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  • 04. Solid Earth::04.08. Volcanology::04.08.01. Gases  (38)
  • 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics  (19)
  • Apennines
  • Elsevier Science Limited  (35)
  • Elsevier  (22)
  • Blackwell Publishing Ltd  (2)
  • Elsevier Ltd.
  • 2010-2014  (60)
  • 1990-1994
  • 1980-1984
  • 1925-1929
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Years
Year
  • 1
    Publication Date: 2021-05-17
    Description: The Lower Pliocene succession of the Crotone Basin (Calabrian Arc, Southern Italy) is mainly comprised of blue-grey marly clay with good magnetic properties. Here the bio-magnetostratigraphic data indicate a mean sedimentation rate of about 12–15 cm/kyr. Around 3.7–3.6 Ma a major change in the sedimentation regime occurred: the blue-grey hemipelagic marls grade rapidly into silty marls with a significant increase in the terrigenous fraction and with abundant siliceous remains throughout the whole interval. Magnetic properties of these sediments are very poor, but an integrated calcareous plankton biostratigraphy (foraminifera and nannofossils) infers a high average sedimentation rate (about 50–60 cm/kyr). The abrupt onset of this sedimentation regime in the Crotone Basin is contemporaneous with a major unconformity already recognized in the northern sector of the basin, part of amajor reorganization phase in the whole Apenninic–Maghrebid Chain known as “Globorotalia puncticulata event”. Reports of coeval siliceous sediments in other marginal basins of the Apennines (Southern Calabria, Southern and Northern Apennines) suggest that this “siliceous event” might have been regionally extensive, having important palaeoceanographical implications.We infer that the “siliceous event” is characterized by a combined tectonic- and climate-induced change in palaeoceanographic conditions. The tectonic triggering factors may have been linked to two synchronous events in the Tyrrhenian–Apennine system: 1) the shortening event also known as “G. puncticulata event”, and 2) the coeval opening of the Vavilov Basin in the Tyrrhenian Sea which yielded profound influences in terms of physiography and characteristics of the Crotone Basin. The consequent uplift of the Southern Apennines would have increased sediment supply and availability of silica, resulting in eutrophication and enhanced silica preservation. Strong winter mixing and possibly upwelling conditions could have increased primary productivity during heavy isotope stages Gi4, Gi2 and MG8, at the onset of the “siliceous event”. This important event, lasting from ca. 3.6 Ma to ca. 3.2 Ma, would have recorded a peculiar transitional period before further climatic deterioration and more drastic palaeoceanographic changes occurred around 3.1 Ma, leading to cyclic sapropel deposition in the whole of the Mediterranean sea.
    Description: Published
    Description: 398-410
    Description: 1A. Geomagnetismo e Paleomagnetismo
    Description: JCR Journal
    Description: restricted
    Keywords: Biostratigraphy ; Magnetostratigraphy ; Pliocene ; Calabrian Arc ; 04. Solid Earth::04.04. Geology::04.04.08. Sediments: dating, processes, transport ; 04. Solid Earth::04.04. Geology::04.04.10. Stratigraphy ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Publication Date: 2020-11-26
    Description: The volcano–hydrothermal system of El Chichón volcano, Chiapas, Mexico, is characterized by numerous thermal manifestations including an acid lake, steam vents and boiling springs in the crater and acid and neutral hot springs and steaming ground on the flanks. Previous research on major element chemistry reveals that thermal waters of El Chichón can be divided in two groups: (1) neutral waters discharging in the crater and southern slopes of the volcano with chloride content ranging from 1500 to 2200 mg/l and (2) acid-toneutral waters with Cl up to 12,000 mg/l discharging at the western slopes. Our work supports the concept that each group of waters is derived from a separate aquifer (Aq. 1 and Aq. 2). In this study we apply Sr isotopes, Ca/Sr ratios and REE abundances along with the major and trace element water chemistry in order to discriminate and characterize these two aquifers. Waters derived from Aq. 1 are characterized by 87Sr/86Sr ratios ranging from 0.70407 to 0.70419, while Sr concentrations range from 0.1 to 4 mg/l and Ca/Sr weight ratios from 90 to 180, close to average values for the erupted rocks. Waters derived from Aq. 2 have 87Sr/86Sr between 0.70531 and 0.70542, high Sr concentrations up to 80 mg/l, and Ca/Sr ratio of 17–28. Aquifer 1 is most probably shallow, composed of volcanic rocks and situated beneath the crater, within the volcano edifice. Aquifer 2 may be situated at greater depth in sedimentary rocks and by some way connected to the regional oil-gas field brines. The relative water output (l/s) from both aquifers can be estimated as Aq. 1/Aq. 2– 30. Both aquifers are not distinguishable by their REE patterns. The total concentration of REE, however, strongly depends on the acidity. All neutral waters including high-salinity waters from Aq. 2 have very low total REE concentrations (b0.6 μg/l) and are characterized by a depletion in LREE relative to El Chichón volcanic rock, while acid waters from the crater lake (Aq. 1) and acid AS springs (Aq. 2) have parallel profile with total REE concentration from 9 to 98 μg/l. The highest REE concentration (207 μg/l) is observed in slightly acid shallow cold Ca-SO4 ground waters draining fresh and old pyroclastic deposits rich in magmatic anhydrite. It is suggested that the main mechanism controlling the concentration of REE in waters of El Chichón is the acidity. As low pH results from the shallow oxidation of H2S contained in hydrothermal vapors, REE distribution in thermal waters reflects the dissolution of volcanic rocks close to the surface or lake sediments as is the case for the crater lake.
    Description: -
    Description: Published
    Description: 55-66
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: hydrogeochemistry ; geothermal systems ; Sr isotopes ; REE ; El Chichón Volcano ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 3
    Publication Date: 2020-12-15
    Description: The Africa–Eurasia convergence in Sicily and southern Calabria is currently expressed by two different tectonic and geodynamic domains: thewestern region, governed by a roughlyN–S compression generated by a continental collision; the eastern one, controlled by a NW–SE extension related to the south-east-directed expansion of the Calabro–Peloritan Arc. The different deformation pattern of these two domains is accommodated by a right-lateral shear zone (Aeolian–Tindari–Letojanni fault system) which, from the Ionian Sea, north of Mt. Etna, extends across the Peloritani chain to the Aeolian Islands. In this work, we study the evidence of active tectonics characterizing this shear zone, through the analysis of seismic and geodetic data acquired by the INGV networks in the last 15 years. The study is completed by structural and morphological surveys carried out between Capo Tindari and the watershed of the chain. The results allowed defining a clear structural picture depicting the tectonic interferences between the two different geodynamic domains. The results indicate that, besides the regional ~N130°E horizontal extensional stress field, another one, NE–SW-oriented, is active in the investigated area. Both tension axes are mutually independent and have been active up to the present at different times. The coexistence of these different active horizontal extensions is the result of complex interactions between several induced stresses: 1) the regional extension (NW–SE) related to the slab rollback and back-arc extension; 2) the strong uplift of the chain; 3) the accommodation between compressional and extensional tectonic regimes along the Aeolian– Tindari–Letojanni faults, through a SSE–NNW right-lateral transtensional displacement. In these conditions, the greater and recurring uplift activity is not able to induce a radial extensional dynamics, but, under the “directing” action of the shear system, it can only act on the regional extension (NW–SE) and produce the second system of extension (NE–SW).
    Description: Published
    Description: 1-17
    Description: 3.2. Tettonica attiva
    Description: JCR Journal
    Description: open
    Keywords: Africa–Eurasia convergence ; Aeolian–Tindari fault system ; Transform activity ; Stress and strain fields ; Multidisciplinary approach ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 4
    Publication Date: 2021-01-27
    Description: A variety of atypical plume-like structures and focused upwellings that are not rooted in the lower mantle have recently been discussed, and seismological imaging has shown ubiquitous small-scale convection in the uppermost mantle in regions such as the Mediterranean region, the western US, and around the western Pacific. We argue that the three-dimensional return flow and slab fragmentation associated with complex oceanic subduction trajectories within the upper mantle can generate focused upwellings and that these may play a significant role in regional tectonics. The testable surface expressions of this process are the outsidearc alkaline volcanism, topographic swell, and low-velocity seismic anomalies associated with partial melt. Using three-dimensional, simplified numerical subduction models, we show that focused upwellings can be generated both ahead of the slab in the back-arc region (though ~five times further inward from the trench than arc-volcanism) and around the lateral edges of the slab (in the order of 100 km away from slab edges). Vertical mass transport, and by inference the associated decompression melting, in these regions appears strongly correlated with the interplay between relative trench motion and subduction velocities. The upward flux of material from the depths is expected to be most pronounced during the first phase of slab descent into the upper mantle or during slab fragmentation. We discuss representative case histories from the Pacific and the Mediterranean where we find possible evidence for such slab-related volcanism.
    Description: Published
    Description: 54-68
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: JCR Journal
    Description: reserved
    Keywords: subduction ; magmatism ; upper mantle convection ; geodynamic modeling ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 5
    Publication Date: 2021-01-27
    Description: We model a fault cross-cutting the brittle upper crust and the ductile lower crust. In the brittle layer the fault is assumed to have stick–slip behaviour, whereas the lower ductile crust is inferred to deform in a steady-state shear. Therefore, the brittle–ductile transition (BDT) separates two layers with different strain rates and structural styles. This contrasting behaviour determines a stress gradient at the BDT that is eventually dissipated during the earthquake. During the interseismic period, along a normal fault it should form a dilated hinge at and above the BDT. Conversely, an over-compressed volume should rather develop above a thrust plane at the BDT. On a normal fault the earthquake is associated with the coseismic closure of the dilated fractures generated in the stretched hangingwall during the interseismic period. In addition to the shear stress overcoming the friction of the fault, the brittle fault moves when the weight of the hangingwall exceeds the strength of the dilated band above the BDT. On a thrust fault, the seismic event is instead associated with the sudden dilation of the previously over-compressed volume in the hangingwall above the BDT, a mechanism requiring much more energy because it acts against gravity. In both cases, the deeper the BDT, the larger the involved volume, and the bigger the related magnitude. We tested two scenarios with two examples from L’Aquila 2009 (Italy) and Chi-Chi 1999 (Taiwan) events. GPS data, energy dissipation and strain rate analysis support these contrasting evolutions. Our model also predicts, consistently with data, that the interseismic strain rate is lower along the fault segment more prone to seismic activation.
    Description: Published
    Description: 160-161
    Description: JCR Journal
    Description: open
    Keywords: faul activation ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 6
    Publication Date: 2021-06-22
    Description: Total CO2 output from soil gas and plume, discharged from the Stromboli Island, was estimated. The CO2 emission of the plume emitted from the active crater was estimated on the basis of the SO2 crater output and C/S ratio, while CO2 discharged through diffuse soil emission was quantified on the basis of 419 measurements of CO2 fluxes from the soil of the whole island, performed by using the accumulation chamber method. The results indicate an overall output of ≅416 t day−1 of CO2 from the island. The main contribution to the total CO2 output comes from the summit area (396 t day−1), with 370 t/day from the active crater and 26 t day−1 from the Pizzo sopra La Fossa soil degassing area. The release of CO2 from peripheral areas is ≅20 t day−1 by soil degassing (Scari area mainly). The result of the soil degassing survey confirms the persistence of the highest CO2 degassing areas located on the North-East crater side and Scari area.
    Description: Published
    Description: 52-60
    Description: 2V. Dinamiche di unrest e scenari pre-eruttivi
    Description: 4V. Vulcani e ambiente
    Description: JCR Journal
    Description: restricted
    Keywords: CO2 flux ; CO2 output ; Stromboli Island ; SO2 flux ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 7
    Publication Date: 2021-05-11
    Description: The CO2 laser-based lidar ATLAS has been used to study the Stromboli volcano plume. ATLAS measured water vapor concentration in cross-sections of the plume and wind speed at the crater. Water vapor concentration and wind speed were retrieved by differential absorption lidar and correlation technique, respectively. Lidar returns were obtained up to a range of 3 km. The spatial resolution was 15 mand the temporal resolution was 20 s. By combining these measurements, the water vapor flux in the Stromboli volcano plume was found. To our knowledge, it is the first time that lidar retrieves water vapor concentrations in a volcanic plume.
