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  • Chemistry  (25,303)
  • Cell & Developmental Biology
  • Fluid Mechanics and Thermodynamics
  • Seismology
  • 2010-2014  (786)
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  • 1
    Publication Date: 2017-04-04
    Description: Following the paper by Fraser-Smith et al. (1990), many scientists have focused their research on the ULF geomagnetic field pulsations in the hope of finding possible anomalous signals caused by the seismic activity. Thereafter, many papers have reported ULF geomagnetic field polarization ratio increases which have been claimed to be related to the occurrence of moderate and strong earthquakes. Even if there is no firm evidence of correlation between the polarization ratio increase and seismic events, these publications maintain that these ‘‘anomalous’’ increases are without doubt precursors of pending earthquakes. Furthermore, several researchers suggest that these seismogenic signals may be considered a promising approach towards the possibility of developing short-term earthquake prediction capabilities based on electromagnetic precursory signatures. On the contrary, a part of the scientific community emphasizes the lack of validation of claimed seismogenic anomalies and doubt their association with the seismic activity. Since earthquake prediction is a very important topic of social importance, the authenticity of earthquake precursors needs to be carefully checked. The aim of this paper is to investigate the reliability of the ULF magnetic polarization ratio changes as an earthquakes’ precursor. Several polarization ratio increases of the geomagnetic field, which previous researchers have claimed to have a seismogenic origin, are put into question by a qualitative investigation. The analysis takes into account both the temporal evolution of the geomagnetic field polarization ratio reported in previous papers, and the global geomagnetic activity behaviour. Running averages of the geomagnetic index Kp are plotted onto the original figures from previous publications. Moreover, further quantitative analyses are also reported. Here, nine cases are investigated which include 17 earthquakes. In seven cases it is shown that the suggested association between the geomagnetic field polarization ratio increases and the earthquake preparation process seems to be rather doubtful. More precisely, the claimed seismogenic polarization ratio increases are actually closely related to decreases in the geomagnetic activity level. Furthermore, the last two investigated cases seem to be doubtful as well, although a close correspondence between polarization ratio and geomagnetic activity cannot be unambiguously demonstrated.
    Description: Published
    Description: 19-32
    Description: 2.6. TTC - Laboratorio di gravimetria, magnetismo ed elettromagnetismo in aree attive
    Description: JCR Journal
    Description: restricted
    Keywords: Earthquake precursors ; Short-term earthquake prediction ; Geomagnetic field ; Seismology ; 04. Solid Earth::04.05. Geomagnetism::04.05.99. General or miscellaneous ; 04. Solid Earth::04.05. Geomagnetism::04.05.04. Magnetic anomalies ; 04. Solid Earth::04.06. Seismology::04.06.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Publication Date: 2017-04-04
    Description: Prattes et al. (2011) report ULF magnetic anomalous signals claiming them to be possibly precursor of the 6 April 2009 MW6.3 L’Aquila earthquake. This comment casts doubts on the possibility that the observed magnetic signatures could have a seismogenic origin by showing that these pre-earthquake signals are actually part of normal global geomagnetic activity.
    Description: Published
    Description: 1717–1719
    Description: 2.6. TTC - Laboratorio di gravimetria, magnetismo ed elettromagnetismo in aree attive
    Description: JCR Journal
    Description: open
    Keywords: Geomagnetic field ; Earthquake precursors ; Magnetic anomalies ; Seismology ; 04. Solid Earth::04.05. Geomagnetism::04.05.99. General or miscellaneous ; 04. Solid Earth::04.05. Geomagnetism::04.05.04. Magnetic anomalies ; 04. Solid Earth::04.06. Seismology::04.06.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 3
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    Springer
    Publication Date: 2017-04-04
    Description: n/a
    Description: Published
    Description: 125-127
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: restricted
    Keywords: Core-mantle boundary topography ; Seismology ; 04. Solid Earth::04.01. Earth Interior::04.01.03. Mantle and Core dynamics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: book chapter
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  • 4
    Publication Date: 2017-04-04
    Description: La Rete Sismica Mobile (RSM) in dotazione al Centro Nazionale Terremoti (CNT) è da anni impiegata nell’attività di monitoraggio in occasione di emergenze sismiche e vulcaniche ma soprattutto in numerosi progetti scientifici con particolare riguardo allo studio di dettaglio di specifiche aree e/o strutture sismotettoniche. In numerose occasioni gli esperimenti di acquisizione di nuovi dati sismici e le emergenze sismiche o vulcaniche degli ultimi anni hanno visto una collaborazione con altre unità di reti mobili sia interne all’INGV (la Sezione di Catania, la Sezione di Milano-Pavia e l’Osservatorio Vesuviano di Napoli) che esterne (ad esempio il Centro Ricerche Sismologiche di Udine). All’inizio del 2009 Jesús M. Ibáñez Direttore dell’Instituto Andaluz de Geofísica Universidad di Granada ha proposto alla RSM del CNT di partecipare all’esperimento di sismica passiva da realizzare al Teide, complesso vulcanico nell’isola di Tenerife, nell’ambito del Progetto di ricerca finanziato “High resolution imagin of seismogenetic volumes in active volcanoes, Tenerife and Deception Islands, and its significance for volcanic hazard assestment” (HISS). L’esperimento, iniziato il 10 novembre 2009 proprio con l’installazione di una delle 6 stazioni messe a disposizione dalla RSM del CNT, avrà la durata di circa un anno. In questo rapporto tecnico viene descritta la campagna di installazione della RSM del CNT.
    Description: Istituto Nazionale di Geofisica e Vulcanologia
    Description: Published
    Description: open
    Keywords: Teide volcano ; Seismology ; Instruments ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: report
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  • 5
    Publication Date: 2017-04-04
    Description: Hirano and Hattori (2011), hereafter cited as H&H, report the observation of anomalous increases in the ULF geomagnetic field spectral density ratio which the authors claim to be possible precursors of the 2008 Iwate–Miyagi Nairiku earthquake. Here the results of H&H are reviewed taking into account the global geomagnetic activity level by means ofPKp index. This paper cast serious doubts on the seismogenic origin of the magnetic signatures documented by H&H showing that the anomalous signals are normal ULF magnetic variations induced by solar–terrestrial interaction. In summary, H&H’s claims that magnetic field disturbances about a month before the Mw 6.9 Iwate–Miyagi Nairiku earthquake on June 13, 2008 are precursors to the earthquake are unlikely to be correct.
    Description: Published
    Description: 258-262
    Description: 2.6. TTC - Laboratorio di gravimetria, magnetismo ed elettromagnetismo in aree attive
    Description: JCR Journal
    Description: restricted
    Keywords: Geomagnetic field ; Magnetic anomalies ; Earthquake precursors ; Seismology ; 04. Solid Earth::04.05. Geomagnetism::04.05.99. General or miscellaneous ; 04. Solid Earth::04.05. Geomagnetism::04.05.04. Magnetic anomalies ; 04. Solid Earth::04.06. Seismology::04.06.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 6
    Publication Date: 2017-04-04
    Description: Ida et al. (2005) document significant changes in the multi-fractal parameters of the ULF geomagnetic field H component starting about one month before the 1993 Guam earthquake. According to the authors, these multi-fractal signatures can be considered as precursory signals of the Guam earthquake. As a consequence, they conclude that the multifractal analysis may have an important role in the development of short-term earthquake prediction capabilities. Since this and other similar reports have motivated the idea that earthquake prediction based on electromagnetic precursory signals may one day become a routine technique, the presumed precursors need to be validated through independent datasets. In this review the seismogenic origin of the multifractal magnetic signatures documented by Ida et al. (2005) before the 8 August 1993 Guam earthquake is seriously put into question. By means of the geomagnetic ΣKp index, it is demonstrated that these multi-fractal parameter changes are normal signals induced by the variation of the global geomagnetic activity level.
    Description: Published
    Description: 187-191
    Description: 2.6. TTC - Laboratorio di gravimetria, magnetismo ed elettromagnetismo in aree attive
    Description: JCR Journal
    Description: open
    Keywords: Geomagnetic field ; Magnetic anomalies ; Earthquake precursors ; Seismology ; 04. Solid Earth::04.05. Geomagnetism::04.05.04. Magnetic anomalies
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 7
    Publication Date: 2017-04-03
    Description: This paper reports the analyses of ULF (Ultra-Low-Frequency) geomagnetic field observations coming from the Geomagnetic Observatory of L'Aquila during the period 2008–2009. This period includes the L'Aquila 2009 seismic sequence, where the main shock of 6 April heavily damaged the medieval centre of the town and its surrounding area, causing 308 deaths, more than 1000 injuries and about 60,000 displaced people. Recently, several publications have documented the observation of precursory signals which occurred before the 6 April earthquake (e.g. Eftaxias et al., 2009, 2010), while others do not find any pre-earthquake anomaly (e.g. Villante et al., 2010; Di Lorenzo et al., 2011). In light of this, the goal of this study is to carry out further retrospective investigations. ULF magnetic field data are investigated by means of conventional analyses of magnetic polarization ratio, improved magnetic polarization ratio, and fractal analysis. In addition, total geomagnetic field data coming from the INGV Central Italy tectonomagnetic network have also been investigated, using the simple inter-station differentiation method. Within the limits of these methods, no magnetic anomalous signal which may be reasonably characterized as a precursor of the L'Aquila earthquakes has been found.
