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  • 1
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    Cambridge University Press
    In:  Cambridge, 342 pp., Cambridge University Press, vol. 13, no. XVI:, pp. 227-235, (ISBN 3-540-43528-X)
    Publication Date: 1983
    Keywords: Textbook of geophysics ; Seismology ; Seismics (controlled source seismology) ; Waves
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  • 2
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    Cambridge University Press
    In:  Cambridge, 416 pp., Cambridge University Press, vol. 271, no. ALEX(01)-FR-77-01, AFTAC Contract F08606-76-C-0025, pp. 329, (ISBN: 0-08-043649-8)
    Publication Date: 1997
    Keywords: FractureT ; Chaotic behaviour ; Non-linear effects ; SOC ; Seismicity ; cracks and fractures (.NE. fracturing) ; Earthquake precursor: prediction research ; Handbook of geophysics
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  • 3
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    Cambridge University Press
    In:  Cambridge, Cambridge University Press, vol. 271, no. ALEX(01)-FR-77-01, AFTAC Contract F08606-76-C-0025, pp. 329, (ISBN: 0-08-043649-8)
    Publication Date: 1992
    Keywords: FractureT ; Chaotic behaviour ; Handbook of geophysics ; Handbook of geology
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  • 4
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    Cambridge University Press
    In:  New York, 475 pp., Cambridge University Press, vol. 26, no. ALEX(01)-FR-77-01, AFTAC Contract F08606-76-C-0025, pp. 329, (ISBN 0-521-62434-7 hc (0-521-62478-9 pb))
    Publication Date: 1999
    Keywords: Textbook of geophysics ; Seismology ; traditional ; Udias
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  • 5
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    Cambridge University Press
    In:  Cambridge, Cambridge University Press, vol. 10, no. 1, pp. 1-40, (ISBN: 0-08-040286-0)
    Publication Date: 1922
    Keywords: Textbook of mathematics
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  • 6
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    Cambridge University Press
    In:  Cambridge, UK, Cambridge University Press, vol. 10, no. 1, pp. 1-40, (ISBN 0-521-84678-1 (550 pp.))
    Publication Date: 2005
    Description: ... Overall, An Introduction to Programming with Mathematica is a useful and readable book that could serve as the text for a generic programming class, a supporting text for a class on programming for geoscientists, or an introduction for experienced geoscience programmers looking for an easily readable summary of Mathematica's programming language. Experienced Mathematica programmers may find it useful as a refresher. The book's principal drawbacks are the high price of Mathematica for those who do not already have the software (although a modestly priced student version is available) and, for geoscientists in particular, a lack of relevant example problems
    Keywords: Handbook of mathematics ; computer ; algebra ; software
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  • 7
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    Cambridge University Press
    In:  A Continent Revealed - the European Geotraverse, Cambridge, Cambridge University Press, vol. 37, pp. 33-69, (ISBN 0080419208)
    Publication Date: 1992
    Keywords: Deep seismic sounding (espec. cont. crust) ; Review article ; Earth model, also for more shallow analyses ! ; European Geotraverse ; CRUST ; earth mantle ; Muller
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  • 8
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    Cambridge University Press
    In:  Cambridge, 264 pp., Cambridge University Press, vol. 42, no. 3, pp. 275-291, (ISBN: 0-444-51422-8)
    Publication Date: 1997
    Keywords: physics ; philosophy
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  • 9
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    Cambridge University Press
    In:  Cambridge, 368 pp., Cambridge University Press, vol. 159, no. 22, pp. 662-664, (ISBN 0-470-87000-1 (HB), ISBN 0-470-87001-X (PB))
    Publication Date: 1997
    Keywords: Textbook of geophysics ; Seismology ; Seismics (controlled source seismology) ; Gravimetry, Gravitation ; Geoelectrics ; Geomagnetics ; Earth tides ; Earth rotation
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  • 10
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    Cambridge University Press
    In:  New York, 260 pp., Cambridge University Press, vol. Developments in Petroleum Science vol. 15B, no. Publ. No. 12, pp. 9, (ISBN 0-521-66023-8 hc (0-521-66953-7 pb))
    Publication Date: 1999
    Keywords: Textbook of geophysics ; Seismology ; modern
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  • 11
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    Cambridge University Press
    In:  Boston, 227 pp., Cambridge University Press, vol. Developments in Petroleum Science vol. 15B, no. Publ. No. 12, pp. 9, (ISBN 0-521-66023-8 hc (0-521-66953-7 pb))
    Publication Date: 1982
    Keywords: Textbook of geophysics ; Seismics (controlled source seismology)
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  • 12
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    Cambridge University Press
    In:  Cambridge, Cambridge University Press, vol. 3, pp. 6322, (ISBN 0-521-79203-7)
    Publication Date: 1990
    Keywords: Textbook of physics ; Chaotic behaviour ; FractureT
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  • 13
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    Cambridge University Press
    In:  Cambridge, 4th Edition, 470 pp., Cambridge University Press, vol. 106, pp. 503, (ISBN 0-415-24328-9 (hb), 0-203-47128-8 (pb))
    Publication Date: 1985
    Keywords: Textbook of geophysics ; Seismology
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  • 14
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    Cambridge University Press
    In:  Cambridge, 264 pp., Cambridge University Press, vol. 42, no. 3, pp. 632 pp., (ISBN 052)
    Publication Date: 2004
    Keywords: Textbook of geophysics ; Seismology ; Wave propagation ; Ray seismics ; Anisotropy ; Acoustics ; Elasticity ; Layers ; Cagniard ; Inversion ; WKBJ ; Maslov ; Born ; Kirchhoff ; Migration of earthquakes ; Inhomogeneity ; more ; advanced ; than ; Aki ; and ; Richards ; MATLAB
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  • 15
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    Cambridge University Press
    In:  Cambridge, Cambridge University Press, vol. 34, no. 22, pp. 65-70, (ISBN 0-691-12183-4, 2005 (481 pp. + CD-ROM))
    Publication Date: 1993
    Keywords: Textbook of geophysics ; Textbook of geology ; Rock mechanics ; Physical properties of rocks ; Fracture
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  • 16
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    Cambridge University Press
    In:  Cambridge, Cambridge University Press, vol. IUGG Volume 18, no. 85, pp. 175, (3-7723-6434-9)
    Publication Date: 1971
    Keywords: Seismics (controlled source seismology) ; Textbook of geophysics ; SEModelling ; Data analysis / ~ processing
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  • 17
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    Cambridge University Press
    In:  Cambridge, 444 pp., Cambridge University Press, vol. 7, no. Publ. No. 12, pp. 127, (ISBN: 0 521 52046 0 (pb); ISBN: 0 521 81730 7 (hb))
    Publication Date: 2003
    Description: ... Pujol's book differs from the others in its purely theoretical approach to the generation and propagation of seismic waves. The author aims to fill a gap between the advanced books and the introductory ones, providing a complete derivation of the mathematical developments. ... One does not have to look for proofs elsewhere.
    Keywords: Textbook of geophysics ; Seismology ; Elasticity ; Source ; Wave propagation ; theory
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  • 18
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    Cambridge University Press
    In:  Boston, 227 pp., Cambridge University Press, vol. Developments in Petroleum Science vol. 15B, no. Publ. No. 12, pp. 9, (ISBN 0-521-66023-8 hc (0-521-66953-7 pb))
    Publication Date: 1983
    Keywords: Textbook of geophysics ; Seismics (controlled source seismology)
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  • 19
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    Cambridge University Press
    In:  New York, Cambridge University Press, vol. 4, no. 1, pp. 1-40, (ISBN 0-87071-024-9)
    Publication Date: 1997
    Keywords: Earthquake ; Volcanology ; Earthquake precursor: prediction research ; Earthquake hazard ; Tsunami(s)
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  • 20
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    Cambridge University Press
    In:  New York, Cambridge University Press, vol. 283, no. 2, pp. 15-17, (ISBN: 3-7643-7044-0)
    Publication Date: 1987
    Keywords: Statistical investigations ; Handbook of mathematics ; Data analysis / ~ processing ; Borehole breakouts ; circular ; angular ; directional ; Staatsbibl. ; B: ; 779785
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  • 21
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    Cambridge University Press
    In:  Cambridge, Cambridge University Press, vol. 7, no. Publ. No. 12, pp. 127, (ISBN: 0521839270, 520 p.)
    Publication Date: 2005
    Description: Fundamentals of Structural Geology provides a new framework for the investigation of geological structures by integrating field mapping and mechanical analysis. Assuming a basic knowledge of physical geology, introductory calculus and physics, it emphasizes the observational data, modern mapping technology, principles of continuum mechanics, and the mathematical and computational skills, necessary to quantitatively map, describe, model, and explain deformation in Earth's lithosphere. By starting from the fundamental conservation laws of mass and momentum, the constitutive laws of material behavior, and the kinematic relationships for strain and rate of deformation, the authors demonstrate the relevance of solid and fluid mechanics to structural geology. This book offers a modern quantitative approach to structural geology for advanced students and researchers in structural geology and tectonics. It is supported by a website hosting images from the book, additional colour images, student exercises and MATLAB scripts. Solutions to the exercises are available to instructors
    Keywords: Structural geology ; Textbook of geology ; MATLAB ; scripts ; Tectonics ; Lithosphere
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  • 22
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    Cambridge University Press
    In:  Cambridge, Cambridge University Press, vol. 7, no. Publ. No. 12, pp. 127, (ISBN 1-58488-323-5)
    Publication Date: 1986
    Keywords: Inversion ; Handbook of mathematics
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  • 23
    Publication Date: 2020-02-06
    Description: Environmental histories that span the last full glacial cycle and are representative of regional change in Australia are scarce, hampering assessment of environmental change preceding and concurrent with human dispersal on the continent ca. 47,000 years ago. Here we present a continuous 150,000-year record offshore south-western Australia and identify the timing of two critical late Pleistocene events: wide-scale ecosystem change and regional megafaunal population collapse. We establish that substantial changes in vegetation and fire regime occurred B70,000 years ago under a climate much drier than today. We record high levels of the dung fungus Sporormiella, a proxy for herbivore biomass, from 150,000 to 45,000 years ago, then a marked decline indicating megafaunal population collapse, from 45,000 to 43,100 years ago, placing the extinctions within 4,000 years of human dispersal across Australia. These findings rule out climate change, and implicate humans, as the primary extinction cause.
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  • 24
    Publication Date: 2019-07-19
    Description: Slope failure like in the Hinlopen/Yermak Megaslide is one of the major geohazards in a changing Arctic environment. We analysed hydroacoustic and 2D high-resolution seismic data from the apparently intact continental slope immediately north of the Hinlopen/Yermak Megaslide for signs of past and future instabilities. Our new bathymetry and seismic data show clear evidence for incipient slope instability. Minor slide deposits and an internally-deformed sedimentary layer near the base of the gas hydrate stability zone imply an incomplete failure event, most probably about 30000 years ago, contemporaneous to or shortly after the Hinlopen/Yermak Megaslide. An active gas reservoir at the base of the gas hydrate stability zone demonstrate that over-pressured fluids might have played a key role in the initiation of slope failure at the studied slope, but more importantly also for the giant HYM slope failure. To date, it is not clear, if the studied slope is fully preconditioned to fail completely in future or if it might be slowly deforming and creeping at present. We detected widespread methane seepage on the adjacent shallow shelf areas not sealed by gas hydrates.
