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  • 1
    Publication Date: 2017-12-11
    Description: Volcanoes emit fluids and solid particles into the atmosphere that modify the chemical composition of natural precipitation. We have investigated the geochemistry of Stromboli's rainfall during the period from November 2014 to March 2016 using a network of a new type of sampler specifically designed for operations on volcanic islands.Wefound thatmost of the chemicalmodifications are due to processes occurring after the storage of rainwater in the sampling bottles. These processes include dissolution of volcanogenic soluble salts encrusting volcanic ash and a variable contribution of sea spray aerosol. Our data showed noticeably less scatter than has previously been achieved with a different sampling systemthat wasmore open to the atmosphere. This demonstrates the improved efficacy of the new sampler design. The data showed that post-depositional chemical alteration of rain samples dominates over processes occurring during droplet formation ad precipitation. This has important implications for the calculation of fluxes of chemicals from rainfall in volcanic regions.
    Description: FSE postgraduate specialisation course “Valutazione e monitoraggio dei rischi ambientali naturali” (Regione Siciliana, Asse IV, Capitale Umano)
    Description: Published
    Description: 82-91
    Description: 3V. Proprietà dei magmi e dei prodotti vulcanici
    Description: 5V. Dinamica dei processi eruttivi e post-eruttivi
    Description: JCR Journal
    Description: restricted
    Keywords: Rainwater chemistry; Sea spray; Plume Volcanic ash; Stromboli; Post-depositional processes ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Publication Date: 2024-05-09
    Description: Real-time measurements of GEM and H2S discharged fromnatural and anthropogenic sources are a valuable tool to investigate the dispersion dynamics of these contaminants in air. In this study, a new approach to measure GEM and H2S concentrations in air, carried out by coupling a portable Zeeman atomic absorption spectrometer with high frequency modulation of light polarization (Lumex RA-915M) and a pulsed fluorescence gas analyzer (Thermo Scientific Model 450i), was applied to two distinct areas: (i) in the surroundings of Piancastagnaio (Siena, Central Italy), located in the eastern flanks ofMt. Amiata (a 200,000 years old volcano), where three geothermal plants are operating and whose exhaust gases are dispersed in the atmosphere after passing through the turbines and an abatement system to mitigate the environmental impact on air, and (ii) at Solfatara Crater (Campi Flegrei, Southern Italy), a volcanic apparatus characterized by intense hydrothermal activity. In 2014, seven GEMand H2S surveys were carried out in the two areas along pre-defined pathways performed by car at both the study sites. The lowest and highest recorded GEM and H2S concentrations at Piancastagnaio were up to 194 and 77 ng/m3, respectively, whilst at Solfatara Crater were up to 690 and 3392 μg/m3, respectively. Although the GEM concentrations at Piancastagnaio were lower than the limit value recommended by local regulations for outdoor environment (300 ng/m3), they were almost one order of magnitude higher than the GEM background both in Tuscany (~3.5 ng/m3) and Mt. Amiata (3–5 ng/m3), suggesting that the main source of GEM was likely related to the geothermal plants. At Solfatara Crater, the highest GEM values were recognized in proximity of the main fumarolic gas discharges. As far as the H2S concentrations are concerned, the guideline value of 150 μg/m3, recommended by WHO (2000), was frequently overcome in the study areas. Dot (in the surroundings of Piancastagnaio) and contour (at Solfatara Crater) maps for GEM and H2S concentrations built for each survey highlighted the important effects played by the meteorological parameters, the latter being measured by a Davis® Vantage Vue weather station. In particular, the GEM and H2S plumes were strongly affected by the wind speed and direction thatwere able to modify the dispersion of the two parameters in air in a matter of hours, indicating that the proposed analytical approach is able to produce a more realistic picture of the distribution of these air pollutants than that provided by using passive traps. Finally, the H2S/GEMratio, calculated by normalizing the measured GEM and H2S concentrations to their highest values (nH2S/GEM),was used as a good proxy for the chemical-physical processes that these two gas species can suffer once emitted in the air. In particular, H2S resulted to be more affected by secondary processes than GEM, possibly related to photochemical oxidation reactions.
    Description: Published
    Description: 48-58
    Description: 4V. Vulcani e ambiente
    Description: JCR Journal
    Description: restricted
    Keywords: Real-time measurements ; gaseous elemental mercury ; Hydrogen sulphide ; Gaseous contaminants ; Solfatara crater ; Mt. Amiata ; 01. Atmosphere::01.01. Atmosphere::01.01.03. Pollution ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 3
    Publication Date: 2017-04-04
    Description: The most commonly used method for satellite cloud top height (CTH) compares brightness temperature of the cloud with the atmospheric temperature profile. Because of the uncertainties of this method, we propose a photogrammetric approach. As clouds can move with high velocities, even instruments with multiple cameras are not appropriate for accurate CTH estimation. Here we present two solutions. The first is based on the parallax between data retrieved from geostationary (SEVIRI, HRV band; 1000 m spatial resolution) and polar orbiting satellites (MODIS, band 1; 250 m spatial resolution). The procedure works well if the data from both satellites are retrieved nearly simultaneously. However, MODIS does not retrieve the data at exactly the same time as SEVIRI. To compensate for advection in the atmosphere we use two sequential SEVIRI images (one before and one after the MODIS retrieval) and interpolate the cloud position from SEVIRI data to the time of MODIS retrieval. CTH is then estimated by intersection of corresponding lines-of-view from MODIS and interpolated SEVIRI data. The second method is based on NASA program Crew Earth observations from the International Space Station (ISS). The ISS has a lower orbit than most operational satellites, resulting in a shorter minimal time between two images, which is needed to produce a suitable parallax. In addition, images made by the ISS crew are taken by a full frame sensor and not a push broom scanner that most operational satellites use. Such data make it possible to observe also short time evolution of clouds.
    Description: Published
    Description: 247-254
    Description: 3V. Dinamiche e scenari eruttivi
    Description: N/A or not JCR
    Description: open
    Keywords: photogrammetry, cloud top height, volcanic ash, SEVIRI, MODIS, ISS ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 4
    Publication Date: 2024-05-09
    Description: In this study, hydrogen sulfide (H2S) measurements in air carried out using (a) passive/diffusive samplers (Radiello® traps) and (b) a high-frequency (60 s) real-time analyzer (Thermo® 450i) were compared in order to evaluate advantages and limitations of the two techniques. Four different sites in urban environments (Florence, Italy) and two volcanic areas characterized by intense degassing of H2S-rich fluids (Campi Flegrei and Vulcano Island, Italy) were selected for such measurements. The concentrations of H2S generally varied over 5 orders of magnitude (from 10 1e103 mg/m3), the H2S values measured with the Radiello® traps (H2SR) being significantly higher than the average values measured by the Thermo® 450i during the trap exposure (H2STa), especially when H2S was 〈30 mg/m3. To test the reproducibility of the Radiello® traps, 8 passive/diffusive samplers were contemporaneously deployed within an 0.2 m2 area in an H2S-contaminated site at Mt. Amiata (Tuscany, Italy), revealing that the precision of the H2SR values was ±49%. This large uncertainty, whose cause was not recognizable, is to be added to that related to the environmental conditions (wind speed and direction, humidity, temperature), which are known to strongly affect passive measurements. The Thermo® 450i analyzer measurements highlighted the occurrence of short-term temporal variations of the H2S concentrations, with peak values (up to 5732 mg/m3) potentially harmful to the human health. The Radiello® traps were not able to detect such temporal variability due to their large exposure time. The disagreement between the H2SR and H2STa values poses severe concerns for the selection of an appropriate methodological approach aimed to provide an accurate measurement of this highly toxic air pollutant in compliance with the WHO air quality guidelines. Although passive samplers may offer the opportunity to carry out low-cost preliminary surveys, the use of the high-frequency H2S analyzer is preferred when an accurate assessment of air quality is required. In fact, the latter provides precise real-time measurements for a reliable estimation of the effective exposure to hazardous H2S concentrations, giving insights into the mechanisms regulating the dispersion of this air pollutant in relation to the meteorological parameters.
    Description: Published
    Description: 51-58
    Description: 4V. Vulcani e ambiente
    Description: JCR Journal
    Description: restricted
    Keywords: active analysers ; Passive/diffusive samplers ; Gaseous contaminants ; Air quality monitoring ; Hydrogen sulphide ; 01. Atmosphere::01.01. Atmosphere::01.01.03. Pollution ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 01. Atmosphere::01.01. Atmosphere::01.01.08. Instruments and techniques
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 5
    Publication Date: 2017-04-04
    Description: Volcanic emissions represent one of the most relevant natural sources of trace elements to the troposphere. Due to their potential toxicity they may have important environmental impacts from the local to the global scale and they can severely affect the atmospheric and terrestrial environment also at timescales ranging from a few to million years. Etna volcano is known as one of the largest global contributors of magmatic gases (CO2, SO2, and halogens) and particulate matter, including some toxic trace elements. The aim of this study was to characterize the chemical composition and the mineralogical features of the volcanogenic aerosol passively emitted from Mt. Etna. Nine samples were collected by using the filtration technique at different sites on summer 2010 and 2011. Chemical and mineralogical analyses allowed to discriminate two main constituents: the first is mainly referable to the silicate component in the volcanic plume, like lithic and juvenile fragments, crystals (e.g., plagioclases, pyroxenes, oxides) and shards of volcanic glass; the second one is linked to the soluble components like sulfosalts or halide minerals (sulfates, chlorides and fluorides). These investigations are especially important in the study area because the summit of Mt. Etna is yearly visited by nearly one hundred thousand tourists that are exposed to potentially harmful compounds.
    Description: Published
    Description: Castellaneta Marina (TA), Italy
    Description: 4V. Vulcani e ambiente
    Description: open
    Keywords: Volcanic emissions ; Volcanic aerosols ; trace elements ; environmental impact ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 01. Atmosphere::01.01. Atmosphere::01.01.08. Instruments and techniques
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Conference paper
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  • 6
    Publication Date: 2017-04-04
    Description: Explosive eruptions and volcanic passive degassing inject large quantities of gas and particles into the atmosphere that are ultimately deposited at the Earth’s surface through wet or dry deposition processes, affecting the atmosphere, the hydrosphere and the biosphere. Mount Etna (Italy) is one of the most prodigious and persistent sources of gases and particles to the troposphere. Volcanic emissions were studied at Etna volcano by using moss-bags technique. Mosses (Sphagnum species) were exposed around the volcano at different distances from the active vents to evaluate the impact of its emissions into the atmosphere and in the local surrounding. The results confirmed the huge amount of silicates, sulfates and halides compounds emitted into the atmosphere from Mount Etna. X-ray microanalysis showed that chemical composition of the particles is mostly defined by silicate (from pure silica to metal-rich silicate composition) and sulfate/halide compounds. The contents of major and trace elements in the Sphagnum moss-bags significantly increased after their exposure to volcanic emissions, confirming mosses as efficient accumulators. Metals uptake rate rapidly decreases with the distance from the volcanic emission vents. The elements that showed the greatest accumulation after exposition were S, Na, Fe, Al, Cu, V, As, Cd, Li, Se, Sc, Th, Bi and Tl. This study confirmed the marked environmental impact of volcanic emissions in the eastern sector of Etna, leading to an intense “geochemical anomaly” of volatile major and trace elements due to the fumigation by the volcanic plume, in agreement with passive biomonitoring studies reported by previous authors. Finally, moss-bags techniques provide a cheap and efficient method to investigate quantitatively in space and time the environmental impact of volcanogenic atmospheric deposition.
    Description: Published
    Description: Castellaneta Marina (TA), Italy
    Description: 4V. Vulcani e ambiente
    Description: open
    Keywords: trace elements ; volcanic emissions ; atmospheric deposition ; biomonitoring ; geochemistry ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 01. Atmosphere::01.01. Atmosphere::01.01.08. Instruments and techniques
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Conference paper
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  • 7
    Publication Date: 2017-04-04
    Description: Volcanoes are well known as an impressive large natural source of trace elements into the troposphere. Etna (Italy) and Nyiragongo (D.R. Congo) are two stratovolcanoes located in different geological settings, both characterized by persistent passive degassing from their summit craters. Here, we present some results on trace element composition in volcanic plume emissions, atmospheric bulk deposition (rainwater) and their uptake by the surrounding vegetation, with the aim to compare and identify differences and similarities between these two volcanoes. Volcanic emissions were sampled by using active filter-packs for acid gases (sulfur and halogens) and specific teflon filters for particulates (major and trace elements). The environmental impact of the volcanogenic deposition in the area surrounding of the crater rims was investigated by using different sampling techniques: bulk rain collectors’ gauges were used to collect atmospheric bulk deposition, and biomonitoring was carried out to collect gases and particulates by using endemic plant species. The estimates of the trace element fluxes confirm that Etna and Nyiragongo are large sources of metals into the atmosphere, especially considering their persistent state of passive degassing. The large amount of emitted trace elements is clearly reflected on the chemical composition of rainwater collected at the summit areas both for Etna and Nyiragongo. Moreover, the biomonitoring results highlight that bioaccumulation of trace elements is extremely high in the proximity of the crater rim and decreases with the distance from the active craters.
    Description: Published
    Description: 1 - 6
    Description: 4V. Vulcani e ambiente
    Description: JCR Journal
    Description: open
    Keywords: volcanic emissions ; filter-packs ; trace elements ; biomonitoring ; bulk deposition ; 01. Atmosphere::01.01. Atmosphere::01.01.03. Pollution ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 8
    Publication Date: 2020-02-24
    Description: We present a coupled fluid-dynamic and electromagnetic model for volcanic ash plumes. In a forward approach, the model is able to simulate the plume dynamics from prescribed input flow conditions and generate the corresponding synthetic thermal infrared (TIR) image, allowing a comparison with field-based observations. An inversion procedure is then developed to retrieve vent conditions from TIR images, and to independently estimate the mass eruption rate. The adopted fluid-dynamic model is based on a one-dimensional, stationary description of a self-similar turbulent plume, for which an asymptotic analytical solution is obtained. The electromagnetic emission/absorption model is based on Schwarzschild's equation and on Mie's theory for disperse particles, and we assume that particles are coarser than the radiation wavelength (about 10 μm) and that scattering is negligible. In the inversion procedure, model parameter space is sampled to find the optimal set of input conditions which minimizes the difference between the experimental and the synthetic image. Application of the inversion procedure to an ash plume at Santiaguito (Santa Maria volcano, Guatemala) has allowed us to retrieve the main plume input parameters, namely mass flow rate, initial radius, velocity, temperature, gas mass ratio, entrainment coefficient and their related uncertainty. Moreover, by coupling with the electromagnetic model we have been able to obtain a reliable estimate of the equivalent Sauter diameter of the total particle size distribution. The presented method is general and, in principle, can be applied to the spatial distribution of particle concentration and temperature obtained by any fluid-dynamic model, either integral or multidimensional, stationary or time-dependent, single or multiphase. The method discussed here is fast and robust, thus indicating potential for applications to real-time estimation of ash mass flux and particle size distribution, which is crucial for model-based forecasts of the volcanic ash dispersal process.
    Description: Published
    Description: 129–147
    Description: 3V. Dinamiche e scenari eruttivi
    Description: 4V. Vulcani e ambiente
    Description: 5V. Sorveglianza vulcanica ed emergenze
    Description: JCR Journal
    Description: restricted
    Keywords: Volcanic ash plume ; Volcanic ash plume ; Thermal camera ; Inversion ; Mass flow ; Particle size ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 01. Atmosphere::01.01. Atmosphere::01.01.08. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.02. Experimental volcanism ; 04. Solid Earth::04.08. Volcanology::04.08.04. Thermodynamics ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.01. Computational geophysics::05.01.01. Data processing ; 05. General::05.01. Computational geophysics::05.01.03. Inverse methods ; 05. General::05.01. Computational geophysics::05.01.04. Statistical analysis ; 05. General::05.05. Mathematical geophysics::05.05.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 9
    Publication Date: 2017-04-04
    Description: A particular synergy among GPS and SAR techniques, to improve the precision of the current ground deformation monitoring techniques, is investigated. The study of atmo- spheric anomalies in the GPS EM waves propagation is useful to extrapolate information about the wet refractivity field. Because of its height and the quite variable weather conditions, the estimation of Mount Etna atmospheric anomalies using GPS measure- ments have noticeable importance to calibrate the SAR interferograms and to establish the “effective” ground deformation of the volcanic edifice. In this study we presented a method to obtain a 3D electromagnetic waves velocity tomography, starting from the GPS output data analysis. Thanks to the agreement between the University of Catania and the INGV-OE, the GPS data used in this work come from ”Etn@net” framework. The GPS processing has been carried out by using the GAMIT software, by adopting appropriate processing parameters. A new software was developed for deriving the tro- pospheric tomography from the GPS data. The code was validated by using synthetic tests which assume different structure of atmospheric anomalies and with random noise about twice severe than the typical errors of the GPS. The results of the tests proved that the tomography software is able to reconstruct the simulated anomalies faithfully. The code was applied to study the structure of the atmosphere in an actual case: the period of August 12, 2011 at 10.00 am. The results of the tomography indicate clearly important features of the refractivity field of the studied day. In conclusion, the syn- thetic tests and the application on actual data sets of the new software demonstrate that it is able to reveal the tropospheric anomalies and thus it is an useful tool to improve the results of the SAR interferometry. An indirect outcome of the use of the GPS for the atmospheric sounding on an active volcanic area is that concerning the detection of volcanic products in the atmosphere. Due to the Mt. Etna persistent activity occurred during the last two years, the capability of GPS to detect the volcanic plume was investigated. The Etna volcano is particularly suited for an in-depth investigation into the aptitude of GPS observations to detect volcanic plumes, owing to both the high frequency of explosive episodes and also the well-developed GPS network. Two different approaches were tested, in order to examine the capability of the GPS network to detect volcanic plumes at Etna. The first approach is applied on the signal strength of the GPS L2 carrier phase data, the second approach, instead, is statistical, and analyzes the single difference post fit residual of elaboration signals to assert the hypothesis that the plume affects the GPS data. The proposed method has been tested for the September 4–5, 2007 activity of Mt. Etna. Results from nineteen GPS permanent stations show that during this explosive activity, the GPS residuals definitely include the contribution of the volcanic plume. In the future, data derived from the GPS stations located on Etna’s flanks could be used to improve the alerting system of volcanic ash, already operating at the Istituto Nazionale di Geofisica e Vulcanologia, Osservatorio Etneo.
    Description: Università degli Studi di Catania
    Description: Published
    Description: 3V. Dinamiche e scenari eruttivi
    Description: 4V. Vulcani e ambiente
    Description: 5IT. Osservazioni satellitari
    Description: restricted
    Keywords: Atmosphere ; Etna ; Tomography ; 01. Atmosphere::01.01. Atmosphere::01.01.01. Composition and Structure ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 01. Atmosphere::01.01. Atmosphere::01.01.08. Instruments and techniques
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: thesis
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  • 10
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    Società editrice Il Mulino, Bologna
    Publication Date: 2017-04-04
    Description: I fenomeni naturali, anche nei loro aspetti più temibili, ci ricordano che la Terra è un pianeta vivo. L’Italia, paese geologicamente fragile, è soggetto a terremoti, eruzioni, frane, inondazioni dagli effetti spesso devastanti. A un ambiente fisico così difficile si sono colpevolmente aggiunte l’incuria e la disattenzione dell’uomo. Quali sono le cause dei fenomeni naturali? In che misura sono prevedibili? Come possiamo difenderci? Il primo passo è trasformare la cultura del soccorso e dell’emergenza in cultura della prevenzione e della mitigazione del rischio.
    Description: Published
    Description: 3T. Pericolosità sismica e contributo alla definizione del rischio
    Description: 4V. Vulcani e ambiente
    Description: 4A. Clima e Oceani
    Description: reserved
    Keywords: Rischi naturali ; Terremoti ; Frane ; Eruzioni vulcaniche ; Rischio sismico ; Rischio idrogeologico ; Incendi ; Rischio vulcanico ; Rischio idraulico ; Valanghe ; Tsunami ; Subsidenza ; Cavità sotterranee ; Rischio geochimico ; Rischio geomineralogico ; Rischio minerario ; Rischio meteorologico ; Rischio climatico ; Meteoriti ; Percezione del rischio ; Emergenza ; Prevenzione ; Ciclo del disastro ; 01. Atmosphere::01.01. Atmosphere::01.01.02. Climate ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 02. Cryosphere::02.03. Ice cores::02.03.06. Precipitation ; 04. Solid Earth::04.06. Seismology::04.06.11. Seismic risk ; 04. Solid Earth::04.07. Tectonophysics::04.07.04. Plate boundaries, motion, and tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.08. Risk::05.08.01. Environmental risk ; 05. General::05.08. Risk::05.08.02. Hydrogeological risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: book
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  • 11
    Publication Date: 2017-04-04
    Description: We present the results of laboratory experiments on the aggregation and disaggregation of colliding volcanic ash particles. Ash particles of different composition and size 〈90 µm were held in turbulent suspension and filmed in high speed while colliding, aggregating, and disaggregating, forming a growing layer of electrostatically bound particles along a vertical plate. At room conditions and regardless of composition, 60–80% of the colliding particles smaller than 32 µm remained aggregated. In contrast, aggregation of particles larger than 63 µm was negligible, and, when a layer formed, periods when disaggregation (mainly by collisions or drag) exceeded aggregation occurred twice as frequently than for smaller particles. An empirical relationship linking the aggregation index, i.e., the effective fraction of aggregated particles surviving disaggregation, to the mean particle collision kinetic energy is provided. Our results have potential implications on the dynamics of volcanic plumes and ash mobility in the environment.
    Description: INGV-DPC project V1 “Probabilistic evaluation of volcanic hazard”; EU Seventh Programme FP7 “MED-SUV” grant agreement 308665
    Description: Published
    Description: 1068–1075
    Description: 3V. Dinamiche e scenari eruttivi
    Description: 2IT. Laboratori sperimentali e analitici
    Description: JCR Journal
    Description: restricted
    Keywords: volcanic ash ; disaggregation ; experimental modeling ; volcanic plumes ; aggregation processes ; colliding particles ; sticking rate ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.08. Volcanology::04.08.02. Experimental volcanism ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 12
    Publication Date: 2017-04-04
    Description: L'Olocene è l'epoca geologica più recente e si estende convenzionalmente da circa 11.700 anni fa fino ai giorni nostri. È in questo periodo che appaiono le più importanti civiltà umane. Pertanto, a partire dall'Olocene, i cambiamenti ambientali, i fenomeni naturali e i pericoli ad essi associati diventano determinanti per il loro impatto sugli eventi storici, spesso andando a sovrapporsi alle vicende umane e influenzando l'ascesa o il declino delle civiltà stesse. Questo lavoro vuole offrire una panoramica sulle condizioni geologiche, climatiche e paleogeografiche che caratterizzano l'Olocene nell'Europa settentrionale e dell'area mediterranea, per fornire elementi utili ad inquadrare in modo più accurato l'ipotesi formulata da Felice Vinci sulla migrazione delle popolazioni del Baltico verso il Mediterraneo nell'Età del Bronzo, alla fine del "Optimum climatico". Nello studio vengono sintetizzate informazioni sulle variazioni glacio-eustatiche e sul sollevamento isostatico olocenico che hanno caratterizzato l'Atlantico settentrionale, il Mare del Nord, la Scandinavia ed il Mar Baltico. Inoltre, vengono illustrati dati su terremoti, eruzioni vulcaniche e probabili tsunami che interessarono la regione del Mediterraneo ed il Nord Europa nell'Olocene: tali eventi catastrofici potrebbero in qualche modo aver favorito lo spostamento e l'insediamento di popolazioni scandinave provenienti dal nord nelle aree mediterranee, anche in virtù dell'indebolimento demografico e socio-economico delle popolazioni indigene. I dati e le informazioni sono stati attinti dalla letteratura scientifica, riportata in bibliografia. Tuttavia è importante evidenziare che la quantità di informazioni disponibili sugli argomenti trattati in questo lavoro è rilevante e talvolta teorie sviluppate a partire dagli stessi dati si mostrano in conflitto. Il confronto tra l'area mediterranea e la regione baltica (una delle quali potrebbe essere stata il teatro degli eventi raccontati da Omero) potrebbe rivelarsi utile per individuare tracce, evidenze e prove di eventi geologici catastrofici nella narrazione omerica e per fornire nuovi elementi sui luoghi in cui i poemi sono ambientati, delineando spunti di discussione e di approfondimento per studi scientifici che possano verificare o confutare l'ipotesi formulata da Vinci .
    Description: Published
    Description: 341-362
    Description: 3T. Pericolosità sismica e contributo alla definizione del rischio
    Description: 4V. Vulcani e ambiente
    Description: 4A. Clima e Oceani
    Description: N/A or not JCR
    Description: restricted
    Keywords: Olocene ; Geologia ; Clima ; Eustatismo ; Terremoti ; Vulcani ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.06. Seismology::04.06.11. Seismic risk ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.08. Risk::05.08.99. General or miscellaneous ; 05. General::05.09. Miscellaneous::05.09.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 13
    Publication Date: 2017-04-04
    Description: Annals of Geophysics (ISSN: 1593-5213; from 2010, 2037-416X) is a bimonthly international journal, which publishes scientific papers in the field of geophysics sensu lato. It derives from Annali di Geofisica (ISSN: 0365-2556), which commenced publication in January 1948 as a quarterly periodical devoted to general geophysics, seismology, Earth magnetism, and atmospheric studies....