    Description: Published
    Description: 1295–1298
    Description: 1.10. TTC - Telerilevamento
    Description: JCR Journal
    Description: reserved
    Keywords: Lidar ; Volcanic plume ; DIAL ; Water vapor ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 8
    Publication Date: 2020-12-07
    Description: Low-field anisotropy of magnetic susceptibility (AMS) analyses were performed on 532 samples col-lected in 36 (mostly lower Pliocene to lower Pleistocene) marine clay sites from the Crotone basin, afore-arc basin located on top of the external Calabrian accretionary wedge. The Crotone basin formedsince mid-late Miocene under a predominant extensional tectonic regime, but it was influenced there-after by complex interactions with NW–SE left-lateral strike-faults bounding the basin, which also yieldedpost-1.2 Ma ~30◦counterclockwise block rotations. The basin is filled by continental to marine sedimentsyielding one of the thickest and best-exposed Neogene succession available worldwide. The deep-marinefacies – represented by blue-grey marly clays gave the best results, as they both preserved a clear mag-netic fabric, and provided accurate chronology based on previously published magnetostratigraphy andcalcareous plankton (i.e. foraminifers and nannofossils) biostratigraphy. Magnetic susceptibility rangeand rock magnetic analyses both indicate that AMS reflects paramagnetic clay matrix crystal arrange-ment. The fabric is predominantly oblate to triaxial, the anisotropy degree low (〈1.06), and the magneticfoliation mostly subparallel to bedding. Magnetic lineation is defined in 30 out of 36 sites (where thee12 angle is 〈35◦). By also considering local structural analysis data, we find that magnetic fabric wasgenerally acquired during the first tectonic phases occurring after sediment deposition, thus validatingits use as temporally dependent strain proxy. Although most of the magnetic lineations trend NW–SE andare orthogonal to normal faults (as observed elsewhere in Calabria), few NE–SW compressive lineationsshow that the Neogene extensional regime of the Crotone basin was punctuated by compressive episodes.Finally, compressive lineations (prolate magnetic fabric) documented along the strike-slip fault boundingthe basin to the south support the significance of Pleistocene strike-slip tectonics. Thus the Crotone basinshows a markedly different tectonics with respect to other internal and western basins of Calabria, asit yields a magnetic fabric still dominated by extensional tectonics but also revealing arc-normal short-ening episodes and recent strike-slip fault activity. The tectonics documented in the Crotone basin iscompatible with a continuous upper crustal structural reorganization occurring during the SE-migrationof the Calabria terrane above the Ionian subduction system.
    Description: Published
    Description: 67-79
    Description: 1A. Geomagnetismo e Paleomagnetismo
    Description: JCR Journal
    Description: restricted
    Keywords: Calabrian Arc, Anisotropy of magnetic susceptibility, Structural analysis, Fore-arc region ; 04. Solid Earth::04.04. Geology::04.04.08. Sediments: dating, processes, transport ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism ; 04. Solid Earth::04.05. Geomagnetism::04.05.07. Rock magnetism ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 9
    Publication Date: 2021-01-27
    Description: Na–HCO3–CO2-rich thermomineral waters issue in the N of Portugal, within the Galicia-Trás-os-Montes region, linked to a major NNE-trending fault, the so-called Penacova-Régua-Verin megalineament. Along this tectonic structure different occurrences of CO2-rich thermomineral waters are found: Chaves hot waters (67 °C) and also several cold (16.1 °C) CO2-rich waters. The δ2H and δ18O values of the thermomineral waters are similar to those of the local meteoric waters. The chemical composition of both hot and cold mineral waters suggests that water–rock reactions are mainly controlled by the amount of dissolved CO2 (g) rather than by the water temperature. Stable carbon isotope data indicate an external CO2 inorganic origin for the gas. δ13CCO2 values ranging between −7.2‰ and −5.1‰ are consistent with a two-component mixture between crustal and mantle-derived CO2. Such an assumption is supported by the 3He/4He ratios measured in the gas phase, are between 0.89 and 2.68 times the atmospheric ratio (Ra). These ratios which are higher than that those expected for a pure crustal origin (≈0.02 Ra), indicating that 10 to 30% of the He has originated from the upper mantle. Release of deep-seated fluids having a mantle-derived component in a region without recent volcanic activity indicates that extensive neo-tectonic structures originating during the Alpine Orogeny are still active (i.e., the Chaves Depression).
    Description: Published
    Description: 49-56
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: reserved
    Keywords: CO2-rich thermomineral waters ; mantle volatiles ; isotopes ; Chaves geothermal system ; N-Portugal ; 03. Hydrosphere::03.02. Hydrology::03.02.02. Hydrological processes: interaction, transport, dynamics ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 10
    Publication Date: 2017-04-04
    Description: SO2 fluxes emitted by Stromboli during the 27th February–2nd April 2007 effusive eruption were regularly measured both by an automatic network of scanning ultraviolet spectrometers and by traverse measurements conducted by boat and helicopter. The results from both methodologies agree reasonably well, providing a validation for the automatic flux calculations produced by the network. Approximately 22,000 t of SO2 were degassed during the course of the 35 day eruption at an average rate of 620 t per day. Such a degassing rate is much higher than that normally observed (150–200 t/d), because the cross-sectional area occupied by ascending degassed magma is much greater than normal during the effusion, as descending, degassed magma that would normally occupy a large volume of the conduit is absent. We propose that the hydrostatically controlled magma level within Stromboli's conduit is the main control on eruptive activity, and that a high effusion rate led to the depressurisation of an intermediate magma reservoir, creating a decrease in the magma level until it dropped beneath the eruptive fissure, causing the rapid end of the eruption. A significant decrease in SO2 flux was observed prior to a paroxysm on 15th March 2007, suggesting that choking of the gas flowing in the conduit may have induced a coalescence event, and consequent rapid ascent of gas and magma that produced the explosion.
    Description: Published
    Description: 214-220
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: SO2 flux ; Stromboli ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 11
    Publication Date: 2017-04-04
    Description: Nitrogen isotopes , N2/36Ar and 3He/4He were measured in volcanic fluids within different geodynamic settings. Subduction zones are represented by Aeolian archipelago, Mexican volcanic belt and Hellenic arc, spreading zones – by Socorro island in Mexico and Iceland and hot spots by Iceland and Islands of Cabo Verde. The δ15N values, corrected for air contamination of volcanic fluids, discharged from Vulcano Island (Italy), highlighted the presence of heavy nitrogen (around +4.3 ±0.5‰). Similar 15N values (around +5‰), have been measured for the fluids collected in the Jalisco Block, that is a geologically and tectonically complex forearc zone of the northwestern Mexico [1]. Positive values (15N around +3‰) have been also measured in the volcanic fluids discharged from Nysiros island located in the Ellenic Arc characterized by subduction processes. All uncorrected data for the Socorro island are in the range of -1 to -2‰. The results of raw nitrogen isotope data of Iceland samples reveal more negative isotope composition (about -4.4‰). On the basis of the non-atmospheric N2 fraction (around 50%) the corrected data of 15N for Iceland are around -16‰, very close to the values proposed by [2]. In a volcanic gas sample from Fogo volcano (Cabo Verde islands) we found a very negative value: -9.9‰ and -15‰ for raw and corrected values, respectively.
    Description: Published
    Description: Davos, Switzerland
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: open
    Keywords: Nitrogen Isotopes ; Subduction ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Poster session
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  • 12
    Publication Date: 2017-04-04
    Description: The recent availability of small, cheap ultraviolet spectrometers has facilitated the rapid deployment of automated networks of scanning instruments at several volcanoes, measuring volcanic SO2 gas flux at high frequency. These networks open up a range of other applications, including tomographic reconstruction of the gas distribution which is of potential use for both risk mitigation, particularly to air traffic, and environmental impact modelling. Here we present a methodology for visualising reconstructed plumes using virtual globes, such as GoogleEarth, which allows animations of the evolution of the gas plume to be displayed and easily shared on a common platform. We detail the process used to convert tomographically reconstructed cross-sections into animated gas plume models, describe how this process is automated and present results from the scanning network around Mt.Etna, Sicily. We achieved an average rate of one frame every12 min, providing a good visual representation of the plume which can be examined from all angles. Increating these models, an approximation to turbulent diffusion in the atmosphere was required. To this end we derived the value of the turbulent diffusion coefficient for quiescent conditions near Etna to be around 200–500 m2s-1.
    Description: Published
    Description: 1837-1842
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: Volcanic Plumes ; Tomography ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
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  • 13
    Publication Date: 2017-04-04
    Description: In this paper we present and discuss an improved picture of the seismicity distribution of the Umbria– Marche–Abruzzi Apennines as obtained through the integration of the national and the regional seismic networks operating from 2002 to 2006. During this period, both the Istituto Nazionale di Geofisica e Vulcanologia (INGV) National Seismic Network and the regional networks have been greatly improved. We compare the results of the integrated catalogue obtained in this study with the Catalogue of the Italian Seismicity between 1981 and 2001 [Castello, B., Selvaggi, G., Chiarabba, C., Amato, A., 2006. CSI Catalogo della sismicità italiana 1981–2002, versione 1.1. INGV-CNT, Roma.http://legacy.ingv.it/CSI )], confirming the basic known features of the seismic activity in the region, but also evidencing some original and interesting results. In particular, the new data set allows us to better define the geometry and kinematics of the crustal seismicity, which is confined to the upper 20 km and shows a clear general deepening from west to east. In the crust, we find additional evidence of extensional seismicity below the central portion of the belt and thrust/reverse faulting mechanisms at the outer fronts of the Apennines. Looking at the seismicity along the belt, it is also possible to observe aseismic regions, which could be due to either locked or creeping portions of the Apenninic fault system. At greater depth, the west-dipping seismicity distribution down to about 70 km confirms the hypothesis of a slab of Adriatic lithosphere subducted below the Apennines, but also suggests that there are strong lateral heterogeneities and possibly tears in the slab.
    Description: Published
    Description: 121-135
    Description: 1.1. TTC - Monitoraggio sismico del territorio nazionale
    Description: JCR Journal
    Description: reserved
    Keywords: Seismicity ; Seismic monitoring ; Focal mechanisms ; Subduction ; Apennines ; Italy ; 04. Solid Earth::04.06. Seismology::04.06.99. General or miscellaneous
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  • 14
    Publication Date: 2017-04-04
    Description: We investigated the dynamics of explosive activity at Mt. Etna between 31 August and 15 December 2006 by combining vesicle studies in the erupted products with measurements of the gas composition at the active, summit crater. The analysed scoria clasts present large, connected vesicles with complex shapes and smaller, isolated, spherical vesicles, the content of which increases in scoriae from the most explosive events. Gas geochemistry reports CO2/SO2 and SO2/HCl ratios supporting a deep-derived gas phase for fire-fountain activity. By integrating results from scoria vesiculation and gas analysis we find that the highest energy episodes of Mt. Etna activity in 2006 were driven by a previously accumulated CO2-rich gas phase but we highlight the lesser role of syn-eruptive vesicle nucleation driven by water exsolution during ascent. We conclude that syn-eruptive vesiculation is a common process in Etnean magmas that may promote a deeper conduit magma fragmentation and increase ash formation.
    Description: Published
    Description: 265-269
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: JCR Journal
    Description: reserved
    Keywords: Etna ; fire-fountains ; vesicle textures ; volcanic degassing ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 15
    Publication Date: 2017-04-04
    Description: SURMODERR is a MATLAB toolbox intended for the estimation of reliable velocity uncertainties of a non-permanent GPS station (NPS), i.e. a GPS receiver used in campaign-style measurements. The implemented method is based on the subsampling of daily coordinate time series of one or more continuous GPS stations located inside or close to the area where the NPSs are installed. The continuous time series are subsampled according to real or planned occupation tables and random errors occurring in antenna replacement on different surveys are taken into account. In order to overcome the uncertainty underestimation that typically characterizes short duration GPS time series, statistical analysis of the simulated data is performed to estimate the velocity uncertainties of this real NPS. The basic hypotheses needed to apply the method are: i) the signal must be a long-term linear trend plus seasonal and colored noise for each coordinate; ii) the standard data processing should have already been performed to provide daily data series; iii) if the method is applied to survey planning, the future behavior should not be significantly different from the past behavior. In order to show the strength of the approach, two case studies with real data are presented and discussed (Central Apennine and Panarea Island, Italy). Keywords: Non-permanent GPS; Episodic GPS; Campaign-style GPS; Velocity Field; Strain Rate; Survey Optimization.
    Description: Published
    Description: 1033-1041
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: JCR Journal
    Description: restricted
    Keywords: Non-permanent GPS ; Episodic GPS ; Campaign-style GPS ; Velocity field ; Strain rate ; Survey optimization ; 04. Solid Earth::04.03. Geodesy::04.03.07. Satellite geodesy ; 04. Solid Earth::04.03. Geodesy::04.03.09. Instruments and techniques ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 16
    Publication Date: 2017-04-04
    Description: We re-evaluate the possibility that Earth's rotation contributes to plate tectonics on the basis of the following observations: 1) plates move along a westerly polarized flow that forms an angle relative to the equator close to the revolution plane of the Moon; 2) plate boundaries are asymmetric, being their geographic polarity the first order controlling parameter; unlike recent analysis, the slab dip is confirmed to be steeper along W-directed subduction zones; 3) the global seismicity depends on latitude and correlates with the decadal oscillations of the excess length of day (LOD); 4) the Earth's deceleration supplies energy to plate tectonics comparable to the computed budget dissipated by the deformation processes; 5) the Gutenberg–Richter law supports that the whole lithosphere is a self-organized system in critical state, i.e., a force is acting contemporaneously on all the plates and distributes the energy over the whole lithospheric shell, a condition that can be satisfied by a force acting at the astronomical scale. Assuming an ultra-low viscosity layer in the upper asthenosphere, the horizontal component of the tidal oscillation and torque would be able to slowly shift the lithosphere relative to the mantle.
