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  • Industrial Chemistry  (9,655)
  • Turbulence
  • Wiley-Blackwell  (9,681)
  • American Meteorological Society  (41)
  • American Geophysical Union  (14)
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  • 1
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2008. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 35 (2008): L08606, doi:10.1029/2008GL033532.
    Description: Turbulent-scale temperature and conductivity were measured during the pan-arctic Beringia 2005 Expedition. The rates of dissipation of thermal variance and diapycnal diffusivities are calculated along a section from Alaska to the North Pole, across deep flat basins (Canada and Makarov Basins) and steep ridges (Alpha-Mendeleev and Lomonosov Ridges). The mixing rates are observed to be small relative to lower latitudes but also remarkably non-uniform. Relatively elevated turbulence is found over deep topography, confirming the dominant role of bottom-generated internal waves. Measured patterns of mixing in the Arctic are also associated with other mechanisms, such as double-diffusive structures and deep overflows. A better knowledge of the distribution of mixing is essential to understand the dynamics of the changing Arctic environment.
    Description: This work was funded by the National Science Foundation through a Small Grant for Exploratory Research (ARC-0527874) and grant ARC-0612342 with additional support from the Doherty Foundation and internal WHOI Funds.
    Keywords: Turbulence ; Arctic ; Topography
    Repository Name: Woods Hole Open Access Server
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  • 2
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2004. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 109 (2004): C05004, doi:10.1029/2003JC002094.
    Description: Rates of turbulent kinetic energy (TKE) production and buoyancy flux in the region immediately seaward (~1 km) of a highly stratified estuarine front at the mouth of the Fraser River (British Columbia, Canada) are calculated using a control volume approach. The calculations are based on field data obtained from shipboard instrumentation, specifically velocity data from a ship mounted acoustic Doppler current profiler (ADCP), and salinity data from a towed conductivity-temperature-depth (CTD) unit. The results allow for the calculation of vertical velocities in the water column, and the total vertical transport of salt and momentum. The vertical turbulent transport quantities (inline equation, inline equation) can then be estimated as the difference between the total transport and the advective transport. Estimated production is on the order of 10−3 m2 s−3, yielding a value of ɛ(νN2)−1 on the order of 104. This rate of TKE production is at the upper limit of reported values for ocean and coastal environments. Flux Richardson numbers in this highly energetic system generally range from 0.15 to 0.2, with most mixing occurring at gradient Richardson numbers slightly less than inline equation. These values compare favorably with other values in the literature that are associated with turbulence observations from regimes characterized by scales several orders of magnitude smaller than are present in the Fraser River.
    Description: This work was performed as a part of D. MacDonald’s Ph.D. thesis, and was funded by Office of Naval Research grants N000-14-97-10134 and N000-14-97- 10566, National Science Foundation grant OCE-9906787, a National Science Foundation graduate fellowship, and support from the WHOI Academic Programs Office.
    Keywords: Turbulence ; Entrainment ; Estuary
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  • 3
    Publication Date: 2022-05-25
    Description: Author Posting. © American Meteorological Society, 2015. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 45 (2015): 2006–2024, doi:10.1175/JPO-D-14-0234.1.
    Description: The effects of wind-driven whitecapping on the evolution of the ocean surface boundary layer are examined using an idealized one-dimensional Reynolds-averaged Navier–Stokes numerical model. Whitecapping is parameterized as a flux of turbulent kinetic energy through the sea surface and through an adjustment of the turbulent length scale. Simulations begin with a two-layer configuration and use a wind that ramps to a steady stress. This study finds that the boundary layer begins to thicken sooner in simulations with whitecapping than without because whitecapping introduces energy to the base of the boundary layer sooner than shear production does. Even in the presence of whitecapping, shear production becomes important for several hours, but then inertial oscillations cause shear production and whitecapping to alternate as the dominant energy sources for mixing. Details of these results are sensitive to initial and forcing conditions, particularly to the turbulent length scale imposed by breaking waves and the transfer velocity of energy from waves to turbulence. After 1–2 days of steady wind, the boundary layer in whitecapping simulations has thickened more than the boundary layer in simulations without whitecapping by about 10%–50%, depending on the forcing and initial conditions.
    Description: We thank Skidmore College for financial and infrastructure support, and Skidmore and the National Science Foundation for funding travel to meetings where early versions of this work were presented. We also thank the National Science Foundation, Oregon State University, Jonathan Nash, and Joe Jurisa for funding and hosting a workshop on River Plume Mixing in October, 2013, where ideas and context for this paper were developed.
    Description: 2016-02-01
    Keywords: Circulation/ Dynamics ; Mixing ; Turbulence ; Wave breaking ; Wind stress ; Atm/Ocean Structure/ Phenomena ; Mixed layer
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  • 4
    Publication Date: 2022-05-25
    Description: Author Posting. © American Meteorological Society, 2018. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 48 (2018): 1555-1566, doi:10.1175/JPO-D-17-0231.1.
    Description: A primary challenge in modeling flow over shallow coral reefs is accurately characterizing the bottom drag. Previous studies over continental shelves and sandy beaches suggest surface gravity waves should enhance the drag on the circulation over coral reefs. The influence of surface gravity waves on drag over four platform reefs in the Red Sea is examined using observations from 6-month deployments of current and pressure sensors burst sampling at 1Hz for 4–5min. Depth-average current fluctuations U0 within each burst are dominated by wave orbital velocities uw that account for 80%–90%of the burst variance and have a magnitude of order 10 cm s21, similar to the lower-frequency depth-average current Uavg. Previous studies have shown that the cross-reef bottom stress balances the pressure gradient over these reefs. A bottom stress estimate that neglects the waves (rCdaUavgjUavgj, where r is water density and Cda is a drag coefficient) balances the observed pressure gradient when uw is smaller than Uavg but underestimates the pressure gradient when uw is larger than Uavg (by a factor of 3–5 when uw 5 2Uavg), indicating the neglected waves enhance the bottom stress. In contrast, a bottom stress estimate that includes the waves [rCda(Uavg 1 U0)jUavg 1 U0j)] balances the observed pressure gradient independent of the relative size of uw and Uavg, indicating that this estimate accounts for the wave enhancement of the bottom stress. A parameterization proposed by Wright and Thompson provides a reasonable estimate of the total bottom stress (including the waves) given the burst-averaged current and the wave orbital velocity.
    Description: The Red Sea field program was supported by Awards USA 00002 and KSA 00011 made by KAUST. S. Lentz was supported for the analysis by NSF Award OCE-1558343.
    Description: 2019-01-13
    Keywords: Coastal flows ; Currents ; Dynamics ; Gravity waves ; Turbulence
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  • 5
    Publication Date: 2022-05-25
    Description: Author Posting. © American Meteorological Society, 2009. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 39 (2009): 1077–1096, doi:10.1175/2008JPO4044.1.
    Description: Observations of turbulent kinetic energy (TKE) dynamics in the ocean surface boundary layer are presented here and compared with results from previous observational, numerical, and analytic studies. As in previous studies, the dissipation rate of TKE is found to be higher in the wavy ocean surface boundary layer than it would be in a flow past a rigid boundary with similar stress and buoyancy forcing. Estimates of the terms in the turbulent kinetic energy equation indicate that, unlike in a flow past a rigid boundary, the dissipation rates cannot be balanced by local production terms, suggesting that the transport of TKE is important in the ocean surface boundary layer. A simple analytic model containing parameterizations of production, dissipation, and transport reproduces key features of the vertical profile of TKE, including enhancement near the surface. The effective turbulent diffusion coefficient for heat is larger than would be expected in a rigid-boundary boundary layer. This diffusion coefficient is predicted reasonably well by a model that contains the effects of shear production, buoyancy forcing, and transport of TKE (thought to be related to wave breaking). Neglect of buoyancy forcing or wave breaking in the parameterization results in poor predictions of turbulent diffusivity. Langmuir turbulence was detected concurrently with a fraction of the turbulence quantities reported here, but these times did not stand out as having significant differences from observations when Langmuir turbulence was not detected.
    Description: The Office of Naval Research funded this work as a part of CBLAST-Low.
    Keywords: Turbulence ; Boundary layer ; Sea/ocean surface ; Air-sea interaction ; Energy transport
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  • 6
    Publication Date: 2022-05-25
    Description: Author Posting. © American Meteorological Society, 2007. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 37 (2007): 1764-1777, doi:10.1175/jpo3098.1.
    Description: The vertical structure of the dissipation of turbulence kinetic energy was observed in the nearshore region (3.2-m mean water depth) with a tripod of three acoustic Doppler current meters off a sandy ocean beach. Surface and bottom boundary layer dissipation scaling concepts overlap in this region. No depth-limited wave breaking occurred at the tripod, but wind-induced whitecapping wave breaking did occur. Dissipation is maximum near the surface and minimum at middepth, with a secondary maximum near the bed. The observed dissipation does not follow a surfzone scaling, nor does it follow a “log layer” surface or bottom boundary layer scaling. At the upper two current meters, dissipation follows a modified deep-water breaking-wave scaling. Vertical shear in the mean currents is negligible and shear production magnitude is much less than dissipation, implying that the vertical diffusion of turbulence is important. The increased near-bed secondary dissipation maximum results from a decrease in the turbulent length scale.
    Description: Funding was provided by NSF and ONR.
    Keywords: Turbulence ; Kinetic energy ; Ocean
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  • 7
    Publication Date: 2022-05-25
    Description: Author Posting. © American Meteorological Society, 2012. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 42 (2012): 2143–2152, doi:10.1175/JPO-D-12-027.1.
    Description: Direct measurements of turbulence levels in the Drake Passage region of the Southern Ocean show a marked enhancement over the Phoenix Ridge. At this site, the Antarctic Circumpolar Current (ACC) is constricted in its flow between the southern tip of South America and the northern tip of the Antarctic Peninsula. Observed turbulent kinetic energy dissipation rates are enhanced in the regions corresponding to the ACC frontal zones where strong flow reaches the bottom. In these areas, turbulent dissipation levels reach 10−8 W kg−1 at abyssal and middepths. The mixing enhancement in the frontal regions is sufficient to elevate the diapycnal turbulent diffusivity acting in the deep water above the axis of the ridge to 1 × 10−4 m2 s−1. This level is an order of magnitude larger than the mixing levels observed upstream in the ACC above smoother bathymetry. Outside of the frontal regions, dissipation rates are O(10−10) W kg−1, comparable to the background levels of turbulence found throughout most mid- and low-latitude regions of the global ocean.
    Description: This work was supported by the U.S. National Science Foundation and by the Natural Environment Research Council of the United Kingdom.
    Description: 2013-06-01
    Keywords: Southern Ocean ; Turbulence ; Diapycnal mixing
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  • 8
    Publication Date: 2022-05-25
    Description: Author Posting. © American Meteorological Society, 2018. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 48 (2018): 435-453, doi:10.1175/JPO-D-17-0122.1.
    Description: Observations of surface waves, currents, and turbulence at the Columbia River mouth are used to investigate the source and vertical structure of turbulence in the surface boundary layer. Turbulent velocity data collected on board freely drifting Surface Wave Instrument Float with Tracking (SWIFT) buoys are corrected for platform motions to estimate turbulent kinetic energy (TKE) and TKE dissipation rates. Both of these quantities are correlated with wave steepness, which has previously been shown to determine wave breaking within the same dataset. Estimates of the turbulent length scale increase linearly with distance from the free surface, and roughness lengths estimated from velocity statistics scale with significant wave height. The vertical decay of turbulence is consistent with a balance between vertical diffusion and dissipation. Below a critical depth, a power-law scaling commonly applied in the literature works well to fit the data. Above this depth, an exponential scaling fits the data well. These results, which are in a surface-following reference frame, are reconciled with results from the literature in a fixed reference frame. A mapping between free-surface and mean-surface reference coordinates suggests 30% of the TKE is dissipated above the mean sea surface.
    Description: Funding for this project was provided by the Office of Naval Research as part of the RIVET-II DRI, and for the DARLA group.
    Keywords: Ocean ; Estuaries ; Gravity waves ; Turbulence ; Wave breaking ; In situ oceanic observations
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  • 9
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2004. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 109 (2004): C10013, doi:10.1029/2003JC002194.
    Description: Dye release experiments were performed together with microstructure profiling to compare the two methods of estimating diapycnal diffusivity during summer and fall stratification on the continental shelf south of New England. The experiments were done in 1996 and 1997 as part of the Coastal Mixing and Optics Experiment. During the 100 hours or so of the experiments the area of the dye patches grew from less than 1 km2 to more than 50 km2 [ Sundermeyer and Ledwell, 2001 ]. Diapycnal diffusivities inferred from dye dispersion range from 10−6 to 10−5 m2/s at buoyancy frequencies from 9 to 28 cycles/hour. Diffusivities estimated from the dye and those estimated from dissipation rates in the companion paper by Oakey and Greenan [2004] agree closely in most cases. Estimates of diffusivities from towed conductivity microstructure measurements made during the cruises by Duda and Rehmann [2002] and Rehmann and Duda [2000] are fairly consistent with the dye diffusivities. The dye diffusivities would be predicted well by an empirical formula involving shear and stratification statistics developed by MacKinnon and Gregg [2003] from profiling microstructure measurements obtained at the same site in August 1996. All of the measurements support the general conclusion that the diffusivity, averaged over several days, is seldom greater than 10−5 m2/s in the stratified waters at the site, and usually not much greater than 10−6 m2/s. Severe storms, such as a hurricane that passed over the CMO site in 1996, can dramatically increase the mixing at the site, however.
    Description: This work was part of the ONR Coastal Mixing and Optics Experiment, and was funded by grants N00014-95-1- 0633, N00014-95-1-1063, N00014-95-1-1064, and N00014-01-1-0211. Completion of this paper was supported by the Edward W. and Ellyn B. Scripps Chair awarded to J. Ledwell. H. Seim’s participation was supported by ONR grant N00014-96-1-0616.
    Keywords: Dispersion ; Turbulence ; Continental shelf
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  • 10
    Publication Date: 2022-05-25
    Description: Author Posting. © American Meteorological Society, 2007. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 37 (2007): 1496-1511, doi:10.1175/jpo3071.1.
    Description: Measurements collected in the York River estuary, Virginia, demonstrate the important impact that tidal and lateral asymmetries in turbulent mixing have on the tidally averaged residual circulation. A reduction in turbulent mixing during the ebb phase of the tide caused by tidal straining of the axial density gradient results in increased vertical velocity shear throughout the water column during the ebb tide. In the absence of significant lateral differences in turbulent mixing, the enhanced ebb-directed transport caused by tidal straining is balanced by a reduction in the net seaward-directed barotropic pressure gradient, resulting in laterally uniform two-layer residual flow. However, the channel–shoal morphology of many drowned river valley estuaries often leads to lateral gradients in turbulent mixing. Tidal straining may then lead to tidal asymmetries in turbulent mixing near the deeper channel while the neighboring shoals remain relatively well mixed. As a result, the largest lateral asymmetries in turbulent mixing occur at the end of the ebb tide when the channel is significantly more stratified than the shoals. The reduced friction at the end of ebb delays the onset of the flood tide, increasing the duration of ebb in the channel. Conversely, over the shoal regions where stratification is more inhibited by tidal mixing, there is greater friction and the transition from ebb to flood occurs more rapidly. The resulting residual circulation is seaward over the channel and landward over the shoal. The shoal–channel segregation of this barotropically induced estuarine residual flow is opposite to that typically associated with baroclinic estuarine circulation over channel–shoal bathymetry.
    Description: Support for this research was provided by the National Science Foundation Division of Ocean Sciences Grant OCE- 9984941.
    Keywords: Tides ; Ocean circulation ; Estuaries ; Turbulence
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  • 11
    Publication Date: 2022-05-25
    Description: Author Posting. © American Meteorological Society, 2007. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography. 37 (2007): 2363-2386, doi:10.1175/jpo3118.1.
    Description: Intrinsic low-frequency variability is studied in the idealized, quasigeostrophic, midlatitude, wind-driven ocean gyres operating at large Reynolds number. A robust decadal variability mode driven by the transient mesoscale eddies is found and analyzed. The variability is a turbulent phenomenon, which is driven by the competition between the eddy rectification process and the potential vorticity anomalies induced by changes of the intergyre transport
    Description: Funding for Pavel Berloff was provided by NSF Grants OCE-0091836 and OCE- 0344094, by the U.K. Royal Society Fellowship, and by the Newton Trust Award, A. M. Hogg was supported by an Australian Research Council Postdoctoral Fellowship (DP0449851) during this work, and William K. Dewar was supported by NSF Grants OCE-0424227 and OCE-0550139.
    Keywords: Turbulence ; Gyres ; Transport ; Potential vorticity ; Mesoscale processes
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  • 12
    Publication Date: 2022-05-25
    Description: Author Posting. © American Meteorological Society, 2011. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 41 (2011): 166-185, doi:10.1175/2010JPO4470.1.
