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  • Inorganic Chemistry  (1,627)
  • Fisheries
  • LUNAR AND PLANETARY EXPLORATION
  • 2020-2023  (33)
  • 1950-1954  (1,627)
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  • 1
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    The International Collective in Support of Fishworkers (ICSF) | India
    Publication Date: 2022-02-21
    Description: Yemaya No. 63, dated May 2021, features articles from US, The Netherlands, Myanmar, Senegal, and an article on women in fisheries and human rights. The article from the US by Linda Behnken argues that a growing coalition of small-scale, community-based fishers is calling for the recognition and protection of Alaska’s invaluable coastal fisheries during COVID-19. The article from the Netherlands by Cornelie Quist looks at the challenges facing women engaged in small-scale fishing and supplying fish through retailers and how they found new ways to directly reach consumers. The conversation between Miranda Bout and Cornelie Quist focuses on how they combined new product development with the use of social media to contact their customer base during the pandemic-induced disruption of traditional marketing chains. The article by Elena Finkbeiner, Juno Fitzpatrick and Whitney Yadao-Evans looks at recent media revelations and scientific research that have brought increased attention to human-rights violations and the myriad social issues facing fisheries, but with a disproportionate focus on labour-rights violations at sea and in industrial fishing operations. The systemic inequalities combined with the effects of COVID-19 exacerbated vulnerabilities of women to health risks, food and livelihood security. The article from Senegal by Aby Dia from Lumière Synergie pour le Développement (LSD), in collaboration with WoMin African Alliance, South Africa, narrates the story of traditional women fish processors from the Bargny who have been, for more than a decade, struggling against development projects that jeopardise their environment, health and livelihoods. In order to preserve their livelihoods, women processors in Senegal have come together to oppose the Tosyali steel project. The European Network of Women in Fisheries and Aquaculture in Europe (AKTEA) urges the Office of the Commissioner for the Environment, Oceans and Fisheries to integrate gender into all aspects of European fishing policy. The Profile column looks at how Linda Behnken became a fisher in Alaska and how fishing has shaped her individuality and work. Natalie Sattler says that fishing for halibut, sablefish and salmon from the sparkling waters of the Pacific along with her children and at the same time passion for working with the Alaska Longline Fishermen’s Association and the Alaska Sustainable Fisheries Trust is an immense challenge.
    Description: Published
    Description: Refereed
    Keywords: Fishing Communities ; Women in fisheries ; Gender ; Small-scale fisheries ; Aquaculture ; Fisheries
    Repository Name: AquaDocs
    Type: Book/Monograph/Conference Proceedings
    Format: 12p.
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  • 2
    Publication Date: 2022-06-28
    Description: Las pesquerías basadas en las agregaciones reproductivas pueden amenazar a especies como los pargos que tienen conductas gregarias durante el período reproductivo. Esta nota ofrece elementos que sugieren la existencia de sitios de agregación no registrados previamente y no protegidos en el Parque Nacional Cayos de San Felipe (PNCSF), región suroccidental de Cuba. La información tradicional obtenida de pescadores locales y trabajadores del parque se corroboró con muestreos cualitativos y cuantitativos de peces de arrecifes y datos de pesquerías locales del 2014. En la época de reproducción de pargos (mayo a julio) se observaron grupos de entre 40-100 ejemplares de Lutjanus cyanopterus, Lutjanus synagris y Lutjanus jocu en los arrecifes de la zona occidental del PNCSF (camellones entre 15-30 m de profundidad cerca del borde de la plataforma). Dentro de esa área, se señalan dos sitios que parecen ser utilizados para agregaciones de predesove, por lo que requieren protección y ser estudiados. Los censos cuantitativos confirmaron que en mayo y junio la zona occidental tiene densidad alta de pargos adultos. También, el pico de captura de estas especies ocurrió en la época reproductiva. Se comprobó que las pesquerías se realizaron durante las migraciones de peces hacia el borde de la plataforma en áreas de la zona occidental del PNCSF, y que más del 60% de los individuos tuvieron gónadas maduras (antes de desovar). Esta información debe incentivar el estudio de las agregaciones de desove en esta región de Cuba, la protección de especies amenazadas y áreas de alta significación ecológica y la implementación de pesquerías sostenibles.
