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  • 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases
  • 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems
  • Mt. Etna
  • 1
    Publication Date: 2024-01-30
    Description: This study focus on the Mt Etna December 2018 eruption with the aim of investigating the geochemical characteristics of the feeding magma. New data on major and trace element geochemistry of olivine-hosted melt inclusions (MI) in volcanic products are presented together with the noble gas geochemistry of fluid inclusions (FI) in olivines. The noble gas geochemistry of fluid inclusions (FIs) in olivines was also investigated. The major element composition of MIs is variable from tephrite/trachybasalt to phonotephrite/basaltic trachyandesite, with SiO2 = 45.51–52.72 wt%, MgO = 4.01–6.02 wt%, and CaO/Al2O3 = 0.34–0.72. Trace element patterns of MIs present a typical enrichment in LILE and LREE, depletion in HFSE, and relatively fractionated REE patterns: (La/Lu) N= 18.8–41.08, with Eu/Eu* = (0.5–1.8). Positive anomalies in Sr (Sr/Sr* = 0.8–2.3) and Ba can be ascribed to the assimilation of plagioclase-rich cumulates in the magmatic reservoir. The variable Ba/La (9.8–15.8), K/Nb (260–1037), Ce/Nb (1.9–3.4), Rb/La (0.4–1.6), and Ba/Nb (10.8–25.8) ratios reveal mixing between two types of end-member magmas comparable to those emitted from 1) the 2001 Upper Vents and 2002–03 Northern Fissures (Type-1) and 2) the 2001 Lower Vents and 2002–03 Southern Fissures (Type-2), respectively. Type-2 represents a magma that was under the influence of a crustal component, whereas Type-1 is compatible with a HIMU–MORB-type heterogeneous mantle source. It appears that the 2018 MIs have captured the two different types of magmas, and the lack of homogenization may imply a very fast ascent (a few months). Compatible with the contemporary presence of primordial HIMU–MORB and crust-contaminated end-members are the data on noble gases from FI that highlighted an 3He/4He value of 6.5–6.6Ra. The hypothesis of two different types of magmas, identified by the trace element geochemistry in MIs, is, thus, reinforced by helium isotopic data on FI of the 2018 eruption together with data from other Etnean eruptions and allows the inference of a bicomponent magma mixing.
    Description: Published
    Description: 1122132
    Description: OSV2: Complessità dei processi vulcanici: approcci multidisciplinari e multiparametrici
    Description: JCR Journal
    Keywords: melt inclusions ; fluid inclusions ; trace elements ; noble gases ; Mt. Etna ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Publication Date: 2024-06-12
    Description: On December 26, 2018 (2:19 UTC), during a volcanic eruption on the Mt. Etna eastern flank (Sicily, southern Italy), the largest instrumental earthquake ever recorded in the volcano ruptured the Fiandaca Fault, with epicenter between Fleri and Pennisi villages (hypocenter at ca. 300 m a. s. l., Mw 4.9). This was the mainshock of an earthquake swarm and it was accompanied by widespread surface faulting and extensive damage along a narrow belt near the fault trace. Few hours after the mainshock, an episodic aseismic creep event occurred along the Aci Platani Fault, a SE extension of the Fiandaca Fault, which caused several damages in the Aci Platani village. We surveyed and mapped the coseismic and aseismic ground ruptures, and collected structural data on their geometry, displacement, and fault zone fabric. We compared the mapped surface ruptures with topography, lithology, and morphology of the buried top of the sedimentary basement. We conclude that the geometry of the volcanic pile influenced the surface expression of faulting during the December 26, 2018 event. The top surface of the marly clay basement should be considered as a detachment surface for shallow sliding blocks. The earthquake occurred on top of a depression of the sedimentary basement forcing the sliding eastward, causing at surface the re-arrangement of the fault strand pattern and deformation style, switching from shear faulting to a tensile failure. The Fleri earthquake therefore provides an unprecedented dataset for 1) understanding active faulting in the European largest onshore volcano, 2) modeling its complex dynamics, and 3) contributing to a more refined surface faulting hazard assessment at Mt. Etna. Results from this investigation might be useful for characterizing capable faulting in similar volcano-tectonic settings worldwide.
    Description: Published
    Description: 25-41
    Description: JCR Journal
    Keywords: 2018 Fleri earthquake ; Mt. Etna ; Surface faulting ; Geological hazards ; Aseismic creep
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 3
    Publication Date: 2023-02-21
    Description: Sector-zoned clinopyroxene records kinetic effects imposed by variable degrees of magma undercooling, ΔT, and can be utilised to track the dynamics of magmatic systems. The partitioning of trace elements into sectors grown in different crystallographic orientations can be used as a proxy for ΔT. However, an experimental assessment of the relationship between trace element zoning and ΔT has been lacking to date. Here we present trace element data from a series of undercooling crystallisation experiments on a primitive trachybasalt from Mt. Etna (Italy), at conditions of crustal storage (400 MPa, NNO + 2), and ΔT ranging from 23 to 173 °C. Changes in ΔT were modulated by varying both resting and liquidus temperatures, the latter via the melt-H2O content of the experiments. The resting temperature was retained for 24 h to ensure the attainment of near-equilibrium conditions. High-resolution elemental mapping reveals the distribution of trace elements in individual clinopyroxene zones. Increasing ΔT drives a shift from polyhedral morphologies with Al-rich prism and Al-poor hourglass sectors (ΔT = 23–25 °C), to skeletal (ΔT = 75–123 °C) and dendritic (ΔT = 132–173 °C) crystals with Al-rich skeletons and Al-poor overgrowths. Aluminium-rich zones have higher concentrations of rare earth elements (REE) and high field strength elements (HFSE) than Al-poor zones across all investigated ΔT conditions, and overall, Al, REE and HFSE contents increase with ΔT. This indicates that tetrahedral aluminium (TAl) and associated charge-balancing mechanisms govern the incorporation of REE and HFSE within clinopyroxene. Lattice strain parameters for REE in the M2 site indicate the incorporation of light relative to heavy REE in clinopyroxene is controlled by competing effects between the strain-free partition coefficient, D0, and the optimum cation radius, r0. Critically, the middle and heavy REE switch from incompatible to compatible with increasing ΔT. Used to model fractional crystallisation, our data demonstrate that fractionation of clinopyroxene at low ΔT controls pre-eruptive melt evolution. Importantly, this indicates crystallisation of clinopyroxene in the deep portions of Mt. Etna’s plumbing system is not rapid and is unlikely to result in the early formation of dendrites. We develop a parameterisation of ΔT based on REE partitioning between experimental clinopyroxene and coexisting melt, which can be applied to sector-zoned augite crystallising from mafic alkaline magmas, to reconstruct dynamic processes and thermal pathways during magma transport and storage. Applied to sector-zoned clinopyroxene microphenocrysts and groundmass microcrysts from the 1974 eccentric eruption at Mt. Etna, our parameterisation tracks an increase in ΔT with magma ascent and eruption, following recharge of Cr-rich mafic magma at depth. Sector-zoned clinopyroxene can track ΔT variations leading to volcanism at Mt. Etna and could be applied to quantify magma dynamics in other active volcanoes.
    Description: This work was supported by a Foundation Research Excellence Award from The University of Queensland (UQ-FREA RM2019001828, T.U.), the Advance Queensland Women’s Research Assistance Program from the Queensland Government (WRAP109-2019RD1 RM2020002371, T.U.) and the HP-HT laboratory of Experimental Geophysics and Volcanology (INGV, Rome). A.M. was supported by the Australian Government Research Training Program (RTP). S.M, M.M. and A.P. were supported by the MIUR project “Time scales of solidification in magmas: Applications to Volcanic Eruptions, Silicate Melts, Glasses, Glass- Ceramics” (PRIN 2017J277S9).
    Description: Published
    Description: 249-268
    Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Description: 4V. Processi pre-eruttivi
    Description: JCR Journal
    Keywords: Clinopyroxene ; Sector Zoning ; Trace element partitioning ; Undercooling ; Dendritic crystals ; Rare earth elements ; LA ICP-MS Mapping ; Mt. Etna ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 4
    Publication Date: 2023-02-01
    Description: Offshore data in the western Ionian Sea indicate that the NW–SE-trending dextral shear zone of the Alfeo–Etna Fault System turns to the N–S direction near the Ionian coastline, where the extensional Timpe Fault System is located. Morpho-structural data show that NW–SE-trending right-lateral strikeslip faults connect the Timpe Fault System with the upper slope of the volcano, where the eruptive activity mainly occurs along the N–S to NE–SW-trending fissures. Fault systems are related to the ~E–Wtrending extension and they are seismically active having given rise to shallow and low-moderate magnitude earthquakes in the last 150 years. As a whole, morpho-structural, geodetic and seismological data, seismic profiles and bathymetric maps suggest that similar geometric and kinematic features characterize the shear zone both on the eastern flank of the volcano and in the Ionian offshore. The Alfeo– Etna Fault System probably represents a major kinematic boundary in the western Ionian Sea associated with the Africa–Europe plate convergence since it accommodates, by right-lateral kinematics, the differential motion of adjacent western Ionian compartments. Along this major tectonic alignment, crustal structures such as releasing bends, pull-apart basins and extensional horsetails occur both offshore and on-land, where they probably represent the pathway for magma uprising from depth
    Description: This research was funded by the Catania University PIA.CE.RI. Project (linea 2) “Interaction between volcanic activity and active tectonic processes in the Mt. Etna area (InvultEtna). The research has moreover benefited from funding provided by the agreement between Istituto Nazionale di Geofisica e Vulcanologia (INGV) and the Italian Presidenza del Consiglio dei Ministri, Dipartimento della Protezione Civile
    Description: Published
    Description: 128
    Description: 2T. Deformazione crostale attiva
    Description: JCR Journal
    Keywords: Ionian Sea ; Mt. Etna ; seismic reflection data ; GNSS data ; tectonic-driven volcanism ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 5
    Publication Date: 2023-05-17
    Description: Radon gas and its radioactive daughters have been extensively studied on Mt. Etna, both in local volcanic rocks and in all types of fluid emissions from the volcano (crater gases, fumaroles, mofettes, soil gases, groundwaters). The first measurements date back to 1976 and were carried out both in local volcanic rocks and in the crater plume. Since then, fifty-four scientific articles have been published. The largest majority of them (more than 50%) correlated radon emissions with volcanic activity and/or magma dynamics inside Mt. Etna. Many others were focused on possible correlations between time variations of in-soil radon and tectonic activity. The concentration of radionuclides in Etna volcanic rocks was measured on several occasions in order to set background values of radon parents and to study the dynamics of Etna magmas. Some articles analyzed the concentrations of radon in Etna groundwaters and their temporal changes in relation to volcanic activity. Only a few studies focused on methodological aspects of radon measurements in the laboratory. Finally, in recent years, geoscientists began to analyze the possible negative effects on human health from high concentrations of indoor radon in houses near active faults. The overall results show that, in most cases, it is possible to understand the endogenous mechanisms that cause changes in soil radon release from rocks and its migration to the surface. Several physical models were produced to explain how those changes were correlated with Etna’s volcanic activity, making them potential precursors, especially in the cases of eruptive paroxysms. More complex is the analysis of radon changes in relation to tectonic activity. Indeed, if measurements of radon in soil is now considered a robust methodology for identifying buried faults, radon time variations are not always clearly correlated with seismic activity. This difficulty is likely due to the complex interplay between tectonic stress, magma migration/eruption and gas release through faults. In any case, the potential high hazard for human health due to high concentrations of indoor radon in houses close to faults seems to be a well-established fact, which requires particular attention both from the scientific community and the public health authorities.
    Description: Published
    Description: 1176051
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Keywords: radon ; Mt. Etna ; Volcano monitoring ; human health ; soil gas ; indoor pollution ; magmatic degassing ; faults
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 6
    Publication Date: 2023-02-07
    Description: Objective: To study the blood levels of selected trace elements (TE) in Multiple Sclerosis (MS) patients living in high-incidence cluster areas in the Etna volcano region. Methods: MS patients living in the province of Catania have been retrospectively enrolled among those followed by the Neurologic Clinic of the AOU Policlinico “G. Rodolico-San Marco” who had the disease onset between 2005 and 2020.Aserumsample was used for the determination of TE levels (As,Cd, Cr, Cu, Fe, Mg, Mn, Ni, Se, Zn). All the analyses have been conducted with an ICPMS with the standard addition technique, previous digestion of the samples with nitric acid. MS patients living the high incidence clusters were frequency matched with MS patients living outside the clusters. Comparisons of TE across the groups were conducted using the Mann-Whitney test. Results: A total of 86 (48 women; 55.8%) MS patients was recruited, with a mean age of 41.6±13.1 years, a mean disease duration of 2.0±2.6 years and a mean Expanded Disability Status Scale of 2.3±1.7. Of these patients, 40 belonged to high incidence clusters and 46 were outside the clusters. No differences were found in demographic characteristics between the groups. Concerning TE, we found a significant higher concentration of Mn in incluster patients (6.7±16.6 μg/L vs 2.5±5.9 μg/L). Discussion: Several environmental factors may modulate the pathogenesis of the disease, and among them TE play an important role. Our findings suggest that Manganese, which has several toxic effects, might contribute to the higher incidence of MS previously observed in a cluster of communalities in the south-eastern flank of the Etna volcano, where volcanic ashes rich in TE usually fall due to the prevailing winds. Conclusions: Exposition to high levels of Mn could be a cofactor in the pathogenesis of MS.
    Description: Published
    Description: Milano
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Keywords: Multiple Sclerosis ; Mt. Etna ; 05. General
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Conference paper
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  • 7
    Publication Date: 2022-10-28
    Description: From the 2010s on, pattern classification has proven an effective method for flagging alerts of volcano unrest before eruptive activity at Mt. Etna, Italy. The analysis has been applied online to volcanic tremor data, and has supported the surveillance activity of the volcano that provides timely information to Civil Protection and other authorities. However, after declaring an alert, no one knows how long the volcano unrest will last and if a climactic eruptive activity will actually begin. These are critical aspects when considering the effects of a prolonged state of alert. An example of longstanding unrest is related to the Christmas Eve eruption in 2018, which was heralded by several months of almost continuous Strombolian activity. Here, we discuss the usage of thresholds to detect conditions leading to paroxysmal activity, and the challenges associated with defining such thresholds, leveraging a dataset of 52 episodes of lava fountains occurring in 2021. We were able to identify conservative settings regarding the thresholds, allowing for an early warning of impending paroxysm in almost all cases (circa 85% for the first 4 months in 2021, and over 90% for the whole year). The chosen thresholds also proved useful to predict that a paroxysmal activity was about to end. Such information provides reliable numbers for volcanologists for their assessments, based on visual information, which may not be available in bad weather or cloudy conditions.
    Description: Project IMPACT (A multidisciplinary Insight on the kinematics and dynamics of Magmatic Processes at Mt. Etna Aimed at identifying preCursor phenomena and developing early warning sysTems). IMPACT belongs to the Progetti Dipartimentali INGV [DIP7], https://progetti.ingv.it/index.php/it/progetti-dipartimentali/vulcani/impact#informazioni-sul-progetto.
    Description: Published
    Description: 17895
    Description: 4V. Processi pre-eruttivi
    Description: JCR Journal
    Keywords: Volcanic tremor ; Volcano monitoring ; Pattern recognition ; Self Organizing maps ; Fuzzy clustering ; Mt. Etna ; 04.06. Seismology ; 04.08. Volcanology ; 05.01. Computational geophysics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 8
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    MDPI - Multidisciplinary Digital Publishing Institute
    Publication Date: 2024-03-27
    Description: Remote sensing data and methods are increasingly being implemented in assessments of volcanic processes and risk. This happens thanks to their capability to provide a spectrum of observation and measurement opportunities to accurately sense the dynamics, magnitude, frequency, and impacts of volcanic activity. This book includes research papers on the use of satellite, aerial, and ground-based remote sensing to detect thermal features and anomalies, investigate lava and pyroclastic flows, predict the flow path of lahars, measure gas emissions and plumes, and estimate ground deformation. The multi-disciplinary character of the approaches employed for volcano monitoring and the combination of a variety of sensor types, platforms, and methods that come out from the papers testify to the current scientific and technology trends toward multi-data and multi-sensor monitoring solutions. The added value of the papers lies in the demonstration of how remote sensing can improve our knowledge of volcanoes that pose a threat to local communities; back-analysis and critical revision of recent volcanic eruptions and unrest periods; and improvement of modeling and prediction methods. Therefore, the selected case studies also demonstrate the societal impact that this scientific discipline can potentially have on volcanic hazard and risk management.
    Keywords: volcanic thermal anomalies ; change detection ; Villarrica Volcano ; small satellites ; FireBIRD ; TET-1 ; gas emission monitoring ; X-band InSAR ; scanning Mini-DOAS ; Multi-GAS ; volcanic gases ; precipitable water vapor ; radar path delay ; Láscar volcano ; Mt. Etna ; multi-platform satellite observations ; RSTVOLC ; Stromboli volcano ; landslides ; effusive activity ; Ground-Based InSAR ; infrared live cam ; seismic monitoring ; PLEIADES ; Digital Elevation Models ; optical sensors ; volcano remote sensing ; volcano deformation ; SAR interferometry ; post-unrest deflation ; inversion modelling ; Santorini ; hyperspectral ; FENIX ; lava field ; SMACC ; LSMA ; volcano monitoring ; thermal imaging ; time series ; Seasonal-Trend Decomposition ; heat flux ; emissivity ; lava flow modeling ; remote sensing ; volcanic eruption interpretation ; eruption forecasting ; MSG SEVIRI ; wavelet ; thermal measurements ; lava fountain ; lava flow ; Mt.Etna ; eruptive style ; Timanfaya volcanic area ; HDR geothermal systems ; GPR ; EMI ; magnetic anomalies ; seasonality ; lahars hazard ; magma accumulation ; pyroclastic flows ; ash plumes ; volcanic cloud ; Landsat 8 ; elevation model ; Volcán de Colima ; lava flow volume estimation ; SPOT ; EO-1 ALI ; MODIS data ; SENTINEL-2 images ; infrasonic activity ; open-vent activity ; fissural eruption ; long- and short-term precursors ; SO2 fluxes ; UV Camera ; Etna Volcano ; explosive basaltic volcanism ; Bezymianny ; monitoring ; lava dome ; inflation ; SAR imaging ; radar pixel offsets ; acoustic infrasound ; volcanic emissions ; ground-based remote sensing ; Sentinel missions ; Convolutional Neural Network (CNN) ; Synthetic Aperture Radar (SAR) imaging ; InSAR processing ; infrared remote sensing ; SO2 gas emission ; satellite remote sensing ; ash fall ; lava flows ; pyroclastic density currents ; mapping ; volcanic hazard ; gas emissions ; edifice growth and collapse ; volcanic unrest ; thermal anomalies ; thema EDItEUR::G Reference, Information and Interdisciplinary subjects::GP Research and information: general
    Language: English
    Format: application/octet-stream
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  • 9
    Publication Date: 2021-02-23
    Description: We report on original geochemical data, which combine the rainfall trace metal contents from three different areas of Mt. Etna, variably fumigated by the volcanic plume, and those from soils, collected over the whole volcano. Trace element contents in rainfall appear mostly related to acidic ash leaching, while only for the most volatile elements (Cu, Zn, Cd, Pb, As, Sb, Tl, Se). We analyzed separately the labile fraction of soil samples, considered the fraction bioavailable to plants and soil organisms living in. The complexing medium used to extract the bioavailable fraction simulates the growth environment of plant roots.The contents of trace elements in the bioavailable fraction from soil samples showed peculiar patterns, apparently unrelated to the plume fumigation. The transition metal contents in the bioavailable fraction account for less than 15 % of the pseudo-total fraction and the highest contents were measured in the less acidic soil samples and farthest from the summit craters. In particular, high Fe, Mn, Co, Ni, Pb, Zn, Cd contents were paralleled by high soil organic carbon concentrations, which increased in the samples collected downwind the summit vents. Concerning immobile elements, their abundance in the bioavailable fraction was related to the degree of alteration of soils. Two elements, Se and Tl, were enriched in soil samples collected at closer distance from the summit vents. Their origin is probably related to the plume deposition.The study highlighted that the accessibility of plants to potentially harmful trace elements present in the soil is not simply related to the exposure to pollutants, but also to their fate in the pedogenetic environment.
    Description: Published
    Description: 57-78
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Keywords: trace elements ; Mt. Etna ; soil ; rainwater ; 03.04. Chemical and biological
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 10
    Publication Date: 2021-06-21
    Description: Sulphur behaviour and variations in redox conditions during magma differentiation and degassing in the Mt Etna (Italy) volcanic system have been explored by integrating the study of olivine-hosted melt inclusions (MIs) with an experimental survey of sulphur solubility in hydrous basaltic magmas. Sulphur solubility experiments were performed at conditions relevant to the Etnean plumbing system (1200 C, 200MPa and oxygen fugacity between NNOþ0 2 and NNOþ1 7, with NNO being the nickel–nickel oxide buffer), and their results confirm the important control of oxygen fugacity (fO2) on S abundance in mafic magmas and on S partitioning between fluid and melt phases (DSfluid/melt). The observed DSfluid/melt value increases from 5164 to 14666 when fO2 decreases from NNOþ1 760 5 to NNOþ0 3. Based on the calculated DSfluid/melt and a careful selection of previously published data, an empirical model is proposed for basaltic magmas to predict the variation of DSfluid/melt values with variations in P (25–300 MPa), T (1030–1200 C) and fO2 (between NNO– 0 8 and NNOþ2 4). Olivine-hosted melt inclusions (Fo89-91) from tephra of the prehistoric (4 ka BP) sub-plinian picritic eruption, named FS (‘Fall Stratified’), have been investigated for their major element compositions, volatile contents and iron speciation (expressed as Fe3þ/PFe ratio). These primitive MIs present S content from 235677 to 34456168 ppm, and oxygen fugacity values, estimated from Fe3þ/PFe ratios, range from NNOþ0 760 2 to NNOþ1 660 2. Iron speciation has also been investigated in more evolved and volatile-poorer Etnean MIs. The only primitive melt inclusion from the Mt Spagnolo eruption (4–15 ka BP) presents a S content of 1515649ppm and an estimated fO2 of NNOþ1 460 1. The more evolved MIs (from 2002–2003, 2006, 2008–2009 and 2013 eruptions) have S content lower than 500 ppm, and their Fe3þ/RFe ratios result in fO2 between NNO– 0 960 1 and NNOþ0 460 1. Redox conditions and S behaviour in Etnean magmas during degassing and fractional crystallization were modelled coupling MELTS code with our empirical DSfluid/melt model. Starting from an FS-type magma composition and upon decrease of T and P, fractional crystallization of olivine, clinopyroxene, spinel and plagioclase causes a significant fO2 decrease. The fO2 reduction, in turn, causes a decrease in sulphur solubility and an increase in DSfluid/melt, promoting S exsolution during magma ascent, which further enhances the reduction of fO2. For the evolved MIs of 2002–2013 eruptions, magma differentiation may therefore have played a crucial role in decreasing redox conditions and favouring efficient S degassing. Differently, during the unusual FS eruption, only limited melt evolution is observed and S exsolution seems to have been triggered by a major pressure decrease accompanied by H2O and CO2 exsolution during fast magmatic ascent.
    Description: Published
    Description: egaa095
    Description: 4V. Processi pre-eruttivi
    Description: JCR Journal
    Keywords: melt inclusions ; sulphur solubility experiments ; XANES ; Mt. Etna ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 11
    Publication Date: 2021-01-07
    Description: Monitoring of hydrothermal fluid emissions can provide detailed information about convective upwelling of geothermal fluids and their geochemical characteristics, as a function of tectonic stress or deeper gas input. In particular, at the Salinelle of Mt. Etna Geosite (Paternò and Belpasso, Eastern Sicily) natural emissions mainly consist of a fluid phase made of salty water, mud, gas and liquid hydrocarbons from an admixture of magmatic and hydrothermal gases. In this framework, our study mainly focused on the thermal and geochemical monitoring of hydrothermal fluids of the most active site, Salinelle dei Cappuccini. Nearby hydrothermal vents (Salinelle del Fiume; Salinelle di San Biagio), were also investigated. Analysis of the magnitude and frequency of seismic events all around Mt. Etna were conducted as well. Analysis of daily temperatures showed a constant trend: higher values (〉 35° C) within the first monitoring period, followed by a strong decrease (down to 9° C), and a new gradual increase over the following months. This trend seems to be linked to magmatic processes occurring at depth below Mt. Etna, and could lead to a modification of the geochemical and thermal characteristics of the fluids issuing at the mud-pools and gas vents of Salinelle. The higher the frequency of seismic events corresponding to higher daily energy released, the higher fluid temperatures observed. Understanding how these fluids blend and what is their relationship with Mt. Etna volcanism can be of great importance in forecasting new eruptive cycles in the case they precede changes in volcanic activity.
    Description: Published
    Description: GD670
    Description: 7A. Geofisica per il monitoraggio ambientale
    Description: JCR Journal
    Keywords: Salinelle ; Mud volcanoes ; Mt. Etna ; Geothermal fluids ; Hydrothermal fluid emissions ; 04.02. Exploration geophysics ; 05.09. Miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 12
    Publication Date: 2021-01-22
    Description: The injection of gas and pyroclastic material from volcanic vents into the atmosphere is a prolific source of acoustic waves. Infrasound arrays offer efficient, cost-effective, and near real-time solutions to track the rate and intensity of surface activity at volcanoes. Here, we present a simple framework for the analysis of acoustic array data, based on least-squares beamforming, that allows to evaluate the direction and speed of propagation of acoustic waves between source and array. The algorithms include a new and computationally efficient approach for quantitative assessment of the uncertainty on array measurements based on error propagation theory. We apply the algorithms to new data collected by two 6-element infrasound arrays deployed at Mt. Etna during the period July–August 2019. Our results demonstrate that the use of two infrasound arrays allowed detecting and tracking acoustic sources from multiple craters and active vents associated with degassing and ash-rich explosions, vigorous and frequent Strombolian activity, opening of new eruptive fractures and emplacement of lava flows. Finally, we discuss the potential use of metrics based on infrasound array analyses to inform eruption monitoring operations and early warning at volcanoes characterized by episodic intensification of activity.
