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  • Wiley-Blackwell  (13,286)
  • American Meteorological Society
  • 2010-2014  (2,046)
  • 2000-2004  (2,135)
  • 1995-1999  (14,113)
  • 2012  (2,046)
  • 2000  (2,135)
  • 1996  (14,113)
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  • 2010-2014  (2,046)
  • 2000-2004  (2,135)
  • 1995-1999  (14,113)
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  • 1
    Publication Date: 2021-01-07
    Description: The elemental fluxes and heat flow associated with large aquifer systems can be significant both at local and at regional scales. In fact, large amounts of heat transported by regional groundwater flow can affect the subsurface thermal regime, and the amount of matter discharged towards the surface by large spring systems can be significant relative to the elemental fluxes of surface waters. The Narni-Amelia regional aquifer system (Central Italy) discharges more than 13 m3 sec)1 of groundwater characterised by a slight thermal anomaly, high salinity and high pCO2. During circulation in the regional aquifer, groundwater reacts with the host rocks (dolostones, limestones and evaporites) and mixes with deep CO2-rich fluids of mantle origin. These processes transfer large amounts of dissolved substances, in particular carbon dioxide, and a considerable amount of heat towards the surface. Because practically all the water circulating in the Narni-Amelia system is discharged by few large springs (Stifone-Montoro), the mass and energy balance of these springs can give a good estimation of the mass and heat transported from the entire system towards the surface. By means of a detailed mass and balance of the aquifer and considering the soil CO2 fluxes measured from the main gas emission of the region, we computed a total CO2 discharge of about 7.8 · 109 mol a)1 for the whole Narni-Amelia system. Finally, considering the enthalpy difference between infiltrating water and water discharged by the springs, we computed an advective heat transfer related to groundwater flow of 410 ± 50 MW.
    Description: Published
    Description: 182-196
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: reserved
    Keywords: carbon dioxide degassing ; heat flow ; regional aquifer ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 2
    Publication Date: 2020-12-14
    Description: We study the implications of a recently published mass balance of the Greenland ice sheet (GrIS), derived from repeated surface elevation measurements from NASA’s ice cloud and land elevation satellite (ICESat) for the time period between 2003 and 2008. To characterize the effects of this new, high-resolution GrIS mass balance, we study the time-variations of various geophysical quantities in response to the current mass loss. They include vertical uplift and subsidence, geoid height variations, global patterns of sea level change (or fingerprints), and regional sea level variations along the coasts of Greenland. Long-wavelength uplifts and gravity variations in response to current or past ice thickness variations are obtained solving the sea level equation, which accounts for both the elastic and the viscoelastic components of deformation. To capture the short-wavelength components of vertical uplift in response to current ice mass loss, which is not resolved by satellite gravity observations, we have specifically developed a high-resolution regional elastic rebound (ER) model. The elastic component of vertical uplift is combined with estimates of the viscoelastic displacement fields associated with the process of glacial-isostatic adjustment (GIA), according to a set of published ice chronologies and associated mantle rheological profiles. We compare the sensitivity of global positioning system (GPS) observations along the coasts of Greenland to the ongoing ER and GIA. In notable contrast with past reports, we show that vertical velocities obtained by GPS data from five stations with sufficiently long records and from one tide gauge at the GrIS margins can be reconciled with model predictions based on the ICE-5G deglaciation model and the ER associated with the new ICESat-derived mass balance.
    Description: Published
    Description: 1457-1474
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: JCR Journal
    Description: restricted
    Keywords: Sea level change ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 3
    Publication Date: 2021-06-22
    Description: The building materials of the Theatre of Marcellus, 44–11 BCE, reflect Roman builders’ careful selections of tuff and travertine for dimension stone and volcanic aggregates for pozzolanic concretes. The vitric–lithic–crystal Tufo Lionato tuff dimension stone contains a high proportion of lava lithic fragments, which increase its compressive strength and decrease water sorption, enhancing durability. Sophisticated installations of travertine dimension stone reinforce the tuff masonry, which is integrated with durable concrete walls and barrel vaults. The pozzolanic mortars of the concretes contain harenae fossiciae mainly from the intermediate alteration facies of the mid-Pleistocene, scoriaceous Pozzolane Rosse pyroclastic flow. They have pervasive interpenetrating pozzolanic cements, including strätlingite, similar to highquality, imperial era mortars. Concrete walls are faced with refined Tufo Lionato opus reticulatum and tufelli, and opus testaceum of fired, greyish-yellow brick. The exploratory concrete masonry, which includes some of the earliest examples of brick facings and strätlingite cements in Rome, and the integration of these materials in complex architectural elements and internal spaces, reflect the highly skilled workmanship, rigorous work-site management and technical supervision of Roman builders trained in republican era methods and materials.
    Description: Published
    Description: 728–742
    Description: JCR Journal
    Description: restricted
    Keywords: VOLCANIC TUFF MASONRY ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous
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  • 4
    Publication Date: 2017-04-04
    Description: We propose a method to introduce a refined representation of the ground motion in the framework of the Probabilistic Seismic Hazard Analysis (PSHA). This study is especially oriented to the incorporation of a priori information about source parameters, by focusing on the directivity effect and its influence on seismic hazard maps. Two strategies have been followed. One considers the seismic source as an extended source, and it is valid when the PSHA seismogenetic sources are represented as fault segments. We show that the incorporation of variables related to the directivity effect can lead to variations up to 30% of the hazard level, in terms of spectral acceleration response at 5 sec., exceeding probability of 10% in 50 years. The second one concerns the more general problem of the seismogenetic areas, where each point is a seismogenetic source having the same chance of enucleate a seismic event. In our proposition the point source is associated to the rupture-related parameters, defined using a statistical description. As an example, we consider a source point of an area characterized by strike slip faulting style. With the introduction of the directivity correction the modulation of the hazard map reaches values up to 100%. The introduction of directivity does not increase uniformly the hazard level, but acts more like a redistribution of the estimation that is consistent with the fault orientation. A general increase appears only when no a-priori information is available. However, nowadays good a-priori knowledge exists on style of faulting, dip and orientation of faults associated to the majority of the seismogenetic zones of the present seismic hazard maps. Following this method, all the information collected may be easily converted to obtain a more comprehensive and meaningful probabilistic Seismic Hazard formulation.
    Description: Published
    Description: 616-626
    Description: 4.1. Metodologie sismologiche per l'ingegneria sismica
    Description: JCR Journal
    Description: reserved
    Keywords: Earthquake ground motion ; Earthquake source observation ; Probabilistic Seismic Hazard ; 04. Solid Earth::04.06. Seismology::04.06.11. Seismic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 5
    Publication Date: 2017-04-04
    Description: The occurrence of crystallized and glassy melt inclusions (MI) in high-grade, partially melted metapelites and metagraywackes has opened up new possibilities to investigate anatectic processes. The present study focuses on three case studies: khondalites from the Kerala Khondalite Belt (India), the Ronda migmatites (Spain), and the Barun Gneiss (Nepal Himalaya). The results of a detailed microstructural investigation are reported, along with some new microchemical data on the bulk composition of MI. These inclusions were trapped within peritectic garnet and ilmenite during crystal growth and are therefore primary inclusions. They are generally isometric and very small in size, mostly £15 lm, and only rarely reaching 30 lm; they occur in clusters. In most cases inclusions are crystallized ( nanogranites ) and contain a granitic phase assemblage with quartz, feldspar and one or two mica depending on the particular case study, commonly with accessory phases (mainly zircon, apatite, rutile). In many cases the polycrystalline aggregates that make up the nanogranites show igneous microstructures, e.g. granophyric intergrowths, micrographic quartz in K-feldspar and cuneiform rods of quartz in plagioclase. Further evidence for the former presence of melt within the investigated inclusions consists of melt pseudomorphs, similar to those recognized at larger scale in the host migmatites. Moreover, partially crystallized inclusions are locally abundant and together with very small (£8 lm) glassy inclusions may occur in the same clusters. Both crystallized and partially crystallized inclusions often display a diffuse nanoporosity, which may contain fluids, depending on the case study. After entrapment, inclusions underwent limited microstructural modifications, such as shape maturation, local necking down processes, and decrepitation (mainly in the Barun Gneiss), which did not influence their bulk composition. Re-homogenized nanogranites and glassy inclusions show a leucogranitic and peraluminous composition, consistent with the results of partial melting experiments on metapelites and metagraywackes. Anatectic MI should therefore be considered as a new and important opportunity to understand the partial melting processes.
    Description: Published
    Description: 303-322
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: JCR Journal
    Description: restricted
    Keywords: garnet ; melt inclusions ; melt microstructures ; migmatites ; nanogranite ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology
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  • 6
    Publication Date: 2017-04-03
    Description: Campi Flegrei collapse caldera (Italy) is a high-risk volcanic area located close to Naples and includes part of the densely populated city. This area is characterised by large up and down ground displacements. The last large uplift episode caused 3.5 m of cumulative vertical displacement at the centre of the town of Pozzuoli, during the period 1969–1984. Up and down ground movements in this area often occur without intercurring eruptions and are similar to what is observed at other calderas worldwide. Here, however, they appear more evident and amplified. Understanding the mechanism of such movements is crucial for hazard assessment and eruption forecast, mainly due to this densely populated area. This paper presents a detailed model for ground displacements due to deep fluid injection in shallower layers. Such a model explains in a natural way the occurrence of uplift and subsidence without eruptions. We show that it is possible to fit observed ground deformation in this area with a thermofluid dynamical model. The model obtained is also consistent with other observations like microgravity changes, changes in CO2 flux, etc. Here, we suggest that significant uplift and subsidence at calderas can be due to effects of deep fluid injections other than magma. At Campi Flegrei, however, a partial magmatic contribution at the origin of the observed episodes cannot be excluded.
    Description: Published
    Description: 833–847
    Description: JCR Journal
    Description: restricted
    Keywords: Numerical approximations and analysis; Hydrothermal systems; Explosive volcanism; Calderas ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous
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  • 7
    Publication Date: 2017-04-04
    Description: Two direct search methods, simulated annealing and neighbourhood algorithm, are applied to the inversion of the viscosity profile of the mantle using relative sea level time-histories for the Hudson Bay region. In problems characterized by a low-dimensional model space (Nd = 2 in this study), the two inversion methods show comparable performances. When a larger number of dimensions is involved (specifically Nd = 6), we directly show that simulated annealing is less effective than neighbourhood algorithm in overcoming the obstacles that are found in the model space when our specific data set is employed. This study confirms that modifications of the conventional Monte Carlo inversion method, such as simulated annealing and neighbourhood algorithm, are viable tools to determine the viscosity profile of the mantle, which, until recently, has been mainly tackled by means of linearized techniques.
    Description: Published
    Description: 890-900
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: JCR Journal
    Description: restricted
    Keywords: mantle viscosity ; simulated annealing ; neighbourhood algorithm ; postglacial rebound ; 04. Solid Earth::04.01. Earth Interior::04.01.03. Mantle and Core dynamics
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  • 8
    Publication Date: 2017-04-03
    Description: In the first part of this work, we make use of two non-parametric statistical pattern recognition algorithms and a multiple regression analysis to analyse seismic clusters occur ring around Mount Etna, Italy. The aim is to determine if the onset of flank eruptions at Mount Etna is linked to variations in the regional seismicity at a timescale of few weeks. From the analysis, we find that the discrimination between clusters preceding flank eruptions and clusters not related in time to flank activity is mainly linked to the volume output of the previous flank eruption, in some cases together with the time elapsed from its end. Instead, we do not find any difference in the seismicity features characterizing different types of clusters, except for a very small contribution of the number of seismic events in the clusters. This result does not confirm the existence, suggested in the past, of a direct link between the regional state of stress at a timescale of few weeks and the occurrence of flank eruptions on Mount Etna volcano. On the contrary, the result suggests that a prominent role in the flank eruption occur rence is played by the re-charging of the feeding system. In the second part of this study we analyse the relationship between the magma volume erupted in an eruption and the interevent time following it, finding that a ‘time-predictable model’ satisfactorily describes the occurrence of eruptions at Mount Etna in the last decades. The latter analysis is car ried out both on the flank eruption catalogue only, and on the complete catalogue of flank and summit eruptions, with comparable results.
    Description: Published
    Description: 1203–1218
    Description: JCR Journal
    Description: restricted
    Keywords: flank eruptions ; Mount Etna volcano ; regional tectonic stress ; statistical pattern recognition ; time predictability ; 05. General::05.01. Computational geophysics::05.01.04. Statistical analysis
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  • 9
    Publication Date: 2017-04-03
    Description: In this paper, we present a significant update of the Italian present-day stress data compilation not only to improve the knowledge on the tectonic setting of the region or to constrain future geodynamic models, but also to understand the mechanics of processes linked to faulting and earthquakes. In this paper, we have analysed, revised and collected new contemporary stress data from borehole breakouts and we have assembled earthquake and fault data. In total, 206 new quality-ranked entries complete the definition of the horizontal stress orientation and tectonic regime in some areas, and bring new information mainly in Sicily and along the Apenninic belt. Now the global Italian data set consists of 715 data points, including 499 of A–C quality, representing an increase of 37 per cent compared to the previous compilation. The alignment of horizontal stresses measured in some regions, closely matches the ∼N–S first- order stress field orientation of ongoing relative crustal motions between Eurasia and Africa plates. The Apenninic belt shows a diffuse extensional stress regime indicating a ∼NE–SW direction of extension, that we interpret as related to a second-order stress field. The horizontal stress rotations observed in peculiar areas reflect a complex interaction between first-order stress field and local effects revealing the importance of the tectonic structure orientations. In particular, in Sicily the new data delineate a more complete tectonic picture evidencing adjacent areas characterized by distinct stress regime: northern offshore of Sicily and in the Hyblean plateau the alignment of horizontal stresses is consistent with the crustal motions, whereas different directions have been observed along the belt and foredeep.
    Description: Published
    Description: 705–716
    Description: 3.2. Tettonica attiva
    Description: JCR Journal
    Description: restricted
    Keywords: Downhole methods; Seismicity and tectonics; Crustal structure; Europe. ; borehole breakouts, earthquakes, faults ; 04. Solid Earth::04.07. Tectonophysics::04.07.05. Stress
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  • 10
    Publication Date: 2017-04-04
    Description: In this study, we investigate the rupture history of the April 6th 2009 (Mw 6.1) L’Aquila normal faulting earthquake by using a nonlinear inversion of strong motion, GPS and DInSAR data. Both the separate and joint inversion solutions reveal a complex rupture process and a heterogeneous slip distribution. Slip is concentrated in two main asperities: a smaller shallow patch of slip located up-dip from the hypocenter and a second deeper and larger asperity located southeastward along strike direction. The key feature of the source process emerging from our inverted models concerns the rupture history, which is characterized by two distinct stages. The first stage begins with rupture nucleation and with up-dip propagation at relatively high (∼ 4.0 km/s), but still sub-shear, rupture velocity. The second stage starts nearly 2.0÷2.5 seconds after nucleation and it is characterized by the along strike rupture propagation. The largest and deeper asperity fails during this stage of the rupture process. The rupture velocity is larger in the up-dip than in the along-strike direction. The up-dip and along-strike rupture propagation are separated in time and associated with a Mode II and a Mode III crack, respectively. The comparison between the source models inferred in this study with the Poisson ratio anomalies in the crustal volume containing the fault plane (Di Stefano et al., 2011) allows the interpretation of the delay in along-strike rupture propagation in terms of a structural control of the rupture history. Our results show that the L’Aquila earthquake featured a very complex rupture, with strong spatial and temporal heterogeneities suggesting a strong frictional and/or structural control of the rupture process.
    Description: Published
    Description: 607-621
    Description: 3.1. Fisica dei terremoti
    Description: JCR Journal
    Description: restricted
    Keywords: Inverse theory;Earthquake dynamics;Earthquake ground motions;Earthquake source observations;Body waves;Rheology and friction of fault zones ; 04. Solid Earth::04.06. Seismology::04.06.99. General or miscellaneous
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  • 11
    Publication Date: 2017-04-04
    Description: We investigate shear wave polarization in the Hayward fault zone near Niles Canyon, Fremont, CA. Waveforms of 12 earthquakes recorded by a seven-accelerometer seismic array around the fault are analysed to clarify directional site effects in the fault damage zone. The analysis is performed in the frequency domain through H/V spectral ratios with horizontal components rotated from 0◦ to 180◦, and in the time domain using the eigenvectors and eigenvalues of the covariance matrix method employing three component records. The near-fault ground motion tends to be polarized in the horizontal plane. At two on-fault stations where the local strike is N160◦, ground motion polarization is oriented N88 ± 19◦ and N83 ± 32◦, respectively. At a third on-fault station, the motion is more complex with horizontal polarization varying in different frequency bands. However, a polarization of N86 ± 7◦, similar to the results at the other two on-fault stations, is found in the frequency band 6–8 Hz. The predominantly high-angle polarization from the fault strike at the Hayward Fault is consistent with similar results at the Parkfield section of the San Andreas Fault and the Val d’Agri area (a Quaternary extensional basin) in Italy. In all these cases, comparisons of the observed polarization directions with models of fracture orientation based on the fault movement indicate that the dominant horizontal polarization is near-orthogonal to the orientation of the expected predominant cracking direction. The results help to develop improved connections between fault mechanics and near-fault ground motion.
    Description: Published
    Description: 1255–1272
    Description: JCR Journal
    Description: open
    Keywords: Earthquake ground motions. ; Interface waves ; Site effects ; Wave propagation ; 04. Solid Earth::04.06. Seismology::04.06.04. Ground motion
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  • 12
    Publication Date: 2017-04-04
    Description: We present the results of a multi-temporal, differential interferometric synthetic aperture radar (DInSAR) analysis aiming to identify active surface deformation phenomena in southeastern Sicily. The study area has been chosen because of its strong seismicity, high concentration of industrial and agricultural activities, and high density of people living in the coastal area. Furthermore, the morphology, lithology and climatic feature of this sector of the Hyblean foreland are suitable for an interferometric analysis, providing a high coherence over the area. We used the Small BAseline Subset (SBAS) multitemporal DInSAR technique from Berardino et al., 2002, to calculate mean ground velocity maps and displacement time series from a large data set of European Remote Sensing Satellites (ERS 1-2) images spanning the time period 1992-2000. The reliability of the DInSAR results was tested calculating the EastSAR and UpSAR values over two permanent global positioning system (GPS) stations in the area, and comparing them with the EastGPS and UpGPS values. The residuals between GPS and DInSAR velocities were 1 and 0.6 mm/yr for the Up and East components, respectively. Four main subsiding areas, previously undetected, have been identified, in correspondence of the towns of Augusta, Siracusa, Priolo, and Villasmundo. The observed deformation phenomena are located within coastal structural basins, filled with Pleistocene and Holocence deposits, except the Villasmundo land subsidence which is located on the Hyblean plateau. The measured deformation rates reach values up to -18 mm/yr in Augusta, -6 mm/yr in Siracusa, -5 mm/yr in Villasmundo and -4.5 mm/yr in Priolo. The examination of velocity profiles, time series, and geological data allows us to relate all the detected deformation patterns primarily to groundwater over-exploitation. A multi-dimensional interpolation with kriging was performed to obtain a field subsidence map. A first order elastic deformation model was used to simulate the peculiar features of the Villasmundo subsidence
    Description: ASI-SIGRIS project. ESA Cat1 3769. MIUR Fondo per il sostegno dei giovani.
