ALBERT

All Library Books, journals and Electronic Records Telegrafenberg

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

Export
Filter
  • kinetics  (58)
  • phosphorus  (51)
  • Springer  (109)
  • American Meteorological Society
  • Periodicals Archive Online (PAO)
  • 1995-1999  (109)
  • 1990-1994
  • 1935-1939
  • 1997  (109)
Collection
Keywords
Publisher
  • Springer  (109)
  • American Meteorological Society
  • Periodicals Archive Online (PAO)
  • Wiley-Blackwell  (70)
Years
  • 1995-1999  (109)
  • 1990-1994
  • 1935-1939
Year
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of applied electrochemistry 27 (1997), S. 1198-1206 
    ISSN: 1572-8838
    Keywords: alloy ; amorphous ; anomalous ; hydrogen ; iron ; nickel ; phosphorus ; plating
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Electrical Engineering, Measurement and Control Technology
    Notes: Abstract In this study we have investigated the electrodeposition of amorphous iron–nickel–phosphorus alloys from a sulfate electrolyte. Fe-Ni alloys are known to exhibit an ’anomalous‘ type of plating behaviour in which deposition of the less noble metal is favoured. We have found that the codeposition of phosphorus from hypophosphite in the electrolyte led to a reversal to a ’normal‘ behaviour. This reversal was due both to the suppression of iron and enhancement of nickel partial currents. The overall deposition process is dominated by the hydrogen evolution reaction. This is exacerbated by the low pH needed to codeposit sufficient phosphorus to achieve an amorphous structure.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 2
    ISSN: 1572-8757
    Keywords: characterisation ; equilibria ; kinetics ; micropore size distribution ; n-butane ; nutshell
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Physics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Abstract Adsorption equilibria and dynamics ofn-butane on two activated carbon samples prepared from the physical activation of nutshell are studied in this paper. The micropore size distribution (MPSD) is considered as the main source of solid heterogeneity. Lennard-Jones' potential theory and Dubinin's theory (TVFM) are used in the equilibria data to derive the MPSD, which is well fitted by a Gamma distribution function. The adsorption energy distribution derived from the MPSD is very asymmetric for both the samples studied, and this energy distribution used in the HMSD/HMSMD kinetics models for the study of adsorption dynamics ofn-butane.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Cellulose 4 (1997), S. 1-5 
    ISSN: 1572-882X
    Keywords: paper ; degradation ; ageing ; kinetics ; modelling
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 4
    ISSN: 1572-8773
    Keywords: aromatic donor molecules ; horseradish peroxidase ; kinetics ; lactoperoxidase
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Chemistry and Pharmacology
    Notes: Abstract Based on kinetic evidence, it has been shown for the first time that the mode of binding of aromatic donor molecules is similar in horseradish peroxidase and lactoperoxidase; also that the nature of the heme plays an important role in the reaction with hydrogen peroxide, and has no effect on the reaction of the intermediate compound II with aromatic substrates.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Environmental geology 30 (1997), S. 224-230 
    ISSN: 1432-0495
    Keywords: Key words Sediment ; Washington ; DC ; Pollution ; phosphorus ; nutrients
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract  Sediments in the rivers and basins around Washington, DC, have high concentrations of phosphorus, which, based on geographic distributions, is largely derived from urban runoff and municipal sewage. Dissolved-particulate phosphate exchange reactions and biological uptake of dissolved phosphorus from the water column may be an added source of phosphorus to the sediments. Concentrations of total sedimentary phosphorus ranged from 24 to 56 μm P/g-dw, and were highest in areas near combined sewer outfalls. As a part of this study, sedimentary phosphorus was fractionated into Fe-P, Ca-P, Al-P, and organic phases using a selective-sequential leaching procedure. The distribution of the phases in all sediments analyzed follow the order , Fe-P〉Ca-P〉Al-P. Spatial variations in the amounts of phosphorus in the different phases is related to the sources of phosphorus to the area. The proportions of occluded Al-P and organic P are 10–20% of the total P, respectively. This suggests that phosphorus from natural sources is small compared to anthropogenic inputs in this area. The high leachable Fe-P and Ca-P in these sediments might contribute a substantial amount of P to the water column under conditions of remobilization.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 6
    Electronic Resource
    Electronic Resource
    Springer
    European journal of clinical pharmacology 52 (1997), S. 505-506 
    ISSN: 1432-1041
    Keywords: Key words Ibuprofen; effervescent tablets ; kinetics ; bioavailability
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Medicine
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Journal of thermal analysis and calorimetry 48 (1997), S. 917-923 
    ISSN: 1572-8943
    Keywords: copper compound ; coupled technique ; kinetics ; macrocyclic complex ; non-isothermal
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The thermal decomposition process of the complex [Cu(NBOCTB)][Cu(NO3)4] H2O has been studied by TG and DTG technique, and possible intermediates of the thermal decomposition have also been conjectured from the TG and DTG curves. The results suggest that the decomposition of the complex involves five steps: The non-isothermal kinetics of steps 1, 2 and 3 have been studied by means of the Achar and Coats-Redfern method based on TG and DTG curves. Step 1 is a ‘Coring and Growth’ mechanism (n= 1), its kinetic equation may be expressed as: dα/dt=Ae−E/RT(1−α). Steps 2 and 3 are both ‘two order chemical reaction’ mechanisms, their kinetic equations can be expressed as: dα/dt=Ae−E/RT(1−α)2.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 8
    Electronic Resource
    Electronic Resource
    Springer
    Journal of thermal analysis and calorimetry 49 (1997), S. 87-94 
    ISSN: 1572-8943
    Keywords: kinetics ; poly(di-propyl itaconates) ; polymer structure ; thermal degradation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Non-isothermal thermogravimetry was performed in a dynamic nitrogen atmosphere, on a series of poly(di-n-propyl itaconates) (PDnPI) and poly(di-iso-propyl itaconates) (PDiPI) which had been prepared in the presence of various amounts of the chain transfer agentn-dodecyl mercaptan (DDM). Differential thermogravimetry (DTG) showed that both polymers degraded in two stages. The DTG curve of PDnPI had a large first peak followed by a smaller shoulder, whereas the DTG curve of PDiPI was composed of two peaks of almost equal heights. The addition of DDM during the polymerisations in both cases resulted in a similar decrease in the relative area of the first peak.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 9
    Electronic Resource
    Electronic Resource
    Springer
    Journal of thermal analysis and calorimetry 49 (1997), S. 183-191 
    ISSN: 1572-8943
    Keywords: kinetics ; thermooxidative degradation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The results of non-isothermal kinetic analysis of the thermooxidative degradation in air and oxygen of an unsaturated polyester resin are presented. It has been shown that the thermooxidative degradation in oxygen occurs at lower temperatures than the thermooxidative degradation in air. The kinetic parameters of the thermooxidative degradation depend on the heating rate and the oxygen pressure. Two straight lines of InAvs. E (A is the preexponential factor andE is the activation energy), characteristic for the compensation effect, have been obtained for the thermooxidative degradation in air and in oxygen respectively. The difference between the intercepts of these straight lines can be explained by dependence of the pre-exponential factor on the oxygen pressure.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 10
    Electronic Resource
    Electronic Resource
    Springer
    Journal of thermal analysis and calorimetry 49 (1997), S. 857-862 
    ISSN: 1572-8943
    Keywords: analytical methods ; kinetics ; powder milk ; temperature
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract This work present comparative results on powder milk storage quality, obtained from analytical methods. Protein content was determined conventional (Kjeldahl) and colorimetric with biuret reagent at 540 nm and integral quality by thermogravimetric and biological methods. A method was developed for the protein separation of powder milk. Powder milk was submitted to degradation processes at 45, 60 and 80°C for 20 days. The results indicated that protein content values were inconsistent if determinations by Kjeldahl and colorimetric methods and biological tests were compared. There is evidence of thermal decomposition of powder milk as detected by biological and thermogravimetric methods.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 11
    Electronic Resource
    Electronic Resource
    Springer
    Journal of thermal analysis and calorimetry 49 (1997), S. 937-941 
    ISSN: 1572-8943
    Keywords: kinetics ; mebendazole ; quality control ; technology
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract A study was made of the thermal behavior of the starting materials, their mixtures and the resulting mebendazole tablets. The thermal curves were obtained with a Shimadzu thermobalance, model TGA-50, using an air flow of 50 mL min−1 and a heating rate of 10°C min−1 in the temperature interval 30–900°C. The reaction constant velocities for the mebendazole salt and tablets were determined isothermally, using the Arrhenius expression. The thermal stability of mebendazole tablets is lower than that of the mebendazole salt, due to the presence of starch and lactose in the composition. Analysis of the data reveals that thermogravimetry is a powerful tool in pharmaceutical technology and quality control.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 12
    Electronic Resource
    Electronic Resource
    Springer
    Journal of thermal analysis and calorimetry 48 (1997), S. 343-348 
    ISSN: 1572-8943
    Keywords: activation energy ; combustion ; crude oil ; differential scanning calorimetry ; kinetics ; thermogravimetric analysis
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract A weighted mean activation energy method was applied to describe the reactivity and combustibility of crude oils via simultaneous TG/DTG. Thermal experiments were conducted with a non-isothermal method at a heating rate of 10
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 13
    Electronic Resource
    Electronic Resource
    Springer
    Journal of thermal analysis and calorimetry 48 (1997), S. 385-401 
    ISSN: 1572-8943
    Keywords: dehydration and decomposition ; kinetics ; Fe(III) chloride
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Fe(III) chloride hydrate (FeCl3·xH2O) undergoes simultaneous dehydration and dehydrochlorination from its molten phase in the temperature range 100–200
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 14
    Electronic Resource
    Electronic Resource
    Springer
    Journal of thermal analysis and calorimetry 48 (1997), S. 413-425 
    ISSN: 1572-8943
    Keywords: alcoholic fermentation ; kinetics
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The control of alcoholic fermentation is necessary to obtain a quality wine. The overall dynamic and phenomenological modelling already applied to the simulation of this type of reaction enables us to suggest, in this study, a simple model (of which two variants), are relatively satisfactory. The first variant does not take into account the variation of the ambient temperature; the model translates exactly the first phase of the experimental curve or the moment when highest temperatures are measured. The relaxation phase is less well described because of influence of variation of the ambient temperature is relatively important. The second one considers the system depending on the ambient temperature, the model is correct for the relaxation phase too (the reaction temperature decreases, it nears the ambient temperature). The advantage of this model: It permits one to determine the reaction enthalpy and the kinetic parameters.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 15
    Electronic Resource
    Electronic Resource
    Springer
    Journal of thermal analysis and calorimetry 48 (1997), S. 623-634 
    ISSN: 1572-8943
    Keywords: bismalleimide/carbon fiber composite ; DMA ; kinetics ; TSC
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The correlation between structure/microstructure and thermomechanical properties has been investigated by the Thermally Stimulated Creep (TSC) technique in a high performance thermostable thermoset matrix composite. The high resolving power of this technique allows us to analyse the α retardation mode. The kinetics of molecular movements liberated at the glass transition has been investigated by the technique of fractional loading: the analysis of each elementary process gives the real compliance and the retardation time as a function of temperature. The values of the activation parameters show the existence of a compensation phenomenon which characterizes the microstructure. It also gives access to the loss compliance of the composite material as a function of temperature and frequency. The predictive calculation of loss compliance has been validated by the results obtained by dynamic mechanical analysis (DMA).
