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  • 1
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    Wiley
    In:  EPIC3Paleoceanography, Wiley, 32, pp. 304-317, ISSN: 0883-8305
    Publikationsdatum: 2017-06-12
    Repository-Name: EPIC Alfred Wegener Institut
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  • 2
    Publikationsdatum: 2017-09-13
    Beschreibung: This paper investigates new observations from the poorly understood region between the Kara and Laptev Seas in the Eastern Arctic Ocean. We discuss relevant circulation features including riverine freshwater, Atlantic-derived water, and polynya-formed dense water, emphasize Vilkitsky Strait (VS) as an important Kara Sea gateway, and analyze the role of the adjacent 250 km-long submarine Vilkitsky Trough (VT) for the Arctic boundary current. Expeditions in 2013 and 2014 operated closely spaced hydrographic transects and 1 year-long oceanographic mooring near VT’s southern slope, and found persistent annually averaged flow of 0.2 m s21 toward the Nansen Basin. The flow is nearly barotropic from winter through early summer and becomes surface intensified with maximum velocities of 0.35 m s21 from August to October. Thermal wind shear is maximal above the southern flank at 30 m depth, in agreement with basinward flow above VT’s southern slope. The subsurface features a steep front separating warm (–0.58C) Atlantic-derived waters in central VT from cold (〈–1.58C) shelf waters, which episodically migrates across the trough indicated by current reversals and temperature fluctuations. Shelf-transformed waters dominate above VT’s slope, measuring near-freezing temperatures throughout the water column at salinities of 34–35. These dense waters are vigorously advected toward the Eurasian Basin and characterize VT as a conduit for near-freezing waters that could potentially supply the Arctic Ocean’s lower halocline, cool Atlantic water, and ventilate the deeper Arctic Ocean. Our observations from the northwest Laptev Sea highlight a topographically complex region with swift currents, several water masses, narrow fronts, polynyas, and topographically channeled storms.
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  • 3
    Publikationsdatum: 2017-09-18
    Beschreibung: The mechanisms causing widespread flow acceleration of Jakobshavn Isbræ, West Greenland, remain unclear despite an abundance of observations and modeling studies. Here we simulate the glacier's evolution from 1985 to 2016 using a three-dimensional thermomechanical ice flow model. The model captures the timing and 90% of the observed changes by forcing the calving front. Basal drag in the trough is low, and lateral drag balances the ice stream's driving stress. The calving front position is the dominant control on changes of Jakobshavn Isbræ since the ice viscosity in the shear margins instantaneously drops in response to the stress perturbation caused by calving front retreat, which allows for widespread flow acceleration. Gradual shear margin warming contributes 5 to 10% to the total acceleration. Our simulations suggest that the glacier will contribute to eustatic sea level rise at a rate comparable to or higher than at present.
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  • 4
    Publikationsdatum: 2017-12-01
    Beschreibung: Greenland's bed topography is a primary control on ice flow, grounding line migration, calving dynamics and subglacial drainage. Moreover, fjord bathymetry regulates the penetration of warm Atlantic Water (AW) that rapidly melts and undercuts Greenland's marine-terminating glaciers. Here, we present a new compilation of Greenland bed topography that assimilates seafloor bathymetry and ice thickness data through a mass conservation (MC) approach. A new 150-m horizontal resolution bed topography/bathymetric map of Greenland is constructed with seamless transitions at the ice/ocean interface, yielding major improvements over previous datasets, particularly in the marine-terminating sectors of northwest and southeast Greenland. Our map reveals the total sea level potential of the Greenland Ice Sheet is 7.42±0.05 m, which is 7 cm greater than previous estimates. Furthermore, it explains recent calving front response of numerous outlet glaciers and reveals new pathways by which AW can access glaciers with marine-based basins, thereby highlighting sectors of Greenland that are most vulnerable to future oceanic forcing.
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  • 5
    Publikationsdatum: 2017-05-04
    Beschreibung: We present a simulation of Antarctic iceberg drift and melting that includes small, medium-sized, and giant tabular icebergs with a realistic size distribution. For the first time, an iceberg model is initialized with a set of nearly 7000 observed iceberg positions and sizes around Antarctica. The study highlights the necessity to account for larger and giant icebergs in order to obtain accurate melt climatologies. We simulate drift and lateral melt using iceberg-draft averaged ocean currents, temperature, and salinity. A new basal melting scheme, originally applied in ice shelf melting studies, uses in situ temperature, salinity, and relative velocities at an iceberg's bottom. Climatology estimates of Antarctic iceberg melting based on simulations of small (≤ 2.2 km), 'small-to-medium'-sized (≤ 10 km), and small-to-giant icebergs (including icebergs 〉 10 km) exhibit differential characteristics: successive inclusion of larger icebergs leads to a reduced seasonality of the iceberg meltwater flux and a shift of the mass input to the area north of 58 °S, while less meltwater is released into the coastal areas. This suggests that estimates of meltwater input solely based on the simulation of small icebergs introduce a systematic meridional bias; they underestimate the northward mass transport and are, thus, closer to the rather crude treatment of iceberg melting as coastal runoff in models without an interactive iceberg model. Future ocean simulations will benefit from the improved meridional distribution of iceberg melt, especially in climate change scenarios where the impact of iceberg melt is likely to increase due to increased calving from the Antarctic ice sheet.
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  • 6
    Publikationsdatum: 2017-09-25
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  • 7
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    Wiley
    In:  EPIC3Global Biogeochemical Cycles, Wiley, ISSN: 0886-6236
    Publikationsdatum: 2017-10-27
    Repository-Name: EPIC Alfred Wegener Institut
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  • 8
    Publikationsdatum: 2019-12-03
    Beschreibung: The Southern Hemisphere Antarctic stratosphere experienced two noteworthy events in 2015: a significant injection of sulfur from the Calbuco volcanic eruption in Chile in April, and a record-large Antarctic ozone hole in October and November. Here, we quantify Calbuco's influence on stratospheric ozone depletion in austral spring 2015 using observations and an earth system model. We analyze ozonesondes, as well as data from the Microwave Limb Sounder. We employ the Community Earth System Model, version 1, with the Whole Atmosphere Community Climate Model (CESM1(WACCM)) in a specified dynamics setup, which includes calculations of volcanic effects. The Cloud Aerosol Lidar with Orthogonal Polarization data indicate enhanced volcanic liquid sulfate 532 nm backscatter values as far poleward as 68°S during October and November (in broad agreement with WACCM). Comparison of the location of the enhanced aerosols to ozone data supports the view that aerosols played a major role in increasing the ozone hole size, especially at pressure levels between 150 and 100 hPa. Ozonesonde vertical ozone profiles from the sites of Syowa, South Pole, and Neumayer, display the lowest individual October or November measurements at 150 hPa since the 1991 Mt. Pinatubo eruption period, with Davis showing similarly low values, but no available 1990s data. The analysis suggests that under the cold conditions ideal for ozone depletion, stratospheric volcanic aerosol particles from the moderate-magnitude eruption of Calbuco in 2015 greatly enhanced austral ozone depletion, particularly at 55–68°S, where liquid binary sulfate aerosols have a large influence on ozone concentrations.
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  • 9
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    Wiley
    In:  EPIC3Geophysical Research Letters, Wiley, 44(13), pp. 6974-6983, ISSN: 0094-8276
    Publikationsdatum: 2018-01-11
    Beschreibung: Near-surface air temperatures close to 0°C were observed in situ over sea ice in the central Arctic during the last three winter seasons. Here we use in situ winter (December–March) temperature observations, such as those from Soviet North Pole drifting stations and ocean buoys, to determine how common Arctic winter warming events are. Observations of winter warming events exist over most of the Arctic Basin. Temperatures exceeding -5°C were observed during 〉30% of winters from 1954 to 2010 by North Pole drifting stations or ocean buoys. Using the ERA-Interim record (1979–2016), we show that the North Pole (NP) region typically experiences 10 warming events (T2m 〉 10°C) per winter, compared with only five in the Pacific Central Arctic (PCA). There is a positive trend in the overall duration of winter warming events for both the NP region (4.25 days/decade) and PCA (1.16 days/decade), due to an increased number of events of longer duration.
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  • 10
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    Wiley
    In:  EPIC3Journal of Geophysical Research-Earth Surface, Wiley, 122, pp. 1619-1634, ISSN: 0148-0227
    Publikationsdatum: 2018-08-30
    Beschreibung: Retrogressive thaw slumps (RTSs) are among the most active landforms in the Arctic; their number has increased significantly over the past decades. While processes initiating discrete RTSs are well identified, the major terrain controls on the development of coastal RTSs at a regional scale are not yet defined. Our research reveals the main geomorphic factors that determine the development of RTSs along a 238 km segment of the Yukon Coast, Canada. We (1) show the current extent of RTSs, (2) ascertain the factors controlling their activity and initiation, and (3) explain the spatial differences in the density and areal coverage of RTSs. We mapped and classified 287 RTSs using high-resolution satellite images acquired in 2011. We highlighted the main terrain controls over their development using univariate regression trees model. Coastal geomorphology influenced both the activity and initiation of RTSs: active RTSs and RTSs initiated after 1972 occurred primarily on terrains with slope angles greater than 3.9° and 5.9°, respectively. The density and areal coverage of RTSs were constrained by the volume and thickness of massive ice bodies. Differences in rates of coastal change along the coast did not affect the model. We infer that rates of coastal change averaged over a 39 year period are unable to reflect the complex relationship between RTSs and coastline dynamics. We emphasize the need for large-scale studies of RTSs to evaluate their impact on the ecosystem and to measure their contribution to the global carbon budget.
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  • 11
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    Wiley
    In:  EPIC3Tectonics, Wiley, 36, pp. 229-240, ISSN: 0278-7407
    Publikationsdatum: 2019-07-17
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  • 12
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    Wiley
    In:  EPIC3Journal of Geophysical Research-Oceans, Wiley, 122(2), pp. 914-940, ISSN: 2169-9275
    Publikationsdatum: 2017-05-30
    Repository-Name: EPIC Alfred Wegener Institut
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  • 13
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    Wiley
    In:  EPIC3Geochemistry Geophysics Geosystems, Wiley, 18(1), pp. 457-470, ISSN: 1525-2027
    Publikationsdatum: 2018-02-02
    Beschreibung: Digital grids of basement age of the world’s oceans are essential for modern geodynamic and paleoceanographic studies. Any such grid is built using a plate kinematic model, whose accuracy and reli- ability directly influence the accuracy and reliability of the grid. We present a seafloor age grid for the South Atlantic based on a recent high-resolution plate kinematic model. The grid is built from a data set of points whose ages are defined in or for the plate kinematic model, incorporating breaks at tectonic boundaries like fracture zones where the age function is discontinuous. We compare predictions of the new grid and of a previously published one, which is based on an older plate kinematic model, to magnetic isochron pick data sets. The comparison shows the new grid to provide a more reliable depiction of seafloor age in the South Atlantic. Numerical estimates of the new grid’s uncertainty are determined by interpolation between (1) misfits at grid cells coinciding with magnetic isochron ages, (2) misfits implied by locational uncertainties in predicted isochrons propagated from uncertainties in the plate kinematic model, and (3) by the proxim- ities of cells to fracture zone traces or ridge-jump scars. Estimated total uncertainty is 〈10 My for 94% of the grid and 〈5 My for 72%, but much larger in areas where magnetic anomaly data are scarce (such as the Cretaceous Normal Superchron) and in the vicinity of long-offset fracture zones.
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  • 14
    Publikationsdatum: 2018-08-10
    Beschreibung: The deep southern component water (SCW), comprising Lower Circumpolar Deep Water (LCDW) and Antarctic Bottom Water (AABW), is a major component of the global oceanic circulation. It has been suggested that the deep Atlantic water mass structure changed significantly during the last glacial/interglacial cycle. However, deep SCW source-proximal records remain sparse. Here we present three coherent deep SCW paleocurrent records from the deep Argentine continental margin shedding light on deep water circulation and deep SCW flow strength in the Southwest Atlantic since the Last Glacial Maximum (LGM). Based on increased sortable silt values, we propose enhanced deep SCW flow strength from 14 to 10 cal ka B.P. relative to the early deglacial/LGM and the Holocene. We propose a direct influence of deep northern component water (NCW) on deep SCW flow strength due to vertical narrowing of deep SCW spreading, concurrent with a migration of the high-energetic LCDW/AABW interface occupying our core sites. We suggest a shoaled NCW until 13 cal ka B.P., thereby providing space for deep SCW spreading that resulted in reduced carbonate preservation at our core sites. Increased carbonate content from 13 cal ka B.P. indicates that the NCW expanded changing deep water properties at our core sites in the deep Southwest Atlantic. However, southern sourced terrigenous sediments continued to be deposited at our core sites, suggesting that deep SCW flow was uninterrupted along the Argentine continental margin since the LGM.