    Description: Published
    Description: E0191
    Description: 1T. Geodinamica e interno della Terra
    Description: 2T. Tettonica attiva
    Description: 3T. Pericolosità sismica e contributo alla definizione del rischio
    Description: 4T. Fisica dei terremoti e scenari cosismici
    Description: 5T. Sorveglianza sismica e operatività post-terremoto
    Description: 6T. Sismicità indotta e caratterizzazione sismica dei sistemi naturali
    Description: 1V. Storia e struttura dei sistemi vulcanici
    Description: 2V. Dinamiche di unrest e scenari pre-eruttivi
    Description: 3V. Dinamiche e scenari eruttivi
    Description: 4V. Vulcani e ambiente
    Description: 5V. Sorveglianza vulcanica ed emergenze
    Description: 1A. Geomagnetismo e Paleomagnetismo
    Description: 2A. Fisica dell'alta atmosfera
    Description: 3A. Ambiente Marino
    Description: 4A. Clima e Oceani
    Description: 5A. Energia e georisorse
    Description: 6A. Monitoraggio ambientale, sicurezza e territorio
    Description: 7A. Geofisica di esplorazione
    Description: 1IT. Reti di monitoraggio e Osservazioni
    Description: 2IT. Laboratori sperimentali e analitici
    Description: 3IT. Calcolo scientifico e sistemi informatici
    Description: 4IT. Banche dati
    Description: 5IT. Osservazioni satellitari
    Description: 6IT. Sale operative
    Description: JCR Journal
    Description: open
    Keywords: editorial ; 01. Atmosphere::01.01. Atmosphere::01.01.99. General or miscellaneous ; 01. Atmosphere::01.01. Atmosphere::01.01.01. Composition and Structure ; 01. Atmosphere::01.01. Atmosphere::01.01.02. Climate ; 01. Atmosphere::01.01. Atmosphere::01.01.03. Pollution ; 01. Atmosphere::01.01. Atmosphere::01.01.04. Processes and Dynamics ; 01. Atmosphere::01.01. Atmosphere::01.01.05. Radiation ; 01. Atmosphere::01.01. Atmosphere::01.01.06. Thermodynamics ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 01. Atmosphere::01.01. Atmosphere::01.01.08. Instruments and techniques ; 01. Atmosphere::01.02. Ionosphere::01.02.99. General or miscellaneous ; 01. Atmosphere::01.02. Ionosphere::01.02.01. Ion chemistry and composition ; 01. Atmosphere::01.02. Ionosphere::01.02.02. Dynamics ; 01. Atmosphere::01.02. Ionosphere::01.02.03. Forecasts ; 01. Atmosphere::01.02. Ionosphere::01.02.04. Plasma Physics ; 01. Atmosphere::01.02. Ionosphere::01.02.05. Wave propagation ; 01. Atmosphere::01.02. Ionosphere::01.02.06. Instruments and techniques ; 01. Atmosphere::01.02. Ionosphere::01.02.07. Scintillations ; 01. Atmosphere::01.03. Magnetosphere::01.03.99. General or miscellaneous ; 01. Atmosphere::01.03. Magnetosphere::01.03.01. Interplanetary physics ; 01. Atmosphere::01.03. Magnetosphere::01.03.02. Magnetic storms ; 01. Atmosphere::01.03. Magnetosphere::01.03.03. Magnetospheric physics ; 01. Atmosphere::01.03. Magnetosphere::01.03.04. Structure and dynamics ; 01. Atmosphere::01.03. Magnetosphere::01.03.05. Solar variability and solar wind ; 01. Atmosphere::01.03. Magnetosphere::01.03.06. Instruments and techniques ; 02. Cryosphere::02.01. Permafrost::02.01.99. General or miscellaneous ; 02. Cryosphere::02.01. Permafrost::02.01.01. Active layer ; 02. Cryosphere::02.01. Permafrost::02.01.02. Cryobiology ; 02. Cryosphere::02.01. Permafrost::02.01.03. Cryosol ; 02. Cryosphere::02.01. Permafrost::02.01.04. Periglacial processes ; 02. Cryosphere::02.01. Permafrost::02.01.05. Seasonally frozen ground ; 02. Cryosphere::02.01. Permafrost::02.01.06. Thermokarst ; 02. Cryosphere::02.01. Permafrost::02.01.07. Tundra ; 02. Cryosphere::02.01. Permafrost::02.01.08. Instruments and techniques ; 02. Cryosphere::02.02. Glaciers::02.02.99. General or miscellaneous ; 02. Cryosphere::02.02. Glaciers::02.02.01. Avalanches ; 02. Cryosphere::02.02. Glaciers::02.02.02. Cryosphere/atmosphere Interaction ; 02. Cryosphere::02.02. Glaciers::02.02.03. Geomorphology ; 02. Cryosphere::02.02. Glaciers::02.02.04. Ice ; 02. Cryosphere::02.02. Glaciers::02.02.05. Ice dynamics ; 02. Cryosphere::02.02. Glaciers::02.02.06. Mass balance ; 02. Cryosphere::02.02. Glaciers::02.02.07. Ocean/ice interaction ; 02. Cryosphere::02.02. Glaciers::02.02.08. Rock glaciers ; 02. Cryosphere::02.02. Glaciers::02.02.09. Snow ; 02. Cryosphere::02.02. Glaciers::02.02.10. Instruments and techniques ; 02. Cryosphere::02.03. Ice cores::02.03.99. General or miscellaneous ; 02. Cryosphere::02.03. Ice cores::02.03.01. Aerosols ; 02. Cryosphere::02.03. Ice cores::02.03.02. Atmospheric Chemistry ; 02. Cryosphere::02.03. Ice cores::02.03.03. Climate Indicators ; 02. Cryosphere::02.03. Ice cores::02.03.04. Ice Core Air Bubbles ; 02. Cryosphere::02.03. Ice cores::02.03.05. Paleoclimate ; 02. Cryosphere::02.03. Ice cores::02.03.06. Precipitation ; 02. Cryosphere::02.03. Ice cores::02.03.07. Teleconnection ; 02. Cryosphere::02.03. Ice cores::02.03.08. Temperature ; 02. Cryosphere::02.03. Ice cores::02.03.09. Instruments and techniques ; 02. Cryosphere::02.04. Sea ice::02.04.99. General or miscellaneous ; 02. Cryosphere::02.04. Sea ice::02.04.01. Atmosphere/sea ice/ocean interaction ; 02. Cryosphere::02.04. Sea ice::02.04.02. Leads ; 02. Cryosphere::02.04. Sea ice::02.04.03. Polynas ; 02. Cryosphere::02.04. Sea ice::02.04.04. Instruments and techniques ; 03. Hydrosphere::03.01. General::03.01.99. General or miscellaneous ; 03. Hydrosphere::03.01. General::03.01.01. Analytical and numerical modeling ; 03. Hydrosphere::03.01. General::03.01.02. Equatorial and regional oceanography ; 03. Hydrosphere::03.01. General::03.01.03. Global climate models ; 03. Hydrosphere::03.01. General::03.01.04. Ocean data assimilation and reanalysis ; 03. Hydrosphere::03.01. General::03.01.05. Operational oceanography ; 03. Hydrosphere::03.01. General::03.01.06. Paleoceanography and paleoclimatology ; 03. Hydrosphere::03.01. General::03.01.07. Physical and biogeochemical interactions ; 03. Hydrosphere::03.01. General::03.01.08. Instruments and techniques ; 03. Hydrosphere::03.02. Hydrology::03.02.99. General or miscellaneous ; 03. Hydrosphere::03.02. Hydrology::03.02.01. Channel networks ; 03. Hydrosphere::03.02. Hydrology::03.02.02. Hydrological processes: interaction, transport, dynamics ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring ; 03. Hydrosphere::03.02. Hydrology::03.02.05. Models and Forecasts ; 03. Hydrosphere::03.02. Hydrology::03.02.06. Water resources ; 03. Hydrosphere::03.02. Hydrology::03.02.07. Instruments and techniques ; 03. Hydrosphere::03.03. Physical::03.03.99. General or miscellaneous ; 03. Hydrosphere::03.03. Physical::03.03.01. Air/water/earth interactions ; 03. Hydrosphere::03.03. Physical::03.03.02. General circulation ; 03. Hydrosphere::03.03. Physical::03.03.03. Interannual-to-decadal ocean variability ; 03. Hydrosphere::03.03. Physical::03.03.04. Upper ocean and mixed layer processes ; 03. Hydrosphere::03.03. Physical::03.03.05. Instruments and techniques ; 03. Hydrosphere::03.04. Chemical and biological::03.04.99. General or miscellaneous ; 03. Hydrosphere::03.04. Chemical and biological::03.04.01. Biogeochemical cycles ; 03. Hydrosphere::03.04. Chemical and biological::03.04.02. Carbon cycling ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.04. Ecosystems ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 03. Hydrosphere::03.04. Chemical and biological::03.04.07. Radioactivity and isotopes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.08. Instruments and techniques ; 04. Solid Earth::04.01. Earth Interior::04.01.99. General or miscellaneous ; 04. Solid Earth::04.01. Earth Interior::04.01.01. Composition and state ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes ; 04. Solid Earth::04.01. Earth Interior::04.01.03. Mantle and Core dynamics ; 04. Solid Earth::04.01. Earth Interior::04.01.04. Mineral physics and properties of rocks ; 04. Solid Earth::04.01. Earth Interior::04.01.05. Rheology ; 04. Solid Earth::04.02. Exploration geophysics::04.02.99. General or miscellaneous ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration ; 04. Solid Earth::04.02. Exploration geophysics::04.02.02. Gravity methods ; 04. Solid Earth::04.02. Exploration geophysics::04.02.03. Heat flow ; 04. Solid Earth::04.02. Exploration geophysics::04.02.04. Magnetic and electrical methods ; 04. Solid Earth::04.02. Exploration geophysics::04.02.05. Downhole, radioactivity, remote sensing, and other methods ; 04. Solid Earth::04.02. Exploration geophysics::04.02.06. Seismic methods ; 04. Solid Earth::04.02. Exploration geophysics::04.02.07. Instruments and techniques ; 04. Solid Earth::04.03. Geodesy::04.03.99. General or miscellaneous ; 04. Solid Earth::04.03. Geodesy::04.03.01. Crustal deformations ; 04. Solid Earth::04.03. Geodesy::04.03.02. Earth rotation ; 04. Solid Earth::04.03. Geodesy::04.03.03. Gravity and isostasy ; 04. Solid Earth::04.03. Geodesy::04.03.04. Gravity anomalies ; 04. Solid Earth::04.03. Geodesy::04.03.05. Gravity variations ; 04. Solid Earth::04.03. Geodesy::04.03.06. Measurements and monitoring ; 04. Solid Earth::04.03. Geodesy::04.03.07. Satellite geodesy ; 04. Solid Earth::04.03. Geodesy::04.03.08. Theory and Models ; 04. Solid Earth::04.03. Geodesy::04.03.09. Instruments and techniques ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.01. Earthquake geology and paleoseismology ; 04. Solid Earth::04.04. Geology::04.04.02. Geochronology ; 04. Solid Earth::04.04. Geology::04.04.03. Geomorphology ; 04. Solid Earth::04.04. Geology::04.04.04. Marine geology ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology ; 04. Solid Earth::04.04. Geology::04.04.06. Rheology, friction, and structure of fault zones ; 04. Solid Earth::04.04. Geology::04.04.07. Rock geochemistry ; 04. Solid Earth::04.04. Geology::04.04.08. Sediments: dating, processes, transport ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.04. Geology::04.04.10. Stratigraphy ; 04. Solid Earth::04.04. Geology::04.04.11. Instruments and techniques ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.05. Geomagnetism::04.05.99. General or miscellaneous ; 04. Solid Earth::04.05. Geomagnetism::04.05.01. Dynamo theory ; 04. Solid Earth::04.05. Geomagnetism::04.05.02. Geomagnetic field variations and reversals ; 04. Solid Earth::04.05. Geomagnetism::04.05.03. Global and regional models ; 04. Solid Earth::04.05. Geomagnetism::04.05.04. Magnetic anomalies ; 04. Solid Earth::04.05. Geomagnetism::04.05.05. Main geomagnetic field ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism ; 04. Solid Earth::04.05. Geomagnetism::04.05.07. Rock magnetism ; 04. Solid Earth::04.05. Geomagnetism::04.05.08. Instruments and techniques ; 04. Solid Earth::04.05. Geomagnetism::04.05.09. Environmental magnetism ; 04. Solid Earth::04.06. Seismology::04.06.99. General or miscellaneous ; 04. Solid Earth::04.06. Seismology::04.06.01. Earthquake faults: properties and evolution ; 04. Solid Earth::04.06. Seismology::04.06.02. Earthquake interactions and probability ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics ; 04. Solid Earth::04.06. Seismology::04.06.04. Ground motion ; 04. Solid Earth::04.06. Seismology::04.06.05. Historical seismology ; 04. Solid Earth::04.06. Seismology::04.06.06. Surveys, measurements, and monitoring ; 04. Solid Earth::04.06. Seismology::04.06.07. Tomography and anisotropy ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 04. Solid Earth::04.06. Seismology::04.06.09. Waves and wave analysis ; 04. Solid Earth::04.06. Seismology::04.06.10. Instruments and techniques ; 04. Solid Earth::04.06. Seismology::04.06.11. Seismic risk ; 04. Solid Earth::04.07. Tectonophysics::04.07.99. General or miscellaneous ; 04. Solid Earth::04.07. Tectonophysics::04.07.01. Continents ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.03. Heat generation and transport ; 04. Solid Earth::04.07. Tectonophysics::04.07.04. Plate boundaries, motion, and tectonics ; 04. Solid Earth::04.07. Tectonophysics::04.07.05. Stress ; 04. Solid Earth::04.07. Tectonophysics::04.07.06. Subduction related processes ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.07. Tectonophysics::04.07.08. Volcanic arcs ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.02. Experimental volcanism ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.04. Thermodynamics ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.01. Computational geophysics::05.01.99. General or miscellaneous ; 05. General::05.01. Computational geophysics::05.01.01. Data processing ; 05. General::05.01. Computational geophysics::05.01.02. Cellular automata, fuzzy logic, genetic alghoritms, neural networks ; 05. General::05.01. Computational geophysics::05.01.03. Inverse methods ; 05. General::05.01. Computational geophysics::05.01.04. Statistical analysis ; 05. General::05.01. Computational geophysics::05.01.05. Algorithms and implementation ; 05. General::05.02. Data dissemination::05.02.99. General or miscellaneous ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.02. Data dissemination::05.02.02. Seismological data ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions ; 05. General::05.02. Data dissemination::05.02.04. Hydrogeological data ; 05. General::05.02. Data dissemination::05.02.05. Collections ; 05. General::05.03. Educational, History of Science, Public Issues::05.03.99. General or miscellaneous ; 05. General::05.04. Instrumentation and techniques of general interest::05.04.99. General or miscellaneous ; 05. General::05.05. Mathematical geophysics::05.05.99. General or miscellaneous ; 05. General::05.06. Methods::05.06.99. General or miscellaneous ; 05. General::05.07. Space and Planetary sciences::05.07.99. General or miscellaneous ; 05. General::05.07. Space and Planetary sciences::05.07.01. Solar-terrestrial interaction ; 05. General::05.07. Space and Planetary sciences::05.07.02. Space weather ; 05. General::05.08. Risk::05.08.99. General or miscellaneous ; 05. General::05.08. Risk::05.08.01. Environmental risk ; 05. General::05.08. Risk::05.08.02. Hydrogeological risk ; 05. General::05.09. Miscellaneous::05.09.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 14
    Publication Date: 2019-01-09
    Description: Nisyros Island, Greece, is a stratovolcano known for its intense hydrothermal activity. On June 2013, during a multidisciplinary field campaign, soil samples were collected in the caldera area to determinate the main mineralogical assemblages and to investigate the distribution of trace element concentrations and the possible relationship to the contribution of fluids of deep origin. Soil samples were analysed with XRD and for the chemical composition of their leachable (deionized water) and pseudo total (microwave digestion) fraction both for major and trace elements. The results allow to divide the samples in 2 groups: Lakki Plain and Stefanos Crater. The latter, where a fumarolic area is located, shows a mineralogical assemblage dominated by phases typical of hydrothermal alteration. Their very low pH values (1.9 – 3.4) show the strong impact of fumarolic gases which are probably also the cause of strong enrichments in these soils of highly volatile elements like S, As, Se, Bi, Sb, Tl and Te.
    Description: Published
    Description: 2SR. VULCANI - Servizi e ricerca per la Società
    Description: JCR Journal
    Description: open
    Keywords: Trace elements ; Hydrothermal alteration ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 15
    Publication Date: 2017-04-04
    Description: Hourly values of atmospheric pressure and air temperature have been acquired at the top of two volcanic islands, Stromboli and Salina in the Aeolian Archipelago (Italy), very similar in height and morphology but completely different with regard to their volcanic activity state: the former is permanently active, whereas the latter is extinguished. During the last four years Stromboli experienced normal activity, volcanic unrests, and an effusive eruption (August–November 2014).The comparative analysis of the recorded data, both in the time and frequency domains, evidenced a peculiar micrometeorological regime at Stromboli, more turbulent during unrests with respect to the quieter periods, but showing an apparent paradox during eruptions, characterized by a lower atmospheric turbulence. These observations suggest that the studied volcanic-micrometeorological system is chaotic, due to contemporary opposite transients generated in the atmosphere by volcanic activity changes, and that micrometeorological conditions in volcanic areas are controlled both by exogenous processes and volcanic activity.
    Description: Published
    Description: Article ID 434090
    Description: 4V. Vulcani e ambiente
    Description: JCR Journal
    Description: open
    Keywords: Air temperature ; Atmospheric pressure ; Stromboli ; Volcanic activity ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 16
    Publication Date: 2021-06-22
    Description: Total CO2 output from soil gas and plume, discharged from the Stromboli Island, was estimated. The CO2 emission of the plume emitted from the active crater was estimated on the basis of the SO2 crater output and C/S ratio, while CO2 discharged through diffuse soil emission was quantified on the basis of 419 measurements of CO2 fluxes from the soil of the whole island, performed by using the accumulation chamber method. The results indicate an overall output of ≅416 t day−1 of CO2 from the island. The main contribution to the total CO2 output comes from the summit area (396 t day−1), with 370 t/day from the active crater and 26 t day−1 from the Pizzo sopra La Fossa soil degassing area. The release of CO2 from peripheral areas is ≅20 t day−1 by soil degassing (Scari area mainly). The result of the soil degassing survey confirms the persistence of the highest CO2 degassing areas located on the North-East crater side and Scari area.
    Description: Published
    Description: 52-60
    Description: 2V. Dinamiche di unrest e scenari pre-eruttivi
    Description: 4V. Vulcani e ambiente
    Description: JCR Journal
    Description: restricted
    Keywords: CO2 flux ; CO2 output ; Stromboli Island ; SO2 flux ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 17
    Publication Date: 2021-06-21
    Description: Volcanic plume samples taken in 2008 and 2009 from the Halemàumàu eruption at Kīlauea provide new insights into Kīlauea's degassing behaviour. The Cl, F and S gas systematics are consistent with syn-eruptive East Rift Zone measurements suggesting that the new Halemàumàu activity is fed by a convecting magma reservoir shallower than the main summit storage area. Comparison with degassing models suggests that plume halogen and S composition is controlled by very shallow (〈3m depth) decompression degassing and progressive loss of volatiles at the surface. Compared to most other global volcanoes, Kīlauea's gases are depleted in Cl with respect to S. Similarly, our Br/S and I/S ratio measurements in Halemàumàu's plume are lower than those measured at arc volcanoes, consistent with contributions from the subducting slab accounting for a significant proportion of the heavier halogens in arc emissions. Analyses of Hg in Halemàumàu's plume were inconclusive but suggest a flux of at least 0.6kgday -1 from this new vent, predominantly (〉77%) as gaseous elemental mercury at the point of emission. Sulphate is an important aerosol component (modal particle diameter ∼0.44μm). Aerosol halide ion concentrations are low compared to other systems, consistent with the lower proportion of gaseous hydrogen halides. Plume concentrations of many metallic elements (Rb, Cs, Be, B, Cr, Ni, Cu, Mo, Cd, W, Re, Ge, As, In, Sn, Sb, Te, Tl, Pb, Mg, Sr, Sc, Ti, V, Mn, Fe, Co, Y, Zr, Hf, Ta, Al, P, Ga, Th, U, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Er, Tm) are elevated above background air. There is considerable variability in metal to SO 2 ratios but our ratios (generally at the lower end of the range previously measured at Kīlauea) support assertions that Kīlauea's emissions are metal-poor compared to other volcanic settings. Our aerosol Re and Cd measurements are complementary to degassing trends observed in Hawaiian rock suites although measured aerosol metal/S ratios are about an order of magnitude lower than those calculated from degassing trends determined from glass chemistry. Plume enrichment factors with respect to Hawaiian lavas are in broad agreement with those from previous studies allowing similar element classification schemes to be followed (i.e., lithophile elements having lower volatility and chalcophile elements having higher volatility). The proportion of metal associated with the largest particle size mode collected (〉2.5μm) and that bound to silicate is significantly higher for lithophiles than chalcophiles. Many metals show higher solubility in pH 7 buffer solution than deionised water suggesting that acidity is not the sole driver in terms of solubility. Nonetheless, many metals are largely water soluble when compared with the other sequential leachates suggesting that they are delivered to the environment in a bioavailable form. Preliminary analyses of environmental samples show that concentrations of metals are elevated in rainwater affected by the volcanic plume and even more so in fog. However, metal levels in grass samples showed no clear enrichment downwind of the active vents. © 2011 Elsevier Ltd.
    Description: Published
    Description: 292-323
    Description: 4V. Vulcani e ambiente
    Description: JCR Journal
    Description: restricted
    Keywords: acidity; aerosol; degassing; emission; halogen; isotopic ratio; lava; magma chamber; mercury (element); particle size; plume; solubility; trace metal; volcanic eruption; volcano ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 18
    Publication Date: 2021-06-07
    Description: The La Fossa cone of Vulcano Island (Aeolian Archipelago, Italy) is a closed conduit volcano. Today, Vulcano Island is characterized by sulfataric activity, with a large fumarolic field that is mainly located in the summit area. A scanning differential optical absorption spectroscopy instrument designed by the Optical Sensing Group of Chalmers University of Technology in Göteborg, Sweden, was installed in the framework of the European project "Network for Observation of Volcanic and Atmospheric Change", in March 2008. This study presents the first dataset of SO2 plume fluxes recorded for a closed volcanic system. Between 2008 and 2010, the SO2 fluxes recorded showed average values of 12 t.d—1 during the normal sulfataric activity of Vulcano Island, with one exceptional event of strong degassing that occurred between September and December, 2009, when the SO2 emissions reached up to 100 t.d—1.
    Description: Published
    Description: 301-308
    Description: 2V. Dinamiche di unrest e scenari pre-eruttivi
    Description: 4V. Vulcani e ambiente
    Description: 6A. Monitoraggio ambientale, sicurezza e territorio
    Description: JCR Journal
    Description: open
    Keywords: SO2 ; Differential optical absorption spectroscopy ; Vulcano Island ; Network for Observation of Volcanic and Atmospheric Change ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.02. Exploration geophysics::04.02.05. Downhole, radioactivity, remote sensing, and other methods ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 19
    Publication Date: 2021-06-14
    Description: Volcanic and geothermal systems emit endogenous gases by widespread degassing from soils, including CH4, a greenhouse gas twenty-five times as potent as CO2. Recently, it has been demonstrated that volcanic or geothermal soils are not only a source of methane, but are also sites of methanotrophic activity. Methanotrophs are able to consume 10–40 Tg of CH4 a−1 and to trap more than 50% of the methane degassing through the soils. We report on methane microbial oxidation in the geothermally most active site of Pantelleria (Italy), Favara Grande, whose total methane emission was previously estimated at about 2.5Mga−1 (t a−1). Laboratory incubation experiments with three top-soil samples from Favara Grande indicated methane consumption values of up to 59.2 nmol g−1 soil d.w. h−1. One of the three sites, FAV2, where the highest oxidation rate was detected, was further analysed on a vertical soil profile, the maximum methane consumption was measured in the topsoil layer, and values greater than 6.23 nmol g−1 h−1 were still detected up to a depth of 13 cm. The highest consumption rate was measured at 37 C, but a still detectable consumption at 80 C (〉1.25 nmol g−1 h−1) was recorded. The soil total DNA extracted from the three samples was probed by Polymerase Chain Reaction (PCR) using standard proteobacterial primers and newly designed verrucomicrobial primers, targeting the unique methane monooxygenase gene pmoA; the presence of methanotrophs was detected at sites FAV2 and FAV3, but not at FAV1, where harsher chemical–physical conditions and negligible methane oxidation were detected. The pmoA gene libraries from the most active site (FAV2) pointed to a high diversity of gammaproteobacterial methanotrophs, distantly related to Methylocaldum-Metylococcus genera, and the presence of the newly discovered acido-thermophilic Verrucomicrobia methanotrophs. Alphaproteobacteria of the genus Methylocystis were isolated from enrichment cultures under a methane-containing atmosphere at 37 C. The isolates grow at a pH range of 3.5 to 8 and temperatures of 18–45 C, and consume 160 nmol of CH4 h−1 mL−1 of culture. Soils from Favara Grande showed the largest diversity of methanotrophic bacteria detected until now in a geothermal soil. While methanotrophic Verrucomicrobia are reported as dominating highly acidic geothermal sites, our results suggest that slightly acidic soils, in high-enthalpy geothermal systems, host a more diverse group of both culturable and uncultivated methanotrophs.
