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  • Chemistry  (33,712)
  • Chemical Engineering  (2,596)
  • Wiley-Blackwell  (33,678)
  • American Association for the Advancement of Science (AAAS)  (34)
  • 1980-1984  (33,712)
Collection
Publisher
  • Wiley-Blackwell  (33,678)
  • American Association for the Advancement of Science (AAAS)  (34)
  • Springer  (3)
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Year
  • 1
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    American Association for the Advancement of Science (AAAS)
    Publication Date: 1981-08-14
    Description: 〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Klotz, I M -- Haney, D N -- King, L C -- New York, N.Y. -- Science. 1981 Aug 14;213(4509):724-31.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/7256275" target="_blank"〉PubMed〈/a〉
    Keywords: Anemia, Sickle Cell/*drug therapy ; Aspirin/analogs & derivatives/therapeutic use ; Chemical Phenomena ; Chemistry ; *Hemoglobin, Sickle ; Humans ; Protein Binding/drug effects ; Protein Conformation ; Salicylates/*therapeutic use ; Solubility ; Structure-Activity Relationship
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
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  • 2
    Publication Date: 1982-09-10
    Description: Alkyl-Substituted gamma-butyrolactones were synthesized and tested for their convulsant and anticonvulsant actions in mice and guinea pigs. The alpha-substituted compounds, alpha, alpha-dimethyl-, and alpha-ethyl-alpha-methyl-gamma-butyrolactone were anticonvulsant compounds with a spectrum of activity similar to that of ethosuximide. In contrast, beta-substituted compounds were convulsant agents similar to picrotoxinin. The alpha-substituted-gama-butyrolactones represent a new class of anticonvulsant drug with experimental and clinical potential.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Klunk, W E -- McKeon, A -- Covey, D F -- Ferrendelli, J A -- GM-07200/GM/NIGMS NIH HHS/ -- GM-24483/GM/NIGMS NIH HHS/ -- NS-14834/NS/NINDS NIH HHS/ -- etc. -- New York, N.Y. -- Science. 1982 Sep 10;217(4564):1040-2.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/6810462" target="_blank"〉PubMed〈/a〉
    Keywords: *4-Butyrolactone/analogs & derivatives/*therapeutic use/toxicity ; Animals ; *Anticonvulsants ; Chemical Phenomena ; Chemistry ; Convulsants ; Drug Evaluation, Preclinical ; Electroencephalography ; Epilepsy, Absence/drug therapy ; Ethosuximide/pharmacology ; *Furans/*therapeutic use ; Guinea Pigs ; Mice ; Structure-Activity Relationship ; Trimethadione/pharmacology
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  • 3
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    American Association for the Advancement of Science (AAAS)
    Publication Date: 1983-05-06
    Description: Crystalline cholesterol undergoes a phase transition a few degrees below human body temperature. The high-temperature form has an unusually complex structure with 16 independent molecules. In the transition two molecules change side chain conformation, four reorient about their long axes, and ten remain unchanged. The transition mechanism implies relatively nonspecific intermolecular interactions, qualitatively consistent with the behavior of cholesterol in biomembranes. The transition preserves a remarkably closely obeyed pseudosymmetry present in the structure.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Hsu, L Y -- Nordman, C E -- GM15259/GM/NIGMS NIH HHS/ -- New York, N.Y. -- Science. 1983 May 6;220(4597):604-6.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/6836303" target="_blank"〉PubMed〈/a〉
    Keywords: Body Temperature ; Chemical Phenomena ; Chemistry ; *Cholesterol ; Crystallization ; Humans ; Magnetic Resonance Spectroscopy ; Molecular Conformation
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  • 4
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    American Association for the Advancement of Science (AAAS)
    Publication Date: 1984-07-20
    Description: The iron-carbon monoxide stretching mode and the iron-carbon-oxygen bending mode in carbon monoxide-bound cytochrome oxidase have been assigned at 520 and 578 cm-1, respectively. The frequencies, widths, and intensities of these modes show that the Fe-C-O grouping in carbon monoxide-cytochrome a3 is linear but tilted from the normal to the heme plane; that the iron-histidine bond in both five- and six-coordinate cytochrome a3 is strained; and that the carbon monoxide and the proximal histidine each have characteristic, well-defined orientations in all molecules. These data can account for the binding affinities of carbon monoxide and dioxygen under physiological conditions.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Argade, P V -- Ching, Y C -- Rousseau, D L -- New York, N.Y. -- Science. 1984 Jul 20;225(4659):329-31.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/6330890" target="_blank"〉PubMed〈/a〉
    Keywords: Animals ; Carbon Monoxide/metabolism ; Cattle ; Chemical Phenomena ; Chemistry ; Electron Transport Complex IV/*metabolism ; Myoglobin/metabolism ; Oxidation-Reduction ; Oxygen/metabolism ; Spectrum Analysis, Raman
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  • 5
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    American Association for the Advancement of Science (AAAS)
    Publication Date: 1983-05-06
    Description: Arachidonic acid plays a central role in a biological control system where such oxygenated derivatives as prostaglandins, thromboxanes, and leukotrienes are mediators. The leukotrienes are formed by transformation of arachidonic acid into an unstable epoxide intermediate, leukotriene A4, which can be converted enzymatically by hydration to leukotriene B4, and by addition of glutathione to leukotriene C4. This last compound is metabolized to leukotrienes D4 and E4 by successive elimination of a gamma-glutamyl residue and glycine. Slow-reacting substance of anaphylaxis consists of leukotrienes C4, D4, and E4. The cysteinyl-containing leukotrienes are potent bronchoconstrictors, increase vascular permeability in postcapillary venules, and stimulate mucus secretion. Leukotriene B4 causes adhesion and chemotactic movement of leukocytes and stimulates aggregation, enzyme release, and generation of superoxide in neutrophils. Leukotrienes C4, D4, and E4, which are released from the lung tissue of asthmatic subjects exposed to specific allergens, seem to play a pathophysiological role in immediate hypersensitivity reactions. These leukotrienes, as well as leukotriene B4, have pro-inflammatory effects.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Samuelsson, B -- New York, N.Y. -- Science. 1983 May 6;220(4597):568-75.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/6301011" target="_blank"〉PubMed〈/a〉
    Keywords: Animals ; Arachidonic Acids/metabolism/pharmacology/physiology ; Bronchi/drug effects ; Cats ; Chemical Phenomena ; Chemistry ; Cricetinae ; Guinea Pigs ; Haplorhini ; Humans ; Hypersensitivity, Immediate/*physiopathology ; Inflammation/*physiopathology ; Leukocytes/drug effects/metabolism ; Leukotriene B4/pharmacology/*physiology ; Mice ; Microcirculation/drug effects ; Rabbits ; Rats ; SRS-A/*physiology
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  • 6
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    American Association for the Advancement of Science (AAAS)
    Publication Date: 1984-01-20
    Description: Peptide synthesis can be used for elucidating the roles of secondary structures in the specificity of hormones, antigens, and toxins. Intermediate sized peptides with these activities assume amphiphilic secondary structures in the presence of membranes. When models are designed to optimize the amphiphilicity of the secondary structure, stronger interactions can be observed with the synthetic peptides than with the naturally occurring analogs.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Kaiser, E T -- Kezdy, F J -- HL-18577/HL/NHLBI NIH HHS/ -- New York, N.Y. -- Science. 1984 Jan 20;223(4633):249-55.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/6322295" target="_blank"〉PubMed〈/a〉
    Keywords: Amino Acid Sequence ; Apolipoprotein A-I ; Apolipoproteins ; Binding Sites ; Calcitonin ; Chemical Phenomena ; Chemistry ; Corticotropin-Releasing Hormone ; Endorphins ; Glucagon ; Growth Hormone-Releasing Hormone ; *Hormones/pharmacology ; Lipoproteins, HDL ; Melitten ; Models, Structural ; *Peptides/chemical synthesis/metabolism/pharmacology ; Protein Conformation ; Structure-Activity Relationship ; beta-Endorphin
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  • 7
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    American Association for the Advancement of Science (AAAS)
    Publication Date: 1984-10-19
    Description: Fourier transform mass spectrometry will play an important role in the future because of its unique combination of high mass resolution, high upper mass limit, and multichannel advantage. These features have already found application in gas chromatography-mass spectrometry, multiphoton ionization, laser desorption, and secondary ion mass spectrometry. However, its most notable feature is the ability to store ions. This characteristic, when combined with the others, will allow expeditious study of the interaction of gas-phase ions with both photons (photodissociation) and neutral molecules, and the convenient application of this fundamental information for chemical analysis.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Gross, M L -- Rempel, D L -- 2-8423576/PHS HHS/ -- New York, N.Y. -- Science. 1984 Oct 19;226(4672):261-8.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/6385250" target="_blank"〉PubMed〈/a〉
    Keywords: Chemical Phenomena ; Chemistry ; *Fourier Analysis ; Ions ; Lasers ; *Mass Spectrometry/instrumentation/methods
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  • 8
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    American Association for the Advancement of Science (AAAS)
    Publication Date: 1984-08-31
    Description: High-resolution carbon-13 nuclear magnetic resonance (NMR) spectra of enzyme-inhibitor and enzyme-substrate complexes provide detailed structural and stereochemical information on the mechanism of enzyme action. The proteases trypsin and papain are shown to form tetrahedrally coordinated complexes and acyl derivatives with a variety of compounds artificially enriched at the site or sites of interest. These results are compared with the structural information derived from x-ray diffraction. Detailed NMR studies have provided a clearer picture of the ionization state of the residues participating in enzyme-catalyzed processes than other more classical techniques. The dynamics of enzymic catalysis can be observed at sub-zero temperatures by a combination of cryoenzymology and carbon-13 NMR spectroscopy. With these powerful techniques, transient, covalently bound intermediates in enzyme-catalyzed reactions can be detected and their structures rigorously assigned.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Mackenzie, N E -- Malthouse, J P -- Scott, A I -- New York, N.Y. -- Science. 1984 Aug 31;225(4665):883-9.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/6433481" target="_blank"〉PubMed〈/a〉
    Keywords: Binding Sites ; Carbon Isotopes ; Carboxypeptidases/metabolism ; Carboxypeptidases A ; Catalysis ; Chemical Phenomena ; Chemistry ; Coenzymes/*metabolism ; Endopeptidases/metabolism ; Enzymes/*metabolism ; Freezing ; Fructose-Bisphosphate Aldolase/metabolism ; Magnetic Resonance Spectroscopy ; Papain/metabolism ; Pepsin A/metabolism ; Peptide Hydrolases/*metabolism ; Protease Inhibitors ; Pterins/metabolism ; Pyridoxal Phosphate/metabolism ; Serine Endopeptidases
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  • 9
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    American Association for the Advancement of Science (AAAS)
    Publication Date: 1984-03-09
    Description: 〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Maugh, T H 2nd -- New York, N.Y. -- Science. 1984 Mar 9;223(4640):1051-2.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/6695193" target="_blank"〉PubMed〈/a〉
    Keywords: *Air Pollutants ; *Atmosphere ; Carbon Tetrachloride ; Chemical Phenomena ; Chemistry ; *Chlorofluorocarbons, Methane ; Free Radicals ; Nitrogen Dioxide ; Nitrous Oxide ; Oxygen ; *Ozone ; Photochemistry ; Risk ; Singlet Oxygen ; Trichloroethanes ; Ultraviolet Rays
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  • 10
    Publication Date: 1984-10-19
    Description: Pyrolysis mass spectrometry in combination with computerized multivariate statistical analysis enables qualitative and quantitative analysis of nonvolatile organic materials containing molecular assemblies of a complexity and size far beyond the capabilities of direct mass spectrometry. The state of the art in pyrolysis mass spectrometry techniques is illustrated through specific applications, including structural determination and quality control of synthetic polymers, quantitative analysis of polymer mixtures, classification and structural characterization of fossil organic matter, and nonsupervised numerical extraction of component patterns from complex biological samples.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Meuzelaar, H L -- Windig, W -- Harper, A M -- Huff, S M -- McClennen, W H -- Richards, J M -- New York, N.Y. -- Science. 1984 Oct 19;226(4672):268-74.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/6484572" target="_blank"〉PubMed〈/a〉
    Keywords: Biochemical Phenomena ; Biochemistry ; Chemical Phenomena ; Chemistry ; Coal ; Enterobacteriaceae/analysis/isolation & purification ; Hot Temperature ; Mass Spectrometry/*methods ; Polymers
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  • 11
    Publication Date: 1984-08-31
    Description: The splicing of messenger RNA precursors in vitro proceeds through an intermediate that has the 5' end of the intervening sequence joined to a site near the 3' splice site. This lariat structure, which has been characterized for an adenovirus 2 major late transcript, has a branch point, with 2'-5' and 3'-5' phosphodiester bonds emanating from a single adenosine residue. The excised intervening sequence retains the branch site and terminates in a guanosine residue with a 3' hydroxyl group. The phosphate group at the splice junction between the two exons originates from the 3' splice site at the precursor.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Padgett, R A -- Konarska, M M -- Grabowski, P J -- Hardy, S F -- Sharp, P A -- P01-CA14051/CA/NCI NIH HHS/ -- P01-CA26717/CA/NCI NIH HHS/ -- R01-GM32467/GM/NIGMS NIH HHS/ -- New York, N.Y. -- Science. 1984 Aug 31;225(4665):898-903.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/6206566" target="_blank"〉PubMed〈/a〉
    Keywords: Adenoviruses, Human/metabolism ; Base Sequence ; Chemical Phenomena ; Chemistry ; Nucleic Acid Conformation ; Nucleic Acid Precursors/analysis/*metabolism ; Oligoribonucleotides/metabolism ; Phosphates/metabolism ; RNA/analysis/*metabolism ; RNA Precursors ; *RNA Splicing ; RNA, Messenger/analysis/*metabolism ; RNA, Viral/analysis/*metabolism
