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  • phosphorus  (681)
  • Springer  (681)
  • American Chemical Society
  • Frontiers
  • MDPI Publishing
  • 101
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    Hydrobiologia 395-396 (1999), S. 293-308 
    ISSN: 1573-5117
    Keywords: phosphorus ; sediments ; eutrophication ; Scotland
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract This paper considers the range of management techniques which are currently available for the remediation of eutrophic lakes, with respect to two lochs within southwest Scotland. Preliminary studies of sources of nutrients identified the need for the development of different management prescriptions for each. Such studies will ensure that the management is tailored to meet the specific needs of the site. The two lochs, Carlingwark Loch at Castle Douglas and Castle Loch at Lochmaben, both support algal blooms but have different nutrient sources. Carlingwark Loch appears to be receiving large quantities of nutrients from the surrounding catchment, whereas Castle Loch shows a net loss of nutrients over its surface inflows, indicating release from the sediments and/or input from overwintering wildfowl. In these cases, if preliminary studies had not been undertaken, the management programmes developed may not have used the most effective control measures.
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  • 102
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    Hydrobiologia 408-409 (1999), S. 307-316 
    ISSN: 1573-5117
    Keywords: macrophytes ; turbidity ; phytoplankton ; zooplankton ; nutrients ; phosphorus ; model ; grazing ; top-down control
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract A review of the literature suggests that aquatic macrophytes can enhance water clarity and reduce phytoplankton biomass through shading, reduction of nutrient availability, excretion of allelopathic substances and reduction of resuspension. In addition, vegetation fields are reported to enhance grazing on phytoplankton by providing a day-time refuge against fish predation for planktonic filter feeders such as Daphniaand by providing a suitable habitat for macrophyte associated filter feeders such as Sida crystallina, Eurycercus lamellatusand Simocephalus velutus. I use a graphical and a simple mathematical model to explore how top-down control by these grazers may interact with the effect of reduced phytoplankton production due to the other factors mentioned. The analysis suggests that grazing tends to be an all-or-none effect, driving phytoplankton to a very low biomass once a certain threshold level of grazing pressure is exceeded. This threshold level is predicted to increase with the productivity of the phytoplankton. Thus, the model suggests that, in plant beds, productivity reducing factors such as shading and reduced nutrient concentrations can pave the way for top-down control of phytoplankton even by a relatively moderate population of filter-feeders, and that phytoplankton biomass will decrease sharply beyond a critical macrophyte (or grazer) density. Indeed such a discontinuous response is observed in field experiments. Also, the idea that filter feeding cladocerans such as Daphniaplay a key role is in line with the observation that brackish lakes where Daphniadoes not thrive tend to be turbid despite the often dense weed beds.
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  • 103
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    Hydrobiologia 408-409 (1999), S. 389-394 
    ISSN: 1573-5117
    Keywords: mictic type ; water transparency ; nitrogen ; phosphorus ; chlorophyll:nutrient ratio ; chlorophyll:seston ratio
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Data for comparison are from 17 dimictic and four polymictic lakes interconnected to form a system of the Great Masurian Lakes. Both summer epilimnetic total phosphorus and chlorophyll were higher in dimictic than in polymictic lakes. Chlorophyll was probably not limited either by phosphorus or by nitrogen in shallow lakes. Utilization of phosphorus in terms of chlorophyll:particulate phosphorus and chlorophyll:particulate nitrogen ratios was similar in the two groups of lakes. Significant differences were found, however, in the chlorophyll:seston ratio, higher in dimictic lakes. These observations together suggest that seston in shallow lakes contains a significant, though unpredictable contribution of detritus/mineral particles much poorer in phosphorus than those in dimictic lakes. Secchi disc depth was better explained in shallow lakes by seston variability than by chlorophyll. Thus, algal production in shallow masurian lakes seems to be limited by light conditions resulting from resuspension of non-living particles while the production in deep lakes is nutrient (both nitrogen and phosphorus) limited.
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  • 104
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    Hydrobiologia 408-409 (1999), S. 359-365 
    ISSN: 1573-5117
    Keywords: eutrophication ; trends ; lakes ; phosphorus ; nitrogen ; chlorophyll-a ; transparency
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The relation between (inter)national programs aiming at nutrient load reduction and changes in eutrophication has been studied for 231 Dutch lakes over the period 1980–1996. Trends in total-phosphorus (P) and total-nitrogen (N) were negative, as determined by analysis of both individual lakes and the complete data set. The relative trends in the nutrient concentrations as well as in the N/P ratio correspond with the significantly reduced P emission and the limited reduction of N emission in The Netherlands since the beginning of the 1980s. Negative trends in chlorophyll-aand positive trends in Secchi-disc transparency may be partly explained by reduced nutrient concentrations. Perspectives for the nearby future are discussed. Lake characteristics had only a minor impact on the trends. The improvement of the water quality was found for all subsets of average depth, surface area, hydraulic retention time and soil type. Furthermore, the effect of restoration measures and meteorological conditions on the trends were studied. Biomanipulation resulted in an additional improvement of several water quality variables compared to lakes that were only subject to (inter)national programs on nutrient load reduction. Specific measures resulting in additional P load reduction resulted only in lowered P concentrations. Severe winters resulted in lower chlorophyll-aconcentrations in the following summer and dry conditions in spring were favourable for all eutrophication variables in the following summer.
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  • 105
    ISSN: 1573-515X
    Keywords: Chihuahuan desert ; desert ; desertification ; grassland ; nitrogen ; nutrient budgets ; phosphorus ; runoff
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences
    Notes: Abstract Rainfall simulation experiments were performed in areas of semiarid grassland (Bouteloua eriopoda) and arid shrubland (Larrea tridentata) in the Chihuahuan desert of New Mexico. The objective was to compare the runoff of nitrogen (N) and phosphorus (P) from these habitats to assess whether losses of soil nutrients are associated with the invasion of grasslands by shrubs. Runoff losses from grass- and shrub-dominated plots were similar, and much less than from bare plots located in the shrubland. Weighted average concentrations of total dissolved N compounds in runoff were greatest in the grassland (1.72 mg/l) and lowest in bare plots in the shrubland (0.55 mg/l). More than half of the N transported in runoff was carried in dissolved organic compounds. In grassland and shrub plots, the total N loss was highly correlated to the total volume of discharge. We estimate that the total annual loss of N in runoff is 0.25 kg/ha/yr in grasslands and 0.43 kg/ha/yr in shrublands – consistent with the depletion of soil N during desertification of these habitats. Losses of P from both habitats were very small.
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  • 106
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    Environmental monitoring and assessment 58 (1999), S. 151-172 
    ISSN: 1573-2959
    Keywords: GIS ; ground water vulnerability ; leaching index ; nitrate ; pesticide ; phosphorus ; potassium ; statistical analysis ; uncertainty
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Statistical methods and a Geographic Information System (GIS) were used to investigate potential indicators of ground water vulnerability to agricultural chemical contamination in a representative area of the Mississippi River alluvial aquifer. A total of 47 wells were sampled for analysis of nitrate, phosphorus, potassium, and 13 pesticides commonly-used in the area. Ten soil and hydrogeologic variables and five ground water vulnerability indices were examined to explain the variations of chemical concentrations. The results showed that no individual soil or hydrogeologic variables or their linear combinations could explain more than 25% of the variation of the chemical concentrations. A quadratic response surface model with the values of confining unit thickness, slope, soil permeability, depth to ground water, and recharge rate accounted for 62% of the variation of nitrate, 43% of P, and 83% of K, suggesting that the interactions among soil and hydrogeologic variables were significant. Observed trends of decreasing nitrate and P concentrations with increasing well depth and/or depth to ground water seemed to correlate with carbonate equilibrium in the aquifer and more reduced environment with depth. In view of uncertainties involved, it was recognized that the limitations associated with input data resolution used in GIS and the formulation of leaching indices limited their use for predicting ground water vulnerability. Misuse of pesticides could be another factor that would complicate the relationships between pesticide concentrations and the vulnerability indices.
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  • 107
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    Reaction kinetics and catalysis letters 66 (1999), S. 177-181 
    ISSN: 1588-2837
    Keywords: Silica ; surface ; phosphorus
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The interaction of gaseous PCl3 and POCl3 with dried and wetted pyrogenic silica has been studied by IR spectroscopy. The acceleration of the chemisorption accompanied by the formation of Si−O−P bonds in the presence of water vapor has been observed only with phosphorus trichloride.
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  • 108
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    Reaction kinetics and catalysis letters 66 (1999), S. 257-263 
    ISSN: 1588-2837
    Keywords: Alkylation ; toluene ; ZSM-5 ; phosphorus ; chromium ; nickel
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract H-ZSM-5 zeolite was modified with phosphorus. The obtained P/ZSM-5 catalyst was subjected to further treatments with chromium and nickel. The distribution and strength of different acid sites of zeolites were investigated by means of temperature-programmed desorption of ammonia. The active and strong acid sites were confirmed by measuring the rate constants for cracking ofn-hexane, as a probe molecule. Reduction of pore opening size of the modified ZSM-5 was monitored by a standard test reaction of probe molecules ofm-xylene and ethylbenzene. Selective alkylation of toluene with methanol top-xylene was studied over ZSM-5 and modified zeolite catalysts. The P/ZSM-5 zeolite was the most selective catalyst top-xylene but the toluene conversion decreased drastically. The addition of chromium to P/ZSM-5 zeolite increased the toluene conversion and the yield ofp-xylene was very close to P/ZSM-5 catalyst. The addition of nickel did not exhibit a significant improvement of the catalyst performance. The deactivation of catalysts, due to coke deposition during run, was also considered. P/ZSM-5 zeolite showed the lowest stability with time on stream. The addition of chromium and nickel to P/ZSM-5 zeolite increased the stability of the catalyst.
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  • 109
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    Water, air & soil pollution 111 (1999), S. 1-18 
    ISSN: 1573-2932
    Keywords: biodegradation ; hydrocarbon ; nitrogen ; nutrient ratios ; phosphorus ; soils
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The biodegradation of hexadecane (C as hexadecane-C) was assessed under 34 different external nitrogen (N supplied as NO3-N) and phosphorus (P supplied as PO4-3-P) supply conditions in order to determine how different nutrient formulations affected nutrient limitation conditions during degradation. CO2 production yields indicated that shifts in N and P supply levels resulted in variable biodegradation responses due to shifts in the limiting-nutrient (e.g., from N to P). For example, the estimated maximum fractional CO2 yield ratio was 0.24 (mg CO2-C produced mg-1 hexadecane-C) for P-limited nutrient formulations (P:hexadecane-C〈0.01), whereas the yield ratio was more than two times greater when the system was not P- limited. Similar effects were observed for N-limited (N:hexadecane- C〈0.15) versus non-N-limited formulations. The relative bioavailability of natural soil-N and soil-P also was examined. In the soil studied, background soil-N was 96.3% organic-N and was found to be largely nonbioavailable. In contrast, high CO2 yields were observed even when no external P was supplied. An iterative mathematical procedure indicated that the Olsen soil-P subfraction (inorganic soil-P plus soluble organic soil- P) best approximated bioavailable soil-P for this soil. Our results indicate that both N and P additions affect biodegradation yields, but that stoichiometrically inappropriate nutrient mixes produce suboptimal CO2 yields. We also found that the bioavailable fractions of soil-N and soil-P should be incorporated into estimating the most suitable nutrient formulations for a given contamination scenario.
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  • 110
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    Water, air & soil pollution 109 (1999), S. 303-312 
    ISSN: 1573-2932
    Keywords: adsorption ; citrus ; fractionation ; leaching ; phosphorus ; Spodosol
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The retention and transport of P by three horizon samples (A, E, and Bh) of a Spososol (Oldsmar sand: sandy, silicious, hyperthermic Alfic Arenic Haplaquods) were evaluated using a batch-equilibration and leaching column techniques with application of P in rates equivalent to 25 and 100 kg P ha-1. Adsorption coefficient (K) values followed the order: Bh 〉 A 〉 E. Adsorption of P by the E horizon soil sample was negligible (M = 4 μg g-1 soil) as compared to that of either A or Bh horizon samples, e.g., 303 and 479 μg g-1, respectively. The leaching column study with application of P equivalent to 100 kg ha-1 showed 39, 68, and 98% of applied P were leached from the Bh, A, and E horizons, respectively, with eight pore volumes of leachate. Elution curves showed the peak P elution at the second pore volume (equivalent to 3.7 cm of water addition). After leaching with eight pore volumes, the residual P in the soil was present primarily in non-occluded Fe and Al-P forms in the A and Bh horizons.
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  • 111
    ISSN: 1572-879X
    Keywords: selective catalytic reduction ; nitric oxide reduction ; phosphorus ; acid property
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract To examine the influence of phosphorus on the commercial V2O5(WO3)/TiO2 SCR catalyst, measurements were carried out by means of infrared and Raman spectroscopy, XPS, and NO reduction measurement as a function of phosphorus loading. Phosphorus added to the catalyst was found to disperse well over the catalyst without a significant agglomeration up to 5 wt% P2O5 addition. The number of the hydroxyl groups bonded to the vanadium and titanium species decreased readily with increasing amount of phosphorus. Correspondingly, the hydroxyl groups bonded to the phosphorus species were formed. NH3 adsorbed on both hydroxyl groups bonded to vanadium and phosphorus as ammonium ions, implying that the P–OH groups formed are also responsible for the Brønsted acidity. The NO reduction activity was found to be decreased with increasing amount of phosphorus; however, the influence of phosphorus was relatively small irrespective of the large amount of phosphorus addition. The deactivation might be caused by the change in the nature of the surface hydroxyl groups as Brønsted acid sites. Phosphorus species might partially wrap the surface V=O and W=O groups, which might also contribute to the deactivation.
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  • 112
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    Journal of paleolimnology 20 (1998), S. 47-55 
    ISSN: 1573-0417
    Keywords: diatoms ; spatial variability ; canonical correspondence analysis ; lake eutrophication ; transfer functions ; phosphorus
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract Diatom analyses were undertaken of sediment cores covering a range of water depths in a small eutrophic lake (Lough Augher, Co. Tyrone, N. Ireland). The significance of between-core variability in diatom relative frequency stratigraphy was assessed by Canonical Correspondence Analysis (CCA) where the ordination axes were constrained to external environmental variables (sediment depth, core location coordinates, water depth, effective fetch, distance-from-shore and distance-from-inflow). After the removal of the effect of sediment age by partialling it out, the resultant first two axes from the partial-CCA were significantly correlated with water depth and distance-from-shore, indicating non-uniform diatom stratigraphies across the lake. Despite this variability, all cores show the same succession of species and, therefore, record the eutrophication of the lake. Diatom-inferred total phosphorus (DI-TP) was inferred for six cores using weighted averaging regression and calibration. Apart from considerable differences of DI-TP in surficial sediment samples, there was good between-core repeatability of DI-TP profiles. These data support the use of DI-TP for establishing background nutrient concentrations for lakes, and associated implications for lake restoration schemes using single cores. Comparisons of DI-TP profiles and total diatom accumulation rate data for the individual cores indicate that diatom production peaked prior to the maximum TP concentrations in the lake.
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  • 113
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    Journal of paleolimnology 20 (1998), S. 31-46 
    ISSN: 1573-0417
    Keywords: phosphorus ; Lake Okeechobee ; lead-210 dating ; eutrophication ; phosphorus loading
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract Phosphorus accumulation rates in depositional zone sediments of Lake Okeechobee were determined in 11 mud-zone cores and two peat-zone cores dated by 210Pb. Although difficulties were encountered in interpreting 210Pb data from some sites, reliable dating of sediments from the mud zone of this shallow lake is possible. Sediment accumulation rates in this zone have increased during the present century by an average of about twofold, and accumulation of organic sediments in the lake during pre-settlement times apparently was much slower than during the past century. Concentrations of all forms of sedimentary P but especially nonapatite inorganic-P and organic-P also have increased since pre-settlement times and especially since about 1940. Annual P accumulation rates in the lake's sediments have increased about fourfold during the 1900s, with most of the increase occurring in the past 40–50 years. The recent accumulation rate of sedimentary P (past ~ 10 years) agrees within a factor of 1.5 with the net retention of P in the lake calculated from published input-output mass balances.
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  • 114
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    Nutrient cycling in agroecosystems 50 (1998), S. 321-324 
    ISSN: 1573-0867
    Keywords: nutrient modelling ; leaching ; nitrogen ; phosphorus ; schematization
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract In context of preparing the Fourth National Policy Document on Water Management in the Netherlands effects of different scenarios of fertilizer management on nitrogen (N) and phosphorus (P) leaching from rural areas into Dutch surface waters were analyzed. The manuscript offers insight into the model instrument that is used to simulate the different scenarios. Main parts of the modelinstrument are: a procedure to schematize the Netherlands in horizontal areal units, field scale mechanistic models for water and nutrient behaviour in the soil and an empirical model for fertilizer additions.
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  • 115
    ISSN: 1573-0867
    Keywords: agriculture ; catchment ; fertilizer ; historical ; manure ; nitrate ; phosphorus
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract A suggested increase in the growth of macrophytic algae within the Ythan estuary (N.E. Scotland) over recent years has been linked to the increased amounts of nitrogen in the form of NO3–N entering the estuary from the river. The increased NO3 concentration in the river has been associated with recent changes in farming practices in this predominantly agricultural catchment. Terrestrially derived phosphorus is also considered to contribute increasingly to eutrophication of fresh waters. Historical agricultural census data together with appropriate surveys of fertilizer practice were used to calculate the total quantities of fertilizer and manure derived N and P applied annually over the wholeYthan catchment during the period 1960 – 1990. While the total agricultural land area has remained similar, significant changes in cropping practice have occurred. In particular, a greater proportion of land is given to autumn sown crops while the area of grassland has declined. These changes in farming practice are associated with differences in both the total amounts and timing of fertilizer applied. The use of inorganic N in the catchment has trebled since 1960 and is currently approximately 6400 tonnes (104 kg N/ha). The use of P has decreased by more than a quarter to 1274 tonnes (21 kg P/ha) over a similar time period. There has been no obvious change in total quantity of N and P derived from animal manures, estimated to be 44 and 11 kg per ha, respectively, when averaged over the area of agricultural land. Cattle and sheep numbers have remained relatively constant and together account for approximately 80% of the manure N and 70% of the manure P produced annually. However, poultry have declined by 70% since 1960 while pig numbers have increased six-fold. The average annual application rate of manure derived N over the whole catchment (44 kg/ha) is considerably below that proposed at the farm scale in the EC Nitrate Directive (210–170 kg/ha). However, on a local scale difficulties may arise for large manure producing concerns such as dairy or pig units.