    Description: Published
    Description: 169
    Description: 5V. Processi eruttivi e post-eruttivi
    Description: JCR Journal
    Keywords: volcano infrasound ; infrasound arrays ; volcanic degassing ; ash explosions ; lava flow ; Mt. Etna ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 13
    Publication Date: 2021-03-01
    Description: Between 1994 and 1995, gas samples from fumaroles and thermal waters were collected on Ischia Island. The chemical composition of the shallow and deep natural hydrothermal fluids discharged is related to the main hydrological and lithological characteristics of the rock formations present in the reservoir. A biphase reservoir (liquid 1 gas) is identified, where the dominant liquid has a temperature of about 2808C. On the basis of d 13CTDC values it was possible to hypothesize a deep source characterised by carbon isotopic values varying from 0 to 23d‰. These values are noticeably more positive with respect to those attributed to magmatic CO2 d13CCO2 ranging from 25 to 28d ‰), thus suggesting a magmatic source modified by crustal contamination. This hypothesis is supported by the carbon isotopic composition of CO2 in sampled gases, which varied from 0 to 25d‰. The inferred isotopic value of carbon of magmatic CO2 would then be about 22d‰. The observed differences in C isotopic composition between fumarolic and magmatic gases would be caused by kinetic and/or equilibrium fractionation processes. These processes would cause a fractionation of d 13C of deep CO2 towards more negative values (down to 25‰). Actually, CO2 removal or addition processes caused by the interaction between deep gases and shallow hydrothermal waters are likely to be responsible for the different chemical and isotopic compositions of gaseous emissions. For these reasons, and on the basis of the homogeneity of geothermometric values, the existence of a single, large reservoir that feeds all of the fluids discharged at Ischia Island can be hypothesised. Based on acquired data, a new geochemical model of the geothermal system of Ischia Island is proposed.
    Description: Published
    Description: 151-178
    Description: 6V. Pericolosità vulcanica e contributi alla stima del rischio
    Description: JCR Journal
    Keywords: gas thermometers; water geothermometer; dissolved gases; geothermal system; Ischia Island ; 03. Hydrosphere::03.02. Hydrology::03.02.02. Hydrological processes: interaction, transport, dynamics ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 14
    Publication Date: 2021-11-29
    Description: origonal paper
    Description: An application for a quick earthquake damage scenario assessment is here presented as a potential tool for planning prevention actions or managing seismic emergencies in the volcanic region of Mt. Etna (Italy). As case-study, we considered the December 26, 2018 earthquake that, with a magnitude MW 4.9, represents the largest event occurring in the area during the last 70 years. The QUEST working group (the INGV macroseismic team) carried out a detailed survey in the damage area, collecting data on the number of buildings in the different vulnerability classes and related damage, with the aim to assign intensity. The maximum intensity reached degree VIII EMS along a narrow strip extending for 5 km astride the Fiandaca fault. In this paper, we simulated the damage scenario in the most struck municipalities of the epicentral area by testing different methodological approaches proposed in the literature using the information of the ISTAT census data collected by the Italian Institute of Statistics. We evaluated the damage level of the residential buildings and we validated the results comparing with the real damage data recognized in the field. Our analysis highlighted the difficulty of applying methods calibrated for larger earthquakes in tectonic domains, to small magnitude events in volcanic zones, where some operating assumptions must be introduced. Despite this, the results confirm the potential of the simulations based on statistical damage assessment methods also in these peculiar conditions, opening the way to finalized plans of pre- and post-earthquake interventions.
    Description: Published
    Description: 629184
    Description: 5T. Sismologia, geofisica e geologia per l'ingegneria sismica
    Description: JCR Journal
    Keywords: volcano seismicity ; macroseismic survey ; intensity data ; seismic scenario ; building vulnerability ; damage scenario ; Mt. Etna ; 05.08. Risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 15
    Publication Date: 2021-12-22
    Description: Despite Mt. Etna's long-standing reputation as an effusive volcano, since 1986 there has been an evident increase in mid-intensity explosive eruptions from its summit craters, with more than 240 episodes, better known as paroxysms (otherwise called paroxysmal episodes). These are characterized by strong Strombolian to lava fountaining activity that lasts from tens of minutes to a few days, producing some km-high volcanic plumes and tephra fallouts up to hundreds of km on the ground. Most paroxysms give life to sequences which are clustered like “episodic” eruptions for periods of a few days to a few months, their frequent recurrence causing hazard to air traffic and impacting densely inhabited areas. Nonetheless, a list containing the dates and data of these eruptions is lacking. In this paper, we tried to fill this gap by compiling a complete record, including master data (date, crater), eruption style and seismic parameters for identifying, characterizing and quantifying both the individual episodes and the entire period. This information comes from a critical review of surveillance reports, raw-data analysis and scientific literature. A retrieval of homogenous and comparable seismic data was possible only for episodes after 2006 following the renewal of seismic stations. The eruption list provides a complete picture of the 1986–2021 paroxysms, allowing to evaluate their temporal distribution, make a statistical analysis of their time-interval, and undertake a comprehensive investigation of the features of volcanic tremor. The results show a high probability (72%) of having a paroxysmal episode in the 10 days following the previous one. Moreover, a scaling relationship associated with the number-size distribution of the amplitude increases of volcanic tremor accompanying the explosive activities has been constrained. During sequences of paroxysms, combining these outputs can help improve the hazard assessment in terms of frequency of the associated tephra fallouts, and predict the duration of the entire sequence.
    Description: Published
    Description: 103686
    Description: 1V. Storia eruttiva
    Description: JCR Journal
    Keywords: Mt. Etna ; Summit craters ; Paroxysmal episodes ; Volcanic tremor ; Statistical analysis ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 16
    Publication Date: 2023-11-21
    Description: 3D earthquake locations, focal mechanisms and stress tensor distribution in a 16- month interval covering the 2018 Mt. Etna flank eruption, enabled us to investigate the relationship between magma intrusion and structural response of the volcano and shed light on the dynamic processes affecting the instability of Mt. Etna. The magma intrusion likely caused tension in the flanks of the volcano, leading to significant ground deformation and redistribution of stress on the neighbouring faults at the edge of Mt. Etna's unstable sector, encouraging the ESE sliding of the eastern flank of the volcano. Accordingly, FPSs of the post-eruptive events show strike slip faulting mechanisms, under a stress regime characterized by a maximum compressive σ1, NE-SW oriented. In this perspective, any flank eruption could temporarily enhance the sliding process of both the southern and eastern flanks of the volcano.
    Description: Published
    Description: 334-344
    Description: 5V. Processi eruttivi e post-eruttivi
    Description: JCR Journal
    Keywords: Mt. Etna ; volcano
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 17
    Publication Date: 2020-09-15
    Description: Over the last few years it is growing the need to monitor the volcanic activity with modern technology in order to mitigate volcanic hazard through the detection of any possible precursor phenomena. The use of high performance seismic stations, such as borehole instruments, may increase the signal to noise ratio (SNR), improving the capability to detect very small signals. Over the past 40 years much attention has been given to the use of seismic arrays to measure the slowness vector of coherent signals. The main advantage of seismic arrays consists in their ability to detect weak or emergent signals, and to allow for an effective noise reduction through multichannel waveform stacking. A reliable prediction of the ray-path back-propagated from the recording site to the source is strongly limited by the poor knowledge of the local shallow velocity structure. Usually in volcanic environments the propagation of seismic signals through the shallow layers is strongly affected by lateral heterogeneity, attenuation, scattering, and interaction with the free surface. Driven by these motivations, on May 2014, in collaboration with the colleagues of Osservatorio Vesuviano (INGV), we deployed a 3D seismic array in the area where the borehole seismic station called Pozzo Pitarrone is installed at a depth of about 130 meters. This will improve our knowledge about: • the structure of the top layer and its relationship with geology; • analysis of the signal to noise ratio (SNR) of volcanic signals as a function of frequency; • study of seismic ray-path deformation caused by the interaction of the seismic waves with the free surface; • evaluation of the attenuation of the seismic signals correlated with the volcanic activity. The results of these analyses will improve the general knowledge of wave propagation in the shallow layers and will give a new contribution to the seismic monitoring of Etna volcano.
    Description: Published
    Description: Nicolosi (Catania), Italy
    Description: 1T. Struttura della Terra
    Keywords: 3D-Array Techniques ; Mt. Etna
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Extended abstract
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  • 18
    Publication Date: 2019-03-01
    Description: Mud volcanoes are often associated with large areas of CO2 and CH4 emission that are potentially dangerous due to sudden paroxysmal gas and mud eruptions. Despite the interest in understanding such natural environments, they have not yet been thoroughly investigated and a single interpretative framework remains to be elaborated. This lack of knowledge may be due to the difficulty in measuring in-plume CO2 as there is very little contrast with atmospheric CO2, coupled with the complex organizational strategies required for long-term monitoring. This work features three different methods that were used to evaluate the CO2 flux at the Salinelle mud volcano in the foothills of Mt Etna (Italy), carried out periodically from December 2013 to April 2018. We computed in-plume CO2 flux indirectly using a tunable laser and a portable MultiGAS and, directly, measuring the gas volumetric flux from bubbling pools. The morphological variations of the mud field were recorded using unmanned aerial vehicle (UAV) imagery, which provided information on the migration of vents in relation to the observed variations in measured gas output. Our analysis shows that the three methods gave comparable values, indicating the feasibility of this approach. Our findings suggest a pseudo-cyclical pattern in the bulk CO2 emitted at Salinelle, introducing a new interpretation of the processes involved in mud volcano dynamics.We theorize that the periodic variation of the gas emitted at the Salinelle may be attributed to a Bgeyser-like^ mechanism that may be subject to interruption or changes in magnitude by volcanic or seismic events.
    Description: Published
    Description: id 2
    Description: 5V. Dinamica dei processi eruttivi e post-eruttivi
    Description: JCR Journal
    Keywords: mud volcano ; gas emission ; Mt. Etna ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 19
    Publication Date: 2021-11-29
    Description: In this paper we present a multidisciplinary approach aimed at assessing seismic risk regarding non-structural damage. The study has been carried out in the framework of the European KnowRISK Project and focuses on the pilot area of Mt. Etna volcano (Italy). Both instrumental data and as well as macroseismic observations provide unique opportunities for testing innovative and classical approaches for assessing seismic risk. Starting from the seismic hazard analysis, we first identify a test site (Zafferana) affected by non-structural damage. We produce seismic scenarios based on macroseismic and ground-motion data and finally obtain the relevant risk map using the Italian census data to classify buildings into vulnerability classes and a model to predict damage distribution.
    Description: Published
    Description: 277-292
    Description: 4T. Sismologia, geofisica e geologia per l'ingegneria sismica
    Keywords: Mt. Etna ; KnowRISK project ; Seismic scenarios ; Risk map
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: book chapter
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  • 20
    Publication Date: 2022-06-08
    Description: Magmatic degassing, typically measured as SO2 flux, plays a fundamental role in controlling volcanic eruption style and is one of the key parameters used by volcano observatories to assess volcanic unrest and detect eruption precursors. Volcanic tremor, the integrated amplitude of seismic energy release over a range of frequencies, is also a key parameter in volcano monitoring. A connection between volcanic degassing and tremor has been inferred through correlations between the signals which are often, but not always, observed during periods of unrest or eruption. However, data are often equivocal and our understanding of the physical processes, which couple degassing with tremor are still evolving. New insights into degassing-tremor coupling can be made by investigation of the long-term relationship between degassing and tremor, focusing on the frequency-dependence of tremor and passive degassing behavior. In this study, we examine how long-term SO2 emission rates and volcanic tremor on Mt. Etna, track rapid variability in eruptive dynamics. Correlations between SO2 flux and tremor are explored in both quiescent and eruptive periods, comparing the two parameters at both long and short time-scales (〈 〈 1 day) for 2 years. Our analysis reveals that over month-long timescales passive degassing of SO2 and tremor tend to be well-correlated, but these correlations are lost over shorter timescales. This reflects a coupling process between passive degassing and tremor, produced by a combination of gas flow through permeable magma and the convective flow of magma within the conduit. Short-term correlations are lost because variations in the continuous degassing process are relatively small compared with the overall degassing rate and fall below measurement noise. During eruptive periods strong correlations are observed between degassing and tremor, with a significant contribution of higher frequency signal in tremor, controlled by eruptive style. These observations suggest that in syneruptive periods the tremor source is dominated by the coupling between the eruption column and the ground through infrasonic waves, rather than conduit processes. Our results demonstrate the importance of high quality long-term observations and offer new insights into the physical mechanisms which couple degassing and volcanic tremor at active volcanoes.
    Description: Published
    Description: Article 157
    Description: 5V. Processi eruttivi e post-eruttivi
    Description: JCR Journal
    Keywords: Mt. Etna ; SO2 flux ; volcanic tremor ; eruptive and quiescent degassing ; volcano monitoring ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 21
    Publication Date: 2022-06-14
    Description: In May 2016, three powerful paroxysmal events, mild Strombolian activity, and lava emissions took place at the summit crater area of Mt. Etna (Sicily, Italy). During, and immediately after the eruption, part of the North-East crater (NEC) collapsed, while extensive subsidence affected the Voragine crater (VOR). Since the end of the May eruptions, a diffuse fumarolic activity occurred from a fracture system that cuts the entire summit area. Starting from 7 August, a small vent (of ~20–30min diameter) opened up within the VOR crater, emitting high-temperature gases and producing volcanic glow which was visible at night. We investigated those volcanic phenomena from space, exploiting the information provided by the satellite-based system developed at the Institute of Methodologies for Environmental Analysis (IMAA), which monitors Italian volcanoes in near-real time by means of the RSTVOLC (Robust Satellite Techniques–volcanoes) algorithm. Results, achieved integrating Advanced Very High Resolution Radiometer (AVHRR) and Moderate Resolution Imaging Spectroradiometer (MODIS) observations, showed that, despite some issues (e.g., in some cases, clouds masking the underlying hot surfaces), RSTVOLC provided additional information regarding Mt. Etna activity. In particular, results indicated that the Strombolian eruption of 21 May lasted longer than reported by field observations or that a short-lived event occurred in the late afternoon of the same day. Moreover, the outcomes of this study showed that the intensity of fumarolic emissions changed before 7 August, as a possible preparatory phase of the hot degassing activity occurring at VOR. In particular, the radiant flux retrieved from MODIS data decreased from 30 MW on 4 July to an average value of about 7.5 MW in the following weeks, increasing up to 18 MW a few days before the opening of a new degassing vent. These outcomes, in accordance with information provided by Sentinel-2 MSI (Multispectral Instrument) and Landsat 8-OLI (Operational Land Imager) data, confirm that satellite observations may also contribute greatly to the monitoring of active volcanoes in areas where efficient traditional surveillance systems exist.
    Description: Published
    Description: id 1948
    Description: 5V. Processi eruttivi e post-eruttivi
    Description: JCR Journal
    Keywords: Mt. Etna ; multi-platform satellite observations ; RSTvolc ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 22
    Publication Date: 2018-02-27
    Description: We monitored the soil gas emission of CO2 from selected sites of Mt. Etna volcano during the period February 2009 to December 2010 by measuring periodically the soil CO2 ef- flux together with the associated stable carbon isotope com- position of CO2. Correlation between the two parameters showed distinct behaviors depending on the sites as a re- flection of the different interactions between crustal and sub-crustal fluids. Where deep CO2 interacted with shallow cold ground water and/or with shallow biogenic CO2, a positive correlation between soil CO2 effluxes and carbon isotopes was evident and it depended strongly on the veloc- ity of gas through the soil. In these cases, the highest CO2 effluxes corresponded to δ13CCO2 values similar to those of the deep magmatic CO2 emitted from the crater and peri- crateric gas emissions at the summit. In areas where a shal- low hydrothermal system was presumed, then a similar correlation was less evident or even absent, suggesting strong control on C isotopes arising from the interactions between CO2 gas and dissolved HCO3- that occur in aquifers at T〉120 °C. Marked temporal variations were observed in both parameters at all sites. No significant effect of me- teorological parameters was found, so the observed changes were reasonably attributed to variations in volcanic activity of Mt. Etna. In particular, the variations were attributed to increased degassing of CO2 from incoming new magma, possibly coupled with increased hydrothermal activity in at least some of the shallow aquifers of the volcano. The largest anomalies in the monitored parameters preceded the opening of the New Southeast Crater in late 2009 and there- fore they could represent a key to unveiling the dynamics of the volcano.
    Description: Slovenian Re- search Programme “Cycling of substances in the environment, mass balances, modelling of environmental processes and risk assessment” (P1-0143) and bilateral Slovenian-Italian Cooperation “Mercury emis sions, its influence and correlation with Rn on Etna area”.
    Description: Published
    Description: S0663
    Description: 4V. Dinamica dei processi pre-eruttivi
    Description: JCR Journal
    Keywords: Mt. Etna ; Carbon isotopes ; CO2 efflux ; Volcanic activity ; Hydrothermal systems ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 23
    Publication Date: 2018-03-30
    Description: In the Central Mediterranean region, the production of chemically diverse volcanic products (e.g., those from Mt. Etna and the Aeolian Islands archipelago) testifies to the complexity of the tectonic and geodynamic setting. Despite the large number of studies that have focused on this area, the relationships among volcanism, tectonics, magma ascent, and geodynamic processes remain poorly understood. We present a tomographic inversion of P-wave velocity using active and passive sources. Seismic signals were recorded using both temporary on-land and ocean bottom seismometers and data from a permanent local seismic network consisting of 267 seismic stations. Active seismic signals were generated using air gun shots mounted on the Spanish Oceanographic Vessel ‘Sarmiento de Gamboa’. Passive seismic sources were obtained from 452 local earthquakes recorded over a 4-month period. In total, 184,797 active P-phase and 11,802 passive P-phase first arrivals were inverted to provide three different velocity models. Our results include the first crustal seismic active tomography for the northern Sicily area, including the Peloritan–southern Calabria region and both the Mt. Etna and Aeolian volcanic environments. The tomographic images provide a detailed and complete regional seismotectonic framework and highlight a spatially heterogeneous tectonic regime, which is consistent with and extends the findings of previous models. One of our most significant results was a tomographic map extending to 14 km depth showing a discontinuity striking roughly NW–SE, extending from the Gulf of Patti to the Ionian Sea, south-east of Capo Taormina, corresponding to the Aeolian–Tindari– Letojanni fault system, a regional deformation belt. Moreover, for the first time, we observed a high-velocity anomaly located in the south-eastern sector of the Mt. Etna region, offshore of the Timpe area, which is compatible with the plumbing system of an ancient shield volcano located offshore of Mt. Etna.
    Description: Published
    Description: 57-97
    Description: 7T. Struttura della Terra e geodinamica
    Description: JCR Journal
    Keywords: Seismic tomography ; Mt. Etna ; Aeolian Islands ; Volcanic ; 04
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 24
    Publication Date: 2018-03-26
    Description: On Mt. Etna (Italy), an enhanced Normalized Difference in Vegetation Index (NDVI) signature was detected in the summers of 2001 and 2002 along a distinct line where, in November 2002, a flank eruption subsequently occurred. These observations suggest that pre-eruptive volcanic activity may have enhanced photosynthesis along the future eruptive fissure. If a direct relation between NDVI and future volcanic eruptions could be established, it would provide a straightforward and low-cost method for early detection of upcoming eruptions. However, it is unclear if, or to what extent, the observed enhancement of NDVI can be attributed to volcanic activity prior to the subsequent eruption. We consequently aimed at determining whether an increase in ambient temperature or additional water availability owing to the rise of magma and degassing of water vapour prior to the eruption could have increased photosynthesis of Mt. Etna's trees. Using dendro-climatic analyses we quantified the sensitivity of tree ring widths to temperature and precipitation at high elevation stands on Mt. Etna. Our findings suggest that tree growth at high elevation on Mt. Etna is weakly influenced by climate, and that neither an increase in water availability nor an increase in temperature induced by pre-eruptive activity is a plausible mechanism for enhanced photosynthesis before the 2002/2003 flank eruption. Our findings thus imply that other, yet unknown, factors must be sought as causes of the pre-eruption enhancement of NDVI on Mt. Etna.
    Description: Published
    Description: e0169297
    Description: 4V. Dinamica dei processi pre-eruttivi
    Description: JCR Journal
    Keywords: Mt. Etna ; Normalized Difference in Vegetation Index (NDVI) ; photosynthesis ; eruption ; relation between NDVI and future volcanic eruptions
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 25
    Publication Date: 2018-03-07
    Description: In this paper we present a multidisciplinary approach aimed at assessing seismic risk due to non-structural damage. The study has been carried out in the framework of the European KnowRISK Project and focuses on the pilot area of Mt. Etna volcano (Italy). Both instrumental data and as well as macroseismic observations provide unique opportunities for testing innovative and classical approaches for assessing seismic risk. Starting from the seismic hazard analysis, we first identify a test site (Zafferana) affected by non-structural damage. We produce seismic scenarios based on macroseismic and ground-motion data and finally obtain the relevant risk map using the Italian census data to classify buildings into vulnerability classes and a model to predict damage distribution.
    Description: Published
    Description: Reykjavik, Iceland
    Description: 4T. Sismologia, geofisica e geologia per l'ingegneria sismica
    Keywords: Mt. Etna ; KnowRisk Project ; seismic scenarios ; ground motion parameters ; risk map
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Conference paper
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  • 26
    Publication Date: 2020-12-14
    Description: In Earth Sciences there is a growing interest in studies concerning soil-radon activity, due to its potential as a tracer of numerous natural phenomena. Our work marks an advance in the comprehension of the interplay between tectonic activity, volcanic eruptions and gas release through faults. Soil-radon measurements, acquired on Mt. Etna volcano in 2009–2011, were analyzed. Our radon probe is sensitive to changes in both volcanic and seismic activity. Radon data were reviewed in light of the meteorological parameters. Soil samples were analyzed to characterize their uranium content. All data have been summarized in a physical model which identifies the radon sources, highlights the mechanism of radon transport and envisages how such a mechanism may change as a consequence of seismicity and volcanic events. In the NE of Etna, radon is released mainly from a depth of 〈1400 m, with an ascent speed of 〉50 m/day. Three periods of anomalous gas release were found (February 2010, January and February 2011). The trigger of the first anomaly was tectonic, while the second and third had a volcanic origin. These results mark a significant step towards a better understanding of the endogenous mechanisms that cause changes in soil-radon emission at active volcanoes.
    Description: Published
    Description: 24581
    Description: 6A. Monitoraggio ambientale, sicurezza e territorio
    Description: JCR Journal
    Description: restricted
    Keywords: Mt. Etna ; soil radon ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 27
    Publication Date: 2017-08-07
    Description: For thousands of years man has marvelled at the gigantic structure that makes up Mt. Etna, the largest active volcano in Europe, and has lived side by side with the mountain, which despite its intense eruptive activity has always been considered a "friendly giant." After the Second World War, with its frequent but non life-threatening eruptions, Mt. Etna represented an ideal location for volcanological research for the national and international scientific community. Numerous scientists from Belgium, Germany, France, the United Kingdom, and the United States of America have taken part in volcanological research aimed at understanding the volcano.
    Description: Published
    Description: 1-27
    Description: 1V. Storia eruttiva
    Description: 5V. Dinamica dei processi eruttivi e post-eruttivi
    Description: 6V. Pericolosità vulcanica e contributi alla stima del rischio
    Keywords: Volcano ; Mt. Etna ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: book chapter
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  • 28
    Publication Date: 2019-01-09
    Description: A comprehensive hydrogeochemical study of the cold and thermal groundwaters of the presently quiescent volcanic system at Methana was undertaken that involved collecting 71 natural water samples. Methana is a peninsula in Peloponnesus, Greece whose arid climate and hydrological situation is similar to that of the nearby small islands of the Aegean Sea. Similarly, the chemical and isotopic compositions of its water are dominated by the mixing of seawaterwith meteoric water both through direct intrusion and meteoric recharge. However, the simple mixing trends at Methana are modified by water–rock interaction processes, enhanced by the dissolution of endogenous CO2, which lead to strong enrichments in alkalinity, Ca, Ba, Fe and Mn. The thermal waters show very high salinity that is sometimes close to that of seawater [total dissolved solids (TDS)=8.5–40 g/l]. Although the cold groundwaters sometimes also show elevated TDS values (up to 6.3 g/l), their overall quality is acceptable due to the trace metal and nitrate contents mostly being below acceptable limits. While the saltiest groundwaters are not acceptable for human consumption, they are used for irrigation without exerting toxic effects on plants, which is probably due to the high permeability of the soils not supporting salt accumulation and salinity-resistant crops being cultivated.
    Description: Published
    Description: 110-119
    Description: 4V. Vulcani e ambiente
    Description: JCR Journal
    Description: restricted
    Keywords: Hydrogeochemistry ; volcanic aquifers ; Salinization ; stable isotopes ; Trace elements ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 29
    Publication Date: 2017-08-07
    Description: For thousands of years man has marvelled at the gigantic structure that makes up Mt. Etna, the largest active volcano in Europe, and has lived side by side with the mountain, which despite its intense eruptive activity has always been considered a "friendly giant." After the Second World War, with its frequent but non life-threatening eruptions, Mt. Etna represented an ideal location for volcanological research for the national and international scientific community. Numerous scientists from Belgium, Germany, France, the United Kingdom, and the United States of America have taken part in volcanological research aimed at understanding the volcano.
    Description: Published
    Description: 77-89
    Description: 1V. Storia eruttiva
    Description: 3V. Proprietà dei magmi e dei prodotti vulcanici
    Keywords: Volcano ; Mt. Etna ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: book chapter
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  • 30
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    Elsevier - Procedia Earth and Planetary Science vol. 17
    Publication Date: 2017-04-04
    Description: Zr and Hf are two elements having same ionic charge and similar ionic size at a given coordination number. Despite the Zr/Hf ratio is considered to be quite constant in meteorites and lithospheric rocks, seawaters collected from the surface down to varying depths of several Pacific Ocean stations reveal that the Zr/Hf ratio increases by one order of magnitude. Very recent studies have shown that, in both ground waters and lake waters, the Zr/Hf ratio is either higher or lower compared to the interacting minerals displaying a large variability in the distribution of these twin elements. In this communication the possible processes responsible for such a large fractionation are discussed but further work is needed to test the validity of these interpretations. This basic problem of scientific significance needs more attention from the water-rock interaction community.
