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  • Triticum aestivum  (853)
  • kinetics  (727)
  • Adaptation
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  • GPS
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  • Springer Berlin Heidelberg  (32)
  • 1
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    Springer Nature | Springer
    Publikationsdatum: 2024-03-29
    Beschreibung: The world is currently undergoing an historic energy transition, driven by increasingly stringent decarbonisation policies and rapid advances in low-carbon technologies. The large-scale shift to low-carbon energy is disrupting the global energy system, impacting whole economies, and changing the political dynamics within and between countries. This open access book, written by leading energy scholars, examines the economic and geopolitical implications of the global energy transition, from both regional and thematic perspectives. The first part of the book addresses the geopolitical implications in the world’s main energy-producing and energy-consuming regions, while the second presents in-depth case studies on selected issues, ranging from the geopolitics of renewable energy, to the mineral foundations of the global energy transformation, to governance issues in connection with the changing global energy order. Given its scope, the book will appeal to researchers in energy, climate change and international relations, as well as to professionals working in the energy industry.
    Schlagwort(e): International Relations ; Energy Policy, Economics and Management ; Natural Resource and Energy Economics ; Climate Change/Climate Change Impacts ; Environmental Economics ; Earth System Sciences ; Energy transition geopolitics ; International decarbonisation policies ; Global warming ; Global energy system ; Geopolitics of the global energy transition ; Economic and political impacts of low-carbon technologies ; Power generation mix ; Geopolitical implications of global warming ; Governance of the global energy order ; Open Access ; International relations ; Energy technology & engineering ; Energy industries & utilities ; Environmental economics ; Climate change ; thema EDItEUR::J Society and Social Sciences::JP Politics and government::JPS International relations ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TH Energy technology and engineering ; thema EDItEUR::K Economics, Finance, Business and Management::KC Economics::KCV Economics of specific sectors::KCVG Environmental economics ; thema EDItEUR::R Earth Sciences, Geography, Environment, Planning::RN The environment::RNP Pollution and threats to the environment::RNPG Climate change
    Sprache: Englisch
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  • 2
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    Springer Nature | Springer
    Publikationsdatum: 2022-03-16
    Beschreibung: This Open Access book’s main focus is agriculture and natural resource management, disaster risk reduction, and human resource development in the countries of East and Southeast Asia and Japan. Asia is one of the regions which is the most vulnerable to the impacts of climate change. More than sixty percent of the world’s people live in the region, making it the growth center of the world. Asia is vast and includes various countries and regions, this book is focused on East and Southeast Asia including Japan. It is essential to share the knowledge and experiences for adapting climate change among these areas. In order to tackle these issues, the book aims to: Promote inter-local lessons learnt sharing climate change adaptations; "agriculture and natural resource management" and "disaster risk reduction and human resource development" Provides insights into new adaptation measures and research approaches that can consider the regional nature of Southeast Asia Share practical adaptation options permeated by society in each country/region This book will be of interest to researchers and students examining climate change impacts in East and Southeast Asia.
    Schlagwort(e): Climate change ; Climate-Change Adaptation ; Disaster risk reduction ; East and Southeast Asia ; Agriculture ; bic Book Industry Communication::R Earth sciences, geography, environment, planning::RB Earth sciences::RBP Meteorology & climatology ; bic Book Industry Communication::R Earth sciences, geography, environment, planning::RN The environment::RNR Natural disasters ; bic Book Industry Communication::R Earth sciences, geography, environment, planning::RN The environment::RNF Environmental management ; bic Book Industry Communication::R Earth sciences, geography, environment, planning::RN The environment::RNU Sustainability ; bic Book Industry Communication::T Technology, engineering, agriculture::TV Agriculture & farming::TVB Agricultural science ; bic Book Industry Communication::J Society & social sciences::JP Politics & government::JPQ Central government::JPQB Central government policies
    Sprache: Englisch
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  • 3
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    Springer Nature | Springer
    Publikationsdatum: 2021-02-10
    Beschreibung: This open access textbook provides a concise introduction to economic approaches and mathematical methods for the study of water allocation and distribution problems. Written in an accessible and straightforward style, it discusses and analyzes central issues in integrated water resource management, water tariffs, water markets, and transboundary water management. By illustrating the interplay between the hydrological cycle and the rules and institutions that govern today’s water allocation policies, the authors develop a modern perspective on water management. Moreover, the book presents an in-depth assessment of the political and ethical dimensions of water management and its institutional embeddedness, by discussing distribution issues and issues of the enforceability of human rights in managing water resources. Given its scope, the book will appeal to advanced undergraduate and graduate students of economics and engineering, as well as practitioners in the water sector, seeking a deeper understanding of economic approaches to the study of water management.
    Schlagwort(e): Natural Resource and Energy Economics ; Water Policy/Water Governance/Water Management ; Waste Water Technology / Water Pollution Control / Water Management / Aquatic Pollution ; Environmental Economics ; Water ; Pollution ; Water economics ; Sustainable water management ; Water engineering ; Hydro-economic models ; Affordable water tariffs ; Eco-hydrology ; Human rights to water ; Water recycling ; Open Access book ; Climate change ; Environmental economics ; Environmental management, ; Water supply & treatment ; Energy industries & utilities ; bic Book Industry Communication::K Economics, finance, business & management::KC Economics::KCN Environmental economics ; bic Book Industry Communication::R Earth sciences, geography, environment, planning::RN The environment::RNF Environmental management ; bic Book Industry Communication::T Technology, engineering, agriculture::TQ Environmental science, engineering & technology::TQS Sanitary & municipal engineering::TQSW Water supply & treatment
    Sprache: Englisch
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  • 4
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    Springer Nature | Springer
    Publikationsdatum: 2021-02-10
    Beschreibung: This open access book provides worldwide examples demonstrating the importance of the interplay between demography and disasters in regions and spatially. It marks an advance in practical and theoretical insights for understanding the role of demography in planning for and mitigating impacts from disasters in developed nations. Both slow onset (like the of loss polar ice from climate change) and sudden disasters (such as cyclones and man-made disasters) have the capacity to fundamentally change the profiles of populations at local and regional levels. Impacts vary according to the type, rapidity and magnitude of the disaster, but also according to the pre-existing population profile and its relationships to the economy and society. In all cases, the key to understanding impacts and avoiding them in the future is to understand the relationships between disasters and population change. In most chapters in this book we compare and contrast studies from at least two cases and summarize their practical and theoretical lessons.
    Schlagwort(e): Demography ; Human Geography ; Climate Change ; Statistics for Social Sciences, Humanities, Law ; Population Economics ; Natural Hazards ; Population and Demography ; Environmental Sciences ; Statistics in Social Sciences, Humanities, Law, Education, Behavorial Sciences, Public Policy ; Impact of disasters ; Demograhic change ; Regional effects of disasters ; Population dynamics ; Environmental change ; Open access ; Population & demography ; Human geography ; Climate change ; Social research & statistics ; Political economy ; Natural disasters ; bic Book Industry Communication::J Society & social sciences::JH Sociology & anthropology::JHB Sociology::JHBD Population & demography ; bic Book Industry Communication::R Earth sciences, geography, environment, planning::RG Geography::RGC Human geography ; bic Book Industry Communication::R Earth sciences, geography, environment, planning::RN The environment::RNP Pollution & threats to the environment::RNPG Climate change ; bic Book Industry Communication::J Society & social sciences::JH Sociology & anthropology::JHB Sociology::JHBC Social research & statistics ; bic Book Industry Communication::K Economics, finance, business & management::KC Economics::KCP Political economy ; bic Book Industry Communication::R Earth sciences, geography, environment, planning::RN The environment::RNR Natural disasters
    Sprache: Englisch
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  • 5
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    Springer Nature | Springer
    Publikationsdatum: 2021-02-10
    Beschreibung: This open access book is a result of the Dalhousie-led research project Safe Navigation and Environment Protection, supported by a grant from the Ocean Frontier Institute’s the Canada First Research Excellent Fund (CFREF). The book focuses on Arctic shipping and investigates how ocean change and anthropogenic impacts affect our understanding of risk, policy, management and regulation for safe navigation, environment protection, conflict management between ocean uses, and protection of Indigenous peoples’ interests. A rapidly changing Arctic as a result of climate change and ice loss is rendering the North more accessible, providing new opportunities while producing impacts on the Arctic. The book explores ideas for enhanced governance of Arctic shipping through risk-based planning, marine spatial planning and scaling up shipping standards for safety, environment protection and public health.
    Schlagwort(e): Polar Geography ; Climate Change/Climate Change Impacts ; Water Policy/Water Governance/Water Management ; Environmental Management ; Freshwater & Marine Ecology ; Physical Geography ; Earth System Sciences ; Water ; Freshwater and Marine Ecology ; Arctic cruise shipping ; Arctic fisher safety ; Climate change impacts in the Arctic region ; Governance of the Arctic and Northwest Atlantic ; Marine spatial planning ; Northwest Atlantic and Canadian Eastern Arctic Gateway ; Safe navigation and environment protection ; Sea ice in the Arctic ; Search and Rescue (SAR) ; Open Access ; Physical geography & topography ; Climate change ; Environmental management, ; Ecological science, the Biosphere ; Hydrobiology ; bic Book Industry Communication::R Earth sciences, geography, environment, planning::RG Geography::RGB Physical geography & topography ; bic Book Industry Communication::R Earth sciences, geography, environment, planning::RN The environment::RNP Pollution & threats to the environment::RNPG Climate change ; bic Book Industry Communication::R Earth sciences, geography, environment, planning::RN The environment::RNF Environmental management ; bic Book Industry Communication::P Mathematics & science::PS Biology, life sciences::PSA Life sciences: general issues::PSAF Ecological science, the Biosphere
    Sprache: Englisch
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  • 6
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    Springer Nature | Springer
    Publikationsdatum: 2021-02-10
    Beschreibung: This open access book presents the most current research results and knowledge from five multidisciplinary themes: Vulnerability of Arctic Environments, Vulnerability of Arctic Societies, Local and Traditional Knowledge, Building Long-term Human Capacity, New Markets for the Arctic, including tourism and safety. The themes are those discussed at the first ever UArctic Congress Science Section, St. Petersburg, Russia, September 2016. The book looks at the Arctic from a holistic perspective; how the environment (both marine and terrestrial) and communities can adapt and manage the changes due to climate change. The chapters provide examples of the state-of-the-art research, bringing together both scientific and local knowledge to form a comprehensive and cohesive volume. Except where otherwise noted, this book is licensed under a Creative Commons Attribution 4.0 International License. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/. ; Provides a multidisciplinary view on topical Arctic issues and research Discusses capacity building on different scales Shares knowledge about the northern systems across the Arctic
    Schlagwort(e): Environmental Management ; Climate Change/Climate Change Impacts ; Quality of Life Research ; Environment Studies ; Political Economy/Economic Systems ; Earth System Sciences ; Environmental Sciences ; Political Economy and Economic Systems ; Climate change and the Arctic ; Human capacity and knowledge building ; Vulnerability of Arctic environments ; Marine and terrestrial polar landscapes ; Local, indigenous knowledge and tourism ; Open Access ; Environmental management, ; Climate change ; Social & ethical issues ; Society & Social Sciences ; The environment ; Political economy ; bic Book Industry Communication::R Earth sciences, geography, environment, planning::RN The environment::RNF Environmental management ; bic Book Industry Communication::R Earth sciences, geography, environment, planning::RN The environment::RNP Pollution & threats to the environment::RNPG Climate change ; bic Book Industry Communication::J Society & social sciences::JF Society & culture: general::JFF Social issues & processes ; bic Book Industry Communication::J Society & social sciences ; bic Book Industry Communication::K Economics, finance, business & management::KC Economics::KCP Political economy
    Sprache: Englisch
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  • 7
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    Springer Nature | Springer
    Publikationsdatum: 2021-02-10
    Beschreibung: This open access book discusses the impact of human-induced global climate change on the regional climate and monsoons of the Indian subcontinent, adjoining Indian Ocean and the Himalayas. It documents the regional climate change projections based on the climate models used in the IPCC Fifth Assessment Report (AR5) and climate change modeling studies using the IITM Earth System Model (ESM) and CORDEX South Asia datasets. The IPCC assessment reports, published every 6–7 years, constitute important reference materials for major policy decisions on climate change, adaptation, and mitigation. While the IPCC assessment reports largely provide a global perspective on climate change, the focus on regional climate change aspects is considerably limited. The effects of climate change over the Indian subcontinent involve complex physical processes on different space and time scales, especially given that the mean climate of this region is generally shaped by the Indian monsoon and the unique high-elevation geographical features such as the Himalayas, the Western Ghats, the Tibetan Plateau and the adjoining Indian Ocean, Arabian Sea, and Bay of Bengal. This book also presents policy relevant information based on robust scientific analysis and assessments of the observed and projected future climate change over the Indian region.
    Schlagwort(e): Earth System Sciences ; Climate Change/Climate Change Impacts ; Climate Change Management and Policy ; Climatology ; Climate Change ; Environmental Sciences ; Indian Subcontinent ; Indian Ocean ; Himalayas ; Monsoon ; Temperature Changes ; Atmospheric Trace Gases ; Droughts and Floods ; Himalayan Cryosphere ; Open Access ; Earth sciences ; Environmental science, engineering & technology ; Climate change ; The environment ; Meteorology & climatology ; bic Book Industry Communication::R Earth sciences, geography, environment, planning::RB Earth sciences ; bic Book Industry Communication::R Earth sciences, geography, environment, planning::RN The environment::RNP Pollution & threats to the environment::RNPG Climate change ; bic Book Industry Communication::R Earth sciences, geography, environment, planning::RN The environment::RND Environmental policy & protocols ; bic Book Industry Communication::R Earth sciences, geography, environment, planning::RB Earth sciences::RBP Meteorology & climatology
    Sprache: Englisch
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  • 8
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    Springer Berlin Heidelberg
    Publikationsdatum: 2020-10-14
    Beschreibung: We present an up-to-date high resolution picture of the ongoing crustal deformation field of Iberian region, based on an extensive combination of permanent and non-permanent GPS observations carried out since 1999. We detected appreciable deformation along the NW and SE margins of the Iberian Peninsula and along the Gibraltar arc, while on the inner parts of the peninsula, the crustal deformation occurs locally at rate 〈 15 nanostrain/year.
    Beschreibung: Published
    Beschreibung: 369-372
    Beschreibung: 1T. Geodinamica e interno della Terra
    Beschreibung: restricted
    Schlagwort(e): GPS ; Strain-rate ; Plate motion ; Iberia ; 04. Solid Earth::04.03. Geodesy::04.03.01. Crustal deformations
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: book chapter
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  • 9
    Publikationsdatum: 2017-04-04
    Beschreibung: Ground deformation occurring on the southern flank of Mt Etna volcano during the JulyAugust 2001 eruption was monitored by GPS measurements along an EW profile crossing the fissure system. This profile was measured eight times during the eruption, using the 'stop and go' semi-kinematic technique. Horizontal and vertical displacements between GPS surveys are reported for each station. The most significant event is a deformation episode occurring during the first week of the eruption, between 2527 July. Displacements were measured on benchmarks close to the eruptive fissure and the tensile 1989 fracture. Data inversions for measured displacements were performed using the Okada model. The model shows the narrowing of the 2001 dyke accompanied by a dextral dislocation along an east-dipping fault, parallel to the 1989 fracture.
    Beschreibung: Published
    Beschreibung: 336-341
    Beschreibung: partially_open
    Schlagwort(e): GPS ; Ground deformation ; Modelling ; Volcano monitoring ; 04. Solid Earth::04.03. Geodesy::04.03.07. Satellite geodesy ; 04. Solid Earth::04.03. Geodesy::04.03.09. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
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  • 10
    Publikationsdatum: 2019-12-05
    Beschreibung: The analysis of Global Positioning System (GPS) coordinates time series is a valuable tool in quantifying crustal deformations. The longer continuous GPS time series allow estimation of nonlinear signatures. As a matter of fact, besides the linear and periodic behaviors, other relevant signals are present in such time series as the so-called transient deformations. They can be related to, e.g., slow slip events, which play a crucial role in studying fault mechanisms. To give reliable estimates of these signals, an appropriate and rigorous approach for defining the deterministic and the stochastic models of the data is needed. We prove that the theory of the second order stationary random process (SOSRP) can be used to describe the stochastic behavior of the daily GPS time series. In particular, the second order stationarity condition has to be verified for the daily GPS coordinate time series to be described as a SOSRP. This method has been already used for modeling the gravity field of the earth and in predicting/filtering problems, and this work shows that it can also be useful for characterizing the colored noise in the GPS time series.