    Description: Hungarian Scientific Research Fund OTKA in the framework of project K 60394
    Description: Published
    Description: 60-73
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: JCR Journal
    Description: reserved
    Keywords: Plate tectonics ; Earth's rotation ; Tidal despinning ; Earth's energy budget ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 17
    Publication Date: 2017-04-04
    Description: Detailed structural analysis of tourmaline-rich veins hosted in the contact aureole of the ∼6 Ma Porto Azzurro granite in southeastern Elba Island, northern Tyrrhenian Sea is presented. Using geometric features of the veins, the physical conditions at the time of vein formation are estimated, namely the stress ratio (Φ = (σ2 − σ3)/(σ1 − σ3)), driving stress ratio (R′ = (Pf − σ3)/(σ1 − σ3)) and fluid overpressure (ΔPo = Pf − σ3). Two vein sets (A veins and B veins) have been recognized based on orientation and thickness distributions and infilling material. Analysis of vein pole distributions indicates Φ = 0.57 and R′ = 0.24 for the A veins and Φ = 0.58 and R′ = 0.47 for the B veins, and fluid pressures less than the intermediate stress magnitude. Analysis of geometric features of the veins gives estimated fluid overpressures of between ∼16 MPa (A veins) and ∼32 MPa (B veins). We propose a model for the tectonic environment of vein development, in which formation of secondary permeability in the deforming thermal aureole of the Porto Azzurro pluton was controlled by ongoing development of fracture systems in the hinge zone of a regional NNW–SSE trending fold that favored transport and localization of hydrothermal fluids.
    Description: Published
    Description: 1509-1522
    Description: 3.2. Tettonica attiva
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: JCR Journal
    Description: reserved
    Keywords: Thermal aureole ; Upper crust ; Deformation ; Fluid circulation ; Northern Apennines ; Elba Island ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 18
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    Elsevier Science Limited
    In:  Supplementary data associated with this article can be found in the online version, at http://dx.doi.org/10.1016/j.jvolgeores.2012.08. 013.
    Publication Date: 2017-04-04
    Description: A pilot GIS-based system has been implemented for the assessment and analysis of hazard related to active faults affecting the eastern and southern flanks of Mt. Etna. The system structure was developed in ArcGis® environment and consists of different thematic datasets that include spatially-referenced arc-features and associated database. Arc-type features, georeferenced into WGS84 Ellipsoid UTM zone 33 Projection, represent the five main fault systems that develop in the analysed region. The backbone of the GIS-based system is constituted by the large amount of information which was collected from the literature and then stored and properly geocoded in a digital database. This consists of thirty five alpha-numeric fields which include all fault parameters available from literature such us location, kinematics, landform, slip rate, etc. Although the system has been implemented according to the most common procedures used by GIS developer, the architecture and content of the database represent a pilot backbone for digital storing of fault parameters, providing a powerful tool in modelling hazard related to the active tectonics of Mt. Etna. The database collects, organises and shares all scientific currently available information about the active faults of the volcano. Furthermore, thanks to the strong effort spent on defining the fields of the database, the structure proposed in this paper is open to the collection of further data coming from future improvements in the knowledge of the fault systems. By layering additional user-specific geographic information and managing the proposed database (topological querying) a great diversity of hazard and vulnerability maps can be produced by the user. This is a proposal of a backbone for a comprehensive geographical database of fault systems, universally applicable to other sites.
    Description: Published
    Description: 170-186
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 3.2. Tettonica attiva
    Description: 4.3. TTC - Scenari di pericolosità vulcanica
    Description: 5.5. TTC - Sistema Informativo Territoriale
    Description: JCR Journal
    Description: reserved
    Keywords: GIS-based system ; Hazard assessment ; Volcano-tectonics ; Flank dynamics ; Georeferenced arc-features ; Active fault database ; 04. Solid Earth::04.01. Earth Interior::04.01.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.06. Rheology, friction, and structure of fault zones ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.06. Seismology::04.06.99. General or miscellaneous ; 04. Solid Earth::04.07. Tectonophysics::04.07.99. General or miscellaneous ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.05. Stress ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 05. General::05.08. Risk::05.08.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 19
    Publication Date: 2017-04-04
    Description: The aim of this paper is to propose an alternative model for the Pliocene-Quaternary to present evolution of the Northern–Central Apennines by combining geometrical requirements (Riedel shear system) with existing structural and geological geometries (fault systems and their tectonic associations). We define three sectors characterized by different geological, seismological, geodetic and geothermal signatures: the North-Western Sector (NWS), the Western Central Sector (WCS) and the Eastern Central Sector (ECS). According to GPS data derived from literature the three blocks move independently. In particular, the NWS is bound between the ECS/WCS and the Alps; this constraint leads to a stress accumulation responsible for a fragmentation into further several blocks, which move either to the NE or SW. The WCS is relatively stable; the ECS moves towards NE and is characterized by the presence of numerous releasing and restraining bends, which can be related to the action of a main NNW–SSE left-lateral shear zone. Accordingly, the recent and active tectonic setting of the Northern–Central Apennines is rather related to the dynamics of the introduced blocks, caused by the push of the African plate against Europe, than to subduction processes.
    Description: Published
    Description: 55-63
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: JCR Journal
    Description: restricted
    Keywords: Northern-Central Apennines ; Riedel shear system ; Strike slip ; Restraining and releasing bends ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 20
    Publication Date: 2017-04-04
    Description: The main goal of this study is to provide moment tensor solutions for small and moderate earthquakes of the Matese seismic sequence in southern Italy for the period of December 2013–January 2014. We estimate the focal mechanisms of 31 earthquakes with local magnitudes related to the Matese earthquake seismic sequence (December 2013–January 2014) in Southern-Central Italy which are recorded by the broadband stations of the Italian National Seismic Network and the Mediterranean Very Broadband Seismographic Network (MedNet) run by the Istituto Nazionale di Geofisica e Vulcanologia (INGV). The solutions show that normal faulting is the prevailing style of seismic deformation in agreement with the local faults mapped outin the area. Comparisons with already published solutions and with seismological and geological information available allowed us to properly interpret the moment tensor solutions in the frame of the seismic sequence evolution and also to furnish additional information about less energetic seismic phases. Focal data were inverted to obtain the seismogenic stress in the study area. The results are compatible with the major tectonic domain of the area.
    Description: Published
    Description: 118-124
    Description: 2T. Tettonica attiva
    Description: JCR Journal
    Description: restricted
    Keywords: Moment tensors ; Southern Italy ; Apennines ; Stress inversion ; Seismicity and tectonics ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 21
    Publication Date: 2017-04-04
    Description: Society’s needs for a network of in situ ocean observing systems cross many areas of earth and marine science. Here we review the science themes that benefit from data supplied from ocean observatories. Understanding from existing studies is fragmented to the extent that it lacks the coherent long-term monitoring needed to address questions at the scales essential to understand climate change and improve geo-hazard early warning. Data sets from the deep sea are particularly rare with long-term data available from only a few locations worldwide. These science areas have impacts on societal health and well-being and our awareness of ocean function in a shifting climate. Substantial efforts are underway to realise a network of open-ocean observatories around European Seas that will operate over multiple decades. Some systems are already collecting high-resolution data from surface, water column, seafloor, and sub-seafloor sensors linked to shore by satellite or cable connection in real or near-real time, along with samples and other data collected in a delayed mode. We expect that such observatories will contribute to answering major ocean science questions including: How can monitoring of factors such as seismic activity, pore fluid chemistry and pressure, and gas hydrate stability improve seismic, slope failure, and tsunami warning? What aspects of physical oceanography, biogeochemical cycling, and ecosystems will be most sensitive to climatic and anthropogenic change? What are natural versus anthropogenic changes? Most fundamentally, how are marine processes that occur at differing scales related? The development of ocean observatories provides a substantial opportunity for ocean science to evolve in Europe. Here we also describe some basic attributes of network design. Observatory networks provide the means to coordinate and integrate the collection of standardised data capable of bridging measurement scales across a dispersed area in European Seas adding needed certainty to estimates of future oceanic conditions. Observatory data can be analysed along with other data such as those from satellites, drifting floats, autonomous underwater vehicles, model analysis, and the known distribution and abundances of marine fauna in order to address some of the questions posed above. Standardised methods for information management are also becoming established to ensure better accessibility and traceability of these data sets and ultimately to increase their use for societal benefit. The connection of ocean observatory effort into larger frameworks including the Global Earth Observation System of Systems (GEOSS) and the Global Monitoring of Environment and Security (GMES) is integral to its success. It is in a greater integrated framework that the full potential of the component systems will be realised.
    Description: Published
    Description: 1-33
    Description: 3.7. Dinamica del clima e dell'oceano
    Description: JCR Journal
    Description: reserved
    Keywords: Seafloor and water columnobservatories ; 01. Atmosphere::01.01. Atmosphere::01.01.02. Climate ; 01. Atmosphere::01.01. Atmosphere::01.01.04. Processes and Dynamics ; 01. Atmosphere::01.01. Atmosphere::01.01.08. Instruments and techniques ; 03. Hydrosphere::03.01. General::03.01.03. Global climate models ; 03. Hydrosphere::03.01. General::03.01.07. Physical and biogeochemical interactions ; 03. Hydrosphere::03.01. General::03.01.08. Instruments and techniques ; 03. Hydrosphere::03.03. Physical::03.03.01. Air/water/earth interactions ; 03. Hydrosphere::03.03. Physical::03.03.02. General circulation ; 03. Hydrosphere::03.03. Physical::03.03.03. Interannual-to-decadal ocean variability ; 03. Hydrosphere::03.03. Physical::03.03.05. Instruments and techniques ; 03. Hydrosphere::03.04. Chemical and biological::03.04.01. Biogeochemical cycles ; 03. Hydrosphere::03.04. Chemical and biological::03.04.02. Carbon cycling ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.04. Ecosystems ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 03. Hydrosphere::03.04. Chemical and biological::03.04.08. Instruments and techniques ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes ; 04. Solid Earth::04.04. Geology::04.04.04. Marine geology ; 04. Solid Earth::04.04. Geology::04.04.11. Instruments and techniques ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.05. Geomagnetism::04.05.05. Main geomagnetic field ; 04. Solid Earth::04.05. Geomagnetism::04.05.08. Instruments and techniques ; 04. Solid Earth::04.06. Seismology::04.06.06. Surveys, measurements, and monitoring ; 04. Solid Earth::04.06. Seismology::04.06.07. Tomography and anisotropy ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 04. Solid Earth::04.06. Seismology::04.06.10. Instruments and techniques ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.03. Heat generation and transport ; 04. Solid Earth::04.07. Tectonophysics::04.07.04. Plate boundaries, motion, and tectonics ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.02. Experimental volcanism ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 05. General::05.01. Computational geophysics::05.01.01. Data processing ; 05. General::05.02. Data dissemination::05.02.99. General or miscellaneous ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.02. Data dissemination::05.02.02. Seismological data ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions ; 05. General::05.02. Data dissemination::05.02.04. Hydrogeological data ; 05. General::05.08. Risk::05.08.01. Environmental risk ; 05. General::05.08. Risk::05.08.02. Hydrogeological risk
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  • 22
    Publication Date: 2017-04-04
    Description: A local seismic network, over a five-year period, recorded about 450 earthquakes in western Argentina. In this region, the geodynamics is controlled by the subduction of the Nazca plate beneath the South American lithosphere, which is characterised here by a sub-horizontal path before reassuming its downward descent. As accurate earthquake locations are of primary importance when studying the seismicity of a given area, events recorded by the local seismic network enable in-depth investigations into seismo-tectonic patterns, allowing to improve the earthquake source characterization and knowledge on the ongoing seismo-tectonics of the region. To this end, we performed a simultaneous 1-D inversion of both the velocity structure and the hypocentre location. The minimum 1-D model obtained is complemented by station corrections which lead to a first insight into the deeper 3-D structure. In addition, stability tests were performed to verify the robustness of our earthquake location results. They reveal a fairly stable hypocentre determination, demonstrating that the locations obtained by the inversion process are not systematically biased. The results show that Sierra Pie de Palo is characterised by a crustal seismogenic structure, dipping west and extending from its eastern boundary to about 30 km of depth. The study also provided new constraints on the geometry of the subducted slab. We noted a great concentration of shallower seismicity compared to that of the surrounding areas of the Wadati-Benioff zone, at the expected position of the Juan Fernandez Ridge (JFR). Our hypocentres indicate that JFR certainly influences the subduction style along its strike, leading to the formation of a bend in the slab geometry.