    Description: Published
    Description: 5865–5875
    Description: 4V. Vulcani e ambiente
    Description: JCR Journal
    Description: open
    Keywords: geothermal soils ; methanotrophic activity ; Verrucomicrobia ; Alphaproteobacteria ; Gammaproteobacteria ; geothermal gases ; 01. Atmosphere::01.01. Atmosphere::01.01.02. Climate ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 20
    Publication Date: 2017-04-04
    Description: Volcanic emissions were studied at Mount Etna (Italy) by using moss-bags technique. Mosses were exposed around the volcano at different distances from the active vents to evaluate the impact of volcanic emissions in the atmosphere. Morphology and mineralogy of volcanic particulate intercepted by mosses were investigated using scanning electron microscopy (SEM) equipped with energy dispersive spectrometer (EDS). Particles emitted during passive degassing activity from the two active vents, Bocca Nuova and North East Crater (BNC and NEC), were identified as silicates, sulfates and halide compounds. In addition to volcanic particles, we found evidences also of geogenic, anthropogenic and marine spray input. The study has shown the robustness of this active biomonitoring technique to collect particles, very useful in active volcanic areas characterized by continuous degassing and often not easily accessible to apply conventional sampling techniques.
    Description: Published
    Description: 1456–1464
    Description: 4V. Vulcani e ambiente
    Description: JCR Journal
    Description: restricted
    Keywords: Volcanic aerosols ; Plume ; Passive degassing ; Sphagnum ; Sulphate ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 01. Atmosphere::01.01. Atmosphere::01.01.08. Instruments and techniques
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 21
    Publication Date: 2017-04-04
    Description: Active long-path differential optical absorption spectroscopy (LP-DOAS) has been an effective tool for measuring atmospheric trace gases for several decades. However, instruments were large, heavy and powerinefficient, making their application to remote environments extremely challenging. Recent developments in fibre-coupling telescope technology and the availability of ultraviolet light emitting diodes (UV-LEDS) have now allowed us to design and construct a lightweight, portable, low-power LP-DOAS instrument for use at remote locations and specifically for measuring degassing from active volcanic systems. The LP-DOAS was used to measure sulfur dioxide (SO2) emissions from La Fossa crater, Vulcano, Italy, where column densities of up to 1.2 1018 molec cm􀀀2 ( 500 ppmm) were detected along open paths of up to 400m in total length. The instrument’s SO2 detection limit was determined to be 2 1016 molec cm􀀀2 ( 8 ppmm), thereby making quantitative detection of even trace amounts of SO2 possible. The instrument is capable of measuring other volcanic volatile species as well. Though the spectral evaluation of the recorded data showed that chlorine monoxide (ClO) and carbon disulfide (CS2/ were both below the instrument’s detection limits during the experiment, the upper limits for the X/ SO2 ratio (XDClO, CS2/ could be derived, and yielded 2 10􀀀3 and 0.1, respectively. The robust design and versatility of the instrument make it a promising tool for monitoring of volcanic degassing and understanding processes in a range of volcanic systems.
    Description: Published
    Description: 355-367
    Description: 2V. Dinamiche di unrest e scenari pre-eruttivi
    Description: 3V. Dinamiche e scenari eruttivi
    Description: 4V. Vulcani e ambiente
    Description: 5V. Sorveglianza vulcanica ed emergenze
    Description: 6A. Monitoraggio ambientale, sicurezza e territorio
    Description: N/A or not JCR
    Description: open
    Keywords: LP-DOAS ; volcanic gas measurements ; Vulcano Island ; sulfur dioxide ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 01. Atmosphere::01.01. Atmosphere::01.01.08. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 22
    Publication Date: 2017-04-04
    Description: Here, we report the first continuous data of geochemical parameters acquired directly from the active summit crater of Vulcano. This approach provides a means to better investigate deep geochemical processes associated with the degassing system of Vulcano Island. In particular, we report on soil CO2 fluxes from the upper part of Vulcano, a closed-conduit volcano, from September 2007 to October 2010. Large variations in the soil CO2 and plume SO2 fluxes (order of magnitude), coinciding with other discontinuous geochemical parameters (CO2 concentrations in fumarole gas) and physical parameters (increase of shallow seismic activity and fumarole temperatures) have been recorded. The results from this work suggest new prospects for strengthening geochemical monitoring of volcanic activity and for improving the constraints in the construction of a “geochemical model”, this being a necessary condition to better understand the functioning of volcanic systems.
    Description: Published
    Description: 1859-1863
    Description: 2V. Dinamiche di unrest e scenari pre-eruttivi
    Description: 4V. Vulcani e ambiente
    Description: 5V. Sorveglianza vulcanica ed emergenze
    Description: 1R. Reti di monitoraggio e Osservazioni
    Description: JCR Journal
    Description: restricted
    Keywords: Vulcano Island ; Geochemical monitoring ; CO2 flux ; CO2 fumaroles ; SO2 flux ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 23
    Publication Date: 2017-04-04
    Description: No abstract
    Description: Published
    Description: 92-117
    Description: 4V. Vulcani e ambiente
    Description: restricted
    Keywords: geogenic gases ; gas hazard ; geomithology ; underworld ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: book chapter
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  • 24
    Publication Date: 2017-04-04
    Description: Volatile metal(loid)s are known to be emitted from volcanoes worldwide.We tested the suitability of active moss monitoring for tracking volatilemetal(loid)s released fromthe fumarolic field on Vulcano Island, Italy, and differentiated fumaroles from other sources of gaseous and particulate trace elements such as sea spray and soil.Metal(loid) accumulation on the mosses per day did depend neither on the state of the exposed moss (dead or living) nor exposure time (3, 6, or 9 weeks). After collection, mosses were digested with either HNO3/H2O2 or deionized water and analyzed by ICP-MS.While for most elements both extraction methods yielded similar concentrations, higher concentrations were observed e.g. for Pb in the stronger HNO3/H2O2 extracts, indicating the presence of particles, which were not digested and removed by filtration in deionized water extracts. Due to their ubiquitous detection in comparable concentrations at all 23 moss monitoring stations all over the island, Li, Mg and Sr were attributed to sea spray origin. Iron, Co, W, V, Pb, Cr, Mo, and Ba occurred predominantly at the crater, where the soil was not covered by vegetation, and thus likely represent soil-borne particulate transport. Arsenic, Sb, S, Se, Tl, Bi, and I showed a clear concentration maximum within the fumarolic field. Concentrations gradually decreased along a transect in wind direction fromthe fumaroles, which confirms their volcanic origin. Activemossmonitoring thus proved to be an inexpensive and easy-to-apply tool for investigations of volcanic metal(loid) emissions and distributions enabling differentiation of trapped elements by their source of origin.
    Description: Published
    Description: 30–39
    Description: 4V. Vulcani e ambiente
    Description: JCR Journal
    Description: restricted
    Keywords: La Fossa crater ; particle transport ; biomonitoring ; volatilization ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 25
    Publication Date: 2017-04-04
    Description: We investigated the structure and evolution of the 2010 Eyjafjallajökull volcanic cloud and its dispersal over Iceland and Europe integrating satellite multispectral images and numerical simulations. Data acquired by Medium Resolution Imaging Spectrometer (MERIS)and Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) have been analyzed to quantify the cloud extent and composition. The VOL-CALPUFF dispersal code was applied to reconstruct the transient and 3-D evolution of the cloud. Source parameters estimated on the base of available a posteriori volcanological data sets have been used. Quantitative comparisons between satellite retrievals and modeling results were performed for two selected instants of time during the first and third eruptive phases on a regional scale. Sensitivity of the model to initial volcanological conditions has been analyzed at continental scale. Several complex non intuitive features of cloud dynamics have been highlighted and strengths and limitations of the adopted methods identified. The main findings are: the level of quantitative agreement between satellite observations and numerical results depends on ash cloud composition (particle sizes and concentration) with better agreement for smaller particles and higher concentrations; the agreement between observations and modeling outcomes also depends on the temporal stability of volcanological conditions and the complexity of the meteorological wind field; the irregular dispersion of ash, as reconstructed from satellite data and numerical modeling, can be well explained by the different response of particle sizes to strong vertical wind-shear, and by resuspension processes acting at ground level; eruptive source conditions are the main source of uncertainty in modeling, especially during an ongoing crisis and at long-range scales.
    Description: Published
    Description: 4729–4747
    Description: 3V. Dinamiche e scenari eruttivi
    Description: JCR Journal
    Description: restricted
    Keywords: Volcanic ash cloud ; Satellite retrieval ; Numerical modelling ; Eyjafjallajokull ; Ash dispersal and deposition ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 26
    Publication Date: 2017-04-04
    Description: Active biomonitoring using moss-bags was applied to an active volcanic environment for the first time. Bioaccumulation originating from atmospheric deposition was evaluated by exposing mixtures of washed and air-dried mosses (Sphagnum species) at 24 sites on Mt. Etna volcano (Italy). Concentrations of major and a large suite of trace elements were analysed by inductively coupled mass and optical spectrometry (ICP-MS and ICP-OES) after total acid digestion. Of the 49 elements analysed those which closely reflect summit volcanic emissions were S, Tl, Bi, Se, Cd, As, Cu, B, Na, Fe, Al. Enrichment factors and cluster analysis allowed clear distinction between volcanogenic, geogenic and anthropogenic inputs that affect the local atmospheric deposition. This study demonstrates that active biomonitoring with moss-bags is a suitable and robust technique for implementing inexpensive monitoring in scarcely accessible and harsh volcanic environments, giving time-averaged quantitative results of the local exposure to volcanic emissions. This task is especially important in the study area because the summit area of Mt. Etna is visited by nearly one hundred thousand tourists each year who are exposed to potentially harmful volcanic emissions.
    Description: Published
    Description: 1447–1455
    Description: 4V. Vulcani e ambiente
    Description: JCR Journal
    Description: restricted
    Keywords: Volcanoes ; Bioaccumulators ; Enrichment factors ; Environmental impact ; Atmospheric deposition ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 01. Atmosphere::01.01. Atmosphere::01.01.08. Instruments and techniques
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 27
    Publication Date: 2021-06-14
    Description: Methane plays an important role in the Earth’s atmospheric chemistry and radiative balance being the most important greenhouse gas after carbon dioxide. It has recently been established that geogenic gases contribute significantly to the natural CH4 flux to the atmosphere (Etiope et al., 2008). Volcanic/geothermal areas contribute to this flux, being the site of widespread diffuse degassing of endogenous gases (Chiodini et al., 2005). In such an environment soils are a source rather than a sink for atmospheric CH4 (Cardellini et al., 2003; Castaldi and Tedesco, 2005; D’Alessandro et al., 2009; 2011; 2013). Due to the fact that methane soil flux measurements are laboratory intensive, very few data have been collected until now in these areas. Preliminary studies (Etiope et al., 2007) estimated a total CH4 emission from European geothermal and volcanic systems in the range 4-16 kt a-1. This estimate was obtained indirectly from CO2 or H2O output data and from CO2/CH4 or H2O/CH4 values measured in the main gaseous manifestations. Such methods, although acceptable to obtain order-of-magnitude estimates, completely disregard possible methanotrophic activity within the soil. At the global scale, microbial oxidation in soils contributes for about 3-9% to the total removal of methane from the atmosphere. But the importance of methanotrophic organisms is even larger because they oxidise the greatest part of the methane produced in the soil and in the subsoil before its emission to the atmosphere. Environmental conditions in the soils of volcanic/geothermal areas (i.e. low oxygen content, high temperature and proton activity, etc.) have been considered inadequate for methanotrophic microrganisms. But recently, it has been demonstrated that methanotrophic consumption in soils occurs also under such harsh conditions due to the presence of acidophilic and thermophilic Verrucomicrobia. These organisms were found in Italy at the Solfatara di Pozzuoli (Pol et al., 2007), in New Zealand at Hell’s Gate (Dunfield et al., 2007) and in Kamchatka, Russia (Islam et al., 2008). Both the Italian and the Hellenic territories are geodynamically very active with many active volcanic and geothermal areas. Here we report on methane flux measurements made at Pantelleria (Italy) and at Sousaki and Nisyros (Greece). The total methane output of these three systems is about 10, 19 and 1 t a-1, respectively (D’Alessandro et al., 2009; 2011; 2013). The total emissions obtained from methane flux measurements are up to one order of magnitude lower than those obtained through indirect estimations. Clues of methanotrophic activity within the soils of these areas can be found in the CH4/CO2 ratio of the flux measurements which is always lower than that of the respective fumarolic manifestations, indicating a loss of CH4 during the travel of the gases towards earth’s surface. Furthermore laboratory methane consumption experiments made on soils collected at Pantelleria and Sousaki revealed, for most samples, CH4 consumption rates up to 9.50 µg h-1 and 0.52 µg h-1 respectively for each gram of soil (dry weight). Only few soil samples displayed no methane consumption activity. Finally, microbiological and molecular investigations allowed us to identify the presence of methanotrophic bacteria belonging to the Verrucomicrobia and to the Alpha- and Gamma-Proteobacteria in the soils of the geothermal area of Favara Grande at Pantelleria. While the presence of the former was not unexpected due to the fact that they include acidophilic and thermophilic organisms that were previously found in other geothermal environments, the latter are generally considered not adapted to live in harsh geothermal environments. Their presence in the soils of Pantelleria could be explained by the fact that these soils do not have extremely low pH values (〉5). Indeed thermotollerant methanotrophic Gamma-proteobacteria, have been previously found in the sediments of thermal springs in Kamchatka (Kizilova et al., 2012). Such species could find their niches in the shallowest part of the soils of Favara Grande were the temperatures are not so high and they thrive on the abundant upraising hydrothermal methane.
    Description: Published
    Description: Patras, Greece
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: open
    Keywords: soil methane fluxes ; methanotrophic activity ; geothermal areas ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Oral presentation
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  • 28
    Publication Date: 2013-09-15
    Description: Methane plays an important role in the Earth’s atmospheric chemistry and radiative balance being the most important greenhouse gas after carbon dioxide. It is released to the atmosphere by a wide number of sources, both natural and anthropogenic, with the latter being twice as large as the former. It has recently been established that significant amounts of geological methane, produced within the Earth’s crust, are currently released naturally into the atmosphere. Active or recent volcanic-geothermal areas represent one of these sources of geological methane. Due to the fact that methane flux measurements are laboratory intensive, very few data have been collected until now and the contribution of this source has been often indirectly estimated. Both the Italian and the Hellenic territories are geodynamically very active with many volcanic and geothermal areas. Here we report on methane flux measurements made at Pantelleria (Italy), Sousaki and Nisyros (Greece). The total outputs of these three systems are about 10, 19 and 2 t a-1 respectively. These figures are up to one order of magnitude lower than those obtained through indirect estimations. At the global scale, microbial oxidation in soils contributes to the total removal of methane from the atmosphere. Environmental conditions in the soils of volcanic/geothermal areas (i.e. low pH, high temperature, etc.) have been considered inadequate for methanotrophic microrganisms. But recently, it has been demonstrated that methanotrophic consumption in soils occurs also under such harsh conditions due to the presence of thermo-acidophilic Verrucomicrobia. Here we present the results of laboratory incubation experiments on soil samples collected at the main exhalative areas that highlighted methanotrophic activity also at Pantelleria and Sousaki. Soil metagenomic DNA was extracted from some of the Pantelleria samples and analysed using Temporal Temperature Gradient Electrophoresis (TTGE) of the amplified Bacterial 16S rRNA gene in order to evaluate the total bacterial diversity. Soil DNA amplification with primers targeting Proteobacterial and Verrucomicrobial methane monooxygenase genes (pmmo) revealed the presence of methanotrophs affiliated to both phyla up to a depth of 11 cm and a temperature of 80°C. The diversity of proteobacterial methanotrophs was investigated by creating a clone library of the amplified methane mono-oxygenase encoding gene, pmmoA. The clone sequences are close to those of uncultured type I methanotrophic proteobacteria. An attempt to isolate methanotrophs was carried out on soils from Pantelleria, sampled at different depths, by enrichment cultures on a mineral medium in a methane-enriched atmosphere. No isolates were obtained from enrichments carried out at 65°C while incubation at 37°C allowed to isolate a few methanothropic strains that were identified as Methylocystis spp.
    Description: Published
    Description: Kagoshima, Japan
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: open
    Keywords: soil methane fluxes ; methane output ; methanotrophic activity ; geothermal systems ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Oral presentation
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  • 29
    Publication Date: 2017-04-04
    Description: Emissions of volcanoes and their depositions do have an immediate impact on their surrounding environment. In the present study, emissions and depositions of the active volcanic and geothermal system Vulcano (Italy) were investigated by active moss biomonitoring (Fig. 1) in the spring of 2012. Sphagnum moss bags were exposed for periods of 3 days, 3, 6 and 9 weeks. Soil and rainwater samples as well as meteorological data were also collected. After exposure, mosses were oven-dried, grinded and each sample was extracted either in deionized water or HNO3 (with H2O2). Extraction solutions were analyzed by ICP-MS for total concentrations of Li, Mg, Sr, Ba, Cr, Mn, S, Fe, Co, Cu, Zn, Mo, W, Tl, As, Sb, Bi, I, and Se. Soil and rain water samples were analyzed for the same trace elements. For elements such as As and Tl, deionized water extracts showed comparable concentrations to HNO3 extracts, indicating either the absence of particles or the presence of water-soluble particles. Elements such as Pb, Ba, Se and Sr were only dissolved to about 10 % or less in deionized water, indicating a significant share of water-insoluble particle formation. Distribution patterns of emissions and depositions over the whole island of Vulcano allowed classifying all investigated elements into four groups based on their origin (Fig. 2). Lithium was found ubiquitously on the island thus likely is of either marine or geogenic origin (group a in Fig. 2). The elements Mg, Fe, Sr, Mn, Zn, Co, and W were found predominantly on the crater where bare soil was present, and were grouped as “soilborne elements” (group b). These elements are characterized by deposition close to their source of origin. Elements with higher concentrations at the fumarolic field were grouped according to their transport characteristics. The elements I, Se, Tl, Bi, Sb, As, and S were considered as true volatiles (group c) being found also further away from the fumarolic field than Pb, Cr, Mo, and Ba which were interpreted to be predominantly emitted as particles (group d). Moss-bag biomonitoring proved to be an effective tool for the study of emission and deposition processes in active volcanic areas which also allows a classification of elements accumulated on the moss by their origin and distribution patterns.
    Description: Published
    Description: Patras, Greece
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: open
    Keywords: Moss-bags ; trace elements ; biomonitoring ; volcanic emissions ; 01. Atmosphere::01.01. Atmosphere::01.01.03. Pollution ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Oral presentation
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  • 30
    Publication Date: 2017-04-04
    Description: About 120 rainwater samples were collected through a network of five bulk collectors in the area of the Louros basin (Epirus, Greece) during the wet season from October 2008 to August 2009. They were analysed for their isotopic (δD and δ18O) and chemical (H+, Na+, K+, Mg2+, Ca2+, NH4 +, F−, Cl−, Br−, NO3 −, SO4 2 −) composition. A local meteoric water line (δD‰ = 5.80 ± 0.02 δ18O‰ + 0.02 ± 0.12) and a local isotopic lapse rate (−0.18 δ18O‰/100 m) were obtained considering the volume-weighted means of the five sampling sites. These results agree well with those obtained in nearby areas. The chemical composition of the samples allows to identify an almost entirely marine origin for chloride and sodium with decreasing deposition values at increasing distance from the coast. Nitrate and ammonium are almost completely of anthropogenic origin, calcium and potassium are overwhelmingly geogenic, sulphate has a prevailingly anthropogenic origin with a significant marine contribution and magnesium has a mixedmarine and soil dust origin. Finally, as for most of the Mediterranean area, rainwater acidity is buffered by the dissolution of the abundant geogenic carbonate aerosol.
    Description: Published
    Description: 399-410
    Description: 4.4. Scenari e mitigazione del rischio ambientale
    Description: JCR Journal
    Description: restricted
    Keywords: Precipitation ; Neutralization ; Stable isotopes ; Chemical composition ; Bulk deposition ; 01. Atmosphere::01.01. Atmosphere::01.01.02. Climate ; 01. Atmosphere::01.01. Atmosphere::01.01.03. Pollution ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 02. Cryosphere::02.03. Ice cores::02.03.06. Precipitation ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 31
    Publication Date: 2017-04-03
    Description: Il sistema CUMAS (Cabled Underwater Module for Acquisition of Seismological data) è un prodotto tecnologico-scientifico complesso nato con il Progetto V4 [Iannaccone et al., 2008] allo scopo di monitorare l’area vulcanica dei Campi Flegrei (fenomeno del bradisismo). Si tratta di un modulo sottomarino cablato e connesso a una boa galleggiante (meda elastica). Il sistema è in grado di acquisire e trasmettere alla sala di monitoraggio dell’OV, in continuo e in tempo reale, sia i segnali sismologici sia quelli di interesse geofisico ed oceanografico (maree, correnti marine, segnali acustici subacquei, parametri funzionali di varia natura). Il sistema è in grado di ricevere comandi da remoto per variare diversi parametri di acquisizione e di monitorare un cospicuo numero di variabili di funzionamento. Il sistema si avvale del supporto di una boa galleggiante attrezzata. La boa è installata a largo del golfo di Pozzuoli (Napoli) a circa 3 km dalla costa. Il modulo sottomarino, collegato via cavo alla parte fuori acqua della boa, è installato sul fondale marino a una profondità di circa 100 metri.