    Description: Published
    Description: 273-286
    Description: 1.10. TTC - Telerilevamento
    Description: JCR Journal
    Description: partially_open
    Keywords: subsidence ; InSAR ; 05. General::05.08. Risk::05.08.02. Hydrogeological risk
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  • 13
    Publication Date: 2017-04-03
    Description: A global ocean three-dimensional variational data assimilation system was developed with the aim of assimilating along-track sea level anomaly observations, along with in situ observations from bathythermographs and conventional sea stations. All the available altimetric data within the period October 1992–January 2006 were used in this study. The sea level corrections were covariated with vertical profiles of temperature and salinity according to the bivariate definition of the background-error vertical covariances. Sea level anomaly observational error variance was carefully defined as a sum of instrumental, representativeness, observation operator, and mean dynamic topography error variances. The mean dynamic topography was computed from the model long-term mean sea surface height and adjusted through an optimal interpolation scheme to account for observation minus first-guess biases. Results show that the assimilation of sea level anomaly observations improves the model sea surface height skill scores as well as the subsurface temperature and salinity fields. Furthermore, the estimate of the tropical and subtropical surface circulation is clearly improved after assimilating altimetric data. Nonnegligible impacts of the mean dynamic topography used have also been found: compared to a gravimeter-based mean dynamic topography the use of the mean dynamic topography discussed in this paper improves both the consistency with sea level anomaly observations and the verification skill scores of temperature and salinity in the tropical regions. Furthermore, the use of a mean dynamic topography computed from the model long-term sea surface height mean without observation adjustments results in worsened verification skill scores and highlights the benefits of the current approach for deriving the mean dynamic topography.
    Description: European Commission WP4 Fondazione Cassa di Risparmio di Bologna Cnes
    Description: Published
    Description: 738-754
    Description: 3.7. Dinamica del clima e dell'oceano
    Description: 4.6. Oceanografia operativa per la valutazione dei rischi in aree marine
    Description: 5.4. Banche dati di geomagnetismo, aeronomia, clima e ambiente
    Description: JCR Journal
    Description: partially_open
    Keywords: Data assimilation ; Satellite observations ; Ocean models ; Sea level ; In situ observations ; Variational analysis ; 03. Hydrosphere::03.01. General::03.01.01. Analytical and numerical modeling ; 03. Hydrosphere::03.01. General::03.01.03. Global climate models ; 03. Hydrosphere::03.01. General::03.01.04. Ocean data assimilation and reanalysis
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  • 14
    Publication Date: 2017-04-04
    Description: We have analysed the history of seismic activity in the region of L'Aquila to compare the 2009 sequence with previous ones. Historical catalogues are exhaustive for large shocks, but not for small earthquakes and swarms. Our original compilation highlights repeated seismic sequences from 1315 ad to present. In the 20th century, at least 23 sequences affected the Abruzzi region, 8 of which were very close to L'Aquila. In previous centuries, we found evidence of at least 13 sequences around L'Aquila, with maximum magnitude ∼4 to ∼5. Only three sequences were followed by stronger shocks (1461, 1703 and 2009). However, many strong events of the region (1349, 1762, 1915, 1950) were not preceded by foreshocks. We describe here the last of these sequences (1985) showing its strong similarity with the 2009 one, except its final evolution (no large event in 1985). Our analysis suggests that seismic sequences alone cannot be considered straight forerunners of incoming strong events.
    Description: Published
    Description: 52–61
    Description: 3.1. Fisica dei terremoti
    Description: JCR Journal
    Description: reserved
    Keywords: L’Aquila earthquake ; 04. Solid Earth::04.06. Seismology::04.06.01. Earthquake faults: properties and evolution
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  • 15
    Publication Date: 2017-04-04
    Description: An improved method based on equilibrium partitioning between water samples and an inert host gas, introduced after sampling, is proposed for determining multiple species of dissolved gases in brackish water. The method itself, and the most convenient equations for describing gas solubilities in brackish waters, is described in detail. The method allows the rapid characterization of several sites and represents a useful tool for geochemical surveys. A comparison between replicate samples analyzed using different procedures demonstrates the efficiency of the method and indicates that the abundances of the main dissolved gases can be obtained, which can then be used to determine underlying geochemical processes. A Microsoft Excel worksheet is provided to easily calculate the concentration of dissolved gas species.
    Description: Published
    Description: 236-244
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: restricted
    Keywords: brackish thermal waters ; dissolved gases ; 03. Hydrosphere::03.03. Physical::03.03.01. Air/water/earth interactions
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  • 16
    Publication Date: 2017-04-04
    Description: The present-day sea level variations and geodetically observed ground deformations in the Mediterranean area are normally ascribed to the combined effect of tectonic or human-driven subsidence and postglacial uplift as a result of the melting of the major Pleistocene ice sheets. However, another potential cause of deformation, only marginally considered to date, is the melting of the glacier that covered the Alps during the last glacial maximum (LGM). The aim of this paper is to predict the long-term sea level variations induced by the melting of both the late-Pleistocene and Alpine ice sheets and compare our results with the relative sea level (RSL) observations available in the Mediterranean region. This task is accomplished solving the sea level equation (SLE) for a spherically symmetric viscoelastic Earth. Our analysis shows that the melting of the Alpine glacier has marginally affected the Holocene sea level variations in the near-field sites in southern France (Marseilles and Roussillon) and the central Tyrrhenian sea (Civitavecchia), and that the RSL predictions are significantly sensitive to the chronology of the remote ice aggregates. The computations, which are performed using a specific mantle viscosity profile consistent with global observations of RSL rise, show that the uplift rate driven by the Alpine isostatic readjustment may account for up to 1/3 of the rates observed at GPS stations in the western portion of the chain. Our results suggest that a thorough modelization of both near- and far-field ice sheets is necessary to gain a better insight into the present-day deformations and sea level variations in the Mediterranean region.
    Description: Published
    Description: 137-147
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: JCR Journal
    Description: restricted
    Keywords: Alpine glacier ; glacial rebound ; mantle viscosity ; sea level variations ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics
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  • 17
    Publication Date: 2017-04-04
    Description: Although characterized by low seismicity, the Monferrato area of north-western Italy was affected by earthquakes, of magnitude M5.1 and M4.8, in 2000 and 2001. At the same time, marked changes were recorded in water temperature and chemistry in several wells within the epicentral area. In May 2004, an automatic network for the continuous monitoring of groundwater was installed in selected wells to study the phenomenon. Here, we report on data collected during a 3-year period of groundwater monitoring. During the first year, episodes of water heating (by up to 20°C) were observed in one monitored well. The temporal analysis of the seismic activity recorded in the area revealed as almost all seismic events occurred during the period of elevated water temperatures. The similar timing of earthquakes and groundwater-temperature anomalies suggests that both may be triggered by the same processes acting in the crust.
    Description: Published
    Description: 142-149
    Description: JCR Journal
    Description: reserved
    Keywords: groundwater monitoring ; pore fluid pressure; ; tectonic stress ; 03. Hydrosphere::03.02. Hydrology::03.02.02. Hydrological processes: interaction, transport, dynamics ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 18
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    American Meteorological Society
    Publication Date: 2020-02-24
    Description: An aquaplanet model is used to study the nature of the highly persistent low-frequency waves that have been observed in models forced by zonally symmetric boundary conditions. Using the Hayashi spectral analysis of the extratropical waves, the authors find that a quasi-stationary wave 5 belongs to a wave packet obeying a well-defined dispersion relation with eastward group velocity. The components of the dispersion relation with k ≥ 5 baroclinically convert eddy available potential energy into eddy kinetic energy, whereas those with k 〈 5 are baroclinically neutral. In agreement with Green’s model of baroclinic instability, wave 5 is weakly unstable, and the inverse energy cascade, which had been previously proposed as a main forcing for this type of wave, only acts as a positive feedback on its predominantly baroclinic energetics. The quasi-stationary wave is reinforced by a phase lock to an analogous pattern in the tropical convection, which provides further amplification to the wave. It is also found that the Pedlosky bounds on the phase speed of unstable waves provide guidance in explaining the latitudinal structure of the energy conversion, which is shown to be more enhanced where the zonal westerly surface wind is weaker. The wave’s energy is then trapped in the waveguide created by the upper tropospheric jet stream. In agreement with Green’s theory, as the equator-to-pole SST difference is reduced, the stationary marginally stable component shifts toward higher wavenumbers, while wave 5 becomes neutral and westward propagating. Some properties of the aquaplanet quasi-stationary waves are found to be in interesting agreement with a low frequency wave observed by Salby during December–February in the Southern Hemisphere so that this perspective on low frequency variability, apart from its value in terms of basic geophysical fluid dynamics, might be of specific interest for studying the earth’s atmosphere.
    Description: Published
    Description: 1023–1040.
    Description: JCR Journal
    Description: restricted
    Keywords: Boundary conditions ; 03. Hydrosphere::03.02. Hydrology::03.02.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 19
    Publication Date: 2020-02-24
    Description: Integration of geologic, geomorphologic and seismologic data sets is used to reconstruct the recent tectonic evolution and active deformation pattern in the Val d’Agri area, located in the seismically active axial sector of the Southern Apennines (Italy). The western portion of the Apennines thrust belt has been affected by Pliocene–Quaternary extension during easterly roll-back and crustal delamination of the Adriatic slab. The bulk of Quaternary extension has been accommodated bySW-dipping oblique and normal faults,which have attained mature morphologic and structural features and, nowadays, separate mountain ranges from intermontane basins. However, in the present seismogenic belt, coseismic faulting locally occurs on NE-dipping structures, which might cut the inherited Pleistocene landscape. In theVal d’Agri basin, in spite of the large Early–Middle Pleistocene, displacement occurred on SW-dipping faults bordering its eastern flank, our investigations show that the recent basin evolution has been controlled by a NE-dipping fault system (Monti della Maddalena fault system, MMFS). This fault system cuts across the Monti della Maddalena range, west of the Agri valley and has not yet created an evident tectonic landscape. Notwithstanding, fault motion since the Middle Pleistocene might explain geomorphologic and hydrographic anomalies of the Agri river and its valley, where fault-controlled subsidence has captured the river course and produced an aggrading plain within a regional uplift context. Recent and ongoing motion is documented by fault scarplets in loose deposits, 14C ages of palaeosols and the spatial relation with low to moderate instrumental seismicity. Results from fault kinematic analysis are compatible with fault-plane solutions of local and regional seismic events, and indicate ∼NE–SW oriented extension. Recognition of the MMFS as a potential seismogenic fault increases the longitudinal extent of the NE-dipping, morphologically immature seismic sources in the Southern Apennines and argues against the range-bounding fault model for active extension in the region. The regional size of the NE-dipping seismogenic belt may result from impingement of a mantle wedge beneath the Apenninic chain and possibly track the external front of crustal delamination.
    Description: Published
    Description: 591-609
    Description: 3.2. Tettonica attiva
    Description: JCR Journal
    Description: reserved
    Keywords: active tectonics ; crustal deformation ; earthquakes ; geomorphology ; normal faulting ; Southern Italy ; 04. Solid Earth::04.04. Geology::04.04.01. Earthquake geology and paleoseismology ; 04. Solid Earth::04.04. Geology::04.04.03. Geomorphology ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 20
    Publication Date: 2020-02-24
    Description: After an earthquake, rapid, real-time assessment of hazards such as ground shaking and tsunami potential is important for early warning and emergency response. Tsunami potential depends on seafloor displacement, which is related to the length, L, width, W, mean slip, D, and depth, z, of earthquake rupture. Currently, the primary discriminant for tsunami potential is the centroid-moment tensor magnitude, MCMT, representing the seismic potency LWD, and w estimated through an indirect, inversion procedure. The obtained MCMT and the implied LWD w value vary with the depth of faulting, assumed earth model and other factors, and is only available 30 min or more after an earthquake. The use of more direct procedures for hazard assessment, when available, could avoid these problems and aid in effective early warning. Here we present a direct procedure for rapid assessment of earthquake tsunami potential using two, simple measures on P-wave seismograms—the dominant period on the velocity records, Td, and the likelihood that the high-frequency, apparent rupture-duration, T0, exceeds 50–55 s. T0 can be related to the critical parameters L and z, while Td may be related to W, D or z. For a set of recent, large earthquakes, we show that the period-duration product T T gives more information on tsunami impact and size than MCMT and other currently used d0w discriminants. All discriminants have difficulty in assessing the tsunami potential for oceanic strike-slip and backarc or upper plate, intraplate earthquake types. Our analysis and results suggest that tsunami potential is not directly related to the potency LWD from the ‘seismic’ faulting model, as is assumed with the use of the MCMT discriminant. Instead, knowledge of w rupture length, L, and depth, z, alone can constrain well the tsunami potential of an earthquake, with explicit determination of fault width, W, and slip, D, being of secondary importance. With available real-time seismogram data, rapid calculation of the direct, period-duration discriminant can be completed within 6–10 min after an earthquake occurs and thus can aid in effective and reliable tsunami early warning.
    Description: Published
    Description: 283-291
    Description: JCR Journal
    Description: restricted
    Keywords: earthquake dynamics ; earthquake source observation ; 04. Solid Earth::04.06. Seismology::04.06.06. Surveys, measurements, and monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 21
    Publication Date: 2020-02-24
    Description: This article analyzes the ocean forecast response to surface vector wind (SVW) distributions generated by a Bayesian hierarchical model (BHM) developed in Part I of this series. A new method for ocean ensemble forecasting (OEF), the socalled BHM-SVW-OEF, is described. BHM-SVW realizations are used to produce and force perturbations in the ocean state during 14 day analysis and 10 day forecast cycles of the Mediterranean Forecast System (MFS). The BHM-SVW-OEF ocean response spread is amplified at the mesoscales and in the pycnocline of the eddy field. The new method is compared with an ensemble response forced by European Centre for Medium-Range Weather Forecasts (ECMWF) ensemble prediction system (EEPS) surface winds, and with an ensemble forecast started from perturbed initial conditions derived froman ad hoc thermocline intensified random perturbation (TIRP) method. The EEPS-OEF shows spread on basin scales while the TIRP-OEF response is mesoscale-intensified as in the BHM-SVW-OEF response. TIRP-OEF perturbations fill more of the MFS domain, while the BHM-SVW-OEF perturbations are more location-specific, concentrating ensemble spread at the sites where the ocean-model response to uncertainty in the surface wind forcing is largest.
    Description: Published
    Description: 879–893
    Description: JCR Journal
    Description: embargoed_20140501
    Keywords: forecast uncertainty ; 03. Hydrosphere::03.01. General::03.01.03. Global climate models
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 22
    Publication Date: 2020-03-16
    Description: Post-seismic relaxation is known to occur after large or moderate earthquakes, on time scales ranging from days to years or even decades. In general, long-term deformation following seismic events has been detected by means of standard geodetic measurements, although seismic instruments are only used to estimate short timescale transient processes. Albeit inertial seismic sensors are also sensitive to rotation around their sensitive axes, the recording of very slow inclination of the ground surface at their standard output channels is practically impossible, because of their design characteristics. However, modern force-balance, broad- band seismometers provide the possibility to detect and measure slow surface inclination, through the analysis of the mass position signal. This output channel represents the integral of the broad-band velocity and is generally considered only for state-of-health diagnostics. In fact, the analysis of mass position data recorded at the time of the 2009 April 6, L’Aquila (MW = 6.3) earthquake, by a closely located STS-2 seismometer, evidenced the occurrence of a very low frequency signal, starting right at the time of the seismic event. This waveform is only visible on the horizontal components and is not related to the usual drift coupled with the temperature changes. This analysis suggests that the observed signal is to be ascribed to slowly developing ground inclination at the station site, caused by post-seismic relaxation following the main shock. The observed tilt reached 1.7 × 10−5 rad in about 2 months. This estimate is in very good agreement with the geodetic observations, giving comparable tilt magnitude and direction at the same site. This study represents the first seismic analysis ever for the mass position signal, suggesting useful applications for usually neglected data.
    Description: Published
    Description: 1717-1724
    Description: 3.1. Fisica dei terremoti
    Description: JCR Journal
    Description: restricted
    Keywords: Seismic cycle ; Earthquake source observations ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 23
    Publication Date: 2017-04-03
    Description: On 2009 April 6 a Mw = 6.3 earthquake struck the Abruzzi region (Central Italy) and caused severe destruction in L’Aquila and the surrounding area. In this work we present a Finite Element analysis of the event based on a realistic complex 3-D model, accounting for topographic relief and rheological heterogeneities deduced from local tomography. Finite Element computed Green’s functions were implemented in a linear inversion of GPS coseismic displacements, to retrieve the slip distribution on the rupture plane. The inverted slip models basically agree with previous studies carried out on homogeneous domains, but reveal the presence of a single high slip patch, whereas half-space or 1-D approaches obtain a more complex slip pattern. Our results point out that the introduction of 3-D features significantly influences the obtained source model, suggesting a trade-off between domain complexities and source details.
    Description: Published
    Description: 1339–1358
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: JCR Journal
    Description: restricted
    Keywords: Numerical approximations and analysis ; Seismicity and tectonics ; Dynamics and mechanics of faulting ; L'Aquila earthquake ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics
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  • 24
    Publication Date: 2017-04-04
    Description: The accurate determination of locations and magnitudes of seismic events in a monitored region is important for many scientific, industrial and military studies and applications; for these purposes a wide variety of seismic networks are deployed throughout the world. It is crucial to know the performance of these networks not only in detecting and locating seismic events of different sizes throughout a specified source region, but also by evaluating their location errors as a function of the magnitude and source location. In this framework, we have developed a method for evaluating network performance in surface and borehole seismic monitoring. For a specified network geometry, station characteristics and a target monitoring volume, the method determines the lowest magnitude of events that the seismic network is able to detect (Mw detect), and locate (Mw loc) and estimates the expected location and origin time errors for a specified magnitude. Many of the features related to the seismic signal recorded at a single station are considered in this methodology, including characteristics of the seismic source, the instrument response, the ambient noise level, wave propagation in a layered, anelastic medium and uncertainties on waveform measures and the velocity model. We applied this method to two different network typologies: a local earthquake monitoring network, Irpinia Seismic Network (ISNet), installed along the Campania-Lucania Apennine chain in Southern Italy, and a hypothetic borehole network for monitoring microfractures induced during the hydrocarbon extraction process in an oil field. The method we present may be used to aid in enhancing existing networks and/or understanding their capabilities, such as for the ISNet case study, or to optimally design the network geometry in specific target regions, as for the borehole network example.