    Description: Published
    Description: 44-54
    Description: 3.2. Tettonica attiva
    Description: JCR Journal
    Description: restricted
    Keywords: Minimum 1-D velocity model ; high precision earthquake location ; seismogenic structure ; flat-slab subduction ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics
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  • 23
    Publication Date: 2017-04-04
    Description: We present an improved evaluation of the current strain and stress fields in Southern Apennines (Italy) obtained through a careful analysis of geodetic, seismological and borehole data. In particular, our analysis provides an updated comparison between the accrued strain recorded by geodetic data, and the strain released by seismic activity in a region hit by destructive historical earthquakes. To this end, we have used 9 years of GPS observations (2001-2010) from a dense network of permanent stations, a dataset of 73 well constrained stress indicators (borehole breakouts and focal mechanisms of moderate to large earthquakes), and published estimations of the geological strain accommodated by active faults in the region. Although geodetic data are generally consistent with seismic and geologic information, previously unknown features of the current deformation in southern Italy emerge from this analysis. The newly obtained GPS velocity field supports the well-established notion of a dominant NE-SW-oriented extension concentrated in a ~50 km wide belt along the topographic relief of the Apennines, as outlined by the distribution of seismogenic normal faults. Geodetic deformation is, however, non uniform along the belt, with two patches of higher strain-rate and shear stress accumulation in the north (Matese Mountains) and in the south (Irpinia area). Low geodetic strain-rates are found in the Bradano basin and Apulia plateau to the east. Along the Ionian Sea margin of southern Italy, in southern Apulia and eastern Basilicata and Calabria, geodetic velocities indicate NW-SE extension which is consistent with active shallow-crustal gravitational motion documented by geological studies. In the west, along the Tyrrhenian margin of the Campania region, the tectonic geodetic field is disturbed by volcanic processes. Comparison between the magnitude of the geodetic and the seismic strain-rates (computed using a long historical seismicity catalogue) allow detecting areas of high correlation, particularly along the axis of the mountain chain, indicating that most of the geodetic strain is released by earthquakes. This relation does not hold for the instrumental seismic catalogue, as a consequence of the limited time span covered by instrumental data. In other areas (e.g. Murge plateau in central Apulia), where seismicity is very low or absent, the yet appreciable geodetic deformation might be accommodated in aseismic mode. Overall, the excellent match between the stress and the strain-rate directions in much of the Apennines indicates that both earthquakes and ground deformation patterns are driven by the same crustal forces.
    Description: Published
    Description: 1270-1282
    Description: 3.2. Tettonica attiva
    Description: JCR Journal
    Description: restricted
    Keywords: Satellite geodesy ; Plate motions ; Neotectonics ; Europe ; Apennines ; 04. Solid Earth::04.03. Geodesy::04.03.01. Crustal deformations
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 24
    Publication Date: 2017-04-03
    Description: Fluorine adsorption experiments were performed on 28 samples of the first 5 cm of topsoil collected on the flanks of Mt. Etna. The soil samples were equilibrated with F-rich rainwater (3.25 mg/L) at a soil/water weight ratio of 1/25. Aliquots of the supernatant were collected after 1, 7, 72, 720 and 5640 h and analysed for F content. The soil samples could be subdivided into three groups based on their F-adsorption behaviours after 1 h and at the end of the experiment: (1) negative adsorption (F released from the soil to the solution) after 1 h and negative or moderately positive adsorption at the end, (2) from negative after 1 h to strongly positive adsorption at the end, and (3) always strong positive adsorption. The adsorption capacity of the soils was positively correlated with the soil pH, the contents of finer granulometric fractions (clay and silt) and the weathering stage (as quantified by the chemical alteration index). The most F adsorbing soils are found at the periphery of the volcano where aquifers are more vulnerable to contamination due to the shallower depth of the water table. This study further evidences the importance of the Etnean soils in protecting groundwater from an excessive magmatic F input.
    Description: Published
    Description: 1179–1188
    Description: 4.4. Scenari e mitigazione del rischio ambientale
    Description: JCR Journal
    Description: restricted
    Keywords: volcanic soils ; fluoride adsorption ; Mt. Etna ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.08. Risk::05.08.01. Environmental risk
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  • 25
    Publication Date: 2017-04-04
    Description: According to the most common interpretation, the Apennines developed in Neogene and Quaternary times in the hanging wall of a west directed subduction zone. Seismic tomography is the most powerful tool to investigate large volume of Earth at depth, and it has been extensively applied to shed light on the geometry and shape of the subduction under the Italian peninsula. The various experiments were able to display the slab under the Southern Apennines, but even the most recent tomographic images were non-uniquely interpretable and left open questions about the characteristics of the subduction in the Northern-Central sector of the chain. We here present the results of an improved inversion experiment focused on the Northern and Central Apennines. The results do not show any pronounced subduction slab and the most evident anomaly is a low velocity body extending down to 100 km depth, located in a relatively small area under the western Tuscany. On the basis of accurate synthetic tests, we assess that, if established, a subduction like geometry should be visible in our tomographic images. We then conclude that no subduction is imaged in the Northern and Central Apennines. We thus interpret this anomaly as an asthenospheric flow. However, we cannot exclude that our result is due to intrinsic limitations of the methodology. In fact in response to the original question about the capability of local earthquake tomography to settle the matter about subduction, we underline that the absence of deep earthquakes to illuminate the model from below, the existence of seismic gaps in some sectors of the area under study even at shallow depth and the non uniqueness of interpretation of the tomographic images make local tomography unable to give alone definitive information on the deep structure of the Northern and Central Apennines.
    Description: Published
    Description: 63-73
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: JCR Journal
    Description: restricted
    Keywords: Seismic tomography ; Apennines ; Subduction ; Asthenospheric upwelling ; 04. Solid Earth::04.06. Seismology::04.06.07. Tomography and anisotropy
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  • 26
    Publication Date: 2017-04-04
    Description: In this paper, we report four years of soil CO2 emission data measured monthly at 130 sites in two peripheral areas of Mt Etna Volcano that are well known for their high discharge rates of volcanic gas. We remove the influence of atmospheric parameters, and by means of statistical analyses, we (i) demonstrate that variations in CO2 emissions are due mainly to CO2 of a deep origin and (ii) quantify the total amounts of CO2 derived from a deep magma source. Periods of anomalous deep degassing are identified in both areas. A comparison of the timing of these anomalies and geophysical data indicates that the periods of anomalous degassing can be mostly ascribed to intrusions of fresh magma into the Etna plumbing system, which is in agreement with many previous works. Based on the existing literature, we formulate an interpretative framework of magma migration within the plumbing system, consistent with temporal trends in the observed anomalies. Finally, we reconstruct the processes of recent magma ascent at Mt Etna based on our interpretative framework, published geophysical data, and records of volcanic activity.
    Description: Published
    Description: 218-227
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: Soil CO2 flux ; Mt Etna ; Volcanic activity ; Magma transfer ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 27
    Publication Date: 2017-04-04
    Description: From October 2008 to November 2009, soil CO2, radon and structural field surveys were performed on Mt. Etna, in order to acquire insights into active tectonic structures in a densely populated sector of the south-eastern flank of the volcano, which is involved in the flank dynamics, as highlighted by satellite data (InSAR). The studied area extends about 150 km2, in a sector of the volcano where InSAR results detected several lineaments that were not well-defined from previous geological surveys. In order to validate and better constrain these features with ground data evidences, soil CO2 and soil radon measurements were performed along transects roughly orthogonal to the newly detected faults, with measurement points spaced about 100 m. In each transect, the highest CO2 values were found very close to the lineaments evidenced by InSAR observations. Anomalous soil CO2 and radon values were also measured at old eruptive fractures. In some portions of the investigated area soil gas anomalies were rather broad over transects, probably suggesting a complex structural framework consisting of several parallel volcano-tectonic structures, instead of a single one. Soil gas measurements proved particularly useful in areas at higher altitude on Mt. Etna (i.e. above 900 m asl), where InSAR results are not very informative/ are fairly limited, and allowed recognizing the prolongation of some tectonic lineaments towards the summit of the volcano. At a lower altitude on the volcanic edifice, soil gas anomalies define the active structures indicated by InSAR results prominently, down to almost the coastline and through the northern periphery of the city of Catania. Coupling InSARwith soil gas prospectingmethods has thus proved to be a powerful tool in detecting hidden active structures that do not show significant field evidences.
    Description: This work was funded by the DPC-INGV project “Flank”
    Description: Published
    Description: 27-40
    Description: 3.2. Tettonica attiva
    Description: JCR Journal
    Description: reserved
    Keywords: CO2 ; Radon ; InSAR ; Faults ; Etna ; Volcano-tectonics ; 04. Solid Earth::04.03. Geodesy::04.03.01. Crustal deformations ; 04. Solid Earth::04.03. Geodesy::04.03.07. Satellite geodesy ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 28
    Publication Date: 2017-04-04
    Description: Despite the clear evidence of active flank dynamics that is affecting the eastern side of Mount Etna, the contribution of tectonic processes has not been yet understood. So far, the various models proposed to explain the observed flank deformation have been based on onshore structural data, coming from the volcanic edifice. The Ionian offshore of Mount Etna has been only recently investigated using multichannel seismic profiles, and offers the opportunity to image the structural features of the substrate of the unstable flank of the volcano. This contribution aims at describing the deformation located offshore Mount Etna using multichannel seismic profiles recently acquired during three seismic surveys. The onshore flank deformation of Mount Etna appears to be laterally confined by two tectonic guidelines, trending roughly E–W, located to the north and south of the deforming flank; the northern guideline, in particular, takes the surface expression of a sharp fault (Pernicana Fault). Though often assumed that these boundary structures continue offshore as linear features, connected to a frontal thrust ramp, the occurrence of this simple offshore structural system has not been imaged. In fact, seismic data show a remarkable degree of structural complexity offshore Mount Etna. The Pernicana Fault, for instance, is not continuing offshore as a sharp feature; rather, the deformation is expressed as ENE–WSW folds located very close to the coastline. It is possible that these tectonic structures might have affected the offshore of Mount Etna before the Pernicana Fault system was developed, less than 15 ka ago. The southern guideline of the collapsing eastern flank of the volcano is poorly expressed onshore, and does not show up offshore; in fact, seismic data indicate that the Catania canyon, a remarkable E–W-trending feature, does not reflect a tectonic control. Seismic interpretation also shows the occurrence of a structural high located just offshore the edifice of Mount Etna. Whereas a complex deformation affects the boundary of this offshore bulge, it shows only limited internal deformation. Part of the topography of the offshore bulge pre-existed the constructional phase of Mount Etna, being an extension of the Hyblean Plateau. Only in the northern part, the bulge is a recent tectonic feature, being composed by Plio-Quaternary strata that were folded before and during the building of Mount Etna. The offshore bulge is bounded by a thrust fault that can be related to the intrusion of the large-scale magmatic body below Mount Etna.
    Description: Published
    Description: 50-64
    Description: 3.2. Tettonica attiva
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: JCR Journal
    Description: restricted
    Keywords: Mount Etna offshore ; Volcano flank instability ; Active tectonics ; Multichannel reflection seismics ; Intrusive body ; 04. Solid Earth::04.04. Geology::04.04.04. Marine geology ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.02. Experimental volcanism
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  • 29
    Publication Date: 2017-04-04
    Description: The ordinary, low intensity, activity of Stromboli volcano is sporadically interrupted by more energetic events termed, depending on their intensity, “major explosions” and “paroxysms”. These short-lived energetic episodes represent a potential risk to visitors to the highly accessible summit of Stromboli. Observations made at Stromboli over the last decade have shown that the composition of gas emitted from the summit craters may change prior to such explosions, allowing the possibility that such changes may be used to forecast these potentially dangerous events. In 2008 we installed a novel, remote-controlled, open-path FTIR scanning system called Cerberus at the summit of Stromboli, with the objective of measuring gas compositions from individual vents within the summit crater terrace of the volcano with high temporal resolution and for extended periods. In this work we report the first results from the Cerberus system, collected in August-September 2009, November 2009 and May-June 2010. We find significant, fairly consistent, intra-crater variability for CO2/SO2 and H2O/CO2 ratios, and relatively homogeneous SO2/HCl ratios. In general, the southwest crater is richest in CO2, and the northeast crater poorest, while the central crater is richest in H2O. It thus appears that during the measurement period the southwest crater had a somewhat more direct connection to a primary, deep degassing system; whilst the central and northeast craters reflect a slightly more secondary degassing nature, with a supplementary, shallow H2O source for the central crater, probably related to puffing activity. Such water-rich emissions from the central crater can account for the lower crystal content of its eruption products, and emphasise the role of continual magma supply to the shallowest levels of Stromboli's plumbing system. Our observations of heterogeneous crater gas emissions and high H2O/CO2 ratios do not agree with models of CO2-flushing, and we show that simple depressurisation during magma ascent to the surface is a more likely model for H2O loss at Stromboli. We highlight that alternative explanations other than CO2 flushing are required to explain distributions of H2O and CO2 amounts dissolved in melt inclusions. We detected fairly systematic increases in CO2/SO2 ratio some weeks prior to major explosions, and some evidence of a decrease in this ratio in the days immediately preceding the explosions, with periods of low, stable CO2/SO2 ratios between explosions otherwise. Our measurements, therefore, confirm the medium term (~ weeks) precursory increases previously observed with MultiGas instruments, and, in addition, reveal new, short-term precursory decreases in CO2/SO2 ratios. immediately prior to the major explosions. Such patterns, if shown to be systematic, may be of great utility for hazard management at Stromboli's summit. Our results suggest that intra-crater CO2/SO2 variability may produce short-term peaks and troughs in CO2/SO2 time series measured with in-situ MultiGas instruments, due simply to variations in wind direction.