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  • 12
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    American Association for the Advancement of Science (AAAS)
    Publication Date: 1984-05-11
    Description: The mechanism of lipid peroxidation and the manner in which antioxidants function is reviewed. beta-Carotene is a purported anticancer agent, which is believed by some to have antioxidant action of a radical-trapping type. However, definitive experimental support for such action has been lacking. New experiments in vitro show that beta-carotene belongs to a previously unknown class of biological antioxidants. Specifically, it exhibits good radical-trapping antioxidant behavior only at partial pressures of oxygen significantly less than 150 torr, the pressure of oxygen in normal air. Such low oxygen partial pressures are found in most tissues under physiological conditions. At higher oxygen pressures, beta-carotene loses its antioxidant activity and shows an autocatalytic, prooxidant effect, particularly at relatively high concentrations. Similar oxygen-pressure-dependent behavior may be shown by other compounds containing many conjugated double bonds.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Burton, G W -- Ingold, K U -- New York, N.Y. -- Science. 1984 May 11;224(4649):569-73.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/6710156" target="_blank"〉PubMed〈/a〉
    Keywords: Antioxidants/*metabolism ; Carotenoids/*metabolism ; Chemical Phenomena ; Chemistry ; Free Radicals ; Humans ; Linoleic Acids/metabolism ; *Lipid Metabolism ; Oxidation-Reduction ; Oxygen/metabolism ; Partial Pressure ; Peroxides/metabolism ; Tetrahydronaphthalenes/metabolism ; beta Carotene
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  • 13
    Publication Date: 1983-12-16
    Description: Aplysiatoxin and debromoaplysiatoxin, which are isolated from the seaweed, Lyngbya gracilis, differ in their chemical structure only by the presence or absence of a bromine residue in the hydrophilic region. The function and the structure-activity relation of the hydrophilic region are not known. Aplysiatoxin increased malignant transformation, stimulated DNA synthesis, and inhibited the binding of phorbol-12,13-dibutyrate and epidermal growth factor to cell receptors. Debromoaplysiatoxin inhibited the binding of these two substances as strongly as aplysiatoxin but did not increase malignant transformation or stimulate DNA synthesis. These results indicate that a slight change in the chemical structure of the hydrophilic region of aplysiatoxin affects its abilities to increase cell transformation and stimulate DNA synthesis and that the abilities of the tumor promoters to inhibit the binding of phorbol-12,13-dibutyrate and epidermal growth factor are dissociable from their abilities to increase cell transformation and stimulate DNA synthesis under some circumstances.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Shimomura, K -- Mullinix, M G -- Kakunaga, T -- Fujiki, H -- Sugimura, T -- New York, N.Y. -- Science. 1983 Dec 16;222(4629):1242-4.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/6316505" target="_blank"〉PubMed〈/a〉
    Keywords: Animals ; *Caenorhabditis elegans Proteins ; Carcinogens/*pharmacology ; Carrier Proteins ; Cell Line ; Cell Transformation, Neoplastic/*drug effects ; Chemical Phenomena ; Chemistry ; DNA/biosynthesis ; Epidermal Growth Factor/metabolism ; Lactones/analysis/*pharmacology ; *Lyngbya Toxins ; Mice ; Phorbol 12,13-Dibutyrate ; Phorbol Esters/metabolism ; *Protein Kinase C ; Receptor, Epidermal Growth Factor ; Receptors, Cell Surface/metabolism ; *Receptors, Drug ; Structure-Activity Relationship
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  • 14
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    American Association for the Advancement of Science (AAAS)
    Publication Date: 1984-03-16
    Description: Yeast phenylalanine transfer RNA was subjected to a 12-picosecond molecular dynamics simulation. The principal features of the x-ray crystallographic analysis are reproduced, and the amplitudes of atomic displacements appear to be determined by the degree of exposure of the atoms. An analysis of the hydrogen bonds shows a correlation between the average length of a bond and the fluctuation in that length and reveals a rocking motion of bases in Watson-Crick guanine X cytosine base pairs. The in-plane motions of the bases are generally of larger amplitude than the out-of-plane motions, and there are correlations in the motions of adjacent bases.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Harvey, S C -- Prabhakaran, M -- Mao, B -- McCammon, J A -- New York, N.Y. -- Science. 1984 Mar 16;223(4641):1189-91.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/6560785" target="_blank"〉PubMed〈/a〉
    Keywords: Chemical Phenomena ; Chemistry ; Computers ; Cytosine ; Guanine ; Hydrogen Bonding ; Nucleic Acid Conformation ; *RNA, Fungal ; *RNA, Transfer, Amino Acyl ; Yeasts/analysis
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  • 15
    Publication Date: 1984-11-16
    Description: Sequence-dependent variations in DNA revealed by x-ray crystallographic studies have suggested that certain DNA-reactive drugs may react preferentially with defined sequences in DNA. Drugs that wind around the helix and reside within one of the grooves of DNA have perhaps the greatest chance of recognizing sequence-dependent features of DNA. The antitumor antibiotic CC-1065 covalently binds through N-3 of adenine and resides within the minor groove of DNA. This drug overlaps with five base pairs for which a high sequence specificity exists.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Hurley, L H -- Reynolds, V L -- Swenson, D H -- Petzold, G L -- Scahill, T A -- New York, N.Y. -- Science. 1984 Nov 16;226(4676):843-4.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/6494915" target="_blank"〉PubMed〈/a〉
    Keywords: Antibiotics, Antineoplastic/*metabolism ; *Base Sequence ; Binding Sites ; Chemical Phenomena ; Chemistry ; DNA/*metabolism ; *Indoles ; Leucomycins/*metabolism ; Molecular Conformation ; X-Ray Diffraction
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  • 16
    Publication Date: 1984-06-15
    Description: A new class of synthetic antifungal agents, the allylamines , has been developed by modification of naftifine , a topical antimycotic. SF 86-327, the most effective of these compounds so far, is highly active in vitro against a wide range of fungi and exceeds clinical standards in the oral and topical treatment of guinea pig dermatophytoses. SF 86-327 is a powerful specific inhibitor of fungal squalene epoxidase, a key enzyme in sterol biosynthesis.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Petranyi, G -- Ryder, N S -- Stutz, A -- New York, N.Y. -- Science. 1984 Jun 15;224(4654):1239-41.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/6547247" target="_blank"〉PubMed〈/a〉
    Keywords: Allylamine/analogs & derivatives/*chemical synthesis/pharmacology ; Amines/*chemical synthesis ; Animals ; Antifungal Agents/*chemical synthesis/pharmacology ; Chemical Phenomena ; Chemistry ; Dermatomycoses/drug therapy ; Fungi/*drug effects/enzymology ; Guinea Pigs ; Naphthalenes/chemical synthesis/pharmacology ; Oxygenases/*antagonists & inhibitors ; Squalene Monooxygenase
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  • 17
    Publication Date: 1984-11-02
    Description: By recombinant DNA techniques, a disulfide bond was introduced at a specific site in T4 lysozyme, a disulfide-free enzyme. This derivative retained full enzymatic activity and was more stable toward thermal inactivation than the wild-type protein. The derivative, T4 lysozyme (Ile3----Cys), was prepared by substituting a Cys codon for an Ile codon at position 3 in the cloned lysozyme gene by means of oligonucleotide-dependent, site-directed mutagenesis. The new gene was expressed in Escherichia coli under control of the (trp-lac) hybrid tac promoter, and the protein was purified. Mild oxidation generated a disulfide bond between the new Cys3 and Cys97, one of the two unpaired cysteines of the native molecule. Oxidized T4 lysozyme (Ile3----Cys) exhibited specific activity identical to that of the wild-type enzyme when measured at 20 degrees C in a cell-clearing assay. The cross-linked protein was more stable than the wild type during incubation at elevated temperatures as determined by recovered enzymatic activity at 20 degrees C.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Perry, L J -- Wetzel, R -- New York, N.Y. -- Science. 1984 Nov 2;226(4674):555-7.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/6387910" target="_blank"〉PubMed〈/a〉
    Keywords: Chemical Phenomena ; Chemistry ; DNA, Recombinant/metabolism ; Escherichia coli/enzymology ; *Genetic Engineering ; Kinetics ; Muramidase/*genetics/metabolism ; Protein Denaturation
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  • 18
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    American Association for the Advancement of Science (AAAS)
    Publication Date: 1983-09-09
    Description: The structures of three proteins that regulate gene expression have been determined recently and suggest how these proteins may bind to their specific recognition sites on the DNA. One protein (Cro) is a repressor of gene expression, the second (CAP) usually stimulates gene expression, and the third (lambda repressor) can act as either a repressor or an activator. The three proteins contain a substructure consisting of two consecutive alpha helices that is virtually identical in each case. Structural and amino acid sequence comparisons suggest that this bihelical fold occurs in a number of proteins that regulate gene expression, and is an intrinsic part of the DNA-protein recognition event. The modes of repression and activation by Cro and lambda repressor are understood reasonably well, but the mode of action of CAP is still unclear.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Takeda, Y -- Ohlendorf, D H -- Anderson, W F -- Matthews, B W -- GM20066/GM/NIGMS NIH HHS/ -- GM28138/GM/NIGMS NIH HHS/ -- GM30894/GM/NIGMS NIH HHS/ -- New York, N.Y. -- Science. 1983 Sep 9;221(4615):1020-6.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/6308768" target="_blank"〉PubMed〈/a〉
    Keywords: Amino Acid Sequence ; Chemical Phenomena ; Chemistry ; *DNA Helicases ; DNA-Binding Proteins ; Escherichia coli/genetics ; Gene Expression Regulation ; Models, Chemical ; Protein Conformation
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  • 19
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    American Association for the Advancement of Science (AAAS)
    Publication Date: 1984-06-08
    Description: The effect of a partial pressure of nitrogen of 50 atmospheres (5065 kilopascals ) on the hydrogen evolution reaction of nitrogenase has been investigated. Evolution of hydrogen was not blocked completely by 50 atmospheres of nitrogen in any of four experiments; rather, 27.3 +/- 2.4 percent of the total electron flux through nitrogenase was directed toward production of hydrogen. The ratio of hydrogen evolved to nitrogen fixed was close to 1:1, which implies that hydrogen evolution is obligatory in the fixation of molecular nitrogen by nitrogenase.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Simpson, F B -- Burris, R H -- AI-00848/AI/NIAID NIH HHS/ -- New York, N.Y. -- Science. 1984 Jun 8;224(4653):1095-7.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/6585956" target="_blank"〉PubMed〈/a〉
    Keywords: Chemical Phenomena ; Chemistry ; *Hydrogen ; *Nitrogen ; Nitrogen Fixation ; *Nitrogenase ; Partial Pressure
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  • 20
    Publication Date: 1980-01-04
    Description: In concentrates of water produced in a laboratory simulation of a drinking water treatment process, direct-acting, nonvolatile mutagens were readily detected by means of the Ames Salmonella test. The mutagens were shown to be produced by the chlorination process. Treatment of the water with chloramine resulted in less mutagenic activity than treatment with free chlorine. Dechlorination of drinking water with sulfite sharply reduced the mutagenic activity. Treatment with sulfur dioxide is proposed as an effective, inexpensive method of reducing the direct-acting mutagenic activity of drinking water and of aqueous industrial effluents.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Cheh, A M -- Skochdopole, J -- Koski, P -- Cole, L -- New York, N.Y. -- Science. 1980 Jan 4;207(4426):90-2.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/6985746" target="_blank"〉PubMed〈/a〉
    Keywords: Chemical Phenomena ; Chemistry ; Chloramines ; Chlorine ; Mutagens/*analysis ; Salmonella typhimurium/genetics ; Sulfites ; Water Pollutants/*analysis ; Water Pollutants, Chemical/*analysis ; Water Supply/*analysis
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  • 21
    Publication Date: 1981-10-16
    Description: The DNA/RNA Synthesizer provides a complete and automated procedure for the synthesis of DNA sequences. Each base unit is added in a 30-minute cycle, permitting a tetradecamer to be constructed in 6 1/2 hours. The complete procedure is described, including a practical procedure for isolation and purification of the desired DNA sequence.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Alvarado-Urbina, G -- Sathe, G M -- Liu, W C -- Gillen, M F -- Duck, P D -- Bender, R -- Ogilvie, K K -- New York, N.Y. -- Science. 1981 Oct 16;214(4518):270-4.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/6169150" target="_blank"〉PubMed〈/a〉
    Keywords: Automation ; Chemical Phenomena ; Chemistry ; DNA/*chemical synthesis ; *Genes, Synthetic ; RNA/*chemical synthesis ; Solubility
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  • 22
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    American Association for the Advancement of Science (AAAS)
    Publication Date: 1981-05-15
    Description: Research on chitin as a marine resource is pointing to novel applications for this cellulose-like biopolymer. Discovery of nondegrading solvent systems has permitted the spinning of filaments, for example, for use as surgical sutures. New methods for preparing the bioactive alkyl glycoside of N-acetyl-D-glucosamine (the monomer unit of chitin) and a microcrystalline chitin has encouraged their use as promoters for growth of bifidobacteria and as an aid in digestion of high-lactose cheese whey by domestic animals. Chitin-protein complexes of several crustacean species show great variability in ratios of chitin to covalently bound protein and in residual protein in the "purified" chitins.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Austin, P R -- Brine, C J -- Castle, J E -- Zikakis, J P -- New York, N.Y. -- Science. 1981 May 15;212(4496):749-53.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/7221561" target="_blank"〉PubMed〈/a〉
    Keywords: Animal Feed ; Animals ; Cheese ; Chemical Phenomena ; Chemistry ; Chickens ; *Chitin ; Crystallography ; Lactose/metabolism ; Proteins/analysis ; Sutures ; *Technology