    Description: Published
    Description: 793-806
    Description: 4.1. Metodologie sismologiche per l'ingegneria sismica
    Description: JCR Journal
    Description: restricted
    Keywords: Earthquake ground motions ; Computational seismology ; 04. Solid Earth::04.06. Seismology::04.06.10. Instruments and techniques
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 25
    Publication Date: 2017-04-03
    Description: Computing the magnitude of an earthquake requires correcting for the propagation effects from the source to the receivers. This is often accomplished by performing numerical simulations using a suitable Earth model. In this work, the energy magnitude Me is considered and its determination is performed using theoretical spectral amplitude decay functions over teleseismic distances based on the global Earth model AK135Q. Since the high frequency part (above the corner frequency) of the source spectrum has to be considered in computing Me, the influence of propagation and site effects may not be negligible and they could bias the single station Me estimations. Therefore, in this study we assess the inter- and intrastation distributions of errors by considering the Me residuals computed for a large data set of earthquakes recorded at teleseismic distances by seismic stations deployed worldwide. To separate the inter- and intrastation contribution of errors, we apply a maximum likelihood approach to the Me residuals. We show that the interstation errors (describing a sort of site effect for a station) are within ±0.2 magnitude units for most stations and their spatial distribution reflects the expected lateral variation affecting the velocity and attenuation of the Earth's structure in the uppermost layers, not accounted for by the 1-D AK135Q model. The variance of the intrastation error distribution (describing the record-to-record component of variability) is larger than the interstation one (0.240 against 0.159), and the spatial distribution of the errors is not random but shows specific patterns depending on the source-to-station paths. The set of coefficients empirically determined may be used in the future to account for the heterogeneities of the real Earth not considered in the theoretical calculations of the spectral amplitude decay functions used to correct the recorded data for propagation effects.
    Description: Published
    Description: 1444-1454
    Description: JCR Journal
    Description: restricted
    Keywords: time series analysis ; 04. Solid Earth::04.06. Seismology::04.06.06. Surveys, measurements, and monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 26
    Publication Date: 2017-04-04
    Description: The monitoring of crustal motions in Northern Victoria Land (NVL) of Antarctica by means of episodic GPS stations (EGPSs) provides an accurate and dense (∼50-km spaced) velocity field. The data, gathered starting in Austral summer 1999, derive from a series of benchmarks belonging to the Victoria Land Network for DEFormation control (VLNDEF) geodetic network. The velocity uncertainties are checked on the basis of length and returning time of the episodic surveys, to obtain a meaningful strain rate field by means of a least-square computation where the contribution of a GPS station is weighted by the inverse square of its velocity error. The study shows that the NVL is characterized by a complex kinematics and that, although three subregions with different prevailing deformational behaviour can be recognized, the single blocks cannot be resolved because too few stations exist. Only features having 150–200 km size at least can be recognized. Moreover, it is demonstrated that an appropriate data processing of EGPS data can lead to an accurate evaluation of the strain rate field even in a harsh environment like Antarctica.
    Description: Published
    Description: 851-862
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: JCR Journal
    Description: reserved
    Keywords: Time-series analysis ; Satellite geodesy ; Geomorphology ; Antarctica ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 27
    Publication Date: 2017-04-04
    Description: The Gulf of Manfredonia and the Tavoliere Plain have experienced intense human colonization since the neolithic times. There is past evidence in the study area of a Roman-age settlement historically known as Salapia, probably located close to the salt-production ponds. In particular, several portions of a partly submerged ancient pier-like structure were found close to Torre Pietra town. This structure has been interpreted as a portion of a dragged-ship channel that connected the town of Salapia to the sea. In this article we discuss the results of a high-resolution geophysical prospecting of the Margherita di Savoia offshore archaeological site (Puglia, Italy). We collected magnetic gradiometric and bathymetric data to map the submerged remains of Salapia harbour. We found evidence of an offshore projection of a Torre Pietra pier-like structure, identifying the direction of the ship channel and possibly the location of the harbour’s defensive post
    Description: Published
    Description: 89-101
    Description: 3.4. Geomagnetismo
    Description: JCR Journal
    Description: restricted
    Keywords: Marine magnetic survey; ; Manfredonia Gulf ; Roman archaeological finds ; buried ruins ; analytic signal; ; horizontal gradient ; 04. Solid Earth::04.05. Geomagnetism::04.05.04. Magnetic anomalies ; 05. General::05.01. Computational geophysics::05.01.01. Data processing
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 28
    Publication Date: 2017-04-04
    Description: The overall picture of Mount Etna deformation emerging since a couple of decades of geodetic surveys shows effects of magma accumulation, characterized by inflation/deflation cycle, accompanied by a sliding instability of the southeast flank, whose manifestation is an increase in the horizontal deformation away from the volcano summit. This is a very interesting case to test whether advanced models, taking into account topography, internal structure and frictional rheology, may contribute to a better understanding of the complex interplay among mechanical response, magmatic activity and gravitational load occurring in a volcanic system. Using finite element numerical models we make predictions of surface displacements associated with a simple expansion source and with a dike like vertical discontinuity. A new methodology is developed to initalize the lithostatic stress field according to the material and geometrical complexities of the models considered. Our results show that, while an amplification of the horizontal displacement can be easily obtained up to a maximum distance of 10 km from the source, we have not been able to find any onfiguration to extend further this signal. For the case of Mount Etna this suggests that the large horizontal displacements observed in the east flank along the coast cannot be directly related to magma accumulation below the volcano's summit.
    Description: Published
    Description: 939-953
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: JCR Journal
    Description: partially_open
    Keywords: Numerical solutions ; Space geodetic surveys ; Elasticity and anelasticity ; Eruption mechanisms and flow emplacement ; Volcanic hazards and risks ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 29
    Publication Date: 2017-04-04
    Description: The Solfatara is one of the major volcanoes of the Phlegrean Fields (Campi Flegrei) volcanic complex, and it is located in a densely populated area a few kilometres west of the city of Naples. It is an active resurgent caldera that has been characterized by a rich history of surface–ground deformation and soil diffuse degassing and fumarolic emissions, which are indications of the top of a hydrothermal plume. A seismic survey was completed in May 2009 for the characterization of the main subsurface features of the Solfatara. Using the complete data set, we have carried out surface wave inversion with high spatial resolution. A classical minimization of a least-squares objective function was first computed to retrieve the dispersion curves of the surface waves. Then, the fitting procedure between the data and a three-sedimentlayer forward model was carried out (to a depth of 7 m), using an improved version of the neighbourhood algorithm. The inversion results indicate a NE-SW fault, which is not visible at the surface. This was confirmed by a temperature survey conducted in 2010. A passive seismic experiment localized the ambient noise sources that correlate well with the areas of high CO2 flux and high soil temperatures. Finally, considering that the intrinsic attenuation is proportional to the frequency, a centroid analysis provides an overview of the attenuation of the seismic waves, which is closely linked to the petrophysical properties of the rock. These different approaches that merge complete active and passive seismic data with soil temperature and CO2 flux maps confirm the presence of the hydrothermal system plume. Some properties of the top of the plume are indicated and localized.
    Description: Published
    Description: 1725–1733
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: Inverse theory ; Tomography ; Hydrothermal systems ; Europe ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 04. Solid Earth::04.04. Geology::04.04.11. Instruments and techniques ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 30
    Publication Date: 2017-04-04
    Description: The magnetic properties (first-order reversal curves, ferromagnetic resonance and decomposition of saturation remanent magnetization acquisition) of Magnetovibrio blakemorei, a cultivated marine magnetotactic bacterium, differ from those of other magnetotactic species from sediments deposited in lakes and marine habitats previously studied. This finding suggests that magnetite produced by some magnetotactic bacteria retains magnetic properties in relation to the crystallographic structure of the magnetic phase produced and thus might represent a ‘magnetic fingerprint’ for a specific magnetotactic bacterium. The use of this fingerprint is a non-destructive, new technology that might allow for the identification and presence of specific species or types of magnetotactic bacteria in certain environments such as sediments.
    Description: Published
    Description: 664-668
    Description: 1.8. Osservazioni di geofisica ambientale
    Description: 2.2. Laboratorio di paleomagnetismo
    Description: 3.8. Geofisica per l'ambiente
    Description: JCR Journal
    Description: restricted
    Keywords: batteri magnetotattici ; magnetite ; 03. Hydrosphere::03.01. General::03.01.06. Paleoceanography and paleoclimatology ; 04. Solid Earth::04.05. Geomagnetism::04.05.09. Environmental magnetism
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  • 31
    Publication Date: 2017-10-06
    Description: In this study we have determined detailed Vp and Vs seismic velocity models of the Ionian lithosphere subducting beneath the Tyrrhenian basin and of the surrounding mantle, by applying a post-processing technique to a large sample of local earthquake tomography studies. Our seismic velocity models permit us to infer the presence of low velocity anomalies within the slab, which we interpret as regions that are partially hydrated by fluids released during the subduction process. A petrological interpretation of the velocity anomalies gives new details on the magmatism of the volcanic Aeolian arc. Furthermore our velocity models provide a more detailed description of the boundary of the slab and its connection with the large seismically active Tindari-Letojanni strike slip system. Finally these results allow describing in detail some features of the slab as the presence of lateral and vertical tears. In conclusion, the obtained models provide some constraints for inferences on mantle circulation, and on the geodynamical evolution of the central-western Mediterranean.
    Description: Published
    Description: 751-764
    Description: 2.5. Laboratorio per lo sviluppo di sistemi di rilevamento sottomarini
    Description: JCR Journal
    Description: reserved
    Keywords: Tomography, petrology, Ionian slab ; 04. Solid Earth::04.06. Seismology::04.06.07. Tomography and anisotropy
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  • 32
    Publication Date: 2020-02-24
    Description: A Bayesian hierarchical model (BHM) is developed to estimate surface vector wind (SVW) fields and associated uncertainties over the Mediterranean Sea. The BHM–SVW incorporates data-stage inputs from analyses and forecasts of the European Centre for Medium-Range Weather Forecasts (ECMWF) and SVW retrievals from the QuikSCAT data record. The process-model stage of the BHM–SVW is based on a Rayleigh friction equation model for surface winds. Dynamical interpretations of posterior distributions of the BHM–SVW parameters are discussed. Ten realizations from the posterior distribution of the BHM–SVW are used to force the data-assimilation step of an experimental ensemble ocean forecast system for the Mediterranean Sea in order to create a set of ensemble initial conditions. The sequential data-assimilation method of the Mediterranean forecast system (MFS) is adapted to the ensemble implementation. Analyses of sample ensemble initial conditions for a single data-assimilation period in MFS are presented to demonstrate the multivariate impact of the BHM–SVW ensemble generation methodology. Ensemble initial-condition spread is quantified by computing standard deviations of ocean state variable fields over the ten ensemble members. The methodological findings in this article are of two kinds. From the perspective of statistical modelling, the process-model development is more closely related tophysicalbalances than inpreviousworkwithmodels for the SVW.Fromthe ocean forecast perspective, the generation of ocean ensemble initial conditions via BHM is shown to be practical for operational implementation in an ensemble ocean forecast system. Phenomenologically, ensemble spread generated via BHM–SVW occurs on ocean mesoscale time- and space-scales, in close association with strong synoptic-scale wind-forcing events. A companion article describes the impacts of the BHM–SVW ensemble method on the ocean forecast in comparisons with more traditional ensemble methods.
    Description: Published
    Description: 858–878
    Description: JCR Journal
    Description: embargoed_20140501
    Keywords: QuikSCAT surface winds ; 03. Hydrosphere::03.01. General::03.01.05. Operational oceanography
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  • 33
    Publication Date: 2020-02-24
    Description: A simulation and two reanalyses from 1985 to 2007 have been produced for the Mediterranean Sea using different assimilation schemes: a reduced-order optimal interpolation [System for Ocean Forecast and Analysis (SOFA)] and a three-dimensional variational scheme (OceanVar). The observational dataset consists of vertical temperature and salinity in situ profiles and along-track satellite sea level anomalies; daily mean fields of satellite sea surface temperature are used for correcting the air–sea fluxes. This paper assesses the quality of the reanalyses with respect to observations and the simulation. Both the SOFA and OceanVar schemes give very similar root-mean-square errors and biases for temperature and salinity fields compared with the assimilated observations. The largest errors are at the thermocline level and in regions of large eddy field variability. However, OceanVar gives 20% better results for sea level anomaly root-mean-square error.
    Description: Published
    Description: 569-59
    Description: JCR Journal
    Description: open
    Keywords: Mediterranean Sea ; 03. Hydrosphere::03.01. General::03.01.05. Operational oceanography
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  • 34
    Publication Date: 2020-02-24
    Description: In this study, new intensity prediction equations are derived for Central Asia, considering about 6000 intensity data points from 66 earthquakes encompassing the surface-wave magnitude range of 4.6–8.3. The suitability of the functional form used for constructing the model is assessed by comparing its predictions with those achieved through a non-parametric model. The parametric regressions are performed considering different measures of the source-to-site distance, namely the hypocentral, epicentral and the extended distance metrics. The latter is defined as the minimum distance from the site to a line crossing the epicentres, oriented along the strike of the earthquake and having a length estimated from the event’s magnitude. Although the extended distance is introduced as a preliminary attempt to improve the prediction capability of the model by considering the finiteness of the fault extension, the standard deviation of the residual distribution obtained considering the extended distance (σ = 0.734) does not show an improvement with respect to the results for the epicentral distance (σ = 0.737). The similarity of the two models in term of average residuals is also confirmed by comparing the interevent errors obtained for the two regressions, obtaining very similar values for all earthquakes but the 1911, M 8.2 Kemin event. In particular, different evidences suggest that the magnitude of this event could be overestimated by about half a magnitude unit. Regarding the variability of the residual distribution, all the three considered components (i.e. interevent, interlocation and record-to-record variances) are not negligible, although the largest contribution is related to the record-to-record variability, suggesting that both source and propagation as well as site effects not captured by the considered model influence the spatial variability of the intensity values.
    Description: Published
    Description: 327–337
    Description: JCR Journal
    Description: restricted
    Keywords: Earthquake ground motions ; 05. General::05.01. Computational geophysics::05.01.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 35
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    American Meteorological Society
    In:  EPIC3Monthly Weather Review., American Meteorological Society, 140(5), pp. 1589-1602
    Publication Date: 2014-04-17
    Repository Name: EPIC Alfred Wegener Institut
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  • 36
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    Wiley-Blackwell
    In:  EPIC3Oxidative Stress in Aquatic Ecosystems, Abele, D., Zenteno-Savin, T, Vasquez-Medina, J. (Eds) Oxidatve Stress in Aquatic Ecosystems, Blackwell-Wiley., Oxford UK, Wiley-Blackwell, 15 p., pp. 141 -156, ISBN: 978-1-4443-3548-4
    Publication Date: 2019-07-16
    Repository Name: EPIC Alfred Wegener Institut
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  • 37
    Publication Date: 2014-04-17
    Description: Compensatory dynamics, overyielding and statistical averaging are mechanisms promoting the temporal stability of natural communities. Using the model of European intertidal rocky shore assemblages and collating 17 datasets, we investigated how the strength of these stability-enhancing mechanisms varies with latitude and how it can be altered by the loss of habitat-formers (e.g. canopy-forming macroalgae). Community stability decreased with increasing latitude, mostly as a consequence of a greater synchronization of species fluctuations. Statistical averaging and overyielding (i.e. richness effects) promoted stability, but their strength did not vary with latitude. The experimental removal of macroalgal canopies caused a strengthening of the statistical averaging effect that was consistent across the latitudinal gradient investigated. Nonetheless, the loss of canopies depressed stability by enhancing the synchronization of species fluctuations on southernmost shores, while it had weak effects on shores at higher latitudes. Variation in life-history traits among canopy-forming species and/or in prevailing environmental conditions across a gradient of latitude could underlie variable effects of habitat-formers on species fluctuations. Our study shows i) that the stability of intertidal assemblages and strength of compensatory dynamics varies with latitude, ii) that canopy-forming macroalgae, exerting a strong control on understorey species, can influence the strength of compensatory dynamics and iii) that biological forcing (i.e. facilitation) can be as important as environmental forcing in enhancing the synchronization of species fluctuations.
    Repository Name: EPIC Alfred Wegener Institut
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  • 38
    Publication Date: 2022-05-25
    Description: Author Posting. © American Meteorological Society, 2011. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Atmospheric and Oceanic Technology 28 (2011): 1539–1553, doi:10.1175/JTECH-D-11-00001.1.
    Description: Turbulent Reynolds stresses are now routinely estimated from acoustic Doppler current profiler (ADCP) measurements in estuaries and tidal channels using the variance method, yet biases due to surface gravity waves limit its use in the coastal ocean. Recent modifications to this method, including spatially filtering velocities to isolate the turbulence from wave velocities and fitting a cospectral model to the below-wave band cospectra, have been used to remove this bias. Individually, each modification performed well for the published test datasets, but a comparative analysis over the range of conditions in the coastal ocean has not yet been performed. This work uses ADCP velocity measurements from five previously published coastal ocean and estuarine datasets, which span a range of wave and current conditions as well as instrument configurations, to directly compare methods for estimating stresses in the presence of waves. The computed stresses from each were compared to bottom stress estimates from a quadratic drag law and, where available, estimates of wind stress. These comparisons, along with an analysis of the cospectra, indicated that spectral fitting performs well when the wave climate is wide-banded and/or multidirectional as well as when instrument noise is high. In contrast, spatial filtering performs better when waves are narrow-banded, low frequency, and when wave orbital velocities are strong relative to currents. However, as spatial filtering uses vertically separated velocity bins to remove the wave bias, spectral fitting is able to resolve stresses over a larger fraction of the water column.
    Description: J. Rosman acknowledges funding from the National Science Foundation (OCE-1061108).
    Keywords: Coastal flows ; Momentum ; Ocean circulation ; Waves, oceanic ; In situ observations ; Instrumentation/sensors
    Repository Name: Woods Hole Open Access Server
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  • 39
    facet.materialart.
    Unknown
    American Meteorological Society
    Publication Date: 2022-05-25
    Description: Author Posting. © American Meteorological Society, 2012. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 42 (2012): 1012–1021, doi:10.1175/JPO-D-11-0184.1.
    Description: Pacific Water flows across the shallow Chukchi Sea before reaching the Arctic Ocean, where it is a source of heat, freshwater, nutrients, and carbon. A substantial portion of Pacific Water is routed through Barrow Canyon, located in the northeast corner of the Chukchi. Barrow Canyon is a region of complex geometry and forcing where a variety of water masses have been observed to coexist. These factors contribute to a dynamic physical environment, with the potential for significant water mass transformation. The measurements of turbulent kinetic energy dissipation presented here indicate diapycnal mixing is important in the upper canyon. Elevated dissipation rates were observed near the pycnocline, effectively mixing winter and summer water masses, as well as within the bottom boundary layer. The slopes of shear/stratification layers, combined with analysis of rotary spectra, suggest that near-inertial wave activity may be important in modulating dissipation near the bottom. Because the canyon is known to be a hotspot of productivity with an active benthic community, mixing may be an important factor in maintenance of the biological environment.
    Description: ELS was supported as a WHOI Postdoctoral Scholar through the WHOI Ocean and Climate Change Institute.