    Description: Published
    Description: 66-76
    Description: JCR Journal
    Description: open
    Keywords: OP-FTIR scanning system ; Stromboli Volcano ; Explosive activity ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 30
    Publication Date: 2017-04-04
    Description: We performed an in-depth analysis of the ongoing tectonics of a large sector of southern Sicily, including the Hyblean Foreland and the front of the Maghrebian Chain, as well as the Ionian Sea offshore, through the integration of seismic and GPS observations collected in the nearly two decades. In particular, a dataset consisting of more than 1100 small-to moderate-magnitude earthquakes (1.0 ≤ ML ≤ 4.6) has been used for local earthquake tomography in order to trace the characteristics of the faulting systems, and for focal mechanisms computation to resolve the current local stress field and to characterise the faulting regime of the investigated area. In addition, GPS measurements, carried out on both episodic and continuous stations, allowed us to infer the main features of the current crustal deformation pattern. Main results evidence that the Hyblean Plateau is subject to a general strike–slip faulting regime, with a maximum horizontal stress axis NW–SE to NNW–SSE oriented, in agreement with the Eurasia–Nubia direction of convergence. The Plateau is separated into two different tectonic crustal blocks by the left-lateral strike–slip Scicli–Ragusa Fault System. The western block moves in agreement with central Sicily while the eastern one accommodates part of the contraction arising from the main Eurasia–Nubia convergence. Furthermore, we provided evidences leading to consider the Hyblean–Maltese Escarpment Fault System as an active boundary characterised by a left-lateral strike–slip motion, separating the eastern block of the Plateau from the Ionian basin. All these evidences lend credit to a crustal segmentation of the southeastern Sicily.
    Description: Published
    Description: 137-149
    Description: 1T. Geodinamica e interno della Terra
    Description: JCR Journal
    Description: open
    Keywords: Southeastern Sicily ; Seismotectonics ; Tomography ; Focal mechanisms ; Crustal stress ; Geodetic strain rate ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 31
    Publication Date: 2017-04-04
    Description: Herein we report on the chemical and isotopic (C, H, O, and He) compositions of the fluids from La Fossa crater fumaroles of Vulcano from 1999 to 2010. Consistent with records obtained since the end of the 1980s, our data show that the geochemical features of the fumarole system have experienced several episodes of remarkable change, each lasting no more than a few months. Typical signatures of these short-term anomalies are large increments in CO2, N2, and He concentrations, coupled to increased 13C/12C isotopic ratios, but their meaning remains widely debated. Within a model of fumarolic fluids based on mixing between hydrothermal and magmatic endmembers, we have developed a novel approach to constrain chemical (He/ CO2 and N2/He) and isotopic (13C/12C, D/H, and 3He/4He) ratios of the magmatic endmember during the short-term anomalies. Although much of the geochemical variability in fumaroles results from changes in mixing proportions, the magmatic fluid unquestionably shows significant variations in time. The magmatic He/CO2, N2/He, 13C/12C, and 3He/4He values throughout 1988–1996 differed from those feeding the anomaly at the end of 2004. Early clues of the new magmatic fluid appeared in 1998–1999, far from any short-term anomaly, whereas new and old magmatic fluids coexisted after 2004. We quantitatively prove that the detected geochemical changes are consistent with the degassing path of a magma having a latitic composition, and suggest the presence of two magma ponding levels at slightly different pressures, where bubble–melt decoupling can occur. The different He-isotope compositions at these levels suggest low hydraulic connectivity typical of a complex reservoir with dike and sill structures. In this framework, the short-term geochemical anomalies are probably due to gas accumulation at the top of magma bodies followed by massive escape, or activation of new degassing levels in the reservoir, for which the stress field almost certainly plays a key role. Such a scenario explains the observed increases in both fumarole output and shallow high-frequency seismicity (due to increased pore pressure) during the anomalies, while being consistent with the concomitant absence of any deep seismicity or ground deformation, eventually related to magma movement.
    Description: Published
    Description: 158-178
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: restricted
    Keywords: fumarole geochemistry ; magma degassing ; thermodynamic modeling ; noble gas geochemistry ; carbon isotopes ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.04. Thermodynamics ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 32
    Publication Date: 2020-05-28
    Description: The Main Ethiopian Rift (MER) offers a complete record of the time–space evolution of a continental rift. We have characterized the brittle deformation in different rift sectors through the statistical analysis of a new database of faults obtained from the integration between satellite images and digital elevation models, and implemented with field controls. This analysis has been compared with the results of lithospheric-scale analogue models reproducing the kinematical conditions of orthogonal and oblique rifting. Integration of these approaches suggests substantial differences in fault architecture in the different rift sectors that in turn reflect an along-axis variation of the rift development and southward decrease in rift evolution. The northernmost MER sector is in a mature stage of incipient continental rupture, with deformation localised within the rift floor along discrete tectono-magmatic segments and almost inactive boundary faults. The central MER sector records a transitional stage in which migration of deformation from boundary faults to faults internal to the rift valley is in an incipient phase. The southernmost MER sector is instead in an early continental stage, with the largest part of deformation being accommodated by boundary faults and almost absent internal faults. The MER thus records along its axis the typical evolution of continental rifting, from fault-dominated rift morphology in the early stages of extension toward magma-dominated extension during break-up. The extrapolation of modelling results suggests that a variable rift obliquity contributes to the observed along-axis variations in rift architecture and evolutionary stage, being oblique rifting conditions controlling the MER evolution since its birth in the Late Miocene in relation to a constant post ca. 11 Ma ~ N100°E Nubia–Somalia motion.
    Description: Published
    Description: 479-492
    Description: 3.2. Tettonica attiva
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: JCR Journal
    Description: reserved
    Keywords: continental rifting ; East African Rift ; Main Ethiopian Rift ; rift kinematics ; plate kinematics ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics
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  • 33
    Publication Date: 2017-04-04
    Description: We measured volcanic gas emissions from the northeast crater (NEC) and central crater (CC) of Mount Etna on 21st July 2008, and 3rd and 31st August 2009, using a novel, lightweight open-path Fourier transform infrared spectrometry (OP-FTIR) in active mode with a portable infrared lamp. Contemporaneously we measured the SO2 flux of the total gas emission released by the combined summit craters 14 km downwind and the SO2 flux emitted by the NEC measured at the summit. Combining these data we determined the flux of the major volcanic components H2O, CO2, SO2, HCl and HF emitted individually from CC and NEC craters. The results reveal similar SO2/HCl ratios but distinct CO2/SO2 ratios (1.3 and 10.9 for NEC and CC, respectively) and an order of magnitude greater CO2 flux from the CC compared with the NEC. A simple model in which the NEC branches from a central feeding conduit at a depth of ~2 km can reproduce these observations. We highlight that in such a system short-term variations in CO2/SO2 ratios at each crater can occur due to minor variations in the magma/gas flux entering each conduit at the branch, without an overall change in magma supply. CO2/ SO2 variations measured at individual craters may therefore be unrepresentative of the volcanic system and require cautious interpretation. Monitoring of the total CO2 and SO2 fluxes emitted from each crater is, on the contrary, an optimal monitoring strategy and can be achieved using a combination of CO2/SO2 instruments and SO2 imaging cameras
    Description: INGV-DPC “Sicilia” Project (Gas plumeTask).
    Description: Published
    Description: 368-376
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: magma degassing, OP-FTIR, Mt. Etna ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 34
    Publication Date: 2017-04-04
    Description: Methane soil flux measurements have been made in 38 sites at the geothermal system of Sousaki (Greece) with the closed chamber method. Fluxes range from –47.6 to 29,150 mg m-2 d-1 and the diffuse CH4 output of the system has been estimated at 19 t a-1. Contemporaneous CO2 flux measurements showed a moderate positive correlation between CO2 and CH4 fluxes. Comparison of the CO2/CH4 soil flux ratios with the CO2/CH4 ratio of the gases of the main gas manifestations provided evidence for methanotrophic activity within the soil. Laboratory CH4 consumption experiments confirmed the presence of methanotrophic microorganisms in soil samples collected at Sousaki. Consumption was generally in the range from –4.9 to –38.9 pmolCH4 h-1 g-1 but could sometimes reach extremely high values (–33,000 pmolCH4 h-1 g-1.). These results are consistent with recent studies on other geothermal systems that revealed the existence of thermoacidophilic bacteria exerting methanotrophic activity in hot, acid soils, thereby reducing methane emissions to the atmosphere.
    Description: Published
    Description: 97–107
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: reserved
    Keywords: Sousaki ; accumulation chamber ; soil degassing ; hydrothermal systems ; methane output ; methanotrophic activity ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
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  • 35
    Publication Date: 2017-04-04
    Description: We present the velocity field in Italy derived from over 300 continuous GPS stations operated in the 1998– 2009 time span. The GPS network maps the whole country with a mean inter-site distance of about 50 km and provides a valuable source of data to study the ongoing deformation processes in the central Mediterranean. The estimated horizontal and vertical velocity fields show major significant features and also less known second-order kinematic features. A general uplift characterizes the whole Apennines and Alpine belts that follow the topographic ridge, whereas the Po Plain shows a gradually increasing subsidence from west to east. The Apennines belt displays a distinctive extension (50–80 10−9 yr−1)while compressive tectonic regimes characterize northern Sicily, eastern Alps and the northeast front of the northern Apennines (25–50 10−9 yr−1). Second-order deformation patterns, on large scale wavelength (~100 km) have been detected on the accretionary prism of central and southern Apennines that are highly correlated with other geophysical data (Vp anomalies, seismic anisotropy, etc.) and related to deep rooted sections (70– 100 km), marked by different subduction regimes. Apparently at this scale-length the observed deformations are governed by the lithosphere as a whole. We interpret these deformations as a result of different subduction mechanisms, such as variations of the subduction rollback velocity affecting different segments of the subduction zone and/or to mantle flows in proximity of the slab edges. Further south, in central-southern Sicily, we detect a contraction of (−1.1±0.2) mm/yr that probably accommodates part of the Africa–Eurasia convergence on the outer thrust front of the Apennines–Maghrebides belt. This hypothesis agrees with an independent analysis of the seismicity associated to the Sicilian Basal Thrust, thought to be still active. The ITRF2005 estimates of the new GPS velocity field are available also in SINEX format as supplementary file S1.
    Description: Published
    Description: 230-241
    Description: 1.9. Rete GPS nazionale
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: JCR Journal
    Description: restricted
    Keywords: GPS velocity field ; Apennines ; Alps ; Adria ; Plate kinematics ; Subduction zone ; 04. Solid Earth::04.03. Geodesy::04.03.99. General or miscellaneous
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  • 36
    Publication Date: 2017-04-04
    Description: Here we report results from a multidisciplinary field campaign at Villarrica volcano, Chile, in March 2009. A range of direct sampling and remote sensing techniqueswas employed to assess gas and aerosol emissions from the volcano, and extend the time series of measurements that have been made during recent years. Airborne traverses beneath the plume with an ultraviolet spectrometer yielded an average SO2 flux of 3.7 kg s−1. This value is similar to previous measurements made at Villarrica during periods of quiescent activity. The composition of the plume was measured at the crater rim using electrochemical sensors and, for the first time, open-path Fourier transforminfrared spectroscopy, yielding a composition of 90.5 mol% H2O, 5.7% CO2, 2.6%SO2, 0.9% HCl, 0.3% HF and b0.01% H2S. Comparison with previous gas measurements made between 2000 and 2004 shows a correlation between increased SO2/HCl ratios and periods of increased activity. Base-treated filter packs were also employed during our campaign, yielding molar ratios of HBr/SO2=1.1×10−4, HI/SO2=1.4×10−5 and HNO3/SO2=1.1×10−3 in the gas phase. Our data represent the most comprehensive gas inventory at Villarrica to date, and the first evaluation of HBr and HI emissions from a South American volcano. Sun photometry of the plume showed the near-source aerosol size distributions were bimodal with maxima at b0.1 and ~1 μm. These findings are consistent with results from analyses in 2003. Electron microscope analysis of particulatematter collected on filters showed an abundance of sphericalmicron-sized particles that are rich in Si, Mg and Al. Non-spherical, S-rich particles were also observed.
    Description: Antofagasta plc via the University of Cambridge Centre for Latin American Studies, NERC Field Spectroscopy Facility, NERC projectNE/F004222/1, “Volgaspec” projectANR-06-CATT-012-01 and from the NOVAC project. Istituto Nazionale di Geofisica e Vulcanologia and Dipartimento di Protezione Civile-Regione Sicilia. Christ's College, University of Cambridge, NERC IKIMP project, (NE/G001219/1) and NERC grantNE/G01700X/1 for financial support. NERC National Centre for EarthObservation (“Dynamic Earth and geohazards”)
    Description: Published
    Description: 62-75
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: Villarrica ; FTIR ; SO2 flux ; DOAS ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
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  • 37
    Publication Date: 2017-04-04
    Description: Volcanic edifices are often unable to support their own load, triggering the instability of their flanks. Many analogue models have been aimed, especially in the last decade, at understanding the processes leading to volcano flank instability; general behaviors were defined and the experimental results were compared to nature. However, available data at well-studied unstable volcanoes may allow a deeper understanding of the specific processes leading to instability, providing insights also at the local scale. Etna (Italy) constitutes a suitable example for such a possibility, because of its well-monitored flank instability, for which different triggering factors have been proposed in the last two decades. Among these factors, recent InSAR data highlight the role played by magmatic intrusions and a weak basement, under a differential unbuttressing at the volcano base. This study considers original and recently published experimental data to test these factors possibly responsible for flank instability, with the final aim to better understand and summarize the conditions leading to flank instability at Etna. In particular, we simulate the following processes: a) the longterm activity of a lithospheric boundary, as the Malta Escarpment, separating the Ionian oceanic lithosphere from the continental Sicilian lithosphere, below the most unstable east flank of the volcano; b) spreading due to a weak basement, with different boundary conditions; c) the pressurization of a magmatic reservoir, as that active during the 1994–2001 inflation period; d) dike emplacement, as observed during the major 2001 and 2002–2003 eruptions. The experimental results suggest that: 1) the long-term activity of a lithospheric tectonic boundary may create a topographic slope which provides a differential buttressing at the volcano base, a preparing factor to drive longer-term (〉105 years) instability on the east flank of the volcano; 2) volcano spreading (b104 years) has limited effect on flank instability at Etna; 3) magmatic intrusions (b101 years), both in the form of Mogi-like sources or dikes, provide the most important conditions to trigger flank instability on the shorter-term.