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  • 23
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    American Association for the Advancement of Science (AAAS)
    Publication Date: 1981-12-18
    Description: 〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Gilbert, W -- New York, N.Y. -- Science. 1981 Dec 18;214(4527):1305-12.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/7313687" target="_blank"〉PubMed〈/a〉
    Keywords: Base Sequence ; Chemical Phenomena ; Chemistry ; DNA/*genetics ; Eukaryotic Cells/physiology ; *Genes ; Hydrazines ; Lac Operon ; Methylation ; Prokaryotic Cells/physiology ; Sulfuric Acid Esters
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  • 24
    Publication Date: 1982-07-09
    Description: A new process has been developed which is called "Boradeption" to signify boronic acid--dependent phase transfer of water-insoluble agents. Highly fluorescent boronic acid dervatives, FluoroBoras, are solubilized with a physiologically compatible carrier buffer containing a receptor group for boronate adduct formation. The system can be used to stain living cells. In another variation of the Boradeption concept, an insoluble reporter molecule containing a boronate receptor is solubilized with a carrier buffer containing a boronic acid functional group. The boronate-receptor complexes, which are in dynamic equilibrium, can be designed as vital stains and reagents for a variety of biological and medical applications.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Gallop, P M -- Paz, M A -- Henson, E -- AG-00376-07/AG/NIA NIH HHS/ -- HL-20764-04A1/HL/NHLBI NIH HHS/ -- New York, N.Y. -- Science. 1982 Jul 9;217(4555):166-9.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/6178158" target="_blank"〉PubMed〈/a〉
    Keywords: Animals ; *Biological Transport ; *Boron Compounds/therapeutic use ; *Boronic Acids/therapeutic use ; *Cell Membrane Permeability ; Cells, Cultured ; Chemical Phenomena ; Chemistry ; Chromogenic Compounds/metabolism ; Cricetinae ; Fibroblasts ; Fluorescent Dyes/metabolism ; Humans ; Rats ; Staining and Labeling
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  • 25
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    American Association for the Advancement of Science (AAAS)
    Publication Date: 1981-12-11
    Description: The scrapie agent causes a degenerative nervous system disease in sheep and goats. Studies with extensively purified preparations demonstrated that the agent contains a protein that is required for infectivity. Chemical modification of the scrapie agent by diethyl pyrocarbonate reduced the titer 1000-fold. Exposure of the inactivated agent to hydroxylamine, a strong nucleophile, resulted in complete restoration of infectivity. Presumably, nucleophilic residues within a scrapie agent protein undergo carbethoxylation on reaction with diethyl pyrocarbonate, and subsequent addition of hydroxylamine displaces these carbethoxy groups.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉McKinley, M P -- Masiarz, F R -- Prusiner, S B -- NS14069/NS/NINDS NIH HHS/ -- New York, N.Y. -- Science. 1981 Dec 11;214(4526):1259-61.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/6795721" target="_blank"〉PubMed〈/a〉
    Keywords: Animals ; Biological Assay ; Brain/microbiology ; Chemical Phenomena ; Chemistry ; Cricetinae ; Diethyl Pyrocarbonate/pharmacology ; Histidine/pharmacology ; *Prions ; Ribonucleases/pharmacology ; Serum Albumin, Bovine/pharmacology ; Viral Proteins/*isolation & purification/pharmacology
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  • 26
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    American Association for the Advancement of Science (AAAS)
    Publication Date: 1981-01-30
    Description: The incubation of lens proteins with reducing sugars leads to the formation of fluorescent yellow pigments and cross-like similar to those reported in aging and cataractous human lenses. Called nonenzymatic browning or the Maillard reaction, this aging process also occurs in stored foods. Reducing sugars condense with the free amino group of proteins, then rearrange and dehydrate to form unsaturated pigments and cross-linked products. Although most proteins in living systems turn over with sufficient rapidity to avoid nonenzymatic browning, some, such as lens crystallins and skin collagen, are exceptionally long-lived and may be vulnerable.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Monnier, V M -- Cerami, A -- AM 19655/AM/NIADDK NIH HHS/ -- New York, N.Y. -- Science. 1981 Jan 30;211(4481):491-3.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/6779377" target="_blank"〉PubMed〈/a〉
    Keywords: *Aging ; Animals ; Cattle ; Chemical Phenomena ; Chemistry ; *Crystallins ; Diabetes Mellitus/physiopathology ; Glucose ; Glucosephosphates ; In Vitro Techniques ; Lysine ; *Proteins ; Spectrophotometry, Ultraviolet
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  • 27
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    American Association for the Advancement of Science (AAAS)
    Publication Date: 1981-03-13
    Description: Great advances have been made in fundamental scientific research in recent years. The new knowledge gathered, in addition to deepening our understanding of the physical universe, contributes a range of abilities and opportunities to society that would not otherwise be available. Much research that may be called applied because it addresses needs of society is quite fundamental in character, and support of such research at the National Science Foundation is to be handled in tandem by the research directorates. Other areas that require a refocusing of support are engineering science and education, at all levels, in science and engineering. Increasing our strength in these areas is essential to achieve our national economic, social, and political goals. Steps are being taken by the National Science Foundation to make its structure better able to deal with engineering and applied research and to provide greater mutual reinforcement between applied and basic research.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Slaughter, J B -- New York, N.Y. -- Science. 1981 Mar 13;211(4487):1131-6.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/7466384" target="_blank"〉PubMed〈/a〉
    Keywords: Cell Biology ; Chemical Phenomena ; Chemistry ; *Forecasting ; Geological Phenomena ; Geology ; *Government Agencies ; Molecular Biology ; Neurochemistry ; Physical Phenomena ; Physics ; Research Support as Topic ; United States
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  • 28
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    American Association for the Advancement of Science (AAAS)
    Publication Date: 1982-12-10
    Description: The discovery that cis-diamminedichloroplatinum(II) (cis-DDP) has clinically useful antitumor properties and can form platinum blues spawned an extensive investigation of its chemistry in water. Several new molecules have been synthesized, some rather old ones have been characterized for the first time, and clues have begun to emerge about the chemical interaction of cis-DDP with its likely biological target, DNA.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Lippard, S J -- New York, N.Y. -- Science. 1982 Dec 10;218(4577):1075-82.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/6890712" target="_blank"〉PubMed〈/a〉
    Keywords: Chemical Phenomena ; Chemistry ; *Cisplatin ; *Dna ; Hydrolysis ; Pigments, Biological
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  • 29
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    American Association for the Advancement of Science (AAAS)
    Publication Date: 1982-12-03
    Description: The visual response is initiated by light reception and transduction into chemical and electrical energy in the outer-segment membranes of rod and cone cells. Recent research on the molecular events controlled by light has clarified the roles of some of the rod outer-segment biomolecules. These developments and the current unresolved questions are described.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉O'Brien, D F -- New York, N.Y. -- Science. 1982 Dec 3;218(4576):961-6.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/6291153" target="_blank"〉PubMed〈/a〉
    Keywords: Animals ; Blood Proteins/metabolism ; Calcium/metabolism ; Chemical Phenomena ; Chemistry ; Enzyme Activation ; Enzymes/metabolism ; GTP-Binding Proteins ; Light ; Membranes/metabolism ; Models, Biological ; Phosphoric Diester Hydrolases/biosynthesis ; Photoreceptor Cells/*metabolism ; Receptors, Cell Surface/metabolism ; Rhodopsin/metabolism ; Rod Cell Outer Segment/*metabolism ; Vision, Ocular/*physiology
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  • 30
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    American Association for the Advancement of Science (AAAS)
    Publication Date: 1983-06-10
    Description: 〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Krenitsky, T A -- Beauchamp, L -- New York, N.Y. -- Science. 1983 Jun 10;220(4602):1106.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/6857236" target="_blank"〉PubMed〈/a〉
    Keywords: Acyclovir/metabolism ; *Antiviral Agents/metabolism ; Chemical Phenomena ; Chemistry ; Humans ; Vidarabine/metabolism
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  • 31
    Publication Date: 1983-05-06
    Description: Resonance Raman spectra of photolyzed carbonmonoxyhemoglobin obtained with 10-nanosecond pulses are compared with the spectra of photolyzed carbonmonoxyhemoglobin stabilized at 80 K. In comparing the deoxy with the photodissociated species, the changes in the Raman spectra are the same for these two experimental regimes. These results show that at ambient and cryogenic temperatures the heme pocket in liganded hemoglobin is significantly different from that of deoxyhemoglobin. It is concluded that measurements of the properties of intermediate species from photodissociated hemoglobin stabilized at low temperatures can be used to probe the short-lived metastable forms of hemoglobin present after photodissociation under biologically relevant solution conditions.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Ondrias, M R -- Friedman, J M -- Rousseau, D L -- New York, N.Y. -- Science. 1983 May 6;220(4597):615-7.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/6836305" target="_blank"〉PubMed〈/a〉
    Keywords: Carboxyhemoglobin ; Chemical Phenomena ; Chemistry ; Freezing ; *Hemoglobins ; Humans ; Ligands ; Spectrum Analysis, Raman ; Temperature
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  • 32
    Publication Date: 1983-04-15
    Description: Alkylating agents that display strong selectivity for opiate receptor types delta or mu were prepared by appropriate modification of the structures of the strong analgesics fentanyl, etonitazene, and endoethenotetrahydrooripavine. The availability of these substances should facilitate studies of the structural basis of receptor specificity and of the physiologic roles of these receptors.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Rice, K C -- Jacobson, A E -- Burke, T R Jr -- Bajwa, B S -- Streaty, R A -- Klee, W A -- New York, N.Y. -- Science. 1983 Apr 15;220(4594):314-6.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/6132444" target="_blank"〉PubMed〈/a〉
    Keywords: Alkylation ; Animals ; Benzimidazoles/analogs & derivatives/metabolism ; Brain/physiology ; Cells, Cultured ; Chemical Phenomena ; Chemistry ; Enkephalin, Methionine/analogs & derivatives/metabolism ; Fentanyl/analogs & derivatives/metabolism ; *Isothiocyanates ; Ligands ; Rats ; Receptors, Opioid/*metabolism/physiology ; Thebaine/analogs & derivatives/pharmacology
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  • 33
    Publication Date: 1980-10-01
    Description: 〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Bumb, R R -- Crummett, W B -- Cutie, S S -- Gledhill, J R -- Hummel, R H -- Kagel, R O -- Lamparski, L L -- Luoma, E V -- Miller, D L -- Nestrick, T J -- Shadoff, L A -- Stehl, R H -- Woods, J S -- New York, N.Y. -- Science. 1980 Oct;210(4468):385-90.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/6159682" target="_blank"〉PubMed〈/a〉
    Keywords: Air Pollutants/analysis ; Chemical Phenomena ; Chemistry ; Chromatography, High Pressure Liquid ; *Dioxins/analysis ; *Fires ; Power Plants ; Smoke/analysis ; Soil Pollutants/analysis ; Tetrachlorodibenzodioxin/analysis ; Vehicle Emissions/analysis ; Water Pollutants, Chemical/analysis
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  • 34
    Publication Date: 1984-05-25
    Description: Polypeptide analogs of the known members of the corticotropin-releasing factor (CRF) family were synthesized and tested in vitro and in vivo for enhanced potency or competitive antagonism. Predictive methods and physicochemical measurements had suggested an internal secondary alpha-helical conformation spanning about 25 residues for at least three members of the CRF family. Maximization of alpha-helix-forming potential by amino acid substitutions from the native known sequences (rat/human and ovine CRF, sauvagine, and carp and sucker urotensin 1) led to the synthesis of an analog that was found to be more than twice as potent as either of the parent peptides in vitro. In contrast, certain amino-terminally shortened fragments, such as alpha-helical CRF or ovine CRF residues 8 to 41, 9 to 41, and 10 to 41, were found to be competitive inhibitors in vitro. Selected antagonists were examined and also found to be active in vivo.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Rivier, J -- Rivier, C -- Vale, W -- AA03504/AA/NIAAA NIH HHS/ -- AM20917/AM/NIADDK NIH HHS/ -- AM26741/AM/NIADDK NIH HHS/ -- etc. -- New York, N.Y. -- Science. 1984 May 25;224(4651):889-91.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/6326264" target="_blank"〉PubMed〈/a〉
    Keywords: Adrenocorticotropic Hormone/secretion ; Animals ; Binding, Competitive ; Chemical Phenomena ; Chemistry ; Corticotropin-Releasing Hormone/*antagonists & inhibitors ; Rats
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  • 35
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Materialwissenschaft und Werkstofftechnik 11 (1980), S. 1-14 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Material Stressing under Rolling Contact - Influence of Friction and Residual StressesMaterial stressing of parts in rolling contact is in the main made up by the normal load to be transmitted, by surface friction due to slippage of the body in rolling contact and by residual stresses. The effects of varying slippage rates are described as well as the additional influence of residual stresses on magnitude, position and direction of load.By the aid of mere mechanical reflections the formation of flat and steep White Bands can be interpreted which are observed in long-lived ball bearings subjected to high stresses. The report shows that residual stresses and friction must not be neglected when describing the material stressing by rolling contact. This especially applies to residual stresses originating from rolling contact.