    Description: Published
    Description: 310–317
    Description: 2.6. TTC - Laboratorio di gravimetria, magnetismo ed elettromagnetismo in aree attive
    Description: JCR Journal
    Description: restricted
    Keywords: Geomagnetic field ; Magnetic anomalies ; Earthquake precursors ; Seismology ; 04. Solid Earth::04.05. Geomagnetism::04.05.99. General or miscellaneous ; 04. Solid Earth::04.05. Geomagnetism::04.05.04. Magnetic anomalies ; 04. Solid Earth::04.06. Seismology::04.06.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 8
    Publication Date: 2017-04-04
    Description: USEMS and GLASS are two projects financed by the European Research Council (ERC) as part of the ERC starting grants scheme within the FP7 framework. The rationale behind the funding scheme is to support some of the most promising scientific endeavours in Europe that are being led by young researchers, and to emphasize the excellence of individual ideas rather than specific research areas; in other words, to promote bottom-up frontier research. The general benefits of this rationale are evident in the two ongoing projects that deal with earthquake physics, as these projects are increasingly recognized in their scientific community. We can say that putting excellence at the heart of European Research strongly contributes to the construction of a European knowledge-based society. From a researcher point-of-view one of the most challenging aspects of these projects is to approach and convey the results of the projects to a general public, contributing actually to the construction of knowledge-based society. Luckily, media interest and the availability of a number of new communication tools facilitate the outreach of scientific achievements. The largest earthquakes during the last ten years (e.g. Sumatra 2004 and Japan 2011) have received widespread attention in the media world (TV, W.W.W., Newspaper and so on) for months, and successful research projects such as those above also become media protagonists, gaining their space in the media bullring. The USEMS principal investigator and his team have participated in several dissemination events in the Mass Media, such as interviews wit Italian and French TV national broadcasts (RAI Due TG2, RAI Uno Unomattina, Rai Tre Geo & Geo, FRANCE 2); interviews in scientific journals: SCIENCE (Sept. 2010), newspapers and web (Corriere della Sera, Il Gazzettino, Il Messagero, La Stampa, Libero, Il Mattino, Yahoo, ANSA, AdnKronos and AGI); radio (RadioRai Uno, RadioRai Tre Scienza); documentary “Die Eroberung der Alpen” produced by Tangram Film (Munchen, Germany). The USEMS project started in June 2008, and the GLASS project in October 2010. For both projects we developed a number of web pages through the official web site of the host institution, the National Institute of Geophysics and Volcanology (INGV) in Rome. In these pages we describe the projects, publish pictures and short-movies of the experimental activities and keep the project results up to date. In addition the research teams collaborate within various INGV outreach schemes (school and student visits in the laboratory, writing short news reports for the INGV press office, and interviews with journalists) as well as using WWW channels (Facebook, Youtube) to make the project results available to the general public. Finally, it is notable that the ERC funding agency itself is fully involved in the outreach activities using its own communication channels and its highly skilled resources which promote through brochures, web pages, publications and documentaries the best projects. We are going to improve our effort in this direction up to the end of the projects.
    Description: Unpublished
    Description: San Francisco
    Description: 5.9. Formazione e informazione
    Description: open
    Keywords: PUBLIC ISSUES / Science policy EDUCATION / Geoscience education research PUBLIC ISSUES / Funding. ; Seismology ; 05. General::05.03. Educational, History of Science, Public Issues::05.03.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Poster session
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  • 9
    Publication Date: 2017-10-19
    Description: Starting from late May 2012, the Emilia region (Northern Italy) was severely shaken by an intense seismic sequence, originated from a ML 5.9 earthquake on May 20th, at a hypocentral depth of 6.3 km, with thrusttype focal mechanism. In the following days, the seismic rate remained high, counting 50 ML ≥ 2.0 earthquakes a day, on average. Seismicity spreads along a 30 km east–west elongated area, in the Po river alluvial plain, in the nearby of the cities Ferrara and Modena. Nine days after the first shock, another destructive thrust-type earthquake (ML 5.8) hit the area to the west, causing further damage and fatalities. Aftershocks following this second destructive event extended along the same east-westerly trend for further 20 km to the west, thus illuminating an area of about 50 km in length, on thewhole. After the first shock struck, on May 20th, a dense network of temporary seismic stations, in addition to the permanent ones, was deployed in the meizoseismal area, leading to a sensible improvement of the earthquake monitoring capability there. A combined dataset, including threecomponent seismic waveforms recorded by both permanent and temporary stations, has been analyzed in order to obtain an appropriate 1-D velocity model for earthquake location in the study area. Here we describe the main seismological characteristics of this seismic sequence and, relying on refined earthquakes location, we make inferences on the geometry of the thrust system responsible for the two strongest shocks.
    Description: Published
    Description: 44-55
    Description: 2T. Tettonica attiva
    Description: JCR Journal
    Description: open
    Keywords: Seismology ; Hypocentral location ; Seismic sequence ; Velocity model ; Thrust fault system ; Po alluvial Plain ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 10
    Publication Date: 2021-05-19
    Description: Daily topical application of the aqueous ethanolic extract of the marine sea grass, Thalassia testudinum, on mice skin exposed to UVB radiation resulted in a dose dependent recovery of the skin macroscopic alterations over a 6-day period. Maximal effect (90%) occurred at a dose of 240 μg/cm2, with no additional effects at higher doses. Bioassay-guided fractionation of the plant extract resulted in the isolation of thalassiolin B (1). Topical application of 1 (240 μg/cm2) markedly reduces skin UVB-induced damage. In addition, thalassiolin B scavenged 2,2-diphenyl-2-picrylhydrazyl radical with an EC50=100 μg/ml. These results suggest that thalassiolin B is responsible for the skin regenerating effects of the crude extract of T. testudinum
    Description: Published
    Description: Flavonoids, Thalassiolin B, DPPH scavenged, antioxidant activity, Skin regenerating activity, Thalassia testudinum
    Keywords: Chemistry ; Pharmacology ; Chemistry ; Pharmacology
    Repository Name: AquaDocs
    Type: Journal Contribution
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  • 11
    Publication Date: 2021-05-19
    Description: Bioguided fractionation of Agelas cerebrum crude extract resulted in isolation of four bromopyrrole and four bromopyrrole aminoimidazole alkaloids, identified as 5-bromopyrrole-2-carboxylic acid (1), 4-bromopyrrole-2-carboxylic acid (2), 3,4-bromopyrrole-2-carboxylic acid (3), 4,5-bromopyrrole-2-carboxylic acid (4), oroidin (5), bromoageliferin (6), dibromoageliferin (7) and dibromosceptrin (8) on the basis of spectroscopic data analyses (UV, IR, HRMS, 1D and 2D NMR) and comparison with literature data. This is the first report of compounds 2 and 3 in a marine sponge belonging to the Agelas genus and the first evidence of the presence of 1 from a natural source.
    Description: Published
    Description: Agelas cerebrum, bromopyrrole alkaloids, antitumoral, antiprotozoal activity
    Keywords: Chemistry ; Alkaloids ; Sponges ; Alkaloids ; Sponges ; Chemistry
    Repository Name: AquaDocs
    Type: Journal Contribution
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  • 12
    Publication Date: 2021-05-19
    Description: La velocidad de descomposición de tres fenólicos, el p-hidroxibenzoico, el protocatecúico y el gálico, los cuales se diferencian en el número de grupos OH, fue investigada en el suelo. Con el aumento de grupos OH aumenta también la velocidad de descomposición microbial. El ácido gálico se descompone más rápido que el protocatecúico y este a su vez más rápido que el phidroxibenzoico.
    Description: The rate of decomposition of the three phenolics, p-hydroxybenzoic acid, protocatechuic acid and gallic acid, whose difference is the amount of OH-groups, was investigated in the soil. With the increase in OH-groups increases the rate of microbial decomposition. Gallic acid decomposes faster than protocatecuic acid and this again faster than p-hydroxybenzoic acid.