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  • 25
    Publication Date: 2019-02-01
    Description: Polymetallic nodule mining at abyssal depths in the Clarion Clipperton Fracture Zone (Eastern Central Pacific) will impact one of the most remote and least known environments on Earth. Since vast areas are being targeted by concession holders for future mining, large-scale effects of these activities are expected. Hence, insight into the fauna associated with nodules is crucial to support effective environmental management. In this study video surveys were used to compare the epifauna from sites with contrasting nodule coverage in four license areas. Results showed that epifaunal densities are more than two times higher at dense nodule coverage (〉25 versus ≤10 individuals per 100 m2), and that taxa such as alcyonacean and antipatharian corals are virtually absent from nodule-free areas. Furthermore, surveys conducted along tracks from trawling or experimental mining simulations up to 37 years old, suggest that the removal of epifauna is almost complete and that its full recovery is slow. By highlighting the importance of nodules for the epifaunal biodiversity of this abyssal area, we urge for cautious consideration of the criteria for determining future preservation zones.
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  • 26
    Publication Date: 2020-06-18
    Description: The Ontong Java and Manihiki oceanic plateaus are believed to have formed through high-degree melting of a mantle plume head. Boninite-like, low-Ti basement rocks at Manihiki, however, imply a more complex magma genesis compared with Ontong Java basement lavas that can be generated by ∼30% melting of a primitive mantle source. Here we show that the trace element and isotope compositions of low-Ti Manihiki rocks can best be explained by re-melting of an ultra-depleted source (possibly a common mantle component in the Ontong Java and Manihiki plume sources) re-enriched by ≤1% of an ocean-island-basalt-like melt component. Unlike boninites formed via hydrous flux melting of refractory mantle at subduction zones, these boninite-like intraplate rocks formed through adiabatic decompression melting of refractory plume material that has been metasomatized by ocean-island-basalt-like melts. Our results suggest that caution is required before assuming all Archaean boninites were formed in association with subduction processes.
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  • 27
    Publication Date: 2020-06-18
    Description: Tectonically induced changes in oceanic seaways had profound effects on global and regional climate during the Late Neogene. The constriction of the Central American Seaway reached a critical threshold during the early Pliocene ~4.8–4 million years (Ma) ago. Model simulations indicate the strengthening of the Atlantic Meridional Overturning Circulation (AMOC) with a signature warming response in the Northern Hemisphere and cooling in the Southern Hemisphere. Subsequently, between ~4–3 Ma, the constriction of the Indonesian Seaway impacted regional climate and might have accelerated the Northern Hemisphere Glaciation. We here present Pliocene Atlantic interhemispheric sea surface temperature and salinity gradients (deduced from foraminiferal Mg/Ca and stable oxygen isotopes, δ18O) in combination with a recently published benthic stable carbon isotope (δ13C) record from the southernmost extent of North Atlantic Deep Water to reconstruct gateway-related changes in the AMOC mode. After an early reduction of the AMOC at ~5.3 Ma, we show in agreement with model simulations of the impacts of Central American Seaway closure a strengthened AMOC with a global climate signature. During ~3.8–3 Ma, we suggest a weakening of the AMOC in line with the global cooling trend, with possible contributions from the constriction of the Indonesian Seaway.
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  • 28
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    Cambridge University Press
    In:  Journal of the Marine Biological Association of the United Kingdom, 64 . pp. 573-579.
    Publication Date: 2020-07-16
    Description: Males of Eledone cirrhosa grow to a size little over 600 g and normally have well-developed, and presumably active, reproductive organs from about 200 g upwards. Total weight of the genital bag is well correlated with total body weight (r= 0·906). Growth of the testis precedes that of the spermatophoric sac, and the size of neither of these reproductive components is predictable from body weight. The sizes of these organs and the estimated number and length of stored spermatophores are given for 100 g intervals of total body weight. No evidence was obtained for a seasonal trend in male maturity.
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  • 29
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    Cambridge University Press
    In:  Journal of the Marine Biological Association of the United Kingdom, 66 . pp. 855-865.
    Publication Date: 2020-07-16
    Description: A survey of the ecology of the octopus Eledone cirrhosa in Scottish waters is compiled from structured interviews with fishermen, records of occurrence in traps (for lobster and crab), and a research vessel survey. This species is widespread and common throughout the inshore waters covered by fishing activity (shoreline- 140 m) on bottom types ranging through rock, stones, sand and mud. It is caught in all months of the year but is especially common inshore in the summer (July-September) and further offshore on trawling grounds in October-December. The octopus is a normal and regular predator of large Crustacea (Hotnarus, Nephrops, Cancer) caught in commercial traps but gut contents yield little identifiable dietary remains.
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  • 30
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    Cambridge University Press
    In:  Geological Magazine, 140 (3). pp. 245-252.
    Publication Date: 2020-07-31
    Description: Markedly different cooling histories for the hanging- and footwall of theVari detachment on Syros and Tinos islands, Greece, are revealed by zircon and apatite fission-track data. The Vari/Akrotiri unit in the hangingwall cooled slowly at rates of 5–15 ◦CMyr−1 since Late Cretaceous times. Samples from the Cycladic blueschist unit in the footwall of the detachment on Tinos Island have a mean zircon fission-track age of 10.0±1.0 Ma, which together with a published mean apatite fission-track age of 9.4±0.5 Ma indicates rapid cooling at rates of at least ∼60 ◦CMyr−1. We derive a minimum slip rate of ∼6.5 kmMyr−1 and a displacement of 〉∼20 km and propose that the development of the detachment in the thermally softened magmatic arc aided fast displacement. Intra-arc extension accomplished the final ∼6–9 km of exhumation of the Cycladic blueschists from ∼60 km depth. The fast-slipping intra-arc detachments did not cause much exhumation, but were important for regionalscale extension and the formation of the Aegean Sea.
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  • 31
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    Cambridge University Press
    In:  Journal of the Marine Biological Association of the United Kingdom, 70 (04). pp. 829-840.
    Publication Date: 2020-07-16
    Description: Serological methods for prey identification have been applied to detection of residues ofsandeel (Ammodytidae) protein in faeces of common seals (Phoca vitulina) and grey seals(Halichoerus grypus) from the Moray Firth, north-east Scotland. Antisera raised to muscleprotein from Ammodytes marinus were evaluated by testing their reactions with proteinextracts made from a range of North Sea fish species and protein residues in in vitro digestates,seal digestive tracts and seal faeces. It was concluded that, using fused rocketimmuno-electrophoresis, linkage of precipitin peaks from unknown samples with peaksfrom standard sandeel extract was a reliable indicator of the presence of sandeel in theunknown sample. Seasonal variation in the incidence of sandeels in common seal diet in theMoray Firth was examined by identifying otoliths, bones, and proteins, and all threemethods indicated that sandeels occurred in the majority of samples tested in the summer,but were less important during the winter. Proteins were detected in fewer samples thanotoliths, particularly in February and March. Possible reasons for this difference arediscussed. Serological identification of sandeel proteins is potentially applicable to dietarystudies on all marine predators.
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  • 32
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    Cambridge University Press
    In:  Journal of the Marine Biological Association of the United Kingdom, 72 (02). p. 271.
    Publication Date: 2020-07-16
    Description: Age and growth were estimated in the European squid, Loligo vulgaris, by examining growth increments in the statoliths of 203 specimens collected from off the French Mediterranean coast. Length and increment data were analyzed assuming that the increments were formed daily. The relationships between age and length showed that: growth rate varied considerably among individuals; growth was double exponential; the squids grew on average to 240 mm ML at 240 d from hatching, with a maximum of 350 mm at 240 d; the life span is probably about one year.
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  • 33
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    Cambridge University Press
    In:  Journal of the Marine Biological Association of the United Kingdom, 72 (03). p. 543.
    Publication Date: 2020-07-16
    Description: Some of the limits to the use of serology to identify prey species in the digestive tracts of cephalopods have been evaluated. Cuttlefish, Sepia officinalis, were given meals of krill slurry (Euphausia superba). Protein extracts of contents from four regions of the digestive tract, stomach, caecum, digestive gland and intestine, were tested for prey antigenicity. Digestion times (loss of antigenicity) ranged from 1 to 8 h depending on sampling site. Stomach and caecum emptied rapidly, but meal antigenicity persisted longer in the digestive gland. The Sepia experiments provide a basis for interpretation of results from natural predation by cephalopods).
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  • 34
    Publication Date: 2020-02-06
    Description: Enhanced atmospheric input of dust-borne nutrients and minerals to the remote surface ocean can potentially increase carbon uptake and sequestration at depth. Nutrients can enhance primary productivity, and mineral particles act as ballast, increasing sinking rates of particulate organic matter. Here we present a two-year time series of sediment trap observations of particulate organic carbon flux to 3,000 m depth, measured directly in two locations: the dust-rich central North Atlantic gyre and the dust-poor South Atlantic gyre. We find that carbon fluxes are twice as high and a higher proportion of primary production is exported to depth in the dust-rich North Atlantic gyre. Low stable nitrogen isotope ratios suggest that high fluxes result from the stimulation of nitrogen fixation and productivity following the deposition of dust-borne nutrients. Sediment traps in the northern gyre also collected intact colonies of nitrogen-fixing Trichodesmium species. Whereas ballast in the southern gyre is predominantly biogenic, dust-derived mineral particles constitute the dominant ballast element during the enhanced carbon fluxes in the northern gyre. We conclude that dust deposition increases carbon sequestration in the North Atlantic gyre through the fertilization of the nitrogen-fixing community in surface waters and mineral ballasting of sinking particles
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  • 35
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    Cambridge University Press
    In:  Journal of the Marine Biological Association of the United Kingdom, 50 (01). pp. 53-64.
    Publication Date: 2020-07-16
    Description: Spirula spirula has stimulated considerable interest since it was first discovered. It is a member of one of the two genera of sepioids to frequent oceanic water (the other being Heteroteuthis); it has a unique spiral shell which acts as a buoyancy mechanism and can withstand considerable pressure (Denton, Gilpin-Brown & Howarth, 1967); and, until the capture by the Danish Oceanographical expeditions it was considered very rare, only 12 specimens having been captured. The Dana expeditions caught 193 individuals from 1909 to 1931 and these were described by Kerr (1931) and Bruun (1943,1955). Most of these were caught in the waters around the Canary Islands of the North Atlantic. Bruun (1943) arranged the specimens according to month and size and claimed that two size groups could be distinguished. The specimens were taken over a wide geographical area, in several years and during the months of February (1 specimen), March (40), April (3), May (8), June (1), August (1) and October (23). His conclusion concerning growth depends entirely upon his decision to split the March sample into two year-groups; those above 1.9 cm in ventral mantle length he put in a separate year-class to those below 1.9 cm in ventral mantle length. This division was arbitrary and, one suspects, based on a belief that a one-year life-span was likely. Clearly the growth of Spirula requires further study based on a larger collection and the present paper is an attempt to fulfil this need.