    Notes: Die Werkstoffanstrengung bei Wälzkontakt ist im wesentlichen gegeben durch die zu übertragenden Normalkräfte, die Reibung an der Oberfläche (durch das Gleiten der beiden Wälzpartner) und durch die Eigenspannungen. Die Wirkung unterschiedlich großer Gleitanteile wird dargestellt und der zusätzliche Einfluß von Eigenspannungen auf die Höhe, Lage und Richtung der Beanspruchung ausgewiesen.Anhand rein mechanischer Betrachtungen läßt sich die Entstehung von flachen und steilen Weißen Bändern deuten, die in langlebigen, hochbeanspruchten Kugellagern beobachtet werden. Der Bericht zeigt, daß Eigenspannungen und Reibung keinesfalls bei der Beschreibung der Werkstoffanstrengung durch Wälzbeanspruchung vernachlässigt werden dürfen. Dies gilt insbesondere auch für die Eigenspannungen, die durch die Wälzbeanspruchung entstehen.
    Additional Material: 27 Ill.
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  • 36
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Materialwissenschaft und Werkstofftechnik 11 (1980) 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
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  • 37
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Materialwissenschaft und Werkstofftechnik 11 (1980), S. 21-30 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Investigations of Crack Initiation and Crack Propagation in Plain Carbon Steels by Means of Acoustic-EmissionCrack initiation and propagation has been studied during fatigue tests with ferritic, ferritic-pearlitic and pearlitic specimens by means of acoustic emission (A.E.) instrumentation. The ferrite and the ferrite-pearlite showed acoustic emission only in connection with fast yielding of large volumes. Early steps of crack initiation showed no detectable acoustic emission because of very small yielded volumes and small amounts of crack surface friction. Gapping of the cracks inhibited A.E. due to friction during the early steps of crack propagation. Pearlitic specimens showed strong A.E. prior to microscopic detection of cracks, ascribed to fast fracture modes.Cracks in ferritic and ferritic-pearlitic CT-specimens are only detectable by crack surface friction. The increase of yielded volume with the propagating crack is too small to be distinguished from friction noise. Pearlitic specimens showed strong burst-signal activity ascribed to cleavage fracture and fast fracture modes.Great differences in A.E. of specimens with the same microstructure are in most cases the result of differing crack surface topography and therefore very differing friction areas. Friction noise depends clearly upon loading conditions and crack surface geometry.
    Notes: An drei unlegierten Kohlenstoffstählen mit ferritischer, ferritischperlitischer und rein perlitischer Gefügestruktur wurden Untersuchungen über den Rißbeginn und den Rißfortschritt bei schwingender Beanspruchung mit Hilfe von Schallemissionsmessungen durchgeführt.Bei den Untersuchungen des Rißbeginnes konnten in den ferritischen und den ferritisch-perlitischen Werkstoffen nur rasch ablaufende Verformungsvorgänge mit ausreichendem Verformungsvolumen über die Schallemission registriert werden. Durch die örtlich begrenzten plastischen Verformungen und die geringen Flächenanteile der Rißuferreibung waren die Rißkeimbildungen nicht erfaßbar. Die ersten Stadien der Rißausbreitung ergaben ebenfalls, aufgrund des Klaffens der gebildeten Risse, keine registrierbare Schallemission durch Reibung. Bei perlitischen Werkstoffen kam es vor Erkennung eines mikroskopischen Risses zu starker Schallemission, die offensichtlich mit energiereichen Ereignissen, wie rasch ablaufenden Bruchmoden, im Zusammenhang stehen.Ein Riß ist bei Schwingungsbeanspruchung in ferritischen und ferritisch-perlitischen CT-Proben bei ausreichender Größe der Rißflächen nur über Reibung feststellbar. Der eigentliche Rißfortschritt konnte durch die geringe Volumenzunahme der plastischen Zone pro Lastwechsel nicht registriert werden. Bei perlitischen Proben trat vor allem bei grob lamellarer Ausbildung des Zementits eine starke Schallemission meist in Form von Burstsignalen auf, die vorwiegend auf die Bildung von Bruchmoden hoher Energie, wie z. B. Spaltbruch, zurückzuführen sein dürften.Die vielfach sehr starken Unterschiede der Schallemission beim Rißfortschritt in Proben gleicher Gefügeausbildung sind überwiegend der verschieden großen Rißflächenreibung durch die oft sehr unterschiedliche Topographie der Rißbruchflächen zuzuschreiben. Bei Änderung der Mittellast oder der Lastamplitude ist eine deutliche Abhängigkeit des Reibungsgeräusches aus den Rißflächen von den Rißöffnungsverhältnissen hinter der Rißfront festzustellen. Nach einzelnen Überlasten während des Rißfortschrittes kann die Schallemission in gleicher Weise mit Veränderungen der Reibungsverhältnisse hinter der Rißspitze interpretiert werden.
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  • 38
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    Materialwissenschaft und Werkstofftechnik 11 (1980), S. 60-67 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Applicability of the Potential Drop Technique for Crack Growth InvestigationsA potential drop method, based on the compensation concept is described; technical parameters and capability are discussed.Selected examples with metallic alloys for high temperature and heat resistant application demonstrate the applicability of the method for fatigue and creep crack growth investigations in the temperature range up to 1173 K and 1223 K, respectively. At room temperature and at 1173 K the results of the potential drop method are verified by optical means.
    Notes: Es wird eine Potentialsondenmethode nach dem Kompensationsprinzip vorgestellt; ihre technischen Merkmale sowie ihr Leistungsvermögen werden diskutiert.Anhand ausgesuchter Beispiele an metallischen Legierungen für den warmfesten und hitzebeständigen Anwendungsbereich wird ihr Einsatz in Versuchen zum Ermüdungs- bzw. 1223 K demonstriert. Bei Raumtemperatur sowie 1173 K wurden die Meßergebnisse durch Vergleichsmessungen mit optischen Mitteln verifiziert.
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  • 39
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    Materialwissenschaft und Werkstofftechnik 11 (1980), S. 73-76 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Hardening Behaviour of Steels by Cold WorkingContrary to common opinion work hardening increases with higher initial hardness (strength) of steel. This is proved by analysing stressstrain curves of tensile tests at overeleastic load carried out with normalized, hardened and tempered steel. Test results taken from literature are supported by own experiments. Practical application of this fact is discussed very shortly.
    Notes: Bei Stählen steigt im Gegensatz zur herrschenden Meinung die Kaltverfestigung (Aufhärtung) mit steigender Ausgangshärte oder -festigkeit an. Dies wird nachgewiesen an Ergebnissen aus Zugversuchen mit normalisierten und vergüteten Stählen. Ergebnisse der Literatur werden durch eigene Versuche ergänzt. Die praktische Nutzanwendung dieses Tatbestandes wird knapp andiskutiert.
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  • 40
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    Materialwissenschaft und Werkstofftechnik 11 (1980), S. 101-110 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Acoustic Emission Monitoring of Polymeric Composite Materials. Part II: Experimental resultsThe technique of acoustic emission monitoring of polymeric composite materials is described. It is a high sensitive, quasi-nondestructive testing method that indicates the origin and the behaviour of flaws in such materials, when submitted to different load histories. In the usage of sophisticated signal-analysis-methods it is possible to distinguish between different types of failure mechanisms, such as fiber fracture, delamination or fiber pull-out. Imperfections can be detected while monitoring complex composite structures by acoustic emission measurements.
    Notes: Das quasi-zerstörungsfreie Werkstoffprüfverfahren der Schallemissionsmessung und dessen Anwendung bei polymeren Verbundwerkstoffen wird beschrieben. Dieses Verfahren ermöglicht es, das Entstehen und das Verhalten von Werkstoffdefekten bei unterschiedlichen Lasteinwirkungen anzuzeigen. Mittels signalbewertender Analysenmethoden können die in Verbundwerkstoffen ablaufenden, unterschiedlichen Versagensmechanismen differenziert werden.Bei Bauteiluntersuchungen erweist sich das Schallemissionsmeßverfahren als außerordentlich sensitiv, um bauteilgefährdende Defekte und Werkstoffehler anzuzeigen.
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    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 42
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    Materialwissenschaft und Werkstofftechnik 11 (1980), S. 205-208 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Contribution to the Problem of Pressure-less Measurements of the Electric Conductivity of Powder MaterialsTwo authors (1, 2) proposed to use the electric conductivity of a loosely packed powder bed as the electric characteristics of the power material. The authors got reproducible and intercomparable results applying their method on various oxide powders, e.g. reduced MnO2 and mixed oxides. This is in contradiction to the common experience that in the range of small pressure, reliable results hardly can be obtained. Obviously, some special conditions have made the good results possible. Here below, the pressure-less method has been applied to four different powders: a species of MnO2, copper, Cd(OH)2 and PbO2.As the principal result, it has to be stated that the pressure-less method delivers reliable results only in the case of such powders, whose grain core resistance doesn't have to be neglected against the contact resistance between the grains. This condition is fulfilled here only in the case of manganese dioxide. Probably, the oxide powders under study in (1, 2) also have been in the correct range. In spite of this, the pressure-less method may not be applied on metal powders or on the metal-likek PbO2 powder. Also in the case of Cd(OH)2 masses, severe objections exist.
    Notes: Von zwei Autoren (1, 2) ist vorgeschlagen worden, die Leitfähigkeit einer Pulverschüttung als elektrische Kenngröße für den betreffenden Werkstoff zu verwenden. Das Verfahren ist in den beiden Arbeiten auf pulverförmige Oxide, z. B. reduziertes MnO2 und Mischoxide, angewendet worden und hat reproduzierbare und untereinander vergleichbare Meßwerte ergeben. Das widerspricht der bisherigen Erfahrung, wonach im Gebiet kleinster Drücke verläßliche Werte für die Leitfähigkeit nicht ermittelt werden können. Offenbar haben besondere Verhältnisse vorgelegen. In dieser Arbeit wird das drucklose Verfahren auf vier verschiedene Pulver angewendet: je ein Braunstein-, Kupfer-, PbO2- und Cd(OH)2-Pulver.Als wesentliches Ergebnis kann festgehalten werden, daß nur solche Pulverproben bei der drucklosen Messung verläßliche Werte ergeben, bei denen der Widerstandsanteil des Korninneren neben dem Kontaktwiderstand nicht vernachlässigbar klein ist. Das ist hier nur bei dem Braunstein-Pulver der Fall, ebenso wahrscheinlich bei den von (1, 2) untersuchten Oxidpulvern. Auf Metallpulver oder auf das annähernd metallisch leitende PbO2-Pulver dagegen darf die drucklose Meßmethode nicht angewendet werden. Auch bei dem Cd(OH)2-Pulver bestehen Bedenken.
