanism of adsorption and desorption of ethyl cellulose (EC) on and from silver powder was studied. After analysis with DSC, XPS and dynamic FT-IR, which could be heated by a program-controlled heater, applied to observe the states of pure EC and of EC adsorbed on silver powder, and also the thermal decomposition of EC from silver powder, the chemisorption bonding bridge between the oxygen atoms of EC and the silver atoms investigated. The differences in thermal decomposition between pure EC and EC adsorbed in silver powder were also studied. It was concluded that the chemisorption bonding between the oxygen atoms of EC and the silver atoms mainly involved the lone-pair electrons of the oxygen atoms on the EC chain and the outer empty 5 sp3 hybrid orbital of the silver. Because of the formation of this bridge, the bonds between neighboring carbon and oxygen atoms are weakened. As a result of this effect, the C-O bonds in the EC chain are broken more easily than the C-H bonds, which leads to the observation of -C-H- fragments in the upper space when EC adsorbed on silver is heated. When the same experiments were carried out on pure EC, almost all kinds of broken fragments of the EC molecule, including -C-H-, -C=O- and -C-O- appeared simultaneously.
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  • 37
    Digitale Medien
    Digitale Medien
    Springer
    Journal of thermal analysis and calorimetry 49 (1997), S. 1467-1475 
    ISSN: 1572-8943
    Schlagwort(e): CRTA ; DSC ; kinetics ; synthetic brochantite ; TG-DTA ; thermal decomposition
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The reaction pathway of the thermal decomposition of synthetic brochantite, Cu4(OH)6SO4, to copper(II) oxide was investigated through the detailed kinetic characterization of the thermal dehydration and desulferation processes. The dehydration process was characterized by dividing into two overlapped kinetic processes with a possible formation of an intermediate compound, Cu4O(OH)4SO4. The dehydrated sample, Cu4O3SO4, was found first to be amorphous by means of XRD, followed by the crystallization to a mixture of CuO and CuO-CuSO4 at around 776 K. The specific surface area and the crystallization behaviour of the amorphous dehydrated compound depend largely on the dehydration conditions. The thermal desulferation process is influenced by the gross diffusion of the gaseous product SO3, which is governed by the advancement of the overall reaction interface from the top surface of the sample particle assemblage to the bottom.
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  • 38
    Digitale Medien
    Digitale Medien
    Springer
    Journal of thermal analysis and calorimetry 50 (1997), S. 365-373 
    ISSN: 1572-8943
    Schlagwort(e): DSC ; heat capacity ; indium ; linearity ; modulated DSC
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Experiments using a commercial modulated DSC (MDSC) for the measurement of specific heat capacity of a sample have been carried out. It is found that because the amplitude of heat flow of MDSC is a complicated non-linear function of various experimental conditions such as the modulation frequency and the heat capacities of a sample and pan, the methodology of heat capacity determination using an MDSC in a single run has not been justified. The experimental results, on the other hand, agree with the theoretical equation of one of the authors. It is therefore concluded that the capabilities of MDSC should be further examined.
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  • 39
    Digitale Medien
    Digitale Medien
    Springer
    Journal of thermal analysis and calorimetry 50 (1997), S. 625-632 
    ISSN: 1572-8943
    Schlagwort(e): DSC ; NMR ; 8-quinolinol compounds ; TG-DTG ; stability ; thermal decomposition
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Solid M-Ox compounds, whereM represents Mg(II), Zn(II), Pb(II) and NbO(III), and Ox is 8-quinolinol, have been prepared. Thermogravimetry, derivative thermogravimetry (TG, DTG), differential scanning calorimetry (DSC), nuclear magnetic resonance (NMR) and infrared absorption spectra (IR) have been used to characterize and to study the thermal stability and thermal decomposition of these compounds.
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  • 40
    Digitale Medien
    Digitale Medien
    Springer
    Journal of thermal analysis and calorimetry 49 (1997), S. 1125-1134 
    ISSN: 1572-8943
    Schlagwort(e): calibration material ; calibration procedure ; DSC ; heat calibration ; heat flow rate calibration ; standards ; temperature calibration
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Metrologically based measuring procedures and evaluation methods are recommended as guidance for practical temperature, heat and heat flow rate calibration of DSC instruments which are largely independent of instrumental, test and sample parameters. The relevant terms are defined, the measuring procedures and evaluation methods described, calibration materials and their characteristic data stated and guidance for the sample handling provided. Reference is made to three extended papers on calibration. The recommendations were developed by the working group ‘Calibration of Scanning Calorimeters’ of the German Society of Thermal Analysis (GEFTA).
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  • 41
    Digitale Medien
    Digitale Medien
    Springer
    Journal of thermal analysis and calorimetry 50 (1997), S. 773-783 
    ISSN: 1572-8943
    Schlagwort(e): DSC ; FT-IR ; kinetics and mechanism ; SEM ; sodium hydrogencarbonate ; thermal decomposition
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract New EGA findings revealed that the small endothermal event preceding that of the main decomposition of commercial NaHCO3 involves the simultaneous evolution of water and CO2. At very high sensitivity, EGA experiments evidenced that the above (limited) evolution of gases also took place from the recrystallized material for which thermal methods gave no indication of endotherms. Careful reexamination of previous DSC results indicated that for one kind of recrystallized material a very small endotherm had been neglected. Renewed experiments revealed that this endotherm can be enhanced if the samples are prepared by crushing and sieving in a wet atmosphere. Parallel FT-IR experiments on commercial and recrystallized materials demonstrated the presence of carbonate in samples that had previously been taken just beyond the first small endotherm; this confirmed the EGA results. SEM experiments showed that surface texture changes take place when samples are heated to temperatures just above that of the preliminary endotherm. On the basis of these new findings, the interpretation previously given to the small endotherm is revised and detailed knowledge is gained on the mechanism of decomposition of NaHCO3.
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  • 42
    Digitale Medien
    Digitale Medien
    Springer
    Journal of thermal analysis and calorimetry 48 (1997), S. 287-295 
    ISSN: 1572-8943
    Schlagwort(e): (AgxK1−x)NO3 ; DSC ; IR ; solid solution
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The effect of partial replacement of K+ by Ag+ in the mixed system of KNO3 and AgNO3 during a set of DSC heating cycles was studied by means of a modern computerized DSC system. Thermal analysis was performed in the vicinity of the phase transition II → I for pure KNO3. The results revealed a large change in enthalpy and the phase transition temperature close to the morphotropic boundary x=0.5–0.6. At this boundary, the transformation enthalpy reached the maximum value of ∼101 J g−1. On the basis of the data obtained from this accurate thermal analysis work, a model is suggested for the energy barrier of rotation of the nitrate ion in the mixed nitrate system.
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  • 43
    Digitale Medien
    Digitale Medien
    Springer
    Journal of thermal analysis and calorimetry 48 (1997), S. 683-690 
    ISSN: 1572-8943
    Schlagwort(e): calorimetry ; DSC ; egg white ; egg white fractions ; fractionation ; thermoph-pr
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Egg white is of great interest for many culinary and industrial applications. Egg white is used for coating, gluing, thickening and so on in pasta, desserts, etc. There is thus a great interest from the industrial point of view to better know this raw material, used in very large amounts in the dessert production for example, and to obtain egg white fractions with different functional properties. Various egg white fractions prepared by selected procedures were analyzed by differential scanning calorimetry (DSC). The products resulting from a given fractionation procedure can thus be described by the thermal denaturation parameters (temperatures and enthalpies) of the egg white proteins. This work demonstrates the interest of the DSC technique and proves that the fractionation procedures selected here give the expected protein fractions.
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  • 44
    Digitale Medien
    Digitale Medien
    Springer
    Journal of thermal analysis and calorimetry 48 (1997), S. 903-907 
    ISSN: 1572-8943
    Schlagwort(e): DSC ; liquid-crystalline ; PMMS-PMOBAOB ; PMOBAOB ; transformation kinetics
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The transformation kinetics of liquid-crystalline 1,4-phenylene 4-n-methoxybenzoate-4-allyl-oxybenzoate (PMOBAOB) and a liquid-crystalline poly(mesogen/methyl) siloxane (PMMS) was studied by means of a non-isothermal method using differential scanning calorimetry. This determination led to an apparent activation energy of transformation of 639.0 and 306.5 kJ mol−1, respectively. The values of the Avrami exponentn were 1.8 and 1.1. The results show that the process of transformation of PMOBAOB involves a constant number of nuclei growing in two dimensions at a constant rate, while the process of transformation of PMMS-PMOBAOB involves a constant number of nuclei growing in one dimension at a constant rate.
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  • 45
    Digitale Medien
    Digitale Medien
    Springer
    Journal of thermal analysis and calorimetry 48 (1997), S. 1229-1248 
    ISSN: 1572-8943
    Schlagwort(e): α-Cu-Al alloys ; dislocations ; DSC ; energetics ; recrystallization ; rolled ; segregation ; short-range-order
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract A general model is discussed for assessing the energy release due to the pinning of solute atoms to partial dislocations. The present approach discloses the influence of dislocation character distributions on the magnitude of this energy. In order to test its validity in αCu-Al alloys, differential scanning calorimetry (DSC) evaluations associated with the different peaks involved during linear heating were performed employing both cold worked and quenched materials. Dislocation densities were calculated from recrystallization traces. On the basis of this model it was concluded that the observed energy difference between the deformed and the quenched materials during the exothermic peak designated as Stage 2 corresponds to the pinning process. It was also concluded that nearly equal number of edge and screw dislocations are present in the dislocation configuration of deformed alloys. Nevertheless, it is proposed that dislocation-induced order might also occur as a consequence of enhanced solute concentration around the partials.
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  • 46
    Digitale Medien
    Digitale Medien
    Springer
    Journal of thermal analysis and calorimetry 48 (1997), S. 1299-1310 
    ISSN: 1572-8943
    Schlagwort(e): compatibility ; DSC ; master curves ; mechanical measurements ; rubber blends
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The compatibility of some technically important polymer blends, namely BR/NR, NR/NBR and CR/NBR, has been investigated using the DSC method. In addition, dynamic mechanical measurements have been carried out for the NR/NBR blends over the frequency range of 10−4 Hz –200 Hz and temperatures ranging from −70 to +70°C. The results obtained show that the three rubber blends are not compatible over the entire composition range as proven by the DSC and mechanical measurements. By analyzing the heat capacity increases at the glass transitions of the separate phases in the NR/BR blend, it was possible to suggest the presence of a limited compatibility at the boundaries of the two phases. By comparing this work with prior measurements, it was possible to conclude that the calorimetric method is a more efficient tool for the study of compatibility of polymer blends when compared to ultrasonic and viscosity methods. Furthermore, it was found that polymers that show compatibility when measured with an ultrasonic method could behave compatible, semicompatible or incompatible when analyzed by DSC. On the other hand, blends that show incompatibility by the ultrasonic method are always incompatible by the DSC method.