    Description: Submitted
    Description: 82-85
    Description: 1.1. TTC - Monitoraggio sismico del territorio nazionale
    Description: 1.3. TTC - Sorveglianza geodetica delle aree vulcaniche attive
    Description: 1.4. TTC - Sorveglianza sismologica delle aree vulcaniche attive
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 1.8. Osservazioni di geofisica ambientale
    Description: 2.5. Laboratorio per lo sviluppo di sistemi di rilevamento sottomarini
    Description: 5.2. TTC - Banche dati di sismologia strumentale
    Description: N/A or not JCR
    Description: open
    Keywords: Monitoraggio sismico; sistemi sottomarini; boa; meda elastica ; 01. Atmosphere::01.01. Atmosphere::01.01.99. General or miscellaneous ; 01. Atmosphere::01.01. Atmosphere::01.01.01. Composition and Structure ; 01. Atmosphere::01.01. Atmosphere::01.01.02. Climate ; 01. Atmosphere::01.01. Atmosphere::01.01.03. Pollution ; 01. Atmosphere::01.01. Atmosphere::01.01.04. Processes and Dynamics ; 01. Atmosphere::01.01. Atmosphere::01.01.05. Radiation ; 01. Atmosphere::01.01. Atmosphere::01.01.06. Thermodynamics ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 01. Atmosphere::01.01. Atmosphere::01.01.08. Instruments and techniques ; 01. Atmosphere::01.02. Ionosphere::01.02.99. General or miscellaneous ; 01. Atmosphere::01.02. Ionosphere::01.02.01. Ion chemistry and composition ; 01. Atmosphere::01.02. Ionosphere::01.02.02. Dynamics ; 01. Atmosphere::01.02. Ionosphere::01.02.03. Forecasts ; 01. Atmosphere::01.02. Ionosphere::01.02.04. Plasma Physics ; 01. Atmosphere::01.02. Ionosphere::01.02.05. Wave propagation ; 01. Atmosphere::01.02. Ionosphere::01.02.06. Instruments and techniques ; 01. Atmosphere::01.02. Ionosphere::01.02.07. Scintillations ; 01. Atmosphere::01.03. Magnetosphere::01.03.99. General or miscellaneous ; 01. Atmosphere::01.03. Magnetosphere::01.03.01. Interplanetary physics ; 01. Atmosphere::01.03. Magnetosphere::01.03.02. Magnetic storms ; 01. Atmosphere::01.03. Magnetosphere::01.03.03. Magnetospheric physics ; 01. Atmosphere::01.03. Magnetosphere::01.03.04. Structure and dynamics ; 01. Atmosphere::01.03. Magnetosphere::01.03.05. Solar variability and solar wind ; 01. Atmosphere::01.03. Magnetosphere::01.03.06. Instruments and techniques ; 02. Cryosphere::02.01. Permafrost::02.01.99. General or miscellaneous ; 02. Cryosphere::02.01. Permafrost::02.01.01. Active layer ; 02. Cryosphere::02.01. Permafrost::02.01.02. Cryobiology ; 02. Cryosphere::02.01. Permafrost::02.01.03. Cryosol ; 02. Cryosphere::02.01. Permafrost::02.01.04. Periglacial processes ; 02. Cryosphere::02.01. Permafrost::02.01.05. Seasonally frozen ground ; 02. Cryosphere::02.01. Permafrost::02.01.06. Thermokarst ; 02. Cryosphere::02.01. Permafrost::02.01.07. Tundra ; 02. Cryosphere::02.01. Permafrost::02.01.08. Instruments and techniques ; 02. Cryosphere::02.02. Glaciers::02.02.99. General or miscellaneous ; 02. Cryosphere::02.02. Glaciers::02.02.01. Avalanches ; 02. Cryosphere::02.02. Glaciers::02.02.02. Cryosphere/atmosphere Interaction ; 02. Cryosphere::02.02. Glaciers::02.02.03. Geomorphology ; 02. Cryosphere::02.02. Glaciers::02.02.04. Ice ; 02. Cryosphere::02.02. Glaciers::02.02.05. Ice dynamics ; 02. Cryosphere::02.02. Glaciers::02.02.06. Mass balance ; 02. Cryosphere::02.02. Glaciers::02.02.07. Ocean/ice interaction ; 02. Cryosphere::02.02. Glaciers::02.02.08. Rock glaciers ; 02. Cryosphere::02.02. Glaciers::02.02.09. Snow ; 02. Cryosphere::02.02. Glaciers::02.02.10. Instruments and techniques ; 02. Cryosphere::02.03. Ice cores::02.03.99. General or miscellaneous ; 02. Cryosphere::02.03. Ice cores::02.03.01. Aerosols ; 02. Cryosphere::02.03. Ice cores::02.03.02. Atmospheric Chemistry ; 02. Cryosphere::02.03. Ice cores::02.03.03. Climate Indicators ; 02. Cryosphere::02.03. Ice cores::02.03.04. Ice Core Air Bubbles ; 02. Cryosphere::02.03. Ice cores::02.03.05. Paleoclimate ; 02. Cryosphere::02.03. Ice cores::02.03.06. Precipitation ; 02. Cryosphere::02.03. Ice cores::02.03.07. Teleconnection ; 02. Cryosphere::02.03. Ice cores::02.03.08. Temperature ; 02. Cryosphere::02.03. Ice cores::02.03.09. Instruments and techniques ; 02. Cryosphere::02.04. Sea ice::02.04.99. General or miscellaneous ; 02. Cryosphere::02.04. Sea ice::02.04.01. Atmosphere/sea ice/ocean interaction ; 02. Cryosphere::02.04. Sea ice::02.04.02. Leads ; 02. Cryosphere::02.04. Sea ice::02.04.03. Polynas ; 02. Cryosphere::02.04. Sea ice::02.04.04. Instruments and techniques ; 03. Hydrosphere::03.01. General::03.01.99. General or miscellaneous ; 03. Hydrosphere::03.01. General::03.01.01. Analytical and numerical modeling ; 03. Hydrosphere::03.01. General::03.01.02. Equatorial and regional oceanography ; 03. Hydrosphere::03.01. General::03.01.03. Global climate models ; 03. Hydrosphere::03.01. General::03.01.04. Ocean data assimilation and reanalysis ; 03. Hydrosphere::03.01. General::03.01.05. Operational oceanography ; 03. Hydrosphere::03.01. General::03.01.06. Paleoceanography and paleoclimatology ; 03. Hydrosphere::03.01. General::03.01.07. Physical and biogeochemical interactions ; 03. Hydrosphere::03.01. General::03.01.08. Instruments and techniques ; 03. Hydrosphere::03.02. Hydrology::03.02.99. General or miscellaneous ; 03. Hydrosphere::03.02. Hydrology::03.02.01. Channel networks ; 03. Hydrosphere::03.02. Hydrology::03.02.02. Hydrological processes: interaction, transport, dynamics ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring ; 03. Hydrosphere::03.02. Hydrology::03.02.05. Models and Forecasts ; 03. Hydrosphere::03.02. Hydrology::03.02.06. Water resources ; 03. Hydrosphere::03.02. Hydrology::03.02.07. Instruments and techniques ; 03. Hydrosphere::03.03. Physical::03.03.99. General or miscellaneous ; 03. Hydrosphere::03.03. Physical::03.03.01. Air/water/earth interactions ; 03. Hydrosphere::03.03. Physical::03.03.02. General circulation ; 03. Hydrosphere::03.03. Physical::03.03.03. Interannual-to-decadal ocean variability ; 03. Hydrosphere::03.03. Physical::03.03.04. Upper ocean and mixed layer processes ; 03. Hydrosphere::03.03. Physical::03.03.05. Instruments and techniques ; 03. Hydrosphere::03.04. Chemical and biological::03.04.99. General or miscellaneous ; 03. Hydrosphere::03.04. Chemical and biological::03.04.01. Biogeochemical cycles ; 03. Hydrosphere::03.04. Chemical and biological::03.04.02. Carbon cycling ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.04. Ecosystems ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 03. Hydrosphere::03.04. Chemical and biological::03.04.07. Radioactivity and isotopes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.08. Instruments and techniques ; 04. Solid Earth::04.01. Earth Interior::04.01.99. General or miscellaneous ; 04. Solid Earth::04.01. Earth Interior::04.01.01. Composition and state ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes ; 04. Solid Earth::04.01. Earth Interior::04.01.03. Mantle and Core dynamics ; 04. Solid Earth::04.01. Earth Interior::04.01.04. Mineral physics and properties of rocks ; 04. Solid Earth::04.01. Earth Interior::04.01.05. Rheology ; 04. Solid Earth::04.02. Exploration geophysics::04.02.99. General or miscellaneous ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration ; 04. Solid Earth::04.02. Exploration geophysics::04.02.02. Gravity methods ; 04. Solid Earth::04.02. Exploration geophysics::04.02.03. Heat flow ; 04. Solid Earth::04.02. Exploration geophysics::04.02.04. Magnetic and electrical methods ; 04. Solid Earth::04.02. Exploration geophysics::04.02.05. Downhole, radioactivity, remote sensing, and other methods ; 04. Solid Earth::04.02. Exploration geophysics::04.02.06. Seismic methods ; 04. Solid Earth::04.02. Exploration geophysics::04.02.07. Instruments and techniques ; 04. Solid Earth::04.03. Geodesy::04.03.99. General or miscellaneous ; 04. Solid Earth::04.03. Geodesy::04.03.01. Crustal deformations ; 04. Solid Earth::04.03. Geodesy::04.03.02. Earth rotation ; 04. Solid Earth::04.03. Geodesy::04.03.03. Gravity and isostasy ; 04. Solid Earth::04.03. Geodesy::04.03.04. Gravity anomalies ; 04. Solid Earth::04.03. Geodesy::04.03.05. Gravity variations ; 04. Solid Earth::04.03. Geodesy::04.03.06. Measurements and monitoring ; 04. Solid Earth::04.03. Geodesy::04.03.07. Satellite geodesy ; 04. Solid Earth::04.03. Geodesy::04.03.08. Theory and Models ; 04. Solid Earth::04.03. Geodesy::04.03.09. Instruments and techniques ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.01. Earthquake geology and paleoseismology ; 04. Solid Earth::04.04. Geology::04.04.02. Geochronology ; 04. Solid Earth::04.04. Geology::04.04.03. Geomorphology ; 04. Solid Earth::04.04. Geology::04.04.04. Marine geology ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology ; 04. Solid Earth::04.04. Geology::04.04.06. Rheology, friction, and structure of fault zones ; 04. Solid Earth::04.04. Geology::04.04.07. Rock geochemistry ; 04. Solid Earth::04.04. Geology::04.04.08. Sediments: dating, processes, transport ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.04. Geology::04.04.10. Stratigraphy ; 04. Solid Earth::04.04. Geology::04.04.11. Instruments and techniques ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.05. Geomagnetism::04.05.99. General or miscellaneous ; 04. Solid Earth::04.05. Geomagnetism::04.05.01. Dynamo theory ; 04. Solid Earth::04.05. Geomagnetism::04.05.02. Geomagnetic field variations and reversals ; 04. Solid Earth::04.05. Geomagnetism::04.05.03. Global and regional models ; 04. Solid Earth::04.05. Geomagnetism::04.05.04. Magnetic anomalies ; 04. Solid Earth::04.05. Geomagnetism::04.05.05. Main geomagnetic field ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism ; 04. Solid Earth::04.05. Geomagnetism::04.05.07. Rock magnetism ; 04. Solid Earth::04.05. Geomagnetism::04.05.08. Instruments and techniques ; 04. Solid Earth::04.05. Geomagnetism::04.05.09. Environmental magnetism ; 04. Solid Earth::04.06. Seismology::04.06.99. General or miscellaneous ; 04. Solid Earth::04.06. Seismology::04.06.01. Earthquake faults: properties and evolution ; 04. Solid Earth::04.06. Seismology::04.06.02. Earthquake interactions and probability ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics ; 04. Solid Earth::04.06. Seismology::04.06.04. Ground motion ; 04. Solid Earth::04.06. Seismology::04.06.05. Historical seismology ; 04. Solid Earth::04.06. Seismology::04.06.06. Surveys, measurements, and monitoring ; 04. Solid Earth::04.06. Seismology::04.06.07. Tomography and anisotropy ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 04. Solid Earth::04.06. Seismology::04.06.09. Waves and wave analysis ; 04. Solid Earth::04.06. Seismology::04.06.10. Instruments and techniques ; 04. Solid Earth::04.06. Seismology::04.06.11. Seismic risk ; 04. Solid Earth::04.07. Tectonophysics::04.07.99. General or miscellaneous ; 04. Solid Earth::04.07. Tectonophysics::04.07.01. Continents ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.03. Heat generation and transport ; 04. Solid Earth::04.07. Tectonophysics::04.07.04. Plate boundaries, motion, and tectonics ; 04. Solid Earth::04.07. Tectonophysics::04.07.05. Stress ; 04. Solid Earth::04.07. Tectonophysics::04.07.06. Subduction related processes ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.07. Tectonophysics::04.07.08. Volcanic arcs ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.02. Experimental volcanism ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.04. Thermodynamics ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.01. Computational geophysics::05.01.99. General or miscellaneous ; 05. General::05.01. Computational geophysics::05.01.01. Data processing ; 05. General::05.01. Computational geophysics::05.01.02. Cellular automata, fuzzy logic, genetic alghoritms, neural networks ; 05. General::05.01. Computational geophysics::05.01.03. Inverse methods ; 05. General::05.01. Computational geophysics::05.01.04. Statistical analysis ; 05. General::05.01. Computational geophysics::05.01.05. Algorithms and implementation ; 05. General::05.02. Data dissemination::05.02.99. General or miscellaneous ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.02. Data dissemination::05.02.02. Seismological data ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions ; 05. General::05.02. Data dissemination::05.02.04. Hydrogeological data ; 05. General::05.02. Data dissemination::05.02.05. Collections ; 05. General::05.03. Educational, History of Science, Public Issues::05.03.99. General or miscellaneous ; 05. General::05.04. Instrumentation and techniques of general interest::05.04.99. General or miscellaneous ; 05. General::05.05. Mathematical geophysics::05.05.99. General or miscellaneous ; 05. General::05.06. Methods::05.06.99. General or miscellaneous ; 05. General::05.07. Space and Planetary sciences::05.07.99. General or miscellaneous ; 05. General::05.07. Space and Planetary sciences::05.07.01. Solar-terrestrial interaction ; 05. General::05.07. Space and Planetary sciences::05.07.02. Space weather ; 05. General::05.08. Risk::05.08.99. General or miscellaneous ; 05. General::05.08. Risk::05.08.01. Environmental risk ; 05. General::05.08. Risk::05.08.02. Hydrogeological risk ; 05. General::05.09. Miscellaneous::05.09.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: manuscript
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  • 32
    Publication Date: 2017-04-04
    Description: no abstract
    Description: Published
    Description: 2351–2354
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: trace elements ; mud volcanoes ; Environmental impact of volcanic activity ; Etna ; 01. Atmosphere::01.01. Atmosphere::01.01.03. Pollution ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 33
    Publication Date: 2017-04-04
    Description: The Geochemical Monitoring System II (GMSII)prototype was designed, assembled, tested and installed at the Acqua Difesa test site, near Belpasso (Catania).
    Description: Published
    Description: 273-306
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: JCR Journal
    Description: restricted
    Keywords: Geochemical Monitoring System ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 34
    Publication Date: 2017-04-04
    Description: Passive samplers were used to measure the atmospheric concentrations of SO2 naturally emitted at three volcanoes in Italy (Etna, Vulcano and Stromboli) and of H2S naturally emitted at three volcanic/geothermal areas in Greece (Milos, Santorini and Nisyros). The measured concentrations and dispersion patterns varied with the strength of the source (open conduits or fumaroles), the meteorological conditions and the area topography. At Etna, Vulcano and Stromboli, SO2 concentrations reach values that are dangerous to people affected by bronchial asthma or lung diseases (〉1000 μg m−3). H2S values measured at Nisyros also exceed the limit considered safe for the same group of people (〉3000 μg m−3). The data obtained using passive samplers represent time-averaged values over periods from a few days up to 1 month, and hence concentrations probably reached much higher peak values that were potentially also dangerous to healthy people. The present study provides evidence of a peculiar volcanic risk associated with tourist exploitation of active volcanic areas. This risk is particularly high at Mt. Etna, where the elderly and people in less-than-perfect health can easily reach areas with dangerous SO2 concentrations via a cableway and off-road vehicles
    Description: Published
    Description: 1-13
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: Sulphur dioxide ; Hydrogen sulphide ; Volcanic risks ; Gas hazard ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 35
    Publication Date: 2017-04-04
    Description: A model to describe the cloud dispersion of gas denser than air is presented here. The dispersion of heavy gas is basically governed by the gravity but, when the density contrast (gas vs air) is not important the dispersion is controlled by the wind and atmospheric turbulence (so-called “passive dispersion”). DisGas is a model for dense gases which are dispersed under passive conditions, based on the full solution of the advection-diffusion equations for the gas concentration (Sankaranarayanan et al., 1998). The wind field can be assumed with a horizontally uniform profile calculated in accord to the Monin-Obukhov similarity theory or it can be estimated by the so-called DIAGNO, a Diagnostic Wind Model (DWM) developed by the US Environmental Protection Agency, the latter option requiring topographic data, average wind and atmospheric stability information within the computational domain. The model is able to forecast gas dispersion over large and complex terrain. Following the study of Costa et al., (2005), we present here an application of DisGas on the gas dispersion from the crater of Solfatara (Campi Flegrei) which releases a large quantity of CO2 into the surrounding densely-inhabited areas. For the simulated cases, the soil CO2 flow rate was assumed to be about 800 ton/day, such as the average of twelve different surveys carried out in the period 1998 to 2008 (Chiodini et al., 2010). Local atmospheric dynamics (3-components of the wind, friction velocity, Monin-Obukhov length) were derived by a two-year period of observations with micrometeorological technique inside the Solfatara crater. Our main finding showed that the urban area of Naples is affected by the CO2 buildup above the normal air CO2 content for this “natural” contribution, particularly in the no windy nocturnal situation. Estimated values show the absence of any risk to the population safety at the present emission rate but suggest that volcanic CO2 contributes towards deteriorating and warming the urban air of Naples. DisGas model is able to simulate the dispersion of a heavy warm gas accounting for obstacles, topographic effects, variation of atmospheric conditions and wind direction. So, a possible application is the cloud dispersion of pollutant and/or greenhouse gases emitted by industrial chimney over urban or suburban environmental.
    Description: Unpublished
    Description: Torino
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: open
    Keywords: Carbon dioxide air concentration ; volcanic plume ; Campi Flegrei ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Oral presentation
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  • 36
    Publication Date: 2017-04-04
    Description: The identification and characterisation of high-frequency climatic changes during the Holocene requires natural archives with precise and accurate chronological control, which is usually difficult to achieve using only 14C chronologies. The presence of time-spaced tephra beds in Quaternary Mediterranean successions represents an additional, independent tool for dating and correlating different sedimentary archives. These tephra layers are potentially useful for resolving long-standing issues in paleoclimatology and can help towards correlating terrestrial and marine paleoclimate archives. Known major tephras of regional extent derive from central and southern Italy, the Hellenic Arc, and from Anatolia. A striking feature of major Holocene tephra deposition events in the Mediterranean is that they are clustered rather than randomly distributed in time. Several tephra layers occurred at the time of the S1 sapropel formation between c. 8.4 and 9.0 ka BP (Mercato, Gabellotto-Fiumebianco/E1, Cappadocia) and other important tephra layers (Avellino, Agnano Monte Spina, ‘Khabur’ and Santorini/Thera) occurred during the second and third millennia BC, marking an important and complex phase of environmental changes during the mid- to late-Holocene climatic transition. There is great potential in using cryptotephra to overlap geographically Italian volcanic ashes with those originating from the Aegean and Anatolia, in order to connect regional tephrochronologies between the central and eastern Mediterranean.
    Description: Published
    Description: 33-52
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: 3.7. Dinamica del clima e dell'oceano
    Description: JCR Journal
    Description: reserved
    Keywords: Holocene ; Mediterranean basin ; paleoclimate ; tephrochronology ; tephrostratigraphy ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 03. Hydrosphere::03.01. General::03.01.06. Paleoceanography and paleoclimatology ; 04. Solid Earth::04.04. Geology::04.04.02. Geochronology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 37
    Publication Date: 2017-04-04
    Description: Volcanic emissions are considered one of the major natural sources of several trace metals (e.g. As, Cd, Cu, Pb, and Zn) to the atmosphere [Nriagu, 1989], and the geochemical cycles of these elements have to be considered strongly influenced by volcanic input. However, the accurate estimation of the global volcanic emissions of volatile trace metals into the atmosphere is still affected by a high level of uncertainty. The latter depends on the large variability in the emission of the different volcanoes, and on their changing stage of activity. Moreover, only few of the potential sources in the world have been directly measured [Hinkley et al. 1999]. Atmospheric deposition processes (wet and dry) are the pathways through which volcanic emissions return to the ground (soils, plants, aquifers), resulting in both harmful and beneficial effects [Baxter et al. 1982; Aiuppa et al. 2000; Brusca et al. 2001; Delmelle, 2003; Bellomo et al. 2007; Martin et al. 2009; Floor et al. 2011; Calabrese et al. 2011]. In the first part of this study we present the results of a literature review on trace metals emissions from active volcanoes around the world. In the second part, we present new data on the fluxes of the trace metals from Etna (Italy) and four active volcanoes in the world: Turrialba (Costarica), Nyiragongo (DRC), Mutnovsky and Gorely (Kamchatka). We found 27 publications (the first dating back to the 70’s), 13 of which relate to the Etna and the other include some of the world’s most active volcanoes: Mt. St. Helens, Erebus, Merapi, White Island, Kilauea, Popocatepetl, Galeras, Indonesian arc, Satasuma and Masaya. The review shows that currently there are very few data available, and that the most studied volcano is Mt. Etna. Using these data, we defined a range of fluxes for As, Ba, Bi, Cd, Cu, Fe, Mn, Pb, Se, V and Zn (Figure 1). To obtain new data we sampled particulate filters at the five above mentioned volcanoes. Filters were mineralized (acid digestion) and analyzed by ICP-MS. Sulphur to trace element ratios were related to sulphur fluxes to indirectly estimate trace elements fluxes. Etna confirms to be one of the greatest point sources in the world. The Nyiragongo results to be also a significant source of metals to the atmosphere, especially considering its persistent state of degassing from the lava lake. Also Turrialba and Gorely have high emission rates of trace metals considering the global range. Only Mutnovsky Volcano show values which are sometimes lower than the range obtained from the review, consistent with the fact that it is mainly a fumarolic field. This work highlights the need to expand the current dataset including many other active volcanoes for a better constraint of global trace metal fluxes from active volcanoes.
    Description: Published
    Description: Nicolosi (Catania)
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: open
    Keywords: Volcanic degassing ; trace elements ; environmental impact of volcanic activity ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Oral presentation
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  • 38
    Publication Date: 2017-04-04
    Description: Volcanic emissions represent one of the most relevant natural sources of trace elements to the troposphere, both during and between eruptions. Due to their potential toxicity they may have important environmental impacts from the local to the global scale. Mount Etna, the largest European volcano and one of the most active volcano in the world, covers an area of about 1250 km2 and reaches an altitude of about 3340 m. It has been persistently active during historical time, with frequent paroxysmal episodes separated by passive degassing periods. Atmospheric precipitation was collected approximately every two weeks, from April 2006 to December 2007, using a network of five rain gauges, located at various altitudes on the upper flanks around the summit craters of Etna Volcano. The collected samples were analysed for major (Ca, Mg, K, Na, F, SO4, Cl, NO3) and a large suite of trace elements (Ag, Al, As, Au, B, Ba, Be, Bi, Cd, Co, Cr, Cs, Cu, Fe, Hg, La, Li, Mn, Mo, Ni, Pb, Rb, Si, Sb, Sc, Se, Sr, Th, Ti, Tl, U, V, Zn) by using different techniques (IC, SPEC, ICP-MS and CV-AFS). The monitoring of atmospheric deposition gave the opportunity to occasionally sample volcanic fresh ashes emitted by the volcano during the paroxysmal events. This was possible because the network of five rain gauges were equipped with a filter-system to block the coarse material. In this way, more than twenty events of ashfall were collected. Unfortunately, only half of these samples were suitable for a complete chemical analysis, because of the small amount of sample. In order to obtain elemental chemical composition of ashes, powdered samples were analysed by a combination of methods, including X-ray Fluorescence Spectroscopy (XRF), total digestion followed by Inductively Coupled Plasma Emission Mass Spectrometry (ICP-MS), Instrumental Neutron Activation Analysis (INAA), and infrared detection (IR). The chemistry of rainwater reveals that most of the investigated elements have higher concentrations close to the emission vent of the volcano, confirming the prevailing volcanic contribution. Rainwater composition clearly reflects the volcanic plume input. Ash-normalised rainwater composition indicates a contrasting behaviour between volatile elements, which are highly-enriched in rainwater, and refractory elements, which have low rainwater/ash concentration ratios. The degree of interaction between collected ash and rainwater was variable, depending on several factors: (i) the length of the period in which tephra was present in the sampler (the ash fall may have occurred any day from the first to the last day of the rain collecting period); (ii) the amount of rainwater fallen on the collectors after the ash-fall event, and its acidity; (iii) the granulometry of the ash samples that was widely variable (from few centimetres to micrometric particles) increasing the interaction with decreasing dimensions of the grains; (iv) the distance of collector with respect to the craters. In order to investigate the role of volcanic ash on the evolution of the rainwater chemistry, absolute concentrations of rain and ash were plotted in binary plot diagrams (Figure 1). Each diagram corresponds to a single event, and pH and TDS of the solution collected is reported. The diagonal bars in the diagrams represent the rain/ash ratios (1:1 and 1:10000). The results confirm that sulphate and halide salt aerosols are adsorbed onto ash particles, and their rate of dissolution in rainwater depends on solubility. Moreover, rapid chemical weathering of the silicate glass by volcanic acid (SO2, HCl and HF) can also explain the enrichment of several refractory elements (Na, K, Ca, Mg, Si, Al, Fe, Ti, Sc). Our observations highlight how explosive activity can increase enormously the deposition rate of several chemical elements, up to several km away from the emission vents.
    Description: Published
    Description: Nicolosi (Catania)
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: open
    Keywords: volcanic ash ; trace elements ; environmental impact of volcanic activity ; rainwater chemistry ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Extended abstract
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  • 39
    Publication Date: 2017-04-03
    Description: Total CO2 output from fumaroles, soil gas, bubbling gas discharges and water dissolved gases discharged from the island, was estimated for Vulcano island, Italy. The CO2 emission from fumaroles from the La Fossa summit crater was estimated from the SO2 crater output, while CO2 discharged through diffuse soil emission was quantified on the basis of 730 measurements of CO2 fluxes from the soil of the island, performed by using the accumulation chamber method. The results indicate an overall output of ≅500 t/day of CO2 from the island. The main contribution to the total CO2 output comes from the summit area of the La Fossa cone (453 t/day), with 362 t/day from crater fumaroles and 91 t/day from crater soil degassing. The release of CO2 from peripheral areas is ≅20 t/day by soil degassing (Palizzi and Istmo areas mainly), an amount comparable to both the contribution of water dissolved CO2 (6 t/day), as well as to seawater bubbling CO2 (4 t/day measured in the Istmo area). Presented data (September 2007) refer to a period of moderate solphataric activity, when the fumaroles temperature were 450°C and gas/water molar ratio of fumaroles was up to 0.16. The calculated total CO2 emission allows the estimation of the mass release and related thermal energy from the volcanic-hydrothermal system.