    Description: Published
    Description: Evora, Portugal
    Description: 4V. Vulcani e ambiente
    Description: open
    Keywords: Zr/Hf ratio ; natural waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Extended abstract
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  • 31
    Publication Date: 2017-04-04
    Description: Abstract The 87Sr/86Sr ratio was investigated in groundwater circulating in the volcanic edifice of Mt. Etna in order to estimate the possible contribution of deep brines circulating in the sedimentary basement. Samples from 14 sites were collected and analyzed for their chemical composition and Sr-isotope ratios. While the most common approach of coupling 87Sr/86Sr ratios with the concentration of dissolved Sr is not effective in distinguishing between the deep brine and seawater contributions, we suggest that the Sr/Cl ratio is a useful complementary parameter that needs to be considered when attempting to clearly identify the Sr sources. The obtained data indicate that the Sr-isotope signature of groundwater is determined by the volcanics hosting the aquifer. The volcanic isotopic signature is modified by very small amounts of brines (〈 1%), characterized by a high concentration of Sr and a 87Sr/86Sr ratio typical of sedimentary environments, but only at sites where the groundwater circulates almost in contact with the sedimentary basement. Conversely, the contribution of seawater is completely ruled out since this should produce a higher concentration of chloride. The proposed approach is potentially very effective for tracing the circulation of groundwater not only at Mt. Etna but also at volcanic edifices that overlie a bedrock with different 87Sr/86Sr ratios as well as at volcanic islands where freshwater overlies seawater.
    Description: Published
    Description: 102-107
    Description: 4V. Vulcani e ambiente
    Description: JCR Journal
    Description: restricted
    Keywords: Mt. Etna ; 03. Hydrosphere::03.02. Hydrology::03.02.02. Hydrological processes: interaction, transport, dynamics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 32
    Publication Date: 2017-04-04
    Description: Abstract The chemical composition of the groundwater at Mt. Etna was investigated in order to determine the extent to which the persistent plume affects the chemical composition of circulating waters. Samples from 31 springs and wells were collected during June and July 2014 and analyzed for their chemical compositions. The content of dissolved elements derives from the bulk deposition (wet and dry deposition) at the recharge areas as well as from the weathering of volcanic rocks during the infiltration and transport of groundwater. In its early phase, the chemical weathering of volcanic rocks and ashes is promoted by the acid rain that characterizes the area and subsequently by the huge amount of deep magmatic carbon dioxide (CO2) coming up through the volcanic edifice and dissolving in the water. The high content of chlorine is mainly derived from interactions between the plume and rainwater, while the total alkalinity can be completely ascribed to the dissociation of carbonic acid (H2CO3) after the hydration of CO2. The relative contributions of plume-derived elements/weathering and CO2-driven weathering has been computed for each element. In addition, the comparison between the chemical compositions of the bulk deposition and of groundwater provides a new understanding about the mobility of volatile elements. The proposed approach has revealed that the persistent plume strongly affects the chemical composition of groundwater at Mt. Etna and probably also at other volcanoes characterized by huge open-conduit degassing activity.
    Description: Published
    Description: 68-80
    Description: 4V. Vulcani e ambiente
    Description: JCR Journal
    Description: restricted
    Keywords: Mt. Etna ; 03. Hydrosphere::03.02. Hydrology::03.02.02. Hydrological processes: interaction, transport, dynamics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 33
    Publication Date: 2017-04-04
    Description: Con il nome di Salinelle vengono chiamate delle manifestazioni naturali di emissione di fl uidi, con formazione anche di vulcanetti di fango, che avvengono nei dintorni dell’abitato di Paternò. Tre sono i siti caratterizzati da questi fenomeni naturali: le Salinelle dei Cappuccini o dello Stadio (Paternò), le Salinelle del Fiume (Paternò) e le Salinelle del Vallone Salato o di San Biagio (Belpasso). Queste manifestazioni naturali sono caratterizzate dall’emissione di acqua salata, generalmente a temperatura ambiente, fango, gas ed idrocarburi liquidi. La peculiarità di questi siti risiede nel fatto che le emissioni fl uide, differentemente da altri siti simili, sono originate dalla commistione tra gas magmatici/ idrotermali, che costituiscono la maggior parte della fase gassosa emessa, e gas crostali provenienti da serbatoi di idrocarburi. Ciò produce morfologie uniche, a rilievo blando, legate all’emissione di una abbondante componente liquida priva della frazione argillosa, dovuta anche alla condensazione di fl uidi ad alta entalpia di origine magmatica. Altri vulcani di fango in Italia e nel mondo hanno invece tipicamente emissioni prevalentemente fangoso-argillose. Per tali motivi l’emissione di fl uidi alle Salinelle è fortemente vincolata all’attività profonda dell’Etna, producendo eruzioni parossistiche spesso spettacolari e con emissione anche di acque termalizzate, il che rende le Salinelle interessanti anche per studi di tipo vulcanologico e geotermale. Inoltre, l’attività di emissione di fl uidi è continua, a differenza di quanto accade presso altri siti. Infi ne, all’interesse dato dalla rarità del fenomeno geologico, alla sua estensione nonché all’interesse geomorfologico si aggiunge il fatto che il sito è esemplifi cativo dei fenomeni pseudovulcanici e produce morfologie estremamente varie e peculiari. Queste caratteristiche rendono le Salinelle quasi uniche nel panorama mondiale dei vulcani di fango, poiché normalmente i gas che guidano la risalita del fango e delle acque in questo tipo di manifestazioni naturali sono composti quasi interamente da metano e altri idrocarburi. Ciò ha portato al riconoscimento delle Salinelle tra i Geositi di interesse mondiale.
    Description: Published
    Description: 42-47
    Description: 5A. Energia e georisorse
    Description: N/A or not JCR
    Description: restricted
    Keywords: Vulcani di fango ; Monte Etna ; Gas magmatici ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 34
    Publication Date: 2017-04-04
    Description: We have carried out a preliminary study on the potential risks caused by the sub-10 mu m fraction of volcanic ash (particulate matter, PM10) after the basaltic explosive eruptions from Mt. Etna volcano (Italy), which have dramatically increased in frequency over the last 20 years. We present results deriving from the study of the ash concentration in the air following the lava fountain episode from the New Southeast Crater of Etna on 15 November 2011, which caused tephra fallout over the eastern slope of the volcano. Short-duration tests of PM10 measurements were carried out at three different sites using a TSI (R) DustTrak (TM) aerosol monitor a few hours after the end of the eruption, and readouts of the air quality were repeated at the same sites a month later without volcanic activity. Furthermore, ash samples were characterized by grain size, componentry and morphological and petrochemical analyses. By comparing PM10 levels measured a few hours after the 15 November lava fountain and on 15 December, we found that relatively low amounts (500-1500 gm(-2)) of tephra fallout cause high levels of PM10 in the air. This is because the coarse particles, particularly basaltic ash, are readily broken up by traffic and hence remobilized into the air. We believe the impact from ash fallout in the Etnean territory should receive greater attention, especially regarding potential health problems. Simple but effective actions can be implemented to reduce eventual risks, first and foremost the prompt removal of the ash deposits from the urbanized areas.
    Description: Published
    Description: 29-40
    Description: 4V. Vulcani e ambiente
    Description: JCR Journal
    Description: open
    Keywords: Mt. Etna ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 35
    Publication Date: 2021-06-07
    Description: Methane-rich fluid vents have been widely observed and associated to active faults in the Sea of Marmara, along the submerged portion of the North Ana- tolian Fault (NAF). Episodic gas seepage also occurs in the Izmit Gulf, along the NAF segment that ruptured during the 1999 Izmit earthquake. This site is thus a unique area to test the hypothesis on the relation between strike-slip deforma- tion, seismic activity and gas expulsion within an active fault zone. A long-term multi-parametric experiment can be an effective way to study the irregular dy- namics of gas emission from seafloor and to understand its possible relation with seismic activity. A benthic seafloor observatory (SN-4) was deployed in the Izmit Gulf in 2009 using the R/V Urania as a demonstration mission in the framework of the EC ES- ONET (European Seas Observatory NETwork) project. Instrumental redundancy and specific cross-correlation of data from different sensors, proves to be funda- mental to distinguish actual seepage events from other signals related to ocean- ographic behaviour or even sensor biases. The observatory was equipped with a three component broad-band seismometer, a CTD with turbidity meter, two methane detectors, an oxygen sensor and a current-meter. All sensors installed on the observatory were managed by dedicated low-power electronics, which can manage a wide set of data streams with quite different sampling rates. A unique reference time, set by a central high-precision clock, is used to tag each datum. After six months of continuous monitoring, SN-4 was recovered in March 2010 in order to download the data and replace the batteries for a further six month mission period and finally recovered in October 2010. The data analysis clearly shows frequent degassing events, recorded as methane anomalies in seawater and as high-frequency short-duration signals recorded by the seismometer.. The time series of other oceanographic parameters (tempera- ture, oxygen concentration, turbidity and salinity) shows patterns that seem to be linked to both local gas seepage and to the circulation of water masses in the Gulf of Izmit. A comparative analysis of the various observables and their mutual correlation, can be a key tool to understand actual degassing events along the NAF. This analysis is first attempt in finding possible correlations be
    Description: Published
    Description: Cadiz, Spain
    Description: 3A. Ambiente Marino
    Description: restricted
    Keywords: seafloor observatory ; methane seepage ; multi-parametric ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 03. Hydrosphere::03.04. Chemical and biological::03.04.08. Instruments and techniques ; 04. Solid Earth::04.06. Seismology::04.06.06. Surveys, measurements, and monitoring ; 04. Solid Earth::04.06. Seismology::04.06.10. Instruments and techniques
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Extended abstract
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  • 36
    Publication Date: 2017-04-04
    Description: This work presents the results of an extensive geochemical survey aimed at measuring soil CO2 effluxes and soil temperatures over a large portion of Mt. Etna's summit area, coupled with an updated structural survey of the same area. The main goals of this study were i) to find concealed or hidden volcano-tectonic structures in the studied area by detecting anomalous soil gas emissions, ii) to investigate the origin of the emitted gas and the mechanism of gas and heat transport to the surface, iii) to produce a structural model based both on the surface geology and on the soil gas data and, lastly, iv) to contribute to the assessment of hazard from slope failure and crater collapses at Mt. Etna. The results revealed many concealed structural lines that followed the major directions of structural weakness in the summit area of Mt. Etna, mostly due to a combined action of gravitational spreading of the volcano and magma intrusions. Both recent and old volcano-tectonic lines were found to act as pathways for the leakage of magmatic gases to the surface. An important role in driving magmatic gases to the surface is also played by fracturing and faulting due to caldera-forming collapses and smaller crater collapses. Correlation between soil CO2 emissions and soil temperature allowed discriminating areas of active shallow hydrothermal circulation along deep fractures (characterized by high values of both parameters, but mostly soil temperature) from those affected by undeveloped fractures that did not reach the surface (characterized by high CO2 emissions at low temperature). The former corresponded to weak zones of the volcano edifice that were frequently site of past eruptions, indicating that those areas keep a high potential for future opening of eruptive fissures. The latter were likely related to sites where new eruptive fissures may open in the near future due to backward propagation of extensional tectonic stress.
    Description: project CGL2005-07509/CLI, Ministry of Education and Science of Spain; DPC-INGV project FLANK; Istituto Nazionale di Geofisica e Vulcanologia — Osservatorio Etneo, Sezione di Catania
    Description: Published
    Description: 79-98
    Description: 5A. Energia e georisorse
    Description: JCR Journal
    Description: restricted
    Keywords: Mt. Etna ; Soil CO2 ; Soil temperature ; Hidden faults ; Structural framework ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 37
    Publication Date: 2017-04-04
    Description: This paper focuses on the chemical composition changes in soil gases through both a theoretical model and laboratory experiments. The model describes the one-dimensional mass transfer process, which is triggered by changes in the flux parameters of the system, and the time-dependent evolution of the composition of the soil gases as a function of i) the pristine gas mixture, ii) the diffusivity of the chemicals, and iii) the thickness of the transited medium. Carbon dioxide (CO2), hydrogen (H2), and helium (He) were used in a laboratory-scale flux simulator to investigate the evolution of the gas composition profile in an artificial soil of constant thickness. The agreement between the theoretical calculations and the experimental results supports the validity of the model. Our results indicate a good reproducibility of the transient changes in the concentrations of CO2, He, and H2 in CO2-rich gas mixtures that contain He and H2 as trace gases. Finally, the theoretical results were used to analyze the H2 and CO2 continuous monitoring data collected at Etna volcano in 2010
    Description: Published
    Description: 1565–1583
    Description: 2V. Dinamiche di unrest e scenari pre-eruttivi
    Description: 5V. Sorveglianza vulcanica ed emergenze
    Description: 1IT. Reti di monitoraggio e Osservazioni
    Description: JCR Journal
    Description: open
    Keywords: Soil gases ; Volcanic gas composition ; Hydrogen ; Carbon dioxide ; CO2 ; Helium ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 38
    Publication Date: 2019-01-09
    Description: Greece has a very complex geodynamic setting deriving from a long and complicat-ed geological history being characterized by intense seismic activity and enhanced geothermal gradient. This activity, with the contribution of an active volcanic arc, favours the existence of many gas manifestations. Depending on the prevailing gas species, the latter can be subdivided in three main groups: CO2-, N2- and CH4-dominated. In the present work, we focus on methane and light hydrocarbons (C2-C6) to define their origin. CH4 concentrations (〈2 to 915,200 μmol/mol) and isotop-ic ratios (δ13C -79.8 to +16.9 ‰, δD -298 to +264‰) cover a wide range of values indicating different origins and/or secondary post-genetic processes. Samples from gas discharged along the Ionian coast and in northern Aegean Sea have a prevail-ing microbial origin. Cold and thermal gas manifestations of central and northern Greece display a prevalent thermogenic origin. Methane in gases released along the active volcanic arc is prevailingly abiogenic, although thermogenic contributions cannot be excluded. Gases collected in the geothermal areas of Sperchios basin and northern Euboea are likely affected by strong secondary oxidation processes, as suggested by their highly positive C and H isotopic values (up to +16.9‰ and +264‰ respectively) and low C1/(C2+C3) ratios.
    Description: Submitted
    Description: Thessaloniki, Greece
    Description: 4V. Vulcani e ambiente
    Description: open
    Keywords: Hellenic territory ; hydrothermal gases ; cold gas emissions ; origin of hydrocarbon gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Conference paper
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  • 39
    Publication Date: 2017-04-04
    Description: Characteristics of radon transport in porous media were studied through both in situ and lab-scale measurements. In situ measurements of radon activity concentration, together with soil thoron and carbon dioxide efflux, were carried out on Mt. Etna volcano. More detailed information on radon transport mechanisms has been obtained from laboratory measurements. In particular, we report the first results of a systematic study carried out at the University of Catania (Italy) by means of a facility consisting of a large cylindrical stainless steel vessel, homogeneously filled with different materials. Radon concentration vertical profiles were extracted in low-moisture samples for different advective fluxes, temperatures and porosities.
    Description: Published
    Description: 673-684
    Description: 6A. Monitoraggio ambientale, sicurezza e territorio
    Description: JCR Journal
    Description: restricted
    Keywords: Controlled conditions ; Diffusion coefficient ; Radon vessel ; Advective flux ; Mt. Etna ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 40
    Publication Date: 2017-04-04
    Description: Although there are many methods for investigating tectonic structures, many faults remain hidden, and they can endanger the life and property of people living along them. The slopes of volcanoes are covered with such hidden faults, near which strong earthquakes and gas releases can appear. Revealing hidden faults can therefore contribute significantly to the protection of people living in volcanic areas. In the study, seven different techniques were used for making measurements of in-soil radon concentrations in order to search for hidden faults on the SE flank of the Mt. Etna volcano. These reported methods had previously been proved to be useful tools for investigating fault structures. The main aim of the experiment presented here was to evaluate the usability of these methods in the geological conditions of the Mt. Etna region, and to find the best place for continual radon monitoring using a permanent station in the near future.
    Description: Published
    Description: 70-73
    Description: 5V. Sorveglianza vulcanica ed emergenze
    Description: JCR Journal
    Description: restricted
    Keywords: Mt. Etna ; soil gas ; hidden faults ; radon ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 41
    Publication Date: 2017-04-04
    Description: Instrumental seismic catalogues are an essential tool for the zonation of the territory and the production of seismic hazard maps. They are also a valuable instrument for detailed seismological studies regarding active volcanoes and, above all, for interpreting the magma dynamics and the evolution of eruptive phenomena. In this paper, we show the first instrumental earthquake catalogue of Mt. Etna, for the period 2000-2010, with the purpose of producing a homogeneous dataset of 10 years of seismological observations. During this period, 16,845 earthquakes have been recorded by the seismic network run by the Istituto Nazionale di Geofisica and Vulcanologia, Osservatorio Etneo, in Catania. A total of 6,330 events, corresponding to approximately 40% of all earthquakes recorded, were located by using a one-dimensional VP velocity model. The magnitude completeness of the catalogue is equal to about 1.5 for the whole period, except for some short periods in 2001 and 2002-2003 and at the end of 2009. The reliability of the data collected is supported by the good values of the main hypocentral parameters through the time. The spatial distribution of seismicity allowed the highlighting of several seismogenetic areas characterized by different seismic rates and focal depths. This seismic catalogue represents a fundamental tool for several research aiming to a better understanding of the behavior of an active volcano such as Mt. Etna.
    Description: Published
    Description: S0435
    Description: 4IT. Banche dati
    Description: JCR Journal
    Description: open
    Keywords: Catalogue ; Mt. Etna ; eartquakes ; 04. Solid Earth::04.06. Seismology::04.06.06. Surveys, measurements, and monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 42
    Publication Date: 2017-04-04
    Description: The stable carbon isotopes of CO2 provide constraints about the sources and the fluxes between different carbon reservoirs and sinks such as the atmosphere, the biosphere, the carbon dioxide of deep origin, and the oceans. From a volcanological standpoint, the amount of CO2 emitted by soils during unrests equals or exceeds the carbon dioxide released from the craters of the volcanoes. Among the techniques of volcano surveillance, the stable isotope composition of carbon of the CO2 emitted from the ground is a proxy for magmatic activity. Since decades, the carbon isotope composition has been analyzed in the laboratory by mass spectrometer on the gas samples collected in field. Since a few years ago, the development of new optical class of isotope analyzer based on the infrared laser allowed to determine in situ the isotope composition of the atmospheric CO2. This study focuses on the measurement in situ of δ13C of the CO2 emitted by soils and shows the results of the tests carried out in the laboratory and in field. A special gas sampling method has been fine tuned to collect the gas at a constant flux rate from a depth of 50 cm in the soils, and to identify the isotopologues of the CO2. The method has been tested in the laboratory and in field with a Delta RayTM Isotope Ratio Infrared Spectrometer of the ThermoFisher Scientific, field-able to analyze the δ13C and δ18O of CO2. The gases were collected by a pumping system, and addressed online to the analyzer through a precision valve. This tailor-made device was added to the standard equipment of the instrument in order to adjust the gas flow in input to the analyzer. In this way, the CO2 concentration in the cell fulfills the concentration range of the analyzer (200 - 3500 ppm vol) in spite of the CO2 concentration in the ground gases. The spatial survey of carbon isotopologues of CO2 emitted by soils were performed at Vulcano (Aeolian Islands) on a sampling grid that consists of 20 measurement points on a 2.2 km2 area at the base of the La Fossa cone. The measurement of the soil CO2 flux was also performed in the same sampling grid according to the dynamic concentration method. The results indicate that the sampling system allows the measurement of δ13C in the ground gases with CO2 concentration in the range from 〈 1000 ppm vol to 100% vol. During the spatial survey we measured δ13C of CO2 values in the range -22‰ (organic source) to 0‰, that represents the signature of deep source of CO2 at Vulcano. Furthermore, the measurement of the δ13C allowed to differentiate the sources (volcanic, biogenic, atmospheric) involved in the CO2 emissions from the soils, and identify two areas of degassing with isotopic signature of deep origin at Faraglione and Grotta dei Palizzi. Furthermore, the results of the extensive investigation of both the spatial distribution of the carbon isotopologues and the CO2 flux from soils allowed to assess the budget of CO2 of deep origin emitted from the degassing areas.
    Description: Published
    Description: Firenze
    Description: 2V. Dinamiche di unrest e scenari pre-eruttivi
    Description: 4V. Vulcani e ambiente
    Description: 5V. Sorveglianza vulcanica ed emergenze
    Description: open
    Keywords: CO2 isotopologues ; 03. Hydrosphere::03.04. Chemical and biological::03.04.02. Carbon cycling ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 03. Hydrosphere::03.04. Chemical and biological::03.04.08. Instruments and techniques ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Poster session
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  • 43
    Publication Date: 2017-04-04
    Description: The Dead Sea Transform (DST) fault system,where a lateral displacement between the African and Arabian plates occurs, is characterised by anomalous heat flux in the Israeli area close to the border with Syria and Jordan. The concentration of He and CO2, and isotopic composition of He and total dissolved inorganic carbon were studied in cold and thermalwaters collected along the DST, in order to investigate the source of volatiles and their relationship with the tectonic framework of the DST. The waters with higher temperature (up to 57.2 °C) are characterised by higher amounts of CO2 and helium (up to 55.72 and 1.91 ∗ 10−2 cc l−1, respectively). Helium isotopic data (R/Ra from 0.11 to 2.14) and 4He/20Ne ratios (0.41–106.86) show the presence of deep-deriving fluids consisting of a variable mixture ofmantle and crust end-members,with the former reaching up to 35%. Carbon isotope signature of total dissolved carbon from hot waters falls within the range of magmatic values, suggesting the delivery of deep-seated CO2. The geographical distribution of helium isotopic data and isotopic carbon (CO2) values coupled with (CO2/3He ratios) indicate a larger contribution of mantle-derived fluids affecting the northern part of the investigated area, where the waters reach the highest temperature. These evidences suggest the occurrence of a favourable tectonic framework, including a Moho discontinuity up-rise and/or the presence of a deep fault system coupled with the recent magmatic activity recognised in the northern part of Israel.
    Description: Published
    Description: 50–57
    Description: 4V. Vulcani e ambiente
    Description: JCR Journal
    Description: restricted
    Keywords: Dead Sea Fault ; Fluid geochemistry ; Dissolved gases ; Helium isotopes ; Carbon isotopes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 44
    Publication Date: 2017-04-04
    Description: A close relationship between earthquake swarms, volcanic eruptions, and ground deformation at Mt. Etna was well documented shortly before the beginning of the July–August 2001 eruption. Past experiences at this volcano suggest how magma/dike intrusion in the shallow crust or in the upper part of the volcanic pile normally occurs after several years/months of internal recharging. Since seismic investigations provide a means to study the scale and origin of stress perturbations at active volcanoes, allowing to better investigating the preparation phase of an eruption, in this paper, we performed a close examination of the seismic activity recorded at Mt. Etna in the months preceding the 2001 eruption and in particular between November 2000 and July 2001. After integrating data recorded by the two networks operating during that time and run by the Istituto Internazionale di Vulcanologia and SISTEMA POSEIDON, we relocated 522 earthquakes by using the tomoDD code in a 3D velocity model, and then we computed their fault plane solutions. The application of different selection criteria enabled obtaining a good-quality revised data set consisting of 111 fault plane solutions. The high-precision locations identified well-defined seismic clusters, in different periods, suggesting a link with the magma migration from a depth of 8–13 km b.s.l. towards shallower zones. Moreover, the computed maximum compressive stress axis, as inferred from earthquake focal mechanisms, indicated a roughlyW-E-oriented σ1. This findings reflect an overpressure of the mid to shallow crust due to the progressive magma uprising in central portion of the volcano and also highlighted a rotation of the local stress field with respect to the regional one N-S trending. In addition, P-axis distribution pointed out the presence of a center of pressure located to the south of the Central Craters. These results provide particularly compelling evidence for a direct causal link between pressurization of the midlevel volcanic plumbing system by ascending magma and precursory local stress field reorientations, demonstrating that seismological analysis can be used to detect subtle local stress changes that herald eruptive activity.
    Description: Published
    Description: 11-23
    Description: 1T. Geodinamica e interno della Terra
    Description: JCR Journal
    Description: restricted
    Keywords: Volcanic unrest ; Mt. Etna ; earthquakes ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 45
    Publication Date: 2022-01-11
    Description: Submarine volcanism represents ~80% of the volcanic activity on Earth and is an important source of mantle-derived gases. These gases are of basic importance for the comprehension of mantle characteristics in areas where subaerial volcanism is missing or strongly modified by the presence of crustal/atmospheric components. Though, the study of submarine volcanism remains a challenge due to their hazardousness and sea-depth. Here, we report 3He/4He measurements in CO2–dominated gases discharged at 500 m below sea level from the high-temperature (~220 °C) hydrothermal system of the Kolumbo submarine volcano (Greece), located 7 km northeast off Santorini Island in the central part of the Hellenic Volcanic Arc (HVA). We highlight that the mantle below Kolumbo and Santorini has a 3He/4He signature of at least 7.0 Ra (being Ra the 3He/4He ratio of atmospheric He equal to 1.39×10−6), 3 Ra units higher than actually known for gases-rocks from Santorini. This ratio is also the highest measured across the HVA and is indicative of the direct degassing of a Mid-Ocean-Ridge- Basalts (MORB)-like mantle through lithospheric faults. We finally highlight that the degassing of high-temperature fluids with a MORB-like 3He/4He ratio corroborates a vigorous outgassing of mantlederived volatiles with potential hazard at the Kolumbo submarine volcano.