    Description: Thisworkwas partially funded by INGV and the Italian DPC (DPC-INGV project V4 “Flank”).
    Description: Published
    Description: 98-111
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 3.2. Tettonica attiva
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: 3.6. Fisica del vulcanismo
    Description: JCR Journal
    Description: reserved
    Keywords: volcano instability ; analogue modeling ; Etna ; unbuttressing ; 04. Solid Earth::04.01. Earth Interior::04.01.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.06. Rheology, friction, and structure of fault zones ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.07. Tectonophysics::04.07.99. General or miscellaneous ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.05. Stress ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.02. Experimental volcanism ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
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  • 38
    Publication Date: 2017-04-04
    Description: Ambrym is one of the most actively erupting basaltic volcanoes in the Vanuatu island arc. Scoria clasts collected from a fallout deposit in the inner terrace of its Benbow active crater were analyzed through series of synchrotron X-ray computed microtomographic experiments, as well as permeability measurements and simulations. Our goal was to reconstruct and visualize scoria textures in 3D and to quantify vesicularity, permeability, vesicle sizes and distributions in order to understand how gas moves in and out of Ambrym basaltic magma. We find that vesicle size distributions in the volume range between ~ 103 and 1010 μm3 define two scoria classes. Vesicle size distributions in the low-to-moderately (0.44–0.67) vesicular samples can be fit by power laws with an exponent of 1 ± 0.2; distributions in the highly vesicular (0.86–0.88) samples can be fit by power laws with a higher exponent (1.4 to 1.7), as well as by exponential fits. Highly vesicular samples exhibit a very pronounced large vesicle, consisting of networks of smaller, interconnected vesicles, that is more than three orders of magnitude larger in volume than all other vesicles in each distribution. This type of vesicle is not found in the low-to-moderately vesicular samples. In addition, vesicle number density negatively correlates with vesicularity: less vesicular samples have the highest number density and vice versa, and contain far more numerous small-to-medium-sized vesicles than highly vesicular samples. Measured and calculated viscous (Darcian) permeabilities overlap in the range 10− 13 and 10− 9 m2, with higher values in the more vesicular samples. We ascribe these differences in the textural and physical properties of the scoria clasts to their derivation from distinct magma portions in the conduit that were driven by convective overturn and underwent different vesiculation histories and gas transport dynamics. Comparing basaltic scoria clasts from Ambrym to those from mild explosive activity at Stromboli volcano (Italy) reveals that differences in their vesicle size distributions may result from the influence of different crystal contents and shapes on the vesiculation and permeability of the respective magmas. Finally, we highlight how rheological properties have a fundamental role in determining the degassing behaviour of basaltic magma at Ambrym and other volcanoes in general.
    Description: Published
    Description: 55-64
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: JCR Journal
    Description: restricted
    Keywords: Ambrym ; Basaltic scoria ; 3D X-ray micro-tomography analysis ; Volcanic degassing ; Magma convection ; Crystal effect ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks
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  • 39
    Publication Date: 2017-04-04
    Description: Herein, we present a method for continuous measurement of soil CO2 flux that is completely new and distinct from existing instruments. The foremost difference is that instead of using an infrared gas analyser (IRGA), the new device measures soil CO2 flux by means of a simple pressure sensor, measuring pressure transients inside a closed polymeric tube inserted into the soil. This allows continuous measurements even in soil placed in environments that could potentially damage IRGA. In addition, due to the innovative operating principle, measurements of soil CO2 flux can be effortlessly performed also in strongly harsh weather conditions. Theoretical equations were derived for calculating soil CO2 flux solely using measured transient values. The reliability of the equations was rigorously tested with a variety of experiments. Continuous measurements over four months, acquired in a high-emission area on the Island of Vulcano, compared favourably with the data obtained using an established method.
    Description: Published
    Description: 102-109
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: JCR Journal
    Description: restricted
    Keywords: Soil CO2 flux measurements ; Continuous monitoring ; Methods of measurement ; Polymeric membranes ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
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  • 40
    Publication Date: 2017-04-04
    Description: Soil carbonates are key features in soils of arid and semiarid environment, playing an important role from pedogenetic, landscape history, paleoclimatic and environmental points of view. The objectives of this work were (i) to study pathways of pedogenic carbonate (PC) formation, (ii) to distinguish between lithogenic and pedogenic inorganic C by using the natural C isotope abundance, and (iii) to estimate the soil C pools in a gypsiferous semiarid Mediterranean environment (Sicily, Italy). Five soil pedons developed on calcareous and non-calcareous parent materials from Holocene (10,000 years BP) to Upper Tortonian (7.2–5.3 Ma BP) in age were surveyed. During field soil description, the highest stage of carbonate morphology was found in soils developed on non-calcareous Holocene colluvial deposits (youngest deposits in age) which also showed the highest amount of PC. The great amount of PC in soils developed on youngest deposits was ascribed to a soil–landscape relationships. Being located in a doline overhung by gypsum outcrops, precipitation of Ca2+ from gypsum dissolved by rainfall and biogenic CO2 is reliable. The significant positive relationship between soil organic C and pedogenic carbonates δ13C values confirms that PC was formed from biogenic CO2. Organic C pool in the first cubic meter of soil ranged from 17 to 42 kg, whilst pedogenic inorganic C pool from 2.8 to 30.7 kg. The estimated rate of inorganic C accumulation in soils developed on youngest deposits was 2.5 g m−3 y−1, whereas the rate was negligible on older parent material. The hypothesized pathways of PC formation were ex-novo precipitation of gypsum–Ca2+ and biogenic CO2 and dissolution of lithogenic CaCO3 and re-precipitation of Ca2+ with biogenic CO2. From an environmental prospective, investigated soils may act as a sink of C when Ca2+ from gypsum is available for the formation of pedogenic carbonates.
    Description: Published
    Description: 31-38
    Description: 6A. Monitoraggio ambientale, sicurezza e territorio
    Description: JCR Journal
    Description: restricted
    Keywords: Gypsiferous soils ; Soil carbonates ; Stable C isotopes ; Soil C pools ; Soil–landscape relationship ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 41
    Publication Date: 2017-04-04
    Description: Our study is aimed to develop a 3D physical model of the Campi Flegrei geothermal system, in order to achieve a more accurate and comprehensive representation of the hydrothermal processes occurring in the caldera. The new model, developed by using the TOUGH2 code simulator, accounts for the caldera rocks' physical properties, bathymetry and water table topography. In particular, the computational domain is constrained by density values obtained by tomographic inversion of gravity data collected during several surveys at CF both onshore and offshore the caldera. Empirical relations between density and porosity and between porosity and permeability, derived by published data on samples cored in deep wells or collected in outcrops, allowed us to characterize the main rocks physical parameters controlling the dynamic of the CF geothermal system. We have performed and compared several simulations investigating the effects of the injection at depth, underneath Solfatara crater, of a hot gaseous mixture rich in CO2. We show that, with respect to the available literature on 2D axisymmetric models, the effects of the water table topography together with the bathymetry and the heterogeneous distribution of the rocks' physical properties, lead to important differences in the hydrothermal circulation of fluids at CF. These constraints allow the activation of convective cells with different behaviors, which produce variable patterns of temperature inside the hydrothermal system. As a consequence, the predominant effect is again represented by a central plume below the Solfatara crater, but with a non-axisymmetric structure and a wider extension. Additionally, high temperature zones are present near the coastline and in the middle part of the submerged area of the caldera with a SE–NW alignment. Moreover, our results indicate that, the submerged part of the CF caldera would deserve a more accurate study and survey, being affected by phenomenon of heating and degassing. This information could be very useful in terms of hazard assessment and volcanic risk mitigation in such an active and densely inhabited volcanic and geothermal area.
    Description: Published
    Description: 172-182
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: Campi Flegrei ; Geothermal system ; 3D model ; Water table topography ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 42
    Publication Date: 2017-04-04
    Description: Epidermis micromorphology of in situ Erica arborea L. exposed for generations to long-term effect of volcanic gases in Pisciarelli and Solfatara di Pozzuoli areas have been studied by X-ray analyses, SEM and TEM observations. In particular, the aim of this study is to investigate the effects of volcanic gases on extant and possibly fossil plants. Plants of the same species living in a nearby control site were also studied for comparison. SEM coupled with EDX analysis was used to localize different elements within the leaves (mesophyll, cell wall and cuticle). After conventional and cryo preparation, SEM of mature leaves ascertained that the abaxial side is more serrate in fumigated leaves and hairs, epicuticular wax alterations have also been noted. Leaves experiencing chronic fumigation display stomata more sunken with respect to the epidermal surface. TEM of transverse and longitudinal sections of cuticle showed an outer A2 granular amorphous layer and external to a B1 fibrillous layer. Significant statistical variations of ultrastructural components of the cuticle revealed a response of E. arborea to this extreme environment. At the ultrastructural level, significant variations in thickness of the cell wall plus cuticle, cell wall and A2 layer among fumigated and non-fumigated leaves have been found. In the studied localities a positive correlation between atmospheric CO2 concentration and the thickness of A2 layer also exists. The results are of interest being applicable in the understanding of plant cuticle responses during periods of normal vs. volcanic activity.
    Description: Published
    Description: 197– 206
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: Phlegrean Fields ; Erica arborea ; Volcanic gases ; Epidermis ; Cuticle ultrastructure ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring ; 03. Hydrosphere::03.04. Chemical and biological::03.04.04. Ecosystems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 43
    Publication Date: 2017-04-04
    Description: We present the first chlorine isotope compositional data for gases and lavas from Mount Etna (Italy), and to our knowledge, of active Mediterranean volcanism. We investigated lavas erupted and gases discharged during 2008-2011 from a high-temperature fumarole (HT; 〉300°C) and plume gases from both North East and Central Craters. Most of the samples vary in a narrow range of chlorine isotope composition (37Cl values ≈ 0 ± 0.7‰) with gases partially overlapping with rocks. Only HT gases sampled in 2009 have been clearly affected by secondary processes (37Cl values 〉 15.9‰), resulting in partial removal of chlorine and isotopic fractionation producing a 37Cl enrichment in the residual gaseous HCl. These secondary processes also affect, although to a lesser extent, plume gases from North East Crater (NEC). Although post-magmatic processes are able to modify the chlorine isotope composition, 37Cl values are not affected by magma degassing for residual fractions ≥ 0.3 in the melt, or any effect is within our data variability. Finally, 37Cl values and Cl/K ratios of magmatic chlorine constrain the Etnean source to be compatible with depleted mantle (DMM) contaminated by altered oceanic crust (AOC), in agreement with indications from more common isotopic tracers of mantle processes.
    Description: Published
    Description: 134-142
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: restricted
    Keywords: Mount Etna ; chlorine isotope ; plume ; fumarole ; degassing ; mantle source ; 04. Solid Earth::04.04. Geology::04.04.07. Rock geochemistry ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 44
    Publication Date: 2017-04-04
    Description: Volatile metal(loid)s are known to be emitted from volcanoes worldwide.We tested the suitability of active moss monitoring for tracking volatilemetal(loid)s released fromthe fumarolic field on Vulcano Island, Italy, and differentiated fumaroles from other sources of gaseous and particulate trace elements such as sea spray and soil.Metal(loid) accumulation on the mosses per day did depend neither on the state of the exposed moss (dead or living) nor exposure time (3, 6, or 9 weeks). After collection, mosses were digested with either HNO3/H2O2 or deionized water and analyzed by ICP-MS.While for most elements both extraction methods yielded similar concentrations, higher concentrations were observed e.g. for Pb in the stronger HNO3/H2O2 extracts, indicating the presence of particles, which were not digested and removed by filtration in deionized water extracts. Due to their ubiquitous detection in comparable concentrations at all 23 moss monitoring stations all over the island, Li, Mg and Sr were attributed to sea spray origin. Iron, Co, W, V, Pb, Cr, Mo, and Ba occurred predominantly at the crater, where the soil was not covered by vegetation, and thus likely represent soil-borne particulate transport. Arsenic, Sb, S, Se, Tl, Bi, and I showed a clear concentration maximum within the fumarolic field. Concentrations gradually decreased along a transect in wind direction fromthe fumaroles, which confirms their volcanic origin. Activemossmonitoring thus proved to be an inexpensive and easy-to-apply tool for investigations of volcanic metal(loid) emissions and distributions enabling differentiation of trapped elements by their source of origin.