    Description: Published
    Keywords: Chemical decomposition ; OH Groups ; Microbes ; Phenols ; Chemistry ; Phenols ; Chemistry
    Repository Name: AquaDocs
    Type: Journal Contribution
    Format: pp.141-143
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  • 13
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    Massachusetts Institute of Technology and Woods Hole Oceanographic Institution
    Publication Date: 2022-05-25
    Description: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution February 1999
    Description: In this thesis the analysis of natural ice events is carried out based on direct measurements of ice-borne seismo-acoustic waves generated by ice fracturing processes. A major reason for studying this phenomenon is that this acoustic emission is a significant contributor to Arctic ocean ambient noise. Also the Arctic contains rich mineral and oil resources and in order to design mining facilities able to withstand the harsh environmental conditions, we need to have a better understanding of the processes of sea ice mechanics. The data analyzed in this thesis were collected during the Sea Ice Mechanics Initiative SIMI’94 experiment which was carried out in the spring of 1994 in the Central Arctic. One of the contributions of this thesis was the determination of the polarization characteristics of elastic waves using multicomponent geophone data. Polarization methods are well known in seismology, but they have never been used for ice event data processing. In this work one of the polarization methods so called Motion Product Detector method has been successfully applied for localization of ice events and determination of polarization characteristics of elastic waves generated by fracturing events. This application demonstrates the feasibility of the polarization method for ice event data processing because it allows one to identify areas of high stress concentration and "hot spots" in ridge building process. The identification of source mechanisms is based on the radiation patterns of the events. This identification was carried out through the analysis of the seismo-acoustic emission of natural ice events in the ice sheet. Previous work on natural ice event identification was done indirectly by analyzing the acoustic energy radiated into the water through coupling from elastic energy in the ice sheet. After identification of the events, the estimation of the parameters of fault processes in Arctic ice is carried out. Stress drop, seismic moment and the type of ice fracture are determined using direct near-field measurements of seismo-acoustic signals generated by ice events. Estimated values of fracture parameters were in good agreement with previous work for marginal ice zone. During data processing the new phenomenon was discovered: "edge waves", which are waves propagating back and forth along a newly opened ice lead. These waves exhibit a quasi-periodic behavior suggesting some kind of stick-slip generation mechanism somewhere along the length of the lead. The propagation characteristics of these waves were determined using seismic wavenumber estimation techniques. In the low frequency limit the dispersion can be modeled approximately by an interaction at the lead edges of the lowest order, antisymmetric modes of the infinite plate.
    Description: Support for this thesis was provided by Office of Naval Research.
    Keywords: Microseisms ; Seismology ; Underwater acoustics ; Remote sensing ; Sea ice ; Ice
    Repository Name: Woods Hole Open Access Server
    Type: Thesis
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  • 14
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    Massachusetts Institute of Technology and Woods Hole Oceanographic Institution
    Publication Date: 2022-05-25
    Description: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution February 2013
    Description: In this thesis we present results from inversion of data using dense arrays of collocated seismic and magnetotelluric stations located in the Cascadia subduction zone region of central Washington. In the migrated seismic section, we clearly image the top of the slab and oceanic Moho, as well as a velocity increase corresponding to the eclogitization of the hydrated upper crust. A deeper velocity increase is interpreted as the eclogitization of metastable gabbros, assisted by fluids released from the dehydration of upper mantle chlorite. A low velocity feature interpreted as a fluid/melt phase is present above this transition. The serpentinized wedge and continental Moho are also imaged. The magnetotelluric image further constrains the fluid/melt features, showing a rising conductive feature that forms a column up to a conductor indicative of a magma chamber feeding Mt. Rainier. This feature also explains the disruption of the continental Moho found in the migrated image. Exploration of the assumption of smoothness implicit in the standard MT inversion provides tools that enable us to generate a more accurate MT model. This final MT model clearly demonstrates the link between slab derived fluids/melting and the Mt. Rainier magma chamber.
    Description: Funding for this work was made possible by the American Society for Engineering education through a National Defense Science and Engineering Fellowship, and by the National Science Foundation through two grants for the CAFE and CAFE MT projects.
    Keywords: Seismic networks ; Seismology
    Repository Name: Woods Hole Open Access Server
    Type: Thesis
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  • 15
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    Massachusetts Institute of Technology and Woods Hole Oceanographic Institution
    Publication Date: 2022-05-25
    Description: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution May 1998
    Description: Planktonic protozoan grazers have the potential to significantly affect the chemistry of particle-associated trace metals. This is due both to the importance of protists as consumers of bacterial-sized particles, and to the unique low-pH, enzyme-rich microenvironment of the grazer food vacuole. This thesis examines the role of protozoan grazers in the marine geochemistry of strongly hydrolyzed, particle-reactive trace metals, in particular Th and Fe. A series of tracer experiments was carried out in model systems in order to determine the effect of grazer-mediated transformations on the chemical speciation and partitioning of radioisotopes C9Fe, 234Th, 51Cr) associated with prey cells. Results indicate that protozoan grazers are equally able to mobilize intracellular and extracellular trace metals. In some cases, protozoan regeneration of trace metals appears to lead to the formation of metal-organic complexes. Protozoan grazing may generate colloidal material that can scavenge trace metals and, via aggregation, lead to an increase in the metal/organic carbon ratio of aggregated particles. Model system experiments were also conducted in order to determine the effect of grazers on mineral phases, specifically colloidal iron oxide (ferrihydrite). Several independent techniques were employed, including size fractionation ors9Fe-labeled colloids, competitive ligand exchange, and iron-limited diatoms as "probes" for bioavailable Fe. Experimental evidence strongly suggests that protozoan grazing can affect the surface chemistry and increase the dissolution rate of iron oxide phases through phagotrophic ingestion. In further work on protozoan-mediated dissolution of colloidal Fe oxides, a novel tracer technique was developed based on the synthesis of colloidal ferrihydrite impregnated with 133Ba as an inert tracer. This technique was shown to be a sensitive, quantitative indicator for the extent of ferrihydrite dissolution/alteration by a variety of mechanisms, including photochemical reduction and ligand-mediated dissolution. In field experiments using this technique, grazing by naturally occuring protistan assemblages was shown to significantly enhance the dissolution rate of colloidal ferrihydrite over that in non-grazing controls. Laboratory and field results indicate that, when integrated temporally over the entire euphotic zone, protozoan grazing may equal or exceed photoreduction as a pathway for the dissolution of iron oxides.
    Description: This work was financially supported by a Department of Defense ONR-NDSEG Graduate Fellowship, Office ofNaval Research AASERT Award (N00014-94-1-0711), and the National Science Foundation EGB Program (OCE-9523910).
    Keywords: Protozoa ; Water chemistry ; Trace elements in water ; Marine zooplankton ; Chemistry
    Repository Name: Woods Hole Open Access Server
    Type: Thesis
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  • 16
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    Massachusetts Institute of Technology and Woods Hole Oceanographic Institution
    Publication Date: 2022-05-25
    Description: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and Woods Hole Oceanographic Institution February 1994
    Description: Ambient noise in the sea has been observed for over 100 years. Previous studies conclude that the primary source of microseisms is nonlinear interaction of surface gravity waves at the sea surface. Though this source relationship is generally accepted, the actual processes by which the wave generated acoustic noise in the water column couples and propagates to and along the sea floor are not well understood. In this thesis, the sources and propagation of sea floor and sub-sea floor microseismic noise between 0.2 and 10 Hz are investigated. This thesis involves a combination of theoretical, observational and numerical analysis to probe the nature of the microseismic field in the Blake Bahama Basin. Surface waves are the primary mechanism for noise propagation in the crust and fall into two separate groups depending on the relative wavelength/water depth ratio. Asymptotic analysis of the Sommerfeld integral in the complex ray parameter plane shows results that agree with previous findings by Strick (1959) and reveal two fundamental interface wave modes for short wavelength noise propagation in the crust: the Stoneley and pseudo-Rayleigh wave. For ocean sediments, where the shear wave velocity is less than the acoustic wave velocity of water, only the Stoneley interface wave can exist. For well consolidated sediments and basalt, the shear velocity exceeds the acoustic wave velocity of water and the pseudo-Rayleigh wave can also exist. Both interface waves propagate with retrograde elliptic motion at the sea floor and attenuate with depth into the crust, however the pseudo-Rayleigh wave travels along the interface with dispersion and attenuation and "leaks" energy into the water column for a half-space ocean over elastic crust model. For finite depth ocean models, the pseudo-Rayleigh wave is no longer leaky and approaches the Rayleigh wave velocity of the crust. The analysis shows that longer wavelength noise propagates as Rayleigh and Stoneley modes of the ocean+crust waveguide. These long wavelength modes are the fundamental mechanism for long range noise propagation. During the Low Frequency Acoustic Seismic Experiment (LFASE) a four-node, 12- channel borehole array (SEABASS) was deployed in the Blake Bahama Basin off the coast of eastern Florida (DSDP Hole 534B). This experiment is unique and is the first use of a borehole array to measure microseismic noise below the sea floor. Ambient background noise from a one week period is compared between an Ocean Bottom Seismometer (OBS) and SEABASS at sub-bottom depths of 10, 40, 70 and 100 meters below the sea floor. The 0.3 H z microseism peak is found to be nearly invariant with depth and has a power level of 65 and 75 dB rel 1 (nm/ s2)2)/ H z for the vertical and horizontal components respectively. At 100 m depth, the mean microseismic noise levels above 0.7 Hz are 10 dB and 15-20 dB quieter for the vertical and horizontal components respectively. Most of this attenuation occurs in the upper 10 m above 1.0 Hz, however higher modes in the spectra show narrow bandwidth variability in the noise field that is not monotonic with depth. Dispersion calculations show normal mode Stoneley waves below 0.7 Hz and evidence of higher modes above 0.8 Hz. A strong correlation between noise levels in the borehole and local sea state conditions is observed along with clear observation of the nonlinear frequency doubling effect between ocean surface waves and microseisms. Particle motion analysis further verifies that noise propagates through the array as Rayleigh/Stoneley waves. Polarization direction indicates at least two sources; distant westerly swell during quiescent times and local surface waves due to a passing storm. Above 1.0 Hz the LFASE data shows little coherence and displays random polarization. Because of this, we believe scattered energy is a significant component of the noise field in the Blake Bahama Basin. A fully 3-D finite difference algorithm is used to model both surface and volume heterogeneities in the ocean crust. Numerical modeling of wave propagation for hard and soft bottom environments shows that heterogeneities on the order of a seismic wavelength radiate energy into the water column and convert acoustic waves in the water into small wavelength Stoneley waves observed at the borehole. Sea floor roughness is the most important elastic scattering feature of the ocean crust. Comparisons of 2D and 3D rough sea floor models show that out-of-plane effects necessitate the use of 3D methods. The out-of-plane energy that is present in the LFASE data comes from either heterogeneities in the source field (i.e. mixed gravity wave directions) or, equally likely, scattering of the source field from surface or volume heterogeneities in the sea floor.