    Description: Published
    Description: 28013
    Description: 1V. Storia e struttura dei sistemi vulcanici
    Description: 4V. Vulcani e ambiente
    Description: 3A. Ambiente Marino
    Description: JCR Journal
    Description: reserved
    Keywords: Kolumbo ; submarine volcano ; 3He/4He ; volcanic gases ; hydrothermal system ; volcanic arc ; Aegean ; Greece ; MORB ; mantle ; Santorini ; crustal contamination ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.06. Subduction related processes ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.07. Tectonophysics::04.07.08. Volcanic arcs ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 46
    Publication Date: 2024-05-09
    Description: The Principal Cordillera of Central Chile is characterized by two belts of different ages and lithologies: (i) an eastern Mesozoic belt, consisting of limestone- and gypsum-rich sedimentary rocks at the border between Central Chile and Argentina, where the active volcanic arc occurs; and (ii) a western belt of Cenozoic age containing basaltic to andesitic volcanic and volcanoclastic sequences. This distinctive geological setting controls water chemistry of cold and thermal springs in the region, which are fed by meteoric water that circulates through deep regional structures. In the western sector of Principal Cordillera, water–rock interaction processes produce lowTDS, slightly alkaline HCO3 − dominatedwaters, although dissolution of underlyingMesozoic evaporitic rocks occasionally causes SO4 2− and Cl− enrichments. In this area, few Na+–HCO3 − and Na+–SO4 2− waters occurred, being likely produced by a Ca2+–Na+ exchange during water–rock interactions. Differently, the chemical features of Ca2+–Cl−waterswas likely related to an albitization–chloritization process affecting basaltic to andesitic rocks outcropping in this area. Addition of Na+–Cl− brines uprising from the eastern sector through the westverging thrust faults cannot be excluded, as suggested by the occurrence of mantle He (~19%) in dissolved gases. In contrast, in the eastern sector of the study region, mainly characterized by the occurrence of evaporitic sequences and relatively high heat flow,mature Na+–Cl− waters were recognized, the latter being likely related to promising geothermal reservoirs, as supported by the chemical composition of the associated bubbling and fumarolic gases. Their relatively low3He/4He ratios (up to 3.9 Ra)measured in the fumaroles on this area evidenced a significant crustal contamination by radiogenic 4He. The latter was likely due to (i) degassing from 4He-rich magma batches residing in the crust, and/or (ii) addition of fluids interacting with sedimentary rocks. This interpretation is consistent with the measured δ13C-CO2 values (from−13.2 to−5.72‰vs. V-PDB) and the CO2/3He ratios (up to 14.6 × 1010), which suggest that CO2 mostly originates from the limestone-rich basement and recycling of subducted sediments,with an important addition of sedimentary (organic-derived) carbon,whereas mantle degassing contributes at a minor extent. According to geothermometric estimations based on the Na+, K+, Mg2+ and Ca2+ contents, the mature Na+–Cl− rich waters approached a chemical equilibrium with calcite, dolomite, anhydrite, fluorite, albite, K-feldspar and Ca- andMg-saponites at a broad range of temperatures (up to ~300 °C) In the associated gas phase, equilibria of chemical reactions characterized by slowkinetics (e.g. sabatier reaction) suggested significant contributions from hot and oxidizing magmatic gases. This hypothesis is consistent with the δ13C-CO2, Rc/Ra, CO2/3He values of the fumarolic gases. Accordingly, the isotopic signatures of the fumarolic steam is similar to that of fluids discharged from the summit craters of the two active volcanoes in the study area (Tupungatito and Planchón–Peteroa). These results encourage the development of further geochemical and geophysical surveys aimed to provide an exhaustive evaluation of the geothermal potential of these volcanic–hydrothermal systems.
    Description: Published
    Description: 97-113
    Description: 1V. Storia e struttura dei sistemi vulcanici
    Description: JCR Journal
    Description: restricted
    Keywords: Fluid geochemistry ; Central Chile ; Water–gas–rock interaction ; Hydrothermal reservoir ; Geothermal resource ; Volcanoes ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 47
    Publication Date: 2020-12-09
    Description: We report a new case of methane (CH4) of apparent abiotic origin in continental serpentinized ultramafic rocks. Multiple analytical techniques, on-site and in the laboratory, revealed methane and ethane degassing from hyperalkaline (pH 〉 11) Ca2þ eOH mineral waters in boreholes drilled in the Alter-do- Chão igneous intrusion, at Cabeço de Vide, in mainland Portugal. The C and H isotopic composition of CH4 (d13C w 20&; d2H: 283&) suggests a dominant abiotic origin, although minor thermogenic contributions cannot be excluded. Similarly, low methane-to-ethane ratios suggest a predominantly nonmicrobial source, consistent with previous microbiological data showing the lack of methanogenic archaea in these waters. Heavier hydrocarbons, CO2 and H2 are below detection limits. This case study confirms that CH4 from serpentinized ultramafic rocks can be transported by hyperalkaline fluids linked to deep circulation of meteoric waters. Maximum depth of Cabeço de Vide serpentinized rocks is less than 1 km, and present temperatures are likely lower than 50 C. Serpentinization and related gas formation may have occurred at any time during thermal evolution of the igneous intrusion, so gas formation temperature cannot be easily determined. This case is an opportunity to test thermometry provided by CH4 isotopologue analyses. The existence of methane in continental serpentinized igneous rocks is more widespread than previously thought and petroleum systems with similar serpentinized ultramafics in reservoir rocks may have traces of the observed 13C-enriched CH4
    Description: Published
    Description: 12-16
    Description: 7A. Geofisica di esplorazione
    Description: JCR Journal
    Description: restricted
    Keywords: Abiotic methane, serpentinization ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 48
    Publication Date: 2021-07-13
    Description: Hot Lake is a recently described thermal brine pool off Panarea Island (Eolian Islands, Italy) where emitted fluids are highly saline and rich in CO2 and H2S. The prokaryotic community composition in surface sediment samples was analyzed by high-throughput Illumina sequencing targeting the V3 region of the 16S rRNA at two time points that differed mainly with respect to temperature conditions, high-temperature (94 °C, HT09) and low-temperature (28.5 °C, LT10). Bacterial richness and diversity were greater than those of Archaea under both temperature conditions. In contrast to Bacteria, diversity and evenness of Archaea greatly increased at LT10. While the phylogenetic analysis indicated the presence of members mostly affiliated with the same taxonomic groups, their relative abundances differed from HT09 to LT10, resulting in different bacterial and archaeal assemblages. Both HT09 and LT10 were dominated by members of the Epsilonproteobacteria. Within this subphylum, bacteria of the genus Sulfurimonas were most frequently detected at HT09, while Arcobacter prevailed at LT10. The abundance of other dominant taxonomic groups (≥1 % of Illumina reads) also correlated with temperature conditions. Members assigned to hyperthermophilic Euryarchaeota (Thermococci) or to thermophilic (Caldiserica) and thermoresistant (Firmicutes) bacterial taxa were dominant at HT09, while those related to non-thermophilic Bacteroidetes, Fusobacteria and Actinobacteria were dominant at LT10. Several, probably photosynthetic, members of the Alphaproteobacteria, Chlorobi, Cyanobacteria and Chloroflexi were recovered under both temperature conditions. The co-occurrence of photosynthetic and chemolithotrophic microorganisms represents a unique feature of shallow vents such as Hot Lake
    Description: Published
    Description: 547-559
    Description: 3A. Ambiente Marino
    Description: JCR Journal
    Description: restricted
    Keywords: Microbial diversity ; Shallow Idrthermal systems ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 49
    Publication Date: 2021-07-14
    Description: The geochemical behaviour of Rare Earth Elements, Zr and Hf was investigated in the thermal waters of Nevado del Ruiz volcano system. A wide range of pH, between 1.0 and 8.8, characterizes these fluids. The acidic waters are sulphate dominatedwith different Cl/SO4 ratios. The important role of the pH and the ionic complexes for the distribution of REE, Zr and Hf in the aqueous phase was evidenced. The pH rules the precipitation of authigenic Fe and Al oxyhydroxides producing changes in REE, Zr, Hf amounts and strong anomalies of Cerium. The precipitation of alunite and jarosite removes LREE from the solution, changing the REE distribution in acidic waters. Y–Ho and Zr–Hf (twin pairs) have a different behaviour in strong acidic waterswith respect to the water with pH near-neutral. Yttrium and Ho behave as Zr and Hf in waters with pH near neutral-to-neutral, showing superchondritic ratios. The twin pairs showed to be sensitive to the co-precipitation and/or adsorption onto the surface of authigenic particulate (Fe-, Al-oxyhydroxides), suggesting an enhanced scavenging of Ho and Hf with respect to Y and Zr, leading to superchondritic values. In acidic waters, a different behaviour of twin pairs occurs with chondritic Y/Ho ratios and sub-chondritic Zr/Hf ratios. For the first time, Zr and Hf were investigated in natural acidic fluids to understand the behaviour of these elements in extreme acidic conditions and different major anion chemistry. Zr/Hf molar ratio changes from 4.75 to 49.29 in water with pH b 3.6. In strong acidic waters the fractionation of Zr and Hf was recognized as function of major anion contents (Cl and SO4), suggesting the formation of complexes leading to sub-chondritic Zr/Hf molar ratios.
    Description: Published
    Description: 125–133
    Description: 2V. Dinamiche di unrest e scenari pre-eruttivi
    Description: JCR Journal
    Description: restricted
    Keywords: Zirconium ; Hafnium ; Rare earth elements ; Ionic complexes ; Acidic waters ; Fe–Al oxyhydroxides ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 50
    Publication Date: 2020-12-22
    Description: Natural hydrocarbon gas seeps are surface expressions of Petroleum Seepage Systems, whereby gas is ascending through faults from pressurized reservoirs that are typically associated with sandstones or limestones. A spectacular “eternal flame” in western New York State marks a gas macroseep of dominantly thermogenic origin emanating directly from deep shale source rocks, which makes this a rare case in contrast to most Petroleum Seepage Systems where gas derives from conventional reservoirs. The main flaming seep releases about 1 kg of methane per day and may feature the highest ethane and propane (C2 þ C3) concentration ever reported for a natural gas seep (w35 vol. %). The same gas is also released to the atmosphere through nearby invisible and diffuse seepages from the ground. The synopsis of our data with available gas-geochemical data of reservoir gases in the region and the stratigraphy of underlying shales suggests that the thermogenic gas originates from Upper Devonian shales without intermediation of a conventional reservoir. A similar investigation on a second “eternal flame” in Pennsylvania suggests that gas is migrating from a conventional sandstone pool and that the seep is probably not natural but results from an undocumented and abandoned gas or oil well. The large flux of the emitted shale gas in New York State implies the existence of a pressurized gas pool at depth. Tectonically fractured shales seem to express “naturally fracked” characteristics and may provide convenient targets for hydrocarbon exploration. Gas production from “tectonically fracked” systems might not require extensive artificial fracking.
    Description: Published
    Description: 178-186
    Description: 7A. Geofisica di esplorazione
    Description: JCR Journal
    Description: restricted
    Keywords: gas seep, methane, shale-gas, hydrocarbons ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 51
    Publication Date: 2021-05-12
    Description: In the framework of the UPStrat-MAFA project, a seismic hazard assessment has been undertaken in the volcanic region of Mt. Etna as a first step in studies aimed at evaluating the risk on an urban scale. The analysis has been carried out with the SASHA code which uses macroseismic data in order to calculate, starting from the site seismic history, the maximum intensity value expected in a given site with a probability of exceedance of 10 % (Iref), for a fixed exposure time. Depending on the aims of the project, hazard is estimated for local volcano-tectonic seismicity and short exposure times (10 and 30 years), without taking into account the contribution of ‘‘regional’’ events characterized by much longer recurrence times. Results from tasks A, B and D of the project have produced an updated macroseismic dataset, better performing attenuation models and new tools for SASHA, respectively. The maps obtained indicate that the eastern flank of Etna, the most urbanized sector of the volcano, is characterized by a high level of hazard with Iref values up to degree VIII EMS, and even IX EMS locally. The disaggregated data analysis allows recognizing the ‘‘design earthquake’’ and the seismogenic fault which most contribute to the hazard at a site-scale. The latter analysis is the starting point to select the scenario earthquake to be used in the analyses of tasks C and F of the project dealing with, respectively, synthetic ground motion simulations and the evaluation of the Disruption Index.
    Description: Published
    Description: 1813–1825
    Description: 3T. Pericolosità sismica e contributo alla definizione del rischio
    Description: JCR Journal
    Description: reserved
    Keywords: Volcano-tectonic earthquakes ; Macroseismic intensity ; Seismic history ; Attenuation models ; Exceedance probability ; Seismic hazard ; Mt. Etna ; Italy ; 04. Solid Earth::04.06. Seismology::04.06.11. Seismic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 52
    Publication Date: 2017-04-04
    Description: The spectacular Indonesian Lusi mud eruption started in May 2006 following to a 6.3 M earthquake striking the island of Java (Mazzini et al., 2007). Previous studies investigated the mechanisms of reactivation of the Watukosek fault system that crosses Lusi locality (Mazzini et al., 2009) and continues to the NE of Java. Results show that the quake triggered lateral movement of this strike-slip system resulting in several aligned eruptions sites including Lusi. Geochemical studies of the erupted fluids reveal a mantle signature and point to a connection with the neighboring Arjuno-Welirang volcanic complex (Mazzini et al., 2012) indicating that Lusi is a sedimentary hosted geothermal system. In order to estimate the amount of gas that is being released around the Lusi crater ( 7 km2), we recently conducted a survey of over 300 stations (CO2 and CH4 flux measurements) using a closed-chamber flux-meter system and collected gas samples to analyze the composition of the seeps. In addition 20 soil gas concentrations were collected using a steel probe driven into the ground to a depth of 0.7-0.8 m to avoid the major influence of meteorological variables. Results show that the highest CO2 flux is present along the NE-SW oriented Watukosek fault (with peaks up to 400 g/m2day) and along the E-W oriented Siring antithetic fault (with peaks up to 110 g/m2day). The pools have overall a CH4-dominated composition, while the dry fault-related fractures are CO2-dominated which is in agreement with higher recorded temperatures at these sites. Flux measurements in the seeping pools reveal that CO2 flux is an order of magnitude higher than that measured in the fault zones, and two order of magnitude for CH4 flux. C02 and CH4 microseepage is occurring in significant amount throughput the mud-covered area with average values of 297 and 95 g/m2day, respectively. CH4 flux shows the highest values in the W and NW sector of the Lusi area, while CO2 flux highlights the presence of three areas characterized by high values, in the northern, southern and western sectors. Methane concentrations show high values (maximum value 1490 ppm) in the eastern part of Lusi crater, while CO2 show low values (maximum value 11580 ppm) along the west Lusi profile.
    Description: Unpublished
    Description: Vienna
    Description: 7A. Geofisica di esplorazione
    Description: restricted
    Keywords: Gas flux ; seep ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Oral presentation
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  • 53
    Publication Date: 2017-04-04
    Description: We present a geochemical study on olivine- and clinopyroxene-hosted melt inclusions (MIs) from 2001-2006 Etna basaltic lavas and pyroclastites. Three MI suites are distinguished on the basis of trace element fingerprinting. Type-1 MIs (from 2001 Upper South and 2002 Northeast vents) share their trace element signature with low-K lavas erupted before 1971. Critical trace element ratios (e.g.,K/La, Ba/Nb), along with Pb isotope data of Type-1 MIs provide evidence for a heterogeneous mantle source resulting from mixing of three end-members with geochemical and isotopic characteristics of EM2, DMM and HIMU components. Type-1 MIs composition does not support involvement of subduction-related components. Type-2 (from 2001 Lower and 2002 South vents) and Type-3 (2004 eruption) MIs reveal “ghost plagioclase signatures”, namely lower concentrations in strongly incompatible elements, and positiveSr, Ba and Eu anomalies. Both Type-1 and Type-2 MIs occur in 2006 olivines, which highlight the occurrence of mixing between Type-1 and Type-2 end-members. Type-2/Type-3 MIs testify to en-route processes(plagioclase assimilation and volatile fluxing) peculiar for “deep dike fed” eruptions. The latter are strongly controlled by tectonics or flank instability that occasionally promote upraise ofundegassed, more radiogenic primitive magma, which may interact with plagioclase-rich crystal mush/cumulates before erupting. Type-2/Type-3 MIs approach the less radiogenic Pb isotopic compositionof plagioclase from prehistoric lavas, thus suggesting geochemical overprinting of present-day melts by older products released from distinct mantle sources. Our study emphasizes that MIs microanalysis offers new insights on both source characteristics and en-route processes, allowing to a link between melt composition and magma dynamics.
    Description: Published
    Description: 2109–2126
    Description: 1V. Storia e struttura dei sistemi vulcanici
    Description: JCR Journal
    Description: restricted
    Keywords: Mt. Etna ; source heterogeneity ; melt inclusion ; ghost plagioclase ; 04. Solid Earth::04.04. Geology::04.04.07. Rock geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 54
    Publication Date: 2017-04-04
    Description: A multidisciplinary approach integrating self-potential, soil temperature, heat flux, CO2 efflux and gravity gradiometry signals was used to investigate a relatively small fissure-related hydrothermal systemnear the summit of Mt. Etna volcano (Italy). Measurements were performed through two different surveys carried out at the beginning and at the end of July 2009, right after the end of the long-lived 2008–2009 flank eruption and in coincidencewith an increase in diffuse flank degassing related to a reactivation of the volcano, leading to the opening of a new summit vent (NSEC). The main goal was to use a multidisciplinary approach to the detection of hidden fractures in an area of evident near-surface hydrothermal activity. Despite the different methodologies used and the different geometry of the sampling grid between the surveys, all parameters concurred in confirming that the study area is crossed by faults related with the main fracture systems of the south flank of the volcano,where a continuous hydrothermal circulation is established. Results also highlighted that hydrothermal activity in this area changed both in space and in time. These changes were a clear response to variations in themagmatic system, notably tomigration of magma at various depth within the main feeder systemof the volcano. The results suggest that this specific area, initially chosen as the optimal test-site for the proposed approach, can be useful in order to get information on the potential reactivation of the summit craters of Mt. Etna.
    Description: Istituto Nazionale di Geofisica e Vulcanologia — Sezione di Catania — Osservatorio Etneo
    Description: Published
    Description: 111-125
    Description: 4V. Vulcani e ambiente
    Description: JCR Journal
    Description: restricted
    Keywords: Etna volcano ; Hydrothermal system ; Fractures systems ; Multidisciplinary ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 55
    Publication Date: 2020-02-24
    Description: Over the last 30 years, geochemical research has demonstrated that abiotic methane (CH4), formed by chemical reactions which do not directly involve organic matter, occurs on Earth in several specific geologic environments. It can be produced by either high-temperature magmatic processes in volcanic and geothermal areas, or via low-temperature (〈100 C) gas-water-rock reactions in continental settings, even at shallow depths. The isotopic composition of C and H is a first step in distinguishing abiotic from biotic (including either microbial or thermogenic) CH4. Herein we demonstrate that integrated geochemical diagnostic techniques, based on molecular composition of associated gases, noble gas isotopes, mixing models, and a detailed knowledge of the geologic and hydrogeologic context are necessary to confirm the occurrence of abiotic CH4 in natural gases, which are frequently mixtures of multiple sources. Although it has been traditionally assumed that abiotic CH4 is mainly related to mantle-derived or magmatic processes, a new generation of data is showing that low-temperature synthesis related to gas-water-rock reactions ismore common than previously thought. This paper reviews the major sources of abiotic CH4 and the primary approaches for differentiating abiotic from biotic CH4, including novel potential tools such as clumped isotope geochemistry. A diagnostic approach for differentiation is proposed
    Description: Published
    Description: 276-299
    Description: 7A. Geofisica di esplorazione
    Description: JCR Journal
    Description: restricted
    Keywords: Abiotic methane ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 56
    Publication Date: 2017-04-04
    Description: The paper proposes a method to evaluate the potential for electric power production at any site of possible geothermal interest. Accounting for geological data of the reservoirs, the method allows the computation of the available electrical power of the investigated site. Electrical energy production from geothermal sources is realized through different techniques, such as single flash and double flash, dry steam, and binary ORC plants. The technique chosen to be the most productive is determined by analyzing a specific range of geofluid properties, mainly temperature and pressure. Moreover, each plant typology has a global efficiency that may be correlated to geofluid enthalpy by empiric relations available in literature. The proposed evaluation method brings together all these correlations, yielding the power availability from a geosource, once its temperature and pressure are known. The method takes as input the geofluid available flow rate, its pressure, temperature and non-condensable gas content. It defines the best plant option from these parameters, calculates its global efficiency and finally returns the actual available power. For sites of geothermic interest, such as the volcanic island of Ischia in Southern Italy, the results of the application of this new method clearly highlight the most suitable zones for power plants installations.
    Description: Published
    Description: 303-312
    Description: 4V. Vulcani e ambiente
    Description: 5A. Energia e georisorse
    Description: JCR Journal
    Description: restricted
    Keywords: Geothermal power plants Geothermal exergy Ischia volcanic island ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration ; 04. Solid Earth::04.02. Exploration geophysics::04.02.03. Heat flow ; 04. Solid Earth::04.08. Volcanology::04.08.04. Thermodynamics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 57
    Publication Date: 2017-04-04
    Description: Between January 2011 and April 2013, Mt. Etna's eruptive activity consisted of episodic intra-crater strombolian explosions and paroxysms from Bocca Nuova, Voragine, and the New South-East (NSEC) summit craters, respectively. Eruptions from NSEC consisted of initial increasing strombolian activity and lava flow output, passing to short-lasting lava fountaining. In this study we present seismic, infrasound, radiometric, plume SO2 and HCl fluxes and geodetic data collected by the INGV monitoring system between May 2012 and April 2013. The multi-parametric approach enabled characterization of NSEC eruptive activity at both daily and monthly time scales and tracking of magma movement within Mt. Etna's plumbing system. While seismic, infrasound and radiometric signals give insight on the energy and features of the 13 paroxysms fed by NSEC, SO2 and halogen fluxes shed light on the likely mechanisms triggering the eruptive phenomena. GPS data provided clear evidence of pressurization of Mt. Etna's plumbing system from May 2012 to middle February 2013 and depressurization during the February-April 2013 eruptive activity. Taking into account geochemical data, we propose that the paroxysms' sequence represented the climax of a waxing-waning phase of degassing that had started as early as December 2012, and eventually ended in April 2013. Integration of the multidisciplinary observations suggests that the February-April 2013 eruptive activity reflects a phase of release of a volatile-rich batch of magma that had been stored in the shallow volcano plumbing system at least four months before, and with the majority of gas released between February and March 2013. This article is protected by copyright. All rights reserved.
    Description: European FP7 MED-SUV (MEditerranean SUpersite Volcanoes). Grant Number: 308665 European Research Council European FP7 (FP/2007-2013)/ERC. Grant Number: 279802 SIGMA (Sistema Integrato di sensori in ambiente cloud per la Gestione Multirischio Avanzata)
    Description: Published
    Description: 1932–1949
    Description: 3V. Dinamiche e scenari eruttivi
    Description: JCR Journal
    Description: restricted
    Keywords: Mt. Etna ; paroxysmal activity ; SO2 and HCl fluxes ; infrasound and seismic signals ; radiometry ; ground deformation ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 58
    Publication Date: 2017-04-04
    Description: Soil–gas measurements of different gas species were performed in two distinct areas of the Corinth Gulf Rift (Greece): the Aigion-Neos Erineos-Lambiri (ANEL) fault zone and the Rion-Patras fault zone. Both zones lie in one of the most seismically active areas of the Euro-Mediterranean region, where a fast-opening continental rift is located. In particular, the geochemical investigations were focused on fault segments and fracture systems previously inferred by geomorphological, lithological and structural studies. In this work the applicability of soil–gas geochemistry surveys for the exploration of buried/hidden faults was tested by using various statistical methods. Moreover, a comprehensive geostatistical treatment of the collected data provided new insights into the control exerted by active structures on deep-seated gas migration towards the surface. In both investigated areas, the highest 222Rn and CO2 concentration peaks correspond with zones where the interaction among fracture and fault segments was inferred by structural and morphological methods. This indicates a clear correlation between the shape and orientation of the anomalies and the different attitude and kinematic behavior of the faults recognized in the two areas. Furthermore, obtained results show that gases migrate preferentially through zones of brittle deformation by advective processes, as suggested by the relatively high rate of migration needed to obtain anomalies of short-lived 222Rn in the soil pores
    Description: Published
    Description: 86-100
    Description: 5A. Energia e georisorse
    Description: JCR Journal
    Description: restricted
    Keywords: gas geochemistry ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 59
    Publication Date: 2017-04-04
    Description: Tritium is a naturally occurring radionuclide, due to interactions of cosmic-rays with the upper layers of the atmosphere; but its presence in the environment is mainly due to residual fallout from nuclear weapons atmosphere tests, carried out from 1952 till 1980. Tritium reaches the Earth’s surface mainly in the form of precipitation, becoming part of the hydrological cycle, then the interest of tritium content analysis in drinking water is both for dosimetry and health-risk and for using tritium as a natural tracer in the groundwater circulation system. This paper presents results from a survey carried out in the Mt. Etna area (east and west flanks) and in the southern side of Nebrodi in Sicily (Italy), in order to determine tritium activity concentrations in water samples by using liquid scintillation counter. The investigated areas show quite low tritium concentrations, much below the Italian limit of 100 Bq L-1 for drinking water and even comparable with the minimum detectable activity value. The effective dose due to tritium for public drinking water consumption was also evaluated.
    Description: Published
    Description: 861-866
    Description: 6A. Monitoraggio ambientale, sicurezza e territorio
    Description: JCR Journal
    Description: restricted
    Keywords: Tritium ; Tritiated water ; Liquid scintillation ; Mt. Etna ; Drinking water ; 03. Hydrosphere::03.04. Chemical and biological::03.04.07. Radioactivity and isotopes
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 60
    Publication Date: 2017-04-04
    Description: Starting off from a review of previous literature on kinematic models of the unstable eastern flank of Mt. Etna, we propose a new model. The model is based on our analysis of a large quantity of multidisciplinary data deriving from an extensive and diverse network of INGV monitoring devices deployed along the slopes of the volcano. Our analysis had a twofold objective: first, investigating the origin of the recently observed slow-slip events on the eastern flank of Mt. Etna; and second, defining a general kinematic model for the instability of this area of the volcano. To this end, we investigated the 2008–2013 period using data collected from different geochemical, geodetic, and seismic networks, integrated with the tectonic and geologic features of the volcano and including the volcanic activity during the observation period. The complex correlations between the large quantities of multidisciplinary data have given us the opportunity to infer, as outlined in this work, that the fluids of volcanic origin and their interrelationship with aquifers, tectonic and morphological features play a dominant role in the large scale instability of the eastern flank of Mt. Etna. Furthermore, we suggest that changes in the strain distribution due to volcanic inflation/deflation cycles are closely connected to changes in shallow depth fluid circulation. Finally, we propose a general framework for both the short and long term modeling of the large flank displacements observed.
