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  • Chemistry  (8,512)
  • Cell & Developmental Biology  (1,110)
  • General Chemistry  (1,050)
  • Chemical Engineering  (691)
  • SPACE RADIATION
  • 1995-1999
  • 1985-1989  (9,692)
  • 1970-1974
  • 1988  (9,692)
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  • 1995-1999
  • 1985-1989  (9,692)
  • 1970-1974
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  • 1
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    Characterization of a helical protein designed from first principles (1988)
    American Association for the Advancement of Science (AAAS)
    Details
    Publication Date: 1988-08-19
    Description: The question of how the primary amino acid sequence of a protein determines its three-dimensional structure is still unanswered. One approach to this problem involves the de novo design of model peptides and proteins that should adopt desired three-dimensional structures. A systematic approach was aimed at the design of a four-helix bundle protein. The gene encoding the designed protein was synthesized and the protein was expressed in Escherichia coli and purified to homogeneity. The protein was shown to be monomeric, highly helical, and very stable to denaturation by guanidine hydrochloride (GuHCl). Thus a globular protein has been designed that is capable of adopting a stable, folded structure in aqueous solution.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Regan, L -- DeGrado, W F -- New York, N.Y. -- Science. 1988 Aug 19;241(4868):976-8.〈br /〉〈span class="detail_caption"〉Author address: 〈/span〉E. I. du Pont de Nemours & Company, Central Research & Development Department, Wilmington, DE 19898.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/3043666" target="_blank"〉PubMed〈/a〉
    Keywords: Amino Acid Sequence ; Chemical Phenomena ; Chemistry ; Chromatography, Gel ; Escherichia coli/genetics ; Molecular Sequence Data ; Plasmids ; *Protein Conformation ; *Proteins/genetics
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 2
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    DNA binding by proteins (1988)
    American Association for the Advancement of Science (AAAS)
    Details
    Publication Date: 1988-09-02
    Description: Study of proteins that recognize specific DNA sequences has yielded much information, but the field is still in its infancy. Already two major structural motifs have been discovered, the helix-turn-helix and zinc finger, and numerous examples of DNA-binding proteins containing either of them are known. The restriction enzyme Eco RI uses yet a different motif. Additional motifs are likely to be found as well. There is a growing understanding of some of the physical chemistry involved in protein-DNA binding, but much remains to be learned before it becomes possible to engineer a protein that binds to a specific DNA sequence.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Schleif, R -- New York, N.Y. -- Science. 1988 Sep 2;241(4870):1182-7.〈br /〉〈span class="detail_caption"〉Author address: 〈/span〉Graduate Department of Biochemistry, Brandeis University, Waltham, MA 02254.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/2842864" target="_blank"〉PubMed〈/a〉
    Keywords: Amino Acids/metabolism ; Binding Sites ; Chemical Phenomena ; Chemistry ; DNA/metabolism ; DNA Restriction Enzymes/metabolism ; DNA-Binding Proteins/*metabolism ; Deoxyribonuclease EcoRI ; Electrochemistry ; Nucleic Acids/metabolism ; Protein Conformation ; Zinc
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 3
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    Introduction of nucleophiles and spectroscopic probes into antibody combining sites (1988)
    American Association for the Advancement of Science (AAAS)
    Details
    Publication Date: 1988-11-18
    Description: A general chemical strategy has been developed whereby antibody combining sites can be selectively derivatized with natural or synthetic molecules, such as catalytic groups, drugs, metals, or reporter molecules. Cleavable affinity labels were used to selectively introduce a thiol into the combining site of the immunoglobulin A MOPC 315. This thiol acted both as a nucleophile to accelerate ester thiolysis 60,000-fold and as a handle for selectively derivatizing the antibody with additional functional groups. For example, derivatization of the antibody with a fluorophore made possible a direct spectroscopic assay of antibody-ligand complexation. This chemistry should not only extend our ability to exploit antibody specificity in chemical catalysis, diagnostics, and therapeutics, but may also prove generally applicable to the functional modification of other proteins for which detailed structural information is unavailable.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Pollack, S J -- Nakayama, G R -- Schultz, P G -- AI24695-02/AI/NIAID NIH HHS/ -- New York, N.Y. -- Science. 1988 Nov 18;242(4881):1038-40.〈br /〉〈span class="detail_caption"〉Author address: 〈/span〉Department of Chemistry, University of California, Berkeley 94720.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/3194752" target="_blank"〉PubMed〈/a〉
    Keywords: Affinity Labels ; Animals ; *Antigen-Antibody Reactions ; *Binding Sites, Antibody ; Chemical Phenomena ; Chemistry ; Dinitrobenzenes ; Immunoglobulin Fab Fragments ; Mice ; Spectrometry, Fluorescence ; Sulfhydryl Compounds
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
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  • 4
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    Insights into enzyme function from studies on mutants of dihydrofolate reductase (1988)
    American Association for the Advancement of Science (AAAS)
    Details
    Publication Date: 1988-03-04
    Description: Kinetic analysis and protein mutagenesis allow the importance of individual amino acids in ligand binding and catalysis to be assessed. A kinetic analysis has shown that the reaction catalyzed by dihydrofolate reductase is optimized with respect to product flux, which in turn is predetermined by the active-site hydrophobic surface. Protein mutagenesis has revealed that specific hydrophobic residues contribute 2 to 5 kilocalories per mole to ligand binding and catalysis. The extent to which perturbations within this active-site ensemble may affect catalysis is discussed in terms of the constraints imposed by the energy surface for the reaction.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Benkovic, S J -- Fierke, C A -- Naylor, A M -- GM24129/GM/NIGMS NIH HHS/ -- New York, N.Y. -- Science. 1988 Mar 4;239(4844):1105-10.〈br /〉〈span class="detail_caption"〉Author address: 〈/span〉Department of Chemistry, Pennsylvania State University, University Park 16802.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/3125607" target="_blank"〉PubMed〈/a〉
    Keywords: Binding Sites ; Catalysis ; Chemical Phenomena ; Chemistry ; Escherichia coli/enzymology ; Kinetics ; Lactobacillus casei/enzymology ; *Mutation ; Structure-Activity Relationship ; Tetrahydrofolate Dehydrogenase/genetics/*metabolism ; Thermodynamics
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
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  • 5
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    Induction of an antibody that catalyzes the hydrolysis of an amide bond (1988)
    American Association for the Advancement of Science (AAAS)
    Details
    Publication Date: 1988-09-02
    Description: Catalysis of amide bond hydrolysis is of singular importance in enzymology. An antibody was induced to an analog of a high-energy intermediate anticipated along the reaction coordinate of amide hydrolysis. This antibody is an amidase with high specificity and a large rate enhancement (250,000) relative to the uncatalyzed reaction. This reaction represents the kinetically most difficult hydrolysis reaction yet catalyzed by an antibody.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Janda, K D -- Schloeder, D -- Benkovic, S J -- Lerner, R A -- New York, N.Y. -- Science. 1988 Sep 2;241(4870):1188-91.〈br /〉〈span class="detail_caption"〉Author address: 〈/span〉Department of Molecular Biology, Research Institute of Scripps Clinic, La Jolla, CA 92037.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/3413482" target="_blank"〉PubMed〈/a〉
    Keywords: Amidohydrolases/metabolism ; Animals ; Antibodies, Monoclonal/biosynthesis/*physiology ; Antibody Specificity ; Antigens/immunology ; *Catalysis ; Chemical Phenomena ; Chemistry ; Hemocyanin/analogs & derivatives/immunology ; Hydrolysis ; Immunization ; Kinetics ; Mice ; Organophosphorus Compounds/immunology ; Substrate Specificity
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 6
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    The S1-sensitive form of d(C-T)n.d(A-G)n: chemical evidence for a three-stranded structure in plasmids (1988)
    American Association for the Advancement of Science (AAAS)
    Details
    Publication Date: 1988-09-30
    Description: Homopurine-homopyrimidine sequences that flank certain actively transcribed genes are hypersensitive to single strand-specific nucleases such as S1. This has raised the possibility that an unusual structure exists in these regions that might be involved in recognition or regulation. Several of these sequences, including d(C-T)n.d(A-G)n, are known to undergo a transition in plasmids to an underwound state that is hypersensitive to single strand-specific nucleases; this transition occurs under conditions of moderately acid pH and negative supercoiling. Chemical probes were used to examine the reactivity of a restriction fragment from a human U1 gene containing the sequence d(C-T)18.d(A-G)18 as a function of supercoiling and pH, and thus analyze the structure in this region. Hyperreactivity was seen in the center and at one end of the (C-T)n tract, and continuously from the center to the same end of the (A-G)n tract, in the presence of supercoiling and pH less than or equal to 6.0. These results provide strong support for a triple-helical model recently proposed for these sequences and are inconsistent with other proposed structures.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Johnston, B H -- New York, N.Y. -- Science. 1988 Sep 30;241(4874):1800-4.〈br /〉〈span class="detail_caption"〉Author address: 〈/span〉Department of Biology, Massachusetts Institute of Technology, Cambridge 02139.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/2845572" target="_blank"〉PubMed〈/a〉
    Keywords: Base Sequence ; Chemical Phenomena ; Chemistry ; *Dna ; DNA, Superhelical ; Endonucleases/*metabolism ; Hydrogen-Ion Concentration ; Molecular Sequence Data ; *Nucleic Acid Conformation ; Plasmids ; Single-Strand Specific DNA and RNA Endonucleases
    Print ISSN: 0036-8075
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  • 7
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    Structural and functional roles of glycosyl-phosphatidylinositol in membranes (1988)
    American Association for the Advancement of Science (AAAS)
    Details
    Publication Date: 1988-01-15
    Description: Glycosylated forms of phosphatidylinositol, which have only recently been described in eukaryotic organisms, are now known to play important roles in biological membrane function. These molecules can serve as the sole means by which particular cell-surface proteins are anchored to the membrane. Lipids with similar structures may also be involved in signal transduction mechanisms for the hormone insulin. The utilization of this novel class of lipid molecules for these two distinct functions suggests new mechanisms for the regulation of proteins in biological membranes.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Low, M G -- Saltiel, A R -- DK33804/DK/NIDDK NIH HHS/ -- GM35873/GM/NIGMS NIH HHS/ -- New York, N.Y. -- Science. 1988 Jan 15;239(4837):268-75.〈br /〉〈span class="detail_caption"〉Author address: 〈/span〉Department of Physiology and Cellular Biophysics, College of Physicians and Surgeons of Columbia University, New York, NY 10032.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/3276003" target="_blank"〉PubMed〈/a〉
    Keywords: Animals ; Cell Membrane/*physiology ; Chemical Phenomena ; Chemistry ; Glycolipids/biosynthesis/*physiology ; Glycosylation ; Humans ; Hydrolysis ; Insulin/physiology ; Membrane Lipids/physiology ; Membrane Proteins/physiology ; Phosphatidylinositols/biosynthesis/*physiology ; Phospholipases/metabolism ; Phospholipid Ethers/biosynthesis/physiology ; Trypanosoma brucei brucei/metabolism
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
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  • 8
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    The design of molecular hosts, guests, and their complexes (1988)
    American Association for the Advancement of Science (AAAS)
    Details
    Publication Date: 1988-05-06
    Description: The origins, definitions, tools, and guiding principles of host-guest chemistry are developed. Perching, nesting, and capsular complexes are exemplified through molecular model and crystal structure comparisons. The degree of preorganization of a host for binding is a central determinant of its binding power. Complementarity of binding site placement in host and guest is a central determinant of structural recognition in complexation. Examples are given of chiral recognition in complexation, of partial transacylase mimics, of caviplexes, and of a synthetic molecular cell.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Cram, D J -- New York, N.Y. -- Science. 1988 May 6;240(4853):760-7.〈br /〉〈span class="detail_caption"〉Author address: 〈/span〉Department of Chemistry and Biochemistry, University of California, Los Angeles 90024.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/3283937" target="_blank"〉PubMed〈/a〉
    Keywords: Acylation ; Binding Sites ; Chemical Phenomena ; Chemistry ; Crystallization ; Enzymes ; *Models, Chemical ; Models, Molecular ; Nucleic Acids ; Thermodynamics
    Print ISSN: 0036-8075
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  • 9
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    Toxic DNA damage by hydrogen peroxide through the Fenton reaction in vivo and in vitro (1988)
    American Association for the Advancement of Science (AAAS)
    Details
    Publication Date: 1988-04-29
    Description: Exposure of Escherichia coli to low concentrations of hydrogen peroxide results in DNA damage that causes mutagenesis and kills the bacteria, whereas higher concentrations of peroxide reduce the amount of such damage. Earlier studies indicated that the direct DNA oxidant is a derivative of hydrogen peroxide whose formation is dependent on cell metabolism. The generation of this oxidant depends on the availability of both reducing equivalents and an iron species, which together mediate a Fenton reaction in which ferrous iron reduces hydrogen peroxide to a reactive radical. An in vitro Fenton system was established that generates DNA strand breaks and inactivates bacteriophage and that also reproduces the suppression of DNA damage by high concentrations of peroxide. The direct DNA oxidant both in vivo and in this in vitro system exhibits reactivity unlike that of a free hydroxyl radical and may instead be a ferryl radical.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Imlay, J A -- Chin, S M -- Linn, S -- GM19020/GM/NIGMS NIH HHS/ -- P30ES01896/ES/NIEHS NIH HHS/ -- New York, N.Y. -- Science. 1988 Apr 29;240(4852):640-2.〈br /〉〈span class="detail_caption"〉Author address: 〈/span〉Department of Biochemistry, University of California, Berkeley 94720.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/2834821" target="_blank"〉PubMed〈/a〉
    Keywords: Bacteriophage lambda ; Chemical Phenomena ; Chemistry ; *DNA Damage ; DNA Repair ; DNA, Bacterial/*drug effects ; Escherichia coli/drug effects/*genetics ; Ferrous Compounds ; Free Radicals ; Hydrogen Peroxide/administration & dosage/*pharmacology ; Hydrogen-Ion Concentration ; Hydroxides ; Hydroxyl Radical ; Oxidation-Reduction