    Description: This research was supported by Office of Naval Research grants N00014-89-C-0018, N00014-89-J-1012, N00014-90-C-0098, N00014-90-J-1493 and N00014-93-1-1352.
    Keywords: Microseisms ; Ocean bottom ; Seismology ; Boundary layer noise ; Underwater acoustics
    Repository Name: Woods Hole Open Access Server
    Type: Thesis
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  • 17
    Publication Date: 2022-06-09
    Description: In the frame of the Italian research project INGV-DPC S2 (http://nuovoprogettoesse2.stru.polimi.it/), funded by the Dipartimento della Protezione Civile (DPC; National Civil Protection Department) within the agreement 2007-2009, a tool for probabilistic seismic hazard assessment (PSHA) was developed. The main goal of the project was to provide a flexible computational tool for PSHA; the requirements considered essential for the success of the project included: •ability to handle both stationary and non-stationary earthquake time-occurrence models; •ability to use ground-motion prediction models that are not parametric equations but probabilistic "footprints" of the intensities generated by earthquakes of known magnitude and focal characteristics. Usually, these footprints are results of ground motion simulations. Some commonly used programs (e.g., FRISK, by McGuire, 1978; SEISRISK III, by Bender and Perkins, 1987) and more recent and state-of-the-art tools (e.g. OpenSHA, by Field et al., 2003, http://www.opensha.org; OpenQuake, http://openquake.org) for PSHA were analyzed. It was decided to focus on CRISIS2007, which was already a mature and well known application (e.g., Kalyan Kumar and Dodagoudar, 2011; Teraphan et al., 2011; D’Amico et al., 2012; see also http://ecapra.org/CRISIS-2007), but also suitable for additional development and evolution since its source code is freely available on request. The computational tool resulted in an extensive redesign and renovation of the previous CRISIS2007 version. CRISIS is a computer program for PSHA, originally developed in the late 1980's using Fortran as programming language (Ordaz, 1991). In this format, still without a graphical user interface (GUI), it was distributed as part of SEISAN tools (Ottemöller et al., 2011). Ten years later, a GUI was constructed, generating what was called CRISIS99 (Ordaz, 1999). In this version, all the graphic features were written in Visual Basic, but the computation engine remained a Fortran dynamic link library. The reason for the use of mixed-language programming was that computations in Visual Basic were extremely slow. Around 2007 the program was upgraded, in view of the advantages offered by the object-oriented technologies. An object-oriented programming language was required and the natural choice was Visual Basic.Net. In the new version (called CRISIS2007), both the GUI and the computation engine were written in the same language. Finally, in the frame of the mentioned S2 project, starting from 2008, the program was split into two logical layers: core (CRISIS Core Library) and presentation (CRISIS2008). In addition, a new presentation layer was developed for accessing the same functionalities via Web (CRISISWeb). It is worth noting that CRISIS has been mainly written by people that are, at the same time, PSHA practitioners. Therefore, the development loop has been relatively short, and most of the modifications and improvements have been made to satisfy the needs of the developers themselves.
    Description: Italian Presidenza del Consiglio dei Ministri, Dipartimento della Protezione Civile (DPC).
    Description: Published
    Description: 495-504
    Description: 4.2. TTC - Modelli per la stima della pericolosità sismica a scala nazionale
    Description: JCR Journal
    Description: restricted
    Keywords: Seismic Hazard ; Seismology ; Probabilistic Seismic Hazard Assesment ; PSHA ; 04. Solid Earth::04.06. Seismology::04.06.02. Earthquake interactions and probability ; 04. Solid Earth::04.06. Seismology::04.06.04. Ground motion ; 04. Solid Earth::04.06. Seismology::04.06.11. Seismic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 18
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1018-1027 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Bei nochmaliger Untersuchung der Umsetzung von CCl4 mit Si/Cu-Gemischen werden, wie bereits bekannt, SiCl4, C2Cl4 und Si2Cl6 gefunden. Darüber hinaus lief eine direkte Synthese. Sie führte wahrscheinlich zur Bildung des allerdings dabei nicht nachgewiesenen Cl3C·SiCl3. Dagegen wurde die nach der direkten Synthese entstandene Verbindung C(SiCl3)4 erstmalig aufgefunden.  -  Die Entstehung der ebenfalls nachgewiesenen Verbindungen Cl3SiC·C⋮CC·SiCl3 und Cl3SiC·(Cl)C:C(Cl)C·SiCl3 wird durch Dechlorierungen des Cl3CC·SiCl3 mit Kupfer erklärt.  -  Für die neuen Verbindungen wurden Strukturbeweise geführt. Es wurden C2Cl4 und Cl3CC·SiCl3 mit Si/Cu-Gemischen umgesetzt. Die letzte Umsetzung ergab dieselben Reaktionsprodukte wie das CCl4, so daß auch bei diesem eine direkte Synthese über das Cl3CC·SiCl3 glaubhaft gemacht ist.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1048-1055 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Eigenschaften von tert.-Butylthionitrit, Triphenylmethylthionitrit und tert.-Butylthionitrat werden Rückschlüsse auf die Elektronenstruktur der schwefelhaltigen Gruppe gezogen.
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    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Als weiteres Beispiel für die präparative Überlegenheit der säurekatalysierten Aldolreaktionen des Formaldehyds gegenüber den OH⊖-katalysierten wird über die Synthese der bisher unbekannten Bisanhydro-ennea-heptose, die das Ringsystem des 3.7-Dioxa-bicyclo-[1.3.3]-nonans enthält, berichtet.  -  Bei der Untersuchung des Verhaltens der Bisanhydro-ennea-heptose gegen Alkalien machten sich in der Abspaltbarkeit der Hydroxymethylgruppen charakteristische Unterschiede geltend, deren Erklärung in den konstitutionell-konstellativen Gegebenheiten zu suchen ist.  -  Bei dem Versuch einer Ringerweiterung an der Anhydro-ennea-heptose mit Diazomethan bildet sich eine Verbindung C9H16O5, die wahrscheinlich kein Derivat des Oxa-cycloheptanons-(4), sondern ein Derivat des Tetrahydro-γ-pyrons ist.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1092-1101 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Substituierte Ammoniumsalze vom Typ I liefern mit Abkömmlingen des Phenylglyoxals in Methanol in glatter Reaktion Lactolid-Basen vom Typ II. Aus diesen lassen sich verschiedene Octa- bzw. Decahydroisochinolin-Derivate darstellen, die in 1-Stellung einen substituierten Benzylrest tragen.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1115-1117 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die jodometrische Bestimmung der Hydroperoxyde von Benzolkohlenwasserstoffen kann durch katalytische Wirkung von Kupferionen verbessert werden.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1135-1139 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Umsetzung von Tetraacetyl-α-D-glucopyranosylbromid und Tetraacetyl-6-trityl-β-D-glucopyranose mit Silberperchlorat oder Silberfluoroborat in Nitromethan liefert in guter Ausbeute Octaacetyl-β-gentiobiose. Die gleiche Umsetzung mit einem Überschuß an Tetraacetyl-α-D-glucopyranosylbromid und Silberperchlorat führt zur Octaacetyl-α-gentiobiose. Es wird eine Deutung des Reaktionsablaufs gegeben.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1126-1129 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Tachysterin2 wurde mit durch Glas gefiltertem Quecksilberdampflicht in Präcalciferol2 umgewandelt.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1152-1158 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Um eine Aussage über den Reaktionsmechanismus bei der Mercurierung des Ammonium-Ions in wäßrigen Lösungen machen zu können, wurde Quecksilber-(II)-diamminchlorid, Hg(NH3)2Cl2, mit wäßriger Ammoniumacetat-Lösung zum sog. „unschmelzbaren Präzipitat“, HgNH2Cl, umgesetzt. Die Lösung enthielt 1 Mol. 203Hg(CH3CO2)2 pro Mol. des Diammoniakates.Die beiden heterogenen Austauschreaktionen Hg(NH3)2Cl2/[203Hg(NH3)4]2⊕ und HgNH2Cl/[203Hg(NH3)4]2⊕ wurden in Abhängigkeit von der Temperatur untersucht.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1158-1163 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Von den sechs möglichen Isomeren des Decalindiols-(1.4) wurden zwei der Reihe des cis-Decalins und zwei der Reihe des trans-Decalins angehörende Diole durch Reduktion von cis- und trans-Decalindion-(1.4) sowie durch katalyt. Hydrierung von Naphthohydrochinon-(1.4) und ar-Tetralindiol-(5.8) mit Raney-Nickel im Autoklaven erhalten, eindeutig der cis- und trans-Reihe zugeordnet und durch Derivate charakterisiert.