    Description: Published
    Description: 635–658
    Description: 1IT. Reti di monitoraggio e Osservazioni
    Description: JCR Journal
    Description: restricted
    Keywords: Mt. Etna ; monitoring data ; GPS ; flank instability ; gas geochemistry ; volcanic tremor ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 61
    Publication Date: 2017-04-04
    Description: Annals of Geophysics (ISSN: 1593-5213; from 2010, 2037-416X) is a bimonthly international journal, which publishes scientific papers in the field of geophysics sensu lato. It derives from Annali di Geofisica (ISSN: 0365-2556), which commenced publication in January 1948 as a quarterly periodical devoted to general geophysics, seismology, Earth magnetism, and atmospheric studies....
    Description: Published
    Description: E0191
    Description: 1T. Geodinamica e interno della Terra
    Description: 2T. Tettonica attiva
    Description: 3T. Pericolosità sismica e contributo alla definizione del rischio
    Description: 4T. Fisica dei terremoti e scenari cosismici
    Description: 5T. Sorveglianza sismica e operatività post-terremoto
    Description: 6T. Sismicità indotta e caratterizzazione sismica dei sistemi naturali
    Description: 1V. Storia e struttura dei sistemi vulcanici
    Description: 2V. Dinamiche di unrest e scenari pre-eruttivi
    Description: 3V. Dinamiche e scenari eruttivi
    Description: 4V. Vulcani e ambiente
    Description: 5V. Sorveglianza vulcanica ed emergenze
    Description: 1A. Geomagnetismo e Paleomagnetismo
    Description: 2A. Fisica dell'alta atmosfera
    Description: 3A. Ambiente Marino
    Description: 4A. Clima e Oceani
    Description: 5A. Energia e georisorse
    Description: 6A. Monitoraggio ambientale, sicurezza e territorio
    Description: 7A. Geofisica di esplorazione
    Description: 1IT. Reti di monitoraggio e Osservazioni
    Description: 2IT. Laboratori sperimentali e analitici
    Description: 3IT. Calcolo scientifico e sistemi informatici
    Description: 4IT. Banche dati
    Description: 5IT. Osservazioni satellitari
    Description: 6IT. Sale operative
    Description: JCR Journal
    Description: open
    Keywords: editorial ; 01. Atmosphere::01.01. Atmosphere::01.01.99. General or miscellaneous ; 01. Atmosphere::01.01. Atmosphere::01.01.01. Composition and Structure ; 01. Atmosphere::01.01. Atmosphere::01.01.02. Climate ; 01. Atmosphere::01.01. Atmosphere::01.01.03. Pollution ; 01. Atmosphere::01.01. Atmosphere::01.01.04. Processes and Dynamics ; 01. Atmosphere::01.01. Atmosphere::01.01.05. Radiation ; 01. Atmosphere::01.01. Atmosphere::01.01.06. Thermodynamics ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 01. Atmosphere::01.01. Atmosphere::01.01.08. Instruments and techniques ; 01. Atmosphere::01.02. Ionosphere::01.02.99. General or miscellaneous ; 01. Atmosphere::01.02. Ionosphere::01.02.01. Ion chemistry and composition ; 01. Atmosphere::01.02. Ionosphere::01.02.02. Dynamics ; 01. Atmosphere::01.02. Ionosphere::01.02.03. Forecasts ; 01. Atmosphere::01.02. Ionosphere::01.02.04. Plasma Physics ; 01. Atmosphere::01.02. Ionosphere::01.02.05. Wave propagation ; 01. Atmosphere::01.02. Ionosphere::01.02.06. Instruments and techniques ; 01. Atmosphere::01.02. Ionosphere::01.02.07. Scintillations ; 01. Atmosphere::01.03. Magnetosphere::01.03.99. General or miscellaneous ; 01. Atmosphere::01.03. Magnetosphere::01.03.01. Interplanetary physics ; 01. Atmosphere::01.03. Magnetosphere::01.03.02. Magnetic storms ; 01. Atmosphere::01.03. Magnetosphere::01.03.03. Magnetospheric physics ; 01. Atmosphere::01.03. Magnetosphere::01.03.04. Structure and dynamics ; 01. Atmosphere::01.03. Magnetosphere::01.03.05. Solar variability and solar wind ; 01. Atmosphere::01.03. Magnetosphere::01.03.06. Instruments and techniques ; 02. Cryosphere::02.01. Permafrost::02.01.99. General or miscellaneous ; 02. Cryosphere::02.01. Permafrost::02.01.01. Active layer ; 02. Cryosphere::02.01. Permafrost::02.01.02. Cryobiology ; 02. Cryosphere::02.01. Permafrost::02.01.03. Cryosol ; 02. Cryosphere::02.01. Permafrost::02.01.04. Periglacial processes ; 02. Cryosphere::02.01. Permafrost::02.01.05. Seasonally frozen ground ; 02. Cryosphere::02.01. Permafrost::02.01.06. Thermokarst ; 02. Cryosphere::02.01. Permafrost::02.01.07. Tundra ; 02. Cryosphere::02.01. Permafrost::02.01.08. Instruments and techniques ; 02. Cryosphere::02.02. Glaciers::02.02.99. General or miscellaneous ; 02. Cryosphere::02.02. Glaciers::02.02.01. Avalanches ; 02. Cryosphere::02.02. Glaciers::02.02.02. Cryosphere/atmosphere Interaction ; 02. Cryosphere::02.02. Glaciers::02.02.03. Geomorphology ; 02. Cryosphere::02.02. Glaciers::02.02.04. Ice ; 02. Cryosphere::02.02. Glaciers::02.02.05. Ice dynamics ; 02. Cryosphere::02.02. Glaciers::02.02.06. Mass balance ; 02. Cryosphere::02.02. Glaciers::02.02.07. Ocean/ice interaction ; 02. Cryosphere::02.02. Glaciers::02.02.08. Rock glaciers ; 02. Cryosphere::02.02. Glaciers::02.02.09. Snow ; 02. Cryosphere::02.02. Glaciers::02.02.10. Instruments and techniques ; 02. Cryosphere::02.03. Ice cores::02.03.99. General or miscellaneous ; 02. Cryosphere::02.03. Ice cores::02.03.01. Aerosols ; 02. Cryosphere::02.03. Ice cores::02.03.02. Atmospheric Chemistry ; 02. Cryosphere::02.03. Ice cores::02.03.03. Climate Indicators ; 02. Cryosphere::02.03. Ice cores::02.03.04. Ice Core Air Bubbles ; 02. Cryosphere::02.03. Ice cores::02.03.05. Paleoclimate ; 02. Cryosphere::02.03. Ice cores::02.03.06. Precipitation ; 02. Cryosphere::02.03. Ice cores::02.03.07. Teleconnection ; 02. Cryosphere::02.03. Ice cores::02.03.08. Temperature ; 02. Cryosphere::02.03. Ice cores::02.03.09. Instruments and techniques ; 02. Cryosphere::02.04. Sea ice::02.04.99. General or miscellaneous ; 02. Cryosphere::02.04. Sea ice::02.04.01. Atmosphere/sea ice/ocean interaction ; 02. Cryosphere::02.04. Sea ice::02.04.02. Leads ; 02. Cryosphere::02.04. Sea ice::02.04.03. Polynas ; 02. Cryosphere::02.04. Sea ice::02.04.04. Instruments and techniques ; 03. Hydrosphere::03.01. General::03.01.99. General or miscellaneous ; 03. Hydrosphere::03.01. General::03.01.01. Analytical and numerical modeling ; 03. Hydrosphere::03.01. General::03.01.02. Equatorial and regional oceanography ; 03. Hydrosphere::03.01. General::03.01.03. Global climate models ; 03. Hydrosphere::03.01. General::03.01.04. Ocean data assimilation and reanalysis ; 03. Hydrosphere::03.01. General::03.01.05. Operational oceanography ; 03. Hydrosphere::03.01. General::03.01.06. Paleoceanography and paleoclimatology ; 03. Hydrosphere::03.01. General::03.01.07. Physical and biogeochemical interactions ; 03. Hydrosphere::03.01. General::03.01.08. Instruments and techniques ; 03. Hydrosphere::03.02. Hydrology::03.02.99. General or miscellaneous ; 03. Hydrosphere::03.02. Hydrology::03.02.01. Channel networks ; 03. Hydrosphere::03.02. Hydrology::03.02.02. Hydrological processes: interaction, transport, dynamics ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring ; 03. Hydrosphere::03.02. Hydrology::03.02.05. Models and Forecasts ; 03. Hydrosphere::03.02. Hydrology::03.02.06. Water resources ; 03. Hydrosphere::03.02. Hydrology::03.02.07. Instruments and techniques ; 03. Hydrosphere::03.03. Physical::03.03.99. General or miscellaneous ; 03. Hydrosphere::03.03. Physical::03.03.01. Air/water/earth interactions ; 03. Hydrosphere::03.03. Physical::03.03.02. General circulation ; 03. Hydrosphere::03.03. Physical::03.03.03. Interannual-to-decadal ocean variability ; 03. Hydrosphere::03.03. Physical::03.03.04. Upper ocean and mixed layer processes ; 03. Hydrosphere::03.03. Physical::03.03.05. Instruments and techniques ; 03. Hydrosphere::03.04. Chemical and biological::03.04.99. General or miscellaneous ; 03. Hydrosphere::03.04. Chemical and biological::03.04.01. Biogeochemical cycles ; 03. Hydrosphere::03.04. Chemical and biological::03.04.02. Carbon cycling ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.04. Ecosystems ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 03. Hydrosphere::03.04. Chemical and biological::03.04.07. Radioactivity and isotopes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.08. Instruments and techniques ; 04. Solid Earth::04.01. Earth Interior::04.01.99. General or miscellaneous ; 04. Solid Earth::04.01. Earth Interior::04.01.01. Composition and state ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes ; 04. Solid Earth::04.01. Earth Interior::04.01.03. Mantle and Core dynamics ; 04. Solid Earth::04.01. Earth Interior::04.01.04. Mineral physics and properties of rocks ; 04. Solid Earth::04.01. Earth Interior::04.01.05. Rheology ; 04. Solid Earth::04.02. Exploration geophysics::04.02.99. General or miscellaneous ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration ; 04. Solid Earth::04.02. Exploration geophysics::04.02.02. Gravity methods ; 04. Solid Earth::04.02. Exploration geophysics::04.02.03. Heat flow ; 04. Solid Earth::04.02. Exploration geophysics::04.02.04. Magnetic and electrical methods ; 04. Solid Earth::04.02. Exploration geophysics::04.02.05. Downhole, radioactivity, remote sensing, and other methods ; 04. Solid Earth::04.02. Exploration geophysics::04.02.06. Seismic methods ; 04. Solid Earth::04.02. Exploration geophysics::04.02.07. Instruments and techniques ; 04. Solid Earth::04.03. Geodesy::04.03.99. General or miscellaneous ; 04. Solid Earth::04.03. Geodesy::04.03.01. Crustal deformations ; 04. Solid Earth::04.03. Geodesy::04.03.02. Earth rotation ; 04. Solid Earth::04.03. Geodesy::04.03.03. Gravity and isostasy ; 04. Solid Earth::04.03. Geodesy::04.03.04. Gravity anomalies ; 04. Solid Earth::04.03. Geodesy::04.03.05. Gravity variations ; 04. Solid Earth::04.03. Geodesy::04.03.06. Measurements and monitoring ; 04. Solid Earth::04.03. Geodesy::04.03.07. Satellite geodesy ; 04. Solid Earth::04.03. Geodesy::04.03.08. Theory and Models ; 04. Solid Earth::04.03. Geodesy::04.03.09. Instruments and techniques ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.01. Earthquake geology and paleoseismology ; 04. Solid Earth::04.04. Geology::04.04.02. Geochronology ; 04. Solid Earth::04.04. Geology::04.04.03. Geomorphology ; 04. Solid Earth::04.04. Geology::04.04.04. Marine geology ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology ; 04. Solid Earth::04.04. Geology::04.04.06. Rheology, friction, and structure of fault zones ; 04. Solid Earth::04.04. Geology::04.04.07. Rock geochemistry ; 04. Solid Earth::04.04. Geology::04.04.08. Sediments: dating, processes, transport ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.04. Geology::04.04.10. Stratigraphy ; 04. Solid Earth::04.04. Geology::04.04.11. Instruments and techniques ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.05. Geomagnetism::04.05.99. General or miscellaneous ; 04. Solid Earth::04.05. Geomagnetism::04.05.01. Dynamo theory ; 04. Solid Earth::04.05. Geomagnetism::04.05.02. Geomagnetic field variations and reversals ; 04. Solid Earth::04.05. Geomagnetism::04.05.03. Global and regional models ; 04. Solid Earth::04.05. Geomagnetism::04.05.04. Magnetic anomalies ; 04. Solid Earth::04.05. Geomagnetism::04.05.05. Main geomagnetic field ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism ; 04. Solid Earth::04.05. Geomagnetism::04.05.07. Rock magnetism ; 04. Solid Earth::04.05. Geomagnetism::04.05.08. Instruments and techniques ; 04. Solid Earth::04.05. Geomagnetism::04.05.09. Environmental magnetism ; 04. Solid Earth::04.06. Seismology::04.06.99. General or miscellaneous ; 04. Solid Earth::04.06. Seismology::04.06.01. Earthquake faults: properties and evolution ; 04. Solid Earth::04.06. Seismology::04.06.02. Earthquake interactions and probability ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics ; 04. Solid Earth::04.06. Seismology::04.06.04. Ground motion ; 04. Solid Earth::04.06. Seismology::04.06.05. Historical seismology ; 04. Solid Earth::04.06. Seismology::04.06.06. Surveys, measurements, and monitoring ; 04. Solid Earth::04.06. Seismology::04.06.07. Tomography and anisotropy ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 04. Solid Earth::04.06. Seismology::04.06.09. Waves and wave analysis ; 04. Solid Earth::04.06. Seismology::04.06.10. Instruments and techniques ; 04. Solid Earth::04.06. Seismology::04.06.11. Seismic risk ; 04. Solid Earth::04.07. Tectonophysics::04.07.99. General or miscellaneous ; 04. Solid Earth::04.07. Tectonophysics::04.07.01. Continents ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.03. Heat generation and transport ; 04. Solid Earth::04.07. Tectonophysics::04.07.04. Plate boundaries, motion, and tectonics ; 04. Solid Earth::04.07. Tectonophysics::04.07.05. Stress ; 04. Solid Earth::04.07. Tectonophysics::04.07.06. Subduction related processes ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.07. Tectonophysics::04.07.08. Volcanic arcs ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.02. Experimental volcanism ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.04. Thermodynamics ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.01. Computational geophysics::05.01.99. General or miscellaneous ; 05. General::05.01. Computational geophysics::05.01.01. Data processing ; 05. General::05.01. Computational geophysics::05.01.02. Cellular automata, fuzzy logic, genetic alghoritms, neural networks ; 05. General::05.01. Computational geophysics::05.01.03. Inverse methods ; 05. General::05.01. Computational geophysics::05.01.04. Statistical analysis ; 05. General::05.01. Computational geophysics::05.01.05. Algorithms and implementation ; 05. General::05.02. Data dissemination::05.02.99. General or miscellaneous ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.02. Data dissemination::05.02.02. Seismological data ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions ; 05. General::05.02. Data dissemination::05.02.04. Hydrogeological data ; 05. General::05.02. Data dissemination::05.02.05. Collections ; 05. General::05.03. Educational, History of Science, Public Issues::05.03.99. General or miscellaneous ; 05. General::05.04. Instrumentation and techniques of general interest::05.04.99. General or miscellaneous ; 05. General::05.05. Mathematical geophysics::05.05.99. General or miscellaneous ; 05. General::05.06. Methods::05.06.99. General or miscellaneous ; 05. General::05.07. Space and Planetary sciences::05.07.99. General or miscellaneous ; 05. General::05.07. Space and Planetary sciences::05.07.01. Solar-terrestrial interaction ; 05. General::05.07. Space and Planetary sciences::05.07.02. Space weather ; 05. General::05.08. Risk::05.08.99. General or miscellaneous ; 05. General::05.08. Risk::05.08.01. Environmental risk ; 05. General::05.08. Risk::05.08.02. Hydrogeological risk ; 05. General::05.09. Miscellaneous::05.09.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 62
    Publication Date: 2019-01-09
    Description: Nisyros Island, Greece, is a stratovolcano known for its intense hydrothermal activity. On June 2013, during a multidisciplinary field campaign, soil samples were collected in the caldera area to determinate the main mineralogical assemblages and to investigate the distribution of trace element concentrations and the possible relationship to the contribution of fluids of deep origin. Soil samples were analysed with XRD and for the chemical composition of their leachable (deionized water) and pseudo total (microwave digestion) fraction both for major and trace elements. The results allow to divide the samples in 2 groups: Lakki Plain and Stefanos Crater. The latter, where a fumarolic area is located, shows a mineralogical assemblage dominated by phases typical of hydrothermal alteration. Their very low pH values (1.9 – 3.4) show the strong impact of fumarolic gases which are probably also the cause of strong enrichments in these soils of highly volatile elements like S, As, Se, Bi, Sb, Tl and Te.
    Description: Published
    Description: 2SR. VULCANI - Servizi e ricerca per la Società
    Description: JCR Journal
    Description: open
    Keywords: Trace elements ; Hydrothermal alteration ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 63
    Publication Date: 2020-02-24
    Description: Serpentinization of ultramafic rocks is considered a major process of production of abiotic methane (CH4) and hydrogen (H2) on Earth, and it may be responsible for CH4 occurrence on other planets. While serpentinization and CH4 synthesis have been widely studied and modeled in high temperature hydrothermal conditions, such as on submarine mid-ocean ridges, the increasing number of discoveries of abiotic CH4 in ophiolites on continents shows the importance of present-day (meteoric water driven) serpentinization in low temperature (〈100 °C) gas synthesis. As a new case, we report compositional, isotopic, and flux data of gas dissolved in hyperalkaline Ca-OH waters issuing from serpentinized peridotites at Genova (Italy). CH4 is dominantly abiotic (δ13C: -9 ‰ VPDB; δ2H: -168 to - 225 ‰ VSMOW), similar to that released by ophiolites in Oman, Turkey, the Philippines, and by the submarine Lost City serpentinization system. While the absence of CO2 was expected in this kind of fluids, the absence of H2 is unusual. This could be due to hydration of olivine and pyroxene by CO2-rich fluids, eventually associated with high silica activity, which inhibits H2 formation and produces CH4 directly. Thermodynamic modeling and H2O-CH4 isotope equilibrium confirm the low temperatures (〈60°C) of the serpentinization system, and thus the abiotic methane synthesis.
    Description: Published
    Description: 248-251
    Description: 7A. Geofisica di esplorazione
    Description: N/A or not JCR
    Description: restricted
    Keywords: methane, ophiolites, serpentinization ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 64
    Publication Date: 2020-02-24
    Description: The occurrence and origin of methane (CH4) generated by serpentinization of ultramafic rocks is of current timely interest in planetary geology, astrobiology and energy resource exploration, as it may contribute, in particular, to decipher the source of methane on Mars, the origin of life and the potential of abiotic hydrocarbon synthesis. Methane of dominant abiotic origin in serpentinized peridotites on continents (ophiolites or igneous intrusions) has been documented so far, with complete carbon and hydrogen isotope composition, in six countries, in the Philippines, Turkey, Oman, New Zealand, Japan and Italy. We report the discovery of two new sites in Greece, at Archani and Ekkara, located in the Othrys ophiolite massif. Portable sensors based on Fourier Transform InfraRed spectrometry (FTIR) and Tunable Diode Laser Absorption Spectroscopy (TDLAS) allowed to realize that out of 21 ophiolitic springs, methane is released only by four hyperalkaline (pH from 10.7 to 11.3) and calcium hydroxide (Ca–OH) type waters; all other 17 springs with pH b 8.7 and magnesium-rich waters in the Pindos, Vourinos and Veria ophiolites, do not show methane. This correlation between gas occurrence and water type seems to occur worldwide; accordingly, CH4 production appears to be intimately related to the depth and residence time of the circulating meteoric waters. Methane is emitted into the atmosphere also from the soil surrounding the hyperalkaline springs, with fluxes of the same order of magnitude (~102–103 mg m−2 day−1) of seepage typically observed over conventional petroleum systems. Othrys CH4 has an isotopic composition (δ13C from −27‰ to −37.3‰ VPDB, δ2H from −250‰ to −311‰ VSMOW) similar to that reported in ultramafic rocks in New Zealand and Japan, and in Precambrian crystalline shields, which were considered dominantly abiotic and probably derived from Fischer–Tropsch Type reactions. The paucity of CO2, which is the norm in hyperalkaline waters, and of other hydrocarbons prevents from evaluating possible mixing of gas of different sources, including microbial methanogenesis. Also the H2 content is trivial, notwithstanding it being a typical product of serpentinization; this could be due to complete H2 consumption by CO2 reduction in a limited or decreased H2 production system due, for example, to a late stage of increased silica activity, as suggested by preliminary petrographic observations. The low geothermal gradient of the area and the present-day serpentinization imply that,whatever the CH4 production mechanism, it took place at temperatures below those traditionally considered for the origin of abiotic methane in hydrothermal systems.
    Description: Published
    Description: 161-174
    Description: 7A. Geofisica di esplorazione
    Description: JCR Journal
    Description: restricted
    Keywords: Abiotic methane, serpentinization, ophiolite ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 65
    Publication Date: 2020-02-24
    Description: Recent studies have highlighted the need to consider geological carbon sources when estimating the net ecosystem carbon balance (NECB) of terrestrial ecosystems located in areas potentially affected by geofluid circulation. We propose a new methodology using physical parameters of the atmospheric boundary layer to quantify the CO2 coming from deep ground origin in a steppe ecosystem located in the SE of Spain. Then, we compared published NECB estimates at the site with seasonal patterns of soil CO2 efflux and biological activity measured by satellite images over a 2-year period (2007/2008). The alpha grass ecosystem was a net carbon source (93.8 and 145.1 g C m-2 year-1, in 2007 and 2008, respectively), particularly as a result of large amounts of carbon released over the dry period that were not related to biological activity. While the highest ecosystem CO2 emission rates were measured over the dry period (reaching up to 15 lmol m-2 s-1), soil CO2 efflux rates (ca. 0.5 lmol m-2 s-1) and plant productivity were minimal during this period. After using a linear relationship between NECB and wind speed for different stability conditions and wind sectors, we estimated the geological flux FGEO (217.9 and 244.0 g C m-2 in 2007 and 2008, respectively) and subtracted it from the NECB to obtain the biological flux FBIO (-124.0 and -98.9 g C m-2 in 2007 and 2008, respectively). We then partitioned FBIO into gross primary productivity and ecosystem respiration and proved that, after removing FGEO, ecosystem respiration and soil CO2 efflux followed similar seasonal patterns. The annual contribution of the geological component to NECB was 49.6 and 46.7 % for the year 2007 and 2008, respectively. Therefore, it is clear that geological carbon sources should be quantified in those ecosystems located in areas with potential natural emission of geological gases to the surface.
    Description: Published
    Description: 83-101
    Description: 7A. Geofisica di esplorazione
    Description: JCR Journal
    Description: restricted
    Keywords: carbon emission, soil, dry land ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 66
    Publication Date: 2021-12-16
    Description: Fluid-rock interactions can control earthquake nucleation and the evolution of earthquake sequences. Experimental studies of fault frictional properties in the presence of fl uid can provide unique insights into these interactions. We report the fi rst results from experiments performed on cohesive silicate-bearing rocks (microgabbro) in the presence of pressurized pore fl uids (H2 O, drained conditions) at realistic seismic deformation conditions. The experimental data are compared with those recently obtained from carbonate-bearing rocks (Carrara marble). Contrary to theoretical arguments, and consistent with the interpretation of some fi eld observations, we show that frictional melting of a microgabbro develops in the presence of water. In microgabbro, the initial weakening mechanism (fl ash melting of the asperities) is delayed in the presence of water; conversely, in calcite marble the weakening mechanism (brittle failure of the asperities) is favored. This opposite behavior highlights the importance of host-rock composition in controlling dynamic (frictional) weakening in the presence of water: cohesive carbonate-bearing rocks are more prone to slip in the presence of water, whereas the presence of water might delay or inhibit the rupture nucleation and propagation in cohesive silicate-bearing rocks.
    Description: Published
    Description: 27-30
    Description: 4T. Fisica dei terremoti e scenari cosismici
    Description: JCR Journal
    Description: reserved
    Keywords: carbonates faults ; hydro-elasto-dynamics ; earthquake nucleation ; friction ; rock mechanics ; fluid-rcok interactions ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.01. Earth Interior::04.01.04. Mineral physics and properties of rocks ; 04. Solid Earth::04.01. Earth Interior::04.01.05. Rheology ; 04. Solid Earth::04.04. Geology::04.04.06. Rheology, friction, and structure of fault zones ; 04. Solid Earth::04.06. Seismology::04.06.01. Earthquake faults: properties and evolution
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 67
    Publication Date: 2022-05-25
    Description: An extensive self-potential survey was carried out in the central volcanic complex of Tenerife Island (Canary Islands, Spain). A total amount of ~237 kmof profileswith 20 mspacing betweenmeasurementswas completed, including radial profiles extending from the summits of Teide and Pico Viejo, and circular profiles inside and around Las Cañadas caldera and the northern slopes of Teide and Pico Viejo. One of themain results of this mapping is the detection ofwell-developed hydrothermal systemswithin the edifices of Teide and Pico Viejo, and also associated with the flank satellite M. Blanca and M. Rajada volcanoes. A strong structural control of the surface manifestation of these hydrothermal systems is deduced from the data, pointing to the subdivision of Teide and Pico Viejo hydrothermal systems in three zones: summit crater, upper and lower hydrothermal systems. Self-potential maxima related to hydrothermal activity are absent from the proximal parts of the NE and NW rift zones as well as from at least two of the mafic historical eruptions (Chinyero and Siete Fuentes), indicating that long-lived hydrothermal systems have developed exclusively over relatively shallow felsic magma reservoirs. Towards Las Cañadas caldera floor and walls, the influence of the central hydrothermal systems disappears and the self-potential signal is controlled by the topography, the distance to thewater table of Las Cañadas aquifer and its geometry. Nevertheless, fossil or remanent hydrothermal activity at some points along the Caldera wall, especially around the Roques de García area, is also suggested by the data. Self-potential data indicate the existence of independent groundwater systems in the three calderas of Ucanca, Guajara and Diego Hernández, with a funnel shaped negative anomaly in the Diego Hernández caldera floor related to the subsurface topography of the caldera bottom. Two other important self-potential features are detected: positive values towards the northwestern Santiago rift, possibly due to the relatively high altitude of the water-table in this area; and a linear set ofminima to thewest of Pico Viejo, aligned with the northwestern rift and related to meteoricwater infiltration along its fracture system.