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  • 47
    Digitale Medien
    Digitale Medien
    Springer
    Journal of thermal analysis and calorimetry 49 (1997), S. 115-121 
    ISSN: 1572-8943
    Schlagwort(e): comb-like polymer ; DSC ; fluorocarbon chain ; side-chain crystallization ; X-ray diffraction
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Thermal properties of acrylate and methacrylate monomers containing long-fluorocarbon chains (H(CF2)nCH2OCOCH=CH2, (FnA) and H(CF2)nCH2OCOC(CH3)=CH2, (FnMA), wheren=6, 8, 10) and their comb-like polymers have been investigated by differential scanning calorimeter (DSC) and X-ray diffraction. The comb-like polymers (PF10A and PF10MA) with sufficiently long-fluorocarbon chains showed a simple melting and crystallizing behavior. For the fusion of PF10A in 1st heating, enthalpy change δH f was 18 kJ mol−1 and entropy change δS f was 45 J K−1 mol−1, while for PF10MA the values δH f and δSf were 5.3 kJ mol−1 and 14 J K−1 mol−1, respectively. Melted PF8A crystallized slowly, whereas PF8MA with same fluorocarbon chain and also both of PF6A and PF6MA with shorter fluorocarbon chains can hardly crystallize by the aggregation of side-chains. Effects of the length of side-chain and the flexibility of main chain on the side-chain crystallization of comb-like polymers are clear. Crystallization process of the methacrylate monomers was sensitively affected by the scanning rate of DSC measurement and the length of fluorocarbon chains.
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  • 48
    Digitale Medien
    Digitale Medien
    Springer
    Journal of thermal analysis and calorimetry 49 (1997), S. 193-199 
    ISSN: 1572-8943
    Schlagwort(e): DSC ; liquid crystals ; temperature calibration
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The temperature calibration of a TA Instruments 3200-2920 DSC has been performed on cooling using the isotropic → nematic, isotropic → cholesteric and other liquid crystal → liquid crystal transitions of thermally stable, high purity liquid crystals. The thermal stability of these liquid crystals has been verified by measuring the temperature of the mentioned transitions during cyclic heating and cooling experiments. Correspondence has been established between the real and indicated temperature during cooling for all combinations of heating and cooling rates of practical interest: correction values were determined to the indicated temperature in order to obtain the real temperature on cooling. These correction values were calculated as the average from the temperatures of four or five different liquid crystal transitions for each heating-cooling rate combination. The accuracy of the temperature calibration on cooling is ca. 0.2
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  • 49
    Digitale Medien
    Digitale Medien
    Springer
    Journal of thermal analysis and calorimetry 49 (1997), S. 227-234 
    ISSN: 1572-8943
    Schlagwort(e): DSC ; EVA ; interaction parameter ; polymer blends ; PVC
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract In order to provide additional information on the miscibility of the PVC/EVA system, calorimetric parameters such as ΔC pi,T gi and ΔT gi were obtained with a different approach. A qualitative and quantitative measure of the blend composition at the interface was obtained. This indicated that the domains are rich in each component and the presence of the second component in the phase has little effect on the main chain relaxation. The PVC fraction in the EVA-rich phase is always larger than the EVA fraction in the PVC-rich phase. Positive and small values of the Flory-Huggins interaction parameter were obtained from calorimetric data.
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  • 50
    Digitale Medien
    Digitale Medien
    Springer
    Journal of thermal analysis and calorimetry 49 (1997), S. 235-245 
    ISSN: 1572-8943
    Schlagwort(e): DSC ; EVA ; interaction parameter ; polymer blends ; PVC
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Poly(vinyl chloride) was blended with ethylene-vinyl acetate copolymer containing 70 wt% of vinyl acetate. The system shows a single glass transition temperature for all compositions, indicating their miscibility. TheT g vs. composition curves display an inflection, which changes with the chemical environment of the initial solution. The best fit to the shape of the curve was well reproduced by the Kovacs-Braun equation. The δT g values reveal local heterogeneity, which means no total miscibility at a molecular level. Negative values of the Flory-Huggins interaction parameter were obtained from the calorimetric data.
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  • 51
    Digitale Medien
    Digitale Medien
    Springer
    Journal of thermal analysis and calorimetry 49 (1997), S. 293-301 
    ISSN: 1572-8943
    Schlagwort(e): characterization ; cis- ; trans isomers ; crystallinity ; DEA ; degradation ; DMA ; DSC ; DTG ; enthalpy ; glass transition temperature ; isomers ; vinyl
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Many of the isomers of polybutadiene and polyisoprene elastomers can be characterized by thermal analysis.T g is sensitive to side chain units (1,2 or 3,4 structure) for both polymers. Crystallinity measurements can characterizecis andtrans isomers. DMA and DEA master curves provide an idea of the heterogeneity of the chain units from the width of the loss factor curves in theT g region. Thermal and thermooxidative degradation, as followed by DSC and DTG, can differentiate specific natural and synthetic isomers of polyisoprenes in raw and vulcanized states.
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  • 52
    Digitale Medien
    Digitale Medien
    Springer
    Journal of thermal analysis and calorimetry 49 (1997), S. 303-310 
    ISSN: 1572-8943
    Schlagwort(e): curing ; DSC ; epoxy ; gel time ; gelation
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract A new method for determining the degree of conversion of gelation (αgel) and gel time (t gel) at gel point using a single technology, DSC, is discussed in this work. Four kinds of thermoset resins are evaluated. It is found that the mutation points of reduced reaction rate (V r ) vs. reaction conversion (α) curves, corresponding with the changes of reaction mechanism, represents the gelation of the reaction. The α at the mutation point is defined as αgel. From isothermal DSC curves, the point at αgel is defined ast gel. Traditional techniques (ASTM D3532 and DSC method) are also used to determine αgel andt gel in order to demonstrate this new method. We have found that the results obtained from this new method are very consistent with the results obtained from traditional methods.
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  • 53
    Digitale Medien
    Digitale Medien
    Springer
    Journal of thermal analysis and calorimetry 49 (1997), S. 693-702 
    ISSN: 1572-8943
    Schlagwort(e): DSC ; helical conformation ; poly(α-n-alkyl-L-aspartate)s
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract A series of poly(α-n-alkyl β-L-aspartate)s (n being the number of carbon atoms in the linear alkyl side chain, withn=1, 2, 4, 6, 8, 12, 18 and 22), was studied by differential scanning calorimetry and thermogravimetric analysis. The effect of the length of the alkyl group on thermal properties such as stability, melting and crystallization of side chains, was investigated. For the polymers with n≥12, two endothermic peaks at T1 and T2 were detected separating three distinct phases A, B and C. The peak at T1 corresponds to the melting of the crystallized paraffinic side chains (transition A-B), and the peak: at T2 may be attributed to a transition (B-C), implying a liquid crystal phase.
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  • 54
    Digitale Medien
    Digitale Medien
    Springer
    Journal of thermal analysis and calorimetry 49 (1997), S. 1105-1114 
    ISSN: 1572-8943
    Schlagwort(e): DSC ; resolution ; sensitivity ; test
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The Dutch Society for Thermal Analysis has developed tests to measure the resolution and the sensitivity of Differential Scanning Calorimeters. For this test the substance 4,4′-azoxyanisole is used. This substance shows two transitions: a solid to liquid crystal transition at about 117°C (ΔH≈120 J g−1) and a liquid crystal to isotropic liquid transition at about 134°C (ΔH≈2 J g−1). The resolution test is performed using an amount of 5 mg substance and a high heating rate of 20°C min−1. The resolution is evaluated by measuring how well the two peaks are separated. An amount of 0.25 mg substance and a low heating rate of 0.1 °C min−1 is used for the sensitivity test. The sensitivity is evaluated as the ratio of the peak height of the LC-transition and the top-top noise level. Members of the TAWN were asked to participate in the test. Each participant was provided with an amount of sample and a test procedure. 47 Contributions were received and these results are presented.
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  • 55
    Digitale Medien
    Digitale Medien
    Springer
    Journal of thermal analysis and calorimetry 49 (1997), S. 1321-1326 
    ISSN: 1572-8943
    Schlagwort(e): alkali metal compounds ; DSC ; heat capacity ; high temperature ; thermodynamic data
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The heat capacities of selected inorganic binary and ternary alkali metal compounds are determined using differential scanning calorimetry (DSC). As part of an ongoing research program at Battelle Memorial Institute since 1983, the heat capacities of cesium and rubidium chalcogenides, aluminates, silicates and uranates in the temperature range 310 to 800 K have been added to the series of compounds. The measured data is to be combined with the standard enthalpies of formation and low temperature heat capacities to obtain reliable thermodynamic data on the alkali metal compounds to high temperatures.
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  • 56
    Digitale Medien
    Digitale Medien
    Springer
    Journal of thermal analysis and calorimetry 50 (1997), S. 617-624 
    ISSN: 1572-8943
    Schlagwort(e): bound water ; DSC ; free water
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The differences in bound water content of beef semimembranous muscle samples obtained from previously chilled (24 h at +4°C) middle-aged beef carcasses were determined by the use of DSC. Initially, samples obtained from fresh, unprocessed meat were frozen at −40, −50 or −65°C to determine their melting peaks for freezable water (free water) content with the use of DSC. The samples were then subjected to an environment with an ambient temperature of −30, −35, −40 or −45°C, with no air circulation, or with an air circulation speed of 2 m s−1, until a thermal core temperature of −18°C was attained; this was followed by thawing the samples until a thermal core temperature of 0°C was reached. This process was followed by subjecting the samples to the ambient temperatures mentioned above, to accomplish complete freezing and thawing of the samples, with DSC, and thereby determination of the freezable water contents, which were then used to determine the peaks of melting. The calculated peak areas were divided by the latent heat of melting for pure water, to determine the freezable water contents of the samples. The percentage freezable water content of each sample was determined by dividing its freezable water content by its total water content; and the bound water content of each sample was determined by subtracting the percentage free water content from the total. In view of the fact that the free water content of a sample is completely in the frozen phase at temperatures of −40°C and below, the calculations of free and bound water contents of the samples were based on the averages of values obtained at three different temperatures.
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  • 57
    Digitale Medien
    Digitale Medien
    Springer
    Journal of thermal analysis and calorimetry 50 (1997), S. 347-354 
    ISSN: 1572-8943
    Schlagwort(e): DSC ; eutectic composition ; LiCl-KCl system ; phase diagram
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Thermal analysis of the binary system KCl-LiCl in the composition range 0.368–0.812 mol fraction of LiCl was studied by differential scanning calorimetry (DSC). On the basis of the DSC curves, the experimental data for the phase-diagram, the latent heat of fusion, and the average specific heat in the liquid and solid states are presented as a function of the composition of the mixture. The experimental results compared with literature data. The following empirical correlation between the heat of fusion (ΔH) and of compositions of the mixture in mol fraction of LiCl (x) was obtained: ·GH=26.95−50.20x+43.06x2 with a minimum value of 11.8 kJ(g mol)−1 at the eutectic point of 0.587 mol fraction of LiCl at 354.4°C. These results are required as basic data to develop thermal energy storage materials, based on the phase change of a molten mixture of KCl-LiCI.