    Description: Published
    Description: Q02012
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: restricted
    Keywords: CO2 flux, SO2 flux, Vulcano island ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 40
    Publication Date: 2021-12-06
    Description: Marked changes in human dispersal and development during the Middle to Upper Paleolithic transition have been attributed to massive volcanic eruption and/or severe climatic deterioration. We test this concept using records of volcanic ash layers of the Campanian Ignimbrite eruption dated to ca. 40,000 y ago (40 ka B.P.). The distribution of the Campanian Ignimbrite has been enhanced by the discovery of cryptotephra deposits (volcanic ash layers that are not visible to the naked eye) in archaeological cave sequences. They enable us to synchronize archaeological and paleoclimatic records through the period of transition from Neanderthal to the earliest anatomically modern human populations in Europe. Our results con!rm that the combined effects of a major volcanic eruption and severe climatic cooling failed to have lasting impacts on Neanderthals or early modern humans in Europe. We infer that modern humans proved a greater competitive threat to indigenous populations than natural disasters.
    Description: funded by the United Kingdom Natural Environment Research Council through a Response of Humans to Abrupt Environmental Transitions (RESET) Consortium Grant
    Description: Published
    Description: 13532–13537
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: JCR Journal
    Description: restricted
    Keywords: Neanderthals ; modern humans ; cryptotephra deposits ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 41
    Publication Date: 2023-10-18
    Description: Volcanic ash clouds detection and retrieval represent a key issue for aviation safety due to the harming effects on aircraft. A lesson learned from the recent Eyjafjallajokull eruption is the need to obtain accurate and reliable retrievals on a real time basis. In this work we have developed a fast and accurate Neural Network (NN) approach to detect and retrieve volcanic ash cloud properties from the Moderate Resolution Imaging Spectroradiometer (MODIS) data in the Thermal InfraRed (TIR) spectral range. Some measurements collected during the 2001, 2002 and 2006 Mt. Etna volcano eruptions have been considered as test cases. The ash detection and retrievals obtained from the Brightness Temperature Difference (BTD) algorithm are used as training for the NN procedure that consists in two separate steps: ash detection and ash mass retrieval. The ash detection is reduced to a classification problem by identifying two classes: “ashy” and “non-ashy” pixels in the MODIS images. Then the ash mass is estimated by means of the NN, replicating the BTD-based model performances. A segmentation procedure has also been tested to remove the false ash pixels detection induced by the presence of high meteorological clouds. The segmentation procedure shows a clear advantage in terms of classification accuracy: the main drawback is the loss of information on ash clouds distal part. The results obtained are very encouraging; indeed the ash detection accuracy is greater than 90 %, while a mean RMSE equal to 0.365 t km−2 has been obtained for the ash mass retrieval. Moreover, the NN quickness in results delivering makes the procedure extremely attractive in all the cases when the rapid response time of the system is a mandatory requirement.
    Description: Published
    Description: 2619–2631
    Description: 1.10. TTC - Telerilevamento
    Description: JCR Journal
    Description: open
    Keywords: neural network ; volcanic ash ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 42
    Publication Date: 2012-02-03
    Description: The Kasatochi 2008 eruption was detected by several infrared satellite sensors including Moderate Resolution Imaging Spectroradiometer (MODIS), Advanced Very High Resolution Radiometer (AVHRR), and Atmospheric Infrared Sounder (AIRS). In this work a comparison between the volcanic cloud SO2 and ash retrievals derived from these instruments has been undertaken. The SO2 retrieval is carried out by using both the 7.3 and 8.7 micron absorption features while ash retrieval exploits the 10–12 micron atmospheric window. A radiative transfer scheme is also used to correct the volcanic ash effect on the 8.7 micron SO2 signature. As test cases, three near‐contemporary images for each sensor, collected during the first days of the eruption, have been analyzed. The results show that the volcanic SO2 and ash are simultaneously present and generally collocated. The MODIS and AVHRR total ash mass loadings are in good agreement and estimated to be about 0.5 Tg, while the AIRS retrievals are slightly lower and equal to about 0.3 Tg. The AIRS and MODIS 7.3 micron SO2 mass loadings are also in good agreement and vary between 0.3 and 1.2 Tg, while the MODIS ash corrected 8.7 micron SO2 masses vary between 0.4 and 2.7 Tg. The mass increase with time confirms the continuous SO2 injection in the atmosphere after the main explosive episodes. Moreover the difference between the 7.3 and 8.7 micron retrievals suggests a vertical stratification of the volcanic cloud. The results also confirm the importance of the ash correction; the corrected 8.7 micron SO2 total masses are less than 30–40% of the uncorrected values.
    Description: Published
    Description: D00L21
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 1.10. TTC - Telerilevamento
    Description: JCR Journal
    Description: reserved
    Keywords: Remote sensing ; ash retrieval ; SO2 retrieval ; multispectral satellite instruments ; MODIS ; AVHRR ; AIRS ; hyperspectral satellite instruments ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 01. Atmosphere::01.01. Atmosphere::01.01.08. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 43
    Publication Date: 2017-04-04
    Description: Volcano monitoring aims at the recognition of changes in instrumentally observable parameters before hazardous activity in order to alert governmental authorities. Among these parameters seismic data in general and volcanic tremor in particular play a key role. Recent major explosive eruptions such as Okmok (Aleutians) and Chaitén (Chile) in 2008 and numerous smaller events at Mt Etna (Italy), have shown that the period of premonitory seismic activity can be short (only a few hours), which entails the necessity of effective automatic data processing near on-line. Here we present a synoptic pattern classification analysis based on Self Organizing Maps and Fuzzy Cluster Analysis which is applied to volcanic tremor data recorded during a series of paroxysmal eruptive episodes and a flank eruption at Etna in 2007–2008. In total, eight episodes were analyzed; in six of these significant changes in the dynamic regime of the volcano were detected up to 9 h prior to the onset of eruptive activity, and long before changes in volcanic tremor amplitude and spectral content became evident in classical analysis. In two cases, the state transition was b1 h before the onset of eruptive activity, which we interpret as evidence for very rapid magma ascent through an open conduit. We further detected twenty failed paroxysms, that is episodes of volcanic unrest that did not culminate in eruptive activity, between March and April 2007. As the application of the software for this synoptic pattern classification is straightforward and requires only moderate computational resources, it was possible to exploit it in an on-line application, which was tested and now is in use at the Istituto Nazionale di Geofisica e Vulcanologia in Catania for the monitoring of Etna. We believe that the pattern classification presented here may become a powerful addition to the repertoire of volcano monitoring tools and early warning techniques worldwide.
    Description: Published
    Description: 1-17
    Description: 1.4. TTC - Sorveglianza sismologica delle aree vulcaniche attive
    Description: JCR Journal
    Description: restricted
    Keywords: volcanic tremor, volcano monitoring, pattern recognition, Self Organizing Maps. fuzzy clustering, Mt Etna ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 44
    Publication Date: 2017-04-04
    Description: The occurrence of particle aggregation has a dramatic effect on the transport and sedimentation of volcanic ash. The aggregation process is complex and can occur under different conditions and in multiple regions of the plume and in the ash cloud. In the companion paper, Costa et al. develop an aggregation model based on a fractal relationship to describe the rate particles are incorporated into ash aggregates. The model includes the effects of both magmatic and atmospheric water present in the volcanic cloud and demonstrates that the rate of aggregation depends on the characteristics of the initial particle size distribution. The aggregation model includes two parameters, the fractal exponent Df, which describes the efficiency of the aggregation process, and the aggregate settling velocity correction factor ye, which influences the distance at which distal mass deposition maxima form. Both parameters are adjusted using features of the observed deposits. Here this aggregation model is implemented in the FALL3D volcanic ash transport model and applied to the 18 May 1980 Mount St. Helens and the 17–18 September 1992 Crater Peak eruptions. For both eruptions, the optimized values for Df (2.96–3.00) and ye (0.27–0.33) indicate that the ash aggregates had a bulk density of 700–800 kg m−3. The model provides a higher degree of agreement than previous fully empirical aggregation models and successfully reproduces the depositional characteristics of the deposits investigated over a large range of scales, including the position and thickness of the secondary maxima.
    Description: Published
    Description: B09202
    Description: 4.3. TTC - Scenari di pericolosità vulcanica
    Description: JCR Journal
    Description: restricted
    Keywords: volcanic ash ; particle aggregation ; 01. Atmosphere::01.01. Atmosphere::01.01.04. Processes and Dynamics ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 05. General::05.01. Computational geophysics::05.01.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 45
    Publication Date: 2017-04-04
    Description: This paper presents the preliminary results of a biomonitoring study based on the use of moss bags exposed at 24 sites on Etna volcano. Sphagnum mosses were used to study bioaccumulation originating from atmospheric deposition, by measuring the tissue contents of major and a large suite of trace elements. Elements, such as Tl, Bi, As, Se, Cu and Cd, display high concentrations in the exposed samples close to the active vents. This study confirms the effectiveness of the moss bags technique also in active volcanic areas.
    Description: Published
    Description: Florence, Italy
    Description: 4.4. Scenari e mitigazione del rischio ambientale
    Description: open
    Keywords: Moss-bags ; Trace elements ; Mt. Etna ; 01. Atmosphere::01.01. Atmosphere::01.01.03. Pollution ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Extended abstract
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  • 46
    Publication Date: 2017-04-04
    Description: Biomonitoring may be defined as the use of organisms and biomaterials (biomonitors) to obtain informations on certain characteristics of a particular medium (atmosphere, hydrosphere etc.). In particular, mosses accumulate large amounts of trace metals, making them good bioaccumulators to estimate atmospheric pollution. The moss-bags technique, introduced in the early 1970’, has become very popular. Such active biomonitoring technique is particularly useful in highly polluted areas and has been extensively used in industrial and/or urban areas to examine deposition patterns and to recognize point sources of pollution. The main objective of this study, which represents the first application of the moss-bags technique in an active volcanic area, was to test its efficacy in such environment. Complementary objectives were: to determine the different behavior and the geographic dispersion of volcanogenic elements emitted from Mt. Etna; to check the usefulness of a simpler analytical techniques (leaching instead of mineralization of the moss samples). A mixture of Sphagnum species was picked in a clean area, treated in laboratory (washed, dried and packed) and exposed in field for 1 month. Sites were chosen considering the prevailing wind at Mt. Etna’s summit. Milled samples were analyses for major and trace elements concentrations, after microwave digestion (HNO3 + H2O2), by ICP-MS and ICP-OES techniques. The same elements were also analyzed after simple leaching with deionized water (1/50 weight ratio for 4 hours). Leaching solutions were also analyzed by IC for F, Cl and SO4. Analyses clearly showed the efficacy of the moss-bags technique also in this peculiar environment. Several elements were strongly enriched in the mosses exposed to the volcanic emissions. The highest enrichment was measured close to the summit crater, but evidences of metals bioaccumulation were also found in down wind sites, at several km from the volcanic source. The accumulation factor (exposed/unexposed moss) allowed us to distinguish a group of elements (Tl, Bi, Se, Cu, As, Cd, S), which are highly mobile in the high temperature volcanic environment. Also alkali metals showed a significant increase in their concentrations, probably because of their affinity for the halide species carried by the volcanic plume. Also the simple and cheap leaching technique gave important indications on the plume dispersion pattern, especially for highly volatile elements (F, Cl, S, Tl).
    Description: Published
    Description: Torino, Italia
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: open
    Keywords: biomonitoring ; moss-bags ; trace elements ; Etna ; Volcanic emissions ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.08. Risk::05.08.01. Environmental risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Poster session
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  • 47
    Publication Date: 2017-04-04
    Description: Active volcanoes are thought to be important contributors to the atmospheric mercury (Hg) budget, and this chemical element is one of the most harmful atmospheric pollutants, owing to its high toxicity and long residence time in ecosystems. There is, however, considerable uncertainty over the magnitude of the global volcanic Hg flux, since the existing data on volcanogenic Hg emissions are sparse and often ambiguous. In an attempt to extend the currently limited dataset on volcanogenic Hg emissions, we summarize the results of Hg flux measurements at seven active open-conduit volcanoes; Stromboli, Asama, Miyakejima, Montserrat, Ambrym, Yasur, and Nyiragongo.. Data from the domebuilding Soufriere Hills volcano are also reported. Using our determined mercury to SO2 mass ratios in tandem with the simultaneously-determined SO2 emission rates, we estimate that the 7 volcanoes have Hg emission rates ranging from 0.2 to 18 t yr-1 (corresponding to a total Hg flux of ~41 t·yr-1). Based on our dataset and previous work, we propose that a Hg/SO2 plume ratio ~10-5 is bestrepresentative of gas emissions from quiescent degassing volcanoes. Using this ratio, we infer a global volcanic Hg flux from persistent degassing of ~95 t·yr-1
    Description: Published
    Description: 497-510
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: JCR Journal
    Description: restricted
    Keywords: Volcanogenic mercury ; Mercury ; Volcanic plume ; Mercury flux ; Mercury inventories ; Atmospheric mercury ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 48
    Publication Date: 2017-04-04
    Description: We report here on the first hydrogen determinations in the volcanic gas plume of Mount Etna, in Italy, which we obtained during periodic field surveys on the volcano’s summit area with an upgraded MultiGAS. Using a specific (EZT3HYT) electrochemical sensor, we resolved H2 concentrations in the plume of 1–3 ppm above ambient (background) atmosphere and derived H2‐SO2 and H2‐H2O plume molar ratios of 0.002–0.044 (mean 0.013) and 0.0001–0.0042 (mean 0.0018), respectively. Taking the above H2‐SO2 ratios in combination with a time‐averaged SO2 flux of 1600 Gg yr−1, we evaluate that Etna contributes a time‐averaged H2 flux of ∼0.65 Gg yr−1, suggesting that the volcanogenic contribution to the global atmospheric H2 budget (70,000–100,000 Gg yr−1) is marginal. We also use our observed H2‐H2O ratios to propose that Etna’s passive plume composition is (at least partially) representative of a quenched (temperatures between 750°C and 950°C) equilibrium in the gas‐magma system, at redox conditions close to the nickel‐nickel oxide (NNO) mineral buffer. The positive dependence between H2‐SO2, H2‐H2O, and CO2‐SO2 ratios suggests that H2 is likely supplied (at least in part) by deeply rising CO2‐rich gas bubbles, fluxing through a CO2‐depleted shallow conduit magma.
    Description: Published
    Description: B10204
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: JCR Journal
    Description: restricted
    Keywords: Hydrogen ; Mount Etna ; Open-vent volcano ; plume ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 49
    Publication Date: 2017-04-04
    Description: Many volcanoes show a change in chemical composition of the gas phase prior to periods of eruptive activity. Fine‐grained tephra erupted from active vents and transported through volcanic plumes can adsorb, and therefore rapidly scavenge, volatile elements such as sulfur, halogens, and metal species in the form of soluble salts adhering to ash surfaces. Analysis of such water‐soluble surface materials is a suitable supplement for remote monitoring of volcanic gases at inaccessible volcanoes. In this work, ash samples of the 2004 to 2009 eruptive activity of Stromboli volcano were sampled, leached, and analyzed for major and trace elements. Data analysis and interpretation was focused on determining the relationship between chemical composition of water‐soluble components adhering to volcanic ash and the volcano’s activity state. First results show significant temporal variations in ash leachate compositions, reflecting changes in the eruptive style of the volcano. In particular, we reveal that ash leachates S/F and Mg/Na ratios showed marked increases prior to a large‐scale explosion on 15 March 2007.
    Description: Published
    Description: D17204
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: Leachate analyses of volcanic ashes ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects
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  • 50
    Publication Date: 2017-04-04
    Description: Methane soil flux measurements have been made in 38 sites at the geothermal system of Sousaki (Greece) with the closed chamber method. Fluxes range from –47.6 to 29,150 mg m-2 d-1 and the diffuse CH4 output of the system has been estimated at 19 t a-1. Contemporaneous CO2 flux measurements showed a moderate positive correlation between CO2 and CH4 fluxes. Comparison of the CO2/CH4 soil flux ratios with the CO2/CH4 ratio of the gases of the main gas manifestations provided evidence for methanotrophic activity within the soil. Laboratory CH4 consumption experiments confirmed the presence of methanotrophic microorganisms in soil samples collected at Sousaki. Consumption was generally in the range from –4.9 to –38.9 pmolCH4 h-1 g-1 but could sometimes reach extremely high values (–33,000 pmolCH4 h-1 g-1.). These results are consistent with recent studies on other geothermal systems that revealed the existence of thermoacidophilic bacteria exerting methanotrophic activity in hot, acid soils, thereby reducing methane emissions to the atmosphere.
    Description: Published
    Description: 97–107
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: reserved
    Keywords: Sousaki ; accumulation chamber ; soil degassing ; hydrothermal systems ; methane output ; methanotrophic activity ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
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  • 51
    Publication Date: 2017-04-04
    Description: Volcanoes are one of the major natural sources of several trace elements to the atmosphere: They contribute to atmospheric pollution by increasing the amount of reactive and greenhouse gases and aerosols. In particular, Mt. Etna is considered to be, on long-term average, the major global atmospheric point source of many environmental harmful compounds. Their emission occurs either through continuous passive degassing from open-conduit activity or through sporadic paroxysmal eruptive activity, in the form of gases, aerosols or particulate. For several months during the year (generally December-May), the summit of Mt. Etna is under a thick blanket of snow. This huge reservoir of frozen water, interacting with the volcanic plume, accumulates a great quantity of volcanogenic elements during the winter. Samples of snow were collected at different distances from summit craters along an 8 km radial transects, in the 2006 and 2007 winters. Each snow sample was analyzed for 37 elements in the laboratory using IC, ICP-OES and ICP-MS techniques. The impact of volcanic emissions is clearly detectable considering the opposite trends of pH and TDS (total dissolved solid) measured in snow samples with increasing distance from their “source”. The pH values range from 1.7 on the rim of the summit craters up to 7.6 at a distance of about 8 km, and TDS ranges from diluted samples (few mg/l) at distal sites, up to extremely concentrated samples (500 - 3500 mg/l) close to the emission vents. The acidity in precipitation around the volcano depends mainly on the concentrations of volcanogenic acid forming ions (SO2, HCl and HF), as well as on concentrations of mainly geogenic alkaline species, which may eventually neutralize the acidity. Regarding metals concentrations, there are orders of magnitude of difference between the different sites with decreasing values from the crater’s rim up to the farthest sites (5-8 km from craters). In particular three groups of elements were extremely enriched (many orders of magnitude higher) at the summit craters with respect to the distal samples: Halogens (Br, Cl, F, I) and S ascribable to volcanic gas contribution; Al, Fe and Ti deriving from magmatic silicate particulate; and elements such as Se, Cu, As, Bi, Cd, Tl, Pb and Hg which are highly mobile in the high temperature volcanic environment.
    Description: Published
    Description: Bari, Italy
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: open
    Keywords: Snow Chemistry ; Trace elements ; Etna ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 02. Cryosphere::02.02. Glaciers::02.02.09. Snow ; 02. Cryosphere::02.03. Ice cores::02.03.02. Atmospheric Chemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Oral presentation
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  • 52
    Publication Date: 2017-04-04
    Description: Volcanic and geothermal areas are one of the major natural sources of sulphur gases to the atmosphere. Hydrogen sulphide (H2S) is a toxic gas mainly associated to geothermal systems while sulphur dioxide (SO2) is released in huge quantities from volcanoes characterized by open conduit activity. Apart from being one of the most impressive geodynamic expressions, volcanoes are also an important tourist attraction. During the summer season the number of tourists visiting the crateric areas each day is on average many tens at Stromboli, hundreds at Vulcano, Santorini and Nisyros and thousands at Etna. Touristic exploitation of active volcanic areas cannot exempt from warranting a reasonable security to the visiting persons. But while many risks in these areas have been since long time considered, gas hazard, a very subtle risk, is often disregarded. The atmospheric concentrations and dispersion pattern of naturally emitted SO2 were measured at three volcanoes of southern Italy (Etna, Vulcano and Stromboli) while that of H2S at four volcanic/geothermal areas of Greece (Sousaki, Milos, Santorini and Nisyros). Measurements were made with a network of passive samplers positioned at about 1.5 m above the ground, which gave time-integrated values for periods from few days to 1 month. Samplers were placed in zones of the volcanoes with high tourist frequentation. Measured concentrations and dispersion pattern depend on the strength of the source (craters, fumaroles), meteorological conditions and geomorphology of the area. At Etna, Vulcano, Stromboli and Nisyros measured concentrations reach values that are absolutely dangerous to people affected by bronchial asthma or lung diseases. But considering that these are average values over periods from few days up to one month, concentrations could have reached much higher peak values dangerous also to healthy people. The present study evidences a peculiar volcanic risk connected to the touristic exploitation of volcanic areas. Such risk is particularly enhanced at Etna where elderly and not perfectly healthy people can easily reach, with cableway and off-road vehicles, areas with dangerous SO2 concentrations.
    Description: Published
    Description: Bari, Italy
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: open
    Keywords: sulphur gases ; passive samplers ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.08. Risk::05.08.01. Environmental risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Oral presentation
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  • 53
    Publication Date: 2017-04-04
    Description: Biomonitoring may be defined as the use of organisms and biomaterials (biomonitors) to obtain informations on certain characteristics of a particular medium (atmosphere, hydrosphere etc.). In particular, mosses accumulate large amounts of trace metals, making them good bioaccumulators to estimate atmospheric pollution. The moss-bags technique, introduced in the early 1970’, has become very popular. Such active biomonitoring technique is particularly useful in highly polluted areas and has been extensively used in industrial and/or urban areas to examine deposition patterns and to recognize point sources of pollution. The main objective of this study, which represents the first application of the moss-bags technique in an active volcanic area, was to test its efficacy in such environment. Complementary objectives were: to determine the different behaviour and the areal dispersion of volcanogenic elements emitted from Mt. Etna; to characterize the morphology and mineralogy of particles transported in the plume-system, basing on microscopy investigation. A mixture of Sphagnum species was picked in a clean area, treated in laboratory (rinsed, dried and packed) and exposed in field for 1 month. Sites were chosen considering the prevailing wind at Mt. Etna’s summit. Milled samples were analyses for major and trace elements concentrations, after microwave digestion (HNO3 + H2O2), by ICP-MS and ICP-OES techniques. Morphology and mineralogy of volcanic particulate were investigated by using a SEM with EDS. Analyses clearly showed the efficacy of the moss-bags technique also in this peculiar environment. Several elements were strongly enriched in the mosses exposed to the volcanic emissions. The highest enrichment was measured close to the summit crater, but evidences of metals bioaccumulation were also found in down wind sites, at several km from the volcanic source. The accumulation factor (exposed/unexposed moss) allowed us to distinguish a group of elements (Tl, Bi, Se, Cu, As, Cd, S), which are highly mobile in the high temperature volcanic environment. Also alkali metals showed a significant increase in their concentrations, probably because of their affinity for the halide species carried by the volcanic plume. Microscopic observations evidenced sulphate and halide crystals on particles trapped by the mosses. Mosses exposed at sites directly fumigated by the volcanic plume showed crystal growth also directly on the moss surface.
    Description: Published
    Description: Bari, Italy
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: open
    Keywords: biomonitoring ; moss-bags ; trace elements ; Etna ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.08. Risk::05.08.01. Environmental risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Poster session
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  • 54
    Publication Date: 2017-04-04
    Description: In this paper are shown the results obtained from Geometric High Precision Levelling survey performed at Ischia Island in June 2010. The measures have been carried out on the whole network of the island further expanded by increasing of the benchmarks and the establishment of new lines. The compensated height for each benchmark (Bm) are referred to Bm 1 located at Ischia harbour, were compared to those obtained in previous Levelling survey of 2003. The results show significant ground subsidence of different entities affecting various areas of the island. In addition, a further comparison with the measurements performed in 1987 confirms the existence of such differential movements characterised by subsidence velocity constant over time. At last, we found a good agreement between levelling and GPS velocities, calculated in time span 1997-2003.
    Description: Published
    Description: 1.3. TTC - Sorveglianza geodetica delle aree vulcaniche attive
    Description: N/A or not JCR
    Description: open
    Keywords: Leveling, Ischia Island, Epomeo ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 55
    Publication Date: 2017-04-04
    Description: This study reports on the first quantitative assessment of the geochemical cycling of volcanogenic elements, from their atmospheric release to their deposition back to the ground. Etna’s emissions and atmospheric depositions were characterised for more than 2 years, providing data on major and trace element abundance in both volcanic aerosols and bulk depositions. Volcanic aerosols were collected from 2004 to 2007, at the summit vents by conventional filtration techniques. Precipitation was collected, from 2006 to 2007, in five rain gauges, at various altitudes around the summit craters. Analytical results for volcanic aerosols showed that the dominant anions were S, Cl, and F, and that the most abundant metals were K, Ca, Mg, Al, Fe, and Ti (1.5–50 lg m 3). Minor and trace element concentrations ranged from about 0.001 to 1 lg m 3. From such analysis, we derived an aerosol mass flux ranging from 3000 to 8000 t a 1. Most analysed elements had higher concentrations close to the emission vent, confirming the prevailing volcanic contribution to bulk deposition. Calculated deposition rates were integrated over the whole Etna area, to provide a first estimate of the total deposition fluxes for several major and trace elements. These calculated deposition fluxes ranged from 20 to 80 t a 1 (Al, Fe, Si) to 0.01–0.1 t a 1 (Bi, Cs, Sc, Th, Tl, and U). Comparison between volcanic emissions and atmospheric deposition showed that the amount of trace elements scavenged from the plume in the surrounding of the volcano ranged from 0.1% to 1% for volatile elements such as As, Bi, Cd, Cs, Cu, Tl, and from 1% to 5% for refractory elements such as Al, Ba, Co, Fe, Ti, Th, U, and V. Consequently, more than 90% of volcanogenic trace elements were dispersed further away, and may cause a regional scale impact. Such a large difference between deposition and emission fluxes at Mt. Etna pointed to relatively high stability and long residence time of aerosols in the plume.