    Print ISSN: 0036-8075
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    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 10
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    DNA damage and oxygen radical toxicity (1988)
    American Association for the Advancement of Science (AAAS)
    Details
    Publication Date: 1988-06-03
    Description: A major portion of the toxicity of hydrogen peroxide in Escherichia coli is attributed to DNA damage mediated by a Fenton reaction that generates active forms of hydroxyl radicals from hydrogen peroxide, DNA-bound iron, and a constant source of reducing equivalents. Kinetic peculiarities of DNA damage production by hydrogen peroxide in vivo can be reproduced by including DNA in an in vitro Fenton reaction system in which iron catalyzes the univalent reduction of hydrogen peroxide by the reduced form of nicotinamide adenine dinucleotide (NADH). To minimize the toxicity of oxygen radicals, the cell utilizes scavengers of these radicals and DNA repair enzymes. On the basis of observations with the model system, it is proposed that the cell may also decrease such toxicity by diminishing available NAD(P)H and by utilizing oxygen itself to scavenge active free radicals into superoxide, which is then destroyed by superoxide dismutase.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Imlay, J A -- Linn, S -- New York, N.Y. -- Science. 1988 Jun 3;240(4857):1302-9.〈br /〉〈span class="detail_caption"〉Author address: 〈/span〉University of California, Berkeley.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/3287616" target="_blank"〉PubMed〈/a〉
    Keywords: Chemical Phenomena ; Chemistry ; *DNA Damage ; DNA, Bacterial/*drug effects ; Escherichia coli/drug effects/*genetics ; Free Radicals ; Hydrogen Peroxide/*pharmacology ; Iron ; NAD/metabolism ; Oxidation-Reduction ; Oxygen/*metabolism
    Print ISSN: 0036-8075
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  • 11
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    Escherichia coli aspartate transcarbamylase: the relation between structure and function (1988)
    American Association for the Advancement of Science (AAAS)
    Details
    Publication Date: 1988-08-05
    Description: The x-ray structures of the allosteric enzyme aspartate transcarbamylase from Escherichia coli have been solved and refined for both allosteric forms. The T form was determined in the presence of the heterotropic inhibitor cytidine triphosphate, CTP, while the R form was determined in the presence of the bisubstrate analog N-phosphonacetyl-L-aspartate. These two x-ray structures provide the starting point for an understanding of how allosteric enzymes are able to control the rates of metabolic pathways. Insights into the mechanisms of both catalysis and homotropic cooperativity have been obtained by using site-directed mutagenesis to probe residues thought to be critical to the function of the enzyme based on these x-ray structures.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Kantrowitz, E R -- Lipscomb, W N -- GM 06920/GM/NIGMS NIH HHS/ -- GM26237/GM/NIGMS NIH HHS/ -- New York, N.Y. -- Science. 1988 Aug 5;241(4866):669-74.〈br /〉〈span class="detail_caption"〉Author address: 〈/span〉Department of Chemistry, Boston College, MA 02167.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/3041592" target="_blank"〉PubMed〈/a〉
    Keywords: Allosteric Regulation ; Allosteric Site ; Aspartate Carbamoyltransferase/*physiology ; Binding Sites ; Chemical Phenomena ; Chemistry ; Escherichia coli/*enzymology ; Macromolecular Substances ; Protein Conformation ; Structure-Activity Relationship
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  • 12
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    Structure of the lambda complex at 2.5 A resolution: details of the repressor-operator interactions (1988)
    American Association for the Advancement of Science (AAAS)
    Details
    Publication Date: 1988-11-11
    Description: The crystal structure of a complex containing the DNA-binding domain of lambda repressor and a lambda operator site was determined at 2.5 A resolution and refined to a crystallographic R factor of 24.2 percent. The complex is stabilized by an extensive network of hydrogen bonds between the protein and the sugar-phosphate backbone. Several side chains form hydrogen bonds with sites in the major groove, and hydrophobic contacts also contribute to the specificity of binding. The overall arrangement of the complex is quite similar to that predicted from earlier modeling studies, which fit the protein dimer against linear B-form DNA. However, the cocrystal structure reveals important side chain-side chain interactions that were not predicted from the modeling or from previous genetic and biochemical studies.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Jordan, S R -- Pabo, C O -- GM-31471/GM/NIGMS NIH HHS/ -- New York, N.Y. -- Science. 1988 Nov 11;242(4880):893-9.〈br /〉〈span class="detail_caption"〉Author address: 〈/span〉Department of Biophysics, Howard Hughes Medical Institute, Johns Hopkins University School of Medicine, Baltimore, MD 21205.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/3187530" target="_blank"〉PubMed〈/a〉
    Keywords: Base Composition ; Base Sequence ; Binding Sites ; Chemical Phenomena ; Chemistry ; Crystallization ; DNA/*metabolism ; *DNA-Binding Proteins ; Glutamine/metabolism ; Hydrogen Bonding ; Molecular Sequence Data ; Molecular Structure ; Nucleic Acid Conformation ; *Operator Regions, Genetic ; Protein Binding ; Protein Conformation ; Repressor Proteins/genetics/*metabolism ; Sugar Phosphates/metabolism ; Transcription Factors/*metabolism ; Viral Proteins ; Viral Regulatory and Accessory Proteins
    Print ISSN: 0036-8075
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  • 13
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    Magnetically induced neutrino oscillations and neutrino refractive effects in the early universe (1988)
    In:  Other Sources
    Details
    Publication Date: 2011-08-19
    Description: The interrelation between hypothetical neutrino magnetic dipole moments (MDMs) and primeval magnetic fields is discussed. The parameter range over which these possibilities are mutually exclusive is determined, taking into account for the first time neutrino refractive effects in the early universe. It is shown that an independent determination of either the neutrino MDMs or the primeval magnetic field strength would set powerful bounds on the other quantity.
    Keywords: SPACE RADIATION
    Type: Physical Review Letters (ISSN 0031-9007); 60; 879-881
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    NASA TECHNICAL REPORTS
  • 14
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    Correlation mass method for analysis of neutrinos from supernova 1987A (1988)
    In:  Other Sources
    Details
    Publication Date: 2011-08-19
    Description: Application of a time-energy correlation method to the Kamiokande II (KII) observations of neutrinos apparently emitted from supernova 1987A has yielded a neutrino rest mass of 3.6 eV. A Monte Carlo analysis shows a reconfirming probabilty distribution for the neutrino rest mass peaked at 2.8, and dropping to 50 percent of the peak at 1.4 and 4.8 eV. Although the KII data indicate a very short time scale of emission, over an extended period on the order of 10 sec, both data from the Irvine-Michigan-Brookhaven experiment and the KII data show a tendency for the more energetic neutrinos to be emitted earlier at the source, suggesting the possibility of cooling.
    Keywords: SPACE RADIATION
    Type: Astrophysical Journal, Part 1 (ISSN 0004-637X); 329; 326-334
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    NASA TECHNICAL REPORTS
  • 15
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    Gamma-ray line emission from SN1987A (1988)
    In:  Other Sources
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    Publication Date: 2011-08-19
    Description: The inferred average line flux at about 847 keV in the background-subtracted spectrum of SN1987A from August 1 to October 31, 1987 is about (1.0 + or - 0.25) x 10 to the -3rd photons/sq cm/s at an energy of 843 + or - 5 keV. This feature cannot be explained by any statistical or systematic fluctuations observed in the seven previous years of gamma-ray spectrometer data. There is also evidence for the 1238-keV line from Co-56 decay, with an average flux of about (6 + or - 2) x 10 to the -4th photons/sq cm/s. This observation confirms that Co-56 is present in the supernova ejecta and that nucleosynthesis occurred during the explosion.
    Keywords: SPACE RADIATION
    Type: Nature (ISSN 0028-0836); 331; 416-418
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    NASA TECHNICAL REPORTS
  • 16
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    The origin and location of the 5 March 1979 gamma-ray burst (1988)
    In:  Other Sources
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    Publication Date: 2011-08-19
    Description: Evidence and arguments concerning the origin and location of the gamma-ray burst (GRB) of March 5, 1979 are reviewed. This GRB has been positionally identified with the SNR 49 in the LMC. Such an association would fix the GRB's distance at 55 kpc, and the observed flux from the GRB would require prodigious energy and luminosity, casting doubt on the GRB's distance and its association with the LMC. Some Kosmos 856 observations which may provide more direct evidence on the energy released are discussed.
    Keywords: SPACE RADIATION
    Type: Nature (ISSN 0028-0836); 331; 320
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    NASA TECHNICAL REPORTS
  • 17
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    A benchmark for galactic cosmic-ray transport codes (1988)
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    Details
    Publication Date: 2011-08-19
    Description: A nontrivial analytic benchmark solution for galactic cosmic ray transport is presented for use in transport code validation. Computational accuracy for a previously-developed cosmic ray transport code is established to within one percent by comparison with this exact benchmark. Hence, solution accuracy for the transport problem is mainly limited by inaccuracies in the input spectra, input interaction databases, and the use of a straight ahead/velocity-conserving approximation.
    Keywords: SPACE RADIATION
    Type: Radiation Research (ISSN 0033-7587); 114; 201-206
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    Calculations of rates for direct detection of neutralino dark matter (1988)
    In:  Other Sources
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    Publication Date: 2011-08-19
    Description: The detection rates in cryogenic detectors of neutralinos, the most well motivated supersymmetric dark-matter candidate, are calculated. These rates can differ greatly from the special case of pure photinos and pure Higgsinos which are usually considered. In addition, a new term is found in the elastic-scattering cross section proportional to the Z-ino component which is 'spin independent', even for these Majorana particles. As a result, substantial detection rates exist for previously disfavored, mostly spinless materials such as germanium and mercury.
    Keywords: SPACE RADIATION
    Type: Physical Review Letters (ISSN 0031-9007); 61; 666-669
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  • 19
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    The charge state of the anomalous cosmic-ray component (1988)
    In:  Other Sources
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    Publication Date: 2011-08-19
    Description: H, He, and O cosmic-ray energy spectra obtained in the outer heliosphere by the Voyager 2 and Pioneer 10 spacecraft during the most recent periods of declining solar activity are presented graphically and analyzed. The recovery of high-rigidity particles is shown to be significantly delayed relative to that of the low-rigidity particles. This finding and the demodulated source spectra are attributed to the presence of singly ionized anomalous He and O, as predicted by Fisk et al. (1974).
    Keywords: SPACE RADIATION
    Type: Astrophysical Journal, Part 2 - Letters (ISSN 0004-637X); 333; L109-L11
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    Shot noise cross-correlation functions and cross spectra - Implications for models of QPO X-ray sources (1988)
    In:  Other Sources
    Details
    Publication Date: 2011-08-19
    Description: The cross-correlation functions (CCFs) and cross spectra expected for quasi-periodic oscillation (QPO) shot noise models are calculated under various assumptions, and the results are compared to observations. Effects due to possible coherence of the QPO oscillations are included. General formulas for the cross spectrum, the cross-phase spectrum, and the time-delay spectrum for QPO shot models are calculated and discussed. It is shown that the CCFs, cross spectra, and power spectra observed for Cyg X-e2 imply that the spectrum of the shots evolves with time, with important implications for the interpretation of these functions as well as of observed average energy spectra. The possible origins for the observed hard lags are discussed, and some physical difficulties for the Comptonization model are described. Classes of physical models for QPO sources are briefly addressed, and it is concluded that models involving shot formation at the surface of neutron stars are favored by observation.
    Keywords: SPACE RADIATION
    Type: Astrophysical Journal, Part 1 (ISSN 0004-637X); 331; 247-260
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  • 21
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    Benchmark solutions for the galactic ion transport equations with spatial and energy coupling (1988)
    In:  CASI
    Details
    Publication Date: 2013-08-31
    Description: In order to anticipate future space shielding requirements, NASA has initiated an effort to formulate computational methods to simulate radiation effects in space. As part of the program, numerical transport algorithms have been developed for the deterministic Boltzman equation describing galactic cosmic ray (GCR) interactions with matter. It thus becomes necessary to assess the accuracy of proposed deterministic algorithms. For this reason, analytical benchmark solutions to mathematically tractable galactic cosmic ray equations have recently been obtained. Even though these problems involve simplifying assumptions of the associated physics, they still contain the essential features of the basic transport processes. The solutions obtained are features of the basic transport processes. The solutions obtained are compared to results from numerical algorithms in order to ensure proper coding and to provide a measure of the accuracy of the numerical methods used in the algorithm. For the first time, mathematical methods have been applied to the galactic ion transport (GIT) equations in the straight ahead approximation with constant nuclear properties. The approach utilizes a Laplace transforms inversion yielding a closed form benchmark solution which is also computationally efficient.
    Keywords: SPACE RADIATION
    Type: Hampton Inst., NASA/American Society for Engineering Educ; Hampton Inst., NASA(
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  • 22
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    Cosmic-ray detectors on the Moon (1988)
    In:  CASI
    Details
    Publication Date: 2013-08-31
    Description: The state of cosmic ray physics is reviewed. It is concluded that the nonexistent lunar magnetic field, the low lunar radiation background, and the lack of an atmosphere on the Moon provide an excellent environment for the study of high energy primary cosmic rays.