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 16
    Electronic Resource
    Electronic Resource
    Springer
    Journal of thermal analysis and calorimetry 48 (1997), S. 769-782 
    ISSN: 1572-8943
    Keywords: kinetics ; non-linear optimization ; reactor time constants ; software ; time constants of sensors
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract All temperature sensors have a finitely time constant. The influence of the sensor time constant gts on the results of kinetic evaluation is demonstrated at four reaction types. The ignorance of the sensor indolence gives incorrect activation parameters. Therefore the determination of Τs is necessary. For the estimation of parameters the nonlinear evaluation program TA-kin was used. With its help it is possible to find the real parameters, also when Τs=32 s, if the real Τs-value was entered.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 17
    Electronic Resource
    Electronic Resource
    Springer
    Journal of thermal analysis and calorimetry 49 (1997), S. 1517-1525 
    ISSN: 1572-8943
    Keywords: β-cyclodextrin ; cinnamyl alcohol ; kinetics ; thermal analysis
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The stability of β-cyclodextrin-cinnamyl alcohol inclusion complex (β-CD·C9H10·8H2O) was investigated using TG and DSC. The mass loss took place in three stages: the dehydration occurred between 50–120°C; the dissociation of β-CD·C9H10O occurred in the range of 210–260°C; and the decomposition of β-CD began at 280°C. The dissociation of β-CD·C9H10O was studied by means of thermogravimetry, and the results showed: the dissociation of β-CD·C9H10O was dominated by a two-dimensional diffusion process (D2). The activation energyE was 161.2 kJ mol−1, the pre-exponential factorA was 4.5×1013 min−1. Cyclodextrin is able to form inclusion complexes with a great variety of guest molecules, and the interesting of studies focussed on the energy binding cyclodextrin and the guest molecule. In this paper, β-cyclodextrin-cinnamyl alcohol inclusion complex was studied by fluorescence spectrophotometry and infrared absorption spectroscopy, and the results show: the stable energy of inclusion complexes of β-CD with weakly polar guest molecules consists mainly of Van der Waals interaction.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 18
    Electronic Resource
    Electronic Resource
    Springer
    Journal of thermal analysis and calorimetry 49 (1997), S. 1553-1564 
    ISSN: 1572-8943
    Keywords: deconvolution ; differential scanning calorimetry ; feedforward neural networks ; kinetics ; signal filtering ; simulations ; thermal analysis
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Feedforward neural networks have been used for kinetic parameters determination and signal filtering in differential scanning calorimetry. The proper learning function was chosen and the network topology was optimized, using an empiric procedure. The learning process was achieved using simulated thermoanalytical curves. The resilient-propagation algorithm have led to the best minimization of the error computed over all the patterns. Relative errors on the thermodynamic and kinetic parameters were evaluated and compared to those obtained with the usual thermal analysis methods (single scan methods). The errors are much lower, especially in presence of noisy signals. Then, our program was adapted to simulate thermal effects with known thermodynamic and kinetic parameters, generated electrically, using a PC computer and an electronic interface on the serial port. These thermal effects have been generated by using an inconel thread.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 19
    Electronic Resource
    Electronic Resource
    Springer
    Journal of thermal analysis and calorimetry 49 (1997), S. 1467-1475 
    ISSN: 1572-8943
    Keywords: CRTA ; DSC ; kinetics ; synthetic brochantite ; TG-DTA ; thermal decomposition
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The reaction pathway of the thermal decomposition of synthetic brochantite, Cu4(OH)6SO4, to copper(II) oxide was investigated through the detailed kinetic characterization of the thermal dehydration and desulferation processes. The dehydration process was characterized by dividing into two overlapped kinetic processes with a possible formation of an intermediate compound, Cu4O(OH)4SO4. The dehydrated sample, Cu4O3SO4, was found first to be amorphous by means of XRD, followed by the crystallization to a mixture of CuO and CuO-CuSO4 at around 776 K. The specific surface area and the crystallization behaviour of the amorphous dehydrated compound depend largely on the dehydration conditions. The thermal desulferation process is influenced by the gross diffusion of the gaseous product SO3, which is governed by the advancement of the overall reaction interface from the top surface of the sample particle assemblage to the bottom.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 20
    Electronic Resource
    Electronic Resource
    Springer
    Journal of thermal analysis and calorimetry 50 (1997), S. 455-462 
    ISSN: 1572-8943
    Keywords: kinetics ; statistical analysis
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract A statistical technique based on the Wilcockson criterion is suggested for estimation of the reproducibility of thermoanalytical experiments. Reduction of the whole physicochemical process to a quasi-one-stage process is described.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 21
    Electronic Resource
    Electronic Resource
    Springer
    Journal of thermal analysis and calorimetry 50 (1997), S. 425-430 
    ISSN: 1572-8943
    Keywords: decomposition ; kinetics ; non-isothermal
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The authors present the results concerning the thermal behaviour of three polynuclear coordination compounds of Nd(III) and Co(II) or Fe(III) with triptophan. For the dehydration steps the values of the non-isothermal kinetic parameters have been determined.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 22
    Electronic Resource
    Electronic Resource
    Springer
    Journal of thermal analysis and calorimetry 49 (1997), S. 1227-1241 
    ISSN: 1572-8943
    Keywords: inorganic sulphates ; kinetics ; mechanism ; thermodynamics
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Thermal decomposition of different inorganic sulphates are presented. A number of techniques, but mainly TG and DTA, are used to prove the mechanism and kinetics of CaSO4, BaSO4, FeSO4·xH2O, Al2(SO4)3·xH2O under various gas atmospheres. It is shown how the partial pressure of gas components and heating rate may effect the mechanism and kinetic parameters. There are also examples on the effects of some additives and initial treatment on the thermal processes. On the base of the results obtained some recommendations are given concerning the precautions to be taken into account in the thermal decomposition studies and the sulphur recovering.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 23
    Electronic Resource
    Electronic Resource
    Springer
    Journal of thermal analysis and calorimetry 49 (1997), S. 1477-1484 
    ISSN: 1572-8943
    Keywords: CRTA ; kinetics ; particle size distribution ; rate jump method
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The kinetic curves at infinite temperature for the solid-state reactions of the interface shrinkage type were drawn theoretically by taking account the particle size distribution in the sample mixture. The CRTA curves for the reactions with the particle size distribution can be drawn by utilizing the universal kinetic curves at infinite temperature. The proper kinetic treatment for the CRTA curves with the particle size distribution is discussed in connection with the property of the kinetic equation with respect to the particle size distribution. The present kinetic consideration is taken as a simulation for the reactions with a certain distribution in α among the reactant particles, produced preferably by the mass and heat transfer phenomena during the thermoanalytical measurements. The merit of the rate jump method by a single cyclic CRTA curve is also discussed on the basis of the present results.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 24
    Electronic Resource
    Electronic Resource
    Springer
    Journal of thermal analysis and calorimetry 49 (1997), S. 1161-1170 
    ISSN: 1572-8943
    Keywords: basicity ; dinitramides ; kinetics ; oxidation ; tanδ ; transition temperatures
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The dinitramide salts of ammonia (ADN), hexamethylenetetramine (HDN), potassium (KDN), and sodium (NaDN) showed a linear relationship between the DSC rate of decomposition at the peak maximum and the DEA tanδ value at the low temperature transition peak. As the cation basicity increased in the series ADN〈HDN〈KDN〈NaDN, there was an increase in the low temperature transition peak, the energy barrier for relaxation, and the decomposition peak temperature, and a decrease in the tanδ value at the low temperature transition peak, specific heat capacity, and the rate and enthalpy of decomposition. The more basic salts were more thermally stable (i.e., higher decomposition temperature) and less energetic (i.e., lower enthalpy of decomposition). The more internal free volume (disorder) present in these salts, the higher the rates of relaxation and decomposition. Five aluminum powders of different surface areas were analyzed by DSC in platinum sample pans, and it was found that the enthalpy and rate of oxidation increased as the particle size of Al decreased while the enthalpy of the Al melt decreased. TG showed a two-step weight gain in the oxidation of Al with plateaus in the 650 and 1130°C regions and the percent weight gain increased as the particle size of Al decreased. Variable DSC and TG heating rate studies showed that the activation energies for the first step in the oxidation process increased as the particle size of Al increased.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 25
    Electronic Resource
    Electronic Resource
    Springer
    Journal of thermal analysis and calorimetry 50 (1997), S. 33-50 
    ISSN: 1572-8943
    Keywords: Ba[Cu(C2O4)2(H2O)]·5H2O ; decomposition ; dehydration ; kinetics
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The thermal behaviour of Ba[Cu(C2O4)2(H2O)]·5H2O in N2 and in O2 has been examined using thermogravimetry (TG) and differential scanning calorimetry (DSC). The dehydration starts at relatively low temperatures (about 80°C), but continues until the onset of the decomposition (about 280°C). The decomposition takes place in two major stages (onsets 280 and 390°C). The mass of the intermediate after the first stage corresponded to the formation of barium oxalate and copper metal and, after the second stage, to the formation of barium carbonate and copper metal. The enthalpy for the dehydration was found to be 311±30 kJ mol−1 (or 52±5 kJ (mol of H2O)−1). The overall enthalpy change for the decomposition of Ba[Cu(C2O4)2] in N2 was estimated from the combined area of the peaks of the DSC curve as −347 kJ mol−1. The kinetics of the thermal dehydration and decomposition were studied using isothermal TG. The dehydration was strongly deceleratory and the α-time curves could be described by the three dimensional diffusion (D3) model. The values of the activation energy and the pre-exponential factor for the dehydration were 125±4 kJ mol−1 and (1.38±0.08)×1015 min−1, respectively. The decomposition was complex, consisting of at least two concurrent processes. The decomposition was analysed in terms of two overlapping deceleratory processes. One process was fast and could be described by the contracting-geometry model withn=5. The other process was slow and could also be described by the contracting-geometry model, but withn=2. The values ofE a andA were 206±23 kJ mol−1 and (2.2±0.5)×1019 min−1, respectively, for the fast process, and 259±37 kJ mol−1 and (6.3±1.8)×1023 min−1, respectively, for the slow process.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 26
    Electronic Resource
    Electronic Resource
    Springer
    Journal of thermal analysis and calorimetry 48 (1997), S. 359-366 
    ISSN: 1572-8943
    Keywords: decomposition ; kinetics ; non-isothermal
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Results are presented on the thermal behaviour of two derivatives of malic acid. The decomposition intermediates obtained at about 400
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 27
    Electronic Resource
    Electronic Resource
    Springer
    Journal of thermal analysis and calorimetry 49 (1997), S. 45-56 
    ISSN: 1572-8943
    Keywords: accommodation function ; fractional reaction ; kinetics ; solid-state reaction ; thermal analysis
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The physico-geometric kinetics for the solid-state reactions by thermoanalytical (TA) measurements were reexamined by focusing some fundamental aspects: (1) the fundamental kinetic equation, (2) the kinetic model function, (3) the fractional reaction α, and (4) the apparent kinetic parameters. It was pointed out that some pitfalls in the practical kinetic study are originated by the disagreement between the kinetic information from the TA measurements and the theory of the physico-geometric kinetics. In order to increase the degree of coordination between the theory and practice, several attempts were made from both the theoretical and experimental points of views. The significance of the apparent kinetic parameters was discussed with a possible orientation for obtaining the reliable kinetic parameters.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 28
    Electronic Resource
    Electronic Resource
    Springer
    Journal of thermal analysis and calorimetry 49 (1997), S. 255-260 
    ISSN: 1572-8943
    Keywords: catalytic degradation ; kinetics ; polyethylene
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract HZSM-5 zeolite was screened as catalyst for high density polyethylene degradation at 450
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 29
    Electronic Resource
    Electronic Resource
    Springer
    Journal of thermal analysis and calorimetry 49 (1997), S. 261-268 
    ISSN: 1572-8943
    Keywords: kinetics ; phenol-formaldehyde resins ; pyrolysis-GC ; thermal degradation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Phenol-formaldehyde resins (I andII), synthesised at a monomer feed ratio of F/P = 1.0 and 1.5, were cured at 130
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 30
    Electronic Resource
    Electronic Resource
    Springer
    Journal of thermal analysis and calorimetry 49 (1997), S. 17-32 
    ISSN: 1572-8943
    Keywords: Arrhenius equation ; compensation ; distinguishability ; kinetics ; mechanisms ; nonisothermal
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract This paper is a review of some of the controversial kinetic aspects of thermal analysis, starting from the ‘šesták questions’ posed in 1979 and looking at developments in some areas since that time. Aspects considered include: temperature programmes and variations, models and mechanisms, kinetic parameters, distinguishability and extent of fit of kinetic models, complementary evidence for kinetic models, the Arrhenius equation and the compensation effect. The value of the ideas of non-isothermal kinetics in chemical education is emphasized.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 31
    Electronic Resource
    Electronic Resource
    Springer
    Journal of thermal analysis and calorimetry 49 (1997), S. 1025-1037 
    ISSN: 1572-8943
    Keywords: crystallographic evaluation ; evaluation with difference procedure ; kinetics ; Rietveld refinement ; X-ray diffraction ; temperature resolved
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Time and temperature resolved X-ray diffraction was used for thermal analysis. Series of diffraction patterns were measured, while the samples are heated/cooled stepwise or isothermally with freely selectable temperature programs. The method was applied for the investigation of the phase transitions of ammonium nitrate and HMX (1,3,5,7-tetranitro-1,3,5,7-tetraaza-cyclooctane), when the identification of phases was required. Its capability in the field of kinetics is demonstrated with the isothermal investigation of the solid state reaction of ammonium nitrate with copper oxide and the non-isothermal investigation of the high temperature corrosion of nickel, which was performed by means of a difference procedure. For obtaining structural details peak fitting and Rietveld refinement were applied for the investigation of ammonium nitrate and HMX.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 32
    Electronic Resource
    Electronic Resource
    Springer
    Journal of thermal analysis and calorimetry 49 (1997), S. 617-625 
    ISSN: 1572-8943
    Keywords: combustion ; kinetics ; lignite ; thermal analysis
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Beypazari lignite was investigated by differential scanning calorimetry (DSC), thermogravimetry (TG), high pressure thermogravimetry (HPTG) and combustion cell experiments. All the experiments were conducted at non-isothermal heating conditions with a heating rate of 10°C min−1, in the temperature range of 20–700°C. DSC-TG data were analysed using an Arrhenius-type reaction model assuming a first-order reaction. For the HPTG data the Coats and Redfern equation was used for kinetic analysis. In the combustion cell experiments the Fassihi and Brigham approach was used in order to calculate kinetic data. Finally a comparison is made between the kinetic results.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 33
    Electronic Resource
    Electronic Resource
    Springer
    Journal of thermal analysis and calorimetry 49 (1997), S. 609-615 
    ISSN: 1572-8943
    Keywords: combustion ; crude oil ; kinetics ; thermogravimetric analysis
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract High pressure thermogravimetric analysis (HPTG) was used in order to study the oxidation of crude oil in a porous medium under pressurised conditions for simulation of in-situ combustion during oil recovery. Three distinct reaction regions were observed from the HPTG curves in an oxidising environment subjected to a constant heating rate. These were low temperature oxidation, fuel deposition and high temperature oxidation. The method of Coats and Redfern was used to obtain kinetic parameters and the results are discussed.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 34