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  • 15
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    Wiley
    In:  EPIC3Journal of Geophysical Research-Biogeosciences, Wiley, ISSN: 0148-0227
    Publikationsdatum: 2019-03-31
    Beschreibung: Measurements of late springtime nutrient concentrations in Arctic waters are relatively rare due to the extensive sea ice cover that makes sampling difficult. During the SUBICE cruise in May-June 2014, an extensive survey of hydrography and pre-bloom nutrient concentrations was conducted in the Chukchi Sea. Cold (〈 -1.5°C) winter water was prevalent throughout the Chukchi Sea shelf, and the water column was weakly stratified. Nitrate (NO3-) concentration averaged 12.6±1.92 µM in surface waters and 14.0±1.91 µM near the bottom and was significantly correlated with salinity. The highest NO3- concentrations were associated with winter water within the Central Channel flow path. NO3- concentrations were much reduced near the northern shelfbreak within the upper halocline waters of the Canada Basin and along the eastern side of the shelf near the Alaskan coast. Net community production (NCP), estimated as the difference in depth-integrated NO3- content between spring (this study) and summer (historical), varied from 28-38 g C m-2 a-1. This is much lower than previous NCP estimates using NO3- concentrations from the southeastern Bering Sea as a baseline. These results demonstrate the importance of using local profiles of NO3- measured as close to the beginning of the spring bloom as possible when estimating NCP.
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  • 16
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    In:  EPIC3Tectonics, Wiley, 36, pp. 2846-2862, ISSN: 0278-7407
    Publikationsdatum: 2018-03-04
    Beschreibung: The Eger Rift is an active element of the European Cenozoic Rift System associated with intense Cenozoic intraplate alkaline volcanism and system of sedimentary basins. The intracontinental Cheb Basin at its western part displays geodynamic activity with fluid emanations, persistent seismicity, Cenozoic volcanism, and neotectonic crustal movements at the intersections of major intraplate faults. In this paper, we study detailed geometry of the crust/mantle boundary and its possible origin in the western Eger Rift. We review existing seismic and seismological studies, provide new interpretation of the reflection profile 9HR, and supplement it by new results from local seismicity. We identify significant lateral variations of the high-velocity lower crust and relate them to the distribution and chemical status of mantle-derived fluids and to xenolith studies from corresponding depths. New interpretation based on combined seismic and isotope study points to a local-scale magmatic emplacement at the base of the continental crust within a new rift environment. This concept of magmatic underplating is supported by detecting two types of the lower crust: a high-velocity lower crust with pronounced reflectivity and a high-velocity reflection-free lower crust. The character of the underplated material enables to differentiate timing and tectonic setting of two episodes with different times of origin of underplating events. The lower crust with high reflectivity evidences magmatic underplating west of the Eger Rift of the Late Variscan age. The reflection-free lower crust together with a strong reflector at its top at depths of ~28–30 km forms a magma body indicating magmatic underplating of the late Cenozoic (middle and upper Miocene) to recent. Spatial and temporal relations to recent geodynamic processes suggest active magmatic underplating in the intracontinental setting.
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  • 17
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    In:  EPIC3Geophysical Research Letters, Wiley, 44, ISSN: 0094-8276
    Publikationsdatum: 2019-07-17
    Beschreibung: Antarctica is the largest reservoir of ice on Earth. Understanding its ice sheet dynamics is crucial to unraveling past global climate change and making robust climatic and sea level predictions. Of the basic parameters that shape and control ice flow, the most poorly known is geothermal heat flux. Direct observations of heat flux are difficult to obtain in Antarctica, and until now continent-wide heat flux maps have only been derived from low-resolution satellite magnetic and seismological data. We present a high-resolution heat flux map and associated uncertainty derived from spectral analysis of the most advanced continental compilation of airborne magnetic data. Small-scale spatial variability and features consistent with known geology are better reproduced than in previous models, between 36% and 50%. Our high-resolution heat flux map and its uncertainty distribution provide an important new boundary condition to be used in studies on future subglacial hydrology, ice sheet dynamics, and sea level change.
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  • 18
    Publikationsdatum: 2017-12-19
    Beschreibung: The evidence from both data and models indicates that specific equilibrium climate sensitivity S[X]—the global annual mean surface temperature change (ΔTg) as a response to a change in radiative forcing X (ΔR[X])—is state dependent. Such a state dependency implies that the best fit in the scatterplot of ΔTg versus ΔR[X] is not a linear regression but can be some nonlinear or even nonsmooth function. While for the conventional linear case the slope (gradient) of the regression is correctly interpreted as the specific equilibrium climate sensitivity S[X], the interpretation is not straightforward in the nonlinear case. We here explain how such a state-dependent scatterplot needs to be interpreted and provide a theoretical understanding—or generalization—how to quantify S[X] in the nonlinear case. Finally, from data covering the last 2.1 Myr we show that—due to state dependency—the specific equilibrium climate sensitivity which considers radiative forcing of CO2 and land ice sheet (LI) albedo, math formula, is larger during interglacial states than during glacial conditions by more than a factor 2.
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  • 19
    Publikationsdatum: 2018-01-09
    Beschreibung: We present vertically resolved observations of aerosol composition during pristine summertime Arctic background conditions. The methansulfonic acid (MSA)-to-sulfate ratio peaked near the surface (mean 0.10), indicating a contribution from ocean-derived biogenic sulfur. Similarly, the organic aerosol (OA)-to-sulfate ratio increased toward the surface (mean 2.0). Both MSA-to-sulfate and OA-to-sulfate ratios were significantly correlated with FLEXPART-WRF-predicted air mass residence time over open water, indicating marine-influenced OA. External mixing of sea salt aerosol from a larger number fraction of organic, sulfate, and amine-containing particles, together with low wind speeds (median 4.7 m s−1), suggests a role for secondary organic aerosol formation. Cloud condensation nuclei concentrations were nearly constant (∼120 cm−3) when the OA fraction was 〈60% and increased to 350 cm−3 when the organic fraction was larger and residence times over open water were longer. Our observations illustrate the importance of marine-influenced OA under Arctic background conditions, which are likely to change as the Arctic transitions to larger areas of open water.
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  • 20
    Publikationsdatum: 2018-01-11
    Beschreibung: Arctic sea ice has displayed significant thinning as well as an increase in drift speed in recent years. Taken together this suggests an associated rise in sea ice deformation rate. A winter and spring expedition to the sea ice covered region north of Svalbard–the Norwegian young sea ICE2015 expedition (N-ICE2015)—gave an opportunity to deploy extensive buoy arrays and to monitor the deformation of the first-year and secondyear ice now common in the majority of the Arctic Basin. During the 5 month long expedition, the ice cover underwent several strong deformation events, including a powerful storm in early February that damaged the ice cover irreversibly. The values of total deformation measured during N-ICE2015 exceed previously measured values in the Arctic Basin at similar scales: At 100 km scale, N-ICE2015 values averaged above 0.1 d-1, compared to rates of 0.08 d-1 or less for previous buoy arrays. The exponent of the power law between the deformation length scale and total deformation developed over the season from 0.37 to 0.54 with an abrupt increase immediately after the early February storm, indicating a weakened ice cover with more free drift of the sea ice floes. Our results point to a general increase in deformation associated with the younger and thinner Arctic sea ice and to a potentially destructive role of winter storms.
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  • 21
    Publikationsdatum: 2018-11-16
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  • 22
    Publikationsdatum: 2018-03-06
    Beschreibung: We investigate the impact of different CO2 levels and different subarctic gateway configurations on the surface temperatures during the latest Cretaceous using the Earth System Model COSMOS. The simulated temperatures are compared with the surface temperature reconstructions based on a recent compilation of the latest Cretaceous proxies. In our numerical experiments, the CO2 level ranges from 1 to 6 times the preindustrial (PI) CO2 level of 280 ppm. On a global scale, the most reasonable match between modeling and proxy data is obtained for the experiments with 3 to 5 × PI CO2 concentrations. However, the simulated low- (high-) latitude temperatures are too high (low) as compared to the proxy data. The moderate CO2 levels scenarios might be more realistic, if we take into account proxy data and the dead zone effect criterion. Furthermore, we test if the model-data discrepancies can be caused by too simplistic proxy-data interpretations. This is distinctly seen at high latitudes, where most proxies are biased toward summer temperatures. Additional sensitivity experiments with different ocean gateway configurations and constant CO2 level indicate only minor surface temperatures changes (〈~1°C) on a global scale, with higher values (up to ~8°C) on a regional scale. These findings imply that modeled and reconstructed temperature gradients are to a large degree only qualitatively comparable, providing challenges for the interpretation of proxy data and/or model sensitivity. With respect to the latter, our results suggest that an assessment of greenhouse worlds is best constrained by temperatures in the midlatitudes.
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  • 23
    Publikationsdatum: 2017-10-18
    Beschreibung: State-of-the-art Arctic Ocean mean sea surface (MSS) models and global geoid models (GGMs) are used to support sea ice freeboard estimation from satellite altimeters, as well as in oceanographic studies such as mapping sea level anomalies and mean dynamic ocean topography. However, errors in a given model in the high frequency domain, primarily due to unresolved gravity features, can result in errors in the estimated along-track freeboard. These errors are exacerbated in areas with a sparse lead distribution in consolidated ice pack conditions. Additionally model errors can impact ocean geostrophic currents, derived from satellite altimeter data, while remaining biases in these models may impact longer-term, multi-sensor oceanographic time-series of sea level change in the Arctic. This study focuses on an assessment of five state-of-the-art Arctic MSS models (UCL13/04, DTU15/13/10) and a commonly used GGM (EGM2008). We describe errors due to unresolved gravity features, inter-satellite biases, and remaining satellite orbit errors, and their impact on the derivation of sea ice freeboard. The latest MSS models, incorporating CryoSat-2 sea surface height measurements, show improved definition of gravity features, such as the Gakkel Ridge. The standard deviation between models ranges 0.03-0.25 m. The impact of remaining MSS/GGM errors on freeboard retrieval can reach several decimeters in parts of the Arctic. While the maximum observed freeboard difference found in the central Arctic was 0.59 m (UCL13 MSS minus EGM2008 GGM), the standard deviation in freeboard differences is 0.03-0.06 m.
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  • 24
    Publikationsdatum: 2018-06-14
    Beschreibung: Species flocks (SFs) fascinate evolutionary biologists who wonder whether such striking diversification can be driven by normal evolutionary processes. Multiple definitions of SFs have hindered the study of their origins. Previous studies identified a monophyletic taxon as a SF if it displays high speciosity in an area in which it is endemic (criterion 1), high ecological diversity among species (criterion 2), and if it dominates the habitat in terms of biomass (criterion 3); we used these criteria in our analyses. Our starting hypothesis is that normal evolutionary processes may provide a sufficient explanation for most SFs. We thus clearly separate each criterion and identify which biological (intrinsic) and environmental (extrinsic) traits are most favourable to their realization. The first part focuses on evolutionary processes. We highlight that some popular putative causes of SFs, such as key innovations or ecological speciation, are neither necessary nor sufficient to fulfill some or all of the three criteria. Initial differentiation mechanisms are diverse and difficult to identify a posteriori because a primary differentiation of one type (genetic, ecological or geographical) often promotes other types of differentiation. Furthermore, the criteria are not independent: positive feedbacks between speciosity and ecological diversity among species are expected whatever the initial cause of differentiation, and ecological diversity should enhance habitat dominance at the clade level. We then identify intrinsic and extrinsic factors that favour each criterion. Low dispersal emerges as a convincing driver of speciosity. Except for a genomic architecture favouring ecological speciation, for which assessment is difficult, high effective population sizes are the single intrinsic factor that directly enhances speciosity, ecological diversity and habitat dominance. No extrinsic factor appeared to enhance all criteria simultaneously but a combination of factors (insularity, fragmentation and environmental stability) may favour the three criteria, although the effect is indirect for habitat dominance. We then apply this analytical framework to Antarctic marine environments by analysing data from 18 speciose clades belonging to echinoderms (five unrelated clades), notothenioid fishes (five clades) and peracarid crustaceans (eight clades). Antarctic shelf environments and history appear favourable to endemicity and speciosity, but not to ecological specialization. Two main patterns are distinguished among taxa. (i) In echinoderms, many brooding, species‐rich and endemic clades are reported, but without remarkable ecological diversity or habitat dominance. In these taxa, loss of the larval stage is probably a consequence of past Antarctic environmental factors, and brooding is suggested to be responsible for enhanced allopatric speciation (via dispersal limitation). (ii) In notothenioids and peracarids, many clades fulfill all three SF criteria. This could result from unusual features in fish and crustaceans: chromosome instability and key innovations (antifreeze proteins) in notothenioids, ecological opportunity in peracarids, and a genomic architecture favouring ecological speciation in both groups. Therefore, the data do not support our starting point that normal evolutionary factors or processes drive SFs because in these two groups uncommon intrinsic features or ecological opportunity provide the best explanation. The utility of the three‐criterion SF concept is therefore questioned and guidelines are given for future studies.