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  • 58
    ISSN: 1573-4846
    Schlagwort(e): thorium ; tin ; phosphate xerogels ; EPR ; DSC
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Different transparent phosphate xerogels were synthesized usingconcentrated solutions of metal chlorides and phosphoric acid with aproper mole ratio of both components. By this method we prepared bulksamples of thorium and tin(IV) phosphate xerogels by drying at room temperature or at 350 K. Some properties of these amorphous materialswere studied by means of differential scanning calorimetry (DSC) andelectron paramagnetic resonance (EPR) techniques. Depending on moleratio $$\frac{{{\text{metal}}}}{{{\text{phosphate}}}}$$ , these xerogels show, near 180 K, inflection points which we interpret as T g . Samples dried at 425 K lose their transparency and have no T g . Thus, it seems that the “glassy” state is due to water molecules remaining in the material. The same properties wereconfirmed by EPR studies of the xerogels doped with Cr3+ andFe3+ ions as probes. These results show the existence of twodifferent phases in the xerogels: a liquid-like one, in the range from190 K to 350 K and a solid-like one, in the range from 4 K to 190 K.
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  • 59
    Digitale Medien
    Digitale Medien
    Springer
    Environmental and resource economics 10 (1997), S. 341-362 
    ISSN: 1573-1502
    Schlagwort(e): Baltic Sea ; eutrophication ; nitrogen ; phosphorus ; cost effective
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik , Wirtschaftswissenschaften
    Notizen: Abstract Due to eutrophication caused by heavy loads of nitrogen and phosphorus, the biological conditions of the Baltic Sea have been disturbed: large sea bottom areas without any biological life, low stocks of cods, and toxic blue green algaes. It is recognized that the nitrogen and phosphorus loads to the Baltic Sea must be reduced by 50% in order to restore the sea. The main purpose of this paper is to calculate cost effective nitrogen and phosphorus reductions to the Baltic Sea from the nine countries surrounding the Baltic Sea. The results show a significant difference in minimum costs of decreasing nitrogen and phosphorus loads to the Sea: approximately 12 000 millions of SEK per year and 3 000 millions of SEK respectively for reductions by 50%. It is also shown that a change from a policy of cost-effective nutrient reductions to a policy where each country reduces the nutrient loads by 50% increase total costs for both nitrogen and phosphorus reductions by about 300%. The results are, however, sensitive to several of the underlying assumptions and should therefore be interpreted with much caution.
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  • 60
    Digitale Medien
    Digitale Medien
    Springer
    Water, air & soil pollution 99 (1997), S. 477-486 
    ISSN: 1573-2932
    Schlagwort(e): sediment ; nitrogen ; phosphorus ; organic matter ; cluster analysis ; Gulf of Finland ; estuaries
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract Dry weight (DW), ignition loss (IL) and concentrations of total nitrogen (TN) and total phosphorus (TP) of the sediment surface layer (0 to 10 cm, 1 cm slices) were analyzed from 20 sites in the eastern Gulf of Finland. The distance of the sampling sites from the mouth of the River Neva explained the nutrient concentrations of the sediments well, while the effect of water depth was negligible. The increase of TN and the decrease of TP along the transect from the river mouth towards the open Gulf were caused by the diminishing share of allochthonous material supplied from the River Neva. The mean TN concentration of the different accumulation areas was about 40 % higher in the sediment surface than in the deeper layer (9 to 10 cm). The corresponding difference for TP varied from 53 to 56 %. The results suggest considerable netflux of nutrients from sediment to water. The net sediment accumulation of nutrients were estimated as 6.0 g m-2 a-1 of N and 1.7 g m-2 a-1 of P corresponding 22 000 t a-1 of N and 6 100 t a-1 of P for the whole eastern Gulf.
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  • 61
    Digitale Medien
    Digitale Medien
    Springer
    Water, air & soil pollution 99 (1997), S. 305-314 
    ISSN: 1573-2932
    Schlagwort(e): Adriatic Sea ; nutrients ; benthic fluxes ; carbon ; nitrogen ; silicon ; phosphorus ; budgets
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract Benthic fluxes of dissolved inorganic N, Si and P nutrients, alkalinity, dissolved inorganic C (DIC), and O2 from sediments in the Gulf of Trieste (northern Adriatic, Italy) were measured monthly in the period September 1995 – August 1996 using in situ incubated light benthic chambers. The highest efluxes of DIC, NH4 +, PO4 3−, Si(OH)4, and NO3 − influxes encountered in late summer — early autumn were the consequence of degradation of benthic microalgae, and in autumn mostly of sedimented phytoplankton. High NO3 − efflux was observed in spring. Only NH4 + and Si(OH)4 fluxes were significantly correlated with temperature. This correlation suggests that the rate of downward input and the quality and quantity of sedimentary organic matter (autochthonous and allochthonous) were superimposed on the temperature fluctuations. High DIC, NH4 + and Si(OH)4 effluxes observed in July 1996 were due to the late spring — early summer degradation of sedimentary organic matter produced by benthic microalgae, while the autumn phytoplankton bloom was quickly reflected in enhanced benthic fluxes due to higher temperature. Significant correlations between NH4 +, PO4 3− and Si(OH)4 fluxes suggested their parallel regeneration and utilization at the sediment-water interface. The nutrient fluxes were linked to O2 consumption, suggesting that aerobic oxidation processes were important at the sediment-water interface in the Gulf. The N, P and Si nutrients released from sediment pore waters are probably utilized in benthic microalgal and bottom-water primary production. This indicates that pelagic and benthic communities in the central part of the Gulf of Trieste function relatively independently of each other.
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  • 62
    Digitale Medien
    Digitale Medien
    Springer
    Water, air & soil pollution 98 (1997), S. 389-399 
    ISSN: 1573-2932
    Schlagwort(e): fertilizer ; nitrogen ; pollution ; runoff ; stable isotopes ; sugarcane
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract In many forested wetlands of Louisiana, surface water quality is being deteriorated by nutrient input from adjacent agricultural production area. This field study assesses the input of fertilizer N, applied to sugarcane fields, to forested wetlands. The potential use of natural abundance variations in15N/14N ratios for identification and tracing surface water N sources (NH 4 + - and NO 3 − -N) was evaluated. Runoff and surface water samples were collected from sugarcane fields and bordering forested wetlands (6 stations) over a 16 month period and analyzed for NH 4 + -N, NO 3 − -N, and associated NH 4 + -δ 15N and NO 3 − -δ 15N ratios. FertilizerN draining into adjacent forested wetland was estimated to be only a small fraction of the amount applied. Concentrations of NH 4 + - and NO 3 − -N in the collected water samples were low and ranged from 0.02 to 1.79 mg L−1. Isotopic analysis revealed NH 4 + -δ 15N and NO 3 − -δ 15N means were distinctive and may have the potential to be used as tracers of N contamination. The mean NH 4 + -δ 15N value was +18.6±7.1‰ and the NO 3 − -δ 15N mean was +8.3±3.1‰. Anomalously high NO 3 − -δ 15N values (〉30‰) were attributed to denitrification.
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  • 63
    ISSN: 1573-4846
    Schlagwort(e): thorium ; tin ; phosphate xerogels ; EPR ; DSC
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Different transparent phosphate xerogels were synthesized using concentrated solutions of metal chlorides and phosphoric acid with a proper mole ratio of both components. By this method we prepared bulk samples of thorium and tin(IV) phosphate xerogels by drying at room temperature or at 350 K. Some properties of these amorphous materials were studied by means of differential scanning calorimetry (DSC) and electron paramagnetic resonance (EPR) techniques. Depending on mole ratio metal/phosphate, these xerogels show, near 180 K, inflection points which we interpret asT g . Samples dried at 425 K lose their transparency and have noT g . Thus, it seems that the “glassy” state is due to water molecules remaining in the material. The same properties were confirmed by EPR studies of the xerogels doped with Cr3+ and Fe3+ ions as probes. These results show the existence of two different phases in the xerogels: a liquid-like one, in the range from 190 K to 350 K and a solid-like one, in the range from 4 K to 190 K.
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  • 64
    ISSN: 1610-7403
    Schlagwort(e): litterbag ; mass loss ; microclimate ; microcosms ; nitrogen
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Land- und Forstwirtschaft, Gartenbau, Fischereiwirtschaft, Hauswirtschaft
    Notizen: Abstract The decay rates of Japanese Konara Oak (Quercus serrata Murray) and Japanese Red Pine (Pinus densiflora Sieb. et Zucc.) leaf litter were monitored for one year. It aimed to compare the decomposition of leaf litter using microcosms set up in the field (FM) and in the greenhouse (GM), with the litterbag (LB) method as control. Results showed that incubation setting affected the decay rate (k), respiration rates and the changes in the concentrations of nitrogen (N). Thek value ofQuercus in FM was higher than LB, while thek value ofPinus was higher in the LB than in FM. The decay ratesk for both species, however, were significantly lower in GM than FM and LB, clearly suggesting that decay rate was inhibited in the greenhouse. Significant differences in microclimatic variables and soil biological activities (soil respiration) existed between greenhouse and field microcosms, hence, the decay rates were affected. The N concentrations for both litter types increased as decomposition proceeded. Decomposition studies using laboratory microcosm approach alone may lead to erroneous conclusions especially if no appropriate field studies are conducted along with it.
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  • 65
    ISSN: 1573-5052
    Schlagwort(e): Aster ; Atriplex ; Chenopodium ; nitrogen ; phosphorus ; roots ; shoots
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie
    Notizen: Abstract The loss of dry mass, nitrogen and phosphorus from shoot and root litter of mudflat annuals was examined in a series of experimental marshes in the Delta Marsh, Manitoba, Canada. Litter bags containing shoot material of three mudflat annuals (Aster laurentianus Fern., Atriplex patula L., and Chenopodium rubrum L.) were placed on the sediment surface of the marshes under drawdown conditions. In addition, litter bags containing root material of these three species were shallowly buried. Approximately 70% and 50% of both shoot and root litter, respectively, was still present after one year in the field. During the second year when the marshes were flooded, shoot and root litter lost an additional 20% and 0% of their mass, respectively. Except for Chenopodium roots, which accumulated nitrogen and phosphorus during both years, shoot and root litter lost from 0 to 50% of their nitrogen and phosphorus early in the first year, with levels generally remaining constant through the remainder of the study period. Our results indicate that mudflat annual litter decomposed slowly and would provide abundant habitat for aquatic invertebrates when these marshes were reflooded. However, most nutrient loss took place in the first year when the litter was unflooded, with little loss occurring in the second year when flooded.