    Description: Field observations of turbulent kinetic energy (TKE), dissipation rate ε, and turbulent length scale demonstrate the impact of both density stratification and nonlocal turbulent production on turbulent momentum flux. The data were collected in a highly stratified salt wedge estuary using the Mobile Array for Sensing Turbulence (MAST). Estimates of the dominant length scale of turbulent motions obtained from the vertical velocity spectra provide field confirmation of the theoretical limitation imposed by either the distance to the boundary or the Ozmidov scale, whichever is smaller. Under boundary-limited conditions, anisotropy generally increases with increasing shear and decreased distance to the boundary. Under Ozmidov-limited conditions, anisotropy increases rapidly when the gradient Richardson number exceeds 0.25. Both boundary-limited and Ozmidov-limited conditions demonstrate significant deviations from a local production–dissipation balance that are largely consistent with simple scaling relationships for the vertical divergence in TKE flux. Both the impact of stratification and deviation from equilibrium turbulence observed in the data are largely consistent with commonly used turbulence closure models that employ “nonequilibrium” stability functions. The data compare most favorably with the nonequilibrium version of the L. H. Kantha and C. A. Clayson stability functions. Not only is this approach more consistent with the observed critical gradient Richardson number of 0.25, but it also accounts for the large deviations from equilibrium turbulence in a manner consistent with the observations.
    Description: The funding for this research was obtained from ONR Grant N00014-06-1-0292 and NSF Grants and OCE-08-25226 and OCE-08-24871.
    Keywords: Turbulence ; Estuaries ; Kinetic energy
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  • 13
    Publication Date: 2022-05-25
    Description: Author Posting. © American Meteorological Society, 2012. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 42 (2012): 855–868, doi:10.1175/JPO-D-10-05010.1.
    Description: Data from the Hudson River estuary demonstrate that the tidal variations in vertical salinity stratification are not consistent with the patterns associated with along-channel tidal straining. These observations result from three additional processes not accounted for in the traditional tidal straining model: 1) along-channel and 2) lateral advection of horizontal gradients in the vertical salinity gradient and 3) tidal asymmetries in the strength of vertical mixing. As a result, cross-sectionally averaged values of the vertical salinity gradient are shown to increase during the flood tide and decrease during the ebb. Only over a limited portion of the cross section does the observed stratification increase during the ebb and decrease during the flood. These observations highlight the three-dimensional nature of estuarine flows and demonstrate that lateral circulation provides an alternate mechanism that allows for the exchange of materials between surface and bottom waters, even when direct turbulent mixing through the pycnocline is prohibited by strong stratification.
    Description: The funding for this research was obtained from NSF Grant OCE-08-25226.
    Description: 2012-11-01
    Keywords: Mixing ; Ocean circulation ; Shear structure/flows ; Transport ; Turbulence
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  • 14
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2012. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 39 (2012): L24604, doi:10.1029/2012GL054034.
    Description: Eddies and vortices associated with breaking waves rapidly disperse pollution, nutrients, and terrestrial material along the coast. Although theory and numerical models suggest that vorticity is generated near the ends of a breaking wave crest, this hypothesis has not been tested in the field. Here we report the first observations of wave-generated vertical vorticity (e.g., horizontal eddies), and find that individual short-crested breaking waves generate significant vorticity [O(0.01 s−1)] in the surfzone. Left- and right-handed wave ends generate vorticity of opposite sign, consistent with theory. In contrast to theory, the observed vorticity also increases inside the breaking crest, possibly owing to onshore advection of vorticity generated at previous stages of breaking or from the shape of the breaking region. Short-crested breaking transferred energy from incident waves to lower frequency rotational motions that are a primary mechanism for dispersion near the shoreline.
    Description: Funding was provided by a National Security Science and Engineering Faculty Fellowship, the Office of Naval Research, and a Woods Hole Oceanographic Institution Postdoctoral Fellowship.
    Description: 2013-06-21
    Keywords: Mixing ; Nearshore ; Turbulence ; Vorticity ; Waves
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  • 15
    Publication Date: 2022-05-25
    Description: Author Posting. © American Meteorological Society, 2013. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 43 (2013): 259–282, doi:10.1175/JPO-D-11-0194.1.
    Description: This study reports on observations of turbulent dissipation and internal wave-scale flow properties in a standing meander of the Antarctic Circumpolar Current (ACC) north of the Kerguelen Plateau. The authors characterize the intensity and spatial distribution of the observed turbulent dissipation and the derived turbulent mixing, and consider underpinning mechanisms in the context of the internal wave field and the processes governing the waves’ generation and evolution. The turbulent dissipation rate and the derived diapycnal diffusivity are highly variable with systematic depth dependence. The dissipation rate is generally enhanced in the upper 1000–1500 m of the water column, and both the dissipation rate and diapycnal diffusivity are enhanced in some places near the seafloor, commonly in regions of rough topography and in the vicinity of strong bottom flows associated with the ACC jets. Turbulent dissipation is high in regions where internal wave energy is high, consistent with the idea that interior dissipation is related to a breaking internal wave field. Elevated turbulence occurs in association with downward-propagating near-inertial waves within 1–2 km of the surface, as well as with upward-propagating, relatively high-frequency waves within 1–2 km of the seafloor. While an interpretation of these near-bottom waves as lee waves generated by ACC jets flowing over small-scale topographic roughness is supported by the qualitative match between the spatial patterns in predicted lee wave radiation and observed near-bottom dissipation, the observed dissipation is found to be only a small percentage of the energy flux predicted by theory. The mismatch suggests an alternative fate to local dissipation for a significant fraction of the radiated energy.
    Description: SW acknowledges the support of the Grantham Institute for Climate Change, Imperial College London. ACNG acknowledges the support of a NERC Advanced Research Fellowship (Grant NE/C517633/1). KLP acknowledges support from Woods Hole Oceanographic Institution bridge support funds.
    Description: 2013-08-01
    Keywords: Diapycnal mixing ; Internal waves ; Turbulence
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  • 16
    Publication Date: 2022-05-25
    Description: Author Posting. © American Meteorological Society, 2018. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 48 (2018): 905-923, doi:10.1175/JPO-D-17-0133.1.
    Description: Observations of turbulent kinetic energy, dissipation, and turbulent stress were collected in the middle reaches of Chesapeake Bay and were used to assess second-moment closure predictions of turbulence generated beneath breaking waves. Dissipation scaling indicates that the turbulent flow structure observed during a 10-day wind event was dominated by a three-layer response that consisted of 1) a wave transport layer, 2) a surface log layer, and 3) a tidal, bottom boundary layer limited by stable stratification. Below the wave transport layer, turbulent mixing was limited by stable stratification. Within the wave transport layer, where dissipation was balanced by a divergence in the vertical turbulent kinetic energy flux, the eddy viscosity was significantly underestimated by second-moment turbulence closure models, suggesting that breaking waves homogenized the mixed surface layer to a greater extent than the simple model of TKE diffusing away from a source at the surface. While the turbulent transport of TKE occurred largely downgradient, the intermittent downward sweeps of momentum generated by breaking waves occurred largely independent of the mean shear. The underprediction of stress in the wave transport layer by second-moment closures was likely due to the inability of the eddy viscosity model to capture the nonlocal turbulent transport of the momentum flux beneath breaking waves. Finally, the authors hypothesize that large-scale coherent turbulent eddies played a significant role in transporting momentum generated near the surface to depth.
    Description: This work was supported by National Science Foundation Grants OCE-1061609 and OCE-1339032.
    Description: 2018-10-19
    Keywords: Mixing ; Turbulence ; Waves, oceanic ; Boundary layer
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  • 17
    Publication Date: 2022-05-25
    Description: Author Posting. © American Meteorological Society, 2018. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 48 (2018): 1815-1830, doi:10.1175/JPO-D-17-0275.1.
    Description: Recent progress in direct numerical simulations (DNSs) of stratified turbulent flows has led to increasing attention to the validity of the constancy of the dissipation flux coefficient Γ in the Osborn’s eddy diffusivity model. Motivated by lack of observational estimates of Γ, particularly under weakly stratified deep-ocean conditions, this study estimates Γ using deep microstructure profiles collected in various regions of the North Pacific and Southern Oceans. It is shown that Γ is not constant but varies significantly with the Ozmidov/Thorpe scale ratio ROT in a fashion similar to that obtained by previous DNS studies. Efficient mixing events with Γ ~ O(1) and ROT ~ O(0.1) tend to be frequently observed in the deep ocean (i.e., weak stratification), while moderate mixing events with Γ ~ O(0.1) and ROT ~ O(1) tend to be observed in the upper ocean (i.e., strong stratification). The observed negative relationship between Γ and ROT is consistent with a simple scaling that can be derived from classical turbulence theories. In contrast, the observed results exhibit no definite relationships between Γ and the buoyancy Reynolds number Reb, although Reb has long been thought to be another key parameter that controls Γ.
    Description: This study was supported by MEXT KAKENHI Grant JP15H05824 and JSPS KAKENHI Grant JP15H02131.
    Description: 2019-02-15
    Keywords: Abyssal circulation ; Mixing ; Subgrid-scale processes ; Turbulence ; In situ oceanic observations
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  • 18
    Publication Date: 2022-05-25
    Description: Author Posting. © American Meteorological Society, 2018. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 48 (2018):1941-1950, doi:10.1175/JPO-D-17-0194.1.
    Description: Subglacial discharges have been observed to generate buoyant plumes along the ice face of Greenland tidewater glaciers. These plumes have been traditionally modeled using classical plume theory, and their characteristic parameters (e.g., velocity) are employed in the widely used three-equation melt parameterization. However, the applicability of plume theory for three-dimensional turbulent wall plumes is questionable because of the complex near-wall plume dynamics. In this study, corrections to the classical plume theory are introduced to account for the presence of a wall. In particular, the drag and entrainment coefficients are quantified for a three-dimensional turbulent wall plume using data from direct numerical simulations. The drag coefficient is found to be an order of magnitude larger than that for a boundary layer flow over a flat plate at a similar Reynolds number. This result suggests a significant increase in the melting estimates by the current parameterization. However, the volume flux in a wall plume is found to be one-half that of a conical plume that has 2 times the buoyancy flux. This finding suggests that the total entrainment (per unit area) of ambient water is the same and that the plume scalar characteristics (i.e., temperature and salinity) can be predicted reasonably well using classical plume theory.
    Description: This work was supported by the Linné FLOW Centre at KTH and the Academy of Finland Center of Excellence Programme Grant 307331 (author Ezhova) and by VR Swedish Research Council GrantVR2014-5001 (author Brandt). Support to author Cenedese was given by NSF Project OCE-1434041.
    Description: 2019-02-27
    Keywords: Buoyancy ; Entrainment ; Turbulence
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  • 19
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2006. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 111 (2006): C02006, doi:10.1029/2005JC003011.
    Description: Net northward transport below γn 〉 28.1 kgm−3 (≈3200 m) into the Perth Basin of between 4.4 and 5.8 Sv is estimated from a year-long current meter mooring array between the Broken and Naturaliste Plateaus. Northward transport of between 2.0 and 2.5 Sv of Antarctic Bottom Water (γn 〉28.2 kgm−3), that must upwell within the southern region of the Perth Basin, results in an area-averaged diapycnal velocity and diffusivity of w*=2.5− 3.1× 10−6 ms−1 and κ = 13−15×10−4 m2s−1, respectively. Diffusivity estimates for the Perth Basin are several times larger than area averaged mixing estimates for the abyssal subtropical South Atlantic and Pacific Oceans. However, the dissipation of turbulent kinetic energy required to maintain the abyssal mixing in the Perth basin, ε=O(10−9 Wkg−1), is similar to that required in the South Atlantic Ocean. The area-averaged diffusivity in the Perth Basin does not require unreasonable energy dissipation rates as this ocean basin is only weakly stratified. The abyssal diffuvisity of the Perth Basin results from intense mixing at the basin boundary and in the basin interior over rough topography. The complex bathymetry and low abyssal stratification suggests that the Indian Ocean, for a given energy dissipation, may support a larger meridional overturning circulation than other subtropical basins.
    Description: BMS was supported by funds from the Ocean and Climate Change Institute at the Woods Hole Oceanographic Institution, and The James S. Cole and Cecily C. Selby Endowed Fund and The Penzance Endowed Fund in support of Assistant Scientists. The mooring array was funded by Australia’s CSIRO Marine Research.
    Keywords: Water masses ; Deep recirculation and transport ; Turbulence ; Diffusion ; Indian Ocean
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  • 20
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2009. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 114 (2009): C07009, doi:10.1029/2008JC005008.
    Description: Results from a rain and gas exchange experiment (Bio2 RainX III) at the Biosphere 2 Center demonstrate that turbulence controls the enhancement of the air-sea gas transfer rate (or velocity) k during rainfall, even though profiles of the turbulent dissipation rate ɛ are strongly influenced by near-surface stratification. The gas transfer rate scales with ɛ inline equation for a range of rain rates with broad drop size distributions. The hydrodynamic measurements elucidate the mechanisms responsible for the rain-enhanced k results using SF6 tracer evasion and active controlled flux technique. High-resolution k and turbulence results highlight the causal relationship between rainfall, turbulence, stratification, and air-sea gas exchange. Profiles of ɛ beneath the air-sea interface during rainfall, measured for the first time during a gas exchange experiment, yielded discrete values as high as 10−2 W kg−1. Stratification modifies and traps the turbulence near the surface, affecting the enhancement of the transfer velocity and also diminishing the vertical mixing of mass transported to the air-water interface. Although the kinetic energy flux is an integral measure of the turbulent input to the system during rain events, ɛ is the most robust response to all the modifications and transformations to the turbulent state that follows. The Craig-Banner turbulence model, modified for rain instead of breaking wave turbulence, successfully predicts the near-surface dissipation profile at the onset of the rain event before stratification plays a dominant role. This result is important for predictive modeling of k as it allows inferring the surface value of ɛ fundamental to gas transfer.
    Description: This work was funded by a generous grant from the David and Lucile Packard Foundation and the Lamont-Doherty Earth Observatory Climate Center. Additional funding was provided by the National Science Foundation (OCE-05-26677) and the Office of Naval Research Young Investigator Program (N00014-04-1-0621).
    Keywords: Turbulence ; Rain ; Gas transfer
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  • 21
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2010. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 37 (2010): L22607, doi:10.1029/2010GL045272.
    Description: Shear instability is the dominant mechanism for converting fluid motion to mixing in the stratified ocean and atmosphere. The transition to turbulence has been well characterized in laboratory settings and numerical simulations at moderate Reynolds number—it involves “rolling up”, i.e., overturning of the density structure within the cores of the instabilities. In contrast, measurements in an energetic estuarine shear zone reveal that the mixing induced by shear instability at high Reynolds number does not primarily occur by overturning in the cores; rather it results from secondary shear instabilities within the zones of intensified shear separating the cores. This regime is not likely to be observed in the relatively low Reynolds number flows of the laboratory or in direct numerical simulations, but it is likely a common occurrence in the ocean and atmosphere.
    Description: This research was supported by NSF grant OCE‐0824871 and ONR grant N00014‐0810495.
    Keywords: Stratification ; Turbulence ; Mixing
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  • 22
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2010. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 115 (2010): C12024, doi:10.1029/2009JC006061.
    Description: Turbulent mixing of salt is examined in a shallow salt wedge estuary with strong fluvial and tidal forcing. A numerical model of the Merrimack River estuary is used to quantify turbulent stress, shear production, and buoyancy flux. Little mixing occurs during flood tides despite strong velocities because bottom boundary layer turbulence is dislocated from stratification elevated in the water column. During ebbs, bottom salinity fronts form at a series of bathymetric transitions. At the fronts, near-bottom velocity and shear stress are low, but shear, stress, and buoyancy flux are elevated at the pycnocline. Internal shear layers provide the dominant source of mixing during the early ebb. Later in the ebb, the pycnocline broadens and moves down such that boundary layer turbulence dominates mixing. Mixing occurs primarily during ebbs, with internal shear mixing accounting for about 50% of the total buoyancy flux. Both the relative contribution of internal shear mixing and the mixing efficiency increase with discharge, with bulk mixing efficiencies between 0.02 and 0.07. Buoyancy fluxes in the estuary increase with discharge up to about 400 m3 s−1 above which a majority of the mixing occurs offshore. Observed buoyancy fluxes were more consistent with the k-ɛ turbulence closure than the Mellor-Yamada closure, and more total mixing occurred in the estuary with k-ɛ. Calculated buoyancy fluxes were sensitive to horizontal grid resolution, as a lower resolution grid yielded less integrated buoyancy flux in the estuary and exported lower salinity water but likely had greater numerical mixing.