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  • 25
    Publikationsdatum: 2017-09-25
    Beschreibung: Our study followed the seasonal cycling of soluble (SFe), colloidal (CFe), dissolved (DFe), total dissolvable (TDFe), labile particulate (LPFe) and total particulate (TPFe) iron in the Celtic Sea (NE Atlantic Ocean). Preferential uptake of SFe occurred during the spring bloom, preceding the removal of CFe. Uptake and export of Fe during the spring bloom, coupled with a reduction in vertical exchange, led to Fe deplete surface waters (〈0.2 nM DFe; 0.11 nM LPFe, 0.45 nM TDFe, 1.84 nM TPFe) during summer stratification. Below the seasonal thermocline, DFe concentrations increased from spring to autumn, mirroring NO3- and consistent with supply from remineralised sinking organic material, and cycled independently of particulate Fe over seasonal timescales. These results demonstrate that summer Fe availability is comparable to the seasonally Fe limited Ross Sea shelf, and therefore is likely low enough to affect phytoplankton growth and species composition.
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  • 26
    Publikationsdatum: 2018-01-09
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  • 27
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    Wiley
    In:  EPIC3Geochemistry Geophysics Geosystems, Wiley, 18(1), pp. 125-141, ISSN: 1525-2027
    Publikationsdatum: 2017-03-20
    Beschreibung: Northwestern Namibia, at the landfall of the Walvis Ridge, was affected by the Tristan da Cunha mantle plume during continental rupture between Africa and South America, as evidenced by the presence of the Etendeka continental flood basalts. Here we use data from a passive-source seismological network to investigate the upper mantle structure and to elucidate the Cretaceous mantle plume-lithosphere interaction. Receiver functions reveal an interface associated with a negative velocity contrast within the lithosphere at an average depth of 80 km. We interpret this interface as the relic of the lithosphereasthenosphere boundary (LAB) formed during the Mesozoic by interaction of the Tristan da Cunha plume head with the pre-existing lithosphere. The velocity contrast might be explained by stagnated and ‘‘frozen’’ melts beneath an intensively depleted and dehydrated peridotitic mantle. The present-day LAB is poorly visible with converted waves, indicating a gradual impedance contrast. Beneath much of the study area, converted phases of the 410 and 660 km mantle transition zone discontinuities arrive 1.5 s earlier than in the landward plume-unaffected continental interior, suggesting high velocities in the upper mantle caused by a thick lithosphere. This indicates that after lithospheric thinning during continental breakup, the lithosphere has increased in thickness during the last 132 Myr. Thermal cooling of the continental lithosphere alone cannot produce the lithospheric thickness required here. We propose that the remnant plume material, which has a higher seismic velocity than the ambient mantle due to melt depletion and dehydration, significantly contributed to the thickening of the mantle lithosphere.
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  • 28
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    Unbekannt
    Wiley
    In:  EPIC3Journal of Geophysical Research-Oceans, Wiley, 122(3), pp. 2108-2119, ISSN: 0148-0227
    Publikationsdatum: 2017-04-26
    Beschreibung: Snow on sea ice alters the properties of the underlying ice cover as well as associated physical and biological processes at the interfaces between atmosphere, sea ice, and ocean. The Antarctic snow cover persists during most of the year and contributes significantly to the sea-ice mass due to the widespread surface flooding and related snow-ice formation. Snow also enhances the sea-ice surface reflectivity of incoming shortwave radiation and determines therefore the amount of light being reflected, absorbed, and transmitted to the upper ocean. Here, we present results of a case study of spectral solar radiation measurements under Antarctic pack ice with an instrumented Remotely Operated Vehicle in the Weddell Sea in 2013. In order to identify the key variables controlling the spatial distribution of the under-ice light regime, we exploit under-ice optical measurements in combination with simultaneous characterization of surface properties, such as sea-ice thickness and snow depth. Our results reveal that the distribution of flooded and nonflooded sea-ice areas dominates the spatial scales of under-ice light variability for areas smaller than 100 m-by-100 m. However, the heterogeneous and highly metamorphous snow on Antarctic pack ice obscures a direct correlation between the under-ice light field and snow depth. Compared to the Arctic, light levels under Antarctic pack ice are extremely low during spring (〈0.1%). This is mostly a result of the distinctly different dominant sea ice and snow properties with seasonal snow cover (including strong surface melt and summer melt ponds) in the Arctic and a year-round snow cover and widespread surface flooding in the Southern Ocean.
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  • 29
    Publikationsdatum: 2021-01-26
    Beschreibung: Snow thickness on sea ice is a largely under-sampled parameter, yet of importance for the sea-ice mass balance and for satellite based sea-ice thickness estimates and thus our general understanding of global ice-volume change. Traditional direct thickness measurements with meter sticks can provide accurate but only spot information, referred to as "needles" due to their pinpoint focus and information while airborne and satellite remote sensing snow products, referred to as "the haystack" have large uncertainties due to their scale. We demonstrate the remarkable accuracy and applicability of ground penetrating radar (GPR) snow-thickness measurements by comparing them with in-situ, meter-stick data from two field campaigns to Antarctica in late winter/early spring. The efficiency and millimeter- to centimeter accuracy of GPR enables practitioners to acquire extensive, semi-regional data with the potential to upscale "needles" to "the haystack" and to potentially calibrate satellite remote sensing products that we confirm to derive roughly 30 % of the in-situ thickness. We find the radar wave propagation velocity in snow to be rather constant (+/- 6%), encouraging regional snow-thickness surveys. Snow thinner than 10 cm is under the detection limit with the off-the-shelf GPR setup utilized in our study.
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  • 30
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    Unbekannt
    Wiley
    In:  EPIC3Journal of Geophysical Research-Oceans, Wiley, 122(8), pp. 6437-6453, ISSN: 0148-0227
    Publikationsdatum: 2019-10-04
    Beschreibung: New two-year long records from three moorings, located at 76°S along the eastern flank and shelf of the Filchner Trough, give insight in the seasonal cycle of hydrography to a region where Modified Warm Deep Water (MWDW) enters the southern Weddell Sea continental shelf, possibly reaching the Filchner Ronne Ice Shelf, the biggest ice shelf (by volume) in Antarctica. A persistent northward flow of Ice Shelf Water (ISW) is found along the slope of the trough at 600 m depth, while the data on the shelf indicate a seasonal cycle, characterized by four phases. A distinct warm inflow period (separated in two phases), with maximum temperatures of −1°C, appears to be related to the seasonal heaving of the Antarctic Slope Front thermocline along the continental shelf break further north and a seasonal extension of the ISW layer onto the Eastern Shelf. The density gradients between the ISW in the trough and the MWDW on the adjacent shelf drive the southward flow during these phases. A flow reversal is found in winter, ceasing the southward flow along the eastern flank of the trough. Weaker density gradients between the trough and the shelf during winter allow a westward flow, partly driven by a N-S density gradient, existing across the Eastern Shelf during this time. From spring through to summer the ISW layer in the trough extends onto the eastern shelf where it occupies the bottom layer at our moorings and it is associated with northward flow.
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  • 31
    Publikationsdatum: 2017-07-21
    Repository-Name: EPIC Alfred Wegener Institut
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  • 32
    Publikationsdatum: 2020-03-05
    Beschreibung: The Norwegian young sea ICE (N-ICE2015) expedition was designed to investigate the atmosphere-snow-ice-ocean interactions in the young and thin sea ice regime north of Svalbard. Radiosondes were launched twice daily during the expedition from January to June 2015. Here we use these upper air measurements to study the multiple cyclonic events observed during N-ICE2015 with respect to changes in the vertical thermodynamic structure, moisture content, and boundary layer characteristics. We provide statistics of temperature inversion characteristics, static stability, and boundary layer extent. During winter, when radiative cooling is most effective, we find the strongest impact of synoptic cyclones. Changes to thermodynamic characteristics of the boundary layer are associated with transitions between the radiatively “clear” and “opaque” atmospheric states. In spring, radiative fluxes warm the surface leading to lifted temperature inversions and a statically unstable boundary layer. Further, we compare the N-ICE2015 static stability distributions to corresponding profiles from ERA-Interim reanalysis, from the closest land station in the Arctic North Atlantic sector, Ny-Ålesund, and to soundings from the SHEBA expedition (1997/1998). We find similar stability characteristics for N-ICE2015 and SHEBA throughout the troposphere, despite differences in location, sea ice thickness, and snow cover. For Ny-Ålesund, we observe similar characteristics above 1000 m, while the topography and ice-free fjord surrounding Ny-Ålesund generate great differences below. The long-term radiosonde record (1993–2014) from Ny-Ålesund indicates that during the N-ICE2015 spring period, temperatures were close to the climatological mean, while the lowest 3000 m were 1–3∘C warmer than the climatology during winter.
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  • 33
    Publikationsdatum: 2019-07-17
    Beschreibung: Focused research on the Pine Island and Thwaites glaciers, which drain the West Antarctic Ice Shelf (WAIS) into the Amundsen Sea Embayment (ASE), revealed strong signs of instability in recent decades that result from variety of reasons, such as inflow of warmer ocean currents and reverse bedrock topogra- phy, and has been established as the Marine Ice Sheet Instability hypothesis. Geothermal heat flux (GHF) is a poorly constrained parameter in Antarctica and suspected to affect basal conditions of ice sheets, i.e., basal melting and subglacial hydrology. Thermomechanical models demonstrate the influential boundary condition of geothermal heat flux for (paleo) ice sheet stability. Due to a complex tectonic and magmatic history of West Antarctica, the region is suspected to exhibit strong heterogeneous geothermal heat flux variations. We present an approach to investigate ranges of realistic heat fluxes in the ASE by different methods, discuss direct observations, and 3-D numerical models that incorporate boundary conditions derived from various geophysical studies, including our new Depth to the Bottom of the Magnetic Source (DBMS) estimates. Our in situ temperature measurements at 26 sites in the ASE more than triples the number of direct GHF observations in West Antarctica. We demonstrate by our numerical 3-D models that GHF spatially varies from 68 up to 110 mW m-2.
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  • 34
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    Wiley
    In:  EPIC3Journal of Geophysical Research-Oceans, Wiley, 122(2), pp. 1497-1512, ISSN: 0148-0227
    Publikationsdatum: 2017-10-10
    Beschreibung: The Barents Sea is one of the fastest changing regions of the Arctic, and has experienced the strongest decline in winter-time sea-ice area in the Arctic, at -23 +/- 4% per decade. Sea-ice thickness in the Barents Sea is not well studied. We present two previously unpublished helicopter-borne electromagnetic (HEM) ice thickness measurements from the northwestern Barents Sea acquired in March 2003 and 2014. The HEM data are compared to ice thickness calculated from ice draft measured by ULS deployed between 1994 and 1996. These data show that ice thickness varies greatly from year to year; influenced by the thermodynamic and dynamic processes that govern local formation vs long-range advection. In a year with a large inflow of sea-ice from the Arctic Basin, the Barents Sea ice cover is dominated by thick multiyear ice; as was the case in 2003 and 1995. In a year with an ice cover that was mainly grown in situ, the ice will be thin and mechanically unstable; as was the case in 2014. The HEM data allow us to explore the spatial and temporal variability in ice thickness. In 2003 the dominant ice class was more than 2 years old; and modal sea-ice thickness varied regionally from 0.6 to 1.4 m, with the thinner ice being either first-year ice, or multiyear ice which had come into contact with warm Atlantic water. In 2014 the ice cover was predominantly locally grown ice less than 1 month old (regional modes of 0.5–0.8 m). These two situations represent two extremes of a range of possible ice thickness distributions that can present very different conditions for shipping traffic; or have a different impact on heat transport from ocean to atmosphere.