    Keywords: SPACE RADIATION
    Type: NASA, Lyndon B. Johnson Space Center, Future Astronomical Observatories on the Moon; p 55-62
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  • 23
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    Gradients of galactic cosmic rays and anomalous components (1988)
    In:  CASI
    Details
    Publication Date: 2013-08-31
    Description: Measurements of radial and latitudinal gradients of galactic cosmic rays and anomalous components now cover radii from 0.3 to 40 AU from the sun and latitudes up to 30 deg above the ecliptic plane for particle energies from approx. 10 MeV/n up to relativistic energies. The most accurate measurements cover the period 1972 through 1987, which includes more than one full 11 year cycle of solar activity. Radial gradients for glactic cosmic rays of all energies and species are small (similar to less than 10 percent AU), and variable in time, reaching a minimum of near 0 percent AU out to 30 AU for some species at solar maximum. Gradients for anomalous components are larger, of order 15 percent AU, may show similar time variability, and are relatively independent of particle species and energy. For the period 1985 through 1986 the intensity decreased away from the ecliptic for all species and energies. For galactic cosmic rays, the measured gradients are approx. 0.5 percent/degree near 20 AU, while for anomalous components the gradients are larger, ranging from 3 to 6 percent/degree. Comparison with a similar measurement for anomalous helium in 1975 through 1976 suggests that the latitude gradients for anomalous components have changed sign between 1975 and 1985. For galactic cosmic rays, the available evidence suggests no change in sign of the latitudinal gradient for relativistic particles.
    Keywords: SPACE RADIATION
    Type: Jet Propulsion Lab., California Inst. of Tech., Interplanetary Particle Environment. Proceedings of a Conference; p 135-148
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    Current models of the intensely ionizing particle environment in space (1988)
    In:  CASI
    Details
    Publication Date: 2013-08-31
    Description: The Cosmic Ray Effects on MicroElectronics (CREME) model that is currently in use to estimate single event effect rates in spacecraft is described. The CREME model provides a description of the radiation environment in interplanetary space near the orbit of the earth that contains no major deficiencies. The accuracy of the galactic cosmic ray model is limited by the uncertainties in solar modulation. The model for solar energetic particles could be improved by making use of all the data that has been collected on solar energetic particle events. There remain major uncertainties about the environment within the earth's magnetosphere, because of the uncertainties over the charge states of the heavy ions in the anomalous component and solar flares, and because of trapped heavy ions. The present CREME model is valid only at 1 AU, but it could be extended to other parts of the heliosphere. There is considerable data on the radiation environment from 0.2 to 35 AU in the ecliptic plane. This data could be used to extend the CREME model.
    Keywords: SPACE RADIATION
    Type: Jet Propulsion Lab., California Inst. of Tech., Interplanetary Particle Environment. Proceedings of a Conference; p 49-56
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  • 25
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    Angular response calibration of the burst and transient source experiment (1988)
    In:  CASI
    Details
    Publication Date: 2013-08-31
    Description: The Gamma Ray Observatory includes four experiments designed to observe the gamma-ray universe. Laboratory measurements to test the response the Burst and Transient Source Experiment (BATSE) modules to gamma-ray sources that are non-axial were recently completed. The results of these observations are necessary for the correct interpretation of BATSE data obtained after it is put in Earth orbit. The launch is planned for March, 1900. Preliminary analyses of these test data show the presence of a radial dependence to the detector's light collection efficiency. It is proposed to evaluate the importance of this radial response, analyze future experimental data to derive the actual functional dependence on radius, and calculate the net effect on the output spectrum as a function of the angle of incidence.
    Keywords: SPACE RADIATION
    Type: Alabama Univ., Research Reports: 1988 NASA(ASEE Summer Faculty Fellowship Program; 34 p
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  • 26
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    Toward a descriptive model of galactic cosmic rays in the heliosphere (1988)
    In:  CASI
    Details
    Publication Date: 2013-08-31
    Description: Researchers review the elements that enter into phenomenological models of the composition, energy spectra, and the spatial and temporal variations of galactic cosmic rays, including the so-called anomalous cosmic ray component. Starting from an existing model, designed to describe the behavior of cosmic rays in the near-Earth environment, researchers suggest possible updates and improvements to this model, and then propose a quantitative approach for extending such a model into other regions of the heliosphere.
    Keywords: SPACE RADIATION
    Type: Interplanetary Particle Environment. Proceedings of a Conference; p 14-32
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  • 27
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    High energy gamma-ray observations of SN 1987A (1988)
    In:  Other Sources
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    Publication Date: 2011-08-19
    Description: Results are presented from observations of SN 1987A made with a combined high energy gamma ray and hard X-ray payload carried on a balloon flight over Alice Springs, Australia on April 5, 1988. The payload instrumentation is described, emphasizing the characteristics of the gamma-ray detector. The gamma-ray emission profile is illustrated and the preliminary results of the observations are summarized.
    Keywords: SPACE RADIATION
    Type: Astronomical Society of Australia, Proceedings (ISSN 0066-9997); 7; 4, 19; 486-489
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  • 28
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    On the high-energy gamma-ray signature of cosmic-ray sources (1988)
    In:  Other Sources
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    Publication Date: 2011-08-19
    Description: Monte Carlo simulations of the gamma-ray emission from hypothetical cosmic-ray sources are performed. Sources which might correspond to acceleration by supernova shocks in 'average' interstellar conditions and deep within giant molecular clouds are considered. The consequences of dropping the common assumption that the cosmic-ray spectrum at the sources is the same as that observed at earth are examined. Spectral effects which can be related to the depth of the material shroud and the population of accelerated particles are explored using these simulations and are described. The results are compared with the COS B catalog of gamma-ray sources, and the implications for the underlying particle populations and source mechanisms are discussed.
    Keywords: SPACE RADIATION
    Type: Astrophysical Journal, Part 1 (ISSN 0004-637X); 334; 722-733
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  • 29
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    Upper limits to the high-energy gamma-ray and hard X-ray flux from SN 1987A on day 55 (1988)
    In:  Other Sources
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    Publication Date: 2011-08-19
    Description: A balloon-borne experiment was carried out on April 19, 1987 from Alice Springs, Australia to detect high-energy gamma-rays and hard X-rays from the supernova SN 1987A in the Large Magellanic Cloud. An optical spark chamber for measuring the high-energy gamma-rays and a multiwire proportional counter for measuring the hard X-rays shared a common balloon platform. No positive emission was observed by either detector. The gamma-ray upper limit obtained indicates that either the expanding supernova shell was opaque to gamma-rays at the time of the flight, or that the supernova cosmic ray luminosity was less than about 10 to the 40th erg/s. The X-ray upper limit obtained confirms the opacity of the shell to Comptonized hard X-rays.
    Keywords: SPACE RADIATION
    Type: Royal Astronomical Society, Monthly Notices (ISSN 0035-8711); 234; 73P-77P
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  • 30
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    Evidence for cyclotron absorption from spectral features in gamma-ray bursts seen with Ginga (1988)
    In:  Other Sources
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    Publication Date: 2011-08-19
    Description: New observations by the gamma-ray burst detector on board the Ginga satellite, which has two well-calibrated detectors covering a wide energy range of 1.5 to 375 keV, are reported. The spectral features obtained are consistent with first and second cyclotron harmonics. This finding is taken as strong evidence for the magnetized neutron star model of gamma-ray bursts.
    Keywords: SPACE RADIATION
    Type: Nature (ISSN 0028-0836); 335; 234
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  • 31
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    Galactic cosmic rays in three dimensions (1988)
    In:  Other Sources
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    Publication Date: 2019-01-25
    Description: A general conclusion is that the cosmic rays increase with increasing distance from the Sun at approximately 2 percent a.u. There is a strong correlation of the cosmic ray intensity with distance with the tilt of the heliospheric current sheet. Moreover, researchers find that the variation of the cosmic rays with time changes in alternate sun spot cycles. Finally, it seems that during alternate sun spot minima (1965 and 1985) the cosmic rays access to the inner solar system was along the equatorial current sheet, wheras in 1975 the cosmic rays came in over the poles. The recently discovered anomalous component of cosmic rays is very much related to this whole problem, and probably corresponds to particles being accelerated at the termination of the solar wind at some 50 to 100 astonomical units from the sun. In summary, many predictions of the models remain controversial in detail. Nonetheless, it appears now that we can expect more cosmic rays over the poles in the next sunspot cycle, and the intensity will continue to increase with heliocentric radius out to the interstellar medium.
    Keywords: SPACE RADIATION
    Type: Jet Propulsion Lab., California Inst. of Tech., Interplanetary Particle Environment. Proceedings of a Conference; p 162-163
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  • 32
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    Measurement of C-12, O-16, and Fe-56 charge changing cross sections in helium at high energy, comparison with cross sections in hydrogen, and application to cosmic-ray propagation (1988)
    In:  CASI
    Details
    Publication Date: 2019-06-28
    Description: We present measurements of the spallation cross sections of carbon, oxygen, and iron in helium and hydrogen, at beam energies from 540 to 1600 MeV/nucleon, performed by exposing liquid helium, CH2, and C targets. Charge changing cross sections are reported for fragments down to Ne for Fe + alpha and Fe + p reactions, and down to B for O + alpha, O + p, C + alpha, and C + p reactions. Alpha- to p-induced cross section ratios (sigma(sub alpha)/sigma(sub p)) are determined at the same energy per nucleon. From these measurements an empirical formula for the (sigma(sub alpha)/sigma(sub p)) ratios is derived and is found in good agreement with available isotopic cross sections data from radioactivity and radiochemical techniques. These results are applied to the propagation of heavy charged cosmic rays in an interstellar medium with a helium to hydrogen abundance ratio of 0.10. It is shown that the Sc-Mn/Fe ratio prediction is decreased relative to the B/C ratio when compared to propagation calculations in a pure hydrogen interstellar medium.
    Keywords: SPACE RADIATION
    Type: NASA-CR-190581 , NAS 1.26:190581
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    Elemental composition and energy spectra of galactic cosmic rays (1988)
    In:  CASI
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    Publication Date: 2019-06-28
    Description: A brief review is presented of the major features of the elemental composition and energy spectra of galactic cosmic rays. The requirements for phenomenological models of cosmic ray composition and energy spectra are discussed, and possible improvements to an existing model are suggested.
    Keywords: SPACE RADIATION
    Type: Jet Propulsion Lab., California Inst. of Tech., Interplanetary Particle Environment. Proceedings of a Conference; p 121-132
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    Preliminary estimates of galactic cosmic ray shielding requirements for manned interplanetary missions (1988)
    In:  CASI
    Details
    Publication Date: 2019-06-28
    Description: Estimates of radiation risk to the blood forming organs from galactic cosmic rays are presented for manned interplanetary missions. The calculations use the Naval Research Laboratory cosmic ray spectrum model as input into the Langley Research Center galactic cosmic ray transport code. This transport code, which transports both heavy ions and nucleons, can be used with any number of layers of target material, consisting of up to five different constituents per layer. Calculated galactic cosmic ray doses and dose equivalents behind various thicknesses of aluminum and water shielding are presented for solar maximum and solar minimum periods. Estimates of risk to the blood forming organs are made using 5 cm depth dose/dose equivalent values for water. These results indicate that at least 5 g/sq cm (5 cm) of water of 6.5 g/sq cm (2.4 cm) of aluminum shield is required to reduce annual exposure below the current recommended limit of 50 rem. Because of the large uncertainties in fragmentation parameters, and the input cosmic ray spectrum, these exposure estimates may be uncertain by as much as 70 percent. Therefore, more detailed analyses with improved inputs could indicate the need for additional shielding.
    Keywords: SPACE RADIATION
    Type: NASA-TM-101516 , NAS 1.15:101516
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    Solar-flare shielding with Regolith at a lunar-base site (1988)
    In:  CASI
    Details
    Publication Date: 2019-06-28
    Description: The Langley high energy nucleon transport computer code BRYNTRN is used to predict time-integrated radiation dose levels at the lunar surface due to high proton flux from solar flares. The study addresses the shielding requirements for candidate lunar habitat configurations necessary to protect crew members from these large and unpredictable radiation fluxes. Three solar proton events have been analyzed, and variations in radiation intensity in a shield medium due to the various primary particle energy distributions are predicted. Radiation dose predictions are made for various slab thicknesses of a lunar soil model. Results are also presented in the form of dose patterns within specific habitat configurations shielded with lunar material.
    Keywords: SPACE RADIATION
    Type: NASA-TP-2869 , L-16488 , NAS 1.60:2869
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    Cascade model of gamma-ray bursts: Power-law and annihilation-line components (1988)
    In:  CASI
    Details
    Publication Date: 2019-06-28
    Description: If, in a neutron star magnetosphere, an electron is accelerated to an energy of 10 to the 11th or 12th power eV by an electric field parallel to the magnetic field, motion of the electron along the curved field line leads to a cascade of gamma rays and electron-positron pairs. This process is believed to occur in radio pulsars and gamma ray burst sources. Results are presented from numerical simulations of the radiation and photon annihilation pair production processes, using a computer code previously developed for the study of radio pulsars. A range of values of initial energy of a primary electron was considered along with initial injection position, and magnetic dipole moment of the neutron star. The resulting spectra was found to exhibit complex forms that are typically power law over a substantial range of photon energy, and typically include a dip in the spectrum near the electron gyro-frequency at the injection point. The results of a number of models are compared with data for the 5 Mar., 1979 gamma ray burst. A good fit was found to the gamma ray part of the spectrum, including the equivalent width of the annihilation line.
    Keywords: SPACE RADIATION
    Type: NASA-TM-101176 , NAS 1.15:101176 , CSSA-ASTRO-88-13
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    The hard X-ray burst spectrometer event listing 1980-1987 (1988)
    In:  CASI
    Details
    Publication Date: 2019-06-28
    Description: This event listing is a comprehensive reference for the Hard X-ray bursts detected with the Hard X-ray Burst Spectrometer on the Solar Maximum Mission from the time of launch 14 February 1980 to December 1987. Over 8600 X-ray events were detected in the energy range from 30 to approx. 600 keV with the vast majority being solar flares. The listing includes the start time, peak time, duration and peak rate of each event.