    Beschreibung: Published
    Beschreibung: id 86
    Beschreibung: 2T. Deformazione crostale attiva
    Beschreibung: JCR Journal
    Schlagwort(e): GPS ; time series ; Stationary stochastic process ; Auto-covariance function ; Power law spectrum ; 04.03. Geodesy
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
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  • 11
    Publikationsdatum: 2018-03-16
    Beschreibung: In this paper, we analyze the tropospheric delay observed on some ground-based CGPS stations in a dense small regional network and its time evolution during extreme weather conditions. In particular, we studied two severe weather events occurring in the Campanian Region (Italy) on October 12, 2012 and December 2, 2014, reaching 42 and 28 mm rainfall during about 1 h at Naples (MAFE) and Gragnano (GRAG) stations respectively. The main concern of this study is the retrieval of the precipitable water (PW) from co-located GPS and meteorological stations. We investigate the correlation between PW and rain amount at ground level. We analyse phase residuals for each visible GPS satellite using sky plots of the phase residuals along the GPS satellites tracks, showing that the two phenomena are shown in the phase residual plots. Moreover, we compare PWdata retrieved from observed meteorological data and from models (GPT2 and ECMWF), evidencing that there is a need for co-located CGPS and weather stations to improve the assessment of water content in the troposphere.
    Beschreibung: Published
    Beschreibung: 293-302
    Beschreibung: 4A. Oceanografia e clima
    Beschreibung: 7A. Geofisica per il monitoraggio ambientale e geologia medica
    Schlagwort(e): Precipitable water ; Tropospheric delay ; GPT2 ; ECMWF ; GPS ; 01.01. Atmosphere
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: book chapter
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  • 12
    Publikationsdatum: 2022-05-25
    Beschreibung: © The Author(s), 2012. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Plant and Soil 356 (2012): 405-417, doi:10.1007/s11104-012-1130-x.
    Beschreibung: Soil warming from global climate change could increase decomposition of fine woody debris (FWD), but debris size and quality may mitigate this effect. The goal of this study was to investigate the effect of soil warming on decomposition of fine woody debris of differing size and quality. We placed FWD of two size classes (2 × 20 cm and 4 × 40 cm) and four species (Acer saccharum, Betula lenta, Quercus rubra and Tsuga canadensis) in a soil warming and ambient area at Harvard Forest in central Massachusetts. We collected the debris from each area over two years and measured mass loss and lignin concentration. Warming increased mass loss for all species and size classes (by as much as 30%), but larger debris and debris with higher initial lignin content decomposed slower than smaller debris and debris with lower initial lignin content. Lignin degradation did not follow the same trends as mass loss. Lignin loss from the most lignin-rich species, T. canadensis, was the highest despite the fact that it lost mass the slowest. Our results suggest that soil warming will increase decomposition of FWD in temperate forests. It is imperative that future models and policy efforts account for this potential shift in the carbon storage pool.
    Schlagwort(e): Woody debris ; Lignin ; Decomposition ; Soil warming ; Climate change
    Repository-Name: Woods Hole Open Access Server
    Materialart: Article
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  • 13
    Publikationsdatum: 2022-05-25
    Beschreibung: © The Author(s), 2017. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Carbon Balance and Management 12 (2017): 10, doi:10.1186/s13021-017-0077-x.
    Beschreibung: Determining national carbon stocks is essential in the framework of ongoing climate change mitigation actions. Presently, assessment of carbon stocks in the context of greenhouse gas (GHG)-reporting on a nation-by-nation basis focuses on the terrestrial realm, i.e., carbon held in living plant biomass and soils, and on potential changes in these stocks in response to anthropogenic activities. However, while the ocean and underlying sediments store substantial quantities of carbon, this pool is presently not considered in the context of national inventories. The ongoing disturbances to both terrestrial and marine ecosystems as a consequence of food production, pollution, climate change and other factors, as well as alteration of linkages and C-exchange between continental and oceanic realms, highlight the need for a better understanding of the quantity and vulnerability of carbon stocks in both systems. We present a preliminary comparison of the stocks of organic carbon held in continental margin sediments within the Exclusive Economic Zone of maritime nations with those in their soils. Our study focuses on Namibia, where there is a wealth of marine sediment data, and draws comparisons with sediment data from two other countries with different characteristics, which are Pakistan and the United Kingdom. Results indicate that marine sediment carbon stocks in maritime nations can be similar in magnitude to those of soils. Therefore, if human activities in these areas are managed, carbon stocks in the oceanic realm—particularly over continental margins—could be considered as part of national GHG inventories. This study shows that marine sediment organic carbon stocks can be equal in size or exceed terrestrial carbon stocks of maritime nations. This provides motivation both for improved assessment of sedimentary carbon inventories and for reevaluation of the way that carbon stocks are assessed and valued. The latter carries potential implications for the management of human activities on coastal environments and for their GHG inventories.
    Beschreibung: We acknowledge research support from ETH Zurich and the Swiss National Science Foundation.
    Schlagwort(e): Carbon stocks ; Sediments ; Oceans ; Climate change ; Exclusive Economic Zone ; Carbon inventory
    Repository-Name: Woods Hole Open Access Server
    Materialart: Article
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  • 14
    Publikationsdatum: 2017-04-04
    Beschreibung: The study and management of the groundwater resources of a large, deep, coastal, karstic aquifer represent a very complex hydrogeological problem. Here, this problem is successfully approached by using an equivalent porous continuous medium (EPCM) to represent a karstic Apulian aquifer (southern Italy). This aquifer, which is located on a peninsula and extends to hundreds of metres depth, is the sole local source of high-quality water resources. These resources are at risk due to overexploitation, climate change and seawater intrusion. The model was based on MODFLOW and SEAWAT codes. Piezometric and salinity variations from 1930 to 2060 were simulated under three past scenarios (up to 1999) and three future scenarios that consider climate change, different types of discharge, and changes in sea level and salinity. The model was validated using surveyed piezometric and salinity data. An evident piezometric drop was confirmed for the past period (until 1999); a similar dramatic drop appears to be likely in the future. The lateral intrusion and upconing effects of seawater intrusion were non-negligible in the past and will be considerable in the future. All phenomena considered here, including sea level and sea salinity, showed non-negligible effects on coastal groundwater.
    Beschreibung: Published
    Beschreibung: 115-128
    Beschreibung: 5A. Energia e georisorse
    Beschreibung: JCR Journal
    Beschreibung: embargoed_20160501
    Schlagwort(e): Karstic coastal aquifer ; Numerical modelling ; Seawater intrusion ; Climate change ; 03. Hydrosphere::03.02. Hydrology::03.02.06. Water resources
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
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  • 15
    Publikationsdatum: 2023-12-16
    Beschreibung: For more than 20 years, precise point positioning (PPP) has been a well-established technique for carrier phase-based navigation. Traditionally, it relies on precise orbit and clock products to achieve accuracies in the order of centimeters. With the modernization of legacy GNSS constellations and the introduction of new systems such as Galileo, a continued reduction in the signal-in-space range error (SISRE) can be observed. Supported by this fact, we analyze the feasibility and performance of PPP with broadcast ephemerides and observations of Galileo and GPS. Two different functional models for compensation of SISREs are assessed: process noise in the ambiguity states and the explicit estimation of a SISRE state for each channel. Tests performed with permanent reference stations show that the position can be estimated in kinematic conditions with an average three-dimensional (3D) root mean square (RMS) error of 29 cm for Galileo and 63 cm for GPS. Dual-constellation solutions can further improve the accuracy to 25 cm. Compared to standard algorithms without SISRE compensation, the proposed PPP approaches offer a 40% performance improvement for Galileo and 70% for GPS when working with broadcast ephemerides. An additional test with observations taken on a boat ride yielded 3D RMS accuracy of 39 cm for Galileo, 41 cm for GPS, and 27 cm for dual-constellation processing compared to a real-time kinematic reference solution. Compared to the use of process noise in the phase ambiguity estimation, the explicit estimation of SISRE states yields a slightly improved robustness and accuracy at the expense of increased algorithmic complexity. Overall, the test results demonstrate that the application of broadcast ephemerides in a PPP model is feasible with modern GNSS constellations and able to reach accuracies in the order of few decimeters when using proper SISRE compensation techniques.
    Beschreibung: Deutsches Zentrum für Luft- und Raumfahrt e. V. (DLR) (4202)
    Schlagwort(e): ddc:526 ; Precise point positioning ; GPS ; Galileo ; Broadcast ephemerides ; Signal-in-space range error
    Sprache: Englisch
    Materialart: doc-type:article
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  • 16
    Publikationsdatum: 2023-08-08
    Beschreibung: Within the Ararat Valley (Armenia), a continuously growing water demand (for irrigation and fish farming) and a simultaneous decline in groundwater recharge (due to climate change) result in increasing stress on the local groundwater resources. This detrimental development is reflected by groundwater-level drops and an associated reduction of the area with artesian conditions in the valley centre. This situation calls for increasing efforts aimed at more sustainable water resources management. The aim of this baseline study was the collection of data that allows for study on the origin and age distribution of the Ararat Valley groundwater based on environmental tracers, namely stable (δ〈sup〉2〈/sup〉H, δ〈sup〉18〈/sup〉O) and radioactive (〈sup〉35〈/sup〉S, 〈sup〉3〈/sup〉H) isotopes, as well as physical-chemical indicators. The results show that the Ararat Valley receives modern recharge, despite its (semi-)arid climate. While subannual groundwater residence times could be disproved (〈sup〉35〈/sup〉S), the detected 〈sup〉3〈/sup〉H pattern suggests groundwater ages of several decades, with the oldest waters being recharged around 60 years ago. The differing groundwater ages are reflected by varying scatter of stable isotope and hydrochemical signatures. The presence of young groundwater (i.e., younger that the 1970s), some containing nitrate, indicates groundwater vulnerability and underscores the importance of increased efforts to achieve sustainable management of this natural resource. Since stable isotope signatures indicate the recharge areas to be located in the mountains surrounding the valley, these efforts must not be limited to the central part of the valley where most of the abstraction wells are located.
    Beschreibung: Technische Universität Darmstadt (3139)
    Schlagwort(e): ddc:551 ; Groundwater residence time ; Tritium ; Radiosulphur ; Stable isotopes ; Armenia
    Sprache: Englisch
    Materialart: doc-type:article
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  • 17
    Publikationsdatum: 2023-08-08
    Beschreibung: Die Bundesanstalt für Geowissenschaften und Rohstoffe (BGR) führte in den Jahren 2000–2014 umfangreiche (etwa 5900 km2) aerogeophysikalische Erkundungen an der niedersächsischen Nordseeküste durch. Die Aeroelektromagnetik liefert Informationen über die elektrisch leitfähigen Strukturen im Erduntergrund und ermöglicht die Unterscheidung von Süß- und Salzwasser wie auch von Tonen und Sanden. Im Landesamt für Bergbau, Energie und Geologie (LBEG) sowie am Leibniz Institut für Angewandte Geophysik (LIAG) wurden diese Daten zur Kartierung der Tiefenlage der Süß‑/Salzwassergrenze genutzt. Dadurch ist unter anderem eine detaillierte Karte der Grundwasserversalzung innerhalb der küstennahen Aquifere entlang der niedersächsischen Nordseeküste im Maßstab 1:50.000 entstanden. Diese zeigt den aktuellen Stand der Grundwasserversalzung, abgeleitet aus den gewonnenen Elektromagnetik-Modellen. Die Modelle waren auch Grundlage für eine hydraulische Modellierung der Süßwasserlinse der Nordseeinsel Borkum. Darauf aufbauende Simulationen zeigen die Entwicklung der Grundwassersituation für den Zeitraum bis 2100.
    Beschreibung: Landesamt für Bergbau, Energie und Geologie (LBEG) (4273)
    Schlagwort(e): ddc:551.49 ; Grundwasserversalzung ; Modellierung ; Aeroelektromagnetik ; Klimawandel ; Süßwasserlinse ; Fresh-saline groundwater Interface ; Climate change ; Airborne electromagnetics ; Freshwater lenses
    Sprache: Deutsch
    Materialart: doc-type:article
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  • 18
    Publikationsdatum: 2023-08-01
    Beschreibung: Cereal crop production in sub-Saharan Africa has not achieved the much-needed increase in yields to foster economic development and food security. Maize yields in the region’s semi-arid agroecosystems are constrained by highly variable rainfall, which may be worsened by climate change. Thus, the Tanzanian government has prioritized agriculture as an adaptation sector in its intended nationally determined contribution, and crop management adjustments as a key investment area in its Agricultural Sector Development Programme. In this study, we investigated how future changes in maize yields under different climate scenarios can be countered by regional adjusted crop management and cultivar adaptation strategies. A crop model was used to simulate maize yields in the Singida region of Tanzania for the baseline period 1980–2012 and under three future climate projections for 2020–2060 and 2061–2099. Adaptation strategies to improve yields were full irrigation, deficit irrigation, mulch and nitrogen addition and another cultivar. According to our model results, increase in temperature is the main driver of future maize yield decline. Increased respiration and phenological development were associated with lower maize yields of 16% in 2020–2060 and 20% in 2061–2099 compared to the 1980–2012 baseline. Surprisingly, none of the management strategies significantly improved yields; however, a different maize variety that was tested as an alternative coping strategy performed better. This study suggests that investment in accessibility of improved varieties and investigation of maize traits that have the potential to perform well in a warmer future are better suited for sustaining maize production in the semi-arid region than adjustments in crop management.
    Beschreibung: Leibniz Centre for Agricultural Landscape Research (ZALF)
    Beschreibung: Universität Hohenheim (3153)
    Schlagwort(e): ddc:631 ; Maize ; Climate change ; Adaptation ; Model ; Tanzania ; NDC
    Sprache: Englisch
    Materialart: doc-type:article
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  • 19
    Publikationsdatum: 2023-08-01
    Beschreibung: Sao Tome and Principe is a small insular country in the west coast of Central Africa. The small dimensions of the islands and the limited natural resources put these islands under highly vulnerable to climate change. To assess the possible future impacts and risks on their agricultural activities, the high-resolution 4-km downscaled climate change projections using Eta regional climate model are used. A crop risk index (CRI) is proposed to assess the risk of climate change on cocoa (Theobroma cacao L.), pepper (Piper nigrum L. and Piper guinesse L.), taro (Colocasia esculenta (L.) Schott), and maize (Zea mays L.). The index takes into account the vulnerability to climate conditions and the crop yield in the future, and it is classified into very-high, high, moderate, low, and very-low. The climate change projections indicate increase in the risk of taro crop, partly due to thermal stress and partly due to the susceptibility to the leaf blight crop disease in taro. The risk of production of the pepper crop is very-high, mainly due to water stress. In mountain regions, the greater risk is due to the thermal stress caused by low temperatures. The cocoa crop is at risk due to water stress, mainly in the northwestern part of the Sao Tome Island, where major local production occurs. The projection indicates increase of the area with very-high risk to maize crops due to the increase of thermal stress and susceptibility to rust. In addition, in parts of the coastal regions, the risk changed from very-low to high risk, due to the low productivity potential. In general, the risks of the four major crops of Sao Tome and Principe increase in the future climate conditions.
    Beschreibung: UNEP, FUNDEP, Sao Tome and Principe National Institute of Meteorology
    Beschreibung: CNPq
    Schlagwort(e): ddc:631 ; Crop risk index ; Climate change ; Small Islands Developing States ; Eta model ; Agriculture risk assessment
    Sprache: Englisch
    Materialart: doc-type:article
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  • 20
    Publikationsdatum: 2023-08-01
    Beschreibung: Changing climate conditions are supposed to have particularly strong impacts on agricultural production in the tropics with strong implications on food security. Ethiopia’s economy is profoundly dominated by agriculture, contributing to around 40% of the gross domestic product. Thereby, Ethiopia is one of the most vulnerable countries to the impact of climate change and has a wide gap in regional climate change impact studies. In this study, we systematically investigate climate change impacts on yields for the Gambella region in Ethiopia, exemplarily for maize. Here, we show how yields change until 2100 for RCPs 2.6, 4.5, and 8.5 from a climate model ensemble under rainfed and irrigated conditions. While rainfed yields decrease by 15% and 14% respectively for RCPs 2.6 and 4.5, yields decrease by up to 32% under RCP 8.5. Except for RCP 8.5, yields are not further decreasing after 2040–2069. We found that temperature increase, changing soil water availability, and atmospheric CO2 concentration have different effects on the simulated yield potential. Our results demonstrate the dominance of heat response under future climate conditions in the tropical Gambella region, contributing to 85% of total yield changes. Accordingly, irrigation will lose effectiveness for increasing yield when temperature becomes the limiting factor. CO2, on the other hand, contributes positively to yield changes by 8.9% for RCP 8.5. For all scenarios, the growing period is shorted due to increasing temperature by up to 29 days for RCP 8.5. Our results suggest that new varieties with higher growing degree days are primarily required to the region for adapting to future climate conditions.
    Beschreibung: Ludwig-Maximilians-Universität München (1024)
    Schlagwort(e): ddc:631 ; Climate change ; Agriculture ; Regional study ; Crop model
    Sprache: Englisch
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  • 21
    Publikationsdatum: 2023-08-09
    Beschreibung: Salinization of the upper aquifer of the northern Elbe-Weser region almost extends to the surface. Chloride content exceeds 250 mg/l and the groundwater is therefore, according to the German Drinking Water Ordinance, not suitable as drinking water. The chloride content in the aquifer originates from early flooding with seawater which occurred during the Holocene sea level rise. Depth and extent of the salinization were mapped by airborne electromagnetic surveys and validated by groundwater analyses. In the transition zone between the marshlands and geest areas, the fresh-saline groundwater interface falls to a depth of 〉 −175 m NHN. Due to the extensive drainage of the marshlands, seepage of fresh groundwater is impeded. Instead, an upconing of the fresh-saline groundwater interface appears due to an upwardly directed hydraulic gradient. Due to climate change, chloride concentrations will increase along the coastlines. Further inland, a decrease of chloride content in near-surface groundwater will occur.