    Description: 2012-12-01
    Keywords: Arctic ; Continental shelf/slope ; Mixing ; Small scale processes
    Repository Name: Woods Hole Open Access Server
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  • 40
    Publication Date: 2022-05-25
    Description: Author Posting. © American Meteorological Society, 2012. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Climate 25 (2012): 5153–5172, doi:10.1175/JCLI-D-11-00463.1.
    Description: Atlantic meridional overturning circulation (AMOC) variability is documented in the Community Climate System Model, version 4 (CCSM4) preindustrial control simulation that uses nominal 1° horizontal resolution in all its components. AMOC shows a broad spectrum of low-frequency variability covering the 50–200-yr range, contrasting sharply with the multidecadal variability seen in the T85 × 1 resolution CCSM3 present-day control simulation. Furthermore, the amplitude of variability is much reduced in CCSM4 compared to that of CCSM3. Similarities as well as differences in AMOC variability mechanisms between CCSM3 and CCSM4 are discussed. As in CCSM3, the CCSM4 AMOC variability is primarily driven by the positive density anomalies at the Labrador Sea (LS) deep-water formation site, peaking 2 yr prior to an AMOC maximum. All processes, including parameterized mesoscale and submesoscale eddies, play a role in the creation of salinity anomalies that dominate these density anomalies. High Nordic Sea densities do not necessarily lead to increased overflow transports because the overflow physics is governed by source and interior region density differences. Increased overflow transports do not lead to a higher AMOC either but instead appear to be a precursor to lower AMOC transports through enhanced stratification in LS. This has important implications for decadal prediction studies. The North Atlantic Oscillation (NAO) is significantly correlated with the positive boundary layer depth and density anomalies prior to an AMOC maximum. This suggests a role for NAO through setting the surface flux anomalies in LS and affecting the subpolar gyre circulation strength.
    Description: The CCSM project is supported by NSF and the Office of Science (BER) of the U.S. Department of Energy. SGY and YOK were supported by the NOAA Climate Program Office under Climate Variability and Predictability Program Grants NA09OAR4310163 and NA10OAR4310202, respectively.
    Description: 2013-02-01
    Keywords: Meridional overturning circulation ; Coupled models ; Ocean models ; Oceanic variability
    Repository Name: Woods Hole Open Access Server
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  • 41
    Publication Date: 2022-05-25
    Description: Author Posting. © American Meteorological Society, 2012. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 42 (2012): 1524–1547, doi:10.1175/JPO-D-11-0117.1.
    Description: Evidence is presented for the transfer of energy from low-frequency inertial–diurnal internal waves to high-frequency waves in the band between 6 cpd and the buoyancy frequency. This transfer links the most energetic waves in the spectrum, those receiving energy directly from the winds, barotropic tides, and parametric subharmonic instability, with those most directly involved in the breaking process. Transfer estimates are based on month-long records of ocean velocity and temperature obtained continuously over 80–800 m from the research platform (R/P) Floating Instrument Platform (FLIP) in the Hawaii Ocean Mixing Experiment (HOME) Nearfield (2002) and Farfield (2001) experiments, in Hawaiian waters. Triple correlations between low-frequency vertical shears and high-frequency Reynolds stresses, uiw∂Ui/∂z, are used to estimate energy transfers. These are supported by bispectral analysis, which show significant energy transfers to pairs of waves with nearly identical frequency. Wavenumber bispectra indicate that the vertical scales of the high-frequency waves are unequal, with one wave of comparable scale to that of the low-frequency parent and the other of much longer scale. The scales of the high-frequency waves contrast with the classical pictures of induced diffusion and elastic scattering interactions and violates the scale-separation assumption of eikonal models of interaction. The possibility that the observed waves are Doppler shifted from intrinsic frequencies near f or N is explored. Peak transfer rates in the Nearfield, an energetic tidal conversion site, are on the order of 2 × 10−7 W kg−1 and are of similar magnitude to estimates of turbulent dissipation that were made near the ridge during HOME. Transfer rates in the Farfield are found to be about half the Nearfield values.
    Description: This work was supported by the National Science Foundation and the Office of Naval Research.
    Description: 2013-03-01
    Keywords: Diapycnal mixing ; Energy transport ; Internal waves ; Nonlinear dynamics ; Ship observations ; Spectral analysis/models/distribution
    Repository Name: Woods Hole Open Access Server
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  • 42
    Publication Date: 2022-05-25
    Description: Author Posting. © American Meteorological Society, 2012. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Atmospheric and Oceanic Technology 29 (2012): 1377–1390, doi:10.1175/JTECH-D-11-00160.1.
    Description: Estimates of surface currents over the continental shelf are now regularly made using high-frequency radar (HFR) systems along much of the U.S. coastline. The recently deployed HFR system at the Martha’s Vineyard Coastal Observatory (MVCO) is a unique addition to these systems, focusing on high spatial resolution over a relatively small coastal ocean domain with high accuracy. However, initial results from the system showed sizable errors and biased estimates of M2 tidal currents, prompting an examination of new methods to improve the quality of radar-based velocity data. The analysis described here utilizes the radial metric output of CODAR Ocean Systems’ version 7 release of the SeaSonde Radial Site Software Suite to examine both the characteristics of the received signal and the output of the direction-finding algorithm to provide data quality controls on the estimated radial currents that are independent of the estimated velocity. Additionally, the effect of weighting spatial averages of radials falling within the same range and azimuthal bin is examined to account for differences in signal quality. Applied to two month-long datasets from the MVCO high-resolution system, these new methods are found to improve the rms difference comparisons with in situ current measurements by up to 2 cm s−1, as well as reduce or eliminate observed biases of tidal ellipses estimated using standard methods.
    Description: 2013-03-01
    Keywords: Coastal flows ; Currents ; Data processing ; Data quality control ; In situ atmospheric observations ; Remote sensing
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  • 43
    Publication Date: 2022-05-25
    Description: Author Posting. © American Meteorological Society, 2011. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 41 (2011): 2168–2186, doi:10.1175/JPO-D-11-08.1.
    Description: This paper studies the interaction of an Antarctic Circumpolar Current (ACC)–like wind-driven channel flow with a continental slope and a flat-bottomed bay-shaped shelf near the channel’s southern boundary. Interaction between the model ACC and the topography in the second layer induces local changes of the potential vorticity (PV) flux, which further causes the formation of a first-layer PV front near the base of the topography. Located between the ACC and the first-layer slope, the newly formed PV front is constantly perturbed by the ACC and in turn forces the first-layer slope with its own variability in an intermittent but persistent way. The volume transport of the slope water across the first-layer slope edge is mostly directly driven by eddies and meanders of the new front, and its magnitude is similar to the maximum Ekman transport in the channel. Near the bay’s opening, the effect of the topographic waves, excited by offshore variability, dominates the cross-isobath exchange and induces a mean clockwise shelf circulation. The waves’ propagation is only toward the west and tends to be blocked by the bay’s western boundary in the narrow-shelf region. The ensuing wave–coast interaction amplifies the wave amplitude and the cross-shelf transport. Because the interaction only occurs near the western boundary, the shelf water in the west of the bay is more readily carried offshore than that in the east and the mean shelf circulation is also intensified along the bay’s western boundary.
    Description: Y. Zhang acknowledges the support of the MIT-WHOI Joint Program in Physical Oceanography and NSF OCE-9901654 and OCE- 0451086. J. Pedlosky acknowledges the support of NSF OCE-9901654 and OCE-0451086.
    Keywords: Baroclinic flows ; Eddies ; Fronts ; Mass fluxes/transport ; Mesoscale processes ; Topographic effects
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  • 44
    Publication Date: 2022-05-25
    Description: Author Posting. © American Meteorological Society, 2012. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Climate 25 (2012): 343–349, doi:10.1175/JCLI-D-11-00059.1.
    Description: The Equatorial Undercurrent (EUC) is a major component of the tropical Pacific Ocean circulation. EUC velocity in most global climate models is sluggish relative to observations. Insufficient ocean resolution slows the EUC in the eastern Pacific where nonlinear terms should dominate the zonal momentum balance. A slow EUC in the east creates a bottleneck for the EUC to the west. However, this bottleneck does not impair other major components of the tropical circulation, including upwelling and poleward transport. In most models, upwelling velocity and poleward transport divergence fall within directly estimated uncertainties. Both of these transports play a critical role in a theory for how the tropical Pacific may change under increased radiative forcing, that is, the ocean dynamical thermostat mechanism. These findings suggest that, in the mean, global climate models may not underrepresent the role of equatorial ocean circulation, nor perhaps bias the balance between competing mechanisms for how the tropical Pacific might change in the future. Implications for model improvement under higher resolution are also discussed.
    Description: KBK gratefully acknowledges the J. Lamar Worzel Assistant Scientist Fund. GCJ is supported by NOAA’s Office of Oceanic and Atmospheric Research. RM gratefully acknowledges the generous support and hospitality of the Divecha Centre for Climate Change and CAOS at IISc, Bangalore, and partial support by NASA PO grants.
    Description: 2012-07-01
    Keywords: Tropics ; Ocean circulation ; Ocean dynamics ; Climate models ; Coupled models ; Ocean models
    Repository Name: Woods Hole Open Access Server
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  • 45
    Publication Date: 2022-05-25
    Description: Author Posting. © American Meteorological Society, 2012. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Climate 25 (2012): 1096–1115, doi:10.1175/2011JCLI4228.1.
    Description: Ventilation, including subduction and obduction, for the global oceans was examined using Simple Ocean Data Assimilation (SODA) outputs. The global subduction rate averaged over the period from 1959 to 2006 is estimated at 505.8 Sv (1 Sv ≡ 106 m3 s−1), while the corresponding global obduction rate is estimated at 482.1 Sv. The annual subduction/obduction rates vary greatly on the interannual and decadal time scales. The global subduction rate is estimated to have increased 7.6% over the past 50 years, while the obduction rate is estimated to have increased 9.8%. Such trends may be insignificant because errors associated with the data generated by ocean data assimilation could be as large as 10%. However, a major physical mechanism that induced these trends is primarily linked to changes in the Southern Ocean. While the Southern Ocean plays a key role in global subduction and obduction rates and their variability, both the Southern Ocean and equatorial regions are critically important sites of water mass formation/erosion.
    Description: This work was supported by the Key State Basic Research Program of China under Grant 2012CB417401, the National Natural Science Foundation of China (Grants 40906007, 40890152), and the Open Foundation of Physical Oceanography Laboratory, OUC, under Grant 200902.
    Description: 2012-08-15
    Keywords: Decadal variability ; Southern Ocean ; Trends ; Water masses ; Convergence ; Mixing
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  • 46
    Publication Date: 2022-05-25
    Description: Author Posting. © American Meteorological Society, 2012. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 42 (2012): 659–668, doi:10.1175/JPO-D-11-0125.1.
    Description: Ice-tethered profiler (ITP) measurements from the Arctic Ocean’s Canada Basin indicate an ocean surface layer beneath sea ice with significant horizontal density structure on scales of hundreds of kilometers to the order 1 km submesoscale. The observed horizontal gradients in density are dynamically important in that they are associated with restratification of the surface ocean when dense water flows under light water. Such restratification is prevalent in wintertime and competes with convective mixing upon buoyancy forcing (e.g., ice growth and brine rejection) and shear-driven mixing when the ice moves relative to the ocean. Frontal structure and estimates of the balanced Richardson number point to the likelihood of dynamical restratification by isopycnal tilt and submesoscale baroclinic instability. Based on the evidence here, it is likely that submesoscale processes play an important role in setting surface-layer properties and lateral density variability in the Arctic Ocean.
    Description: Funding was provided by the National Science Foundation Office of Polar Programs Arctic Sciences Section under Awards ARC-0519899, ARC-0856479, and ARC-0806306. Support was also provided by the Woods Hole Oceanographic Institution Arctic Research Initiative.
    Description: 2012-10-01
    Keywords: Arctic ; Ocean dynamics
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  • 47
    Publication Date: 2022-05-25
    Description: Author Posting. © American Meteorological Society, 2012. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Climate 25 (2012): 2622–2651, doi:10.1175/JCLI-D-11-00301.1.
    Description: This study presents an overview of the El Niño–Southern Oscillation (ENSO) phenomenon and Pacific decadal variability (PDV) simulated in a multicentury preindustrial control integration of the NCAR Community Climate System Model version 4 (CCSM4) at nominal 1° latitude–longitude resolution. Several aspects of ENSO are improved in CCSM4 compared to its predecessor CCSM3, including the lengthened period (3–6 yr), the larger range of amplitude and frequency of events, and the longer duration of La Niña compared to El Niño. However, the overall magnitude of ENSO in CCSM4 is overestimated by ~30%. The simulated ENSO exhibits characteristics consistent with the delayed/recharge oscillator paradigm, including correspondence between the lengthened period and increased latitudinal width of the anomalous equatorial zonal wind stress. Global seasonal atmospheric teleconnections with accompanying impacts on precipitation and temperature are generally well simulated, although the wintertime deepening of the Aleutian low erroneously persists into spring. The vertical structure of the upper-ocean temperature response to ENSO in the north and south Pacific displays a realistic seasonal evolution, with notable asymmetries between warm and cold events. The model shows evidence of atmospheric circulation precursors over the North Pacific associated with the “seasonal footprinting mechanism,” similar to observations. Simulated PDV exhibits a significant spectral peak around 15 yr, with generally realistic spatial pattern and magnitude. However, PDV linkages between the tropics and extratropics are weaker than observed.
    Description: M. Alexander, A. Capotondi, and J. Scott’s participation was supported by a grant from the NSF Climate and Large-scale Dynamics Program. Y.-O. Kwon gratefully acknowledges support from a WHOI Heyman fellowship and a grant from the NSF Climate and Largescale Dynamics Program. The CESM project is supported by the National Science Foundation and the Office of Science (BER) of the U.S. Department of Energy.
    Description: 2012-10-15
    Keywords: Atmosphere-ocean interaction ; El Nino ; ENSO ; La Nina ; Pacific decadal oscillation ; Climate models
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  • 48
    Publication Date: 2022-05-25
    Description: Author Posting. © American Meteorological Society, 2012. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Climate 25 (2012): 3515–3531, doi:10.1175/JCLI-D-11-00028.1.
    Description: The study examined global variability of air–sea sensible heat flux (SHF) from 1980 to 2009 and the large-scale atmospheric and ocean circulations that gave rise to this variability. The contribution of high-latitude wintertime SHF was identified, and the relative importance of the effect of the sea–air temperature difference versus the effect of wind on decadal SHF variability was analyzed using an empirical orthogonal function (EOF) approach. The study showed that global SHF anomalies are strongly modulated by SHF at high latitudes (poleward of 45°) during winter seasons. Decadal variability of global wintertime SHF can be reasonably represented by the sum of two leading EOF modes, namely, the boreal wintertime SHF in the northern oceans and the austral wintertime SHF in the southern oceans. The study also showed that global wintertime SHF is modulated by the prominent modes of the large-scale atmospheric circulation at high latitudes. The increase of global SHF in the 1990s is attributable to the strengthening of the Southern Hemisphere annular mode index, while the decrease of global SHF after 2000 is due primarily to the downward trend of the Arctic Oscillation index. This study identified the important effects of wind direction and speed on SHF variability. Changes in winds modify the sea–air temperature gradient by advecting cold and dry air from continents and by imposing changes in wind-driven oceanic processes that affect sea surface temperature (SST). The pattern of air temperature anomalies dominates over the pattern of SST anomalies and dictates the pattern of decadal SHF variability.
    Description: The study is supported by the NOAA Office of Climate Observations (OCO) and the WHOI Arctic Climate Initiative. X. Song acknowledges the support from the China Scholarship Council, National Natural Science Foundation of China (NSFC) (40930844, 40976004, and 40921004) and the Ministry of Education’s 111 Project (B07036).
    Description: 2012-11-15
    Keywords: Atmosphere-ocean interaction
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  • 49
    Publication Date: 2022-05-25
    Description: Author Posting. © American Meteorological Society, 2012. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 42 (2012): 1083–1098, doi:10.1175/JPO-D-11-015.1.
    Description: Here, the response of a coastally trapped buoyant plume to downwelling-favorable wind forcing is explored using a simplified two-dimensional numerical model and a prognostic theory for the resulting width, depth, and density anomaly and along-shelf transport of the plume. Consistent with the numerical simulations, the analytical model shows that the wind causes mixing of the plume water and that the forced cross-shelf circulation can also generate significant deepening and surface narrowing, as well as increased along-shelf transport. The response is due to a combination of the purely advective process that leads to the steepening of the isopycnals and the entrainment of ambient water into the plume. The advective component depends on the initial plume geometry: plumes that have a large fraction of their total width in contact with the bottom (“bottom trapped”) suffer relatively small depth and width changes compared to plumes that have a large fraction of their total width detached from the bottom (“surface trapped”). Key theoretical parameters are Wγ/Wα, the ratio of the width of the plume detached from the bottom to the width of the plume in contact with it, and the ratio of the wind-generated mixed layer δe to the initial plume depth hp, which determines the amount of water initially entrained into the plume. The model results also show that the cross-shelf circulation can be strongly influenced by the wind-driven response in combination with the geostrophic shear of the plume. The continuous entrainment into the plume, as well as transient events, is also discussed.
    Description: This work has been supported by FONDECYT Grant 1070501. S. Lentz received support by theNational Science Foundation GrantOCE-0751554. C. Moffat had additional support from the National Science Foundation Office of Polar Programs through U.S. Southern Ocean GLOBEC Grants OPP 99-10092 and 06- 23223.
    Description: 2013-01-01
    Keywords: Baroclinic flows ; Boundary currents ; Coastal flows ; Upwelling/downwelling ; Wind ; Ocean models
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  • 50
    Publication Date: 2022-05-25
    Description: Author Posting. © American Meteorological Society, 2012. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Climate 25 (2012): 3549–3565, doi:10.1175/JCLI-D-11-00320.1.
    Description: The recently released NCEP Climate Forecast System Reanalysis (CFSR) is used to examine the response to ENSO in the northeast tropical Pacific Ocean (NETP) during 1979–2009. The normally cool Pacific sea surface temperatures (SSTs) associated with wind jets through the gaps in the Central American mountains at Tehuantepec, Papagayo, and Panama are substantially warmer (colder) than the surrounding ocean during El Niño (La Niña) events. Ocean dynamics generate the ENSO-related SST anomalies in the gap wind regions as the surface fluxes damp the SSTs anomalies, while the Ekman heat transport is generally in quadrature with the anomalies. The ENSO-driven warming is associated with large-scale deepening of the thermocline; with the cold thermocline water at greater depths during El Niño in the NETP, it is less likely to be vertically mixed to the surface, particularly in the gap wind regions where the thermocline is normally very close to the surface. The thermocline deepening is enhanced to the south of the Costa Rica Dome in the Papagayo region, which contributes to the local ENSO-driven SST anomalies. The NETP thermocline changes are due to coastal Kelvin waves that initiate westward-propagating Rossby waves, and possibly ocean eddies, rather than by local Ekman pumping. These findings were confirmed with regional ocean model experiments: only integrations that included interannually varying ocean boundary conditions were able to simulate the thermocline deepening and localized warming in the NETP during El Niño events; the simulation with variable surface fluxes, but boundary conditions that repeated the seasonal cycle, did not.