    Electronic Resource
    Electronic Resource
    Springer
    Journal of thermal analysis and calorimetry 49 (1997), S. 1527-1533 
    ISSN: 1572-8943
    Keywords: β-cyclodextrin ; cinnamic aldehyde ; kinetics ; thermal analysis
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The stability of the inclusion complex of β-CD with cinnamic aldehyde was investigated by means of TG and DSC. The mass loss takes place in three stages: dehydration occurs at 50–120°C; dissociation of β-CD·C9H8O proceeds in the range 200–260°C; and decomposition of β-CD begins at 280°C. The kinetics of the dissociation of β-CD·C9H8O was studied by means of thermogravimetry both at constant temperature and with linearly increasing temperature. The results demonstrate that the dissociation of β-CD·C9H8O is dominated by a one-dimensional diffusion process. The activation energyE is 160 kJ mol−1, and the pre-exponential factorA is 5.8×1014 min−1. Scanning electron microscope observations and the results of crystal structure analysis are in good agreement with those of thermogravimetry.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 35
    Electronic Resource
    Electronic Resource
    Springer
    Journal of thermal analysis and calorimetry 49 (1997), S. 1485-1492 
    ISSN: 1572-8943
    Keywords: bias ; constant temperature stability ; isothermal crystallization ; kinetics ; oxidative induction time
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Oxidative induction time (OIT), constant temperature stability (CTS) and isothermal crystallization are examples of isothermal time-to-event (TTE) measurements obtained using differential scanning calorimetry. In TTE experiments, a test specimen is heated/cooled at a constant rate from the setup temperature to an isothermal test temperature. Once the test temperature is achieved, a clock is started and the time to the thermal event (e.g., onset to oxidation, thermal decomposition or crystallization exotherm peak) is measured. Such TTE values may be used to rank stability of the material at the test temperature. Some portion of the reaction of interest, however, takes place during the pre-isothermal period as the test specimen approaches the test temperature. This amount of reaction is unmeasured and represents a bias in the resultant TTE value. An equation has been derived and numerically integrated to estimate this bias. This approach shows that the bias is dependent upon the activation energy of the test reaction, the heating/cooling rate used and the temperature range between the melting temperature and the test temperature. For commonly used heating rates, the bias for OIT and CTS tests is small. Further, the myth that isothermal crystallization kinetics determinations required high cooling rates is dispelled with the bias of less than 0.9 min resulting from heating rates as low as 10°C min−1. Knowledge of magnitude of this bias permits the selection of experimental conditions without the expense of high heating/cooling rate apparatus or extra cost cooling accessories.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 36
    Electronic Resource
    Electronic Resource
    Springer
    Journal of thermal analysis and calorimetry 50 (1997), S. 533-545 
    ISSN: 1572-8943
    Keywords: Cu-19 at% Al ; dislocations ; kinetics ; segregation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract A model is proposed to describe the kinetics of solute segregation to partial dislocations in solid solutions of cold-rolled alloys. The case when half edge and half screw dislocations are present is considered. The model gives account of the kinetic behaviour observed in a deformed Cu-19 at% Al alloy where two unknown processes could be assessed during calorimetric isothermal experiments. The faster process corresponds to segregation to screw dissociated dislocations while the slower one corresponds to segregation to edge dissociated dislocations. Experimental activation energies, larger for edge dislocations, are close to that for pipe diffusion along the partials corrected by pinner binding energy terms. It is also predicted that segregation occurs faster as the dislocation density is increased. A quantitative comparison of experimental results with model predictions is given.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 37
    ISSN: 1573-4889
    Keywords: oxidation ; Incoloy 909 ; superalloy ; scale ; high temperature ; kinetics
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The oxidation of an Fe-38Ni-13Co-4.7Nb-1.5Ti-0.4Si superalloy (Incoloy 909 type alloy), was investigated at temperatures between 1000 K and 1400 K in Ar-(1, 10%)H20 atmosphere using metallographic, electron probe microanalysis, and X-ray diffraction techniques. The oxide scales consist of an external scale and an internal scale which has an intergranular scale (above 1200 K) and an intergranular scale. The oxide phases in each scale are identified asα-Fe2,O3 (below 1200 K) or FeO (above 1300 K) and CoO · Fe2O3 and FeO · Nb2O5, respectively. The morphologies, the oxide phases and the oxidation rates do not depend on the partial pressure of H2O in the range between one and ten percent in Ar gas. The rate constants for the intergranular-scale formation in this alloy are about one-tenth as large as those in Fe-36%Ni alloy reported previously. At all the temperatures the scales grow according to a parabolic rate law and the apparent activation energies for the processes are estimated.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 38
    ISSN: 1573-4889
    Keywords: oxidation ; kinetics ; iron ; iron-nitride
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The oxidation of α-Fe and ɛ-Fe2N1−z at 573 K and 673 K in O2 at 1 atm was investigated by thermogravimetrical analysis, X-ray diffraction, light-optical microscopy, scanning electron microscopy and electron probe X-ray microanalysis. Upon oxidation at 573 K and 673 K, on α-Fe initially α-Fe2O3 develops, whereas on ɛ-Fe2N1−z initially Fe3O4 develops. In an early stage of oxidation the oxidation rate of ɛ-Fe2N1−z appears to be much larger than of α-Fe. This can be attributed largely to an effective surface area available for oxygen uptake, which is much larger for ɛ-Fe2N1−z than for α-Fe due to the porous structure of ɛ-Fe2N1−z as prepared by gaseous nitriding of iron. The development of a magnetite layer in-between the hematite layer and the α-Fe substrate, at a later stage of oxidation, enhances layer-growth kinetics. After 100 min oxidation at 673 K the (parabolic) oxidation rates for α-Fe and ɛ-Fe2N1−z become about equal, indicating that on both substrates the oxide growth is controlled by the same rate limiting step which is attributed to short-circuit diffusion of iron cations. Oxidizing ɛ-Fe2N1−z increases the nitrogen concentration in the remaining ɛ-iron nitride, because the outward flux of iron cations, necessary for oxide growth, leads to an accumulation of nitrogen atoms left behind.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 39
    Electronic Resource
    Electronic Resource
    Springer
    Oxidation of metals 48 (1997), S. 171-184 
    ISSN: 1573-4889
    Keywords: TiAl, corrosion ; high-temperature ; kinetics ; nitrogen dependence
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The oxide scale formation on γ-TiAl at 800 and 900°C was studied using high temperature X-ray diffraction as anin situ-method. The experiments were performed in air and in He with 20 vol.% O2. The formation of alumina in the form of α-Al2O3 and of TiO2 in the form of rutile was observed in both atmospheres and the formation of TiN was detected in air. Depending on the atmosphere the diffraction peaks of two different additional phases were detected, which do not exist in any data base nor in the Ti-Al-O phase diagram. One of them, the Z-phase, appears in He with 20 vol.% O2 and the other, the X-phase, in air. The Zphase was also found at room temperature after oxidation at 900°C in air. The growth of both phases, X and Z, starts immediately with the oxidation process and follows the parabolic rate law.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 40
    ISSN: 1573-4889
    Keywords: oxidation ; titanium ; rutile ; scale ; high temperature ; kinetics
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The oxidation behavior of pure titanium has been investigated in the temperature range of 1000 K to 1300 K in CO2 or Ar-10%CO2. Optical microscopy, electron probe microanalyses, and X-ray measurements on the oxide scales formed during oxidation indicate that their structures are nearly independent of temperature and the corrosion atmosphere. The scales consisted of two layers, an external one and an internal one, having a rutile (TiO2) structure. The parabolic rate law was confirmed for growth of the external scale and the permeation depth of oxygen in titanium with apparent activation energies of 266 and 226 kJ/mol, respectively. The rate-determining diffusion species in the oxidation processes are discussed.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 41
    ISSN: 1573-4846
    Keywords: zirconium butoxide ; titanium butoxide ; kinetics ; hydrolysis ; condensation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract A continuous flowing-rapid mixing technique was combined with FTIR, SAXS and electrical conductivity to study the early stages of polymer formation and growth during the acid-catalyzed hydrolysis and condensation of titanium and zirconium alkoxides. Reaction times as short as 80 milliseconds were investigated. FTIR spectroscopy was used to monitor the water and M–OR concentrations during the reaction. Hydrolysis of ∼25–50% of the alkoxy groups was facile. The FTIR and SAXS data showed that condensation was also very rapid. The activity and mobility of the ions in the solution were monitored by electrical conductivity measurements. The decrease in the normalized solution conductivity during the reaction correlated with the loss of [M–OR]. Furthermore, the radius of gyration of the growing polymers increased rapidly in regimes where the conductivity and [M–OR] decreased fastest. This finding suggests that the mobility of some of the charge carrying species decreases because of the growth in size of the polymers.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 42
    ISSN: 1573-4889
    Keywords: binary alloys ; oxidation ; transient state ; kinetics
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The initial transient stage in the oxidation of binary alloys forming scales exclusively composed of the most stable oxide is examined by means of a simplified approach which avoids the numerical integration of the diffusion equation for the transport of the metal components in the alloy. At variance with previous solutions to this problem obtained by means of numerical methods, this treatment takes into account also the effect of the gas-scale reaction at the outer surface of the oxide. The concentration of the most-reactive component at the alloy surface changes gradually with time from the initial bulk value towards the corresponding steady-state value without involving any minimum, while the overall rate of the reaction presents a gradual transition from an initial nearly linear towards final parabolic behavior.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 43
    Electronic Resource
    Electronic Resource
    Springer
    Environmental and resource economics 10 (1997), S. 341-362 
    ISSN: 1573-1502
    Keywords: Baltic Sea ; eutrophication ; nitrogen ; phosphorus ; cost effective
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Economics
    Notes: Abstract Due to eutrophication caused by heavy loads of nitrogen and phosphorus, the biological conditions of the Baltic Sea have been disturbed: large sea bottom areas without any biological life, low stocks of cods, and toxic blue green algaes. It is recognized that the nitrogen and phosphorus loads to the Baltic Sea must be reduced by 50% in order to restore the sea. The main purpose of this paper is to calculate cost effective nitrogen and phosphorus reductions to the Baltic Sea from the nine countries surrounding the Baltic Sea. The results show a significant difference in minimum costs of decreasing nitrogen and phosphorus loads to the Sea: approximately 12 000 millions of SEK per year and 3 000 millions of SEK respectively for reductions by 50%. It is also shown that a change from a policy of cost-effective nutrient reductions to a policy where each country reduces the nutrient loads by 50% increase total costs for both nitrogen and phosphorus reductions by about 300%. The results are, however, sensitive to several of the underlying assumptions and should therefore be interpreted with much caution.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 44
    ISSN: 1573-2932
    Keywords: phosphorus ; P flux ; microbial activity ; redox ; simulation ; Lake Kinneret ; sediment ; accumulative P release
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Different factors which interactively control the flux of soluble reactive phosphorus (SRP) at the sediment-water interface (SWI) of Lake Kinneret were studied seasonally. The influence of pH, Eh and microbial activity on SRP flux at the SWI was investigated by manipulating the conditions in the overlying water of intact sediment cores. The calculated diffusive SRP flux out of the sediment was lower in cores sampled during winter and spring than during the period of amixis. Potential SRP release, as measured in the absence of microbial activity, was strongly enhanced upon the transition from oxic to anoxic conditions indicating P release from iron(III)-bound phosphorus. In spring and summer cores, an enhanced SRP flux from sediments at pH 7 in comparison to pH 8 indicated P release from carbonate-bound P which sedimented previously as result of high pH values during the algal spring bloom. Microbial uptake at the SWI was the most important sink for SRP and no net-flux occured under oxic conditions. The higher net-flux of P under anoxic conditions was linked to carbon limitation of the bacteria at the SWI.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 45
    Electronic Resource
    Electronic Resource
    Springer
    Water, air & soil pollution 99 (1997), S. 457-464 
    ISSN: 1573-2932
    Keywords: sediment ; phosphorus ; fractionation ; release ; humic lake
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Lake Flosek (north-eastern part of Poland) is a small shallow and without outflow lake which has been limed in 1970. The concentration of Ca was increased from 3-4 mg L-1 to 17 mg L-1 in the water and from 0.2-0.3% dry weight to 0.9-1.7% dry weight in sediments (5 cm upper layer) due to CaCO3 addition to the lake. In the spring-summer seasons of 1992 and 1993, an experimental study was conducted in Lake Flosek to assess the capacity of bottom sediments to uptake and release mineral phosphorus. The rate of phosphorus exchange between sediments and near-bottom water was experimentally measured under conditions of high (100%), and of reduced (10%) oxygen saturation in near-bottom water. To determine the component of sediments responsible for the uptake of most phosphorus, the proportions of phosphorus forms in sediments were analysed. Sediments of Lake Flosek showed a slight tendency to release phosphates. The rate of this process was similar under high (100%) and low (10%) oxygen saturations ranging from - 0.161 to + 0.200 mg P m-2 d-1. This is much lower (by 1-2 orders of magnitude) than reported from other harmonic, non-humic lakes. In the total phosphorus pool, the highest content of phosphorus was found in the organic and residual phosphorus fractions (over 70% of the total phosphorus in sediments). The largest part of the readily extractable phosphorus was found in the fraction bound to Al and humic substances (41%). Both these fractions determine a weak exchange of phosphorus between sediments and water. No difference in P-release related to P-fraction compound was found in the cores taken from three sites in the lake.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 46
    Electronic Resource
    Electronic Resource
    Springer
    Water, air & soil pollution 99 (1997), S. 477-486 
    ISSN: 1573-2932
    Keywords: sediment ; nitrogen ; phosphorus ; organic matter ; cluster analysis ; Gulf of Finland ; estuaries
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Dry weight (DW), ignition loss (IL) and concentrations of total nitrogen (TN) and total phosphorus (TP) of the sediment surface layer (0 to 10 cm, 1 cm slices) were analyzed from 20 sites in the eastern Gulf of Finland. The distance of the sampling sites from the mouth of the River Neva explained the nutrient concentrations of the sediments well, while the effect of water depth was negligible. The increase of TN and the decrease of TP along the transect from the river mouth towards the open Gulf were caused by the diminishing share of allochthonous material supplied from the River Neva. The mean TN concentration of the different accumulation areas was about 40 % higher in the sediment surface than in the deeper layer (9 to 10 cm). The corresponding difference for TP varied from 53 to 56 %. The results suggest considerable netflux of nutrients from sediment to water. The net sediment accumulation of nutrients were estimated as 6.0 g m-2 a-1 of N and 1.7 g m-2 a-1 of P corresponding 22 000 t a-1 of N and 6 100 t a-1 of P for the whole eastern Gulf.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 47
    ISSN: 1573-2932
    Keywords: Adriatic Sea ; nutrients ; benthic fluxes ; carbon ; nitrogen ; silicon ; phosphorus ; budgets