    Description: This research was funded by National Science Foundation Grant OCE‐0452054. Ralston also received support from The Penzance Endowed Fund in Support of Assistant Scientists and The John F. and Dorothy H. Magee Fund in Support of Scientific Staff at Woods Hole Oceanographic Institution.
    Keywords: Mixing ; Turbulence ; Salt wedge estuary
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  • 23
    Publication Date: 2022-05-25
    Description: Author Posting. © American Meteorological Society, 2011. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 41 (2011): 2223–2241, doi:10.1175/2011JPO4344.1.
    Description: Results are presented from an observational study of stratified, turbulent flow in the bottom boundary layer on the outer southeast Florida shelf. Measurements of momentum and heat fluxes were made using an array of acoustic Doppler velocimeters and fast-response temperature sensors in the bottom 3 m over a rough reef slope. Direct estimates of flux Richardson number Rf confirm previous laboratory, numerical, and observational work, which find mixing efficiency not to be a constant but rather to vary with Frt, Reb, and Rig. These results depart from previous observations in that the highest levels of mixing efficiency occur for Frt 〈 1, suggesting that efficient mixing can also happen in regions of buoyancy-controlled turbulence. Generally, the authors find that turbulence in the reef bottom boundary layer is highly variable in time and modified by near-bed flow, shear, and stratification driven by shoaling internal waves.
    Description: Funding was provided by grants from the National Oceanic and Atmospheric Administration’s National Undersea Research Program, National Science Foundation Grants OCE-0622967 and OCE- 0824972 to SGM, and the Singapore Stanford Program. Kristen Davis was supported by a National Defense Science and Engineering Graduate Fellowship and an ARCS Foundation Fellowship.
    Keywords: Boundary layer ; Turbulence ; Bottom currents ; Mixing ; Internal waves
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  • 24
    Publication Date: 2022-05-25
    Description: Author Posting. © American Meteorological Society, 2015. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 45 (2015): 2381–2406, doi:10.1175/JPO-D-14-0086.1.
    Description: While near-inertial waves are known to be generated by atmospheric storms, recent observations in the Kuroshio Front find intense near-inertial internal-wave shear along sloping isopycnals, even during calm weather. Recent literature suggests that spontaneous generation of near-inertial waves by frontal instabilities could represent a major sink for the subinertial quasigeostrophic circulation. An unforced three-dimensional 1-km-resolution model, initialized with the observed cross-Kuroshio structure, is used to explore this mechanism. After several weeks, the model exhibits growth of 10–100-km-scale frontal meanders, accompanied by O(10) mW m−2 spontaneous generation of near-inertial waves associated with readjustment of submesoscale fronts forced out of balance by mesoscale confluent flows. These waves have properties resembling those in the observations. However, they are reabsorbed into the model Kuroshio Front with no more than 15% dissipating or radiating away. Thus, spontaneous generation of near-inertial waves represents a redistribution of quasigeostrophic energy rather than a significant sink.
    Description: “The Study of Kuroshio Ecosystem Dynamics for Sustainable Fisheries (SKED)” supported by MEXT, MIT-Hayashi Seed Fund, ONR (Awards N000140910196 and N000141210101), NSF (Award OCE 0928617, 0928138) for support.
    Description: 2016-03-01
    Keywords: Circulation/ Dynamics ; Frontogenesis/frontolysis ; Fronts ; Internal waves ; Turbulence ; Upwelling/downwelling ; Atm/Ocean Structure/ Phenomena ; Jets
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  • 25
    Publication Date: 2022-05-25
    Description: Author Posting. © American Meteorological Society, 2015. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 45 (2015): 2497–2521, doi:10.1175/JPO-D-14-0128.1.
    Description: Oceanic density overturns are commonly used to parameterize the dissipation rate of turbulent kinetic energy. This method assumes a linear scaling between the Thorpe length scale LT and the Ozmidov length scale LO. Historic evidence supporting LT ~ LO has been shown for relatively weak shear-driven turbulence of the thermocline; however, little support for the method exists in regions of turbulence driven by the convective collapse of topographically influenced overturns that are large by open-ocean standards. This study presents a direct comparison of LT and LO, using vertical profiles of temperature and microstructure shear collected in the Luzon Strait—a site characterized by topographically influenced overturns up to O(100) m in scale. The comparison is also done for open-ocean sites in the Brazil basin and North Atlantic where overturns are generally smaller and due to different processes. A key result is that LT/LO increases with overturn size in a fashion similar to that observed in numerical studies of Kelvin–Helmholtz (K–H) instabilities for all sites but is most clear in data from the Luzon Strait. Resultant bias in parameterized dissipation is mitigated by ensemble averaging; however, a positive bias appears when instantaneous observations are depth and time integrated. For a series of profiles taken during a spring tidal period in the Luzon Strait, the integrated value is nearly an order of magnitude larger than that based on the microstructure observations. Physical arguments supporting LT ~ LO are revisited, and conceptual regimes explaining the relationship between LT/LO and a nondimensional overturn size are proposed. In a companion paper, Scotti obtains similar conclusions from energetics arguments and simulations.
    Description: B.D.M. and S.K.V. gratefully acknowledge the support of the Office of Naval Research under Grants N00014-12-1-0279, N00014-12-1-0282, and N00014-12-1-0938 (Program Manager: Dr. Terri Paluszkiewicz). S.K.V. also acknowledges support of the National Science Foundation under Grant OCE-1151838. L.S.L. acknowledges support for BBTRE by the National Science Foundation by Contract OCE94-15589 and NATRE and IWISE by the Office of Naval Research by Contracts N00014-92-1323 and N00014-10-10315. J.N.M. was supported through Grant 1256620 from the National Science Foundation and the Office of Naval Research (IWISE Project).
    Description: 2016-04-01
    Keywords: Circulation/ Dynamics ; Diapycnal mixing ; Small scale processes ; Turbulence ; Atm/Ocean Structure/ Phenomena ; Mixing ; Observational techniques and algorithms ; Profilers, oceanic ; Models and modeling ; Parameterization
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  • 26
    Publication Date: 2022-05-25
    Description: Author Posting. © American Meteorological Society, 2015. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 45 (2015): 2621–2639, doi:10.1175/JPO-D-14-0239.1.
    Description: Measurements made as part of a large-scale experiment to examine wind-driven circulation and mixing in Chesapeake Bay demonstrate that circulations consistent with Langmuir circulation play an important role in surface boundary layer dynamics. Under conditions when the turbulent Langmuir number Lat is low (〈0.5), the surface mixed layer is characterized by 1) elevated vertical turbulent kinetic energy; 2) decreased anisotropy; 3) negative vertical velocity skewness indicative of strong/narrow downwelling and weak/broad upwelling; and 4) strong negative correlations between low-frequency vertical velocity and the velocity in the direction of wave propagation. These characteristics appear to be primarily the result of the vortex force associated with the surface wave field, but convection driven by a destabilizing heat flux is observed and appears to contribute significantly to the observed negative vertical velocity skewness. Conditions that favor convection usually also have strong Langmuir forcing, and these two processes probably both contribute to the surface mixed layer turbulence. Conditions in which traditional stress-driven turbulence is important are limited in this dataset. Unlike other shallow coastal systems where full water column Langmuir circulation has been observed, the salinity stratification in Chesapeake Bay is nearly always strong enough to prevent full-depth circulation from developing.
    Description: The funding for this research was provided by the National Science Foundation Grants OCE-1339032 and OCE-1338518.
    Description: 2016-04-01
    Keywords: Circulation/ Dynamics ; Convection ; Instability ; Mixing ; Turbulence ; Wave breaking ; Wind stress
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  • 27
    Publication Date: 2022-05-25
    Description: Author Posting. © American Meteorological Society, 2016. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 46 (2016): 3155-3163, doi:10.1175/JPO-D-16-0123.1.
    Description: Idealized laboratory experiments have been conducted in a two-layer stratified fluid to investigate the leading-order dynamics that control submarine melting and meltwater export near a vertical ice–ocean interface as a function of subglacial discharge. In summer, the discharge of surface runoff at the base of a glacier (subglacial discharge) generates strong buoyant plumes that rise along the glacier front entraining ambient water along the way. The entrainment enhances the heat transport toward the glacier front and hence the submarine melt rate increases with the subglacial discharge rate. In the laboratory, the effect of subglacial discharge is simulated by introducing freshwater at freezing temperature from a point source at the base of an ice block representing the glacier. The circulation pattern observed both with and without subglacial discharge resembles those observed in previous observational and numerical studies. Buoyant plumes rise vertically until they find either their neutrally buoyant level or the free surface. Hence, the meltwater can deposit within the interior of the water column and not entirely at the free surface, as confirmed by field observations. The heat budget in the tank, calculated following a new framework, gives estimates of submarine melt rate that increase with the subglacial discharge and are in agreement with the directly measured submarine melting. This laboratory study provides the first direct measurements of submarine melt rates for different subglacial discharges, and the results are consistent with the predictions of previous theoretical and numerical studies.
    Description: Support to C. C. was given by the NSF project OCE- 1130008 and OCE-1434041. M. G. received support from the ‘‘Gori’’ Fellowship.
    Description: 2017-04-07
    Keywords: Glaciers ; Buoyancy ; Density currents ; Turbulence ; Laboratory/physical models
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  • 28
    Publication Date: 2022-05-26
    Description: Author Posting. © American Meteorological Society, 2010. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 40 (2010): 2381-2400, doi:10.1175/2010JPO4403.1.
    Description: Langmuir circulation (LC) is a turbulent upper-ocean process driven by wind and surface waves that contributes significantly to the transport of momentum, heat, and mass in the oceanic surface layer. The authors have previously performed a direct comparison of large-eddy simulations and observations of the upper-ocean response to a wind event with rapid mixed layer deepening. The evolution of simulated crosswind velocity variance and spatial scales, as well as mixed layer deepening, was only consistent with observations if LC effects are included in the model. Based on an analysis of these validated simulations, in this study the fundamental differences in mixing between purely shear-driven turbulence and turbulence with LC are identified. In the former case, turbulent kinetic energy (TKE) production due to shear instabilities is largest near the surface, gradually decreasing to zero near the base of the mixed layer. This stands in contrast to the LC case in which at middepth range TKE production can be dominated by Stokes drift shear. Furthermore, the Eulerian mean vertical shear peaks near the base of the mixed layer so that TKE production by mean shear flow is elevated there. LC transports horizontal momentum efficiently downward leading to an along-wind velocity jet below LC downwelling regions at the base of the mixed layer. Locally enhanced vertical shear instabilities as a result of this jet efficiently erode the thermocline. In turn, enhanced breaking internal waves inject cold deep water into the mixed layer, where LC currents transport temperature perturbation advectively. Thus, LC and locally generated shear instabilities work intimately together to facilitate strongly the mixed layer deepening process.
    Description: This research was supported by the Office of Naval Research through Grants N00014-09-M-0112 (TK) and N00014-06-1-0178 (AP, JT). Author TK also received support from a Woods Hole Oceanographic Institution Cooperative Institute for Climate and Ocean Research Postdoctoral Scholarship.
    Keywords: Mixed layer ; Shear structure/flows ; Wind effects ; Turbulence ; Thermocline ; Internal waves ; Advection
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  • 29
    Publication Date: 2022-05-26
    Description: Author Posting. © American Meteorological Society, 2013. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 43 (2013): 1841–1861, doi:10.1175/JPO-D-12-0231.1.
    Description: In this idealized numerical modeling study, the composition of residual sediment fluxes in energetic (e.g., weakly or periodically stratified) tidal estuaries is investigated by means of one-dimensional water column models, with some focus on the sediment availability. Scaling of the underlying dynamic equations shows dependence of the results on the Simpson number (relative strength of horizontal density gradient) and the Rouse number (relative settling velocity) as well as impacts of the Unsteadiness number (relative tidal frequency). Here, the parameter space given by the Simpson and Rouse numbers is mainly investigated. A simple analytical model based on the assumption of stationarity shows that for small Simpson and Rouse numbers sediment flux is down estuary and vice versa for large Simpson and Rouse numbers. A fully dynamic water column model coupled to a second-moment turbulence closure model allows to decompose the sediment flux profiles into contributions from the transport flux (product of subtidal velocity and sediment concentration profiles) and the fluctuation flux profiles (tidal covariance between current velocity and sediment concentration). Three different types of bottom sediment pools are distinguished to vary the sediment availability, by defining a time scale for complete sediment erosion. For short erosion times scales, the transport sediment flux may dominate, but for larger erosion time scales the fluctuation sediment flux largely dominates the tidal sediment flux. When quarter-diurnal components are added to the tidal forcing, up-estuary sediment fluxes are strongly increased for stronger and shorter flood tides and vice versa. The theoretical results are compared to field observations in a tidally energetic inlet.
    Description: Project funding was provided by the German Research Foundation (DFG) in the framework of the Project ECOWS (Role of Estuarine Circulation for Transport of Suspended Particulate Matter in the Wadden Sea, BU 1199/11) and by the German Federal Ministry of Research and Education in the framework of the Project PACE [The future of the Wadden Sea sediment fluxes: still keeping pace with sea level rise? (FKZ 03F0634A)].
    Description: 2014-03-01
    Keywords: Channel flows ; Coastal flows ; Mixing ; Transport ; Turbulence ; Single column models
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  • 30
    Publication Date: 2022-05-26
    Description: Author Posting. © American Meteorological Society, 2014. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 44 (2014): 1466–1492, doi:10.1175/JPO-D-12-0154.1.
    Description: Simultaneous full-depth microstructure measurements of turbulence and finestructure measurements of velocity and density are analyzed to investigate the relationship between turbulence and the internal wave field in the Antarctic Circumpolar Current. These data reveal a systematic near-bottom overprediction of the turbulent kinetic energy dissipation rate by finescale parameterization methods in select locations. Sites of near-bottom overprediction are typically characterized by large near-bottom flow speeds and elevated topographic roughness. Further, lower-than-average shear-to-strain ratios indicative of a less near-inertial wave field, rotary spectra suggesting a predominance of upward internal wave energy propagation, and enhanced narrowband variance at vertical wavelengths on the order of 100 m are found at these locations. Finally, finescale overprediction is typically associated with elevated Froude numbers based on the near-bottom shear of the background flow, and a background flow with a systematic backing tendency. Agreement of microstructure- and finestructure-based estimates within the expected uncertainty of the parameterization away from these special sites, the reproducibility of the overprediction signal across various parameterization implementations, and an absence of indications of atypical instrument noise at sites of parameterization overprediction, all suggest that physics not encapsulated by the parameterization play a role in the fate of bottom-generated waves at these locations. Several plausible underpinning mechanisms based on the limited available evidence are discussed that offer guidance for future studies.
    Description: The SOFine project is funded by the United Kingdom’s Natural Environmental Research Council (NERC) (Grant NE/G001510/1). SW acknowledges the support of anARCDiscovery Early CareerResearchAward (Grant DE120102927), as well as the Grantham Institute for Climate Change, Imperial College London, and the ARC Centre of Excellence for Climate System Science (Grant CE110001028). ACNG acknowledges the support of a NERC Advanced Research Fellowship (Grant NE/C517633/1).KLP acknowledges support fromWoods Hole Oceanographic Institution bridge support funds.
    Description: 2014-11-01
    Keywords: Circulation/ Dynamics ; Diapycnal mixing ; Internal waves ; Small scale processes ; Turbulence ; Observational techniques and algorithms ; In situ oceanic observations ; Profilers, oceanic
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  • 31
    Publication Date: 2022-05-26
    Description: Author Posting. © American Meteorological Society, 2014. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 44 (2014): 2593–2616, doi:10.1175/JPO-D-13-0120.1.
    Description: The first direct estimate of the rate at which geostrophic turbulence mixes tracers across the Antarctic Circumpolar Current is presented. The estimate is computed from the spreading of a tracer released upstream of Drake Passage as part of the Diapycnal and Isopycnal Mixing Experiment in the Southern Ocean (DIMES). The meridional eddy diffusivity, a measure of the rate at which the area of the tracer spreads along an isopycnal across the Antarctic Circumpolar Current, is 710 ± 260 m2 s−1 at 1500-m depth. The estimate is based on an extrapolation of the tracer-based diffusivity using output from numerical tracers released in a one-twentieth of a degree model simulation of the circulation and turbulence in the Drake Passage region. The model is shown to reproduce the observed spreading rate of the DIMES tracer and suggests that the meridional eddy diffusivity is weak in the upper kilometer of the water column with values below 500 m2 s−1 and peaks at the steering level, near 2 km, where the eddy phase speed is equal to the mean flow speed. These vertical variations are not captured by ocean models presently used for climate studies, but they significantly affect the ventilation of different water masses.
    Description: NSF support through Awards OCE-1233832, OCE-1232962, and OCE-1048926 is gratefully acknowledged.