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  • 66
    Digitale Medien
    Digitale Medien
    Springer
    Hydrobiologia 357 (1997), S. 165-171 
    ISSN: 1573-5117
    Schlagwort(e): fish food ; faeces ; nutrient ; nitrogen ; phosphorus
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie
    Notizen: Abstract The fish food and faeces were fractioned into the differentcomponents of phosphorus and nitrogen. There was a rapid release ofphosphorus from the fish food and faeces and a decrease thereafterwhereas ammonium release was slow at first with the rate increasingwith time. Both temperature and pH affected the release of nutrientsfrom fish food and faeces. The release of phosphorus and nitrogen washigher at higher temperatures. The maximum release of phosphorus wasat pH 4.0 whereas nitrogen release was maximum at neutral (7.0) toalkaline (10.0) media.
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  • 67
    Digitale Medien
    Digitale Medien
    Springer
    Hydrobiologia 342-343 (1997), S. 387-394 
    ISSN: 1573-5117
    Schlagwort(e): nitrogen ; phosphorus ; drainage waters ; sediments ; sorption
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie
    Notizen: Abstract Lake Łuknajno, a shallow (max. depth 3 m) and relativelylarge(630 ha) water body situated in the Great Masurian Lakessystem(Poland) is strongly affected by its agricultural watershed.Thetotal volume of drainage waters pumped into the lake in 1993amounted 2.84 × 106m3 which is equivalentto65% of the lake volume. In spring and autumn drainage waterswereextremely rich in nitrogen (especially nitrates) and the N:Pratioreached 57 in spring. In summer, drainage waters containedrelatively more phosphorus so the N:P ratio decreased tonearly 10.Nutrient concentrations in lake water followed the changes ininflowing waters. High concentrations of nitrates and ammoniawerenoted in lake water in spring but summer concentrations oftheseions were close to zero. Soluble reactive phosphorus variedbetween10 and 20 µg P l−1 throughout the season. A constantoutflow of nitrogen to the lower Lake Śniardwy was assumedbased ona permanent concentration gradient between waters of these twolakes.Lake Łuknajno is a hard water lake. Co-precipitation ofphosphorus with calcium carbonate is likely to occur though nosignificant P accumulation in bottom sediments was found.Sorptionof phosphorus on sediments as measured under experimentalconditions has minor effects on P cycling. Bottom sedimentscomposed mainly of calcareous gyttja do not accumulate eitherorganic matter or mineral forms of nutrients.
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  • 68
    ISSN: 1573-5117
    Schlagwort(e): pristine ; hydrochemistry ; podzol ; soil processes ; sulphate ; nitrogen
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie
    Notizen: Abstract During the Surface Water Acidification Programme, ahydrochemical plot study was carried out at thepristine Høylandet study site during 1986–89. Theplot soils were acidic iron podzols (sensuKubiena), with a significant content of secondaryaluminium (Al), forming a potential major source oftoxic Al in streams and lakes. Rain and mist inputscontain small amounts of anthropogenic sulphate, withammonium inputs being enhanced during the summermonths. Vegetation canopy interactions, includingsorption and leaching, change input water chemistrybefore it reaches the soil, in which organicinteractions increase, especially during the summer.Amphibole in the soil parent material is probablyresponsible for the large mineral weathering ratedetermined and this source of base cations, alliedwith the small anthropogenic inputs, results in Alconcentrations in the streamwater being small incomparison with impacted sites.
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  • 69
    ISSN: 1573-5117
    Schlagwort(e): sediment–water fluxes ; nitrogen ; chlorophyll a ; derivatives ; seasonal variations ; estuaries ; Mediterranean Coast
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie
    Notizen: Abstract The seasonal variability of sediment–water ammonium flux andoxygen uptake was studied in an estuarine bay (Alfacs Bay, Ebro Delta, NWMediterranean) influenced by temporal freshwater discharges. Three stationswith different organic loading were sampled. The relationships of benthicfluxes to bottom water (temperature, dissolved oxygen, ammonium, nitrateplus nitrite) and to sediment (porosity, chlorophyll a derivative pigments,organic carbon and nitrogen) variables were examined. Oxygen uptake rangedfrom 0.3 to 2.5 mmol m−2 h−1 and ammoniumrelease ranged from 6 to 230 µmol m−2 h−1.The lowest value was recorded at the station furthest from the freshwaterinputs, and the highest was at the littoral station nearest the freshwaterdischarge channels (for oxygen uptake) and at the deep station at the saltwedge front (for ammonium flux). Water temperature and the concentration ofchlorophyll a derivative pigments on the surface sediment were revealed asthe main variables to be taken into account to explain the variabilityfound. Changes in fluxes reflecting temperature changes were found at thestation furthest from the freshwater inputs, while at the other, fluxvariability was found to be related to the cycle of functioning offreshwater discharge channels. The different patterns of variability arediscussed in relation to the dynamics of the estuary and to the mainfeatures of benthic nitrogen cycling.
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  • 70
    ISSN: 1573-5117
    Schlagwort(e): lake sediment ; bioturbation ; chironomid larvae ; organic matter decomposition ; nutrient exchange ; nitrogen ; phosphorus
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie
    Notizen: Abstract The importance of Chironomus plumosus larvae onbenthic metabolism and nutrient exchange across thesediment–water interface was evaluated in a shalloweutrophic lake (Lake Arreskov, Denmark) following aphytoplankton sedimentation. Chironomus plumosuslarvae were added to laboratory sediment microcosms,corresponding to a density of 2825 larvae m−2.Non-inhabited microcosms served as controls. Asedimentation pulse of organic matter was simulated byadding fresh algal material (Chlamydomonasreinhardii) to sediment cores (36 g dryweight m−2). The mineralization was followed bymeasuring fluxes of O2, CO2, dissolvedinorganic nitrogen and phosphate. A rapid clearance ofalgae from the water column in faunated microcosmssuggested that chironomids may be of major importancein controlling phytoplankton concentrations in shalloweutrophic lakes. Chironomids increased the sedimentO2 uptake ≈ 3 times more than what wouldbe expected from their own respiration, indicating astimulation of microbial activity and decomposition oforganic matter in the sediment. Addition of algaeenhanced the release of CO2, NH+ 4 ando-P. The excess inorganic C, N and P released inamended non-inhabited sediment after 36 dayscorresponded to 65, 31 and 58% of the C, N and P inthe added algae. In sediment inhabited by Chironomus plumosus the corresponding numbers were147, 45 and 73%, indicating that mineralization oforganic matter also from the indigenous sediment poolwas stimulated by chironomids.
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  • 71
    Digitale Medien
    Digitale Medien
    Springer
    Hydrobiologia 364 (1997), S. 83-91 
    ISSN: 1573-5117
    Schlagwort(e): wastewater ; nitrogen ; phosphate ; constructed wetlands ; Phragmites mauritianus ; mesocosms
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie
    Notizen: Abstract Artificial wetlands have not yet been used in Ugandafor wastewater purification. The feasibility of usingartificial wetlands to improve presettled wastewaterquality was tested using 40 l experimental buckets(mesocosms) at Kirinya sewage works, Jinja, Uganda.These mesocosms were operated in an intermittent,vertical flow mode. They were synoptic experiments toa pilot constructed wetland project in which theutility of Phragmites mauritianus to treatpresettled wastewater for P and N was examined. Results showed that the laterite-gravel rootedPhragmites reactors improved the wastewater qualitysignificantly, possibly to advanced secondary ortertiary water quality levels. These reactors achievedreduction efficiency of over 90% for P and over 60%for N after a 5-day water retention time. The massbalances of N and P over the reactors, indicated ahigher uptake rate for P by the plant than for N.Laterite-gravel rooted Phragmites mesocosms weremore efficient than the floating Phragmitesmesocosms for the wastewater treatment.
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  • 72
    ISSN: 1573-904X
    Schlagwort(e): solution ; protein stability ; factor VIII ; formulation ; kinetics ; DSC
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Purpose. To investigate the influence of various nonreducing disaccharides and sugar alcohols on the inactivation kinetics of recombinant factor VIII SQ (r-VIII SQ) in aqueous solution not containing albumin as a stabiliser. Methods. The stability of r-VIII SQ was followed using measurement of activity (VIII: C) and HPLC gel filtration at different temperatures. The thermal stability was investigated using differential scanning calorimetry (DSC). Results. The decline in VIII:C followed pseudo-first order kinetics. However, the Arrhenius plot was not linear for formulations without carbohydrate, demonstrating a distinct, reproducible curvature. The reaction rate at 5°C was faster than expected from the Arrhenius kinetics. The energy of activation (Ea) for formulations without added carbohydrates, derived from the linear part of the Arrhenius plot, varied between 77 and 86 kJ/mole in the temperature range 20−37°C. The addition of 600 mg/ml sucrose increased the Ea to 104 kJ/mole. DSC measurements showed thatTm′ was 64.2 ± 0.2°C for r-VIII SQ without stabiliser. This value increased linearly with increasing concentrations of carbohydrate. This stabilising effect is most probably explained by the theory of preferential hydration. Conclusions. The inactivation kinetics of r-VIII SQ in aqueous solution without addition of carbohydrates followed pseudo-first order kinetics but the Arrhenius plot was nonlinear. Sucrose and sorbitol both had highly stabilising effects on r-VIII SQ at concentrations above 300 mg/ml. The preparation containing 600 mg/ml sucrose was stable for at least 12 months at 5°C and 6 months at 25°C.
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  • 73
    Digitale Medien
    Digitale Medien
    Springer
    Pharmaceutical research 14 (1997), S. 899-904 
    ISSN: 1573-904X
    Schlagwort(e): amorphous material ; crystallization ; solid state reaction kinetics ; XRPD ; DSC ; microcalorimetry
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Purpose. The purpose of the work was to study the crystallization kinetics of amorphous sterotex K at different temperatures and with different methods, and to compare the obtained kinetic and thermodynamic results. Methods. Isothermal microcalorimetry was the principal technique to determine the crystallization behavior of sterotex K. X-ray powder diffraction and differential scanning calorimetry were employed to interpret the microcalorimetric heat flow curves and compare the kinetics and the calculated value for the transition enthalpy. Results. The best way to analyze the x-ray diffractograms was the statistic Wakelin's correlation method. The method gave consistent quantitative results with microcalorimetry and both methods showed crystallization to consist of two partially parallel part-processes, which attached probably to the different growing rates of the forms consisting of different lattice planes having the same spacing. The quantitative analysis of differential scanning calorimetry scans was troublesome to perform but the obtained average value of −51 J/g for the enthalpy of the crystallization was in good agreement with the values obtained with the other methods, the average being −52 J/g. Calculating heat flow versus released energy plots from the microcalorimetric data the crystallization mechanism was observed to change as a function of temperature. Conclusions. A sensitive isothermal microcalorimeter can give precise and fast knowledge about possible solid state transition mechanism, but the source of the heat flow signal must be verified with other analytical methods to avoid incorrect conclusions. Due to the sensitivity and the real-time data the microcalorimetry can show up the mechanism of the transition for varying as a function of temperature and reveal the uselessness of the conventional Arrhenius relationship for extrapolations.