    Description: Published
    Description: 30–39
    Description: 4V. Vulcani e ambiente
    Description: JCR Journal
    Description: restricted
    Keywords: La Fossa crater ; particle transport ; biomonitoring ; volatilization ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 45
    Publication Date: 2017-04-04
    Description: Infrared satellite images measured with the MODIS instrument of the volcanic plume produced during the 2006 eruption of Mt. Etna were analysed to produce maps of SO2 amount. We used these maps to reconstruct time series of SO2 fluxes by integrating profiles of SO2 orthogonal to the plume advection direction and multiplying with wind speeds from a meteorological model. These data were then compared with a reconstructed time series of SO2 fluxes measured with the FLAME ground-based network of ultraviolet DOAS systems surrounding the volcano. We found weak agreement on 3rd December when little ash was emitted, but this agreement improved when a 0.3 m s−1 wind speed correction factor was used. FLAME and MODIS results were in good agreement on the 6th December, and improved when a –0.3 m s−1 offset was applied. The corrected data revealed that the only period of time when FLAME and MODIS did not track together was coincident with the presence of ash, which interferes with the IR imagery and retrieval of SO2. We highlight that combining two independent time series of SO2 flux allows a precise determination of wind speed, if there is sufficient time-dependent structure in the SO2 signal. The observed increase in SO2 flux prior to the ash emission is interpreted as a quiescent release of an accumulated gas phase that drive eruptive activity, as previously suggested for the southeast crater system of Etna. In this case the SO2 flux signal therefore acted as a precursor to the eruptive ash events. This work demonstrates that quantitative reconstruction of SO2 flux time series is feasible using MODIS data, opening a new frontier in the use of satellite data to interpret volcanic processes, in particular in poorly monitored remote locations.
    Description: European Space Agency's Earth Observation Envelope Programme (EOEP) – Data User Element (project SAVAA).
    Description: Published
    Description: 80-87
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: SO2 flux ; Modis ; Etna ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 46
    Publication Date: 2017-04-04
    Description: A 4-year geochemical survey of some fumaroles at the Voragine summit crater of Mt Etna was performed in combination with synchronous monitoring of peripheral gas emissions at the base of the volcano. This was the first geochemical study at Mt Etna to have included the abundances of Ar, He, and C isotopes. Once the effects of postmagmatic shallow processes were identified and quantitatively removed, the He–Ar–CO2 systematics of the Voragine crater fumaroles and peripheral gas emissions described the same degassing path. Combining the carbon-isotope composition with information about noble gases provided evidence that the crater fumaroles are fed from a two-endmember mixture composed of a deep member coming from pressures between 200 and 400 MPa (depending on time), and a shallower one exsolved at 130 MPa. Similar mixing processes probably also occur in gases from peripheral vents. The simultaneous assessment of d13CCO2 and He/Ar values of crater fumaroles over time has identified simple changes in the mixing proportion between the two endmembers and, moreover, periods during which the exsolution pressure of the deep fluid increased. These periods seem to be linked to pre-eruptive phases of the volcano. The identified open-system degassing processes are indicative of efficient bubble–melt decoupling at depth, whereas the mixing process requires a convective transfer of the deeply exsolved fluids toward shallower levels of magma where further vapor is exsolved. In agreement with the most recent geophysical and petrological data from Mt Etna, these observations allow inferences about a deep portion of the plumbing system (5 to 12 km b.s.l.), comprising sill-like reservoirs connected by small vertical structures, and a main reservoir at 2–3 km b.s.l. that is probably fluxed by magmatic volatiles. 2012 Elsevier Ltd. All rights reserved.
    Description: Published
    Description: 380-394
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: restricted
    Keywords: gas geochemistry, isotopes, degassing, modelling ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 47
    Publication Date: 2017-04-04
    Description: We analyzed crater SO2 fluxes from Mt Etna, together with soil CO2 effluxes from the volcano's flanks, in the period from 2001 to 2005. Between the 2001 and 2002–2003 eruptions, persistently low values of both parameters suggest that no new gas-rich magma was accumulating at shallow depth (b5 km) within Etna's central conduit, whereas very high SO2 sin-eruptive fluxes during the two eruptions indicated sudden decompression of an un-degassed magma rising along newly-formed eccentric conduits. In November 2003, soil CO2 data indicate migration of gas-rich magma from deep (〉10 km) to shallow (b5 km) portions of the feeding conduits, preceded by an increase in crater SO2 fluxes. A similar behavior was observed also during and after the following 2004–2005 eruption. This degassing style matches a period of increased structural instability of the volcanic edifice caused by acceleration of spreading that affected both its eastern and southern flanks. Spreading could have triggered progressively deeper depressurization in the central conduit, inducing release of the more soluble gas (SO2) first, and then of CO2, contrary to what was observed before the 2001 eruption. This suggests that the edifice has depressurized, promoting ascent of fresh-magma and increasing permeability favouring release of CO2 flux. By integrating geochemical and structural data, previous degassing models developed at Mt. Etna have been updated to advance the understanding of eruptive events that occurred in recent years.
    Description: This work was funded by grants from the Istituto Nazionale di Geofisica e Vulcanologia (INGV) and from the Dipartimento per la Protezione Civile (Italy).
    Description: Published
    Description: 90-97
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: 3.6. Fisica del vulcanismo
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: reserved
    Keywords: Geochemical modeling ; volcano monitoring ; volcanic gases ; Tectonics and magmatism ; flank collapse ; 04. Solid Earth::04.01. Earth Interior::04.01.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.07. Tectonophysics::04.07.99. General or miscellaneous ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.05. Stress ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.04. Thermodynamics ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 05. General::05.08. Risk::05.08.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 48
    Publication Date: 2017-04-04
    Description: Cuticle micromorphology together with epidermal and epistomatal wax, in both current- and first-year-old needles of conifer Pinus halepensis (Aleppo pine) trees growing under volcanic gas fumigation was analysed in Pisciarelli area, Campi Flegrei, Southern Italy. As a control, current- and first-year-old needles growing far from volcanic gas emission were also sampled. Using a multidisciplinary approach with SEM, TEM and X-ray, volcanic gases were shown to cause degradation on epicuticular and epistomatal waxes. Significant statistical variations of ultrastructural components of the cuticle, with 30 measurements, including total thickness of the cuticle, and details and proportions of all different layers, and use of confidence interval, revealed a high degree of sensitivity of Aleppo pine to this extreme environment. In the present study, non-significant thickness variations of the cell wall plus cuticle among current- and first-year-old needles of both fumigated and non fumigated trees have been found. However, at the ultrastructural level, significant variations in cell wall and total cuticle thickness, especially within the three zones of B1 fibrillar layer, revealed different equilibria for each of the four types of material. Using energy dispersive X-ray microanalysis, no sulphur was found in either cuticle or epidermal cells, but the presence of H2S in the fumarole gas is suspected to cause indirect and/or direct cuticle alterations of wax structure. Ultrastructural characters of plant cuticles related to emission of volcanic gases during the geological past are also discussed. Among these considerations, an identification key enabling distinction between non fumigated and fumigated materials with 9 characters, provides a good tool detecting the influence of volcanism for extant and fossil plants.
    Description: Published
    Description: 1–17
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: Campi Flegrei ; Volcanic gases ; Pinus halepensis ; Hydrogen sulphide (H2S) ; 04. Solid Earth::04.03. Geodesy::04.03.06. Measurements and monitoring ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
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  • 49
    Publication Date: 2017-04-04
    Description: The chemistry of Yellowstone fumarole gases shows the existence of two component waters, type MC, influenced by the addition of deep mantle fluid, and type CC, influenced by crustal interactions (CC). MC is high in 3He/4He (22 Ra) and low in 4He/40Ar ( 1), reflecting input of deep mantle components. The other water is characterized by 4He concentrations 3–4 orders of magnitude higher than air-saturated meteoric water (ASW). These high He concentrations originate through circulation in Pleistocene volcanic rocks, as well as outgassing of Tertiary and older (including Archean) basement, some of which could be particularly rich in uranium, a major 4He source. Consideration of CO2–CH4–CO–H2O–H2 gas equilibrium reactions indicates equilibration temperatures from 170 C to 310 C. The estimated temperatures highly correlate with noble-gas variations, suggesting that the two waters differ in temperature. Type CC is 170 C whereas the MC is hotter, at 340 C. This result is similar to models proposed by previous studies of thermal water chemistry. However, instead of mixing the deep hot component simply with cold, meteoric waters we argue that addition of a 4He-rich component, equilibrated at temperatures around 170 C, is necessary to explain the range in fumarole gas chemistry.
    Description: Published
    Description: 265–278
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: hydrothermal fluids ; Yellowstone Plateau ; 04. Solid Earth::04.03. Geodesy::04.03.06. Measurements and monitoring ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
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  • 50
    Publication Date: 2017-04-04
    Description: In the present study the attenuation mechanism of seismic wave energy in and around the source area of the Chamoli earthquake of 29th March 1999 is estimated using the aftershock data. Most of the analyzed events are from the vicinity of the Main Central Thrust (MCT), which is a well-defined tectonic discontinuity in the Himalayas. Separation of intrinsic (Q 1 i ) and scattering (Q 1 s ) attenuation coefficient is done over the frequencies 1, 2, 4, 8 and 16 Hz using Multiple Lapse Time Window Analysis (MLTWA) method. It is observed that S-waves and their coda are primarily attenuated due to scattering attenuation and seismic albedo is very high at all the frequencies. A comparison of attenuation characteristics obtained using these aftershock data with those obtained using data of general seismicity of this region reveal that at lower frequencies both intrinsic and scattering attenuation for Chamoli was much higher compared to those for Garwhal-Kumaun region using general seismicity data. At higher frequencies intrinsic attenuation for Chamoli is lower than and scattering attenuation is comparable to those obtained using general seismicity data of Garwhal-Kumaun region.
    Description: A partial support has been given by Italy INGV-DPC (Istituto Nazionale di Geofisica e Vulcanologia and Dipartimento di Protezione Civile) Projects UNREST and SPEED, and by Italy’s Ministry of Education PRIN project (Seismic Hazard in Central Apennines, UR Del Pezzo).
    Description: Published
    Description: 446-454
    Description: 1T. Geodinamica e interno della Terra
    Description: 4T. Fisica dei terremoti e scenari cosismici
    Description: JCR Journal
    Description: restricted
    Keywords: MLTWA ; Intrinsic attenuation ; Scattering attenuation ; Chamoli Himalayas ; Himalayas ; 04. Solid Earth::04.06. Seismology::04.06.07. Tomography and anisotropy ; 04. Solid Earth::04.06. Seismology::04.06.09. Waves and wave analysis ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics
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  • 51
    Publication Date: 2017-04-04
    Description: In this work we show that the main springs of the central Apennine transport a total amount of heat of ∼2.2 109 J s−1. Most of this heat (57%) is the result of geothermal warming while the remaining 43% is due to gravitational potential energy dissipation. This result indicates that a large area of the central Apennines is very hot with heat flux values 4300 mWm−2. These values are higher than those measured in the magmatic and famously geothermal provinces of Tuscany and Latium and about 1/3 of the total heat discharged at Yellowstone. This finding is surprising because the central Apennines have been thought to be a relatively cold area. Translated by CO2 rich fluids, this heat anomaly suggests the existence of a thermal source such as a large magmatic intrusion at depth. Recent tomographic images of the area support the presence of such an intrusion visible as a broad negative velocity anomaly in seismic waves. Our results indicate that the thermal regime of tectonically active areas of the Earth, where meteoric waters infiltrate and deeply circulate, should be revised on the basis of mass and energy balances of the groundwater systems.
    Description: Published
    Description: 65–74
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: heat flux ; CO2 Earth degassing ; central Apennine ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
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  • 52
    Publication Date: 2017-04-04
    Description: Passive samplers were used to measure the atmospheric concentrations of SO2 naturally emitted at three volcanoes in Italy (Etna, Vulcano and Stromboli) and of H2S naturally emitted at three volcanic/geothermal areas in Greece (Milos, Santorini and Nisyros). The measured concentrations and dispersion patterns varied with the strength of the source (open conduits or fumaroles), the meteorological conditions and the area topography. At Etna, Vulcano and Stromboli, SO2 concentrations reach values that are dangerous to people affected by bronchial asthma or lung diseases (〉1000 μg m−3). H2S values measured at Nisyros also exceed the limit considered safe for the same group of people (〉3000 μg m−3). The data obtained using passive samplers represent time-averaged values over periods from a few days up to 1 month, and hence concentrations probably reached much higher peak values that were potentially also dangerous to healthy people. The present study provides evidence of a peculiar volcanic risk associated with tourist exploitation of active volcanic areas. This risk is particularly high at Mt. Etna, where the elderly and people in less-than-perfect health can easily reach areas with dangerous SO2 concentrations via a cableway and off-road vehicles
    Description: Published
    Description: 1-13
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: Sulphur dioxide ; Hydrogen sulphide ; Volcanic risks ; Gas hazard ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
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  • 53
    Publication Date: 2017-04-04
    Description: Commenton “CO2 variabilityinmid-oceanridge basalts fromsyn-emplacementdegassing: Constraintsoneruptiondynamics”
    Description: Published
    Description: 251-253
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: restricted
    Keywords: non-equilibrium degassing, modeling, CO2, bubble growth, MORB, gas geochemistry ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.04. Thermodynamics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 54
    Publication Date: 2017-04-04
    Description: A better understanding of degassing processes at open-vent basaltic volcanoes requires collection of new datasets of H2O–CO2–SO2 volcanic gas plume compositions, which acquisition has long been hampered by technical limitations. Here, we use the MultiGAS technique to provide the best-documented record of gas plume discharges from Stromboli volcano to date. We show that Stromboli's gases are dominated by H2O (48–98 mol%; mean, 80%), and by CO2 (2–50 mol%; mean, 17%) and SO2 (0.2–14 mol%; mean, 3%). The significant temporal variability in our dataset reflects the dynamic nature of degassing process during Strombolian activity; which we explore by interpreting our gas measurements in tandem with the melt inclusion record of pre-eruptive dissolved volatile abundances, and with the results of an equilibrium saturation model. Comparison between natural (volcanic gas and melt inclusion) and modelled compositions is used to propose a degassing mechanism for Stromboli volcano, which suggests surface gas discharges are mixtures of CO2-rich gas bubbles supplied from the deep (〉 4 km) plumbing system, and gases released from degassing of dissolved volatiles in the magma filling the upper conduits. The proposed mixing mechanism offers a viable and general model to account for composition of gas discharges at all volcanoes for which petrologic evidence of CO2 fluxing exists. A combined volcanic gas-melt inclusion-modelling approach, as used in this paper, provides key constraints on degassing processes, and should thus be pursued further.