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Benthic fluxes of dissolved inorganic N, Si and P nutrients, alkalinity, dissolved inorganic C (DIC), and O2 from sediments in the Gulf of Trieste (northern Adriatic, Italy) were measured monthly in the period September 1995 – August 1996 using in situ incubated light benthic chambers. The highest efluxes of DIC, NH4 +, PO4 3−, Si(OH)4, and NO3 − influxes encountered in late summer — early autumn were the consequence of degradation of benthic microalgae, and in autumn mostly of sedimented phytoplankton. High NO3 − efflux was observed in spring. Only NH4 + and Si(OH)4 fluxes were significantly correlated with temperature. This correlation suggests that the rate of downward input and the quality and quantity of sedimentary organic matter (autochthonous and allochthonous) were superimposed on the temperature fluctuations. High DIC, NH4 + and Si(OH)4 effluxes observed in July 1996 were due to the late spring — early summer degradation of sedimentary organic matter produced by benthic microalgae, while the autumn phytoplankton bloom was quickly reflected in enhanced benthic fluxes due to higher temperature. Significant correlations between NH4 +, PO4 3− and Si(OH)4 fluxes suggested their parallel regeneration and utilization at the sediment-water interface. The nutrient fluxes were linked to O2 consumption, suggesting that aerobic oxidation processes were important at the sediment-water interface in the Gulf. The N, P and Si nutrients released from sediment pore waters are probably utilized in benthic microalgal and bottom-water primary production. This indicates that pelagic and benthic communities in the central part of the Gulf of Trieste function relatively independently of each other.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 48
    ISSN: 1573-2932
    Keywords: fractionation ; redistribution ; saturation ; kinetics ; heavy metals
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Solid-phase transformations of Cd, Cu, Cr, Ni and Zn, added as soluble salts at several levels to two arid-zone soils, were studied over a period of one year. The soils were maintained under a saturated-paste regime and sampled periodically. A selective sequential dissolution procedure was employed to determine the changes in metal distribution among six operationally defined solid-phase fractions. A function, Uts was introduced to measure the fractional attainment of equilibrium of the soils following a perturbation. The direction and rate of redistribution of the added metals in the soils were affected by the nature of the metal, the soil properties and the metal loading level. Cd added to the soils was transferred from the exchangeable (EXC) into the carbonate (CARB) fraction. When soluble Cu, Cr, Ni and Zn were added at low loading levels, metals were transferred from the reducible oxides(RO) bound and easily reducible oxides (ERO) bound fractions and the EXC fraction, into the CARB fraction. However, at the higher loading level, metals were transferred from the EXC and CARB fractions into the organic matter bound (OM), ERO and RO fractions. The Uts function approached lower values as incubation continued but remained removed from 1. The overall flux of metals among fractions was the combined result of the readjustment of the metals in the native soil to changing conditions due to saturation, and the transfer of added soluble metals to the less labile fractions.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 49
    Electronic Resource
    Electronic Resource
    Springer
    Water, air & soil pollution 99 (1997), S. 633-640 
    ISSN: 1573-2932
    Keywords: zebra mussel ; Dreissena polyrnorpha ; phosphorus ; trophic state ; recovery ; take Como
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract A large scale study on the western basin of Lake Como (N. Italy) was started in 1995 to examine the effects of the zebra mussel colonization which began in early '90. Our results have been related to '91–92 data (pre-Dreissena period), before the maximum colonization of zebra mussel. In spring and summer of the post-Dreissena period total phosphorus, P-PO4, nitrate and chlorophyll values decreased, while ammonium and tranparency increased at every sampling station. Zebra mussel does not modify the trophic state of this sub-basin but it plays an important role in nutrient cycling. The entire population can filter epilimnetic craters 2.1 times per year and can produce 2.9 × 104 t y of pseudofaeces which are transferred to sediments.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 50
    ISSN: 1573-4846
    Keywords: zirconium butoxide ; titanium butoxide ; kinetics ; hydrolysis ; condensation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract A continuous flowing-rapid mixing technique was combined with FTIR, SAXS and electrical conductivity to study the early stages of polymer formation and growth during the acid-catalyzed hydrolysis and condensation of titanium and zirconium alkoxides. Reaction times as short as 80 milliseconds were investigated. FTIR spectroscopy was used to monitor the water and M−OR concentrations during the reaction. Hydrolysis of ∼25–50% of the alkoxy groups was facile. The FTIR and SAXS data showed that condensation was also very rapid. The activity and mobility of the ions in the solution were monitored by electrical conductivity measurements. The decrease in the normalized solution conductivity during the reaction correlated with the loss of [M−OR]. Furthermore, the radius of gyration of the growing polymers increased rapidly in regimes where the conductivity and [M−OR] decreased fastest. This finding suggests that the mobility of some of the charge carrying species decreases because of the growth in size of the polymers.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 51
    ISSN: 1573-5052
    Keywords: Aster ; Atriplex ; Chenopodium ; nitrogen ; phosphorus ; roots ; shoots
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The loss of dry mass, nitrogen and phosphorus from shoot and root litter of mudflat annuals was examined in a series of experimental marshes in the Delta Marsh, Manitoba, Canada. Litter bags containing shoot material of three mudflat annuals (Aster laurentianus Fern., Atriplex patula L., and Chenopodium rubrum L.) were placed on the sediment surface of the marshes under drawdown conditions. In addition, litter bags containing root material of these three species were shallowly buried. Approximately 70% and 50% of both shoot and root litter, respectively, was still present after one year in the field. During the second year when the marshes were flooded, shoot and root litter lost an additional 20% and 0% of their mass, respectively. Except for Chenopodium roots, which accumulated nitrogen and phosphorus during both years, shoot and root litter lost from 0 to 50% of their nitrogen and phosphorus early in the first year, with levels generally remaining constant through the remainder of the study period. Our results indicate that mudflat annual litter decomposed slowly and would provide abundant habitat for aquatic invertebrates when these marshes were reflooded. However, most nutrient loss took place in the first year when the litter was unflooded, with little loss occurring in the second year when flooded.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 52
    ISSN: 1573-5117
    Keywords: fish food ; faeces ; nutrient ; nitrogen ; phosphorus
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The fish food and faeces were fractioned into the differentcomponents of phosphorus and nitrogen. There was a rapid release ofphosphorus from the fish food and faeces and a decrease thereafterwhereas ammonium release was slow at first with the rate increasingwith time. Both temperature and pH affected the release of nutrientsfrom fish food and faeces. The release of phosphorus and nitrogen washigher at higher temperatures. The maximum release of phosphorus wasat pH 4.0 whereas nitrogen release was maximum at neutral (7.0) toalkaline (10.0) media.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 53
    ISSN: 1573-5117
    Keywords: phytoplankton ; zooplankton ; planktivorous fish ; phosphorus ; biomanipulation ; trophic interactions
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Water chemistry, phytoplankton, zooplankton and fish populations werestudied over several years in three shallow, non-stratified lakes withdiffering nutrient loadings and fish communities in southwest Finland. LakePyhäjärvi was weakly mesotrophic in 1980–1996, LakeKöyliönjärvi was highly eutrophic in 1991–1996, andLake Littoistenjärvi was mesotrophic in 1993–1996 and eutrophicin 1992. In Lake Pyhäjärvi, natural year-class fluctuations ofvendace and smelt (range of combined biomass 5–28 kgha™1) caused significant variation in planktivory. The verydense fish stocks of Lake Köyliönjärvi (mainly roach, breamand smelt) were decimated from 〉175 kg ha™1 in 1991 toabout 50 kg ha−1 in 1996 by removal fishing. The roach stockof Lake Littoistenjärvi declined from about 71 kg ha−1 toabout 28 kg ha−1 during 1993–1996. In LakePyhäjärvi, strong stocks of planktivorous fish were accompaniedwith depressed crustacean zooplankton biomass, reduced role of calanoids andcladocerans, a low proportion of larger cladocerans (length 〉 0.5 mm),and a high chlorophyll level. In the lakes Littoistenjärvi andKöyliönjärvi, zooplankton was dependent on both fish andphytoplankton: in spite of dense fish stocks, a high crustacean biomassdeveloped in a phytoplankton peak year, but it was dominated by very smallcladocerans. In Lake Pyhäjärvi, late summer chlorophyllconcentration was predictable from total phosphorus in water and cladoceranbiomass (r2 = 0.68), both factors explaining roughlysimilar fraction of total variation. In combined data from all three lakes,chlorophyll was almost solely dependent on total phosphorus, while thecladocerans were regulated both from below by productivity and from above byfish. Our data from Pyhäjärvi lend support to consumer regulationof late summer phytoplankton; low chlorophyll values prevailed whenplanktivorous fish biomass was below 15 kg ha−1. In largeeutrophic lakes it may be difficult to reduce fish stocks to such a lowlevel: in Lake Köyliönjärvi, after six years of removalfishing, fish biomass still remained higher, and changes in plankton wereaccordingly small. Unexpectedly, in 1993–1996, phytoplankton biomassin Littoistenjärvi remained low in spite of low crustacean zooplanktonbiomass; submerged macrophytes probably regulated the water quality.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 54
    ISSN: 1573-5117
    Keywords: nitrogen ; phosphorus ; drainage waters ; sediments ; sorption
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Lake Łuknajno, a shallow (max. depth 3 m) and relativelylarge(630 ha) water body situated in the Great Masurian Lakessystem(Poland) is strongly affected by its agricultural watershed.Thetotal volume of drainage waters pumped into the lake in 1993amounted 2.84 × 106m3 which is equivalentto65% of the lake volume. In spring and autumn drainage waterswereextremely rich in nitrogen (especially nitrates) and the N:Pratioreached 57 in spring. In summer, drainage waters containedrelatively more phosphorus so the N:P ratio decreased tonearly 10.Nutrient concentrations in lake water followed the changes ininflowing waters. High concentrations of nitrates and ammoniawerenoted in lake water in spring but summer concentrations oftheseions were close to zero. Soluble reactive phosphorus variedbetween10 and 20 µg P l−1 throughout the season. A constantoutflow of nitrogen to the lower Lake Śniardwy was assumedbased ona permanent concentration gradient between waters of these twolakes.Lake Łuknajno is a hard water lake. Co-precipitation ofphosphorus with calcium carbonate is likely to occur though nosignificant P accumulation in bottom sediments was found.Sorptionof phosphorus on sediments as measured under experimentalconditions has minor effects on P cycling. Bottom sedimentscomposed mainly of calcareous gyttja do not accumulate eitherorganic matter or mineral forms of nutrients.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 55
    Electronic Resource
    Electronic Resource
    Springer
    Hydrobiologia 342-343 (1997), S. 1-8 
    ISSN: 1573-5117
    Keywords: model ; phosphorus ; eutrophication ; hysteresis ; lake ; restoration
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract There is increasing evidence that, within a range of nutrientloadings, shallow lakes may have two alternative stablestates. One is dominated by phytoplankton and the other one bysubmerged macrophytes as the main primary producer. Thequestion arises at what level of nutrient loading a transitionmay occur between the two states. This question was addressedby means of the integrated lake model PCLake. The modeldescribes the competition between phytoplankton andmacrophytes, within the framework of closed nutrient cycles inthe lake system, including the upper sediment. Top-downeffects via the food web were regarded as well. The model wasrun for a hypothetical shallow lake, representative for thesituation in The Netherlands. Long-term simulations werecarried out for a realistic range of nutrient loadings andstarting from different initial conditions. The results showeda highly non-linear response, which also showed hysteresis:the loading level at which a transition occurs turned out tobe dependent on the initial conditions. The results werecompared with empirically derived chlorophyll a tophosphorus relations. Factors influencing the ’criticalnutrient level‘ were the lake dimensions and the netsedimentation rate. The model was also used to evaluate therole of food web management in lake restoration. The resultssuggest that a long-term effect of additional management ispossible only if combined with a decrease in nutrient loading.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 56
    Electronic Resource
    Electronic Resource
    Springer
    Hydrobiologia 345 (1997), S. 39-44 
    ISSN: 1573-5117
    Keywords: Crystal Lake ; phosphorus ; 210Pb ; 137Cs ; geochronology
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Isotopes like 210Pb and 137Cs are effectivetools for determining chronology in lake sediments. Once the chronology is established, environmentalchanges in lakes can be investigated, and the causesfor those changes can often be inferred. 210Pband 137Cs profiles were constructed for thesediments of Crystal Lake, Connecticut, USA. Thegeochronology was used to determine the historicalchanges in organic matter and P accumulationin the sediment. Those profiles showed twosignificant periods of sedimentation which correlatewith major precipitation events. DecreasingP accumulation in the sediments of the lakein the last decade was also correlated with increasingeutrophication as documented by increases inepilimnetic P and decreases intransparency.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 57
    ISSN: 1573-5117
    Keywords: eutrophication ; phosphorus ; bioavailability ; nutrient balance ; agriculture ; models
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract This study assesses the effects of external and internalloading on the nutrient concentrations in an agriculturallyloaded shallow lake. Using 13 years of observations of thelake's input and outflow, we calculated the long-term balancesof Tot-P and Tot-N. A more detailed balance, which includeddissolved nutrients and suspended solids, was estimated for anice-free period of one year. The contribution of the externalload was assessed using a mass-balance model. The internalload was estimated from the nutrient balances and on the basisof sedimentation measurements and bioassays. The drainagebasin of the lake provided most of the external nutrientinput; the remaining load was derived from atmosphericdeposition to the lake. The proportions of river-transported Pand N in dissolved form were 25% and 77%, respectively. Thelake retained 〉80% of the external load. Particulatenutrients settled to the bottom and were probably resuspendedseveral times before permanent sedimentation. Dissolvednutrients were bound by primary producers and a highproportion of dissolved P was removed with the fish catch.Dissolved N was also lost via denitrification. Themass-balance model showed that external loading only partlyregulated the mean annual nutrient concentrations in the lake.The regulation was probably due to internal loading, which washigh despite the efficient net retention of nutrients. Duringthe ice-free period, the temporal variations in nutrientconcentrations were controlled almost solely by internalprocesses, such as resuspension of inorganic and organicbottom matter. Although the internal load of bioavailable Pmay, under favourable conditions, exceed the external load,the mechanism by which bioavailable P is translocated from thebottom sediments to the water could not be fully identified. Abbreviations used in this paper follow the editor'srules.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 58
    ISSN: 1573-5117
    Keywords: drainage area ; reservoir ; sedimentcomposition ; phosphorus ; phosphate extraction
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The study of four drinking-water reservoirsdemonstrates how the anthropogenic land use of acatchment may affect binding and mobility ofphosphorus in the sediment. Pdiss concentrationgradients at the sediment–water interface weremeasured to calculate potential diffusive releaserates. P binding forms were determined by sequentialextraction of fresh sediment and settling seston. Mainstudy sites were Saidenbach Reservoir (mesotrophic,densely populated drainage area with 73% agriculturalland use) and Neunzehnhain Reservoir (oligotrophic,unpopulated drainage area forested to 80%) in thesilicate-rich Erzgebirge mountains of eastern Germany.Tot-P concentrations and P binding forms of typicalerosive matter from each catchment were similar to thesediment of both pre-reservoirs and reservoirs' mouth.In Saidenbach Reservoir, diatoms responded to highnutrient loading by incorporating ortho-P. Whilesettling, the org-P was partly transformed toFe(OOH) ≈ P. Apart from hypolimnetic O2depletion, this P binding form dominated in thesurface sediment mainly in front of the dam. Withincreasing sediment depth, org-P and Fe(OOH) ≈ Pnot only redissolved into the pore water, but alsoadsorbed onto Al compounds. In Neunzehnhain Reservoir,acidification of the low buffered catchment favouredloading of humic compounds and Al3+ ions, whichprecipitated and redox-independently adsorbed ortho-Pdue to a pH increase in the lake. Neunzehnhainsediment was able to immobilize Fe(OOH) ≈ P fromSaidenbach sediment in a batch experiment. Comparativesequential P extraction of sediment from SosaReservoir (oligo-mesotrophic, sparsely populateddrainage area forested to 94%) and Kleine KinzigReservoir (nearly unpopulated drainage area forestedto 98%) also demonstrated effective P immobilizationby Al-/humic compounds. It is concluded that the absence of settlements in thecatchment, together with forestry as dominating landuse, favour not only oligotrophic conditions in thereservoir but also confine internal P loading from thesediment. But attention should be paid toacidification problems.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 59