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    Materialwissenschaft und Werkstofftechnik 11 (1980), S. 213-216 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Measurement of Residual Stress Reduction by Analysis of the Barkhausen-EffectResidual stresses and their variations under fatigue conditions have been measured by analysis of the Barkhausen-Effect.The stresses are proportional to the magnetic parameter M in a definite area.The investigations have been made on a high-strength fine-grained steel. under fatigue condition the relief of residual stresses is finished after a few stress cycles.By superposition of residual and load stresses the longitudinal stresses accept in consequence of the lateral contraction, whereas the transverse stresses are growing up in reason of their orientation to the direction of load stress.A change of the residual stress distribution could not be established.
    Notes: Eigenspannungen und ihre Veränderungen unter Ermüdungsbeanspruchung wurden durch Analyse des Barkhausen-Rauschens ermittelt. Die Spannungen sind in einem begrenzten Bereich dem magnetischen Parameter M proportional.Die Untersuchungen wurden an einem hochfesten Feinkornbaustahl durchgeführt. Bei Ermüdungsbeanspruchung ist der Eigenspannungsabbau nach wenigen Lastspielen beendet.Durch die Überlagerung von Eigen- und Lastspannungen nehmen die Längsspannungen infolge der Querkontraktion weiter ab, während die Querspannungen, da sie in Richtung der Belastung liegen, erhöht werden.Eine Veränderung der Eigenspannungsverteilung konnte nicht festgestellt werden.
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    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Materials Performance and Materials Selection under the Aspect of Cooling Water Corrosion of Heat ExchangersFor the chemical process industry cooling water corrosion problems are of special importance. Of the known corrosion phenomena nearly all can be observed with heat exchangers depending on water quality and material used. By appropriate water treatment, favourable design measures and optimum materials selection the corrosion problem on the cooling water side of heat exchangers can be solved. Water treatment and design measures are only casually delt with in this paper which emphasizes the aspects of materials selection. Using the proper material is of special importance for once-through cooling systems. For this reason the performance of various materials is described, e. g. unalloyed steel, unalloyed steel protected by organic coatings, austenitic 18 Cr-9 Ni-steels, ferritic Cr-steels, ferritic-austenitic steels, copper and copper alloys, titanium. For a variety of operating conditions the materials selection criteria are described. Finally, some aspects of corrosion economics in selecting materials are discussed.
    Notes: Für die chemische Industrie haben die Probleme der Korrosion in Kühlwässern besondere Bedeutung. Eine Vielzahl der bekannten Korrosionserscheinungen kann je nach Wasserqualität und eingestztem Werkstoff an Wärmetauschern beobachtet werden. Durch geeignete Wasserbehandlung, durch konstruktive Maßnahmen und nicht zuletzt durch eine optimale Werkstoffauswahl wird versucht, das Problem der Kühlwasserkorrosion zu lösen. Die beiden erstgenannten Punkte können allerdings hier nur am Rande behandelt werden. Die Werkstoffauswahl ist für die Konstruktion eines Wärmetauschers, insbesondere in Durchlaufsystemen, von besonderer Wichtigkeit. Das Verhalten der verschiedensten Werkstoffe (z. B. unlegierter Stahl, unlegierter Stahl + organische Beschichtungen, austenitische 18/8-CrNi-Stähle, ferritische Cr-Stähle, ferritisch-austenitische Stähle, Kupfer und Kupferlegierungen, Titan) in Kühlwässern wird beschrieben; entsprechende Auswahlkriterien werden angegeben. Abschließend werden einige wirtschaftliche Überlegungen zur Werkstoffauswahl dargestellt.
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    Materialwissenschaft und Werkstofftechnik 11 (1980), S. A60 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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    Materialwissenschaft und Werkstofftechnik 11 (1980), S. 275-281 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Carbon Fibres - Production, Properties and ApplicationsCarbon fibres are primarily regarded as a reinforcing material for resins, but can also be used in metal or carbon matrices. It is anticipated that over the next few years the present inception phase will develop into one of rapid business growth. The expected turnover and price developments, as well as the main fields of application are discussed.A great variety of carbon fibre types are available, whose properties are dictated by differences in the basic structure, yielding an exceptional range of properties from the isotropic low modulus to the high strength, high modulus, highly anisotropic HT and HM carbon fibres. The method of manufacture and the precursor materials are described, in particular the individual processing steps and changes accompanying the pyrolysis of PAN fibres. Future improvements in processing technology and precursor quality, promise a significant increase in the already very high properties level.
    Notes: Kohlenstoffasern sind vor allem als hochwertige Verstärkungskomponente in Verbundwerkstoffen mit Kunstharzen aber auch mit Metallen und Kohlenstoff als Matrix zu betrachten. Es ist vorauszusehen, daß die Phase der Markteinführung in den nächsten Jahren von einer starken Wachstumsphase abgelöst wird. Die zu erwartende Mengen- und Preisentwicklung sowie die sich abzeichnenden Hauptanwendungsgebiete werden diskutiert.Zum Verständnis der Eigenschaften der verschiedenen auf den Markt eingeführten Kohlenstoffasertypen werden deren Struktur und die Beziehungen zu den wichtigsten Fasereigenschaften behandelt. Daraus lassen sich auch die ungewöhnlichen Variationsmöglichkeiten ableiten  -  von den hochanisotropen HF- und HM-Fasern bis zu den isotropen Fasern.Die Faserherstellung und die verwendeten Rohstoffe werden beschrieben. Hierbei wird auf die Verfahrensschritte und auf die beim thermischen Abbau ablaufenden Vorgänge am Beispiel der PAN- Faser näher eingegangen. Die Weiterentwicklung der Herstellungs-technologie als auch der Rohfaserqualität läßt für die Zukunft noch eine fühlbare Steigerung des bereits heute hohen Eigenschaftsniveaus erwarten.
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    Materialwissenschaft und Werkstofftechnik 11 (1980), S. 287-293 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Fatigue Crack Propagation of High Strength AlloysInvestigations of the crack propagation behaviour under variable amplitude loading conditions show a strong influence of sequence effects. The fatigue crack propagation as a consequence of changes in the loading conditions is not linear. New continuum mechanical analyses enable an interpretation of the influence of sequence effects on fatigue crack propagation by considering the plastic deformations and displacements around the crack tip and their correlation to the crack closure behaviour. In order to enable a direct investigation of the crack propagation and crack closure behaviour in the scanning electron microscope a special loading equipment was designed. The investigations led to the following results: there existed only a weak correlation between the crack propagation rates and mechanisms at the side surfaces and on the fracture surfaces of the specimens,the crack propagation behaviour was significantly influenced by the microstructural constitution of the alloy,the continuum mechanical analyses could be corroborated in the tests.For the tests the high strength aluminum alloys 2024-T3 and X-7075 were applied.
    Notes: Bei der Betriebsbelastung schwingbeanspruchter Bauteile treten deutliche Last-Reihenfolgeneinflüsse auf. Die Rißausbreitung folgt diesen Änderungen in den Beanspruchungsbedingungen nicht linear. Neuere Erkenntnisse der Kontinuumsmechanik ermöglichen die Beurteilung von Reihenfolgeneinflüssen auf das Rißausbreitungsverhalten, bei denen insbesondere der Einfluß plastischer Verformungen und Verschiebungen auf das Rißschließverhalten berücksichtigt werden. Mit Hilfe einer speziellen Belastungsvorrichtung konnten die Rißausbreitung und die Rißschließung direkt im Rasterelektronenmikroskop untersucht werden. Es konnte festgestellt werden, daß an der Probenoberfläche und im Probeninnern Rißfortschritt und Rißausbreitungsmechanismus nicht vollständig korrelieren,der Mikromechanismus der Rißausbreitung deutlich durch die Mikrostruktur beeinflußt wird,die kontinuumsmechanischen Vorhersagen über den Rißschließvorgang weitgehend zutreffen.Die Versuche wurden mit den hochfesten Aluminiumlegierungen Al 2024-T3 und X-7075 durchgeführt.
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    Materialwissenschaft und Werkstofftechnik 11 (1980), S. A68 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Materialwissenschaft und Werkstofftechnik 11 (1980), S. 361-367 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Mechanische Eigenschaften von SiliciumnitridDie mechanischen Raumtemperatureigenschaften von reaktionsgebundenem und heißgepreßtem Siliciumnitrid werden unter Berücksichtigung des Gefüges dieser Werkstoffe besprochen.Materialbedingte Gefügeeigenschaften zeigen einen ausgeprägten Einfluß auf die Festigkeit. Bei reaktionsgebundenem Siliciumnitrid sind dies der Volumenanteil der Porosität und die Porengrößenverteilung im Werkstoff. Im Falle des heißgepreßten Siliciumnitrids beeinflussen der Volumenanteil der während der α/β-Phasenumwandlung gebildeten stäbchenförmigen β-Körner und deren Korngrößenverteilung die Festigkeit.
    Notes: The room temperature mechanical properties of reaction bonded and hot-pressed silicon nitride are reviewed with respect to the microstructure of the material. It is shown that the strength of these compounds is predominantly controlled by microstructural features. These are the volume fraction of porosity and the pore size distribution for reaction bonded Si3N4, and the volume fraction of elongated transformed β grains and their grain size for hot-pressed Si3N4.
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    Materialwissenschaft und Werkstofftechnik 11 (1980), S. A79 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Materialwissenschaft und Werkstofftechnik 11 (1980), S. A86 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Materialwissenschaft und Werkstofftechnik 11 (1980), S. 411-414 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
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    Materialwissenschaft und Werkstofftechnik 11 (1980) 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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    Materialwissenschaft und Werkstofftechnik 11 (1980), S. 423-434 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Kriechrißwachstum in austenitischen Stählen - Anwendbarkeit bruchmechanischer ParameterDie Ergebnisse über Kriechrißwachstum in den austenitischen Stählen AISI 304 und AISI 316 werden zusammengestellt. Der Vergleich der verschiedenen bruchmechanischen Parameter, die mit der Geschwindigkeit von Kriechrissen korreliert werden können, zeigt, daß momentan eine abschließende Bewertung nicht möglich ist. Bei der Übertragung von Kleinproben-Meßwerten auf Bauteile erscheinen für zukünftige Arbeiten das J-Integral bzw. modifizierte Versionen wie z. B. C* am aussichtsreichsten. Gewisse Attraktivität besitzt auch das Nettospannungskriterium. Der Spannungsintensitätsfaktor scheint wenig geeignet. Seine Anwendung führt zu einer konservativen Interpretation des bruchmechanischen Verhaltens.Im Zusammenhang mit den verschiedenen Parametern werden die Einflüsse von Temperatur, Geometrie und Umgebungsmedium auf das Kriechrißwachstum diskutiert.
    Notes: The comparison of fracture mechanics parameters, which have been applied to creep crack growth in case of the austenitic stainless steels AISI 304 and AISI 316, is possible only to a limited extent thus showing evidence that a reliable judgement cannot be given at this moment. With respect to the mechanical characterization of a cracked component by using small specimen data the J-integral resp. modified versions like C* have to be favoured for future work. The net-section stress seems to show promise under certain conditions as well. The application of the stress intensity factor will not characterize properly creep cracking by giving a conservative interpretation of the mechanical behaviour.With regard to fracture mechanics parameters the effects of temperature, geometry and environment on creep crack growth have also been discussed.
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    Materialwissenschaft und Werkstofftechnik 12 (1981), S. A2 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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    Materialwissenschaft und Werkstofftechnik 12 (1981), S. 11-13 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Quality Control of HDPE Pipes.Trials are reported made with the aim of finding an correlation between creep rupture test results obtained with two different types of testing samples: Pipes under internal pressure and tensile rods cut out of these pipes in a longitudinal direction.
    Notes: Es wird über Versuche berichtet, eine Korrelation zwischen Ergebnissen aus Zeitstand-Innendruckversuchen an HDPE-Rohren und Zeitstandversuchen an Längszugstäben aus diesen Rohren zu finden.