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  • 35
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    Wiley
    In:  EPIC3Journal of Geophysical Research-Biogeosciences, Wiley, 122, pp. 1689-1704, ISSN: 0148-0227
    Publikationsdatum: 2017-10-24
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  • 36
    Publikationsdatum: 2017-09-20
    Beschreibung: Antarctic pack ice serves as habitat for microalgae which contribute to Southern Ocean primary production and serve as important food source for pelagic herbivores. Ice algal biomass is highly patchy and remains severely undersampled by classical methods such as spatially restricted ice coring surveys. Here we provide an unprecedented view of ice algal biomass distribution, mapped (as chlorophyll a) in a 100 m by 100 m area of a Weddell Sea pack ice floe, using under-ice irradiance measurements taken with an instrumented remotely operated vehicle. We identified significant correlations (p 〈 0.001) between algal biomass and concomitant in situ surface measurements of snow depth, ice thickness, and estimated sea ice freeboard levels using a statistical model. The model’s explanatory power (r2 = 0.30) indicates that these parameters alone may provide a first basis for spatial prediction of ice algal biomass, but parameterization of additional determinants is needed to inform more robust upscaling efforts.
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  • 37
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    Wiley
    In:  EPIC3Paleoceanography, Wiley, 32, ISSN: 0883-8305
    Publikationsdatum: 2017-04-25
    Beschreibung: The global ocean state for the modern age and for the Last Glacial Maximum (LGM) was dynamically reconstructed with a sophisticated data assimilation technique. A substantial amount of data including global seawater temperature, salinity (only for the modern estimate), and the isotopic composition of oxygen and carbon (only in the Atlantic for the LGM) were integrated into an ocean general circulation model with the help of the adjoint method, thereby the model was optimized to reconstruct plausible continuous fields of tracers, overturning circulation and water mass distribution. The adjoint-based LGM state estimation of this study represents the state of the art in terms of the length of forward model runs, the number of observations assimilated, and the model domain. Compared to the modern state, the reconstructed continuous sea-surface temperature field for the LGM shows a global-mean cooling of 2.2 K, and the reconstructed LGM ocean has a more vigorous Atlantic meridional overturning circulation, shallower North Atlantic Deep Water (NADW) equivalent, stronger stratification, and more saline deep water.
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  • 38
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    Wiley
    In:  EPIC3Journal of Geophysical Research-Oceans, Wiley, 122(5), pp. 4004-4020, ISSN: 0148-0227
    Publikationsdatum: 2018-01-02
    Beschreibung: Nioghalvfjerdsfjorden Glacier (79NG) is the largest of three marine-terminating outlet glaciers draining the Northeast Greenland Ice Stream. To understand how Atlantic waters supply waters in the cavity beneath the floating 79NG, we analyze historic and recent bathymetric, hydrographic, and velocity observations obtained on the Northeast Greenland continental shelf. The bathymetry is characterized by a trough system, consisting of the Westwind Trough and the Norske Trough in the northern and southern part of the continental shelf, respectively. Atlantic waters recirculating in Fram Strait cross the shelf break and enter the trough system at its southeastern inlet toward the inner shelf. Warm Atlantic Intermediate Water (AIW) present below 200 m in the Norske Trough shows large contributions of the recirculating Atlantic water. We found that the bathymetry is sufficiently deep to provide a direct subsurface pathway for warm AIW between the shelf break and the 79NG cavity via the Norske Trough. Likewise, based on the hydrographic data, we show that the Norske Trough supplies AIW warmer than 1°C to the 79NG, which is not present in the Westwind Trough. Our moored and lowered velocity measurements indicate that a boundary current carries warm AIW along the northeastern slope of Norske Trough toward the 79NG. We suggest that anomalies in Atlantic water temperatures in Fram Strait could reach 79NG within less than 1.5 years, thereby modifying the glacier's basal melt rates.
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  • 39
    Publikationsdatum: 2018-08-10
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  • 40
    Publikationsdatum: 2022-03-28
    Beschreibung: The Central Yakutian permafrost landscape is rapidly being modified by land use and global warming, but small-scale thermokarst process variability and hydrological conditions are poorly understood. We analyze lake-area changes and thaw subsidence of young thermokarst lakes on ice-complex deposits (yedoma lakes) in comparison to residual lakes in alas basins during the last 70 years for a local study site and we record regional lake size and distribution on different ice-rich permafrost terraces using satellite and historical airborne imagery. Statistical analysis of climatic and ground-temperature data identified driving factors of yedoma- and alas-lake changes. Overall, lake area is larger today than in 1944 but alas-lake levels have oscillated greatly over 70 years, with a mean alas-lake-radius change rate of 1.663.0 m/yr. Anthropogenic disturbance and forest degradation initiated, and climate forced rapid, continuous yedoma-lake growth. The mean yedoma lake-radius change rate equals 1.261.0 m/yr over the whole observation period. Mean thaw subsidence below yedoma lakes is 6.261.4 cm/yr. Multiple regression analysis suggests that winter precipitation, winter temperature, and active-layer properties are primary controllers of area changes in both lake types; summer weather and permafrost conditions additionally influence yedoma-lake growth rates. The main controlling factors of alas-lake changes are unclear due to larger catchment areas and subsurface hydrological conditions. Increasing thermokarst activity is currently linked to older terraces with higher ground-ice contents, but thermokarst activity will likely stay high and wet conditions will persist within the near future in Central Yakutian alas basins.
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  • 41
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    Wiley
    In:  EPIC3Ecosphere, Wiley, 8(3), pp. e01742-e01742, ISSN: 2150-8925
    Publikationsdatum: 2023-09-22
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  • 42
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 90 (2001), S. 4474-4484 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: A detailed study of the formation of β-FeSi2 films by ion-beam mixing of Fe/Si bilayers with noble gas ions is presented. Fe films of 35–50 nm deposited on Si (100) were irradiated with 80–700 keV Ar, Kr, or Xe ions in a wide temperature interval, from room temperature to 600 °C. The structures were analyzed by Rutherford backscattering spectroscopy, x-ray diffraction, conversion electron Mössbauer spectroscopy, elastic recoil detection analysis, cross-section high resolution transmission electron microscopy, and energy dispersive x-ray spectroscopy. Already after Xe irradiation at 300 °C the whole Fe layer is transformed to a mixture of Fe3Si, cursive-epsilon-FeSi, and β-FeSi2 phases. At 400–450 °C, a unique, layer by layer growth of β-FeSi2 starting from the surface was found. A full transformation of 35 nm Fe on Si to a 105 nm β-FeSi2 layer was achieved by irradiation with 205 keV Xe to 2×1016 ions/cm2, at a temperature of 600 °C. The fully ion-beam grown layers exhibit a pronounced surface roughness, but a sharp interface to Si. This structure is assigned to a growth of β-FeSi2 grains in a local surrounding of interdiffused silicon. Rapid diffusion of silicon to the surface was observed during all ion irradiations. Single-phase β-FeSi2 layers were also synthesized by vacuum annealing for 2 h at 600 °C of 35 nm Fe/Si bilayers premixed with Xe at 450 °C. In this case, the layers form with a smoother surface topography. It is concluded that ion-beam mixing can be used successfully for growth of β-FeSi2 layers at moderate temperatures, either directly or combined with postirradiation annealing. © 2001 American Institute of Physics.
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  • 43
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 90 (2001), S. 4489-4493 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: Optical properties of ZnO quantum dots (QDs) capped with polyvinyl pyrrolidone (PVP) molecules have been investigated. It is demonstrated that surface modification by PVP can dramatically change the emission spectra of the ZnO QDs. At the optimized condition with a PVP/Zn2+ ratio of 3:5, the photoluminescence (PL) spectrum of ZnO QDs shows a strong ultraviolet (UV) emission while the low energy green emission is fully quenched. This is a result of the surface passivation of the ZnO QDs by the PVP molecules. The origin of the green emission is attributed to the surface states associated with oxygen vacancies. Temperature and excitation power dependent PL studies suggest that the UV emission is associated with localized states. © 2001 American Institute of Physics.
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  • 44
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 90 (2001), S. 4494-4497 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: We have revisited the still unresolved puzzle of the dispersion of the Raman disorder-induced D band as a function of laser excitation photon energy EL in graphite-like materials. We propose that the D mode is a combination of an optic phonon at the K point in the Brillioun zone and an acoustic phonon whose momentum is determined uniquely by the double resonance condition. The fit of the experimental data with the double-resonance model yields the reduced effective mass of 0.025 me for the electron-hole pairs corresponding to the A2 transition, in agreement with other experiments. The model can also explain the difference between ωS and ωAS for D and D* modes, and predicts its dependence on the Raman excitation frequency. © 2001 American Institute of Physics.
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  • 45
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 90 (2001), S. 4800-4804 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: The diode ideality factor, reverse breakdown voltage, and forward current characteristic were used to measure the effect on electric performance of GaAs rectifiers deposited with thin films of SiNx. Over a broad range of deposition conditions there were minimal changes (〈10%) in breakdown voltage and the cause was hydrogen passivation of Si dopants in the GaAs. Ion-induced damage did not appear to play a significant role in the results. The ideality factors and forward leakage currents were essentially unchanged by the SiNx deposition indicating that the plasma exposure did not create defects states around the periphery of the Schottky contact. © 2001 American Institute of Physics.
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  • 46
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 90 (2001), S. 4791-4795 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: Electrostatic force microscopy (EFM) with phase detection has been applied to cleaved cross sections of wafer-bonded transparent substrate (TS) AlGaInP light-emitting diode (LED) structures. EFM was performed with the LED under active bias to image the voltage drops across the device layers. Measurements on a nonwafer-bonded, absorbing substrate (AS) AlGaInP LED wafer, showed a voltage drop only at the p–n junction. A TS wafer with high forward voltage (Vf ) showed a much larger voltage drop at the wafer-bonded interface, compared with a normal TS LED wafer. Secondary ion mass spectrometry profiles of these wafers revealed ∼1×1013 cm−2 of carbon at the bonded interface in the high Vf sample, compared to ∼3×1012 cm−2 in the normal wafer. The unwanted voltage drop at the bonded interface was likely caused by a combination of carbon acting as a p-type dopant and the presence of interface states due to a ∼3° in-plane rotational misalignment at wafer bonding. © 2001 American Institute of Physics.
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  • 47
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 90 (2001), S. 3442-3449 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: The effect of thermal energy (kBT), which has been found to play some important roles in the magnetic properties of recently developed antiferromagnetically coupled media, is described. It was observed that the thermal energy helps to obtain an antiparallel configuration of moments at remanence. Therefore, a reduction in the remnant moment–thickness product (Mrδ) is observed, even for smaller values of J (interface coupling constant) than those used in simulations that do not consider thermal energy. The magnetic viscosity measurement helps to distinguish the magnetization decay behavior of the top and bottom layers. The magnetic moments of top and bottom layers show maximum decay at different fields and the decay rates approximately scale with their thickness. Viscosity results also point out that the magnetization reversal of the bottom layer should occur in the first quadrant, in order to obtain a low noise and thermally stable media. Micromagnetic simulation was performed by including thermal effects. In that case, Mrδ reduction could be obtained for smaller values of J than in the case where thermal energy is not included in the simulation. © 2001 American Institute of Physics.
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  • 48
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 90 (2001), S. 3720-3725 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: The electron density and the electron temperature in a low-pressure neon mercury positive column are determined using Thomson scattering. Special attention has been given to the stray light reduction in the Thomson scattering setup. The results are obtained in a discharge tube with a 26 mm diam, 10 mbar of neon, a mercury pressure inbetween 0.14 and 0.85 Pa, and an electric current ranging from 100 to 400 mA. The systematic error in the electron density is 15%–45%, the statistical error is 25%–35%. The total error in the electron temperature is 15%–35%. © 2001 American Institute of Physics.