    Keywords: SPACE RADIATION
    Type: NASA-TM-4036 , REPT-88B0124 , NAS 1.15:4036
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    Preliminary estimates of radiation exposures for manned interplanetary missions from anomalously large solar flare events (1988)
    In:  CASI
    Details
    Publication Date: 2019-06-28
    Description: Preliminary estimates of radiation exposures for manned interplanetary missions resulting from anomalously large solar flare events are presented. The calculations use integral particle fluences for the February 1956, November 1960, and August 1972 events as inputs into the Langley Research Center nucleon transport code BRYNTRN. This deterministic code transports primary and secondary nucleons (protons and neutrons) through any number of layers of target material of arbitrary thickness and composition. Contributions from target nucleus fragmentation and recoil are also included. Estimates of 5 cm depth doses and dose equivalents in tissue are presented behind various thicknesses of aluminum, water, and composite aluminum/water shields for each of the three solar flare events.
    Keywords: SPACE RADIATION
    Type: NASA-TM-100620 , NAS 1.15:100620
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    Time variation of galactic cosmic rays (1988)
    In:  CASI
    Details
    Publication Date: 2019-06-28
    Description: Time variations in the flux of galactic cosmic rays are the result of changing conditions in the solar wind. Maximum cosmic ray fluxes, which occur when solar activity is at a minimum, are well defined. Reductions from this maximum level are typically systematic and predictable but on occasion are rapid and unexpected. Models relating the flux level at lower energy to that at neutron monitor energy are typically accurate to 20 percent of the total excursion at that energy. Other models, relating flux to observables such as sunspot number, flare frequency, and current sheet tilt are phenomenological but nevertheless can be quite accurate.
    Keywords: SPACE RADIATION
    Type: Jet Propulsion Lab., California Inst. of Tech., Interplanetary Particle Environment. Proceedings of a Conference; p 149-161
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    A new proton fluence model for E greater than 10 MeV (1988)
    In:  CASI
    Details
    Publication Date: 2019-06-28
    Description: Researchers describe a new engineering model for the fluence of protons with energies greater than 10 MeV. The data set used is a combination of observations made primarily from the Earth's surface between 1956 and 1963 and observations made from spacecraft in the vicinity of Earth between 1963 and 1985. With this data set we find that the distinction between ordinary proton events and anomalously large proton events made in earlier work disappears. The greater than 10 MeV fluences at 1 AU calculated with the new model are about twice those expected on the basis of models now in use. In contrast to earlier models, results do not depend critically on the fluence from any one event.
    Keywords: SPACE RADIATION
    Type: Interplanetary Particle Environment. Proceedings of a Conference; p 58-71
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  • 41
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    The anomalous cosmic-ray component (1988)
    In:  CASI
    Details
    Publication Date: 2019-06-28
    Description: This brief report is intended to update the anomalous component section of the summary report of the galactic cosmic-ray working group (Mewaldt et al., 1987), which was drafted at the March 1987 Workshop on the Interplanetary Charged Particle Environment at the Jet Propulsion Laboratory. The description of the spectrum of the anomalous cosmic-ray component is contained in section 3.3 of that report. That description is based on data analyzed through day 310 of 1986, and in it we proposed that the energy spectrum of the various species of the anomalous component could be derived by scaling from two generic spectra. Two generic spectra were required because the energy spectrum of the anomalous component changed shape near the time of the solar magnetic field reversal in 1980. These two generic spectra are shown in Figure 2 of the summary report.
    Keywords: SPACE RADIATION
    Type: Jet Propulsion Lab., California Inst. of Tech., Interplanetary Particle Environment. Proceedings of a Conference; p 133-134
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  • 42
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    An all sky study of fast X-ray transients (1988)
    In:  CASI
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    Publication Date: 2019-06-28
    Description: In the HEAO 1 A-2 survey of fast X-ray transients, a search of 2 to 20 keV scanning data was made for brief increases in flux, greater than 4 millicrabs, on timescales approximately 1 to 10 to the 4th s above a 12-hour average. The search was divided into two regions, and all-sky survey of the Galaxy, and a survey of the Magellanic Clouds. In the latter, 37 events were found and identified with 4 of the 5 brighest sources in the LMC, plus 2 as flares from a foreground star. Np X-ray bursts, no gamma-ray bursts, and no events from the SMC were found. In the all-sky survey, after excluding well-known variable sources, out of the equivalent of approximately 104 days of data, 15 events were found which falling into 2 broad categories: flares from coronal sources, roughly isotropically distributed, with optically thin thermal spectra; and harder fast transients apparently distributed near the Galactic plane. The first were identified as flares from ubiquitous active cool dwarf stars. It was hypothesized that the second may have been from distant Be-neutron star binaries. However, at least two of the harder, more luminous events remained unidentified. Future research should examine the nature of these rare events, and how they may fit into a hierarchy of hard fast transients from gamma-ray bursts to outbursts from pulsar systems.
    Keywords: SPACE RADIATION
    Type: NASA-TM-89716 , REPT-88-014 , NAS 1.15:89716
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    BRYNTRN: A baryon transport computer code, computation procedures and data base (1988)
    In:  CASI
    Details
    Publication Date: 2019-06-28
    Description: The development is described of an interaction data base and a numerical solution to the transport of baryons through the arbitrary shield material based on a straight ahead approximation of the Boltzmann equation. The code is most accurate for continuous energy boundary values but gives reasonable results for discrete spectra at the boundary with even a relatively coarse energy grid (30 points) and large spatial increments (1 cm in H2O).
    Keywords: SPACE RADIATION
    Type: NASA-TM-4037 , L-16432 , NAS 1.15:4037
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    Gamma radiation background measurements from Spacelab 2 (1988)
    In:  CASI
    Details
    Publication Date: 2019-06-28
    Description: A Nuclear Radiation Monitor incorporating a NaI(Tl) scintillation detector was flown as part of the verification flight instrumentation on the Spacelab 2 mission, July 29 to August 6, 1985. Gamma-ray spectra were measured with better than 20 s resolution throughout most of the mission in the energy range 0.1 to 30 MeV. Knowledge of the decay characteristics and the geomagnetic dependence of the counting rates enable measurement of the various components of the Spacelab gamma-ray background: prompt secondary radiation, Earth albedo, and delayed induced radioactivity. The status of the data analysis and present relevant examples of typical background behavior are covered.
    Keywords: SPACE RADIATION
    Type: NASA-CR-183782 , NAS 1.26:183782 , SSL-PREPRINT-88-136
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    Solar cycle dependence of the radial gradient of cosmic ray intensity (1988)
    In:  Other Sources
    Details
    Publication Date: 2019-07-12
    Description: Observation of the interplanetary intensity of cosmic rays (Ep greater than 80 MeV) by Pioneers 10 and 11 now spans a 16-year time period 1972-1988 and heliocentric radial distances, out to 43.7 AU for Pioneer 10 and 25.8 AU for Pioneer 11. Solar modulation continues to be present at the current distances of both spacecraft. The radial gradient of intensity is measured continuously over the slowly varying, outward moving radial segment r10-r11. The 50-day mean values of the gradient G vary systematically and cyclically in phase with solar activity as measured by sunspot number, with a maximum value of about 2.1 percent/AU at sunspot maximum and a minimum value of about 1.2 percent/AU at sunspot minimum.
    Keywords: SPACE RADIATION
    Type: AD-A204377 , Geophysical Research Letters (ISSN 0094-8276); 15; 1527-153
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  • 46
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    The spatial distribution of ultraviolet line and continuum emission in Herbig-Haro objects (1988)
    In:  Other Sources
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    Publication Date: 2019-07-12
    Description: Archival IUE data and monochromatic CCD images in the optical range are used to compare the spatial distribution of UV and optical emission in HH 1, HH 2, HH 24, HH 32, HH 43, and HH 47. For all six objects, the observed UV radiation is shown to originate in the objects themselves. The results indicate that the C IV and semiforbidden emission-line regions are small. Although the continuum in the IUE short-wavelength range displays a distribution that is broader than that of any measured line emission in the UV or optical range, the continuum distribution in the IUE long-wavelength range is quite narrow.
    Keywords: SPACE RADIATION
    Type: Astronomical Journal (ISSN 0004-6256); 96; 1690-170
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  • 47
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    The Scintillating Optical Fiber Isotope Experiment (1988)
    In:  Other Sources
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    Publication Date: 2019-07-13
    Description: This paper describes the Scintillating Optical Fiber Isotope Experiment (SOFIE) which is being developed by Washington University and the University of New Hampshire to study the abundances of cosmic ray isotopes in the iron charge region. This detector system is a Cerenkov-Range-dE/dx experiment and utilizes range and trajectory detectors made of scintillating optical fibers, a fused silica Cerenkov counter, and plastic scintillator dE/dx counters to determine the charge and mass of cosmic ray nuclei. A brief description of the balloon flight instrument presently being developed will be given followed by initial results of an engineering model calibration at the LBL Bevalac heavy ion accelerator. In addition a brief discussion of the potential of scintillating fiber trajectory detectors for use in experiments requiring precise trajectory determination such as those being planned for the NASA Particle Astrophysics Magnet Facility (Astromag) program is presented.
    Keywords: SPACE RADIATION
    Type: Genesis and propagation of cosmic rays; Jun 01, 1986 - Jun 09, 1986; Erice; Italy
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  • 48
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    Recent improvement of spallation cross section calculations, applicable to cosmic ray physics (1988)
    In:  Other Sources
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    Publication Date: 2019-07-13
    Description: About half of the cosmic ray nuclei heavier than helium have suffered nuclear transformations while colliding with the interstellar gas. The semiempirical calculations developed for calculating the still unmeasured cross sections had errors of about 25-50 per cent, depending on the target mass interval. Recent precise measurements have permitted significant improvements in the calculation of cross sections. Several such improvements are discussed. A status report on work-in-progress is presented on a general modification of the spallation equation parameters.
    Keywords: SPACE RADIATION
    Type: Genesis and propagation of cosmic rays; Jun 01, 1986 - Jun 09, 1986; Erice; Italy
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  • 49
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    Ultra heavy nuclei in the cosmic radiation (1988)
    In:  Other Sources
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    Publication Date: 2019-07-13
    Description: This paper describes the measurements of the ultraheavy cosmic ray abundances obtained by the Heavy Nuclei Experiment aboard the NASA High Energy Astronomy Observatory-3. It is found that the cosmic ray abundances are in broad agreement with solar system abundances with a step-FIP fractionation model applied although in detail there are some differences. In particular, Ge and Pb appear to be underabundant in the cosmic radiation. Although the platinum/lead ratio and the actinides are consistent with some r-process enhancement, the cosmic ray source is not dominated by the r-process up through the 50s as evidenced by the Sr/Rb ratio and by the abundance of Sn and Ba. The actinides are not greatly enhanced, ruling out freshly synthesized r-process production as the primary source of the heavy cosmic rays.
    Keywords: SPACE RADIATION
    Type: Genesis and propagation of cosmic rays; Jun 01, 1986 - Jun 09, 1986; Erice; Italy
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  • 50
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    Galactic cosmic ray hydrogen and helium (1988)
    In:  Other Sources
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    Publication Date: 2019-07-13
    Description: This paper provides a summary of the spectra and propagation of the quartet of isotopes of hydrogen and helium which occur in arriving cosmic radiation. The unraveling of modulation effects is addressed, and the calculation of the local interstellar spectrum from a model of interstellar propagation is discussed. Two models for propagation are considered, one having an energy-independent mean pathlength and the other having an energy-dependent one.
    Keywords: SPACE RADIATION
    Type: Genesis and propagation of cosmic rays; Jun 01, 1986 - Jun 09, 1986; Erice; Italy
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  • 51
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    The Cosmic Ray Nuclei Experiment on the Spacelab-II mission (1988)
    In:  Other Sources
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    Publication Date: 2019-07-13
    Description: The Cosmic Ray Nuclei Experiment flown on the Spacelab-II mission was designed to measure the elemental composition of individual cosmic ray nuclei (Li to Ni) from 40 Gev/amu to several TeV/amu. The detector utilizes plastic scintillation counters for charge measurement, and gas Cerenkov and transition radiation detectors for energy measurements. The data analysis is in progress and results on the energy spectra are expected in the near future.
    Keywords: SPACE RADIATION
    Type: Genesis and propagation of cosmic rays; Jun 01, 1986 - Jun 09, 1986; Erice; Italy
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  • 52
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    Solar-cycle modulation of galactic cosmic rays (1988)
    In:  Other Sources
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    Publication Date: 2019-07-13
    Description: This paper describes a numerical solution of the spherically-symmetric, time-dependent, cosmic-ray modulation equation, compares it to data taken near the ecliptic, and probes the physical mechanisms responsible for the solar-cycle variations in the cosmic-ray intensity. With a physically defensible diffusion coefficient and other reasonable parameters, the spectra of protons and electrons can be simulated simultaneously over the cycle, the radial intensity gradients for particles greater than about 100 MeV, the overall intensity variation during the cycle, and the time lag in the recovery of low-energy particles behind high-energy ones, known commonly as the 'hysteresis.' The results suggest that cosmic-ray variations near the ecliptic are dominated by turbulent scattering regions in the heliosphere, overwhelming any effects of gradient and curvature drifts.