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    Materialwissenschaft und Werkstofftechnik 12 (1981), S. 23-31 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Controlled Pickling of Apparatus made of Chemical-Resistant SteelsExamples of material failure and corrosion trials are used to show that the chemical resistance of austenitic steel depends in many ways on the surface condition. Pickling is the best method for removing layers of oxide in preparation for passivation. Internal tensile stresses which are created near the surface by mechanical working, e.g. by turning, drilling and grinding, can assume higher values than those caused by shaping and welding. As a result stress corrosion cracking often occurs only in the region where the surface has been worked. Because the stresses responsible for this phenomenon rapidly fall off below the surface, it is usually possible to reduce them by pickling to the point at which damage of this kind is prevented. The amount of material which must be removed by pickling is determined by trials and pickling must be controlled accordingly.
    Notes: An Schadensfällen und durch Korrosionsversuche wird gezeigt, daß die chemische Beständigkeit der austenitischen Stähle in mehrfacher Weise von ihrem Oberflächenzustand abhängt. Beim Entfernen von Oxidbelägen, als Voraussetzung für eine gute Passivschicht, liefert das Beizen das beste Ergebnis. Oberflächennahe Zug-Eigenspannungen, die durch eine mechanische Bearbeitung, z. B. Drehen, Bohren, Schleifen, eingebracht werden, können höhere Werte annehmen als die durch Verformen und Schweißen verursachten Spannungen. Als Folge davon tritt oft nur im Bereich einer Oberflächenbearbeitung Spannungsrißkorrosion auf. Weil die zugehörigen Spannungen unter der Oberfläche schnell abfallen, ist es meist möglich, sie durch ein abtragendes Beizen so weit abzubauen, daß Schäden dieser Art unterbleiben. Der notwendige Beizabtrag ist durch Versuche zu ermitteln und das Beizen entsprechend zu überwachen.
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    Materialwissenschaft und Werkstofftechnik 12 (1981), S. 90-96 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Crack Growth Behaviour of Structural Steels in SeawaterThe influence of a synthetic seawater environment upon the crack growth behaviour of two structural steels was investigated. The results were presented in terms of the stress intensity fracture toughness parameter. Data were generated in air and in seawater with or without a cathodic protection. Results show that seawater environment and a cathodic protection influence the crack propagation at the applied frequencies of 0,04 and 0,25 Hz. The use of cathodic protection raises questions concerning the resistance to hydrogen embrittlement of the two steels. Some fractographic examinations of selected specimens show the microstructure of the two steels at various test conditions.
    Notes: Die Kenntnis der Ausbreitungsgeschwindigkeit von Rissen an Materialien in korrosiver Atmosphäre unter Betriebsbelastung ist für die Konstruktionsauslegung von großer Bedeutung. Von den Baustählen X70 sowie St70 ist mittels angeschwungener CT-Proben die Rißausbreitung bestimmt worden. Die Versuchsfrequenzen lagen - bezogen auf realistische Seegangsspektren - bei 0,04 Hz und 0,25 Hz. Durch Aufgabe kathodischer Schutzpotentiale wird bei Vorhandensein von Anrissen die Rißausbreitung stark beschleunigt. Es tritt eine wasserstoffinduzierte Spannungsrißkorrosion auf. Über das Ausmaß der Wasserstoffaufname der Bruchflächen werden Angaben gemacht. Durch REM-Aufnahmen wird das Bruchaussehen dokumentiert.
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    Materialwissenschaft und Werkstofftechnik 12 (1981), S. 107-108 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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    Materialwissenschaft und Werkstofftechnik 12 (1981), S. A28 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
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    Materialwissenschaft und Werkstofftechnik 12 (1981), S. 19-22 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Investigation of Different Welding Processes with Nickel-Alloy NiMo 16 Cr 16 TIThe overall favourable corrosion resistance of the nickel-chromium-molybdenum alloy NiMo 16Cr 16 Ti against attack by powerful oxidizing acids ensures a wide field of applications for this material. The alloy is readily processable using encased rod electrodes and shielded are welding. However, shielded arc welding should be given preference, as there are considerable differences in the analytical results between smelted welded material from encased rod electrodes and bright rods and wires. The different welded materials influence the corrosion resistance and the possibilities of forging welded constructions.
    Notes: Die allgemeine gute Korrosionsbeständigkeit der Nickelbasislegierung NiMo 16 Cr 16 Ti gegen den Angriff stark oxidierender Säuren sichert diesem Werkstoff ein breites Einsatzgebiet. Die Legierung ist mit umhüllten Stabelektroden und nach Schutzgasschweißverfahren gut zu verarbeiten. Bevorzugt sollte jedoch das Schutzgasschweißen eingesetzt werden, da erhebliche Analyseunterschiede zwischen dem niedergeschmolzenen Schweißgut aus umhüllten Stabelektroden und aus blanken Stäben und Drähten bestehen. Das unterschiedliche Schweißgut hat Einfluß auf das Korrosionsverhalten und die Warmformgebungsmöglichkeiten von geschweißten Konstruktionen.
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    Materialwissenschaft und Werkstofftechnik 12 (1981), S. A10 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Materialwissenschaft und Werkstofftechnik 12 (1981), S. 150-150 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
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    Materialwissenschaft und Werkstofftechnik 12 (1981), S. A34 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
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    Materialwissenschaft und Werkstofftechnik 12 (1981), S. 256-262 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Anisotropy Effects in Copper Alloy Strip MaterialsThe textures and effects of mechanical anisotropy have been measured in several copper alloy strip materials with commercial hardness levels. In most cases mixed textures have been found with a qualitative correlation to the mechanical effects.The optimum position for spring elements proved to be transverse to rolling direction, especially the relation of the elastic limit in bonding to yield strength has a maximum in this direction.
    Notes: Bei Bändern aus verschiedenen Kupferlegierungen in handelsüblichen Festigkeitszuständen wurden die Texturen und die mechanischen Anisotropieeffekte gemessen. In den meisten Fällen wurden Mischtexturen festgestellt, welche die mechanischen Anisotropieeffekte qualitativ erklären.Für Federelemente ist die Querlage die günstigste, insbesondere ist in dieser Richtung das Verhältnis Federbiegegrenze zu Streckgrenze am höchsten.
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    Materialwissenschaft und Werkstofftechnik 12 (1981) 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Materialwissenschaft und Werkstofftechnik 12 (1981), S. 330-334 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: The Guarantee of Quality for the Steel Hoops of the Refueling Machine of the Nuclear Ship OTTO HAHN by Way of a Special Procedure with UltrasonicThe basic overhaul and renewal of the refueling machine constructed 1965-1967 for the reactor system of the nuclear ship OTTO HAHN required among other things the replacement of the lifting hoops which are necessary for raising the fuel elements and guiding the gripping device. These steel hoops are the critical components of the refueling machine. Therefore the quality assurance of the material was articularly specified.On way of ensuring this guarantee of quality is to carry out tests involving the use of ultrasonic equipment as desired and applied here. The process is explained and its application with the results obtained is described.
    Notes: Die Grundüberholung und teilweise Erneuerung der in den Jahren 1965-1967 gebauten Brennelement-Wechselmaschine für die Reaktoranalage des NS OTTO HAHN erforderte u.a. die Auswechselung der zur Lastaufnahme und Greifersteuerung dienenden Hubbänder. Diese Stahlbänder sind die kritischen Bauteile der Brennelement-Wechselmaschine. Aus diesem Grunde wurde die Gütesicherung besonders spezifiert. Eine der Gütesicherung dienende zerstörungsfreie Prüfung ist die hier beschriebene und angewendete Impuls-Durchschallung in Tauchtechnik. Das Verfahren wird erklärt und die Durchführung mit dem erzielten Ergebnis beschrieben.
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    Materialwissenschaft und Werkstofftechnik 12 (1981), S. 315-324 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Behaviour of Hip - Joint Endoprostheses under quasi-static and dynamic LoadClinical experience with total-hip endoprostheses has shown that the following problems take priority: - Loosening of the socket (acetabular cup) and the femoral prosthesis - Fracture of the femoral prosthesis - Loosing due to deep infection.Accordingly aims the research at locating the biological and mechanical reasons for the failures as well as testing alternative solutions such as - methods of fixation - construction of protheses - new materials and finishing methods. This publication concerns areas of the mechanical side of the problem.The comparison between the original system of proximal femur and acetabulum and the implanted prosthetic system shows changes in the stiffness of the systems depending on the different types of implanted endoprostheses.The influence of the frequency of loading on the deformation of the system is investigated in a frequency range between quasi-static and dynamically changing loads.The movements between implanted cup and neighbouring pelvic bone during cyclic load is measured.The results of these examinations give clues concerning qualitative and quantitative repercussions from the different endoprosthetic systems under conditions optimal in view of true comparison, and possible or desirable alternative solutions of the problem in view of construction and material.
    Notes: Aufgrund bisher vorliegender klinischer Erfahrungen mit Hüftgelenks-Totalendoprothesen nehmen folgende Problemstellungen eine gewisse Priorität ein: - Pfannen- und Schaftlockerungen, - Schaftbrüche - Infektlockerungen.Dementsprechend konzentriert sich die Forschung auf die Ermittlung der biologischen und mechanischen Ursachen des Fehlverhaltens sowie auf die Erprobung alternativer Lösungen hinsichtlich - Fixationsmethodik - Konstruktion von Endoprothesen - Werkstoff und Fertigungsmethoden.Die vorliegende Arbeit bezieht sich auf Teile des mechanischen Komplexes dieser Problemstellung.Durch vergleichende Untersuchungen am Original- sowie am Implantatsystem „proximaler Femur/Hüftgelenkspfanne“ wird die Änderung der Steifigkeit infolge Implantation unterschiedlicher Typen von Endoprothesen ermittelt.Der Einfluß der Belastungsfrequenz auf die Deformationsverhältnisse in diesem System wird in einem Frequenzbereich überprüft, der sich von quasi-statischer bis zu dynamisch-wechselnder Belastung erstreckt.Die Relativbewegung zwischen implantierter Hüftgelenkspfanne und benachbartem knöchernen Bereich wird bei zyklischer Belastung erfaßt und messend verfolgt.Die Befunde geben punktuelle Hinweise hinsichtlich qualitativer und quantitativer Auswirkungen unterschiedlicher endoprothetischer Maßnahmen unter Bedingungen optimierter Vergleichbarkeit sowie hinsichtlich möglicher oder zweckmäßiger alternativer Lösungen im konstruktiven und stofflichen Bereich der anstehenden Fragestellungen.
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    Materialwissenschaft und Werkstofftechnik 12 (1981), S. A76 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Materialwissenschaft und Werkstofftechnik 12 (1981), S. 335-335 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Materialwissenschaft und Werkstofftechnik 12 (1981), S. 366-374 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Exact and Approximate Calculations of UD-LayersIt is shown that the quasi-elastic solution of layers nearly almost used in practical viscoelastic calculations is an excellent approach. The exact solution achieved with simple integral equations are compared with the quasi-elastic solution and the occuring deviations are described. The creep functions of layers are given the form of the uniaxial creep function of the isotropic viscoelastic material. This makes the creep behaviour of layers very clear and symplifies practical calculations. The given solutions are under no restriction with regard to the chosen form of the uni-axial creep function.
    Notes: Es wird gezeigt, daß die in der Praxis zur viskoelastischen Berechnung unidirektionaler Laminate verwendete quasielastische Lösung eine hervorragende Näherungslösung darstellt. Die exakten, mit Hilfe einfacher Integralbeziehungen gewonnenen, Lösungen werden mit der quasielastischen Lösung verglichen und es werden die zu erwartenden Abweichungen beschrieben. Die Kriechfunktionen der Laminate werden auf die Form der Kriechfunktion des viskoelastisch-isotropen Materials bei einachsiger Beanspruchung gebracht. Dadurch wird das Kriechverhalten der Laminate besonders deutlich und die praktische Rechnung wird vereinfacht. Die bereitgestellten Lösungen unterliegen keiner Beschränkungen hinsichtlich der funktionalen Form der einachsigen Kriechfunktion.
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    Materialwissenschaft und Werkstofftechnik 12 (1981), S. 402-407 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Pitting Corrosion at Copper Tubes of Tap Water Systems released by Soldering FluxThe pitting corrosion is the mostly observed reason for getting corrosion damage of copper tubes in tap water systems. In case of loss the reason for corrosion attack is ascribed to rests of cracked drawing compounds at the copper tube wall.The results from own examinations of copper tubes corroded in different tap waters show in case of loss the reason for corrosion damage as cracked soldering flux. This gets by the different described ways into the copper tube and becomes cracked by the soldering temperature. This way formed corrosion attacks often show breaches firstly far away from the soldered joint so that mostly other reasons of damage (cracked drawing compounds) are simulated.