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  • 27
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1184-1188 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Einwirkung von Aryldiazoniumsalzen auf verschiedene monoalkylierte Dihydroresorcine wurde untersucht. Dabei wurden im glatten Reaktionsverlauf δ-Keto-δ-arylhydrazono-carbonsäuren erhalten. Die gleiche Reaktion führte beim 2-Acetamino-dihydroresorcin infolge einer sekundär verlaufenden Wasserabspaltung zu einem Derivat des 1.2.4-Triazols, dessen Konstitution bewiesen wurde.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1206-1212 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Durch Umsetzung von Alkylhydroperoxyden oder Wasserstoffperoxyd mit Formaldehyd und sekundären Aminen werden nach Art der Mannich-Reaktion Aminoalkylperoxyde erhalten. In mineralsaurer Lösung gelingt auch die Umsetzung von Benzamid oder Harnstoff mit Formaldehyd und Alkylhydroperoxyden.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1216-1223 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Einführung der Carbonsäurechloridgruppe in 1- bzw. 3-Stellung des Azulensystems gelingt durch Substitution mittels Phosgens ohne Friedel-Crafts-Katalysatoren. Befindet sich in Nachbarstellung zur Carbonsäurechloridgruppe am 7-Ring kein Substituent, so lassen sich die Verbindungen zu den freien Carbonsäuren hydrolysieren, andernfalls tritt Decarboxylierung ein. Die Säurechloride lassen sich in Ester, Amide und Anilide überführen. Die spektralen Verschiebungen gegenüber den zugrunde liegenden Azulenen werden diskutiert.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1195-1205 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Hydrierung des Adrenalins mit Raney-Nickel liefert keine brauchbaren Ergebnisse. Das Hexahydro-adrenalin (Xb) wird deshalb synthetisch aus Tetrahydro-benzaldehyd in 5 Stufen in guter Ausbeute dargestellt. Es wird gezeigt, daß das synthetische Produkt eine sterisch weitgehend einheitliche Verbindung ist und die 3(trans).4(cis)-Konfiguration besitzt.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1212-1215 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Aus cyclischen Ketonen und sekundären Aminen erhältliche α.β-ungesättigte Amine addieren Wasserstoffperoxyd an der Doppelbindung und geben kristalline Peroxyde.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1237-1237 
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    Keywords: Chemistry ; Inorganic Chemistry
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    Topics: Chemistry and Pharmacology
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1239-1246 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Tetrahydroxy-p-benzochinon zeigt einige Eigenschaften, die es als „doppeltes aci-Redukton“ erscheinen lassen. So erleidet es „Diazo-Spaltung“ unter Bildung von Mesoxalsäure-bis-arylhydrazid. Diazomethan verwandelt es in den Tetramethyläther, der leicht, sogar durch den Ausgangsstoff, zum entspr. Hydrochinon reduziert wird. Es werden noch Acetyl- und Aminoderivate des Tetrahydroxy-p-benzochinons und seines Dimethyläthers beschrieben sowie die UV- und IR-Spektren diskutiert.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1276-1287 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Ausgehend von den in der ersten Veröffentlichung(1) beschriebenen Substanzen wurden Derivate der folgenden Peptide synthetisiert: Glycyl-L-glutaminsäure, Glycyl-glycyl-L-glutaminsäure, γ-L-Glutamyl-glycin, α- und γ-L-Glutamylglycyl-L-glutaminsäure, α- und γ-L-Glutamyl-α-L-glutamyl-glycin und α-L-Glutamyl-L-tyrosin. Auch einige freie Peptide konnten erhalten werden. Als interessante Nebenprodukte der Peptidsynthese über gemischte Anhydride mit Kohlensäure-halbestern wurden in zwei Fällen Diacylimide erhalten.
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    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Beim Behandeln von N-Benzoyl-D-glucosamin (IV) mit chlorwasserstoffhaltigem Aceton entsteht das Acetonderivat VII eines Phenyloxazolins, welches Furanosestruktur besitzt. Dieses wird mit chlorwasserstoffhaltigem Methanol in das entsprechende Aceton-β-methylfuranosid IX und anschließend in das acetonfreie β-Methylfuranosid X umgewandelt.  -  Behandeln von O-Tetraacetyl-N-carbobenzoxy-D-glucosamin (XI) mit TiCl4 oder mit AlCl3/PCl5 führt unter Abspaltung von Benzylchlorid zur Bildung eines Oxazolonderivates (XIII).
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1313-1319 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Methylphenylhydrazone der Monobenzoyl-aldosen liegen im kristallisierten und gelösten Zustand nur als Schiffsche Basen vor, sie zeigen keine Mutarotation und lassen sich zu 5-Benzoyl-2.3.4-triacetyl-pentose- bzw. 6-Benzoyl-2.3.4.5-tetraacetyl-hexose-methylphenylhydrazonen acetylieren, deren Struktur durch Synthese bewiesen wird. Die aus Monobenzoyl-aldose-phenylhydrazonen mit Phenylhydrazin darstellbaren Monobenzoyl-aldose-phenylhydrazonen werden sehr leicht zu Aldose-phenylosazonen und Benzoesäure hydrolysiert.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1329-1335 
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Darstellung des Monobrom-, Monojod- und Trimethoxy-pivalophenons werden beschrieben. Die Halogenverbindungen erleiden bei der Einwirkung wäßriger Alkalien eine hydrolytische Spaltung. Die Methoxyverbindung ist gegen Alkalien stabil.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1363-1366 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: β-Aroyl-acrylsäuren reagieren mit Pyrrol, 1- und 2-Methyl-pyrrol nach dem Schema der substituierenden Addition.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1386-1397 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Durch Oxydation von Tetralol-(6) und Östradiol-17-monoacetat mit Bleitetraacetat werden Tetralin-p-chinolacetat und 17β-Acetoxy-östra-p-chinol-(10ζ)-acetat dargestellt. Aus den Chinolacetaten lassen sich die Chinole durch basenkatalysierte Umesterung in Freiheit setzen. Dem aufgezeigten Weg kommt allgemeine Bedeutung zur Darstellung von p-Chinolen zu.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1472-1477 
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: β-Phenyl-äthylamine lassen sich mit Cyclohexanon-(2)-essigsäure zu partiell hydrierten Oxindol-Derivaten kondensieren, die durch Ringschluß in Verbindungen der Erythrinan-Reihe übergeführt werden.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1478-1480 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Umsetzung von Chlorameisensäure-benzylester mit überschüssigem Hydrazinhydrat in absol. Chloroform ergibt Carbobenzoxy-hydrazin. In wäßrigem Medium entsteht vorwiegend N.N′-Dicarbobenzoxy-hydrazin (I), das von rauchender Salpetersäure leicht zu Azodicarbonsäure-dibenzylester (II) dehydriert wird.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1483-1500 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wurden 2 Tetraphenyl-äthylene, 2 Tetraphenyl-butatriene und 2 Tetraphenyl-hexapentaene mit je 2 meta- bzw. para-ständigen Nitrogruppen dargestellt. Es gelang, die beiden Äthylene durch Kristallisation und das Butatrien mit m-ständigen NO2-Gruppen durch Chromatographie in der cis- und in der trans-Form zu gewinnen. Damit ist bei einem zweiten Beispiel die von J. H. van't Hoff 1874 vorausgesagte Isomerie an einer Verbindung verwirklicht worden, in der 4 C-Atome durch 3 Doppelbindungen verknüpft sind.  -  Die Isomeren des Triens sind lichtempfindlich. Das Mengenverhältnis cis : trans im photochemischen Gleichgewicht entspricht der Zusammensetzung des Kumulens, wie es bei der Synthese anfällt. Die thermische cis-trans-Umlagerung der Butatriene läßt sich vorzüglich IR-spektroskopisch verfolgen. Die Zuordnung der mit A und B bezeichneten isomeren Butatriene zur cis- und trans-Formel wird diskutiert.  -  Von den beiden Hexapentaenen konnte dasjenige mit 2 p-ständigen Nitrogruppen in roten Kristallen, aber nicht in cis-trans-isomeren Formen gewonnen werden. Das entsprechende Hexapentaen mit 2 m-ständigen NO2-Gruppen war in Lösung beständig, es zersetzte sich aber teilweise bei Entfernung des Lösungsmittels.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1517-1523 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Umsetzung von 1.3.5-Trinitro-benzol mit Nitrophloroglucin sowie diejenige von Pikrinsäure mit Phloroglucin führt zu polycyclischen Verbindungen. Deren adamantanartige Konstitution wird auf Grund UV-spektroskopischer Vergleiche diskutiert.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1559-1563 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: α.α′-Alkandialdehyde wurden durch Abbau von α.α′-Dibrom-dicarbonsäuren nach Curtius erhalten. Aus α.α′-Dibrom-korksäure bzw. α.α′-Dibrom-azelainsäure entstanden unter geeigneten Bedingungen l-Formyl-cyclopenten-(1) bzw.-cyclohexen-(1).