    Beschreibung: Interreg http://dx.doi.org/10.13039/100013276
    Beschreibung: Landesamt für Bergbau, Energie und Geologie (LBEG) (4273)
    Schlagwort(e): ddc:551.49 ; Fresh-saline groundwater interface ; HEM ; Drainage ; Cl/Br ratio ; Climate change ; Süß‑/Salzwassergrenze ; HEM ; Cl/Br-Verhältnis ; Klimawandel
    Sprache: Englisch
    Materialart: doc-type:article
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  • 22
    Publikationsdatum: 2023-06-23
    Beschreibung: Die Ergebnisse regionaler Klimaprojektionen für Deutschland weisen auf eine Zunahme der mittleren Lufttemperatur und eine innerjährliche Verschiebung der Niederschläge – mit feuchteren Wintern und trockeneren Sommern – hin. Darüber hinaus werden sich regional die Häufigkeit, Intensität und Dauer von Hitzewellen, Trockenperioden und Starkregenereignissen weiter erhöhen. Durch diese Veränderungen wird sich auch der Jahresgang der Grundwasserneubildung ändern. Als Folge dessen können sich Änderungen bei den hohen, mittleren und tiefen Grundwasserständen, Grundwasserschwankungsbreiten und dem Grundwasserdargebot ergeben. Aber nicht nur die Ressource Grundwasser wird durch die Folgen des Klimawandels betroffen. Auch die gesamte Infrastruktur – von der Förderung bis zur Verteilungsleitung zum Kunden – kann beeinträchtigt werden. Neben den direkten Einflüssen sind auch indirekte Beeinflussungen durch Kaskadeneffekte – beispielsweise ausgehend vom Energiesektor – möglich. Darum gilt es integrative, ganzheitliche und systemische Lösungen zu erarbeiten, um die Funktionalität der kritischen Infrastruktur dauerhaft auch unter Berücksichtigung der Folgen des Klimawandels gewährleisten zu können.
    Beschreibung: Helmholtz-Zentrum Geesthacht - Zentrum für Material- und Küstenforschung GmbH (HZG) (4216)
    Beschreibung: Climate change impacts on groundwater use—impacts and action needs
    Schlagwort(e): ddc:304.28 ; Klimawandel ; Wasserversorgung ; Kritische Infrastruktur ; Anpassung ; Climate change ; Impacts ; Water supply ; Critical infrastructure ; Adaptation
    Sprache: Deutsch
    Materialart: doc-type:article
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  • 23
    Publikationsdatum: 2023-06-21
    Beschreibung: North Africa is considered a climate change hot spot. Existing studies either focus on the physical aspects of climate change or discuss the social ones. The present article aims to address this divide by assessing and comparing the climate change vulnerability of Algeria, Egypt, Libya, Morocco, and Tunisia and linking it to its social implications. The vulnerability assessment focuses on climate change exposure, water resources, sensitivity, and adaptive capacity. The results suggest that all countries are exposed to strong temperature increases and a high drought risk under climate change. Algeria is most vulnerable to climate change, mainly due to the country’s high sensitivity. Across North Africa, the combination of climate change and strong population growth is very likely to further aggravate the already scarce water situation. The so-called Arab Spring has shown that social unrest is partly caused by unmet basic needs of the population for food and water. Thus, climate change may become an indirect driver of social instability in North Africa. To mitigate the impact of climate change, it is important to reduce economic and livelihood dependence on rain-fed agriculture, strengthen sustainable land use practices, and increase the adaptive capacity. Further, increased regional cooperation and sub-national vulnerability assessments are needed.
    Beschreibung: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Beschreibung: National Geographic Society http://dx.doi.org/10.13039/100006363
    Schlagwort(e): ddc:304.28 ; Climate change ; Vulnerability ; Resilience ; Water ; Conflict ; North Africa
    Sprache: Englisch
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  • 24
    Publikationsdatum: 2023-06-21
    Beschreibung: Currently, many commercial airline aircraft cannot perform three-dimensionally guided approaches based on satellite-based augmentation systems. We propose a system to rebroadcast the correction and integrity data via a data link as provided by the ground-based augmentation system such that aircraft equipped with a GPS landing system (GLS) can use the wide-area corrections and perform localizer performance with vertical guidance (LPV) approaches while maintaining the same level of integrity. In consequence, the system loses some availability and the time to alert is slightly increased. We build a prototype system and present data collected for one week, confirming technical feasibility. There is a loss of 5.3 percent of availability during a 1-week data collection cycle in which we compared our system to standalone LPV service. We tested our prototype with two commercially available GLS receivers with positive results and successfully demonstrated the functionality with a conventional Airbus 319 equipped with a standard GLS receiver.
    Schlagwort(e): ddc:526 ; SBAS ; Satellite ; Navigation ; Augmentation ; Aviation ; GPS ; GNSS
    Sprache: Englisch
    Materialart: doc-type:article
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  • 25
    Publikationsdatum: 2023-06-21
    Beschreibung: The European CORDEX (EURO-CORDEX) initiative is a large voluntary effort that seeks to advance regional climate and Earth system science in Europe. As part of the World Climate Research Programme (WCRP) - Coordinated Regional Downscaling Experiment (CORDEX), it shares the broader goals of providing a model evaluation and climate projection framework and improving communication with both the General Circulation Model (GCM) and climate data user communities. EURO-CORDEX oversees the design and coordination of ongoing ensembles of regional climate projections of unprecedented size and resolution (0.11° EUR-11 and 0.44° EUR-44 domains). Additionally, the inclusion of empirical-statistical downscaling allows investigation of much larger multi-model ensembles. These complementary approaches provide a foundation for scientific studies within the climate research community and others. The value of the EURO-CORDEX ensemble is shown via numerous peer-reviewed studies and its use in the development of climate services. Evaluations of the EUR-44 and EUR-11 ensembles also show the benefits of higher resolution. However, significant challenges remain. To further advance scientific understanding, two flagship pilot studies (FPS) were initiated. The first investigates local-regional phenomena at convection-permitting scales over central Europe and the Mediterranean in collaboration with the Med-CORDEX community. The second investigates the impacts of land cover changes on European climate across spatial and temporal scales. Over the coming years, the EURO-CORDEX community looks forward to closer collaboration with other communities, new advances, supporting international initiatives such as the IPCC reports, and continuing to provide the basis for research on regional climate impacts and adaptation in Europe.
    Schlagwort(e): ddc:551.6 ; EURO-CORDEX ; CORDEX ; Climate change ; Regional climate models ; Regional climate modelling
    Sprache: Englisch
    Materialart: doc-type:article
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  • 26
    Publikationsdatum: 2023-07-20
    Beschreibung: Late Cenozoic was a period of large-scale extension in the Aegean. The extension is mainly recorded in the metamorphic core complexes with little data from the sedimentary sequences. The exception is the Thrace Basin in the northern Aegean, which has a continuous record of Middle Eocene to Oligocene marine sedimentation. In the Thrace Basin, the Late Oligocene–Early Miocene was characterized by north-northwest (N25°W) shortening leading to the termination of sedimentation and formation of large-scale folds. We studied the stratigraphy and structure of one of these folds, the Korudağ anticline. The Korudağ anticline has formed in the uppermost Eocene–Lower Oligocene siliciclastic turbidites with Early Oligocene (31.6 Ma zircon U–Pb age) acidic tuff beds. The turbidites are underlain by a thin sequence of Upper Eocene pelagic limestone. The Korudağ anticline is an east-northeast (N65°E) trending fault-propagation fold, 9 km wide and 22 km long and with a subhorizontal fold axis. It is asymmetric with shallowly-dipping northern and steeply-dipping southern limbs. Its geometry indicates about 1 km of shortening in a N25°W direction. The folded strata are unconformably overlain by Middle Miocene continental sandstones, which constrain the age of folding. The Korudağ anticline and other large folds in the Thrace Basin predate the inception of the North Anatolian Fault (NAF) by at least 12 myr. The Late Oligocene–Early Miocene (28–17 Ma) shortening in the Thrace Basin and elsewhere in the Balkans forms an interlude between two extensional periods, and is probably linked to changes in the subduction dynamics along the Hellenic trench.
    Beschreibung: TÜBİTAK
    Beschreibung: İTÜ-BAP
    Beschreibung: TÜBA
    Beschreibung: Freie Universität Berlin (1008)
    Schlagwort(e): ddc:551 ; Thrace Basin ; Shortening ; Oligocene ; Miocene ; Aegean
    Sprache: Englisch
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  • 27
    Publikationsdatum: 2023-07-20
    Beschreibung: New whole-rock geochemical and coupled U–Pb and Lu–Hf LA-ICP-MS zircon data of metasedimentary rocks of the Austroalpine, South Alpine and Penninic basement domains are presented, to disentangle the pre-Variscan tectonic evolution of the proto-Alps. The studied units seem to record distinct stages of protracted Late Ediacaran to Carboniferous tectonosedimentary processes prior to the Variscan collision. In the case of Austroalpine and South Alpine units, nevertheless, no major differences in terms of provenance are observed, since most detrital zircon samples are characterized by a major Pan-African peak. Their detrital zircon spectra record a provenance from the northeastern Saharan Metacraton and the Sinai basement at the northern Arabian-Nubian Shield, being thus located along the eastern Early Paleozoic northern Gondwana margin, whereas sources located further west are inferred for the Penninic Unit, which might have been placed close to the Moldanubian Unit of the Bohemian Massif. In any case, it is thus clear that the Alpine basement remained in a close position to the Gondwana mainland at least during the Early Paleozoic. The Late Ediacaran to Silurian tectonic evolution, which includes Cadomian and Cenerian tectonometamorphic and magmatic processes, seem thus to record a continuum related to a retreating-mode accretionary orogen, with diachronous back-arc basin opening and possibly discrete compressional/transpressional pulses linked to changes in subduction zone dynamics. On the other hand, it is inferred that the Alpine basement essentially comprises Pan-African metasedimentary and subordinate metaigneous rocks, possibly with very few Early Neoproterozoic relics. This basement was significantly reworked during the protracted Paleozoic orogenic evolution, due to anatexis and/or assimilation by mantle-derived juvenile magmatism.
    Beschreibung: Georg-August-Universität Göttingen (1018)
    Schlagwort(e): ddc:551 ; Alpine basement ; Cadomian orogeny ; Cenerian orogeny ; Retreating-mode accretionary orogen ; Sedimentary provenance ; Detrital zircons
    Sprache: Englisch
    Materialart: doc-type:article
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  • 28
    Publikationsdatum: 2023-07-20
    Beschreibung: GNSS satellite and receiving antennas exhibit group delay variations (GDV), which affect code pseudorange measurements. Like antenna phase center variations, which affect phase measurements, they are frequency-dependent and vary with the direction of the transmitted and received signal. GNSS code observations contain the combined contributions of satellite and receiver antennas. If absolute GDV are available for the receiver antennas, absolute satellite GDV can be determined. In 2019, an extensive set of absolute receiver antenna GDV was published and, thus, it became feasible to estimate absolute satellite antenna GDV based on terrestrial observations. We used the absolute GDV of four selected receiver antenna types and observation data of globally distributed reference stations that employ these antenna types to determine absolute GDV for the GPS, GLONASS, Galileo, BeiDou, and QZSS satellite antennas. Besides BeiDou-2 satellites whose GDV are known to reach up to 1.5 m peak-to-peak, the GPS satellites show the largest GDV at frequencies L1 and L5 with up to 0.3 and 0.4 m peak-to-peak, respectively. They also show the largest satellite-to-satellite variations within a constellation. The GDV of GLONASS-M satellites reach up to 25 cm at frequency G1; Galileo satellites exhibit the largest GDV at frequency E6 with up to 20 cm; BeiDou-3 satellites show the largest GDV of around 15 cm at frequencies B1-2 and B3. Frequencies L2 of GPS IIIA, E1 of Galileo FOC, and B2a/B2b of BeiDou-3 satellites are the least affected. Their variations are below 10 cm.
    Beschreibung: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Beschreibung: Technische Universität Dresden (1019)
    Schlagwort(e): ddc:526 ; Absolute group delay variations ; Code-minus-carrier combination ; GPS ; GLONASS ; Galileo ; BeiDou ; QZSS
    Sprache: Englisch
    Materialart: doc-type:article
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  • 29
    Publikationsdatum: 2023-07-27
    Beschreibung: Extensive morphological and age studies on more than 4600 detrital zircon grains recovered from modern sands of Namibia reveal complex mechanisms of sediment transport. These data are further supplemented by a zircon age database containing more than 100,000 single grain analyses from the entire southern Africa and allow for hypothesising of a large Southern Namibian Sediment Vortex located between the Damara Orogen and the Orange River in southern Namibia. The results of this study also allow assuming a modified model of the Orange River sand highway, whose origin is likely located further south than previously expected. Moreover, studied samples from other parts of Namibia give first insights into sediment movements towards the interior of the continent and highlight the potential impact of very little spatial variations of erosion rates. Finally, this study points out the huge potential of detrital zircon morphology and large geo-databases as an easy-to-use additional tool for provenance analysis.
    Beschreibung: deutsche forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Beschreibung: Senckenberg Naturhistorische Sammlungen Dresden (3507)
    Schlagwort(e): ddc:551 ; Namibia ; Zircon ; Mineral morphology ; Sediment transport ; Geochronology ; Database
    Sprache: Englisch
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  • 30
    Publikationsdatum: 2023-07-27
    Beschreibung: The Brenner normal fault bounds the Tauern Window to the west and accommodated a significant portion of the orogen-parallel extension in the Eastern Alps. Here, we use zircon (U–Th)/He, apatite fission track, and apatite (U–Th)/He dating, thermokinematic modeling, and a topographic analysis to constrain the exhumation history of the western Tauern Window in the footwall of the Brenner fault. ZHe ages from an E–W profile (parallel to the slip direction of the fault) decrease westwards from ~ 11 to ~ 8 Ma and suggest a fault-slip rate of 3.9 ± 0.9 km/Myr, whereas AFT and AHe ages show no spatial trends. ZHe and AFT ages from an elevation profile indicate apparent exhumation rates of 1.1 ± 0.7 and 1.0 ± 1.3 km/Myr, respectively, whereas the AHe ages are again spatially invariant. Most of the thermochronological ages are well predicted by a thermokinematic model with a normal fault that slips at a rate of 4.2 km/Myr between ~ 19 and ~ 9 Ma and produces 35 ± 10 km of extension. The modeling reveals that the spatially invariant AHe ages are caused by heat advection due to faulting and posttectonic thermal relaxation. The enigmatic increase of K–Ar phengite and biotite ages towards the Brenner fault is caused by heat conduction from the hot footwall to the cooler hanging wall. Topographic profiles across an N–S valley in the fault footwall indicate 1000 ± 300 m of erosion after faulting ceased, which agrees with the results of our thermokinematic model. Valley incision explains why the Brenner fault is located on the western valley shoulder and not at the valley bottom. We conclude that the ability of thermokinematic models to quantify heat transfer by rock advection and conduction is crucial for interpreting cooling ages from extensional fault systems.
    Beschreibung: Westfälische Wilhelms-Universität Münster (1056)
    Beschreibung: https://github.com/jeanbraun
    Schlagwort(e): ddc:551 ; European Alps ; Tauern Window ; Thermochronology ; Thermokinematic modeling
    Sprache: Englisch
    Materialart: doc-type:article
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  • 31
    Publikationsdatum: 2023-07-21
    Beschreibung: Late Paleozoic (Variscan) magmatism is widespread in Central Europe. The Lusatian Block is located in the NE Bohemian Massif and it is part of the Saxothuringian Zone of the Variscan orogen. It is bordered by two major NW-trending shear zones, the Intra-Sudetic Fault Zone towards NE and the Elbe Fault Zone towards SW. The scarce Variscan igneous rocks of the Lusatian Block are situated close to these faults. We investigated 19 samples from Variscan plutonic and volcanic rocks of the Lusatian Block, considering all petrological varieties (biotite-bearing granites from the Koenigshain and Stolpen plutons, amphibole-bearing granites from three boreholes, several volcanic dykes, and two volcanites from the intramontane Weissig basin). We applied whole-rock geochemistry (18 samples) and zircon evaporation dating (19 samples). From the evaporation data, we selected six representative samples for additional zircon SHRIMP and CA–ID–TIMS dating. For the Koenigshain pluton, possible protoliths were identified using whole-rock Nd-isotopes, and zircon Hf- and O-isotopes. The new age data allow a subdivision of Variscan igneous rocks in the Lusatian Block into two distinct magmatic episodes. The spatial relation of the two age groups to either the Elbe Fault Zone (298–299 Ma) or the Intra-Sudetic Fault Zone (312–313 Ma) together with reports on the fault-bound character of the dated intrusions suggests an interpretation as two major post-collisional faulting episodes. This assumption of two distinct magmatic periods is confirmed by a compilation of recently published zircon U–Pb CA–ID–TIMS data on further Variscan igneous rocks from the Saxothuringian Zone. New geochemical data allow us to exclude a dominant sedimentary protolith for the Koenigshain pluton as supposed by previous investigations. This conclusion is mainly based on new O- and Hf-isotope data on zircon and the scarcity of inherited zircons. Instead, acid or intermediate igneous rocks are supposed as the main source for these I-type granitoids from the Koenigshain pluton.