    Keywords: SPACE RADIATION
    Type: Genesis and propagation of cosmic rays; Jun 01, 1986 - Jun 09, 1986; Erice; Italy
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  • 53
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    An overview of cosmic ray research - Composition, acceleration and propagation (1988)
    In:  Other Sources
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    Publication Date: 2019-07-13
    Description: An overview of cosmic ray (CR) research and its relationship to other areas of high-energy astrophysics is presented. Research being conducted on the composition of cosmic rays (CRs) is examined, including the study of the solar system 'template' for CRs, CR abundances at earth, solar energetic particles, the CR elements beyond zinc, and the study of electrons, positrons, antinuclei, and of isotopic composition of CRs. Research on the CR energy spectrum and anisotropy is briefly reviewed. The study of acceleration processes, particle confinement, and propagation of CRs is addressed. Finally, the investigation of source abundances in CRs is discussed.
    Keywords: SPACE RADIATION
    Type: Genesis and propagation of cosmic rays; Jun 01, 1986 - Jun 09, 1986; Erice; Italy
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  • 54
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    The Joint NASA/Goddard-University of Maryland Research Program in Charged Particle and High Energy Photon Detector Technology (1988)
    In:  CASI
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    Publication Date: 2019-07-13
    Description: Having recognized at an early stage the critical importance of maintaining detector capabilities which utilize state of the art techniques, a joint program was formulated. This program has involved coordination of a broad range of efforts and activities including joint experiments, collaboration in theoretical studies, instrument design, calibrations, and data analysis. Summaries of the progress made to date are presented. A representative bibliography is also included.
    Keywords: SPACE RADIATION
    Type: NASA-CR-182612 , NAS 1.26:182612
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  • 55
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    Spectral observations of the extreme ultraviolet astronomical background radiation (1988)
    In:  Other Sources
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    Publication Date: 2019-07-12
    Description: Observations in the FUV and soft X-ray bands suggest that the ISM contains several components of high-temperature gas (100,000-1 million K). If large volumes of local interstellar space are filled with this hot plasma, emission lines will be produced in the EUV. Diffuse EUV radiation, however, has only been detected with photometric instruments; no spectral measurements exist below 520 A. A unique grazing-incidence spectrometer to study the diffuse emission between 80 and 650 A with resolution 10-30 A was successfully flown on a sounding rocket in April 1986, and a preliminary analysis reveals several features. In addition to the expected interplanetary He I 584 A emission and the geocoronal He II 304 A emission, other features appear which may orginate in the hot ionized interstellar gas.
    Keywords: SPACE RADIATION
    Type: Supplement (ISSN 0449-1947); 49; C1-63 to
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  • 56
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    Intrinsic and artificial bias in the KONUS cumulative number distribution (1988)
    In:  Other Sources
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    Publication Date: 2019-07-12
    Description: The known biases affecting the KONUS gamma burst cumulative number distribution are discussed and categorized as intrinsic (unavoidable) and artificial (avoidable). Artificial biases are removed to obtain a revised, more faithful representation of the true KONUS log N-log Pc, where Pc is in counts (1/0.25 s). A low Pc turnover is still apparent in the revised log N-log Pc. Conflicting claims that the KONUS log N-log Pc is compatible with a nearby disk or an isotropic, homogeneous distribution are tested using the revised log N-log Pc and a rigorous treatment of the KONUS intrinsic gamma background bias. The claims are shown to be improbable. Other possibilities and problms concerning log N-log Pc are discussed, but the need for a complete explanation of the low Pc turnover remains.
    Keywords: SPACE RADIATION
    Type: Astrophysical Journal, Part 1 (ISSN 0004-637X); 333; 700-718
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  • 57
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    A 2.2 second period in the 1984 August 5 gamma-ray burst (1988)
    In:  Other Sources
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    Publication Date: 2019-07-12
    Description: A time history and Fourier power spectrum are presented for the August 5, 1984 gamma-ray burst (GRB) observed with the SMM Hard X-ray Burst Spectrometer and the Pioneer Venus Orbiter spacecraft. A significant complex feature of the event is identifiable in both data sets: a gradual ripple with a well-defined 2.2-sec period lasting for seven cycles, with a series of narrow spikes, which appear always on the ascending phase of the sinusoidal ripple. This event is unusual in both its temporal and spectral attributes: it exhibits coexistence of periodic and nonperiodic features, and it was also reported as the most intense GRB event observed with the SMM Gamma-Ray Spectrometer, extending up to 100 MeV.
    Keywords: SPACE RADIATION
    Type: Astrophysical Journal, Part 2 - Letters (ISSN 0004-637X); 330; L101-L10
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  • 58
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    Interplanetary protons (Ep of about 1 MeV) 1973-1986 and out to 22.4 AU (1988)
    In:  Other Sources
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    Publication Date: 2019-07-12
    Description: This paper uses annual mean counting rate data from detectors on two long-lived spacecraft, Pioneer 11 and IMP 8, to study the temporal and heliocentric radial distance variations of the intensity of interplanetary protons (Ep of about 1 MeV) over solar activity cycle 21. The Pioneer 11 data cover the time period April 1973 through 1986 and the heliocentric radial distance range r of between 1.0 and 2.4 AU. IMP 8, in an approximately circular geocentric orbit of semimajor axis 35 earth radii, provides comparable data at 1 AU over the time period 1974-1986. The combination of the two bodies of data shows that the annual mean intensity of such protons varies as the inverse square of the distance from the sun, irrespective of solar activity as measured by the annual mean sunspot number S. Also it is found that the annual intensity at 1 AU is approximately proportional to S, except for anomalously low values in 1979 and 1980, and that the product of the annual mean intensity at Pioneer 11 by r-squared is also approximately proportional to S, except for anomalously low values in 1979, 1980 (in particular), and 1981. The common 1980 'anomaly' is attributed to gross changes in interplanetary conditions associated with the reversal of the polarity of the sun's polar magnetic field.
    Keywords: SPACE RADIATION
    Type: AD-A194328 , Geophysical Research Letters (ISSN 0094-8276); 15; 237-240
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  • 59
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    Energy spectra of cosmic-ray nuclei from 50 to 2000 GeV per amu (1988)
    In:  Other Sources
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    Publication Date: 2019-07-12
    Description: A direct measurement of the elemental composition of cosmic rays up to energies of several TeV/amu was performed during the Spacelab 2 flight of the Space Shuttle. Results on the spectral shape for the elements C, O, Ne, Mg, Si, and Fe, obtained from this experiment, are presented. It was found that the C and O energy spectra retain a power-law spectrum in energy with an exponent Gamma of about 2.65. The Fe spectrum is flatter (Gamma of about 2.55) up to a particle energy of about 10 to the 14th eV, indicating a steady increase in the relative abundance of iron in cosmic rays up to this energy. The energy spectra of Ne, Mg, and Si are steeper than anticipated. This behavior is unexpected within current models of cosmic-ray acceleration.
    Keywords: SPACE RADIATION
    Type: Astrophysical Journal, Part 2 - Letters to the Editor (ISSN 0004-637X); 327; L31-L34
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  • 60
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    Cosmic-ray antiprotons, positrons, and gamma rays from halo dark matter annihilation (1988)
    In:  Other Sources
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    Publication Date: 2019-07-12
    Description: The subject of cosmic ray antiproton production is reexamined by considering other choices for the nature of the Majorana fermion chi other than the photino considered in a previous article. The calculations are extended to include cosmic-ray positrons and cosmic gamma rays as annihilation products. Taking chi to be a generic higgsino or simply a heavy Majorana neutrino with standard couplings to the Z-zero boson allows the previous interpretation of the cosmic antiproton data to be maintained. In this case also, the annihilation cross section can be calculated independently of unknown particle physics parameters. Whereas the relic density of photinos with the choice of parameters in the previous paper turned out to be only a few percent of the closure density, the corresponding value for Omega in the generic higgsino or Majorana case is about 0.2, in excellent agreement with the value associated with galaxies and one which is sufficient to give the halo mass.
    Keywords: SPACE RADIATION
    Type: Astrophysical Journal, Part 1 (ISSN 0004-637X); 325; 16-25
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  • 61
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    Cosmic-ray energy spectra between 10 and several hundred GeV per atomic mass unit for elements from Ar-18 to Ni-28 - Results from HEAO 3 (1988)
    In:  Other Sources
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    Publication Date: 2019-07-12
    Description: Results from the Heavy Nuclei experiment on HEAO 3 are used to determine the primary abundances of Ni and Fe. Ni and Fe are found to have nearly constant relative abundances over the interval of 10 to about 500 GeV per amu. Individual secondary elements derived principally from interactions of primary Fe nuclei are shown to display a power-law decrease in relative abundance up to about 150 GeV per amu. Ar/Fe and Ca/Fe ratios of 2.6 + or - 0.7 percent and 8.8 + or - 0.7 percent, respectively, are found, confirming a fractionation of source abundances in which elements with high values of the first ionization potential are depleted relative to those with low first ionization potential.
    Keywords: SPACE RADIATION
    Type: Astrophysical Journal, Part 1 (ISSN 0004-637X); 324; 1106-111
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  • 62
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    The ultraviolet spectrum of noncoronal late-type stars - The Gamma Crucis (M3.4 III) reference spectrum (1988)
    In:  Other Sources
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    Publication Date: 2019-07-12
    Description: A guide is presented to the UV spectrum of M-type giants and supergiants whose outer atmospheres contain warm chromospheres but not coronae. The M3 giant Gamma Crucis is taken as the archetype of the cooler, oxygen-rich, noncoronal stars. Line identifications and integrated line flux measurements of the chromospheric emission features seen in the 1200-3200 A range of IUE high-resolution spectra are presented. The major fluorescence processes operating in the outer atmosphere of Gamma Crucis, including eight previously unknown pumping processes and 21 new fluorescent line products, are summarized, and the enhancements of selected line strengths by 'line leakage' is discussed. A set of absorption features toward the longer wavelength end of this range is identified which can be used to characterize the radial velocity of the stellar photospheres. The applicability of the results to the spectra of noncoronal stars with different effective temperatures and gravities is discussed.
    Keywords: SPACE RADIATION
    Type: Astrophysical Journal Supplement Series (ISSN 0067-0049); 68; 345-369
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  • 63
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    Distribution of intensities of gamma-ray bursts (1988)
    In:  Other Sources
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    Publication Date: 2019-07-12
    Description: A spatial distribution of gamma-ray bursts which is based on a log N - log n(max) relation, where N is the number of bursts which have a maximum photon count rate in excess of n(max), is proposed. A relation of N of about n(max) exp -1.5 is predicted for the case of sources uniformly distributed in infinite, flat space. It is noted that the apparently isotropic distribution of about 100 bursts over the sky combined with the N of about n(max) exp -1.5 distribution does not permit a purely observational distance estimate for the sources. It is predicted that the data from the GRANAT and GRO missions will help distinguish between a Galactic and an extragalactic origin of the bursts.
    Keywords: SPACE RADIATION
    Type: Astrophysical Journal, Part 1 (ISSN 0004-637X); 333; 694-699
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  • 64
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    New limit on the low-energy antiproton/proton ratio in the Galactic cosmic radiation (1988)
    In:  Other Sources
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    Publication Date: 2019-07-12
    Description: Results are presented from a balloon-borne apparatus searching for low-energy antiprotons in the Galactic cosmic rays. For energies less than 640 MeV at the top of the atmosphere, no cosmic-ray antiprotons were observed. This yields an upper limit to the antiproton/proton ratio of 0.000046 at the 85-percent confidence level.
    Keywords: SPACE RADIATION
    Type: Physical Review Letters (ISSN 0031-9007); 61; 145-148
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    Cosmic ultraviolet background radiation and zodiacal light (1988)
    In:  Other Sources
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    Publication Date: 2019-07-12
    Description: Spectroscopic measurements of the diffuse cosmic UV background in the 1700-2850-A range are presented. In agreement with previous results, the data have resulted in the detection at high Galactic latitude of an intensity of 300 + or - 100 photons/sq cm s sr A at 1800 A without correction for starlight or airglow, a similar intensity over the 1900-2500-A range after correction for measured airglow, and a similar intensity over the 2500-2800-A range after correction for zodiacal light. It is suggested that this radiation may originate partly in line radiation from a Galactic halo and partly from extragalactic sources, perhaps the integrated light of distant galaxies.
    Keywords: SPACE RADIATION
    Type: Astrophysical Journal, Part 1 (ISSN 0004-637X); 330; 435-444
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    The submillimeter spectrum of the cosmic background radiation (1988)
    In:  Other Sources
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    Publication Date: 2019-07-12
    Description: The diffuse brightness of the sky has been measured in six submillimeter passbands, using a rocket-borne, liquid helium-cooled, absolute radiometer. The flux measured at 1160 microns is in good agreement with the average of longer wavelength measurements of the temperature of the cosmic background radiation. The fluxes measured at 709 microns and 481 microns show a rapid decrease toward shorter wavelength, but correspond to significantly higher temperatures. No local source of this excess flux has been identified. The spectrum of the excess significantly constrains cosmological models. Data at 262, 137, and 102 microns are consistent with emission from interstellar dust.
    Keywords: SPACE RADIATION
    Type: Astrophysical Journal, Part 1 (ISSN 0004-637X); 329; 567-571
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    Limiting energy spectrum of a saturated radiation belt (1988)
    In:  Other Sources
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    Publication Date: 2019-07-12
    Description: The condition for magnetospheric wave growth in the presence of anisotropic charged particle distributions is used to extend the Kennel-Petschek theory that traditionally imposes an upper bound on the integral flux of charged particles at energies above a certain threshold to provide a limit on the differential flux at any energy above this threshold. A closed-form expression is derived for the limiting energy spectrum consistent with marginal occurrence of a magnetospheric maser at all wave frequencies below a certain fraction of the electron or proton gyrofrequency. The bounded integral can be recast in such a way that repeated differentiations with respect to v(parallel) actually generate a closed expression for the limiting form of the velocity space distribution, and thus for the limiting energy spectrum of the corresponding particles, whenever the anisotropy parameter is an integer.