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  • 36
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    Cambridge University Press
    In:  Journal of the Marine Biological Association of the United Kingdom, 33 (02). pp. 515-536.
    Publication Date: 2020-09-09
    Description: During 1950, the Common Octopus (Octopus vulgaris Lamarck) was to be found along the south coast of England in greater numbers than at any time since Garstang (1900) reported on the ‘plague’ on the coasts of Devon and Cornwall in 1899–1900. In earlier papers (Rees, 1950, 1952) the distribution of the octopus in our northern waters was reviewed, and it was demonstrated that this species is an immigrant which breeds on our south coast only rarely. It reaches these coasts by being brought there as a planktonic larva by the water circulation in the English Channel and by migrations of the adult. The most important factor in controlling the movements of the adult, however, might be expected to be the water temperature in the English Channel—where the species is at the northern limit of its breeding range and might therefore be extremely sensitive to slight changes in temperature.
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  • 37
    Publication Date: 2020-02-06
    Description: Folate-mediated one-carbon metabolism (FOCM) is an interconnected network of metabolic pathways, including those required for the de novo synthesis of dTMP and purine nucleotides and for remethylation of homocysteine to methionine. Mouse models of folate-responsive neural tube defects (NTDs) indicate that impaired de novo thymidylate (dTMP) synthesis through changes in SHMT expression is causative in folate-responsive NTDs. We have created a hybrid computational model comprised of ordinary differential equations and stochastic simulation. We investigated whether the de novo dTMP synthesis pathway was sensitive to perturbations in FOCM that are known to be associated with human NTDs. This computational model shows that de novo dTMP synthesis is highly sensitive to the common MTHFR C677T polymorphism and that the effect of the polymorphism on FOCM is greater in folate deficiency. Computational simulations indicate that the MTHFR C677T polymorphism and folate deficiency interact to increase the stochastic behavior of the FOCM network, with the greatest instability observed for reactions catalyzed by serine hydroxymethyltransferase (SHMT). Furthermore, we show that de novo dTMP synthesis does not occur in the cytosol at rates sufficient for DNA replication, supporting empirical data indicating that impaired nuclear de novo dTMP synthesis results in uracil misincorporation into DNA.
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  • 38
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    Cambridge University Press
    In:  Journal of the Marine Biological Association of the United Kingdom, 73 (03). p. 571.
    Publication Date: 2020-07-16
    Description: The stomachsof 23 striped dolphins (Stenella coeruleoalba Meyen, 1833, Cetacea), stranded along the Ligurian coast (western Mediterranean Sea), contained 32 species of cephalopods, crustaceans and fishes, totalling an estimated 2,723 prey specimens representing about 36 kg in weight. Cephalopods and bony fishes were equally important in the diet (50%). Todarodes sagittatus (34.5%) and Micromesistius poutassou (25.9%) were found to be the most important food species. Other species belonging to six cephalopod families, three crustacean families and nine bony fish families, contributed to the diet with variable numbers, weights, and occurrences, demonstrating the opportunistic character of striped dolphin feeding.
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  • 39
    Publication Date: 2021-04-23
    Description: Accurate pH measurements in polar waters and sea ice brines require pH indicator dyes characterized at near-zero and below-zero temperatures and high salinities. We present experimentally determined physical and chemical characteristics of purified meta-Cresol Purple (mCP) pH indicator dye suitable for pH measurements in seawater and conservative seawater-derived brines at salinities (S) between 35 and 100 and temperatures (T) between their freezing point and 298.15 K (25 °C). Within this temperature and salinity range, using purified mCP and a novel thermostated spectrophotometric device, the pH on the total scale (pHT) can be calculated from direct measurements of the absorbance ratio R of the dye in natural samples as pHT=−log(kT2e2)+log(R−e11−Re3e2) Based on the mCP characterization in these extended conditions, the temperature and salinity dependence of the molar absorptivity ratios and − log(kT2e2) of purified mCP is described by the following functions: e1 = −0.004363 + 3.598 × 10−5T, e3/e2 = −0.016224 + 2.42851 × 10−4T + 5.05663 × 10−5(S − 35), and − log(kT2e2) = −319.8369 + 0.688159 S −0.00018374 S2 + (10508.724 − 32.9599 S + 0.059082S2) T−1 + (55.54253 − 0.101639 S) ln T −0.08112151T. This work takes the characterisation of mCP beyond the currently available ranges of 278.15 K ≤ T ≤ 308.15 K and 20 ≤ S ≤ 40 in natural seawater, thereby allowing high quality pHT measurements in polar systems.
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  • 40
    Publication Date: 2020-07-16
    Description: Microbial mats collected at cold methane seeps in the Black Sea carry out anaerobic oxidation of methane (AOM) to carbon dioxide using sulfate as the electron acceptor. These mats, which predominantly consist of sulfate-reducing bacteria and archaea of the ANME-1 and ANME-2 type, contain large amounts of proteins very similar to methyl-coenzyme M reductase from methanogenic archaea. Mass spectrometry of mat samples revealed the presence of two nickel-containing cofactors in comparable amounts, one with the same mass as coenzyme F430 from methanogens (m/z = 905) and one with a mass that is 46 Da higher (m/z = 951). The two cofactors were isolated and purified, and their constitution and absolute configuration were determined. The cofactor with m/z = 905 was proven to be identical to coenzyme F430 from methanogens. For the m/z = 951 species, high resolution ICP-MS pointed to F430 + CH2S as the molecular formula, and LA-ICP-SF MS finally confirmed the presence of one sulfur atom per nickel. Esterification gave two stereoisomeric pentamethyl esters with m/z = 1021, which could be purified by reverse phase HPLC and were subjected to comprehensive NMR analysis, allowing determination of their constitution and configuration as (172S)−172-methylthio-F430 pentamethyl ester and (172R)−172-methylthio-F430 pentamethyl ester. The corresponding diastereoisomeric pentaacids could also be separated by HPLC and were correlated to the esters via mild hydrolysis of the latter. Equilibration of the pentaacids under acid catalysis showed that the (172S) isomer is the naturally occurring albeit thermodynamically less stable one. The more stable (172R) isomer (80% at equilibrium) is an isolation artifact generated under the acidic conditions necessary for the isolation of the cofactors from the calcium carbonate-encrusted mats.
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  • 41
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    Cambridge University Press
    In:  Journal of the Marine Biological Association of the United Kingdom, 80 . pp. 249-257.
    Publication Date: 2020-07-16
    Description: A new species of terebellid polychaete, Lanice arakani sp. nov., is described from two specimens collected in deep water at seamounts of the west Pacific by the submersible `JAGO', and comparisons are made with the established species of the genus. Special reference is given to the morphology of the worm's sediment tube and in situ observations.
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  • 42
    Publication Date: 2020-06-18
    Description: Paleo-climate records and geodynamic modelling indicate the existence of complex interactions between glacial sea level changes, volcanic degassing and atmospheric CO2, which may have modulated the climate system's descent into the last ice age. Between ∼85 and 70 kyr ago, during an interval of decreasing axial tilt, the orbital component in global temperature records gradually declined, while atmospheric CO2, instead of continuing its long-term correlation with Antarctic temperature, remained relatively stable. Here, based on novel global geodynamic models and the joint interpretation of paleo-proxy data as well as biogeochemical simulations, we show that a sea level fall in this interval caused enhanced pressure-release melting in the uppermost mantle, which may have induced a surge in magma and CO2 fluxes from mid-ocean ridges and oceanic hotspot volcanoes. Our results reveal a hitherto unrecognized negative feedback between glaciation and atmospheric CO2 predominantly controlled by marine volcanism on multi-millennial timescales of ∼5,000-15,000 years.
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  • 43
    Publication Date: 2017-11-20
    Description: Marine methane hydrate in sands has huge potential as an unconventional gas resource; however, no field test of their production potential had been conducted. Here, we report the world’s first offshore methane hydrate production test conducted at the eastern Nankai Trough and show key findings toward future commercial production. Geological analysis indicates that hydrate saturation reaches 80% and permeability in the presence of hydrate ranges from 0.01 to 10 mdarcies. Permeable (1–10 mdarcies) highly hydrate-saturated layers enable depressurization-induced gas production of approximately 20,000 Sm3/D with water of 200 m3/D. Numerical analysis reveals that the dissociation zone expands laterally 25 m at the front after 6 days. Gas rate is expected to increase with time, owing to the expansion of the dissociation zone. It is found that permeable highly hydrate-saturated layers increase the gas–water ratio of the production fluid. The identification of such layers is critically important to increase the energy efficiency and the technical feasibility of depressurization-induced gas production from hydrate reservoirs.
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  • 44
    Publication Date: 2020-06-18
    Description: High primary productivity in the equatorial Atlantic and Pacific oceans is one of the key features of tropical ocean biogeochemistry and fuels a substantial flux of particulate matter towards the abyssal ocean. How biological processes and equatorial current dynamics shape the particle size distribution and flux, however, is poorly understood. Here we use high-resolution size-resolved particle imaging and Acoustic Doppler Current Profiler data to assess these influences in equatorial oceans. We find an increase in particle abundance and flux at depths of 300 to 600 m at the Atlantic and Pacific equator, a depth range to which zooplankton and nekton migrate vertically in a daily cycle. We attribute this particle maximum to faecal pellet production by these organisms. At depths of 1,000 to 4,000 m, we find that the particulate organic carbon flux is up to three times greater in the equatorial belt (1° S–1° N) than in off-equatorial regions. At 3,000 m, the flux is dominated by small particles less than 0.53 mm in diameter. The dominance of small particles seems to be caused by enhanced active and passive particle export in this region, as well as by the focusing of particles by deep eastward jets found at 2° N and 2° S. We thus suggest that zooplankton movements and ocean currents modulate the transfer of particulate carbon from the surface to the deep ocean.
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  • 45
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    Cambridge University Press
    In:  Geological Magazine, 64 (6). pp. 263-275.
    Publication Date: 2020-07-31
    Description: In a recent paper I stated that the hypothesis of a continuously cooling earth had “consistently failed to lead to any adequate explanations of fissure eruptions and other volcanic and tension phenomena, mountain-building processes and their distribution in time and space, and the alternation of marine transgressions and recessions”. It seems to be desirable that I should further justify this sweeping integration of objections, for Dr. Harold Jeffreys, who has actively explored the consequences of this theory during recent years, takes exception to my discouraging view of the position, and claims that the alleged failures include the principal successes of the theory. The evidence on which my summary indictment was based will be reviewed in this paper; and attention will be directed to certain other phenomena—such as the growth of geosynclines—of which the significance has not yet been generally realized. As a preliminary it will be convenient to discuss the gradually converging evidence bearing on the thickness and substructure of the continents.