    Electronic Resource
    Electronic Resource
    Springer
    Hydrobiologia 345 (1997), S. 15-20 
    ISSN: 1573-5117
    Keywords: phosphorus ; phosphorus budget ; retention ; sedimentation ; sediment traps ; sediment cores
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract We compared P retention with direct measures of Psedimentation, estimated fromsediment cores (annual P sedimentation) and sedimenttraps (daily P sedimentation),to quantify P sedimentation in Eau Galle Reservoir,Wisconsin. Mean annual Pretention was similar to mean annual P sedimentation,as estimated from sediment corerates integrated over the entire lake basin,indicating that annual P mass balanceapproximated annual net P sedimentation in thisreservoir. However, sediment trap Prates, measured over the summer stratified period,overestimated P retention ratesdetermined over the same period, suggestingsubstantial deposition of internally-derived P.Inclusion of measured internal P loadings from avariety of sources in EauGalle Reservoir in a P mass balance only accounted foran additional 24% of thesummer sediment trap P rate, indicating substantialuncertainty in the overall P budget.Imbalances in the P budget may also suggest depositionof sediment from other as yetunquantified internal sources. Potential internalsources of P include sedimentresuspension and chemical release and direct uptake ofP from the sediment byphytoplankton.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 60
    ISSN: 1573-5117
    Keywords: alkaline phosphatase ; chlorophyll a ; phosphorus ; algae ; phosphorus regeneration
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Alkaline phosphatase activity (APA) of unfiltered andfractionated (algae, bacteria, dissolved) surface watersamples was measured using a spectrophotometric method in LakeŁuknajno from May to September 1993. The total enzymaticactivity varied between 0.44–2.35 µmol l−1h−1.Algae were major producers of alkaline phosphatase activity insurface water of the lake from May to August, and theiractivity constituted on the average 67% of the total APAactivity in the water. APA activity in bacterial size fractionwas low and constituted 9.6% (mean) of the total activity.The activities of free (dissolved in water) enzymes wererelative high during the time of study. This study show thathydrolysis of organic phosphomonoesters by alkalinephosphatase was negligible in the recycling of phosphorus inŁuknajno Lake.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 61
    ISSN: 1573-5117
    Keywords: lake sediment ; bioturbation ; chironomid larvae ; organic matter decomposition ; nutrient exchange ; nitrogen ; phosphorus
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The importance of Chironomus plumosus larvae onbenthic metabolism and nutrient exchange across thesediment–water interface was evaluated in a shalloweutrophic lake (Lake Arreskov, Denmark) following aphytoplankton sedimentation. Chironomus plumosuslarvae were added to laboratory sediment microcosms,corresponding to a density of 2825 larvae m−2.Non-inhabited microcosms served as controls. Asedimentation pulse of organic matter was simulated byadding fresh algal material (Chlamydomonasreinhardii) to sediment cores (36 g dryweight m−2). The mineralization was followed bymeasuring fluxes of O2, CO2, dissolvedinorganic nitrogen and phosphate. A rapid clearance ofalgae from the water column in faunated microcosmssuggested that chironomids may be of major importancein controlling phytoplankton concentrations in shalloweutrophic lakes. Chironomids increased the sedimentO2 uptake ≈ 3 times more than what wouldbe expected from their own respiration, indicating astimulation of microbial activity and decomposition oforganic matter in the sediment. Addition of algaeenhanced the release of CO2, NH+ 4 ando-P. The excess inorganic C, N and P released inamended non-inhabited sediment after 36 dayscorresponded to 65, 31 and 58% of the C, N and P inthe added algae. In sediment inhabited by Chironomus plumosus the corresponding numbers were147, 45 and 73%, indicating that mineralization oforganic matter also from the indigenous sediment poolwas stimulated by chironomids.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 62
    ISSN: 1573-904X
    Keywords: solution ; protein stability ; factor VIII ; formulation ; kinetics ; DSC
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Purpose. To investigate the influence of various nonreducing disaccharides and sugar alcohols on the inactivation kinetics of recombinant factor VIII SQ (r-VIII SQ) in aqueous solution not containing albumin as a stabiliser. Methods. The stability of r-VIII SQ was followed using measurement of activity (VIII: C) and HPLC gel filtration at different temperatures. The thermal stability was investigated using differential scanning calorimetry (DSC). Results. The decline in VIII:C followed pseudo-first order kinetics. However, the Arrhenius plot was not linear for formulations without carbohydrate, demonstrating a distinct, reproducible curvature. The reaction rate at 5°C was faster than expected from the Arrhenius kinetics. The energy of activation (Ea) for formulations without added carbohydrates, derived from the linear part of the Arrhenius plot, varied between 77 and 86 kJ/mole in the temperature range 20−37°C. The addition of 600 mg/ml sucrose increased the Ea to 104 kJ/mole. DSC measurements showed thatTm′ was 64.2 ± 0.2°C for r-VIII SQ without stabiliser. This value increased linearly with increasing concentrations of carbohydrate. This stabilising effect is most probably explained by the theory of preferential hydration. Conclusions. The inactivation kinetics of r-VIII SQ in aqueous solution without addition of carbohydrates followed pseudo-first order kinetics but the Arrhenius plot was nonlinear. Sucrose and sorbitol both had highly stabilising effects on r-VIII SQ at concentrations above 300 mg/ml. The preparation containing 600 mg/ml sucrose was stable for at least 12 months at 5°C and 6 months at 25°C.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 63
    Electronic Resource
    Electronic Resource
    Springer
    Colloid & polymer science 275 (1997), S. 303-306 
    ISSN: 1435-1536
    Keywords: Key words Vesicle ; self-assembly ; hydrotrope ; stopped-flow ; kinetics
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract  The kinetics of vesicle formation from a hydrotrope (sodium xylenesulfonate) solution of a surfactant (Laureth 4) is studied by the use of a stopped-flow apparatus combined with a dynamic light scattering device to determine vesicle size in the system. The hydrotrope system studied presents a system with a high surfactant solubilization combined with vesicle formation simply by dilution with water. The kinetic results show a single exponential decay time. The kinetic analysis indicates that the vesicles are formed from a molecular solution which resulted from the shear in the stopped-flow device and grow by monomeric association.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 64
    ISSN: 1435-1536
    Keywords: Key words 3-aminopropyltriethoxy silane ; silica gel ; interaction ; kinetics
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract  Three silica gel sample systems, modified with 3-amino-propyltriethoxy silane (APTS), were prepared by sequentially sampling the reaction mixture at various time intervals. The concentrations of 3-aminopropylsilyl groups (APS) bound on the silica surface were determined by elemental analysis. For the same sample systems, 29Si NMR intensities of an (–O)4Si species belonging only to the silica gel particles and corrected by a cross-polarization correction factor were also measured. Both the APS-concentrations and the correc-ted 29Si NMR intensities depended upon reaction time, reflecting the rate of the APTS–silica gel reaction. Kinetic analysis of these data was made by use of the Gauss–Newton method, and the overall reaction was found to consist of three reaction processes (an initial fast reaction, a slower second reaction and a much slower third reaction). In particular, the conversion of (–O)3SiOH to (–O)4Si is predominant in the second reaction process and the pore size of a silica gel particle affects the reaction mechanism.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 65
    ISSN: 1573-5036
    Keywords: Frankia ; phosphatase activity ; phosphorus ; protein ; viability
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract An in vitro experiment was conducted to investigate the effects of different sources and levels of P supply on growth, viability and phosphatase activity of three tropical Frankia strains isolated from Casuarina. P concentration for optimum growth was between 0.1 and 10.0 μM in the absence of external combined nitrogen. Specific viability was not influenced by P supply. Morphological features of Frankia, such as hyphal length and vesicle numbers, were found to largely mirror growth. Phosphatase activity was detected in all three Frankia strains and was highest when P was omitted from the culture solution. There were more than 10-fold differences between the Frankia strains in the level of phosphatase activities shown. This study suggested that soils low in P are unlikely to restrict micro-symbiont growth activity.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 66
    ISSN: 1573-5036
    Keywords: eutrophication ; herons ; nesting site ; nitrogen ; nitrophyllous species ; phosphorus ; similarity index
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Effects of colony nesting of herons on soil properties and herb layer composition in Pinus densiflora forest were studied at Pomaeri, Kangwon Province in Korea. Herons have used this habitat as a nesting site from January to October every year. In 1995, more than 500 herons were observed in this habitat. Nutrient content of soil was much higher at the nesting site than that of the non-nesting site (control). Total nitrogen concentration of soil at the nesting site and the control site was 14.8±1.85 mg g-1 and 2.8±0.35 mg g-1, respectively. Phosphorus content of soil in the nesting site was 32 times greater than that of the control site. This is evidently due to the addition of feces of the herons, and decomposition of thin twigs and organic debris from the canopy of dead trees and bird nests. Light intensity at herb layer of the nesting site and of the control site was 80% and 20%, respectively, of incident on outside forest. Species diversity of herb layer in the nesting site (9 species) was quite lower than that in the control site (14 species). Similarity index of the herb layer between the two sites was 0.07. The nesting site was dominated by indicator species of soil eutrophication such as Humulus japonicus, Persicaria perfoliata, Persicaria fauriei, Commelina communis, Chelidonium majus var. asiaticum. Changes of herb species composition in the nesting site was evidently due to the eutrophication of the soil and increased light intensity of the herb layer.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 67
    ISSN: 1573-5036
    Keywords: DRIS ; nitrogen ; perennial ryegrass ; phosphorus ; potassium ; sulphur
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Herbage analysis offers a definitive means of determining the N, P, K and S status of perennial ryegrass swards. Unfortunately, the results of such analyses can be difficult to interpret, simply because the minimum or 'critical' concentration of a nutrient in plant tissue for optimum growth, varies both with crop age and with changes in the concentrations of other nutrients. The Diagnosis and Recommendation Integrated System (DRIS) could help to improve the reliability of such interpretations. Diagnoses made using DRIS are based on relative rather than on absolute concentrations of nutrients in plant tissue, and as such should be comparatively independent of crop age. The aim of this study was to establish and test DRIS methodology for high-yielding perennial ryegrass swards. Because of prohibitive costs, setting up a whole new series of field experiments to evaluate DRIS model parameters for perennial ryegrass was out of the question. Instead, the diagnostic norms and associated coefficients of variation for the model were evaluated using data from a single (large) multi-factorial glasshouse experiment. Of the nutrient ratios selected to form the diagnostic norms, K/N and S/N had the clearest physiological rationale, whereas those involving Ca and Mg in combination with N, P, K and S appeared to have little physiological basis. It was reasoned, though, that because Ca and Mg uptake by plants are largely passive processes (ultimately governed by plant growth), the DRIS indices for these nutrients, together reflected the degree to which growth may be limited by non-nutritional (environmental) factors relative to nutritional ones. Both indices were combined to form a single reference (Ri) index. Without such an internal reference, plant growth could be limited by multiple nutrient deficiencies, and yet N, P, K and S indices might all be close to, or equal to zero (i.e. the optimum), simply because the absolute concentrations of each nutrient (while low) had been in the correct state of balance. Moreover, by effectively using Ca and Mg as internal reference parameters in DRIS, 'nutrient concentrations' which previously formed the basis of the critical value approach, were essentially incorporated into the DRIS model, thus combining the strengths of the two diagnostic approaches; the only difference being that Ca and Mg, and not dry matter, were the internal references against which the levels of the major nutrients were compared.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 68
    Electronic Resource
    Electronic Resource
    Springer
    Plant and soil 195 (1997), S. 351-364 
    ISSN: 1573-5036
    Keywords: barrier island ; environmental effects ; litter quality ; nitrogen ; phosphorus ; root decomposition
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract A root decomposition study using the litterbag approach was conducted along a dune and swale chronosequence on the Virginia Coast Reserve-Long Term Ecological Research Site in Virginia, USA to evaluate how environmental and substrate quality factors influence belowground decay and associated nutrient dynamics. Gradients in moisture levels and nitrogen availability associated with the chronosequence provided the experimental framework. Spartina patens roots were buried at all sites as a standard substrate to evaluate environmental influences. Roots native to each site were buried to evaluate community decay dynamics and the influence of litter quality. Spartina decay was reduced in the wet, anoxic soils of swale sites (k = 0.21–0.33 yr-1) relative to decay in dunes soils (k = 0.52–0.72 yr-1). Increasing soil nitrogen availability from younger to older sites had no effect on the rate of Spartina root decay. Native root decay across the Hog Island chronosequence exhibits certain trends expected in response to nitrogen limitation and moisture availability. Increased nitrogen content of root material corresponds to increased soil nitrogen availability. Among dune sites, native root decay increased in concert with increased root nitrogen (6 year k = 0.34 yr-1, 120 year dune: k = 0.97 yr-1). Litter quality, alone, does not explain this trend since Spartina roots decayed more slowly than native dune roots and had a higher initial nitrogen content. Among swales, increased moisture levels and associated soil anoxia inhibited native root decomposition and minimized the effects of litter quality on decay. In general, phosphorus was rapidly lost from decaying roots while nitrogen immobilization was low to nonexistent. The low nitrogen immobilization of decaying roots in a nitrogen limited ecosystem warrants further study and may reveal that belowground decay increases the rate of nutrient cycling relative to decay aboveground.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 69
    ISSN: 1573-5036
    Keywords: arbuscular mycorrhizae ; banana ; Glomus mosseae ; interaction ; Meloidogyne incognita ; Musa AAA ; phosphorus
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract The effects of the interaction between the arbuscular mycorrhizal fungus Glomus mosseae and the root-knot nematode Meloidogyne incognita on growth and nutrition of micropropagated ‘;Grand Naine’ banana (Musa AAA) cultivar was studied under greenhouse conditions. Inoculation with two G. mosseae isolates significantly increased growth of plants in relation to non-mycorrhizal plants. Response to mycorrhizae was as effective as with an optimum P fertilization in promoting plant development for most growth parameters. Meloidogyne incognita had no apparent effect on the percentage of root colonization in mycorrhizal plants. In contrast, G. mosseae suppressed root galling and nematode buildup in the roots. The percentage of mycorrhizal colonization was high (over 80%) in low P fertilized plants, but optimum P rates for bananas (four times higher than low P) significantly reduced mycorrhizal colonization. Most elements were within sufficiency levels for banana with exception of N which was low for all treatments. Mycorrhizal plants fertilized with a low P rate showed higher N, P, K, Ca, and Mg contents as compared to non-mycorrhizal plants low in P with or without the nematode. Inoculation with G. mosseae favours growth of banana plants by enhancing plant nutrition and by suppressing nematode reproduction and galling during the early stages of plant development.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 70
    Electronic Resource
    Electronic Resource
    Springer
    Plant and soil 191 (1997), S. 181-188 
    ISSN: 1573-5036
    Keywords: cereal genotypes ; diffusion ; genetic ; phosphorus ; rhizosphere ; root hairs