    Notes: Die häufigste zum Versagen von Kupferrohren in der Trinkwasserinstallation führende Korrosionsart ist die Lochkorrosion. Als schadensauslösend werden dabei in der Literatur die beim Weichglühen der Rohre gecrackten Ziehmittelreste (Kohlenstoffbeläge der Rohrinnenwandungen) und Rückstände von chloridhaltigen Weichlöt-Fluß-mitteln angesehen.Eigene Untersuchungen von Schadensfällen an Kupferrohren der Trinkwasserinstallation zeigen, daß die Ursache, welche zum Versagen der Rohre führt, meistens nicht gecrackte Ziehmittelreste oder eingeflossenes Flußmittel, sondern gecrackte Flußmittel sind. Diese gelangen, auf unterschiedlichste Art und Weise, in das Rohrinnere und werden beim Einwirken der Löttemperatur gecrackt. Da ein so eingeleiteter Korrosionsangriff oftmals erst in relativ weiter Entfernung von der Lötstelle zum Durchbruch führt (Kondensatzone), werden meist andere Schadensursachen (z. B. gecrackte Ziehmittelreste) vorgetäuscht.
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    Materialwissenschaft und Werkstofftechnik 12 (1981), S. 438-439 
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    Keywords: Chemistry ; Polymer and Materials Science
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    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
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    Materialwissenschaft und Werkstofftechnik 13 (1982), S. 80-84 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Wiederkehrende Prüfungen am Reaktorkühlsystem bei LeichtwasserreaktorenUm eine dauerhafte Sicherheit der Komponenten des Reaktorkühlsystems zu gewährleisten, werden nach Inbetriebnahme eines Kernkraftwerks wiederkehrende Prüfungen durchgeführt.Dieser Beitrag behandelt die Komponenten des Reaktorkühlsystems in Bezug auf die gesetzlich vorgeschriebenen Auflagen, sicherheitstechnischen Aspekte und den Umfang der wiederkehrenden Prüfungen während des laufenden Reaktorbetriebs.Im einzelnen werden die Art und zeitliche Folge der Prüfungen, die Durchführungstechnik, ihre Ergebnisse und künftige Entwicklungstendenzen beschrieben.Funktionsprüfungen, die im Rahmen der wiederkehrenden Prüfungen anfallen, sind nicht Gegenstand dieses Beitrags.
    Notes: In order to guarantee constant safety of the components of the reactor cooling system, regular in-service inspections are carried out after commissioning of the nuclear power plant.This contribution is concerned with the components of the reactor cooling system, referring to the legal requirements, safety-related purposes and scope of the in-service inspections during the entire period of operation of a nuclear power plant.Reports are made with respect to type, examination intervals, examination technique, results and future development.The functional tests which are carried out within the scope of the inservice inspections are not part of this contribution.
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    Materialwissenschaft und Werkstofftechnik 13 (1982) 
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    Materialwissenschaft und Werkstofftechnik 13 (1982), S. A33 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Materialwissenschaft und Werkstofftechnik 13 (1982), S. A39 
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    Materialwissenschaft und Werkstofftechnik 13 (1982), S. 103-109 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Deep Rolling and Fatigue StrengthThe fatigue properties of specimens and components are largely increased by deep rolling. Depending on geometrical shape of components and material strength the compressive residual stresses and the increased surface hardness made by deep rolling have a different effect on the improvement of fatigue strength.The fatigue properties of smooth specimens and components with a sufficient toughness can be raised by increase of surface hardness, whereas in case of notched parts the influence of permanent compressive residual stresses is dominant.The application of deep rolling in case of crankshafts shows a clear superiority of mechanical strengthening procedure to thermal surface strengthening. If there are some reasons to improve the wear behaviour beside the fatigue strength it is commendable to combine thermal and mechanical surface strengthening.
    Notes: Die Schwingfestigkeitseigenschaften von Proben und Bauteilen können durch Festwalzen beträchtlich angehoben werden. Je nach Bauteilgeometrie und Werkstoffestigkeit wirken sich die durch den Festwalzprozeß eingebrachten Druckeigenspannungen 1. Art und die Randhärtesteigerung unterschiedlich auf die Erhöhung der Dauerfestigkeit aus. Während bei glatten Proben oder Bauteilen ausreichender Duktilität der Zuwachs an Schwingfestigkeit im wesentlichen auf die Zunahme der Randhärte zurückzuführen ist, beruht die Dauerfestigkeitserhöhung von Bauteilen mit Kerben auf das Vorhandensein stabiler Druckeigenspannungen.Die Anwendung des Festwalzprozesses bei Kurbelwellen zeigt die deutliche Überlegenheit des mechanischen Verfestigungsverfahrens gegenüber einem rein thermischen Randschichthärteverfahren. Sollte neben der Schwingfestigkeit auch das Verschleißverhalten verbessert werden, empfiehlt sich eine Kombination von thermischem und mechanischem Oberflächenverfestigungsverfahren.
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    Materialwissenschaft und Werkstofftechnik 13 (1982), S. A40 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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    Materialwissenschaft und Werkstofftechnik 13 (1982), S. 120-128 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: The Prediction of the Fatigue Strength with Regard to the Statistical Size Effect310 fatigue tests in the range for alternating stresses were performed with smooth and notched round bar specimens (Fig. 5 and Table 3) of different size. The 30 (20) tests of each series were fatigued at two stress levels with constant maximum root stress σ1 max and σ2 max. At each stress level, the probability of fracture (Eq. 11) had been determined. The test results are shown in Table 2. The evaluation of the test results was made on the basis of a two-parametric-Weibull-equation (Eq. 2) which can be derived by the theory of extreme value statistics. In the case of a non-uniform-stress-field (notched specimens), Eq. 2 is replaced by Eq. 6. The stress-integral (Eq. 6b) was numerically calculated for the different shapes of the specimens used. The value of the stress-integral A can also be obtained by Eq. 10 with an accuracy better than 11%. The Eqs. 7, 8 and 9 were used to calculate and predict test results. To show the error which arises by the application of the Eqs. 7, 8 and 9, the fatigue stress at 50% probability of fracture was calculated and compared with the experimental results. If the results of only one test series are used to calculate the fatigue strength of all the other series, the mean deviation is 5%, the maximum observed deviation is 14,1% (Table 5). If all the results are used to determine the constants of the two-parametric-Weibull-equation (Eq. 16), all the test results can be predicted with an accuracy better than 5,7%.In cases of homogeneous materials and mainly linear elastic stress-strain relationship, the two-parametric-Weibull-equation therefore is very well suited to describe the size effect in fatigue (Fig. 6).
    Notes: Es wurden 310 Zug-Druck-Dauerschwingversuche im reinen Wechsellastbereich an glatten und gekerbten Rundproben unterschiedlicher Größe (11 Probeserien) im Übergangsgebiet des Wöhlerfeldes durchgeführt. Die Auswertung der Versuche erfolgte unter Zugrundelegung der statistischen Fehlstellentheorie. Die beiden Konstanten des zweiparametrigen Weibullansatzes wurden für jede Probenserie bestimmt. Der Vergleich zwischen experimentellem und berechnetem Wert wurde jeweils für die Dauerfestigkeit mit einer Bruchwahrscheinlichkeit von 50% vorgenommen. Verwendet man zur Vorhersage die Ergebnisse nur einer Probeserie, so können die. Ergebnisse der anderen Probeserien mit einem mittleren Fehler von 5% (max. 14,1%) berechnet werden. Legt man alle experimentellen Ergebnisse der Vorhersage zugrunde, so verringert sich der mittlere Fehler auf 3,2% (max. 5,7%). Die statistische Fehlstellentheorie kann daher für querschnittshomogene Werkstoffe im Übergangsgebiet des Wöhlerfeldes mit sehr gutem Ergebnis zur Beschreibung des Größeneinflusses herangezogen werden.
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  • 84
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    Materialwissenschaft und Werkstofftechnik 13 (1982), S. 138-147 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Transformation-Toughened CeramicsA summary is given on the toughening of ceramics by utilizing the tetragonal-to-monoclinic phase transformation of ZrO2 particles dispersed in the ceramic matrix. Various parameters controlling this martensitic transformation (especially Ms) are discussed together with in situ-TEM observations. The possible toughening mechanisms that allow for additional energy dissipation at crack tips are stress-induced transformation and nucleation of microcracks. Further strengthening is achieved by introducing steady-state surface compressive stresses. The type and magnitude of toughening is controlled by the microstructural design parameters such as volume fraction, chemical composition, size and size distribution of ZrO2 particles which again determine the Ms temperature. The homogeneous dispersion of ZrO2 is the most important step in the technology of transformation-toughened ceramics. Experimental examples for the toughening effect are given for the ceramic matrices Al2O3, ZnO, spinel, mullite and Si3N4.
    Notes: Die Arbeit gibt einen Überblick über Forschungsergebnisse des Max-Planck-Instituts für Metallforschung auf dem Gebiet der Umwandlungsverstärkung keramischer Werkstoffe. Die kontrollierte Ausnutzung der tetragonal → monoklinen Phasenumwandlung dispergierter ZrO2-Teilchen ermöglicht eine Reihe unterschiedlicher Verstärkungsarten, die im wesentlichen von der Umwandlungstemperatur (Ms) bestimmt werden. Die Einflußparameter von Ms, z. B. Volumenanteil, chemische Zusammensetzung, Größe und Größenverteilung der ZrO2-Teilchen und die daraus abzuleitenden Maßnahmen für eine Gefügeentwicklung, werden besprochen. Die möglichen Mechanismen für eine zusätzliche Absorption von Bruchenergie, und damit für eine Erhöhung des Bruchwiderstands sind spannungsinduzierte Umwandlung und Bildung von Mikrorissen. Eine weitere Verstärkung kann durch Einbringen von Oberflächendruckspannungen erzielt werden. Der wichtigste technologische Schritt in der Herstellung umwandlungsverstärkter Keramiken ist eine homogene Dispersion der ZrO2-Teilchen. Eine Reihe experimenteller Beispiele für die Verstärkung von Al2O3, ZnO, Mullit, Spinell und Si3N4 mit Hilfe von ZrO2 wird diskutiert.
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  • 85
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    Materialwissenschaft und Werkstofftechnik 13 (1982) 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 86
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    Materialwissenschaft und Werkstofftechnik 13 (1982), S. 176-181 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Preparation and Properties of Layered Composites of GFK-SteelThe development of insulating joints of GFK and steel is described. The strength of the GFK and steel is described. The strength of the GFK and the adhesion between the GFK and steel is in this context of special interest. Results for the Young's Modulus, the ultimate and adhesion strength measured in bursting and bending tests are compared to those measured in tensile- and adhesion tests; the data agree well with each other. The correspondence between literature data of mechanical properties of the GFK and the measured values is satisfying.
    Notes: Es wird die Weiterentwicklung von Isolierstücken für erdverlegte Leitungen bis zur Abnahmereife durch den Technischen Überwachungsverein mit besonderer Berücksichtigung der Festigkeit des glasfaserverstärkten Kunststoffes und der Haftung des glasfaserverstärkten Kunststoffes am Trägermaterial angegeben. Ergebnisse für den E-Modul, die Zug- und Haftfestigkeit ermittelt aus Berst- und Biegeversuchen an den Isolierstücken werden verglichen mit Daten, die sich aus Zerreiß- und Haftfestigkeitsuntersuchungen ergeben. Die Übereinstimmung ist befriedigend; die Daten sind im Einklang mit Literaturergebnissen an vergleichbaren glasfaserverstärkten Kunststoffen.
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    Materialwissenschaft und Werkstofftechnik 13 (1982), S. 204-207 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Ermüdungsverhalten der Legierung Ti-6AI-4VEs wurden Wechselverformungsversuche (LCF) in Vakuum und Luft durchgeführt. Unter zyklischer Beanspruchung trat in der Ti-6Al-4V in Abhängigkeit von der Aushärtung, der Spannungsamplitude und der Mikrostruktur sowohl Verfestigung als auch Entfestigung auf. Die plastische Verformung der β-Phase verursachte im ungehärteten Zustand infolge der spannungsinduzierten martensitischen Umwandlung eine zyklische Verfestigung. Zyklische Entfestigung wurde gemessen, wenn die durch kohärente Ti3Al-Teilchen ausgehärtete α-Phase plastisch verformt wurde.Die globularen Gefüge zeigten eine stärkere zyklische Entfestigung als die lamellaren Gefüge. Dieses Verhalten konnte dadurch erklärt werden, daß die globularen Gefüge eine ausgeprägte Textur besaßen, während die lamellaren Gefüge texturlos waren.Im Bereich der Kurzzeitermüdung (LCF) wurde die Lebensdauer entscheidend vom Entfestigungsverhalten bestimmt. Die Gefüge mit starker zyklischer Entfestigung zeigten bei Berücksichtigung der unterschiedlichen Elastizitätsgrenzen (Normierung σa/σy) geringere Bruchlastspielzahlen als die Gefüge mit schwächerer zyklischer Entfestigung.