    Keywords: SPACE RADIATION
    Type: Journal of Geophysical Research (ISSN 0148-0227); 93; 59-76
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  • 68
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    Observations related to the acceleration, injection, and interplanetary propagation of energetic protons during the solar cosmic ray event on February 16, 1984 (1988)
    In:  Other Sources
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    Publication Date: 2019-07-12
    Description: This paper presents an analysis of data collected by the worldwide network of neutron monitors and from IMP-8 cosmic-ray telescopes, as well as by particle detectors on the GOES 5 and 6 and ICE satellites, on the solar cosmic ray event that took place on February 16, 1984. Using these data, the intensity-time (IT) profiles, the anisotropy-time profiles, the energy spectra, and the pitch angle distributions of the solar protons near earth were deduced. It was found that the solar protons propagated essentially scatter-free from the sun to the earth. The solar protons had easy access to the IMF lines to earth; the time from the onset to maximum intensity and the shape of the IT profiles at earth as a function of energy could be explained by the diffusion of the flare protons near the acceleration region. The energy spectrum of the solar flare protons injected into the undisturbed IMF at the sun was changing with time in both amplitude and shape. The observations suggest a shock acceleration process.
    Keywords: SPACE RADIATION
    Type: Journal of Geophysical Research (ISSN 0148-0227); 93; 7206-721
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  • 69
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    Unstable matter and the 1-0 MeV gamma-ray background (1988)
    In:  Other Sources
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    Publication Date: 2019-07-12
    Description: The spectrum of photons produced by an unstable particle which decayed while the universe was young is calculated. This spectrum is compared to that of the 1-10 MeV shoulder, a feature of the high-energy, extragalactic gamma-ray background, whose origin has not yet been determined. The calculated spectrum contains two parameters which are adjusted to obtain a maximal fit to the observed spectrum; the fit thus obtained is accurate to the 99 percent confidence level. The implications for the mass, lifetime, initial abundance, and branching ratio of the unstable particle are discussed.
    Keywords: SPACE RADIATION
    Type: Astrophysical Journal, Part 2 - Letters to the Editor (ISSN 0004-637X); 324; L47-L50
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  • 70
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    Observations of intense trapped electron fluxes at synchronous altitudes (1988)
    In:  Other Sources
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    Publication Date: 2019-07-12
    Description: The concept of flux limiting in the outer radiation belt proposed by Kennel and Petschek (1966) has been tested in a dynamic situation by using data acquired with instruments aboard the SCATHA satellite. A case-by-case analysis of 12 events for evidence of flux limiting under various magnetospheric conditions is made. The reuslts indicate qualitative agreement with the flux limiting theory for all the events studied. Even the quiescent events and hard-spectrum events are consistent with flux limiting. The limiting flux level at any instant appears to depend strongly on the recent history of the trapped electrons and plasma in the outer magnetosphere.
    Keywords: SPACE RADIATION
    Type: Journal of Geophysical Research (ISSN 0148-0227); 93; 77-95
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    Measurements of the anisotropy of the cosmic background radiation and diffuse galactic emission at millimeter and submillimeter wavelengths (1988)
    In:  Other Sources
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    Publication Date: 2019-07-12
    Description: The results of a balloon-borne observing program to measure the large angular scale brightness distribution of the 2.7 K cosmic background radiation (CBR) at millimeter and submillimeter wavelengths are reported. A new determination of the dipole anisotropy of the CBR is found with 3.40 + or - 0.42 mK toward alpha = 12.1 + or - 0.24 hr, delta = - 23 + or - 5 deg in a 1.2 to 8/cm band and 4.7 + or - 1.4 mK toward alpha = 9.9 + 1.7 or - 1.1 hr, delta = - 38 + or - 21 deg between 5 and 18/cm, where the amplitudes are listed as thermodynamic temperatures. New estimates of the absolute temperature in these two bands of 2.86 + or - 0.26 K and 3.01 + or - 0.31 are obtained under the assumption that the CBR has a Planck spectrum. The diffuse Galactic emission is fitted by a secant distribution in Galactic latitude, and the resulting Galactic pole antenna temperatures are given. Maps of sky brightness, measurements of zodiacal emission, and measurements of fluctuations of the atmospheric emission which dominates the noise budget are also presented.
    Keywords: SPACE RADIATION
    Type: Astrophysical Journal, Part 1 (ISSN 0004-637X); 332; 596-614
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    Cosmic-ray viscosity (1988)
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    Publication Date: 2019-07-12
    Description: The transport equation for cosmic rays scattered by magnetic field irregularities carried in a rarefied conducting fluid has been reexamined. To lowest order in the ratio, U/w, of flow speed to random particle speed, the analysis gives the standard equation first derived by Parker (1965), but additional terms are found in the next order of this ratio. One new term, which reflects viscous damping of fluid motions by the energetic-particle gas, describes both a change in the mean particle momentum and a spreading around the mean. Other new terms, which derive from accelerations of the fluid, describe inertial drift and energy changes. Although these effects are small, they are potentially important at shocks, because they are proportional to the square of velocity derivatives. In addition, they can be significant for the case of pure velocity shear, in which the adiabatic energy change is zero.
    Keywords: SPACE RADIATION
    Type: Astrophysical Journal, Part 2 - Letters (ISSN 0004-637X); 331; L91-L94
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    Cosmic-ray lifetime in the Galaxy - Experimental results and models (1988)
    In:  Other Sources
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    Publication Date: 2019-07-12
    Description: The separation of the cosmic-ray Be isotopes achieved by two satellite experiments is discussed. From the measured isotopic ratio between the radioactive Be-10 (half-life = 1,500,000 years) and the stable Be-9, it is deduced that the cosmic rays propagate through matter with an average density of 0.24 = or - 0.07 atoms/ cu cm. The implications of this result for the cosmic-ray age is reviewed in the context of two models of confinement and propagation: the homogeneous model, normally identified with confinement ot the galactic gaseous disk, and a diffusion model in which the cosmic rays extend into a galactic halo. A newly deduced cosmic-ray pathlength distribution, a self-consistent model of solar modulation, and a set of fragmentation cross sections are calculated. It is concluded that in a homogeneous model, the cosmic-ray age is 15 (+7, -4) million years, about a factor longer than early estimates based on the abundances of the light nuclei Li, Be, and B and a nominal interstellar density of 1 atom/ cu cm.
    Keywords: SPACE RADIATION
    Type: Space Science Reviews (ISSN 0038-6308); 46; 3-4; 205-224
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    Cosmic-ray hydrodynamics at relativistic shocks (1988)
    In:  Other Sources
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    Publication Date: 2019-07-12
    Description: A test particle description of first-order Fermi acceleration of cosmic rays at plane-parallel relativistic shocks is presented in which the pitch angle distribution is obtained explicitly and used to determine the pressure anisotropy or variable Eddington factor as a function of position. The Eddington factor is in turn used to find the hydrodynamical cosmic-ray sound speed, taking the anisotropy into account. For upstream flows speeds above c/sq rt 3, it is shown that the cosmic-ray sound speed exceeds the shock speed in a region just upstream of the shock and decreases montonically with distance further upstream, reaching the value c/sq rt 3 far from the shock. Thus, the shock succeeds in maintaining an anisotropy in the cosmic-ray distribution which is sufficient to keep the flow subsonic with respect to the cosmic-ray sound speed both downstream and in a finite region upstream. The astrophysical implications of these findings are discussed.
    Keywords: SPACE RADIATION
    Type: Astrophysical Journal, Part 1 (ISSN 0004-637X); 331; 336-342
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    Isotopic composition of cosmic-ray boron and nitrogen (1988)
    In:  Other Sources
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    Publication Date: 2019-07-12
    Description: New measurements of the cosmic-ray boron and nitrogen isotopes at earth and of the elemental abundances of boron, carbon, nitrogen, and oxygen are presented. A region of mutually allowed values for the cosmic-ray nitrogen source ratios is determined, and the cosmic-ray escape mean free path is determined as a function of energy using a leaky box model for cosmic-ray propagation in the Galaxy. Relative to O-16, a N-15 source abundance consistent with solar system composition and a N-14 source abundance which is a factor of about three underabundant relative to the solar value are found.
    Keywords: SPACE RADIATION
    Type: Astrophysical Journal, Part 1 (ISSN 0004-637X); 328; 940-953
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    SMM detection of diffuse Galactic 511 keV annihilation radiation (1988)
    In:  Other Sources
    Details
    Publication Date: 2019-07-12
    Description: Observations of the 511 keV annihilation line from the vicinity of the Galactic center from October to February for 1980/1981, 1981/1982, 1982/1983, 1984/1985, and 1985/1986 are presented. The measurements were made with the gamma-ray spectrometer on the SMM. The design of the instrument and some of its properties used in the analysis are described, and the methods used for accumulating, fitting, and analyzing the data are outlined. It is shown how the Galactic 511 keV line was separated from the intense and variable background observed in orbit. The SMM observations are compared with previous measurements of annihilation radiation from the Galactic center region, and the astrophysical implications are discussed. It is argued that most of the measurements made to date suggest the presence of an extended Galactic source of annihilation radiation.
    Keywords: SPACE RADIATION
    Type: Astrophysical Journal, Part 1 (ISSN 0004-637X); 326; 717-732
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    Modified non-linear Burgers' equations and cosmic ray shocks (1988)
    In:  Other Sources
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    Publication Date: 2019-07-12
    Description: A reductive perturbation scheme is used to derive a generalized non-linear Burgers' equation, which includes the effects of dispersion, in the long wavelength regime for the two-fluid hydrodynamical model used to describe cosmic ray acceleration by the first-order Fermi process in astrophysical shocks. The generalized Burger's equation is derived for both relativistic and non-relativistic cosmic ray shocks, and describes the time evolution of weak shocks in the theory of diffusive shock acceleration. The inclusion of dispersive effects modifies the phase velocity of the shock obtained from the lower order non-linear Burger's equation through the introduction of higher order terms from the long wavelength dispersion equation. The travelling wave solution of the generalized Burgers' equation for a single shock shows that larger cosmic ray pressures result in broader shock transitions. The results for relativistic shocks show a steepening of the shock as the shock speed approaches the relativistic cosmic ray sound speed. The dependence of the shock speed on the cosmic ray pressure is also discussed.
    Keywords: SPACE RADIATION
    Type: Astronomy and Astrophysics (ISSN 0004-6361); 189; 1-2; 338-348
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    Research in particle and gamma-ray astrophysics (1988)
    In:  CASI
    Details
    Publication Date: 2019-07-13
    Description: This research program is directed toward the investigation of the astrophysical aspects of cosmic rays and gamma rays and of the radiation and electromagnetic field environment of the Earth and other planets. The emphasis was on precice measurements with high resolution in charge, mass and energy. These investigations were carried out by means of energetic particle and photon detector systems flown on spacecraft and balloons.
    Keywords: SPACE RADIATION
    Type: NASA-CR-183111 , NAS 1.26:183111
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    The emergence of X-rays and gamma-rays from supernova 1987A (1988)
    In:  Other Sources
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    Publication Date: 2019-07-13
    Description: Attempts to arrive at a unified scenario for the optical, X-ray, and gamma-ray emission of SN 1987A are discussed. Theoretical spectra are in reasonable agreement with recent observations of hard X-rays by the Ginga and Mir satellites, but the early turn-on of X-rays suggests that the mantle and envelope may be 'leaky', perhaps as a result of Rayleigh-Taylor instabilities and clumping. The soft X-ray spectrum should be dominated by a 6.4 keV Fe K-alpha fluorescence line. The reported Ginga detection of 4-10 keV X-ray emission is also discussed.
    Keywords: SPACE RADIATION
    Type: Geroge Mason Astrophysics Workshop; Oct 12, 1987 - Oct 14, 1987; Fairfax, VA; United States
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    Gamma-ray observations of SN 1987A with an array of high-purity germanium detectors (1988)
    In:  Other Sources
    Details
    Publication Date: 2019-07-13
    Description: A balloonborne gamma-ray spectrometer comprising an array of high-purity n-type germanium (HPGe) detectors surrounded by an active NaI(T1) collimator and Compton suppressing anticoincidence shield was flown on May 29-30, 1987. The average column depth of residual atmosphere in the direction of SN 1987A at float altitude was 6.3 g/sq cm during the observation. The 3-sigma upper limit obtained for the 1238-keV line from Co-56 is 0.0013 photons/sq cm s. The corresponding limit for the 847-keV line is 0.0017 photons/sq cm s.
    Keywords: SPACE RADIATION
    Type: Geroge Mason Astrophysics Workshop; Oct 12, 1987 - Oct 14, 1987; Fairfax, VA; United States
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    Origin and anisotropy of the cosmic submillimeter background (1988)
    In:  Other Sources
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    Publication Date: 2019-07-13
    Description: Some cosmological implications of the recently discovered submillimeter background (SMB) are discussed. Opacity and isotropy arguments show that if the background is due to dust emission it must originate at a high redshift z greater than about 10. Isotropy measurements are used to constrain the amplitude of dust optical-depth fluctuations and hence the scale of dust inhomogeneity. The observed flux, the inferred high z and high opacity imply that on small scales the mock gravitational instability driven by radiation pressure may have dominated gravitational effects.
    Keywords: SPACE RADIATION
    Type: The Post-Recombination Universe; Jul 27, 1987 - Aug 07, 1987; Cambridge
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    Recent observations of cosmic ray antiprotons and a critical assessment of the theories of their origin (1988)
    In:  Other Sources
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    Publication Date: 2019-07-12
    Description: The models proposed to explain the observed spectrum of cosmic ray antiprotons are reexamined in light of recent results from balloon-borne experiments. It is found that the prediction of modified closed galaxy model fits the observed data very well. Models in which secondary antiprotons are produced in the sources, could be made consistent with the data provided the secondary particles do not suffer considerable adiabatic deceleration. It has been shown that there cannot be any significant contribution to the observed antiprotons, from the evaporation of mini black holes or from the annihilation of dark matter like photinos. The role of extragalactic cosmic rays has been examined critically in the context of the recent data, and they are not the source of cosmic ray antiprotons. However, determination of the energy spectrum of antiprotons at least up to a few tens of GeV would be valuable to provide information on the possible existence of supersymmetric particles and on the modulation of extragalactic cosmic rays while entering the Galaxy.