    Description: This research was supported by grants from the NOAA office of Global Programs and the NSF Climate and Global Dynamics Division.
    Description: 2012-11-15
    Keywords: North Pacific Ocean ; Atmosphere-ocean interaction ; ENSO ; Thermocline circulation ; Waves, oceanic ; Ocean models
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  • 51
    Publication Date: 2022-05-25
    Description: Author Posting. © American Meteorological Society, 2012. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Atmospheric and Oceanic Technology 29 (2012): 1363–1376, doi:10.1175/JTECH-D-12-00060.1.
    Description: The design of a surface mooring for deployment in the Gulf Stream in the Mid-Atlantic Bight is described. The authors' goals were to observe the surface meteorology; upper-ocean variability; and air–sea exchanges of heat, freshwater, and momentum in and near the Gulf Stream during two successive 1-yr deployments. Of particular interest was quantifying these air–sea fluxes during wintertime events that carry cold, dry air from the land over the Gulf Stream. Historical current data and information about the surface waves were used to guide the design of the surface mooring. The surface buoy provided the platform for both bulk meteorological sensors and a direct covariance flux system. Redundancy in the meteorological sensors proved to be a largely successful strategy to obtain complete time series. Oceanographic instrumentation was limited in size by considerations of drag; and two current meters, three temperature–salinity recorders, and 15 temperature recorders were deployed. Deployment from a single-screw vessel in the Gulf Stream required a controlled-drift stern first over the anchor sites. The first deployment lasted the planned full year. The second deployment ended after 3 months when the mooring was cut by unknown means at a depth of about 3000 m. The mooring was at times in the core of the Gulf Stream, and a peak surface current of over 2.7 m s−1 was observed. The 15-month records of surface meteorology and air–sea fluxes captured the seasonal variability as well as several cold-air outbreaks; the peak observed heat loss was in excess of 1400 W m−2.
    Description: This work was funded by the National Science Foundation Grant OCE04-24536 as part of the CLIVAR Mode Water Dynamics Experiment (CLIMODE). The Vetlesen Foundation is also acknowledged for the early support of SB.
    Description: 2013-03-01
    Keywords: Buoy observations
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  • 52
    Publication Date: 2022-05-25
    Description: Author Posting. © American Meteorological Society, 2012. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 42 (2012): 1981–2000, doi:10.1175/JPO-D-12-028.1.
    Description: Packets of nonlinear internal waves (NLIWs) in a small area of the Mid-Atlantic Bight were 10 times more energetic during a local neap tide than during the preceding spring tide. This counterintuitive result cannot be explained if the waves are generated near the shelf break by the local barotropic tide since changes in shelfbreak stratification explain only a small fraction of the variability in barotropic to baroclinic conversion. Instead, this study suggests that the occurrence of strong NLIWs was caused by the shoaling of distantly generated internal tides with amplitudes that are uncorrelated with the local spring-neap cycle. An extensive set of moored observations show that NLIWs are correlated with the internal tide but uncorrelated with barotropic tide. Using harmonic analysis of a 40-day record, this study associates steady-phase motions at the shelf break with waves generated by the local barotropic tide and variable-phase motions with the shoaling of distantly generated internal tides. The dual sources of internal tide energy (local or remote) mean that shelf internal tides and NLIWs will be predictable with a local model only if the locally generated internal tides are significantly stronger than shoaling internal tides. Since the depth-integrated internal tide energy in the open ocean can greatly exceed that on the shelf, it is likely that shoaling internal tides control the energetics on shelves that are directly exposed to the open ocean.
    Description: This research was supported by ONR Grants N00014-05-1-0271, N00014-08-1-0991, N00014-04- 1-0146, and N00014-11-1-0194.
    Description: 2013-05-01
    Keywords: Internal waves ; Nonlinear dynamics ; Tides
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  • 53
    Publication Date: 2022-05-25
    Description: Author Posting. © American Meteorological Society, 2012. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 42 (2012): 329-351, doi:10.1175/JPO-D-11-026.1.
    Description: Data from a closely spaced array of moorings situated across the Beaufort Sea shelfbreak at 152°W are used to study the Western Arctic Shelfbreak Current, with emphasis on its configuration during the summer season. Two dynamically distinct states of the current are revealed in the absence of wind, with each lasting approximately one month. The first is a surface-intensified shelfbreak jet transporting warm and buoyant Alaskan Coastal Water in late summer. This is the eastward continuation of the Alaskan Coastal Current. It is both baroclinically and barotropically unstable and hence capable of forming the surface-intensified warm-core eddies observed in the southern Beaufort Sea. The second configuration, present during early summer, is a bottom-intensified shelfbreak current advecting weakly stratified Chukchi Summer Water. It is baroclinically unstable and likely forms the middepth warm-core eddies present in the interior basin. The mesoscale instabilities extract energy from the mean flow such that the surface-intensified jet should spin down over an e-folding distance of 300 km beyond the array site, whereas the bottom-intensified configuration should decay within 150 km. This implies that Pacific Summer Water does not extend far into the Canadian Beaufort Sea as a well-defined shelfbreak current. In contrast, the Pacific Winter Water configuration of the shelfbreak jet is estimated to decay over a much greater distance of approximately 1400 km, implying that it should reach the first entrance to the Canadian Arctic Archipelago.
    Description: This work was supported by National Science Foundation GrantsOCE-0726640,OPP-0731928, and OPP-0713250.
    Description: 2012-09-01
    Keywords: Arctic ; Continental shelf/slope ; Boundary currents
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  • 54
    Publication Date: 2022-05-25
    Description: Author Posting. © American Meteorological Society, 2012. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 42 (2012): 748–763, doi:10.1175/JPO-D-11-086.1.
    Description: Isohaline coordinate analysis is used to compare the exchange flow in two contrasting estuaries, the long (with respect to tidal excursion) Hudson River and the short Merrimack River, using validated numerical models. The isohaline analysis averages fluxes in salinity space rather than in physical space, yielding the isohaline exchange flow that incorporates both subtidal and tidal fluxes and precisely satisfies the Knudsen relation. The isohaline analysis can be consistently applied to both subtidally and tidally dominated estuaries. In the Hudson, the isohaline exchange flow is similar to results from the Eulerian analysis, and the conventional estuarine theory can be used to quantify the salt transport based on scaling with the baroclinic pressure gradient. In the Merrimack, the isohaline exchange flow is much larger than the Eulerian quantity, indicating the dominance of tidal salt flux. The exchange flow does not scale with the baroclinic pressure gradient but rather with tidal volume flux. This tidal exchange is driven by tidal pumping due to the jet–sink flow at the mouth constriction, leading to a linear dependence of exchange flow on tidal volume flux. Finally, a tidal conversion parameter Qin/Qprism, measuring the fraction of tidal inflow Qprism that is converted into net exchange Qin, is proposed to characterize the exchange processes among different systems. It is found that the length scale ratio between tidal excursion and salinity intrusion provides a characteristic to distinguish estuarine regimes.
    Description: SNC is supported by a WHOI postdoctoral scholarship, a NSF Grant OCE-0926427, and a Taiwan National Science Council Grant NSC 100- 2199-M-002-028.WRGis supported byNSFGrantOCE- 0926427. JAL is supported by NSF Grant OCE-0452054.
    Description: 2012-11-01
    Keywords: Coastal flows
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  • 55
    Publication Date: 2022-05-25
    Description: Author Posting. © American Meteorological Society, 2012. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 42 (2012): 855–868, doi:10.1175/JPO-D-10-05010.1.
    Description: Data from the Hudson River estuary demonstrate that the tidal variations in vertical salinity stratification are not consistent with the patterns associated with along-channel tidal straining. These observations result from three additional processes not accounted for in the traditional tidal straining model: 1) along-channel and 2) lateral advection of horizontal gradients in the vertical salinity gradient and 3) tidal asymmetries in the strength of vertical mixing. As a result, cross-sectionally averaged values of the vertical salinity gradient are shown to increase during the flood tide and decrease during the ebb. Only over a limited portion of the cross section does the observed stratification increase during the ebb and decrease during the flood. These observations highlight the three-dimensional nature of estuarine flows and demonstrate that lateral circulation provides an alternate mechanism that allows for the exchange of materials between surface and bottom waters, even when direct turbulent mixing through the pycnocline is prohibited by strong stratification.
    Description: The funding for this research was obtained from NSF Grant OCE-08-25226.
    Description: 2012-11-01
    Keywords: Mixing ; Ocean circulation ; Shear structure/flows ; Transport ; Turbulence
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  • 56
    Publication Date: 2022-05-25
    Description: Author Posting. © American Meteorological Society, 2011. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 41 (2011): 2307–2327, doi:10.1175/JPO-D-10-05004.1.
    Description: Results from a high-resolution (~2 km) numerical simulation of the Irminger Basin during summer 2003 are presented. The focus is on the East Greenland Spill Jet, a recently discovered component of the circulation in the basin. The simulation compares well with observations of surface fields, the Denmark Strait overflow (DSO), and the hydrographic structure of typical sections in the basin. The model reveals new aspects of the circulation on scales of O(0.1–10) days and O(1–100) km. The model Spill Jet results from the cascade of dense waters over the East Greenland shelf. Spilling can occur in various locations southwest of the strait, and it is present throughout the simulation but exhibits large variations on periods of O(0.1–10) days. The Spill Jet sometimes cannot be distinguished in the velocity field from surface eddies or from the DSO. The vorticity structure of the jet confirms its unstable nature with peak relative and tilting vorticity terms reaching twice the planetary vorticity term. The average model Spill Jet transport is 4.9 ±1.7 Sv (1 Sv ≡ 106 m3 s−1) equatorward, about 2½ times larger than has been previously reported from a single ship transect in August 2001. Kinematic analysis of the model results suggests two different types of spilling events. In the first case (type I), a local perturbation results in dense waters descending over the shelf break into the Irminger Basin. In the second case (type II), surface cyclones associated with DSO deep domes initiate the spilling process. During summer 2003, more than half of the largest Spill Jet transport values are of type II.
    Description: The research is supported by the National Science Foundation Grants OCE-0726393 and OCI-0904640 (MGM and TWNH) and OCE-0726640 (RSP).
    Description: 2012-06-01
    Keywords: North Atlantic Ocean ; In situ observations ; Regional models
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  • 57
    Publication Date: 2022-05-25
    Description: Author Posting. © American Meteorological Society, 2012. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 42 (2012): 126–140, doi:10.1175/2011JPO4513.1.
    Description: A climatologically forced high-resolution model is used to examine variability of subtropical mode water (STMW) in the northwestern Pacific Ocean. Despite the use of annually repeating atmospheric forcing, significant interannual to decadal variability is evident in the volume, temperature, and age of STMW formed in the region. This long time-scale variability is intrinsic to the ocean. The formation and characteristics of STMW are comparable to those observed in nature. STMW is found to be cooler, denser, and shallower in the east than in the west, but time variations in these properties are generally correlated across the full water mass. Formation is found to occur south of the Kuroshio Extension, and after formation STMW is advected westward, as shown by the transport streamfunction. The ideal age and chlorofluorocarbon tracers are used to analyze the life cycle of STMW. Over the full model run, the average age of STMW is found to be 4.1 yr, but there is strong geographical variation in this, from an average age of 3.0 yr in the east to 4.9 yr in the west. This is further evidence that STMW is formed in the east and travels to the west. This is qualitatively confirmed through simulated dye experiments known as transit-time distributions. Changes in STMW formation are correlated with a large meander in the path of the Kuroshio south of Japan. In the model, the large meander inhibits STMW formation just south of Japan, but the export of water with low potential vorticity leads to formation of STMW in the east and an overall increase in volume. This is correlated with an increase in the outcrop area of STMW. Mixed layer depth, on the other hand, is found to be uncorrelated with the volume of STMW.
    Description: E.M.D. acknowledges support of the Doherty Foundation and National Science Foundation (OCE-0849808). S.R.J was sponsored by the National Science Foundation (OCE-0849808). Participation of S.P. and F.B. was supported by the National Science Foundation by its sponsorship of the National Center for Atmospheric Research.
    Description: 2012-07-01
    Keywords: Water masses ; Pacific Ocean ; Tracers ; Advection ; Forcing ; Interannual variuability
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  • 58
    Publication Date: 2022-05-25
    Description: Author Posting. © American Meteorological Society, 2011. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 41 (2011): 2223–2241, doi:10.1175/2011JPO4344.1.
    Description: Results are presented from an observational study of stratified, turbulent flow in the bottom boundary layer on the outer southeast Florida shelf. Measurements of momentum and heat fluxes were made using an array of acoustic Doppler velocimeters and fast-response temperature sensors in the bottom 3 m over a rough reef slope. Direct estimates of flux Richardson number Rf confirm previous laboratory, numerical, and observational work, which find mixing efficiency not to be a constant but rather to vary with Frt, Reb, and Rig. These results depart from previous observations in that the highest levels of mixing efficiency occur for Frt 〈 1, suggesting that efficient mixing can also happen in regions of buoyancy-controlled turbulence. Generally, the authors find that turbulence in the reef bottom boundary layer is highly variable in time and modified by near-bed flow, shear, and stratification driven by shoaling internal waves.
    Description: Funding was provided by grants from the National Oceanic and Atmospheric Administration’s National Undersea Research Program, National Science Foundation Grants OCE-0622967 and OCE- 0824972 to SGM, and the Singapore Stanford Program. Kristen Davis was supported by a National Defense Science and Engineering Graduate Fellowship and an ARCS Foundation Fellowship.
    Keywords: Boundary layer ; Turbulence ; Bottom currents ; Mixing ; Internal waves
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  • 59
    Publication Date: 2022-05-25
    Description: Author Posting. © American Meteorological Society, 2012. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 42 (2012): 669–691, doi:10.1175/2011JPO4129.1.
    Description: The spectral energy density of the internal waves in the open ocean is considered. The Garrett and Munk spectrum and the resonant kinetic equation are used as the main tools of the study. Evaluations of a resonant kinetic equation that suggest the slow time evolution of the Garrett and Munk spectrum is not in fact slow are reported. Instead, nonlinear transfers lead to evolution time scales that are smaller than one wave period at high vertical wavenumber. Such values of the transfer rates are inconsistent with the viewpoint expressed in papers by C. H. McComas and P. Müller, and by P. Müller et al., which regards the Garrett and Munk spectrum as an approximate stationary state of the resonant kinetic equation. It also puts the self-consistency of a resonant kinetic equation at a serious risk. The possible reasons for and resolutions of this paradox are explored. Inclusion of near-resonant interactions decreases the rate at which the spectrum evolves. Consequently, this inclusion shows a tendency of improving of self-consistency of the kinetic equation approach.
    Description: YL is supported by NSF DMS Grant 0807871 and ONR Award N00014-09-1-0515.
    Description: 2012-11-01
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  • 60
    Publication Date: 2022-05-25
    Description: Author Posting. © American Meteorological Society, 2012. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Climate 25 (2012): 6743–6755, doi:10.1175/JCLI-D-11-00549.1.
    Description: From 1969 to 1971 convection in the Labrador Sea shut down, thus interrupting the formation of the intermediate/dense water masses. The shutdown has been attributed to the surface freshening induced by the Great Salinity Anomaly (GSA), a freshwater anomaly in the subpolar North Atlantic. The abrupt resumption of convection in 1972, in contrast, is attributed to the extreme atmospheric forcing of that winter. Here oceanic and atmospheric data collected in the Labrador Sea at Ocean Weather Station Bravo and a one-dimensional mixed layer model are used to examine the causes of the shutdown and resumption of convection in detail. These results highlight the tight coupling of the ocean and atmosphere in convection regions and the need to resolve both components to correctly represent convective processes in the ocean. They are also relevant to present-day conditions given the increased ice melt in the Arctic Ocean and from the Greenland Ice Sheet. The analysis herein shows that the shutdown was initiated by the GSA-induced freshening as well as the mild 1968/69 winter. After the shutdown had begun, however, the continuing lateral freshwater flux as well as two positive feedbacks [both associated with the sea surface temperature (SST) decrease due to lack of convective mixing with warmer subsurface water] further inhibited convection. First, the SST decrease reduced the heat flux to the atmosphere by reducing the air–sea temperature gradient. Second, it further reduced the surface buoyancy loss by reducing the thermal expansion coefficient of the surface water. In 1972 convection resumed because of both the extreme atmospheric forcing and advection of saltier waters into the convection region.
    Description: This research was funded by a grant from the NWO/SRON User Support Programme Space Research. FS acknowledges support from OCE- 0850416 and NOAA NA08OAR4310569.
    Description: 2013-04-01
    Keywords: Atmosphere-ocean interaction ; Intermediate waters ; Oceanic variability
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  • 61
    Publication Date: 2022-05-25
    Description: Author Posting. © American Meteorological Society, 2012. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 42 (2012): 1859–1881, doi:10.1175/JPO-D-11-0235.1.
    Description: In the 1970s and 1980s, there was considerable interest in near-equatorial variability at periods of days to weeks associated with oceanic equatorial inertia–gravity waves and mixed Rossby–gravity waves. At that time, the measurements available for studying these waves were much more limited than today: most of the available observations were from scattered island tide gauges and a handful of short mooring records. More than a decade of the extensive modern data record from the Tropical Atmosphere Ocean (TAO)/Triangle Trans-Ocean Buoy Network (TRITON) mooring array in the Pacific Ocean is used to reexamine the internal-wave climate in the equatorial Pacific, with a focus on interpretation of the zonal-wavenumber/frequency spectrum of surface dynamic height relative to 500 decibars at periods of 3–15 days and zonal wavelengths exceeding 30° of longitude. To facilitate interpretation of the dynamic height spectrum and identification of equatorial wave modes, the spectrum is decomposed into separate spectra associated with dynamic height fluctuations that are symmetric or antisymmetric about the equator. Many equatorial-wave meridional modes can be identified, for both the first and second baroclinic mode. Zonal-wavenumber/frequency spectra of the zonal and meridional wind stress components are also examined. The observed wind stress spectra are used with linear theory of forced equatorial waves to provide a tentative explanation for the zonal-wavenumber extent of the spectral peaks seen in dynamic height. Examination of the cross-equatorial symmetry properties of the wind stress suggests that virtually all of the large-scale equatorial inertia–gravity and mixed Rossby–gravity waves examined may be sensitive to both zonal and meridional wind stress.
    Description: This research was funded by NASA Grant NNX10AO93G.