    Description: Published
    Description: 59-77
    Description: 1V. Storia e struttura dei sistemi vulcanici
    Description: JCR Journal
    Description: reserved
    Keywords: Self-potential ; Hydrothermal system ; Tenerife ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 68
    Publication Date: 2023-11-20
    Description: Active subaerial volcanoes often discharge large amounts of CO2 and H2S to the atmosphere, not only during eruptions but also during periods of quiescence. These gases are discharged through focused (plumes, fumaroles, etc.) and diffuse emissions. Several studies have been carried out to estimate the global contribution of CO2 and H2S emitted to the atmosphere by subaerial volcanism, but additional volcanic degassing studies will help to improve the current estimates of bothCO2 andH2S discharges. In October 2008, a wide-scale survey was carried out at Mt. Etna volcano, one the world’s most actively degassing volcanoes on Earth, for the assessment of the total budget of volcanic/hydrothermal discharges of CO2 and H2S, both from plume and diffuse emissions. Surface CO2 and H2S effluxes were measured by means of the accumulation chamber method at 4075 sites, covering an area of about 972.5 km2. Concurrently, plume SO2 emission at Mt. Etna was remotely measured by a car-borne Differential Optical Absorption Spectrometry (DOAS) instrument. Crater emissions of H2O, CO2 and H2S were estimated by multiplying the plume SO2 emission times the H2O/SO2, CO2/SO2 and H2S/SO2 gas plume mass ratios measured in situ using a portable multisensor. The total output of diffuse CO2 emission from Mt. Etna was estimated to be 20,000 ± 400 t day-1 with 4520 t day-1 of deep-seated CO2. Diffuse H2S output was estimated to be 400 ± 20 kg day-1, covering an area of 9.1 km2 around the summit craters of the volcano. Diffuse H2S emission on the volcano flanks was either negligible or null, probably due to scrubbing of this gas before reaching the surface. During this study, the average crater SO2 emission rate was *2100 t day-1. Based on measured SO2 emission rates, the estimated H2O, CO2 and H2S emission rates from Etna’s crater degassing were 220,000 ± 100,000, 35,000 ± 16,000 and 510 ± 240 t day-1, respectively. These high values are explained in terms of intense volcanic activity at the time of this survey. The diffuse/plume CO2 emission mass ratio at Mt. Etna was *0.57, that is typical of erupting volcanoes (mass ratio\1). The average CO2/SO2 molar ratio measured in the plume was 11.5, which is typical of magmatic degassing at great depth beneath the volcano, and the CO2/H2S mass ratio in total diffuse gas emissions was much higher (*11,000) than in plume gas emissions (*68). These results will provide important implications for estimates of volcanic total carbon and sulfur budget from subaerial volcanoes.
    Description: project CGL2005-07509/CLI, Ministry of Education and Science of Spain
    Description: Published
    Description: 327-349
    Description: 4V. Vulcani e ambiente
    Description: JCR Journal
    Description: restricted
    Keywords: Mt. Etna ; Carbon dioxide ; Hydrogen sulfide ; Gas budget ; Diffuse degassing ; Crater degassing ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 69
    Publication Date: 2023-12-04
    Description: Early in the morning of 24 August, 2013, following by hours the drilling of a shallowborehole in the same spot, a new fumarole producing emissions of CO2-rich gas, water, and mud suddenly appeared at a crossroad along the fenced area of the Fiumicino international airport of Rome, Italy. Similar episodes have been scientifically documented or simply reported in recent and past years. To understandwhy gases are easily entrapped in the shallow subsurface of the Fiumicino area, we used five borehole cores drilled by us, analyzed the stratigraphy of these and other nearby cores, acquired a 2D seismic refraction tomogram, and performed chemical and isotopic analyses of water samples collected from aquifers intercepted by two drilled boreholes. Our boreholes were realized with proper anti-gasmeasures as,while drilling, we recorded the presence of pressurized gases at a specific permeable gravel level. Results showthat, in the study area, gases become mainly entrapped in a mid-Pleistocene gravel horizon at about 40–50 m depth. This horizon contains a confined aquifer that stores the endogenous upwelling gases. The gravel is interposed between two silty–clayey units. The lower unit, very hard and overconsolidated, is affected by fractures that allow ascending gases to bypass the otherwise impermeable shale, permeate the gravel, and dissolve into the aquifer. In contrast, the upper unit is impermeable to fluids and seals the gaspressurized aquifer, which therefore constitutes a source of hazard during human activities such as well drilling, quarrying, and various building-related excavations. As the stratigraphy of the Fiumicino area is very common in large portions of the densely populated Roman area and as the adjacent volcanic districts are hydrothermally active, we conclude that phenomena similar to that observed at Fiumicino could again occur both at Fiumicino and elsewhere in the surrounding region. As a prompt confirmation of our conclusion, we signal that, while writing this paper, new artificially-triggered degassing phenomena occurred off Fiumicino in connection with the construction of the new harbor.
    Description: Published
    Description: 53-66
    Description: 4V. Vulcani e ambiente
    Description: JCR Journal
    Description: restricted
    Keywords: Mud volcano ; gas hazard ; drilling ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 70
    Publication Date: 2024-05-09
    Description: CO2 sequestration in geological formations requires specific conditions to safely store this greenhouse gas underground. Different geological reservoirs can be used for this purpose, although saline aquifers are one of the most promising targets due to both their worldwide availability and storing capacity. Nevertheless, geochemical processes and fluid flow properties are to be assessed pre-, during, and post-injection of CO2. Theoretical calculations carried out by numerical geochemical modeling play an important role to understand the fate of CO2 and to investigate short-to-long-term consequences of CO2 storage into deep saline reservoirs. In this paper, the injection of CO2 in a deep structure located offshore in the Tyrrhenian Sea (central Italy) was simulated. The results of a methodological approach for evaluating the impact that CO2 has in a saline aquifer hosted in Mesozoic limestone formations were discussed. Seismic reflection data were used to develop a reliable 3D geological model, while 3D simulations of reactive transport were performed via the TOUGHREACT code. The simulation model covered an area of 〉100 km2 and a vertical cross-section of 〉3 km, including the trapping structure. Two simulations, at different scales, were carried out to depict the local complex geological system and to assess: (i) the geochemical evolution at the reservoir–caprock interface over a short time interval, (ii) the permeability variations close to the CO2 plume front, and (iii) the CO2 path from the injection well throughout the geological structure. One of the most important results achieved in this study was the formation of a geochemical barrier as CO2-rich acidic waters flowed into the limestone reservoir.
    Description: Published
    Description: 107-143
    Description: 5A. Energia e georisorse
    Description: JCR Journal
    Description: restricted
    Keywords: CO2 geological storage ; Reactive transport modeling ; Deep saline aquifers ; Geochemical barriers ; Permeability feedback ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 71
    Publication Date: 2024-05-09
    Description: The Vicano–Cimino Volcanic District (VCVD) is related to the post-orogenic magmatic activity of the peri- Tyrrhenian sector of Central Italy. The chemical and isotopic compositions of 333 water discharges and 25 gas emissions indicate the occurrence of two main sources: 1) cold Ca-HCO3 to Ca(Na, K)-HCO3 type waters from relatively shallow aquifers hosted in volcanic and sedimentary formations; and 2) thermal Ca-SO4(HCO3) type waters located in a deep CO2-pressurized reservoir, hosted in carbonate–evaporite rocks and separated from the shallow aquifers by thick sequences of low-permeability formations. Carbon dioxide is mainly produced by thermal metamorphic decarbonation within the deepest and hottest parts of the carbonate–evaporite reservoir (δ13C–CO2 from−3.1 to+2.2‰vs. VPDB), likely affected by a mantle-rooted CO2. ReleaseofCO2-rich gases from the deep aquifer into the overlying shallow aquifers produces high-CO2 springs and bubbling pools. The spatial distribution of thermal waters and CO2-rich cold discharges is strongly controlled by fractures and faults located in correspondencewith buried structural highs. Stable isotopes (δD and δ18O) suggest thatmeteoric water feeds both the shallowand deep reservoirs. The relatively lowR/Ra values (0.27–1.19) indicate that He ismainly deriving from a crustal source, with minor component from the mantle affected by crustal contamination related to the subduction of the Adriatic plate. Consistently, relatively high N2/Ar and N2/3He ratios and positive δ15N–N2 values (from0.91 to 5.7‰vs. air) characterize the VCVD gas discharges, suggesting the occurrence of a significant “excess” nitrogen. Isotopic compositions of CH4 (δ13C–CH4 and δD–CH4 values from−28.9 to−22.1‰vs. VPDB and from −176 to −138‰ vs. VSMOW, respectively), and composition of light alkanes are indicative of prevalent thermogenic CH4, although the occurrence of abiogenic CH4 production cannot be excluded. The δ34S–H2S values (from+9.3 to+11.4‰vs. VCDT) are consistentwith the hypothesis of H2S production fromthermogenic reduction of Triassic anhydrites. Gas geothermometry in the H2O–H2–Ar–H2S system suggests that the VCVD gases equilibrated in a liquid phase at redox conditions controlled by interactions of fluids with the local mineral assemblage at temperatures lower (b200 °C) than that andmeasured in deep (N2000 m) geothermalwells. This confirms that secondary processes, i.e. steam condensation, gas dissolution in shallow aquifers, re-equilibration at lower temperature, and microbial activity, significantly affect the chemistry of the uprising fluids. Thermal water chemistry supports the occurrence in this area of an anomalous heat flowthat, coupledwith the recent demographic growth, makes this site suitable for direct and indirect exploitation of the geothermal resource, in agreement with the preliminary surveys carried out in the 1970's–1990's for geothermal exploration purposes.
    Description: Published
    Description: 96-114
    Description: 5A. Energia e georisorse
    Description: JCR Journal
    Description: restricted
    Keywords: geothermal resources ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 72
    Publication Date: 2020-12-15
    Description: Stratigraphic and morphostructural analyses have been carried out in the Mt. Etna volcanic region (eastern Sicily) to investigate in detail the deformation events that have affected the sedimentary successions forming the substratum of the volcano. In the foredeep, Quaternary submarine sedimentation ended 600 ka ago when the whole area emerged in response to homogeneous regional uplift. The irregular distribution of a stratigraphic marker, recognized through the analysis of more than 250 borehole logs, suggests that local dynamics also affected the area. We identify both compressional tectonic dynamics and volcano-related tectonic activity, and discriminate among their associated deformations. In particular, we quantify the vertical deformation component of the compressional structures (thrusts and related folds) and recognize for the first time a vertical component of deformation whose pattern clearly indicates a doming process acting at Mt. Etna. The comparison between long-term and short-term rates suggests that the doming has acted consistently over space and time through the last 600 ka and provides clues to the source of uplift. This component, defined by a specific Quaternary sedimentary horizon, has been compared with vertical deformation obtained by analytical inversion of morphological substratum data, and localizes the source at a depth of ∼16 km, at the mantle-crust transition. This uplift may be the consequence of hydration occurring in the altered ocean-like crust.
    Description: Published
    Description: 816
    Description: 1V. Storia e struttura dei sistemi vulcanici
    Description: JCR Journal
    Description: restricted
    Keywords: Crustal structure ; Volcanotectonics ; Doming process ; Recent deformation ; Sicily ; Mt. Etna ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 73
    Publication Date: 2021-06-15
    Description: We investigated the geochemical features of the fluids circulating over the Amik Basin (SE Turkey–Syria border), which is crossed by the Northern extension of theDSF (Dead Sea Fault) and represents the boundary area of three tectonic plates (Anatolian, Arabian and African plates). We collected 34 water samples (thermal and cold from natural springs and boreholes) as well as 8 gas samples (bubbling and gas seepage) besides the gases dissolved in the sampled waters. The results show that the dissolved gas phase is a mixture of shallow (atmospheric) and deep components either of mantle and crustal origin. Coherently the sampled waters are variable mixtures of shallow and deep ground waters, the latter being characterised by higher salinity and longer residence times. The deep groundwaters (fromboreholes deeper than 1000 m)have a CH4-dominated dissolved gas phase related to the presence of hydrocarbon reservoirs. The very unique tectonic setting of the area includes the presence of an ophiolitic block outcropping in the westernmost area on the African Plate, as well as basalts located to the North and East on the Arabic Plate. The diffuse presence of CO2-enriched gases, although diluted by the huge groundwater circulation, testifies a regional degassing activity. Fluids circulating over the ophiolitic block are marked by H2-dominated gases with abiogenic methane and high-pH waters. The measured 3He/4He isotopic ratios display contributions from both crustal and mantle-derived sources over both sides of the DSF. Although the serpentinization process is generally independent from mantle-type contribution, the recorded helium isotopic ratios highlight variable contents of mantle-derived fluids. Due to the absence of recent volcanism over the western side of the basin (African Plate), we argue that CO2-rich volatiles carrying mantle-type helium and enriched in heavy carbon, are degassed by deep-rooted regional faults rather than from volcanic sources.
    Description: Published
    Description: 23–39
    Description: 2T. Tettonica attiva
    Description: JCR Journal
    Description: restricted
    Keywords: Dead Sea Fault ; Hydrogeochemistry ; Gas geochemistry ; He isotopes ; C isotopes ; Ophiolites ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.02. Carbon cycling ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 74
    Publication Date: 2017-04-04
    Description: This paper describes an application of artificial neural networks for the recognition of volcanic lava flow hot spots using remote sensing data. Satellite remote sensing is a very effective and safe way to monitor volcanic eruptions in order to safeguard the environment and the people affected by such natural hazards. Neural networks are an effective and well-established technique for the classification of satellite images. In addition, once well trained, they prove to be very fast in the application stage. In our study a back propagation neural network was used for the recognition of thermal anomalies affecting hot lava pixels. The network was trained using the three thermal channels of the Advanced Very High Resolution Radiometer (AVHRR) sensor as inputs and the corre- sponding values of heat flux, estimated using a two thermal component model, as reference outputs. As a case study the volcano Etna (Eastern Sicily, Italy) was chosen, and in particular the effusive eruption which took place during the month of 2006 July. The neural network was trained with a time-series of 15 images (12 nighttime images and 3 daytime images) and validated on three independent data sets of AVHRR images of the same eruption and on two relative to an eruption occurred the following month. While for both nighttime and daytime validation images the neural network identified the image pixels affected by hot lava with a 100 per cent success rate, for the daytime images also adjacent pixels were included, apparently not interested by lava flow. Despite these performance differences under different illumination conditions, the proposed method can be considered effective both in terms of classification accuracy and generalization capability. In particular our approach proved to be robust in the rejection of false positives, often corresponding to noisy or cloudy pixels, whose presence in multispectral images can often undermine the performance of traditional classification algorithms. Future work shall address application of the proposed method to data acquired with a high temporal resolution, such as those provided by the spinning enhanced visible and infrared imager sensor on board the Meteosat second generation geostationary satellite.
    Description: Published
    Description: 1525-1535
    Description: 5V. Sorveglianza vulcanica ed emergenze
    Description: JCR Journal
    Description: restricted
    Keywords: Image processing ; Neural networks ; fuzzy logic ; Remote sensing of volcanoes ; Hot-spot detection ; Mt. Etna ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 75
    Publication Date: 2017-04-04
    Description: A new approach in dealing with seismic risk in the volcanic areas of Italy, by taking into account the possible occurrence of damaging pre- or syn-eruptive seismic events, is exciting the scientific interest and is actually the topic developed in several research projects funded by the European Community (e.g., UPStrat- MAFA, www.upstrat-mafa.ov.ingv.it/UPstrat/) and the Civil Defense Department of Italy. To achieve this goal, it is necessary to have a detailed knowledge of the local attenuation-distance relations. In the present paper, we make a survey of the estimates of the seismic quality factor of the medium reported in literature for the Etna area. In the framework of a similar paper published for the Campi Flegrei zone in Southern Italy, we first review the results on seismic attenuation already obtained for Etna and then apply a standard technique to separately measure intrinsic and scattering attenuation coefficients from passive seismic data recorded by the Etna seismological network. Indications are then given for the correct utilization of the attenuation parametersto obtain the best candidate quality factorQ to be used in this area for seismic risk purposes.
    Description: Published
    Description: 105-119
    Description: 4T. Fisica dei terremoti e scenari cosismici
    Description: JCR Journal
    Description: restricted
    Keywords: Seismic attenuation ; MLTWA method ; Mt. Etna ; 04. Solid Earth::04.06. Seismology::04.06.09. Waves and wave analysis
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 76
    Publication Date: 2017-04-04
    Description: We report the results of 16 months of continuous measurements of soil CO2 flux at a fumarole field in the summit area of Mt. Etna. The patterns of soil CO2 emissions suggest two contrasting degassing regimes. During the period of observation, volcanic activity at the summit craters displayed striking extremes, ranging from passive to explosive degassing, which culminated in lava fountains. These changes in activity coincided with fluctuation between the two degassing patterns. Building on the findings of previous studies, we propose an interpretative framework that explains the observed correlation in terms of a modification of the dynamics of magma supply. We argue that periods of higher CO2 flux are associated with deep open system degassing conditions, whereas low-level CO2 flux signals closed system degassing and less efficient discharge of deeply exsolved gas. An important implication of our study is that, in relation to the two degassing regimes, two types of activity are expected at the summit craters. Thus, our measurements represent a valuable tool for the evaluation of the evolution of volcanic activity
    Description: Published
    Description: 846
    Description: 2V. Dinamiche di unrest e scenari pre-eruttivi
    Description: JCR Journal
    Description: restricted
    Keywords: Magma supply dynamics ; Soil CO2 emissions ; Lava fountain ; Mt. Etna ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 77
    Publication Date: 2020-02-24
    Description: The measurement of soil CO2flux variations is a well established practice in many volcanic areas around the world. Until recently, however, most of these were made using direct sampling methods. These days, a variety of automatic devices providing real-time data now make the continuous monitoring of volcanic areas possible. A network of automatic geochemical monitoring stations (EtnaGas network) was developed by INGV Palermo and installed at various sites on the flanks of Mt. Etna. Here, we present a large set of soil CO2 flux data recorded by the network, dating back 10 years, a period in which several noteworthy eruptive phenomena occurred. Our statistical analysis strongly suggests that anomalous measurements of soil CO2flux are attributable to volcanic origin and in almost all cases precede volcanic activity. Here, we present the actual data series recorded by EtnaGAS and an interpretative model of the expected behavior of soil CO2flux (in terms of increase-decrease cycles), which corresponded well with the volcanic activity during this period. Through the use of a comparative approach, incorporating both volcanological and geochemical data, the global soil CO2 flux trends are put into a coherent framework, highlighting close links between the time flux variations and volcanic activities. These insights, made possible from 10 years of uninterrupted data, confirm the importance of continuous monitoring of volcanic soil degassing, and may contribute in the forecasting of imminent eruptive activity or the temporal evolution of an in-progress eruption, therefore facilitating Civil Defense planning in volcanic areas under high-hazard conditions.
    Description: This study has benefited from funding provided by the Italian Presidenza del Consiglio dei Ministri—Dipartimento della Protezione Civile (DPC).
    Description: Published
    Description: 2886–2899
    Description: 2V. Dinamiche di unrest e scenari pre-eruttivi
    Description: 3V. Dinamiche e scenari eruttivi
    Description: 5V. Sorveglianza vulcanica ed emergenze
    Description: 1R. Reti di monitoraggio e Osservazioni
    Description: JCR Journal
    Description: restricted
    Keywords: Mt. Etna ; Volcano monitoring ; Lava fountaining ; CO2 geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.08. Risk::05.08.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 78
    Publication Date: 2017-04-04
    Description: During the spring of 2007, paroxysmal activity occurred at the South-East Crater of Mt Etna, always associated with sharp rises in the amplitude of the volcanic tremor. Activity ranged from strong Strombolian explosions to lava fountains coupled with copious emission of lava flows and tephra. During inter-eruptive periods, recurrent seismic unrest episodes were observed in form of temporary enhancements of the volcanic tremor amplitude, but they did not culminate in eruptive activity. Here, we present the results of an analysis of these inter-eruptive periods by integrating seismic volcanic tremor, in-soil radon, plume SO2 flux and thermal data. SO2 flux and thermal radiation are envisaged as the “smoking gun”, certifying that changes in seismic or radon data can be considered as volcanogenic. Short-term changes were investigated by pattern classification based on Kohonen Maps and fuzzy clustering on volcanic tremor, radon and ambient parameters (pressure and temperature). Our results unveil ‘failed’ eruptions between February and April 2007 that are explained as ascending magma batches, which triggered repeated episodes of gas pulses and rock fracturing, but that failed to reach the surface.
    Description: Published
    Description: 297–313
    Description: 2V. Dinamiche di unrest e scenari pre-eruttivi
    Description: JCR Journal
    Description: restricted
    Keywords: Volcano monitoring ; Failed eruption ; Mt. Etna ; Volcanic tremor ; Plume SO2 flux ; In-soil radon ; Thermal data ; 05. General::05.01. Computational geophysics::05.01.01. Data processing
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 79
    Publication Date: 2017-04-04
    Description: The studied area is a 130 km long fast spreading graben in Central Greece. Its complex geodynamical setting includes both the presence of a subduction slab at depth responsible for the recent (Quaternary) volcanic activity in the area and the western termination of a tectonic lineament of regional importance (the North-Anatolian fault). A high geothermal gradient is made evident by the presence of many thermal springs with temperatures from 19 to 82 C, that discharge along the normal faults bordering the graben. In the period 2004e2012, 58 gas and 69 water samples were collected and their chemical and isotopic analysis revealed a wide range of compositions. Two main groups of thermal waters can be distinguished on the basis of their chemical composition. The first, represented by dilute waters (E.C. 〈0.6 mS/cm) of the westernmost sites, is characterised by the presence of CH4-rich and mixed N2eCH4 gases. The second displays higher salinities (E.C. from 12 to 56 mS/cm) due to mixing with a modified marine component. Reservoir temperatures of 150e160 C were estimated with cationic geothermometers at the easternmost sites. Along the graben, from west to east, the gas composition changes from CH4- to CO2-dominated through mixed N2eCH4 and N2eCO2 compositions, while at the same time the He isotopic composition goes from typical crustal values (〈0.1 R/RA) up to 0.87 R/RA, showing in the easternmost sites a small (3e11%) but significant mantle input. The d13C values of the CO2-rich samples suggest a mixed origin (mantle and marine carbonates).
    Description: Published
    Description: 295-308
    Description: 2T. Tettonica attiva
    Description: JCR Journal
    Description: restricted
    Keywords: Rift zone ; geothermal activity ; Helium isotopes ; Carbon isotopes ; 03. Hydrosphere::03.02. Hydrology::03.02.02. Hydrological processes: interaction, transport, dynamics ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 80
    Publication Date: 2017-04-04
    Description: The shallow thermal aquifer at Vulcano Island is strongly affected by deep volcanic fluids. The most significant variations were observed during the 1989–1996 crisis due to a large input of steam and acidic gases from depth. Besides chemical variations related to the input of deep fluids, the record of the water-table elevation at monitored wells has provided remarkable insights into the pressure conditions of the volcano-hydrothermal system. After the pressure drop due to the extensive vaporization of the hydrothermal aquifer, occurred after 1993, the volcano-hydrothermal system has been re-pressurized since 2001, probably because of the contribution of volatiles from the hydrothermal-magmatic source. The increase in fluid pressure may have caused reopening of fractures (which had self-seated during the previous period of cooling) and the onset of a phase of higher vapor output in the fumarole field later in 2004. The fracture opening would have promoted further vapor separation from the deep fluid reservoir (hypothesized at 0.5–1.5 km depth) and finally the drainage of S-rich fluids into the shallow thermal aquifer (found out at few tens of meters of depth). The monitoring of both the water chemistry and the water-table elevation provides insights into the eventual pressurization of the volcano-hydrothermal system that precedes the fracture opening and the extensive drainage of deep fluids. The findings of this study could represent crucial information about the stability of the volcano edifice, and lead to reliable techniques for determining the risk of or even predicting phreatic explosions.
    Description: Published
    Description: 70-80
    Description: 5V. Sorveglianza vulcanica ed emergenze
    Description: JCR Journal
    Description: restricted
    Keywords: Hydrothermal system ; Vulcano Island ; Fluid pressure ; Thermal wells ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 81
    Publication Date: 2017-04-04
    Description: no abstract
    Description: Published
    Description: 47-75
    Description: 4V. Vulcani e ambiente
    Description: restricted
    Keywords: geothermal systems ; hydrogeochemistry ; Greece ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: book chapter
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  • 82
    Publication Date: 2020-02-24
    Description: Hule and Rı´o Cuarto are maar lakes located 11 and 18 km N of Poa´s volcano along a 27 km long fracture zone, in the Central Volcanic Range of Costa Rica. Both lakes are characterized by a stable thermic and chemical stratification and recently they were affected by fish killing events likely related to the uprising of deep anoxic waters to the surface caused by rollover phenomena. The vertical profiles of temperature, pH, redox potential, chemical and isotopic compositions of water and dissolved gases, as well as prokaryotic diversity estimated by DNA fingerprinting and massive 16S rRNA pyrosequencing along the water column of the two lakes, have highlighted that different bio-geochemical processes occur in these meromictic lakes. Although the two lakes host different bacterial and archaeal phylogenetic groups, water and gas chemistry in both lakes is controlled by the same prokaryotic functions, especially regarding the CO2-CH4 cycle. Addition of hydrothermal CO2 through the bottom of the lakes plays a fundamental priming role in developing a stable water stratification and fuelling anoxic bacterial and archaeal populations. Methanogens and methane oxidizers as well as autotrophic and heterotrophic aerobic bacteria responsible of organic carbon recycling resulted to be stratified with depth and strictly related to the chemical-physical conditions and availability of free oxygen, affecting both the CO2 and CH4 chemical concentrations and their isotopic compositions along the water column. Hule and Rı´o Cuarto lakes were demonstrated to contain a CO2 (CH4, N2)-rich gas reservoir mainly controlled by the interactions occurring between geosphere and biosphere. Thus, we introduced the term of bio-activity volcanic lakes to distinguish these lakes, which have analogues worldwide (e.g. Kivu: D.R.C.-Rwanda; Albano, Monticchio and Averno: Italy; Pavin: France) from volcanic lakes only characterized by geogenic CO2 reservoir such as Nyos and Monoun (Cameroon).