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  • 116
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    Mangroves and salt marshes 2 (1998), S. 37-42 
    ISSN: 1572-977X
    Keywords: mangrove ; phosphorus ; distribution ; dynamics ; exportation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The distribution and dynamics of phosphorus have been studied in the mangroves of Sepetiba Bay, Brazil. Leaf fall contributes 3.0 kg P ha=1yr=1to the sediment. The total above ground biomass of the R. mangle stand was about 65.3 t ha=1, the P accumulation was 3.9 kg P ha=1where 63% of the total P-biomass was accumulated in the leaves. The biomass of below ground roots was about 8.2 tha=1 and accumulated 16% of total P-biomass. Sediment contained 452 kg P ha=1 where P combined with calcium (P-Ca) was the main fraction (260 kg ha=1). The annual flux of P as litter fall was small (〈 1%) compared to total P in the sediment reservoir. The annual export of P by macrodetritus corresponds to 0.05% of the total sediment reservoir.
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  • 117
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    Aquatic ecology 32 (1998), S. 261-279 
    ISSN: 1573-5125
    Keywords: phosphorus ; fatty acid ; growth ; life history ; food limitation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Evidence suggests that marine and freshwater zooplankton generally experience food levels above subsistence values in terms of carbon. However, the quality of this food may be poor due to an insufficiency of other essential nutrients. In this review, we examine recent progress in three main areas of food quality research: (1) elemental (especially P) limitation, (2) digestion resistance, and (3) biochemical (especially fatty acids) limitation. We evaluate laboratory and field evidence in each of these areas, look at new evidence about the life history implications of the elemental limitation hypothesis, and suggest future avenues for research. From a rather large number of seemingly heterogeneous studies, a single consistent picture of food quality emerges: both P and essential fatty acids are predicted to be important dietary factors, but at different places and times. Nevertheless, despite an abundance of valuable laboratory studies, our knowledge of food quality limitation in the field is still poor.
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  • 118
    ISSN: 1573-5117
    Keywords: phosphorus ; nitrate ; silicon ; streams ; English Lake District
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Concentrations of soluble reactive phosphorus (SRP), nitrate, and soluble reactive silicon (SRSi) were monitored in 12 streams draining small catchments (〈10 km2) in the English Lake District. The catchments varied with respect to underlying geology, soil type and land cover. Average concentrations of SRP were in the range 0.5–11.2 μg P l-1, and estimated loads ranged from 0.01 to 0.14 kg P ha-1 a-1. The higher concentrations and loads were associated with catchments containing improved pasture. Mean streamwater concentrations of nitrate varied from 55 to 660 μg N l-1, while loads were in the range 0.8–9.6 kg N ha-1 a-1; no general dependence on catchment properties was discerned. Concentrations of SRSi were similar in all the streams (0.8–2 mg Si l-1), and annual loads were in the range 10–26 kg Si ha-1 a-1. Loads of all three nutrients were greatest during the winter, because of higher discharges, but in some catchments containing improved pasture, considerable transport of P also took place during the summer. Concentrations of nitrate in streams draining unimproved moorland catchments are approximately twice those reported for samples taken from similar streams in 1973 and 1974, possibly because of increased atmospheric deposition of inorganic nitrogen (ammonium and nitrate). Concentrations of SRP in such streams were similar to those reported for the earlier samples. Comparisons of stream loads of SRP and nitrate with estimated inputs suggest that catchment soils retain substantial amounts of these nutrients. Implications for surface water eutrophication of changes in P retention by soils are discussed.
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  • 119
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    Hydrobiologia 373-374 (1998), S. 21-25 
    ISSN: 1573-5117
    Keywords: internal loading ; phosphorus ; fractionation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Lake sediments play an important role in the phosphorus metabolism in lakes. The impact depends on the tendencies to retain and to release phosphorus.The internal loading will often determine the eutrophication status of the lake and the time lag for recovery after reduction of the external loading. Internal loading is most important during the summer. The potential source of phosphorus in the surficial sediments is very large in comparison to the pools in the water column. This means that even if only a very small amount is released, it will have significant impact on the phosphorus concentration in the lake water. The distribution of phosphorus forms in sediments have been investigated since the 1950s. Generally, vertical profiles of sediment phosphorus content, expressed on dry weight basis, show an increasing total content towards the sediment surface. The vertical profile continues up into the water when looking at the particulate matter. A number of environmental factors are important in the mobilisation processes. Most studies indicate that sediment bacteria have a significant role in uptake, storage and release of phosphorus including anaerobic release of iron-bound phosphorus. Several phytoplankton species have resting stages overwintering on the sediment. When growth is induced, they leave their habitat in order to shift their life-form to a pelagic one. In Lake Erken the cyanobacteria Gloeotrichia echinulata has been shown to contribute significantly to the internal loading of phosphorus during the summer.
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  • 120
    ISSN: 1573-5117
    Keywords: Nitrogen ; phosphorus ; catchment ; water quality ; river ; discharges
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Influences of urban and agricultural activities on river water quality were analysed on the upper catchment of the River Vilaine (902 km2), France. Agricultural land covered 78% of the study area. Corn, grass and cereals were the main crops. Total Nitrogen (TN) and Total Phosphorus (TP) loads were determined for individual subcatchments (from 10 to 194 km2) during the hydrological year 1994/95. Relationships between water quality and catchment management were studied. Non-point source produced 95% of TN and 90% of TP of the whole river basin. Significant variation in TN and TP occurred, in time and space. The greatest part was discharged in January and February. Annual river exportation rates ranged from 20 to 65 kg TN ha-1 and from 1.15 to 3.05 kg TP ha-1. Reservoirs will held almost 15% of TN and TP loads. Cyanobacteria blooms occurred in summer and autumn, with significant production of organic matter here, and downstream, in the rivers. Greatest TP river retention rate were determined downstream a town of 15000 people, and highest TN loss occurred in the subcatchment with the highest density of cattle and the most important percent of permanent grassland.
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  • 121
    ISSN: 1573-5117
    Keywords: phytoplankton ; trophic status ; phosphorus ; eutrophication ; species composition
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The paper reports the impact of a sharp artificial enrichment of the available phosphorus in a small, acidic and oligotrophic corrie lake and its effects upon the phytoplankton supported. Annual average chlorophyll increased tenfold within two years, from ∼ 1.2 to 12.6 µg chl a l-1, but the species represented by large populations are the same as previously. Chrysophyte species, however, make up a smaller fraction of the total crop.
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  • 122
    ISSN: 1573-5117
    Keywords: algal biomass development ; vertical distribution ; substrata-dependent variation in regulation ; irradiance ; invertebrate grazing ; phosphorus
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The vertical distribution of algal biomass in the bed sediment and the seasonal development of benthic algae on stones and fine-grained sediments were studied in a small unshaded stream. In addition, field experiments were conducted on the role of irradiance and phosphorus in regulating algal biomass. We found that algal biomass was high at a sediment depth of ten centimetres. Comparison of studies on algal biomass where different depths of the sediment are used should therefore be made with caution. Substrata-dependent differences in algal biomass development were substantial. While algal biomass development on stones was controlled by macroinvertebrate grazing, that on the fine-grained sediment followed the dynamics of incident irradiance, but was attenuated by sediment rebedding. Because of the high grazing pressure on algal biomass on stony substrata, no significant response to phosphorus enrichment was attained. In contrast, algal biomass development on fine-grained sediments was phosphorus-limited. Heavy shading of the fine-grained sediments did not significantly affect algal biomass development, thus suggesting that phosphorus limitation prevents algae from fully utilizing the light resource in this stream.
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  • 123
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    Wetlands ecology and management 6 (1998), S. 121-132 
    ISSN: 1572-9834
    Keywords: Lake Agmon ; Lake Hula ; Lake Kinneret ; phosphorus ; water quality
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Sixty km2 of the southern Hula Valley (northern Israel) peat lands were flooded in 1994 as part of the Hula Valley Restoration Project. The small, shallow lake (110 ha, mean depth 〈 1 m) and network of ca. 90 km of canals created were designed to ameliorate problems (e.g., underground fires, soil subsidence, increased nutrient loading downstream to Lake Kinneret) resulting from drying the Lake Hula wetlands in the 1950s. This new wetland area now serves as the focus for developing eco-tourism in northern Israel. The initial development of this new ecosystem has been followed closely by a multi-disciplinary team of researchers, with an emphasis on water quality in the new lake and the potential impact of the project on Lake Kinneret. Here we report an overview of developments in general water chemistry of Lake Agmon during its first three years (1994–1996). Water quality in Agmon was within general expectations for a shallow lake situated on peat. The first year of Agmon was characterized by the heavy influence of stream and drainage inflows with high pH, alkalinity, turbidity and electrical conductivity and high concentrations of sulfate and total dissolved solids. By the third year, however, many “in lake” processes (e.g., nutrient cycling and algal and macrophytic production) were well-developed and thus strongly affected lake water quality. Excessive phosphorus and nitrogen concentrations in the lake have led to hypertrophy, characterized by low dissolved oxygen concentrations and prolific blooms of nuisance algae. The management of this new ecosystem in the near future will require persistent, and innovative measures.
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  • 124
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    Plant and soil 198 (1998), S. 185-192 
    ISSN: 1573-5036
    Keywords: colonization ; crop-rotation ; maize ; mycorrhiza ; phosphorus ; tillage
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract We selected three crop production practices; crop rotation, tillage and phosphorus fertilization, all known to affect arbuscular mycorrhiza (AM) development, to study early AM intraradical colonization in maize. Half of the plots were planted during the first year with either a host (maize, Zea mays L.) or a non-host (canola, Brassica napus L.) crop, and all of them with maize for the second year. Tillage and P fertilization treatments were applied to the plots in the second year. Mycorrhiza development in maize was measured in pot culture bioassays conducted before planting and after harvest of the previous and the subsequent crops, and in the field during the second crop season. Previous cropping of a soil with canola (Brassica napus L.), a non-host plant species, delayed mycorrhiza development of maize in a bioassay conducted with that soil in comparison with a previous cropping cycle with maize (Zea mays L.) or with the original plant species in the field site, bromegrass (Bromus inermis Leys.) and alfalfa (Medicago sativa L.). The delay in mycorrhiza development after cropping with canola was also observed in samples taken from the field and in a bioassay, both conducted at the beginning of the subsequent cropping cycle. Tillage had, on average, little effect on intraradical colonization either in the field or in the bioassays. Phosphorus fertilization also had little effect on mycorrhiza development in the field. Crop rotation with a non-host had the strongest effect on intraradical mycorrhiza development of the three practices studied.
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  • 125
    ISSN: 1573-5036
    Keywords: endophyte ; Festuca arundinacea ; Neotyphodium coenophialum ; phenolics ; phosphorus ; root activity ; tall fescue
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Endophyte-infected (E+) tall fescue (Festuca arundinacea Schreb.) plants grown in phosphorus (P) deficient soils accumulate more P in roots and shoots than noninfected isolines. In a growth chamber experiment, four tall fescue genotypes DN2, DN4, DN7, and DN11, infected with their naturally occurring strains of Neotyphodium coenophialum (Morgan-Jones & Gams) Glenn, Bacon & Hanlin, and their noninfected isolines (E-), were cultivated in nutrient solution at two P levels: 31 ppm (P+) and 0 ppm (P-) for 4 wk. The Fe3+ reducing activity of extracellular reductants and intact root tissues, and total phenolic concentration in roots and shoots were measured. Endophyte infection significantly increased Fe3+ reducing activity rate of extracellular reductants (9.6 × 10-3 μmol Fe3+ h-1 g-1 root FW) when compared to E- plants (3.9 × 10-3) and Fe3+ reduction rate of intact root tissues (6.16 and 4.48 μmol Fe3+ h-1 g-1 root FW, respectively for E+ and E- plants). In response to P deficiency, Fe3+ reduction rate of intact root tissues increased in E+ plants by 375% when compared to E- plants, whereas no significant differences were observed when P was provided. Total phenolic concentration was 20% greater in shoots of E+ plants than in E- plants. In response to P deficiency, total phenolic concentration significantly increased in roots of E+ plants by 7%, and decreased in roots of E- plants by 10%. The most active Fe3+ reducing zones were located along branching of secondary and tertiary roots. The Fe3+ reducing activity on the root surface and total phenolic concentration in roots and shoots increased dramatically in response to endophyte infection, especially under P limiting conditions.
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  • 126
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    Plant and soil 203 (1998), S. 269-277 
    ISSN: 1573-5036
    Keywords: fertilization ; pH ; phosphorus ; rice ; sodicity ; sodium
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Rice seedlings transplanted into sodic soil are exposed to an excess of potentially toxic ions as well as nutritional imbalance, both of which adversely affect their growth and yield. The present study was aimed to investigate the beneficial effects of fertilization with phosphorus and potassium on the plants at varying sodicity levels and also the response of genotypes with known variability in their tolerance to sodicity. In pot-house experiments during two seasons, the alleviating effects of P and K fertilization on three rice genotypes were examined at four sodicity levels. Seedlings of CSR13 and Jaya (both moderately tolerant to sodicity), died by 25–35 days after transplanting in sodic soils of pH 9.7–9.9 where Olsen's P was 12.5 and 14.8 kg/ha, respectively. However, there was no problem of survival or growth in these soils when Olsen's P was 17.6 and 20.8 kg/ha. Depletion in P from 12.0 kg to 10 kg resulted in some mortality of the seedlings even at pH 9.1. Sodicity tolerant genotype CSR10, did show some survival and growth even at pH 9.9 with Olsen's P at 14.8 kg/ha (without P fertilization) which suggests that differences in tolerance to sodicity which exist at genotypic level are not masked by low P. None of the three genotypes showed any survival problem at pH 8.0 and 8.1 with Olsen's P at 8.5 and 8.7 kg/ha, respectively. Seedlings in P fertilized sodic soils not only produced significantly more new roots but also higher root biomass than those in unfertilized sodic soils and these roots seem to have some control on Na uptake as reflected by low Na concentration in the shoots. Thus, P fertilization not only improved P and K status of plants but also reduced the concentration of potentially toxic Na ions in shoots, resulting in better survival, growth and yield. Although fertilization with K alone did improve shoot K content, it had no significant effect on reducing Na. So the mortality of the seedlings or grain yield in K fertilized sodic soils was as good as in control and this could be explained on the basis of lack of any significant difference in Na concentrations in shoots between these two treatments.
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  • 127
    ISSN: 1573-5036
    Keywords: grassland ; nitrogen ; nutrient competition ; phosphorus ; plant diversity ; potassium
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Many studies carried out during these last few years have focused on the factors influencing plant diversity in species-rich grasslands. This is due to the fact that these ecosystems, among the most diversified in temperate climates, are extremely threatened; in some areas, they have almost disappeared. The re-establishment of these habitats implies to know the living conditions of the associations to be recreated. Very often, the typical species of these communities have become so rarefied that the seed bank or the seed rain are not sufficient to recreate the plant community. Most of the time, to achieve the restoration of these communities, they have to be totally recreated by sowing. For the restoration or the maintenance of the community, the soil chemical characteristics have also to be appropriate or if not modified. This research tends to establish a relation between some soil chemical factors and the plant diversity of a great number of stations. This research has illuminated the relationship between soil extractable phosphorus and potassium and plant diversity. Over 5 mg of phosphorus per 100 g of dry soil (acetate + EDTA extraction), no station containing more than 20 species per 100 m2 has been found. The highest number of species is found below the optimum content of the soil for plant nutrition (5–8 mg P/100 g). Concerning the potassium, the highest number of species is found at 20 mg/100, a value corresponcing to an optimum content of the soil for plant nutrition. High potassium contents, in opposition to phosphorus contents, are thus compatible with high values of diversity. Other factors (i.e. pH, organic matter, total nitrogen and calcium) do not show so clearly a relation with plant diversity. Excess of N–NO3 is known for its negative effect on the diversity of plant communities. In these environments, apart from the atmospheric deposits which can be important in some areas, N–NO3 is derived mainly from the symbiotic fixation of atmospheric nitrogen by legumes as well as from the mineralization of the organic matter of the soil. It is possible that, when in small quantities, the available soil phosphorus could be a limiting factor of the N–NO3 supply by these two sources. In this hypothesis, nitrogen would remain the main element limitating plant diversity but its availability would be controlled by phosphorus.
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  • 128
    ISSN: 1573-5117
    Keywords: lake ; predictive modelling ; water quality forecasting ; temperature ; phosphorus ; dissolved oxygen
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract In order to assess the efficiency of eutrophication control programs, predictive models are necessary. We propose a methodology for implementing such a model, based on the coupling of a biogeochemical model of a lake and the use of long term time series of meteorological data. This methodology is applied to lake Bourget (Savoie, France). It allows to obtain both mean and standard deviation (first and second order moments) of the state variables of the model on a 1 y period. The sensitivity of the model to the various forcing variables, as well as to the initial conditions is analyzed as well as the linear or non-linear behavior of the model. Finally, the propagation of the uncertainties (standard deviations) in time and space, for both water temperature and dissolved oxygen are assessed.
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  • 129
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    Hydrobiologia 379 (1998), S. 111-122 
    ISSN: 1573-5117
    Keywords: macroinvertebrates ; stormwater ; phosphorus ; multivariate statistics ; marsh ecology ; biological assessment
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract This study evaluated the water quality effects of both untreated and state-of-the-art treated stormwater on a Florida freshwater oligotrophic marsh macroinvertebrate assemblage during 1995–96. Twenty sampling sites were distributed throughout the length of the Savannas State Preserve freshwater marsh. Sites received runoff from natural upland areas or one of two major subdivisions that utilize the Preserve for stormwater disposal. Multivariate and other statistical tests were used to elucidate differences in the macroinvertebrate assemblage, and to identify specific water quality variables that correlated with these differences. Areas of the Preserve that received both treated and untreated stormwater were shown to possess macroinvertebrate assemblages that differed from those of natural areas, with the greatest differences being observed in association with untreated stormwater. Areas that received untreated stormwater had higher levels of pH, phosphorus, and hardness, and lower levels of dissolved oxygen; while only elevated pH and hardness were documented in areas that received treated stormwater. Several species were identified as important factors driving observed macroinvertebrate differences, and the abundances of these species were related to their environmental requirements. Several violations of State water quality and aquatic life rules were documented. On the basis of these results, a multi-agency task force has been convened to address the stormwater pollution.