    Description: 2013-05-01
    Keywords: Inertia-gravity waves
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  • 62
    Publication Date: 2021-12-15
    Description: Some of the most structurally innovative concrete vaults built in imperial Rome employed lightweight volcanic rocks to reduce the lateral thrust on the supporting walls, the most famous being the Pantheon. Roman concrete (opus caementicium) was made up of mortar binding together pieces of large aggregate (caementa) usually ranging from 10 to 20 cm long, which were hand laid in the mortar (as opposed to being poured as is typical in modern concrete), so that it resembles mortared rubble. A key aspect of the development of large-scale concrete vaulting was the ability to regulate the weight of the ingredients in order to reduce the weight of the vaults and to control the forces within the structure. The volcanic environment along the west coast of Italy provided numerous stones of different weights and physical properties from which the builders could choose (Fig. 1), including pumice and scoria, which were the most common choices for the lightweight caementa of the most innovative vaulted structures. Because these materials were produced by many of the Italian volcanoes, our goal was to establish the provenance of those used in vaults in Rome in order to understand better the supply network. We first used thin sections to narrow the potential sources and then we submitted selected samples to X-ray fluorescence
    Description: Published
    Description: 707-727
    Description: JCR Journal
    Description: restricted
    Keywords: concrete vault ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous
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  • 63
    Publication Date: 2022-05-26
    Description: Author Posting. © American Meteorological Society, 2012. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 42 (2012): 291–305, doi:10.1175/JPO-D-11-043.1.
    Description: A number of previous observational studies have found that the waters of the deep Pacific Ocean have an age, or elapsed time since contact with the surface, of 700–1000 yr. Numerical models suggest ages twice as old. Here, the authors present an inverse framework to determine the mean age and its upper and lower bounds given Global Ocean Data Analysis Project (GLODAP) radiocarbon observations, and they show that the potential range of ages increases with the number of constituents or sources that are included in the analysis. The inversion requires decomposing the World Ocean into source waters, which is obtained here using the total matrix intercomparison (TMI) method at up to 2° × 2° horizontal resolution with 11 113 surface sources. The authors find that the North Pacific at 2500-m depth can be no younger than 1100 yr old, which is older than some previous observational estimates. Accounting for the broadness of surface regions where waters originate leads to a reservoir-age correction of almost 100 yr smaller than would be estimated with a two or three water-mass decomposition and explains some of the discrepancy with previous observational studies. A best estimate of mean age is also presented using the mixing history along circulation pathways. Subject to the caveats that inference of the mixing history would benefit from further observations and that radiocarbon cannot rule out the presence of extremely old waters from exotic sources, the deep North Pacific waters are 1200–1500 yr old, which is more in line with existing numerical model results.
    Description: GG is supported by the J. Lamar Worzel Assistant Scientist Fund and the Penzance Endowed Fund in Support of Assistant Scientists. PJH is supported by NSF Award 0960787.
    Description: 2012-08-01
    Keywords: North Pacific Ocean ; Mass fluxes/transport ; Ocean circulation ; Tracers ; Optimization ; Variational analysis
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  • 64
    Publication Date: 2022-05-24
    Description: Series of multiple main shocks that develop on adjacent faults is a typical way in which active extension is accommodated in the Apennines of Italy. This behaviour is explained by fault interaction that occurs at a scale ranging from seconds to days, yielding a space–time clustering of earthquakes, termed as earthquake storms. We show that the seismic energy released by historical earthquakes in central Apennines is clustered into two main small time periods, around 600 and 300 years ago, during which a great portion of the normal faulting belt failed. We favour the hypothesis that clustering results from sudden input of deep fluids into the brittle upper crust. The roughly 300 years periodicity and the 3–4 mm year−1 of tectonic extension suggest that earthquake storms need to be taken into account in seismic hazard scenarios.
    Description: Published
    Description: 300–306
    Description: JCR Journal
    Description: restricted
    Keywords: Apennines ; 04. Solid Earth::04.06. Seismology::04.06.99. General or miscellaneous
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  • 65
    Publication Date: 2022-06-08
    Description: Although no deterministic and reliable earthquake precursor is known to date, we are steadily gaining insight into probabilistic forecasting that draws on space–time characteristics of earthquake clustering. Clustering-based models aiming to forecast earthquakes within the next 24 hours are under test in the global project ‘Collaboratory for the Study of Earthquake Predictability’ (CSEP). The 2011 March 11 magnitude 9.0 Tohoku-Oki earthquake in Japan provides a unique opportunity to test the existing 1-day CSEP models against its unprecedentedly active aftershock sequence. The original CSEP experiment performs tests after the catalogue is finalized to avoid bias due to poor data quality. However, this study differs from this tradition and uses the preliminary catalogue revised and updated by the Japan Meteorological Agency (JMA), which is often incomplete but is immediately available. This study is intended as a first step towards operability-oriented earthquake forecasting in Japan. Encouragingly, at least one model passed the test in most combinations of the target day and the testing method, although the models could not take account of the megaquake in advance and the catalogue used for forecast generation was incomplete. However, it can also be seen that all models have only limited forecasting power for the period immediately after the quake. Our conclusion does not change when the preliminary JMAcatalogue is replaced by the finalized one, implying that the models perform stably over the catalogue replacement and are applicable to operational earthquake forecasting. However, we emphasize the need of further research on model improvement to assure the reliability of forecasts for the days immediately after the main quake. Seismicity is expected to remain high in all parts of Japan over the coming years. Our results present a way to answer the urgent need to promote research on time-dependent earthquake predictability to prepare for subsequent large earthquakes in the near future in Japan.
    Description: Published
    Description: 653-658
    Description: 3.1. Fisica dei terremoti
    Description: JCR Journal
    Description: restricted
    Keywords: Time-series analysis ; Probabilistic forecasting ; Seismicity and tectonics ; Computational seismology ; Statistical seismology ; Asia ; 04. Solid Earth::04.06. Seismology::04.06.02. Earthquake interactions and probability
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  • 66
    Publication Date: 2022-06-10
    Description: A multi-proxy record is presented for approximately the last 4500 cal a BP from Lake Shkodra, Albania/Montenegro. Lithological analyses, C/N ratio and δ13C of the organic and inorganic carbon component suggest that organic matter and bulk carbonate are predominantly authigenic. The δ18O record of bulk carbonate indicates the presence of two prominent wet periods: one at ca. 4300 cal a BP and one at ca. 2500–2000 cal a BP. The latter phase is also found in southern Spain and Central Italy, and represents a prominent event in the western and central Mediterranean. In the last 2000 years, four relatively wet intervals occurred between ca. 1800 and 1500 cal a BP (150–450 AD), 1350–1250 (600–700 AD), 1100–800 (850–1150 AD), and at ca. 90 cal a BP (1860 AD). Between ca. 4100 and 2500 cal a BP δ18O values are relatively high, with three prominent peaks indicating drier conditions at ca. 4100–4000 cal a BP, ca. 3500 and at ca. 3300 cal a BP. Four additional drier events are identified at 1850 (ca. 100 AD), 1400 (ca. 550 AD), 1150 (800 AD) and ca.750 cal a BP (1200 AD). The pollen record does not show changes in accordance with these episodes owing to the poor sensitivity of vegetation in this area, which is dominated by an orographic rainfall effect and where changes in altitudinal vegetation belts do not affect the pollen rain in the lake catchment. However, since ca. 900 cal a BP a significant decrease in the percentage arboreal pollen and in pollen concentrations suggest major deforestation produced by human activities. Copyright © 2012 John Wiley & Sons, Ltd.
    Description: Published
    Description: 780-789
    Description: 3.7. Dinamica del clima e dell'oceano
    Description: JCR Journal
    Description: reserved
    Keywords: Lake Shkodra ; late Holocene ; Mediterranean ; palaeoclimate ; stable isotopes ; 03. Hydrosphere::03.01. General::03.01.06. Paleoceanography and paleoclimatology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 67
    Publication Date: 2022-05-24
    Description: Two different free-air gravity datasets from the Apennines have been analysed in the frequency domain to investigate the mechanisms of support of topography. At short wavelength (λ〈150 km) the best fit between the observed and the calculated admittance gives a value of the elastic thickness of 3.7 km. The observed behaviour of the admittance at larger wavelengths (λ〉150 km) shows that such topography is not supported by elastic stresses in the lithosphere but is dynamically supported by mantle convection. The distribution of gravity anomalies and topography suggests that the mantle is rising beneath the main topographic bulge of the Apennines and that this flow is maintained by buoyancy forces, rather than being driven by movement of the subducted slab.
    Description: Published
    Description: 228-233
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: JCR Journal
    Description: reserved
    Keywords: Dynamic Topography ; Gravity ; Apennines ; 04. Solid Earth::04.03. Geodesy::04.03.03. Gravity and isostasy
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 68
    Publication Date: 2022-05-24
    Description: GPS measurements on Mount St. Helens spanning the 2004.00-2010.85 time interval, encompassing the 2004-2008 dome-building eruption, were analyzed. First, a local reference frame was derived in order to isolate the volcanic ground deformation from the background tectonic pattern related to the interactions between the Pacific, Juan de Fuca and North American plates. Secondly, the resulting ground deformation patterns were modelled to constrain magmatic sources. Results suggest a vertically elongated magma chamber centred at 8 - 9 km depth beneath the summit area that deflated during the beginning of the dome growth and inflated since January 2008, evidencing that a primary magma reservoir was active both during and after the eruption in a magmatic system persistent over the time.
    Description: Published
    Description: 148-155
    Description: 1.3. TTC - Sorveglianza geodetica delle aree vulcaniche attive
    Description: JCR Journal
    Description: restricted
    Keywords: Mount St. Helens ; Ground deformation modelling ; local reference frame ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 69
    Publication Date: 2022-05-24
    Description: The early Cenozoic, which is punctuated by several negative carbon isotope excursions (CIEs), was a time of climatic and oceanographic transition from ’Greenhouse’ to ’Icehouse’ conditions. The occurrence of a 0.5& CIE starting at the top of Chron C27n (TC27N) is reconfirmed with stable isotope data from Zumaia (Spain) and Bjala (Bulgaria) localities. Spectral analysis on respective carbonate ⁄magnetic susceptibility proxy records substantiates the orbital cyclostratigraphy allowing correlation to a high-resolution benthic foraminifera isotope record from ODP Pacific Site 1209, that indicates a coeval 2 C transient warming. The hyperthermal event lasts 200 ka, contrasting with other short-lived events from the Eocene, and displays a relatively rapid onset and a longer tailing back to pre-event values similar to the Palaeocene–Eocene Thermal Maximum (PETM), though lower in amplitude. That a causal trigger for the TC27N event may be the onset of volcanism in the North Atlantic Igneous Province (NAIP) can be inferred from a 200-m-thick lava pile erupted during C27n ⁄ C26r polarity transition in the E Greenland margin.
    Description: Published
    Description: 477-486
    Description: 2.2. Laboratorio di paleomagnetismo
    Description: JCR Journal
    Description: reserved
    Keywords: hyperthermal ; isotope excursion ; TC27N event ; Zumaia ; 03. Hydrosphere::03.01. General::03.01.06. Paleoceanography and paleoclimatology ; 04. Solid Earth::04.04. Geology::04.04.08. Sediments: dating, processes, transport ; 04. Solid Earth::04.04. Geology::04.04.10. Stratigraphy
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 70
    Publication Date: 2022-06-10
    Description: Earthquake forecasts are usually underinformed, and can be plagued by uncertainty in terms of the most appropriate model, and parameter values used in that model. In this paper, we explore the application of two different models to the same seismogenic area. The first is a renewal model based on the characteristic earthquake hypothesis that uses historical/palaeoseismic recurrence times, and fixed rupture geometries. The hazard rate is modified by the Coulomb static stress change caused by nearby earthquakes that occurred since the latest characteristic earthquake. The second model is a very simple earthquake simulator based on plate-motion, or fault-slip rates and adoption of a Gutenberg–Richter magnitude–frequency distribution. This information is commonly available even if historical and palaeoseismic recurrence data are lacking. The intention is to develop and assess a simulator that has a very limited parameter set that could be used to calculate earthquake rates in settings that are not as rich with observations of large-earthquake recurrence behaviour as the Nankai trough. We find that the use of convergence rate as a primary constraint allows the simulator to replicate much of the spatial distribution of observed segmented rupture rates along the Nankai, Tonankai and Tokai subduction zones. Although we note rate differences between the two forecast methods in the Tokai zone, we also see enough similarities between simulations and observations to suggest that very simple earthquake rupture simulations based on empirical data and fundamental earthquake laws could be useful forecast tools in information-poor settings.
    Description: Published
    Description: 1673-1688
    Description: 3.1. Fisica dei terremoti
    Description: JCR Journal
    Description: restricted
    Keywords: Time series analysis ; Spatial analysis ; Probability distributions ; Seismic cycle ; Earthquake interaction ; forecasting, and prediction ; Statistical seismology. ; 04. Solid Earth::04.06. Seismology::04.06.02. Earthquake interactions and probability ; 04. Solid Earth::04.06. Seismology::04.06.05. Historical seismology ; 04. Solid Earth::04.07. Tectonophysics::04.07.05. Stress
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 71
    Publication Date: 2022-05-26
    Description: Author Posting. © American Meteorological Society, 2012. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Climate 25 (2012): 1361–1389, doi:10.1175/JCLI-D-11-00091.1.
    Description: The ocean component of the Community Climate System Model version 4 (CCSM4) is described, and its solutions from the twentieth-century (20C) simulations are documented in comparison with observations and those of CCSM3. The improvements to the ocean model physical processes include new parameterizations to represent previously missing physics and modifications of existing parameterizations to incorporate recent new developments. In comparison with CCSM3, the new solutions show some significant improvements that can be attributed to these model changes. These include a better equatorial current structure, a sharper thermocline, and elimination of the cold bias of the equatorial cold tongue all in the Pacific Ocean; reduced sea surface temperature (SST) and salinity biases along the North Atlantic Current path; and much smaller potential temperature and salinity biases in the near-surface Pacific Ocean. Other improvements include a global-mean SST that is more consistent with the present-day observations due to a different spinup procedure from that used in CCSM3. Despite these improvements, many of the biases present in CCSM3 still exist in CCSM4. A major concern continues to be the substantial heat content loss in the ocean during the preindustrial control simulation from which the 20C cases start. This heat loss largely reflects the top of the atmospheric model heat loss rate in the coupled system, and it essentially determines the abyssal ocean potential temperature biases in the 20C simulations. There is also a deep salty bias in all basins. As a result of this latter bias in the deep North Atlantic, the parameterized overflow waters cannot penetrate much deeper than in CCSM3.
    Description: NCAR is sponsored by the National Science Foundation. The CCSM is also sponsored by the Department of Energy. SGY was supported by the NOAA Climate Program Office under Climate Variability and Predictability Program Grant NA09OAR4310163.
    Description: 2012-09-01
    Keywords: Ocean circulation ; Climate models ; General circulation models ; Ocean models
    Repository Name: Woods Hole Open Access Server
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  • 72
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    Unknown
    American Meteorological Society
    Publication Date: 2022-05-26
    Description: Author Posting. © American Meteorological Society, 2012. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 42 (2012): 644–658, doi:10.1175/JPO-D-11-0143.1.
    Description: When steady flow in a stratified ocean passes between the continental slope and open ocean, its ability to cross isobaths is potentially limited by buoyancy arrest. If the bottom Ekman transport vanishes and there are no interior stresses, then steady linear flow on an f plane must be geostrophic and follow isobaths exactly. The influence of arrest on cross-shelf transport is investigated here to establish 1) whether there are substantial penetration asymmetries between cases with upwelling and downwelling in the bottom boundary layer; 2) over what spatial scales, hence in what parameter regime, buoyancy arrest is important; and 3) the effects of depth-dependent interior flow. The problem is approached using scalings and idealized numerical models. The results show that there is little or no asymmetry introduced by bottom boundary layer behavior. Further, if the stratification is weak or moderate, as measured by a slope Burger number s = αN/f (where α is the bottom slope, N is buoyancy frequency, and f is the Coriolis parameter), buoyancy arrest does not exert a strong constraint on cross-isobath exchange.
    Description: This research was supported by the National Science Foundation Physical Oceanography program through Grant OCE-0849498.
    Description: 2012-10-01
    Keywords: Coastal flows ; Ekman pumping/transport
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 73
    facet.materialart.
    Unknown
    American Meteorological Society
    Publication Date: 2022-05-26
    Description: Author Posting. © American Meteorological Society, 2012. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 42 (2012): 1684–1700, doi:10.1175/JPO-D-11-0230.1.
    Description: The influences of precipitation on water mass transformation and the strength of the meridional overturning circulation in marginal seas are studied using theoretical and idealized numerical models. Nondimensional equations are developed for the temperature and salinity anomalies of deep convective water masses, making explicit their dependence on both geometric parameters such as basin area, sill depth, and latitude, as well as on the strength of atmospheric forcing. In addition to the properties of the convective water, the theory also predicts the magnitude of precipitation required to shut down deep convection and switch the circulation into the haline mode. High-resolution numerical model calculations compare well with the theory for the properties of the convective water mass, the strength of the meridional overturning circulation, and also the shutdown of deep convection. However, the numerical model also shows that, for precipitation levels that exceed this critical threshold, the circulation retains downwelling and northward heat transport, even in the absence of deep convection.
    Description: This study was supported by the National Science Foundation underGrantsOCE-0850416, OCE-0959381, andOCE-0859381.
    Description: 2013-04-01
    Keywords: Boundary currents ; Deep convection ; Eddies ; Meridional overturning circulation ; Ocean dynamics ; Stability
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 74
    Publication Date: 2022-05-26
    Description: Author Posting. © American Meteorological Society, 2012. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 42 (2012): 1834–1858, doi:10.1175/JPO-D-11-0234.1.
    Description: The theoretical resonant excitation of equatorial inertia–gravity waves and mixed Rossby–gravity waves is examined. Contrary to occasionally published expectations, solutions show that winds that are broadband in both zonal wavenumber and frequency do not in general produce peaks in the wavenumber–frequency spectrum of sea surface height (SSH) at wavenumbers associated with vanishing zonal group velocity. Excitation of total wave energy in inertia–gravity modes by broadband zonal winds is virtually wavenumber independent when the meridional structure of the winds does not impose a bias toward negative or positive zonal wavenumbers. With increasing wavenumber magnitude |k|, inertia–gravity waves asymptote toward zonally propagating pure gravity waves, in which the magnitude of meridional velocity υ becomes progressively smaller relative to the magnitude of zonal velocity u and pressure p. When the total wave energy is independent of wavenumber, this effect produces a peak in |υ|2 near the wavenumber where group velocity vanishes, but a trough in |p|2 (or SSH variance). Another consequence of the shift toward pure gravity wave structure is that broadband meridional winds excite inertia–gravity modes progressively less efficiently as |k| increases and υ becomes less important to the wave structure. Broadband meridional winds produce a low-wavenumber peak in total wave energy leading to a subtle elevation of |p|2 at low wavenumbers, but this is due entirely to the decrease in the forcing efficiency of meridional winds with increasing |k|, rather than to the vanishing of the group velocity. Physical conditions that might alter the above conclusions are discussed.
    Description: This research was funded by NASA Grant NNX10AO93G.