    Description: Fisheries based on reproductive aggregations can threaten species such as snappers that have gregarious behavior during the reproductive period. This note provides evidence to support the existence of aggregation sites, not previously registered and unprotected, in the National Park San Felipe Keys (NPSFK), southwestern region of Cuba. Traditionalinformation obtained from local fishermen and from the park staff was complemented with qualitative and quantitative fish reef censuses and local fisheries data in 2014. In the reproductive season of snappers (May to July) groups of between 40-100 specimens of Lutjanus cyanopterus, Lutja- nus synagris and Lutjanus jocu were observed in the western area of the NPSFK on the reefs (spoor and grove between 20-30 m deep close to the platform edge). Within that area two sites are indicated that can be used for prespawning aggregation, so they require protection and study. Quanti- tative censuses confirmed that in May and June the western zone has high density of adult snappers. Also, the peak of capture of these snapper species occurred in the reproduc- tive season. It was found that fisheries carried out during fish migrations to the edge of the shelf in areas of the western area of the NPSFK and more than 60% of the individuals had mature gonads (before spawning). This information should promote the study of spawning aggregations in this region of Cuba, the protection of threatened species and areas of high ecological significance and the implementation of sustainable fisheries.
    Description: Published
    Description: Refereed
    Keywords: Región suroccidental de Cuba ; Desove ; Pesquerías ; Migration routes ; Spawning ; Fisheries ; Rutas migraciones
    Repository Name: AquaDocs
    Type: Journal Contribution
    Format: pp.54-65
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  • 3
    Publication Date: 2022-09-14
    Description: The ICES Workshop on ICES reference points (WKREF2) was tasked review the WKREF1 report and based on the outcome develop updated guidelines for the ICES reference points system and recommendations for ACOM consideration. The WKREF1 report has suggested 5 key recom- mendations to simplify and harmonise the ICES reference points framework representing a ma- jor change to the current guidelines. At WKREF2, we detailed discussions and four key concerns were raised about the proposed approach. The first related to the simplification of rules to define Blim. Around two thirds of category 1 stocks would end up as WKREF1 “Blim Type 2” where Blim would be set as a fraction of B0. The Allee effect or “depensation” maybe more important than previously thought and should be furthered explored for ICES stocks since it has important consequences for Blim. A number of challenges and issues around defining Blim using the current guidelines were documented. Some suggestions on improvement criteria were discussed including using classifiers to define spas- modic stocks and using change point algorithms to address non-stationary productivity regimes. However, further work is need to make these approaches operational and there was no consen- sus that the WKREF1 Blim types should replace the current guidelines. WKREF1 recommended that the FMSY proxy should be based on a biological proxies and should be less than the deterministic FMSY. It was pointed out that the stochastic FMSY estimated in EqSim for example, is lower than the deterministic FMSY and that the current guidelines ensure that the FMSY should not pose a more than 5% risk to Blim. A large amount of work described in WD 1 was carried out to develop an MSE framework to consistency and robustness test a candidate refer- ence point system for North East Atlantic stocks. However, WKREF2 recommended that further work needs to be carried out to condition and test the simulation framework before the conclu- sions could be adopted by ICES and incorporated into the guidelines. A number of considerations for defining MSY related reference points were discussed including using model validation and prediction skill to ensure that ICES provide robust and credible ad- vice. There is evidence that density dependence (DD) is important in the majority of ICES stocks (68% in recruitment and 54% in growth). The correct prediction of the shape and strength of density-dependence in productivity is key to predicting future stock development and providing the best possible long-term fisheries management advice. A suggested approach to use surplus production models (SPMs) to account for DD in FMSY was suggested and discussed but there was no consensus on whether that approach was appropriate. There was consensus that the FECO approach as a means of adapting target fishing mortality to medium-term changes in productiv- ity should be included in the guidelines subject to a benchmark and ACOM approval. While WKREF1 and 2 focused mainly on Category 1 stocks ToR c) called for a “simplified and harmonised set of guidelines for estimating MSY and precautionary reference points applicable in the advice framework across various ICES stock categories.” Ideally the ICES assessment cat- egories should provide equivalent risk across all stocks. This issue was discussed but no recom- mendations emerged. There was no consensus a revised reference point framework was proposed at WKREF2. How- ever, it was agreed that it should be presented here for further discussion at ACOM and other fora. The key feature of the suggested approach is that the stock status evaluation is treated in- dependent of the Advice Rule (AR). The main feature of the system is that the biomass trigger is not linked to a stock status evaluation, it is linked to the expected biomass when fishing at the target fishing mortality, in contrast to the current ICES approach. It also entailed that FMSY would also become an upper limit of fishing mortality and that the advised fishing mortality would be set at or lower than that level. WKREF2 did not discuss what to do in situations where SSB〈 Blim or alternative forms of HCR for the advice rule. Building community understanding and con- sensus around simplified and harmonised guidelines has yet to be achieved. A further workshop WKREF3 will be required to achieve that aim. The report includes 6 recommendations for ACOM consideration.