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  • 130
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    Biogeochemistry 42 (1998), S. 169-187 
    ISSN: 1573-515X
    Keywords: aridisols ; desertification ; erosion ; geostatistics ; Larrea tridentata ; nitrogen ; phosphorus ; Prosopis glandulosa ; soil heterogeneity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences
    Notes: Abstract Geostatistical analyses show that the distribution of soil N, P and K is strongly associated with the presence of shrubs in desert habitats. Shrubs concentrate the biogeochemical cycle of these elements in ‘islands of fertility’ that are localized beneath their canopies, while adjacent barren, intershrub spaces are comparatively devoid of biotic activity. Both physical and biological processes are involved in the formation of shrub islands. Losses of semiarid grassland in favor of invading shrubs initiate these changes in the distribution of soil nutrients, which may promote the further invasion and persistence of shrubs and cause potential feedbacks between desertification and the Earth's climate system.
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  • 131
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    Fish physiology and biochemistry 19 (1998), S. 83-93 
    ISSN: 1573-5168
    Keywords: phosphorus ; diet ; intestinal absorption ; renal excretion ; Atlantic salmon
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Studies were conducted to determine the absorption, excretion and requirement of dietary phosphorus (P) by Atlantic salmon (Salmo salar). Triplicate groups of salmon parr, initial weight 15 ± 0.5±g , were fed, diets containing 4, 5, 6, 7, 8, 9, 11 and 13 mg P and 20 KJ of digestible energy (DE) per±g of diet (dry matter basis, DMB) to satiation for 16 weeks. The basal diet containing 4 mg P g-1 (0.15 mg available P per KJ DE) was supplemented with graded levels of calcium phosphate, Ca(H2PO4)2⋅H2O to formulate the eight experimental diets. The fish were reared in fresh water at a temperature of 15 °C on a 12 h photoperiod. Vertebrae ash increased from 316 to 516 mg g-1 fat-free dry matter with an increase in dietary P content. P requirement was estimated by using a four-parameter sigmoidal equation. The data suggests that a diet of 0.28 mg available P per KJ DE is needed for Atlantic salmon. Phosphate and calcium levels in plasma and bone increased, whereas levels of magnesium and liver cholecalciferol decreased, with an increase in dietary P. Phosphate excretion in urine and apparent availability of P were determined in deficient and replete fish. In deficient fish, the urine phosphate concentration was 0.10 mmol L-1 before feeding and 0.25 mmol l-1 after feeding, whereas in replete fish these concentrations were 1.09 and 5.11 mmol l-1, respectively. The increase in urine phosphate concentration was higher in replete fish than in deficient fish, however, the apparent absorption of P was found to be significantly lower in replete fish than in deficient fish. These results suggest that similarly to terrestrial vertebrates, P homeostasis in Atlantic salmon is controlled by absorption in the intestine, conservation in the kidney and storage in the bones.
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  • 132
    ISSN: 1573-5117
    Keywords: wetlands ; lake ; water quality ; sediment ; nitrogen ; phosphorus ; macrophytes ; nutrient retention
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The role of wetland on water quality of rivers was estimated in a natural lake, Grand-Lieu (5600 ha), discharging to the Loire estuary. Inputs of its two tributaries, budgets and retention within the lake for particulate matter (PM), nitrogen (N) and phosphorus (P) were compared during the inflow period (Oct–May), by an input-output study, in two hydrologically contrasted years, 1993–94 with high inflow (292 106 m3), and 1995–96 with low inflow (76 106 m3). Globally the loads per ha were similar for the two tributaries for the same year, with higher values at the beginning of the flows, and total inputs markedly higher in 1993–94. During this year, average loads for the main tributary were 154 kg ha-1 PM, 40 kg ha-1 total N and 1.35 kg ha-1 total P. In the two tributaries, NO3 represented 80% of total N for the two years, and PO4 65% and 44% of total P. Total inputs, total outputs and storages are highly related to annual inflow, with large differences between elements. The highest change of inputs occur for NO2, PO4 and PM, and the lowest for NH4. Storage and outputs of the lake were also much higher in 1993–94, the most important annual differences concerning P storage, and outputs of PM and all forms of nitrogen except NH4. However, only the retention rate of total P doubled with the high outflow of 1993–94 (40% against 18%), while those of PO4 and NH4 were equivalent (79–72% and 72–66% respectively). In contrast the retention rate of all the other elements was lower with the large flow of 1993–94: 61 against 86% for NO3, 85–90% for NO2, 32–60% for total N, and 14–20% for PM. Globally, this wetland received important discharge of inorganic nitrogen from its catchment area, trapping or converting most of it (62–85%) into organic matter, while it exported a large amount of dissolved and particulate organic nitrogen (16 g m-2 y-1 in 1993–94 and 4.5 in 1995–96), 2.6 and 1.9 times more than it received. The exportation of organic N per m2 and retention of total N (9.9–14.5 g m-2 y-1) represent record values. This seems mainly due to the importance of water flow, juxtaposition of habitats with different degree of closure, plant biomass and resuspended endogenous, organic sediments in exportation. The lake is not able to counterbalance the dramatic increase of agricultural and sewage inputs, that induce its eutrophication and silting up.
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  • 133
    ISSN: 1573-0867
    Keywords: hydrology ; solute transport ; nitrate ; phosphorus ; polypedon scale
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Over application of poultry litter may cause pollution of surface and ground water. Spatial variability in soil characteristics makes predictions difficult. Composting poultry litter could reduce the risk of pollution by creating more stable organic components. Three rates of poultry litter and compost (10 Mg ha-1 litter, 20 Mg ha-1 litter and 10 Mg ha-1 litter combined with 50 Mg ha-1 compost) to three watersheds under pasture. The watersheds were monitored for surface and subsurface flow. Nitrate-N concentrations in subsurface flow did not exceed the U.S. Environmental Protection Agency drinking water standard of 10 mg L-1. Soluble phosphorus concentrations in runoff were high, reaching a maximum of 8.5 mg L-1 under the compost treatment. These concentrations are generally lower than reported on smaller scale studies, which shows the need of studies at the correct scale.
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  • 134
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    Nutrient cycling in agroecosystems 51 (1998), S. 193-200 
    ISSN: 1573-0867
    Keywords: cropping systems ; inorganic fertilizer ; nitrogen ; organic carbon ; phosphorus ; potassium ; rice-wheat
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Three levels of N (40,80,120 kg N ha-1) and P (0,17.5,35 kg P ha-1), and 2 levels of K (0,33 kg K ha-1) were tested for 19 years in rice and wheat crops of a rice-wheat cropping system in a fixed layout of 3×2×2 factorial partially confounded design along with one control and 3 replications. From this trial, data of 7 treatments, i.e. 0-0-0, 40-35-33, 80-35-33, 120-35-33, 120-0-0, 120-35-0 and 120-0-33 kg ha-1 N-P-K respectively were compared for yield trends, changes in response functions, soil organic -C and available N,P,K status. Soil organic - C decreased in unfertilized plots by 62% (over initial value of 0.45%) but increased by 44, 40 and 36% in plots receiving 120-35-33, 120-35-0 and 80-35-33 kg ha-1 N-P-K respectively. Available N was also greatest in these same three treatments. Available soil P increased by about 5 fold in 15 years in treatments supplied with fertilizer P, but no significant change was detected in treatments without P addition. Yields of rice and wheat exhibited linear declining trend in all treatments. The highest rate of decline (89 kg ha-1 year-1 in rice and 175 kg ha-1 year-1 in wheat), however, was found when 120 kg ha-1 N was applied alone. The least rate of decline of 20 kg ha-1 year-1 in rice and 58 kg ha-1 year-1 in wheat was observed when 40-35-33 kg ha-1 N-P-K respectively was applied to both the crops. At currently recommended levels of NPK (120-35-33 kg ha-1), the rate of decline in yields was 25 kg ha-1 year-1 for rice and 62 kg ha-1 year-1 for wheat. Possible causes of these yield declines are discussed.
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  • 135
    ISSN: 1573-0867
    Keywords: durum wheat ; Glomus mosseae ; micronutrients ; nutrient uptake ; phosphorus ; vesicular-arbuscular ; mycorrhiza
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract The effect of the vesicular arbuscularmycorrhizal fungus (VAMF) Glomus mosseae ongrowth, yield and nutrients' uptake of the durum wheatvariety ‘Sifnos’ was investigated in ten differentsoils. Inoculation had a positive effect on tillering,improved plant growth up to 11.6 times and increasedgrain yield up to 5.4 times as compared tonon-inoculated plants. The thousand kernels weight wasimproved by up to 60%. The analysis of shoot tissue ofthe mycorrhizal plants showed that P concentration wasincreased up to 4 fold, while the K, Ca and Mg uptakewas similar for both mycorrhizal and non-mycorrhizalplants. The concentrations of the trace elements Mn,Zn, Fe and Cu were lower in the mycorrhizal plantscompared to that of non-inoculated ones. The P and Mgconcentration of the grains produced by the inoculatedplants was increased while the Ca concentration wasdecreased. The concentration of the heavy metals waseither decreased ( Mn, Fe, Co, Cr, Ni, Pb) or remainedunchanged (Zn, Cu). The colonization in the roots ranged from 23 to 78%.
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    Euphytica 100 (1998), S. 95-100 
    ISSN: 1573-5060
    Keywords: genetic variation ; wheat genotypes ; nitrogen ; phosphorus ; potassium ; breeding ; low-input cultivars
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Nutrient efficiency in wheat is very complex. It includes two major types: nutrient acquisition efficiency and nutrient use efficiency. Various studies on wild, landraces, old, intermediate and new genotypes of cereals showed that the new varieties produced higher grain yields than the old varieties, and were also more efficient at using nutrients. Several spring wheat cultivars, representing almost all cultivars of spring wheat, released from the Federal Office for Cultivar Registration, Germany and published in the 'Descriptive List of Cultivars', were used to investigate the interactive effects between genotypes and the use efficiencies of the three macro nutrients N, P and K by the grain and straw. The results obtained in this study indicate that nutrient use efficiency of the single nutrients varies widely within recent cultivars. Some cultivars were identified as being multiple-nutrient use efficient. These are considered low-input cultivars. It appears that a special breeding programme of crop cultivars for low nutrient and stress conditions could be successful. Improved cultivar response to nutrients will help to reduce inputs and hence protect the environment.
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  • 137
    ISSN: 1573-5036
    Keywords: leaf expansion rate ; phosphorus ; phyllochron ; plastochron ; wheat
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract In two simultaneous experiments we examined the effects of phosphorus (P) supply on leaf area development in wheat (Triticum aestivum L.) grown in sand with nutrient solutions. In Experiment 1 we studied leaf emergence, leaf elongation, tiller emergence, shoot growth, and P uptake under four levels of P supply (mM) 0.025 (P1), 0.05 (P2), 0.1 (P3), and 0.5 (P4), and. In Experiment 2 there were two levels of P supply, P1 and P4, and we examined the effects of P on leaf primordia differentiation and leaf emergence. The phyllochron was calculated as the inverse of the rate of leaf emergence calculated from the regression of number of leaf tips (PHY-Ltip), Haun index (PHY-Haun), and as the cumulated thermal time between the emergence of two consecutive leaves (PHYtt). The plastochron was calculated from the inverse of the rate of leaf primordia initiation in the apex. P deficiency delayed the emergence of leaves on the main stem and on the tiller 1. Phosphorus deficiency increased the time from emergence to double ridge and anthesis. The final number of leaves was not affected by P. The effects of P on the value of the phyllochron were attributed to both a reduced rate of leaf primordia initiation, and to a reduced leaf elongation rate. P deficiency delayed or even suppressed the emergence of certain tillers. In this work a phosphorus deficiency that reduced shoot growth by 25% at 44 days after emergence significantly modified the structure of the plants by increasing the value of the phyllochron and delaying tillering. These results suggest that any attempt to simulate leaf area development and growth of wheat plants for P-limited conditions should include the effects of the deficiency on leaf emergence.
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  • 138
    ISSN: 1573-5036
    Keywords: leaf expansion rate ; modelling ; phosphorus ; photosynthesis ; sunflower
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Reductions in leaf area and plant growth as a consequence of phosphorus (P) limitations have been attributed both to direct effects of P shortage on leaf expansion rate and to a reduced production of assimilates required for growth. Canopy assimilation and leaf area expansion are closely interrelated processes. In this work we used experimental and simulation techniques to identify and study their importance in determining leaf area on sunflower (Helianthus annuus L.) growing under P-deficient conditions. Experiment 1 was done outdoors, in Buenos Aires, Argentina, and Experiment 2 in a glasshouse in Wageningen, The Netherlands. In both experiments we studied the effects of soil P addition on leaf appearance, leaf expansion, dry matter accumulation, and leaf photosynthesis of non-water stressed plants grown in pots containing a P-deficient soil. Before sowing the equivalent amounts of 0–600 kg of super phosphate ha-1 were added to the pots. Phosphorus deficiency delayed leaf appearance increasing the value of the phyllochron (PHY) up to 76%, the rate of leaf area expansion during the quasi-linear phase of leaf expansion (LER) was reduced by up to 74%, with respect to high P plants. Phosphorus deficiency reduced by up to 50% the rate of light saturated photosynthesis per unit of leaf area (AMAX) in recently expanded leaves, while at low levels of leaf insertion in the canopy, AMAX was reduced by up to 85%, when compared to that in high P plants. Phosphorus deficiency also reduced the duration of the quasi-linear phase of leaf expansion by up to eight days. The values of LER were related (r = 0.56, P 〈 0.05) to the mean concentration of P in all the leaves (Leaves P%) and not to the concentration of P in the individual leaf where LER was determined (r = 0.22, P 〈 0.4) suggesting that under P deficiency individual leaf expansion was not likely to be regulated by the total P concentration at leaf level. The values of AMAX of individual leaves were related (r = 0.79, P 〈 0.01) to the concentration of total P in the corresponding leaf (Leaf P%). LER showed a hyperbolic relationship with Leaves P% (R2 = 0.94, P 〈 0.01, n = 13) that saturate at 0.14%. AMAX showed a hyperbolic relationship with Leaf P% (R2 = 0.73, P 〈 0.01, n = 53) that saturated with values of Leaf P% higher than 0.22. A morphogenetic model of leaf area development and growth was developed to quantify the effect of assimilate supply at canopy level on total leaf area expansion, and to study the effects of model parameters on the growth of sunflower plants under P-deficient conditions. With this model we identified the existence of direct effects of P deficiency on individual leaf area expansion. However, we calculated that under mild P stress conditions up to 83% of the reduction in the observed leaf area was explained by the particular effects of P% on the rate of leaf appearance, on the duration of the linear period of leaf expansion, and on the value of AMAX. We also calculated that the effects of P deficiency on the value of AMAX alone, explained up to 41% of the observed reductions in total leaf area between the highest and the intermediate P level in Experiment 2. Possible mechanisms of action of the direct effects of P on individual leaf expansion are discussed in this paper.
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  • 139
    ISSN: 1573-5036
    Keywords: acid soils ; endophyte ; ergot alkaloids ; Festuca arundinacea ; Neotyphodium coenophialum ; phosphorus ; tall fescue
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Tall fescue (Festuca arundinacea Schreb.) plants infected by the fungal endophyte Neotyphodium coenophialum (Morgan-Jones & Gams) (Glenn et al., 1996) often perform better than noninfected plants, especially in marginal resource environments. There is a lack of information about endophyte related effects on the rhizosphere of grasses. In a greenhouse experiment, four endophyte-infected (E+) tall fescue clones (DN2, DN4, DN7, DN11) and their endophyte-free (E−) forms were grown in limed (pH 6.3) Porter soil (low fertility, acidic, high aluminum and low phosphorus content, coarse-loamy mixed mesic Umbric Dystrochrept) at three soil P levels (17, 50, and 96 mg P kg-1 soil) for five months. Excluding the genotype effect, endophyte infection significantly increased cumulative herbage DM yield by 8% at 17 mg P kg-1 soil but reduced cumulative herbage DM yield by 12% at 96 mg P kg-1 soil. With increased P availability in the soil, shoot and root DM, and root/shoot ratio in E+ plants were significantly less when compared to E− plants. Endophyte infection increased specific root length at 17 and 50 mg P kg-1soil. At soil P level of 17 mg P kg-1soil, E+ plants had significantly higher P concentrations both in roots and shoots. Similar relationships were found for Mg and Ca. E+ plants had significantly higher Zn, Fe, and Al concentration in roots, and lower Mn and Al concentration in shoots when compared to E− plants. Ergot alkaloid concentration and content in shoot of E+ plants increased with increasing P availability in the soil from 17 to 50 mg P kg-1 but declined again at 96 mg P kg-1 soil. Ergot alkaloid accumulation in roots increased linearly with P availability in the soil. Results suggest that endophyte infection affects uptake of phosphorus and other mineral nutrients and may benefit tall fescue grown on P-deficient soils. Phosphorus seems also to be involved in ergot alkaloid accumulation in endophyte-infected tall fescue.
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  • 140
    ISSN: 1573-5036
    Keywords: carbon ; cultivation ; deforestation ; nitrogen ; phosphorus ; tropics
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract The study area, within the Simlipal National Park, India, provides a rare variety of soil sampling sites. These include virgin forests in the proximity of several cultivated areas (where no chemical fertilizers or any modern technology has been used and where periods of cultivation vary from 5 to a little over 100 yr); samples from evergreen forests, deciduous forests and natural grasslands could also be obtained. The availability of numerous such samples made it possible to use statistical methods to evaluate the changes. This study showed that deforestation and cultivation result in statistically significant (P0.05) reduction in organic C, total N and C:N ratios but no significant changes in total and available P levels; C:P and N:P ratios are also reduced. Loss of organic C and N occurs rapidly in the first 15 yr of cultivation and reaches quasi-steady state values around 1–2% organic C and 0.1–0.2% total N; extent of reduction is not related to initial levels. Significant reduction in C:N, C:P ratios following cultivation suggest that mineralisation losses of C are higher than loss of N whereas loss of P is lowest. Lack of significant correlation between organic C and P levels in all types of soils, suggests that the bulk of the P is in the inorganic form. Highest levels of organic C and N were observed in evergreen forests followed by deciduous forests, grasslands and cultivated areas in that order; total and available P levels, however, showed no significant differences. Evergreen vegetative cover appears to provide the ideal environment for organic matter accumulation.