    Beschreibung: Technische Universität Bergakademie Freiberg (3135)
    Schlagwort(e): ddc:551 ; Geochronology ; Zircon ; Variscan granites ; Lusatian block
    Sprache: Englisch
    Materialart: doc-type:article
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  • 32
    Publikationsdatum: 2023-07-29
    Beschreibung: Stabilizing agricultural production is fundamental to food security. At the national level, increasing the effective diversity of cultivated crops has been found to increase temporal production stability, i.e., the year-to-year stability of total caloric production of all crops combined. Here, we specifically investigated these effects at the regional level for the European Union and tested the effect of crop diversity in relation to agricultural inputs, soil properties, climate instability, and time on caloric, protein, and fat stability, as we hypothesized that the effect of diversity is context dependent. We further investigated these relationships for specific countries. We found that greater crop diversity was consistently associated with an increase in production stability, particularly in regions with large areas equipped for irrigation and low soil type diversity. For instance, in Spain and Italy, crop diversity showed the strongest positive effect among all predictors, while on the European level, the stabilizing effect of nitrogen use was substantially higher. In Germany, the crop diversity-stability relationship was weak, suggesting that crops react similarly to climatic, economic, and political factors or are grown in the same periods. With this study, we substantiate previous findings that crop diversity stabilizes agricultural caloric production and extend these with regard to protein and fat. The results elucidate the key drivers that enhance production stability for different European countries and regions, which is of key importance for a comparably productive agricultural region like Europe.
    Beschreibung: Helmholtz-Gemeinschaft http://dx.doi.org/10.13039/501100001656
    Beschreibung: Helmholtz-Zentrum für Umweltforschung GmbH - UFZ (4215)
    Schlagwort(e): ddc: ; Agroecology ; Climate change ; Resilience ; Sustainability
    Sprache: Englisch
    Materialart: doc-type:article
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  • 33
    Publikationsdatum: 2022-05-30
    Beschreibung: Scientific investigations in Antarctica are, for many different reasons, a challenging and fascinating task. Measurements, observations and field operations must be carefully planned well in advance and the capacity of successfully meeting the goals of a scientific project is often related to the capacity of forecasting and anticipating the many different potential mishaps. In order to do that, experience and logistic support are crucial. On the scientific side, the team must be aware of its tasks and be prepared to carry out observations in a hostile environment: both technology and human resources have to be suitably selected, prepared, tested and trained. On the logistic side, nations, institutions and any other organisation involved in the expeditions must ensure the proper amount of competence and practical support. The history of modern Italian Antarctic expeditions dates back to the middle 80’s when the first infrastructures of “Mario Zucchelli Station”, formerly Terra Nova Bay Station, were settled at Terra Nova Bay, Northern Victoria Land. Only a few years later, the first geodetic infrastructures were planned and built. Italian geodetic facilities and activities were, ever since, being constantly maintained and developed. Nowadays, the most remarkable geodetic infrastructures are the permanent Global Positioning System (GPS) station (TNB1) installed at Mario Zucchelli and the GPS geodetic network Victoria Land Network for DEFormation control (VLNDEF) entirely deployed on an area extending between 71° S and 76° S and 160° E and 170° E. These facilities do not only allow carrying out utmost geodetic investigations but also posses interesting capacities on the international multidisciplinary scientific scenario. In order to fully exploit their potentiality, management and maintenance of the infrastructure are crucial; nevertheless, in order to perform high quality scientific research, these abilities must be coupled with the knowledge concerning a proper use and a correct processing of the information that these infrastructures can provide. This work focuses on the different methods that can be applied to process the observations that are performed with GPS technique in Northern Victoria Land, aiming at reaching the highest accuracy of results and assuring the larger significance and versatility of the processing outcomes. Three software were used for the analysis, namely: Bernese v.5.0, Gipsy/Oasis II and Gamit/Globk. The working data sets are (i) the permanent GPS station TNB1 observations continuously performed since 1998 and (ii) the five episodic campaigns performed on the sites of VLNDEF. The two infrastructures can be regarded as neat examples of standard geodetic installation in Antarctica. Therefore, the technological solutions that were adopted and applied for establishing the GPS permanent station and the VLNDEF geodetic network as well as the data processing strategies and the data analysis procedures that were tested on their observation will be illustrated in detail. The results will be presented, compared and discussed. Furthermore, their potentials and role in geodetic research will be carefully described; their versatility will also be highlighted in the foreground of a multidisciplinary Antarctic international scientific activity.
    Beschreibung: Published
    Beschreibung: 37-72
    Beschreibung: 1.8. Osservazioni di geofisica ambientale
    Beschreibung: reserved
    Schlagwort(e): Antarctica ; Geodesy ; Geodetic Infrastructures ; GPS ; 01. Atmosphere::01.01. Atmosphere::01.01.08. Instruments and techniques
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: book chapter
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  • 34
    Publikationsdatum: 2022-05-26
    Beschreibung: © The Author(s), 2017. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Ambio 46, Supple. 1 (2017): 160-173, doi:10.1007/s13280-016-0870-x.
    Beschreibung: Long-term measurements of ecological effects of warming are often not statistically significant because of annual variability or signal noise. These are reduced in indicators that filter or reduce the noise around the signal and allow effects of climate warming to emerge. In this way, certain indicators act as medium pass filters integrating the signal over years-to-decades. In the Alaskan Arctic, the 25-year record of warming of air temperature revealed no significant trend, yet environmental and ecological changes prove that warming is affecting the ecosystem. The useful indicators are deep permafrost temperatures, vegetation and shrub biomass, satellite measures of canopy reflectance (NDVI), and chemical measures of soil weathering. In contrast, the 18-year record in the Greenland Arctic revealed an extremely high summer air-warming of 1.3°C/decade; the cover of some plant species increased while the cover of others decreased. Useful indicators of change are NDVI and the active layer thickness.
    Beschreibung: The Toolik research was supported in part by NSF Grants DEB 0207150, DEB 1026843, ARC 1107701, and ARC 1504006.
    Schlagwort(e): Alaska Toolik ; Climate change ; Ecological effects ; Greenland Zackenberg ; Medium pass filter ; Vegetation
    Repository-Name: Woods Hole Open Access Server
    Materialart: Article
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  • 35
    Publikationsdatum: 2023-06-17
    Beschreibung: Paleo-shorelines on continental shelves give insights into the complex development of coastlines during sealevel cycles. This study investigates the geologic development of the Limpopo Shelf during the last sealevel cycle using multichannel seismic and acoustic datasets acquired on the shelf in front of the Limpopo River mouth. A detailed investigation of seismic facies, shelf bathymetry, and a correlation to sea level revealed the presence of numerous submerged shorelines on the shelf. These shorelines are characterized by distinct topographic ridges and are interpreted as coastal dune ridges that formed in periods of intermittent sealevel still-/slowstand during transgression. The shorelines are preserved due to periods of rapid sealevel rise (melt water pulses) that led to the overstepping of the dune ridges as well as due to early cementation of accumulated sediments that increased the erosive resistance of the ridges. The high along-shelf variability of the submerged dune ridges is interpreted as a result of pre-existing topography affecting shoreline positions during transgression. The pre-existing topography is controlled by the underlying sedimentary deposits that are linked to varying fluvial sediment input at different points on the shelf. The numerous prominent submerged dune ridges form barriers for the modern fluvial sediment from the Limpopo River and dam sediment on the inner shelf. They may also facilitate along-shelf current-induced sediment transport.
    Beschreibung: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Schlagwort(e): ddc:551 ; Limpopo Shelf ; Geology
    Sprache: Englisch
    Materialart: doc-type:article
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  • 36
    Publikationsdatum: 2023-06-17
    Beschreibung: After the onset of plate collision in the Alps, at 32–34 Ma, the deep structure of the orogen is inferred to have changed dramatically: European plate break-offs in various places of the Alpine arc, as well as a possible reversal of subduction polarity in the eastern Alps have been proposed. We review different high-resolution tomographic studies of the upper mantle and combine shear- and body-wave models to assess the most reliable geometries of the slabs. Several hypotheses for the tectonic evolution are presented and tested against the tomographic model interpretations and constraints from geologic and geodetic observations. We favor the interpretation of a recent European slab break-off under the western Alps. In the eastern Alps, we review three published scenarios for the subduction structure and propose a fourth one to reconcile the results from tomography and geology. We suggest that the fast slab anomalies are mainly due to European subduction; Adriatic subduction plays no or only a minor role along the Tauern window sections, possibly increasing towards the Dinarides. The apparent northward dip of the slab under the eastern Alps may be caused by imaging a combination of Adriatic slab, from the Dinaric subduction system, and a deeper lying European one, as well as by an overturned, retreating European slab.
    Beschreibung: GRNE graduate school
    Beschreibung: Deutsche Forschungsgemeinschaft (DE)
    Beschreibung: H2020 Marie Skłodowska-Curie Actions ()
    Beschreibung: http://www.orfeus-eu.org/eida
    Schlagwort(e): ddc:551 ; Seismic tomography ; Subduction slabs ; Alpine subduction system ; Slab break-off ; Slab polarity reversal
    Sprache: Englisch
    Materialart: doc-type:article
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  • 37
    Publikationsdatum: 2023-06-17
    Beschreibung: The Namibian Mesozoic successions may be remnant of a high dynamic sedimentary system that is characterized by multiple stages of sediment accumulation and erosion with contemporaneous homogenization starting with the deposition of the Permo-Carboniferous Dwyka Group strata and continues at least until the Lower Cretaceous. The Lower Cretaceous sedimentary system is interpreted to have involved at least an area covering the whole SW Gondwana, documenting the sedimentary history during the evolution from an ice house environment to an arid desert. To test the sediment homogenization hypothesis, we applied a combination of isotopic and morphometric data on detrital zircon grains, as well as whole-rock geochemical data of selected Mesozoic sandstones from Namibia. As a base for the interpretation of the detrital zircon age data we compiled a zircon age dataset with c. 44,000 analyses for the southern African region. All samples reveal a major detrital pan-African zircon age peak of c. 0.5–0.7 Ga sourced from the pan-African magmatic events occurring around the Kalahari Craton margin. The lowermost Triassic is characterized by the occurrence of additional Mesoproterozoic and Paleoproterozoic age peaks of c. 1.0–1.2 Ga and 1.8–2.0 Ga with a majority of zircon grains showing angular shapes. The protosource of these grains is interpreted to possibly be the Namaqua Metamorphic Complex and other Paleoproterozoic structural units deformed in course of the Namaqua orogeny. In contrast, other samples show a prominent Permo-Triassic age peak and completely rounded zircon grains, putatively derived from within the Gondwanides volcanic arc. The disparity in the zircon age pattern may point towards a change in provenance and also a change in the whole system of zircon recycling during the Mesozoic southern Gondwana. The Lower Triassic Neu Loore fm. are constrained to more local bedrock sources and short zircon transport distance. In contrast, zircon grains of the Middle Triassic Omingonde, the Jurassic Etjo und the Cretaceous Twyfelfontein formations are an expression for a major recycling and sediment homogenization system. The system was facilitated by an interplay between fluvial and eolian sedimentary transport systems.
    Schlagwort(e): ddc:551 ; Zircon U–pb ; Mesozoic ; Gondwana ; Karoo ; Namibia
    Sprache: Englisch
    Materialart: doc-type:article
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  • 38
    Publikationsdatum: 2023-06-16
    Beschreibung: The realization of Coordinated Universal Time, one of the tasks of the International Bureau of Weights and Measures, relies on a network of international time links which currently is organized in a star-like scheme that links all contributing laboratories. GPS signal reception is the technique most widely employed by the laboratories. The PTB currently plays a unique role in the process due to its function as the central pivot in the time transfer between the participating laboratories. We discuss how the PTB meets its obligations to the international timekeeping community as well as to its users in Germany. In its role as an National Metrology Institute (NMI), PTB is entrusted with the realization and dissemination of legal time in Germany. The services were offered to the public support measurements and timing applications traceable to the national and international standards to be made in calibration laboratories and in many industrial sectors. We thus discuss the meaning and definition of traceability, how different GNSS systems can be used to establish traceability and their performance in doing so.
    Schlagwort(e): ddc:526 ; GNSS ; GPS ; Galileo ; Time and frequency metrology ; Traceability
    Sprache: Englisch
    Materialart: doc-type:article
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  • 39
    Publikationsdatum: 2023-06-22
    Beschreibung: The Sentinel-6 (or Jason-CS) altimetry mission provides a long-term extension of the Topex and Jason-1/2/3 missions for ocean surface topography monitoring. Analysis of altimeter data relies on highly-accurate knowledge of the orbital position and requires radial RMS orbit errors of less than 1.5 cm. For precise orbit determination (POD), the Sentinel-6A spacecraft is equipped with a dual-constellation GNSS receiver. We present the results of Sentinel-6A POD solutions for the first 6 months since launch and demonstrate a 1-cm consistency of ambiguity-fixed GPS-only and Galileo-only solutions with the dual-constellation product. A similar performance (1.3 cm 3D RMS) is achieved in the comparison of kinematic and reduced-dynamic orbits. While Galileo measurements exhibit 30–50% smaller RMS errors than those of GPS, the POD benefits most from the availability of an increased number of satellites in the combined dual-frequency solution. Considering obvious uncertainties in the pre-mission calibration of the GNSS receiver antenna, an independent inflight calibration of the phase centers for GPS and Galileo signal frequencies is required. As such, Galileo observations cannot provide independent scale information and the estimated orbital height is ultimately driven by the employed forces models and knowledge of the center-of-mass location within the spacecraft. Using satellite laser ranging (SLR) from selected high-performance stations, a better than 1 cm RMS consistency of SLR normal points with the GNSS-based orbits is obtained, which further improves to 6 mm RMS when adjusting site-specific corrections to station positions and ranging biases. For the radial orbit component, a bias of less than 1 mm is found from the SLR analysis relative to the mean height of 13 high-performance SLR stations. Overall, the reduced-dynamic orbit determination based on GPS and Galileo tracking is considered to readily meet the altimetry-related Sentinel-6 mission needs for RMS height errors of less than 1.5 cm.
    Beschreibung: Deutsches Zentrum für Luft- und Raumfahrt e. V. (DLR) (4202)
    Schlagwort(e): ddc:526 ; Sentinel-6 ; Jason-CS ; Single-receiver ambiguity fixing ; Precise orbit determination ; GPS ; Galileo ; SLR ; Altimetry
    Sprache: Englisch
    Materialart: doc-type:article
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  • 40
    Publikationsdatum: 2023-08-17
    Beschreibung: Für die öffentliche Trinkwasserversorgung in Süddeutschland wird größtenteils Grund- und Quellwasser genutzt. Der Kenntnis über die Entwicklung des Bodenwasserhaushalts und insbesondere der Grundwasserneubildung kommt somit eine große Bedeutung zu. Im Rahmen der Kooperation KLIWA (Klimaveränderung und Konsequenzen für die Wasserwirtschaft, www.kliwa.de) wurde die Entwicklung des Bodenwasserhaushaltes und der Grundwasserneubildung aus Niederschlag für den Zeitraum von 1951 bis 2019 für die Länder Baden-Württemberg, Bayern, Hessen und Rheinland-Pfalz mit dem Bodenwasserhaushaltmodell GWN-BW modelliert. Seit Ende der 1980er-Jahre zeigt sich ein Anstieg der mittleren jährlichen Temperatur in Süddeutschland. Die jährlichen Niederschlagssummen haben sich in der jüngeren Vergangenheit (seit 2003) reduziert und somit eine deutliche Verringerung der Grundwasserneubildung aus Niederschlag bewirkt. Gleichzeitig ist eine Zunahme des Trockenheitsindex (Anzahl an Tagen mit Füllung des Bodenwasserspeichers 〈 30 % der nutzbaren Feldkapazität) zu erkennen. Häufiger werdende und länger anhaltende Trockenperioden stellen auch die Wasserwirtschaft zunehmend vor Herausforderungen und bedürfen der frühzeitigen Entwicklung von Handlungsoptionen, z. B. auf der Basis des hier vorgestellten „Trockenwetterdargebots“, um Nutzungskonflikte zu entschärfen.