    Description: Published
    Description: 195-204
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: JCR Journal
    Description: reserved
    Keywords: volcanic degassing ; Stromboli ; volcanic gases ; CO2 fluxing ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 55
    Publication Date: 2017-04-04
    Description: In addition to rhythmic slug-driven Strombolian activity, Stromboli volcano occasionally produces discrete explosive paroxysms (2 per year on average for the most frequent ones) that constitute a major hazard and whose origin remains poorly elucidated. Partial extrusion of the volatile-rich feeding basalt as aphyric pumice during these events has led to consider their triggering by the fast ascent of primitive magma blobs from possibly great depth. Here I examine and discuss the alternative hypothesis that most of the paroxysms could be triggered and driven by the fast upraise of CO2-rich gas pockets generated by bubble foam growth and collapse in the sub-volcano plumbing system. Data for the SO2 and CO2 crater plume emissions are used to show that Stromboli's feeding magma may originally contain as much as 2 wt.% of carbon dioxide and early coexists with an abundant CO2-rich gas phase with high CO2/SO2 molar ratio (≥60 at 10 km depth below the vents, compared to ∼7 in time-averaged crater emissions). Pressure-related modelling indicates that the time-averaged crater gas composition and output are well accounted for by closed system decompression of the basalt–gas mixture until the volcano–crust interface (∼3 km depth), followed by open degassing and crystallization in the volcano conduits. However, both the low viscosity and high vesicularity of the basaltic magma permit bubble segregation and bubble foam growth at deep sill-like feeder discontinuities and at shallower physical boundaries (such as the volcano–crust interface) where the gasrich aphyric basalt interacts with the unerupted crystal-rich and viscous magma drained back from the volcano conduits. Gas pressure build-up and bubble foam collapse at these boundaries will intermittently trigger the sudden upraise of CO2-rich gas blobs that constitute the main driving force of the paroxysms. Deeper-sourced gas blobs, driving the most powerful explosions, will be the richest in CO2 and have highest CO2/SO2 ratios. This mechanism is shown to account well for the dynamic, seismic and petrologic features of Stromboli's paroxysms and, hence, to provide a potential alternative interpretation for their genesis and their forecasting. Enhanced bubble foam leakage prior to a paroxysm, or foam emptying in several steps, should lead indeed to precursory upstream of CO2-rich gas and increasing CO2/SO2 ratio in crater plume emissions. The recent detection of such signals prior to two explosions in December 2006 and March 2007 strongly supports this expectation and the model proposed in this study.
    Description: Published
    Description: 363–374
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: JCR Journal
    Description: reserved
    Keywords: basaltic volcanoes ; magma degassing ; explosive paroxysms ; CO2 ; gas bubbles ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 56
    Publication Date: 2021-09-03
    Description: Gas hazard was evaluated in the three most important cold gas emission zones on the flanks of the quiescent Colli Albani volcano. These zones are located above structural highs of the buried carbonate basement which represents the main regional aquifer and the main reservoir for gas rising from depth. All extensional faults affecting the limestone reservoir represent leaking pathways along which gas rises to the surface and locally accumulates in shallow permeable horizons forming pressurized pockets that may produce gas blowout when reached by wells. The gas, mainly composed by CO2 (〉90 vol.%), contains appreciable quantities of H2S (0.35-6 vol.%), and both represent a potentially high local hazard. Both gases are denser than air and accumulate near ground where they may reach hazardous concentrations, and actually lethal accidents frequently occur to animals watering at local ponds. In order to evaluate the rate of degassing and the related hazard, CO2 and H2S diffuse soil flux surveys have been repeatedly carried out by accumulation chamber. The viscous gas flux of some important discrete emissions has been also evaluated and the CO2 and H2S air concentration measured by portable devises and by Tunable Diode Laser profiles. The minimum potential lethal concentration of the two gases (250 ppm for H2S and 8 vol.% for CO2) is 320 times higher for CO2, whereas the CO2/H2S concentration ratio in the emitted natural gas is significantly lower (15-159). This explains why H2S reaches hazardous, even lethal, concentrations more frequently than CO2. A relevant hazard exists for both gases in the depressed zones (channels, excavations) particularly in the non-windy early hours of the day.
    Description: Published
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: partially_open
    Keywords: gas hazard ; hydrogen sulfide ; carbon dioxide ; Colli Albani volcano ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 57
    Publication Date: 2022-06-10
    Description: Between January 2011 and April 2012, Santorini volcano (Greece) experienced a period of unrest characterised by the onset of detectable seismicity and caldera-wide uplift. This episode of inflation represented the first sizeable intrusion of magma beneath Santorini in the past 50 years. We employ a new approach using 222 Rn– δ 13 C systematics to identify and quantify the source of diffuse degassing at Santorini during the period of renewed activity. Soil CO 2 flux measurements were made across a network of sites on Nea Kameni between September 2010 and January 2012. Gas samples were collected in April and September 2011 for isotopic analysis of CO 2 ( δ 13 C), and radon detectors were deployed during September 2011 to measure ( 222 Rn). Our results reveal a change in the pattern of degassing from the summit of the volcano (Nea Kameni) and suggest an increase in diffuse CO 2 emissions between September 2010 and January 2012. High-CO 2 -flux soil gas samples have δ 13 C ∼ 0 .Using this value and other evidence from the literature we conclude that these CO 2 emissions from Santorini were a mixture between CO 2 sourced from magma, and CO 2 released by the thermal or metamorphic breakdown of crustal limestone. We suggest that this mixing of magmatic and crustal carbonate sources may account more broadly for the typical range of δ 13 CvaluesofCO 2 (from ∼− 4 to ∼+ 1 )in diffuse volcanic and fumarole gas emissions around the Mediterranean, without the need to invoke unusual mantle source compositions. At Santorini a mixing model involving magmatic CO 2 (with δ 13 C of − 3 ± 2 and elevated ( 222 Rn)/CO 2 ratios ∼ 10 5 –10 6 Bqkg − 1 )andCO 2 released from decarbonation of crustal limestone (with ( 222 Rn)/CO 2 ∼ 30–300 Bqkg − 1 ,and δ 13 Cof + 5 ) can account for the δ 13 C and ( 222 Rn)/CO 2 characteristics of the ‘high flux’ gas source. This model suggests ∼ 60% of the carbon in the high flux deep CO 2 end member is of magmatic origin. This combination of δ 13 Cand( 222 Rn) measurements has potential to quantify magmatic and crustal contributions to the diffuse outgassing of CO 2 in volcanic areas, especially those where breakdown of crustal limestone is likely to contribute significantly to the CO 2 flux
    Description: Published
    Description: 180-190
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: volcanic unrest ; soil gas measurements ; carbon isotopic analysis ; magmatic degassing ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 58
    Publication Date: 2022-11-23
    Description: An underwater geomorphological survey along the coasts of six Cycladic islands (Sifnos, Antiparos, Paros, Naxos, Iraklia and Keros) revealed widespread evidence of a recent 30–40 cm submergence, part of which may have seismic origin. Comparison with information reported from earthquakes having affected the area suggests that at least part of the recent submergence might be an effect of the 1956 Amorgos earthquake. Modelling of the co-seismic and short-term post-seismic effects of the earthquake revealed that part of the observed subsidence may be explained in some of the islands by a fast post-seismic relaxation of a low-viscosity layer underlying the seismogenic zone. However far-field observations are underestimated by our model, and may be affected by a wider deformation field induced by the largest aftershock of the Amorgos sequence, or by other earthquakes.
    Description: Published
    Description: 27-40
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: JCR Journal
    Description: restricted
    Keywords: tidal notch ; sea level change ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 59
    Publication Date: 2024-05-09
    Description: Copahue volcano is part of the Caviahue–Copahue Volcanic Complex (CCVC),which is located in the southwestern sector of the Caviahue volcano-tectonic depression (Argentina–Chile). This depression is a pull-apart basin accommodating stresses between the southern Liquiñe–Ofqui strike slip and the northern Copahue–Antiñir compressive fault systems, in a back-arc setting with respect to the Southern Andean Volcanic Zone. In this study, we present chemical (inorganic and organic) and isotope compositions (δ13C-CO2, δ15N, 3He/4He, 40Ar/36Ar, δ13C-CH4, δD-CH4, and δD-H2O and δ18O-H2O) of fumaroles and bubbling gases of thermal springs located at the foot of Copahue volcano sampled in 2006, 2007 and 2012. Helium isotope ratios, the highest observed for a Southern American volcano (R/Ra up to 7.94), indicate a non-classic arc-like setting, but rather an extensional regime subdued to asthenospheric thinning. δ13C-CO2 values (from −8.8‰ to −6.8‰ vs. V-PDB), δ15N values (+5.3‰ to +5.5‰ vs. Air) and CO2/3He ratios (from 1.4 to 8.8 × 109) suggest that the magmatic source is significantly affected by contamination of subducted sediments. Gases discharged from the northern sector of the CCVC show contribution of 3He-poor fluids likely permeating through local fault systems. Despite the clear mantle isotope signature in the CCVC gases, the acidic gas species have suffered scrubbing processes by a hydrothermal system mainly recharged by meteoric water. Gas geothermometry in the H2O-CO2-CH4-CO-H2 system suggests that CO and H2 re-equilibrate in a separated vapor phase at 200°–220 °C. On the contrary, rock–fluid interactions controlling CO2, CH4 production from Sabatier reaction and C3H8 dehydrogenation seem to occur within the hydrothermal reservoir at temperatures ranging from 250° to 300 °C. Fumarole gases sampled in 2006–2007 show relatively low N2/He and N2/Ar ratios and high R/Ra values with respect to those measured in 2012. Such compositional and isotope variations were likely related to injection of mafic magma that likely triggered the 2000 eruption. Therefore, changes affecting the magmatic systemhad a delayed effect on the chemistry of the CCVC gases due to the presence of the hydrothermal reservoir. However, geochemical monitoring activities mainly focused on the behavior of inert gas compounds (N2 and He), should be increased to investigate the mechanism at the origin of the unrest started in 2011.
    Description: Published
    Description: 44–56
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: Fluid geochemistry ; Copahue volcano ; Fumarolic fluid ; Hydrothermal reservoir ; Volcanic unrest ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 60
    Publication Date: 2024-05-09
    Description: Measurements of soil fluxes of hydrothermal gases, with special emphasis on C6H6, as well as chemical composition of mono-aromatic compounds in fumaroles and air, were carried out in April 2012 at the Solfatara crater (Campi Flegrei, Southern Italy) to investigate the distribution and behavior of these species as they migrate through the soil from their deep source to the atmosphere. Soil fluxes of CO2, CH4 and C6H6 exhibit good spatial correlation, suggesting that diffuse degassing is mainly controlled by local fractures. The calculated total output of diffuse C6H6 from Solfatara is 0.10 kg day 1, whereas fluxes of CO2 and CH4 are 79 103 and 1.04 kg day 1, respectively. A comparison between soil gas fluxes and fumarole composition reveals that within the crater soil CH4 is significantly affected by oxidation processes, which are more efficient for low gas fluxes, being dependent on the residence time of the uprising hydrothermal gases at shallow depth. Benzene degradation, mainly proceeding through oxidation via benzoate, seems to be strongly controlled by the presence of a shallow SO2 4 -rich aquifer located in the central and southwestern sectors of the crater, suggesting that the process is particularly efficient when SO2 4 acts as terminal electron acceptor (SO4 reduction). Relatively high C6H6/C7H8 ratios, typical of hydrothermal fluids, were measured in air close to the main fumarolic field of Solfatara crater. Here, C6H6 concentrations, whose detection limit is 0.1 lgm 3, are more than one order of magnitude higher than the limit value for ambient air (5 lgm 3). This suggests that hydrothermal fluids have a strong impact on air quality in the immediate surroundings of the fumarolic vents. Significant concentrations of endogenous mono-aromatics were also detected in air samples collected from the northern and western sides of the crater, where these gas compounds are mostly fed by diffuse degassing through the crater bottom soil.
    Description: Published
    Description: 142–153
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: hydrothermal gases ; Solfatara crater ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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