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1573-1578 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Der durch Säuren katalysierte Isochinolin-Ringschluß ist unter bestimmten Bedingungen auch mit Substanzen durchführbar, die eine säureempfindliche Gruppe enthalten. Auf diese Weise lassen sich Enoläther bzw. Acetale des Decahydroisochinolons herstellen (XII bzw. XIII), die durch nachfolgende Hydrolyse das freie α.β-ungesättigte Ringketon (XVI) liefern, das man durch direkten Ringschluß nicht erhalten kann.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1594-1599 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Bei der Anlagerung von Ammoniak an Δ1-Tetrahydrobenzoesäure und Cyclopenten-(1)-carbonsäure-(1) entstehen ausschließlich die trans-β-Aminosäuren. Der Nachweis der Konfiguration erfolgt bei den entsprechenden cis-Aminosäuren, die durch Hofmannschen Abbau der cis-Hexahydrophthalamidsäure (V) und des cis-Cyclopentan-dicarbonsäure-(1.2)-monoamids erhalten werden. cis-und trans-2-Amino-cyclopentan-carbonsäure-(1) wurden erstmals dargestellt.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1618-1623 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: D-Arabinose-mercaptale lassen sich mit p-Toluolsulfonsäure- und mit Methansulfonsäurechlorid in Pyridin bei tiefer Temperatur partiell zu 5-Tosyl- bzw. 5-Mesyl-D-arabinose-mercaptalen verestern. Diese werden mit Lithiumaluminiumhydrid zu 5-Desoxy-D-arabinose-mercaptalen reduziert. Daraus gewinnt man durch Abspalten von Mercaptan die 5-Desoxy-D-arabinose.
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    Berichte der deutschen chemischen Gesellschaft 91 (1958), S. 2553-2557 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Aus den Chloriden gesättigter, ungesättigter und aromatischer Mono- und Dicarbonsäuren lassen sich durch Umsetzen mit Kaliumfluorsulfinat die entsprechenden Säurefluoride unter milden Reaktionsbedingungen herstellen.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1550-1558 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die gleichzeitige Einwirkung von o-Phenylendiamin und Phenylhydrazin auf Dehydro-L-ascorbinsäure führt zum 2-Hydroxy-3-[1′-phenylhydrazono-L-threo-2′.3′4′-trihydroxy-butyl]-2.2′-anhydro-chinoxalin, dessen Natriumsalz beim Erhitzen in Wasser unter Ausbildung eines anellierten Pyrazolringes zum 1-Phenyl-3-[L-threo-trihydroxy-propyl]-flavazol kondensiert. Dagegen entsteht unter dem Einfluß von Hydroxylamin-hydrochlorid das 2-Hydroxy-3-[1′-phenyl-5′-hydroxymethyl-pyrazolyl-(3′)]-chinoxalin. Zu der gleichen Verbindung gelangt man auch durch alkalische Verseifung der Diacetylverbindung des Ausgangsstoffes.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1579-1586 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wird der Nachweis erbracht, daß bei der Dieckmann-Kondensation des Esters IVc vorwiegend der Ketoester I entsteht. Hydrierung und Hydrolyse führt zu 3-Hydroxy-piperidin-carbonsäure-(2). Ozonspaltung und Hydrolyse ergibt Oxalsäure. Eine entsprechende Kondensation, ausgehend vom Ester IXc, ergibt den ungesättigten Piperidonester X.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1587-1593 
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Bei der Anlagerung von Ammoniak an Shikimisäure (I) entstehen vorwiegend zwei stereoisomere Aminosäuren der Konstitution III und IV.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1679-1694 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: o-Substituierte Benzole mit 1. aliphatischer Amino- und aromatischer Mercaptogruppe und 2. aliphatischer Mercapto- und aromatischer Aminogruppe wurden in wäßrig-alkoholischem Medium oxydiert. In der 1. Kategorie resultierten je nach pH Sulfenamid oder Disulfid; im geeigneten Fall trat weitere Dehydrierung zum 1.2-Benzisothiazol-Derivat ein. Es wurde ein pH-abhängiges Gleichgewicht Disulfid ⇌ Sulfenamid + Aminomercaptan festgestellt. In der 2. Kategorie lief die Bildung des Sulfenamids (2.1-Benzisothiazol) und des Disulfids nebeneinander in pH-abhängigen Mengenverhältnissen. Ein übergang Disulfid → Sulfenamid konnte nur unter bestimmten oxydativen Bedingungen erzielt werden. Es wurde an diesem Beispiel gezeigt, daß auch unter günstigen sterischen Verhältnissen die aromatische Aminogruppe nicht in der Lage ist, die aliphatische Disulfid-Gruppe zu spalten.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1710-1711 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 5.5-Diphenyl-glykocyamidin wird durch Methyljodid in 3-Stellung methyliert. Durch Ammonolyse (bzw. Aminolyse) von 1-Methyl-2-methylmercapto-4.4-diphenyl-imidazolon-(5) in Gegenwart von Ammoniumsalzen wurden weitere-3-substituierte Glykocyamidine dargestellt.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959) 
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    Keywords: Chemistry ; Inorganic Chemistry
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1638-1643 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Durch Umsetzungen von Glucuron- und Galakturonsäure und einigen ihrer Derivate mit Trimethylchlorsilan werden Substanzen erhalten, die i. Vak. gut destillieren und aus denen sich die Ausgangsverbindungen durch Alkoholyse leicht zurückgewinnen lassen. Die Eigenschaften der Trimethylsilylverbindungen werden beschrieben.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1654-1657 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: (±)-Corypalmin und (±)-Isocorypalmin wurden nach einer vereinfachten Methode zur Darstellung von Tetrahydro-protoberberinen synthetisiert.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1828-1834 
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Carbonsäuren, Carbonsäureester und Kohlensäureester lassen sich durch Umsetzung mit Antimonpentachlorid und Chlorwasserstoff in Acidiumsalze mit Wasserstoff am Oxonium-O-Atom überführen. Diese Acidiumsalze zeigen eine gewisse Chlorwasserstofftension und bilden mit einem zweiten Mol (bzw. bei den Carbonsäuren auch mehreren Molen) der zugehörigen Base H-Brücken-Addukte. Das Dimethyl-carbonatacidium-hexachloroantimonat konnte mittels Diazomethans zum Trimethyl-carbonatacidium-Salz methyliert werden.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1858-1863 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Durch Umsetzung von Kobalt(II)-acetylacetonat, gelöst in Methylenchlorid oder in fester Form, mit gasförmigem Stickoxyd wird ein tiefblaues, kristallines Nitrosyl-kobalt-bis-acetylacetonat rein dargestellt. Dieses ist in Äthylenbromid und anderen organischen Lösungsmitteln monomer löslich. Auf Grund von Leitfähigkeitsmessungen erweist es sich als Nichtelektrolyt und somit als ein Komplex der Koordinationszahl 5. Die aus dem magnetischen Verhalten und dem IR-Spektrum sich ergebenden Bindungsverhältnisse werden diskutiert.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1880-1903 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Aus einem Streptomyces-Stamm wurden drei kristallisierte, als ν-, ζ-und ∊-Pyrromycinon bezeichnete Farbstoffe isoliert. ν-Pyrromycinon ist ein 1.4.6-Trihydroxy-carbomethoxy-äthyl-tetracenchinon, ζ- und ∊-Pyrromycinon sind Derivate des 1.4.6-Trihydroxy-7.8.9.10-tetrahydro-tetracenchinons mit einer Carbomethoxygruppe, einer Äthylgruppe und einer bzw. zwei Hydroxygruppen. Durch Dehydrierung bzw. Wasserabspaltung lassen sie sich in ν-Pyrromycinon überführen. Für alle drei Pyrromycinone werden Konstitutionsformeln aufgestellt. Die Pyrromycinone stehen den Rhodomycinonen nahe, mit denen sie über das aus ν-Pyrromycinon dargestellte ν-Iso-pyrromycinon strukturell verknüpft werden konnten.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1918-1920 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Umsetzung von Formamid mit Methyläthylketon über Aluminiumoxyd führt bei 350-360° zu α-Amino-methyläthylacetonitril, bei 250-260° zu N-[α-Amino-isovaleryl]-N′-[2-imino-5-methyl-3.5-diäthyl-pyrrolidinyl-(3)]-harnstoff.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1944-1949 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: α-Halogen-ketone setzen sich mit Harnstoff, N-mono- und N.N-disubstituierten Harnstoffen in Dimethylformamid als Lösungsmittel zu 2-Amino-oxazolen um. Auf ihre Umwandlung in 2-Amino-imidazole wird hingewiesen.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1950-1956 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Aus den drei isomeren Dichloräthylenen kann mit Methyl-lithium in Äther Lithium-chloracetylenid (I) dargestellt werden, während Äthylmagnesiumbromid praktisch unwirksam ist. Die metallorganischen Eigenschaften von I werden zur Synthese organischer Chloracetylen-Derivate ausgenützt.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1982-1982 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1999-2013 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die bereits früher durchgeführten Umsetzungen von ortho-metalliertem Halogenbenzol mit tertiären Aminen, wie Triäthylamin, zu phenylierten tertiären Aminen lassen sich mit einem nucleophilen Angriff der Base auf Dehydrobenzol interpretieren. Zwingendere Argumente für ein intermediäres Auftreten von Dehydroaromaten liefert das Verhalten von orthometalliertem α- und β-Halogennaphthalin gegenüber Triäthylamin, da hierbei ein und dasselbe isomerenfreie β-Diäthylamino-naphthalin entsteht. Dafür spricht auch die Dien-Reaktion von Dehydronaphthalin mit Furan zum Endoxyd XII.  -  Orthometalliertes Halogenbenzol vermag auch mit elektrophilen Partnern wie Triäthylbor zu reagieren. Gleichzeitige Einwirkung von Triphenylbor und Triphenylphosphin führt zum Betain XV.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 2022-2025 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Beim Erhitzen von Calciumhydrid mit Borsäure-trimethylester entsteht ein komplexes Hydrid, das Carbonylverbindungen sehr spezifisch zu den Alkoholen reduziert.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 2029-2032 
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Aus l-Acetyl-3.3.5-trimethyl-5-benzyl-cyclohexen-(1)-ol-(2)-dion-(4.6) wird bei Hydrierung in Gegenwart von Palladium der Benzylrest als Toluol hydrogenolytisch glatt abgespalten. Analoga mit Allyl- bzw. γ.γ-Dimethyl-allyl-Gruppen anstelle des Benzylrestes werden normal hydriert zum n-Propyl- bzw. Isoamyl-Derivat.