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  • 141
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    Plant and soil 199 (1998), S. 177-186 
    ISSN: 1573-5036
    Keywords: colonization ; crop rotation ; harvest index ; maize ; mycorrhizae ; phosphorus ; tillage ; yield
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract We conducted a field experiment to test the hypothesis that improved phosphorus nutrition occurs in maize plants with rapid arbuscular (AM) mycorrhizae development at early developmental stages and that this also is reflected in dry matter allocation and final yield. A split-split plot design was used with previous crop (Zea mays L.-maize and Brassica napus L.-canola), tillage practices (no-tillage or conventional tillage) and P fertilization (5 levels) as factors chosen to modify mycorrhizae development at early developmental stages of maize. Previous cropping with canola resulted in decreased shoot-P concentration and shoot growth of maize at early stages. No-tillage resulted in higher shoot-P concentration but lower shoot weight than conventional tillage. Greater shoot-P uptake was related to a rapid intraradical development of mycorrhizae (previous crop of maize) or rapid connection to a mycorrhizal mycelium network (no-tillage treatments). Maize yield and harvest index were lower after cropping with canola. The yield for conventional tillage was higher than that for no-tillage but the harvest index was lower. The hypothesis was supported at early stages of maize growth by the effect of previous crop but not by results of tillage, because an unknown factor reduced growth in the no-tillage system. The hypothesis was supported at maturity by increased biomass allocation to grain relative to total shoot weight in treatments with greater shoot-P concentration at early stages.
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  • 142
    ISSN: 1573-5036
    Keywords: leaf expansion rate ; modelling ; phosphorus ; photosynthesis ; phyllochron ; wheat
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Under phosphorus deficiency reductions in plant leaf area have been attributed to both direct effects of P on the individual leaf expansion rate and to a reduced availability of assimilates for leaf growth. In this work we use experimental and simulation techniques to identify and quantify these processes in wheat plants growing under P-deficient conditions. In a glasshouse experiment we studied the effects of soil P addition (0–138 kg P2O5 ha-1) on tillering, leaf emergence, leaf expansion, plant growth, and leaf photosynthesis of wheat plants (cv. INTA Oasis) that were not water stressed. Plants were grown in pots containing a P-deficient (3 mg P g-1 soil) sandy soil. Sowing and pots were arranged to simulate a crop stand of 173 plants m-2. Experimental results were integrated in a simulation model to study the relative importance of each process in determining the plant leaf area during vegetative stages of wheat. Phosphorus deficiency significantly reduced plant leaf area and dry weight production. Under P-deficient conditions the phyllochron (PHY) was increased up to a 32%, compared to that of high-P plants. In low-P plants the rate of individual leaf area expansion during the quasi-linear phase of leaf expansion (LER) was significantly reduced. The effect of P deficiency on LER was the main determinant of the final size of the individual leaves. In recently expanded leaves phosphorus deficiency reduced the photosynthesis rate per unit leaf area at high radiation (AMAX), up to 57%. Relative values of AMAX showed an hyperbolic relationship with leaf P% saturating at 0.27%. Relative values of the tillering rate showed an hyperbolic relationship with the shoot P% saturating at values above 0.38%. The value of LER was not related to the concentration of P in leaves or shoots. A morphogenetic model of leaf area development and growth was developed to quantify the effect of assimilate supply at canopy level on total leaf area expansion, and to study the sensitivity of different model variables to changes in model parameters. Simulation results indicated that under mild P stress conditions up to 80% of the observed reduction in plant leaf area was due to the effects of P deficiency on leaf emergence and tillering. Under extreme P-deficient conditions the simulation model failed to explain the experimental results indicating that other factors not taken into account by the model, i.e. direct effects of P on leaf expansion, must have been active. Possible mechanisms of action of the direct effects of P on individual leaf expansion are discussed in this work.
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  • 143
    ISSN: 1573-5117
    Keywords: Microcosms ; Salton Sea ; saline lakes ; microcosms ; salinity ; ionic composition ; oxygen ; pH ; nutrients ; nitrogen ; phosphorus ; silicon ; fish ; grazing ; Oreochromis mossambicus ; Gammarus mucronatus ; Artemia
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract A 15 month long experiment was undertaken to document responses of the Salton Sea biota to experimentally manipulated salinity levels (30, 39, 48, 57, and 65 g l-1) in 312-liter fiberglass tanks maintained outdoors. At two salinities (39 and 57 g l-1) microcosms were set up each having one small tilapia ( Oreochromis mossambicus) in order to assess its influence on the system. To 28 tanks filled with Salton Sea water diluted to 30 g l-1, different salts (NaCl, Na2SO_4, MgSO4 · 7H2O, KCl) were added in constant proportions to produce the desired salinity levels. Salton Sea shoreline sediment was added to the bottom of each tank, and inocula of algae and invertebrates were added on several occasions. Invertebrate populations, phytoplankton, periphyton, and water chemistry were monitored at regular intervals. This article present the results concerning water chemistry and nutrient cycling. There was no apparent increase in salinity over time, though ∼ 1190 l of tapwater with a salinity of ∼ 0.65 g l-1 were added to each tank during the experiment. Ionic composition varied both among treatments and over time to some degree. Ca2 concentrations were the same at all salinities, while K1 concentrations were 〉3 times greater at the highest salinity than at the lowest. pH showed little consistent variation among salinities until the last few months when it was higher by ∼ 0.4 units at the two higher salinities than at the lower ones; it was unaffected by fish. Absolute oxygen concentrations were negatively correlated with salinity, and occasionally depressed by the presence of fish. PO3-4, dissolved organic phosphorus, and particulate phosphorus concentrations were often reduced by 30–80% at 65 g l-1 relative to lower salinities and by the presence of fish. Early in the experiment NO2-3 concentrations were 〉2 times higher at 57 and 65 g l-1 than at lower salinities, but otherwise effects of salinity on dissolved forms of nitrogen were not marked; particulate nitrogen was much lower at 65 g l-1 than at other salinities and also was reduced by up to 90% by the presence of fish. Silica concentrations increased over time at all salinities, but, relative to those at lower salinities, were reduced by 60–90% at 65 g l-1 by abundant periphytic diatoms. The TN:TP ratio (molar basis) was 24–30 initially and 35–110 at the end of the experiment; it was positively correlated with salinity and the presence of fish. Mechanisms accounting for the above patterns involve principally the biological activities of phytoplankton and periphyton, as modified by grazing by Artemia franciscana and Gammarus mucronatus, and the feeding and metabolic activities of the tilapia. The large reduction in water column TN and TP levels brought about by the fast-growing, phyto- and zooplanktivorous tilapia suggest that amelioration of the Salton Sea's hypereutrophic state might be assisted by a large scale, sustained yield fish harvesting operation.
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  • 144
    ISSN: 1573-5117
    Keywords: Habrotrocha rosa ; nitrogen ; phosphorus ; population dynamics ; predation ; rotifers ; Sarracenia purpurea
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The population growth and biomass production of the pitcher-plant (Sarracenia purpurea L.) inquiline, Habrotocha rosa Donner (Rotifera: Bdelloidea), its consumption by other pitcher-plant inqulines, and its excretion of phosphorus (PO4–P) and nitrogen (NO3–N and NH4–N), were investigated in laboratory experiments. Observed population growth and production rate of H. rosa were higher at pH 4 (2.3 rotifers d-1) than at pH 3 (1.3 rotifers d-1), 5 (1.9 rotifers d-1), or 6 (0.8 rotifers d-1). Populations of H. rosa are an abundant and reliable food source for larvae of the dipteran inqulines Wyeomyia smithii (Coq.) and Blaesoxipha fletcheri (Aldrich) that co-occur with H. rosa in S. purpurea pitchers. Abundance of H. rosa within a pitcher is negatively associated with abundance of dipteran larvae, and these larvae consume rotifers in direct proportion to rotifer density (Type I functional response). Habrotrocha rosa may also account for the majority of the plant's supply of N and P. An average population of rotifers in the field (∼400 per pitcher) can excrete ∼5.2 μg NO3-N, ∼3.91 μg NH4-N, and ∼18.4 μg PO4–P per day into a single leaf, and excretion rate is independent of water pH. Over the six-month growing season of pitcher-plants in Massachusetts, U.S.A., we estimate that rotifers could supply 8.8–43 mg of N and 18.2–88 mg of P. These values far exceed the amount of N and P previously estimated to be supplied annually to the plants through insect capture or rainfall.
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  • 145
    ISSN: 1573-5117
    Keywords: Habrotrocha rosa ; nitrogen ; phosphorus ; population dynamics ; predation ; rotifers ; Sarracenia purpurea
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The population growth and biomass production of the pitcher-plant (Sarracenia purpurea L.) inquiline, Habrotocha rosa Donner (Rotifera: Bdelloidea), its consumption by other pitcher-plant inqulines, and its excretion of phosphorus (PO4–P) and nitrogen (NO3–N and NH4–N), were investigated in laboratory experiments. Observed population growth and production rate of H. rosa were higher at pH 4 (2.3 rotifers d-1) than at pH 3 (1.3 rotifers d-1), 5 (1.9 rotifers d-1), or 6 (0.8 rotifers d-1). Populations of H. rosa are an abundant and reliable food source for larvae of the dipteran inqulines Wyeomyia smithii (Coq.) and Blaesoxipha fletcheri (Aldrich) that co-occur with H. rosa in S. purpurea pitchers. Abundance of H. rosa within a pitcher is negatively associated with abundance of dipteran larvae, and these larvae consume rotifers in direct proportion to rotifer density (Type I functional response). Habrotrocha rosa may also account for the majority of the plant's supply of N and P. An average population of rotifers in the field (∼400 per pitcher) can excrete ∼5.2 μg NO3-N, ∼3.91 μg NH4-N, and ∼18.4 μg PO4–P per day into a single leaf, and excretion rate is independent of water pH. Over the six-month growing season of pitcher-plants in Massachusetts, U.S.A., we estimate that rotifers could supply 8.8–43 mg of N and 18.2–88 mg of P. These values far exceed the amount of N and P previously estimated to be supplied annually to the plants through insect capture or rainfall.
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  • 146
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    Water, air & soil pollution 102 (1998), S. 37-60 
    ISSN: 1573-2932
    Keywords: behavior ; distribution ; Nakdong River ; nitrogen ; phosphorus ; spatial ; temporal
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The concentrations of nitrogen (N) and phosphorous (P) species and relevant hydrographic parameters were determined in main stream and tributary waters of the Nakdong River system during the periods of May through October 1994. During the entire period, the total N (TN) and total P (TP) concentrations in surface waters were found within the ranges of 0.4–7.0 (N=241) and 0.02–1.536 mg L-1 (N=241), respectively. To help derive meaningful interpretations of temporal and geographical variabilities in the nutrient bahavior, the entire data were evaluated for each individual parameter after employing several different grouping schemes. The results of this comparative analysis can be expressed in terms of: (1) high summer/fall ratios for most of nutrient species; and (2) low summer/fall ratios for most of nutrient-to-nutrient ratios and relevant hydrographic parameters. Interestingly, while the former case was found to be more significant in tributary waters than main stream waters, such geographical dependence was not strongly evident for the latter case. A z-statistic test, conducted to check the significance of temporal (between summer and fall) and spatial (between tributary and main stream regions) differences, confirm that the observed variabilities are in most cases strong enough for most of variables studied – nutrient species, their ratios, and relevant hydrographic parameters. In addition, comparison of nutrient species between dissolved and particulate phases reveals several interesting features. Unlike dissolved nutrient species, the concentrations of particulate N or P (PN or PP) exhibited quite extraoridanry behavior. While PN appears to be rather minor component of the total N budget for the Nakdong river, PP seems to make rather strong contributions to its total P budgets with its strong input from tributary waters during rainy summer season. Through an application of correlation analysis, relationships between different parameters were investigated for both before and after the grouping of data sets. The overall picture of this analysis showed that nutrient species were strongly correlated with each other, while the strongest correlations were among such hydrographic parameters as DO, BOD, COD, and conductivity. This analysis was further conducted to more deliberately divided data groups. The results of analyses on these sub-grouped data sets indicate that the occurrences of significant corelations were common from tributary waters relative to main streams for both (1) between different nutrient species and (2) between nutrient and hydrographic parameters. Using the line of evidence gathered from the statistical tests and from the correlation analysis, we conclude that the environmental health of the Nakdong river system is affected by the combined effects of various factors and processes.
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  • 147
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    Water, air & soil pollution 105 (1998), S. 239-250 
    ISSN: 1573-2932
    Keywords: Finland ; forested catchments ; iron ; leaching ; nitrogen ; nutrients ; organic carbon ; peatland ; phosphorus
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract This study provides an assessment of the spatial variability of the long-term leaching of nutrients, total organic carbon (TOC) and iron (Fetot) from 22 forested catchments (0.69-56 km2), distributed across all but the northenmost areas of Finland. The natural, unmanaged Kruunuoja catchment is located in a national park, while the other catchments represent Finnish forestry land. The average leaching of Ptot (4.2 kg km-2 yr-1) from the Kruunuoja catchment was small compared to the catchments representing forestry land (on average 10 kg km-2 yr-1). Moreover, P fertilization was the most important predictor for the spatial variation in Ptot leaching (r2=0.45). Leaching of TOC, Fetot and N compounds was not closely related to forestry practices. Median C/N ratio in the study streams was high (range 34-66). The average inorganic N proportion and leaching of Ptot were lowest in the Kruunuoja catchment (7.3 % and 2.8 kg km-2 yr-1, respectively) and highest in the southernmost Teeressuonoja catchment (54 % and 100 kg km-2 yr-1, respectively) located in the highest N deposition area. The most important forestry practices since the 1960's have affected about 2.4 % of the area of study sites per year (cf. 2% in the entire country in 1991). Moreover, the mean annual runoff from the catchments (230-430 mm yr-1) agrees with the mean annual runoff from Finland (301 mm yr-1). Consequently, the results of the study catchments can be used to estimate average total annual leaching from Finnish forestry land: 2,700 t of Ptot, 48,000 t of Ntot, 110,000 t of Fetot and 1.5 million t of TOC.
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  • 148
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    Water, air & soil pollution 105 (1998), S. 521-538 
    ISSN: 1573-2932
    Keywords: atmosperic deposition ; Long Island Sound ; modeling ; nitrogen ; phosphorus
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Anthropogenic nutrient sources (especially nitrogen and phosphorus) released into the Long Island Sound (LIS) causes excessive phytoplankton growth resulting in hypoxic conditions. Atmospheric deposition (both wet and dry deposition) has significant effect on aquatic and terrestrial ecosystems. Two dry deposition monitoring sites were established along the north shore of LIS in February 1991. Wet and dry deposition samples were collected since then. A dry deposition velocity model, based on the characteristics of the water surface, was used to estimate the loading as well as the seasonal variability (dynamics) of nutrients in atmospheric deposition to LIS. The average nitrogen flux from each site was 6.64 kg (as-N) ha-yr-1. The total atmospheric nitrogen loading was estimated to be 2240 metric tons yr-1 which correcponds to 2.5% of the estimated total nitrogen loading to the Sound from all sources. The average phosphorus flux was 37.44 g (as-P) ha-yr-1. The total atmospheric phosphorus loading to the Sound was estimated to be 12.62 metric tons yr-1. The results show that wet deposition was the predominant source of atmospheric contribution to the Sound.
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  • 149
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    Water, air & soil pollution 102 (1998), S. 361-375 
    ISSN: 1573-2932
    Keywords: alternative on-site wastewatertreatment and disposal systems ; fill material ; low pressuredistribution systems ; minespoil ; nitrogen ; phosphorus ; wastewater renovation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Development of Appalachian coal mining regions of the USA has been severely hampered by lack of domestic waste disposal technologies suited to fills. The suitability of on-site wastewater treatment and disposal systems (OSWTDS) in fill material is uncertain due to the effects of surface mining on soil physical properties. This research was conducted to evaluate the potential for renovation of N and P present in domestic wastewater by fills produced from mining operations. Nitrogen and P were chosen because of their potential adverse environmental impacts. Soil-fill (a mixture of Jefferson, fine-loamy, siliceous, mesic Typic Hapludult and Muskingom, fine-loamy, mixed, mesic Typic Dystrochrept soils) and minespoil (spoil)-fill (blasted rock material associated with the Taggart Marker and Low Splint Bench coal seams of the Upper Middle Wise Formation) were used in this study. Septic tank effluent (STE) and sand filter effluent (SFE) were applied to spoil-fill columns at four loading rates (0, 5.4, 10.8, and 21.6 L m-2d-1) and spoil-fill columns at one loading rate (21.6 L m-2d-1) for a period of 20 wk. Renovation of wastewater was assessed by determining the concentration of N and P present in column leachate. Reduction of inorganic N (NO3 - + NH4 +), based on N/Cl ratios, ranged from 14.9 to 32.1% after the varying application rates of STE and SFE passed through the soil columns. However, leachate NO3 --N concentrations were still above the 10 mg-1 drinking water standard. The quantity of P emerging from the spoil-fill columns (3.0 mg P L-1) was higher than anticipated and may be related to the indigenous P present in the minespoil. Sorption of P in the soil-fill column decreased with increased STE and SFE application (reductions ranged from 99.1 to 74.4%). Results from this study indicate that there is potential for renovating wastewater in OSWTDS in selected soil-fill areas in reclaimed minelands.
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  • 150
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    Water, air & soil pollution 105 (1998), S. 387-397 
    ISSN: 1573-2932
    Keywords: Chesapeake Bay ; Choptank River ; iron ; nitrogen ; phosphorus ; river water chemistry
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The Choptank River basin is a coastal plain catchment dominated by agriculture (52% of land use). We summarize an 11 year data set of discharge and chemistry from a gauged subbasin. Discharge exhibited seasonal variations driven by seasonal evapotranspiration. There were double seasonal maxima of pH, NH4 +, NO3 -, total N, Fe, and total P concentrations in late spring and fall as the saturated zone rose and fell within the soil. Significant interannual variability in discharge was the result of rainfall variation. There were positive nterannual trends in NO3 - concentrations and negative interannual trends in NH4 + and PO4 3- concentrations. These data were combined to estimate N and P export coefficients of 3-11 kg N ha-1 yr-1 and 0.14-0.66 kg P ha-1 yr-1, driven primarily by interannual variations in discharge. These export coefficients are low compared to other coastal plain watersheds dominated by agriculture and may be responsible for the small anthropogenic effects in the Choptank estuary compared to other Chesapeake drainages.