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  • 49
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 90 (2001), S. 3799-3809 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: The exchange of a tracer material, e.g., a radioactive isotope, between two samples forming a diffusion couple depends on the rate of the diffusion of the tracer in each of the two samples and also on the rate of the transfer of the tracer across the interface between these samples which may or may not contain a barrier layer with a different chemical composition and/or structure. Diffusion couples with three different initial tracer distributions are considered. In order to extract from experimental data values for tracer diffusion coefficients and for the rate constant for the tracer transport across the interface, a detailed analysis of the required mathematics is given. This analysis is of interest as well for obtaining true values for bulk diffusivities and also to characterize quantitatively the resistance of interfaces (=barriers) to the exchange of certain species. Some examples of experimental results are presented and briefly discussed. © 2001 American Institute of Physics.
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  • 50
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 90 (2001), S. 3822-3824 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: A B-buried layer with a dose of 1×1014 atoms/cm2 was introduced into p-doped Si at a depth of 2.2 μm to enhance copper diffusion via its inherent gettering effect. Copper was then introduced into silicon either via a low-energy implantation followed by a thermal anneal, or through the thermal drive in of physical vapor deposited (PVD) copper film. Secondary ion mass spectrometry depth profiling of both annealed samples later indicated that while substantial amounts of copper was gettered by the B layer in the former sample, no copper was gettered by the B-buried layer in the latter sample. Further analysis with an x-ray diffraction technique showed that copper silicide, Cu3Si was formed in the latter sample. It is thus surmised that the formation of this silicide layer impeded the diffusion of copper towards the B-buried layer. This work investigates the cause of CuSix formation and the underlying reasons for the lower mobility of Cu in PVD Cu film samples. © 2001 American Institute of Physics.
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  • 51
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 90 (2001), S. 3810-3815 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: Na-22 tracer diffusion experiments were performed to study the exchange of Na ions between liquid crystal display glass substrates (Corning Code 1737) separated by different types of layers. Different types of layers were generated (i) by RCA cleaning, (ii) by preannealing in wet air, and (iii) by low pressure chemical vapor deposition. A sandwich configuration was used to study the effect of such layers between two glass substrates on the exchange of Na ions between these substrates. The sandwiches were of the type substrate 1 (containing Na-22 tracer)/layer/substrate 2. Diffusion annealing of such sandwiches led to a redistribution of the sodium tracer. This redistribution was analyzed experimentally with regard to the sodium tracer diffusion coefficient in the bulk and the rate of the sodium tracer transfer across the layer. It was found that all three types of layers considered act as barrier layers, i.e., they suppress the exchange of Na ions between glass substrates. © 2001 American Institute of Physics.
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  • 52
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 90 (2001), S. 3816-3821 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: AgInSbTe films have recently attracted considerable interest as advanced materials for phase change recording. For this application the determination of crystallization kinetics is of crucial importance. In this work the temperature dependence of structural and electrical properties of sputtered AgInSbTe films has been determined. Temperature dependent measurements of the electrical resistance have been employed to study the kinetics of structural changes of these films. Upon annealing a major resistivity drop is observed at around 160 °C which can be attributed to a structural change as corroborated by x-ray diffraction. X-ray diffraction shows an amorphous phase for as-deposited films, while crystalline films with hexagonal structure (a=4283 Å, c=16 995 Å) are obtained upon annealing above 160 °C. By applying Kissinger's method, an activation energy of 3.03±0.17 eV is obtained for the crystallization. X-ray reflection measurements reveal a density increase of 5.2%±0.2% and a thickness decrease of 5.5%±0.2% upon crystallization. © 2001 American Institute of Physics.
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  • 53
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 90 (2001), S. 3838-3842 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: The results of generalized anisotropic ellipsometry on a biaxial organic single crystal, namely, potassium acid phthalate, are discussed and analyzed to obtain the optical functions of the crystal along the different crystal directions. The dispersion of the real refractive indices nx, ny, and nz in the spectral range from 300 to 1400 nm, as well as the values of the extinction coefficient kx,y at the absorption edge are determined and modeled. © 2001 American Institute of Physics.
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  • 54
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 90 (2001), S. 3825-3830 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: The optical response of regularly arranged noble metal wires with nanoscopic cross sections (nanowire gratings) strongly depends on the polarization direction of the incident light. We use silver and gold nanowire gratings produced by electron beam lithography to study this effect by optical extinction spectroscopy. For a polarization direction perpendicular to the wire axis, the excitation of a dipolar plasmon mode dominates the extinction spectrum. The spectral position of the plasmon resonance can be tuned by an appropriate choice of nanowire geometry and material. For a polarization direction parallel to the wire axis, the profile of the extinction spectrum varies mainly as a function of the grating constant. In particular, a transmission maximum for small grating constants is found. By combining the surface plasmon excitation and grating effect for orthogonal polarization directions, a spectrally selective polarizer with an extinction ratio of 26 is demonstrated. © 2001 American Institute of Physics.
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  • 55
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 90 (2001), S. 3887-3893 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: This article reports a selective-area deposition process using chlorosilane-treated ultrathin SiO2 masks on which the patterns are directly defined by irradiation of a focused electron beam (EB). Three different chlorosilane gases (SiH2Cl2, SiHCl3, and SiCl4) were first adsorbed on the SiO2 surfaces, and the regions with reactive sites were defined by taking advantage of electron-stimulated desorption (ESD) of the surface adsorbates. For the SiHCl3- and SiH2Cl2-treated surfaces, the nucleation density was remarkably high in the EB-irradiated regions. Such nucleation enhancement was less significant for the SiCl4-treated surface. For the purpose of direct patterning and selective growth, we conclude that SiHCl3 is the optimum treatment gas because it effectively suppresses Si nucleation outside of the EB-irradiated patterns. The overall ESD sensitivity of the SiHCl3-adsorbed mask was 50 mC/cm2, and a significant nucleation enhancement was observed by irradiation of 7 mC/cm2. We also report an extension of this selective-area processing to window opening through the ultrathin SiO2 mask layer. The factors limiting the minimum feature size of the grown Si structures and the opened windows are discussed. © 2001 American Institute of Physics.
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  • 56
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: A comprehensive, quantitative analysis is presented of the deformation behavior of coherently strained InAs/GaAs(111)A heteroepitaxial systems. The analysis combines a hierarchical theoretical approach with experimental measurements. Continuum linear elasticity theory is linked with atomic-scale calculations of structural relaxation for detailed theoretical studies of deformation in systems consisting of InAs thin films on thin GaAs(111)A substrates that are mechanically unconstrained at their bases. Molecular-beam epitaxy is used to grow very thin InAs films on both thick and thin GaAs buffer layers on epi-ready GaAs(111)A substrates. The deformation state of these samples is characterized by x-ray diffraction (XRD). The interplanar distances of thin GaAs buffer layers along the [220] and [111] crystallographic directions obtained from the corresponding XRD spectra indicate clearly that thin buffer layers deform parallel to the InAs/GaAs(111)A interfacial plane, thus aiding in the accommodation of the strain induced by lattice mismatch. The experimental measurements are in excellent agreement with the calculated lattice interplanar distances and the corresponding strain fields in the thin mechanically unconstrained substrates considered in the theoretical analysis. Therefore, this work contributes direct evidence in support of our earlier proposal that thin buffer layers in layer-by-layer semiconductor heteroepitaxy exhibit mechanical behavior similar to that of compliant substrates [see, e.g., B. Z. Nosho, L. A. Zepeda-Ruiz, R. I. Pelzel, W. H. Weinberg, and D. Maroudas, Appl. Phys. Lett. 75, 829 (1999)]. © 2001 American Institute of Physics.
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  • 57
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 90 (2001), S. 2725-2729 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: Ge(Si)/Si(001) coherent islands grown at 700 °C by molecular beam epitaxy were investigated using transmission electron microscopy. [001] on-zone bright-field diffraction contrast imaging and image simulation techniques were used to investigate the structure of these coherent islands. Comparison of simulated and experimental images indicates nonuniform composition distribution within the coherent islands when the islands were grown at high temperatures (700 °C), but uniform composition for growth at lower temperatures (600 °C). © 2001 American Institute of Physics.
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  • 58
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 90 (2001), S. 4314-4320 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: We have used a rate equation propagation model of an Er3+/Yb3+ doped Al2O3 waveguide amplifier with copropagating pump at 980 nm to investigate the dependence of gain on Yb3+ concentration. The model includes excited state absorption and energy transfer upconversion processes within the Er3+ as well as the relevant energy transfer processes between Yb3+ and Er3+. The results of the calculations indicate a close relationship of the parameters gain, launched pump power, waveguide length, and Yb3+ concentration. Codoping with a well-chosen Yb3+ concentration is shown to increase the gain around 1530 nm for all combinations of these parameters. The gain is improved most by Yb3+ codoping at pump powers around the amplifier threshold. At high pump powers the increase in gain of an Er3+/Yb3+ doped waveguide is insignificant compared to that of its Er3+ doped counterpart. Furthermore for each launched pump power, a nonzero Yb3+ concentration can be determined, which maximizes the gain. © 2001 American Institute of Physics.
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  • 59
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 90 (2001), S. 4321-4327 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: We investigate the transmission of ultrashort pulses through impurity band-based photonic crystal waveguides. It is found that in the general case the transmission behavior depends strongly on the pulse width with respect to the resonance linewidth in impurity bands. By controlling the configuration of the waveguides, quasiflat impurity bands can be obtained in which the dependence of transmission on pulse width is very weak. As long as the pulse width is much narrower than the bandwidth, pulses can transmit through the quasiflat impurity bands with negligible distortion and attenuation. The conditions necessary for achieving quasiflat impurity bands are derived by examining waveguides of different configurations and properties. The mechanism responsible for the formation of quasiflat impurity bands is revealed from the discussion of the symmetry of single defect and their coupling. © 2001 American Institute of Physics.
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  • 60
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 90 (2001), S. 4328-4337 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: Advances in optical parametric devices, in particular those requiring high conversion efficiency, rely on pump laser and gain medium properties. We describe and theoretically model the source of dephasing due to angular deviation from ideal phase matching in optical parametric amplification. Real laser beams have angular content, which is described by their spatial frequency spectrum. Such beams cannot be treated as single plane waves in nonlinear interactions. Our mathematical model is based on a plane wave decomposition of Gaussian and top-hat beams into their components in spatial frequencies. Several popular nonlinear materials (beta-barium borate, lithium borate, and potassium dihydrogen phosphate) are examined for phase matching angles and dephasing is rigorously calculated. The impact of the beam angular content on small signal gain and on conversion efficiency in the strongly depleted regime is evaluated numerically. In addition, a criterion is formulated for beam quality tolerance in optical parametric amplifiers, for critical and noncritical phase matching. The impact of initial conditions in optical parametric amplification is considered. Our calculations are intended primarily for devices pumped with long (nanosecond) pulses. © 2001 American Institute of Physics.
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  • 61
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 90 (2001), S. 4338-4345 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: In this work, single layer, light-emitting devices have been prepared from pristine tris(2,2′ bipyridyl) ruthenium(II) hexafluorophosphate ([Ru(bpy)3](PF6)2) and blends of [Ru(bpy)3](PF6)2 with glassy polymers such as poly(methylmethacrylate) (PMMA), polycarbonate (PC), and polystyrene. Due to the electrochemical nature of the device operation, a high external quantum efficiency at a low operating voltage is achieved. For pristine devices fabricated with an Al cathode, external quantum efficiencies in the range of 1.2%–1.5% at 100–1000 cd/m2 have been achieved. Such devices, however, show signs of degradation in time when stored in the off state in inert atmosphere. Blending with glassy polymers such as PMMA results in an improved film quality and a slowing of the device degradation which, in return, decreases the leakage current during device operation. Therefore, external quantum efficiencies of 2%–2.5% at a light output of 200 cd/m2 are observed when the electroluminescent tris(2,2′ bipyridyl) ruthenium(II) complex is blended with PMMA or PC. In addition, increased efficiency and lifetime are found when the devices are operated under a 50% duty cycle at 5 V and 1 kHz compared to the operation under constant voltage. With a 50% duty cycle, half lives of around 500–1100 h continuous operation have been achieved at luminance levels in the range of 200–350 cd/m2. When Ag is used as the cathode material, PMMA blend devices exhibit external quantum efficiencies in the range of 2.5%–3.0% at luminance levels of around 50 cd/m2. In addition, devices with a Ag cathode show no signs of degradation when stored in the off state. © 2001 American Institute of Physics.