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  • 46
    Publication Date: 2020-05-11
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  • 47
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    Nature Research
    In:  Nature Ecology & Evolution, 1 (11). pp. 1600-1601.
    Publication Date: 2018-01-05
    Description: Comb jellies are remarkably different from other animals. Phylogenetic analyses of broadly sampled ctenophore transcriptome data provide additional evidence that they are the sister group to all other animals and reveal details of their evolutionary relationships to each other.
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  • 48
    Publication Date: 2021-02-08
    Description: The end-Triassic is characterized by one of the largest mass extinctions in the Phanerozoic, coinciding with major carbon cycle perturbations and global warming. It has been suggested that the environmental crisis is linked to widespread sill intrusions during magmatism associated with the Central Atlantic Magmatic Province (CAMP). Sub-volcanic sills are abundant in two of the largest onshore sedimentary basins in Brazil, the Amazonas and Solimões basins, where they comprise up to 20% of the stratigraphy. These basins contain extensive deposits of carbonate and evaporite, in addition to organic-rich shales and major hydrocarbon reservoirs. Here we show that large scale volatile generation followed sill emplacement in these lithologies. Thermal modeling demonstrates that contact metamorphism in the two basins could have generated 88,000 Gt CO2. In order to constrain the timing of gas generation, zircon from two sills has been dated by the U-Pb CA-ID-TIMS method, resulting in 206Pb/238U dates of 201.477 ± 0.062 Ma and 201.470 ± 0.089 Ma. Our findings demonstrate synchronicity between the intrusive phase and the end-Triassic mass extinction, and provide a quantified degassing scenario for one of the most dramatic time periods in the history of Earth.
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  • 49
    Publication Date: 2021-03-19
    Description: Methane seepage from the upper continental slopes of Western Svalbard has previously been attributed to gas hydrate dissociation induced by anthropogenic warming of ambient bottom waters. Here we show that sediment cores drilled off Prins Karls Foreland contain freshwater from dissociating hydrates. However, our modeling indicates that the observed pore water freshening began around 8 ka BP when the rate of isostatic uplift outpaced eustatic sea-level rise. The resultant local shallowing and lowering of hydrostatic pressure forced gas hydrate dissociation and dissolved chloride depletions consistent with our geochemical analysis. Hence, we propose that hydrate dissociation was triggered by postglacial isostatic rebound rather than anthropogenic warming. Furthermore, we show that methane fluxes from dissociating hydrates were considerably smaller than present methane seepage rates implying that gas hydrates were not a major source of methane to the oceans, but rather acted as a dynamic seal, regulating methane release from deep geological reservoirs.
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  • 50
    Publication Date: 2020-02-06
    Description: Despite the importance of deep-sea corals, our current understanding of their ecology and evolution is limited due to difficulties in sampling and studying deep-sea environments. Moreover, a recent re-evaluation of habitat limitations has been suggested after characterization of deep-sea corals in the Red Sea, where they live at temperatures of above 20 °C at low oxygen concentrations. To gain further insight into the biology of deep-sea corals, we produced reference transcriptomes and studied gene expression of three deep-sea coral species from the Red Sea, i.e. Dendrophyllia sp., Eguchipsammia fistula, and Rhizotrochus typus. Our analyses suggest that deep-sea coral employ mitochondrial hypometabolism and anaerobic glycolysis to manage low oxygen conditions present in the Red Sea. Notably, we found expression of genes related to surface cilia motion that presumably enhance small particle transport rates in the oligotrophic deep-sea environment. This is the first study to characterize transcriptomes and in situ gene expression for deep-sea corals. Our work offers several mechanisms by which deep-sea corals might cope with the distinct environmental conditions present in the Red Sea As such, our data provide direction for future research and further insight to organismal response of deep-sea coral to environmental change and ocean warming.
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  • 51
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    Nature Research
    In:  Nature Chemical Biology, 13 (8). pp. 916-921.
    Publication Date: 2018-01-17
    Description: Alkylation of aromatic rings with alkyl halides is an important transformation in organic synthesis, yet an enzymatic equivalent is unknown. Here, we report that cylindrocyclophane biosynthesis in Cylindrospermum licheniforme ATCC 29412 involves chlorination of an unactivated carbon center by a novel halogenase, followed by a previously uncharacterized enzymatic dimerization reaction featuring sequential, stereospecific alkylations of resorcinol aromatic rings. Discovery of the enzymatic machinery underlying this unique biosynthetic carbon–carbon bond formation has implications for biocatalysis and metabolic engineering.
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  • 52
    Publication Date: 2020-02-06
    Description: General concepts of larval fish ecology in temperate oceans predominantly associate dispersal and survival to exogenous mechanisms such as passive drift along ocean currents. However, for tropical reef fish larvae and species in inland freshwater systems behavioural aspects of habitat selection are evidently important components of dispersal. This study is focused on larval Atlantic herring (Clupea harengus) distribution in a Baltic Sea retention area, free of lunar tides and directed current regimes, considered as a natural mesocosm. A Lorenz curve originally applied in socio-economics to describe demographic income distribution was adapted to a 20 year time-series of weekly larval herring distribution, revealing size-dependent spatial homogeneity. Additional quantitative sampling of distinct larval development stages across pelagic and littoral areas uncovered a loop in habitat use during larval ontogeny, revealing a key role of shallow littoral waters. With increasing rates of coastal change, our findings emphasize the importance of the littoral zone when considering reproduction of pelagic, ocean-going fish species; highlighting a need for more sensitive management of regional coastal zones.
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  • 53
    Publication Date: 2020-07-20
    Description: The guest-exchange method (or replacement) for methane production from gas hydrates has recently received attention because it can be used for both carbon dioxide sequestration and methane production. The structure of gas hydrates is maintained as a structure I (sI) hydrate while methane molecules are exchanged with carbon dioxide. In this study, CH4 + CO2 mixed gas hydrates were examined under terahertz light at various temperatures to simulate CH4–CO2 exchange reactions. Each gas hydrate composition examined was a representative composition at each step of the exchange reaction. The molecular composition was also accurately analyzed by gas chromatography. Refractive indices calculated by the terahertz time-domain spectroscopy (THz-TDS) of gas hydrate samples were correlated to the guest composition, and this novel method was proven to be used to quantify the extent of replacement via optical constant. Furthermore, changes in the water framework from the sI hydrate to ice using THz-TDS were investigated with an increasing temperature. Overall, this study reveals the process of guest exchange and phase transition from a gas hydrate to ice via the optical properties in the terahertz region, and it offers a powerful tool in gas hydrate production.
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  • 54
    Publication Date: 2021-04-21
    Description: Iron (Fe) is an essential micronutrient for marine microbial organisms, and low supply controls productivity in large parts of the world’s ocean. The high latitude North Atlantic is seasonally Fe limited, but Fe distributions and source strengths are poorly constrained. Surface ocean dissolved Fe (DFe) concentrations were low in the study region (〈0.1 nM) in summer 2010, with significant perturbations during spring 2010 in the Iceland Basin as a result of an eruption of the Eyjafjallajökull volcano (up to 2.5 nM DFe near Iceland) with biogeochemical consequences. Deep water concentrations in the vicinity of the Reykjanes Ridge system were influenced by pronounced sediment resuspension, with indications for additional inputs by hydrothermal vents, with subsequent lateral transport of Fe and manganese plumes of up to 250–300 km. Particulate Fe formed the dominant pool, as evidenced by 4–17 fold higher total dissolvable Fe compared with DFe concentrations, and a dynamic exchange between the fractions appeared to buffer deep water DFe. Here we show that Fe supply associated with deep winter mixing (up to 103 nmol m−2 d−1) was at least ca. 4–10 times higher than atmospheric deposition, diffusive fluxes at the base of the summer mixed layer, and horizontal surface ocean fluxes.
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  • 55
    Publication Date: 2021-05-11
    Description: The Messinian salinity crisis (MSC) - the most abrupt, global-scale environmental change since the end of the Cretaceous – is widely associated with partial desiccation of the Mediterranean Sea. A major open question is the way normal marine conditions were abruptly restored at the end of the MSC. Here we use geological and geophysical data to identify an extensive, buried and chaotic sedimentary body deposited in the western Ionian Basin after the massive Messinian salts and before the Plio-Quaternary open-marine sedimentary sequence. We show that this body is consistent with the passage of a megaflood from the western to the eastern Mediterranean Sea via a south-eastern Sicilian gateway. Our findings provide evidence for a large amplitude drawdown in the Ionian Basin during the MSC, support the scenario of a Mediterranean-wide catastrophic flood at the end of the MSC, and suggest that the identified sedimentary body is the largest known megaflood deposit on Earth.
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  • 56
    Publication Date: 2020-02-06
    Description: Our growing awareness of the microbial world’s importance and diversity contrasts starkly with our limited understanding of its fundamental structure. Despite recent advances in DNA sequencing, a lack of standardized protocols and common analytical frameworks impedes comparisons among studies, hindering the development of global inferences about microbial life on Earth. Here we present a meta-analysis of microbial community samples collected by hundreds of researchers for the Earth Microbiome Project. Coordinated protocols and new analytical methods, particularly the use of exact sequences instead of clustered operational taxonomic units, enable bacterial and archaeal ribosomal RNA gene sequences to be followed across multiple studies and allow us to explore patterns of diversity at an unprecedented scale. The result is both a reference database giving global context to DNA sequence data and a framework for incorporating data from future studies, fostering increasingly complete characterization of Earth’s microbial diversity.
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  • 57
    Publication Date: 2021-03-19
    Description: There is a strong spatial correlation between submarine slope failures and the occurrence of gas hydrates. This has been attributed to the dynamic nature of gas hydrate systems and the potential reduction of slope stability due to bottom water warming or sea level drop. However, 30 years of research into this process found no solid supporting evidence. Here we present new reflection seismic data from the Arctic Ocean and numerical modelling results supporting a different link between hydrates and slope stability. Hydrates reduce sediment permeability and cause build-up of overpressure at the base of the gas hydrate stability zone. Resulting hydro-fracturing forms pipe structures as pathways for overpressured fluids to migrate upward. Where these pipe structures reach shallow permeable beds, this overpressure transfers laterally and destabilises the slope. This process reconciles the spatial correlation of submarine landslides and gas hydrate, and it is independent of environmental change and water depth.
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  • 58
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    Cambridge University Press
    In:  Journal of Helminthology, 80 (2). pp. 199-206.