    Description: 2015-04-01
    Keywords: Geographic location/entity ; Southern Ocean ; Circulation/ Dynamics ; Diffusion ; Eddies ; Ocean circulation ; Turbulence ; Physical Meteorology and Climatology ; Isopycnal mixing
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  • 32
    Publication Date: 2022-05-26
    Description: Author Posting. © American Meteorological Society, 2016. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 46 (2016): 1309-1321, doi:10.1175/JPO-D-15-0068.1.
    Description: Direct measurements of oceanic turbulent parameters were taken upstream of and across Drake Passage, in the region of the Subantarctic and Polar Fronts. Values of turbulent kinetic energy dissipation rate ε estimated by microstructure are up to two orders of magnitude lower than previously published estimates in the upper 1000 m. Turbulence levels in Drake Passage are systematically higher than values upstream, regardless of season. The dissipation of thermal variance χ is enhanced at middepth throughout the surveys, with the highest values found in northern Drake Passage, where water mass variability is the most pronounced. Using the density ratio, evidence for double-diffusive instability is presented. Subject to double-diffusive physics, the estimates of diffusivity using the Osborn–Cox method are larger than ensemble statistics based on ε and the buoyancy frequency.
    Description: This work was supported by grants from the U.S. National Science Foundation.
    Description: 2016-10-05
    Keywords: Geographic location/entity ; Southern Ocean ; Circulation/ Dynamics ; Diapycnal mixing ; Mixing ; Turbulence ; Atm/Ocean Structure/ Phenomena ; Fronts ; Observational techniques and algorithms ; Profilers, oceanic
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  • 33
    Publication Date: 2022-05-26
    Description: Author Posting. © American Meteorological Society, 2016. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 46 (2016): 1769-1783, doi:10.1175/JPO-D-15-0193.1.
    Description: High-resolution observations of velocity, salinity, and turbulence quantities were collected in a salt wedge estuary to quantify the efficiency of stratified mixing in a high-energy environment. During the ebb tide, a midwater column layer of strong shear and stratification developed, exhibiting near-critical gradient Richardson numbers and turbulent kinetic energy (TKE) dissipation rates greater than 10−4 m2 s−3, based on inertial subrange spectra. Collocated estimates of scalar variance dissipation from microconductivity sensors were used to estimate buoyancy flux and the flux Richardson number Rif. The majority of the samples were outside the boundary layer, based on the ratio of Ozmidov and boundary length scales, and had a mean Rif = 0.23 ± 0.01 (dissipation flux coefficient Γ = 0.30 ± 0.02) and a median gradient Richardson number Rig = 0.25. The boundary-influenced subset of the data had decreased efficiency, with Rif = 0.17 ± 0.02 (Γ = 0.20 ± 0.03) and median Rig = 0.16. The relationship between Rif and Rig was consistent with a turbulent Prandtl number of 1. Acoustic backscatter imagery revealed coherent braids in the mixing layer during the early ebb and a transition to more homogeneous turbulence in the midebb. A temporal trend in efficiency was also visible, with higher efficiency in the early ebb and lower efficiency in the late ebb when the bottom boundary layer had greater influence on the flow. These findings show that mixing efficiency of turbulence in a continuously forced, energetic, free shear layer can be significantly greater than the broadly cited upper bound from Osborn of 0.15–0.17.
    Description: Holleman was supported by the Devonshire Scholars program. The field study and the coauthors’ contributions were supported by NSF Grant OCE 0926427.
    Description: 2016-11-24
    Keywords: Circulation/ Dynamics ; Mixing ; Shear structure/flows ; Turbulence ; Observational techniques and algorithms ; Ship observations
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  • 34
    Publication Date: 2022-05-26
    Description: © The Author(s), 2016. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Journal of Atmospheric and Oceanic Technology 33 (2016): 873-890, doi:10.1175/JTECH-D-15-0109.1.
    Description: Direct covariance flux (DCF) measurements taken from floating platforms are contaminated by wave-induced platform motions that need to be removed before computation of the turbulent fluxes. Several correction algorithms have been developed and successfully applied in earlier studies from research vessels and, most recently, by the use of moored buoys. The validation of those correction algorithms has so far been limited to short-duration comparisons against other floating platforms. Although these comparisons show in general a good agreement, there is still a lack of a rigorous validation of the method, required to understand the strengths and weaknesses of the existing motion-correction algorithms. This paper attempts to provide such a validation by a comparison of flux estimates from two DCF systems, one mounted on a moored buoy and one on the Air–Sea Interaction Tower (ASIT) at the Martha’s Vineyard Coastal Observatory, Massachusetts. The ASIT was specifically designed to minimize flow distortion over a wide range of wind directions from the open ocean for flux measurements. The flow measurements from the buoy system are corrected for wave-induced platform motions before computation of the turbulent heat and momentum fluxes. Flux estimates and cospectra of the corrected buoy data are found to be in very good agreement with those obtained from the ASIT. The comparison is also used to optimize the filter constants used in the motion-correction algorithm. The quantitative agreement between the buoy data and the ASIT demonstrates that the DCF method is applicable for turbulence measurements from small moving platforms, such as buoys.
    Description: This work was funded by the National Science Foundation Grant OCE04-24536 as part of the CLIVAR Mode Water Dynamic Experiment (CLIMODE).
    Keywords: Circulation/ Dynamics ; Turbulence ; Atm/Ocean Structure/ Phenomena ; Boundary layer ; Physical Meteorology and Climatology ; Air-sea interaction ; Observational techniques and algorithms ; Buoy observations ; Quality assurance/control
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  • 35
    Publication Date: 2023-02-28
    Description: Author Posting. © American Meteorological Society, 2022. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 52(6), (2022): 1091–1110, https://doi.org/10.1175/JPO-D-21-0068.1.
    Description: Hundreds of full-depth temperature and salinity profiles collected by Deepglider autonomous underwater vehicles (AUVs) in the North Atlantic reveal robust signals in eddy isopycnal vertical displacement and horizontal current throughout the entire water column. In separate glider missions southeast of Bermuda, subsurface-intensified cold, fresh coherent vortices were observed with velocities exceeding 20 cm s−1 at depths greater than 1000 m. With vertical resolution on the order of 20 m or less, these full-depth glider slant profiles newly permit estimation of scaled vertical wavenumber spectra from the barotropic through the 40th baroclinic mode. Geostrophic turbulence theory predictions of spectral slopes associated with the forward enstrophy cascade and proportional to inverse wavenumber cubed generally agree with glider-derived quasi-universal spectra of potential and kinetic energy found at a variety of locations distinguished by a wide range of mean surface eddy kinetic energy. Water-column average spectral estimates merge at high vertical mode number to established descriptions of internal wave spectra. Among glider mission sites, geographic and seasonal variability implicate bottom drag as a mechanism for dissipation, but also the need for more persistent sampling of the deep ocean.
    Description: This work was funded by NSF Grant 1736217 and would not have been possible without the help of Kirk O’Donnell, James Bennett, Noel Pelland, and all contributors to Deepglider development. We additionally thank the captain crew of the R/V Atlantic Explorer and the BATS team at the Bermuda Institute of Ocean Sciences, particularly Rod Johnson, as well as Seakeepers International for their professionalism, capability, and generous assistance in deploying and recovering gliders.
    Keywords: North Atlantic Ocean ; Eddies ; Mesoscale processes ; Turbulence ; Energy transport ; In situ oceanic observations ; Oceanic variability
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  • 36
    Publication Date: 2022-10-26
    Description: © The Author(s), 2019. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Bodini, N., Lundquist, J. K., & Kirincich, A. US East Coast lidar measurements show offshore wind turbines will encounter very low atmospheric turbulence. Geophysical Research Letters, 46(10), (2019):5582-5591, doi:10.1029/2019GL082636.
    Description: The rapid growth of offshore wind energy requires accurate modeling of the wind resource, which can be depleted by wind farm wakes. Turbulence dissipation rate (ϵ) governs the accuracy of model predictions of hub‐height wind speed and the development and erosion of wakes. Here we assess the variability of turbulence kinetic energy and ϵ using 13 months of observations from a profiling lidar deployed on a platform off the Massachusetts coast. Offshore, ϵ is 2 orders of magnitude smaller than onshore, with a subtle diurnal cycle. Wind direction influences the annual cycle of turbulence, with larger values in winter when the wind flows from the land, and smaller values in summer, when the wind flows from open ocean. Because of the weak turbulence, wind plant wakes will be stronger and persist farther downwind in summer.
    Description: Collection of the wind data was funded by the Massachusetts Clean Energy Center through agreements with WHOI and AWS Truepower. The authors appreciate the efforts of the MVCO/ASIT technicians and AWS staff who collected the data. This analysis was supported by the National Science Foundation CAREER Award (AGS‐1554055) to J. K. L. and N. B., and by internal funds from WHOI for A. K. This work was authored (in part) by the National Renewable Energy Laboratory, operated by Alliance for Sustainable Energy, LLC, for the U.S. Department of Energy (DOE) under Contract DE‐AC36‐08GO28308. Funding was provided by the U.S. Department of Energy Office of Energy Efficiency and Renewable Energy Wind Energy Technologies Office. The views expressed in the article do not necessarily represent the views of the DOE or the U.S. Government. The U.S. Government retains and the publisher, by accepting the article for publication, acknowledges that the U.S. Government retains a nonexclusive, paid‐up, irrevocable, worldwide license to publish or reproduce the published form of this work, or allow others to do so, for U.S. Government purposes. The lidar observations used here are described at https://www.masscec.com/masscec-metocean-data-initiative, and available at https://doi.org/10.26025/1912/24050. The postprocessed data and the scripts used for the Figures of the present paper can be found at https://github.com/nicolabodini/GRL_OffshoreTurbulence.
    Description: 2019-11-01
    Keywords: Turbulence ; Offshore wind energy ; Lidar ; Wakes
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  • 37
    Publication Date: 2022-10-26
    Description: © The Author(s), 2020. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Evans, D. G., Frajka-Williams, E., Garabato, A. C. N., Polzin, K. L., & Forryan, A. Mesoscale eddy dissipation by a "zoo" of submesoscale processes at a western boundary. Journal of Geophysical Research: Oceans, 125(11), (2020): e2020JC016246, doi:10.1029/2020JC016246.
    Description: Mesoscale eddies are ubiquitous dynamical features that tend to propagate westward and disappear along ocean western boundaries. Using a multiscale observational study, we assess the extent to which eddies dissipate via a direct cascade of energy at a western boundary. We analyze data from a ship‐based microstructure and velocity survey, and an 18‐month mooring deployment, to document the dissipation of energy in anticyclonic and cyclonic eddies impinging on the topographic slope east of the Bahamas, in the North Atlantic Ocean. These observations reveal high levels of turbulence where the steep and rough topographic slope modified the intensified northward flow associated with, in particular, anticyclonic eddies. Elevated dissipation was observed both near‐bottom and at mid depths (200–800 m). Near‐bottom turbulence occurred in the lee of a protruding escarpment, where elevated Froude numbers suggest hydraulic control. Energy was also radiated in the form of upward‐propagating internal waves. Elevated dissipation at mid depths occurred in regions of strong vertical shear, where the topographic slope modified the vertical structure of the northward eddy flow. Here, low Richardson numbers and a local change in the isopycnal gradient of potential vorticity (PV) suggest that the elevated dissipation was associated with horizontal shear instability. Elevated mid‐depth dissipation was also induced by topographic steering of the flow. This led to large anticyclonic vorticity and negative PV adjacent to the topographic slope, suggesting that centrifugal instability underpinned the local enhancement in dissipation. Our results provide a mechanistic benchmark for the realistic representation of eddy dissipation in ocean models.
    Description: The MeRMEED project, DGE, EFW, ACNG and AF were funded under Natural Environment Research Council standard grant NE/N001745/2. ACNG further acknowledges the support of the Royal Society and the Wolfson Foundation.
    Keywords: Direct energy cascade ; Eddy-topography interactions ; Energy ; Instability ; Mesoscale eddies ; Turbulence
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  • 38
    Publication Date: 2022-10-12
    Description: Author Posting. © American Meteorological Society, 2022. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 52(10), (2022): 2325–2341, https://doi.org/10.1175/jpo-d-21-0015.1.
    Description: The ocean surface boundary layer is a gateway of energy transfer into the ocean. Wind-driven shear and meteorologically forced convection inject turbulent kinetic energy into the surface boundary layer, mixing the upper ocean and transforming its density structure. In the absence of direct observations or the capability to resolve subgrid-scale 3D turbulence in operational ocean models, the oceanography community relies on surface boundary layer similarity scalings (BLS) of shear and convective turbulence to represent this mixing. Despite their importance, near-surface mixing processes (and ubiquitous BLS representations of these processes) have been undersampled in high-energy forcing regimes such as the Southern Ocean. With the maturing of autonomous sampling platforms, there is now an opportunity to collect high-resolution spatial and temporal measurements in the full range of forcing conditions. Here, we characterize near-surface turbulence under strong wind forcing using the first long-duration glider microstructure survey of the Southern Ocean. We leverage these data to show that the measured turbulence is significantly higher than standard shear-convective BLS in the shallower parts of the surface boundary layer and lower than standard shear-convective BLS in the deeper parts of the surface boundary layer; the latter of which is not easily explained by present wave-effect literature. Consistent with the CBLAST (Coupled Boundary Layers and Air Sea Transfer) low winds experiment, this bias has the largest magnitude and spread in the shallowest 10% of the actively mixing layer under low-wind and breaking wave conditions, when relatively low levels of turbulent kinetic energy (TKE) in surface regime are easily biased by wave events.
    Description: This paper is VIMS Contribution 4103. Computational resources were provided by the VIMS Ocean-Atmosphere and Climate Change Research Fund. AUSSOM was supported by the OCE Division of the National Science Foundation (1558639).
    Keywords: Turbulence ; Wind shear ; Boundary layer ; Parameterization
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  • 39
    Publication Date: 2022-10-20
    Description: © The Author(s), 2022. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Zippel, S. F., Farrar, J. T., Zappa, C. J., & Plueddemann, A. J. Parsing the kinetic energy budget of the ocean surface mixed layer. Geophysical Research Letters, 49(2), (2022): 2021GL095920, https://doi.org/10.1029/2021GL095920.
    Description: The total rate of work done on the ocean by the wind is of considerable interest for understanding global energy balances, as the energy from the wind drives ocean currents, grows surface waves, and forces vertical mixing. A large but unknown fraction of this atmospheric energy is dissipated by turbulence in the upper ocean. The focus of this work is twofold. First, we describe a framework for evaluating the vertically integrated turbulent kinetic energy (TKE) equation using measurable quantities from a surface mooring, showing the connection to the atmospheric, mean oceanic, and wave energy. Second, we use this framework to evaluate turbulent energetics in the mixed layer using 10 months of mooring data. This evaluation is made possible by recent advances in estimating TKE dissipation rates from long-enduring moorings. We find that surface fluxes are balanced by TKE dissipation rates in the mixed layer to within a factor of two.
    Description: This work was funded by NSF Award No. 2023 020, and by NASA as part of the Salinity Processes in the Upper Ocean Regional Study (SPURS), supporting field work for SPURS-1 (NASA Grant No. NNX11AE84G), and for analysis (NASA Grant No. 80NSSC18K1494), and as part of SASSIE (NASA Grant No. 80NSSC21K0832). This work was also funded by NSF through Grant Award Nos. 1756 839, 2049546, and by ONR through Grant N000141712880 (MISO-BoB).
    Keywords: Air/sea interaction ; Turbulence ; Mixed layer ; Wind work ; Boundary layer ; Waves
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  • 40
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2022. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Oceans 127(5), (2022): e2021JC018056, https://doi.org/10.1029/2021jc018056.
    Description: As Arctic sea ice declines, wind energy has increasing access to the upper ocean, with potential consequences for ocean mixing, stratification, and turbulent heat fluxes. Here, we investigate the relationships between internal wave energy, turbulent dissipation, and ice concentration and draft using mooring data collected in the Beaufort Sea during 2003–2018. We focus on the 50–300 m depth range, using velocity and CTD records to estimate near-inertial shear and energy, a finescale parameterization to infer turbulent dissipation rates, and ice draft observations to characterize the ice cover. All quantities varied widely on monthly and interannual timescales. Seasonally, near-inertial energy increased when ice concentration and ice draft were low, but shear and dissipation did not. We show that this apparent contradiction occurred due to the vertical scales of internal wave energy, with open water associated with larger vertical scales. These larger vertical scale motions are associated with less shear, and tend to result in less dissipation. This relationship led to a seasonality in the correlation between shear and energy. This correlation was largest in the spring beneath full ice cover and smallest in the summer and fall when the ice had deteriorated. When considering interannually averaged properties, the year-to-year variability and the short ice-free season currently obscure any potential trend. Implications for the future seasonal and interannual evolution of the Arctic Ocean and sea ice cover are discussed.