    Description: Published
    Description: e102456
    Description: 4V. Vulcani e ambiente
    Description: JCR Journal
    Description: open
    Keywords: bio activity, volcanic lakes, costa rica ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 83
    Publication Date: 2024-05-09
    Description: A geochemical survey of the main thermal waters discharging in the southwestern part of the Domuyo volcanic complex (Argentina),where the latest volcanic activity dates to 0.11 Ma, has highlighted the extraordinarily high heat loss from this remote site in Patagonia. The thermal water discharges are mostly Na-Cl in composition and have TDS values up to 3.78 g L−1 (El Humazo). A simple hydrogeochemical approach shows that 1,100 to 1,300 kg s−1 of boiling waters, which have been affected by shallow steam separation, flow into the main drainage of the area (Rio Varvarco). A dramatic increase of the most conservative species such as Na, Cl and Li from the Rio Varvarco fromupstreamto downstreamwas observed and related solely to the contribution of hydrothermal fluids. The equilibrium temperatures of the discharging thermal fluids, calculated on the basis of the Na-K-Mg geothermometer, are between 190 °C and 230 °C. If we refer to a liquid originally at 220 °C (enthalpy = 944 J g−1), the thermal energy release can be estimated as high as 1.1±0.2 GW, a value that ismuch higher than the natural release of heat in other important geothermal fields worldwide, e.g., Mutnovsky (Russia), Wairakei (New Zealand) and Lassen Peak (USA). This value is the second highest measured advective heat flux from any hydrothermal system on Earth after Yellowstone.
    Description: Published
    Description: 71–77
    Description: 4V. Vulcani e ambiente
    Description: JCR Journal
    Description: restricted
    Keywords: Domuyo volcano ; Argentine Patagonia ; Geothermal potential ; Water geochemistry ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 84
    Publication Date: 2024-05-09
    Description: Episodic gas seepage occurs at the seafloor in the Gulf of Izmit (Sea of Marmara, NW Turkey) along the submerged segment of the North Anatolian Fault (NAF), which ruptured during the 1999 Mw7.4 Izmit earthquake, and caused tectonic loading of the fault segment in front of the Istanbul metropolitan area. In order to study gas seepage and seismic energy release along the NAF, a multiparametric benthic observatory (SN-4) was deployed in the gulf at the western end of the 1999 Izmit earthquake rupture, and operated for about 1 yr at 166 m water depth. The SN-4 payload included a three-component broad-band seismometer, as well as gas and oceanographic sensors. We analysed data collected continuously for 161 d in the first part of the experiment, from 2009 October to 2010 March. The main objective of our work was to verify whether tectonic deformation along the NAF could trigger methane seepage. For this reason, we considered only local seismicity, that is, within 100 km from the station. No significant (ML ≥ 3.6) local earthquakes occurred during this period; on the other hand, the seismometer recorded high-frequency SDEs (short duration events), which are not related to seismicity but to abrupt increases of dissolved methane concentration in the sea water that we called MPEs (methane peak events). Acquisition of current velocity, dissolved oxygen, turbidity, temperature and salinity, allowed us to analyse the local oceanographic setting during each event, and correlate SDEs to episodic gas discharges from the seabed. We noted that MPEs are the result of such gas releases, but are detected only under favourable oceanographic conditions. This stresses the importance of collecting long-term multiparametric time-series to address complex phenomena such as gas and seismic energy release at the seafloor. Results from the SN-4 experiment in the Sea of Marmara suggest that neither low-magnitude local seismicity, nor regional events affect intensity and frequency of gas flows from the seafloor.
    Description: Published
    Description: 850-866
    Description: 1T. Geodinamica e interno della Terra
    Description: 3A. Ambiente Marino
    Description: 7A. Geofisica di esplorazione
    Description: JCR Journal
    Description: restricted
    Keywords: Time-series analysis ; Seismicity and tectonics ; Broad-band seismometers ; multiparametric seafloor observatory ; Izmit Gulf ; Sea of Marmara ; gas seepage ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 04. Solid Earth::04.04. Geology::04.04.04. Marine geology ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 85
    Publication Date: 2021-06-15
    Description: Twenty-two gas samples were collected in August 2012 in the area of Amik basin (Turkey). Two samples were collected from gas seeps, one was a bubbling gas in a thermal spring, while the remaining were dissolved gases from cold and thermal groundwaters (T 16-43 °C). All gases were analysed for their chemical composition (He, H2, O2, N2, CH4 and CO2) and for their He isotopic composition. Dissolved gases were also analysed for the carbon isotopic composition of the total dissolved carbon (TDC), while free gases also for their higher hydrocarbon (C1 – C5) content and for D of H2 and CH4, 13C of CH4 Basing on their chemical composition, the gases can be roughly subdivided in three groups. Most of the dissolved gases (16) belonging to the first group were collected from springs or shallow wells (〈 150 m depth). All these samples contain mainly atmospheric gasses with very limited H2 (〈 80 ppm) and CH4 (1 – 2700 ppm) contents and minor concentrations of CO2 (0.5 – 11.2 %). The isotopic composition of TDC evidences an almost organic contribution. The only exception is represented by the CO2-richest sample where a small but significant mantle contribution is found. Such contribution can also be evidenced in its 3He rich isotopic composition. Further three samples of this group evidence a small mantle contribution. These samples were collected in the northern part of the basin along the main tectonic structures delimiting the basin and close to areas with quaternary volcanic activity. A second group is composed by two dissolved gases collected from deep boreholes (〉 1200 m depth). Their composition is typical of hydrocarbon reservoirs being very rich in CH4 (〉 78 %) and N2 (〉 13%). Also the water composition is typical of saline connate waters (Cl- and B-rich, SO4-poor). C-isotopic composition of methane ( 13C -65% ) points to a biogenic origin while He-isotopic composition indicates a prevailing crustal signature for one (R/Ra 0.16) of the sites and small mantle contribution for the other (R/Ra 0.98). To the last group belong four gas samples taken at two sites within the ophiolitic basement that crops out west of the basin. These gases have the characteristic composition of gas generated by low temperature serpentinisation processes with high hydrogen (37 – 50 %) and methane (10 – 61 %) concentrations. While all gases show an almost identical D-H2 of -750h those of one of the two sites display an isotopic composition of methane ( 13C -5h D -105% ) and a C1/[C2+C3] ( 100) ratio typical of abiogenic hydrocarbons and mantle-type helium (R/Ra: 1.33), while those of the other site evidence a contribution of a crustal (thermogenic) component ( 13C-CH4 -30h D -325h C1/[C2+C3] 3000). Such crustal contribution is also supported by higher N2 contents (40% instead of 2%) and lower He-isotopic composition (R/Ra 0.07). The preliminary results highlight contributions of mantle-derived volatiles to the fluids vented along the Amik Basin. The main tectonic structure of the area, the Death Sea Fault, and other parallel structures crossing the basin seem to be the responsible for deep-originated volatiles drainage towards shallow levels.
    Description: Submitted
    Description: Vienna, Austria
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: open
    Keywords: gas geochemistry ; water chemistry ; stable isotopes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Conference paper
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  • 86
    Publication Date: 2021-06-14
    Description: Methane is a major contributor to the greenhouse effect, its atmospheric concentration being more than doubled since the XIX century. Every year 22 Tg of methane are released to the atmosphere from several natural and anthropogenic sources. Natural sources include geothermal/volcanic areas but the estimation of the total methane emission from these areas is currently not well defined since the balance between emission through degassing and microbial oxidation within the soils is not well known. Microbial oxidation in soils contributes globally for about 3-9% to the removal of methane from the atmosphere and recent studies evidenced methanotrophic activity also in soils of volcanic/geothermal areas despite their harsh environmental conditions (high temperatures, low pH and high concentrations of H2S and NH3). Methanotrophs are a diverse group of bacteria that are able to metabolize methane as their only source of carbon and energy and are found within the Alpha and Gamma classes of Proteobacteria and within the phylum Verrucomicrobia. Our purpose was to study the interaction between methanotrophic communities and the methane emitted from the geothermally most active site of Pantelleria island (Italy), Favara Grande, whose total methane emission has been previously estimated in about 2.5 t/a. Laboratory incubation experiments with soil samples from Favara Grande showed methane consumption values of up to 9500 ng g-1 dry soil per hour while soils collected outside the geothermal area consume less than 6 ng g-1 h-1. The maximum consumption was measured in the shallowest part of the soil profile (1-3 cm) and high values (〉100 ng g-1 h-1) were maintained up to a depht of 15 cm. Furthermore, the highest consumption was measured at 37 C, and a still recognizable consumption (〉20 ng g-1 h-1) at 80 C, with positive correlation with the methane concentration in the incubation atmosphere. These results can be considered a clear evidence of the presence of methanotrophs that were investigated by culturing and culture-independent techniques. The diversity of proteobacterial methanotrophs was investigated by creating a clone library of the amplified methane mono-oxygenase encoding gene, pmoA. Clone sequencing indicates the presence of Gammaproteobacteria in the soils of Favara Grande. Enrichment cultures, on a mineral medium in a CH4-enriched atmosphere, led to the isolation of different strains that were identified as Methylocistis spp., which belong to the Alphaproteobacteria. The presence of Verrucomicrobia was detected by amplification of pmoA gene using newly designed primers. Soils from Favara Grande show therefore the largest spectrum of methanotrophic microorganisms until now detected in a geothermal environment. While the presence of Verrucomicrobia in geothermal soils was predictable due to their thermophilic and acidophilic character, the presence of both Alpha and Gamma proteobacteria was unexpected. Their presence is limited to the shallowest part of the soil were temperatures are lower and is probably favored by a soil pH that is not too low (pH 5) and their contribution to biological methane oxidation at Pantelleria is significant. Understanding the ecology of methanotrophy in geothermal sites will increase our knowledge of the role of soils in methane emissions in such environments.
    Description: Published
    Description: Vienna, Austria
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: open
    Keywords: soil methane fluxes ; methanotrophic activity ; 03. Hydrosphere::03.04. Chemical and biological::03.04.04. Ecosystems ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Abstract
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  • 87
    Publication Date: 2021-06-15
    Description: The Amik Basin is an asymmetrical composite transtensional basin developed between the seismically active left-lateral Dead Sea Fault (DSF) splays and the left-lateral oblique-slip Karasu Fault segment during neotectonic period. The relationship between the DSF and the East Anatolian Fault Zone is important as it represents a triple junction between Arabian Plate, African Plate and Anatolian Block in which the Amik Basin developed. The basin was formed on a pre-Miocene basement consisting of two rock series: Paleozoic crustal units with a Mesozoic allochthonous ophiolitic complex and ~1300 m thick Upper Miocene-Lower Pliocene sedimentary sequence. Plio-Quaternary sediments and Quaternary volcanics unconformably overlie the deformed and folded Miocene beds. Quaternary alkali-basaltic volcanism, derived from a metasomatized asthenospheric or lithospheric mantle, is most probably related to the syn-collisional transtensional strike-slip deformation in the area. Active faults in the region have the potential to generate catastrophic earthquakes (M〉7). Nineteen samples of cold and thermal groundwaters have been collected over the Amik Basin area for dissolved gas analyses as well as two samples from the gas seeps, and one bubbling gas from a thermal spring Samples were analysed for their chemical and isotopic (He, C) composition. On the basis of their chemical composition, three main groups can be recognized. Most of the dissolved gases (16; Group I) collected from springs or shallow wells (〈 150 m depth), contain mainly atmospheric gasses with very limited H2 (〈 80 ppm) and CH4 (1– 2700 ppm) contents and minor concentrations of CO2 (0.5–11.2 %). The isotopic composition of Total Dissolved Carbon evidences a prevailing organic contribution with possible dissolution of carbonate rocks. However the CO2-richest sample shows a small but significant deep (probably mantle) contribution which is also evidenced by its He isotopic composition. Further three samples, taken from the northern part of the basin close to Quaternary volcanic outcrops and main tectonic structures, also exhibit a small mantle He contribution (Fig. 1). The two dissolved gases (Group II) collected from deep boreholes (〉 1200 m depth) are typical of hydrocarbon reservoirs being very rich in CH4 (〉 78 %) and N2 (〉 13%). The water composition of these samples is also distinctive of saline connate waters (Cl- and B-rich, SO4-poor). Isotopic composition of methane (δ13C ~ -65‰) indicates a biogenic origin while He-isotopic composition points to a prevailing crustal signature for one (R/Ra 0.16) of the sites and a small mantle contribution for the other (R/Ra 0.98) (Fig. 1). The three free gas samples (Group III), taken at two sites within the ophiolitic basement west of the basin, have the typical composition of gas generated by low temperature serpentinisation processes with high hydrogen (37–50 %) and methane (10–61 %) concentrations. While all three gases show an almost identical δD-H2 of ~ -750‰, two of them display an isotopic composition of methane (δ13C ~ -5‰; δD ~ -105‰) and a C1/[C2+C3] ratio (~100) typical of abiogenic hydrocarbons and a significant contribution of mantle-type helium (R/Ra: 1.33). The composition of these two gasses is comparable to that of the gasses issuing in similar geologic conditions (Chimera-Turkey, Zambales-Philippine and Oman ophiolites). The gas composition of the other site evidences a contribution of a crustal (thermogenic) component (δ13C-CH4 ~ -30‰; δD-CH4 ~ -325‰; C1/[C2+C3] ~ 3000). Such crustal contribution is also supported by higher N2 contents (40% instead of 2%) and lower He-isotopic composition (R/Ra 0.07) (Fig. 1). These first results highlight contributions of mantle-derived volatiles possibly drained towards shallow levels by the DSF and other parallel structures crossing the basin showing a tectonic control of the fluids circulating within the Basin .
    Description: Published
    Description: Patras, Greece
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: open
    Keywords: dissolved gases ; natural gas manifestations ; helium isotopes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Oral presentation
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  • 88
    Publication Date: 2017-04-04
    Description: The study area is a 130 km long fast spreading graben in Central Greece. Its complex geodynamical setting includes both the presence at depth of a subduction slab responsible for the recent (Quaternary) volcanic activity in the area and the western termination of a tectonic lineament of regional importance (the North-Anatolian fault). Its high geothermal gradient is evidenced by the presence of many thermal springs with temperatures from 19 to 82 C, issuing along the normal faults bordering the graben. In the period 2004-2012 about 50 gas and water samples have been collected and their chemical and isotopic analysis revealed a wide range of compositions. Going from west to east the gas composition changes from CH4- to CO2-dominated passing through mixed N2- CH4 and N2-CO2 compositions, while at the same time the He isotopic composition goes from typical crustal values (0.05 R/Ra) up to 0.87 R/Ra (corrected for air contamination), showing in the easternmost sites a small but significant mantle input. Isotopic composition of CH4-C indicates a thermogenic origin for the CH4-rich samples and hydrothermal origin for the remaining samples. Positive 15N values indicate a contribution of crustal derived nitrogen for the N2-rich samples. The 13C values of most the CO2-enriched samples show a mixed origin (mantle and marine carbonates). Also the chemical composition of the waters shows differences along the graben and two main groups can be separated. The first, represented by dilute waters (E.C. 〈 600 S/cm), is found in the westernmost sites characterised by the presence of CH4-rich and mixed N2-CH4 gases. The remaining waters display higher salinities (E.C. from 12 to 56 mS/cm) due to the mixing with a modified marine component. Only the water composition of easternmost sites in the Giggenbach’s cation triangular graph plots in the field of the partially equilibrated waters giving estimated temperatures at depth of 150-160 C.
    Description: Published
    Description: Vienna, Austria
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: open
    Keywords: hydrothermal systems ; gas chemistry ; water chemistry ; stable isotopes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Abstract
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  • 89
    Publication Date: 2017-04-04
    Description: This study concerns measurements of radon and thoron emissions from soil carried out in 2004 on the unstable eastern flank of Mt. Etna, in a zone characterized by the presence of numerous seismogenic and aseismic faults. The statistical treatment of the geochemical data allowed recognizing anomaly thresholds for both parameters and producing distribution maps that highlighted a significant spatial correlation between soil gas anomalies and tectonic lineaments. In particular, the highest anomalies were found at the intersection between WNW-ESE and NW-SE -running faults. The seismic activity occurring in and around the study area during 2004 was analyzed, producing maps of hypocentral depth and released seismic energy. These maps revealed a progressive deepening of hypocenters from NW to SE, with the exception of a narrow zone in the central part of the area, with a roughly WNW-ESE direction. Also, the highest values of seismic energy were released during events in the southern and northwestern sectors of the area. Both radon and thoron anomalies were located in areas affected by relatively deep (5-10 km depth) seismic activity, while less evident correlation was found between soil gas anomalies and the released seismic energy. This study confirms that mapping the distribution of radon and thoron in soil gas can reveal hidden faults buried by recent soil cover or faults that are not clearly visible at the surface. The correlation between soil gas data and earthquake depth and intensity can give some hints on the source of gas and/or on fault dynamics. Lastly, an important spin-off of this study is the recognition of some areas where radon activity was so high (〉50000 Bq/m3) that it may represent a potential hazard to the local population. In fact, radon is the leading cause of lung cancer after cigarette smoke for long exposures and, due to its molecular weight, it accumulates in underground rooms or in low ground, particularly where air circulation is low or absent. In the investigated area this risk is real, as it is inhabited by thousands of people who reside there all year long. Therefore, this study serves as a starting point for the assessment of radon hazard in the Mt. Etna area, considering both spatial and temporal changes in soil radon emissions depending on the presence of faults and/or the occurrence of seismic activity.
    Description: Published
    Description: Vienna
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: restricted
    Keywords: Mt. Etna ; radon monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Poster session
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  • 90
    Publication Date: 2017-04-04
    Description: The intricate pathways of fluid–mineral reactions occurring underneath active hydrothermal systems are explored in this study by applying reaction path modelling to the Ischia case study. Ischia Island, in Southern Italy, hosts a well-developed and structurally complex hydrothermal system which, because of its heterogeneity in chemical and physical properties, is an ideal test sites for evaluating potentialities/limitations of quantitative geochemical models of hydrothermal reactions. We used the EQ3/6 software package, version 7.2b, to model reaction of infiltrating waters (mixtures of meteoric water and seawater in variable proportions) with Ischia’s reservoir rocks (the Mount Epomeo Green Tuff units; MEGT). The mineral assemblage and composition of such MEGT units were initially characterised by ad hoc designed optical microscopy and electron microprobe analysis, showing that phenocrysts (dominantly alkali–feldspars and plagioclase) are set in a pervasively altered (with abundant clay minerals and zeolites) groundmass. Reaction of infiltrating waters with MEGT minerals was simulated over a range of realistic (for Ischia) temperatures (95–260 C) and CO2 fugacities (10 0.2 to 100.5) bar. During the model runs, a set of secondary minerals (selected based on independent information from alteration minerals’ studies) was allowed to precipitate from model solutions, when saturation was achieved. The compositional evolution of model solutions obtained in the 95– 260 C runs were finally compared with compositions of Ischia’s thermal groundwaters, demonstrating an overall agreement. Our simulations, in particular, well reproduce the Mg-depleting maturation path of hydrothermal solutions, and have end-ofrun model solutions whose Na–K–Mg compositions well reflect attainment of full-equilibrium conditions at run temperature. High-temperature (180–260 C) model runs are those best matching the Na–K–Mg compositions of Ischia’s most chemically mature water samples, supporting quenching of deep-reservoir conditions for these surface manifestations; whilst Fe, SiO2 and, to a lesser extent, SO4 contents of natural samples are better reproduced in low-temperature (95 C) runs, suggesting that these species reflect conditions of water–rock interaction in the shallow hydrothermal environment. The ability of model runs to reproduce the compositional features of Ischia’s thermal manifestations, demonstrated here, adds supplementary confidence on reaction path modelling as a realistic and insightful representation of mineral–fluid hydrothermal reactions. Our results, in particular, demonstrate the significant impact of host rock minerals’ assemblage in governing the paths and trends of hydrothermal fluids’ maturation.
    Description: Published
    Description: 108-129
    Description: JCR Journal
    Description: restricted
    Keywords: Ischia ; Hydrothermal systems ; EQ3-6 ; Geochemical modelling ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 91
    Publication Date: 2017-04-04
    Description: A geochemical survey, in shallow aquifers and soils, has been carried out to evaluate the feasibility of natural gas (CH4) storage in a deep saline aquifer at Rivara (MO), Northern Italy. This paper discusses the areal distribution of CO2 and CH4 fluxes and CO2, CH4, Rn, He, H2 concentrations both in soils and shallow aquifers above the proposed storage reservoir. The distribution of pathfinder elements such as 222Rn, He and H2 has been studied in order to identify potential faults and/or fractures related to preferential migration pathways and the possible interactions between the reservoir and surface. A geochemical and isotopic characterization of the ground waters circulating in the first 200 m has allowed to investigation of (i) the origin of the circulating fluids, (ii) the gas–water–rock interaction processes, (iii) the amount of dissolved gases and/or their saturation status. In the first 200 m, the presence of CH4-rich reducing waters are probably related to organic matter (peat) bearing strata which generate shallowderived CH4, as elsewhere in the Po Plain. On the basis of isotopic analysis, no hints of thermogenic CH4 gas leakage from a deeper reservoir have been shown. The d13C(CO2) both in ground waters and free gases suggests a prevalent shallow origin of CO2 (i.e. organic and/or soil-derived). The acquisition of preinjection data is strategic for the natural gas storage development project and as a baseline for future monitoring during the gas injection/withdrawing period. Such a geochemical approach is considered as a methodological reference model for future CO2/CH4 storage projects.
    Description: Published
    Description: 3-22
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: natural gas storage ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 92
    facet.materialart.
    Unknown
    Institute of Nuclear Chemistry and Technology, Poland
    Publication Date: 2017-04-04
    Description: Radon (222Rn) activity concentration in outdoor air was measured, using AlphaGuard radon monitors, at 25 points in the Mt. Etna area, at different distances and in different directions from the summit. Values of up to 93 Bq·m–3 were found at three points close to the summit, at altitudes of about 3000 m above the sea level, and in the range of 3.0–19.6 Bq·m–3 elsewhere. An average radon concentration of 7.9 Bq·m–3 was obtained in the northern region, 4.8 Bq·m–3 in the eastern (oriented towards the sea), 9.6 Bq·m–3 in the western (the furthest inland), and 6.5 Bq·m–3 in the southern.
    Description: Published
    Description: 573-577
    Description: 1.8. Osservazioni di geofisica ambientale
    Description: JCR Journal
    Description: restricted
    Keywords: radon ; outdoor air ; Mt. Etna ; AlphaGuard monitors ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 93
    Publication Date: 2017-04-04
    Description: The study area is a 130 km long fast spreading graben in Central Greece bordered by active faults. Its complex geodynamical setting includes the presence at depth of a subduction slab responsible for the recent (Quaternary) volcanic activity in the area which possibly represents the northward continuation of the South Aegean active volcanic arc. To the area belongs also the western termination of the North-Anatolian fault a tectonic lineament of regional importance. The high geothermal gradient of the area is evidenced by the presence of many thermal springs with temperatures from 19 to 82 °C, issuing along the normal faults bordering the graben. In the period 2004-2012 more than 60 gas and water samples have been collected and their chemical and isotopic analysis revealed a wide range of compositions. Going from west to east the gas composition changes (Fig. 1) from CH4- to CO2-dominated passing through mixed N2-CH4 and N2-CO2 compositions, while at the same time the He isotopic composition goes from typical crustal values (0.02 R/Ra) up to 0.87 R/Ra (corrected for air contamination), showing in the easternmost sites a small but significant mantle input (up to ~ 10%). Isotopic composition of CH4-C indicates a thermogenic origin for the CH4-rich samples (δ13C from -50 to -37 ‰) and hydrothermal origin for the remaining samples (〉 -25‰). Positive δ15N values (around +2 ‰) indicate a contribution of crustal derived nitrogen for the N2-rich samples. The most pristine values of δ13C(CO2) refer to the most CO2-rich samples. These values (~ -3 ‰) point to a mixed mantle-marine carbonate source. Lower δ13C values (-10 ÷ -5 ‰) of the other sites can be explained by loss of CO2 due to dissolution processes. Also temperature and salinity of the waters shows differences along the graben increasing from west to east (Fig. 2). Two main groups can be separated on the basis of the total dissolved salts (TDS). The first, represented by dilute waters (TDS 〈 500 mg/l), is found in the westernmost sites characterised by the presence of CH4-rich and mixed N2-CH4 gases. The remaining waters display higher salinities (TDS from 9 to 35 g/l) due to the mixing with high salinity waters. The water composition can be explained by mixing of two end-members, one with low salinity of meteoric origin and the other with high salinity of marine origin. The mixing can be evidenced in Fig. 2. Low salinity waters show low chloride contents and their light water isotope composition overlaps the field of the cold groundwaters of the area confirming their meteoric origin. High salinity waters are aligned along the mixing line between the cold groundwaters and the seawater confirming the contribution of marine component. Most of the water compositions in the triangular graph of Giggenbach fall in the field of the non equilibrated waters being therefore unsuitable for geothermometric estimations. Only the easternmost sites (Gialtra, Ilion and Edipsos) falling the field of the partially equilibrated waters yield estimated temperatures in the range 150-170 °C. Silica geothermometers confirm these estimations. This study revealed that the complex geodynamic setting of the area is clearly reflected in the wide compositional range of the gases collected in the area that evidence contributions from different end-members (atmosphere, crust, mantle and hydrothermal systems). Water chemistry can be explained mainly from the mixing of a meteoric low-salinity end-member with a high-salinity marine end-member partially modified by hydrothermal water-rock interactions. The highest estimated temperatures in the hydrothermal reservoirs are in the range 150-170 °C.
    Description: Published
    Description: Patras, Greece
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: open
    Keywords: gas geochemistry ; hydrothermal systems ; Helium isotopes ; Carbon isotopes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Extended abstract
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  • 94
    Publication Date: 2017-04-04
    Description: Shallow submarine gas vents in Levante Bay, Vulcano Island (Italy), emit around 3.6t CO2 per day providing a natural laboratory for the study of biogeochemical processes related to seabed CO2 leaks and ocean acidification. The main physico-chemical parameters (T, pH and Eh) were measured at more than 70 stations with 40 seawater samples were collected for chemical analyses. The main gas vent area had high concentrations of dissolved hydrothermal gases, low pH and negative redox values all of which returned to normal seawater values at distances of about 400 m from the main vents. Much of the bay around the vents is corrosive to calcium carbonate; the north shore has a gradient in seawater carbonate chemistry that is well suited to studies of the effects of long-term increases in CO2 levels. This shoreline lacks toxic compounds (such as H2S) and has a gradient in carbonate saturation states.