    Publication Date: 2020-07-23
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  • 59
    Publication Date: 2021-02-08
    Description: Members of the gammaproteobacterial clade SUP05 couple water column sulfide oxidation to nitrate reduction in sulfidic oxygen minimum zones (OMZs). Their abundance in offshore OMZ waters devoid of detectable sulfide has led to the suggestion that local sulfate reduction fuels SUP05-mediated sulfide oxidation in a so-called “cryptic sulfur cycle”. We examined the distribution and metabolic capacity of SUP05 in Peru Upwelling waters, using a combination of oceanographic, molecular, biogeochemical and single-cell techniques. A single SUP05 species, UThioglobus perditus, was found to be abundant and active in both sulfidic shelf and sulfide-free offshore OMZ waters. Our combined data indicated that mesoscale eddy-driven transport led to the dispersal of UT. perditus and elemental sulfur from the sulfidic shelf waters into the offshore OMZ region. This offshore transport of shelf waters provides an alternative explanation for the abundance and activity of sulfide-oxidizing denitrifying bacteria in sulfide-poor offshore OMZ waters.
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  • 60
    Publication Date: 2021-02-08
    Description: Parental experience with parasites and pathogens can lead to increased offspring resistance to infection, through a process known as transgenerational immune priming (TGIP). Broadly defined, TGIP occurs across a wide range of taxa, and can be viewed as a type of phenotypic plasticity, with hosts responding to the pressures of relevant local infection risk by altering their offspring’s immune defenses. There are ever increasing examples of both invertebrate and vertebrate TGIP, which go beyond classical examples of maternal antibody transfer. Here we critically summarize the current evidence for TGIP in both invertebrates and vertebrates. Mechanisms underlying TGIP remain elusive in many systems, but while it is unlikely that they are conserved across the range of organisms with TGIP, recent insight into epigenetic modulation may challenge this view. We place TGIP into a framework of evolutionary ecology, discussing costs and relevant environmental variation. We highlight how the ecology of species or populations should affect if, where, when, and how TGIP is realized. We propose that the field can progress by incorporating evolutionary ecology focused designs to the study of the so far well chronicled, but mostly descriptive TGIP, and how rapidly developing -omic methods can be employed to further understand TGIP across taxa.
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  • 61
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    Cambridge University Press
    In:  Journal of the Marine Biological Association of the United Kingdom, 69 (03). pp. 545-553.
    Publication Date: 2020-07-16
    Description: The importance of feeding pattern is well documented in fish (Jenkins & Green, 1977; Simenstad & Cailliet, 1986) but there are not many reported studies in cephalopods. Feeding patterns, as defined by Jenkins & Green (1977) have been studied, to our knowledge, only in Todarodes pacificus (Okiyama, 1965), Loligo pealei (Vovk, 1972), Loligo opalescens (Karpov & Cailliet, 1978), Illex illecebrosus (Amaratunga et ah, 1979; Amaratunga, 1980) and Nototodarus gouldi (O'Sullivan & Cullen, 1983). Boyle (1983) dealt with aspects of feeding in several cephalopod species but not specifically with feeding pattern. Aspects of feeding in Sepia officinalis have been reviewed by Nixon (1987). The present work describes the daily feeding pattern in Sepia officinalis from data collected in the field.
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  • 62
    Publication Date: 2019-02-01
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  • 63
    Publication Date: 2020-06-18
    Description: Coccolithophores—single-celled calcifying phytoplankton—are an important group of marine primary producers and the dominant builders of calcium carbonate globally. Coccolithophores form extensive blooms and increase the density and sinking speed of organic matter via calcium carbonate ballasting. Thereby, they play a key role in the marine carbon cycle. Coccolithophore physiological responses to experimental ocean acidification have ranged from moderate stimulation to substantial decline in growth and calcification rates, combined with enhanced malformation of their calcite platelets. Here we report on a mesocosm experiment conducted in a Norwegian fjord in which we exposed a natural plankton community to a wide range of CO2-induced ocean acidification, to test whether these physiological responses affect the ecological success of coccolithophore populations. Under high-CO2 treatments, Emiliania huxleyi, the most abundant and productive coccolithophore species, declined in population size during the pre-bloom period and lost the ability to form blooms. As a result, particle sinking velocities declined by up to 30% and sedimented organic matter was reduced by up to 25% relative to controls. There were also strong reductions in seawater concentrations of the climate-active compound dimethylsulfide in CO2-enriched mesocosms. We conclude that ocean acidification can lower calcifying phytoplankton productivity, potentially creating a positive feedback to the climate system.
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  • 64
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    Cambridge University Press
    In:  Journal of the Marine Biological Association of the United Kingdom, 70 (02). p. 459.
    Publication Date: 2020-07-16
    Description: Thirty-four adult individuals of Loligo forbesi (males and females with dorsal mantle lengths from 27–77 cm) were observed in captivity in a 3 m diameter closed sea-water system on Faial Island, Azores. Squids were caught by jigging and were fed with horse mackerel (Trachurus picturatus) and chub mackerel (Scomber japonicus), either alive or dead. The maximum survival was 73 days. Feeding behaviour was dependent upon both the size of prey and its state of preservation;e.g. the squid would eat the head of small fish (〈 about 15 cm), reject the head of medium-sized fish (about 15–35 cm) and would eat only the dorsal part of a big fish (〉 about 35 cm) or a fish poorly preserved. Seventeen chromatic, 9 postural and 6 movement components of body patterns were observed and described. Conspecific interactions considered to be aggression and dominance were observed among males; no such interactions occurred when one male and two females were kept together. Body patterns in relation to relaxation, stress, shock, feeding, locomotion and aggression are also described.
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  • 65
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    Cambridge University Press
    In:  Journal of the Marine Biological Association of the United Kingdom, 71 (01). p. 47.
    Publication Date: 2020-07-16
    Description: The presence of Stoloteuthis leucoptera in the Mediterranean is recorded on the basis of three specimens, including an adult male, caught by IKMT and by commercial otter-trawl in the Ligurian Sea. The hypothesis of a recent immigration is discussed. The list of Mediterranean cephalopods (Mangold Wirz, 1963; Torchio, 1968; Bello, 1986; Mangold & Boletzsky, 1987) includes the Sepiolidae of the subfamily Heteroteuthinae, whose members are supposed to be pelagic throughout their life cycle. Mangold Wirz (1963) recognizes in the Mediterranean fauna the unique species Heteroteuthis dispar, the other authors include H. atlantis Voss, which Voss himself (1955) reported at Messina. To this group may now be added Stoloteuthis leucoptera (Verrill, 1878) a species until now recorded in limited Atlantic areas. Verrill (1881) wrote “This species is an exceedingly beautiful one, when living, owing to the elegance and brilliancy of its colours and the gracefulness of its movements. In swimming it moves its fins in a manner analogous to the motion of the wings of a butterfly.”
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  • 66
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    Cambridge University Press
    In:  Geological Magazine, 121 (6). pp. 563-575.
    Publication Date: 2020-07-31
    Description: We present chemical data on magmatically heterogeneous pyroclastic deposits of late Quaternary age erupted from zoned magma systems underlying Tenerife (Canary Islands), Sao Miguel and Faial (Azores), and Vesuvius. The most fractionated magmas present at each centre are respectively Na-rich phonolite, trachyte, and K-rich phonolite. Within any one deposit, chemical variation is either accompanied by changes in the phenocryst assemblage (petrographic zonation) or is largely manifested in trace element abundances, unaccompanied by any petrographic change (occult zonation). Zoning is analogous to that in calc-alkaline systems where the most fractionated products are high-silica rhyolites. When a range of magma types are considered, a correlation emerges between roofward depletion of trace elements (especially REE) in the zoned system and compatability of those same trace elements in the accessory phenocryst phases present. Thus, allanite- or chevkinite-bearing rhyolitic systems are light-REE depleted roofwards, the sphene-bearing Tenerife system is middle-REE depleted roofwards, the melanite-bearing Vesuvius system is heavy-REE depleted roofwards, while the Azores systems, which lack these phases, display roofward REE enrichment. Therefore, the behaviour of trace elements may in each case be explained by fractionation of observed phenocryst assemblages. The resemblance between features of zoned magma systems and published work on the dynamic consequences of cooling saturated aqueous solutions prompts us to suggest that sidewall crystallization and consequent boundary-layer uprise to form a capping layer at top of the system may be a plausible mechanism for the generation of both petrographic and occult zonation. Reverse zoning occurs among the first-erupted tephra of some deposits, demonstrating that the most highly differentiated magma available is not always the first to be tapped during an eruption from a zoned system.
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  • 67
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    Cambridge University Press
    In:  Journal of the Marine Biological Association of the United Kingdom, 63 . pp. 71-83.
    Publication Date: 2020-07-16
    Description: Changes in the relative size of the ovary, oviducal glands and eggs are described for Eledone cirrhosa captured from the North Sea off Aberdeen over a 3 year period (N = 488). The analysis is based only on freshly caught animals, excluding those held in aquarium conditions (〉 5 days). Ovary enlargement and egg size estimates are used as indices of sexual maturity. Between 0–15% and 18–95% of total body weight is contributed by the ovary. Maximum egg length in the ovary ranges up to 7 mm. On these criteria, sexual maturation typically occurs at body sizes between 400–1000 g although some animals of 1000–1200 g are found showing no evidence of ovary enlargement. The majority of the monthly sample is always immature but maturation can apparently occur at almost any time of the year. Increase in mean ovary index and mean values for egg size are strongly seasonal and indicate a peak incidence of sexual maturity over 2–3 months in the July-September period. Spawning is presumed to follow within 1 month. Estimates of the fecundity of the females, based on the egg sample from the ovary, range from 2·2 × 103 to 55 × 10 3 eggs with a mean of 11 × 10 3 and a mode of 7·5 × 10 3 eggs.
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  • 68
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    Cambridge University Press
    In:  Journal of the Marine Biological Association of the United Kingdom, 64 . pp. 581-585.
    Publication Date: 2020-07-16
    Description: Female Eledone cirrhosa held in aquarium conditions for periods of time of five daysand over show relatively enlarged ovary sizes. Values for ovary index considerably exceed thoseof freshly caught animals and the incidence of the final stage of maturity, in which eggs pack the oviducts, is greater. A comparison of maturity indices for fresh and aquarium males was inconclusive. The range of factors associated with aquarium conditions is briefly reviewed and it is concluded that studies of cephalopod reproductive maturation must distinguish fresh and aquarium animals. Introduction External factors effective in inducing sexual maturation in cephalopods have been suggested several times. The influence of the absence of light has been implicated since the experiments of Wells & Wells (1959) showed that blinded Octopus vulgar is matured precociously. An effect of short day length in stimulating the optic glands of Sepia has been found by Defretin & Richard (1967) and Richard (1967) but this is not clearly the case for Octopus (Buckley, 1977). Octopuses kept in aquarium conditions for lengthy periods are said to have larger relative gonad sizes than those fresh from the sea (Wells & Wells, 1975). One of the factors associated with aquarium conditions is often a degree of starvation, and this circumstance alone is held to be a factor in inducing precocious sexual maturation in Eledone (Mangold & Boucher-Rodoni, 1973). In the course of recent studies on the growth and reproduction of Eledone cirrhosa from the North Sea (Boyle & Knobloch, 1982,1983,1984) animals which had remained in aquarium conditions for 5 days or over were separated from the analysis.