    Description: This work was supported by the Postdoctoral Scholar Program at Woods Hole Oceanographic Institution, with funding provided by the Weston Howland Jr. Postdoctoral Scholarship. S. T. Cole was supported by Office of Naval Research grant N00014-16-1-2381.
    Description: 2022-10-14
    Keywords: Arctic ; Internal waves ; Mixing ; Sea ice ; Turbulence
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  • 41
    Publication Date: 2022-05-27
    Description: Author Posting. © American Meteorological Society, 2021. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 51(1), (2021): 19-35, https://doi.org/10.1175/JPO-D-19-0233.1.
    Description: In the Beaufort Sea in September of 2015, concurrent mooring and microstructure observations were used to assess dissipation rates in the vicinity of 72°35′N, 145°1′W. Microstructure measurements from a free-falling profiler survey showed very low [O(10−10) W kg−1] turbulent kinetic energy dissipation rates ε. A finescale parameterization based on both shear and strain measurements was applied to estimate the ratio of shear to strain Rω and ε at the mooring location, and a strain-based parameterization was applied to the microstructure survey (which occurred approximately 100 km away from the mooring site) for direct comparison with microstructure results. The finescale parameterization worked well, with discrepancies ranging from a factor of 1–2.5 depending on depth. The largest discrepancies occurred at depths with high shear. Mean Rω was 17, and Rω showed high variability with values ranging from 3 to 50 over 8 days. Observed ε was slightly elevated (factor of 2–3 compared with a later survey of 11 profiles taken over 3 h) from 25 to 125 m following a wind event which occurred at the beginning of the mooring deployment, reaching a maximum of ε= 6 × 10−10 W kg−1 at 30-m depth. Velocity signals associated with near-inertial waves (NIWs) were observed at depths greater than 200 m, where the Atlantic Water mass represents a reservoir of oceanic heat. However, no evidence of elevated ε or heat fluxes was observed in association with NIWs at these depths in either the microstructure survey or the finescale parameterization estimates.
    Description: This work was supported by NSF Grants PLR 14-56705 and PLR-1303791 and by NSF Graduate Research Fellowship Grant DGE-1650112.
    Keywords: Ocean ; Arctic ; Internal waves ; Turbulence ; Diapycnal mixing
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  • 42
    Publication Date: 2022-05-27
    Description: © The Author(s), 2021. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Spingys, C. P., Garabato, A. C. N., Legg, S., Polzin, K. L., Abrahamsen, E. P., Buckingham, C. E., Forryan, A., & Frajka-Williams, E. E. Mixing and transformation in a deep western boundary current: a case study. Journal of Physical Oceanography, 51(4), (2021): 1205-1222, https://doi.org/10.1175/JPO-D-20-0132.1
    Description: Water-mass transformation by turbulent mixing is a key part of the deep-ocean overturning, as it drives the upwelling of dense waters formed at high latitudes. Here, we quantify this transformation and its underpinning processes in a small Southern Ocean basin: the Orkney Deep. Observations reveal a focusing of the transport in density space as a deep western boundary current (DWBC) flows through the region, associated with lightening and densification of the current’s denser and lighter layers, respectively. These transformations are driven by vigorous turbulent mixing. Comparing this transformation with measurements of the rate of turbulent kinetic energy dissipation indicates that, within the DWBC, turbulence operates with a high mixing efficiency, characterized by a dissipation ratio of 0.6 to 1 that exceeds the common value of 0.2. This result is corroborated by estimates of the dissipation ratio from microstructure observations. The causes of the transformation are unraveled through a decomposition into contributions dependent on the gradients in density space of the: dianeutral mixing rate, isoneutral area, and stratification. The transformation is found to be primarily driven by strong turbulence acting on an abrupt transition from the weakly stratified bottom boundary layer to well-stratified off-boundary waters. The reduced boundary layer stratification is generated by a downslope Ekman flow associated with the DWBC’s flow along sloping topography, and is further regulated by submesoscale instabilities acting to restratify near-boundary waters. Our results provide observational evidence endorsing the importance of near-boundary mixing processes to deep-ocean overturning, and highlight the role of DWBCs as hot spots of dianeutral upwelling.
    Description: CS, ACNG, AF, and EFW were supported by the U.K. Natural Environment Research Council (NERC) Grant NE/K013181/1. ACNG was supported by the Royal Society and Wolfson Foundation. EPA and CEB were supported by NERC Grant NE/K012843/1. CEB was funded by an MSCA grant (No. 798319) from the European Union’s Horizon 2020 program. EPA was supported by NERC Grant NE/N018095/1. SL and KP were supported by U.S. National Science Foundation Grants OCE-1536453 and OCE-1536779. SL acknowledges support of Award NA18OAR4320123 from the National Oceanic and Atmospheric Administration, U.S. Department of Commerce. The statements, findings, conclusions, and recommendations are those of the authors, and do not necessarily reflect the views of the National Oceanic and Atmospheric Administration, or the U.S. Department of Commerce.
    Keywords: Bottom currents ; Diapycnal mixing ; Turbulence ; Southern Ocean
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  • 43
    Publication Date: 2022-09-15
    Description: Author Posting. © American Meteorological Society, 2022. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 52(1),(2022): 75–97, https://doi.org/10.1175/JPO-D-21-0099.1.
    Description: Mesoscale eddies contain the bulk of the ocean’s kinetic energy (KE), but fundamental questions remain on the cross-scale KE transfers linking eddy generation and dissipation. The role of submesoscale flows represents the key point of discussion, with contrasting views of submesoscales as either a source or a sink of mesoscale KE. Here, the first observational assessment of the annual cycle of the KE transfer between mesoscale and submesoscale motions is performed in the upper layers of a typical open-ocean region. Although these diagnostics have marginal statistical significance and should be regarded cautiously, they are physically plausible and can provide a valuable benchmark for model evaluation. The cross-scale KE transfer exhibits two distinct stages, whereby submesoscales energize mesoscales in winter and drain mesoscales in spring. Despite this seasonal reversal, an inverse KE cascade operates throughout the year across much of the mesoscale range. Our results are not incompatible with recent modeling investigations that place the headwaters of the inverse KE cascade at the submesoscale, and that rationalize the seasonality of mesoscale KE as an inverse cascade-mediated response to the generation of submesoscales in winter. However, our findings may challenge those investigations by suggesting that, in spring, a downscale KE transfer could dampen the inverse KE cascade. An exploratory appraisal of the dynamics governing mesoscale–submesoscale KE exchanges suggests that the upscale KE transfer in winter is underpinned by mixed layer baroclinic instabilities, and that the downscale KE transfer in spring is associated with frontogenesis. Current submesoscale-permitting ocean models may substantially understate this downscale KE transfer, due to the models’ muted representation of frontogenesis.
    Description: The OSMOSIS experiment was funded by the U.K. Natural Environment Research Council (NERC) through Grants NE/1019999/1 and NE/101993X/1. ACNG acknowledges the support of the Royal Society and the Wolfson Foundation, and XY that of a China Scholarship Council PhD studentship.
    Keywords: Ageostrophic circulations ; Dynamics ; Eddies ; Energy transport ; Frontogenesis/frontolysis ; Instability ; Mesoscale processes ; Nonlinear dynamics ; Ocean circulation ; Ocean dynamics ; Small scale processes ; Turbulence
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  • 44
    Publication Date: 2022-09-01
    Description: Author Posting. © American Meteorological Society, 2022. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 52(8), (2022): 1677-1691, https://doi.org/10.1175/jpo-d-21-0269.1.
    Description: Oceanic mesoscale motions including eddies, meanders, fronts, and filaments comprise a dominant fraction of oceanic kinetic energy and contribute to the redistribution of tracers in the ocean such as heat, salt, and nutrients. This reservoir of mesoscale energy is regulated by the conversion of potential energy and transfers of kinetic energy across spatial scales. Whether and under what circumstances mesoscale turbulence precipitates forward or inverse cascades, and the rates of these cascades, remain difficult to directly observe and quantify despite their impacts on physical and biological processes. Here we use global observations to investigate the seasonality of surface kinetic energy and upper-ocean potential energy. We apply spatial filters to along-track satellite measurements of sea surface height to diagnose surface eddy kinetic energy across 60–300-km scales. A geographic and scale-dependent seasonal cycle appears throughout much of the midlatitudes, with eddy kinetic energy at scales less than 60 km peaking 1–4 months before that at 60–300-km scales. Spatial patterns in this lag align with geographic regions where an Argo-derived estimate of the conversion of potential to kinetic energy is seasonally varying. In midlatitudes, the conversion rate peaks 0–2 months prior to kinetic energy at scales less than 60 km. The consistent geographic patterns between the seasonality of potential energy conversion and kinetic energy across spatial scale provide observational evidence for the inverse cascade and demonstrate that some component of it is seasonally modulated. Implications for mesoscale parameterizations and numerical modeling are discussed.
    Description: This work was generously funded by NSF Grants OCE-1912302, OCE-1912125 (Drushka), and OCE-1912325 (Abernathey) as part of the Ocean Energy and Eddy Transport Climate Process Team.
    Keywords: Eddies ; Energy transport ; Mesoscale processes ; Turbulence ; Oceanic mixed layer ; Altimetry ; Seasonal cycle
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  • 45
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2004. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 109 (2004): C08S18, doi:10.1029/2003JC001806.
    Description: Rain has been shown to significantly enhance the rate of air-water gas exchange in fresh water environments, and the mechanism behind this enhancement has been studied in laboratory experiments. In the ocean, the effects of rain are complicated by the potential influence of density stratification at the water surface. Since it is difficult to perform controlled rain-induced gas exchange experiments in the open ocean, an SF6 evasion experiment was conducted in the artificial ocean at Biosphere 2. The measurements show a rapid depletion of SF6 in the surface layer due to rain enhancement of air-sea gas exchange, and the gas transfer velocity was similar to that predicted from the relationship established from freshwater laboratory experiments. However, because vertical mixing is reduced by stratification, the overall gas flux is lower than that found during freshwater experiments. Physical measurements of various properties of the ocean during the rain events further elucidate the mechanisms behind the observed response. The findings suggest that short, intense rain events accelerate gas exchange in oceanic environments.
    Description: Funding was provided by a generous grant from the David and Lucile Packard Foundation.
    Keywords: Gas exchange ; Rain ; SF6 ; Turbulence ; Stratification
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  • 46
    Publication Date: 2022-05-26
    Description: Author Posting. © American Meteorological Society, 2016. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 46 (2016): 1823-1837, doi:10.1175/JPO-D-15-0165.1.
    Description: Measurements just beneath the ocean surface demonstrate that the primary mechanism by which energy from breaking waves is transmitted into the water column is through the work done by the covariance of turbulent pressure and velocity fluctuations. The convergence in the vertical transport of turbulent kinetic energy (TKE) balances the dissipation rate of TKE at first order and is nearly an order of magnitude greater than the sum of the integrated Eulerian and Stokes shear production. The measured TKE transport is consistent with a simple conceptual model that assumes roughly half of the surface flux of TKE by wave breaking is transmitted to depths greater than the significant wave height. During conditions when breaking waves are inferred, the direction of momentum flux is more aligned with the direction of wave propagation than with the wind direction. Both the energy and momentum fluxes occur at frequencies much lower than the wave band, consistent with the time scales associated with wave breaking. The largest instantaneous values of momentum flux are associated with strong downward vertical velocity perturbations, in contrast to the pressure work, which is associated with strong drops in pressure and upward vertical velocity perturbations.
    Description: Funding for this research was provided by the National Science Foundation Grants OCE-1339032 and OCE-1338518
    Keywords: Circulation/ Dynamics ; Energy transport ; Mixing ; Momentum ; Turbulence ; Wave breaking ; Waves, oceanic
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  • 47
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2012. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 117 (2012): C08013, doi:10.1029/2011JC007228.
    Description: Direct observations of microstructure near the Kuroshio Front were conducted in August 2008 and October 2009. These show negative potential vorticity (PV) in the mixed layer south of the front, where directly measured turbulent kinetic energy dissipation rates are an order magnitude larger than predicted by wind-scaling. These elevated dissipation rates scale better with an empirical scaling, which considers local wind and Ekman buoyancy flux driven by downfront wind. Near-zero PV in the thermocline under the Kuroshio mainstream is observed at 200–300 m depth, with dissipation exceeding open ocean thermocline values by factors of 10–100. Overall, the large turbulent dissipation rates measured in the Kuroshio can be categorized into two groups, one characterized by low Richardson number along the Kuroshio Front thermocline, and the other characterized by high stratification away from the Kuroshio mainstream. The former is attributed to mixing by unbalanced frontal ageostrophic flows, and the latter is attributed to internal wave breaking. On average, both groups appear in regions of large horizontal density gradients. Observed thermohaline structure shows low salinity tongues from the surface to over 300 m depth and deep cold tongues, extending upward from 500 to 100 m depth in a narrow (20 km) zone, suggesting down and upwelling driven by geostrophic straining, which is confirmed by Quasigeostrophic-Omega equation solutions. This implies that adiabatic along isopycnal subduction and diabatic diapycnal turbulent mixing acting in tandem at the Kuroshio Front likely contribute to NPIW formation.
    Description: This study is supported by Sasagawa Scientific Research grant 20-701M (the Japan Science Society), Grant- in-Aid for Young Scientists (B) 20710002, and Excellent Young Researchers Overseas Visit Program 21-7283 awarded to T. Nagai. A. Tandon would like to acknowledge support from NSFPO- 0928138 and ONR N00014-09-1-0196.
    Description: 2013-03-09
    Keywords: Kuroshio ; Fronts ; Subduction ; Submesoscale ; Symmetric instability ; Turbulence
    Repository Name: Woods Hole Open Access Server
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  • 48
    Publication Date: 2022-05-26
    Description: Author Posting. © American Meteorological Society, 2014. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 44 (2014): 1306–1328, doi:10.1175/JPO-D-12-0191.1.
    Description: The ice–ocean system is investigated on inertial to monthly time scales using winter 2009–10 observations from the first ice-tethered profiler (ITP) equipped with a velocity sensor (ITP-V). Fluctuations in surface winds, ice velocity, and ocean velocity at 7-m depth were correlated. Observed ocean velocity was primarily directed to the right of the ice velocity and spiraled clockwise while decaying with depth through the mixed layer. Inertial and tidal motions of the ice and in the underlying ocean were observed throughout the record. Just below the ice–ocean interface, direct estimates of the turbulent vertical heat, salt, and momentum fluxes and the turbulent dissipation rate were obtained. Periods of elevated internal wave activity were associated with changes to the turbulent heat and salt fluxes as well as stratification primarily within the mixed layer. Turbulent heat and salt fluxes were correlated particularly when the mixed layer was closest to the freezing temperature. Momentum flux is adequately related to velocity shear using a constant ice–ocean drag coefficient, mixing length based on the planetary and geometric scales, or Rossby similarity theory. Ekman viscosity described velocity shear over the mixed layer. The ice–ocean drag coefficient was elevated for certain directions of the ice–ocean shear, implying an ice topography that was characterized by linear ridges. Mixing length was best estimated using the wavenumber of the beginning of the inertial subrange or a variable drag coefficient. Analyses of this and future ITP-V datasets will advance understanding of ice–ocean interactions and their parameterizations in numerical models.
    Description: Support for this study and the overall ITP program was provided by the National Science Foundation and Woods Hole Oceanographic Institution. Support for S. Cole was partially though the Postdoctoral Scholar Program at the Woods Hole Oceanographic Institution, with funding provided by the Devonshire Foundation.
    Description: 2014-11-01
    Keywords: Geographic location/entity ; Arctic ; Sea ice ; Circulation/ Dynamics ; Ekman pumping/transport ; Internal waves ; Turbulence ; Atm/Ocean Structure/ Phenomena ; Oceanic mixed layer
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  • 49
    Publication Date: 2022-06-10
    Description: Author Posting. © American Meteorological Society , 2021. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Zippel, S. F., Farrar, J. T., Zappa, C. J., Miller, U., St Laurent, L., Ijichi, T., Weller, R. A., McRaven, L., Nylund, S., & Le Bel, D. Moored turbulence measurements using pulse-coherent doppler sonar. Journal of Atmospheric and Oceanic Technology, 38(9), (2021): 1621–1639, https://doi.org/10.1175/JTECH-D-21-0005.1.