    Description: Published
    Description: 485–494
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: ocean acidification ; carbon capture and storage ; marine geochemistry ; carbonate saturation state ; volcanic vents ; carbon dioxide ; 03. Hydrosphere::03.04. Chemical and biological::03.04.01. Biogeochemical cycles ; 03. Hydrosphere::03.04. Chemical and biological::03.04.02. Carbon cycling ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.04. Ecosystems ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 95
    Publication Date: 2017-04-03
    Description: Il sistema CUMAS (Cabled Underwater Module for Acquisition of Seismological data) è un prodotto tecnologico-scientifico complesso nato con il Progetto V4 [Iannaccone et al., 2008] allo scopo di monitorare l’area vulcanica dei Campi Flegrei (fenomeno del bradisismo). Si tratta di un modulo sottomarino cablato e connesso a una boa galleggiante (meda elastica). Il sistema è in grado di acquisire e trasmettere alla sala di monitoraggio dell’OV, in continuo e in tempo reale, sia i segnali sismologici sia quelli di interesse geofisico ed oceanografico (maree, correnti marine, segnali acustici subacquei, parametri funzionali di varia natura). Il sistema è in grado di ricevere comandi da remoto per variare diversi parametri di acquisizione e di monitorare un cospicuo numero di variabili di funzionamento. Il sistema si avvale del supporto di una boa galleggiante attrezzata. La boa è installata a largo del golfo di Pozzuoli (Napoli) a circa 3 km dalla costa. Il modulo sottomarino, collegato via cavo alla parte fuori acqua della boa, è installato sul fondale marino a una profondità di circa 100 metri.
    Description: Submitted
    Description: 82-85
    Description: 1.1. TTC - Monitoraggio sismico del territorio nazionale
    Description: 1.3. TTC - Sorveglianza geodetica delle aree vulcaniche attive
    Description: 1.4. TTC - Sorveglianza sismologica delle aree vulcaniche attive
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 1.8. Osservazioni di geofisica ambientale
    Description: 2.5. Laboratorio per lo sviluppo di sistemi di rilevamento sottomarini
    Description: 5.2. TTC - Banche dati di sismologia strumentale
    Description: N/A or not JCR
    Description: open
    Keywords: Monitoraggio sismico; sistemi sottomarini; boa; meda elastica ; 01. Atmosphere::01.01. Atmosphere::01.01.99. General or miscellaneous ; 01. Atmosphere::01.01. Atmosphere::01.01.01. Composition and Structure ; 01. Atmosphere::01.01. Atmosphere::01.01.02. Climate ; 01. Atmosphere::01.01. Atmosphere::01.01.03. Pollution ; 01. Atmosphere::01.01. Atmosphere::01.01.04. Processes and Dynamics ; 01. Atmosphere::01.01. Atmosphere::01.01.05. Radiation ; 01. Atmosphere::01.01. Atmosphere::01.01.06. Thermodynamics ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 01. Atmosphere::01.01. Atmosphere::01.01.08. Instruments and techniques ; 01. Atmosphere::01.02. Ionosphere::01.02.99. General or miscellaneous ; 01. Atmosphere::01.02. Ionosphere::01.02.01. Ion chemistry and composition ; 01. Atmosphere::01.02. Ionosphere::01.02.02. Dynamics ; 01. Atmosphere::01.02. Ionosphere::01.02.03. Forecasts ; 01. Atmosphere::01.02. Ionosphere::01.02.04. Plasma Physics ; 01. Atmosphere::01.02. Ionosphere::01.02.05. Wave propagation ; 01. Atmosphere::01.02. Ionosphere::01.02.06. Instruments and techniques ; 01. Atmosphere::01.02. Ionosphere::01.02.07. Scintillations ; 01. Atmosphere::01.03. Magnetosphere::01.03.99. General or miscellaneous ; 01. Atmosphere::01.03. Magnetosphere::01.03.01. Interplanetary physics ; 01. Atmosphere::01.03. Magnetosphere::01.03.02. Magnetic storms ; 01. Atmosphere::01.03. Magnetosphere::01.03.03. Magnetospheric physics ; 01. Atmosphere::01.03. Magnetosphere::01.03.04. Structure and dynamics ; 01. Atmosphere::01.03. Magnetosphere::01.03.05. Solar variability and solar wind ; 01. Atmosphere::01.03. Magnetosphere::01.03.06. Instruments and techniques ; 02. Cryosphere::02.01. Permafrost::02.01.99. General or miscellaneous ; 02. Cryosphere::02.01. Permafrost::02.01.01. Active layer ; 02. Cryosphere::02.01. Permafrost::02.01.02. Cryobiology ; 02. Cryosphere::02.01. Permafrost::02.01.03. Cryosol ; 02. Cryosphere::02.01. Permafrost::02.01.04. Periglacial processes ; 02. Cryosphere::02.01. Permafrost::02.01.05. Seasonally frozen ground ; 02. Cryosphere::02.01. Permafrost::02.01.06. Thermokarst ; 02. Cryosphere::02.01. Permafrost::02.01.07. Tundra ; 02. Cryosphere::02.01. Permafrost::02.01.08. Instruments and techniques ; 02. Cryosphere::02.02. Glaciers::02.02.99. General or miscellaneous ; 02. Cryosphere::02.02. Glaciers::02.02.01. Avalanches ; 02. Cryosphere::02.02. Glaciers::02.02.02. Cryosphere/atmosphere Interaction ; 02. Cryosphere::02.02. Glaciers::02.02.03. Geomorphology ; 02. Cryosphere::02.02. Glaciers::02.02.04. Ice ; 02. Cryosphere::02.02. Glaciers::02.02.05. Ice dynamics ; 02. Cryosphere::02.02. Glaciers::02.02.06. Mass balance ; 02. Cryosphere::02.02. Glaciers::02.02.07. Ocean/ice interaction ; 02. Cryosphere::02.02. Glaciers::02.02.08. Rock glaciers ; 02. Cryosphere::02.02. Glaciers::02.02.09. Snow ; 02. Cryosphere::02.02. Glaciers::02.02.10. Instruments and techniques ; 02. Cryosphere::02.03. Ice cores::02.03.99. General or miscellaneous ; 02. Cryosphere::02.03. Ice cores::02.03.01. Aerosols ; 02. Cryosphere::02.03. Ice cores::02.03.02. Atmospheric Chemistry ; 02. Cryosphere::02.03. Ice cores::02.03.03. Climate Indicators ; 02. Cryosphere::02.03. Ice cores::02.03.04. Ice Core Air Bubbles ; 02. Cryosphere::02.03. Ice cores::02.03.05. Paleoclimate ; 02. Cryosphere::02.03. Ice cores::02.03.06. Precipitation ; 02. Cryosphere::02.03. Ice cores::02.03.07. Teleconnection ; 02. Cryosphere::02.03. Ice cores::02.03.08. Temperature ; 02. Cryosphere::02.03. Ice cores::02.03.09. Instruments and techniques ; 02. Cryosphere::02.04. Sea ice::02.04.99. General or miscellaneous ; 02. Cryosphere::02.04. Sea ice::02.04.01. Atmosphere/sea ice/ocean interaction ; 02. Cryosphere::02.04. Sea ice::02.04.02. Leads ; 02. Cryosphere::02.04. Sea ice::02.04.03. Polynas ; 02. Cryosphere::02.04. Sea ice::02.04.04. Instruments and techniques ; 03. Hydrosphere::03.01. General::03.01.99. General or miscellaneous ; 03. Hydrosphere::03.01. General::03.01.01. Analytical and numerical modeling ; 03. Hydrosphere::03.01. General::03.01.02. Equatorial and regional oceanography ; 03. Hydrosphere::03.01. General::03.01.03. Global climate models ; 03. Hydrosphere::03.01. General::03.01.04. Ocean data assimilation and reanalysis ; 03. Hydrosphere::03.01. General::03.01.05. Operational oceanography ; 03. Hydrosphere::03.01. General::03.01.06. Paleoceanography and paleoclimatology ; 03. Hydrosphere::03.01. General::03.01.07. Physical and biogeochemical interactions ; 03. Hydrosphere::03.01. General::03.01.08. Instruments and techniques ; 03. Hydrosphere::03.02. Hydrology::03.02.99. General or miscellaneous ; 03. Hydrosphere::03.02. Hydrology::03.02.01. Channel networks ; 03. Hydrosphere::03.02. Hydrology::03.02.02. Hydrological processes: interaction, transport, dynamics ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring ; 03. Hydrosphere::03.02. Hydrology::03.02.05. Models and Forecasts ; 03. Hydrosphere::03.02. Hydrology::03.02.06. Water resources ; 03. Hydrosphere::03.02. Hydrology::03.02.07. Instruments and techniques ; 03. Hydrosphere::03.03. Physical::03.03.99. General or miscellaneous ; 03. Hydrosphere::03.03. Physical::03.03.01. Air/water/earth interactions ; 03. Hydrosphere::03.03. Physical::03.03.02. General circulation ; 03. Hydrosphere::03.03. Physical::03.03.03. Interannual-to-decadal ocean variability ; 03. Hydrosphere::03.03. Physical::03.03.04. Upper ocean and mixed layer processes ; 03. Hydrosphere::03.03. Physical::03.03.05. Instruments and techniques ; 03. Hydrosphere::03.04. Chemical and biological::03.04.99. General or miscellaneous ; 03. Hydrosphere::03.04. Chemical and biological::03.04.01. Biogeochemical cycles ; 03. Hydrosphere::03.04. Chemical and biological::03.04.02. Carbon cycling ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.04. Ecosystems ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 03. Hydrosphere::03.04. Chemical and biological::03.04.07. Radioactivity and isotopes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.08. Instruments and techniques ; 04. Solid Earth::04.01. Earth Interior::04.01.99. General or miscellaneous ; 04. Solid Earth::04.01. Earth Interior::04.01.01. Composition and state ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes ; 04. Solid Earth::04.01. Earth Interior::04.01.03. Mantle and Core dynamics ; 04. Solid Earth::04.01. Earth Interior::04.01.04. Mineral physics and properties of rocks ; 04. Solid Earth::04.01. Earth Interior::04.01.05. Rheology ; 04. Solid Earth::04.02. Exploration geophysics::04.02.99. General or miscellaneous ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration ; 04. Solid Earth::04.02. Exploration geophysics::04.02.02. Gravity methods ; 04. Solid Earth::04.02. Exploration geophysics::04.02.03. Heat flow ; 04. Solid Earth::04.02. Exploration geophysics::04.02.04. Magnetic and electrical methods ; 04. Solid Earth::04.02. Exploration geophysics::04.02.05. Downhole, radioactivity, remote sensing, and other methods ; 04. Solid Earth::04.02. Exploration geophysics::04.02.06. Seismic methods ; 04. Solid Earth::04.02. Exploration geophysics::04.02.07. Instruments and techniques ; 04. Solid Earth::04.03. Geodesy::04.03.99. General or miscellaneous ; 04. Solid Earth::04.03. Geodesy::04.03.01. Crustal deformations ; 04. Solid Earth::04.03. Geodesy::04.03.02. Earth rotation ; 04. Solid Earth::04.03. Geodesy::04.03.03. Gravity and isostasy ; 04. Solid Earth::04.03. Geodesy::04.03.04. Gravity anomalies ; 04. Solid Earth::04.03. Geodesy::04.03.05. Gravity variations ; 04. Solid Earth::04.03. Geodesy::04.03.06. Measurements and monitoring ; 04. Solid Earth::04.03. Geodesy::04.03.07. Satellite geodesy ; 04. Solid Earth::04.03. Geodesy::04.03.08. Theory and Models ; 04. Solid Earth::04.03. Geodesy::04.03.09. Instruments and techniques ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.01. Earthquake geology and paleoseismology ; 04. Solid Earth::04.04. Geology::04.04.02. Geochronology ; 04. Solid Earth::04.04. Geology::04.04.03. Geomorphology ; 04. Solid Earth::04.04. Geology::04.04.04. Marine geology ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology ; 04. Solid Earth::04.04. Geology::04.04.06. Rheology, friction, and structure of fault zones ; 04. Solid Earth::04.04. Geology::04.04.07. Rock geochemistry ; 04. Solid Earth::04.04. Geology::04.04.08. Sediments: dating, processes, transport ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.04. Geology::04.04.10. Stratigraphy ; 04. Solid Earth::04.04. Geology::04.04.11. Instruments and techniques ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.05. Geomagnetism::04.05.99. General or miscellaneous ; 04. Solid Earth::04.05. Geomagnetism::04.05.01. Dynamo theory ; 04. Solid Earth::04.05. Geomagnetism::04.05.02. Geomagnetic field variations and reversals ; 04. Solid Earth::04.05. Geomagnetism::04.05.03. Global and regional models ; 04. Solid Earth::04.05. Geomagnetism::04.05.04. Magnetic anomalies ; 04. Solid Earth::04.05. Geomagnetism::04.05.05. Main geomagnetic field ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism ; 04. Solid Earth::04.05. Geomagnetism::04.05.07. Rock magnetism ; 04. Solid Earth::04.05. Geomagnetism::04.05.08. Instruments and techniques ; 04. Solid Earth::04.05. Geomagnetism::04.05.09. Environmental magnetism ; 04. Solid Earth::04.06. Seismology::04.06.99. General or miscellaneous ; 04. Solid Earth::04.06. Seismology::04.06.01. Earthquake faults: properties and evolution ; 04. Solid Earth::04.06. Seismology::04.06.02. Earthquake interactions and probability ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics ; 04. Solid Earth::04.06. Seismology::04.06.04. Ground motion ; 04. Solid Earth::04.06. Seismology::04.06.05. Historical seismology ; 04. Solid Earth::04.06. Seismology::04.06.06. Surveys, measurements, and monitoring ; 04. Solid Earth::04.06. Seismology::04.06.07. Tomography and anisotropy ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 04. Solid Earth::04.06. Seismology::04.06.09. Waves and wave analysis ; 04. Solid Earth::04.06. Seismology::04.06.10. Instruments and techniques ; 04. Solid Earth::04.06. Seismology::04.06.11. Seismic risk ; 04. Solid Earth::04.07. Tectonophysics::04.07.99. General or miscellaneous ; 04. Solid Earth::04.07. Tectonophysics::04.07.01. Continents ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.03. Heat generation and transport ; 04. Solid Earth::04.07. Tectonophysics::04.07.04. Plate boundaries, motion, and tectonics ; 04. Solid Earth::04.07. Tectonophysics::04.07.05. Stress ; 04. Solid Earth::04.07. Tectonophysics::04.07.06. Subduction related processes ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.07. Tectonophysics::04.07.08. Volcanic arcs ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.02. Experimental volcanism ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.04. Thermodynamics ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.01. Computational geophysics::05.01.99. General or miscellaneous ; 05. General::05.01. Computational geophysics::05.01.01. Data processing ; 05. General::05.01. Computational geophysics::05.01.02. Cellular automata, fuzzy logic, genetic alghoritms, neural networks ; 05. General::05.01. Computational geophysics::05.01.03. Inverse methods ; 05. General::05.01. Computational geophysics::05.01.04. Statistical analysis ; 05. General::05.01. Computational geophysics::05.01.05. Algorithms and implementation ; 05. General::05.02. Data dissemination::05.02.99. General or miscellaneous ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.02. Data dissemination::05.02.02. Seismological data ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions ; 05. General::05.02. Data dissemination::05.02.04. Hydrogeological data ; 05. General::05.02. Data dissemination::05.02.05. Collections ; 05. General::05.03. Educational, History of Science, Public Issues::05.03.99. General or miscellaneous ; 05. General::05.04. Instrumentation and techniques of general interest::05.04.99. General or miscellaneous ; 05. General::05.05. Mathematical geophysics::05.05.99. General or miscellaneous ; 05. General::05.06. Methods::05.06.99. General or miscellaneous ; 05. General::05.07. Space and Planetary sciences::05.07.99. General or miscellaneous ; 05. General::05.07. Space and Planetary sciences::05.07.01. Solar-terrestrial interaction ; 05. General::05.07. Space and Planetary sciences::05.07.02. Space weather ; 05. General::05.08. Risk::05.08.99. General or miscellaneous ; 05. General::05.08. Risk::05.08.01. Environmental risk ; 05. General::05.08. Risk::05.08.02. Hydrogeological risk ; 05. General::05.09. Miscellaneous::05.09.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: manuscript
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  • 96
    Publication Date: 2017-04-04
    Description: Volcanoes generate a broad range of seismo-volcanic and infrasonic signals, whose features and variations are often closely related to volcanic activity. The study of these signals is hence very useful in the monitoring and investigation of volcano dynamics. The analysis of seismo-volcanic and infrasonic signals requires specifically developed techniques due to their unique characteristics, which are generally quite distinct compared with tectonic and volcano-tectonic earthquakes. In this work, we describe analysis methods used to detect and locate seismo-volcanic and infrasonic signals at Mt. Etna. Volcanic tremor sources are located using a method based on spatial seismic amplitude distribution, assuming propagation in a homogeneous medium. The tremor source is found by calculating the goodness of the linear regression fit (R2) of the log-linearized equation of the seismic amplitude decay with distance. The location method for long-period events is based on the joint computation of semblance and R2 values, and the location method of very long-period events is based on the application of radial semblance. Infrasonic events and tremor are located by semblance–brightness- and semblance-based methods, respectively. The techniques described here can also be applied to other volcanoes and do not require particular network geometries (such as arrays) but rather simple sparse networks. Using the source locations of all the considered signals, we were able to reconstruct the shallow plumbing system (above sea level) during 2011.
    Description: Published
    Description: 1751-1771
    Description: 1.4. TTC - Sorveglianza sismologica delle aree vulcaniche attive
    Description: JCR Journal
    Description: restricted
    Keywords: Volcanic tremor ; LP events ; VLP events ; infrasound ; Mt. Etna ; source location ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 97
    Publication Date: 2017-04-04
    Description: On 13 May 2008, an eruption began at Mt. Etna from an eruptive fissure that opened on the upper eastern flank of the volcano. During 12-13 May, 157 infrasonic events, together with the related seismic transients, were collected. We carried out several analyses to obtain dominant frequencies, pseudospectrograms, peak-to-peak amplitudes, source locations and time lags between infrasonic and seismic events. Spectra of the infrasonic events show two main spectral peaks in the frequency bands ~0.4-0.7 Hz and 1.5-2.0 Hz, respectively. Both infrasonic and seismic events were separately located below the North-East Crater, where no eruptive activity was observed. Moreover, significant changes in infrasound spectral content, as well as in the infrasonic-seismic lags, were found a few hours before the beginning of the eruption. On the basis of the collected information the infrasound source mechanism was modelled as a superposition of pipe and Helmholtz resonance, also leading to outline the geometry of the shallower portion of the North-East Crater plumbing system. The occurrence of these seismo-infrasonic events together with other geological and geophysical evidences, led us to inferring a direct link between North-East Crater activity and the eruptive fissure. Further, based on variations over time of both spectral features and seismicinfrasonic time lag, shallowing phenomena of the free magma column inside North-East Crater conduit were hypothesized. Such an uprise of magma was likely caused by a pressure increase inside the plumbing system occurring before the beginning of the 2008-2009 eruption.
    Description: Published
    Description: 53-68
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: JCR Journal
    Description: open
    Keywords: infrasound ; Helmholtz resonator ; plumbing system geometry ; seismo-acoustic studies ; Mt. Etna ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 98
    Publication Date: 2017-10-06
    Description: Themajor elements, trace elements and Sr and Nd isotopes of selected Etnean primitive rocks (b15 ky BP) were studied in order to characterize their mantle source. The noble-gas geochemistry of fluid inclusions in minerals fromthe same lavaswas also investigated. Themajor element compositions ofwhole rocks and minerals showed that these products are among the most primitive atMt. Etna, comprising 6.3–17.5 wt.% MgO. The variable LREE (Light Rare Earth Elements) enrichment relative to MORB (Mid-Ocean Ridge Basalt) (Lan/Ybn = 11–26), togetherwith the patterns of certain trace-element ratios (i.e., Ce/Yb versus Zr/Nb and Th/Y versus La/Yb), can be attributed to varying degrees of melting of a common mantle source. Numerical simulations performed with the MELTS program allowed the melting percentages associated with each product to be estimated. This led us to recalculate the hypothetical parental trace-element content of the Etneanmantle source, whichwas common to all of the investigated rocks. The characteristics of the Sr, Nd and He isotopes confirmed the primitive nature of the rocks,with themost-depleted and primitive lava being that ofMt. Spagnolo (SPA; 143Nd/144Nd = 0.512908 87Sr/ 86Sr = 0.703317–0.703325 and 3He/4He = 7.6 Ra), and highlighted the similarity of the mantle sources feeding the volcanic activity of Mt. Etna and the Hyblean Plateau (a region to the south of Mt. Etna and characterized by oldermagmatismthan Mt. Etna). The coupling of noble gases and trace elements suggests an origin for the investigated Etnean lavas from melting of a Hyblean-like mantle, consisting of a two-component source where a peridotitic matrix is veined by 10% pyroxenite. A variable degree of mantle contamination by crustal-like fluids, probably related to subduction, is proposed to explain the higher Sr-isotope and lowerNd-isotope values in some rocks (143Nd/144Nd up to 0.512865 and 87Sr/86Sr up to 0.703707). This process probably occurred in the source prior tomagma generation, refertilizing some portions of themantle. Accordingly, the estimated degree of melting responsible for each magma appears to be related to its 87Sr/86Sr enrichment. In contrast, the decoupling between 3He/4He and 87Sr/86Sr ratios requires the occurrence in the crustal reservoirs of further processes capable of shifting the He isotope ratio towards slightly more radiogenic values, such as magma aging or a contribution of shallow fluid. Therefore, different residence times in the Etnean reservoir and/or various rates of magma ascent could be key parameters for preserving the original He isotope marker of the Etnean mantle source.
    Description: Published
    Description: 243-258
    Description: 5V. Sorveglianza vulcanica ed emergenze
    Description: JCR Journal
    Description: restricted
    Keywords: Mt. Etna ; Hyblean Plateaux ; Primitive magma ; Mantle metasomatism ; Peridotite ; Pyroxenite ; 04. Solid Earth::04.01. Earth Interior::04.01.03. Mantle and Core dynamics ; 04. Solid Earth::04.04. Geology::04.04.07. Rock geochemistry ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 99
    Publication Date: 2024-05-09
    Description: The genetic relationship between carbon-bearing species (CO, CO2, CH4, C2H6, C3H8, C2H4 and C3H6) was investigated in volcanic-hydrothermal gases emitted from Nisyros (Greece), Vesuvio, La Solfatara (Campi Flegrei) and Pantelleria (all Italy). Apparent carbon isotopic temperatures of the CH4-CO2 system are ~360°C at Nisyros, 420-460°C at Vesuvio, ~450°C at La Solfatara and ~540°C at Pantelleria. These temperatures are confirmed by measured propene/propane and H2/H2O concentration ratios. CH4 and CO2 equilibrate in the single liquid phase prior to the onset of boiling, whereas propene and propane attain equilibrium in the saturated water vapor phase. Boiling in these high-enthalpy hydrothermal systems might occur isothermally. Once vapor has been extracted from the parental liquid, CO/CO2 responds most sensitively to the temperature gradient encountered by the ascending gases. Our results imply that the CH4-CO2 isotopic geothermometer can provide reliable information about temperatures of deep hydrothermal liquids associated with volcanism. Propene/propane and H2/H2O concentration ratios should be measured along with the carbon isotopic composition of CO2 and CH4 to provide independent constraints on the geological significance of the apparent carbon isotopic temperatures.
    Description: Published
    Description: 66–75
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: restricted
    Keywords: Hydrocarbons ; Hydrothermal fluids ; Volcanoes ; Geothermometry ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 100
    Publication Date: 2021-03-01
    Description: In this work, we tackle the problem of seismic hazard at Etna deriving from the recurrent seismogenic activity of local faults, by adopting two independent methods based on probabilistic approaches. We assess the hazard in terms of macroseismic intensity and represent the occurrence probability calculated for different exposure times both on maps and at fault scale. Seismic hazard maps obtained by applying the “site approach” through the SASHA code and a new probabilistic attenuation model, indicate the eastern flank of the volcano as the most hazardous, with expected intensity (Iexp) in 50 years (i.e. the standard exposure time adopted in the seismic regulations) ranging from degrees IX to X EMS. In shorter exposure periods (20, 10, 5 years), values of Iexp up to IX are also reached in the same area, but they are clearly determined by the earthquakes generated by the Timpe fault system. In order to quantify the contribution of local seismogenic sources to the hazard of the region, we reconstruct the seismic history of each fault and calculate with SASHA the probability that earthquakes of a given intensity may be generated in different exposure times. Results confirm the high level of hazard due to the S. Tecla, Moscarello and Fiandaca faults especially for earthquakes of moderate intensity, i.e. VI≤I0≤VII, with probabilities respectively exceeding 50% and 20% in 10 years, and 30% and 10% in 5 years. Occurrence probability of major events (I0≥VIII) at the fault scale has also been investigated by statistics on intertimes. Under stationary assumptions we obtain a probability of 6.8% in 5 years for each structure; by introducing the time-dependency (time elapsed since the last event occurred on each fault) through a BPT model, we identify the Moscarello and S. Tecla faults as the most probable sources to be activated in the next 5 years (2013–2017). This result may represent a useful indication to establish priority criteria for actions aimed at reducing seismic risk at a local scale.
    Description: Published
    Description: 158-169
    Description: 4.2. TTC - Modelli per la stima della pericolosità sismica a scala nazionale
    Description: JCR Journal
    Description: reserved
    Keywords: Macroseismic intensity ; Seismic history ; Occurrence probability ; Time-dependent renewal process ; Individual sources ; Seismic hazard ; Mt. Etna ; 04. Solid Earth::04.06. Seismology::04.06.02. Earthquake interactions and probability ; 04. Solid Earth::04.06. Seismology::04.06.05. Historical seismology ; 04. Solid Earth::04.06. Seismology::04.06.11. Seismic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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