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  • 69
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    Cambridge University Press
    In:  Geological Magazine, 126 (02). p. 95.
    Publication Date: 2020-07-31
    Description: Santorini volcanic field has had 12 major (1–10 km3 or more of magma), and numerous minor, explosive eruptions over the last ~ 200 ka. Deposits from these eruptions (Thera Pyroclastic Formation) are well exposed in caldera-wall successions up to 200 m thick. Each of the major eruptions began with a pumice-fall phase, and most culminated with emplacement of pyroclastic flows. Pyroclastic flows of at least six eruptions deposited proximal lag deposits exposed widely in the caldera wall. The lag deposits include coarse-grained lithic breccias (andesitic to rhyodacitic eruptions) and spatter agglomerates (andesitic eruptions only). Facies associations between lithic breccia, spatter agglomerate, and ignimbrite from the same eruption can be very complex. For some eruptions, lag deposits provide the only evidence for pyroclastic flows, because most of the ignimbrite is buried on the lower flanks of Santorini or under the sea. At least eight eruptions tapped compositionally heterogeneous magma chambers, producing deposits with a range of zoning patterns and compositional gaps. Three eruptions display a silicic–silicic + mafic–silicic zoning not previously reported. Four eruptions vented large volumes of dacitic or rhyodacitic pumice, and may account for 90% or more of all silicic magma discharged from Santorini. The Thera Pyroclastic Formation and coeval lavas record two major mafic-to-silicic cycles of Santorini volcanism. Each cycle commenced with explosive eruptions of andesite or dacite, accompanied by construction of composite shields and stratocones, and culminated in a pair of major dacitic or rhyodacitic eruptions. Sequences of scoria and ash deposits occur between most of the twelve major members and record repeated stratocone or shield construction following a large explosive eruption. Volcanism at Santorini has focussed on a deep NE–SW basement fracture, which has acted as a pathway for magma ascent. At least four major explosive eruptions began at a vent complex on this fracture. Composite volcanoes constructed north of the fracture were dissected by at least three caldera-collapse events associated with the pyroclastic eruptions. Southern Santorini consists of pryoclastic ejecta draped over a pre-volcanic island and a ridge of early- to mid-Pleistocene volcanics. The southern half of the present-day caldera basin is a long-lived, essentially non-volcanic, depression, defined by topographic highs to the south and east, but deepened by subsidence associated with the main northern caldera complex, and is probably not a separate caldera.
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  • 70
    Publication Date: 2021-04-23
    Description: Hydrogen peroxide (H2O2) is present ubiquitously in marine surface waters where it is a reactive intermediate in the cycling of many trace elements. Photochemical processes are considered the dominant natural H2O2 source, yet cannot explain nanomolar H2O2 concentrations below the photic zone. Here, we determined the concentration of H2O2 in full depth profiles across three ocean basins (Mediterranean Sea, South Atlantic and South Pacific Oceans). To determine the accuracy of H2O2 measurements in the deep ocean we also re-assessed the contribution of interfering species to ‘apparent H2O2’, as analysed by the luminol based chemiluminescence technique. Within the vicinity of coastal oxygen minimum zones, accurate measurement of H2O2 was not possible due to interference from Fe(II). Offshore, in deep (〉1000 m) waters H2O2 concentrations ranged from 0.25 ± 0.27 nM (Mediterranean, Balearics-Algeria) to 2.9 ± 2.2 nM (Mediterranean, Corsica-France). Our results indicate that a dark, pelagic H2O2 production mechanism must occur throughout the deep ocean. A bacterial source of H2O2 is the most likely origin and we show that this source is likely sufficient to account for all of the observed H2O2 in the deep ocean.
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  • 71
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    American Institute of Physics
    In:  The Journal of the Acoustical Society of America, 138 (3). pp. 1253-1267.
    Publication Date: 2020-05-11
    Description: Responses obtained in consonant perception experiments typically show a large variability across stimuli of the same phonetic identity. The present study investigated the influence of different potential sources of this response variability. It was distinguished between source-induced variability, referring to perceptual differences caused by acoustical differences in the speech tokens and/or the masking noise tokens, and receiver-related variability, referring to perceptual differences caused by within- and across-listener uncertainty. Consonant-vowel combinations consisting of 15 consonants followed by the vowel /i/ were spoken by two talkers and presented to eight normal-hearing listeners both in quiet and in white noise at six different signal-to-noise ratios. The obtained responses were analyzed with respect to the different sources of variability using a measure of the perceptual distance between responses. The speech-induced variability across and within talkers and the across-listener variability were substantial and of similar magnitude. The noise-induced variability, obtained with time-shifted realizations of the same random process, was smaller but significantly larger than the amount of within-listener variability, which represented the smallest effect. The results have implications for the design of consonant perception experiments and provide constraints for future models of consonant perception.
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  • 72
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    Cambridge University Press
    In:  Journal of the Marine Biological Association of the United Kingdom, 73 (04). p. 949.
    Publication Date: 2020-07-16
    Description: Samples of two loliginid squids Alloteuthis africana and A. subulata were collected from the continental shelf off the west Sahara in August-September 1987. Statoliths were taken from 124 specimens and processed using statolith ageing techniques. Statoliths of both species were very similar in shape. In the ground statolith, growth increments were examined and grouped into four growth zones distinguished mainly by the width of the increments. Age of adult mature males of both species did not exceed eight months, that of females six months. Alloteuthis africana grew faster than A. subulata in weight and, particularly, in length. At age 180 d the mantle of A. africana was twice as long and the body weight 1·2–1·5 times as large. Both species matured over a wide range of sizes and ages (from 120 to 180 d). The life span of A. africana and A. subulata hatching between January and May on the west Saharan shelf is about six months, much shorter than that of A. subulata in its northern temperate range.
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  • 73
    Publication Date: 2020-02-06
    Description: The Mw 8.8 megathrust earthquake that occurred on 27 February 2010 offshore the Maule region of central Chile triggered a destructive tsunami. Whether the earthquake rupture extended to the shallow part of the plate boundary near the trench remains controversial. The up-dip limit of rupture during large subduction zone earthquakes has important implications for tsunami generation and for the rheological behavior of the sedimentary prism in accretionary margins. However, in general, the slip models derived from tsunami wave modeling and seismological data are poorly constrained by direct seafloor geodetic observations. We difference swath bathymetric data acquired across the trench in 2008, 2011 and 2012 and find ∼3-5 m of uplift of the seafloor landward of the deformation front, at the eastern edge of the trench. Modeling suggests this is compatible with slip extending seaward, at least, to within ∼6 km of the deformation front. After the Mw 9.0 Tohoku-oki earthquake, this result for the Maule earthquake represents only the second time that repeated bathymetric data has been used to detect the deformation following megathrust earthquakes, providing methodological guidelines for this relatively inexpensive way of obtaining seafloor geodetic data across subduction zone.
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  • 74
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    Cambridge University Press
    In:  Journal of the Marine Biological Association of the United Kingdom, 64 (02). pp. 285-302.
    Publication Date: 2020-07-16
    Description: A new species of a monogenean Isancistrum subulatae (Gyrodactylidae) has been discovered on the arms and tentacles of the cephalopod mollusc Alloteuthis subulata at Plymouth and I. loliginis, on the gills of the same host, has been re-discovered for the first time since its original description in 1912. I. subulatae, like other gyrodactylids, is viviparous, and has been shown by experiments to transfer to new hosts by contagion. In nature such transfers probably take place during copulation of the hosts and since the parasite may occur in numbers of several thousands per host, it may thereby constitute a venereal disease.
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  • 75
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    Nature Research
    In:  Nature, 544 (7651). p. 395.
    Publication Date: 2020-06-18
    Description: Planetariums are not just for education, or even astronomy: they could display all sorts of data, if only scientists thought to use them, says Tom Kwasnitschka.
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  • 76
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    Cambridge University Press
    In:  Journal of the Marine Biological Association of the United Kingdom, 55 (4). pp. 893-910.
    Publication Date: 2020-07-23
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  • 77
    Publication Date: 2019-02-01
    Description: The potential of the diverse chemistries present in natural products (NP) for biotechnology and medicine remains untapped because NP databases are not searchable with raw data and the NP community has no way to share data other than in published papers. Although mass spectrometry (MS) techniques are well-suited to high-throughput characterization of NP, there is a pressing need for an infrastructure to enable sharing and curation of data. We present Global Natural Products Social Molecular Networking (GNPS; http://gnps.ucsd.edu), an open-access knowledge base for community-wide organization and sharing of raw, processed or identified tandem mass (MS/MS) spectrometry data. In GNPS, crowdsourced curation of freely available community-wide reference MS libraries will underpin improved annotations. Data-driven social-networking should facilitate identification of spectra and foster collaborations. We also introduce the concept of 'living data' through continuous reanalysis of deposited data.
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  • 78
    Publication Date: 2019-02-01
    Description: Synthetic biology has boomed since the early 2000s when it started being shown that it was possible to efficiently synthetize compounds of interest in a much more rapid and effective way by using other organisms than those naturally producing them. However, to thus engineer a single organism, often a microbe, to optimise one or a collection of metabolic tasks may lead to difficulties when attempting to obtain a production system that is efficient, or to avoid toxic effects for the recruited microorganism. The idea of using instead a microbial consortium has thus started being developed in the last decade. This was motivated by the fact that such consortia may perform more complicated functions than could single populations and be more robust to environmental fluctuations. Success is however not always guaranteed. In particular, establishing which consortium is best for the production of a given compound or set thereof remains a great challenge. This is the problem we address in this paper. We thus introduce an initial model and a method that enable to propose a consortium to synthetically produce compounds that are either exogenous to it, or are endogenous but where interaction among the species in the consortium could improve the production line.
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  • 79
    Publication Date: 2020-06-18
    Description: Transparent exopolymer particles (TEP) are a class of marine gel particles and important links between surface ocean biology and atmospheric processes. Derived from marine microorganisms, these particles can facilitate the biological pumping of carbon dioxide to the deep sea, or act as cloud condensation and ice nucleation particles in the atmosphere. Yet, environmental controls on TEP abundance in the ocean are poorly known. Here, we investigated some of these controls during the first multiyear time-series on TEP abundance for the Fram Strait, the Atlantic gateway to the Central Arctic Ocean. Data collected at the Long-Term Ecological Research observatory HAUSGARTEN during 2009 to 2014 indicate a strong biological control with highest abundance co-occurring with the prymnesiophyte Phaeocystis pouchetii. Higher occurrence of P. pouchetii in the Arctic Ocean has previously been related to northward advection of warmer Atlantic waters, which is expected to increase in the future. Our study highlights the role of plankton key species in driving climate relevant processes; thus, changes in plankton distribution need to be accounted for when estimating the ocean’s biogeochemical response to global change.