    Description: Upper-ocean turbulence is central to the exchanges of heat, momentum, and gases across the air–sea interface and therefore plays a large role in weather and climate. Current understanding of upper-ocean mixing is lacking, often leading models to misrepresent mixed layer depths and sea surface temperature. In part, progress has been limited by the difficulty of measuring turbulence from fixed moorings that can simultaneously measure surface fluxes and upper-ocean stratification over long time periods. Here we introduce a direct wavenumber method for measuring turbulent kinetic energy (TKE) dissipation rates ϵ from long-enduring moorings using pulse-coherent ADCPs. We discuss optimal programming of the ADCPs, a robust mechanical design for use on a mooring to maximize data return, and data processing techniques including phase-ambiguity unwrapping, spectral analysis, and a correction for instrument response. The method was used in the Salinity Processes Upper-Ocean Regional Study (SPURS) to collect two year-long datasets. We find that the mooring-derived TKE dissipation rates compare favorably to estimates made nearby from a microstructure shear probe mounted to a glider during its two separate 2-week missions for O(10−8) ≤ ϵ ≤ O(10−5) m2 s−3. Periods of disagreement between turbulence estimates from the two platforms coincide with differences in vertical temperature profiles, which may indicate that barrier layers can substantially modulate upper-ocean turbulence over horizontal scales of 1–10 km. We also find that dissipation estimates from two different moorings at 12.5 and at 7 m are in agreement with the surface buoyancy flux during periods of strong nighttime convection, consistent with classic boundary layer theory.
    Description: This work was funded by NASA as part of the Salinity Processes in the Upper Ocean Regional Study (SPURS), supporting field work for SPURS-1 (NASA Grant NNX11AE84G), for SPURS-2 (NASA Grant NNX15AG20G), and for analysis (NASA Grant 80NSSC18K1494). Funding for early iterations of this project associated with the VOCALS project and Stratus 9 mooring was provided by NSF (Awards 0745508 and 0745442). Additional funding was provided by ONR Grant N000141812431 and NSF Award 1756839. The Stratus Ocean Reference Station is funded by the Global Ocean Monitoring and Observing Program of the National Oceanic and Atmospheric Administration (CPO FundRef Number 100007298), through the Cooperative Institute for the North Atlantic Region (CINAR) under Cooperative Agreement NA14OAR4320158. Microstructure measurements made from the glider were supported by NSF (Award 1129646).
    Keywords: Ocean ; Turbulence ; Atmosphere-ocean interaction ; Boundary layer ; Oceanic mixed layer ; In situ oceanic observations
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  • 50
    Publication Date: 2022-06-13
    Description: © The Author(s), 2022. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Fine, E., MacKinnon, J., Alford, M., Middleton, L., Taylor, J., Mickett, J., Cole, S., Couto, N., Boyer, A., & Peacock, T. Double diffusion, shear instabilities, and heat impacts of a pacific summer water intrusion in the Beaufort Sea. Journal of Physical Oceanography, 52(2), (2022): 189–203, https://doi.org/10.1175/jpo-d-21-0074.1.
    Description: Pacific Summer Water eddies and intrusions transport heat and salt from boundary regions into the western Arctic basin. Here we examine concurrent effects of lateral stirring and vertical mixing using microstructure data collected within a Pacific Summer Water intrusion with a length scale of ∼20 km. This intrusion was characterized by complex thermohaline structure in which warm Pacific Summer Water interleaved in alternating layers of O(1) m thickness with cooler water, due to lateral stirring and intrusive processes. Along interfaces between warm/salty and cold/freshwater masses, the density ratio was favorable to double-diffusive processes. The rate of dissipation of turbulent kinetic energy (ε) was elevated along the interleaving surfaces, with values up to 3 × 10−8 W kg−1 compared to background ε of less than 10−9 W kg−1. Based on the distribution of ε as a function of density ratio Rρ, we conclude that double-diffusive convection is largely responsible for the elevated ε observed over the survey. The lateral processes that created the layered thermohaline structure resulted in vertical thermohaline gradients susceptible to double-diffusive convection, resulting in upward vertical heat fluxes. Bulk vertical heat fluxes above the intrusion are estimated in the range of 0.2–1 W m−2, with the localized flux above the uppermost warm layer elevated to 2–10 W m−2. Lateral fluxes are much larger, estimated between 1000 and 5000 W m−2, and set an overall decay rate for the intrusion of 1–5 years.
    Description: This work was supported by ONR Grant N00014-16-1-2378 and NSF Grants PLR 14-56705 and PLR-1303791, NSF Graduate Research Fellowship Grant DGE-1650112, as well as by the Postdoctoral Scholar Program at Woods Hole Oceanographic Institution, with funding provided by the Weston Howland Jr. Postdoctoral Scholarship.
    Keywords: Arctic ; Diapycnal mixing ; Diffusion ; Fluxes ; Instability ; Mixing ; Turbulence
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  • 51
    Publication Date: 2022-05-26
    Description: © The Author(s), 2020. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Cusack, J. M., Brearley, J. A., Garabato, A. C. N., Smeed, D. A., Polzin, K. L., Velzeboer, N., & Shakespeare, C. J. Observed eddy-internal wave interactions in the Southern Ocean. Journal of Physical Oceanography, 50(10), (2020): 3042-3062, doi:10.1175/JPO-D-20-0001.1.
    Description: The physical mechanisms that remove energy from the Southern Ocean’s vigorous mesoscale eddy field are not well understood. One proposed mechanism is direct energy transfer to the internal wave field in the ocean interior, via eddy-induced straining and shearing of preexisting internal waves. The magnitude, vertical structure, and temporal variability of the rate of energy transfer between eddies and internal waves is quantified from a 14-month deployment of a mooring cluster in the Scotia Sea. Velocity and buoyancy observations are decomposed into wave and eddy components, and the energy transfer is estimated using the Reynolds-averaged energy equation. We find that eddies gain energy from the internal wave field at a rate of −2.2 ± 0.6 mW m−2, integrated from the bottom to 566 m below the surface. This result can be decomposed into a positive (eddy to wave) component, equal to 0.2 ± 0.1 mW m−2, driven by horizontal straining of internal waves, and a negative (wave to eddy) component, equal to −2.5 ± 0.6 mW m−2, driven by vertical shearing of the wave spectrum. Temporal variability of the transfer rate is much greater than the mean value. Close to topography, large energy transfers are associated with low-frequency buoyancy fluxes, the underpinning physics of which do not conform to linear wave dynamics and are thereby in need of further research. Our work suggests that eddy–internal wave interactions may play a significant role in the energy balance of the Southern Ocean mesoscale eddy and internal wave fields.
    Description: Funding for DIMES was provided by U.K. Natural Environment Research Council (NERC) Grants NE/E007058/1 and NE/E005667/1. JMC acknowledges the support of a NERC PhD studentship, and ACNG that of the Royal Society and the Wolfson Foundation. NV acknowledges support from the ARC Centre of Excellence for Climate Extremes (CLEX) Honours Scholarship and the ANU PBSA Partnership - Spotless Scholarship. CJS acknowledges support from an ARC Discovery Early Career Researcher Award DE180100087 and an Australian National University Futures Scheme award. Numerical simulations were conducted on the National Computational Infrastructure (NCI) facility, Canberra, Australia. This study has been conducted using E.U. Copernicus Marine Service Information. We thank two anonymous reviewers for their comments which helped to improve the manuscript significantly. Codes and output files are available online at the project repository (https://github.com/jessecusack/DIMES_eddy_wave_interactions).
    Keywords: Southern Ocean ; Eddies ; Internal waves ; Turbulence
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  • 52
    Publication Date: 2022-05-26
    Description: Author Posting. © American Meteorological Society, 2019. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 49(9), (2019): 2237-2254, doi: 10.1175/JPO-D-18-0181.1.
    Description: A cluster of 45 drifters deployed in the Bay of Bengal is tracked for a period of four months. Pair dispersion statistics, from observed drifter trajectories and simulated trajectories based on surface geostrophic velocity, are analyzed as a function of drifter separation and time. Pair dispersion suggests nonlocal dynamics at submesoscales of 1–20 km, likely controlled by the energetic mesoscale eddies present during the observations. Second-order velocity structure functions and their Helmholtz decomposition, however, suggest local dispersion and divergent horizontal flow at scales below 20 km. This inconsistency cannot be explained by inertial oscillations alone, as has been reported in recent studies, and is likely related to other nondispersive processes that impact structure functions but do not enter pair dispersion statistics. At scales comparable to the deformation radius LD, which is approximately 60 km, we find dynamics in agreement with Richardson’s law and observe local dispersion in both pair dispersion statistics and second-order velocity structure functions.
    Description: This research was supported by the Air Sea Interaction Regional Initiative (ASIRI) under ONR Grant N00014-13-1-0451 (SE and AM) and ONR Grant N00014-13-1-0477 (VH and LC). Additionally, AM and SE thank NSF (Grant OCE-I434788) and ONR (Grant N00014-16-1-2470) for support; VH and LC were further supported by ONR Grant N00014-15-1-2286 and NOAA GDP Grant NA10OAR4320156. We thank Joe LaCasce, Dhruv Balwada, and one anonymous reviewer for helpful comments and discussions that significantly improved this manuscript. The authors thank the captain and crew of the R/V Roger Revelle. The SVP-type drifters are part of the Global Drifter Program and supported by ONR Grant N00014-15-1-2286 and NOAA GDP Grant NA10OAR4320156 and are available under http://www.aoml.noaa.gov/phod/dac/. The Ssalto/Duacs altimeter products were produced and distributed by the Copernicus Marine and Environment Monitoring Service (CMEMS, http://www.marine.copernicus.eu).
    Keywords: Dispersion ; Fronts ; Mesoscale processes ; Subgrid-scale processes ; Trajectories ; Turbulence
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  • 53
    Publication Date: 2022-05-26
    Description: © The Author(s), 2019. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Cusack, J. M., Voet, G., Alford, M. H., Girton, J. B., Carter, G. S., Pratt, L. J., Pearson-Potts, K. A., & Tan, S. Persistent turbulence in the Samoan Passage. Journal of Physical Oceanography, 49(12), (2019): 3179-3197, doi: 10.1175/JPO-D-19-0116.1.
    Description: Abyssal waters forming the lower limb of the global overturning circulation flow through the Samoan Passage and are modified by intense mixing. Thorpe-scale-based estimates of dissipation from moored profilers deployed on top of two sills for 17 months reveal that turbulence is continuously generated in the passage. Overturns were observed in a density band in which the Richardson number was often smaller than ¼, consistent with shear instability occurring at the upper interface of the fast-flowing bottom water layer. The magnitude of dissipation was found to be stable on long time scales from weeks to months. A second array of 12 moored profilers deployed for a shorter duration but profiling at higher frequency was able to resolve variability in dissipation on time scales from days to hours. At some mooring locations, near-inertial and tidal modulation of the dissipation rate was observed. However, the modulation was not spatially coherent across the passage. The magnitude and vertical structure of dissipation from observations at one of the major sills is compared with an idealized 2D numerical simulation that includes a barotropic tidal forcing. Depth-integrated dissipation rates agree between model and observations to within a factor of 3. The tide has a negligible effect on the mean dissipation. These observations reinforce the notion that the Samoan Passage is an important mixing hot spot in the global ocean where waters are being transformed continuously.
    Description: The authors thank Zhongxiang Xao and Jody Klymak, who provided earlier setups of the numerical model, and also Arjun Jagannathan for insightful discussions on the subject of flow over topography. We also thank John Mickett and Eric Boget for their assistance in designing, deploying, and recovering the moorings. In addition, we also thank the crew and scientists aboard the R/V Revelle and R/V Thompson, without whom the data presented in this paper could not have been gathered. Ilker Fer and two anonymous reviewers provided thoughtful feedback that improved the paper. This work was supported by the National Science Foundation under Grants OCE-1029268, OCE-1029483, OCE-1657264, OCE-1657795, OCE-1657870, and OCE-1658027.
    Keywords: Gravity waves ; Turbulence ; Abyssal circulation ; Mixing ; Tides
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  • 54
    Publication Date: 2022-05-26
    Description: Author Posting. © American Meteorological Society, 2020. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 50(3), (2020): 715-726, doi:10.1175/JPO-D-19-0021.1.
    Description: Closing the overturning circulation of bottom water requires abyssal transformation to lighter densities and upwelling. Where and how buoyancy is gained and water is transported upward remain topics of debate, not least because the available observations generally show downward-increasing turbulence levels in the abyss, apparently implying mean vertical turbulent buoyancy-flux divergence (densification). Here, we synthesize available observations indicating that bottom water is made less dense and upwelled in fracture zone valleys on the flanks of slow-spreading midocean ridges, which cover more than one-half of the seafloor area in some regions. The fracture zones are filled almost completely with water flowing up-valley and gaining buoyancy. Locally, valley water is transformed to lighter densities both in thin boundary layers that are in contact with the seafloor, where the buoyancy flux must vanish to match the no-flux boundary condition, and in thicker layers associated with downward-decreasing turbulence levels below interior maxima associated with hydraulic overflows and critical-layer interactions. Integrated across the valley, the turbulent buoyancy fluxes show maxima near the sidewall crests, consistent with net convergence below, with little sensitivity of this pattern to the vertical structure of the turbulence profiles, which implies that buoyancy flux convergence in the layers with downward-decreasing turbulence levels dominates over the divergence elsewhere, accounting for the net transformation to lighter densities in fracture zone valleys. We conclude that fracture zone topography likely exerts a controlling influence on the transformation and upwelling of bottom water in many areas of the global ocean.
    Description: The data used in this study were collected in the context of several projects funded by the U.S. National Science Foundation (NSF), in particular BBTRE (OCE-9415589 and OCE-9415598) and DoMORE (OCE-1235094). Funding for the analysis was provided as part of the NSF DoMORE and DECIMAL (OCE-1735618) projects. Author Ijichi is a Japan Society for the Promotion of Science (JSPS) Overseas Research Fellow. Comments on an early draft of this paper by Jim Ledwell and Bryan Kaiser, as well as topical discussions with Jörn Callies and Trevor McDougall, are gratefully acknowledged. The paper was greatly improved during the review process, in particular because of the critical comments from one of the two anonymous reviewers.
    Keywords: Diapycnal mixing ; Topographic effects ; Turbulence ; Upwelling/downwelling ; Bottom currents/bottom water
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  • 55
    Publication Date: 2022-05-26
    Description: Author Posting. © American Meteorological Society, 2017. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 47 (2017): 2611-2630, doi:10.1175/JPO-D-16-0259.1.
    Description: This study reports the results of large-eddy simulations of an axisymmetric turbulent buoyant plume in a stratified fluid. The configuration used is an idealized model of the plume generated by a subglacial discharge at the base of a tidewater glacier with an ambient stratification typical of Greenland fjords. The plume is discharged from a round source of various diameters and characteristic stratifications for summer and winter are considered. The classical theory for the integral parameters of a turbulent plume in a homogeneous fluid gives accurate predictions in the weakly stratified lower layer up to the pycnocline, and the plume dynamics are not sensitive to changes in the source diameter. In winter, when the stratification is similar to an idealized two-layer case, turbulent entrainment and generation of internal waves by the plume top are in agreement with the theoretical and numerical results obtained for turbulent jets in a two-layer stratification. In summer, instead, the stratification is more complex and turbulent entrainment by the plume top is significantly reduced. The subsurface layer in summer is characterized by a strong density gradient and the oscillating plume generates internal waves that might serve as an indicator of submerged plumes not penetrating to the surface.
    Description: This work was supported by Linné FLOW Centre at KTH and the Academy of Finland Centre of Excellence program (Grant 307331) (E. E.) and VR Swedish Research Council, Outstanding Young Researcher Award, Grant VR 2014-5001 (L. B.). Support to C. C. was given by the NSF Project OCE-1434041.
    Description: 2018-04-26
    Keywords: Buoyancy ; Internal waves ; Turbulence ; Jets ; Oscillations ; Large eddy simulations
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  • 56
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 10 (1987) 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 57
    Electronic Resource
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    Chemical Engineering & Technology - CET 10 (1987), S. 33-37 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: All the present experiments confirm that there is some liquid channelling on trays. Liquid channelling is extensive on trays of large diameters. It largely depends on the tilting of the plate, modifications of the inlet weirs and on non-uniform bubble cap spacing. Consequences of liquid channelling for plate efficiency are clear; the higher the degree of liquid channelling the lower the plate efficiency. However, own experimental and theoretical investigations indicate that plate efficiency never falls below the value of point efficiency. Therefore, liquid channelling only affects the crossflow on trays. Liquid channelling reduces the mass transfer performance to a similar extent as does the backmixing of liquid. Consequently, plate efficiency is not very sensitive to liquid channelling. Since the liquid is completely mixed in the downcomer, the effects of liquid channelling are restricted to a single tray. The behaviour of tray columns completely differs from that of packed columns, where the effects of liquid channelling are cumulative over the packed height. Consequently, trays represent a suitable design for columns of large diameters.