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    Keywords: Chemistry ; Inorganic Chemistry
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    Topics: Chemistry and Pharmacology
    Notes: 2.4.6-Trisubstituierte Pyryliumsalze lassen sich mit geeigneten Carbanionen in aromatische Verbindungen überführen. In Analogie zu der früher beschriebenen Reaktion mit Metallsalzen des Nitromethans, wobei Derivate des Nitrobenzols entstehen, werden mit Benzyl-lithium Derivate des Biphenyls, mit Acetessigester substituierte Benzoesäureester, mit Acetylaceton substituierte Acetophenone und mit Cyanessigester substituierte aromatische Nitrile erhalten.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 2051-2056 
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Darstellung einiger Phosphorsäure-monoarylester-dichloride und Phosphorsäure-diarylester-monochloride und eines Phosphonsäure-dichlorids wird beschrieben, ebenso die Kondensation einiger dieser Chloride mit einigen Phenolen zu polymeren Phosphorsäure-phenolestern.
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Umsetzungen des Eisenpentacarbonyls mit Derivaten der Pyridinreihe, z. B. Pyridin-aldehyd-(2) und koordinativ 2-zähligen Pyridin-aldehyd-(2)-imiden, wie dem Methyl- und Äthylimid, führen zu Octacarbonyldiferraten mit hexakoordiniertem Kation, z. B. [Fe(RN=CH—NC5H4)3][Fe2(CO)8]. Mitunter verläuft die Reaktion über eine tieffarbige Additionsverbindung des betr. Amins mit Pentacarbonyl, die beim Anil als 2 Fe(CO)5·C6H5N=CH—NC5H4 gefaßt wurde. Weiterhin entstehen im letzteren Fall mit Eisentetracarbonyl, wie auch mit Pyridin-aldehyd-(2)-p-tolil, ferner mit o-Phenylendiamin oder Bipyridyl-(2.2′) und Pentacarbonyl Hendecacarbonylrifterrate, während sich mit Isochinolin, Pyrrolidon und Methylpyrrolidon und Pentacarbonyl Tridecacarbonyltetraferrate bilden, z. B. die Verbindungen [Fe(RN=CH—NC5H4)3][Fe3(CO)11] oder [Fe(C4H6ON(CH3))4][Fe4(CO)13].  -  Die für die Carbonylferrate angenommene Struktur mit 2-, 3- und 4-kernigen Anionen wird schließlich durch IR-Absorptionsspektren gestützt. Insgesamt zeigen so die Ergebnisse den spezifischen Einfluß der betr. komplexbildenden Komponente auf den Reaktionstyp.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 2088-2094 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Phosphorhalogen-Verbindungen, quartäre Phosphoniumsalze, Phosphorsauerstoff- und Phosphorschwefel-Verbindungen können mit feinverteiltem Natrium zu Natriumphosphiden bzw. Phosphinen reduziert werden. Aus Natrium-phosphiden und Alkylhalogeniden sind quartäre Phosphoniumsalze leicht zugänglich.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 2135-2140 
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Mittels der Reaktion K4[Ni2(CN)6(CO)2] + 8KC ≡CR → K6[Ni2(C≡CR)8] + 2CO + 6KCN ( R = H, CH3, C6H5) werden die gelben explosiven Octa-alkinylo-diniccolate(I) in flüssigem Ammoniak rein dargestellt. Die zweikernige Struktur dieser Verbindungen wird durch ihren Diamagnetismus, ihre Salznatur durch Leitfähigkeitsmessung bewiesen.  -  IR-Messungen an dem als Ausgangsmaterial verwendeten K4[Ni2(CN)6(CO)2] lassen das Vorliegen ketoartiger CO-Brücken im Anion erkennen.
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  • 72
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Azulen-1(bzw. 3)-glyoxylsäuren und -carbonsäuren wurden aus Azulenen und Oxalylbromid ohne Katalysatoren dargestellt. Die Reduktion von Azulenmonocarbonsäuren, -glyoxylsäuren und -dicarbonsäuren wurde untersucht. Die optischen Eigenschaften der erhaltenen Azulenderivate werden diskutiert.
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  • 73
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 2181-2184 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Das in der Überschrift genannte Cyclobutenderivat kann aus Butin-(2) und Chlor bei Anwesenheit von Borfluorid in 45-proz. Ausbeute gewonnen werden.
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  • 74
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 2199-2205 
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Bei der Umwandlung von wasserfreier Hypophosphorsäure erfolgt eine Isomerisierung zu Diphosphor(III,V)-säure. Daneben tritt Oxydoreduktion zu Pyrophosphorsäure und pyrophosphoriger Säure ein. Einige neu vermessene Raman-Spektren von Oxosäuren des Phosphors und deren Salzen werden mitgeteilt.
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  • 75
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die bei der Umsetzung von Tetraphosphor-pentasulfid, P4S5, mit flüssigem Ammoniak entstehenden Ammoniumverbindungen mit vier Phosphor- und fünf Schwefelatomen in der Molekel disproportionieren sich oberhalb von 140° in Tetraphosphor-trisulfid, P4S3, und Tetraphosphor-heptaimido-trisulfid, P4S3(NH)7. Außerdem bilden sich in Nebenreaktionen (ca. 10%) P4S7(NH)3, P4S10 und P4S7. Die Reaktionsmechanismen der Disproportionierungen, die Trennung der hierbei entstehenden Verbindungen und deren Eigenschaften werden beschrieben.
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  • 76
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 2271-2277 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: cis- und trans-2.3-Dithia-decalin werden auf zwei Wegen dargestellt, ihre Eigenschaften mit denen ähnlicher cyclischer Disulfide verglichen, die Konstellationen diskutiert.
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  • 77
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 2026-2029 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Pyrrol-Chinon-Farbstoffe sind auf Grund der jetzigen Erfahrungen über die Mechanismen der Pyrrolreaktionen und die Bildung von Pyrrolfarbstoffen als Dipyrrylchinone zu formulieren.
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  • 78
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 2040-2042 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Schiffsche Basen des Äthylendiamins mit Imidazol-aldehyd-(4 bzw. 5) und Pyridin-aldehyd-(2) aktivieren Kobaltionen in ihrer Peroxydasewirkung. Eisenionen werden durch Chelatbildung mit 4.5-Di-[pyridyl-(2)]-imidazol katalatisch aktiviert.
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  • 79
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Kondensation von 2.4.6-Triphenyl-pyryliumsalzen mit Malonsäurediester oder mit Malodinitril in Gegenwart von Kalium-tert.-butylat verläuft anders als erwartet. Im Gegensatz zu der in früheren Mitteilungen besprochenen Aromatisierungsreaktion werden hier zwei C-Atome des zugesetzten Reagenzes zur Bildung des Benzolrings verwendet; es entstehen nicht Derivate des symm. Triphenylbenzols, sondern des 2.4-Diphenyl-benzophenons.  -  Die Konstitution des mit Malonester gebildeten Stoffes wird durch eine unabhängige Synthese bewiesen.
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  • 80
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Bei der Einwirkung von wasser- und alkoholfreien ätherischen Lösungen von Diazomethan, Diazoäthan, Diazoessigsäure-äthylester bzw. Phenyl-diazomethan auf Triketo-indan erfolgt Ringerweiterung mit anschließender Enolisierung und gegebenenfalls Alkylierung der enolischen OH-Gruppe. Mit Diazomethan wurden auf diese Weise Lawson-methyläther, mit Diazoäthan Phthiocol-äthyläther in guten Ausbeuten erhalten, die sich in bekannter Weise zu den freien Hydroxy-naphthochinonen verseifen ließen.