    Beschreibung: LUBW Landesanstalt für Umwelt Baden-Württemberg (5309)
    Schlagwort(e): ddc:551.49 ; Wasserversorgung ; Bodenwasserhaushalt ; Grundwasserneubildung ; Klimawandel ; Handlungsoption ; Anpassung ; Water supply ; Soil water balance ; Groundwater recharge ; Climate change ; Action recommendation ; Adaption
    Sprache: Deutsch
    Materialart: doc-type:article
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  • 41
    Publikationsdatum: 2023-08-17
    Beschreibung: Samples and documentation of outcrops and drillings, facies analysis, whole rock geochemistry and radiometric ages have been employed to re-evaluate the Late Carboniferous Tharandt Forest caldera (TFC) and the co-genetic Niederbobritzsch granite (NBG) in the eastern Erzgebirge near Dresden, Germany. The c. 52 km2 TFC harbours strongly welded ignimbrites with a preserved minimum thickness of 550 m. Composition of initial fallout tephra at the base of the TFC fill, comprising lithics of rhyolitic and basic lava, and of silica-rich pyroclastic rocks, suggests a bimodal volcanic activity in the area prior to the climactic TFC eruption. The lower part of the TFC fill comprises quartz-poor ignimbrites, overlain by quartz-rich ignimbrites, apparently without a depositional break. Landslides originating from the collapse collar of the caldera plunged into the still hot TFC fill producing monolithic gneiss mesobreccia with clasts ≤ 1 m in a pyroclastic matrix. Aphanitic and porphyritic rhyolitic magma formed ring- and radial dykes, and subvolcanic bodies in the centre of TFC. Whole rock geochemical data indicate a high silica (most samples have 〉 73 wt% SiO2) rhyolitic composition of the TFC magma, and a similar granodiorite–granitic composition for the NBG. Based on drillings and caldera extent, a minimum volume of 22 km3 of TFC fill is preserved, the original fill is assumed at about 33 km3. This estimate translates into a denudation of at least c. 210 m during Late Paleozoic to pre-Cenomanian. Telescopic subsidence of the TFC took place in two, perhaps three stages. A possible TFC outflow facies has been completely eroded and distal TFC tuff has not been recognized in neighboring basins. New CA-ID-TIMS measurements on two TFC samples gave mean zircon ages of 313.4 ± 0.4 Ma and 311.9 ± 0.4 Ma; two samples from NBG resulted in 318.2 ± 0.5 Ma and 319.5 ± 0.4 Ma. In addition, for one sample of the ring dyke an age of ca. 314.5 ± 0.5 Ma has been obtained. These ages, together with field relations, allow for a model of a long-standing evolution of an upper crustal magmatic system (~ 5 Ma?), where pulses of magmatic injection and crustal doming alternate with magmatic quietness and erosion. Together with the Altenberg–Teplice Volcanic Complex, located some 10 km to the southeast, the TFC–NBG Complex represents an early post-Variscan magmatic activity in central Europe.
    Beschreibung: Technische Universität Bergakademie Freiberg (3135)
    Schlagwort(e): ddc:551 ; Single phase caldera evolution ; Caldera wall landslides ; Freiberg gneiss dome ; CA-ID-TIMS zircon dating
    Sprache: Englisch
    Materialart: doc-type:article
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  • 42
    Publikationsdatum: 2023-08-17
    Beschreibung: This paper presents radon flux profiles from four regions in Schleswig–Holstein (Northern Germany). Three of these regions are located over deep-rooted tectonic faults or salt diapirs and one is in an area without any tectonic or halokinetic activity, but with steep topography. Contrary to recently published studies on spatial patterns of soil radon gas concentration we measured flux of radon from soil into the atmosphere. All radon devices of each profile were deployed simultaneously to avoid inconsistencies due to strong diurnal variations of radon exhalation. To compare data from different seasons, values had to be normalized. Observed radon flux patterns are apparently related to the mineralogical composition of the Quaternary strata (particularly to the abundance of reddish granite and porphyry), and its grain size (with a flux maximum in well-sorted sand/silt). Minimum radon flux occurs above non-permeable, clay-rich soil layers. Small amounts of water content in the pore space increase radon flux, whereas excessive water content lessens it. Peak flux values, however, are observed over a deep-rooted fault system on the eastern side of Lake Plön, i.e., at the boundary of the Eastholstein Platform and the Eastholstein Trough. Furthermore, high radon flux values are observed in two regions associated with salt diapirism and near-surface halokinetic faults. These regions show frequent local radon flux maxima, which indicate that the uppermost strata above salt diapirs are very inhomogeneous. Deep-rooted increased permeability (effective radon flux depth) or just the boundaries between permeable and impermeable strata appear to concentrate radon flux. In summary, our radon flux profiles are in accordance with the published evidence of low radon concentrations in the “normal” soils of Schleswig–Holstein. However, very high values of radon flux are likely to occur at distinct locations near salt diapirism at depth, boundaries between permeable and impermeable strata, and finally at the tectonically active flanks of the North German Basin.
    Beschreibung: Bundesministerium für Wirtschaft und Energie http://dx.doi.org/10.13039/501100006360
    Beschreibung: Johannes Gutenberg-Universität Mainz (1030)
    Schlagwort(e): ddc:551 ; Radon flux ; Local radon flux maxima ; Permeability ; Quaternary sediments ; Salt tectonics ; Schleswig–Holstein
    Sprache: Englisch
    Materialart: doc-type:article
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  • 43
    Publikationsdatum: 2024-01-19
    Beschreibung: The total electron content (TEC) data derived from the GAIA (Ground-to-topside model of Atmosphere Ionosphere for Aeronomy) is used to study the seasonal and longitudinal variation of occurrence of medium-scale traveling ionospheric disturbances (MSTIDs) during daytime (09:00–15:00 LT) for the year 2011 at eight locations in northern and southern hemispheres, and the results are compared with ground-based Global Positioning System (GPS)-TEC. To derive TEC variations caused by MSTIDs from the GAIA (GPS) data, we obtained detrended TEC by subtracting 2-h (1-h) running average from the TEC, and calculated standard deviation of the detrended TEC in 2 h (1 h). MSTID activity was defined as a ratio of the standard deviation to the averaged TEC. Both GAIA simulation and GPS observations data show that daytime MSTID activities in the northern and southern hemisphere (NH and SH) are higher in winter than in other seasons. From the GAIA simulation, the amplitude of the meridional wind variations, which could be representative of gravity waves (GWs), shows two peaks in winter and summer. The winter peak in the amplitude of the meridional wind variations coincides with the winter peak of the daytime MSTIDs, indicating that the high GW activity is responsible for the high MSTID activity. On the other hand, the MSTID activity does not increase in summer. This is because the GWs in the thermosphere propagate poleward in summer, and equatorward in winter, and the equatorward-propagating GWs cause large plasma density perturbations compared to the poleward-propagating GWs. Longitudinal variation of daytime MSTID activity in winter is seen in both hemispheres. The MSTID activity during winter in the NH is higher over Japan than USA, and the MSTID activity during winter in the SH is the highest in South America. In a nutshell, GAIA can successfully reproduce the seasonal and longitudinal variation of the daytime MSTIDs. This study confirms that GWs cause the daytime MSTIDs in GAIA and amplitude and propagation direction of the GWs control the noted seasonal variation. GW activities in the middle and lower atmosphere cause the longitudinal variation.
    Beschreibung: Japan Society for the Promotion of Science, KAKENHI (15H05815, 16H06286), Project for Solar-Terrestrial Environment Prediction (PSTEP) and Study of dynamical variation of particles and waves in the inner magnetosphere using ground-based network observation
    Beschreibung: Projekt DEAL
    Schlagwort(e): ddc:551.5 ; Daytime MSTIDs ; GAIA model ; GPS ; Gravity waves ; Meridional wind ; TEC
    Sprache: Englisch
    Materialart: doc-type:article
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  • 44
    Publikationsdatum: 2024-02-14
    Beschreibung: The precise orbit determination (POD) of Global Navigation Satellite System (GNSS) satellites and low Earth orbiters (LEOs) are usually performed independently. It is a potential way to improve the GNSS orbits by integrating LEOs onboard observations into the processing, especially for the developing GNSS, e.g., Galileo with a sparse sensor station network and Beidou with a regional distributed operating network. In recent years, few studies combined the processing of ground- and space-based GNSS observations. The integrated POD of GPS satellites and seven LEOs, including GRACE-A/B, OSTM/Jason-2, Jason-3 and, Swarm-A/B/C, is discussed in this study. GPS code and phase observations obtained by onboard GPS receivers of LEOs and ground-based receivers of the International GNSS Service (IGS) tracking network are used together in one least-squares adjustment. The POD solutions of the integrated processing with different subsets of LEOs and ground stations are analyzed in detail. The derived GPS satellite orbits are validated by comparing with the official IGS products and internal comparison based on the differences of overlapping orbits and satellite positions at the day-boundary epoch. The differences between the GPS satellite orbits derived based on a 26-station network and the official IGS products decrease from 37.5 to 23.9 mm (34% improvement) in 1D-mean RMS when adding seven LEOs. Both the number of the space-based observations and the LEO orbit geometry affect the GPS satellite orbits derived in the integrated processing. In this study, the latter one is proved to be more critical. By including three LEOs in three different orbital planes, the GPS satellite orbits improve more than from adding seven well-selected additional stations to the network. Experiments with a ten-station and regional network show an improvement of the GPS satellite orbits from about 25 cm to less than five centimeters in 1D-mean RMS after integrating the seven LEOs.
    Beschreibung: Chinese Government Scholarship http://dx.doi.org/10.13039/501100010890
    Schlagwort(e): ddc:526 ; POD ; Integrated processing ; Sparse ground network ; GPS ; LEOs ; GRACE ; Jason ; Swarm
    Sprache: Englisch
    Materialart: doc-type:article
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  • 45
    Publikationsdatum: 2024-05-30
    Beschreibung: Past vegetation, fire, and climate dynamics, as well as human impact, have been reconstructed for the first time in the highlands of the Gilan province in the Alborz mountains (above the Hyrcanian forest) for the last 4,300 cal yrs bp. Multi-proxy analysis, including pollen, spores, non-pollen palynomorphs, charcoal, and geochemical analysis, has been applied to investigate the environmental changes at 2,280 m a.s.l., above the Hyrcanian forest. Dominant steppe vegetation occurred in the study area throughout the recorded period. The formation of the studied mire deposits, as well as vegetation composition, suggest a change to wetter climatic conditions after 4,300 until 1,700 cal yrs bp. Fires were frequent, which may imply long-lasting anthropogenic activities in the area. Less vegetation cover with a marked decrease of the Moisture Index (MI) suggests drier conditions between 1,700 and 1,000 cal yrs bp. A high proportion of Cichorioideae and Amaranthaceae, as well as the reduction of trees, in particular Fagus and Quercus, at lower elevations, indicate human activities such as intense livestock grazing and deforestation. Soil erosion as the result of less vegetation due to dry conditions and/or human activities can be reconstructed from a marked increase of Glomus spores and high values of K and Ti. Since 1,000 cal yrs bp, the increasing MI, as well as the rise of Poaceae and Cyperaceae together with forest recovery, suggest a change to wetter conditions. The occurrence of still frequent Cichorioideae and Plantago lanceolata along with Sordaria reflect continued intense grazing of livestock by humans.
    Beschreibung: Deutsche Forschungsgemeinschaft (DE)
    Beschreibung: Georg-August-Universität Göttingen (1018)
    Schlagwort(e): ddc:561 ; Late Holocene ; Northern Iran ; Multi-proxy studies ; Hyrcanian mountain vegetation ; Climate change ; Human impact
    Sprache: Englisch
    Materialart: doc-type:article
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  • 46
    Digitale Medien
    Digitale Medien
    Springer
    Journal of industrial microbiology and biotechnology 4 (1989), S. 109-120 
    ISSN: 1476-5535
    Schlagwort(e): Ground water ; Biodegradation ; Hydrocarbon ; Adaptation ; Subsurface ; Creosote ; Microorganism
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Summary The microbial ecology of pristine, slightly contaminated, and heavily contaminated subsurface materials, and four subsurface materials on the periphery of the plume at an abandoned creosote waste site was investigated. Except for the unsaturated zone of the heavily contaminated material, mineralization of glucose (13.5 ppb) indicated a metabolically active microflora in all subsurface materials. However, mineralization (〈40%) of naphthalene, phenanthrene, and 2-methylnaphthalene was observed in contaminated material and material from the periphery of the plume, but not in pristine material. Pentachlorophenol was mineralized in material from the periphery of the plume. Inorganic and organic nutrient amendments and changes in pH and temperature did not increase the extent of mineralization of the aromatic compounds. An array of organic compounds found in creosote were biotransformed in contaminated ground water; however some compounds were still detected after 7 months of incubation. The data suggest that the subsurface microflora in slightly and heavily contaminated subsurface materials and materials from the periphery of the plume has adapted to degrade many compounds found in creosote.
    Materialart: Digitale Medien
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  • 47
    Digitale Medien
    Digitale Medien
    Springer
    Stochastic environmental research and risk assessment 10 (1996), S. 87-106 
    ISSN: 1436-3259
    Schlagwort(e): Climate change ; daily precipitation modelling ; generalized linear models ; iteratively reweighted least squares ; spline functions
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Architektur, Bauingenieurwesen, Vermessung , Energietechnik , Geographie , Geologie und Paläontologie
    Notizen: Abstract The precipitation amounts on wet days at De Bilt (the Netherlands) are linked to temperature and surface air pressure through advanced regression techniques. Temperature is chosen as a covariate to use the model for generating synthetic time series of daily precipitation in a CO2 induced warmer climate. The precipitation-temperature dependence can partly be ascribed to the phenomenon that warmer air can contain more moisture. Spline functions are introduced to reproduce the non-monotonous change of the mean daily precipitation amount with temperature. Because the model is non-linear and the variance of the errors depends on the expected response, an iteratively reweighted least-squares technique is needed to estimate the regression coefficients. A representative rainfall sequence for the situation of a systematic temperature rise is obtained by multiplying the precipitation amounts in the observed record with a temperature dependent factor based on a fitted regression model. For a temperature change of 3°C (reasonable guess for a doubled CO2 climate according to the present-day general circulation models) this results in an increase in the annual average amount of 9% (20% in winter and 4% in summer). An extended model with both temperature and surface air pressure is presented which makes it possible to study the additional effects of a potential systematic change in surface air pressure on precipitation.
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  • 48
    Digitale Medien
    Digitale Medien
    Springer
    European journal of nutrition 26 (1987), S. 125-137 
    ISSN: 1436-6215
    Schlagwort(e): vitamin C ; functions ; kinetics ; pool ; saturation ; requirements ; RDA
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Land- und Forstwirtschaft, Gartenbau, Fischereiwirtschaft, Hauswirtschaft , Medizin
    Beschreibung / Inhaltsverzeichnis: Zusammenfassung Die Bedeutung von Vitamin C für den menschlichen Organismus wird aus den wichtigen Funktionen ersichtlich, an denen das Vitamin beteiligt ist, wie zum Beispiel Kollagen- und Karnitinsynthesen. In neuerer Zeit entdeckt wurde seine Rolle bei der Noradrenalinsynthese, der Inaktivierung von freien Radikalen sowie der Verhinderung der Nitrosaminbildung. Die Vielfalt dieser Vitamin-C-abhängigen Funktionen läßt erkennen, daß die Bedarfsfestsetzung für Vitamin C nicht nur die Verhütung der Mangelkrankheit Skorbut anvisieren, sondern auch berücksichtigen sollte, daß alle diese Funktionen jederzeit genügend Vitamin C zur Verfügung haben müßten, um optimal reagieren zu können. Das Konzept der Gewebesättigung kommt diesem Ziel am nächsten. Studien mit einem kinetischen Modell haben ergeben, daß eine Sättigung mit täglicher Einnahme von 100 mg Vitamin C bei Nichtrauchern und von 140 mg bei Rauchern eintritt, Mengen, die als optimale Werte gelten können. Bei verschiedenen Krankheiten dürfte der Bedarf höher sein; die genauen Mengen müssen jedoch erst noch ermittelt werden.
    Notizen: Summary The importance of vitamin C is reflected in its multifunctional roles which include participation in collagen and carnitine syntheses, promotion of iron absorption and the more recently discovered participation in noradrenaline synthesis, inactivation of free radical chain reactions, prevention of N-nitroso compound formation and more. Given the many extra-antiscorbutic functions of the vitamin, the Recommended Dietary Allowances (RDA) should not just prevent deficiency disease but should aim at providing sufficient amounts for all vitamin C-dependent functions to operate at full capacity. The concept of vitamin C tissue saturation is best able to meet this demand. The use of kinetic models has shown that the body pool is saturated with a daily intake of 100 mg vitamin C in non-smokers and 140 mg in smokers, amounts that may be regarded as optimal RDA values. Certain disease states may be accompanied by still higher vitamin C requirements but the exact amounts are not yet known.