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  • 74
    ISSN: 1573-5036
    Schlagwort(e): eutrophication ; herons ; nesting site ; nitrogen ; nitrophyllous species ; phosphorus ; similarity index
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Land- und Forstwirtschaft, Gartenbau, Fischereiwirtschaft, Hauswirtschaft
    Notizen: Abstract Effects of colony nesting of herons on soil properties and herb layer composition in Pinus densiflora forest were studied at Pomaeri, Kangwon Province in Korea. Herons have used this habitat as a nesting site from January to October every year. In 1995, more than 500 herons were observed in this habitat. Nutrient content of soil was much higher at the nesting site than that of the non-nesting site (control). Total nitrogen concentration of soil at the nesting site and the control site was 14.8±1.85 mg g-1 and 2.8±0.35 mg g-1, respectively. Phosphorus content of soil in the nesting site was 32 times greater than that of the control site. This is evidently due to the addition of feces of the herons, and decomposition of thin twigs and organic debris from the canopy of dead trees and bird nests. Light intensity at herb layer of the nesting site and of the control site was 80% and 20%, respectively, of incident on outside forest. Species diversity of herb layer in the nesting site (9 species) was quite lower than that in the control site (14 species). Similarity index of the herb layer between the two sites was 0.07. The nesting site was dominated by indicator species of soil eutrophication such as Humulus japonicus, Persicaria perfoliata, Persicaria fauriei, Commelina communis, Chelidonium majus var. asiaticum. Changes of herb species composition in the nesting site was evidently due to the eutrophication of the soil and increased light intensity of the herb layer.
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  • 75
    ISSN: 1573-5036
    Schlagwort(e): DRIS ; nitrogen ; perennial ryegrass ; phosphorus ; potassium ; sulphur
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Land- und Forstwirtschaft, Gartenbau, Fischereiwirtschaft, Hauswirtschaft
    Notizen: Abstract Herbage analysis offers a definitive means of determining the N, P, K and S status of perennial ryegrass swards. Unfortunately, the results of such analyses can be difficult to interpret, simply because the minimum or 'critical' concentration of a nutrient in plant tissue for optimum growth, varies both with crop age and with changes in the concentrations of other nutrients. The Diagnosis and Recommendation Integrated System (DRIS) could help to improve the reliability of such interpretations. Diagnoses made using DRIS are based on relative rather than on absolute concentrations of nutrients in plant tissue, and as such should be comparatively independent of crop age. The aim of this study was to establish and test DRIS methodology for high-yielding perennial ryegrass swards. Because of prohibitive costs, setting up a whole new series of field experiments to evaluate DRIS model parameters for perennial ryegrass was out of the question. Instead, the diagnostic norms and associated coefficients of variation for the model were evaluated using data from a single (large) multi-factorial glasshouse experiment. Of the nutrient ratios selected to form the diagnostic norms, K/N and S/N had the clearest physiological rationale, whereas those involving Ca and Mg in combination with N, P, K and S appeared to have little physiological basis. It was reasoned, though, that because Ca and Mg uptake by plants are largely passive processes (ultimately governed by plant growth), the DRIS indices for these nutrients, together reflected the degree to which growth may be limited by non-nutritional (environmental) factors relative to nutritional ones. Both indices were combined to form a single reference (Ri) index. Without such an internal reference, plant growth could be limited by multiple nutrient deficiencies, and yet N, P, K and S indices might all be close to, or equal to zero (i.e. the optimum), simply because the absolute concentrations of each nutrient (while low) had been in the correct state of balance. Moreover, by effectively using Ca and Mg as internal reference parameters in DRIS, 'nutrient concentrations' which previously formed the basis of the critical value approach, were essentially incorporated into the DRIS model, thus combining the strengths of the two diagnostic approaches; the only difference being that Ca and Mg, and not dry matter, were the internal references against which the levels of the major nutrients were compared.
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  • 76
    ISSN: 1573-5036
    Schlagwort(e): ammonium toxicity ; carbohydrates ; CO2 ; nitrogen ; Pinus taeda ; Pinus ponderosa ; root respiration
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Land- und Forstwirtschaft, Gartenbau, Fischereiwirtschaft, Hauswirtschaft
    Notizen: Abstract We measured CO2 efflux from intact root/rhizosphere systems of 155 day old loblolly (Pinus taeda L.) and ponderosa (Pinus ponderosa Dougl. ex Laws.) pine seedlings in order to study the effects of elevated atmospheric CO2 on the below-ground carbon balance of coniferous tree seedlings. Seedlings were grown in sterilized sand culture, watered daily with either 1, 3.5 or 7 mt M NH 4 + , and maintained in an atmosphere of either 35 or 70 Pa CO2. Carbon dioxide efflux (μmol CO2 plant−1 s−1) from the root/rhizosphere system of both species significantly increased when seedlings were grown in elevated CO2, primarily due to large increases in root mass. Specific CO2 efflux (μmol CO2 g root−1 s−1) responded to CO2 only under conditions of adequate soil nitrogen availability (3.5 mt M). Under these conditions, CO2 efflux rates from loblolly pine increased 70% from 0.0089 to 0.0151 μmol g−1 s−1 with elevated CO2 while ponderosa pine responded with a 59% decrease, from 0.0187 to 0.0077 μmol g−1 s−1. Although below ground CO2 efflux from seedlings grown in either sub-optimal (1 mt M) or supra-optimal (7 mt M) nitrogen availability did not respond to CO2, there was a significant nitrogen treatment effect. Seedlings grown in supra-optimal soil nitrogen had significantly increased specific CO2 efflux rates, and significantly lower total biomass compared to either of the other two nitrogen treatments. These results indicate that carbon losses from the root/rhizosphere systems are responsive to environmental resource availability, that the magnitude and direction of these responses are species dependent, and may lead to significantly different effects on whole plant carbon balance of these two forest tree species.
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  • 77
    Digitale Medien
    Digitale Medien
    Springer
    Plant and soil 195 (1997), S. 351-364 
    ISSN: 1573-5036
    Schlagwort(e): barrier island ; environmental effects ; litter quality ; nitrogen ; phosphorus ; root decomposition
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Land- und Forstwirtschaft, Gartenbau, Fischereiwirtschaft, Hauswirtschaft
    Notizen: Abstract A root decomposition study using the litterbag approach was conducted along a dune and swale chronosequence on the Virginia Coast Reserve-Long Term Ecological Research Site in Virginia, USA to evaluate how environmental and substrate quality factors influence belowground decay and associated nutrient dynamics. Gradients in moisture levels and nitrogen availability associated with the chronosequence provided the experimental framework. Spartina patens roots were buried at all sites as a standard substrate to evaluate environmental influences. Roots native to each site were buried to evaluate community decay dynamics and the influence of litter quality. Spartina decay was reduced in the wet, anoxic soils of swale sites (k = 0.21–0.33 yr-1) relative to decay in dunes soils (k = 0.52–0.72 yr-1). Increasing soil nitrogen availability from younger to older sites had no effect on the rate of Spartina root decay. Native root decay across the Hog Island chronosequence exhibits certain trends expected in response to nitrogen limitation and moisture availability. Increased nitrogen content of root material corresponds to increased soil nitrogen availability. Among dune sites, native root decay increased in concert with increased root nitrogen (6 year k = 0.34 yr-1, 120 year dune: k = 0.97 yr-1). Litter quality, alone, does not explain this trend since Spartina roots decayed more slowly than native dune roots and had a higher initial nitrogen content. Among swales, increased moisture levels and associated soil anoxia inhibited native root decomposition and minimized the effects of litter quality on decay. In general, phosphorus was rapidly lost from decaying roots while nitrogen immobilization was low to nonexistent. The low nitrogen immobilization of decaying roots in a nitrogen limited ecosystem warrants further study and may reveal that belowground decay increases the rate of nutrient cycling relative to decay aboveground.
    Materialart: Digitale Medien
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  • 78
    Digitale Medien
    Digitale Medien
    Springer
    Plant and soil 188 (1997), S. 211-219 
    ISSN: 1573-5036
    Schlagwort(e): catch crop ; mineralisation ; nitrogen ; simulation model ; temperature
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Land- und Forstwirtschaft, Gartenbau, Fischereiwirtschaft, Hauswirtschaft
    Notizen: Abstract The release of nitrogen from incorporated catch crop material in winter is strongly influenced by soil temperatures. A laboratory experiment was carried out to investigate this influence in the range of 1-15 °C. Samples of sandy soil or a mixture of sandy soil with rye shoots were incubated at 1-5-10-15 °C, and samples of sandy soil with rye roots were incubated at 5-10-15 °C. Concentrations of Nmin (NH4 +-N and NO3 --N) were measured after 0-1-2-4-7-10 weeks for the sandy soil and the sandy soil:rye shoot mixture, and after 0-2-7-10 weeks for the sandy soil:rye root mixture. At 1 °C, 20% of total organic N in the crop material had been mineralised after ten weeks, indicating that mineralisation at low temperatures is not negligible. Maximum mineralisation occurred at 15 °C; after ten weeks, it was 39% of total applied organic nitrogen from shoot and 35% from root material. The time course of mineralisation was calculated using an exponential decay function. It was found that the influence of temperature in the range 1-15 °C could be described by the Arrhenius equation, stating a linear increase of ln(k) with T-1, k being the relative mineralisation rate in day-1 and T the temperature (°C). A simulation model was developed in which decomposition, mineralisation and nitrification were modelled as one step processes, following first order kinetics. The relative decomposition rate was influenced by soil temperature and soil moisture content, and the mineralisation of N was calculated from the decomposition of C, the C to N ratio of the catch crop material and the C to N ratio of the microbial biomass. The model was validated first with the results of the experiment. The model was further validated with the results of an independent field experiment, with temperatures fluctuating between 3 and 20 °C. The simulated time course of mineralisation differed significantly from the experimental values, due to an underestimation of the mineralisation during the first weeks of incubation.