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Root-soil contact is an important factor for uptake of a less mobile soil nutrient such as phosphorus (P) by crop plants. Root hairs can substantially increase root-soil contact. Identification of crop cultivars with more and longer root hairs can, therefore, be useful for increasing P uptake in low input agriculture. We studied the root hairs of wheat (Triticum aestivum L. cvs. Kosack, Foreman, Kraka) and barley cultivars (Hordeum vulgare L. cvs. Angora, Hamu, Alexis, Canut) in relation to P depletion from the rhizosphere in three soils of different P levels (0.45, 1.1 and 1.6 mmoles P kg−1 soil; extracted with 0.5 M NaHCO3). Root hairs were measured in solution culture having nutrients and concentration similar to soil solution. Root hairs of Kraka were much longer (1.27 ± 0.26 mm) and denser (38 ± 3) hairs mm−1 root) than those of Kosack which had shorter (0.49 ± 0.2 mm) and fewer (24 ± 3) hairs mm−1 root) root hairs. Root hairs increased root surface area (RSA) of Kraka by 341%. The increase with Foreman was 142% and with Kosack it was 95%. For winter barley, the length (1.1 ± 0.3 mm) and density (30 ± 1 hairs mm−1 root) of root hairs of Hamu differed from root hair length (0.52 ± 0.18 mm) and density (27 ± 1 hairs mm−1 root) of Angora. Root hairs of spring barley cultivars differed in length (Canut 1.0 ± 0.24 mm; Alexis 0.64 ± 0.19 mm) but not in density (Canut 31 ± 1, Alexis 30 ± 2 hairs mm−1 root). Root hair diameter (12 ± 1µm) did not differ among the cultivars. Root hairs increased RSA of Canut by 245%, Hamu by 237%, Alexis by 143% and Angora 112%. The variation in root hair parameters of the cultivars was related to quantity of P depleted from rhizosphere. The correlation (R2) between the root hair lengths of wheat cultivars and the quantity of P depleted from the rhizosphere soil (Q) was (0.99***) in low-P, (0.85***) in medium-P and (0.78**) in high-P soil. The values of (R2) between the root hair surface areas of wheat cultivars and Q were (1.00***) in low-P, (0.74**) in medium-P and (0.66**) in high-P soil. Similar high values of R2 were found for barley. These results show that the variation in root hairs of cereal cultivars can be considerable and it can play a significant role in P acquisition, especially in low-P soils.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 71
    ISSN: 1573-5036
    Keywords: Cichorium intybus ; chicon ; nitrate ; phosphorus ; vegetative growth
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract This study investigated the effects of nitrate and phosphate nutrition on chicory tap root development and chicon quality. Plants of chicory (Cichorium intybus flash) were grown on four concentrations of nitrate and phosphate: 3 mM NO3 / 1 mM PO 4 3− , high N and high P (control plants, N / P); 3 mM NO 3 − / 0.05 mM H2PO3− 4, high N and low P (N / p); 0.6 mM NO3 / 1 mM PO 4 3− , low N and high P (n / P); 0.6 mM NO 3 − / 0.05 mM PO 4 3− , low N and low P (n / p). The results suggested that, nitrogen limitation had the greatest impact on the shoot/root dry weight ratio. Only small changes in the shoot/root dry weight could be attributed to P limitation alone. Compared with the control, N limitation caused a marked increase in root SST activity (sucrose sucrose fructosyl transferase, the enzyme responsible for fructan synthesis in roots), the effect of P limitation on SST activity was less pronounced. The activity of SS (sucrose synthase) was also noticeably elevated at the early sample data by N limitation. N and P uptake were estimated by the amount of N and P accumulated by the whole plant during the vegetative period. With N limitation, P accumulation was decreased by 40-60% over the experimental period. The effects of P limitation on N accumulation were more variable, N uptake was 60% lower than the control during the tuberizing period (107 days after sowing). With N limitation, P concentrations in roots were lowered by 20-25%. With P limitation, total N concentration in roots decreased by 50% relative to the control, while nitrate concentration was increased more than 8 fold. These effects were detected only at 107 DAS. The amino acid content of roots was not affected by P limitation, however, N limitation altered strongly total amino acids. P limitation did alter the relative amino acid composition of roots early in the vegetative period: Roots harvested at the end of vegetative period were forced in the dark to produce an etiolated bud, the edible chicon. High N and high P fertility (N/P) were associated to a poor chicon yield and quality. However the presence of low P during vegetative growth moderates adverse effects of high nitrate and greatly improved chicon yeild and quality.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 72
    ISSN: 1573-5036
    Keywords: aluminium ; cellulose ; coal combustion by-product ; lime ; Lolium perenne ; phosphate rock ; phosphorus ; ryegrass ; Ultisol
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Remediation of soil acidity is crucial for increasing crop production and improving environmental quality of acid infertile soils. Soil incubation and greenhouse pot experiments were carried out to examine the interactions between phosphate rock (PR), coal combustion by-product (BP), dolomitic lime (L), and cellulose (C) in an acidic soil and their effects on ryegrass (Lolium perenne L. cv ‘Linn’) growth. BP and PR application increased plant P content and dry matter yield (DMY) of shoots and roots by improving soil Ca availability and reducing Al toxicity. Application of BP at low rates (5 to 10 g BP kg-1) with PR appeared to decrease both plant P content and DMY compared to PR application alone. The reduced DMY is due to an increased Al concentration in soil solution as a result of displacement of sorbed Al by Ca of BP. Increases in DMY were obtained by addition of lime along with PR and BP at low rates or by increasing BP application rates above 15 g kg-1. This improved plant response was likely related to alleviation of Al toxicity by CaCO3 contained in the BP. In addition to raising the pH to an acceptable level for plant growth, the dolomitic lime supplied needed Mg for plants, thereby maintaining a good balance between available Ca and Mg for plants in the BP- and PR-amended soils. The addition of cellulose to the BP- and PR-amended soils reduced water-soluble Al and increased DMY. Plant growth increased PR dissolution by 2.4 to 243% in a soil with low available P. Use of BP at moderate rates with PR and dolomitic lime appears to be the best combination in increasing crop yields on infertile acidic soils.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 73
    Electronic Resource
    Electronic Resource
    Springer
    Plant and soil 188 (1997), S. 279-297 
    ISSN: 1573-5036
    Keywords: ecosys ; modelling ; phosphorus ; root systems
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract The uptake of P by plant root systems is believed to be controlled by the concentration of soluble orthophosphate at the root surface. If a P transformation model in which this concentration is calculated were coupled to a root and mycorrhizal growth model in which this concentration is used to calculate P uptake, then it should be possible to simulate P uptake under different soil and climate conditions if soil properties relevant to the control of P concentration are known. To test this idea, models for the transformation and transport of inorganic and organic P were coupled to ones for root growth and nutrient uptake as part of the ecosys modelling program. Seasonal estimates of soluble P concentration, root growth and P uptake from the combined models were tested with data measured from barley under fertilized and unfertilized treatments in a long term P fertilizer experiment conducted on two different soils. In both soils the fertilizer treatment increased simulated and measured soluble P concentrations from 0.1-0.2 to 0.2-0.4 g m-3, annual P uptake from 0.6-0.7 to 1.2-1.4 g m-2, and annual DM accumulation from 400-500 to 700-800 g m-2. Increases in soluble P concentrations caused by fertilizer P were reproduced in the model from changes in the balance between the desorption and dissolution of solid P on one hand, and the uptake of P by root and mycorrhizal systems on the other. Increases in P uptake caused by fertilizer P were reproduced in the model from higher solution P concentrations, root uptake kinetics, and from functional equilibria for C and P exchange simulated among mycorrhizal, root and shoot components of the plant. There was a tendency in the model to overestimate P uptake later in the growing season in the unfertilized treatment which could be corrected if parameters for root uptake kinetics were reduced after anthesis. Because the model is constructed independently of data for P uptake, and avoids the use of site-specific parameters, it may provide a means of estimating uptake under different managements and climates from soils of known properties.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 74
    Electronic Resource
    Electronic Resource
    Springer
    Plant and soil 196 (1997), S. 123-131 
    ISSN: 1573-5036
    Keywords: ectomycorrhiza ; ergosterol ; Paxillus ; phosphorus ; Suillus ; weathering
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract The objectives of the study are firstly to test the ability of ectomycorrhizal pine seedlings to use apatite as a P source in comparison with non-mycorrhizal pine seedlings and secondly, to determine if there is a relation between exudation of organic acids and the ability to use apatite as a P source. Non-mycorrhizal Pinus sylvestris (L.) seedlings and seedlings ectomycorrhizal with 4 different isolates of ectomycorrhizal fungi were grown for 220 days in sand/peat filled pots with apatite (Ca5(F,OH)(PO4)3) as the sole P source. In an additional experiment, non-mycorrhizal Pinus sylvestris (L.) seedlings and seedlings ectomycorrhizal with 2 different isolates of ectomycorrhizal fungi were grown without any P source for 250 days. All other nutrients were supplied in a balanced nutrient solution. Ectomycorrhizal seedlings grew less than non-mycorrhizal seedlings but ectomycorrhizal seedlings produced a large external mycelium not included in the biomass estimates. All seedlings in the present study had low shoot:root ratios compared to seedlings growing under optimal conditions. All seedlings grown with apatite as P source had higher foliar P concentrations (0.71–2.11 mg/g) than seedlings growing without any P source (0.57–0.75 mg/g) indicating a significant ability to use apatite as a P source. Seedlings colonized by Suillus variegatus and Paxillus involutus had higher concentrations and total contents of P in shoots compared with non-mycorrhizal seedlings, indicating significant improvement of P uptake by these fungi in comparison with non-mycorrhizal seedlings or seedlings colonized Piloderma croceum. No clear relationship between exudation of organic acids and uptake of P was found. Seedlings colonized by S. variegatus reduced the pH of the soil more than seedlings colonized by P. involutus or non-mycorrhizal seedlings. It is suggested that S. variegatus colonization improves the P uptake by reducing the pH of the soil while P. involutus improves P uptake by having a greater ability to absorb dissolved phosphate than non-mycorrhizal roots or roots colonized by the other fungi used in the study.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 75
    Electronic Resource
    Electronic Resource
    Springer
    New forests 14 (1997), S. 33-44 
    ISSN: 1573-5095
    Keywords: nutrient concetration ; frost hardiness ; growth cessation ; Pinus sylvestris ; visual damage ; nitrogen ; phosphorus ; potassium
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract In this study the effect of summer fertilization on the initiation of frost hardening of containerized second-year Scots pine (Pinus sylvestris L.) seedlings is studied. During the second growing season three different fertilization programs (water soluble NPK with micronutrients) determined by electrical conductivity of peat water extract (0.2, 0.5 and 1.2 mS cm-1) were initiated. The growth and nutrient concentrations of needles were monitored during the fertilization period. The frost hardiness of seedlings was assessed on four separate occasions at two week intervals from August 7 to September 18. This assessment was based on artificial freezing tests and visual damage scoring of tissue browning on current-year needles. Clear differences in foliar N, P and K concentrations were observed between the fertilization treatments. Fertilization prolonged the growing period of needles and increased root collar diameter. In all the tests, the highest fertilization level resulted in the highest level of frost hardiness. The difference between the fertilization treatments ranged from 1 °C to 2.2 °C. Frost hardiness increased with an increase in foliar nitrogen concentration and slightly less consistently with increases in foliar phosphorus and potassium concentrations.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 76
    ISSN: 1573-5087
    Keywords: foliar fertilization ; forage yield ; gibberellic acid ; Lotus tenuis ; phosphorus
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Lotus tenuis is a perennial legume with a good adaptation to infertile, heavy and waterlogging soils. It can replace alfalfa in these sites with a similar feeding value. An important constraint is its weak competitive capacity with other graminae and weed species in permanent pastures, having consequently a poor forage yield. The objective of the present research is to overcome this disadvantage, enhancing its competitive ability with foliar applications of GA3 (GA) and phosphorus (P), increasing L. tenuis forage yield. Field experiments were conducted during 1994 with foliar application of GA (50 mg.l-1) and during 1995 with foliar application of GA (25 and 50 mg.l-1), phosphorus (8 kg.ha-1, as P2O5) and their combinations, in permanent pastures with L. tenuis and other companion grasses. In 1994 GA 50 increased significantly L. tenuis dry matter (DML) in 64.6% but not the dry matter of graminae fraction (DMG) and in consequence the total dry matter of the pasture (TDMP) was increased. In 1995 all GA treatments and their combinations with phosphorus enhanced DML but not DMG. In this sense GA 25 + P was the most effective treatment with a 151% increment of DML. Consequently TDMP was significantly increased due to a larger participation of L. tenuis in the forage yield. This increase was achieved due to a greater length and diameter of L. tenuis branches, with a logical modification in leaf:stem ratio. Moreover GA treatments reduced L. tenuis flower number. Phosphorus treatment, applied alone, showed an increase in the DML. GA treatments did not modify the feeding value of the forage in L. tenuis and graminae fractions, except GA 50 and GA 50 + P in acid detergent fiber (ADF), neutral detergent fiber (NDF) and crude protein (CP), respect to the control. The total crude protein (CP.m-2) was enhanced in all GA and GA + P treatments. Foliar GA3 and phosphorus spray applications increased the competitiveness of trefoil for light, on account of morphological changes in the spatial disposition of L. tenuis stems reaching faster the top of the pasture canopy. This practice can be an adequate alternative to increase the forage yield and total crude protein in permanent and cultivated pastures with a low cost-benefit ratio.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 77
    Electronic Resource
    Electronic Resource
    Springer
    Biogeochemistry 37 (1997), S. 237-252 
    ISSN: 1573-515X
    Keywords: freshwater ; limitation ; marine ; nitrogen ; phosphorus ; ratio ; stoichiometry ; trace elements
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences
    Notes: Abstract Nitrogen supply is often assumed to limitmarine primary production. A global analysis of totalnitrogen (N) to phosphorus (P) molar ratios shows thattotal N:P is low (〈16:1) in some estuarine andcoastal ecosystems, but up to 100:1 in open oceans.This implies that elements other than N may limitmarine production, except in human impacted, estuarineor coastal ecosystems. This pattern may reconcileconflicting enrichment studies, because N additionfrequently increases phytoplankton growth where totalN:P is expected to be low, but P, Fe, or Si augmentphytoplankton growth in waters where total N:P ishigh. Comparison of total N:P stoichiometry betweenmarine and freshwaters yields a model of the form ofthe aquatic N:P cycle.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 78
    ISSN: 1573-515X
    Keywords: carbon ; nitrogen ; Ohio River ; phosphorus ; Red field ratios ; dissolved organic matter ; rivers
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences
    Notes: Abstract A 12-month study was conducted to measure the concentrations ofdissolved organic matter (DOC, TDN, TDP) in four sites within a119 km long reach of the Ohio River, near Louisville, KY. In thisstudy we test whether specific geomorphological and biologicalfactors influenced variations in dissolved organic matter.Concentrations of DOC in the river averaged ≈1200μmol/L, and varied by nearly two orders of magnitudeseasonally (mean DOC during base flow ≈620 μmol/L).Peak periods for DOC at all sites were during April–May. Thesite nearest a navigation dam (deeper, lower current velocities)had significantly lower concentrations of TDN and greater C:Nratios than upstream sites. The largest tributary entering thisreach (Kentucky River) had no significant effect on levels of DOMin the main river, despite having significantly greaterconcentrations of TDN and lower levels of DOC during most monthsof the year. Concentrations of DOC, TDN, and TDP were notsignificantly different in littoral and pelagic habitats at allsites studied, suggesting little floodplain influence on DOM inthis constricted-channel section of the Ohio River. C:N ratios ofDOM in the Ohio were significantly different among seasons; C:Nexceeded or equaled Redfield ratios in summer and fall (6 to 10),but were below Redfield (1.8 to 3.0) during winter and spring.Regression models suggest that total phytoplankton densities andflow conditions are the two most important factors regulating DOMin this very large river.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 79
    Electronic Resource
    Electronic Resource
    Springer
    Journal of inclusion phenomena and macrocyclic chemistry 28 (1997), S. 95-103 
    ISSN: 1573-1111
    Keywords: Inclusion complex ; β-cyclodextrin ; thermal analysis ; kinetics