    Description: 2013-05-01
    Keywords: Inertia-gravity waves ; Ocean dynamics
    Repository Name: Woods Hole Open Access Server
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  • 75
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    Unknown
    Wiley-Blackwell
    In:  EPIC3Oxidative Stress in Aquatic Ecosystems, Oxidative Stress in Aquatic Ecosystems, Wiley-Blackwell, 18 p., pp. 263-280, ISBN: 978-1-4443-3548-4
    Publication Date: 2023-06-21
    Description: The chapter will summarize and critically review metabolic responses to environmental stress and stress effects on energy budgets in mollusks. Metabolic adaptations to environmental stress will be analyzed including alternative energy conserving pathways, aerobic/anaerobic transitions and metabolic arrest. Their role in the efficient use of energy substrates and in the maintenance of cellular homeostasis and redox status will be discussed. General stress effects on energy budget at different organization levels (from the cell to the whole-organism) will be analyzed including energy uptake, assimilation, conversion and expenditure, as well as the metabolic costs associated with stress resistance (including antioxidant protection, chaperone function and damage repair). We will compare metabolic responses to moderate and extreme levels of environmental stressors using temperature, ocean acidification, salinity, oxygen deficiency and toxic metal stress as examples. This chapter will also outline the future research directions to improve our understanding of the stress effects on bioenergetics in mollusks and other invertebrates. Keywords: Stress, metabolic adaptation, metabolic arrest, bioenergetics, cellular defense, energy trade-offs
    Repository Name: EPIC Alfred Wegener Institut
    Type: Inbook , peerRev
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  • 76
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    Wiley-Blackwell
    In:  EPIC3Oxidative Stress in Aquatic Ecosystems, Oxidative Stress in Aquatic Ecosystems, Oxford, Wiley-Blackwell, 524 p., pp. 115-126, ISBN: 978 1 4443 3548 4
    Publication Date: 2023-06-21
    Repository Name: EPIC Alfred Wegener Institut
    Type: Inbook , peerRev
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  • 77
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    Wiley-Blackwell
    In:  EPIC3Wiley-Blackwell, ISBN: 9781444335484
    Publication Date: 2023-06-21
    Repository Name: EPIC Alfred Wegener Institut
    Type: Book , peerRev
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  • 78
    Publication Date: 2023-02-10
    Description: The Indonesian island of Sumatra, located in one of the most active zones of the Pacific Ring of Fire, is characterized by a chain of subduction-zone volcanoes which extend the entire length of the island. As a group of volcanic geochemists, we embarked upon a five-week sampling expedition to these exotic, remote, and in part explosive volcanoes (SAGE 2010; Sumatran Arc Geochemical Expedition). We set out to collect rock and gas samples from 17 volcanic centres from the Sumatran segment of the Sunda arc system, with the aim of obtaining a regionally significant sample set that will allow quantification of the respective roles of mantle versus crustal sources to magma genesis along the strike of the arc. Here we document our geological journey through Sumatra’s unpredictable terrain, including the many challenges faced when working on active volcanoes in pristine tropical climes.
    Description: Swedish Science Foundation (VR), Scripps Institution of Oceanography, Istituto Nazionale di Geofisica e Vulcanologia (INGV), Upp-sala University Centre for Natural Disaster Science (CNDS) and Otterborgska donationsfonden
    Description: Published
    Description: 64-70
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: N/A or not JCR
    Description: restricted
    Keywords: Sumatra ; Indonesia ; geochemisty ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 79
    Publication Date: 2024-05-09
    Description: In this paper, we propose a new model of the crustal structure and seismotectonics for central Sicily (southern Italy) through the analysis of the depth distribution and kinematics of the instrumental seismicity, occurring during the period from 1983 to 2010, and its comparison with individual geological structures that may be active in the area. The analysed data set consists of 392 earthquakes with local magnitudes ranging from 1.0 to 4.7. We defined a new, detailed 1-D velocity model to relocate the earthquakes that occurred in central Sicily, and we calculated a Moho depth of 37 km and a mean VP/VS ratio of 1.73. The relocated seismic events are clustered mainly in the area north of Caltanissetta (e.g. Mainland Sicily) and in the northeastern sector (Madonie Mountains) of the study area; only minor and greatly dispersed seismicity is located in the western sector, near Belice, and along the southern coast, between Gela and Sciacca. The relocated hypocentral distribution depicts a bimodal pattern: 50 per cent of the events occur within the upper crust at depths less than ~16 km, 40 per cent of the events occur within the middle and depth crust, at depths between 16 and 32 km, and the remaining 10 per cent occur at subcrustal depths. The energy release pattern shows a similar depth distribution. On the basis of the kinematic analysis of 38 newly computed focal plane solutions, two major geographically distinct seismotectonic domains are distinguished: the Madonie Mountain domain, with prevalent extensional and extensional-oblique kinematics associated with upper crust Late Pliocene–Quaternary faulting, and the Mainland Sicily domain, with prevalent compressional and compressional-oblique kinematics associated with thrust faulting, at mid to deep crust depth, along the north-dipping Sicilian Basal Thrust (SBT). The stress inversion of the Mainland Sicily focal solutions integrated with neighbouring mechanisms available in the literature highlights a regional homogeneous compressional tensor, with a subhorizontal NNW–SSE-striking σ1 axis. In addition, on the basis of geodetic data, the Mainland Sicily domain may be attributed to the SSE-ward thrusting of the Mainland Sicily block along the SBT plane. Seismogenic shearing along the SBT at mid-crustal depths was responsible for the unexpected Belice 1968 earthquake (Mw 6.1), with evident implications in terms of hazard assessment.
    Description: Published
    Description: 1237-2252
    Description: 1.1. TTC - Monitoraggio sismico del territorio nazionale
    Description: 3.2. Tettonica attiva
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: 5.2. TTC - Banche dati di sismologia strumentale
    Description: JCR Journal
    Description: restricted
    Keywords: Seismicity and tectonics ; Continental tectonics: compressional ; Dynamics: seismotectonics ; Crustal structure ; Europe ; 04. Solid Earth::04.06. Seismology::04.06.99. General or miscellaneous ; 04. Solid Earth::04.06. Seismology::04.06.01. Earthquake faults: properties and evolution ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.99. General or miscellaneous ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.04. Plate boundaries, motion, and tectonics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 80
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 236 (1996), S. 111-127 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Neuartige Fluoropolyether-Polyol-Harze, die mit konventionellen Härtern wie Polyisocyanaten oder Melaminen aushärtbar sind, wurden hergestellt. Zunächst wurden oligomere NCO-terminierte Prepolymere durch Addition von Fluorpolyether-Makrodiolen unterschiedlicher Molekulargewichte an Isophorondiisocyanate erhalten. Durch die Reaktion dieser Prepolymeren mit Trimethylolpropan wurden endständige Hydroxygruppen eingeführt. Die Viskosität von Lösungen dieser Harze wurde bei unterschiedlichen Konzentrationen (Massenbruch 0,4-0,8) und Temperaturen (25°C-65°C) gemessen. Die erhaltenen Werte wurden auf der Basis der Erickson-Gleichung (Konzentrationsabhängigkeit von η) und unter Berücksichtigung des WLF-und des Arrhenius-Modells (Temperaturabhängigkeit von η) diskutiert. Das thermische Verhalten der Harze und von ausgehärteten Filmen wurde mit DSC bestimmt. Dabei wurden zwei Glasübergange beobachtet, die den separierten fluorhaltigen und nicht-fluorhaltigen Phasen zugeordnet werden können. Die Analyse des Zugverhaltens der Filme zeigte besonders bei den mit Isocyanat gehärteten Proben ein ausgeprägtes hart-plastisches Verhalten. Diese Werkstoffe erscheinen für die Anwendung als hoch-wertige, dauerfeste und klare Beschichtungen geeignet.
    Notes: New fluoropolyether polyolic resins are presented suitable to be cured with conventional hardeners as polyisocyanates or melamines. These resins are prepared by addition of fluoropolyether macrodiols (Fomblin® ZDOLTX) of various molecular weights to isophorone diisocyanate (IPDI) to give oligomeric NCO-terminated prepolymers. The final hydroxy functionality is obtained by the reaction of those prepolymers with trimethylolpropane (TMP). The viscosity of the resins is measured at various concentrations (weight fraction 0.8 - 0.4) and temperatures (T = 25-65°C). The results are discussed in terms of the Erickson equation (η vs. concentration) and using the WLF and Arrhenius models (η vs. T). The thermal behavior is studied by DSC for both the resins and cured films indicating the presence of two Tgs, corresponding to the segregated fluorinated and hydrogenated phases, the former particularly evident with the highest molecular weights of the fluorinated macromer. Tensile curves of selfsupported films are then analyzed showing an evident tough-plastic behavior especially for the isocyanate-cured films. The application of such materials as high-durability clear coats is finally proposed.
    Additional Material: 5 Ill.
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  • 81
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 237 (1996), S. 1-44 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Zur Verbesserung der Maßhaltigkeit und der Zähigkeit von gehärteten Melamin-Formaldehyd-Harz-Formmassen (MF) wurden teilverträgliche, methylolgruppenhaltige Epoxidharze (EP) auf Bisphenol A-Basis hergestellt und charakterisiert. Die Vernetzung solcher Epoxyresolharze durch 2-Ethyl-4-methylimidazol in Gegenwart von MF-Harz wurde untersucht. Spritzgepreßte Probekörper zeigen eine Zweiphasenstruktur; die EP-Phase kann als Wirt für carboxy-funktionalisierte, oligomere NBR-Kautschuke (CTBNX) dienen, die für sich allein in MF-Harzen nicht wirksam sind. Unter der Voraussetzung von kovalenten Bindungen in der Phasengrenzfläche kann durch den Zusatz von 0,5 bis 4 Gew.-% CTBNX zur MF-Formmasse bei EP-Anteilen bis 20 Gew.-% eine 50 bis 100proz. Steigerung von Bruchdehnung und Schlagzähigkeit erreicht werden, ohne daß Steifigkeit und Wärmeformbeständigkeit wesentlich abfallen. Bei moderaten EP/CTBNX-Gehalten wird zusätzlich die Nachschwindung von MF-Formteilen vermindert.
    Notes: In order to improve dimension stability and toughness of melamine formaldehyde moulding materials (MF), compatible bisphenol A epoxy resins (EP) with additional methylol groups were synthesized and characterized. Crosslinking of those epoxyresol resins with 2-ethyl-4-methylimidazole in the presence of MF resin was investigated. Transfer-moulded specimens revealed a two-phase morphology in which the EP phase is used as a host for modification with carboxylic functionalized oligomeric NBR rubber (CTBNX), which is not effective in MF moulding materials alone. The addition of 0.5 - 4 wt.-% CTBNX to the MF moulding materials at an epoxy content of maximum 20 wt.-% results in 50-100 % increase of elasticity and toughness without serious decrease in stiffness and heat deflection temperature, provided that covalent interfacial bonds exist. In addition, the post-shrinkage of MF parts decreases if a moderate EP/CTBNX content is introduced.
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  • 82
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 238 (1996), S. 11-30 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Der gleichzeitige Einfluß des Verhältnisses von Fließhilfsmittel (Paraloid K 120N), Rußart und Schlagzähmodifikator (CPE 3615 und Kane Ace B56 A) auf die wichtigsten physiko-mechanischen Eigenschaften unplastifizierter PVC-Mischungen wurde studiert.Die erhaltenen Resultate wurden mathematisch verarbeitet und graphisch als Funktionsflächen dargestellt. Bemerkenswert ist, daß die Einführung von 2,5 und 5 Teilen Ruß eine Verbesserung der physico-mechanischen Eigenschaften ermöglicht. Dieses Resultat ist durch die Anwesenheit der Schlagzäh- und Fließmodifikatoren zu erklären.
    Notes: The concurrent influence of the processing aid (Paraloid K 120N) and the carbon black ratio, as well as the nature and the ratio of the impact modifier (CPE 3615 and Kane Ace B56 A) on the main physico-mechanical characteristics of the poly(vinyl chloride)-based unplasticized mixtures have been studied. The results obtained, processed mathematically and plotted graphically in the form of response surfaces, evidenced that the improvement of certain physico-mechanical properties becomes possible by the introduction of 2.5 parts and 5.0 parts carbon black into these compounds. This is due to the introduction of impact modifiers and processing aids into the mixtures.
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  • 83
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 238 (1996), S. 63-71 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Eine Reihe neuartiger Polyhydrazide mit endständigen Phenoxygruppen wurde aus äquimolaren Anteilen von Dicarbonsäuredichloriden und Phenoxyterephthalsäuredihydrazid durch Lösungspolykondensation in N-Methyl-2-pyrrolidinon (NMP) bei niedriger Temperatur hergestellt. Durch thermische Cyclisierung der Polyhydrazide wurden die entsprehchenden Poly(1,3,4-oxadiazol)e mit endständigen Phenoxygruppen erhalten. Die Polymeren wurden durch Viskosimetrie, Löslichkeitsuntersuchungen, IR-Spektroskopie, Differentialkalorimetrie und Thermogravimetrie charakterisiert.
    Notes: A series of new polyhydrazides containing pendent phenoxy groups has been synthesized by low-temperature solution polycondensation of equimolar amounts of diacid dichlorides and 2-phenoxyterephthalic dihydrazide in N-methyl-2-pyrrolidi-none (NMP). The thermal cyclization of the polyhydrazides gave the corresponding poly(1,3,4-oxadiazole)s containing pendent phenoxy groups. The polymers were characterized by viscometry, solubility measurements, IR spectroscopy, differential scanning calorimetry (DSC) and thermogravimetric analysis.
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  • 84
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 238 (1996), S. 105-117 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Ein Ethylen-Vinylacetat-Copolymeres (EVA) mit 12% Vinylacetat-Gehalt wurde mit Trimethylolpropantrimethacrylat (TMPTMA) als Sensibilisator mit Elektronen bestrahlt. Die mechanischen und elektrischen Eigenschaften der bestrahlten Copolymerproben wurden untersucht. Die Resultate zeigen, daß sich Zugfestigkeit und Bruchdehnung zunächst mit zunehmender Strahlungsdosis verbessern und bei Überschreiten einer optimalen Strahlungsdosis und Sensibilisatorkonzentration wieder verschlechtern. Durch die Bestrahlung wird eine Vernetzung des Polymeren ausgelöst, die auf den sich mit der Strahlungsdosis erhöhenden Gelanteil zurückgeführt wird. Im Vergleich mit den Originalproben nehmen sowohl die Dielektrizitätskonstante als auch der dielektrische Verlustfaktor durch die Elektronenbestrahlung ab.
    Notes: Ethylene-vinyl acetate (EVA) copolymer (12% vinyl acetate content) is subjected to electron beam irradiation using trimethylolpropane trimethacrylate (TMPTMA) as a radiation sensitizer. Mechanical and electrical studies of these irradiated samples show that the strength properties (tensile strength, elongation at break) are increased with radiation dosage up to an optimum radiation dose and sensitizer level above which the properties begin to deteriorate. Crosslinking of the polymer takes place on irradiation which is attributed to an increased gel content with increasing radiation dose. Compared to the original samples both dielectric constant and dielectric loss factor decrease for samples subjected to irradiation.
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  • 85
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    Angewandte Makromolekulare Chemie 238 (1996), S. 143-163 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Cellulose-p-toluolsulfonsäureester (Cellulosetosylate) lassen sich durch homogene Umsetzung von Cellulose in einer Lösung aus N,N-Dimethylacetamid und LiCl mit Tosylchlorid (Tos-Cl) und Triethylamin in 24 h bei 8°C in hoher Ausbeute und mit minimalem Einbau von Chlordesoxy-Gruppen herstellen. Die unterschiedlichen Celluloseausgangsmaterialien hatten durchschnittliche Polymerisationsgrade von 280 bis 5100. Die Produkte wurden mit Elementaranalyse, 13C-NMR- und FTIR-Spektroskopie und durch Bestimmung der Grenzviskositäten charakterisiert. Die Erhöhung des Molverhältnisses Tos-Cl/Anhydroglucose-Einheit (AGU) von 0.6 auf 9.0 führte zu einem Anstieg des Substitutionsgrades (DS) von 0.4 bis auf einen Maximalwert von 2.3. Die Cellulosetosylate sind in herkömmlichen organischen Lösungsmitteln wie Dimethylsulfoxid (im gesamten DS Bereich) und in N,N-Dimethylacetamid, N,N-Dimethylformamid, Aceton, Tetrahydrofuran und Trichlormethan (in Abhängigkeit von DS) löslich. Durch 13C-NMR-Spektroskopie wurde nachgewiesen, daß die Tosylierung am O-6 Atom der AGU schneller als an den O-2/3 Atomen erfolgt. Die Analyse der korrespondierenden Ioddesoxycellulosen, die durch Umsetzung mit NaI in Acetylaceton synthetisiert wurden, bestätigte dies zusätzlich. Darüber hinaus wurden wichtige Eigenschaften der Cellulosetosylate wie die Stabilität gegenüber Alkali und thermischer Beanspruchung untersucht.
    Notes: Pure cellulose p-toluenesulfonates (tosylates) with an insignificant formation of chlorodeoxy groups were prepared by reacting cellulose dissolved in a solution of N,N-dimethylacetamide and LiCI with tosylchloride (Tos-CI) in the presence of triethylamine within 24 h at 8°C. Various cellulosic starting materials with a degree of polymerization from 280 to 5 100 were used. The samples obtained were characterized by means of elemental analysis, FTIR and 13C NMR spectroscopy, and their intrinsic viscosities. The rise of the molar ratio of Tos-CI/anhydroglucose unit (AGU) from 0.6 to 9.0 leads to an increase in the degree of substitution (DS) from 0.4 up to a maximum value of 2.3. The cellulose tosylates are readily soluble in common organic solvents like dimethyl sulfoxide (within the whole DS range) and in N,N-dimethylacetamide, N,N-dimethylformamide, acetone, tetrahydrofuran and trichloromethane depending on DS. As revealed by 13C NMR spectroscopy a faster tosylation takes place at the O-6 atom of AGU compared with the O-2/3 atoms. This was additionally confirmed by analysis of the corresponding iododeoxy celluloses synthesized with NaI in acetylacetone. Furthermore, some important properties as stability against alkaline and heat were studied as well.
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  • 86
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    Angewandte Makromolekulare Chemie 239 (1996), S. 27-32 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Die Herstellung einer SiC-Oberfläche auf Kohlefasern unter Verwendung einer Sol-Gel-Mischung von Tetraethylorthosilikat (TEOS) und Phenolharz wurde untersucht. FTIR- und SEM-Untersuchungen zeigten, daß die SiC-Oberfläche durch carbothermische Reduktion der Sol-Gel-Mischung bei 1 420°C innerhalb von 15-20 min in einer Argon-Atmosphäre gebildet werden kann. Mittels TGA konnte gezeigt werden, daß die SiC-Beschichtung die thermo-oxidative Stabilität der Kohlefasern erhöht. Bei der erreichten SiC-Schichtdicke von 0,47 μm, bei einem C/Si-Verhältnis von 4, zeigt sich keine Beeinflussung der mechanischen Stabilität der Kohlefasern.
    Notes: The preparation of a SiC coating on a carbon fiber surface using a sol-gel mixture of tetraethyl orthosilicat (TEOS) and phenolic resin was studied. FTIR and SEM investigations indicated that the SiC coating can be formed by carbothermal reduction of the sol-gel mixture at 1420°C for 15-20 min in an argon atmosphere. TGA of the coated fiber was also performed, showing that the SiC coating improves the thermooxidative stability of the carbon fiber. With the thickness of the obtained coating of 0.47 μm using a C/Si ratio of 4, this treatment does not affect the carbon fiber strength.