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  • 49
    Digitale Medien
    Digitale Medien
    Springer
    AI & society 7 (1993), S. 248-252 
    ISSN: 1435-5655
    Schlagwort(e): Culture ; Technology ; Cold utilitarianism ; Adaptation ; Civilization ; Western culture ; Eastern culture ; Instrumentality
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Informatik
    Notizen: Abstract The role of cultural models in the process of adaptation to the new technologies is very different according to different civilizations. Some basic cultural items seem to be particularly crucial, such as, for example, the levels of pragmatism or rationalism which characterize a civilization or some periods of its history. This paper presents a sketch aimed at setting up a comparison between Western and Eastern cultures facing the problem of adapting to new technologies. The concept ofcold utilitarianism is introduced. It allows a way of defining adaptation which is only partial and contradictory in Western culture, while it completely describes, though perhaps provisionally, the Eastern way of making and using technology.
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  • 50
    Digitale Medien
    Digitale Medien
    Springer
    Regional environmental change 1 (2000), S. 70-77 
    ISSN: 1436-378X
    Schlagwort(e): Key words Mountain vegetation ; Climate change ; Schynige Platte ; Switzerland
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie , Energietechnik
    Notizen: Abstract Climate change has in the past led to shifts in vegetation patterns; in a future, warmer climate due to enhanced greenhouse-gas concentrations, vegetation is also likely to be highly responsive to such warming. Mountain regions are considered to be particularly sensitive to such changes. In this paper we present an approach to assess the impact of climate change on long-term vegetation plots at the high-elevation site of the Schynige Platte, 2000 m above sea level, in the Bernese Alps (Switzerland). Records of vegetation spanning the period from 1928 to today at two different sites, each with several plots, were considered. The observed change in the species composition was then related to changes in land use and climate. We used daily values of temperature, snow and precipitation from several high-elevation weather stations to conduct these analyses. The correlation between climate and vegetation patterns revealed that species that prefer low thermal conditions move out of the plots, i.e., their frequency of occurrence is negatively correlated with the average number of degree-days over the last six decades. On the other hand, species with higher thermal demands are seen to be invading the plots, i.e., their frequency of occurrence is positively correlated to the average number of degree-days. Nutrient changes – though independent from climate – also play an important role in the observed shifts in species.
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  • 51
    Digitale Medien
    Digitale Medien
    Springer
    Colloid & polymer science 261 (1983), S. 188-189 
    ISSN: 1435-1536
    Schlagwort(e): Polymerization ; kinetics ; redox polymerization ; acrylamide
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau
    Materialart: Digitale Medien
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  • 52
    Digitale Medien
    Digitale Medien
    Springer
    Colloid & polymer science 266 (1988), S. 958-964 
    ISSN: 1435-1536
    Schlagwort(e): a-Se colloids ; photoadsorption ; kinetics ; activation energy ; compensation effect
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau
    Notizen: Abstract In this study, a model is developed to explain in microscopic terms the results obtained from thermally activated photoadsorption experiments in a-Se colloids. The observed compensation effect can be described for two different cases. At low efficiency adsorption, the process is controlled by the potential at the boundary layer. In the high efficiency adsorption case, the process is controlled by diffusion transport.
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  • 53
    Digitale Medien
    Digitale Medien
    Springer
    Colloid & polymer science 262 (1984), S. 366-373 
    ISSN: 1435-1536
    Schlagwort(e): kinetics ; isothermal crystallization ; polymer ; spherulite ; differential scanning calorimetry
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau
    Notizen: Abstract In the DSC technique, isothermal crystallization experiments are usually performed on thin flat specimens, but their interpretation generally uses theories developed for an unbounded volume. In this paper, isothermal crystallization of spherical entities in the volume limited by two parallel infinite planes is considered. Our model, derived from Avrami's theory, gives an analytical expression for the transformed volume fraction as a function of time. It is shown that the influence of thickness becomes important when thickness becomes of the order of or smaller than the average spherulite radius. The main effects of a decreasing thickness are a slower crystallization kinetics and a decrease in the Avrami exponent. These results can be used to interpret experimental data obtained in isothermal polymer crystallization.
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  • 54
    ISSN: 1435-1536
    Schlagwort(e): Phospholipid bilayer ; kinetics ; laser temperature jump ; phase transition
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau
    Notizen: Abstract The iodine-laser temperature-jump technique has been used to investigate the main phase transition in single shell vesicles of dimyristoylphosphatidylcholine. The probe molecules DPH and TMA-DPH were incorporated into the lipid bilayer and laserT-jump experiments with turbidity and flourescence polarization detection were performed. We found three well separated relaxation processes between 5 μs and 10 ms. The relaxation signals showed strong cooperativity in the relaxation times as well as in their corresponding amplituedes. We attributed the relaxation to the formation and dissolution of clusters of different order inside the bilayer.
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  • 55
    Digitale Medien
    Digitale Medien
    Springer
    Colloid & polymer science 265 (1987), S. 58-64 
    ISSN: 1435-1536
    Schlagwort(e): Polymerisation ; emulsion ; styrene ; methylmethacrylate ; kinetics
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau
    Notizen: Abstract The dependence of emulsion polymerisation rates on a number of important parameters is considered. Attention is paid to the use of seeded emulsion systems for the evaluation of radical desorption coefficients (k o). Experimental conditions are shown to be important. When the average number of radicals per particle is low, large changes in the rate coefficient for chain termination do not have a large effect on the kinetics. With styrene and methylmethacrylate, radical re-absorption by the polymer particles is shown to be important and radical capture efficiences can be high. Consistency is established between the results of a number of workers and values fork o are shown to be lower than those calculated from chain transfer rates.
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  • 56
    Digitale Medien
    Digitale Medien
    Springer
    Colloid & polymer science 261 (1983), S. 621-625 
    ISSN: 1435-1536
    Schlagwort(e): Polyamide 6 ; crystallisation ; kinetics ; titania
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau
    Notizen: Abstract The kinetics of isothermal and nonisothermal crystallization of polyamide-6 (PA6) containing titania was studied by means of DSC. It was found thatTiO 2 causes an acceleration in the crystallization of polyamide-6 and lowers the value of the Avrami exponent,n. The presence of TiO2 does not affect equilibrium melting pointT m 0 , glass temperatureT g, or surface free energiesσ e andσ of the basal and lateral surfaces.
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  • 57
    Digitale Medien
    Digitale Medien
    Springer
    Entomologia experimentalis et applicata 91 (1999), S. 403-412 
    ISSN: 1570-7458
    Schlagwort(e): aphid ; Diuraphis noxia ; Triticum aestivum ; endosymbiont ; insect-plant interactions ; phloem ; amino acids
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie
    Notizen: Abstract The feeding behavior of Diuraphis noxia Mordvilko (Homoptera: Aphididae) on susceptible hosts causes both ultrastructural and tissue level damage which may affect phloem composition. Genetic evidence suggests that endosymbiotic bacteria in most aphids overproduce limiting amino acids to benefit hosts but that D. noxia depends less on endosymbionts for these nutrients, possibly due to an enriched diet. To determine whether D. noxia feeding damage results in higher concentrations of essential amino acids, stylet exudates were analyzed from wheat (Triticum aestivum) damaged to different degrees. Comparison of samples from undamaged and damaged susceptible wheat revealed changes in amino acid composition and an increase in levels of essential amino acids, indicating a nutritionally enhanced ingesta. The changes in stylet exudates paralleled changes in leaf exudates, indicating that the effects are systemic. Feeding damage is not observed on a resistant wheat host, var. Halt, and leaf exudates from infested Halt did not show changes in amino acid composition. Mean relative growth of nymphs was significantly lower on Halt than on susceptible Arapahoe, indicating that Halt is a less suitable host. Both varieties show similar amino acid levels in non-infested samples, suggesting that D. noxia infestation does not enhance the phloem environment in Halt. This study provides evidence that aphid feeding can generate a nutritionally enhanced phloem diet.
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  • 58
    Digitale Medien
    Digitale Medien
    Springer
    Fire technology 20 (1984), S. 47-63 
    ISSN: 1572-8099
    Schlagwort(e): Extinguishment ; fire modeling ; mass loss ; heat release ; char ; reflash ; sprinklers ; radiant flux ; kinetics ; reaction rate ; heat loss ; ash ; latent heat ; spray density ; extinguishing agents
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Architektur, Bauingenieurwesen, Vermessung
    Notizen: Abstract The Ad Hoc Mathematical Fire Modeling Working Group was organized about seven years ago to facilitate voluntary cooperation and coordination in developing mathematical fire modeling capability. The group has a steering committee of representatives of agencies that support fire modeling and related research. These include the National Bureau of Standards' Center for Fire Research, Factory Mutual Research Corp., the Naval Research Laboratory, NASA, and the Federal Aviation Agency. The Group holds plenary meetings when it seems desirable to do so (about once each 1 1/2 years), and workshops on topical subjects. Three workshops were held in 1983. Normally, Group meetings are held before or after other meetings at which a number of interested personnel would likely be present. Minutes are mailed to those who attended and to others (including European and Japanese personnel) who have indicated interest. This workshop was arranged by Ron Alpert of Factory Mutual Research Corp. and held at their facilities at Norwood, MA, in November 1983.
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  • 59
    ISSN: 1572-8358
    Schlagwort(e): Adaptation ; Anacystis nidulans ; Cyanobacteria ; Flow-force relationship ; Growth ; Phosphate uptake ; Selforganization of aquatic ecosystems
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie
    Notizen: Abstract The properties of the phosphate uptake system of the cyanobacterium Anacystis nidulans have been studied during the transition from a phosphate-deficient non-growing state to a non-deficient growing state. In the phosphate-deficient state the high affinity phosphate transport system in the cell membrane is extremely adaptive. As a result of these adaptive features the phosphate transport system cannot be described by determinate, fixed parameters, because the transport system is influenced by the measurement of the uptake process itself. When the growing state has been initiated by a persisting phosphate pulse, the transport system rapidly loses its adaptive features and can then be characterized by determinate parameters that remain unchanged for a long period of time, even if no uptake occurs in that time. Depending on the amount of phosphate stored during a pulse the cell makes a choice between slow or fast growth. In the latter case the light harvesting and energy converting machinery is completely reorganized before growth commences. Thereby the components of this machinery conform to each other and to the stable properties of the phosphate transport system. It is suggested that the mutual adjustment of these adaptive energy converting subunits is guided by attractors that function as the final cause for the development of the whole system. An application of this model to an analysis of the selforganization of aquatic ecosystems is discussed.
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  • 60
    Digitale Medien
    Digitale Medien
    Springer
    Wireless personal communications 7 (1998), S. 41-52 
    ISSN: 1572-834X
    Schlagwort(e): microcellular system ; location detection ; radio propagation ; GPS
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Elektrotechnik, Elektronik, Nachrichtentechnik
    Notizen: Abstract Microcellular systems, such as the Personal Handyphone System, need a large number of cell stations to cover service areas. Therefore, a quick and efficient means to evaluate a service area is of great importance. This paper describes a new microcell automatic propagation measuring system (MAPS) employing location recognition and cell-site identification. Service-area evaluation of microcellular systems based on field experiments in urban and suburban areas is also described. Measurement location is recognized using the Global Positioning System, an optical-fiber gyroscope, and a vehicle speed sensor. Cell-site identification is determined through cell-station ID. Computer-aided propagation-data processing using a map database is adopted for service area mapping. This enables evaluation of cell overlaps, out-of-service areas, cell shapes, interference, etc. This system greatly improves the efficiency in propagation measurement and evaluation of service area for microcellular systems.
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  • 61
    Digitale Medien
    Digitale Medien
    Springer
    Entomologia experimentalis et applicata 58 (1991), S. 69-74 
    ISSN: 1570-7458
    Schlagwort(e): Rhopalosiphum padi ; antixenosis ; plant resistance ; Triticum aestivum
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie
    Beschreibung / Inhaltsverzeichnis: Zusammenfassung Die Antixenose gegenüberRhopalosiphum padi (L.) in den drei Weizensorten Timmo, Moghan 2 und Ommid, von denen die zwei letzteren Sorten aus dem Iran stammen, wurde unter Verwendung des systemischen Insektizids Pirimicarb gemessen. Jeweils zwei Pflanzen aus verschiedenen Sorten wurden als Paar verwendet (in allen Kombinationen der drei Sorten), pro Paar ein Topf mit Pirimicarb gegossen, und zwanzig Blattlaüse über Blattflächen von beiden Sorten gekäfigt. Ähnliche Versuche wurden auch ohne Insektizid ausgeführt. Beide Methoden zeigten deutliche Antixenose von Moghan 2 und Ommid in Vergleich mit Timmo. Die Insektizidmethode zeigte auch eine Bevorzugung von Moghan 2 gegenüber Ommid, ein Resultat, das mit der schon bekannten relativen Antibiose dieser zwei Sorten übereinstimmte, während sich ohne Insektizid kein solcher Unterschied erwies. Die statistische Analyse solcher Versuche mit einem Insektizid, die eine Modifikation der Berechnung des erwarteten Werts mit dem χ2 Test enthält, ist beschrieben.
    Notizen: Abstract Antixenosis in three wheat varieties (Timmo, Moghan 2 and Ommid) toRhopalosiphum padi (L.) was measured by pairing plants of any two varieties with one plant of each pair treated with a soil drench of the systemic insecticide pirimicarb. Aphids were then allowed access to equivalent leaf areas from the two plants in a leaf cage. The results were compared with similar choice experiments without insecticide. By either technique, the two Iranian varieties (Moghan 2 and Ommid) showed antixenosis in comparison with Timmo. The statistical analysis of the data, using a heterogeneity χ2 test, is described.
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  • 62
    ISSN: 1570-7458
    Schlagwort(e): LepidopteraEphestia kuehniella ; α-amylase ; Triticum aestivum ; endosperm ; α-amylase inhibitors
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie
    Notizen: Abstract Crude α-amylase preparations from seven Lepidoptera pests were susceptible to inhibition by salt-soluble proteins of bread wheat (Triticum aestivum L.) endosperm. Protein fractions that corresponded to tetrameric, dimeric, and monomeric wheat α-amylase inhibitors, were decreasingly effective against the insect α-amylase activity. To further confirm these results, purified inhibitors were tested against an α-amylase preparation fromEphestia kuehniella (Zeller). This preparation showed decreased activity when increasing amounts of an heterotetrameric inhibitor (reconstituted from its isolated subunits WTAI-CM2, -CM3 and -CM16) were assayed. Activity was only partially inhibited by homodimeric (WDAI-1, synonym 0.53; WDAI-2, synonym 0.19) and monomeric (WMAI-1, synonym 0.28) inhibitors.
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  • 63
    Digitale Medien
    Digitale Medien
    Springer
    Entomologia experimentalis et applicata 91 (1999), S. 111-114 
    ISSN: 1570-7458
    Schlagwort(e): sieve element ; salivation ; aphid ; plant resistance ; wheat ; Sitobion fragariae ; Triticum aestivum
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie
    Notizen: Abstract Extended sieve element salivation (E1 waveform in the electrical penetration graph) is a characteristic activity during early sieve element punctures, particularly in resistant plants. In order to explore a chemically-mediated mechanism of resistance associated with sieve element salivation, we compared the pattern of feeding behaviour of the aphid, Sitobion fragariae (Walker), on two cultivars of the wheat Triticum aestivum L., with different concentrations of hydroxamic acids (Hx). During 24 h of electronic monitoring, aphids dedicated over 50% of the total time to phloem ingestion from the sieve elements. Total time allocated to E1 in the experiment, time to first E1 within the experiment, time allocated to E1 before a sustained phloem ingestion (E2) and the contribution of sieve element salivation to the phloem phase (E1/[E1+E2]) were significantly higher in the high-Hx cultivar. The increased salivation in plants with higher contents of Hx suggests the existence, at least in this system, of a chemically-mediated sieve element constraint.
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  • 64
    Digitale Medien
    Digitale Medien
    Springer
    Journal of solution chemistry 11 (1982), S. 339-346 
    ISSN: 1572-8927
    Schlagwort(e): Carbon dioxide ; hydrolysis ; aqueous solution ; kinetics ; activation volume
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The pressure dependence of the dehydration reaction of H2CO3 was measured in acidic aqueous solution for pressures up to 1 kbar using a high-pressure stopped-flow instrument. The corresponding volume of activation was found to be 6.4±0.4 cm3-mol−1 at 25°C and 0.5 ionic strength. Volume equation calculations result in a value of −9.9±1.9cm3-mol−1 for the volume of activation for the hydrolysis of CO2 under the same conditions. For the first time, the reaction mechanism can be interpreted in terms of dissociative and associative modes, respectively. These data are used to construct an overall reaction volume profile.
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  • 65
    ISSN: 1572-8927
    Schlagwort(e): Temperature jump ; kinetics ; thermodynamics ; TRIS ; iminodiacetic acid ; magnesium ion ; phenol red
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Equations describing the temperature jump amplitudes associated with a system of two coupled reactions (TRIS-phenol red) as well as the ternary system (Mg2+-iminodiacetic acid-phenol red) are presented. The termodynamic parameters calculated from experimentally measured temperature perturbation amplitudes using a multiparametric curve fitting procedure are found to be in good agreement with those determined from pH- and costant rate thermometric titrations. For phenol red, pK I =7.55, ΔH I =3.45 kcal, and for Mg2+ iminodiacetic acid, log K M =2.84, ΔH M =3.25 kcal, were obtained. It is shown that this method can be used to determine accurate thermodynamic enthalpy changes over a narrow temperature interval of less than 1.0°C from a single experiment requiring about 50 μl of sample solution.