    Description: Published
    Description: 7401-7425
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: trace elements ; volcanic plume chemistry ; bulk deposition ; Etna ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 03. Hydrosphere::03.03. Physical::03.03.01. Air/water/earth interactions ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 56
    Publication Date: 2017-04-04
    Description: We report on the first detection of CO2 flux precursors of the till now unforecastable “major” explosions that intermittently occur at Strombolivolcano (Italy). An automated survey of the crater plume emissions in the period 2006–2010, during which 12 such explosions happened, demonstrated that these events are systematically preceded by a brief phase of increasing CO2/SO2 weight ratio (up to 〉40) and CO2 flux (〉1300 t d−1) with respect to the timeaveraged values of 3.7 and 500 t d−1 typical for standard Stromboli’s activity. These signals are best explained by the accumulation of CO2-rich gas at a discontinuity of the plumbing system (decreasing CO2 emission at the surface), followed by increasing gas leakage prior to the explosion. Our observations thus supports the recent model of Allard (2010) for a CO2-rich gas trigger of recurrent major explosions at Stromboli, and demonstrates the possibility to forecast these events in advance from geochemical precursors. These observations and conclusions have clear implications for monitoring strategies at other open-vent basaltic volcanoes worldwide.
    Description: Published
    Description: 135-142
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: N/A or not JCR
    Description: open
    Keywords: CO2 ; Stromboli ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 57
    Publication Date: 2017-04-04
    Description: We performed a quantitative hazard assessment to determine the potential impacts of volcanic tephra fall on human health and infrastructure in the vicinity of Mt. Etna (Italy). Using the numerical model VOL-CALPUFF, we explored the dynamics of long-lasting weak plume eruptions and their effects on the surrounding region. Input data are based on credible estimates of the main parameters characterising the expected events as derived from the historically observed and reconstructed explosive record of Mt. Etna. Monte Carlo techniques are used to capture the effects on estimates of finer ash concentration and total ground deposition due to volcanological uncertainties and meteorological variability. Numerical simulations compute the likelihoods of experiencing critical 10-μm volcanic particle (VP10) concentrations in ambient air and tephra ground deposition at various populated locations around the volcano, including the city of Catania, and at key infrastructure, such as airports and main roads. Results show how the towns and infrastructure on the east side of the volcano are significantly more exposed to ash-related hazards than those on the west side, in accordance with wind statistics. Simulation outcomes also illustrate how, at the sites analysed, the amount of deposited particulate matter is proportional to the intensity (i.e. mass flow rate) of the event whereas predicted values of VP10 concentrations are significantly larger for smaller events due to the reduced dispersal of low altitude plumes. The use of a simple re-mobilization model highlights the fact that particle re-suspension needs to be considered in the estimation of VP10 values. Our findings can be used to inform civil protection agencies responsible for mitigating tephra fall impacts to human health, road transport and aviation safety.
    Description: Published
    Description: 85-96
    Description: 3.6. Fisica del vulcanismo
    Description: 4.3. TTC - Scenari di pericolosità vulcanica
    Description: JCR Journal
    Description: reserved
    Keywords: volcanic ash ; hazard assessment ; VP10 exposure ; numerical simulation ; VOL-CALPUFF ; Mt. Etna ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.01. Computational geophysics::05.01.04. Statistical analysis
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 58
    Publication Date: 2017-04-04
    Description: Because the large emission of gas and solid particles into the atmosphere, the volcanic eruptions represent one of the most important source of natural pollution. Among different gases (mainly H2O, CO2, SO2 and HCl), the volcanic clouds contain a mix of silicate-bearing ash particles in the size range 0.1μm to mm size or larger. Interest in determining the properties, movement and extent of volcanic ash clouds is an important scientific, economic, and public safety issue because the effects on environment, public health and aviation. In particular the problem to track in real time and forecast the volcanic cloud transport is the key task for the aviation safety problems and for the political decision making. Several encounters of en-route aircrafts with volcanic ash clouds have demonstrated the harming effects of ash particles on modern aircrafts (loss of power, failure of high-bypass turbine engines, abrasion of turbine blades, windscreens, fuselage, and Pitot static tubes). Alongside these considerations also the economical problem induced by an airport closure must be taken into account. Both security and economical requirements make essential a great effort to realize robust and affordable ash cloud detection and trajectory forecasting, combining remote sensing and modeling. In this work a quantitative comparison between Moderate Resolution Imaging Spectroradiometer (MODIS) retrievals of volcanic ash cloud mass and Aerosol Optical Depth (AOD) with the FALL3D ash dispersal model has been performed. MODIS, aboard the NASA-Terra and NASA-Aqua polar satellites is a multispectral instrument with 36 spectral bands in the wavelength range from Visible (VIS) to Thermal InfraRed (TIR) and spatial resolution varying between 250 and 1000 m at nadir. The channels centered around 11 and 12 micron have been used for the ash retrievals through the Brightness Temperature Difference algorithm and MODTRAN simulations. FALL3D is a 3-D time-dependent Eulerian model for the transport and deposition of volcanic particles that outputs, among other variables, cloud column mass and AOD. In this work the Mt. Etna volcano 2002 eruptive event has been considered as test case. The results indicate a general good agreement between the mean AOT retrieved and the spatial ash dispersion in the different images, while the modeled FALL3D total mass retrieved result significantly overestimated.
    Description: Published
    Description: EGU General Assembly - Vienna Austria
    Description: open
    Keywords: ash retrieval ; MODIS ; FALL3D ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 59
    Publication Date: 2017-04-04
    Description: Satellite retrievals and transport models represents the key tools to monitor the volcanic clouds evolution. Because of the harming effects of fine ash particles on aircrafts, the real-time tracking and forecasting of volcanic clouds is key for aviation safety. Together with the security reasons also the economical consequences of a disruption of airports must be taken into account. The airport closures due to the recent Icelandic Eyjafjöll eruption caused millions of passengers to be stranded not only in Europe, but across the world. IATA (the International Air Transport Association) estimates that the worldwide airline industry has lost a total of about 2.5 billion of Euro during the disruption. Both security and economical issues require reliable and robust ash cloud retrievals and trajectory forecasting. The intercomparison between remote sensing and modeling is required to assure precise and reliable volcanic ash products. In this work we perform a quantitative comparison between Moderate Resolution Imaging Spectroradiometer (MODIS) retrievals of volcanic ash cloud mass and Aerosol Optical Depth (AOD) with the FALL3D ash dispersal model. MODIS, aboard the NASA-Terra and NASA-Aqua polar satellites, is a multispectral instrument with 36 spectral bands operating in the VIS-TIR spectral range and spatial resolution varying between 250 and 1000 m at nadir. The MODIS channels centered around 11 and 12 micron have been used for the ash retrievals through the Brightness Temperature Difference algorithm and MODTRAN simulations. FALL3D is a 3-D time-dependent Eulerian model for the transport and deposition of volcanic particles that outputs, among other variables, cloud column mass and AOD. Three MODIS images collected the October 28, 29 and 30 on Mt. Etna volcano during the 2002 eruption have been considered as test cases. The results show a general good agreement between the retrieved and the modeled volcanic clouds in the first 300 km from the vents. Even if the modeled volcanic cloud area is systematically wider than the retrieved area, the ash total mass is comparable and varies between 35 and 60 kt and between 20 and 42 kt for FALL3D and MODIS respectively. The mean AOD values are in good agreement and approximately equal to 0.8. When the whole volcanic clouds are considered the ash areas and the total ash masses, computed by FALL3D model are significantly greater than the same parameters retrieved from the MODIS data, while the mean AOD values remain in a very good agreement and equal to about 0.6. The volcanic cloud direction in its distal part is not coincident for the 29 and 30 October 2002 images due to the difference between the real and the modeled local wind fields. Finally the MODIS maps show regions of high mass and AOD due to volcanic puffs not modeled by FALL3D.
    Description: Published
    Description: San Francisco - USA
    Description: open
    Keywords: MODIS ; FALL3D ; ash retrieval ; volcanic risk ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 60
    Publication Date: 2017-04-03
    Description: Observations of volcanic degassing yield insights into the sub-surface magmatic processes which control volcanic activity during both quiescent and eruptive phases. By combining information on volcanic gas flux with constraints on original dissolved volatile contents the volume of degassing magma can be determined. Comparisons between the volume of degassing magma, erupted volume, and ground deformation allow mass balance calculations to be performed, providing insight into the shallow volcanic plumbing system dynamics. For these reasons there is great interest in improving the quality and frequency of volcanic gas flux measurements. Ultraviolet and infrared remote sensing techniques allow determination of SO2 column amounts within volcanic plumes. By calculating SO2 column amounts in a profile orthogonal to the plume-wind direction and multiplying the integrated SO2 cross section by the wind speed the SO2 emission rate can be retrieved. There are currently three main approaches for determining volcanic SO2 fluxes; (i) ground-based mini-DOAS systems, (ii) ground-based SO2 imaging cameras, and (iii) satellite-based infrared and ultraviolet imaging. Here we examine SO2 fluxes obtained by the Flux Automatic Measurement (FLAME) network of scanning mini-DOAS instruments installed at Mt. Etna and by the MODIS instrument aboard the NASA EOS satellite AQUA during the 2006 eruption of Mt. Etna, Sicily, Italy. Mt. Etna produced a highly variable eruptive activity from the South-East crater, characterised by explosive sequences, which could be either ash-rich or ash-poor, lava effusion, partial flank collapse and periods of quiescence. We examined intraday variations in SO2 flux measured with FLAME and MODIS during both ash-rich and ash-poor explosive phases. In general, good agreement was found between the datasets. Of particular interest was the successful recalculation and validation of temporal variations in SO2 flux recorded in a single image from MODIS. By examining the temporal evolution of gas emissions our results provide insight in the eruption mechanism driving the explosive activity.
    Description: Unpublished
    Description: San Francisco, CA, U.S.A.
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: open
    Keywords: SO2 ; ash ; magmatic degassing ; Remote sensing ; DOAS ; MODIS ; Etna ; 01. Atmosphere::01.01. Atmosphere::01.01.05. Radiation ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Conference paper
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  • 61
    Publication Date: 2017-04-04
    Description: We develop a model to describe ash aggregates in a volcanic plume. The model is based on a solution of the classical Smoluchowski equation, obtained by introducing a similarity variable and a fractal relationship for the number of primary particles in an aggregate. The considered collision frequency function accounts for different mechanisms of aggregation, such as Brownian motion, ambient fluid shear, and differential sedimentation. Although model formulation is general, here only sticking efficiency related to the presence of water is considered. However, the different binding effect of liquid water and ice is discerned. The proposed approach represents a first compromise between the full description of the aggregation process and the need to decrease the computational time necessary for solving the full Smoluchowski equation. We also perform a parametric study on the main model parameters and estimate coagulation kernels and timescales of the aggregation process under simplified conditions of interest in volcanology. Further analyses and applications to real eruptions are presented in the companion paper by Folch et al.
    Description: Published
    Description: B09201
    Description: 3.6. Fisica del vulcanismo
    Description: 4.3. TTC - Scenari di pericolosità vulcanica
    Description: JCR Journal
    Description: reserved
    Keywords: volcanic ; Theoretical formulation ; 01. Atmosphere::01.01. Atmosphere::01.01.04. Processes and Dynamics ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 62
    Publication Date: 2021-12-02
    Description: Earth orbiting satellites provide an excellent means for monitoring and measuring emissions from volcanic eruptions. The recent eruption of Eyjafjallajökull in Iceland on 14 April, 2010 and the subsequent movement of the ash clouds were tracked using a variety of satellite instruments as they moved over Europe. Data from the rapid sampling (every 15 minutes) SEVIRI on Meteosat Second Generation were especially useful during this event as the thermal channels between 10–12 micron could be used to detect the ash signal and perform quantitative ash retrievals of mass loadings, optical depths and effective particle size. Higher-spatial resolution ( 1 km2) information from the MODIS sensors on NASA’s Terra and Aqua platforms were also analysed to determine ash microphysics and also to provide ash cloud top height. High-spectral resolution data from the IASI and AIRS sensors showed that initially quantities of ice, potentially with ash cores, were present, and that multi-species retrievals could be performed by exploiting the spectral content of the data. Vertically resolved ash layers were detected using the Caliop lidar on board the Calipso platform. Ash was clearly detected over Europe using the infra-red sensors with mass loadings typically in the range 0.1–5 gm-2, which for layers of 500–1000 m thickness, suggests ash concentrations in the range 0.1–10 mg m-3, and therefore represent a potential hazard to aviation.Little SO2 was detected at the start of the eruption, although both OMI and AIRS detected upper-level SO2 on 15 April. By late April and early May, 0.1–0.3 Tg (SO2) could be detected using these sensors. The wealth of satellite data available, some in near real-time, and the ability of infrared and ultra-violet sensors to detect volcanic ash and SO2 are emphasised in this presentation. The ash/aviation problem can be addressed using remote sensing measurements, validated with ground-based and air-borne, and combined with dispersion modelling. The volcanic ash threat to aviation can be ameliorated by utilising these space-based resources.
    Description: Published
    Description: Vienna - Austria
    Description: open
    Keywords: ash retrieval ; volcanic risk ; MODIS ; SEVIRI ; AIRS ; IASI ; CALIOP ; OMI ; SO2 retrieval ; Eyjafjallajokull ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 63
    Publication Date: 2023-10-18
    Description: The lesson learned from the recent Icelandic Eyjafjallajokull volcanic eruption is the need to obtain accurate near real time retrievals in order to sample the phenomenon evolution. In particular, because of the harming effects of fine volcanic ash particles on aircrafts, the real time tracking of volcanic clouds is a key issue for aviation safety. The current mostly utilized procedure for the ash retrievals is based on the Brightness Temperature Difference (BTD) algorithm, using the 11 and 12 micron channels measurements and radiative transfer model computation. This latter requires many input parameters and is time consuming, preventing the utilization during the crisis phases. In this work a fast and accurate Neural Network (NN) approach has been developed to detect and retrieve volcanic ash cloud properties using multispectral IR measurements. The exploited data come from the Moderate Resolution Imaging Spectroradiometer (MODIS) acquired over Mt. Etna volcano during the 2001, 2002 and 2006 eruptive events. The procedure consists in two separate steps that uses the three MODIS channels 28, 31 and 32: the detection and the ash retrievals. The detection is reduced to a classification problem. In this context several classes can be individuated, such as free sea surface, meteorological clouds, and ash plume. To maintain the solution of the problem as easy as possible we have simplified the scenario identifying only two classes on the MODIS images: 'ash' and 'no ash' pixels. This approach is coherent with the philosophy of this work in which the time passed to obtain the result is a stringent factor. For the ash mass retrieval, the trained network replicates the model. In fact, in order to have a network able to learn a behavior and to represent it through a functional approximation, it is necessary to provide appropriate information by an ensemble of examples. These latter can be obtained from a model if a direct measure is not available. In this work the results obtained with the BTD procedure have been considered. The results obtained from the entire procedure are encouraging, indeed the confusion matrix for the test set has an accuracy greater than 90%. Moreover the ash mass retrieval shows a good agreement with that achieved by BTD procedure.
    Description: Published
    Description: San Francisco - USA
    Description: open
    Keywords: ash retrievals ; MODIS ; neural networks ; volcanic risk ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 64
    Publication Date: 2017-04-04
    Description: Methane plays an important role in the Earth’s atmospheric chemistry and radiative balance being the second most important greenhouse gas after carbon dioxide. Methane is released to the atmosphere by a wide number of sources, both natural and anthropogenic, with the latter being twice as large as the former (IPCC, 2007). It has recently been established that significant amounts of geological methane, produced within the Earth’s crust, are currently released naturally into the atmosphere (Etiope, 2004). Active or recent volcanic/geothermal areas represent one of these sources of geological methane. But due to the fact that methane flux measurements are laboratory intensive, very few data have been collected until now and the contribution of this source has been generally indirectly estimated (Etiope et al., 2007). The Greek territory is geodynamically very active and has many volcanic and geothermal areas. Here we report on methane flux measurements made at two volcanic/geothermal systems along the South Aegean volcanic arc: Sousaki and Nisyros. The former is an extinct volcanic area of Plio-Pleistocene age hosting nowadays a low enthalpy geothermal field. The latter is a currently quiescent active volcanic system with strong fumarolic activity due to the presence of a high enthalpy geothermal system. Both systems have gas manifestations that emit significant amounts of hydrothermal methane and display important diffuse carbon dioxide emissions from the soils. New data on methane isotopic composition and higher hydrocarbon contents point to an abiogenic origin of the hydrothermal methane in the studied systems. Measured methane flux values range from –48 to 29,000 (38 sites) and from –20 to 1100 mg/mˆ2/d (35 sites) at Sousaki and Nisyros respectively. At Sousaki measurement sites covered almost all the degassing area and the diffuse methane output can be estimated in about 20 t/a from a surface of about 10,000 mˆ2. At Nisyros measurements covered the Stephanos and Kaminakia areas, which represent only a part of the entire degassing area. The two areas show very different methane degassing pattern with latter showing much higher flux values. Methane output can be estimated in about 0.25 t/a from an area of about 30,000 mˆ2 at Stephanos and about 1 t/a from an area of about 20,000 mˆ2 at Kaminakia. The total output from the entire geothermal system of Nisyros probably should not exceed 2 t/a.
    Description: Published
    Description: Vienna, Austria
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: open
    Keywords: methane output ; diffuse degassing ; volcanic/hydrothermal systems ; Greece ; 01. Atmosphere::01.01. Atmosphere::01.01.03. Pollution ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.08. Risk::05.08.01. Environmental risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 65
    Publication Date: 2017-04-04
    Description: A biomonitoring survey, above tree line level, using two endemic species (Senecio aethnensis and Rumex aethnensis) was performed on Mt. Etna, in order to evaluate the dispersion and the impact of volcanic atmospheric emissions. Samples of leaves were collected in summer 2008 from 30 sites in the upper part of the volcano (1500- 3000 m a.s.l). Acid digestion of samples was carried out with a microwave oven, and 44 elements were analyzed by using plasma spectrometry (ICP-MS and ICP-OES). The highest concentrations of all investigated elements were found in the samples collected closest to the degassing craters, and in the downwind sector, confirming that the eastern flank of Mt. Etna is the most impacted by volcanic emissions. Leaves collected along two radial transects from the active vents on the eastern flank, highlight that the levels of metals decrease one or two orders of magnitude with increasing distance from the source. This variability is higher for volatile elements (As, Bi, Cd, Cs, Pb, Sb, Tl) than for more refractory elements (Al, Ba, Sc, Si, Sr, Th, U). The two different species of plants do not show significant differences in the bioaccumulation of most of the analyzed elements, except for lanthanides, which are systematically enriched in Rumex leaves. The high concentrations of many toxic elements in the leaves allow us to consider these plants as highly tolerant species to the volcanic emissions, and suitable for biomonitoring researches in the Mt. Etna area.
    Description: Published
    Description: Vienna, Austria
    Description: 4.4. Scenari e mitigazione del rischio ambientale
    Description: open
    Keywords: Mt. Etna ; biomonitoring ; Trace elements ; 01. Atmosphere::01.01. Atmosphere::01.01.03. Pollution ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.08. Risk::05.08.01. Environmental risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Poster session
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  • 66
    Publication Date: 2017-04-04
    Description: Methane soil flux measurements have been made in 38 sites at the geothermal system of Sousaki (Greece) with the closed chamber method. Fluxes range from –47.6 to 29,150 mg m-2 d-1 and the diffuse CH4 output of the system has been estimated in 19 t/a. Contemporaneous CO2 flux measurements showed a fair positive correlation between CO2 and CH4 fluxes but the flux ratio evidenced methanotrophic activity within the soil. Laboratory CH4 consumption experiments confirmed the presence of methanotrophic microorganisms in soil samples collected at Sousaki. These results further confirm recent studies on other geothermal systems that revealed the existence of thermophilic and acidophilic bacteria exerting methanotrophic activity also in hot and acid soils thereby reducing methane emissions to the atmosphere.
    Description: Published
    Description: Thessaloniki, Greece
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: open
    Keywords: Sousaki ; accumulation chamber ; soil degassing ; hydrothermal systems ; methane output ; methanotrophic activity ; 01. Atmosphere::01.01. Atmosphere::01.01.05. Radiation ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Conference paper
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  • 67
    Publication Date: 2017-04-04
    Description: This thematic issue of Geofluids includes 11 papers representing the three main topics discussed in the 10th edition of the International Conference on Gas Geochemistry (ICGG-10): (i) gas in petroleum systems and seepage, (ii) gas in geothermal systems and volcanoes and (iii) gas, seismicity and geohazards. ICGG-10 was held in 2009 in Romania, a country extraordinarily rich in surface gas manifestations, that offers innumerable opportunities for innovative studies on gas geochemistry. We briefly describe the present knowledge on gases occurring both in petroliferous sedimentary basins and geothermal areas of Romania. The 11 contributions of this special issue, which include data from eight countries, are then summarised. Based on these papers and other works presented at the ICGG-10, we find that significant advances in analytical capabilities, data treating and interpretation have led to innovative insights into the origin, distribution and environmental impact of gases migrating to the Earth’s surface. It is increasingly clear, in particular, that gas geochemistry can be more effective for petroleum exploration, volcano-tectonic, geodynamic and environmental studies, if multiparametric studies are performed and the data are interpreted in the geological context.
    Description: Published
    Description: 457-462
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: geothermal gas ; international conference on gas geochemistry ; natural gas ; romania ; seeps ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 68
    Publication Date: 2017-04-04
    Description: Gas seepage from petroleum basins is the second largest natural source of methane to the atmosphere, after wetlands. The uncertainty in global emission estimates should be reduced by extending the flux database which is fundamental for defining the emission factors and the actual area of seepage adopted for up-scaling. As a contribution to this goal, we report a new seepage data-set for the Transylvanian Basin, one of the largest natural gas producing regions of Europe, that is characterized by the widespread occurrence of natural leakages of gas at the surface, including at least 73 mud volcanoes and gas seeps. In this study, methane flux was measured using closed-chambers, from 12 seepage sites, in correspondence with focused gas vents (mud volcano craters, bubbling pools, and flammable gas leaks), in the soil surrounding the vents, and at 15 sites located far from macroseep zones but close to gas fields. Fluxes from individual vents (macro-seeps) were found to reach orders of kg CH4 m)2 day)1 (up to 12 kg m)2 day)1) and diffuse fluxes from soils (miniseepage) were found to be up to a few g CH4 m)2 day)1. Far from seep zones, positive CH4 fluxes (microseepage) may occur locally, typically on the order of tens to hundreds of mg m)2 day)1. The values, as well as the occurrence of seepage even far from vent zones and in mud volcanoes that are apparently extinct, are coherent with results obtained in other countries. Gas fluxes from macro-seeps and soils may change seasonally, but the interannual variation of the average emission factor was found to be minimal. The total CH4 output for Transylvania macro-seeps is estimated conservatively to be around 680 t year)1; the total geo-CH4 seepage emission from the Transylvania petroleum system could be approximately 40 · 103 t year)1, and at least 100 · 103 t year)1 for all Romanian petroleum systems, that is roughly 10% of the total anthropogenic CH4 emission in the country.
    Description: Published
    Description: 463-475
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: gas reservoirs ; methane emissions ; mud volcanoes ; seeps ; Transylvanian Basin ; 04. Solid Earth::04.05. Geomagnetism::04.05.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 69
    Publication Date: 2017-04-04
    Description: Natural gas seeps in the Alpine region are poorly investigated. However, they can provide useful information regarding the hydrocarbon potential of sedimentary Alpine units and related geofluid migration, typically controlled by pressurized gas accumulations and tectonics. A gas seep located near Giswil, in the Swiss Northern Alps, was investigated, for the first time, for molecular and isotopic gas composition, methane flux to the atmosphere, and gas flux variations over time. The analyses indicated that the gas was thermogenic (CH4 〉 96%; d13C1: )35.5& to )40.2&) and showed evidence of subsurface petroleum biodegradation (13C-enriched CO2, and very low C3+ concentrations). The source rock in the region is marine Type II kerogen, which is likely the same as that providing thermogenic gas in the nearby Wilen shallow well, close to Lake Sarnen. However, the lack of d13CCO2 and d13C3 data for that well prevented us from determining whether the Wilen and Giswil seeps are fed by the same reservoir and seepage system. Gas fluxes from the Giswil seep, measured using a closedchamber system, were significant and mainly from two major vents. However, a substantial gas exhalation from the soil occurs diffusely in an area of at least 115 m2, leading to a total CH4 output conservatively estimated to be at least 16 tonnes per year. Gas flux variations, monitored over a 1-month period by a special tent and flowmeter, showed not only daily meteorological oscillations, but also an intrinsic ‘pulsation’ with periods of enhanced flux that lasted 2–6 h each, occurring every few days. The pulses are likely related to episodes of gas pressure build-up and discharge along the seepage system. However, to date, no relationship to seismicity in the active Sarnen strike-slip fault system has been established.