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  • 79
    Digitale Medien
    Digitale Medien
    Springer
    Plant and soil 191 (1997), S. 279-290 
    ISSN: 1573-5036
    Schlagwort(e): acidification ; carbon ; carbon dioxide ; nitrogen ; pasture ; Pinus radiata ; sea salt
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Land- und Forstwirtschaft, Gartenbau, Fischereiwirtschaft, Hauswirtschaft
    Notizen: Abstract The conversion of hill country pasture to exotic forest plantations is occurring rapidly (70,000 ha yr−1) in New Zealand. Impacts of this land-use change on soil properties, soil fertility, and water quality are only beginning to be investigated. This study examines the effects of radiata pine (Pinus radiata) on soil and soil solution chemistry, in a region of low atmospheric pollution, 20 years after plantation establishment, assuming that the pasture and pine research sites had comparable soil properties before planting pine. The primary effects of conversion on soil chemistry were a decrease of organic carbon in the mineral soil that was balanced by an accumulation of the surface litter layer, a decrease in soil N, soil acidification, and increased pools of exchangeable Mg, K, and Na. Soil solution studies revealed a large input of sea salts by enhanced canopy capture of sea salts that contributed to much larger solute concentrations and elemental fluxes in the pine soil. Sea salts appear to accumulate in the micropores of pine soil during the dry summer period and are slowly released to macropore flow during the rainy season. This results in a progressive decrease in solute concentrations over the period of active leaching. While chloride originating from sea salt deposition was the dominant anion in the pine soil, bicarbonate originating from root and microbial respiration was the dominant anion in the pasture soil. Carbon dioxide concentrations in the soil atmosphere were 12.5-fold greater in the pasture soil than in the pine soil due to greater rates of root and microbial respiration and to slower diffusion rates resulting from wetter soil conditions in the pasture. Although elemental fluxes from the upper 20 cm of the soil profile were substantially greater in the pine soil, these losses were compensated for by increased elemental inputs resulting from nutrient cycling and enhanced canopy capture of sea salts.
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  • 80
    ISSN: 1573-5036
    Schlagwort(e): carbohydrates ; carbon dioxide ; nitrogen ; nutrients ; roots ; temperature
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Land- und Forstwirtschaft, Gartenbau, Fischereiwirtschaft, Hauswirtschaft
    Notizen: Abstract Rising atmospheric carbon dioxide, nitrogen deposition and warmer temperatures may alter the quantity and quality of plant-derived organic matter available to soil biota, potentially altering rates of belowground herbivory and decomposition. Our objective was to simulate future growth conditions for an early successional (loblolly) and late successional (ponderosa) species of pine to determine if the physical and chemical properties of the root systems would change. Seedlings were grown for 160 days in greenhouses at the Duke University Phytotron at 35 or 70 Pa CO2 partial pressure, ambient or ambient + 5 °C temperature, and 1 or 5 mMNH4O3. Roots from harvested seedlings were analyzed for changes in surface area, specific root length, mass, total nonstructural carbohydrates (TNC), and concentrations of macro-nutrients. Surface area increased in both species under elevated CO2, due primarily to increases in root length, and this response was greatest (+138%) in loblolly pine at high temperature. Specific root length decreased in loblolly pine at elevated CO2 but increases in mass more than compensated for this, resulting in net increases in total length. TNC was unaffected and nutrient concentrations decreased only slightly at elevated CO2, possibly from anatomical changes to the root tissues. We conclude that future growth conditions will enhance soil exploration by some species of pine, but root carbohydrate levels and nutrient concentrations will not be greatly affected, leaving rates of root herbivory and decomposition unaltered.
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  • 81
    ISSN: 1573-5036
    Schlagwort(e): nitrogen ; 13N ; 15N ; phloem sap ; positron-emitting tracer imaging system ; rice ; xylem
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Land- und Forstwirtschaft, Gartenbau, Fischereiwirtschaft, Hauswirtschaft
    Notizen: Abstract Nitrogen movement through the xylem vessels and sieve tubes in rice plants was studied using xylem and phloem sap analysis in combination with stable and radioactive nitrogen isotope techniques. More than 90% of nitrogen was translocated in the sieve tubes of rice plants as amino acids. When 15N (99.6 atom%) was applied as a nitrate to the root, 15N first appeared in phloem sap of the leaf sheath within 10 minutes and increased to 37 atom% excess 5 hours after the experiment had started. In long-term experiments, 63% of nitrogen in the phloem sap of the leaf sheath and 15% in that of the uppermost internode came from nitrogen absorbed within the last 24 hours and 50 hours, respectively. To obtain information about the more rapid circulation of nitrogen in the plant, radioactive 13N was used as a tracer. A positron-emitting tracer imaging system was used to show that 13N was transferred to the leaf sheath within 8 minutes of its application to the roots. Analysis of the xylem sap of the leaf sheath showed that when the nitrate was applied to the roots, most of the nitrogen in the xylem was transported as a nitrate. These data showed that phloem and xylem sap analysis together with the stable and radioactive nitrogen techniques provide a good method for the detection of nitrogen cycles in plants.
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  • 82
    Digitale Medien
    Digitale Medien
    Springer
    New forests 14 (1997), S. 33-44 
    ISSN: 1573-5095
    Schlagwort(e): nutrient concetration ; frost hardiness ; growth cessation ; Pinus sylvestris ; visual damage ; nitrogen ; phosphorus ; potassium
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Land- und Forstwirtschaft, Gartenbau, Fischereiwirtschaft, Hauswirtschaft
    Notizen: Abstract In this study the effect of summer fertilization on the initiation of frost hardening of containerized second-year Scots pine (Pinus sylvestris L.) seedlings is studied. During the second growing season three different fertilization programs (water soluble NPK with micronutrients) determined by electrical conductivity of peat water extract (0.2, 0.5 and 1.2 mS cm-1) were initiated. The growth and nutrient concentrations of needles were monitored during the fertilization period. The frost hardiness of seedlings was assessed on four separate occasions at two week intervals from August 7 to September 18. This assessment was based on artificial freezing tests and visual damage scoring of tissue browning on current-year needles. Clear differences in foliar N, P and K concentrations were observed between the fertilization treatments. Fertilization prolonged the growing period of needles and increased root collar diameter. In all the tests, the highest fertilization level resulted in the highest level of frost hardiness. The difference between the fertilization treatments ranged from 1 °C to 2.2 °C. Frost hardiness increased with an increase in foliar nitrogen concentration and slightly less consistently with increases in foliar phosphorus and potassium concentrations.
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  • 83
    Digitale Medien
    Digitale Medien
    Springer
    Biogeochemistry 36 (1997), S. 189-203 
    ISSN: 1573-515X
    Schlagwort(e): ammonia volatilization ; grassland ; nitrogen ; ungulate ; Yellowstone National Park
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Geologie und Paläontologie
    Notizen: Abstract We measured ammonia volatilization at three topographic positions(hilltop, mid-slope, slope-bottom) on three grassland landscapes at threetimes during 1995 (April, May, July) on the northern winter range ofYellowstone National Park that supports large herds of native ungulates.Percent ammonia-N lost from all sites during the study ranged 1–24%of urea-N applied. Volatilization among sites was negatively related tosoil cation-exchange capacity (r = –0.85) and rates were highest inJuly. We used the relationship between soil CEC and percent Nvolatilized from urea-amended plots to estimate annual ammonia-Nvolatilization from 5 sites for which annual ungulate urine inputs werepreviously determined (Frank et al. 1994). Estimated mean annualammonia-N volatilized from those sites was 1.4 kg/ha/yr, which wasless than a previously reported regional atmospheric deposition rate (2kg/ha/yr; Swank 1984). Results indicate the need to understand theinteraction between (1) spatially heterogeneous patterns of soilprocesses, and 2) nonuniform patterns of ungulate use of landscapes todetermine rates of ecosystem-level N-gaseous loss. Findings alsosuggest that ammonia-N volatilized from urine patches should not leadto a decline in soil N in this ecosystem.
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  • 84
    Digitale Medien
    Digitale Medien
    Springer
    Biogeochemistry 37 (1997), S. 237-252 
    ISSN: 1573-515X
    Schlagwort(e): freshwater ; limitation ; marine ; nitrogen ; phosphorus ; ratio ; stoichiometry ; trace elements
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Geologie und Paläontologie
    Notizen: Abstract Nitrogen supply is often assumed to limitmarine primary production. A global analysis of totalnitrogen (N) to phosphorus (P) molar ratios shows thattotal N:P is low (〈16:1) in some estuarine andcoastal ecosystems, but up to 100:1 in open oceans.This implies that elements other than N may limitmarine production, except in human impacted, estuarineor coastal ecosystems. This pattern may reconcileconflicting enrichment studies, because N additionfrequently increases phytoplankton growth where totalN:P is expected to be low, but P, Fe, or Si augmentphytoplankton growth in waters where total N:P ishigh. Comparison of total N:P stoichiometry betweenmarine and freshwaters yields a model of the form ofthe aquatic N:P cycle.
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  • 85
    ISSN: 1573-515X
    Schlagwort(e): carbon ; nitrogen ; Ohio River ; phosphorus ; Red field ratios ; dissolved organic matter ; rivers
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Geologie und Paläontologie
    Notizen: Abstract A 12-month study was conducted to measure the concentrations ofdissolved organic matter (DOC, TDN, TDP) in four sites within a119 km long reach of the Ohio River, near Louisville, KY. In thisstudy we test whether specific geomorphological and biologicalfactors influenced variations in dissolved organic matter.Concentrations of DOC in the river averaged ≈1200μmol/L, and varied by nearly two orders of magnitudeseasonally (mean DOC during base flow ≈620 μmol/L).Peak periods for DOC at all sites were during April–May. Thesite nearest a navigation dam (deeper, lower current velocities)had significantly lower concentrations of TDN and greater C:Nratios than upstream sites. The largest tributary entering thisreach (Kentucky River) had no significant effect on levels of DOMin the main river, despite having significantly greaterconcentrations of TDN and lower levels of DOC during most monthsof the year. Concentrations of DOC, TDN, and TDP were notsignificantly different in littoral and pelagic habitats at allsites studied, suggesting little floodplain influence on DOM inthis constricted-channel section of the Ohio River. C:N ratios ofDOM in the Ohio were significantly different among seasons; C:Nexceeded or equaled Redfield ratios in summer and fall (6 to 10),but were below Redfield (1.8 to 3.0) during winter and spring.Regression models suggest that total phytoplankton densities andflow conditions are the two most important factors regulating DOMin this very large river.