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  • 80
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    Unknown
    American Institute of Physics
    In:  Journal of the Acoustical Society of America, 90 (4, Pt. 2). pp. 2255-2256.
    Publication Date: 2020-07-16
    Description: Seafloor topography is neither spatially homogeneous, nor does it obey Gaussian statistics; deviations from both of these assumptions are important from a geological and acoustic point of view. It has been found that the distribution of topographic slopes can be used as a primary tool for understanding the sources and extent of spatial heterogeneities and patterns on the seafloor. The covariance function has been widely used to characterize seafloor topography, but requires the assumption of Gaussian joint probability statistics to be valid. For heterogeneous topography characterized by large transient signals such as steep scarps and volcanoes, the covariance becomes dominated by the transients; in contrast the family slope distributions can still be used to derive stable descriptors for regions with large transient signals, as well as regions containing asymmetric features, and regions with only limited sampling. Knowledge of slopes is useful because a direct relation exists between the covariance and the slope distributions at different spatial scales. Studies of the slope distribution provide a means of identifying the presence of the non‐Gaussian elements in the topography, and flagging their spatial locations. The methods used here are demonstrated by applying them to three small patches of topography located within 20 km of each other in the Eastern Pacific. It is found that dominant azimuthal directions and dip angles differ widely between the patches. In addition, asymmetries in the cross‐sectional shapes of faulted abyssal hills are documented. [Work supported by ONR.]
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  • 81
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    American Chemical Society
    In:  The Journal of Physical Chemistry A, 115 (46). pp. 13324-13331.
    Publication Date: 2020-05-11
    Description: Microscopy, confocal Raman spectroscopy and powder X-ray diffraction (PXRD) were used for in situ investigations of the CO2-hydrocarbon exchange process in gas hydrates and its driving forces. The study comprises the exposure of simple structure I CH4 hydrate and mixed structure II CH4–C2H6 and CH4–C3H8 hydrates to gaseous CO2 as well as the reverse reaction, i.e., the conversion of CO2-rich structure I hydrate into structure II mixed hydrate. In the case of CH4–C3H8 hydrates, a conversion in the presence of gaseous CO2 from a supposedly more stable structure II hydrate to a less stable structure I CO2-rich hydrate was observed. PXRD data show that the reverse process requires longer initiation times, and structural changes seem to be less complete. Generally, the exchange process can be described as a decomposition and reformation process, in terms of a rearrangement of molecules, and is primarily induced by the chemical potential gradient between hydrate phase and the provided gas phase. The results show furthermore the dependency of the conversion rate on the surface area of the hydrate phase, the thermodynamic stability of the original and resulting hydrate phase, as well as the mobility of guest molecules and formation kinetics of the resulting hydrate phase.
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  • 82
    Publication Date: 2020-06-18
    Description: The Palaeocene-Eocene Thermal Maximum(1,2) (PETM) was a global warming event that occurred about 56 million years ago, and is commonly thought to have been driven primarily by the destabilization of carbon from surface sedimentary reservoirs such as methane hydrates(3). However, it remains controversial whether such reservoirs were indeed the source of the carbon that drove the warming(1,3-5). Resolving this issue is key to understanding the proximal cause of the warming, and to quantifying the roles of triggers versus feedbacks. Here we present boron isotope data-a proxy for seawater pH-that show that the ocean surface pH was persistently low during the PETM. We combine our pH data with a paired carbon isotope record in an Earth system model in order to reconstruct the unfolding carbon-cycle dynamics during the event(6,7). We find strong evidence for a much larger (more than 10,000 petagrams)-and, on average, isotopically heavier-carbon source than considered previously(8,9). This leads us to identify volcanism associated with the North Atlantic Igneous Province(10,11), rather than carbon from a surface reservoir, as the main driver of the PETM. This finding implies that climate-driven amplification of organic carbon feedbacks probably played only a minor part in driving the event. However, we find that enhanced burial of organic matter seems to have been important in eventually sequestering the released carbon and accelerating the recovery of the Earth system(12).
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  • 83
    Publication Date: 2021-04-23
    Description: Inputs of silver nanoparticles (AgNPs) to marine waters continue to increase yet mechanisms of AgNPs toxicity to marine phytoplankton are still not well resolved. This study reports a series of toxicity experiments on a representative coastal marine diatom species Chaetoceros curvisetus using the reference AgNP, NM-300K. Exposure to AgNPs resulted in photosynthetic impairment and loss of diatom biomass in proportion to the supplied AgNP dose. The underlying mechanism of toxicity was explored via comparing biological responses in parallel experiments. Diatom responses to AgNP, free Ag(I) species, and dialysis bag-retained AgNP treatments showed marked similarity, pointing towards a dominant role of Ag(I) species uptake, rather than NPs themselves, in inducing the toxic response. In marked contrast to previous studies, addition of the organic complexing agent cysteine (Cys) alongside Ag only marginally moderated toxicity, implying AgCys− complexes were bioavailable to this diatom species. A preliminary field experiment with a natural phytoplankton community in the southeast Atlantic Ocean showed no significant toxic response at a NM-300 K concentration that resulted in ~40% biomass loss in the culture studies, suggesting a modulating effect of natural seawaters on Ag toxicity.
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  • 84
    Publication Date: 2021-04-23
    Description: Nutrient limitation of oceanic primary production exerts a fundamental control on marine food webs and the flux of carbon into the deep ocean1. The extensive boundaries of the oligotrophic sub-tropical gyres collectively define the most extreme transition in ocean productivity, but little is known about nutrient limitation in these zones1, 2, 3, 4. Here we present the results of full-factorial nutrient amendment experiments conducted at the eastern boundary of the South Atlantic gyre. We find extensive regions in which the addition of nitrogen or iron individually resulted in no significant phytoplankton growth over 48 hours. However, the addition of both nitrogen and iron increased concentrations of chlorophyll a by up to approximately 40-fold, led to diatom proliferation, and reduced community diversity. Once nitrogen–iron co-limitation had been alleviated, the addition of cobalt or cobalt-containing vitamin B12 could further enhance chlorophyll a yields by up to threefold. Our results suggest that nitrogen–iron co-limitation is pervasive in the ocean, with other micronutrients also approaching co-deficiency. Such multi-nutrient limitations potentially increase phytoplankton community diversity.
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  • 85
    Publication Date: 2020-02-06
    Description: The western Indian Ocean has been warming faster than any other tropical ocean during the 20th century, and is the largest contributor to the global mean sea surface temperature (SST) rise. However, the temporal pattern of Indian Ocean warming is poorly constrained and depends on the historical SST product. As all SST products are derived from the International Comprehensive Ocean-Atmosphere dataset (ICOADS), it is challenging to evaluate which product is superior. Here, we present a new, independent SST reconstruction from a set of Porites coral geochemical records from the western Indian Ocean. Our coral reconstruction shows that the World War II bias in the historical sea surface temperature record is the main reason for the differences between the SST products, and affects western Indian Ocean and global mean temperature trends. The 20th century Indian Ocean warming pattern portrayed by the corals is consistent with the SST product from the Hadley Centre (HadSST3), and suggests that the latter should be used in climate studies that include Indian Ocean SSTs. Our data shows that multi-core coral temperature reconstructions help to evaluate the SST products. Proxy records can provide estimates of 20th century SST that are truly independent from the ICOADS data base.
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  • 86
    Publication Date: 2020-06-18
    Description: Many marine invertebrates including ctenophores are capable of extensive body regeneration when injured. However, as for the invasive ctenophore Mnemiopsis leidyi, there is a constant subportion of individuals not undergoing whole body regeneration but forming functionally stable half-animals instead. Yet, the driving factors of this phenomenon have not been addressed so far. This study sheds new light on how differences in food availability affect self-repair choice and regeneration success in cydippid larvae of M. leidyi. As expected, high food availability favored whole-body regeneration. However, under low food conditions half-animals became the preferential self-repair mode. Remarkably, both regenerating and half-animals showed very similar survival chances under respective food quantities. As a consequence of impaired food uptake after injury, degeneration of the digestive system would often occur indicating limited energy storage capacities. Taken together, this indicates that half-animals may represent an alternative energy-saving trajectory which implies self-repair plasticity as an adaptive trade-off between high regeneration costs and low energy storage capacities. We conclude that self-repair plasticity could lead to higher population fitness of ctenophores under adverse conditions such as in ships’ ballast water tanks which is postulated to be the major vector source for the species’ spreading around the globe.
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  • 87
    Publication Date: 2020-06-18
    Description: In marine oxygen (O2) minimum zones (OMZs), the transfer of particulate organic carbon (POC) to depth via the biological carbon pump might be enhanced as a result of slower remineralisation under lower dissolved O2 concentrations (DO). In parallel, nitrogen (N) loss to the atmosphere through microbial processes, such as denitrification and anammox, is directly linked to particulate nitrogen (PN) export. However it is unclear (1) whether DO is the only factor that potentially enhances POC transfer in OMZs, and (2) if particle fluxes are sufficient to support observed N loss rates. We performed a degradation experiment on sinking particles collected from the Baltic Sea, where anoxic zones are observed. Sinking material was harvested using surface-tethered sediment traps and subsequently incubated in darkness at different DO levels, including severe suboxia (〈0.5 mg l−1 DO). Our results show that DO plays a role in regulating POC and PN degradation rates. POC(PN) degradation was reduced by approximately 100% from the high to low DO to the lowest DO. The amount of NH4+ produced from the pool of remineralising organic N matched estimations of NH4+ anammox requirements during our experiment. This anammox was likely fueled by DON degradation rather than PON degradation.
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  • 88
    Publication Date: 2021-03-19
    Description: Ocean acidification (OA), the dissolution of excess anthropogenic carbon dioxide in ocean waters, is a potential stressor to many marine fish species. Whether species have the potential to acclimate and adapt to changes in the seawater carbonate chemistry is still largely unanswered. Simulation experiments across several generations are challenging for large commercially exploited species because of their long generation times. For Atlantic cod (Gadus morhua), we present first data on the effects of parental acclimation to elevated aquatic CO2 on larval survival, a fundamental parameter determining population recruitment. The parental generation in this study was exposed to either ambient or elevated aquatic CO2 levels simulating end-of-century OA levels (~1100 µatm CO2) for six weeks prior to spawning. Upon fully reciprocal exposure of the F1 generation, we quantified larval survival, combined with two larval feeding regimes in order to investigate the potential effect of energy limitation. We found a significant reduction in larval survival at elevated CO2 that was partly compensated by parental acclimation to the same CO2 exposure. Such compensation was only observed in the treatment with high food availability. This complex 3-way interaction indicates that surplus metabolic resources need to be available to allow a transgenerational alleviation response to ocean acidification.