    Notes: Low-cycle-fatigue texts in vacuum and air were performed. Under cyclic loading the Ti-6Al-4V showed both cyclic hardening and cyclic softening depending on heat treatment, stress amplitude, and microstructure. Plastic deformation of the β-phase in the unaged condition due to stress induced martensitic transformation caused cyclic hardening. Cyclic softening was observed if the α-phase hardened by coherent Ti3Al particles was plastically deformed.Equiaxed microstructures exhibited a stronger cyclic softening than lamellar structures. This behavior could be explained by the pronounced texture of the equiaxed microstructures, whereas the lamellar structures were texture-free.The fatigue life was influenced by the cyclic softening process mainly in the low-cycle-fatigue regime. The fatigue life at normalized stress amplitude (σa/σy) was shorter for microstructures with strong cyclic softening as compared to microstructures with lower cyclic softening.
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  • 88
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    Materialwissenschaft und Werkstofftechnik 13 (1982), S. 274-285 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: The Formation of Surface Films and the Corrosion Resistance of the Silicon Containing Austenitic Steel X 2 CrNiSi 18 15 in Nitric AcidsThe oxide layers consist of two parts: the lower one is mainly Croxide, the upper one is SiO2. ESCA and AAS measurements were made in order to study the formation of the surface layer on the austenitic steel X2 CrNiSi 18 15 in nitric acids. A film, which is chromium oxide, is formed first. On top of this film a second film consisting of SiO2 grows. The elements nickel and manganese are not found in the formation of the oxide films. Immediately below the oxide layer the steel is enrichened with chromium and depleted of iron.In order to find the in some cases very small corrosion rates (5 · 10-5 mm · a-1) in a reproducible manner, the amounts of iron, chromium and nickel which had been dissolved were measured by means of the AAS method as a function of time.For stationary samples apparent activation energies of 65.2 kJ/Mol (azeotropic nitric acid) and 37.5 kJ/Mol (highly concentrated nitric acid), respectively, were found. These data confirm the assumption that the corrosion rate is determined by reactions at the phase boundaries.No appreciable influence of the flow velocity on the corrosion rate was detected.
    Notes: Mit Hilfe von ESCA- und AAS-Messungen wurde die Ausbildung der Deckschicht auf dem austenitischen Stahl X 2 CrNiSi 18 15 in Salpetersäuren untersucht. Es entsteht eine chromoxidreiche Deckschicht, über der sich eine SiO2-Schicht befindet. Nickel und Mangan sind am Aufbau der Oxidschichten nicht beteiligt. Unter der Oxidschicht wurde eine Chromanreicherung bzw. Eisenverarmung im Stahl nachgewiesen.Um die teilweise sehr geringen (bis 5 · 10-5 mm · a-1) Abtragungsraten reproduzierbar erfassen zu können, wurde in Lösung gegangenes Eisen, Chrom und Nickel in Abhängigkeit von der Beanspruchungsdauer mittels AAS bestimmt.Für ruhende Werkstoffproben ergaben sich scheinbare Aktivierungsenergien von 65,2 kJ/Mol (azeotrope Salpetersäure) bzw. 37,5 kJ/Mol (hochkonzentrierte Salpetersäure); diese Werte bestätigen die Annahme einer geschwindigkeitsbestimmenden Phasengrenzreaktion. Ein nennenswerter Einfluß der Fließgeschwindigkeit auf die Korrosion war nicht nachweisbar.
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    Materialwissenschaft und Werkstofftechnik 13 (1982), S. A84 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Materialwissenschaft und Werkstofftechnik 13 (1982), S. 355-360 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: The Fatigue Behavior of SiSiCFor design purposes the engineering property datas especially the fatigue behavior of silicon carbide (SiSiC) were determined. Using linear elastic fracture mechanics the datas for slip casted and extruded SiSiC-samples were measured at room temperature. The correlation between stress, probability of failure, and time is shown in SPT-diagrams.
    Notes: Auf der Basis der Theorie der linear-elastischen Bruchmechanik wird die für die Konstruktion benötigte, zeitabhängige mechanische Festigkeit (Ermüdung) von stranggepreßtem und schlickergegossenem Siliziumcarbid (SiSiC) bei Raumtemperatur bestimmt.Der Zusammenhang zwischen Belastungshöhe, Ausfallswahrscheinlichkeit und Zeit wird in Form von SPT-Diagrammen dargestellt.
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  • 91
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
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    Materialwissenschaft und Werkstofftechnik 13 (1982), S. 385-388 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Fatigue crack growthIn the following paragraphs the fracture mechanics approach to fatigue crack growth will be described. A relationship between the „Wöhler-type“ concept and the fracture mechanics concept will be established and some aspects of interest for practical applications will be presented.
    Notes: Im folgenden soll das Ermüdungsrißwachstum in der bruchmechanischen Darstellungsweise erläutert werden, wobei eine Beziehung zwischen der Wöhler-Kurve (klassischer Ermüdungsversuch) und dem bruchmechanischen Ermüdungsversuch hergestellt wird, sowie einige für die Ingenieurpraxis interessante Aspekte erläutert werden.
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    Materialwissenschaft und Werkstofftechnik 13 (1982), S. A102 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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    Materialwissenschaft und Werkstofftechnik 13 (1982), S. 423-429 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Stress Fields in Concentrated Contacts - Influence of Normal Load, Tangential Load and Internal StressesThe stresses in the half space of a Hertzian Contact (coordinate stresses and equivalent stresses) are shown in dependence of geometry and Hertzian contact stress. The equivalent stresses were calculated with the Huber, von Mises, Henky criterion.The superposition of combined normal and tangential load with residual stresses in the material was calculated for point and line contact. The course of the maximum of the equivalent stress in dependence of the residual stresses with the parameter friction coefficient is shown.
    Notes: Der Spannungszustand (Koordinatenspannungen, Vergleichspannung) im Halbraum des Hertzschen Kontaktbereiches wird in Abhängigkeit von der Geometrie und der Hertzschen Pressung dargestellt. Die Vergleichsspannung wurde mit der Gestaltänderungsenergiehypothese ermittelt.Die Überlagerung von Normalkraft und Schubkraftbeanspruchung mit im Werkstoff vorhandenen Eigenspannungen wurde für die beiden Fälle Kreis- und Rechteckkontakt durchgeführt. Der Verlauf des Vergleichsspannungsmaximums in Abhängigkeit von den Eigenspannungen mit dem Parameter Reibwert wird dargestellt. Das Ergebnis dieser Berechnungen kann zur Klärung von Oberflächenermüdungsschäden an Wälzlagern, Zahnrädern, Nocken-Stößel-Paarung usw. beitragen.
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    Materialwissenschaft und Werkstofftechnik 13 (1982), S. 434-439 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Strain Measurements of Great Tensile-Test Pieces of Reactor Steel by Holographic InterferometryWith a tensile-test rod of 100 mm diameter the application of holographic interferometry to not vibration isolated mounts has been demonstrated using advanced holographic techniques. The three spatial components of the deformation of an extended part of the rod surface have been calculated and analysed according to a specific deformation behaviour. Especially, it appeared that the strain in the direction of stress showed a discontinuity where later on the rod raptured due to a much greater load.
    Notes: Mit Hilfe fortgeschrittener holographischer Techniken wurde am Beispiel einer 100 mm ∅ Rundzugprobe der Einsatz der holographischen Interferometrie an nicht schwingungsisolierten Aufbauten demonstriert. Die in einem größeren Bereich der Probenoberfläche gemessenen Verschiebungen in den drei Raumrichtungen wurden quantitativ bestimmt und bezüglich spezifischer Deformationen interpretiert. Dabei zeigte sich insbesondere, daß die Dehnung in Zugrichtung einen deutlichen Sprung im Bereich des später, bei sehr viel größeren Belastungen aufgetretenen Bruches aufwies.
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    Materialwissenschaft und Werkstofftechnik 13 (1982), S. A105 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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    Materialwissenschaft und Werkstofftechnik 14 (1983), S. A2 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Materialwissenschaft und Werkstofftechnik 13 (1982), S. 313-316 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Der Eigenspannungsmeßtechnik wurden in den letzten Jahrzehnten viele Arbeiten gewidmet mit einem Trend der Vorliebe zur röntgenographischen Meßmethode und deren Anwendung. 1979 wurde in einem Symposium der Arbeitsgemeinschaft für Wärmebehandlung und Werkstofftechnik e. V., des Deutschen Verbandes für Materialprüfung e. V. und der Deutschen Gesellschaft für Metallkunde e. V. der Stand der Wissenschaft zum Thema „Eigenspannungen“, Entstehung, Berechnung, Messung und Bewertung, in Deutschland abgehandelt [1]. Vorgetragen wurden neben der reinen Theorie einige praxisbezogene Studien über Bauteile, bei denen der Verlauf der Eigenspannungen ermittelt und studiert wurde, was in jedem Fall die Zerstörung des Bauteils zur Folge hat.Anwendungen der Eigenspannungsmessung zur Fertigungskontrolle sind in der Literatur selten.Dennoch, neben diesen zum Teil uralten Betrachtungen gibt es in der Praxis Fälle, bei denen der prinzipielle Spannungsverlauf im Bauteil bekannt ist und zur Fertigungskontrolle eine praktisch zerstörungsfreie Eigenspannungsmessung der Oberfläche notwendig ist. Diesen Messungen steht ein grundsätzliches Problem entgegen: Die zu vermessende Oberfläche muß relevant sein für den wahren Spannungszustand des Bauteils. Aber die Oberfläche stellt eine singuläre Zone dar, deren Spannungszustand durch alle oberflächenaktiven Vorgänge verfälscht wird; je zerstörungsfreier das Meßverfahren, umso sensibler ist die Messung gegen die Meßstellen-(Oberflächen-)Singularität. Um nur einige Beispiele von Oberflächensingularitäten bei Stahl zu erwähnen, sei erinnert an Entkohlung, Verfestigung durch Grobzerspanung, Verhärtungen oder Anlasseffekte durch Schleifen usw., wobei der Gradient der jeweiligen Beeinflussung von vielen Parametern abhängt und im Regelfall unbekannt bleibt.In dieser Arbeit soll berichtet werden, wie und mit welchem Aufwand für einen speziellen Anwendungsfall das Problem der Meßstellenrelevanz gelöst wurde.
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    Materialwissenschaft und Werkstofftechnik 13 (1982), S. 361-369 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Surface-Specific Analytical Methods (AES/SAM, ESCA/XPS, SIMS) for the Investigation of Wear-Resistant CoatingsThis paper gives a brief review of the analytical possibilities by combining some analytical methods of surface analysis for the study of the uppermost layers of atoms of technical interesting materials (metals).The physical fundamentals, limitations and differences of the methods: Auger electron spectroscopy, X-ray photoelectron spectroscopy and secondary ion mass spectrometry are discussed - especially in comparison with the well-known electron microprobe analysis. Finally the application of surface analysis for the characterization of the chemical surface composition of wear-resistant coatings before and after tribological operation is demonstrated.
    Notes: Es werden die analytischen Möglichkeiten aufgezeigt, die sich ergeben, wenn man mehrere oberflächenspezifische Analysenverfahren, hier speziell AES/SAM, ESCA(XPS) und SIMS, zur Charakterisierung von Werkstoffoberflächen kombiniert einsetzen kann.Die Grundprinzipien werden besprochen, die Vor- und Nachteile der Methoden miteinander verglichen - insbesondere in bezug auf die klassische Röntgen-Mikroanalyse - und schließlich anhand von Beispielen aus dem tribologischen Bereich erläutert.
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Wear Resistance of Liner Material for Extruding Non-ferrous AlloysExtruding Al and its alloys Cu, brass, Cu-Ni alloys and Ni on account of variable working conditions (as temperature) different liner materials are used.Processing Al martensitic hot work steels are successful in application. Working up copper high temperature resistant and austenitic steels are additional in use.The high-temperature strength of these materials is well-known.Based on the investigation of the high-temperature wear this paper presents several new considerations.
    Notes: Anforderungen an die Innenbüchsenwerkstoffe für das Strangpressen von Aluminiumlegierungen, Reinkupfer, Messing, Kupfer-Nickellegierungen und Reinnickel; Kriterien für die Stahlauswahl. Verschleißverhalten in Abhängigkeit von Werkstoffpaarung und Beanspruchungstemperatur; Warmfestigkeit von martensitischen Warmarbeitsstählen und hochwarmfesten Austeniten.
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