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  • 66
    Digitale Medien
    Digitale Medien
    Springer
    Journal of solution chemistry 12 (1983), S. 771-781 
    ISSN: 1572-8927
    Schlagwort(e): Ultrasonics ; kinetics ; aqueous solution ; iso-butyl cellosolve
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Ultrasonic absorption and velocity measurements in aqueous solution of iso-butyl cellosolve (ethylene glycol iso-butyl ether) as a function of the concentration are reported. The two relaxational absorptions have been attributed to the perturbation of the equilibria expressed by AB⇌A+B and Aα(1/n)An where A is the solute, B is the solvent, AB is the complex and A n is the solute aggregate. The rate constants for each step have been determined. From the concentration dependence of the maximum excess absorption per wave length, the enthalpy change and the volume change for the reaction between the solute and the solvent have been determined for aqueous solutions of butyl cellosolve (ethylene glycol n-butyl ether), iso-butyl cellosolve and propyl cellosolve (ethylene glycol n-propyl ether). The results are consistent with a hydrogen bonding reaction. The effect of the ethers on water structure are considered and it is clear that the fraction of water molecules which can hydrogen bond to the solute decreases with the increasing hydrophobicity of the solute.
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  • 67
    ISSN: 1572-8927
    Schlagwort(e): Solvolysis ; kinetics ; aqueous solvent mixtures ; Co(III) complexes
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The kinetics of the solvolysis of [Co(CN)5Cl]3− have been investigated in water +2-methoxyethanol and water + diethylene glycol mixtures. Although the addition of these linear hydrophilic cosolvent molecules to water produces curvature in the variation of log(rate constant) with the reciprocal of the dielectric constant, their effect on the enthalpy and entropy of activation is minimal, unlike the effect of hydrophobic cosolvents. The application of a Gibbs energy cycle to the solvolysis in water and in the mixtures using either solvent-sorting or TATB values for the Gibbs energy of transfer of the chloride ion between water and the mixture shows that the relative stability of the emergent solvated Co(III) ion in the transition state compared to that of Co(CN)5Cl3− in the initial state increases with increasing content of cosolvent in the mixture. By comparing the effects of other cosolvents on the solvolysis, this differential increase in the relative stabilities of the two species increases with the degree of hydrophobicity of the cosolvent.
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  • 68
    Digitale Medien
    Digitale Medien
    Springer
    Journal of solution chemistry 6 (1977), S. 203-216 
    ISSN: 1572-8927
    Schlagwort(e): Glucose ; kinetics ; mixed solvent ; kinetic isotope effect ; enthalpy of activation ; entropy of activation ; tetrahydrofuran ; tert-butanol ; mutarotation
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The mutarotation rates of glucose in aqueous mixtures of tetrahydrofuran andtert-butanol in the mole fraction (xi) range 0〈xi〈0.2 have been measured at 5° intervals in the range 5–35°C. The kinetic deuterium isotope effects have been determined for the same solvent compositions at 25 and 35°C. A statistical analysis of the Arrhenius plots indicates that the experimental errors, although small, are too large for the establishment of any compensation behavior between ΔH
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  • 69
    Digitale Medien
    Digitale Medien
    Springer
    Journal of applied electrochemistry 29 (1999), S. 191-200 
    ISSN: 1572-8838
    Schlagwort(e): cyclic redox reaction ; dissolution ; kinetics ; manganese dioxide ; mechanism ; pyrite
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Elektrotechnik, Elektronik, Nachrichtentechnik
    Notizen: Abstract This paper describes a study of the kinetics and mechanism of MnO2 dissolution in H2SO4 in the presence of pyrite through leaching and electrochemical parameters. Manganese(iv) was found to dissolve mainly through reduction by the ferrous ion generated during oxidation of pyrite by the ferric ion. The oxidation which is slower and rate controlling may proceed through two different reactions, one producing S0 and the other SO42−. Manganese dissolution runs at the same rate as that of pyrite oxidation by maintaining ferrous ion concentration at a much lower level than that of ferric. Kinetic equations based on corrosion coupling principles are developed to explain the observed leaching behaviour.
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  • 70
    Digitale Medien
    Digitale Medien
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    Journal of chemical crystallography 28 (1998), S. 69-72 
    ISSN: 1572-8854
    Schlagwort(e): Co(III) complex ; crystal structure ; kinetics ; steric effects
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Geologie und Paläontologie , Physik
    Notizen: Abstract The title compound crystallizes in the orthorhombic space group Pnma, with a = 7.9209(5), b = 9.818(1), c = 16.867(2) Å, and Z = 4. The structure was solved employing 1864 independent x-ray reflections with I〉2σ(I) by Patterson and difference Fourier techniques and refined by full-matrix least-squares to R = 0.036. The trans-[CO(NH3)4(NH2CH3)Cl](ClO4)2 molecule is on a crystallographic mirror plane. The cobalt ion is in an elongated octahedral coordination with four equatorial ammonia ligands [average Co–N distance equal to 1.966(2) Å], an axial methylamine [Co–N=1.965(3)Å], and an axial chlorine ion [Co–Cl=2.2771(9)Å]. Kinetic steric effects of the complex are interpreted in terms of structural results.
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  • 71
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    Journal of solution chemistry 19 (1990), S. 1073-1084 
    ISSN: 1572-8927
    Schlagwort(e): Solvolysis ; kinetics ; mixtures of water+cosolvent
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Rates of solvolysis of the complex cation [Co(4tBupy)4Cl2]+ have been determined in mixtures of water with the hydrophobic solvent, t-butyl alcohol. The solvent composition at which the extremum is found in the variation of the enthalpy ΔH* and the entropy ΔS* of activation correlates well with the extremum in the variation of the relative partial molar volume of t-butyl alcohol in the mixture and the straight line found for the variation of ΔH* with ΔS* is coincident with the same plot for water + 2-propanol mixtures. A free energy cycle is applied to the process initial state (C n+) going to the transition state [M(n+1)+...Cl−] in water and in the mixture using free energies of transfer of the individual ionic species, ΔG t o (i), from water into the mixture. Values for ΔG t o (i) are derived from the solvent sorting method and from the TATB/TPTB method: using data from either method, changes in solvent structure on going from water into the mixture are found to stabilize the cation in the transition state, M(n+1)+, more than in the initial state, C n+. This is compared with the application of the free energy cycle to the solvolysis of complexes [Co(Rpy)4Cl2]+ and [Coen2LCl]+ in mixtures of water with methanol, 2-propanol or t-butyl alcohol: the above conclusion regarding the relative stabilization of the cations holds for all these complexes in their solvolyses in water+alcohol mixtures using values of ΔG t o (Cl−) from either source.
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  • 72
    Digitale Medien
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    Journal of solution chemistry 2 (1973), S. 217-238 
    ISSN: 1572-8927
    Schlagwort(e): Cation ; energies ; H. S. Frank ; M. Eigen ; R. G. Wilkins ; kinetics ; ligand substitution ; mechanism ; mixed solvents ; nonaqueous ; solvation ; solvent ; solvent structure ; solvent exchange ; transition metal
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The role of the solvent in reactions involving ions is considered in relation to the structure of liquids. The rate constants and activation parameters for ligand substitutions at divalent transition metal cations in various solvents are compared with those for solvent exchanges. The differences are related to structural properties of the solvents, represented by their heats of evaporation and fluidities, and interpreted with the aid of a model developed from that of Frank and Wen. Water is not a typical solvent.
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  • 73
    Digitale Medien
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    Journal of solution chemistry 21 (1992), S. 1271-1287 
    ISSN: 1572-8927
    Schlagwort(e): Cu(II) ; kinetics ; reduction ; temperature dependence ; H2O2, NaCl, NaBr, NaClO4
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The rates of reduction of Cu(II) with H2O2 have been measured in NaCl and NaBr solutions and mixtures with NaClO4 as a function of pH (6 to 9), temperature (5 to 45°C) and ionic composition (0.1 to 6M). The effect of pH on the rates was found to be independent of temperature and ionic composition. The rates increased as a function of [H+] raised to the power of 1.3 to 1.6. Speciation calculations indicate that this pH dependence can be attributed to Cu(OH)2 being the reactive species. The rate constants in NaCl and NaBr and mixtures with NaClO4 were independent of ionic strength, but proportional to the halide concentration raised to the power of 2.0 (0.2 to 2.6M). These results can be attributed to Cu(OH)2Cl 2 2− being the reactive species to reduction with H2O2. The Cu(I) halide complexes formed from the reduction are not easily oxidized with O2 or H2O2. The faster rates in Br− solutions, which form stronger complexes with Cu+, support this contention. Measurements made in NaCl with added NaHCO3, NaB(OH)4 EDTA, NTA and glycine were also made. These measurements indicate that the CuL complexes (L=B(OH) 4 − , CO 3 2− , EDTA, NTA, and glycine) are not very reactive to reduction with H2O2. The addition of Mg2+ or Ca2+ caused the rates to increase due to the formation of MgL or CaL complexes and the resultant release of reactive Cu2+.
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  • 74
    Digitale Medien
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    Journal of solution chemistry 23 (1994), S. 483-500 
    ISSN: 1572-8927
    Schlagwort(e): Thermodynamics ; kinetics ; chemical relaxation ; temperature-jump ; amplitudes
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Amplitudes of chemical relaxation signals can provide useful information as to the thermodynamics of coupled chemical reactions. The temperature-jump technique has been used to investigate the thermodynamic behavior of the Nickel(II)-3,5-dinitrosalicylate system in buffer solution, where complex formation steps are coupled to proton transfer steps. The analysis of the relaxation curves is based on the transformation of a set of coupled elementary reactions into a set of uncoupled ‘normal reactions.’ By analogy with classical titrations, the experiments have been performed by changing the metal ion concentration at constant ligand concentration and pH. Each measured amplitude is associated in this way to a point of a ‘dynamic titration’ and a procedure is formulated by which the values of the equilibrium constants and enthalpies of the normal reactions are simultaneously obtained by simple linear plots. From the dependence of these parameters on suitable functions of the concentrations of the reactants the values of ΔG° and ΔH° of the individual steps are derived. It is shown that the addition of a buffer (instead of an indicator) influences the stoichiometric coefficients of the normal reaction in such a way that measurable amplitudes are produced in systems that, as the presently investigated, in unbuffered solution would remain insensitive to the external perturbation. The circumstances under which the dynamic method offers advantages over the classical techniques are discussed.
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  • 75
    Digitale Medien
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    Journal of solution chemistry 5 (1976), S. 163-169 
    ISSN: 1572-8927
    Schlagwort(e): Solvent effects ; tetramethylurea ; hydrolysis ; hydrogen bonding ; kinetics
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Tetramethylurea was hydrolyzed in aqueous hydrochloric acid at temperatures of 80, 90, and 100°C. All reactions were carried out in an excess of both tetramethylurea and water, with first-order dependence on acid concentration being observed. As the concentration of water was increased, the rate of hydrolysis decreased until equimolar amounts of water and tetramethylurea were present. Subsequent addition of water had no effect on the observed rate.
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  • 76
    Digitale Medien
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    Adsorption 1 (1995), S. 133-151 
    ISSN: 1572-8757
    Schlagwort(e): PSA process ; sensitivity ; equilibria ; kinetics ; heats
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Physik , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Abstract Mathematical models for pressure swing adsorption (PSA) processes essentially require the simultaneous solutions of mass, heat and momentum balance equations for each step of the process using appropriate boundary conditions for the steps. The key model input variables needed for estimating the separation performance of the process are the multicomponent adsorption equilibria, kinetics and heats of adsorption for the system of interest. A very detailed model of an adiabatic Skarstrom PSA cycle for production of high purity methane from a ethylene-methane bulk mixture is developed to study the sensitivity of the process performance to the input variables. The adsorption equilibria are described by the heterogeneous Toth model which accounts for variations of isosteric heats of adsorption of the components with adsorbate loading. A linear driving force model is used to describe the kinetics. The study shows that small errors in the heats of adsorption of the components can severely alter the overall performance of the process (methane recovery and productivity). The adsorptive mass transfer coefficients of the components also must be known fairly accurately in order to obtain precise separation performance.
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  • 77
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    Adsorption 2 (1996), S. 265-277 
    ISSN: 1572-8757
    Schlagwort(e): frequency response ; diffusion cell ; kinetics ; diffusion ; heat effects
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Physik , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Abstract This paper deals with frequency response (FR) analysis of a closed diffusion cell system with two resonators, that is both the LHS and RHS volumes are modulated. The analysis is made for a homogeneous particle described by a single effective diffusivity as well as a biporous pellet described by macropore and micropore diffusions. It is shown that if the perturbation of the volume of the reservoir #2 is lagged behind that of the reservoir #1 by 3π/2, the pressure response in reservoir #1 is significantly enhanced with larger amplitude as well as phase angle. When the perturbations of the two reservoirs are out of phase, the heat effect is reduced and can become insignificant when the two perturbations are completely out of phase (ψ = π). Under such a condition, the pressure difference between the two reservoirs could be doubled. In the case of biporous pellets, it is shown that the FR behaviours obtained for micropore diffusion control and macropore diffusion control are well distinguished. In the former case, the FR system reduces to a traditional batch adsorber one while in the latter case, the FR behaviour is the same as for a two resonator system with homogeneous particles. This difference can be used for the discrimination of micropore and macropore diffusion processes.
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  • 78
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    Adsorption 3 (1997), S. 267-275 
    ISSN: 1572-8757
    Schlagwort(e): characterisation ; equilibria ; kinetics ; micropore size distribution ; n-butane ; nutshell
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Physik , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Abstract Adsorption equilibria and dynamics ofn-butane on two activated carbon samples prepared from the physical activation of nutshell are studied in this paper. The micropore size distribution (MPSD) is considered as the main source of solid heterogeneity. Lennard-Jones' potential theory and Dubinin's theory (TVFM) are used in the equilibria data to derive the MPSD, which is well fitted by a Gamma distribution function. The adsorption energy distribution derived from the MPSD is very asymmetric for both the samples studied, and this energy distribution used in the HMSD/HMSMD kinetics models for the study of adsorption dynamics ofn-butane.
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  • 79
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    BioMetals 12 (1999), S. 1-10 
    ISSN: 1572-8773
    Schlagwort(e): acidophilic ; strain ; oxidation ; kinetics
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie , Chemie und Pharmazie
    Notizen: Abstract Recovery of metal values from sulfide ores by use of acidophilic microorganisms is gaining importance. A number of commercial/pilot plants are setup to find out the techno-economic feasibility of the overall process. The main drawback in the process is the slow kinetics of dissolution of metal values from the sulfide ores. To make the technology e attractive the kinetics should be improved considerably. There are various factors which determine the overall kinetics such as bacterial activity and concentration, iron and sulfur oxidation, oxygen consumption, reactor design and nature of ore. A brief review has been made dealing with the above parameters
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  • 80
    ISSN: 1572-879X
    Schlagwort(e): Fischer-Tropsch synthesis ; reaction activation barrier ; carbon chain growth and termination ; kinetics
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract A method is established, by which the difference of the reaction activation barriers of carbon chain growth and termination in Fischer-Tropsch (FT) synthesis can be determined from experiments. A FT synthesis is carried out on Fe/Zn catalyst. We apply the method to analyze the experimental result and obtain the difference of reaction activation barriers of carbon chain growth and termination of α-olefins on the catalyst.
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  • 81
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    Catalysis letters 37 (1996), S. 167-172 
    ISSN: 1572-879X
    Schlagwort(e): dissociation ; kinetics ; Co-Mo sulphide ; H2S
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract In this study, a high surface area 4Co∶6Mo∶100γ-Al2O3 sulphide prepared using precipitation from homogeneous solution (PFHS) has been used for the catalytic splitting of hydrogen sulphide into H2 and elemental sulphur. The activity of this new formulation was significantly better than previously reported recipes. Kinetic data collected over a wide range of H2S partial pressures between 883 and 983 K revealed that, although the decomposition followed a first-order law, a mechanism involving H2S adsorption on co-ordinative unsaturation sites of the Co-Mo sulphide catalyst gave a Langmuir-Hinshelwood rate expression that yielded satisfactory model parameters. In particular, the scission of the surface H-S bond appeared to be the rate determining step.
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  • 82
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    Cellulose 1 (1994), S. 26-56 
    ISSN: 1572-882X
    Schlagwort(e): low-temperature degradation ; kinetics ; mechanisms ; electrical insulation ; transformers
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Land- und Forstwirtschaft, Gartenbau, Fischereiwirtschaft, Hauswirtschaft , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Abstract A critical review is given of the degradation of cellulose in the low-temperature region (below about 300°C) of power transformer operation. The large number of kinetic studies, under a variety of environmental conditions from Kraft paper in insulating oil, to cotton and paper in oxygen, are considered in terms of a first-order polymer chain scission model. In many cases, the data are replotted to suit the model. A common activation energy of 111±6 kjmol−1 is calculated and it is shown that the pre-exponential factor, rather than the activation energy, is sensitive to the oxidizing nature of the environment and the susceptibility to degradation of the material. The chemical mechanisms of degradation are reviewed, and conclusions and recommendations are made regarding chemical condition monitoring and life prediction of electrical insulation.