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  • 151
    ISSN: 1573-8264
    Keywords: bacterial isolates ; grasses ; mycorrhizal colonization ; nitrogen ; phosphorus
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The inoculation of mycorrhizal maize plants with three isolates of microaerophilic diazotrophic bacteria obtained from the mycelium of arbuscular mycorrhizal fungi associated with three grasses (Arrhenatherum elatius - bacterial isolate ARR, Agropyrum repens - isolate AGR and Poa annua - isolate POA) caused no increase in nitrogen content in plant biomass. The inoculation with bacterial isolate ARR resulted in the decreased plant growth. Bacterial isolate AGR decreased the percentage of the root length colonized by arbuscular mycorrhizal fungus Glomus fistulosum. The inoculation with both mycorrhizal fungus and isolate POA increased significantly the concentration of phosphorus in plant shoots compared to uninoculated control.
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  • 152
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    Journal of applied electrochemistry 27 (1997), S. 1198-1206 
    ISSN: 1572-8838
    Keywords: alloy ; amorphous ; anomalous ; hydrogen ; iron ; nickel ; phosphorus ; plating
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Electrical Engineering, Measurement and Control Technology
    Notes: Abstract In this study we have investigated the electrodeposition of amorphous iron–nickel–phosphorus alloys from a sulfate electrolyte. Fe-Ni alloys are known to exhibit an ’anomalous‘ type of plating behaviour in which deposition of the less noble metal is favoured. We have found that the codeposition of phosphorus from hypophosphite in the electrolyte led to a reversal to a ’normal‘ behaviour. This reversal was due both to the suppression of iron and enhancement of nickel partial currents. The overall deposition process is dominated by the hydrogen evolution reaction. This is exacerbated by the low pH needed to codeposit sufficient phosphorus to achieve an amorphous structure.
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  • 153
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    Environmental geology 30 (1997), S. 224-230 
    ISSN: 1432-0495
    Keywords: Key words Sediment ; Washington ; DC ; Pollution ; phosphorus ; nutrients
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract  Sediments in the rivers and basins around Washington, DC, have high concentrations of phosphorus, which, based on geographic distributions, is largely derived from urban runoff and municipal sewage. Dissolved-particulate phosphate exchange reactions and biological uptake of dissolved phosphorus from the water column may be an added source of phosphorus to the sediments. Concentrations of total sedimentary phosphorus ranged from 24 to 56 μm P/g-dw, and were highest in areas near combined sewer outfalls. As a part of this study, sedimentary phosphorus was fractionated into Fe-P, Ca-P, Al-P, and organic phases using a selective-sequential leaching procedure. The distribution of the phases in all sediments analyzed follow the order , Fe-P〉Ca-P〉Al-P. Spatial variations in the amounts of phosphorus in the different phases is related to the sources of phosphorus to the area. The proportions of occluded Al-P and organic P are 10–20% of the total P, respectively. This suggests that phosphorus from natural sources is small compared to anthropogenic inputs in this area. The high leachable Fe-P and Ca-P in these sediments might contribute a substantial amount of P to the water column under conditions of remobilization.
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  • 154
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    Environmental and resource economics 10 (1997), S. 341-362 
    ISSN: 1573-1502
    Keywords: Baltic Sea ; eutrophication ; nitrogen ; phosphorus ; cost effective
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Economics
    Notes: Abstract Due to eutrophication caused by heavy loads of nitrogen and phosphorus, the biological conditions of the Baltic Sea have been disturbed: large sea bottom areas without any biological life, low stocks of cods, and toxic blue green algaes. It is recognized that the nitrogen and phosphorus loads to the Baltic Sea must be reduced by 50% in order to restore the sea. The main purpose of this paper is to calculate cost effective nitrogen and phosphorus reductions to the Baltic Sea from the nine countries surrounding the Baltic Sea. The results show a significant difference in minimum costs of decreasing nitrogen and phosphorus loads to the Sea: approximately 12 000 millions of SEK per year and 3 000 millions of SEK respectively for reductions by 50%. It is also shown that a change from a policy of cost-effective nutrient reductions to a policy where each country reduces the nutrient loads by 50% increase total costs for both nitrogen and phosphorus reductions by about 300%. The results are, however, sensitive to several of the underlying assumptions and should therefore be interpreted with much caution.
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  • 155
    ISSN: 1573-2932
    Keywords: phosphorus ; P flux ; microbial activity ; redox ; simulation ; Lake Kinneret ; sediment ; accumulative P release
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Different factors which interactively control the flux of soluble reactive phosphorus (SRP) at the sediment-water interface (SWI) of Lake Kinneret were studied seasonally. The influence of pH, Eh and microbial activity on SRP flux at the SWI was investigated by manipulating the conditions in the overlying water of intact sediment cores. The calculated diffusive SRP flux out of the sediment was lower in cores sampled during winter and spring than during the period of amixis. Potential SRP release, as measured in the absence of microbial activity, was strongly enhanced upon the transition from oxic to anoxic conditions indicating P release from iron(III)-bound phosphorus. In spring and summer cores, an enhanced SRP flux from sediments at pH 7 in comparison to pH 8 indicated P release from carbonate-bound P which sedimented previously as result of high pH values during the algal spring bloom. Microbial uptake at the SWI was the most important sink for SRP and no net-flux occured under oxic conditions. The higher net-flux of P under anoxic conditions was linked to carbon limitation of the bacteria at the SWI.
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  • 156
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    Water, air & soil pollution 99 (1997), S. 457-464 
    ISSN: 1573-2932
    Keywords: sediment ; phosphorus ; fractionation ; release ; humic lake
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Lake Flosek (north-eastern part of Poland) is a small shallow and without outflow lake which has been limed in 1970. The concentration of Ca was increased from 3-4 mg L-1 to 17 mg L-1 in the water and from 0.2-0.3% dry weight to 0.9-1.7% dry weight in sediments (5 cm upper layer) due to CaCO3 addition to the lake. In the spring-summer seasons of 1992 and 1993, an experimental study was conducted in Lake Flosek to assess the capacity of bottom sediments to uptake and release mineral phosphorus. The rate of phosphorus exchange between sediments and near-bottom water was experimentally measured under conditions of high (100%), and of reduced (10%) oxygen saturation in near-bottom water. To determine the component of sediments responsible for the uptake of most phosphorus, the proportions of phosphorus forms in sediments were analysed. Sediments of Lake Flosek showed a slight tendency to release phosphates. The rate of this process was similar under high (100%) and low (10%) oxygen saturations ranging from - 0.161 to + 0.200 mg P m-2 d-1. This is much lower (by 1-2 orders of magnitude) than reported from other harmonic, non-humic lakes. In the total phosphorus pool, the highest content of phosphorus was found in the organic and residual phosphorus fractions (over 70% of the total phosphorus in sediments). The largest part of the readily extractable phosphorus was found in the fraction bound to Al and humic substances (41%). Both these fractions determine a weak exchange of phosphorus between sediments and water. No difference in P-release related to P-fraction compound was found in the cores taken from three sites in the lake.
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  • 157
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    Water, air & soil pollution 99 (1997), S. 477-486 
    ISSN: 1573-2932
    Keywords: sediment ; nitrogen ; phosphorus ; organic matter ; cluster analysis ; Gulf of Finland ; estuaries
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Dry weight (DW), ignition loss (IL) and concentrations of total nitrogen (TN) and total phosphorus (TP) of the sediment surface layer (0 to 10 cm, 1 cm slices) were analyzed from 20 sites in the eastern Gulf of Finland. The distance of the sampling sites from the mouth of the River Neva explained the nutrient concentrations of the sediments well, while the effect of water depth was negligible. The increase of TN and the decrease of TP along the transect from the river mouth towards the open Gulf were caused by the diminishing share of allochthonous material supplied from the River Neva. The mean TN concentration of the different accumulation areas was about 40 % higher in the sediment surface than in the deeper layer (9 to 10 cm). The corresponding difference for TP varied from 53 to 56 %. The results suggest considerable netflux of nutrients from sediment to water. The net sediment accumulation of nutrients were estimated as 6.0 g m-2 a-1 of N and 1.7 g m-2 a-1 of P corresponding 22 000 t a-1 of N and 6 100 t a-1 of P for the whole eastern Gulf.
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  • 158
    ISSN: 1573-2932
    Keywords: Adriatic Sea ; nutrients ; benthic fluxes ; carbon ; nitrogen ; silicon ; phosphorus ; budgets
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Benthic fluxes of dissolved inorganic N, Si and P nutrients, alkalinity, dissolved inorganic C (DIC), and O2 from sediments in the Gulf of Trieste (northern Adriatic, Italy) were measured monthly in the period September 1995 – August 1996 using in situ incubated light benthic chambers. The highest efluxes of DIC, NH4 +, PO4 3−, Si(OH)4, and NO3 − influxes encountered in late summer — early autumn were the consequence of degradation of benthic microalgae, and in autumn mostly of sedimented phytoplankton. High NO3 − efflux was observed in spring. Only NH4 + and Si(OH)4 fluxes were significantly correlated with temperature. This correlation suggests that the rate of downward input and the quality and quantity of sedimentary organic matter (autochthonous and allochthonous) were superimposed on the temperature fluctuations. High DIC, NH4 + and Si(OH)4 effluxes observed in July 1996 were due to the late spring — early summer degradation of sedimentary organic matter produced by benthic microalgae, while the autumn phytoplankton bloom was quickly reflected in enhanced benthic fluxes due to higher temperature. Significant correlations between NH4 +, PO4 3− and Si(OH)4 fluxes suggested their parallel regeneration and utilization at the sediment-water interface. The nutrient fluxes were linked to O2 consumption, suggesting that aerobic oxidation processes were important at the sediment-water interface in the Gulf. The N, P and Si nutrients released from sediment pore waters are probably utilized in benthic microalgal and bottom-water primary production. This indicates that pelagic and benthic communities in the central part of the Gulf of Trieste function relatively independently of each other.
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  • 159
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    Water, air & soil pollution 99 (1997), S. 633-640 
    ISSN: 1573-2932
    Keywords: zebra mussel ; Dreissena polyrnorpha ; phosphorus ; trophic state ; recovery ; take Como
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract A large scale study on the western basin of Lake Como (N. Italy) was started in 1995 to examine the effects of the zebra mussel colonization which began in early '90. Our results have been related to '91–92 data (pre-Dreissena period), before the maximum colonization of zebra mussel. In spring and summer of the post-Dreissena period total phosphorus, P-PO4, nitrate and chlorophyll values decreased, while ammonium and tranparency increased at every sampling station. Zebra mussel does not modify the trophic state of this sub-basin but it plays an important role in nutrient cycling. The entire population can filter epilimnetic craters 2.1 times per year and can produce 2.9 × 104 t y of pseudofaeces which are transferred to sediments.
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  • 160
    ISSN: 1573-5052
    Keywords: Aster ; Atriplex ; Chenopodium ; nitrogen ; phosphorus ; roots ; shoots
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The loss of dry mass, nitrogen and phosphorus from shoot and root litter of mudflat annuals was examined in a series of experimental marshes in the Delta Marsh, Manitoba, Canada. Litter bags containing shoot material of three mudflat annuals (Aster laurentianus Fern., Atriplex patula L., and Chenopodium rubrum L.) were placed on the sediment surface of the marshes under drawdown conditions. In addition, litter bags containing root material of these three species were shallowly buried. Approximately 70% and 50% of both shoot and root litter, respectively, was still present after one year in the field. During the second year when the marshes were flooded, shoot and root litter lost an additional 20% and 0% of their mass, respectively. Except for Chenopodium roots, which accumulated nitrogen and phosphorus during both years, shoot and root litter lost from 0 to 50% of their nitrogen and phosphorus early in the first year, with levels generally remaining constant through the remainder of the study period. Our results indicate that mudflat annual litter decomposed slowly and would provide abundant habitat for aquatic invertebrates when these marshes were reflooded. However, most nutrient loss took place in the first year when the litter was unflooded, with little loss occurring in the second year when flooded.
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  • 161
    ISSN: 1573-5117
    Keywords: fish food ; faeces ; nutrient ; nitrogen ; phosphorus
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The fish food and faeces were fractioned into the differentcomponents of phosphorus and nitrogen. There was a rapid release ofphosphorus from the fish food and faeces and a decrease thereafterwhereas ammonium release was slow at first with the rate increasingwith time. Both temperature and pH affected the release of nutrientsfrom fish food and faeces. The release of phosphorus and nitrogen washigher at higher temperatures. The maximum release of phosphorus wasat pH 4.0 whereas nitrogen release was maximum at neutral (7.0) toalkaline (10.0) media.
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  • 162
    ISSN: 1573-5117
    Keywords: phytoplankton ; zooplankton ; planktivorous fish ; phosphorus ; biomanipulation ; trophic interactions
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Water chemistry, phytoplankton, zooplankton and fish populations werestudied over several years in three shallow, non-stratified lakes withdiffering nutrient loadings and fish communities in southwest Finland. LakePyhäjärvi was weakly mesotrophic in 1980–1996, LakeKöyliönjärvi was highly eutrophic in 1991–1996, andLake Littoistenjärvi was mesotrophic in 1993–1996 and eutrophicin 1992. In Lake Pyhäjärvi, natural year-class fluctuations ofvendace and smelt (range of combined biomass 5–28 kgha™1) caused significant variation in planktivory. The verydense fish stocks of Lake Köyliönjärvi (mainly roach, breamand smelt) were decimated from 〉175 kg ha™1 in 1991 toabout 50 kg ha−1 in 1996 by removal fishing. The roach stockof Lake Littoistenjärvi declined from about 71 kg ha−1 toabout 28 kg ha−1 during 1993–1996. In LakePyhäjärvi, strong stocks of planktivorous fish were accompaniedwith depressed crustacean zooplankton biomass, reduced role of calanoids andcladocerans, a low proportion of larger cladocerans (length 〉 0.5 mm),and a high chlorophyll level. In the lakes Littoistenjärvi andKöyliönjärvi, zooplankton was dependent on both fish andphytoplankton: in spite of dense fish stocks, a high crustacean biomassdeveloped in a phytoplankton peak year, but it was dominated by very smallcladocerans. In Lake Pyhäjärvi, late summer chlorophyllconcentration was predictable from total phosphorus in water and cladoceranbiomass (r2 = 0.68), both factors explaining roughlysimilar fraction of total variation. In combined data from all three lakes,chlorophyll was almost solely dependent on total phosphorus, while thecladocerans were regulated both from below by productivity and from above byfish. Our data from Pyhäjärvi lend support to consumer regulationof late summer phytoplankton; low chlorophyll values prevailed whenplanktivorous fish biomass was below 15 kg ha−1. In largeeutrophic lakes it may be difficult to reduce fish stocks to such a lowlevel: in Lake Köyliönjärvi, after six years of removalfishing, fish biomass still remained higher, and changes in plankton wereaccordingly small. Unexpectedly, in 1993–1996, phytoplankton biomassin Littoistenjärvi remained low in spite of low crustacean zooplanktonbiomass; submerged macrophytes probably regulated the water quality.
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  • 163
    ISSN: 1573-5117
    Keywords: nitrogen ; phosphorus ; drainage waters ; sediments ; sorption
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Lake Łuknajno, a shallow (max. depth 3 m) and relativelylarge(630 ha) water body situated in the Great Masurian Lakessystem(Poland) is strongly affected by its agricultural watershed.Thetotal volume of drainage waters pumped into the lake in 1993amounted 2.84 × 106m3 which is equivalentto65% of the lake volume. In spring and autumn drainage waterswereextremely rich in nitrogen (especially nitrates) and the N:Pratioreached 57 in spring. In summer, drainage waters containedrelatively more phosphorus so the N:P ratio decreased tonearly 10.Nutrient concentrations in lake water followed the changes ininflowing waters. High concentrations of nitrates and ammoniawerenoted in lake water in spring but summer concentrations oftheseions were close to zero. Soluble reactive phosphorus variedbetween10 and 20 µg P l−1 throughout the season. A constantoutflow of nitrogen to the lower Lake Śniardwy was assumedbased ona permanent concentration gradient between waters of these twolakes.Lake Łuknajno is a hard water lake. Co-precipitation ofphosphorus with calcium carbonate is likely to occur though nosignificant P accumulation in bottom sediments was found.Sorptionof phosphorus on sediments as measured under experimentalconditions has minor effects on P cycling. Bottom sedimentscomposed mainly of calcareous gyttja do not accumulate eitherorganic matter or mineral forms of nutrients.
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  • 164
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    Hydrobiologia 342-343 (1997), S. 1-8 
    ISSN: 1573-5117
    Keywords: model ; phosphorus ; eutrophication ; hysteresis ; lake ; restoration
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract There is increasing evidence that, within a range of nutrientloadings, shallow lakes may have two alternative stablestates. One is dominated by phytoplankton and the other one bysubmerged macrophytes as the main primary producer. Thequestion arises at what level of nutrient loading a transitionmay occur between the two states. This question was addressedby means of the integrated lake model PCLake. The modeldescribes the competition between phytoplankton andmacrophytes, within the framework of closed nutrient cycles inthe lake system, including the upper sediment. Top-downeffects via the food web were regarded as well. The model wasrun for a hypothetical shallow lake, representative for thesituation in The Netherlands. Long-term simulations werecarried out for a realistic range of nutrient loadings andstarting from different initial conditions. The results showeda highly non-linear response, which also showed hysteresis:the loading level at which a transition occurs turned out tobe dependent on the initial conditions. The results werecompared with empirically derived chlorophyll a tophosphorus relations. Factors influencing the ’criticalnutrient level‘ were the lake dimensions and the netsedimentation rate. The model was also used to evaluate therole of food web management in lake restoration. The resultssuggest that a long-term effect of additional management ispossible only if combined with a decrease in nutrient loading.
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  • 165
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    Hydrobiologia 345 (1997), S. 39-44 
    ISSN: 1573-5117
    Keywords: Crystal Lake ; phosphorus ; 210Pb ; 137Cs ; geochronology
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Isotopes like 210Pb and 137Cs are effectivetools for determining chronology in lake sediments. Once the chronology is established, environmentalchanges in lakes can be investigated, and the causesfor those changes can often be inferred. 210Pband 137Cs profiles were constructed for thesediments of Crystal Lake, Connecticut, USA. Thegeochronology was used to determine the historicalchanges in organic matter and P accumulationin the sediment. Those profiles showed twosignificant periods of sedimentation which correlatewith major precipitation events. DecreasingP accumulation in the sediments of the lakein the last decade was also correlated with increasingeutrophication as documented by increases inepilimnetic P and decreases intransparency.