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  • 58
    Electronic Resource
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    Chemical Engineering & Technology - CET 10 (1987), S. 16-27 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Although carbon dixoide is important as an abundant carbonaceous raw material, so far, its utilization in chemical processes has been rather limited. This review covers the reactions of CO2 employed in industry, such as the production of urea, the Kolbe-Schmitt reaction, the synthesis of cyclic organic carbonates and the use of CO2 in methanol synthesis. Interesting recent developments in CO2 chemistry, such as the reactions catalyzed by transition metals, are also described. Apart from the synthesis of polymers and hydrocarbons, the production of oxygen-containing substances appears to be very profitable and attractive for future industrial applications. Not only can derivatives of formic and carbonic acids be produced but also longer-chain carboxylic acids and their derivatives by reactions of carbon dioxide with hydrocarbons such as alkynes, alkenes and 1,3-dienes.
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  • 59
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The present contribution illustrates a way of developing a continuous separation process for near critical fluid extraction, on the example of separation of soya oil from lecithin. First, a suitable solvent was selected. Phase equilibria were measured in autoclaves. Operating conditions for a pilot plant were derived from the phase equilibrium data. The pilot plant experiments provided the necessary data for designing a production plant. Computer programs for phase equilibrium, stage to stage and mass and heat balance calculations were used in order to minimize the number of experiments. A production plant with a capacity of 500 t/a of raw lecithin was designed on the basis of experimental and computational results. A cost estimation, based on tenders, showed that it is more economical to produce lecithin by near critical fluid extraction than by conventional acetone extraction.
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  • 60
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    Chemical Engineering & Technology - CET 10 (1987), S. 56-63 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Ideal flow conditions are generally assumed for the reactor design. If stoichiometry, reaction mechanism and kinetics are known, the balance equations for the ideal flow tube, the ideal steady-state continuous stirred tank reactor or the ideal, completely mixed stirred batch reactor are often applied. In many cases, formal kinetics, which forms the basis of reaction modelling, is so uncertain that the idealization of the flow field can be accepted. In practice, however, deviations from the ideally calculated conversions, yields and product qualities, often occur. In these cases, it is necessary to consider the real flow conditions. In general, a distinction is made between macroand micromixing processes.
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  • 61
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    Chemical Engineering & Technology - CET 10 (1987), S. 1-15 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Using pilot-scale test plant, the interfacial area per unit volume was investigated in different gasliquid reactors, i.e. packed column, bubble column and free jet reactor. The interfacial area was studied as a function of liquid viscosity and of operating parameters. As a rule, identical test conditions were maintained in all the measurements, in order to obtain comparable results. The interfacial area was determined by chemical means using the sulphite system (a solution of sodium sulphite in water as model liquid and air as gaseous medium). The viscosity of the solution can be increased by adding carboxymethyl cellulose without significantly affecting the reaction kinetics. The addition of a surfactant to the sulphite system allowed comparative measurements at reduced surface tension. Based on a large number of measurements, the correlations of the interfacial area are expressed as power laws. The inclusion of experiments with a jet tube reactor and a stirring vessel allows an extensive comparison of all reactors. All tests were carried out with the same material system and the same method was used to determine the interfacial area per unit volume. Therefore, a comparison with respect to mass transfer is possible.
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  • 62
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    Chemical Engineering & Technology - CET 10 (1987), S. 27-32 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A new measurement method for determining the local liquid-phase velocities in multiphase flows is presented. It is based on a tracer technique, using heat introduced into the flow, seemingly at random, instead of a material tracer. The input of heat pulses and measurement of temperature at an adjacent point is performed by small probes. As an intermediate result, the flow time distribution of the heat-labelled fluid elements is calculated on-line as a cross-correlation function between the pseudo-random input and the measured output signals. This calculation and the automatic control of measurements is carried out by a simple microprocessor unit. The device produced excellent results in gas-liquid flows at high gas throughputs and high liquid-phase velocities.
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    Chemical Engineering & Technology - CET 10 (1987), S. 63-72 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Among other processes, adsorption is used for the removal of hydrogen sulphide from natural gases. Hereby, competitive adsorption of the different gas components plays an important role, e.g., that of carbon dioxide. Data of equilibrium loading and adsorption kinetics are required for the design of adsorbers, filled with molecular sieve. In order to obtain these data under the prevailing operating conditions, hydrogen sulphide was removed from gas mixtures H2S/CH4 and H2S/CO2/CH4, in a pilot plant, by adsorption on molecular sieve 5A. The equilibrium loading, the height of transfer zone, and the length of unused bed were determined from the measured breakthrough curves of H2S. With these data, the breakthrough time and the optimum process conditions were calculated for a practical example.
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  • 64
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    Chemical Engineering & Technology - CET 10 (1987), S. 43-55 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The oxidation of carbon monoxide by air in a turbulent flow was investigated under experimental conditions where the rates of turbulent mixing and of chemical reaction are comparable. For this purpose, carbon monoxide was admixed into the completely burnt gas of a natural gas flame operated with excess of air. Measurements of mean values of axial velocity, temperature and volume fractions of carbon monoxide and oxygen were compared with computational simulations involving the k - ∊ turbulence model and several turbulent reaction models for the oxidation of carbon monoxide. The comparison of measurements and numerical calculations demonstrated that the k - ∊ turbulence model is suitable for prediction of the turbulent flow field in the flow system investigated. Furthermore, it could be shown that one-variable turbulent reaction models, such as the flamesheet or the eddy-break-up model, cannot explain the measured carbon monoxide volume fraction profiles. Two-variable turbulent reaction models with a probability density function closure of the source term of the transport equation for the mass fraction of the chemical species result in a better agreement between the measured and simulated volume fraction profiles, particularly in predicting the clear influence of the initial temperature on carbon monoxide volume fractions. Weighting of the kinetic rate expression for the oxidation of carbon monoxide with different presumed probability density functions yields slightly different predictions of the carbon monoxide volume fractions, reflecting the assumed different character of turbulent fluctuations.
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  • 65
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    Chemical Engineering & Technology - CET 10 (1987), S. 92-98 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Distillation columns with vertical partitions can separate a feed mixture into 3 or 4 pure fractions. Compared to other column arrangements, their investment costs and energy consumption are lower. Production columns show good results and are easily controlled. Conventional distillation columns produce only 2 pure product streams at the top and at the bottom of the column. Side products are contaminated by light or heavy components, depending on the location of the side stream in the rectifying or stripping section. This disadvantage is set aside by using a distillation column with a vertical partition. The internal separation wall prevents lateral mixing of liquid and vapour in the central part of the column, forming there separate feed and outlet sections. In the presence of a vertical partition, 3 or 4 pure fractions can be obtained in a single distillation step. This is particularly advantageous when heat sensitive components are to be separated. On account of good thermodynamic properties, the energy consumption is 20 to 35% lower than that of other distillation arrangements. The control behaviour is similar or better than that of conventional distillation columns.
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  • 66
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    Chemical Engineering & Technology - CET 10 (1987), S. 86-92 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The Carman-Arnell equation relates the rate of flow of a fluid through a packed bed to the pressure drop across the bed. This equation is the basis for surface area determination by permeametry. It is found that the surface area measured at sub-atmospheric pressure varies with the bed porosity, so a porosity was selected where the rate of change was at a minimum. The study suggests that, at reduced pressures, the gas flow rate is a linear function of the mean pressure.
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  • 67
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    Chemical Engineering & Technology - CET 10 (1987), S. 104-112 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A 0.5 MW spray-dry scrubbing FGD pilot plant was used in the study of spray dryer performance over a wide range of operating conditions. Experimental findings were compared with a spray dryer model. During operation with large excesses of lime, the SO2 absorption was limited by gas phase diffusion. At operation with a shortage of lime, the rate limiting step was the dissolution rate of lime. In addition, the flow regime in a spray dryer can be best described as well mixed. The SO2 level in the flue gas was found to exert no direct effect on the efficiency of SO2 removal. The observed effects are attributed solely to the changes in the drying process, due to the inter-dependence of slurry composition and SO2 concentration.
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  • 68
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    Chemical Engineering & Technology - CET 10 (1987), S. 73-86 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: As a part of a research project on the mass transfer in liquid pulsed sieve-tray extraction columns (PSE), the diameters and hold-ups of the drops were measured: the drop size using a suction technique, with photoelectric detection, which was adapted to the special boundary conditions of the PSE; the integral hold-up by the pressure difference between the lower and upper parts of the column. Since experimental results cannot be described by known calculation formulae for the Sauter mean diameter and the hold-up, a new method of calculation was developed. It is phenomenologically based on high-speed photographs of the drop motion on a sieve tray. The mathematical-physical model allows the prediction of drop size and hold-up within certain limits, while the possible different operating regimes of the PSE, i.e. the mixer-settler and dispersion regimes can also be estimated.
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  • 69
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    Chemical Engineering & Technology - CET 10 (1987), S. 125-131 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: When crude oil is vacuum distilled, about 30% of the feed remain as low value residue. Hydrocracking can upgrade this residue into valuable light hydrocarbons. The hydrocracking could be optimized catalytically, if the residue were not to contain the metals vanadium and nickel that poison the catalyst. This contribution shows that continuous extraction of the residue with ethyl acetate yields a fraction with low metal content, while an asphaltene fraction with the remaining metal content is filtered off.
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  • 70
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A one-stage model of the formation of primary bubbles is presented in which the bubble volume is deduced from an equilibrium of buoyancy, viscosity, inertia and surface tension forces. In contrast to the two-stage model, presented by Kumar and Kuloor, it was not assumed that the drag coefficient in bubble expansion can be described by the same constants as in the steady-state bubble ascent. The constants were adapted in such a way that the introduction of an additional bubble volume was not necessary. It was demonstrated that this model describes the bubble formation in gravitational and centrifugal fields equally well and, furthermore, is also applicable to structurally viscous liquids, provided that the effective shear gradient \documentclass{article}\pagestyle{empty}\begin{document}$$ \mathop {\rm \gamma }\limits^. = \frac{1}{6}({\rm \Delta \rho }gzd_{\rm B} /{\rm \eta }) $$\end{document} is calculated from the equilibrium of shearing and buoyancy forces. The model is based on the assumption of a constant volumetric flow rate during bubble formation and, for this reason, a minimum Froude number is necessary in analogy to the weeping limit for sieve plates. The normalized presentation permits simple operation. The possibility of applying the model to drop formation was confirmed by comparison of experimental values with those, predicted by the model.
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  • 71
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A new equipment for the measurement of virial coefficients of pure substances and binary mixtures is described. It consists of an improved modification of the set-up proposed by Eucken and Meyer in 1929. The development is based on a critical review of the existing methods particularly with respect to adsorption effects. In order to reduce the influence of adsorption on the accuracy of virial coefficients, an optimum range for gas density is recommended. The accuracy of the virial coefficients is better than 20 cm3 mol-1. The set-up was employed for the measurement of virial coefficients of acetone and hexane in the range from 352.95 to 393.85 K. The results are in excellent agreement with data published in literature. Furthermore, cross-virial coefficients of the binary system acetone/hexane were measured and interpreted.
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  • 72
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    Chemical Engineering & Technology - CET 10 (1987), S. 113-125 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Fouling and/or scaling of heat transfer surfaces causes serious problems in industry. Prevention of fouling is therefore essential for technical (considerable deterioration of heat transfer) and also economic reasons (increased costs). In order to provide successful countermeasures, it is, however, necessary to obtain more detailed information on the physical, chemical and biological processes which produce fouling. Based on the already known fouling mechanisms, it is shown that a satisfactory prediction of fouling behaviour of heat exchangers is not yet possible. This contribution presents a physical model for the description of fouling, caused by sedimentation and crystallization. It is assumed that, during fouling, deposition and removal processes overlap. In order to verify the theoretical considerations, experiments were carried out on a test rig, which could also be used for field experiments. Aqueous CaSO4 solutions served as experimental liquids. A comparison of experimental and calculated fouling factors shows a satisfactory agreement.
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    Chemical Engineering & Technology - CET 10 (1987), S. 157-164 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Based on a paper by Hein, a dimensioning program for tube-bundle heat exchangers with straight tubes and fixed tube sheets has been developed. The equipment to be dimensioned is tested at 14 critical points, with regard to permissible stresses. The optimum thickness of the tube sheet, the shell and channel are subsequently selected on the basis of economic criteria. Compared to dimensioning according to AD-data sheet, it is possible to save between 10 and 25% of production costs. With the aid of a finite-element (FE) program, complex structures such as heat exchangers can be calculated accurately. Several mesh-generation programs were written for the data input. The structure of a tube-bundle heat exchanger with straight tubes is generated with 3/D elements with only some geometrical data. An FE-calculation of a heat exchanger is explained with the aid of an example and stress analysis is presented.
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  • 74
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    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The present contribution reports on a new method for the simulation of the dispersed phase behaviour in liquid-liquid extraction columns. The fluid dynamic description is based on a mathematical model which explicitly takes into account drop transport, break-up and coalescence mechanisms, via a drop population balance along the column. Application of the model requires some simple measurements on single drops in order to determine transport and break-up laws, which are required by the model, and possibly also coalescence parameters. In this study the model is applied to pulsed sieve plate columns. The specific example considered here is based on systematic studies on the determination of break-up rates from the corresponding probabilities of break-up and the generated daughter drop size distributions by means of high-speed photography. The validity of the model was subsequently tested by comparison with some experimental results from studies on two different pulsed columns 80 and 225 mm in diameter for the water/toluene system without mass transfer. The satisfactory agreement between the results justifies the use of such a method for the description of the behaviour of liquid-liquid extraction columns in a wide range of operating conditions. Furthermore, application of the model may help to dispense with long and expensive pilot tests.
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  • 75
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    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Microbial desulphurization of coal by pyrite oxidizing enrichment cultures containing predominantly Thiobacillus ferrooxidans was performed in an air-agitated slurry reactor, 20 l in volume. A model of microbiological and chemical reactions, occurring at various points within the coal, was set up taking into account the pore structure of the coal. The influence of parameters relevant to industrial processes, such as superficial gas velocity, particle size, initial pyrite concentration, and slurry density of the coal, on the conversion of pyrite was examined. Variation of the superficial gas velocity in the range of 0.01 to 0.04 m/s confirmed that the reaction is not controlled by oxygen transfer from gaseous to liquid phase. The rate of pyrite oxidation depends mainly on the accessibility of pyrite to micro-organisms which is determined by the particle size of the coal as well as the distribution of pyrite crystals in the coal matrix. The accessibility of pyrite to the micro-organisms is described by the ratio of effective to maximum microbial activity, measured as oxygen consumption. Starting with higher initial concentration of pyrite in the coal increases the oxidation rate, according to first order kinetics. Enhanced slurry densities lead to a decrease of pyrite conversion, in spite of higher pyrite concentration. The maximum pyrite oxidation rate was measured at 15% (v/v) slurry density and 25°C as 1800 mg Spyr/kg coal per day, or 360 mg Spyr/l reactor volume per day.
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  • 76
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    Chemical Engineering & Technology - CET 10 (1987), S. 131-142 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The influence of electrolytes, which are dissolved in the aqueous absorbent and do not react with nitrogen oxides, on the absorption kinetics of both these components was investigated experimentally. In addition to demineralized water, various salt solutions of different concentrations as well as sodium hydroxide solution were used as absorbents. The term H \documentclass{article}\pagestyle{empty}\begin{document}$ H\sqrt {k_1 D} $\end{document} for N2O4 and N2O3, which is important for the design of industrial absorbers, was determined as a function of composition and concentration of the absorbents. In the case of N2O4, the chosen measuring and evaluation methods permitted a separate determination of the rate constant k of the pseudo first order reaction and of the solubility H. The diffusion coefficient D of the gas in the absorbent can be obtained only by calculation. Experimental results showed that \documentclass{article}\pagestyle{empty}\begin{document}$(H\sqrt {k_1 D} )\,_{{\rm N}_{\rm 2} {\rm O}_{\rm 4} } $\end{document} decreases with increasing ionic strength I, however, without a clear indication of any ion-specific effects. This decrease does not appear to be caused simply by a reduction in solubility (salting out effect), or in diffusion coefficient, but at least, to the same extent, through a decrease of the rate constant k with increasing electrolyte content in the absorbent. The measurements permitted the determination of the gas-based salting out parameter for N2O4. The investigations on the absorption of N2O3 in water and in an Na2SO4 solution showed no experimentally detectable influence of dissolved salts on \documentclass{article}\pagestyle{empty}\begin{document}$(H\sqrt {k_1 D} )\,_{{\rm N}_{\rm 2} {\rm O}_{\rm 3} } $\end{document}. The numerical value of \documentclass{article}\pagestyle{empty}\begin{document}$(H\sqrt {k_1 D} )\,_{{\rm N}_{\rm 2} {\rm O}_{\rm 3} } $\end{document} is six times that of \documentclass{article}\pagestyle{empty}\begin{document}$(H\sqrt {k_1 D} )\,_{{\rm N}_{\rm 2} {\rm O}_{\rm 4} } $\end{document}.