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The stability of the β-CD cinnamic aldehyde inclusion complex wasinvestigated by TG and DSC. The weight loss takes place in three stages:dehydration occurs at 50–120 °C; the dissociationof β-CD⋅C9H8O occurs at 200–260 °C;and the decomposition of β-CD begins at 280 °C. Thekinetics of the dissociation of cinnamic aldehyde from the β-CD cavitywere studied by means of thermogravimetry both at constant temperatureand linear increasing temperature. The results show that the dissociationof β-CD⋅C9H8O is dominated by a one-dimensional diffusionprocess. The activation energy, E, is 160 kJ⋅mol-1. Thepre-exponential factor A is 5.8 × 1014 min-1.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 80
    ISSN: 1573-1561
    Keywords: Nitrosomonas europaea ; nitrification ; inhibition ; kinetics ; monoterpenes ; Sequoia sempervirens ; conifers ; nitrogen cycling
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Chemistry and Pharmacology
    Notes: Abstract Inhibition by allelochemicals, including monoterpenes, has been suggested as a factor in the extremely low nitrification rates observed in coastal redwood forests. Similarities between the molecular structure of known nitrification inhibitors and some conifer monoterpenes have been suggested as one reason for the inhibition of autotrophic nitrifiers by conifer monoterpenes. The effect of monolerpenes on nitrification rate and growth of Nitrosomonas europaea was examined in whole-cell pure culture experiments using the five most abundant monoterpenes in coastal redwood needles. These are (in order of decreasing concentration in the needles) limonene, α-pinenc, sabinene, myrcene, and γ-terpinene. Four of the five compounds significantly inhibited growth of N. europaea in batch culture experiments. Short-term kinetic studies of the two most inhibitory monoterpenes, limonene and α-pinene, were performed on whole cells to evaluate the mode of interaction between these chemicals and nitrification rates. Inhibition constants (K i) of limonene (38 μM) and α-pinene (95 μM) were determined. Lineweaver-Burk plots of nitrification in the presence of monoterpenes appear to fit a noncompetitive inhibition model; however, the mechanisms of inhibition may be more complex.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 81
    Electronic Resource
    Electronic Resource
    Springer
    Agroforestry systems 38 (1997), S. 51-76 
    ISSN: 1572-9680
    Keywords: nitrogen ; nutrient cycling ; phosphorus ; soil fertility ; soil organic matter
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Trees can influence both the supply and availability of nutrients in the soil. Trees increase the supply of nutrients within the rooting zone of crops through (1) input of N by biological N2 fixation, (2) retrieval of nutrients from below the rooting zone of crops and (3) reduction in nutrient losses from processes such as leaching and erosion. Trees can increase the availability of nutrients through increased release of nutrients from soil organic matter (SOM) and recycled organic residues. Roots of trees frequently extend beyond the rooting depth of crops. Research on a Kandiudalfic Eutrudox in western Kenya showed that fast-growing trees with high N demand (Calliandra calothyrsus, Sesbania sesban and Eucalyptus grandis) took up subsoil nitrate that had accumulated below the rooting depth of annual crops. Sesbania sesban was also more effective than a natural grass fallow in extracting subsoil water, suggesting less leaching loss of nutrients under S. sesban than under natural uncultivated fallows. Nutrient release from SOM is normally more dependent on the portion of the SOM in biologically active fractions than on total quantity of SOM. Trees can increase inorganic soil N, N mineralization and amount of N in light fraction SOM. Among six tree fallows of 2- and 3-year duration on an Ustic Rhodustalf in Zambia, inorganic N and N mineralization were higher for the two tree species with lowest (lignin + polyphenol)-to-N ratio (mean = 11) in leaf litter than for the two tree species with highest ratio (mean = 20) in leaf litter. Trees can also restore soil fauna, which are important for SOM and plant residue decomposition. Some agroforestry trees have potential to provide N in quantities sufficient to support moderate crop yields through (i) N inputs from biological N2 fixation and retrieval of nitrate from deep soil layers and (ii) cycling of N from plant residues and manures. The cycling of P from organic materials is normally insufficient to meet the P requirements of crops. Sustained crop production with agroforestry on P-deficient soils will typically require external P inputs.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 82
    ISSN: 1573-5036
    Keywords: cell wall ; groundnut ; phosphorus ; root surface ; sorghum ; soybean
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Groundnuts have a superior ability to take up P from soils with low P fertility compared to sorghum and soybean. Previous experiments showed that this ability was neither attributable to better root development nor to root exudates capable of solubilizing Fe- and Al-bound P, the sparingly soluble P forms in soils. Direct "contact reactions" between cell wall components from these 3 plant species (groundnut, soybean and sorghum) and P-fixing Fe and Al minerals were examined. Cell wall preparations from groundnut roots showed a superior P solubilizing ability than those of soybean and sorghum. Cell wall activity of groundnut roots may thus at least partly explain the superior growth of this crop under P-deficient conditions. To characterize the active site responsible for P solubilization, effects of pH, heat, addition of cations, and digestion with enzymes (pectinase and cellulase) or HCl on P solubilization were investigated. Conclusion are 1) Solubilizing ability is not related to root CEC because soybean with higher root CEC showed an inferior solubilizing ability compared to groundnut. 2) The reaction site of cell-walls of groundnut roots is stable against heating and digestion with cellulase and pectinase. 3) Solubilizing ability was severely reduced by digestion with HCl. 4) Pre-treating cell walls with either Al3+, Fe3+, or Ga3+ decreased solubilizing ability but cations with lower valency such as Na+, K+, Ca2+ or Mg2+ had no effect. Soaking roots of groundnuts grown in solution culture in 0.5 M NaOH for 30 seconds prior to cell wall preparation led to a 30% reduction in solubilization of P from FePO4 without permanently damaging plants. This suggests that 5) the active component of the cell walls was located on the root epidermal cell surfaces. Based on these results a phosphorus solubilizing mechanism is proposed.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 83
    ISSN: 1573-5036
    Keywords: bioavailability ; competition ; phosphorus ; sorption ; sulfate ; uptake
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract The adsorption of phosphate on metal (hydr)oxides may be influenced by the pH and by the adsorption of other ions. In this study, the influence of sulphate and pH on phosphate adsorption on goethite and the availability to plants of adsorbed phosphate was examined. Maize plants were grown on suspensions of goethite with adsorbed phosphate, containing the same total amount of phosphate and either 0.11 mM or 2.01 mM sulphate at pH 3.7, 4.6 or 5.5. The uptake of phosphorus by the plants increased with the larger sulphate concentration and decreasing pH. Mean P uptake in the treatment with 2.01 mM sulphate and pH 3.7 was 55 µmol plant-1, whereas in the treatment with 0.11 mM sulphate and pH 5.5 it was 2 µmol plant-1. Batch adsorption experiments using32 P and speciation modelling of ion adsorption showed that in the presence of sulphate, the phosphate concentration in solution strongly increased with decreasing pH, due to competitive adsorption between sulphate and phosphate on goethite. Modelled phosphate concentrations in solution in the uptake experiment were all below 0.6 µM and correlated well with the observed P uptake. This correlation indicates that the strong influence of the sulphate concentration and pH on the plant-availability of adsorbed phosphate results from the competition between sulphate and phosphate for adsorption on goethite.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 84
    Electronic Resource
    Electronic Resource
    Springer
    Euphytica 98 (1997), S. 177-182 
    ISSN: 1573-5060
    Keywords: Genetic ; mineral nutrition ; phosphorus ; rhizosphere ; root hairs
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Length and density (number mm-1 root) of root hairs of two barley (Hordeum vulgare L.) cultivars Salka and Zita and their capability to absorb phosphorus (P) from nutrient solution as well as from rhizosphere soil were studied. The cultivars were chosen because they differed most among 30 cultivars in ability to absorb P from low P soil in two field conditions. In nutrient solution culture, Salka had 32±4 root hairs mm-1 root, 1.02±0.22 mm long. Zita had 21±3 hairs mm-1 root, 0.54±0.14 mm long. In soil, the root hairs of both the cultivars were slightly longer (Salka 1.10 ±0.16 mm; Zita 0.63±0.18 mm) than in solution culture but the difference was non-significant (p〈0.05). The root hairs increased the effective root surface area of Salka by 206% and that of Zita by 81%. In solution culture, Salka produced 163±9 m g-1 and Zita 153±11 m g-1 dry roots in 21 days. Salka produced 1.65±0.22 g and Zita 1.51±0.31 g of green dry matter (DM). The cultivars did not differ in uptake of P from nutrient solution culture. The P content of DM was 0.42±0.1% in Salka and 0.41±0.08% in Zita. In soil, Salka depleted two times more P from rhizosphere than Zita. The longer root hairs of Salka increased the extension of the depletion zone for NaHCO3-Pi (inorganic P extracted with 0.5 M NaHCO3) in the rhizosphere. The cultivars also depleted NaOH-Pi (inorganic P extracted with 0.1 M NaOH) from the rhizosphere soil, but the difference between the cultivars was non-significant (p〈0.05). The results suggested that the ability of Salka to absorb more inorganic soil P was due to its longer and denser root hairs.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 85
    ISSN: 1573-5079
    Keywords: activation ; deactivation ; induction ; irradiance ; kinetics ; photosynthesis ; phytoplankton ; Rubisco
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The activity of ribulose-1,5-bisphosphate carboxylase/oxygenase (Rubisco) was examined in three marine microalgae: the chlorophyte t Dunaliella tertiolecta and the chromophytes t Pavlova lutheri and t Thalassiosira pseudonana. The three species differed in the sensitivity of Rubisco activity in crude extracts to magnesium ion concentration, the presence of protease inhibitors, the duration of the incubation on activity, and the potential for full activation of Rubisco with 20 mM magnesium chloride and 20 mM bicarbonate t in vitro. t D. tertiolecta had responses that were similar to those described in vascular plants: regulation of initial activity on a gradient of irradiances; maximum initial activities that were 80– 90% of light-saturated photosynthesis; total activities that exceeded light-saturated photosynthesis by 30–100%; and deactivation of Rubisco in darkness. Both initial and total activity declined in darkness and increased on a return to growth irradiance. First-order time constants were about 9 min for deactivation and 3 min for reactivation of initial activity. The decline in total activity after a transition into darkness could not be reversed t in vitro but could be reversed by exposing t D. tertiolecta to light, a characteristic of regulation by CA1P. The responses of t T. pseudonana were qualitatively similar, except that recovery of initial activity was low and could only account for 30–40% of light-saturated photosynthesis. Rubisco from t T. pseudonana exposed to low irradiance could be activated t in vitro but at growth irradiance and higher, total activity was lower than initial activity. The time constants for deactivation and reactivation of initial activity after reciprocal switches between growth irradiance and darkness were 12–18 min and 3 min in t T. pseudonana. t P. lutheri showed no regulation of Rubisco activity in response to changes in irradiance or light-dark transitions. This may have been an artifact of the conditions chosen to measure activity.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 86
    ISSN: 1573-5117
    Keywords: nitrogen ; phosphorus ; phytoplankton biomass ; Daphnia grazing
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The role of nitrogen as a factor controllingphytoplankton biomass was studied in nutrientenrichment incubations in the laboratory using waterfrom pelagic region of two mesotrophic lakes ineastern Finland, Lake Kallavesi (in year 1994) andLake Juurusvesi (in year 1995). We used differentcombinations of phosphorus and nitrogen additions ina total of eight experiments. Furthermore, we includedDaphnia grazing treatment to the experimentaldesign in Lake Juurusvesi experiments. The nitrogentreatments did not increase chlorophyll aconcentration in any of the experiments compared withthe controls. Chlorophyll a content was highestin those nutrient treatments where phosphorus wasadded with or without nitrogen. Daphnia grazingdecreased chlorophyll a concentration comparedwith non-grazed treatments. In some cases grazing alsocaused higher ammonium concentrations. Theseexperiments, as well as the nutrient ratio of the lakewater used, suggest that phosphorus is likely tocontrol the amount of phytoplankton biomass.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 87
    ISSN: 1573-5117
    Keywords: periphyton ; algae ; wetlands ; Everglades ; Eutrophication ; phosphorus ; biomass ; primary productivity ; nutrient cycling
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract We sampled periphyton in dominant habitats at oligotrophic and eutrophic sites in the northern Everglades during the wet and the dryseasons to determine the effects of nutrient enrichment on periphytonbiomass, taxonomic composition, productivity, and phosphorus storage. Arealbiomass was high (100–1600 g ash-free dry mass [AFDM]m−2) in oligotrophic sloughs and in stands of the emergentmacrophyte Eleocharis cellulosa, but was low in adjacent stands of sawgrass,Cladium jamaicense (7–52 g AFDM m−2). Epipelon biomasswas high throughout the year at oligotrophic sites whereas epiphyton andmetaphyton biomass varied seasonally and peaked during the wet season.Periphyton biomass was low (3–68 g AFDM m−2) and limitedto epiphyton and metaphyton in open-water habitats at eutrophic sites andwas undetectable in cattail stands (Typha domingensis) that covered morethan 90% of the marsh in these areas. Oligotrophic periphytonassemblages exhibited strong seasonal shifts in species composition and weredominated by cyanobacteria (e.g., Chroococcus turgidus, Scytonema hofmannii)during the wet season and diatoms (e.g. Amphora lineolata, Mastogloiasmithii) during the dry season. Eutrophic assemblages were dominated byCyanobacteria (e.g., Oscillatoria princeps) and green algae (e.g., Spirogyraspp.) and exhibited comparatively little seasonality. Biomass-specific grossprimary productivity (GPP) of periphyton assemblages in eutrophic openwaters was higher than for comparable slough assemblages, but areal GPP wassimilar in these eutrophic (0.9–9.1 g C m−2d−1) and oligotrophic (1.75–11.49 g C m−2d−1) habitats. On a habitat-weighted basis, areal periphytonGPP was 6- to 30-fold lower in eutrophic areas of the marsh due to extensiveTypha stands that were devoid of periphyton. Periphyton at eutrophic siteshad higher P content and uptake rates than the oligotrophic assemblage, butstored only 5% as much P because of the lower areal biomass.Eutrophication in the Everglades has resulted in a decrease in periphytonbiomass and its contribution to marsh primary productivity. These changesmay have important implications for efforts to manage this wetland in asustainable manner.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 88
    Electronic Resource
    Electronic Resource
    Springer
    Hydrobiologia 363 (1997), S. 117-126 
    ISSN: 1573-5117
    Keywords: nutrient limitation ; eutrophication ; nitrogen ; phosphorus ; Archipelago Sea
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Eutrophication is the most acute environmentalproblem in the Archipelago Sea, SW Finland. Whenanalysing the factors behind this escalatingeutrophication the determination of limitingnutrient at a given time is essential. Besidesexperimentations, nutrient limitation of planktonhas been extensively studied by direct chemicalanalyses. We used the latter approach in this work.Nutrient limitation was studied by calculatingdifferent nutrient ratios – totalnitrogen:phosphorus, inorganic nitrogen:phosphorus,and nutrient balance ratio. Results showed thatphosphorus usually limited primary production onlynear the coast line. In the middle zone of theArchipelago Sea the limiting factor variedtemporally. Outer in the open sea nitrogen limitedprimary production during most of the year.Phosphorus limited phytoplankton growth especiallyin spring and in summer and nitrogen in late summerand in autumn. Our results suggested that nitrogenis an important limiting nutrient in the ArchipelagoSea. In recent years when the eutrophication hasproceeded there has been a shift from productionlimitation by both nutrients to limitation bynitrogen alone. But if we want to define andcharacterize the nutrient limitation of the entireecosystem of the Archipelago Sea, budgets have to becalculated for both N and P and internal recyclingmust be taken into account as well as externalsupply of nutrients and loss processes.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 89
    Electronic Resource
    Electronic Resource
    Springer
    Biogeochemistry 37 (1997), S. 63-75 
    ISSN: 1573-515X
    Keywords: nutrient limitation ; soil development ; nitrogen ; phosphorus ; chronosequence ; Hawai'i
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences