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  • 166
    ISSN: 1573-5117
    Keywords: eutrophication ; phosphorus ; bioavailability ; nutrient balance ; agriculture ; models
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract This study assesses the effects of external and internalloading on the nutrient concentrations in an agriculturallyloaded shallow lake. Using 13 years of observations of thelake's input and outflow, we calculated the long-term balancesof Tot-P and Tot-N. A more detailed balance, which includeddissolved nutrients and suspended solids, was estimated for anice-free period of one year. The contribution of the externalload was assessed using a mass-balance model. The internalload was estimated from the nutrient balances and on the basisof sedimentation measurements and bioassays. The drainagebasin of the lake provided most of the external nutrientinput; the remaining load was derived from atmosphericdeposition to the lake. The proportions of river-transported Pand N in dissolved form were 25% and 77%, respectively. Thelake retained 〉80% of the external load. Particulatenutrients settled to the bottom and were probably resuspendedseveral times before permanent sedimentation. Dissolvednutrients were bound by primary producers and a highproportion of dissolved P was removed with the fish catch.Dissolved N was also lost via denitrification. Themass-balance model showed that external loading only partlyregulated the mean annual nutrient concentrations in the lake.The regulation was probably due to internal loading, which washigh despite the efficient net retention of nutrients. Duringthe ice-free period, the temporal variations in nutrientconcentrations were controlled almost solely by internalprocesses, such as resuspension of inorganic and organicbottom matter. Although the internal load of bioavailable Pmay, under favourable conditions, exceed the external load,the mechanism by which bioavailable P is translocated from thebottom sediments to the water could not be fully identified. Abbreviations used in this paper follow the editor'srules.
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  • 167
    ISSN: 1573-5117
    Keywords: drainage area ; reservoir ; sedimentcomposition ; phosphorus ; phosphate extraction
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The study of four drinking-water reservoirsdemonstrates how the anthropogenic land use of acatchment may affect binding and mobility ofphosphorus in the sediment. Pdiss concentrationgradients at the sediment–water interface weremeasured to calculate potential diffusive releaserates. P binding forms were determined by sequentialextraction of fresh sediment and settling seston. Mainstudy sites were Saidenbach Reservoir (mesotrophic,densely populated drainage area with 73% agriculturalland use) and Neunzehnhain Reservoir (oligotrophic,unpopulated drainage area forested to 80%) in thesilicate-rich Erzgebirge mountains of eastern Germany.Tot-P concentrations and P binding forms of typicalerosive matter from each catchment were similar to thesediment of both pre-reservoirs and reservoirs' mouth.In Saidenbach Reservoir, diatoms responded to highnutrient loading by incorporating ortho-P. Whilesettling, the org-P was partly transformed toFe(OOH) ≈ P. Apart from hypolimnetic O2depletion, this P binding form dominated in thesurface sediment mainly in front of the dam. Withincreasing sediment depth, org-P and Fe(OOH) ≈ Pnot only redissolved into the pore water, but alsoadsorbed onto Al compounds. In Neunzehnhain Reservoir,acidification of the low buffered catchment favouredloading of humic compounds and Al3+ ions, whichprecipitated and redox-independently adsorbed ortho-Pdue to a pH increase in the lake. Neunzehnhainsediment was able to immobilize Fe(OOH) ≈ P fromSaidenbach sediment in a batch experiment. Comparativesequential P extraction of sediment from SosaReservoir (oligo-mesotrophic, sparsely populateddrainage area forested to 94%) and Kleine KinzigReservoir (nearly unpopulated drainage area forestedto 98%) also demonstrated effective P immobilizationby Al-/humic compounds. It is concluded that the absence of settlements in thecatchment, together with forestry as dominating landuse, favour not only oligotrophic conditions in thereservoir but also confine internal P loading from thesediment. But attention should be paid toacidification problems.
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  • 168
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    Hydrobiologia 345 (1997), S. 15-20 
    ISSN: 1573-5117
    Keywords: phosphorus ; phosphorus budget ; retention ; sedimentation ; sediment traps ; sediment cores
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract We compared P retention with direct measures of Psedimentation, estimated fromsediment cores (annual P sedimentation) and sedimenttraps (daily P sedimentation),to quantify P sedimentation in Eau Galle Reservoir,Wisconsin. Mean annual Pretention was similar to mean annual P sedimentation,as estimated from sediment corerates integrated over the entire lake basin,indicating that annual P mass balanceapproximated annual net P sedimentation in thisreservoir. However, sediment trap Prates, measured over the summer stratified period,overestimated P retention ratesdetermined over the same period, suggestingsubstantial deposition of internally-derived P.Inclusion of measured internal P loadings from avariety of sources in EauGalle Reservoir in a P mass balance only accounted foran additional 24% of thesummer sediment trap P rate, indicating substantialuncertainty in the overall P budget.Imbalances in the P budget may also suggest depositionof sediment from other as yetunquantified internal sources. Potential internalsources of P include sedimentresuspension and chemical release and direct uptake ofP from the sediment byphytoplankton.
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  • 169
    ISSN: 1573-5117
    Keywords: alkaline phosphatase ; chlorophyll a ; phosphorus ; algae ; phosphorus regeneration
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Alkaline phosphatase activity (APA) of unfiltered andfractionated (algae, bacteria, dissolved) surface watersamples was measured using a spectrophotometric method in LakeŁuknajno from May to September 1993. The total enzymaticactivity varied between 0.44–2.35 µmol l−1h−1.Algae were major producers of alkaline phosphatase activity insurface water of the lake from May to August, and theiractivity constituted on the average 67% of the total APAactivity in the water. APA activity in bacterial size fractionwas low and constituted 9.6% (mean) of the total activity.The activities of free (dissolved in water) enzymes wererelative high during the time of study. This study show thathydrolysis of organic phosphomonoesters by alkalinephosphatase was negligible in the recycling of phosphorus inŁuknajno Lake.
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  • 170
    ISSN: 1573-5117
    Keywords: lake sediment ; bioturbation ; chironomid larvae ; organic matter decomposition ; nutrient exchange ; nitrogen ; phosphorus
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The importance of Chironomus plumosus larvae onbenthic metabolism and nutrient exchange across thesediment–water interface was evaluated in a shalloweutrophic lake (Lake Arreskov, Denmark) following aphytoplankton sedimentation. Chironomus plumosuslarvae were added to laboratory sediment microcosms,corresponding to a density of 2825 larvae m−2.Non-inhabited microcosms served as controls. Asedimentation pulse of organic matter was simulated byadding fresh algal material (Chlamydomonasreinhardii) to sediment cores (36 g dryweight m−2). The mineralization was followed bymeasuring fluxes of O2, CO2, dissolvedinorganic nitrogen and phosphate. A rapid clearance ofalgae from the water column in faunated microcosmssuggested that chironomids may be of major importancein controlling phytoplankton concentrations in shalloweutrophic lakes. Chironomids increased the sedimentO2 uptake ≈ 3 times more than what wouldbe expected from their own respiration, indicating astimulation of microbial activity and decomposition oforganic matter in the sediment. Addition of algaeenhanced the release of CO2, NH+ 4 ando-P. The excess inorganic C, N and P released inamended non-inhabited sediment after 36 dayscorresponded to 65, 31 and 58% of the C, N and P inthe added algae. In sediment inhabited by Chironomus plumosus the corresponding numbers were147, 45 and 73%, indicating that mineralization oforganic matter also from the indigenous sediment poolwas stimulated by chironomids.
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  • 171
    ISSN: 1573-5036
    Keywords: Frankia ; phosphatase activity ; phosphorus ; protein ; viability
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract An in vitro experiment was conducted to investigate the effects of different sources and levels of P supply on growth, viability and phosphatase activity of three tropical Frankia strains isolated from Casuarina. P concentration for optimum growth was between 0.1 and 10.0 μM in the absence of external combined nitrogen. Specific viability was not influenced by P supply. Morphological features of Frankia, such as hyphal length and vesicle numbers, were found to largely mirror growth. Phosphatase activity was detected in all three Frankia strains and was highest when P was omitted from the culture solution. There were more than 10-fold differences between the Frankia strains in the level of phosphatase activities shown. This study suggested that soils low in P are unlikely to restrict micro-symbiont growth activity.
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  • 172
    ISSN: 1573-5036
    Keywords: eutrophication ; herons ; nesting site ; nitrogen ; nitrophyllous species ; phosphorus ; similarity index
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Effects of colony nesting of herons on soil properties and herb layer composition in Pinus densiflora forest were studied at Pomaeri, Kangwon Province in Korea. Herons have used this habitat as a nesting site from January to October every year. In 1995, more than 500 herons were observed in this habitat. Nutrient content of soil was much higher at the nesting site than that of the non-nesting site (control). Total nitrogen concentration of soil at the nesting site and the control site was 14.8±1.85 mg g-1 and 2.8±0.35 mg g-1, respectively. Phosphorus content of soil in the nesting site was 32 times greater than that of the control site. This is evidently due to the addition of feces of the herons, and decomposition of thin twigs and organic debris from the canopy of dead trees and bird nests. Light intensity at herb layer of the nesting site and of the control site was 80% and 20%, respectively, of incident on outside forest. Species diversity of herb layer in the nesting site (9 species) was quite lower than that in the control site (14 species). Similarity index of the herb layer between the two sites was 0.07. The nesting site was dominated by indicator species of soil eutrophication such as Humulus japonicus, Persicaria perfoliata, Persicaria fauriei, Commelina communis, Chelidonium majus var. asiaticum. Changes of herb species composition in the nesting site was evidently due to the eutrophication of the soil and increased light intensity of the herb layer.
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  • 173
    ISSN: 1573-5036
    Keywords: DRIS ; nitrogen ; perennial ryegrass ; phosphorus ; potassium ; sulphur
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Herbage analysis offers a definitive means of determining the N, P, K and S status of perennial ryegrass swards. Unfortunately, the results of such analyses can be difficult to interpret, simply because the minimum or 'critical' concentration of a nutrient in plant tissue for optimum growth, varies both with crop age and with changes in the concentrations of other nutrients. The Diagnosis and Recommendation Integrated System (DRIS) could help to improve the reliability of such interpretations. Diagnoses made using DRIS are based on relative rather than on absolute concentrations of nutrients in plant tissue, and as such should be comparatively independent of crop age. The aim of this study was to establish and test DRIS methodology for high-yielding perennial ryegrass swards. Because of prohibitive costs, setting up a whole new series of field experiments to evaluate DRIS model parameters for perennial ryegrass was out of the question. Instead, the diagnostic norms and associated coefficients of variation for the model were evaluated using data from a single (large) multi-factorial glasshouse experiment. Of the nutrient ratios selected to form the diagnostic norms, K/N and S/N had the clearest physiological rationale, whereas those involving Ca and Mg in combination with N, P, K and S appeared to have little physiological basis. It was reasoned, though, that because Ca and Mg uptake by plants are largely passive processes (ultimately governed by plant growth), the DRIS indices for these nutrients, together reflected the degree to which growth may be limited by non-nutritional (environmental) factors relative to nutritional ones. Both indices were combined to form a single reference (Ri) index. Without such an internal reference, plant growth could be limited by multiple nutrient deficiencies, and yet N, P, K and S indices might all be close to, or equal to zero (i.e. the optimum), simply because the absolute concentrations of each nutrient (while low) had been in the correct state of balance. Moreover, by effectively using Ca and Mg as internal reference parameters in DRIS, 'nutrient concentrations' which previously formed the basis of the critical value approach, were essentially incorporated into the DRIS model, thus combining the strengths of the two diagnostic approaches; the only difference being that Ca and Mg, and not dry matter, were the internal references against which the levels of the major nutrients were compared.
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  • 174
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    Plant and soil 195 (1997), S. 351-364 
    ISSN: 1573-5036
    Keywords: barrier island ; environmental effects ; litter quality ; nitrogen ; phosphorus ; root decomposition
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract A root decomposition study using the litterbag approach was conducted along a dune and swale chronosequence on the Virginia Coast Reserve-Long Term Ecological Research Site in Virginia, USA to evaluate how environmental and substrate quality factors influence belowground decay and associated nutrient dynamics. Gradients in moisture levels and nitrogen availability associated with the chronosequence provided the experimental framework. Spartina patens roots were buried at all sites as a standard substrate to evaluate environmental influences. Roots native to each site were buried to evaluate community decay dynamics and the influence of litter quality. Spartina decay was reduced in the wet, anoxic soils of swale sites (k = 0.21–0.33 yr-1) relative to decay in dunes soils (k = 0.52–0.72 yr-1). Increasing soil nitrogen availability from younger to older sites had no effect on the rate of Spartina root decay. Native root decay across the Hog Island chronosequence exhibits certain trends expected in response to nitrogen limitation and moisture availability. Increased nitrogen content of root material corresponds to increased soil nitrogen availability. Among dune sites, native root decay increased in concert with increased root nitrogen (6 year k = 0.34 yr-1, 120 year dune: k = 0.97 yr-1). Litter quality, alone, does not explain this trend since Spartina roots decayed more slowly than native dune roots and had a higher initial nitrogen content. Among swales, increased moisture levels and associated soil anoxia inhibited native root decomposition and minimized the effects of litter quality on decay. In general, phosphorus was rapidly lost from decaying roots while nitrogen immobilization was low to nonexistent. The low nitrogen immobilization of decaying roots in a nitrogen limited ecosystem warrants further study and may reveal that belowground decay increases the rate of nutrient cycling relative to decay aboveground.
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  • 175
    ISSN: 1573-5036
    Keywords: arbuscular mycorrhizae ; banana ; Glomus mosseae ; interaction ; Meloidogyne incognita ; Musa AAA ; phosphorus
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract The effects of the interaction between the arbuscular mycorrhizal fungus Glomus mosseae and the root-knot nematode Meloidogyne incognita on growth and nutrition of micropropagated ‘;Grand Naine’ banana (Musa AAA) cultivar was studied under greenhouse conditions. Inoculation with two G. mosseae isolates significantly increased growth of plants in relation to non-mycorrhizal plants. Response to mycorrhizae was as effective as with an optimum P fertilization in promoting plant development for most growth parameters. Meloidogyne incognita had no apparent effect on the percentage of root colonization in mycorrhizal plants. In contrast, G. mosseae suppressed root galling and nematode buildup in the roots. The percentage of mycorrhizal colonization was high (over 80%) in low P fertilized plants, but optimum P rates for bananas (four times higher than low P) significantly reduced mycorrhizal colonization. Most elements were within sufficiency levels for banana with exception of N which was low for all treatments. Mycorrhizal plants fertilized with a low P rate showed higher N, P, K, Ca, and Mg contents as compared to non-mycorrhizal plants low in P with or without the nematode. Inoculation with G. mosseae favours growth of banana plants by enhancing plant nutrition and by suppressing nematode reproduction and galling during the early stages of plant development.
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  • 176
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    Plant and soil 191 (1997), S. 181-188 
    ISSN: 1573-5036
    Keywords: cereal genotypes ; diffusion ; genetic ; phosphorus ; rhizosphere ; root hairs
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Root-soil contact is an important factor for uptake of a less mobile soil nutrient such as phosphorus (P) by crop plants. Root hairs can substantially increase root-soil contact. Identification of crop cultivars with more and longer root hairs can, therefore, be useful for increasing P uptake in low input agriculture. We studied the root hairs of wheat (Triticum aestivum L. cvs. Kosack, Foreman, Kraka) and barley cultivars (Hordeum vulgare L. cvs. Angora, Hamu, Alexis, Canut) in relation to P depletion from the rhizosphere in three soils of different P levels (0.45, 1.1 and 1.6 mmoles P kg−1 soil; extracted with 0.5 M NaHCO3). Root hairs were measured in solution culture having nutrients and concentration similar to soil solution. Root hairs of Kraka were much longer (1.27 ± 0.26 mm) and denser (38 ± 3) hairs mm−1 root) than those of Kosack which had shorter (0.49 ± 0.2 mm) and fewer (24 ± 3) hairs mm−1 root) root hairs. Root hairs increased root surface area (RSA) of Kraka by 341%. The increase with Foreman was 142% and with Kosack it was 95%. For winter barley, the length (1.1 ± 0.3 mm) and density (30 ± 1 hairs mm−1 root) of root hairs of Hamu differed from root hair length (0.52 ± 0.18 mm) and density (27 ± 1 hairs mm−1 root) of Angora. Root hairs of spring barley cultivars differed in length (Canut 1.0 ± 0.24 mm; Alexis 0.64 ± 0.19 mm) but not in density (Canut 31 ± 1, Alexis 30 ± 2 hairs mm−1 root). Root hair diameter (12 ± 1µm) did not differ among the cultivars. Root hairs increased RSA of Canut by 245%, Hamu by 237%, Alexis by 143% and Angora 112%. The variation in root hair parameters of the cultivars was related to quantity of P depleted from rhizosphere. The correlation (R2) between the root hair lengths of wheat cultivars and the quantity of P depleted from the rhizosphere soil (Q) was (0.99***) in low-P, (0.85***) in medium-P and (0.78**) in high-P soil. The values of (R2) between the root hair surface areas of wheat cultivars and Q were (1.00***) in low-P, (0.74**) in medium-P and (0.66**) in high-P soil. Similar high values of R2 were found for barley. These results show that the variation in root hairs of cereal cultivars can be considerable and it can play a significant role in P acquisition, especially in low-P soils.