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  • 62
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 90 (2001), S. 4346-4354 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: A self-consistent two-dimensional particle model coupled to the external circuit equations was developed in an asymmetrical configuration for the self-bias voltage calculation and the reactor design study. An intermediate modeling was performed in one and two symmetrical geometries. The one-dimensional model is used to optimize the computing time which is reduced by a factor of 10 by using some optimization techniques. It is also used to validate the charged particle and basic data choices. We have shown that the consideration of only two charged particle species (electron and H3+ positive ion) is sufficient in the present hydrogen radio-frequency discharge modeling. Computational results (i.e., power density and self-bias voltage) are in good agreement with experimental results. A strong gradient of the plasma parameters (such as electric field, potential, charged particle densities and energies) was observed in the periphery of the driven electrode. Furthermore, the present two-dimensional asymmetric model shows that the interelectrode distance increase (from 1.7 up to 3.7 cm) can lead to reducing the plasma heterogeneity due to the geometrical electric field. © 2001 American Institute of Physics.
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  • 63
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 90 (2001), S. 2943-2948 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: The structural, magnetic, and electronic properties of the polycrystalline La1−xNaxMnO3 (x=0.10, 0.15, 0.20, and 0.30) are investigated. The result of the Rietveld refinement of x-ray powder diffraction shows that these compounds crystallize in a rhombohedrally distorted structure with space group R3¯C. The magnetic measurement shows that Curie temperature TC of the studied samples is near or above room temperature. The temperature dependence of resistivity shows that all samples undergo a sharp transition accompanying a paramagnetic to ferromagnetic with the decrease of temperature, however, for x≥0.15 samples, double transition peaks with a single ferromagnetic transition is observed. In the meanwhile, a large room-temperature magnetoresistance with low applied magnetic field is observed. The co-existing ferromagnetic metallic phases and ferromagnetic insulating (FMI) phases induced by the electronic inhomogeneity as well as the additional FMI phases caused by the presence of vacancies at the A sites, are presented to account for the transport properties and large magnetoresistance in these compounds. © 2001 American Institute of Physics.
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  • 64
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 90 (2001), S. 3090-3094 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: Molecular dynamics simulation was carried out to investigate the stick-slip on an atomic scale by using the embedded atom method potential for Ni–Al. The analyses of the dynamic features of the atoms in the sliding block clearly show that the elastic deformation of the surface layers is the main cause for the stick-slip phenomenon, which is consistent with the macroscopic stick-slip. The simulation results also indicate that phonons are emitted during stick-slip, and a commensurate fit between the contacting surfaces is not significant for the stick-slip friction. © 2001 American Institute of Physics.
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  • 65
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 90 (2001), S. 3095-3099 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: A modified atomic force microscopy (AFM) system, based on a force modulation technique, has been used to find an approximate value for the elastic modulus of a single peptide molecule directly from a mechanical test. For this purpose a self-assembled monolayer built from two kinds of peptides, reactive (able to anchor to the AFM tip) and nonreactive, was synthesized. In a typical experiment a single C3K30C (C=cysteine, K=lysine) peptide molecule was stretched between a Au(111) substrate and the gold-coated tip of an AFM cantilever to which it was attached via gold–sulfur bonds. The amplitude of the cantilever oscillations, due to an external force applied via a magnetic particle to the cantilever, was recorded by a lock-in amplifier and recalculated into stiffness of the stretched molecule. A longitudinal Young's modulus for the α-helix of a single peptide molecule and for the elongated state of this molecule has been estimated. The obtained values; 1.2±0.3 and 50±15 GPa, for the peptide α-helix and elongated peptide backbone, respectively, seem to be reasonable comparing them to the Young's modulus of protein crystals and linear organic polymers. We believe this research opens up a means by which scientists can perform quantitative studies of the elastic properties of single molecule, especially of biologically important polymers like peptides or DNA. © 2001 American Institute of Physics.
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  • 66
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 90 (2001), S. 3952-3955 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: The formation energies of planar defects such as lamellar twins and intrinsic and extrinsic stacking faults in CdTe are calculated using first-principles total-energy calculations. We find that the formation energies, 16 erg/cm2 for lamellar twins and 34 and 31 erg/cm2 for intrinsic and extrinsic stacking faults, are very small. This explains why high densities of planar defects are always present in the fast-grown CdTe thin films. The effects of the planar defects on the formations of important point defects in p-type CdTe are also investigated. We find that the planar defects have negligible effects on Cd vacancies and substitutional Cu, whereas they lower the formation energy of Te antisites by about 0.1 eV compared to the perfect regions. © 2001 American Institute of Physics.
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  • 67
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 90 (2001), S. 3956-3964 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: We have analyzed a series of data sets available from published literature for the temperature dependence of A and B exciton peak positions associated with the fundamental band gap of hexagonal GaN layers grown on sapphire. In this article, in contrast to preceding ones, we use the dispersion-related three-parameter formula Eg(T)=Eg(0)−(αaitch-theta/2)[(1+(π2/6)(2T/aitch-theta)2+(2T/aitch-theta)4)1/4−1], which is a very good approximation in particular for the transition region between the regimes of moderate and large dispersion. This formula is shown here to be well adapted to the dispersion regime frequently found in hexagonal GaN layers. By means of least-mean-square fittings we have estimated the limiting magnitudes of the slopes, S(T)≡−dEg(T)/dT, of the Eg(T) curves published by various experimental groups to be of order α≡S(∞)(approximate)(5.8±1.0)×10−4 eV/K. The effective phonon temperature has been found to be of order aitch-theta(approximate)(590±110) K, which corresponds to an ensemble-averaged magnitude of about 50 meV for the average phonon energy. The location of the latter within the energy gap between the low- and high-energy subsections of the phonon energy spectrum of h-GaN suggests that the weights of contributions made by both subbands to the limiting slope α are nearly the same. This explains the order of Δ(approximate)0.5–0.6 as being typical for the dispersion coefficient of the h-GaN layers under study. The inadequacies of both the Bose–Einstein model (corresponding to the limiting regime of vanishing dispersion Δ→0) and Varshni's ad hoc formula (corresponding to a physically unrealistic regime of excessively large dispersion Δ(approximate)1) are discussed. Unwarranted applications of these conventional models to numerical fittings, especially of unduly restricted data sets (T≤300 K), are identified as the main cause of the excessively large scatter of parameters quoted for h-GaN in various recent articles. © 2001 American Institute of Physics.
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  • 68
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 90 (2001), S. 2143-2147 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: In this article, we present a theory of the pulse train generated by a rational harmonic mode locked ring fiber laser. The pulse width is calculated as a function of the rational harmonic order and the optical transfer function of the modulator. The theoretical work is based on a time domain analysis, which predicts that the pulse width decreases when the rational harmonic order goes up. The pulse width as a function of the modulation amplitude and bias level of the modulator was measured, and the experimental results agree with the theory. © 2001 American Institute of Physics.
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  • 69
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 90 (2001), S. 3984-3987 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: Using a dual-layered photoconductor, we have investigated the primary photocarrier generation process in x-form metal-free phthalocyanine (x-H2Pc) over a wide range of illumination wavelengths. According to the results of quantum efficiency measurements, it has been established that the photocarrier generation mechanism in x-H2Pc occurs via two processes: (i) production of an intermediate that depends solely on the excitation energy, and (ii) subsequent free carrier production in the presence of an electric field. In addition, the spectral quantum efficiency and the electroabsorption spectrum were measured and compared. Based on that, the primary process efficiency was divided into four regions in terms of photon energy, which explained well the relationship between them. The excitation energy dependence of the primary efficiency was semiquantitatively validated based on the electron transfer theory. © 2001 American Institute of Physics.
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  • 70
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 90 (2001), S. 3993-3997 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: The Hall effect and electrical resistivity of n-type CuInSe2 single crystals are measured between 4.2 and 300 K. Using a single conduction band model, the variation of the electron concentration with temperature above 100 K is explained in terms of the thermal activation of a shallow donor. The density of states effective mass me*=0.09me of the electrons, the activation energy of the donors around 7 meV, their concentration, and the compensation ratio are estimated. The temperature dependence of the electron mobility in conduction band is analyzed by taking into account the scattering of the charge carriers by ionized impurities and acoustic and polar optical phonon modes. The adjustable parameters, thus obtained, are compared with those reported earlier. On the other hand, by considering the two-band model with electrons in both the conduction and impurity bands, the change in the Hall coefficient with temperature between 300 and 40 K is explained. It is found that at the temperature where the Hall coefficient is maximum, the mobility in the impurity band is about 20% as compared to its value in the conduction band. The width of the impurity band is found to increase with increasing impurity concentration and the electron mobility below 20 K is explained by considering the effect of Mott-type variable range hopping conduction. © 2001 American Institute of Physics.
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  • 71
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 90 (2001), S. 3998-4006 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: A theory for the current noise associated with carrier generation and recombination in the space-charge region of p–n junctions is presented. We propose a noise model based on the response of the electric field to fluctuations of the trapped charge in this region, and make use of a collective transport-noise theory. The effects of the fluctuations of the space-charge region borders due to the fluctuations of the trapped charge are now taken into account. This new contribution is negligible when generation–recombination current governs the diode current. However, it is significant when diffusion current dominates, allowing the analytical study of generation–recombination noise to be extended to wider ranges of bias and temperature. Experimental results at low and high temperatures are explained with our theory. Empirical formulas of current noise density are also explained according to this complete theory of current noise calculation. © 2001 American Institute of Physics.
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  • 72
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 90 (2001), S. 4007-4018 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: WO3 films, either prepared by sputtering or evaporation under high or ultrahigh vacuum conditions, were irradiated with He+ and Ar+ ions (energy range 300–350 keV) at ambient and low temperatures (77–100 K). The resulting ion induced changes of the optical absorption as well as of the electrical conductivity could be determined on one and the same sample, which enables the variable range hopping (VRH) model to be tested under the assumption that the density of irradiation induced color centers is proportional to the electronic density of states contributing to the hopping conductivity. It is found that the data obtained at 300 K for He+ and Ar+ bombardment can be described within the VRH model by one common conductivity versus absorption curve, even though the effectiveness per projectile of the heavier ion for coloration as well as for increasing the conductivity is much higher. This is different at low temperatures. While the ion induced coloration is practically independent of the irradiation temperature for both projectiles, the effectiveness per projectile to enhance the conductivity is interchanged. This is attributed to the additional damage produced by the heavier ion at low temperatures resulting in strongly impeded hopping processes. Consistent with the VRH model, the temperature dependence of the conductivity of ion bombarded WO3 films follow the Mott "T−1/4" law, if the ion induced conductivity is not too high. For very high ion fluences clear deviations from the VRH model are observed for the conductivity versus absorption curves accompanied by a shift of the above power laws from T−1/4 towards T−1/2. © 2001 American Institute of Physics.
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  • 73
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 90 (2001), S. 4027-4031 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: Transmission electron microscopy (TEM) and selected area electron diffraction pattern (SADP) measurements were carried out to investigate the ordered structures near ZnTe/GaAs heterointerfaces, and Auger electron spectroscopy (AES) and secondary ion mass spectroscopy (SIMS) measurements were performed to determine the compositions of the ZnTe/GaAs interfacial layer. The SADP showed two sets of {〈fraction SHAPE="CASE"〉12 〈fraction SHAPE="CASE"〉12 〈fraction SHAPE="CASE"〉12} extra spots with symmetrical intensity, and the corresponding high-resolution TEM image showed doublet periodicity in contrast of the {111} lattice planes. The results of the SADP and the high-resolution TEM measurements showed that a CuPt-type ordered (Cd, Zn)Te structure was observed near the ZnTe/GaAs heterointerface, and the AES and SIMS results showed that the ordered structure was formed due to the diffusion of Cd atoms into the ZnTe layer. Two variants, one for each direction of the doublet periodicity on the {111} lattice, were observed in the ordering, and each variant had its own domain structure with a similar probability. The formation of the CuPt-type ordered structure near the ZnTe/GaAs heterointerface originated from both the existence of the Cd residual impurities during the initial growth stage of the ZnTe epilayer and the strain relaxation of the ZnTe epilayer. These results can help to improve the understanding of the microstructural properties of the ZnTe/GaAs heterointerface. © 2001 American Institute of Physics.