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  • 89
    Publication Date: 2020-07-27
    Description: In the colloidal synthesis of iron sulfides, a series of dialkyl disulfides, alkyl thiols, and dialkyl disulfides (allyl, benzyl, tert-butyl, and phenyl) were employed as sulfur sources. Their reactivity was found to tune the phase between pyrite (FeS2), greigite (Fe3S4), and pyrrhotite (Fe7S8). DFT was used to show that sulfur-rich phases were favored when the C–S bond strength was low in the organosulfurs, yet temperature dependent studies and other observations indicated the reasons for phase selectivity were more nuanced; the different precursors decomposed through different reaction mechanisms, some involving the oleylamine solvent. The formation of pyrite from diallyl disulfide was carefully studied as it was the only precursor to yield FeS2. Raman spectroscopy indicated that FeS2 forms directly without an FeS intermediate, unlike most synthetic procedures to pyrite. Diallyl disulfide releases persulfide (S–S)2– due to the lower C–S bond strength relative to the S–S bond strength, as well as facile decomposition in the presence of amines through SN2′ mechanisms at elevated temperatures.
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  • 90
    Publication Date: 2021-02-08
    Description: Mid- to late-Holocene sea-level records from low-latitude regions serve as an important baseline of natural variability in sea level and global ice volume prior to the Anthropocene. Here, we reconstruct a high-resolution sea-level curve encompassing the last 6000 years based on a comprehensive study of coral microatolls, which are sensitive low-tide recorders. Our curve is based on microatolls from several islands in a single region and comprises a total of 82 sea-level index points. Assuming thermosteric contributions are negligible on millennial time scales, our results constrain global ice melting to be 1.5–2.5 m (sea-level equivalent) since ~5500 years before present. The reconstructed curve includes isolated rapid events of several decimetres within a few centuries, one of which is most likely related to loss from the Antarctic ice sheet mass around 5000 years before present. In contrast, the occurrence of large and flat microatolls indicates periods of significant sea-level stability lasting up to ~300 years.
    Type: Article , PeerReviewed
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  • 91
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    Nature Research
    In:  Nature Communications, 9 (1). Art.Nr. 690.
    Publication Date: 2021-03-19
    Type: Article , PeerReviewed
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  • 92
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    Nature Research
    In:  Nature, 554 (7693). p. 423.
    Publication Date: 2019-01-29
    Type: Article , NonPeerReviewed
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  • 93
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    American Chemical Society
    In:  ACS Division of Fuel Chemistry Preprints, 42 (2). pp. 544-547.
    Publication Date: 2018-04-11
    Description: Test specimens of methane hydrate were grown under static conditions by combining cold, pressurized CH4 gas with H2O ice grains, then warming the system to promote the reaction CH4 (g) + 6H2O (s???l) ??? CH4??6H2O. Hydrate formation evidently occurs at the nascent ice/liquid water interface, and complete reaction was achieved by warming the system above 271.5 K and up to 289 K, at 25-30 MPa, for approximately 8 hours. The resulting material is pure methane hydrate with controlled grain size and random texture. Fabrication conditions placed the H2O ice well above its melting temperature before reaction completed, yet samples and run records showed no evidence for bulk melting of the ice grains. Control experiments using Ne, a non-hydrate-forming gas, verified that under otherwise identical conditions, the pressure reduction and latent heat associated with ice melting is easily detectable in our fabrication apparatus. These results suggest that under hydrate-forming conditions, H2O ice can persist metastably at temperatures well above its melting point. Methane hydrate samples were then tested in constant-strain-rate deformation experiments at T= 140-200 K, Pc= 50-100 MPa, and ????= 10-4-10-6 s-1. Measurements in both the brittle and ductile fields showed that methane hydrate has measurably different strength than H2O ice, and work hardens to a higher degree compared to other ices as well as to most metals and ceramics at high homologous temperatures. This work hardening may be related to a changing stoichiometry under pressure during plastic deformation; x-ray analyses showed that methane hydrate undergoes a process of solid-state disproportionation or exsolution during deformation at conditions well within its conventional stability field.
    Type: Article , NonPeerReviewed
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  • 94
    Publication Date: 2021-03-19
    Description: Anthropogenic impacts are perturbing the global nitrogen cycle via warming effects and pollutant sources such as chemical fertilizers and burning of fossil fuels. Understanding controls on past nitrogen inventories might improve predictions for future global biogeochemical cycling. Here we show the quantitative reconstruction of deglacial bottom water nitrate concentrations from intermediate depths of the Peruvian upwelling region, using foraminiferal pore density. Deglacial nitrate concentrations correlate strongly with downcore δ13C, consistent with modern water column observations in the intermediate Pacific, facilitating the use of δ13C records as a paleo-nitrate-proxy at intermediate depths and suggesting that the carbon and nitrogen cycles were closely coupled throughout the last deglaciation in the Peruvian upwelling region. Combining the pore density and intermediate Pacific δ13C records shows an elevated nitrate inventory of 〉10% during the Last Glacial Maximum relative to the Holocene, consistent with a δ13C-based and δ15N-based 3D ocean biogeochemical model and previous box modeling studies.
    Type: Article , PeerReviewed , info:eu-repo/semantics/article
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  • 95
    Publication Date: 2018-05-03
    Type: Book chapter , NonPeerReviewed
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  • 96
    Publication Date: 2021-02-08
    Description: Limited insight into eel larvae feeding and diet prevents a holistic overview of the life-cycle of catadromous eels and an understanding of the ecological position of their early stages in marine waters. The present study evaluated the diet of larval European eel, Anguilla anguilla - a critically endangered species. Next-generation 18S rRNA gene sequencing data of Sargasso Sea eel larvae gut contents and marine snow aggregates was compared with a reference plankton database to assess the trophic relations of eel larvae. Gut contents of A. anguilla larvae were not well explained by the eukaryotic composition of marine snow aggregates; gut contents being dominated by gene sequences of Hydrozoa taxa (phylum Cnidaria), while snow aggregates were dominated by Crustacea taxa. Pronounced differences between gut contents and marine snow aggregates were also seen in the prokaryotic 16S rRNA gene composition. The findings, in concert with significant abundances of Hydrozoa in the study area, suggest that Hydrozoa plankton are important in the diet of A. anguilla larvae, and that consideration of these organisms would further our understanding of A. anguilla feeding strategies in the oligotrophic Sargasso Sea, which may be important for potential future rearing of A. anguilla larvae in captivity.
    Type: Article , PeerReviewed
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  • 97
    Publication Date: 2020-02-06
    Description: Methane emission from the geosphere is generally characterized by a radiocarbon-free signature and might preserve information on the deep carbon cycle on Earth. Here we report a clear relationship between the origin of methane-rich natural gases and the geodynamic setting of the West Pacific convergent plate boundary. Natural gases in the frontal arc basin (South Kanto gas fields, Northeast Japan) show a typical microbial signature with light carbon isotopes, high CH4/C2H6 and CH4/³He ratios. In the Akita-Niigata region – which corresponds to the slope stretching from the volcanic-arc to the back-arc –a thermogenic signature characterize the gases, with prevalence of heavy carbon isotopes, low CH4/C2H6 and CH4/³He ratios. Natural gases from mud volcanoes in South Taiwan at the collision zone show heavy carbon isotopes, middle CH4/C2H6 ratios and low CH4/³He ratios. On the other hand, those from the Tokara Islands situated on the volcanic front of Southwest Japan show the heaviest carbon isotopes, middle CH4/C2H6 ratios and the lowest CH4/³He ratios. The observed geochemical signatures of natural gases are clearly explained by a mixing of microbial, thermogenic and abiotic methane. An increasing contribution of abiotic methane towards more tectonically active regions of the plate boundary is suggested.
    Type: Article , PeerReviewed
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  • 98
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    American Institute of Physics
    In:  The Journal of the Acoustical Society of America, 78 (6). pp. 2115-2121.
    Publication Date: 2020-05-11
    Description: The acoustic backscatter of eight well‐curated ferromanganese nodules has been measured in 1 °C seawater at frequencies from 45 to 167 kHz. The nodules have diameters from 37 to 121 mm and are thought to be representative of the Cu–Ni–Co‐rich nodules from the area around 14° 40’ N, 125° 25’ W (DOMES site C). They had been collected in box cores on the Echo 1 expedition and were kept refrigerated and water soaked in air‐tight plastic bags. Acoustic backscatter variations of over 10 dB were observed while the nodule was rotated 10° to 30° about one of its principal axes. The complicated fine structure, as well as the target strength, makes it clear that nodules cannot be modeled as simple spheres.
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  • 99
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    Cambridge University Press
    In:  Journal of the Marine Biological Association of the United Kingdom, 72 (02). pp. 281-291.
    Publication Date: 2020-07-16
    Description: Samples of female lllex argentinus were taken from the catch of a Japanese squid jigging vessel on the Patagonian Shelf during March 1986. Morphometrics of the somatic and reproductive organ systems and the histological structure of the mantle in relation to maturation were examined. The data suggest that growth and maturation occur simultaneously during most of the time that lllex argentinus females are on the feeding grounds. In a squid of a ‘standard’ mantle length the whole body mass increases relative to mantle length during maturation and growth of the reproductive organs. This is accompanied by a small but significant decrease in the relative mass of the mantle, head and viscera whilst the mass of the digestive gland remains constant. Although mantle mass of a ‘standard’ female squid decreases relative to mantle length with maturity this is not associated with degeneration of the mantle muscles. Energy and nutrient resources for maturation are apparently derived from the squid's food, not from reserves, and during the course of maturation there is an increasing shift of emphasis from somatic growth to production of gonad and accessory reproductive organs.
    Type: Article , PeerReviewed
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  • 100
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    Cambridge University Press
    In:  Journal of the Marine Biological Association of the United Kingdom, 72 (02). pp. 301-311.
    Publication Date: 2020-07-16
    Description: The timing of spawning and recruitment in the squid Loligo forbesi in Scottish waters is described on the basis of data from three sources: monthly samples of squid caught by commercial trawls (1986–1988), egg masses found by fishermen (1987–1991), and statistical data on animals caught by research trawls (1978–1987). Spawning females were present in samples from December to June, with peak spawning occurring in March. Most records of egg masses were from these months, but eggs were also found in August and September. These results suggest that there is an extended spawning season. Small squid (≤100 mm dorsal mantle length) were rarely present in commercial samples, but were recorded in research samples almost all year round. Thus there appears to be more or less continuous recruitment into the catchable population. The results of the present study are consistent with published data from other parts of the geographic range in that there is a regular seasonal peak in spawning, and spawning adults disappear from the population in summer. Further interpretation of the life-cycle of this species is not justified on the basis of current knowledge, and more information is needed on migrations, geographical variation, and lifespan in Loligo forbesi.
    Type: Article , PeerReviewed
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