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  • 177
    ISSN: 1573-5036
    Keywords: Cichorium intybus ; chicon ; nitrate ; phosphorus ; vegetative growth
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract This study investigated the effects of nitrate and phosphate nutrition on chicory tap root development and chicon quality. Plants of chicory (Cichorium intybus flash) were grown on four concentrations of nitrate and phosphate: 3 mM NO3 / 1 mM PO 4 3− , high N and high P (control plants, N / P); 3 mM NO 3 − / 0.05 mM H2PO3− 4, high N and low P (N / p); 0.6 mM NO3 / 1 mM PO 4 3− , low N and high P (n / P); 0.6 mM NO 3 − / 0.05 mM PO 4 3− , low N and low P (n / p). The results suggested that, nitrogen limitation had the greatest impact on the shoot/root dry weight ratio. Only small changes in the shoot/root dry weight could be attributed to P limitation alone. Compared with the control, N limitation caused a marked increase in root SST activity (sucrose sucrose fructosyl transferase, the enzyme responsible for fructan synthesis in roots), the effect of P limitation on SST activity was less pronounced. The activity of SS (sucrose synthase) was also noticeably elevated at the early sample data by N limitation. N and P uptake were estimated by the amount of N and P accumulated by the whole plant during the vegetative period. With N limitation, P accumulation was decreased by 40-60% over the experimental period. The effects of P limitation on N accumulation were more variable, N uptake was 60% lower than the control during the tuberizing period (107 days after sowing). With N limitation, P concentrations in roots were lowered by 20-25%. With P limitation, total N concentration in roots decreased by 50% relative to the control, while nitrate concentration was increased more than 8 fold. These effects were detected only at 107 DAS. The amino acid content of roots was not affected by P limitation, however, N limitation altered strongly total amino acids. P limitation did alter the relative amino acid composition of roots early in the vegetative period: Roots harvested at the end of vegetative period were forced in the dark to produce an etiolated bud, the edible chicon. High N and high P fertility (N/P) were associated to a poor chicon yield and quality. However the presence of low P during vegetative growth moderates adverse effects of high nitrate and greatly improved chicon yeild and quality.
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  • 178
    ISSN: 1573-5036
    Keywords: aluminium ; cellulose ; coal combustion by-product ; lime ; Lolium perenne ; phosphate rock ; phosphorus ; ryegrass ; Ultisol
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Remediation of soil acidity is crucial for increasing crop production and improving environmental quality of acid infertile soils. Soil incubation and greenhouse pot experiments were carried out to examine the interactions between phosphate rock (PR), coal combustion by-product (BP), dolomitic lime (L), and cellulose (C) in an acidic soil and their effects on ryegrass (Lolium perenne L. cv ‘Linn’) growth. BP and PR application increased plant P content and dry matter yield (DMY) of shoots and roots by improving soil Ca availability and reducing Al toxicity. Application of BP at low rates (5 to 10 g BP kg-1) with PR appeared to decrease both plant P content and DMY compared to PR application alone. The reduced DMY is due to an increased Al concentration in soil solution as a result of displacement of sorbed Al by Ca of BP. Increases in DMY were obtained by addition of lime along with PR and BP at low rates or by increasing BP application rates above 15 g kg-1. This improved plant response was likely related to alleviation of Al toxicity by CaCO3 contained in the BP. In addition to raising the pH to an acceptable level for plant growth, the dolomitic lime supplied needed Mg for plants, thereby maintaining a good balance between available Ca and Mg for plants in the BP- and PR-amended soils. The addition of cellulose to the BP- and PR-amended soils reduced water-soluble Al and increased DMY. Plant growth increased PR dissolution by 2.4 to 243% in a soil with low available P. Use of BP at moderate rates with PR and dolomitic lime appears to be the best combination in increasing crop yields on infertile acidic soils.
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  • 179
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    Plant and soil 188 (1997), S. 279-297 
    ISSN: 1573-5036
    Keywords: ecosys ; modelling ; phosphorus ; root systems
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract The uptake of P by plant root systems is believed to be controlled by the concentration of soluble orthophosphate at the root surface. If a P transformation model in which this concentration is calculated were coupled to a root and mycorrhizal growth model in which this concentration is used to calculate P uptake, then it should be possible to simulate P uptake under different soil and climate conditions if soil properties relevant to the control of P concentration are known. To test this idea, models for the transformation and transport of inorganic and organic P were coupled to ones for root growth and nutrient uptake as part of the ecosys modelling program. Seasonal estimates of soluble P concentration, root growth and P uptake from the combined models were tested with data measured from barley under fertilized and unfertilized treatments in a long term P fertilizer experiment conducted on two different soils. In both soils the fertilizer treatment increased simulated and measured soluble P concentrations from 0.1-0.2 to 0.2-0.4 g m-3, annual P uptake from 0.6-0.7 to 1.2-1.4 g m-2, and annual DM accumulation from 400-500 to 700-800 g m-2. Increases in soluble P concentrations caused by fertilizer P were reproduced in the model from changes in the balance between the desorption and dissolution of solid P on one hand, and the uptake of P by root and mycorrhizal systems on the other. Increases in P uptake caused by fertilizer P were reproduced in the model from higher solution P concentrations, root uptake kinetics, and from functional equilibria for C and P exchange simulated among mycorrhizal, root and shoot components of the plant. There was a tendency in the model to overestimate P uptake later in the growing season in the unfertilized treatment which could be corrected if parameters for root uptake kinetics were reduced after anthesis. Because the model is constructed independently of data for P uptake, and avoids the use of site-specific parameters, it may provide a means of estimating uptake under different managements and climates from soils of known properties.
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  • 180
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    Plant and soil 196 (1997), S. 123-131 
    ISSN: 1573-5036
    Keywords: ectomycorrhiza ; ergosterol ; Paxillus ; phosphorus ; Suillus ; weathering
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract The objectives of the study are firstly to test the ability of ectomycorrhizal pine seedlings to use apatite as a P source in comparison with non-mycorrhizal pine seedlings and secondly, to determine if there is a relation between exudation of organic acids and the ability to use apatite as a P source. Non-mycorrhizal Pinus sylvestris (L.) seedlings and seedlings ectomycorrhizal with 4 different isolates of ectomycorrhizal fungi were grown for 220 days in sand/peat filled pots with apatite (Ca5(F,OH)(PO4)3) as the sole P source. In an additional experiment, non-mycorrhizal Pinus sylvestris (L.) seedlings and seedlings ectomycorrhizal with 2 different isolates of ectomycorrhizal fungi were grown without any P source for 250 days. All other nutrients were supplied in a balanced nutrient solution. Ectomycorrhizal seedlings grew less than non-mycorrhizal seedlings but ectomycorrhizal seedlings produced a large external mycelium not included in the biomass estimates. All seedlings in the present study had low shoot:root ratios compared to seedlings growing under optimal conditions. All seedlings grown with apatite as P source had higher foliar P concentrations (0.71–2.11 mg/g) than seedlings growing without any P source (0.57–0.75 mg/g) indicating a significant ability to use apatite as a P source. Seedlings colonized by Suillus variegatus and Paxillus involutus had higher concentrations and total contents of P in shoots compared with non-mycorrhizal seedlings, indicating significant improvement of P uptake by these fungi in comparison with non-mycorrhizal seedlings or seedlings colonized Piloderma croceum. No clear relationship between exudation of organic acids and uptake of P was found. Seedlings colonized by S. variegatus reduced the pH of the soil more than seedlings colonized by P. involutus or non-mycorrhizal seedlings. It is suggested that S. variegatus colonization improves the P uptake by reducing the pH of the soil while P. involutus improves P uptake by having a greater ability to absorb dissolved phosphate than non-mycorrhizal roots or roots colonized by the other fungi used in the study.
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  • 181
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    New forests 14 (1997), S. 33-44 
    ISSN: 1573-5095
    Keywords: nutrient concetration ; frost hardiness ; growth cessation ; Pinus sylvestris ; visual damage ; nitrogen ; phosphorus ; potassium
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract In this study the effect of summer fertilization on the initiation of frost hardening of containerized second-year Scots pine (Pinus sylvestris L.) seedlings is studied. During the second growing season three different fertilization programs (water soluble NPK with micronutrients) determined by electrical conductivity of peat water extract (0.2, 0.5 and 1.2 mS cm-1) were initiated. The growth and nutrient concentrations of needles were monitored during the fertilization period. The frost hardiness of seedlings was assessed on four separate occasions at two week intervals from August 7 to September 18. This assessment was based on artificial freezing tests and visual damage scoring of tissue browning on current-year needles. Clear differences in foliar N, P and K concentrations were observed between the fertilization treatments. Fertilization prolonged the growing period of needles and increased root collar diameter. In all the tests, the highest fertilization level resulted in the highest level of frost hardiness. The difference between the fertilization treatments ranged from 1 °C to 2.2 °C. Frost hardiness increased with an increase in foliar nitrogen concentration and slightly less consistently with increases in foliar phosphorus and potassium concentrations.
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  • 182
    ISSN: 1573-5087
    Keywords: foliar fertilization ; forage yield ; gibberellic acid ; Lotus tenuis ; phosphorus
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Lotus tenuis is a perennial legume with a good adaptation to infertile, heavy and waterlogging soils. It can replace alfalfa in these sites with a similar feeding value. An important constraint is its weak competitive capacity with other graminae and weed species in permanent pastures, having consequently a poor forage yield. The objective of the present research is to overcome this disadvantage, enhancing its competitive ability with foliar applications of GA3 (GA) and phosphorus (P), increasing L. tenuis forage yield. Field experiments were conducted during 1994 with foliar application of GA (50 mg.l-1) and during 1995 with foliar application of GA (25 and 50 mg.l-1), phosphorus (8 kg.ha-1, as P2O5) and their combinations, in permanent pastures with L. tenuis and other companion grasses. In 1994 GA 50 increased significantly L. tenuis dry matter (DML) in 64.6% but not the dry matter of graminae fraction (DMG) and in consequence the total dry matter of the pasture (TDMP) was increased. In 1995 all GA treatments and their combinations with phosphorus enhanced DML but not DMG. In this sense GA 25 + P was the most effective treatment with a 151% increment of DML. Consequently TDMP was significantly increased due to a larger participation of L. tenuis in the forage yield. This increase was achieved due to a greater length and diameter of L. tenuis branches, with a logical modification in leaf:stem ratio. Moreover GA treatments reduced L. tenuis flower number. Phosphorus treatment, applied alone, showed an increase in the DML. GA treatments did not modify the feeding value of the forage in L. tenuis and graminae fractions, except GA 50 and GA 50 + P in acid detergent fiber (ADF), neutral detergent fiber (NDF) and crude protein (CP), respect to the control. The total crude protein (CP.m-2) was enhanced in all GA and GA + P treatments. Foliar GA3 and phosphorus spray applications increased the competitiveness of trefoil for light, on account of morphological changes in the spatial disposition of L. tenuis stems reaching faster the top of the pasture canopy. This practice can be an adequate alternative to increase the forage yield and total crude protein in permanent and cultivated pastures with a low cost-benefit ratio.
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  • 183
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    Biogeochemistry 37 (1997), S. 237-252 
    ISSN: 1573-515X
    Keywords: freshwater ; limitation ; marine ; nitrogen ; phosphorus ; ratio ; stoichiometry ; trace elements
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences
    Notes: Abstract Nitrogen supply is often assumed to limitmarine primary production. A global analysis of totalnitrogen (N) to phosphorus (P) molar ratios shows thattotal N:P is low (〈16:1) in some estuarine andcoastal ecosystems, but up to 100:1 in open oceans.This implies that elements other than N may limitmarine production, except in human impacted, estuarineor coastal ecosystems. This pattern may reconcileconflicting enrichment studies, because N additionfrequently increases phytoplankton growth where totalN:P is expected to be low, but P, Fe, or Si augmentphytoplankton growth in waters where total N:P ishigh. Comparison of total N:P stoichiometry betweenmarine and freshwaters yields a model of the form ofthe aquatic N:P cycle.
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  • 184
    ISSN: 1573-515X
    Keywords: carbon ; nitrogen ; Ohio River ; phosphorus ; Red field ratios ; dissolved organic matter ; rivers
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences
    Notes: Abstract A 12-month study was conducted to measure the concentrations ofdissolved organic matter (DOC, TDN, TDP) in four sites within a119 km long reach of the Ohio River, near Louisville, KY. In thisstudy we test whether specific geomorphological and biologicalfactors influenced variations in dissolved organic matter.Concentrations of DOC in the river averaged ≈1200μmol/L, and varied by nearly two orders of magnitudeseasonally (mean DOC during base flow ≈620 μmol/L).Peak periods for DOC at all sites were during April–May. Thesite nearest a navigation dam (deeper, lower current velocities)had significantly lower concentrations of TDN and greater C:Nratios than upstream sites. The largest tributary entering thisreach (Kentucky River) had no significant effect on levels of DOMin the main river, despite having significantly greaterconcentrations of TDN and lower levels of DOC during most monthsof the year. Concentrations of DOC, TDN, and TDP were notsignificantly different in littoral and pelagic habitats at allsites studied, suggesting little floodplain influence on DOM inthis constricted-channel section of the Ohio River. C:N ratios ofDOM in the Ohio were significantly different among seasons; C:Nexceeded or equaled Redfield ratios in summer and fall (6 to 10),but were below Redfield (1.8 to 3.0) during winter and spring.Regression models suggest that total phytoplankton densities andflow conditions are the two most important factors regulating DOMin this very large river.
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  • 185
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    Agroforestry systems 38 (1997), S. 51-76 
    ISSN: 1572-9680
    Keywords: nitrogen ; nutrient cycling ; phosphorus ; soil fertility ; soil organic matter
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Trees can influence both the supply and availability of nutrients in the soil. Trees increase the supply of nutrients within the rooting zone of crops through (1) input of N by biological N2 fixation, (2) retrieval of nutrients from below the rooting zone of crops and (3) reduction in nutrient losses from processes such as leaching and erosion. Trees can increase the availability of nutrients through increased release of nutrients from soil organic matter (SOM) and recycled organic residues. Roots of trees frequently extend beyond the rooting depth of crops. Research on a Kandiudalfic Eutrudox in western Kenya showed that fast-growing trees with high N demand (Calliandra calothyrsus, Sesbania sesban and Eucalyptus grandis) took up subsoil nitrate that had accumulated below the rooting depth of annual crops. Sesbania sesban was also more effective than a natural grass fallow in extracting subsoil water, suggesting less leaching loss of nutrients under S. sesban than under natural uncultivated fallows. Nutrient release from SOM is normally more dependent on the portion of the SOM in biologically active fractions than on total quantity of SOM. Trees can increase inorganic soil N, N mineralization and amount of N in light fraction SOM. Among six tree fallows of 2- and 3-year duration on an Ustic Rhodustalf in Zambia, inorganic N and N mineralization were higher for the two tree species with lowest (lignin + polyphenol)-to-N ratio (mean = 11) in leaf litter than for the two tree species with highest ratio (mean = 20) in leaf litter. Trees can also restore soil fauna, which are important for SOM and plant residue decomposition. Some agroforestry trees have potential to provide N in quantities sufficient to support moderate crop yields through (i) N inputs from biological N2 fixation and retrieval of nitrate from deep soil layers and (ii) cycling of N from plant residues and manures. The cycling of P from organic materials is normally insufficient to meet the P requirements of crops. Sustained crop production with agroforestry on P-deficient soils will typically require external P inputs.
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  • 186
    ISSN: 1573-5036
    Keywords: cell wall ; groundnut ; phosphorus ; root surface ; sorghum ; soybean
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Groundnuts have a superior ability to take up P from soils with low P fertility compared to sorghum and soybean. Previous experiments showed that this ability was neither attributable to better root development nor to root exudates capable of solubilizing Fe- and Al-bound P, the sparingly soluble P forms in soils. Direct "contact reactions" between cell wall components from these 3 plant species (groundnut, soybean and sorghum) and P-fixing Fe and Al minerals were examined. Cell wall preparations from groundnut roots showed a superior P solubilizing ability than those of soybean and sorghum. Cell wall activity of groundnut roots may thus at least partly explain the superior growth of this crop under P-deficient conditions. To characterize the active site responsible for P solubilization, effects of pH, heat, addition of cations, and digestion with enzymes (pectinase and cellulase) or HCl on P solubilization were investigated. Conclusion are 1) Solubilizing ability is not related to root CEC because soybean with higher root CEC showed an inferior solubilizing ability compared to groundnut. 2) The reaction site of cell-walls of groundnut roots is stable against heating and digestion with cellulase and pectinase. 3) Solubilizing ability was severely reduced by digestion with HCl. 4) Pre-treating cell walls with either Al3+, Fe3+, or Ga3+ decreased solubilizing ability but cations with lower valency such as Na+, K+, Ca2+ or Mg2+ had no effect. Soaking roots of groundnuts grown in solution culture in 0.5 M NaOH for 30 seconds prior to cell wall preparation led to a 30% reduction in solubilization of P from FePO4 without permanently damaging plants. This suggests that 5) the active component of the cell walls was located on the root epidermal cell surfaces. Based on these results a phosphorus solubilizing mechanism is proposed.
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  • 187
    ISSN: 1573-5036
    Keywords: bioavailability ; competition ; phosphorus ; sorption ; sulfate ; uptake
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract The adsorption of phosphate on metal (hydr)oxides may be influenced by the pH and by the adsorption of other ions. In this study, the influence of sulphate and pH on phosphate adsorption on goethite and the availability to plants of adsorbed phosphate was examined. Maize plants were grown on suspensions of goethite with adsorbed phosphate, containing the same total amount of phosphate and either 0.11 mM or 2.01 mM sulphate at pH 3.7, 4.6 or 5.5. The uptake of phosphorus by the plants increased with the larger sulphate concentration and decreasing pH. Mean P uptake in the treatment with 2.01 mM sulphate and pH 3.7 was 55 µmol plant-1, whereas in the treatment with 0.11 mM sulphate and pH 5.5 it was 2 µmol plant-1. Batch adsorption experiments using32 P and speciation modelling of ion adsorption showed that in the presence of sulphate, the phosphate concentration in solution strongly increased with decreasing pH, due to competitive adsorption between sulphate and phosphate on goethite. Modelled phosphate concentrations in solution in the uptake experiment were all below 0.6 µM and correlated well with the observed P uptake. This correlation indicates that the strong influence of the sulphate concentration and pH on the plant-availability of adsorbed phosphate results from the competition between sulphate and phosphate for adsorption on goethite.