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  • 74
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 90 (2001), S. 4044-4048 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: Discontinuous multilayered Co80Fe20(t)/Al2O3(30 Å) thin films have been prepared by ion-beam sputtering. We report on structural, magnetic, and transport (for current in plane geometry) results obtained in this system. With growing nominal thickness t of the metal layers, which effectively characterizes the granular structure, a transition from tunnel to metallic conductance is observed, indicating the onset of infinite conducting paths at t〉18 Å. At t〈18 Å, that is within the range of tunnel regime, a different characteristic value t〉13 Å was detected from the magnetization data which display here a transition from superparamagnetic to ferromagnetic behavior. The measurements of tunnel magnetoresistance (MR) show that a sharp maximum of MR sensitivity to field takes place at this thickness, reaching ∼24%/kOe at room temperature. At least, MR itself as a function of t has a break at the same value. All these features suggest that some specific kind of percolation with respect to magnetic order occurs in our system when the disordered granular structure is still well separated, as confirmed by the data of high resolution transmission electron microscopy. Hence such magnetic percolation is clearly distinct from usual electrical percolation in these discontinuous layers. At the same time, the highest MR (∼6.5% at room temperature) in this series is attained with decreasing t only at t=10 Å. © 2001 American Institute of Physics.
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  • 75
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 90 (2001), S. 4049-4055 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: We have investigated the behavior of high-critical-temperature (high Tc) direct-coupled superconducting quantum interference device (SQUID) magnetometers in static and fluctuating magnetic fields. The magnetometers consist of narrow-linewidth superconducting films to prevent flux trap during field cooling. Moreover, they have no superconducting films crossing the bicrystal lines of the substrates (except at the Josephson junctions); i.e., they have no flux dams. When one of these magnetometers was cooled in a static magnetic field Bcool, the low-frequency noise when Bcool〈100 μT was as low as that under zero-field cooling, but above 100 μT the noise increased substantially. On the other hand, when a field Bext of less than 4 μT was applied after zero-field cooling, the low-frequency noise increased in proportion to Bext. It returned to its original value reversibly when Bext was turned off. However, when Bext was greater than or equal to 4 μT, the output of the flux-locked-loop started to drift with time and the low-frequency noise increased further. This additional noise increase remained after turning off Bext. These results suggested that there are two modes of increase for the low-frequency noise induced by flux penetration due to the shielding current: a "reversible" mode and an "irreversible" mode. We found that the low-frequency noises of the two modes were additive with respect to their power, suggesting that the two noises derived from independent sources at different sites on the magnetometer. We also found that the reversible-mode noise could be reduced by improving the profile of the film edge. © 2001 American Institute of Physics.
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  • 76
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 90 (2001), S. 4078-4084 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: Cluster glass and relatively high coercivity at low temperatures were found in disordered ultrafine nickel ferrite powders. High-energy mechanical milling of spinel NiFe2O4 led to formation of a wüstitelike structure. Our investigation suggested that ferrimagnetic clusters formed in an antiferromagnetic matrix. The strong ferri/antiferromagnetic exchange coupling resulted in a strong unidirectional anisotropy and a coercivity of over 10 kOe at 4.2 K. © 2001 American Institute of Physics.
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  • 77
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 90 (2001), S. 4085-4088 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: We have studied the effect of Sm on the magnetic surface anisotropy (MSA) of Pd/Co100−xSmx/Pd (111) trilayers, where Sm content x was varied from 0 to 11. All samples show perpendicular anisotropy due to the strong MSA at the interfaces. The MSA significantly increases with x and attains a maximum value of 0.60 erg/cm2 at x(similar, equals)8.3, which is 36% larger than that of pure Co (x=0). The volume term of the magnetic anisotropy shows a similar behavior as the MSA. The appreciable increase in MSA is considered to be due to the enhancement of orbital moment of Co by the addition of Sm. © 2001 American Institute of Physics.
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  • 78
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 90 (2001), S. 4095-4102 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: Ferroelectric twin-domain structures in epitaxial Pb(Zr, Ti)O3 (PZT) thin films grown on various single-crystal substrates such as MgO(001), KTaO3(001), and SrTiO3(001) were investigated by two-dimensional reciprocal space mapping using synchrotron x-ray diffraction. Each system showed a characteristic domain structure. PbTiO3 thin films grown on MgO(001) showed highly c-axis oriented domain structures consisting of a periodic array of 90° twinlike domains. Perfectly c-axis oriented films were obtained on SrTiO3(001), while the films grown on KTaO3(001) showed a-domain dominant structures with a small amount of c domains embedded in matrix a domains. Contributions of net elastic strain stored in each heteroepitaxial layer and its relaxation to the final domain structures were evaluated considering thermodynamic equilibrium relief of coherency strain by misfit dislocation generation at the film growth temperature. A comparison between theoretical consideration and experimental results clearly demonstrates that the nature of effective misfit strain and its relaxation during film growth play a critical role in the formation of domain structures in epitaxial PZT thin films. Moreover, it was verified that the control of such critical strain factors by changing film composition could modify dominant domain structures in a drastic way. In addition, it was found that the crystalline quality of the films is closely correlated to the tilting nature of the domain structure in each system and coherency strain across the 90° domain boundary is accommodated mainly by the domain tilt of the minor domain. © 2001 American Institute of Physics.
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  • 79
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 90 (2001), S. 3200-3204 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: In this article an interesting result has been reported to highlight the physical implication of finite nonzero electron inertial delay in acoustic oscillations of an ion-beam plasma system. A simple fluid model has been used to demonstrate the excitation of relaxation type resonant instability on the electron inertial delay time scale. Physical arguments have been included to understand and explain the driving mechanism of the instability and its utility to comprehend the ion-beam driven oscillations in plasma sheath experiments. The physical nature and origin of the potential relaxation instability has been correlated to the electron inertial delay effect in the ion current carrying plasma system. © 2001 American Institute of Physics.
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  • 80
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 90 (2001), S. 3205-3211 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: We report on the effect of Ar addition to an O2 plasma on photoresist etching in an inductively coupled, traveling wave driven, large area plasma source (LAPS). We also develop a simplified spatially varying O2/Ar mixture discharge model corresponding to the LAPS in a two-dimensional geometry in order to account for the effect of Ar addition. A photoresist etch kinetics model and spatially varying O2/Ar mixture discharge model are used to explain the experimental data. We find that the addition of 50% Ar increases the plasma density and etch rate approximately by a factor of 2. From the simulation we find that argon metastables (Ar*) play an important role in the mixture plasma. The simulation predicts an enhancement in O-atom density due to Ar addition, even in the presence of dilution of the feed gas. The experimental data and predicted etch rates from the simulation are generally in good agreement, indicating that the increase in the etch rate with Ar addition is due to both the increase in the plasma density and the enhancement in O-atom density attributable to the dissociation of O2 by Ar*. © 2001 American Institute of Physics.
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  • 81
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 90 (2001), S. 3212-3218 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: An experimental investigation of a single-gap pseudospark was conducted using a flexible discharge chamber. The voltage breakdown characteristics were studied against a wide range of parameters such as gas pressure, gap separation, cathode cavity depth, cathode aperture size, external capacitance and applied voltage. An empirical formula, VB=(0.20±0.05) p−4.02±0.18 d−1.77±0.01, was obtained for the breakdown voltage VB in kV, given the gas pressure p in Torr and the gap separation d in mm. The electron beam extracted from this single gap was also studied and a current of up to 100 A was measured at 10 kV. © 2001 American Institute of Physics.
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  • 82
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 90 (2001), S. 4152-4158 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: Micrometric, irregularly shaped Fe particles with a nanocrystalline structure have been prepared by mechanical attrition through ball-milling. Electron holography has been employed to visualize the stray field emerging from isolated Fe particles, both at 300 K and at selected temperatures T≤1200 K, from which indirect information on the magnetic domain configuration has been inferred. By complementary x-ray diffraction and transmission electron microscopy investigations a relationship has been established between the changes of the leakage field and of the microstructure upon annealing: it indicates that the structural evolution is accompanied by strong modifications in the interior magnetization pattern. This relationship finds explanation in the framework of the random anisotropy model, including temperature-induced reversible variations in the exchange correlation length and saturation magnetization. Moreover, the role played by the overall geometrical features of the particles in the determination of the actual domain configuration has been investigated. © 2001 American Institute of Physics.
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  • 83
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 90 (2001), S. 4159-4162 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: Insulating nanogranular-type tunnel magnetoresistive thin films made of (Fe or Fe–Co)–(Mg-fluoride) have been investigated. The films were prepared by a tandem deposition method, using Fe, Co, or Fe+Co metal and MgF2 insulator targets. The granular structure was found to consist of Fe or Fe–Co based nanogranules surrounded by thin intergranules of Mg based fluoride with the MgF2 crystal structure. A magnetoresistance value of 13.3% at room temperature and 10 kOe, the largest values ever reported, were obtained at the compositions of 32 vol %(Fe0.51Co0.49)–(Mg–F). To increase the magnetic field sensitivity of the magnetoresistance, a granular-in-gap film consisting of an (Fe–Co)–(Mg–F) granular thin film filling a narrow gap in a soft magnetic Permalloy thin film was prepared. A remarkably high magnetoresistance of 4% or more at 1–2 Oe was obtained. © 2001 American Institute of Physics.
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  • 84
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 90 (2001), S. 4175-4183 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: In this work we present a detailed structural characterization by Raman spectroscopy of hydrogenated amorphous silicon (a-Si:H) and of nanostructured silicon (ns-Si:H) thin films grown in radio-frequency plasma. The ns-Si:H thin films, also called polymorphous Si thin films, consist of a two-phase mixture of amorphous and ordered Si. The Raman spectra were measured at increasing laser intensities. Very low laser power densities (∼1 kW/cm2) were used to thoroughly analyze the structure of as-deposited thin films. Higher Raman laser powers were found to induce the crystallization of the films, which was characterized by the appearance of a sharp peak around 500 cm−1. This was attained faster in the ns-Si:H than in the conventional a-Si:H thin films because the silicon-ordered particles cause a heterogeneous nucleation process in which they act as seeds for crystallization. The laser power densities for film crystallization, crystal size, and surface temperature were determined from this Raman analysis. The validity and application ranges of the different models that can be used to calculate these parameters are critically discussed. © 2001 American Institute of Physics.
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  • 85
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 90 (2001), S. 4184-4190 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: Porous silicon (PS) based metal/PS/p-Si structures with PS layer of different thickness were prepared on moderate- and high-resistivity substrates. Measurements of current–voltage (I–V) characteristics and impedance at various temperatures were used for the investigation of the electrical properties of these structures. Electrical properties of the structures with relatively thin (1 μm) PS layer significantly differ from those of thick structures. The exponential forward bias I–V dependencies for thin structures spread over several orders of magnitude with a low value of quality factor (close to 2) and have activation temperature dependencies with an activation energy equal to half the c-Si band gap. The reverse current has a square root dependence on the reverse bias voltage and the activation energy is equal to half the c-Si band gap. Therefore, it was concluded that the reverse and forward currents in thin PS-based device structures were determined by the generation and recombination of carriers in the depletion region of the c-Si substrate. It was shown that a large area spreading current exists in structures made on highly resistive substrates, which appears to be due to a highly conductive inverse (n-type) layer formed in the p-Si substrate at the PS/p-Si heterojunction. The spreading effect leads to high reverse currents and high capacitance of the device structures made on highly resistive substrates. © 2001 American Institute of Physics.
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  • 86
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 90 (2001), S. 2504-2510 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: We report photoemission spectroscopic studies of zinc sulfide nanocrystallites in the quantum size regime. The nanocrystallites studied have average sizes of 1.8, 2.5, and 3.5 nm and narrow size distributions as determined from UV-visible absorption spectroscopy, as well as x-ray diffraction and high-resolution transmission electron microscopy. Analysis of sulfur core levels from the nanocrystallites show the presence of the three types of sulfur species corresponding to the core, the surface, and the capping layer of the nanocrystallites. We show that a quantitative analysis of these different sulfur components can be used to estimate the sizes of the nanocrystallites; thus, the obtained sizes are in good agreement with the sizes determined independently from small angle x-ray diffraction and high-resolution electron microscopy. © 2001 American Institute of Physics.