    Description: Published
    Description: 476-485
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: Alps ; isotopes ; methane ; organic geochemistry ; seeps ; Switzerland ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 70
    Publication Date: 2017-04-04
    Description: Natural precipitation and water samples from passive devices were collected at Mt. Vesuvius and Vulcano Island, Italy, during the period 2004–2006, in order to investigate its possible interactions with fumarolic gases. Evidence of chemical reactions between fumarolic fluids and rain samples before and after its deposition into the sampling devices was found at Vulcano Island. Very low pH values (down to 2.5) and significant amounts of chlorine and sulfate (up to 22 mEq/l) were measured at sampling points located close to the fumarolic field. In contrast, anthropogenic contributions and/or dissolution of aerosols (both maritime and continental) influence the chemistry of rainwaters at Mt. Vesuvius, which show inter-annual variations that are highly consistent with those recorded at the coastal site at Vulcano Island. Chemistry of waters directly exposed to fumarolic fluids may then give useful information about its temporal evolution, holding the signal of the ‘‘maximum’’ chemical event occurred in the meanwhile. In addition, the observation of the health status of vegetation colonizing the immediate surroundings of the fumarolic fields, due to its strong dependence on the interactions with these fluids, may work as a possible biomarker of volcanic activity.
    Description: Published
    Description: 159-171
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: restricted
    Keywords: Precipitation ; Fumarole ; Vesuvius ; Vulcano ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 71
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    Publication Date: 2017-04-04
    Description: Sono brevemente descritti i processi che portano alla separazione dei gas da magma ed il ruolo dei gas magmatici nelle eruzioni vulcaniche.Vengono quindi riportati esempi della composizione di gas vulcanici e degli effetti negativi legati all'immissione in atmosfera di grandi quantità di gas vulcanici durante le eruzioni.Infine viene descritto il processo legato all'emissione di gas endogeni in una vasta zona dell'Italia centrale e meridionale.
    Description: Published
    Description: 857-865
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: reserved
    Keywords: inquinamento ; gas ; eruzioni vulcaniche ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: book chapter
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  • 72
    Publication Date: 2023-01-19
    Description: The simultaneous quantitative determination of two-dimensional bromine monoxide (BrO) and sulphur dioxide (SO2) distributions in volcanic gas plumes is described. Measurements at the fumarolic field on the island Vulcano (autumn 2004) and in the plume of Mt. Etna volcano (spring 2005) were carried out with an Imaging DOAS instrument. The SO2 fluxes of several fumaroles were estimated from two-dimensional distributions of SO2. Additionally, the first two-dimensional distributions of BrO within a volcanic plume were successfully retrieved. Slant column densities of up to 2.6×1014 molecules per square centimetre were detected in the plume of Mt. Etna. The investigation of the BrO/SO2 ratio, calculated from the two-dimensional distributions of SO2 and BrO, shows an increase from the centre to the edge of the volcanic plume. These results have significance for the involvement of ozone during BrO formation processes in volcanic emissions.
    Description: Published
    Description: 753-765
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: JCR Journal
    Description: reserved
    Keywords: DOAS ; Imaging DOAS ; Volcanic plume ; BrO ; SO2 ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 01. Atmosphere::01.01. Atmosphere::01.01.08. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 73
    Publication Date: 2021-06-09
    Description: Envisat MERIS and AATSR data have been acquired in the framework of the Eurorisk-Preview project. The project addresses European civil protections and proposes to develop, at the European scale, new information services to support the risk management. In Italy one of the most important natural risks is due to the presence of volcanoes. Mt. Etna in Sicily, displays persistent activity, periodically interrupted by eruptions, which emit volcanic aerosol and ash to different altitudes in troposphere affecting the central Mediterranean area. In order to test the use of MERIS and AATSR data to derive emitted particles parameters as optical depth, effective radius and the ash mass of particles, the already developed remote sensing techniques has been adapted. MERIS and AATSR data acquired during the Mt. Etna 2002-2003 volcanic eruption has been chosen. The use of VIS and TIR bands of the two sensor demonstrates the potential to derive useful information on plume particles and to monitor the volcanic plume during eruption if frequent and high resolution data is available in near real time.
    Description: Published
    Description: Frascati
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 1.10. TTC - Telerilevamento
    Description: 4.3. TTC - Scenari di pericolosità vulcanica
    Description: open
    Keywords: Volcanic aerosol ; Volcanic ash ; Mt. Etna ; Envisat data ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Conference paper
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  • 74
    Publication Date: 2017-04-04
    Description: Quantifying mercury (Hg) emissions from active volcanoes is of particular interest for better constraining the global cycle and environmental impact of this highly toxic element. Here we report on the abundance of total gaseous (TGM=Hg0 (g)+HgII (g)) and particulate (Hg(p)) mercury in the summit gas emissions of La Soufrière andesitic volcano (Guadeloupe island, Lesser Antilles), where enhanced degassing of mixed hydrothermalmagmatic volatiles has been occurring since 1992 from the Southern summit crater.We demonstrate that Hg in volcanic plume occurs predominantly as gaseous mercury, with a mean TGM/Hg(p) mass ratio of ~63. Combining the mean TGM/H2S mass ratio of the volcanic plume (~3.2×10−6), measured close to the source vent, with the H2S plume flux (~0.7 t d−1), determined simultaneously, allows us to estimate a gaseous mercury emission rate of 0.8 kg yr−1 from La Soufrière summit dome. Somewhat lower TGM/Stot mass ratio in fumarolic gases from the source vent (4.4×10−7) suggests that plume chemical composition is not well represented by the emission source (fumaroles) due to chemical processes prior to (or upon) discharge. Current mercury emission from La Soufrìere volcano represents a very small contribution to the estimated global volcanic budget for this element.
    Description: Published
    Description: 276-282
    Description: 4.3. TTC - Scenari di pericolosità vulcanica
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: Mercury ; Fumaroles ; Volcanic plume ; Trace metals ; Gaseous and particulate mercury ; Emission rate ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 75
    Publication Date: 2017-04-04
    Description: Volcanic activity is the main natural sources of sulphur dioxide (SO2) to the atmosphere. Although total anthropogenic sources are overwhelming greater, volcanoes like Mt. Etna and many others are considered to be among the biggest point sources of SO2 also during intereruptive periods. Apart from being one of the most impressive geodynamic expressions, volcanoes are also an important tourist attraction. During the summer season the number of tourists visiting the summit craters each day is on average many tens at Stromboli, hundreds at Vulcano and thousands at Mt. Etna. Of course touristic exploitation of active volcanic areas cannot exempt from warranting a reasonable security to the visiting persons. But while many risks in these areas have been since long time considered, gas hazard, a very subtle risk, is often disregarded. For healthy persons, about 1000 µg m-3 of sulphur dioxide is sensed by smell, 2000 to 4000 µg m-3 cause eye, nose and throat irritation, and 10,000 to 15,000 µg m-3 cause respiratory failure. For individuals with bronchial asthma or lung diseases, exposure to much lower doses could be fatal. Generally, a 700 µg m-3 level is considered to be a safe limit for such persons. The atmospheric concentrations of naturally emitted SO2 were measured at three volcanoes of southern Italy (Mt. Etna, Vulcano and Stromboli). Measurements were made with a network of passive samplers positioned at about 1.5 m above the ground, which gave time-integrated values for periods from few days to 1 month. Samplers were placed in zones of the volcanoes with high tourist frequentation. Measured concentrations reach values as high as 2700, 2400 and 10,000 µg m-3 for Etna, Vulcano and Stromboli respectively. Such values are absolutely dangerous to people affected by bronchial asthma or lung diseases. But considering that these are average values over periods from few days up to one month, SO2 concentrations could reach much higher peak values that could be dangerous also to healthy people. The present study evidences a peculiar volcanic risk connected to the touristic exploitation of active volcanic areas. Such risk is particularly enhanced at Mt.Etna where elderly and not perfectly healthy people can easily reach, with cableway and off-road vehicles, areas with dangerous SO2 concentrations.
    Description: Published
    Description: Bari, Italy
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: open
    Keywords: volcanic degassing ; sulphur dioxide ; passive samplers ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Poster session
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  • 76
    Publication Date: 2017-04-04
    Description: Volcanoes are very strong sources of sulphur, acids and other gases, as well as particles, that are of atmospheric relevance. Some gases only behave as passive tracers, others affect the formation, growth or chemical characteristics of aerosol particles and many lead to adverse effects on vegetation and human health when deposited in the vicinity of volcanoes. In this article the main effects of volcanic emissions on atmospheric chemistry are discussed, with a focus on sulphur and halogen compounds, and to a smaller extent on climate. We primarily focus on quiescent degassing but the main effects of explosive eruptions on the troposphere and stratosphere are covered as well. The key distinction between chemistry in magmatic and hydrothermal settings and the atmosphere is that the atmosphere is oxidising whereas the chemistry is typically reducing in the former cases due to very low oxygen concentrations. Rapid catalytic cycles involving radicals are a further characteristic of atmospheric chemistry. Most reaction cycles involve the photolysis of molecules as a key part of the reaction chains. Recent measurements of halogen radicals in volcanic plumes showed that volcanic plumes are chemically very active. We explain the formation mechanism of halogen oxides in plumes as well as their relevance for the atmosphere.
    Description: Published
    Description: 131-142
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: Quiescent degassing ; Troposphere ; Halogens ; Atmospheric chemistry ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 77
    Publication Date: 2017-04-04
    Description: Mt. Etna is characterized by flank instability of the eastern to south-western portions of the volcanic edifice, producing down-slope movements with rates up to several decimeters in a month during eruptive events of the 2002-2003 activity. The unstable sector is bounded to the North by a E-W transtensive fault (the Pernicana fault system), extending from the NE Rift to the coastline of the Ionian Sea for a length of 〉18 km. The western portion of the Pernicana fault system (close to Piano Pernicana area) is characterized by the most intense deformation. In this area we have performed volcanic tremor measurements on a dense grid along and across the fault zone. Ambient vibration measurements are also performed along a second fault (Tremestieri fault) which confines the slip of the eastern flank to the south-east. The analysis using both microtremors and local earthquakes recorded in these faults shows persistent polarization of ground motion. Horizontal-to-vertical spectral ratios (HVSR) show large directional resonances of horizontal components within the damaged fault zones. The resonance occurs around 1Hz at Piano Pernicana, and around 4 Hz in the Tremestieri fault zone. The resonance amplitude in the HVSRs seems to be fairly well correlated to soil gas anomalous concentrations (in particular, radon and CO2 both considered tracer gases of major crustal discontinuity) in the two fault zones, suggesting that both the effects are linked to local fracturing conditions. According to previous results on velocity anisotropy in the shallow crust, we believe that a role on polarization could be played by stress-induced anisotropy and micro-fracture orientation in the near-surface lavas. The occurrence of directional resonances, if confirmed in other faults, can be a powerful tool to map buried damaged fault zones on the Mt. Etna volcano.
    Description: SSA
    Description: Published
    Description: MonteRey, California
    Description: 1.4. TTC - Sorveglianza sismologica delle aree vulcaniche attive
    Description: open
    Keywords: Pernicana fault, fault zone, volcanic tremor, polarization, directional resonance ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 78
    Publication Date: 2017-04-04
    Description: Active volcanoes emit considerable amounts of contaminants such as As, Se and V. Mount Etna is the biggest volcano of Europe and an excellent geochemical site to study water-soil processes. Due to its volcanic activity, the rainwater has a strong compositional gradient, both in time and space. At present, the behaviour of trace elements in the soils around Mt Etna is poorly understood. To determine the influence of the rainwater pH on the potential mobilization of geogenic pollutants, batch experiments have been performed with synthetic rainwater for 25 soils collected along the flanks of the volcano. Our results show that: i) The maximum concentrations in the leaching solutions are higher for acid rain than for neutral rain (e.g. 7.7 vs 1.3 mg/L for Se). ii) With neutral rain conditions the soils upwind from the volcano have higher concentrations of Se than those downwind (up to 1.3 mg/L compared to ≤0.3 mg/L for the other samples). This trend is less clear for As and V. iii) For soils collected from 2 to 10 km downwind of the craters, Se concentrations in acid rain leachates decrease one order of magnitude with increasing distance. A similar pattern is also observed upwind from the volcano. For As and V no clear relationship between concentrations and location with respect to the volcanic craters is observed. Both i) and ii) result in a low pH dependence for samples upwind from the volcano. The biggest difference between acid and neutral leaching for As and V is observed for a sample 2 km downwind from the craters. The observed patterns are influenced by potential controlling factors, such as organic matter content, total concentrations, mineralogy, influence of the volcanic plume, etc. Our results have implications for the chemical composition of the Etnean aquifer, the only water resource to the one million inhabitants around Mt Etna, as well as for the bioavailability and potential toxicity through agricultural activities, essential to the local economy.
    Description: Published
    Description: Davos, Switzerland
    Description: 4.4. Scenari e mitigazione del rischio ambientale
    Description: open
    Keywords: volcanic soils ; selenium ; arsenic ; vanadium ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 03. Hydrosphere::03.03. Physical::03.03.01. Air/water/earth interactions ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.08. Risk::05.08.01. Environmental risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Oral presentation
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  • 79
    Publication Date: 2017-04-04
    Description: Geochemical comparison between some metals (As, Cd, Cu, Pb, Se, V, Zn) emissions from an active volcano (Mt. Etna) and a highly industrialized area (Salek Valley) showed some interesting similarities: in general, most of the elements emitted into the atmosphere do not return to the Earth's surface and are therefore dispersed into the environment. Exceptions for Salek Valley are Cd, which probably derives in large part from rock leaching, and in part As and Pb, which fall mostly as ash. Also, Etna's emissions are richer in Cd and Cu, whereas industrial emissions at Salek Valley are richer in V and Zn. All other metals have similar fluxes in the two types of emissions.
    Description: Published
    Description: Ljubljana, Slovenia
    Description: 4.4. Scenari e mitigazione del rischio ambientale
    Description: open
    Keywords: Trace metals ; Mt. Etna ; Salek Valley ; metals budget ; pollution ; 01. Atmosphere::01.01. Atmosphere::01.01.03. Pollution ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.08. Risk::05.08.01. Environmental risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 80
    Publication Date: 2017-04-04
    Description: Volcanic and geothermal areas are one of the major natural sources of H2S to the atmosphere. Its environmental impact is often the main cause of the opposition to the development of geothermal energy exploitation programs. In this paper we analyze the air concentrations and dispersion pattern of naturally emitted H2S at the geothermal area of Sousaki (Corinthia, Greece). Measurements, made with a network of passive samplers, evidence a rapid decrease of concentration values away from the emission points. The fact that the decrease is more pronounced in the summer with respect to the winter indicates that it is not only due to a dilution effect, but also to redox reactions favoured by higher temperatures and intense sunlight typical of the summer period.
    Description: Published
    Description: 1723-1728
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: Hydrogen sulphide ; Environmental impact of volcanic activity ; Gas hazard ; Passive samplers ; 01. Atmosphere::01.01. Atmosphere::01.01.03. Pollution ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 81
    Publication Date: 2017-04-04
    Description: Sweet chestnut leaves (Castanea sativa) collected from the flanks of Mt Etna volcano in 2005–2007 were analysed by inductively-coupled plasma mass spectrometry to investigate the spatial and temporal variability of element concentrations. The aim of this work was to determine whether these leaves are a bio-indicator for volcanic gas, aerosol and ash deposition and to gain new insights into the environmental effects of quiescent and eruptive volcanic plumes. Results show a positive correlation between sample variability in the concentration of elements in Castanea sativa and enrichment factors of elements in the plume. The spatial and temporal variability of chalcophilic elements (As, Cd, Cu, Mo, Tl, Zn) is consistent with prevailing winds transporting eruptive plumes to the south-east of the summit, resulting in enhanced plume deposition onto the flanks of the volcano. Similar spatial and temporal variability was found for the halideforming elements (Cs, K, Rb) and intermediate elements (Al, Co, Mn). The spatial variability of chalcophilic, intermediate and halide-forming elements during quiescent periods was diminished (relative to eruptive periods) and could not be explained by plume deposition. In contrast, the concentrations of lithophilic elements (Ba, Ca, Mg, Sr) did not show any clear spatial variability even during eruptive periods. Comparisons between enrichment factors for elements in Castanea sativa and literature values for enrichment factors of the volcanic plume, groundwater and lichen were made. Whilst Castanea sativa offers insights into the spatial and temporal variability of deposition, the species may not be a bio-indicator for plume composition due to biological fractionation.
    Description: Published
    Description: 107-119
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: Mt Etna ; vegetation ; Castanea sativa ; bio-indicator ; emission ; dispersion ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 82
    Publication Date: 2017-04-04
    Description: This study presents baseline data for future geochemical monitoring of the active Tacaná volcano– hydrothermal system (Mexico–Guatemala). Seven groups of thermal springs, related to a NW/SE-oriented fault scarp cutting the summit area (4,100m a.s.l.), discharge at the northwest foot of the volcano (1,500–2,000m a.s.l.); another one on the southern ends of Tacaná (La Calera). The near-neutral (pH from 5.8 to 6.9) thermal (T from 25.7°C to 63.0°C) HCO3–SO4 waters are thought to have formed by the absorption of a H2S/SO2–CO2-enriched steam into a Cl-rich geothermal aquifer, afterwards mixed by Na/HCO3-enriched meteoric waters originating from the higher elevations of the volcano as stated by the isotopic composition (δD and δ18O) of meteoric and spring waters. Boiling temperature fumaroles (89°C at ~3,600m a.s.l. NW of the summit), formed after the May 1986 phreatic explosion, emit isotopically light vapour (δD and δ18O as low as −128 and −19.9‰, respectively) resulting from steam separation from the summit aquifer. Fumarolic as well as bubbling gases at five springs are CO2-dominated. The δ13CCO2 for all gases show typical magmatic values of −3.6 ± 1.3‰ vs V-PDB. The large range in 3He/4He ratios for bubbling, dissolved and fumarolic gases [from 1.3 to 6.9 atmospheric 3He/4He ratio (RA)] is ascribed to a different degree of near-surface boiling processes inside a heterogeneous aquifer at the contact between the volcanic edifice and the crystalline basement (4He source). Tacaná volcano offers a unique opportunity to give insight into shallow hydrothermal and deep magmatic processes affecting the CO2/3He ratio of gases: bubbling springs with lower gas/water ratios show higher 3He/4He ratios and consequently lower CO2/3He ratios (e.g. Zarco spring). Typical Central American CO2/3He and 3He/4He ratios are found for the fumarolic Agua Caliente and Zarco gases (3.1 ± 1.6 × 1010 and 6.0 ± 0.9 RA, respectively). The L/S (5.9 ± 0.5) and (L + S)/M ratios (9.2 ± 0.7) for the same gases are almost identical to the ones calculated for gases in El Salvador, suggesting an enhanced slab contribution as far as the northern extreme of the Central American Volcanic Arc, Tacaná.
    Description: This study was financially supported by DGAPA UNAM #IN101706 and INGVPalermo.
    Description: Published
    Description: 319-335
    Description: 1.3. TTC - Sorveglianza geodetica delle aree vulcaniche attive
    Description: JCR Journal
    Description: partially_open
    Keywords: Tacaná volcano ; Fluid geochemistry ; Volcano–hydrothermal system ; Bubbling gases ; Fumaroles ; Isotopes ; Volcanic surveillance ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 83
    Publication Date: 2017-04-04
    Description: The simultaneous presence of SO2 and ash in a volcanic plume can lead to a significant error in the SO2 column abundance retrieval when multispectral Thermal InfraRed (TIR) data are used. The ash particles within the plume with effective radii from 1 to 10μm reduce the Top Of Atmosphere (TOA) radiance in the entire TIR spectral range, including the channels used for SO2 retrieval. The net effect is a significant SO2 overestimation. In this work the interference of ash is discussed and two correction procedures for satellite SO2 volcanic plume retrieval in the TIR spectral range are developed to achieve an higher computational speed and a better accuracy. The ash correction can be applied when the sensor spectral range includes the 7.3 and/or 8.7μm SO2 absorption bands, and the split window bands centered around 11 and 12μm required for ash retrieval. This allows the possibility of simultaneous estimation of both volcanic SO2 and ash in the same data set. The proposed ash correction procedures have been applied to the Moderate Resolution Imaging Spectroradiometer (MODIS) and the Spin Enhanced Visible and Infrared Imager (SEVIRI) measurements. Data collected during the 24 November 2006 Mt. Etna eruption have been used to illustrate the technique. The SO2 and ash estimation is carried out by using a best weighted least squares fit method and the Brightness Temperature Difference (BTD) procedures, respectively. The simulated TOA radiance Look-Up Table (LUT) needed for the SO2 column abundance and the ash retrievals have been computed using the MODTRAN 4 Radiative Transfer Model. The results show the importance of the ash correction on SO2 retrievals at 8.7μm, where the corrected SO2 column abundance values are less than 50% of the uncorrected values. The ash correction on SO2 retrieval at 7.3μm is much less important and only significant for low SO2 column abundances. Results also show that the simplified and faster correction procedure underestimates the ash correction compared with the more time consuming but more accurate correction procedure. Such underestimation is greater for instruments having better ground pixel resolution, i.e. greater for MODIS than for SEVIRI.
    Description: Published
    Description: 177–191
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 1.10. TTC - Telerilevamento
    Description: N/A or not JCR
    Description: open
    Keywords: volcanic ash retrieval ; volcanic so2 retrieval ; ash correction ; remote sensing ; MODIS ; SEVIRI ; Etna volcano ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 01. Atmosphere::01.01. Atmosphere::01.01.08. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 84
    Publication Date: 2017-04-04
    Description: Chemical and isotopic analyses of the main gas manifestations of the island of Pantelleria (Italy) were used to gain insight on the origin of the released methane. Results indicate that the most probable origin is through abiogenic reactions within the hydrothermal system. Methane and CO2 flux measurements from the soils were made with the accumulation chamber method in an area of about 0.015 km2 within the main fumarolic area of the island (Favara Grande). The 23 measurements range from –34 to 3550 mg m-2 d-1 for CH4 and from 0.6 to 379 g m-2 d-1 for CO2. The relationships between CH4 and CO2 fluxes and the CH4/CO2 ratios in the gases collected between 25 and 100 cm depth provide evidence for methanotrophic processes within the soils. Methane output for the surveyed area was calculated in 2.5 t a-1 and extrapolated to about 5-10 t a-1 for the entire volcanic/hydrothermal system of the island. Previous higher estimates of the CH4 output at Pantelleria (Etiope et al., 2007 - J. Volcanol. Geotherm. Res., 165, 76 – 86) were based on soil CO2 output and CH4/CO2 ratios in fumarolic gases; the present work provides the first direct CH4 flux data and it suggests that methanotrophic activity in the soil could be substantial in reducing the CH4 emission to the atmosphere.
    Description: Published
    Description: 147-157
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: reserved
    Keywords: hydrothermal systems ; gas geochemistry ; isotope composition ; methane output ; methanotrophic consumption ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 85
    Publication Date: 2017-04-04
    Description: Volcanic and geothermal areas are one of the major natural sources of environmentally relevant gases to the atmosphere. Hydrogen sulphide (H2S) is a toxic gas, which is rather always present in geothermal fluids. Like carbon dioxide, being a gas that is denser than atmospheric air, it can accumulate in topographic depressions and enclosures sometimes reaching concentrations (500-1000 ppm) lethal to humans and animals. It has a characteristic odor of rotten eggs to which the human smell is very sensible (odor threshold as low as 10 ppb for very sensible persons). The south Aegean volcanic arc, which is related to the subduction of the African plate beneath the Eurasian plate, comprises many active or extinct volcanic centres. Most of them are characterised by the presence of fumarolic areas. The peculiarity and beauty of such manifestations attracts each year thousands of tourists many of which go very close to the emission vents. In the present study we measured the atmospheric concentrations and dispersion pattern of naturally emitted H2S at four fumarolic areas (Thiochoma – Sousaki, Fyriplaka – Milos. Nea Kameni – Santorini, Lakki plain – Nisyros). Measurements were made with a network of passive samplers positioned at about 1.5 m above the ground, which gave time-integrated values for periods ranging from days to weeks. Values ranged from 0.1 to 2050 ppb at Sousaki, from 0.8 to 33.8 ppb for Milos, from 0.1 to 5.1 ppb for Santorini and from 1.6 to 1240 ppb for Nisyros. At all the fumatolic areas concentrations decreased exponentially with increasing distances from the source. The highest values were recorded at distances of about 5-20 m from the fumarolic vents. The striking difference between the highest values measured at Sousaki and Nisyros with respect to Milos and Santorini depends on two main factors. The first factor is a higher H2S emission rate at the former two sites (stronger total gas emission and higher H2S concentrations). The second factor is the geomorphology of the same two sites that limits the gas exchange with the open atmosphere. In fact, while the fumarolic area of Sousaki is in a narrow ravine and that of Nisyros is within the calderic depression of the island, the fumarolic areas of Milos and Santorini are well exposed to free atmospheric circulation. Nevertheless also the highest measured concentrations, although disconfortable, does not have adverse effects on human health.