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  • 87
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    Angewandte Makromolekulare Chemie 239 (1996), S. 55-62 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Diese Mitteilung behandelt den Einfluß von oligomeren Polypropylen- und Polybutylenölen mit unterschiedlichem Molekulargewicht auf die adhäsiven Eigenschaften von ataktischem Polypropylen (aPP) und dessen Mischungen mit einem Styrol-Ethylhexylacrylat-Copolymeren. Die mechanische Adhäsionsarbeit Am von Mischungen, die ataktisches Polypropylen und das Oligomere enthalten, steigt mit dem Molekulargewicht des Oligomeren, was im Fall des Propylenöls signifikanter ist. Im Fall der ternären Mischungen des ataktischen Polypropylens mit dem Styrol-Ethylhexylacrylat-Copolymeren und Oligomeren wird ein Adhäsions-Maximum beobachtet, wenn der Gehalt an Styrol-Ethylhexylacrylat-Copolymeren in der Mischung ungefähr 30 Gew.-% erreicht. Wenn kein Oligomeres in der Mischung vorhanden ist, kann man bei dieser Zusammensetzung ein Adhäsions-Minimum beobachten, was auf die Unverträglichkeit der übrigen Komponenten zurückzuführen ist.
    Notes: This paper deals with the influence of oligomers, namely propylene oil and butylene oil, of different molecular weight on the adhesive properties of atactic polypropylene (aPP) and its mixtures with styrene-2-ethylhexyl acrylate (S-EHA) copolymer. The mechanical work of adhesion Am of the mixture containing atactic polypropylene and oligomer increases with the molecular weight of the oligomer, which was more significant in the case of propylene oil. For ternary mixtures aPP-S-EHA copolymer/oligomer a maximum of adhesion can be observed if the content of the S-EHA copolymer in the mixture reaches about 30 mass-%. In the absence of oligomers in the mixture a minimum of adhesion can be observed for this composition, which can be attributed to the incompatibility of the remaining components.
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  • 88
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: After comparison of three catalyst systems, i.e. [Nd(Oct)3/Al2Cl3ET3/Al(i-But)3, Ni(Oct)2/BF3OEt2/AlEt3 and Al(i-But)3/I2/TiCl4] the titanium catalyst system was used for the copolymerization of 1,3-butadiene with propylene oxide. The effects of monomer ratio on copolymer composition, conversion, microstructure, molar mass and molar mass distribution as well as of time of polymerization and of the aluminium/titanium ratio were evaluted. The copolymerization parameters were determined according to Kelen-Tüdős as rbutadiene = 0,9 and rpropylene oxide = 3,9. Copolymerization was confirmed by 13C NMR spectroscopy and extract evaluation combined with 1H NMR spectroscopy.
    Notes: Für die Copolymerisation von 1,3-Butadien mit Propylenoxid wurde nach dem Vergleich der drei Katalysatorsysteme Nd(Oct)3/Al2Cl3ET3/Al(i-But)3, Ni(Oct)2/ BF3OEt2/AlEt3 und Al(i-But)3/I2/TiCl4 das Titankatalysatorsystem eingesetzt. Neben dem Einfluß der Monomerzusammensetzung auf den Umsatz, die Microstruktur, die Copolymerzusammensetzung, die Molmassen sowie die Molmassenverteilungen wurden auch die Polymerisationszeit und das Aluminium/Titan-Verhältnis untersucht. Die Copolymerisationsparameter wurden nach Kelen-Tüdős zu rButadien = 0,9 und rPropylenoxid = 3,9 bestimmt. Der Copolymernachweis erfolgte über 13C-NMR-Spektroskopie und Extraktionsuntersuchungen in Verbindung mit 1H-NMR-Spektroskopie.
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  • 89
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    Angewandte Makromolekulare Chemie 239 (1996), S. 191-199 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Phosphorhaltige Polyurethane (PU-P) auf der Basis von Bisphenol A wurden durch N-Alkylierung hergestellt und mittels IR- und 1H NMR-Spektroskopie charakterisiert. Physikalische und thermische Eigenschaften dieser Polyurethane wurden mittels Differentialkalorimetrie, Thermogravimetrie, Röntgenbeugung und Untersuchungen der Löslichkeit, der Feuerbeständigkeit (Sauerstoffindex, LOI) und der reduzierten Viskosität bestimmt. Die Glastemperaturen der N-alkylierten Polymeren sanken von 120°C für das Ausgangspolymere bis auf 29°C für das N-alkylierte Polyurethan mit 2 Gew.-% Phosphor. Die Viskosität der N-alkylierten Polyurethane nahm von 0,36 dL g-1 auf 0,24 dL g-1 ab. Die phosphorhaltigen Polyurethane besitzen eine geringere thermische Stabilität und bessere Löslichkeit sowie höhere Feuerbeständlgkeit als das Ausgangspolymere. Die Röntgenstreuexperimente ergaben, daß ein erhöhter Phosphorgehalt der Polyurethane die Kristallinität herabsetzt.
    Notes: Phosporus-containing polyurethanes (PU-P) based on bisphenol A were prepared by N-alkylation. The structures of N-alkylated polyurethanes were characterized by IR and 1H NMR spectra. Physical and thermal properties of the phosphorus-containing polyurethanes were investigated with differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), X-ray diffraction, tests of solubility, limiting oxygen index (LOI) and reduced viscosity. Tg of the N-alkylated polymers decreased from 120°C for the starting polymer to 29°C of the 2.0 wt.-% phosphorus-containing polyurethanes. The viscosity of N-alkylated polyurethanes also decreased from 0.36 dL g-1 to 0.24 dL g-1. The thermal stability of polyurethanes decreased on the introduction of phosphorus groups. The LOI values of polyurethanes showed that fire resistance of phosphorus-containing polyurethanes was enhanced. X-ray diffraction measurements showed that the increased phosphorus content was accompanied by decreased crystallinity of the polyurethanes. The solubility of PU-P was improved.
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  • 90
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: This question was addressed using various methods to monitor the process of curing and state of the final network. Attention was particularly focused on the possible inhomogeneous network formation as a consequence of the crosslinking process. An analysis of experimental data has revealed that some cured resins can be considered as homogeneous as the corresponding uncrosslinked materials. Resins cured by simple stepwise alternating chemistries, with good compatibility of components, usually fulfill the criterion of homogeneity. A family of epoxy resins cured with polyamines belongs to this category. Nodular structures seen by electron microscopy are a result of interaction of the electron beam or etching. Such structures are also observed for uncrosslinked polymers investigated under the same conditions. Formation of inhomogeneities in a number of thermoset systems is due to (a) chainwise mechanism of network formation with fast propagation inducing cyclization and steric volume exclusion and (b) poor compatibility of components of the system made stronger by increasing molecular weights and crosslinking during curing. Networks formed by freeradical polymerization and copolymerization of polyvinyl monomers can serve as an example of crosslinking-driven formation of inhomogeneities.
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  • 91
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The base and transition metal catalyzed isomerization of allyl and crotyl ethers affords a facile, high yield route to the preparation of a variety of mono-, di-, and multifunctional 1-propenyl and 1-butenyl ethers. Employing this novel method, monomers containing epoxide, ester, ether carbonate and urethane groups can be prepared from their readily available allyl and crotyl precursors. In general, these monomers display very high reactivity in cationic polymerizations. In our work, we have focused on photoinduced cationic polymerizations of these monomers using diaryliodonium and triarylsulfonium salt photoinitiators. To study these very fast photopolymerizations, extensive use of real-time infrared spectroscopy was made. Employing this technique, the effects of monomer and photoinitiator structure on the rates of polymerization were studied.
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  • 92
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    Angewandte Makromolekulare Chemie 240 (1996), S. 137-149 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Rubber elasticity is associated with changes in configurational entropy of a long chain. Because the chain cannot change its configuration instantaneously, there is a time delay in deformation to an applied force. This delayed response is the source of viscoelasticity and hysteresis energy loss of elastomer networks. Many tire performance properties are related to the viscoelasticity of tire components. Wet and dry traction of tire is related to the energy loss of the tread material at very high frequencies. On the other hand, rolling resistance of tire is characterized by the energy loss of tread material at relatively low frequencies. The dynamic viscoelastic properties of elastomer network shows characteristic zones on a frequency scale. At very high frequencies the energy loss is controlled by the segmental motions of the polymer chain. At lower frequencies the energy loss is related to the longer range motions of the chain. A series of polymers was synthesized to study the effect of micro- and macro-structure of the polymer on the viscoelastic properties of tread compounds and their tire performance properties. As expected from the theory, the wet traction of the tire was highly correlated to the segmental motions of the chains; namely, the glass transition temperature of the polymer. The energy loss of the compounds at a higher temperature, however, was related to the macrostructure of the polymer chain. Those examples illustrate that the fundamental understanding of the theory of elastomer network allows a tire engineer to obtain the best balance of tire performance characteristics.
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  • 93
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    Angewandte Makromolekulare Chemie 240 (1996), S. 171-180 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Cationic, anionic, and radical ring-opening polymerization of spiro and bicyclic monomers, and their application to network polymers have been developed. Bicyclo orthoesters (BOEs), spiro orthoesters (SOEs), and spiro orthocarbonates (SOCs) were polymerized by cationic double ring-opening. Bicyclobis(γ-butyrolactone)s and spirobis(γ-butyrolactone)s were copolymerized with epoxides by anionic alternating ring-opening. Polymers from SOCs bearing exomethylene groups consisted of ring-opened and vinyl polymerized units. The degree of ring-opening of SOCs depended upon the number of rings and steric hindrance. The radical polymerization of vinylcyclopropanone cyclic acetals depended on the ring-size. With the monomers bearing 5- and 6-membered acetal rings, single ring-opened polymers were obtained. With the monomer bearing 7-membered acetal ring, the polymer mainly consisted of double ring-opened unit. These monomers could be crosslinked by bifunctionalization. Poly(cyclic orthoester)s linked by covalent bonds with dithiols to bifunctional SOEs were crosslinked by acid catalysts, and the reversible crosslinking-depolymerization system could be controlled by temperature.
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  • 94
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    Angewandte Makromolekulare Chemie 240 (1996), S. 205-211 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Polyester urethane network elastomers with incorporated hard segment oligomers have been prepared by poly(ethylene adipate)glycol (PEA), 2,4-tolylene diisocyanate (TDI), and 1,4-butanediol (BD). These hard segment oligomers were hydroxy-terminated oligomers ([BD-TDI]n-BD; n=1,3), obtained by reacting BD with TDI. Concentrations of allophanate as a cross-linking site were determined by the amine degradation method. Hard segment moieties were obtained by a novel selective hydrolysis of soft segments in the elastomers. Molecular weight distributions of hard segment were measured by means of GPC. Mechanical and thermal properties were measured. Dependence of rubber elasticity on physical cross-linking between normal elastomers and the elastomers with incorporated hard segment oligomers were discussed.
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  • 95
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Poly (vinyl alcohol) with pendent styrylpyridinium groups (SbQ) is insolubilized by photoirradiation. An association takes place in SbQ groups. The association of polymer chains becomes marked with increasing the number of SbQ groups. Mainly intermolecular crosslinks were formed. Transparent and homogeneous macrogels consisting of several intermolecular crosslinks are obtained.The proportion of the free water to the bound water in PVA-SbQ gels was 3.3-2.9 despite of the large change in conversion of photodimerization of SbQ groups, x=0.27-0.58. The water uptake after swelling of the gels in water increased 6-27 times compared to the original weight at pH=7. The higher the degree of photocrosslinking, the lower was the degree of swelling. The water diffusion coefficients, D, were (2.2-5.8) × 10-5 cm2 S-1 for a 88% saponified PVA with 1 . 3 mol% SbQ groups. The volume of the gel increased discontinuously about 10-fold for the 99% saponified PVA with 0 . 096 mol% SbQ and 51% water (49% acetone). The acetone concentration at the transition decreased with increasing the degree of saponification of the PVA.
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  • 96
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    Angewandte Makromolekulare Chemie 239 (1996), S. 151-160 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Durch anionische Copolymerisation von Allylmethacrylat und Methylmethacrylat wurden Makromonomere unterschiedlicher Kettenlänge mit durchschnittlich drei Allyl-Doppelbindungen pro Kette hergestellt́ und mit NMR-Spektroskopie und Gelpermeationschromatographie charakterisiert. Durch Copolymerisation der Makromonomeren mit 1-Vinyl-2-pyrrolidon wurden dreidimensionale Strukturen erhalten. Die optischen und mechanischen Eigenschaften der Produkte wurden untersucht, und die Quellungseigenschaften und Vernetzungsgrade wurden bestimmt. Die Copolymereigenschaften wurden durch Makromonomere mit Kettenlängen bis 40 Einheiten nur wenig beeinflußt. Bei Kettenlängen über 50 Einheiten wurde eine leichte Abnahme der Wasseraufnahmefähigkeit und eine deutliche Erhähung des Elastizitätsmoduls beobachtet. Die Vernetzungsgrade hängen von der Makromonomer-Kettenlange ab; eine merkliche Erhöhung aufgrund der groößeren Zahl an Methyl-Methyl-Wechselwirkungen wurde bei Kettenlangen über 50 Einheiten festgestellt. Die Copolymeren zeigen günstige Festigkeits-Dehnungs-Eigenschaften und einen geringen Gehalt an wasserlöslichen Extrakten, in denen durch IR-Spektroskopie 1-Vinyl-2-pyrrolidon-Homopolymere identifiziert wurden. Obwohl mit allen untersuchten Makromonomeren gute Resultate erzielt wurden, scheint für die Copolymerisation mit 1-Vinyl-2-pyrrolidon das Makromonomere mit 50 Einheiten am besten geeignet.
    Notes: Macromonomers of various chain lengths with an average of three allyl double bonds per chain were prepared by anionic copolymerization of allyl methacrylate with methyl methacrylate. The macromonomers were characterized by gel permeation chromatography and nuclear magnetic resonance. The macromonomers were then copolymerized with 1-vinyl-2-pyrrolidone to form three-dimensional structures. Their optical, swelling and mechanical properties were studied and the crosslinking efficiency was determined. The copolymer properties are not greatly affected by macromonomer chain lengths up to 40-mers; above 50-mers there is a slight decrease in the equilibrium water content and a significant increase in the modulus of elasticity. The crosslinking efficiency depends on the macromonomer chain length; a marked increase was observed for the 50-mer because of a greater number of methyl-methyl interactions. Copolymers have favourable strength-strain properties and a low content of water-soluble extracts, in which the IR analysis demonstrated the presence of 1-vinyl-2-pyrrolidone homopolymers. In spite of the good results obtained for all the macromonomers described in this work, the 50-mer seems to be optimal for copolymerization with 1-vinyl-2-pyrrolidone.
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  • 97
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    Angewandte Makromolekulare Chemie 239 (1996), S. 201-213 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: The curing of diglycidyl ether of bisphenol A (DGEBA) with 2,6-dimethylol-p-cresol modified by hexahydrophthalic acid anhydride was investigated and compared with the analogous in situ curing of DGEBA, hexahydrophthalic acid anhydride and 2,6-dimethylol-p-cresol. The chemical reactions were investigated by means of titration and different spectroscopic and chromatographic methods. It was examined whether the less complicated and therefore cheaper in situ reaction delivers postcured products with equal or better properties. Furthermore, it was investigated whether the results are similar using technical phenolic hardeners.
    Notes: Die Härtung von Diandiglycidylether (DDGE) mit hexahydrophthalsäureanhydridmodifiziertem 2,6-Dimethylol-p-kresol (HHPSA-DMPK) wurde untersucht und mit der in situ durchgeführten Vernetzung von DDGE mit Hexahydrophthalsäureanhydrid (HHPSA) und 2,6-Dimethylol-p-kresol (DMPK) verglichen. Die chemischen Reaktionen wurden durch Titration der Epoxidgruppen und mit verschiedenen spektroskopischen und chromatographischen Methoden untersucht. Es wurde geprüft, ob die weniger aufwendige und daher preiswertere in situ-Härtung zu Produkten mit gleichen oder besseren Endeigenschaften führt. Weiterhin wurde die Übertragbarkeit der Ergebnisse auf den Einsatz technischer Phenolharzhärter getestet.
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  • 98
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Zur Entwicklung neuartiger ökologisch verträglicher makromolekularer Schlichtemittel wurden in früheren Arbeiten Copolymerisationsreaktionen zwischen Polyvinylalkohol (PVA) und Stärke unter Verwendung von chemisch reaktiven bifunktionellen Verbindungen wie N-Methylolacrylamid beschrieben. Im Rahmen dieser Arbeit werden die physikochemischen Eigenschaften des resultierenden Copolymeren untersucht. Von Bedeutung sind hierbei insbesondere Merkmale wie Molekulargewichtsverteilung, Klebekraft, Stabilität, Löslichkeit sowie rheologische Eigenschaften. Derartige Kenntnisse über die physikochemische Beschaffenheit der PVA-Ausgangsverbindung sowie des makromolekularen Endproduktes sind eine wesentliche Voraussetzung für die Entwicklung von neuen Produkten, die als wasserlösliche, recycelbare Schlichtemittel zur Anwendung in der Textilindustrie kommen können.
    Notes: A macromolecular sizing agent based on the copolymerization of poly(vinyl alcohol) (PVA) with hydrolysed starch was prepared using the chemically reactive bifunctional compound N-methylolacrylamide. Detailed characteristics of the resultant PVA/N-methylolcarbamoylethylated starch copolymer were studied where emphasis has been placed on solubility, rheological properties, molecular weight distribution, adhesive power and stability. Elucidation of the nature of the macromolecular segments of both N-methylolcarbamoylethylated PVA as well as PVA/N-methylolcarbamoylethylated starch copolymer fulfilled the prerequisite to tailor PVA/starch copolymer which is appropriate for application as a water-soluble recyclable sizing agent by ultrafiltration.
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  • 99
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Seismic isolation was reconfirmed to be extremely efficient for the protection of buildings, and hence human life, on the occasion of the Great Hanshin Earthquake. Rubber bearings are placed under the buildings for isolation, and thus the type of rubber bearings is a dominant factor for efficient isolation. In this report, the performance of peripherally restraining type rubber bearing (PRB) was examined where its contracted model was found to simulate the performance of full scale PRB precisely. Damping ratio and vertical spring constant of PRB are as good as the existing ones. PRB showed lower critical shear strain, but it was concluded that no problems were found for the actual use of PRB.
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  • 100
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The network formation of phenol-formaldehyde resin was investigated by the Monte Carlo (MC) simulation technique. The observed value of the gel point, pc, was exactly determined as a critical extent of reaction, where the Mw/Mn in soluble parts is maximum. The MC simulation with the cubic percolation theory was applied to the gelation of phenolic resins and gave an exact gel point, which was in excellent agreement with the observed value of pc. The simulation showed that the intramolecular reaction occurred frequently with increasing the gel fraction beyond the gel point. The structural analysis of the maximum cluster with the computer strongly supported the contribution of the intramolecular reaction to the network formation of the gel.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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