    Notes: Abstract Walker & Syers (1976) proposed a conceptual model that describesthe pattern and regulation of soil nutrient pools and availability during long-term soil and ecosystem development. Their model implies that plantproduction generally should be limited by N on young soils and by P on oldsoils; N and P supply should more or less equilibrate onintermediate-aged soils. We tested the application of this model to nutrientlimitation, using a well characterized substrate age sequence in Hawaiianmontane rain forest. Earlier experiments had evaluated nutrient limitationin forests on a young (300 y) and an old (4,100,000 y) substrate on the samedevelopmental sequence; N alone limited tree growth on the youngsubstrate, while P alone did so on the old one. An additional fertilizerexperiment based on replicated treatments with N, P, and all othernutrients combined, applied in individually and in all factorialcombinations, was established in an intermediate-aged site in theLaupahoehoe Forest Reserve, Hawaii. Here, diameter increments of thedominant tree Metrosideros polymorpha increased slightly with Nadditions, and nearly doubled when N and P were added together.Additions of elements other than N and P had no significant effecton growth. These results show that N and P had equilibrated (relativeto plant requirements) in the intermediate aged site. Together withthe earlier experiments, these results suggest that the Walker and Syersmodel provides a useful starting point for explaining the nature anddistribution of nutrient limitation in forest ecosystems.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 90
    ISSN: 1573-6822
    Keywords: diabetes ; rat ; cell culture ; antidepressant ; kinetics ; biotransformation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Medicine
    Notes: Abstract Biotransformation of amitriptyline (AMI) was studied at different intervals in freshly isolated hepatocytes from healthy or streptozocin-induced diabetic rats in order to investigate the influence of the diabetic state. Levels of free and conjugated AMI, demethylated and hydroxylated metabolites, were assessed by HPLC analysis. In hepatocytes isolated from diabetic rats, AMI was less completely metabolized and the demethylation reaction became more important than in non-diabetic rat hepatocytes. Although the proportions of hydroxylated metabolites decreased in diabetic rats, it always remained predominant. Furthermore, glucuronidation of metabolites was greater, especially for (Z)-10-hydroxynortriptyline in diabetic animals.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 91
    ISSN: 1573-2932
    Keywords: phosphorus ; P flux ; microbial activity ; redox ; simulation ; Lake Kinneret ; sediment ; accumulative P release
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Different factors which interactively control the flux of soluble reactive phosphorus (SRP) at the sediment water irterface (SWI) of Lake Kinneret were studied seasonally. The influence of pH, Eh and microbial activity on SRP flux at the SWI was investigated by manipulating the conditions in the overlying water of intact sediment cores. The calculated diffusive SRP flux out of the sediment was lower in cores sampled during winter and spring than during the period of amixis. Potential SRP release, as measured in the absence of microbial activity, was strongly enhanced upon the transition from oxic to anoxic conditions indicating P release from iron(III)-bound phosphorus. In spring and summer cores, an enhanced SRP flux from sediments at pH 7 in comparison to pH 8 indicated P release from carbonate-bound P which sedimented previously as result of high pH values during the algal spring bloom. Microbial uptake at the SWI was the most important sink for SRP and no net-flux occured under oxic conditions. The higher net-flux of P under anoxic conditions was linked to carbon limitation ofthe bacteria at the SWI.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 92
    Electronic Resource
    Electronic Resource
    Springer
    Water, air & soil pollution 99 (1997), S. 477-486 
    ISSN: 1573-2932
    Keywords: sediment ; nitrogen ; phosphorus ; organic matter ; cluster analysis ; Gulf of Finland ; estuaries
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Dry weight (DW), ignition loss (IL) and concentrations of total nitrogen (TN) and total phosphorus (TP) of the sediment surface layer (0 to 10 cm, 1 cm slices) were analyzed from 20 sites in the eastern Gulf of Finland. The distance of the sampling sites from the mouth of the River Neva explained the nutrient concentrations of the sediments well, while the effect of water depth was negligible. The increase of TN and the decrease of TP along the transect from the river mouth towards the open Gulf were caused by the diminishing share of allochthonous material supplied from the River Neva. The mean TN concentration of the different accumulation areas was about 40 % higher in the sediment surface than in the deeper layer (9 to 10 cm). The corresponding difference for TP varied from 53 to 56 %. The results suggest considerable netflux of nutrients from sediment to water. The net sediment accumulation of nutrients were estimated as 6.0 g m−2 a−1 of N and 1.7 g m−2 a−1 of P corresponding 22 000 t a− of N and 6 100 t a−1 of P for the whole eastern Gulf.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 93
    ISSN: 1573-2932
    Keywords: fractionation ; redistribution ; saturation ; kinetics ; heavy metals
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Solid-phase transformations of Cd, Cu, Cr, Ni and Zn, added as soluble salts at several levels to two arid-zone soils, were studied over a period of one year. The soils were maintained under a saturated-paste regime and sampled periodically. A selective sequential dissolution procedure was employed to determine the changes in metal distribution among six operationally defined solid-phase fractions. A function,U ts was introduced to measure the fractional attainment of equilibrium of the soils following a perturbation. The direction and rate of redistribution of the added metals in the soils were affected by the nature of the metal, the soil properties and the metal loading level. Cd added to the soils was transferred from the exchangeable (EXC) into the carbonate (GARB) fraction. When soluble Cu, Cr, Ni and Zn were added at low loading levels, metals were transferred from the reducible oxides(RO) bound and easily reducible oxides (ERO) bound fractions and the EXC fraction, into the CARB fraction. However, at the higher loading level, metals were transferred from the EXC and CARB fractions into the organic matter bound (OM), ERO and RO fractions. TheU ts function approached lower values as incubation continued but remained removed from 1. The overall flux of metals among fractions was the combined result of the readjustment of the metals in the native soil to changing conditions due to saturation, and the transfer of added soluble metals to the less labile fractions.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 94
    ISSN: 1573-2932
    Keywords: Adriatic Sea ; nutrients ; benthic fluxes ; carbon ; nitrogen ; silicon ; phosphorus ; budgets
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Benthic fluxes of dissolved inorganic N, Si and P nutrients, alkalinity, dissolved inorganic C (DIC), and O2 from sediments in the Gulf of Trieste (northern Adriatic, Italy) were measured monthly in the period September 1995 - August 1996 using in situ incubated light benthic chambers. The highest efluxes of DIC, NH4+, PO43-, Si(OH)4, and NO3- influxes encountered in late summer - early autumn were the consequence of degradation of benthic microalgae, and in autumn mostly of sedimented phytoplankton. High NO3- efflux was observed in spring. Only NH4+ and Si(OH)4 fluxes were significantly correlated with temperature. This correlation suggests that the rate of downward input and the quality and quantity of sedimentary organic matter (autochthonous and allochthonous) were superimposed on the temperature fluctuations. High DIC, NH4+ and Si(OH)4 effluxes observed in July 1996 were due to the late spring - early summer degradation of sedimentary organic matter produced by benthic microalgae, while the autumn phytoplankton bloom was quickly reflected in enhanced benthic fluxes due to higher temperature. Significant correlations between NH4+, PO43- and Si(OH)4 fluxes suggested their parallel regeneration and utilization at the sediment-water interface. The nutrient fluxes were linked to O2 consumption, suggesting that aerobic oxidation processes were important at the sediment-water interface in the Gulf. The N, P and Si nutrients released from sediment pore waters are probably utilized in benthic microalgal and bottom-water primary production. This indicates that pelagic and benthic communities in the central part of the Gulf of Trieste function relatively independently of each other.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 95
    ISSN: 1573-2932
    Keywords: Cystoseira myrica ; Red Sea ; coral reefs ; nitrogen ; phosphorus ; pollution ; eutrophication
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Elevated phosphate concentrations at Safaga and Quseir, Red Sea, Egyptian coast, wererelated to some ecological and nutritional aspects of the macro-alga Cystoseira myrica during1985. The results obtained were compared with those recorded for a non-polluted control site atGhardaqa. Chemical analysis of surface seawater samples revealed that the concentrations of dissolvedphosphate at Safaga and Quseir were 3 and 20 times as much as that at Ghardaqa, respectively.The standing crop of C. myrica showed two peaks in spring and autumn. Maximum biomass yield(491 g m-2) and number of individuals (127 m-2) of C. myrica were recorded in the spring at theGhardaqa site. Quseir C. myrica samples contained significantly higher protein-N, total-N andtotal-P values but lower carbohydrate values than the Safaga and Ghardaqa samples (LSD at 1%level). Tissue N:P molar ratios for C. myrica, Laurencia papillosa and Ulva lactuca collected fromGhardaqa ranged from 68-98, compared to 30-59 for the same species collected at thephosphorus polluted sites at Safaga and Quseir. The carbon levels and the C:N ratios of C. myricaexhibited no significant variations in the three studied sites. However, the C:P ratios of Ghardaqaplants were significantly higher than those of Safaga and Quseir.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 96
    ISSN: 1573-2932
    Keywords: Cystoseira myrica ; Red Sea ; coral reefs ; nitrogen ; phosphorus ; pollution ; eutrophication
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Elevated phosphate concentrations at Safaga and Quseir, Red Sea, Egyptian coast, were related to some ecological and nutritional aspects of the macro-algaCystoseira myrica during 1985. The results obtained were compared with those recorded for a non-polluted control site at Ghardaqa. Chemical analysis of surface seawater samples revealed that the concentrations of dissolved phosphate at Safaga and Quseir were 3 and 20 times as much as that at Ghardaqa, respectively. The standing crop ofC. myrica showed two peaks in spring and autumn. Maximum biomass yield (491 g m−2) and number of individuals (127 m−2) ofC. myrica were recorded in the spring at the Ghardaqa site. QuseirC. myrica samples contained significantly higher protein-N, total-N and total-P values but lower carbohydrate values than the Safaga and Ghardaqa samples (LSD at 1% level). Tissue N:P molar ratios forC. myrica, Laurencia papillosa andUlva lactuca collected from Ghardaqa ranged from 68–98, compared to 30–59 for the same species collected at the phosphorus polluted sites at Safaga and Quseir. The carbon levels and the C:N ratios ofC. myrica exhibited no significant variations in the three studied sites. However, the C:P ratios of Ghardaqa plants were significantly higher than those of Safaga and Quseir.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 97
    Electronic Resource
    Electronic Resource
    Springer
    Water, air & soil pollution 93 (1997), S. 243-254 
    ISSN: 1573-2932
    Keywords: arsenic ; lead ; phosphorus ; heavy metal ; mobility
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Past use of lead arsenate insecticides has resulted in elevated concentrations of lead (Pb) and arsenic (As) in topsoils of many existing and former deciduous tree fruit orchard sites throughout the world. Application of phosphate (PO4)-containing fertilizers to these soils can increase soil As solubility, phytoavailability and downward mobility. A laboratory soil column experiment was conducted to determine if As released by phosphate additions to a topsoil artificially contaminated with lead arsenate (1.65 mmol total Pb/kg; 1.10 mmol total As/kg) would be appreciably resorbed by the underlying uncontaminated subsoil. Treatments were a factorial combination of topsoil amendment with monoammonium phosphate (MAP, 0 or 16.67 mmol PO4/kg), and amount of leaching (1, 5 and 10 pore volume displacements (PVD) with distilled water under saturated flow conditions). Soil As decreased in the topsoil with increasing amount of leaching and increased in the subsoil. Addition of MAP substantially increased loss of topsoil As, promoted As transport into and through the subsoil, and increased dissolved As concentrations in the column leachates. After 10 PVDs, 95% of the initial soil As remained in the −MAP columns, while 56% of the initial soil As remained the +MAP columns. Dissolved Pb concentrations were 〈0.05μmol/L in all column leachates. The data are consistent with a mechanism of PO4-enhanced release of As in the topsoil and subsequent promotion of As movement through the subsoil by continuing competition of dissolved As and PO4 for ion adsorption sites. The experimental results indicate that use of PO4-containing fertilizers on lead arsenate-contaminated soils has the potential to greatly enhance downward movement of soil As.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 98
    Electronic Resource
    Electronic Resource
    Springer
    Water, air & soil pollution 99 (1997), S. 633-640 
    ISSN: 1573-2932
    Keywords: zebra mussel ; Dreissena polymorpha ; phosphorus ; trophic state ; recovery ; Lake Como
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract A large scale study on the western basin of Lake Como (N. Italy) was started in 1995 to examine the effects of the zebra mussel colonization which began in early '90. Our results have been related to '91-92 data (pre-Dreissena period), before the maximum colonization of zebra mussel. In spring and summer of the post-Dreissena period total phosphorus, P-PO4,, nitrate and chlorophyll values decreased, while ammonium and transparency increased at every sampling station. Zebra mussel does not modify the trophic state of this sub-basin but it plays an important role in nutrient cycling. The entire population can filter epilimnetic waters 2.1 times per year and can produce 2.9 × 104 t/y of pseudofaeces which are transferred to sediments.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 99
    Electronic Resource
    Electronic Resource
    Springer
    Water, air & soil pollution 93 (1997), S. 243-254 
    ISSN: 1573-2932
    Keywords: arsenic ; lead ; phosphorus ; heavy metal ; mobility
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Past use of lead arsenate insecticides has resulted in elevated concentrations of lead (Pb) andarsenic (As) in topsoils of many existing and former deciduous tree fruit orchard sites throughoutthe world. Application of phosphate (PO4)-containing fertilizers to these soils can increase soil Assolubility, phytoavailability and downward mobility. A laboratory soil column experiment wasconducted to determine if As released by phosphate additions to a topsoil artificially contaminatedwith lead arsenate (1.65 mmol total Pb/kg; 1.10 mmol total As/kg) would be appreciably resorbedby the underlying uncontaminated subsoil. Treatments were a factorial combination of topsoilamendment with monoammonium phosphate (MAP, 0 or 16.67 mmol PO4/kg), and amount ofleaching (1, 5 and 10 pore volume displacements (PVD) with distilled water under saturated flowconditions). Soil As decreased in the topsoil with increasing amount of leaching and increased inthe subsoil. Addition of MAP substantially increased loss of topsoil. As, promoted As transportinto and through the subsoil, and increased dissolved As concentrations in the column leachates.After 10 PVDs, 95% of the initial soil As remained in the -MAP columns, while 56% of the initialsoil As remained the +MAP columns. Dissolved Pb concentrations were 〈0.05 µmol/Lin all column leachates. The data are consistent with a mechanism of PO4-enhanced release of Asin the topsoil and subsequent promotion of As movement through the subsoil by continuingcompetition of dissolved As and PO4 for ion adsorption sites. The experimental results indicatethat use of PO4-containing fertilizers on lead arsenate-contaminated soils has the potential togreatly enhance downward movement of soil As.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 100
    Electronic Resource
    Electronic Resource
    Springer
    Water, air & soil pollution 99 (1997), S. 457-464 
    ISSN: 1573-2932
    Keywords: sediment ; phosphorus ; fractionation ; release ; humic lake
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Lake Flosek (north-eastern part of Poland) is a small shallow and without outflow lake which has been limed in 1970. The concentration of Ca was increased from 3–4 mg L−1 to 17 mg L−1 in the water and from 0.2–0.3% dry weight to 0.9–1.7% dry weight in sediments (5 cm upper layer) due to CaCO3 addition to the lake. In the spring-summer seasons of 1992 and 1993, an experimental study was conducted in Lake Flosek to assess the capacity of bottom sediments to uptake and release mineral phosphorus. The rate of phosphorus exchange between sediments and near-bottom water was experimentally measured under conditions of high (100%), and of reduced (10%) oxygen saturation in near-bottom water. To determine the component of sediments responsible for the uptake of most phosphorus, the proportions of phosphorus forms in sediments were analysed. Sediments of Lake Flosek showed a slight tendency to release phosphates. The rate of this process was similar under high (100%) and low (10%) oxygen saturations ranging from - 0.161 to + 0.200 mg P m−2 d−1. This is much lower (by 1–2 orders of magnitude) than reported from other harmonic, non-humic lakes. In the total phosphorus pool, the highest content of phosphorus was found in the organic and residual phosphorus fractions (over 70% of the total phosphorus in sediments). The largest part of the readily extractable phosphorus was found in the fraction bound to AI and humic substances (41%). Both these fractions determine a weak exchange of phosphorus between sediments and water. No difference in P-release related to P-fraction compound was found in the cores taken from three sites in the lake.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...