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  • 86
    Digitale Medien
    Digitale Medien
    Springer
    Journal of chemical ecology 23 (1997), S. 979-993 
    ISSN: 1573-1561
    Schlagwort(e): Terpenes ; α-pinene ; camphor ; borneol ; cineole ; emission ; carbon-based secondary compounds ; biomass ; nitrogen ; water ; carbon dioxide concentrations
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie , Chemie und Pharmazie
    Notizen: Abstract Rosmarinus officinalis L. plants were grown under carbon dioxide concentrations of 350 and 700 μmol/mol (atmospheric CO2 and elevated CO2) and under two levels of irrigation (high water and low water) from October 1, 1994 to May 31, 1996. Elevated CO2 led to increasingly larger monthly growth rates than the atmospheric CO2 treatments. The increase was 9.5% in spring 1995, 23% in summer 1995, and 53% in spring 1996 in the high-water treatments, whereas in low-water treatments the growth response to elevated CO2 was constrained until the second year spring, when there was a 47% increase. The terpene concentration was slightly larger in the elevated CO2 treatments than in atmospheric CO2 treatments and reached a maximum 37% difference in spring 1996. There was no significant effect of water treatment, likely as a result of a mild low water treatment for a Mediterranean plant. Terpene concentration increased throughout the period of study, indicating possible age effects. The most abundant terpenes were α-pinene, cineole, camphor, borneol, and verbenone, which represented about 75% of the total. No significant differences were found in the terpene composition of the plants in the different treatments or seasons. The emission of volatile terpenes was much larger in spring (about 75 μg/dry wt/hr) than in autumn (about 10 μg/dry wt/hr), partly because of higher temperature and partly because of seasonal effect, but no significant difference was found because of CO2 or water treatment. The main terpene emitted was α-pinene, which represented about 50% of the total. There was no clear correlation between content and emission, either quantitatively or qualitatively. More volatile terpenes were proportionally more important in the total emission than in total content and in autumn than in spring.
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  • 87
    Digitale Medien
    Digitale Medien
    Springer
    World journal of microbiology and biotechnology 14 (1997), S. 113-118 
    ISSN: 1573-0972
    Schlagwort(e): Aspergillus ; continuous culture ; glucoamylase ; growth ; fungi ; nitrogen
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Abstract Maltose-limited continuous culture of Aspergillus niger was carried out with potassium nitrate to investigate growth and glucoamylase formation characteristics. Glucoamylase production was dependent on the specific growth rate. The maximal amount of glucoamylase (units/l and U/g dry weight) was obtained at μ=0.08h−1, and the maximum specific rate of production (units/g/dry weight per hour) was at μ=0.2h−1. The maintenance coefficients (ms and mATP) were higher than for some other fungi. Maximal growth yields on substrate, oxygen and ATP (Yxsm, YxO2m and Yxam) were very efficient (high) and the value of Yxam, which cannot exceed the theoretical maximal value, is obtained when a P/O ratio of 1:1 is assumed. This indicates that biomass formation is energetically inexpensive and most of the expended energy has to be invested in the process of glucoamylase excretion.
    Materialart: Digitale Medien
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  • 88
    ISSN: 1435-1536
    Schlagwort(e): Key words Poly(ethylene-co-5.4 mol% 3 ; 5 ; 5-trimethylhexyl methacrythlate) ; poly(dimethyl-siloxane) ; miscibility ; permeability ; dynamic elastic measurement ; DSC
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau
    Notizen: Abstract  Blends of poly(ethylene- co-5.4 mol% 3,5,5-trimethylhexyl methacrylate) (PE-TMHM) with poly(dimethylsiloxane) (PDMS) were prepared in the PDMS content range from 0 to 20%. The miscibility was studied for PE-TMHM–PDMS blends by DSC, dynamic mechanical and microscopic spectroscopy, and the gas permeability was measured for O2, N2 and CO2 as function of PDMS content. PE-TMHM and PDMS were partially miscible with each other below 20 wt% of PDMS content. The permeability coefficients (P) for O2, N2 and CO2 were increased by the blending of PDMS to PE-TMHM. The change of P for O2 with PDMS content well reflected the partially miscible phase separation behavior.
    Materialart: Digitale Medien
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  • 89
    Digitale Medien
    Digitale Medien
    Springer
    Agroforestry systems 38 (1997), S. 51-76 
    ISSN: 1572-9680
    Schlagwort(e): nitrogen ; nutrient cycling ; phosphorus ; soil fertility ; soil organic matter
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Land- und Forstwirtschaft, Gartenbau, Fischereiwirtschaft, Hauswirtschaft
    Notizen: Abstract Trees can influence both the supply and availability of nutrients in the soil. Trees increase the supply of nutrients within the rooting zone of crops through (1) input of N by biological N2 fixation, (2) retrieval of nutrients from below the rooting zone of crops and (3) reduction in nutrient losses from processes such as leaching and erosion. Trees can increase the availability of nutrients through increased release of nutrients from soil organic matter (SOM) and recycled organic residues. Roots of trees frequently extend beyond the rooting depth of crops. Research on a Kandiudalfic Eutrudox in western Kenya showed that fast-growing trees with high N demand (Calliandra calothyrsus, Sesbania sesban and Eucalyptus grandis) took up subsoil nitrate that had accumulated below the rooting depth of annual crops. Sesbania sesban was also more effective than a natural grass fallow in extracting subsoil water, suggesting less leaching loss of nutrients under S. sesban than under natural uncultivated fallows. Nutrient release from SOM is normally more dependent on the portion of the SOM in biologically active fractions than on total quantity of SOM. Trees can increase inorganic soil N, N mineralization and amount of N in light fraction SOM. Among six tree fallows of 2- and 3-year duration on an Ustic Rhodustalf in Zambia, inorganic N and N mineralization were higher for the two tree species with lowest (lignin + polyphenol)-to-N ratio (mean = 11) in leaf litter than for the two tree species with highest ratio (mean = 20) in leaf litter. Trees can also restore soil fauna, which are important for SOM and plant residue decomposition. Some agroforestry trees have potential to provide N in quantities sufficient to support moderate crop yields through (i) N inputs from biological N2 fixation and retrieval of nitrate from deep soil layers and (ii) cycling of N from plant residues and manures. The cycling of P from organic materials is normally insufficient to meet the P requirements of crops. Sustained crop production with agroforestry on P-deficient soils will typically require external P inputs.
    Materialart: Digitale Medien
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  • 90
    ISSN: 1572-8943
    Schlagwort(e): cure kinetics ; DSC ; etherification ; TGDDM epoxy
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Differential scanning calorimetry (DSC) was applied to study the cure kinetics of an epoxy system containing both tetraglycidyl 4,4′-diaminodiphenylmethane (TGDDM) and a multifunctional Novolac glycidyl ether resin, cured with 4,4′-diaminodiphenylsulfone (DDS). The experimental data were analyzed in terms of a mechanistic model proposed by Cole, which includes the etherification reaction. The kinetics can be completely described in terms of three rate constants, which obey the Arrhenius relationship. This model gives a good description of the cure kinetics up to the onset of vitrification. The effect of diffusion control was incorporated to describe the cure in the later stages. By combining the model and a diffusion factor, it was possible to predict the cure kinetics over the whole range of conversion, including an analysis of the evolution of different chemical species during the curing process. Good agreement with the experimental DSC data was achieved with this mechanistic model over the whole range of cure when the etherification reaction was assumed to be of first order with respect to the concentrations of epoxide groups, hydroxy groups, and the tertiary amine groups formed in the epoxide amine reaction.
    Materialart: Digitale Medien
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  • 91
    ISSN: 1572-8943
    Schlagwort(e): DTA ; DSC ; hydantion ; new ring ; tropane ; X-ray
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Several derivatives containing a new organic ring system, the tropane-6-spiro-5′-hydantoin structure (namely 8-alkyl-8-azabicyclo [3.2.1.] octane-6-spiro-5′-imidazoline-2′,4′-diones) have been characterized by thermal (DSC and simultaneous DTA-TG-DTG) and spectroscopic techniques (IR,1 H-NMR,13 C-NMR). X-ray powder diffraction and elemental analysis were applied for structural and molecular characterization. All the compounds melt in the range 160–250°C and undergo decomposition with progressive mass loss after the solid-liquid thermal transition with molecular degradation. It was found that tropane-6-spiro-5′-hydantoin derivatives with the hydantoin ring in β position are thermally less stable than those containing this ring in α position.
    Materialart: Digitale Medien
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  • 92
    Digitale Medien
    Digitale Medien
    Springer
    Plant and soil 196 (1997), S. 321-325 
    ISSN: 1573-5036
    Schlagwort(e): lettuce ; nitrogen ; phosphorous ; potassium ; nutrient limitation ; nutrient remobilisation ; relative growth rate
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Land- und Forstwirtschaft, Gartenbau, Fischereiwirtschaft, Hauswirtschaft
    Notizen: Abstract The relationship between plant nutrient concentration and relative growth rate (RGR) was studied under non-steady state conditions using data from a new N interruption experiment with young lettuce plants grown hydroponically in the glasshouse. RGRs estimated from the fit of a versatile growth model were shown to decline curvilinearly with plant N concentration as N deficiency increased. Similar curvilinear relationships were also derived when the same model was used to reanalyse data for N, P and K interruption treatments from other experiments previously published in the literature. These results clearly indicate that the rate of remobilisation of nutrient reserves varies with the nutrient status of the plant. This contrasts with the linear relationships observed where the changes in plant N concentration occurred solely as a response to increasing plant age, or when plants were grown under steady state conditions with constant relative nutrient addition rates. These differences in the pattern of response provide strong evidence to support the hypothesis that the form of the relationship between RGR and plant nutrient concentration can vary depending upon whether a plant's external supplies or internal reserves of a particular nutrient are more limiting.
    Materialart: Digitale Medien
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  • 93
    ISSN: 1573-5036
    Schlagwort(e): Allium ursinum ; acidification ; beech stand ; nitrogen ; nutrient leaching ; soil mesofauna ; soil solution chemistry
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Land- und Forstwirtschaft, Gartenbau, Fischereiwirtschaft, Hauswirtschaft
    Notizen: Abstract The aboveground biomass built up annually by Allium ursinum (L.) contains similar amounts of nutrients as the foliage of mature Fagus sylvatica (L.) stands. The decomposition of the A. ursinum stand in early summer provides N rich forage for grazing mesofauna, especially favouring collembolans and accelerating mineralization of soil organic matter. Short term decreases of soil pH had no negative effect on populations of collembolans. Synergistic effects from soil fauna and microbes may accelerate nitrogen release from decomposing leaf litter. A positive feed back may have emerged. High animal abundance and diverse mesofauna populations are capable of high rates of litter fragmentation. Consequently, favourable conditions for microorganisms are created and allow high rates of mineralization and release of nutrients. Our data show that substantial amounts of nitrogen are lost from the system. Undisturbed forest ecosystems are considered to recycle mineralized nitrogen efficiently though. But temporal uncoupling of the N cycle due to microbial activity and delayed or decreased N uptake of higher plants can cause enhanced leaching even from undisturbed systems. The tendency to loose nutrients is apparent from high nitrate concentrations in the soil solution throughout the year. When nutrient losses from A. ursinum subsystems are considered, lateral nutrient imports from adjacent parts of the ecosystem have to be taken into account. If lateral import does not counterbalance losses, maintenance of the soil nutrient status must occur by weathering or a decline is to be expected.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 94
    ISSN: 1573-5036
    Schlagwort(e): cowpea ; crop residues ; mineralisation ; nitrogen ; phosphorusconcentration ; t Stylosanthes
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Land- und Forstwirtschaft, Gartenbau, Fischereiwirtschaft, Hauswirtschaft
    Notizen: Abstract Laboratory studies were conducted to investigate the effect of phosphorus concentration in residues of cowpea (t Vigna unguiculata, L. Walp) and stylo (t Stylosanthes hamata, L., cv Verano) on their rate of nitrogen mineralisation when incubated in a soil whose P status was deficient for plant growth. Residues with a range of P concentrations were obtained by applying varying rates of P to soil in which the plants were grown in the field or the glasshouse. Variations in P concentration of field- or glasshouse-grown residues were not accompanied by variations in other chemical components (C:N ratio, lignin and polyphenol concentrations). Both lignin and polyphenol concentrations were higher in the field-grown than in the glasshouse-grown residues. Lignin concentration was greater in cowpea than in stylo, but polyphenols were higher in stylo. Cowpea residues mineralised N less rapidly than stylo. N mineralisation from residues with low P concentration was consistently less than from those of higher P concentration; reduced mineralisation was observed for P concentration in the residues below 1.6 g kg−1. When inorganic P was added to the residue-soil systems, N mineralisation from the residues was increased, though no interaction between the effects of adding inorganic P and P concentration in the residues was observed.