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  • 87
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 90 (2001), S. 2498-2503 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: The size and depth distributions of pores in silica-based intermetal-dielectric materials were studied using monoenergetic positron beams. Doppler broadening spectra of the annihilation radiation and lifetime spectra of positrons were measured for methyl-silsesquioxane (MSSQ) spin-on-glass films. The size distribution of pores in the MSSQ films fabricated with 8% porogen load was found to be bimodal, with the major peaks located at 3 and 8 nm3. Increasing the porogen load from 8% to 40% caused the smaller pores (3 nm3) to disappear and 30-nm3 ones to appear; these pores were considered to be interconnected, and this structure makes it possible for positronium (Ps) atoms to find paths towards the surface and to escape into vacuum. The 8%-porogen MSSQ films had low porosity near the Si substrate. From measurements of the temperature dependence of the self-annihilation rate of ortho-Ps, we discuss the relationship between o-Ps emission into vacuum and the pore structure. © 2001 American Institute of Physics.
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  • 88
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 90 (2001), S. 2492-2497 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: It has been shown theoretically and demonstrated experimentally that shear horizontal (SH) surface waves can exist when the surface of an isotropic substrate is perturbed by a strong corrugation, for instance consisting of deep grooves etched in the substrate, whereas these waves cannot exist without this perturbation. It is shown in this article that a periodic array of metallic electrodes (wires) exhibiting large aspect ratios deposited over a piezoelectric substrate give rise to surface acoustic waves with general polarization. The admittance of an interdigitated transducer, which is a basic tool for predicting the waves parameters, is calculated by a combination of finite element analysis and a boundary integral method. This approach has been extended to obtain the polarization of the acoustic waves. For different piezoelectric substrates, we predict various surface acoustic modes and their polarization. Along with mostly SH modes, we also find modes mostly polarized in the sagittal plane. We discuss the frequency behavior of the surface modes as a function of the electrode height compared to the period. © 2001 American Institute of Physics.
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  • 89
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 90 (2001), S. 2511-2516 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: The nanocrystalline MnxFe3−xO4 (x=0, 1.18, 1.56, and 1.9) spinel ferrite thin films were investigated by means of the x-ray absorption spectroscopy and x-ray magnetic circular dichroism at the Mn and Fe L2,3 edges. The cationic distributions of thin spinel ferrite films for x=1.18 and 1.56 were determined using a crystal field atomic multiplets scheme for arbitrary symmetry. The results are compared with the distribution of cations obtained from the differential thermogravimetry analysis of fine powders of corresponding compositions. © 2001 American Institute of Physics.
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  • 90
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 90 (2001), S. 2522-2527 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: A multitechnique approach, consisting of x-ray diffraction, differential thermal analysis, low frequency Raman scattering from the acoustic vibrations of nanoclusters, and transmission electron microscopy associated with selected area diffraction, has been used to study the nucleation and crystallization processes in SiO2–Ga2O3–K2O glasses. The specific aim was to determine the structure and the size distribution of nanoparticles embedded in the glass matrix. It has been found that nearly spherical nanocrystals of β-Ga2O3, with a size of ∼2–3 nm, nucleate during thermal treatments at 900 °C. Crystallization was observed after annealing at higher temperature. The amount of the crystalline phase and the mean size of the nanocrystals increased with heat treatment, time and temperature. β-Ga2O3 was the only crystalline phase to appear in all glass samples. © 2001 American Institute of Physics.
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  • 91
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 90 (2001), S. 2517-2521 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: Optical absorption of nanocrystalline thin films can be influenced by the presence of both porosity and grain size effects. If both are present simultaneously, their effects are difficult to separate. In this study it is shown that the combination of uv-vis transmittance and reflectance measurements on porous CeO2 films provides enough data to make this separation. The CeO2 films were prepared by deposition of nanosized (∼5 nm) particles from a water colloidal suspension onto sapphire and subjecting these films to sintering temperatures sufficiently high to provide a series of films with a typical thickness of 0.6 μm with a wide range of grain sizes and porosity. X-ray diffraction, scanning electron microscopy, ellipsometry, and profilometry were used to characterize the films and to compare the observed grain sizes and porosity with that obtained from optical measurements. All of the techniques used gave results on porosity and grain size which were in good agreement, from 15% to 50% and 5 to 65 nm, respectively. For these porous films it was found that the changes in absorption which are normally explained by quantum confinement effects due to the small crystallite size can be attributed primarily to changes in porosity rather than in grain size. © 2001 American Institute of Physics.
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  • 92
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 90 (2001), S. 2528-2532 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: The effect of thermal annealing on the properties of Al–AlOx–Al single electron tunneling transistors is reported. After treatment of the devices by annealing processes in forming gas atmosphere at different temperatures and for different times, distinct and reproducible changes of their resistance and capacitance values were found. According to the temperature regime, we observed different behaviors with regard to the resistance changes, namely the tendency to decrease the resistance by annealing at T=200 °C, but to increase the resistance by annealing at T=400 °C. We attribute this behavior to changes in the aluminum oxide barriers of the tunnel junctions. The good reproducibility of these effects with respect to the changes observed allows the proper annealing treatment to be used for postprocess tuning of tunnel junction parameters. Also, the influence of the annealing treatment on the noise properties of the transistors at low frequency was investigated. In no case did the noise figures in the 1/f regime show significant changes. © 2001 American Institute of Physics.
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  • 93
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 90 (2001), S. 2533-2537 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: Electron-beam evaporation of metal contact is commonly used in the fabrication of semiconductor devices. We have observed that device irradiation by x-ray photons, which are generated by electrons striking the metal (titanium or gold) to be evaporated, has a strong impact on the characteristics of diamond devices used for radiation detection. It results in an improvement of the detector charge collection efficiency by a factor of 1.5 with respect to nonirradiated devices (standard thermal evaporation). Thermally stimulated current measurements showed that this effect is related to deep trap filling by free carriers generated in diamond by x-ray photons impinging the device during e-beam evaporation. Trap filling results in an increase of the free carrier drift distance before trapping. Study of contact annealing and the thermal stability of trap filling showed that charge detrapping at temperatures above 200 °C annihilates the observed detector sensitivity improvement. © 2001 American Institute of Physics.
    Materialart: Digitale Medien
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  • 94
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 90 (2001), S. 2538-2543 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: The avalanche multiplication and excess noise properties of a range of submicron Si diodes have been measured and analyzed using a model for impact ionization which includes the effect of dead space, modified to allow for a gradual onset of ionization, with realistic threshold energies. Good agreement is achieved between the predictions of this "soft dead space" model and measurements of multiplication and excess noise, both on a range of submicron diodes with uniform electric fields and also on a p+n diode with a highly nonuniform electric field. © 2001 American Institute of Physics.
    Materialart: Digitale Medien
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  • 95
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 90 (2001), S. 670-674 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: Instead of the conventional flat collimator a curved collimator was used in double-crystal x-ray topography. The curvature of the collimator was adjusted so that the Bragg condition for x-ray diffraction was uniformly satisfied over a wide area of the silicon wafer. The image area of the wafer was wide enough to characterize the local lattice distortion induced by test element groups of metal–oxide–semiconductor capacitors formed on the wafer. The lattice distortion was measured as variations in lattice plane spacing and in lattice plane orientation using local angular deviations from the Bragg condition. These angular deviations were determined by fitting the x-ray intensities measured at the same point on a series of topographs taken around the Bragg peak to the rocking curve of the sample. The lattice plane spacing changed abruptly by 10−6 at the boundary between the areas of gate oxide (11 nm thick) and the areas of field oxide (400 nm thick), and showed less variation within these areas. The lattice plane orientation changed monotonically in each area, with an inclination of the order of 10−5 rad within the largest gate oxide area (5×5 mm2). © 2001 American Institute of Physics.
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  • 96
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: Crystalline to amorphous transition and subsequent microstructural evolution in silicon induced by Ar+-ion implantation over a wide range of ion fluences (6×1013–1×1017 cm−2) have been investigated by spectroscopic ellipsometry. In the evaluation of the optical and microstructural properties of the damaged layer, the contribution of the surface overlayer to the measured dielectric spectra was separated by fitting a multilayer model with an effective medium approximation. The best fit to the dielectric spectra for disordered silicon could be obtained by taking our highest-fluence implanted (fluence=1×1017 ions/cm2) amorphous silicon (a-Si) data as reference data instead of a-Si data available in the handbook. The derivative spectra as a function of fluence show a distinct and sharp transition from the crystalline to amorphous phase. The threshold fluence for this transition is derived from fitting. Evaluation of standard sum rules and optical moments for imaginary part of the pseudodielectric function reveals no substantial change in various physical parameters below the transition indicating their insensitivity to point defects, while it shows a large change with fluence above the threshold for amorphization. The disorder induced changes in the effective dielectric constant, number of valence electrons per atom participating in optical transition, Penn gap energy, average bond length, coordination number, effective dispersion oscillator energy, an average strength of the interband optical transition with fluence is discussed on the basis of microstructural evolution and corresponding band structure modification. It is also shown that the dielectric functions of damaged silicon are well represented by a sum of six classical Lorentz oscillators. With increasing fluences, each of the oscillator amplitude decreases and linewidth increases except for the 3.3 eV transition which shows increasing amplitude with fluence. These results are discussed in the context of short-range order/disorder and effective band gap reduction along with flattening of the bands with increasing fluence above the amorphization threshold. © 2001 American Institute of Physics.
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  • 97
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 90 (2001), S. 675-681 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: Since the prediction of Liu and Cohen [Science 245, 841 (1989)] of the potential extraordinary mechanical properties of crystalline β-C3N4, many authors have attempted its synthesis. However, in most cases, the obtained materials are amorphous phases with a complex bonding structure. Their characterization is complicated due to the absence of a reference compound, the lack of long-range order, and the poor knowledge about their bonding structure. In this article, we present 1H, 13C, and 15N solid-state nuclear magnetic resonance (NMR) measurements for the determination of the bonding types in amorphous CNx films. NMR measurements do not require long-range order and are able to clearly identify the signals from the sp2- and sp3-bonded phases. The analysis of the data obtained by other characterization techniques, such as infrared spectroscopy, x-ray photoelectron spectroscopy, electron energy-loss spectroscopy, and x-ray absorption near-edge spectroscopy on the same sample, based on the information acquired by NMR, enables the description of a structure model for the studied amorphous-CNx phase prepared by dc-magnetron sputtering and to revise the interpretation found in the literature. © 2001 American Institute of Physics.
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  • 98
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 90 (2001), S. 689-695 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: Using a molecular-dynamics simulation, we study the buildup of damage in an a-Si specimen bombarded by Si atoms with energies between 10 and 150 eV for fluences up to 1.4×1015 cm−2, i.e., an equivalent of 2 monolayer growth. The production rate of overcoordinated atoms increases with the bombarding energy; we analyze its fluence and bombarding-energy dependence in detail. The number of undercoordinated atoms decreases for low-energy bombardment due to the saturation of dangling bonds at the surface; for higher bombarding energies, it increases slightly, but shows only little dependence on bombarding energy. The depth distribution of the damage, of the induced stress, and of the atom relocation in the target demonstrate that bombardment modifies the target at considerably greater depths than the ion range. © 2001 American Institute of Physics.
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  • 99
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 90 (2001), S. 696-698 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: Single-shock (Hugoniot) equation-of-state data of shock-compressed C (graphite) are reported at pressures of 480 and 760 GPa (7.6 Mbar). Graphite is shock-compressed completely into a diamond-like phase at pressures below 80 GPa. At pressures of 80–800 GPa comparison of an ensemble of experimental Hugoniot data for shock-compressed graphite and diamond, and theoretical calculations of the Hugoniots of graphite and diamond, and the 0 K isotherm of diamond suggest diamond melts at ∼300 GPa on the Hugoniot of graphite and that the diamond phase is the ground-state structure of C up to at least 600 GPa. © 2001 American Institute of Physics.
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  • 100
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 90 (2001), S. 682-688 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: We have studied the yield and the time evolution of pulsed laser induced photoluminescence in proton irradiated and thermally annealed amorphous hydrogenated silicon carbon alloys prepared by plasma enhanced chemical vapor deposition. Three major fluorescence decay channels have been observed with decay rates independent from proton irradiation and thermal annealing. Lack of correlation between yield and average decay time suggests a very simple phenomenological model which allows evaluation of the nonradiative time constant which is found to be linearly correlated with the photoluminescence yield. Our model suggests that radiative recombination occurs via exciton decay while the nonradiative recombination is driven by the trapping of carriers in defects states. © 2001 American Institute of Physics.
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