    Description: Published
    Description: Bari, Italy
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: open
    Keywords: Volcanic degassing ; Hydrogen sulphide ; passive samplers ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Poster session
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  • 86
    Publication Date: 2017-04-04
    Description: Volcanic volatiles and aerosol emitted into the atmosphere ultimately fall on the Earth’s surface as wet or dry deposition, and they can influence the environment and the ecosystems at local and regional scales. Therefore, atmospheric deposition plays a key-role in the geochemical cycles, redistributing volcanogenic elements to the ground. For this reason, estimating the volcanogenic trace element fluxes from the atmosphere to the surface is necessary for a better knowledge of the environmental impact of the volcanic emissions. Nevertheless, from a literature review, we have recognized the scarcity of investigation on trace element deposition in the surroundings of active volcanoes. Here, we present a chemical characterization of bulk deposition around Mt. Etna, Italy, including both major and many trace elements. Bulk depositions were collected approximately fortnightly, from April 2006 to December 2007, using a network of five rain gauges, located at various altitudes on the upper flanks around the summit craters of the volcano. For most elements highest concentrations have been found close to the emission vent, confirming the prevailing volcanic contribution to rainwater composition close to the summit craters. Comparison with contemporaneously collected plume emissions shows that deposition processes produce no evident element-to-element fractionation. By contrast, comparison with whole rock composition indicates a contrasting behaviour between volatile elements, which are highly-enriched in rainwater, and refractory elements, which have low rainwater/whole rock concentration ratios. Chemical concentrations in bulk deposition were used to estimate the deposition rates of a large suite of elements. Deposition rates for volatile trace elements like Se, As, and Cd range from 1.7, 1.2 and 0.9 µg m-2 day-1 nearby to the summit vents, to 0.5, 0.3, and 0.1 µg m-2 day-1 at the local background site on the upwind western sector.
    Description: Published
    Description: Davos, Switzerland
    Description: 4.4. Scenari e mitigazione del rischio ambientale
    Description: open
    Keywords: trace metals ; atmospheric deposition ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.08. Risk::05.08.01. Environmental risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 87
    Publication Date: 2020-10-29
    Description: The bulk electrical conductivity of the phonotephritic lava from the 1944 eruption of Mt Vesuvius was measured using complex impedance spectroscopy in a multianvil apparatus at 1 GPa and temperatures up to 700 °C. Melting experiments prior to the electrical measurements were also performed on this sample in a piston cylinder apparatus in order to gauge how bulk conductivity varies as a function of its melt fraction. Unlike the behaviour found in basaltic rocks in which conductivity increases with increasing melt fraction, we observe a conductivity decrease of the order of a factor of ten for samples at 700 °C ranging in melt fraction from 32 vol.% to completely molten.We attribute this anomalous behaviour to the progressive loss of highly conductive leucite upon melting. The addition of potassium to the melt phase, however, does not result in an increase of the total alkali concentration due to the melting of other mineral components. We also present an empirical model to predict the electrical conductivity of fully molten silicate liquids as a function of temperature and chemical composition, based on conductivity data for natural silicate liquids found in the literature. The inclusion of compositional terms reduces the error by more than a factor of four with respect to a composition independent, temperature-only parameterization.
    Description: Published
    Description: 192-201
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: JCR Journal
    Description: reserved
    Keywords: Electrical conductivity ; silicate melts ; partial melting ; Mt. Vesuvius ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 88
    Publication Date: 2017-04-04
    Description: Volcanic eruptions may create a wide range of risks in inhabited areas and, as a consequence, major economic damage to the surrounding territory. An example of volcanic hazard was given between 1998 and 2001 by Mt. Etna volcano, in Italy, with its frequent paroxysmal explosive activity that caused more than a hundred fire-fountain episodes. In the period January–June 2000, in particular, 64 lava fountains took place at the Southeast Crater. During the most intense explosive phase of each episode, a sustained column often formed, reaching up to 6 km above the eruptive vent. Then, the column started to expand laterally causing more or less copious tephra fallout on the slopes of Etna; ash and lapilli, therefore, constituted a serious danger for vehicular and air traffic. A software and hardware warning system was developed to mitigate the volcanic hazard indicating the areas affected by potential ash and lapilli fallout. The alert system was mainly based on the good correspondence between the pattern of volcanic tremor amplitude and the evolution of explosive activity. When a fixed tremor threshold was exceeded, a semiautomatic process started to send faxes to Civil Defence and Municipalities directly affected by tephra fallout, together with information on wind directions from the Meteorological Office. The application of this methodology, during the last 14 eruptive episodes in 2000 and the 14 events occurred in 2001, demonstrated the good correspondence between the forecasts on the areas affected by tephra fallout and the effective tephra distribution on land. Despite the integrity of the performance provided by the alert system, small discrepancies occurred in the technical procedure of alerting, for which possible solutions have been discussed. The improvement of this type of system, could become basic for the Etnean region and be proposed for similar volcanic areas throughout the world.
    Description: Published
    Description: 333-350
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 1.4. TTC - Sorveglianza sismologica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: Alert system ; Volcanic surveillance ; Volcanic tremor ; Lava fountain ; Tephra fallout ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 89
    Publication Date: 2017-04-04
    Description: Volcanoes contribute to atmospheric pollution by increasing the amount of reactive and greenhouse gases and aerosols, making volcanic emissions one of the major natural sources of several trace elements to the atmosphere. In particular, Mt. Etna is considered to be, on the long-term average, the major atmospheric point source of many environmental harmful compounds. Their emission occurs in the form of gases, aerosols or particulate, both through continuous passive degassing from open-conduit activity and through sporadic paroxysmal eruptive activity. To estimate the environmental impact of magma-derived trace metals and their depositions processes, five bulk collectors have been deployed at various altitudes on the upper flanks around the summit craters of the volcano. Samples were collected every second week for a period of one year and analyzed for the main chemical-physical parameters (electric conductivity and pH) and for major and trace elements concentrations. The first data obtained clearly show that the volcanic contribution is always prevailing in the sampling site closest to the summit craters (∼1.5 km). In the distal sites (5.5-10 km from the summit) downwind of the summit craters, the volcanic contribution is also detectable but often overwhelmed by anthropogenic or other natural (seawater spray, geogenic dust) contributions. Volcanic contribution may derive from both dry and wet deposition of gases and aerosols from the volcanic plume, but sometimes also from leaching of freshly emitted volcanic ashes. In fact, in our background site (7.5 km in the upwind direction,) volcanic contribution has been detected only following an ash deposition event. Fluorine, S and Cl, are the major elements that prevailingly characterize the volcanic contribution in bulk deposition on Mt. Etna, but high concentrations of many trace elements are also detected in the studied samples. In particular, Si, Al, Fe, Ti, Cu, As, Rb, Pb, Tl, Cd, Cr, U and Ag display, in the site most exposed to the volcanic emissions, median concentration values about two orders of magnitude higher than those measured in our background site. Furthermore some of the analysed elements display very high enrichment values with respect to the average crust and, in the closest site to the summit craters, also deposition values higher than those measured in polluted urban or industrial sites.
    Description: Unpublished
    Description: Athens, Greece
    Description: 4.5. Degassamento naturale
    Description: open
    Keywords: Mt. Etna ; trace elements ; rainwater ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Oral presentation
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  • 90
    Publication Date: 2017-04-04
    Description: Quiescent and explosive magma degassing at Stromboli volcano sustain high temperature crater gas venting and a permanent volcanic plume which constitute key sources of information on the magma supply and dynamics, the physical processes controlling the explosive activity and, more broadly, the volcano feeding system. The chemical composition and the mass output of these crater emissions (gases, trace metals, radioactive isotopes) were measured using different methodologies: within-plume airborne measurements, ground-based plume filtering and/or in situ analysis, remote UV and OP-FTIR absorption spectroscopies. The results obtained, summarized in this paper, demonstrate a primary control of the magmatic gas phase on the eruptive regime and the budget of the volcano. The large excess gas discharge, compared to the lava extrusion rate, and the source depth of slug-driven strombolian explosions evidence extensive separate gas transfer across the volcano conduits, promoted by the high gas content (vesicularity) and then permeability of the shallow basaltic magma. Combined with data for volatiles dissolved in olivine-hosted melt inclusions, the results provide updated constraints for the magma supply rate (~0.3 m3 s-1 on average), the extent of intrusive versus extrusive magma degassing (~15), and the amount of un-erupted degassed magma that should be convectively cycled back in conduits and accumulated beneath the volcano over time (~0.25 km3 in last three decades). The results also provide insight into the possible triggering mechanism of intermittent paroxysmal explosions and the geochemical signals that might allow forecasting these events in future.
    Description: Unpublished
    Description: 4.4. Scenari e mitigazione del rischio ambientale
    Description: reserved
    Keywords: Stromboli ; magma feeding system ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: book chapter
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  • 91
    Publication Date: 2017-04-04
    Description: Significant changes in both the chemistry of coastal thermal waters and the soil CO2 and Rn emissions in the crater area were recorded at Stromboli prior to the eruption that began on 28 December 2002. The dissolved CO2 contents and the d13C and 3He/4He values were elevated in the thermal aquifer from July 2002. Synchronous variations in the same isotope ratios were recorded in the summit fumarolic gases, with both 3He/4He and d13C values of gases released from a fumarole in the summit area increasing between May and November 2002. These variations are indicative of early degassing of a new gas-rich magma batch with a 13C- and 3He-rich signature. This magma recharge probably fed the intense Strombolian activity recorded during that period. The eruption began with a major explosion that produced a glowing avalanche, immediately followed by a fluid lava overflow from the NE crater and subsequent lava effusion from vents opened in the Sciara del Fuoco depression. Sharp increases in CO2 soil flux and Rn emissions— to values never observed previously—were recorded in the summit crater area 10 d before the eruption onset. These CO2 and Rn anomalies are indicative of a high gas-driven magma supply rate and gas overpressure within the conduit. The sudden depressurization of the magma filling the upper conduit probably caused the major explosion that occurred on 28 December, which heralded the effusive phase. These data demonstrate the importance of collecting a wide spectrum of geochemical data from different geological sites when monitoring a volcano.
    Description: Submitted
    Description: 4.5. Degassamento naturale
    Description: reserved
    Keywords: Stromboli ; geohcemical monitoring ; carbon and helium isotopes ; CO2 and Rn soil emissions ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: book chapter
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  • 92
    Publication Date: 2012-02-03
    Description: Ash and SO2 were detected in the eruptions of Kasatochi and Okmok by infrared and UV sensors, including MODIS, AIRS and OMI. The simultaneous presence of ash and SO2 in these clouds presents a problem for retrieving SO2 column abundance because ash absorbs strongly near the 8.7 mm SO2 absorption feature. This leads to a overestimation of the MODIS SO2 abundance, unless the effects of ash are taken into account. Here, we use a new radiative transfer scheme to correct for the effects of ash on SO2 retrieval at 8.7 mm and also account for the effects of ash on SO2 retrieval at 7.3 mm, although this is much less severe, as we will demonstrate. The retrievals provide an improved quantitative description of the ash and SO2 in volcanic eruptive clouds and will assist in developing warnings for aviation. A comparison between MODIS retrievals and contemporaneous OMI SO2 retrievals and AIRS ash and SO2 retrievals has been also presented.
    Description: Unpublished
    Description: AGU Fall Meeting 15-19 December San Francisco
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: open
    Keywords: volcanic ash and SO2 retrievals ; Kasatochi ; Okmok ; ash correction procedure ; MODIS ; AIRS ; OMI ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Poster session
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  • 93
    Publication Date: 2017-04-04
    Description: This guide reports the description of the experimental apparata in use in the experimental petrology along with an accurate description of some applications of these instrumentations. After a brief introduction concerning what is the experimental petrology and what is used for, we provide a description of the starting materials used in this field of the Earth Sciences. Moreover, particular attention is focused on these apparata used all around the world. We, finally, introduce some examples of different studies conducted with the different experimental equipments. The aim of this guide is, then, to give information concerning the equipments and their potentiality.
    Description: Published
    Description: 1-20
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: N/A or not JCR
    Description: open
    Keywords: Piston cylinder ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 94
    Publication Date: 2017-04-04
    Description: Volcanoes represent an important natural source of several trace elements to the atmosphere. For some species (e.g., As, Cd, Pb and Se) they may be the main natural source and thereby strongly influencing geochemical cycles from the local to the global scale. Mount Etna is one of the most actively degassing volcanoes in the world, and it is considered to be, on the long-term average, the major atmospheric point source of many environmental harmful compounds. Their emission occurs either through continuous passive degassing from open-conduit activity or through sporadic paroxysmal eruptive activity, in the form of gases, aerosols or particulate. To estimate the environmental impact of magma-derived trace metals and their depositions processes, rainwater and snow samples were collected at Mount Etna area. Five bulk collectors have been deployed at various altitudes on the upper flanks around the summit craters of the volcano; samples were collected every two week for a period of one year and analyzed for the main chemical-physical parameters (electric conductivity and pH) and for major and trace elements concentrations. Chemical analysis of rainwater clearly shows that the volcanic contribution is always prevailing in the sampling site closest to the summit crater (about 1.5 km). In the distal sites (5.5-10 km from the summit) and downwind of the summit craters, the volcanic contribution is also detectable but often overwhelmed by anthropogenic or other natural (seawater spray, geogenic dust) contributions. Volcanic contribution may derive from both dry and wet deposition of gases and aerosols from the volcanic plume, but sometimes also from leaching of freshly emitted volcanic ashes. In fact, in our background site (7.5 km in the upwind direction) volcanic contribution has been detected only following an ash deposition event. About 30 samples of fresh snow were collected in the upper part of the volcano, during the winters 2006 and 2007 to estimate deposition processes at high altitude during cold periods. Some of the samples were collected immediately after a major explosive event from the summit craters to understand the interaction between snow and fresh erupted ash. Sulphur, Chlorine and Fluorine, are the major elements that prevailingly characterize the volcanic contribution in atmospheric precipitation on Mount Etna, but high concentrations of many trace elements are also detected in the studied samples. In particular, bulk deposition samples display high concentration of Al, Fe, Ti, Cu, As, Rb, Pb, Tl, Cd, Cr, U and Ag, in the site most exposed to the volcanic emissions: median concentration values are about two orders of magnitude higher than those measured in our background site. Also in the snow samples the volcanic signature is clearly detectable and decreases with distance from the summit craters. Some of the analysed elements display very high enrichment values with respect to the average crust and, in the closest site to the summit craters, also deposition values higher than those measured in polluted urban or industrial sites.
    Description: Published
    Description: Vienna, Austria
    Description: 4.5. Degassamento naturale
    Description: open
    Keywords: Mt. Etna ; trace elements ; rainwater ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 03. Hydrosphere::03.03. Physical::03.03.01. Air/water/earth interactions ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Oral presentation
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  • 95
    Publication Date: 2017-04-04
    Description: Mount Etna is a huge volcano in the Mediterranean basin and is located in the eastern part of Sicily. It is considered to be, on the long-term average, the major atmospheric point source of many environmental harmful compounds. Their emission occurs either through continuous passive degassing from open-conduit activity or through sporadic paroxysmal eruptive activity, in the form of gases, aerosols or particulate. Volcanic volatiles and aerosol emitted into the atmosphere fall on the Earth’s surface as wet or dry deposition, and can influence the environment both at local and regional scale. To estimate the environmental impact of magma-derived trace metals and their depositions processes, bulk deposition samples have been collected approximately fortnightly, using a network of 5 rain gauges located at various altitudes on the upper flanks close to the summit craters, from April 2006 to December 2007. Samples were analyzed for the main chemicalphysical parameters (electric conductivity and pH) and for major and trace elements concentrations. The data obtained clearly show that the volcanic contribution is always prevailing in the sampling site closest to the summit craters (∼1.5 km). In the distal sites (5.5-10 km from the summit) and downwind of the summit craters, the volcanic contribution is also detectable but often overwhelmed by anthropogenic or other natural (seawater spray, geogenic dust) contributions. Volcanogenic contribution may derive from both dry and wet deposition of gases and aerosols from the volcanic plume, but sometimes also from leaching of freshly emitted volcanic ashes. In fact, in our background site (7.5 km in the upwind direction), after an ash deposition event high concentration of lithophiles elements (Si, Al, Fe, Ti) have been measured. Sulphur, Chlorine and Fluorine, represent the main constituents that characterize the volcanic contribution in the bulk deposition on Mt. Etna, although high concentrations of many trace elements (Si, Al, Fe, Ti, Cu, As, Rb, Pb, Tl, Cd, Cr, U and Ag) display, in the site most exposed to the volcanic emissions, average concentrations of about two orders of magnitude higher than those measured in the background site (Mount Intraleo).
    Description: Published
    Description: Catania, Italy
    Description: 4.5. Degassamento naturale
    Description: open
    Keywords: Mt. Etna ; trace elements ; rainwater ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 03. Hydrosphere::03.03. Physical::03.03.01. Air/water/earth interactions ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Oral presentation
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  • 96
    Publication Date: 2017-04-04
    Description: The aim of this paper is to show the feasibility of evaluating the sulphur dioxide (SO2) flux emitted by Mt Etna volcano, using remotely sensed data of Advanced Spaceborne Thermal Emission and Reflection radiometer (ASTER) in the thermal infrared (TIR). ASTER is one of the instruments on board the first Earth Observation System (EOS) satellite launched on 18 December 1999. To simulate the ASTER data, Multispectral Infrared and Visible Imaging Spectrometer (MIVIS) images, acquired during the ‘Sicily ’97’ campaign, were used. The SO2 column abundance maps shown in this paper have been obtained by means of a simple algorithm based on the split-window technique. The parameters of the algorithm were computed using Moderate Resolution Atmospheric Radiance and Transmittance Model (MODTRAN) simulations performed with atmospheric profiles acquired during MIVIS flights. The mean SO2 flux on 12 and 16 June 1997, obtained using the ASTER simulated images, results in 42 and 33 kg s−1 respectively; these values are in good agreement with the results obtained by the inversion procedure used by Teggi et al. (1999) applied to the MIVIS data and with the Correlation Spectrometer (COSPEC) measurements performed during the campaign by other teams.
    Description: Published
    Description: 1207–1218
    Description: 1.10. TTC - Telerilevamento
    Description: JCR Journal
    Description: reserved
    Keywords: Remote sensing ; ASTER measurements ; SO2 retrieval ; MODTRAN RTM ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 97
    Publication Date: 2017-04-04
    Description: In this paper, an algorithm is developed based on the split-window technique, to estimate the SO2 abundance in the plume of Mt. Etna volcano using the multispectral infrared and visible imaging spectrometer (MIVIS). The MIVIS data were remotely sensed in the thermal infrared (TIR) during the Sicily-1997 Campaign. In this study, the MODTRAN 3.5 code has been used to simulate the radiance at the sensor; the radiative transfer model was input along with the data of radio-sounding performed simultaneously with the MIVIS flight using a mobile radio-theodolite. From the SO2 map, derived from the MIVIS image, the SO2 flux along the axis of the plume was computed knowing the wind speed at the plume altitude. The SO2 flux is variable along the plume axis. The average SO2 flux (about 45 kg s–1 on 12 June and about 30 kg s–1 on 16 June) emitted from the vents is compared with the correlation spectrometer (COSPEC) measurements carried out by other teams (from the ground and from a light aircraft flying under the plume) during the MIVIS flight. Finally, by means of this algorithm it should be easier, with respect to the previously described procedure to monitor the SO2 flux of a specific volcano such as Mt. Etna.
    Description: Published
    Description: 328–337
    Description: 1.10. TTC - Telerilevamento
    Description: JCR Journal
    Description: reserved
    Keywords: MIVIS ; Remote sensins ; SO2 retrieval ; Split Window ; Volcanic gas emission ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 98
    Publication Date: 2017-04-04
    Description: This work is aimed at estimating the sulfur dioxide emission of Mt. Etna volcano (Sicily, Italy) using the thermal infrared images remotely sensed by the Advanced Spacebome Thermal Emission and Reflection Radiometer (ASTER). A new procedure (named FUN) is presented based on approximating functions which represent the atmospheric terms of the radiative transfer equation: transmittance, up-welling and down-welling radiances. The parameters of the approximating functions have been computed through the MODTRAN simulations performed using atmospheric monthly mean profiles measured at Trapani (1989-2003). Trapani (WMO station 16429) is located at the western tip of Sicily and is the closest station to Mt. Etna volcano. With these functions MODTRAN is no longer necessary to compute the SO2 abundance in the plume emitted from Mt. Etna and seen by ASTER. Only an atmospheric radiosounding and a digital elevation model (DEM) registered to the ASTER image are required. This new procedure is compared with the known look-up tables (LUT) procedure proposed by other authors. An interesting aspect of the FUN procedure derives from its combined use with a split window (SW) algorithm. In this case only radiosounding is required to compute the SO2 map. The FUN procedure presented in this paper is a rapid, simple and accurate means of generating SO2 map estimates from the ASTER view of Mt. Etna. The proposed scheme can easily be adapted to another sensor and another volcano. In this paper the results from two ASTER images, 19 July 2003 and 29 July 2001, are presented. In July 2003, a ground truth campaign was deployed, SO2 emission was very low (10-25 kg s(-1); Etna baseline is about 50 kg s(-1)). In July 2001, Mt. Etna erupted and a strong SO2 emission (about 140 kg s(-1)) was measured.
    Description: Published
    Description: 74-90
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: JCR Journal
    Description: reserved
    Keywords: Mt. Etna volcano ; sulfur dioxide ; ASTER ; radiative transfer ; TIR ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 99
    Publication Date: 2021-12-02
    Description: Estimation of the daily trend of sulfur dioxide and ash from the thermal infrared measurements of the Spin Enhanced Visible and Infrared Imager (SEVIRI), on board the Meteosat Second Generation (MSG) geosynchronous satellite, has been carried out. The SO2 retrieval is validated vicariously by using satellite sensors and with ground measurements. The 24 November 2006 tropospheric eruption of Etna volcano is used as a test case. MSG-SEVIRI is an optical imaging radiometer characterized by 12 spectral channels, a high temporal resolution (one image every 15 minutes), and a 10 km2 footprint. The instrument’s spectral range includes the 7.3 and 8.7 mm bands (channels 6 and 7) used for SO2 retrieval and the 10.8 and 12.0 mm (channels 9 and 10) split window bands used for ash detection and retrievals. The SO2 columnar abundance and ash are retrieved simultaneously by means of a Look-Up Table least squares fit procedure for SO2 and using a Brightness Temperature Difference algorithm for ash. The SO2 retrievals obtained using different satellite sensors such as AIRS and MODIS have been carried out and compared with SEVIRI estimations. The results were validated using the permanent mini-DOAS ground system network (FLAME) installed and operated by INGV on Mt. Etna. Results show that the simultaneous presence of SO2 and ash in a volcanic plume yields a significant error in the SO2 columnar abundance retrieval in multispectral Thermal Infrared (TIR) data. The ash plume particles with high effective radius (from 1 to 10 mm) reduce the top of atmosphere radiance in the entire TIR spectral range, including the channels used for the SO2 retrieval. The net effect is a significant SO2 overestimation. To take this effect into account a novel ash correction procedure is presented and applied to the retrieval.
    Description: Unpublished
    Description: IAVCEI 2008 General Assembly Reykjavik - ICELAND 17-22 August
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: open
    Keywords: volcanic ash and SO2 retrievals ; MODIS retrievals ; MSG-SEVIRI retrievals ; ash correction procedure ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Poster session
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  • 100
    Publication Date: 2021-02-17
    Description: The number concentrations and size distributions of aerosol particles 〉0.3 mm diameter were measured at the summit of Mount Etna and up to 10 km downwind from the degassing vents during July and August 2004. Aerosol number concentrations reached in excess of 9 106 L 1 at summit vents, compared to 4–8 104 L 1 in background air. Number concentrations of intermediate size particles were higher in emissions from the Northeast crater compared to other summit crater vents, and chemical composition measurements showed that Northeast crater aerosols contained a higher mineral cation content compared to those from Voragine or Bocca Nuova, attributed to Strombolian or gas puffing activity within the vent. Downwind from the summit the airborne plume was located using zenith sky ultraviolet spectroscopy. Simultaneous measurements indicated a coincidence of elevated ground level aerosol concentrations with overhead SO2, demonstrating rapid downward mixing of the plume onto the lower flanks of the volcano under certain meteorological conditions. At downwind sites the ground level particle number concentrations were elevated in all size fractions, notably in the 2.0–7.5 mm size range. These findings are relevant for assessing human health hazard and suggest that aerosol size distribution measurements may aid volcanic risk management.
    Description: Published
    Description: D10302
    Description: JCR Journal
    Description: reserved
    Keywords: aerosols ; Mount Etna ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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