    Keywords: SPACE RADIATION
    Type: Astronomy and Astrophysics (ISSN 0004-6361); 202; 1-2
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    Is there a twenty year wave in the diurnal anisotropy of cosmic rays? (1988)
    In:  Other Sources
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    Publication Date: 2019-08-27
    Description: Data obtained with the Deep River neutron monitor and the underground vertical muon telescope at Embudo for the period 1965-1979 are analyzed. The data show that for 1957-1970 the diurnal anisotropy is unidirectional. During 1971-1979, the diurnal anisotropy consists of two components. One is in the east-west direction and the other is the radial component, with direction along 12:00 LT. The latter attains a maximum amplitude in 1976. No evidence is found for the existence of the twenty year wave in the diurnal anisotropy of cosmic rays.
    Keywords: SPACE RADIATION
    Type: Geophysical Research Letters (ISSN 0094-8276); 15; 287-290
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    Abstracts of Dutch doctoral theses (1988)
    Springer
    Pharmacy world & science 10 (1988), S. 93-95 
    Details
    ISSN: 1573-739X
    Keywords: Anthracyclines ; Chemistry ; Drug stability ; Mitomycins
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01962686
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    Etoposide and teniposide (1988)
    Springer
    Pharmacy world & science 10 (1988), S. 101-116 
    Details
    ISSN: 1573-739X
    Keywords: Chemistry ; Chromatography ; Etoposide ; Immunoassay ; Metabolism ; Podophyllotoxin ; Pharmacokinetics ; Teniposide
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Etoposide (VP 16-213) and teniposide (VM 26) are semisynthetic epipodophyllotoxin derivatives active against a variety of tumours. The clinical efficacy has led to an increasing interest in these compounds. This review presents information on the mechanism of action, biochemical pharmacology, bioanalysis, metabolism and pharmacokinetics of etoposide and teniposide.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01959294
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    A contribution to the UV degradation of polyurethanesPaper presented at the 18th Colloquium of Danubian Countries for “Natural and artificial ageing of plastics” in Villach June 24-26, 1987. (Austria) (1988)
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 158 (1988), S. 247-263 
    Details
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The effects of the nature of the polyols used in polyurethane (PUR) synthesis on the structural transformations after ageing by UV irradiation has been studied. The investigations were performed on PUR prepared from polyester and polyether diol oligomers.The characterization of the samples before and after ageing in view of the structural changes, which influence the course of the photooxidative degradation and photocrosslinking as well as in view of changes of mechanical properties has been done. Comparative investigations were performed by spectroscopic and viscometric measurements.The results show pronounced heterogeneity of the degradative reactions, including the existence of crosslinking processes and producing thus very inhomogeneous polymeric material. The course and the intensity of photooxidative degradation of PUR differ together with changes of mechanical properties depending whether polyester or polyether polyol have been used. The processes of photooxidative degradation is less expressed in polyesterurethane then in polyurethane based on polyether, under the same conditions of experiments. Different structures of polyester diols caused the various ageing behaviour of PUR too.
    Additional Material: 11 Ill.
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    URL: http://dx.doi.org/10.1002/apmc.1988.051580114
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    Beurteilung von hals-verbindungenVortrag anlä-sslich des 18. Donäulandergesprächs über “Natürliche und künstliche Alterung von Kunststoffen” in Villach (Österreich), vom 24. bis 26. Juni 1987. (1988)
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 158 (1988), S. 283-300 
    Details
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: QUALIFICATION OF HALS COMPOUNDSA complex method of examination has been developed suitable for the qualification of light stabilizers; by this method, according to experience, the efficacy of HALS compounds can be extensively and expediently characterized.Several light stabilizers of the HALS-type were examined and qualified, used alone or together with a UV-absorber.It has been found that, when selecting the appropriate structure for a given polymer, the weatherability of polyolefine foils is effectively increase to six-eightfold; the increase is even tenfold when the stabilizer is combined with a benzophenone-type compound.As a utilization of these experiences, a contract with the industry, led to the production of an LDPE based agricultural foil with a life-time of several years.
    Additional Material: 11 Ill.
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    URL: http://dx.doi.org/10.1002/apmc.1988.051580116
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    Simulation des natürlichen hagelschlags an transparenten kunststoffplattenVortrag anläßlich des 18. Donäulandergesprächs über “Nattürliche und künstliche Alterung von Kunststoffen” in Villach (Österreich) vom 24. bis 26. Juni 1987. (1988)
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 158 (1988), S. 301-311 
    Details
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Natural hail impact tests are scarcely available because hailstorms are limited to a small area and cannot be predicted regarding time, place and intensity. Therefore we relied on laboratory tests simulating natural hailstones by polyamide balls (5-50 mm dia.) whose final velocity could be varied according to meteorological data. So the influence of diameter (weight) and velocity of the artificial hailstones could be taken into consideration independently.The energy of damage or equivalent natural hailstone diameter were determined for 16 mm double skin sheet from PMMA as 0.2 J (14 mm dia.) for star shaped cracks and 2 J (26 mm dia.) for holes. These values do not significantly decrease after 10 years weathering. 10 mm double skin sheets from PC show an extremly high energy of damage of abt. 10 J (38 mm dia.) which decreases to a medium level of 2 J (26 mm dia.) after several years weathering. This decrease is remarkably reduced by weather resistant protective coating.As hailstorms consist to more than 80% of hailstones below 10 mm dia. (0.04 J) the mentioned sheet materials are quite hail resistant also after long weathering periods, but they cannot withstand an extreme hail catastrophe as in Munich July 12, 1984.
    Additional Material: 5 Ill.
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    URL: http://dx.doi.org/10.1002/apmc.1988.051580117
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    Specimen temperature as a constant marginal condition and as a variable test parameter during accelerated weatheringVortrag anläßlich des 18. Donauländergesprächs über “Natürliche und künstliche Alterung von Kunststoffen” in Villach (Österreich) vom 24.-26. Juni 1987. (1988)
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 158 (1988), S. 313-320 
    Details
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The influence of the specimen temperature on many ageing processes is well known. Two aspects is dealt with: -Measurements of the specimen temperature on several positions of a specimen in commercial weathering devices at different exposure conditions. Technical measures to achieve to uniform ageing at all positions of a planar and homogeneous specimen. Examples from practical use.-Changing specimen temperatures (+60°C to -20°C) during the course of accelerated weathering, i.e. a combination of conventional accelerated weathering with a temperature cycle test.
    Additional Material: 5 Ill.
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    URL: http://dx.doi.org/10.1002/apmc.1988.051580118
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    Some special aspects of thermal ageing of isotactic polypropylene (measuring method: Isothermal long-term DTA)Vortrag anläßlich des 18. Donauländergesprächs über “Natürliche und künstliche Alterung von Kunststoffen” in Villach (Österreich) vom 24.-26. Juni 1987. (1988)
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 158 (1988), S. 321-334 
    Details
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: An Folien (Dicke 100 pm) aus isotaktischem Polypropylen mit verschiedenen Antioxidansgehalten (0,0% bis 0,1%) wird die thermooxidative Alterunq mit der isothermen Langzeit-Differential-Thermo-Analyse (ILDTA) bis zu Temperaturen weit unter dem Kristallitschmelzbereich verfolqt und die Messwerte mit Ergebnissen aus dem Zeitstand-Zugversuch korreliert. Dabei zeigt sich, daß aus Messunqen mit der ILDTA bereits vor Einsetzen der autokatalytischen Zersetzunq sreaktion Ruckschlüsse auf die thermische Vorqeschichte der Proben und Aussagen auf das rnit einem Abfall der mechanischen Eigenschaften verbundene Ende der thermo-oxidativen Stabilität des Polymeren getroffen werden können.Weiters bietet die ILDTA die Moglichkeit, durch den direkten Zusamenhang zwischen Oxidationszeit und Antioxidansögehalt die örtliche Stabilisatorverteilung in Platten und in Folien zu bestimmen und damit Diffusionsvorqange zu verfolgen.
    Notes: Thermo-oxidative ageing processes were investigated in films (100 μm thick) made from isotactic polypropylene with different antioxidant concentrations between 0% and 0.1% using isothermal long-term differential thermal analysis (ILDTA). The end of the oven life of polypropylene coincided with the loss of mechanical properties which was confirmed by tensile tests at temperatures far below the crystallite melting range. Already prior to the beginning of autocatalytic decomposition, ILDTA experiments permits conclusions to be drawn on the thermal history of the specimens and statements made regarding the end of thermo-oxidative stability of the polymer, which is accompanied by a deterioration in the mechanical properties.In consequence of the correlation between oxidation time and antioxidant concentration the local antioxidant concentration in sheets or films can be measured by ILDTA. Thus, investigating the diffusion of an antioxidant in polypropylene using ILDTA is possible.
    Additional Material: 9 Ill.
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    URL: http://dx.doi.org/10.1002/apmc.1988.051580119
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    Coupling particle size distribution technique. A new ultracentrifuge technique for determination of the particle size distribution of extremely broad distributed dispersionsDedicated to Prof. Dr. H.-J. Cantow on the occasion of his 65th birthday (1988)
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 162 (1988), S. 35-52 
    Details
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Die Größenverteilungsfunktion von Dispersionen mit extrem breiter Verteilung (Durchmesserbereich 20 〈 D 〈 2000 nm) kann in der analytischen Ultrazentrifuge (AUC) nicht durch eine Standardmethode, z. B. durch Messung der Trübung τ bei einer einzigen Konzentration, bestimmt werden, weil sich die spezifische Trübung τ/c von sehr kleinen und sehr großen Teilchen zu stark unterscheidet. Um dieses Problem zu lösen, haben wir eine neue AUC-Technik, die sogenannte Coupling-PSD-Technik entwickelt. Dabei werden zwei unterschiedliche Konzentrationen derselben Dispersion gleichzeitig in einem einzigen AUC-Lauf vermessen und zwei korrespondierende Lichtintensitiit-Zeit-Kurven aufgezeichnet. Bei einer niedrigen Standardkonzentration cs werden hauptsachlich die größeren Teilchen erfaßt während bei einer 5 bis 30 mal heheren Konzentration ch vor allem die kleineren Teilchen registriert werden. Die beiden I(t)-Kurven werden mathematisch verkniipft und unter Verwendung des Stokeschen Gesetzes und der Streutheorie von Mie für homogene isotrope Kugeln in die gesuchte breite Verteilungsfunktion umgerechnet. Wir benutzen eine mit einem 8-Zellen-Rotor und einem Multiplexer ausgestattete AUC. Da sehr groBe und sehr kleine Teilchen gleichzeitig in einem einzigen Zentrifugenlauf bestimmt werden, kennen wir nicht mehr wie zuvor eine konstante Rotorgeschwindigkeit N anwenden, sondern miissen diese mit Hilfe eines Geschwindigkeitsprogramms N(t) innerhalb einer Stunde von 0 auf 40000 U/min erhehen.
    Notes: The particle size distribution (PSD) of extremely broad distributed dispersions (diameter range 20 〈 D 〈 2000 nm) is not possible to be measured by analytical ultracentrifuge (AUC) using the standard technique, i.e. measuring turbidity τ at a single concentration c, because the specific turbidity τ/c varies too much between very small and very large particles. To solve this problem we have developed a new AUC technique, the so-called Coupling-PSD-Technique. Here two different concentrations of the same dispersion are measured simultaneously by one single AUC run with two corresponding curves of light intensity I vs. time t being registered. At a low standard concentration cs, mainly the larger particles are detected, while at a concentration ch 5 to 30 times higher mainly the smaller particles are registered. Both I(t)-curves are coupled mathematically and transformed into the requested broad distribution curve employing Stokes' law and Mie's light scattering theory for homogeneous isotropic spheres.We use an AUC together with an 8-cells-rotor and a multiplexer. Because very large and very small particles are to be measured simultaneously in one single run, we can no more apply a constant rotor speed N as before, but by means of a time program N(t) we always have to increase the rotor speed from 0 to 40000 rpm within one hour.
    Additional Material: 7 Ill.
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    URL: http://dx.doi.org/10.1002/apmc.1988.051620103
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    Graft copolymerization of methyl methacrylate on poly(vinyl chloride) (1988)
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 162 (1988), S. 135-148 
    Details
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Die chemische Modifizierung von Polyvinylchlorid (PVC) durch ein Amin verleiht dem Polymeren höhere Reaktivität gegenüber der Pfropfcopolymerisation mit einem Vinylmonomeren. Die Pfropfcopolymerisation von Methylmethacrylat auf mit n-Butylamin modifiziertes PVC wurde thermisch mit Benzoylperoxid (Bz2O2) als Initiator oder photoaktiviert mit Benzophenon (BP) als Photosensibilisator gestartet. Das aus bestimmten Experimenten erhaltene rohe Polymerprodukt wurde durch fraktionierte Fällung in die verschiedenen Bestandteile wie Polymethylmethacrylat (PMMA, Homopolymeres), PVC-g-PMMA (Pfropfcopolymeres) und unverändertes (aminiertes) PVC aufgespalten. Die getrennten Fraktionen wurden mit Hilfe der IR-Spektroskopie und der Thermogravimetrie charakterisiert. Der Mechanismus der Pfropfcopolymerisation von den beiden verschiedenen Systemen wurde erörtert. In beiden Fällen wurden Pfropfausbeuten um 30 - 70%* und Pfropfcopolymerzusammensetzungen, PMMA/PVC (w/w) zwischen 2 und 3 erhalten.