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  • 77
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    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Slurry bubble columns are widely used in biotechnology. Therefore, the effects of solid particles on fluidization characteristics, gas hold-up and volumetric liquid-side mass transfer coefficient were measured in a slurry bubble column (i.d. 0.14 m). The density and diameter of the suspended particles were similar to those applied in biotechnology with immobilized bacteria. Based on models of turbulence and of liquid circulation induced by rising gas bubbles, equations for critical gas velocity, gas hold-up and volumetric liquid-side mass transfer coefficient were obtained by dimensional analysis.
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  • 78
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    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The detailed dynamic simulation of coupled process units in chemical plants is gaining an increasing importance as a useful tool in plant engineering and operation. The outline of the program package DIVA (Dynamische Simulation verfahrenstechnischer Anlagen) which is currently under development is presented in the following. The dynamic plant equations and the corresponding Jacobian matrix are generated automatically. The full exploitation of sparse matrix techniques in combination with stiff ODE (ordinary differential equation) solvers allows an efficient solution of all the equations simultaneously. The possibilities offered by the simulator are demonstrated by the simulation of two laboratory plants.
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  • 79
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    Chemical Engineering & Technology - CET 10 (1987), S. 190-203 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Spatially resolved oxygen concentration measurements were performed in premixed hydrocarbon flames by using laser induced spontaneous Raman scattering. The measurements demonstrate the performance of a relatively simple pulsed laser Raman probe for fundamental combustion studies and also for the control of the equivalence ratio in flames (best spatial resolution: 0.2 mm3; theoretical detection limit: 0.8% of O2). Comparison of the results with those obtained by a mechanical suction probe (Magnos 2 T) confirmed a good agreement. At present, control of different stoichiometric conditions is possible at a minimum O2 concentration of 1.3%.
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  • 80
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: During the sudden unheated vessel top venting of initially saturated two-component gas/liquid mixtures, in which the gas is also extensively dissolved in the non-evaporating liquid phase, a solubility inequilibrium develops between the phases; re-equilibration can set in only after a so-called desorption delay time. Laboratory measurements of this delay time were under-taken with model mixtures of CO2 and water and viscous aqueous (Newtonian) solutions by high speed cinematography. The parameters of the experiments are relief cross-section, initial liquid level, pressure, temperature, and concentration. The shortest deley time obtained lasts approximately 75 ms. It differs substantially from the minimum boiling delay time previously measured with various refrigerants in the same test facility. The experimental results are correlated by a semi-empirical dimensionless power relationship, which includes all independent primary design variables generally availble in a physically consistent interrelationship. Reasonable extrapolations to other test conditions and aqueous two-component systems with an acceptable accuracy systems can therefore be expected.
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  • 81
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Correlations for pressure drop and upper capacity limit (flooding) are useful for the design of packed columns. Available correlations are based on the results of measurements made at atmospheric pressure. Extrapolation to higher pressures is not recommended. Therefore, systematic experimental investigations were carried out in a pilot plant at pressures of up to 100 bar. The experimental equipment and techniques, evaluation methods, and some characteristic experimental results are presented.
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  • 82
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    Chemical Engineering & Technology - CET 10 (1987), S. 224-230 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: This paper describes a pilot plant for entrainment measurements on various types of column trays. The data obtained from different trays differ by up to a factor of 10. The measurements were compared with the theoretical model of Stichlmair. The Stichlmair entrainment diagram permits a fairly accurate prediction for most types of trays if the height of the two-phase layer is known. Prediction of the height and relative liquid hold-up in this two-phase system should be modified by a term reflecting the vapour flow profile, which requires further testing. These tests should examine the effect of tray spacing, fractional free area and, in particular, the influence of different media.
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  • 83
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    Chemical Engineering & Technology - CET 10 (1987), S. 204-215 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: In three-phase systems, where the liquid constitutes the continuous phase, solid is the catalyst and gas represents the dispersed phase, there are decisive criteria which have to be observed in reactor design. These are e.g. the interfacial area per unit volume between gas and liquid, the volumetric mass transfer coefficient and the mass transfer coefficient. The basic aim of the present work was therefore the investigation of these parameters in relation to the main influencing parameters. Process parameters stirrer speed and superficial gas velocity were varied as well as the physical properties such as liquid viscosity, solids concentration, particle diameter and a geometrical parameter, i.e. reactor diameter. The sulphite method was employed for the determination of these values. The test results confirmed the known relationships of power consumption and superficial gas velocity. An increase in the liquid viscosity leads to a decrease in all the tested values. In most cases, suspended solid particles lead to a lowering of the test values. The influence of the tank diameter on the plots of the test values against specific power consumption turned out to be invariant so that a scale-up of geometrically similar systems can be carried out at constant power consumption, superficial gas velocity and liquid viscosity.
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  • 84
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    Chemical Engineering & Technology - CET 10 (1987), S. 242-248 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Pool boiling data of multicomponent mixtures show that the heat transfer coefficients can be considerably lower than those of a corresponding pure fluid with the same physical properties as the mixture. The proposed model, which assumes maximum mass transfer resistance in the liquid boundary layer, is confirmed by the comparison between calculated and experimental data. The model allows the prediction of heat transfer coefficients in pool boiling of mixtures using only single component properties and vapour-liquid equilibrium data. Judging by experience with a number of different systems, the method should be sufficiently accurate for most practical applications.
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    Chemical Engineering & Technology - CET 10 (1987), S. 248-255 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The development of heat resistant permeation membranes has opened up new possibilities for the conversion of fossil energy resources. In steam reforming of natural gas, such membranes even permit a direct production of hydrogen at high temperatures during the conversion of feed hydrocarbons. Further gas processing, such as required for reformer gas in existing hydrogen production processes, is not necessary. Due to continuous hydrogen discharge directly in the reformer tube, the chemical equilibrium of the occurring reactions becomes displaced towards the products, resulting in more favourable process conditions and, consequently, in improved by 36% utilization of the feed hydrocarbons. At the same time, the hydrogen yield increases by 44%. The heat required, which is provided by a high temperature reactor, is 17% in excess of that in conventional plants. It can be expected that the simplified process design will produce substantial cost advantages over the existing processes for the production of hydrogen.
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  • 86
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: In the present paper, models are developed for the description of coalescence and splitting of bubbles in gas fluidized beds. The distinction between slow and fast bubbles, which originates from the Davidson model of gas flow in and around a rising bubble, was found to be decisive for the modelling of coalescence processes. On the basis of the respective models, it is shown that a change in bed temperature does influence the mechanisms of both bubble coalescence and splitting. In cases of both slow and fast bubbles undergoing splitting, the theory predicts a decrease of bubble size with temperature whereas in the case of a non-splitting system with fast bubbles, typically encountered with Geldart type B particles, no significant temperature effect on bubble size is expected. The theoretical predictions are shown to be in agreement with own measurements as well as with the results of other workers.
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  • 87
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    Chemical Engineering & Technology - CET 10 (1987), S. 262-271 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Pressure pulsations in hydraulic systems, generated by reciprocating pumps, can cause serious problems with regard to plant safety and reliability. In particular, fatigue problems arise in high-pressure piping systems. The available knowledge is not sufficient for an accurate computation of pressure peaks in the piping of reciprocating pumps. A number of calculation models are available which, however, neglect both fluid compressibility and friction. This contribution presents a calculation method which allows a precise modelling of various pump installations. Comparison of calculated and experimental data shows a good agreement and provides a validation of the computational model.
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  • 88
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    Chemical Engineering & Technology - CET 10 (1987), S. 256-261 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: In the separation of gaseous mixtures by gas permeation, it is in some cases impossible to achieve the desired product quality in a single stage and, therefore, several stages may be necessary. Multistage processes can be implemented by membrane modules arranged in the form of a cascade or by a membrane column design. On the basis of an economic analysis, this paper discusses different possible module arrangements for 2 cases, i.e. the enrichment of oxygen from air and the separation of methane from biogas. Present calculations indicate that, in the first case, two-stage cascades with or without recycle and, in the second case, one-stage cascade without recycle constitute the optimum module arrangements. However, depending on the selling price of the methane enriched gas, one- or two-stage cascades with recycle have to be considered. Finally, It was shown that, in the permeation of non-ideal gases, the Joule-Thomson effect has to be taken into account.
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    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 10 (1987), S. 281-289 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Fundamental investigations of coalescence processes in settlers with plate packages for the separation of liquid-liquid dispersions prompted an analysis of the drop motion on the interface of a stratified two-phase flow. Therefore, a physical model was developed, which permits the calculation of drop velocity along the interface of an inclined trickling film. Starting from a balance of forces around a single particle, the model provides the equation of motion for a steady motion of single particles in a stratified two-phase flow. Several assumptions and considerations were necessary to solve this equation, such as taking into account the influence of the wall and of flow resistance. The model calculation assumes Newtonian liquids and laminar, smooth trickling films. A comparison with experimental results confirms that the drop motion behaviour is well reproduced.
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  • 90
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    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 10 (1987), S. 291-296 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The kinetics of extraction processes with chemical reaction was studied experimentally on the system copper/Acorga PT 5050 and quantified according to meaningful kinetic models. These were coupled with other models describing the behaviour of dispersions in columns in order to permit a computer aided simultation of reactive extraction. Thus, a better prediction of column performance is achieved.
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  • 91
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    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 10 (1987), S. 312-322 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Existing heat exchanger design criteria do not satisfy the continually increasing requirements for greater efficiency or mass flux and energy throughput. Occasionally, failures appear even after only a few hours of operation, as shown in section 3. A long series of experiments, often carried out on original scale, did lead to the derivation of a large number of empirical expressions; however, physical explanations of the complex tube-failure interactions could not as yet be found. In contrast, experiments with a well defined simple model, whereby the tube deflections were recorded digitally and, at the same time, tube-fluid interactions were registered on a high-speed film, show that elementary “fluid transport mechanisms” control the stability behaviour of the heat exchanger tubes. Vibration excitation mechanisms such as “galloping”, “jet switching” and “whirling” (fluid elastic coupling) proved, with their characteristics, as typical for the vibration behaviour of single rows within the tube array, but not for the vibration phenomena of tube bundles.
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  • 92
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    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 10 (1987), S. 297-305 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Against the background of long-term availability of natural gas, its present technology and future prospects are described. Particular emphasis is put on the oxidative coupling of methane to C2+ hydrocarbons: (1) Catalyst development, activity, selectivity and deactivation as well as reactor operation are discussed; (2) a tentative process scheme is put forward and its economics evaluated with respect to ethylene production.
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  • 93
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    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 10 (1987), S. 323-329 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The conversion of a number of alcohols, ethers, ketones, aldehydes, carboxylic acids, esters, and cyclic compounds and their mixtures on H-ZSM-5 at 673 K was investigated. These compounds can be easily converted to aromatic hydrocarbons if the C/H ratio of the molecule fragment, remaining after elimination of oxygen as water, is less than 0.62. At higher C/H ratios, coking of the catalyst increases, thus reducing its lifetime, a difficulty which can be overcome by hydrogenation of these compounds prior to their conversion over H-ZSM-5. A procedure is proposed for converting at least a part of organic waste chemicals to valuable products instead of burning them.
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  • 94
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An experimental study of the flow of phosphate mine tailings was carried out in order to characterize these suspensions of fine particles for pipeline transport. Rheological measurements with a rotating cylinder viscometer indicate a viscoplastic behaviour which can be represented by a Herschell-Bulkley or by a Casson model. The variation of the parameters of these models with solids concentration reveals a change in the behaviour at a concentration of 10 to 15%. The pressure drops were measured during flow in capillary tubes, in both laminar and turbulent regimes. The variation of the pressure drop coefficient (Fanning friction factor) as a function of the generalized Reynolds number confirms the validity of the employed rheological models. The results are in good agreement with measurements made in pipes of industrial size. The velocity profiles measured with a novel ultrasonic velocimeter demonstrate the influence of the rheological behaviour on the yield and wall stresses.
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  • 95
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    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 10 (1987), S. 330-337 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The aim of this investigation is to show the demarcation of two possible mechanisms for surface deposition of fine particles on the rear surface of single spheres. By means of single particle trajectory computation, based on numerically determined flow fields (Remax = 103), it is shown that the mere existence of a wake is not in itself sufficient to produce eddy deposition. In addition, the particle's motion must undergo a lateral transfer promoted by fluid trubulence, in order to effect eddy deposition commencing at a Reynolds number of about 100. On the other hand, rear deposition, influenced by electrostatic forces, especially by the Coulomb force, is possible at any Reynolds number. Consequently, for Reynolds numbers of less than 100, only electrostatic effects can produce rear surface deposition. In the range of high Reynolds numbers, the coexistence of both mechanisms is possible. Very high Reynolds numbers (Re 〉 103) and low Stokes numbers indicated the predominance of the electrostatic effect over eddy deposition, whereas at very high Reynolds numbers and medium to high Stokes numbers the electrostatic effect is only predominant in presence of high electrostatic charges.
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  • 96
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    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 10 (1987), S. 349-352 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A simplified reactor model can be used for predicting the performance of an industrial VGO-treater. Laboratory-scale experiments performed on the same feed and catalyst as those in the industrial unit lead to a reactor simulation which agrees well with the data from this unit. In the laboratory experiments, it is possible to overcome the specific hydrodynamic problems of tricklebed reactors by appllying the catalyst dilution technique. Results obtained by this technique allowed the development of a reactor model which enables the user to simulate the adiabatic behaviour of the industrial reactor. In this way, the significant gap between the reaction temperature in the isothermal laboratory reactor and the WABT of the industrial adiabatic reactor can be bridged.
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  • 97
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    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 10 (1987), S. 361-367 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The rate behaviour of multi-step reaction systems is difficult to model. Concentration-controlled investigations in a recycle reactor provide new tools for this purpose, e.g. the possibility to decompose a network into single reaction steps. Methanation of carbon monoxide over a supported Ni catalyst could be shown to be accompanied to a considerable extent by the shift reaction, and to a lesser extent by direct hydrogenation of carbon dioxide. Deactivation of the catalyst was measured at definite gas compositions. The two main steps show different responses to deactivation: Separable kinetics was found only for the methanation step. Power law rate equations were fitted to the rate data of the individual reaction steps to represent the main features of their kinetic behaviour. Some aspects of deactivation kinetics are also discussed.
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  • 98
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    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 10 (1987), S. 368-375 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: This contribution presents the measurements of bubble behaviour in presence of A, B and D powders in a semi-industrial scale pressurized fluidized bed. Local measurements were taken at static pressures of 0.2, 1.0 and 2.5 MPa, using capacitance probes. Quartz sand with mean particle diameter of 157 μm was fluidized in small “two-dimensional” transparent equipment with Frigen R 115. In addition, pressure fluctuations in the bulk of the fluidized bed with inner diameter of 0.4 m were studied experimentally.
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  • 99
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    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 10 (1987), S. 353-360 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Correlation flowmeters have been used in the scientific field for many years and are actually gaining greater commercial importance due to an increasing number of applications in industrial plants. The importance of the correlation method is based on the fact that essentially no alternatives exist for measuring velocity and mass flow rate in pneumatic conveyors. However, the hitherto employed transit time correlation method leads to results which are clouded by uncertainties. The commonly used theoretical model of the measurement process does not explain these effects satisfactorily. Therefore, the theory of non-intrusive flow sensors is reinvestigated from a physical standpoint. The derived model permits a discussion of the transit time correlation method in some detail. Furthermore, this model leads to an alternative sensor arrangement and signal processing scheme which makes it possible to measure the true mean velocities. Examples of experimental results are given.
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  • 100
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: For the simulation of steady- and non-steady-state behaiour of separation columns, a simulation program was developed and employed for the calculation and optimization of methanol-water separation. The demand for increasingly higher purities and energy-saving optimization of plants results in complex column configurations and thus in complex control schemes. The number of possible control schemes was reduced on the basis of heuristic rules. By simulating the process, the optimum control and manipulative variables and measuring points were determined from the reduced number of control concepts. A control scheme was introduced. The model was verified by simulation of the dynamic behaviour of the process. The investigation included the effects of computing technique, time interval, model reduction and tray hold-up on the results. Thus, various effects and interactions were verified theoretically with respect to the robustness of the model. This was followed by a simulation of the non-ontrolled and controlled column. By implementing the controllers in the existing column program, the computer can predict the control parameters. These parameters were checked and corrected when the metahnol-ater column was put in operation. In the start-up phase, major problems were caused by the sensitivity and failure rate of density, throughput and pump measuring sensors. Feed impurities were another source of problems. Operation with high product purities is possible, with a side stream to discharge impurities.
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