    Materialart: Digitale Medien
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  • 95
    Digitale Medien
    Digitale Medien
    Springer
    Plant and soil 192 (1997), S. 237-247 
    ISSN: 1573-5036
    Schlagwort(e): immobilization ; mineralization ; nitrogen ; residues ; sugarbeet
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Land- und Forstwirtschaft, Gartenbau, Fischereiwirtschaft, Hauswirtschaft
    Notizen: Abstract The leaves and crowns from 15N-labelled sugar beets were incubated in either a silty clay loam or sand soil for almost one year. Four additions of fresh, chopped residues mixed with soil were tested: 15N-labelled leaves alone, 15N-labelled leaves plus unlabelled crowns, unlabelled leaves plus 15N-labelled crowns, and 15N-labelled crowns alone; a control with no addition was also incubated. The C:N ratio of the leaves was 11 and that of the crowns 40. Incubations were carried out in pots kept at 20 °C and optimal moisture conditions. The leaves mineralized N from the start of the experiment but the addition of crowns to soil at first caused immobilization of nitrogen followed eventually by mineralization after 6 or 12 weeks depending on soil type. The extra amounts of mineral N found in soil at the end of the experiment where additions were made corresponded to the sum of the background mineralization and the addition; no priming effects were encountered. Very slight differences only were found between the initial rates of mineralization of C in all of the treatments. Although there was also little difference between the sand and silty clay loam soils in the direct mineralization of nitrogen from the sugar beet leaves, where N was first immobilized (i.e. from crowns or a mixture) re-release of N took place more quickly in the sand soil. The total recovery of15 N found in soils after 24 weeks incubation ranged from 70% to 90% with least being lost from the sugar-rich but N-deficient crowns. Where leaves plus crowns were incubated together both residues contributed to the microbial biomass N. In practice, immobilization of this magnitude and duration (expressed as a temperature sum) could exceed the growth period of a spring sown crop. The actual immobilization found in any one field is likely to depend on the C:N ratio of the residues and could account for much of the variation in the residual benefit of sugar beet residues reported in the literature.
    Materialart: Digitale Medien
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  • 96
    ISSN: 1573-5036
    Schlagwort(e): catch crop ; intensive dairy farming ; maize silage ; mineral nitrogen ; nitrogen ; slurry
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Land- und Forstwirtschaft, Gartenbau, Fischereiwirtschaft, Hauswirtschaft
    Notizen: Abstract Nitrate leaching from a double-cropping forage system was measured over a 2-year period (June 1994–May 1996) in the Northwest region of Portugal using ceramic cup samplers. The crops were grown for silage making and include maize (from May to September) and a winter crop (rest of the year) consisting of a mixture of cereals and Italian ryegrass. The experiment was performed on two different sites with a history of many years under the same crop and fertiliser management, but differing in the amounts of N applied as fertiliser and by regular cattle slurry applications. The annual nitrate leaching losses measured ranged from 154 to 338 kg N ha-1. These amounts lead to annual mean concentrations between 22 and 41 mg $$NO_3^ - $$ -N L-1 in the drained water. The coarse textured soils (sandy loams) and the climatic conditions of the region with more than 600 mm of drainage concentrated between October and March, tended to promote the leaching of all the nitrate-N left in the soil after the maize crop plus the N released by mineralization during the winter period. On these soils, the minimum amount of drainage (necessary to provide the complete leaching of all the nitrate-N in the soil profile in the end of summer), seems to be between 300 and 400 mm. The winter crops removed important quantities of N (83–116 kg N ha-1) but, due to their late establishment in autumn they did not succeed in taking up the nitrate-N left in the soil after the maize crop. Approaches for reducing the nitrate leaching losses in this particular system are discussed.
    Materialart: Digitale Medien
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  • 97
    ISSN: 1573-515X
    Schlagwort(e): Amazon ; deforestation ; hydrologic pathway ; groundwater ; nitrogen ; rain forest ; slash-and-burn agriculture ; solutes ; tropical
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Geologie und Paläontologie
    Notizen: Abstract Hydrochemical changes caused by slash-and-burnagricultural practices in a small upland catchment inthe central Amazon were measured. Soluteconcentrations were analyzed in wet deposition,overland flow, shallow throughflow, groundwater andbank seepage in a forested plot (about 5 ha) and anadjacent plot (about 2 ha) which had been deforestedin July 1989 and planted to manioc, and in streamwater in partially deforested and forested catchments. Measurements were made from November 1988 to June1990. The effects of slash-and-burn agriculturalpractices observed in the experimental plot includedincreased overland flow, erosion, and large losses ofsolutes from the rooted zone. Concentrations ofNO3 -, Na+, K+, SO4 2-,Cl- and Mn in throughflow of the experimentalplot were higher than those of the control plot bymore than a factor of 10. Extensive leaching occurredafter cutting and burning, but solute transfers werediminished along pathway stages of throughflow togroundwater, and particularly within the riparian zoneof the catchment. High concentrations of N and P inoverland flow indicate the importance of usingforested riparian buffers to mitigate solute inputs toreceiving waters in tropical catchments.
    Materialart: Digitale Medien
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  • 98
    ISSN: 1573-5117
    Schlagwort(e): nitrogen ; phosphorus ; phytoplankton biomass ; Daphnia grazing
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie
    Notizen: Abstract The role of nitrogen as a factor controllingphytoplankton biomass was studied in nutrientenrichment incubations in the laboratory using waterfrom pelagic region of two mesotrophic lakes ineastern Finland, Lake Kallavesi (in year 1994) andLake Juurusvesi (in year 1995). We used differentcombinations of phosphorus and nitrogen additions ina total of eight experiments. Furthermore, we includedDaphnia grazing treatment to the experimentaldesign in Lake Juurusvesi experiments. The nitrogentreatments did not increase chlorophyll aconcentration in any of the experiments compared withthe controls. Chlorophyll a content was highestin those nutrient treatments where phosphorus wasadded with or without nitrogen. Daphnia grazingdecreased chlorophyll a concentration comparedwith non-grazed treatments. In some cases grazing alsocaused higher ammonium concentrations. Theseexperiments, as well as the nutrient ratio of the lakewater used, suggest that phosphorus is likely tocontrol the amount of phytoplankton biomass.
    Materialart: Digitale Medien
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  • 99
    Digitale Medien
    Digitale Medien
    Springer
    Hydrobiologia 363 (1997), S. 117-126 
    ISSN: 1573-5117
    Schlagwort(e): nutrient limitation ; eutrophication ; nitrogen ; phosphorus ; Archipelago Sea
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie
    Notizen: Abstract Eutrophication is the most acute environmentalproblem in the Archipelago Sea, SW Finland. Whenanalysing the factors behind this escalatingeutrophication the determination of limitingnutrient at a given time is essential. Besidesexperimentations, nutrient limitation of planktonhas been extensively studied by direct chemicalanalyses. We used the latter approach in this work.Nutrient limitation was studied by calculatingdifferent nutrient ratios – totalnitrogen:phosphorus, inorganic nitrogen:phosphorus,and nutrient balance ratio. Results showed thatphosphorus usually limited primary production onlynear the coast line. In the middle zone of theArchipelago Sea the limiting factor variedtemporally. Outer in the open sea nitrogen limitedprimary production during most of the year.Phosphorus limited phytoplankton growth especiallyin spring and in summer and nitrogen in late summerand in autumn. Our results suggested that nitrogenis an important limiting nutrient in the ArchipelagoSea. In recent years when the eutrophication hasproceeded there has been a shift from productionlimitation by both nutrients to limitation bynitrogen alone. But if we want to define andcharacterize the nutrient limitation of the entireecosystem of the Archipelago Sea, budgets have to becalculated for both N and P and internal recyclingmust be taken into account as well as externalsupply of nutrients and loss processes.
    Materialart: Digitale Medien
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  • 100
    Digitale Medien
    Digitale Medien
    Springer
    Biogeochemistry 37 (1997), S. 63-75 
    ISSN: 1573-515X
    Schlagwort(e): nutrient limitation ; soil development ; nitrogen ; phosphorus ; chronosequence ; Hawai'i
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Geologie und Paläontologie
    Notizen: Abstract Walker & Syers (1976) proposed a conceptual model that describesthe pattern and regulation of soil nutrient pools and availability during long-term soil and ecosystem development. Their model implies that plantproduction generally should be limited by N on young soils and by P on oldsoils; N and P supply should more or less equilibrate onintermediate-aged soils. We tested the application of this model to nutrientlimitation, using a well characterized substrate age sequence in Hawaiianmontane rain forest. Earlier experiments had evaluated nutrient limitationin forests on a young (300 y) and an old (4,100,000 y) substrate on the samedevelopmental sequence; N alone limited tree growth on the youngsubstrate, while P alone did so on the old one. An additional fertilizerexperiment based on replicated treatments with N, P, and all othernutrients combined, applied in individually and in all factorialcombinations, was established in an intermediate-aged site in theLaupahoehoe Forest Reserve, Hawaii. Here, diameter increments of thedominant tree Metrosideros polymorpha increased slightly with Nadditions, and nearly doubled when N and P were added together.Additions of elements other than N and P had no significant effecton growth. These results show that N and P had equilibrated (relativeto plant requirements) in the intermediate aged site. Together withthe earlier experiments, these results suggest that the Walker and Syersmodel provides a useful starting point for explaining the nature anddistribution of nutrient limitation in forest ecosystems.
    Materialart: Digitale Medien
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