    Notes: Chemical modification of poly(vinyl chloride), PVC, by an amine renders the polymer more reactive towards graft copolymerization with a vinyl monomer. The graft copolymerization of methyl methacrylate (MMA) on PVC modified by treatment with n-butylamine (n-BA) was started thermally at 30° using benzoyl peroxide (Bz2O2) as initiator and under photoactivation at 40° using benzophenone (BP) as photo sensitizer. The gross polymer products from selected experiments were fractionally separated into the constituent polymeric entities viz., poly(methyl methacrylate), PMMA (homopolymer), PVC-g-PMMA (graft copolymer), and unreacted (aminated) PVC following a method of fractional precipitation. The separated fractions were characterized by IR spectroscopy and thermogravimetry. The mechanisms of graft copolymerization for the two different systems have been discussed. In each case, grafting efficiencies of the order of 30-70% and graft copolymers having compositions given as PMMA/PVC (w/w) equal to 2-3 were readily obtained.
    Additional Material: 7 Ill.
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    URL: http://dx.doi.org/10.1002/apmc.1988.051620109
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    Surface sulphonated highly crosslinked styrene-divinylbenzene copolymers (1988)
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 162 (1988), S. 193-201 
    Details
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Eine Reihe oberflächensulfonierter, makroporöser Styrol-Divinylbenzol-Copolymerer mit unterschiedlichen Gehalten an SO3H-Gruppen wurden hergestellt. Sowohl von diesen Copolymeren als auch vom nichtsulfonierten Copolymeren wurden Porenstruktur, Oberflächenhydrophilie und -polarität sowie das Sorptionsverhalten gegenüber einigen in Blut vorkommenden Substanzen bestimmt. Der Sorptionsgrad wird umso kleiner, je größer die Oberflächenpolarität ist. Die teilsulfonierten Polymeren könnten eine Anwendung in der Hämoperfusion finden.
    Notes: A series of surface sulphonated macroporous styrene-divinylbenzene (S-DVB) copolymers containing various amounts of  - SO3H groups was obtained. Porous structure, surface hydrophilicity and polarity, and sorption properties of these copolymers as well as those of starting S-DVB resin towards some substances which are present in blood were determined. The sorption degree becomes the smaller the higher is the surface polarity. The partially sulphonated copolymers may find an application in hemoperfusion.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/apmc.1988.051620113
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    Studies on the enhancement of separation characteristics of sulfonated poly(phenylene oxide)/polysulfone thin film composite membranes for reverse osmosis applications. I. Effect of chemical treatment (1988)
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 163 (1988), S. 1-13 
    Details
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Der Einfluß einer chemischen Behandlung von dünnen Filmen einer Composit-Membran aus sulfoniertem Polyphenylenoxid wurde untersucht. Über den Einfluß der Konzentration von wáßrigen Lösungen von Formaldehyd, Schwefelsäure, Salzsäure, Phosporsäure, Natriumhydroxid sowie der Behandlungsdauer auf die Trenncharakteristik der inversen Osmose der Composit-Membranen mit einer Ionenaus-tauschkapazität von 2,14 und 2,50 meq/g in verschiedenen Kombinationen wird ausführlich berichtet. Die Ergebnisse zeigen, daß unter den besten chemischen Behandlungsbedingungen eine Erhöhung der Trenncharakteristik der inversen Osmose der sulfonierten Polyphenylenoxid/Polysulfon-Composit-Membran erreicht wird.
    Notes: The effect of chemical treatment on the reverse osmosis (RO) separation characteristics of sulfonated poly(phenylene oxide) (SPPO) thin film composite membranes was investigated. The effects of the concentrations of aqueous solutions of formaldehyde, sulfuric acid, hydrochloric acid, phosphoric acid, sodium hydroxide, and treatment time on the RO separation characteristics of the composite membranes with ion exchange capacity (IEC) of 2.14 and 2.50 meq/g in various combinations are reported in detail. The results indicate some enhancement in RO separation characteristics of the SPPO/polysulfone (PS) composite membrane under the best conditions of the chemical treatment.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/apmc.1988.051630101
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    Studies on the enhancement of separation characteristics of sulfonated poly(phenylene oxide)/polysulfone thin film composite membranes for reverse osmosis applications. II. Effects of nitromethane and the chemical treatment combined with gamma-ray irradiationPart I cf. lit.3. (1988)
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 163 (1988), S. 15-21 
    Details
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Bei der Herstellung dünner Filme von sulfonierten Polyphenylenoxid/Polysulfon (SPPO/PS)-Composit-Membranen wurde untersucht, daß ein Zusatz von Nitromethan zu einer Lösung von sulfoniertem Polyphenylenoxidnatrium erhöhte Wirkung auf die Trenncharakteristik der inversen Osmose besitzt. Der Einfluß von gamma-Strahlung auf dünne Filme der Composit-Membran unter nassen und trockenen Bedingungen wurde ebenfalls untersucht. Um die maximal mögliche Verbesserung zu erreichen, wurden die Composit-Membranen einer kombinierten chemischen und Gammastrahlen-Behandlung unter nassen und trockenen Bedingungen unterworfen.Die experimentellen Ergebnisse dieser kombinierten Behandlung zeigen, dalß die SPPO/PS Composit-Membran dabei abgebaut wird.
    Notes: The enhancement effect of the addition of nitromethane into the coating solution of sulfonated sodium poly(phenylene oxide) (SPPONa) polymer for the synthesis of sulfonated poly(phenylene oxide)/polysulfone (SPPO/PS) thin film composite membranes on reverse osmosis (RO) separation characteristic was studied. The effect of gamma-ray irradiation on the SPPO/PS thin film composite membranes was also evaluated when the membrane samples were in the wet and dry conditions. The composite membranes were also subjected to a chemical treatment combined with gamma-ray irradiation in both wet and dry conditions in the hope of obtaining the maximum possible enhancement under each treatment. However, the experimental data of this combined treatment indicated the possibility of some degradation of the SPPO/PS composite membranes.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/apmc.1988.051630102
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  • 96
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    Effect of blending techniques on the curing of elastomer blends (1988)
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 163 (1988), S. 37-45 
    Details
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Mischungen aus Poly(styrol-co-butadien)/Polybutadien, Naturkautschuk/Poly-(ethylen-co-propylen-co-dien und Naturkautschuk/Poly(butadien-co-acrylnitril)) wurden nach drei unterschiedlichen Verfahren compoundiert und Härtungsverhalten sowie Zugfestigkeit und Bruchdehnung der Vulkanisate wurden verglichen.
    Notes: Compounding of styrene-butadiene copolymer/polybutadiene, natural rubber/ethylene-propylene-diene terpolymer and natural rubber/butadiene-acrylonitrile copolymer blends was done in three different ways and their curing behaviour and the tensile properties of the vulcanizates are compared.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/apmc.1988.051630104
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  • 97
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    Modification of starch by graft copolymerisation with methyl methacrylatePresented at 12th National Conference of the Chemical Society of Nigeria, Calabar, Nigeria, Sept. 23-25, 1987. (1988)
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 163 (1988), S. 93-99 
    Details
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Methylmethacrylat (MMA) wurde mit Hilfe von Cerammoniumnitrat als Initiator auf Stärke gepfropft. Die Pfropfcopolymeren wurden durch selektive Lösungsextraktion in einem Soxhlet-Extraktor isoliert. Der Einfluß von Reaktionszeit, Initiatorkonzentration, Temperatur sowie der Monomer- und Särekonzentration auf die Pfropfausbeute wurde untersucht. Eine erste Studie der Kinetik dieser Pfropfcopolymerisationsreaktion zeigt, daß sie dem üblichen kinetischen Verhalten einer Radikalpolymerisation folgt.
    Notes: Methyl methacrylate (MMA) was grafted onto starch using ceric ammonium nitrate as initiator. The graft copolymers were isolated by selective solvent extraction in a Soxhlet apparatus. The effects of reaction time, initiator concentration, temperature, monomer, and acid concentrations on the graft yields were investigated. A preliminary kinetic study of the graft copolymerisation reactions shows that they follow the conventional kinetic behaviour of free radical polymerisation.
    Additional Material: 5 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/apmc.1988.051630108
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  • 98
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    Adsorption of phenols on carbonaceous adsorbents produced from phenol-formaldehyde-resin mixed with olive stones (1988)
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 163 (1988), S. 47-61 
    Details
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Durch Verwendung von Phenol-Formaldehyd-Harz mit gepreßten Olivenkenen im Gewichtsverháltnis 20/80 wurden kleine zylindrische Formkörper durch Härtung hergestellt. Diese wurden pyrolysiert und einige Proben mit Wasserdampf aktiviert. Für diese Formkörper und für zwei kommerzielle Aktivkohlen für Laboratoriumsbzw. Industrie-Anwendungen wurden folgende Eigenschaften bestimmt: die spezifische Oberfláche, die Struktur, die Adsorptionseigenschaften sowie die Adsorptionskapazität. Die Ergebnisse zeigen, daß die hergestellten kohlenstoffhaltigen Materialien durch Aktivierung höhere Werte für die untersuchten Eigenschaften ergeben als die nur pyrolysierten Proben und die zwei kommerziellen Aktivkohlen. Es wurde festgestellt, daß die Adsorption des 4-Nitrophenols für alle untersuchten kohlenstoffhaltigen Materialien gemäß der Freundlich-Gleichung stattfindet. Die Raster-Elektronenmikroskopie zeigt, daß die hergestellten kohlenstoffhaltigen Materialien andere Porenarten aufweisen als die kommerziellen Aktivkohlen. Die experimentellen Ergebnisse werden durch die molekularen Dimensionen der zur Adsorption verwendeten Substanzen und den Polarisationseffekt der Substituenten am Benzolring erklärt.
    Notes: Mixtures of phenol-formaldehyde-resin and pressed olive stones in a weight ratio of 20/80 were cured as small cylinders and then pyrolyzed. Some samples were also activated by steam. For these specimens and for two commercial activated carbons of laboratory or industrial uses the specific surface area, the structure, the adsorption properties, and the adsorption capacity were determined. The results indicate that the carbonaceous material produced by activation has greater values for the examined properties in comparison to the only pyrolyzed and the two commercial activated carbons, respectively. It was found that the Freundlich-equation is valid for the adsorption of 4-nitrophenol on all carbonaceous materials examined. The produced carbonaceous materials have different kinds of pores than the commercial activated carbons. The experimental results are explained with regard to the molecular dimensions of the adsorptive substances and the polarization effect of the substituents of the benzene ring.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/apmc.1988.051630105
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    Nonlinear programming methods to determine surface free energy components of polymers using harmonic mean approximation (1988)
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 163 (1988), S. 101-114 
    Details
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Durch Anwendung der nichtlinearen Programmiermethode basierend auf der mittleren harmonischen Näherung wurden aus den Kontaktwinkeldaten die freie Dispersions- und polare, freie Oberflächenenergie, γSVd und γSVp, sowie die kritische, freie Oberflächenenergie, γc, von Polymeren bestimmt. Die Komponenten der freien Oberflächenergie der zu untersuchenden Flüssigkeiten, γLVd und γLVp, die die Bedingungen für den maximalen Wechselwirkungsparameter, Φ, wiedergeben, wurden ebenfalls mit Hilfe dieser Methode bestimmt.
    Notes: The dispersion and polar surface free energy components, γSVd and γSVp, and the critical surface free energy, γc, of polymers were determined from contact angle data by the application of a nonlinear programming method using harmonic mean approximation.The surface free energy components of the probe liquids, γLVd and γLVp, which reflect the conditions of the maximized interaction parameter, Φ, were also simultaneously determined by this method.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/apmc.1988.051630109
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    Gemeinsame kondensation von bisphenol A, melamin und formaldehyd (1988)
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 163 (1988), S. 169-193 
    Details
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: The condensation reaction of bisphenol A, melamine, and formaldehyde was investigated by gel permeation chromatography, 13C-NMR-spectroscopy, IR-spectroscopy and elemental analysis. Because of the high reaction rates the condensation could be investigated only in the range of pH 6-10. At pH 6 and 7 the reaction of melamine with formaldehyde is dominating.With increasing pH-value the condensation of bisphenol A with formaldehyde is observed preferably. At pH 10 the condensation results in high molecular products. Cocondensation of melamine and bisphenol A through methylene bridges does not take place. But as a separation of the bisphenol A-formaldehyde condensates from the other condensation products was not possible, the three components may be connected through methylene-ether groups and/or intermolecular hydrogen bridges.
    Notes: Die gemeinsame Kondensation von Bisphenol A, Melamin und Formaldehyd wurde mit Hilfe der Gelpermeationschromatographie, der 13C-NMR-Spektroskopie, IR-Spektroskopie und Elementaranalyse untersucht. Wegen der hohen Kondensationsgeschwindigkeit verläuft die Reaktion in Gegenwart der drei Komponenten nur im Bereich von pH 6-10 kontrollierbar. Bei pH 6 und 7 überwigt die Kondensation zwischen Melamin und Formaldehyd. Mit steigendem pH-Wert tritt die Reaktion von Bisphenol A mit Formaldehyd in den Vordergrund und führt bei pH 10 zu hochmolekularen Kondensationsprodukten.Auf direkte Cokondensation hinweisende Methylenverknüpfungen zwischen der phenolischen Komponente und Melamin konnten nicht nachgewiesen werden. Die Kondensationsprodukte des Melamins bzw. des Bisphenol A mit Formaldehyd lassen sich aber nicht mehr vollständig aus den Reaktionsgemischen der Vorkondensation abtrennen, was dafür spricht, daß die Komponenten über Methylenetherbrücken und/oder intermolekularen Wasserstoffbrücken miteinander verknüpft sind.
    Additional Material: 13 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/apmc.1988.051630115
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