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  • 83
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    Adsorption 6 (2000), S. 137-147 
    ISSN: 1572-8757
    Schlagwort(e): adsorption ; kinetics ; linear driving force model ; process design
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Physik , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Abstract The Linear Driving Force (LDF) model for gas adsorption kinetics is frequently and successfully used for analysis of adsorption column dynamic data and for adsorptive process designs because it is simple, analytic, and physically consistent. Yet, there is a substantial difference in the characteristics of isothermal batch uptake curves on adsorbent particles by the LDF and the more rigorous Fickian Diffusion (FD) model. It is demonstrated by using simple model systems that the characteristics of the adsorption kinetics at the single pore or the adsorbent particle level are lost in (a) evaluating overall uptake on a heterogeneous porous solid, (b) calculating breakthrough curves from a packed adsorbent column, and (c) establishing the efficiency of separation by an adsorptive process due to repeated averaging of the base kinetic property. That is why the LDF model works in practice.
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  • 84
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    Catalysis letters 37 (1996), S. 173-179 
    ISSN: 1572-879X
    Schlagwort(e): ammonia synthesis ; iron catalysts ; potassium promotion ; kinetics
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Measurements were performed of reaction rate in the process of ammonia synthesis (T=370–470°C) on doubly promoted (DP) (Al2O3, CaO) and triply promoted (TP) (K2O, Al2O3, CaO) iron catalysts. The latter were obtained by impregnation of the reduced and subsequently passivated DP precursors with alcoholic solution of KOH. The studies were carried out under high total pressure (10 MPa) in a wide range of ammonia partial pressure in the gas phase: from 0.25 to about 7 bar. The results are shown to be authoritative for the so-called kinetic regime. The effect of the presence of K+ cations in the catalyst was the stronger, as the temperature of the reaction was the lower and, in particular, the ammonia pressure in the gas phase the higher. The obtained results are in good accordance with the results of Somorjai's studies on activity of iron single crystal surfaces both clean and covered with (K+O) adlayer.
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  • 85
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    Catalysis letters 27 (1994), S. 79-90 
    ISSN: 1572-879X
    Schlagwort(e): kinetics ; carbon ; oxygen ; recombination ; rhodium ; surface characterisation ; XPS ; AES
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Different mechanisms of atomic carbon and oxygen recombination on a rhodium surface are studied with Auger electron spectroscopy (AES) and X-ray photoelectron spectroscopy (XPS). The kinetics of adsorbed carbidic carbon oxidation (carbon coverageθ c ≈ 0.1–0.3 ML) by gas-phase oxygen that proceeds by a Langmuir-Hinshelwood reaction mechanism, provides the value of the activation energy for recombination (E rec ⇂t ≈ 170±20 kJ/mol).E rec ⇂t depends slightly on the carbon coverage. An Eley-Rideal type of reaction was observed for adsorbed oxygen and atomic gas-phase carbon recombination which occurs in a dynamic regime. The low value found for the activation energy (near zero) is consistent with the mechanism that this exothermic reaction is too fast for energy dissipation into the substrate; the energy is mainly transferred into translational, vibrational and rotational energy of CO.
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  • 86
    ISSN: 1572-879X
    Schlagwort(e): ammonia synthesis ; kinetics ; ruthenium catalysts ; promotional effect
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The kinetics of NH3 synthesis over carbon-based ruthenium catalysts promoted with barium or alkali was studied. Both the ammonia partial pressure dependencies of the reaction rates (T = 400°C, p = 63 bar, H2 : N2 = 3 : 1) and the pressure variations of the activity (T = 370°C, p= 4–63 bar, H2 : NN2 = 3 : 1) were found to be different for Ba and for the alkali (K, Cs). Ba–Ru/C proved to be more sensitive to the NH3 content and to the total pressure. The rate of synthesis over the alkali-promoted catalysts is, in turn, much stronger influenced by the ruthenium dispersion. TOFs of NH3 synthesis for the promoted samples at 370°C and 4 bar (Ba 0.085 1/s, Cs 0.05 1/s, K 0.035 1/s) are significantly higher than that for the Ru(0001) basal plane (0.0085 1/s results from the literature data at 370°C, 2 bar). The most active Ru/C samples (Ba or Cs) exceed significantly the fused iron catalyst, especially at high conversions.
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  • 87
    ISSN: 1572-882X
    Schlagwort(e): accelerated tests ; aging tests ; cellulose degradation ; durability ; kinetics
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Land- und Forstwirtschaft, Gartenbau, Fischereiwirtschaft, Hauswirtschaft , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Abstract Accelerated aging tests are credible and useful to predict paper permanence only if such tests can be shown to correlate with natural aging. In the first part of this study, a kinetic model was developed based on the accelerated aging results. In this report, we have shown that this kinetic model can indeed predict the natural aging results of lignin-free sheets with a statistical confidence. This is the first quantitative comparison of accelerated aging with natural aging.
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  • 88
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    Journal of solution chemistry 27 (1998), S. 1123-1138 
    ISSN: 1572-8927
    Schlagwort(e): Sol–gel processing ; hydrolysis ; condensation ; kinetics ; methoxydimethyloctylsilane ; copper nitrate hydrate ; phase diagram
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The reaction rate was determined for copper nitrate hydrate with methoxydimethyloctylsilane (MDOS) in methanol. The rate constants of hydrolysis and condensation were established by quantitative measurement of the product and Karl Fischer water determination. The reaction with the hydrated copper salt resulted in the phase separation of an insoluble product from the reaction mixture. The structure of the product was determined, by Fourier Transform Infrared Spectrometry (FTIR) and Nuclear Magnetic Resonance (NMR) to be a dimer of the MDOS. The results showed the alcohol, producing condensation reaction was negligible in the formation of the dimer. contrary to the case for the well-known reaction by trialkoxysilanes and tetraalkoxysilanes.
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  • 89
    ISSN: 1572-8927
    Schlagwort(e): Enthalpies of reaction ; heats of reaction ; kinetics ; ester hydrolysis ; microcalorimetry
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The conditions under which the Picker flow microcalorimeter can be used to measure enthalpies and rates of reactions were investigated. For this purpose, systematic studies were made of the enthalpies of neutralization of HCl, HBr, HNO 3 , acetic, proprionic, and butyric acids with NaOH, enthalpies of hydrolysis of methyl and ethyl acetate with NaOH, and the reaction rates of the ester hydrolysis with NaOH. The general procedure and various sources of error are discussed and it is concluded that enthalpies of slow reactions can be measured to about 1% when the calorimeter is operated in the quasi-isothermal mode and the reaction rates to about 3% when operated in the quasi-adiabatic mode.
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  • 90
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    Cellulose 4 (1997), S. 1-5 
    ISSN: 1572-882X
    Schlagwort(e): paper ; degradation ; ageing ; kinetics ; modelling
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Land- und Forstwirtschaft, Gartenbau, Fischereiwirtschaft, Hauswirtschaft , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
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  • 91
    Digitale Medien
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    Cellulose 3 (1996), S. 243-267 
    ISSN: 1572-882X
    Schlagwort(e): aging tests ; cellulose degradation ; durability ; kinetics ; paper properties
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Land- und Forstwirtschaft, Gartenbau, Fischereiwirtschaft, Hauswirtschaft , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Abstract The validity of accelerated aging tests to predict and rank papers on their permanence has been under question, preventing the development of performance-based standards for permanent paper. We conducted a general kinetic analysis to investigate the aging process of paper. A general kinetic model is proposed to describe the depolymerization of cellulose. Experimentally it was shown that in the case of aging, cellulose degradation follows classic first-order kinetics as a special case of our general kinetic model. The Arrhenius equation was critically re-examined for the case of a multiple reaction system. It was shown analytically that the Arrhenius equation is still applicable when certain conditions are met. This was convincingly supported by experimental results. We also analysed the dependence of the degradation rate on the moisture content and hydrogen ion concentration. By conducting systematic experiments on these two factors, a general and quantitative relationship was established to explain the contribution of each factor and their interactions. Finally, based on this kinetic analysis, the effects of storage conditions on the life expectancy of paper were estimated.
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  • 92
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    Journal of solution chemistry 3 (1974), S. 881-887 
    ISSN: 1572-8927
    Schlagwort(e): Binary aqueous mixtures ; solubilities ; kinetics
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract A treatment which predicts the solubilities of gases in solvent mixtures is examined in the context of the analysis of kinetic data for reactions in aqueous mixtures. The treatment is qualitatively successful to some extent in resolving the effects of changes in the initial state of the reacting substrate in the activation parameters.
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  • 93
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    Journal of inorganic and organometallic polymers and materials 8 (1998), S. 111-117 
    ISSN: 1572-8870
    Schlagwort(e): Organosiloxane ; kinetics ; poly(phenylmethylsiloxane) ; catalyst ; anionic ; ring-opening
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract It is well known that the rate of polymerization for an anionic mechanism is dependent on the ability of the bulk material or solvent system to disassociate the ion pair at the propagating chain end. In the anionic ring-opening polymerization of cyclic organosiloxanes in particular, the larger and softer the counter ion, the more rapidly the reaction proceeds. A recently developed phosphazene initiator system provides a large, soft counter ion relative to other traditional initiators used for the polymerization of poly(dimethylsiloxane) (PDMS). This novel initiator system was used in this investigation for the ring-opening polymerization of tetraphenyltetramethylcyclotetrasiloxane (P4) and the reaction kinetics under bulk and solution conditions were investigated. The new initiator system showed a dramatic increase in the rate of polymerization over the conventional potassium hydroxide-catalyzed system. Furthermore, this initiator was sufficiently reactive to be useful for the ring-opening polymerization of P4 at 293 K.
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  • 94
    ISSN: 1572-8900
    Schlagwort(e): Cellulose ; alkaline degradation ; peeling off ; degree of polymerization ; kinetics ; (gluco)isosaccharinic acid
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Energietechnik , Maschinenbau
    Notizen: Abstract The degradation of cellulosic materials, differing mainly in the degree of polymerization and the number of reducing end groups, was studied under the alkaline conditions similar to those existing in a cementitious repository for low- and intermediate-level radioactive waste (pH 13.3, T = 25°C). The kinetics of alkaline degradation (peeling-off reaction) were studied and the data analyzed by the model of Haas et al. [13]. The observed kinetic parameters for the propagation reaction and overall stopping reaction were compared with literature data. Although measured under different experimental conditions, literature data and data from this study show a consistent picture. Differences in the extent of degradation observed for the different cellulosic materials could be satisfactorily explained by differences in reducing end group content and, consequently, by differences in the degrees of polymerization. Besides the number of reducing end groups, the degree of amorphousness also plays an important role. The main degradation products formed under the experimental conditions used are α- and β-(gluco)isosaccharinic acid. This is in agreement with many other studies on alkaline degradation of cellulose. The two isomers are formed in roughly equal amounts.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 95
    Digitale Medien
    Digitale Medien
    Springer
    Journal of solution chemistry 15 (1986), S. 221-229 
    ISSN: 1572-8927
    Schlagwort(e): Ultrasonics ; kinetics ; aqueous solution ; triethylene glycol monobutyl ether
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The ultrasonic absorption from 6.5 to 220 MHz and velocities at 2.5 MHz have been measured in aqueous solution of triethylene glycol monobutyl ether as a function of concentration at 25°C. A single relaxational excess absorption, observed from 0.60 to 2.5 mol-dm−3, is attributed to a perturbation of an equilibrium associated with solute-solvent interaction. Rate constants for the forward and reverse processes have been determined from the concentration dependence of the relaxation frequency, and the influence on the water structure by an addition of the solute has been considered. Solution densities were also measured in order to obtain the expansivity of the solution. The standard volume and enthalpy changes of the reaction have been estimated from the concentration dependence of the maximum excess absorption per wave length. A linear relationship between the number of oxyethylene groups and the free energy change between bonded water and nonbonded water is established.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 96
    Digitale Medien
    Digitale Medien
    Springer
    Topics in catalysis 5 (1998), S. 133-147 
    ISSN: 1572-9028
    Schlagwort(e): NMR ; catalysis ; high pressure ; dynamic equilibria ; magnetization transfer ; sapphire tube ; gas phase ; kinetics
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract High resolution NMR techniques are applicable to a variety of aspects of catalysis. Methods for studying homogeneously-catalyzed systems under high gas pressure are described along with approaches for obtaining mechanistic and dynamic information. Many of the same techniques may be applied to heterogeneous catalysis by following the reaction chemistry by gas phase NMR.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 97
    Digitale Medien
    Digitale Medien
    Springer
    Entomologia experimentalis et applicata 59 (1991), S. 79-85 
    ISSN: 1570-7458
    Schlagwort(e): Wheat ; Triticum aestivum ; cereals ; Rhopalosiphum padi ; Aphididae ; barley yellow dwarf virus ; hydroxamic acids ; DIMBOA
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie
    Notizen: Abstract 2,4-Dihydroxy-7-methoxy-1,4-benzoxazin-3-one (DIMBOA), a hydroxamic acid (Hx) occurring in wheat, was shown to deter feeding by the aphid Rhopalosiphum padi (L.), and to reduce BYDV transmission to the plant. Dual choice tests with wheat leaves showed the preferential settlement of aphids on leaves with lower levels of DIMBOA. Electric monitoring of aphid feeding behaviour showed that in seedlings with higher DIMBOA levels fewer aphids reached the phloem and they needed longer times to contact a phloem vessel than in those with lower levels. When aphids carrying BYDV were allowed to feed on wheat cultivars with different DIMBOA levels, fewer plants were infected with BYDV in the higher DIMBOA cultivars than in the lower ones. Preliminary field experiments showed a tendency for wheat cultivars with higher Hx levels to be more tolerant to infection by BYDV than lower Hx level ones.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 98
    ISSN: 1572-9028
    Schlagwort(e): nonlinear temperature behavior ; Eyring plot ; modified Eyring plot ; selectivity ; selection process ; enantioselectivity ; selection level ; isoinversion principle ; isoinversion temperature ; inversion temperature ; kinetics ; catalysis ; asymmetric hydrogenation ; dihydroxylation ; cocyclization
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The influence of the temperature on selectivity is described under special consideration of nonlinearities in the corresponding modified Eyring plots. Reasons for the experimentally well-known behavior are discussed. Furthermore, the conditions for nonlinear temperature behavior are quantified and a concept is described which allows the determination of the temperature dependence of a single reaction pathway in a selection process.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 99
    Digitale Medien
    Digitale Medien
    Springer
    Topics in catalysis 1 (1994), S. 305-314 
    ISSN: 1572-9028
    Schlagwort(e): non-Langmuir ; kinetics ; non-linear dynamics ; oscillations ; chaos ; self-organization
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The kinetics of a catalytic reaction is frequently formulated in terms of simple concepts of the Langmuir type. Apart from limitations arising from the non-uniformity of the catalyst's surface and from the coverage dependence of the rate “constants”, several other complications may come into play. These may arise on the “quantum level” where energy flow between the various degrees of freedom may cause failure of simple transition state theory, as well as on the “continuum level” where formulation of rate equations in terms of coupled non-linear differential equations may give rise to a rich scenario of spatio-temporal self-organization, including kinetic oscillations, chaos, and formation of concentration patterns. Several of these phenomena are illustrated by selected examples.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 100
    Digitale Medien
    Digitale Medien
    Springer
    Topics in catalysis 11-12 (2000), S. 327-333 
    ISSN: 1572-9028
    Schlagwort(e): hydrodenitrogenation ; toluidine ; methylcyclohexylamine ; kinetics ; nickel-promoted molybdenum sulphide
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The hydrodenitrogenation (HDN) of o-toluidine and its reaction intermediates was studied over a NiMo/γ-Al2O3 catalyst. The kinetics of the HDN of methylcyclohexylamine and of the hydrogenation of cyclohexene were also studied. Hydrogenation of o-toluidine alone produces methylcyclohexene and methylcyclohexane. When a sufficient quantity of cyclohexene is added during the HDN of toluidine, methylcyclohexylamine, the first intermediate in the hydrogenation of toluidine, becomes detectable. Because of its strong adsorption constant and high rate constant for reacting further to methylcyclohexene and methylcyclohexane, methylcyclohexylamine is not observed in the HDN of toluidine. Adding cyclohexene decreases the adsorption of methylcyclohexylamine, thus enabling its detection. The rate and adsorption constants of methylcyclohexylamine and cyclohexene in the HDN of methylcyclohexylamine were calculated by fitting the kinetic data to a Langmuir–Hinshelwood equation. A two-site model was used to describe the surface reactions, with one site for the methylcyclohexylamine reactions and the other for the cyclohexene reaction.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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