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  • 81
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 2132-2135 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: An Eisenkatalysatoren mit und ohne Träger wird die Dehydrierung der Ameisensäure gemessen. Die Aktivierungsenergie der Reaktion kann systematisch durch Dotierung des als Träger dienenden Aluminiumoxyds beeinflußt werden. Auch der technisch bei der Ammoniaksynthese übliche Zusatz von Kalium läßt sich so auf eine Halbleiterdotierung zurückführen.
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  • 82
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 2439-2450 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Durch Umsetzung von D-Fructose mit optisch einheitlichen Di- und-Tripeptiden wie Glycyl-glycin, Glycyl-L-leucin, Glycyl-L-tyrosin, L-Leucyl-glycin, L-Leucyl-L-tyrosin, Glycyl-glycyl-L-leucin und Glutathion lassen sich als Hauptreaktionsprodukte „D-Glucose-Peptide“ gewinnen, die durch Umlagerung der zunächst gebildeten N-D-Fructosylpeptide entstehen.
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  • 83
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 2451-2460 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Bei der Umsetzung von D-Fructose mit Gelatine in Dimethylsulfoxyd reagieren 50-60% der freien ∊-Aminogruppen der Lysinbausteine. Der Zucker wird dabei in der Art der Aldose-Aminosäuren (2-N-Aminosäure-2-desoxy-aldosen) an das Protein gebunden. In Eisessig reagieren nur 15% der Lysinbausteine.
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  • 84
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 2478-2481 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Bei der Darstellung von 1.2.4-Triazinen aus Ammoniak und Monoacylhydrazonen unsymmetrischer 1.2-Diketone können neben den erwarteten 5.6-Disubstitutionsprodukten (A) die isomeren 6.5-Derivate (B) entstehen. Der Bildungsmechanismus wird diskutiert.
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  • 85
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Phosphinoxyde (und Phosphonate) mit einer zur PO-Gruppierung nachbarständigen CH-Gruppe setzen sich mit Aldehyden und Ketonen unter Mitwirkung von Basen  -  vorteilhaft Kalium-tert.-butylat  -  zu Olefinen um. Die Reaktion verläuft über die Stufe der β-Hydroxy-alkylphosphinoxyde. Ein Vertreter dieser Verbindungsklasse, auf einem übersichtlichen Weg synthetisiert, zerfällt in Anwesenheit von Kalium-tert.-butylat in Phosphinsäure und Olefin.  -  Mit Phenyl-lithium in α-Stellung metallierte Phosphinoxyde reagieren mit Carbonylverbindungen zu β-Hydroxy-alkylphosphinoxyden. Durch Umsetzung von Phosphinoxyden mit Carbonsäureestern und Kalium-tert.-butylat als Kondensationsmittel entstehen β-Keto-alkylphosphinoxyde.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 2516-2520 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die schrittweise Chlorierung des Cyclohexandions-(1.2) in wäßriger Lösung verläuft über isolierbare Hydrate; die bei deren Entwässerung entstehenden Enole sind weiterchlorierbar. Das 3.3-Dichlor-cyclohexandion-(1.2)-hydrat-(2) lagert sich, den Beobachtungen in der 5-Ring-Reihe entsprechend, in die Enolform des 3.6-Dichlor-cyclohexandions-(1.2) um. Ein Teil der Verbindungen erleidet überraschend leicht Benzilsäure-Umlagerung.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 2676-2676 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wird eine wesentlich verbesserte Methode zur Hydrierung von 2-Nitro-3-hydroxy-benzoylalanin (I) zu 3-Hydroxy-kynurenin (II) beschrieben.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 2681-2694 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Aliphatische und cycloaliphatische Chlorphosphine, R2PCl, für die ein allgemein anwendbares Darstellungsverfahren beschrieben wird, reagieren mit Natrium in Dioxan unter Bildung von Diphosphinen, R2P—PR2. Auf diese Weise werden aus (C2H5)2PCl, (C4H9)2PCl und (C6H11)2PCl die Verbindungen (C2H5)2P—P(C2H5)2, (C4H9)2P—P(C4H9)2 und (C6H11)2P—P(C6H11)2 dargestellt, die sich mit Schwefel bzw. Sauerstoff zu den entsprechenden Disulfiden, R2P(S)—P(S)R2, bzw. Dioxyden, R2P(O)—P(O)R2, vereinigen. Die Tetraalkyldiphosphine lagern ein Mol. Alkylhalogenid unter Bildung von Pentaalkyldiphosphoniumhalogeniden, [R4P2R′]J, an, während im Tetracycloalkyl-diphosphin die P—P-Brücke gespalten wird.  -  Die Wechselwirkung der Diphosphine mit elementarem Jod bzw. Brom führt zu Jodphosphinen, R2PJ, bzw. Bromphosphinen, R2PBr.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 2723-2732 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Durch Autoxydation von Cyclohexylmagnesiumchlorid, Hexamethylenmagnesiumchlorid und Indenyl-(3)-lithium bei tiefen Temperaturen und nachfolgende Hydrolyse wurden die zugehörigen Hydroperoxyde erhalten.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 2749-2751 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 1.2;3.4-Dibenzpyren (IV) entsteht aus Tetraphen (III) durch Umsetzung mit Benzol und Aluminiumchlorid. 8.9-Benztetraphen (1.2;5.6-Dibenzanthracen) (VII) gibt in dieser Reaktion das 1.2;4.5;8.9-Tribenzpyren (VI).
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 2761-2767 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Mono-Anionen der Phosphorsäure und ihrer Monoester I reagieren mit Isocyanaten II zu Phosphorsäure-carbaminsäure-anhydriden III, die in Form ihrer Salze beständig sind; sie reagieren mit Phosphorsäuren zu Pyrophosphaten V.
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  • 92
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 2779-2783 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Einwirkung von Methyljodid, Dimethylsulfat und Diazomethan sowie von deren Äthylhomologen auf 2-Hydroxy-thiazolo[4.5-b]- und -[5.4-b]chinolin wird untersucht. Dabei zeigt sich, daß das -[4.5-b]-Derivat ausschließlich N-Alkylverbindungen bildet, während von dem 2-Hydroxy-thiazolo[5.4-b]chinolin in einigen Fällen auch O-Alkylverbindungen erhalten werden.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 2674-2675 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 1.2-Diphenyl-3.5-dioxo-pyrazolidin wird von Diazomethan quantitativ am Sauerstoff methyliert und gibt Farbreaktion mit FeCl3. Fehlangaben im Schrifttum werden durch diese Befunde berichtigt.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 2677-2678 
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 2694-2700 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die von E. Fischer und G. Bertrand beschriebenen Tribenzal-L-idite erwiesen sich als identisch mit 1.3;2.4;5.6-Tribenzal-L-idit. Unter wenig abgeänderten Versuchsbedingungen entsteht neben dem Tribenzal-L-idit ein Dibenzal-Derivat, welches einen 2.3.4.5-, wahrscheinlich 2.4;3.5-Dibenzal-L-idit darstellt. Es wird auf den unterschiedlichen Verlauf der Acetalisierung des L-Idits mit Benzaldehyd, bzw. Formaldehyd hingewiesen.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 2732-2740 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Nach Autoxydation von Aryl-lithium- und -magnesium-Verbindungen bei -150 oder -75° war keine Arylperoxy-Verbindung nachweisbar. Addukte von Alkalimetallen an mehrkernige aromatische Kohlenwasserstoffe, gelöst in Glykoldimethyläther oder Tetrahydrofuran, reagieren mit überschüssigem Sauerstoff auch bei -75° ausschließlich zu Metallperoxyd unter Rückbildung des Ausgangskohlenwasserstoffes.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 2887-2892 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Eine Anzahl von Thioanisolen wird durch N-Brom-succinimid in Tetrachlorkohlenstoff im Gegensatz zu anderen gemischten und aliphatischen Thioäthern an der Schwefel-Kohlenstoff-Bindung unter Bildung von N-Arylmercapto-succinimiden gespalten.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 2902-2916 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Umsetzung von Naphthylendiamin-(2.3) und 4.5-Diamino-1.3-dimethyluracil mit α.β-ungesättigten Carbonsäuren, α.β-ungesättigten Ketonen, 1.2-Diketonen und β-Ketocarbonsäureestern wird beschrieben.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 2917-2926 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Hydrochinonmonophosphat (I) wurde durch Phosphorylierung von Hydrochinonmonobenzoat mit POCl3 und ammonolytische Abspaltung des Benzoylrests als krist. Bariumsalz erhalten. Die Synthese des Naphthohydrochinon-(1.4)-monophosphats (II) gelang auf analoge Weise, ausgehend von der Monocarbobenzoxyverbindung III über V. Der neue Phosphorsäureester wurde als krist. Bis-cyclohexylammonium-Salz isoliert.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 2967-2976 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Bei der Ringaufspaltung gesättigter und ungesättigter Azlactone mit Stickstoffwasserstoffsäure entstehen α-[Tetrazolyl-(1)]-propion- bzw. -acrylsäuren (XIV bzw. VII), deren Konstitution sichergestellt wird. Bei 2-Aryl-4-aryliden-oxazolonen-(5) mit para-ständigen Nitrogruppen in den aromatischen Ringen tritt diese Reaktion zugunsten einer anderen zurück.
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