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  • 188
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    Euphytica 98 (1997), S. 177-182 
    ISSN: 1573-5060
    Keywords: Genetic ; mineral nutrition ; phosphorus ; rhizosphere ; root hairs
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Length and density (number mm-1 root) of root hairs of two barley (Hordeum vulgare L.) cultivars Salka and Zita and their capability to absorb phosphorus (P) from nutrient solution as well as from rhizosphere soil were studied. The cultivars were chosen because they differed most among 30 cultivars in ability to absorb P from low P soil in two field conditions. In nutrient solution culture, Salka had 32±4 root hairs mm-1 root, 1.02±0.22 mm long. Zita had 21±3 hairs mm-1 root, 0.54±0.14 mm long. In soil, the root hairs of both the cultivars were slightly longer (Salka 1.10 ±0.16 mm; Zita 0.63±0.18 mm) than in solution culture but the difference was non-significant (p〈0.05). The root hairs increased the effective root surface area of Salka by 206% and that of Zita by 81%. In solution culture, Salka produced 163±9 m g-1 and Zita 153±11 m g-1 dry roots in 21 days. Salka produced 1.65±0.22 g and Zita 1.51±0.31 g of green dry matter (DM). The cultivars did not differ in uptake of P from nutrient solution culture. The P content of DM was 0.42±0.1% in Salka and 0.41±0.08% in Zita. In soil, Salka depleted two times more P from rhizosphere than Zita. The longer root hairs of Salka increased the extension of the depletion zone for NaHCO3-Pi (inorganic P extracted with 0.5 M NaHCO3) in the rhizosphere. The cultivars also depleted NaOH-Pi (inorganic P extracted with 0.1 M NaOH) from the rhizosphere soil, but the difference between the cultivars was non-significant (p〈0.05). The results suggested that the ability of Salka to absorb more inorganic soil P was due to its longer and denser root hairs.
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  • 189
    ISSN: 1573-5117
    Keywords: nitrogen ; phosphorus ; phytoplankton biomass ; Daphnia grazing
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The role of nitrogen as a factor controllingphytoplankton biomass was studied in nutrientenrichment incubations in the laboratory using waterfrom pelagic region of two mesotrophic lakes ineastern Finland, Lake Kallavesi (in year 1994) andLake Juurusvesi (in year 1995). We used differentcombinations of phosphorus and nitrogen additions ina total of eight experiments. Furthermore, we includedDaphnia grazing treatment to the experimentaldesign in Lake Juurusvesi experiments. The nitrogentreatments did not increase chlorophyll aconcentration in any of the experiments compared withthe controls. Chlorophyll a content was highestin those nutrient treatments where phosphorus wasadded with or without nitrogen. Daphnia grazingdecreased chlorophyll a concentration comparedwith non-grazed treatments. In some cases grazing alsocaused higher ammonium concentrations. Theseexperiments, as well as the nutrient ratio of the lakewater used, suggest that phosphorus is likely tocontrol the amount of phytoplankton biomass.
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  • 190
    ISSN: 1573-5117
    Keywords: periphyton ; algae ; wetlands ; Everglades ; Eutrophication ; phosphorus ; biomass ; primary productivity ; nutrient cycling
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract We sampled periphyton in dominant habitats at oligotrophic and eutrophic sites in the northern Everglades during the wet and the dryseasons to determine the effects of nutrient enrichment on periphytonbiomass, taxonomic composition, productivity, and phosphorus storage. Arealbiomass was high (100–1600 g ash-free dry mass [AFDM]m−2) in oligotrophic sloughs and in stands of the emergentmacrophyte Eleocharis cellulosa, but was low in adjacent stands of sawgrass,Cladium jamaicense (7–52 g AFDM m−2). Epipelon biomasswas high throughout the year at oligotrophic sites whereas epiphyton andmetaphyton biomass varied seasonally and peaked during the wet season.Periphyton biomass was low (3–68 g AFDM m−2) and limitedto epiphyton and metaphyton in open-water habitats at eutrophic sites andwas undetectable in cattail stands (Typha domingensis) that covered morethan 90% of the marsh in these areas. Oligotrophic periphytonassemblages exhibited strong seasonal shifts in species composition and weredominated by cyanobacteria (e.g., Chroococcus turgidus, Scytonema hofmannii)during the wet season and diatoms (e.g. Amphora lineolata, Mastogloiasmithii) during the dry season. Eutrophic assemblages were dominated byCyanobacteria (e.g., Oscillatoria princeps) and green algae (e.g., Spirogyraspp.) and exhibited comparatively little seasonality. Biomass-specific grossprimary productivity (GPP) of periphyton assemblages in eutrophic openwaters was higher than for comparable slough assemblages, but areal GPP wassimilar in these eutrophic (0.9–9.1 g C m−2d−1) and oligotrophic (1.75–11.49 g C m−2d−1) habitats. On a habitat-weighted basis, areal periphytonGPP was 6- to 30-fold lower in eutrophic areas of the marsh due to extensiveTypha stands that were devoid of periphyton. Periphyton at eutrophic siteshad higher P content and uptake rates than the oligotrophic assemblage, butstored only 5% as much P because of the lower areal biomass.Eutrophication in the Everglades has resulted in a decrease in periphytonbiomass and its contribution to marsh primary productivity. These changesmay have important implications for efforts to manage this wetland in asustainable manner.
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  • 191
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    Hydrobiologia 363 (1997), S. 117-126 
    ISSN: 1573-5117
    Keywords: nutrient limitation ; eutrophication ; nitrogen ; phosphorus ; Archipelago Sea
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Eutrophication is the most acute environmentalproblem in the Archipelago Sea, SW Finland. Whenanalysing the factors behind this escalatingeutrophication the determination of limitingnutrient at a given time is essential. Besidesexperimentations, nutrient limitation of planktonhas been extensively studied by direct chemicalanalyses. We used the latter approach in this work.Nutrient limitation was studied by calculatingdifferent nutrient ratios – totalnitrogen:phosphorus, inorganic nitrogen:phosphorus,and nutrient balance ratio. Results showed thatphosphorus usually limited primary production onlynear the coast line. In the middle zone of theArchipelago Sea the limiting factor variedtemporally. Outer in the open sea nitrogen limitedprimary production during most of the year.Phosphorus limited phytoplankton growth especiallyin spring and in summer and nitrogen in late summerand in autumn. Our results suggested that nitrogenis an important limiting nutrient in the ArchipelagoSea. In recent years when the eutrophication hasproceeded there has been a shift from productionlimitation by both nutrients to limitation bynitrogen alone. But if we want to define andcharacterize the nutrient limitation of the entireecosystem of the Archipelago Sea, budgets have to becalculated for both N and P and internal recyclingmust be taken into account as well as externalsupply of nutrients and loss processes.
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  • 192
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    Biogeochemistry 37 (1997), S. 63-75 
    ISSN: 1573-515X
    Keywords: nutrient limitation ; soil development ; nitrogen ; phosphorus ; chronosequence ; Hawai'i
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences
    Notes: Abstract Walker & Syers (1976) proposed a conceptual model that describesthe pattern and regulation of soil nutrient pools and availability during long-term soil and ecosystem development. Their model implies that plantproduction generally should be limited by N on young soils and by P on oldsoils; N and P supply should more or less equilibrate onintermediate-aged soils. We tested the application of this model to nutrientlimitation, using a well characterized substrate age sequence in Hawaiianmontane rain forest. Earlier experiments had evaluated nutrient limitationin forests on a young (300 y) and an old (4,100,000 y) substrate on the samedevelopmental sequence; N alone limited tree growth on the youngsubstrate, while P alone did so on the old one. An additional fertilizerexperiment based on replicated treatments with N, P, and all othernutrients combined, applied in individually and in all factorialcombinations, was established in an intermediate-aged site in theLaupahoehoe Forest Reserve, Hawaii. Here, diameter increments of thedominant tree Metrosideros polymorpha increased slightly with Nadditions, and nearly doubled when N and P were added together.Additions of elements other than N and P had no significant effecton growth. These results show that N and P had equilibrated (relativeto plant requirements) in the intermediate aged site. Together withthe earlier experiments, these results suggest that the Walker and Syersmodel provides a useful starting point for explaining the nature anddistribution of nutrient limitation in forest ecosystems.
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  • 193
    ISSN: 1573-2932
    Keywords: phosphorus ; P flux ; microbial activity ; redox ; simulation ; Lake Kinneret ; sediment ; accumulative P release
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Different factors which interactively control the flux of soluble reactive phosphorus (SRP) at the sediment water irterface (SWI) of Lake Kinneret were studied seasonally. The influence of pH, Eh and microbial activity on SRP flux at the SWI was investigated by manipulating the conditions in the overlying water of intact sediment cores. The calculated diffusive SRP flux out of the sediment was lower in cores sampled during winter and spring than during the period of amixis. Potential SRP release, as measured in the absence of microbial activity, was strongly enhanced upon the transition from oxic to anoxic conditions indicating P release from iron(III)-bound phosphorus. In spring and summer cores, an enhanced SRP flux from sediments at pH 7 in comparison to pH 8 indicated P release from carbonate-bound P which sedimented previously as result of high pH values during the algal spring bloom. Microbial uptake at the SWI was the most important sink for SRP and no net-flux occured under oxic conditions. The higher net-flux of P under anoxic conditions was linked to carbon limitation ofthe bacteria at the SWI.
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  • 194
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    Water, air & soil pollution 99 (1997), S. 477-486 
    ISSN: 1573-2932
    Keywords: sediment ; nitrogen ; phosphorus ; organic matter ; cluster analysis ; Gulf of Finland ; estuaries
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Dry weight (DW), ignition loss (IL) and concentrations of total nitrogen (TN) and total phosphorus (TP) of the sediment surface layer (0 to 10 cm, 1 cm slices) were analyzed from 20 sites in the eastern Gulf of Finland. The distance of the sampling sites from the mouth of the River Neva explained the nutrient concentrations of the sediments well, while the effect of water depth was negligible. The increase of TN and the decrease of TP along the transect from the river mouth towards the open Gulf were caused by the diminishing share of allochthonous material supplied from the River Neva. The mean TN concentration of the different accumulation areas was about 40 % higher in the sediment surface than in the deeper layer (9 to 10 cm). The corresponding difference for TP varied from 53 to 56 %. The results suggest considerable netflux of nutrients from sediment to water. The net sediment accumulation of nutrients were estimated as 6.0 g m−2 a−1 of N and 1.7 g m−2 a−1 of P corresponding 22 000 t a− of N and 6 100 t a−1 of P for the whole eastern Gulf.
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  • 195
    ISSN: 1573-2932
    Keywords: Adriatic Sea ; nutrients ; benthic fluxes ; carbon ; nitrogen ; silicon ; phosphorus ; budgets
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Benthic fluxes of dissolved inorganic N, Si and P nutrients, alkalinity, dissolved inorganic C (DIC), and O2 from sediments in the Gulf of Trieste (northern Adriatic, Italy) were measured monthly in the period September 1995 - August 1996 using in situ incubated light benthic chambers. The highest efluxes of DIC, NH4+, PO43-, Si(OH)4, and NO3- influxes encountered in late summer - early autumn were the consequence of degradation of benthic microalgae, and in autumn mostly of sedimented phytoplankton. High NO3- efflux was observed in spring. Only NH4+ and Si(OH)4 fluxes were significantly correlated with temperature. This correlation suggests that the rate of downward input and the quality and quantity of sedimentary organic matter (autochthonous and allochthonous) were superimposed on the temperature fluctuations. High DIC, NH4+ and Si(OH)4 effluxes observed in July 1996 were due to the late spring - early summer degradation of sedimentary organic matter produced by benthic microalgae, while the autumn phytoplankton bloom was quickly reflected in enhanced benthic fluxes due to higher temperature. Significant correlations between NH4+, PO43- and Si(OH)4 fluxes suggested their parallel regeneration and utilization at the sediment-water interface. The nutrient fluxes were linked to O2 consumption, suggesting that aerobic oxidation processes were important at the sediment-water interface in the Gulf. The N, P and Si nutrients released from sediment pore waters are probably utilized in benthic microalgal and bottom-water primary production. This indicates that pelagic and benthic communities in the central part of the Gulf of Trieste function relatively independently of each other.
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  • 196
    ISSN: 1573-2932
    Keywords: Cystoseira myrica ; Red Sea ; coral reefs ; nitrogen ; phosphorus ; pollution ; eutrophication
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Elevated phosphate concentrations at Safaga and Quseir, Red Sea, Egyptian coast, wererelated to some ecological and nutritional aspects of the macro-alga Cystoseira myrica during1985. The results obtained were compared with those recorded for a non-polluted control site atGhardaqa. Chemical analysis of surface seawater samples revealed that the concentrations of dissolvedphosphate at Safaga and Quseir were 3 and 20 times as much as that at Ghardaqa, respectively.The standing crop of C. myrica showed two peaks in spring and autumn. Maximum biomass yield(491 g m-2) and number of individuals (127 m-2) of C. myrica were recorded in the spring at theGhardaqa site. Quseir C. myrica samples contained significantly higher protein-N, total-N andtotal-P values but lower carbohydrate values than the Safaga and Ghardaqa samples (LSD at 1%level). Tissue N:P molar ratios for C. myrica, Laurencia papillosa and Ulva lactuca collected fromGhardaqa ranged from 68-98, compared to 30-59 for the same species collected at thephosphorus polluted sites at Safaga and Quseir. The carbon levels and the C:N ratios of C. myricaexhibited no significant variations in the three studied sites. However, the C:P ratios of Ghardaqaplants were significantly higher than those of Safaga and Quseir.
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  • 197
    ISSN: 1573-2932
    Keywords: Cystoseira myrica ; Red Sea ; coral reefs ; nitrogen ; phosphorus ; pollution ; eutrophication
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Elevated phosphate concentrations at Safaga and Quseir, Red Sea, Egyptian coast, were related to some ecological and nutritional aspects of the macro-algaCystoseira myrica during 1985. The results obtained were compared with those recorded for a non-polluted control site at Ghardaqa. Chemical analysis of surface seawater samples revealed that the concentrations of dissolved phosphate at Safaga and Quseir were 3 and 20 times as much as that at Ghardaqa, respectively. The standing crop ofC. myrica showed two peaks in spring and autumn. Maximum biomass yield (491 g m−2) and number of individuals (127 m−2) ofC. myrica were recorded in the spring at the Ghardaqa site. QuseirC. myrica samples contained significantly higher protein-N, total-N and total-P values but lower carbohydrate values than the Safaga and Ghardaqa samples (LSD at 1% level). Tissue N:P molar ratios forC. myrica, Laurencia papillosa andUlva lactuca collected from Ghardaqa ranged from 68–98, compared to 30–59 for the same species collected at the phosphorus polluted sites at Safaga and Quseir. The carbon levels and the C:N ratios ofC. myrica exhibited no significant variations in the three studied sites. However, the C:P ratios of Ghardaqa plants were significantly higher than those of Safaga and Quseir.
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  • 198
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    Water, air & soil pollution 93 (1997), S. 243-254 
    ISSN: 1573-2932
    Keywords: arsenic ; lead ; phosphorus ; heavy metal ; mobility
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Past use of lead arsenate insecticides has resulted in elevated concentrations of lead (Pb) and arsenic (As) in topsoils of many existing and former deciduous tree fruit orchard sites throughout the world. Application of phosphate (PO4)-containing fertilizers to these soils can increase soil As solubility, phytoavailability and downward mobility. A laboratory soil column experiment was conducted to determine if As released by phosphate additions to a topsoil artificially contaminated with lead arsenate (1.65 mmol total Pb/kg; 1.10 mmol total As/kg) would be appreciably resorbed by the underlying uncontaminated subsoil. Treatments were a factorial combination of topsoil amendment with monoammonium phosphate (MAP, 0 or 16.67 mmol PO4/kg), and amount of leaching (1, 5 and 10 pore volume displacements (PVD) with distilled water under saturated flow conditions). Soil As decreased in the topsoil with increasing amount of leaching and increased in the subsoil. Addition of MAP substantially increased loss of topsoil As, promoted As transport into and through the subsoil, and increased dissolved As concentrations in the column leachates. After 10 PVDs, 95% of the initial soil As remained in the −MAP columns, while 56% of the initial soil As remained the +MAP columns. Dissolved Pb concentrations were 〈0.05μmol/L in all column leachates. The data are consistent with a mechanism of PO4-enhanced release of As in the topsoil and subsequent promotion of As movement through the subsoil by continuing competition of dissolved As and PO4 for ion adsorption sites. The experimental results indicate that use of PO4-containing fertilizers on lead arsenate-contaminated soils has the potential to greatly enhance downward movement of soil As.
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  • 199
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    Water, air & soil pollution 99 (1997), S. 633-640 
    ISSN: 1573-2932
    Keywords: zebra mussel ; Dreissena polymorpha ; phosphorus ; trophic state ; recovery ; Lake Como
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract A large scale study on the western basin of Lake Como (N. Italy) was started in 1995 to examine the effects of the zebra mussel colonization which began in early '90. Our results have been related to '91-92 data (pre-Dreissena period), before the maximum colonization of zebra mussel. In spring and summer of the post-Dreissena period total phosphorus, P-PO4,, nitrate and chlorophyll values decreased, while ammonium and transparency increased at every sampling station. Zebra mussel does not modify the trophic state of this sub-basin but it plays an important role in nutrient cycling. The entire population can filter epilimnetic waters 2.1 times per year and can produce 2.9 × 104 t/y of pseudofaeces which are transferred to sediments.
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  • 200
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    Water, air & soil pollution 93 (1997), S. 243-254 
    ISSN: 1573-2932
    Keywords: arsenic ; lead ; phosphorus ; heavy metal ; mobility
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Past use of lead arsenate insecticides has resulted in elevated concentrations of lead (Pb) andarsenic (As) in topsoils of many existing and former deciduous tree fruit orchard sites throughoutthe world. Application of phosphate (PO4)-containing fertilizers to these soils can increase soil Assolubility, phytoavailability and downward mobility. A laboratory soil column experiment wasconducted to determine if As released by phosphate additions to a topsoil artificially contaminatedwith lead arsenate (1.65 mmol total Pb/kg; 1.10 mmol total As/kg) would be appreciably resorbedby the underlying uncontaminated subsoil. Treatments were a factorial combination of topsoilamendment with monoammonium phosphate (MAP, 0 or 16.67 mmol PO4/kg), and amount ofleaching (1, 5 and 10 pore volume displacements (PVD) with distilled water under saturated flowconditions). Soil As decreased in the topsoil with increasing amount of leaching and increased inthe subsoil. Addition of MAP substantially increased loss of topsoil. As, promoted As transportinto and through the subsoil, and increased dissolved As concentrations in the column leachates.After 10 PVDs, 95% of the initial soil As remained in the -MAP columns, while 56% of the initialsoil As remained the +MAP columns. Dissolved Pb concentrations were 〈0.05 µmol/Lin all column leachates. The data are consistent with a mechanism of PO4-enhanced release of Asin the topsoil and subsequent promotion of As movement through the subsoil by continuingcompetition of dissolved As and PO4 for ion adsorption sites. The experimental results indicatethat use of PO4-containing fertilizers on lead arsenate-contaminated soils has the potential togreatly enhance downward movement of soil As.
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