    Description: ICES
    Description: The main objective of the workshop was to review the recommendations of WKREF1 and con- sider how these might feed into a new reference points framework and guidelines for ICES. There were a number of presentations on the wider issues of best practice for reference points, the Allee effect, density dependence and the WKIRISH approach. The starting point was to try and develop a set of simplified and harmonised guidelines based on the WKREF1 report rather than evolving the current guidelines to include the WKREF1 conclusions. A key aspect of the meeting was to allow for discussions in order to build a shared understanding of the strengths and weakness of the current framework and of the new framework emerging from WKREF1.
    Description: Published
    Description: Non Refereed
    Keywords: ICES ; Reference points ; Management advice ; Fisheries ; Fishery management reference points
    Repository Name: AquaDocs
    Type: Report
    Format: 103pp
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  • 4
    Publication Date: 2022-10-26
    Description: © The Author(s), 2022. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Dowd, S., Chapman, M., Koehn, L., & Hoagland, P. The economic tradeoffs and ecological impacts associated with a potential mesopelagic fishery in the California Current. Ecological Applications, 32(4), (2022): e2578, https://doi.org/10.1002/eap.2578.
    Description: The ocean's mesopelagic zone (200–1000 m) remains one of the most understudied parts of the ocean despite knowledge that mesopelagic fishes are highly abundant. Apex predators from the surface waters are known to consume these fishes, constituting an important ecological interaction. Some countries have begun exploring the potential harvest of mesopelagic fishes to supply fishmeal and fish oil markets due to the high fish abundance in the mesopelagic zone compared with overfished surface waters. This study explored the economic and ecological implications of a moratorium on the harvest of mesopelagic fishes such as lanternfish off the US West Coast, one of the few areas where such resources are managed. We adapted a bioeconomic decision model to examine the tradeoffs between the values gained from a hypothetical mesopelagic fishery with the potential values lost from declines in predators of mesopelagic fishes facing a reduced prey resource. The economic rationale for a moratorium on harvesting mesopelagics was sensitive both to ecological relationships and the scale of the nonmarket values attributed to noncommercial predators. Using a California Current-based ecological simulation model, we found that most modeled predators of mesopelagic fishes increased in biomass even under high mesopelagic harvest rates, but the changes (either increases or decreases) were small, with relatively few predators responding with more than a 10% change in their biomass. While the ecological simulations implied that a commercial mesopelagic fishery might not have large biomass impacts for many species in the California Current system, there is still a need to further explore the various roles of the mesopelagic zone in the ocean.
    Description: Sally Dowd acknowledges sponsorship from the WHOI Summer Student Fellowship and the Rausser College of Natural Resources Honors Program at UC Berkeley. This project would not have been possible without the guidance provided by Kama Thieler and Carl Boettiger. Porter Hoagland acknowledges funding from the Audacious Project, a collaborative endeavor, housed at TED and the J. Seward Johnson Fund in support of the Marine Policy Center at WHOI.
    Keywords: Bioeconomic model ; Fisheries ; Mesopelagic fishes ; Moratorium ; Nonmarket value ; Predators ; Rpath ; Willingness-to-pay values
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 5
    Publication Date: 2022-05-27
    Description: Buesseler, K., Jin, D., Kourantidou, M., Levin, D., Ramakrishna, K., Renaud, P., Ausubel, J., Baltes, K., Gjerde, K., Holland, M., Kostel, K., LaCapra, V., Martin, A., Sosik, H., Thorrold, S., Tierney, T., Joyce, K., Renier, N., Taylor, E. (2022). The Ocean Twilight Zone’s Role in Climate Change. Woods Hole Oceanographic Institution, 32 pp.
    Description: The ocean twilight zone (more formally known as the mesopelagic zone) plays a fundamental role in global climate. It is the mid-ocean region roughly 100 to 1000 meters below the surface, encompassing a half-mile deep belt of water that spans more than two-thirds of our planet. The top of the ocean twilight zone only receives 1% of incident sunlight and the bottom level is void of sunlight. Life in the ocean twilight zone helps to transport billions of metric tons (gigatonnes) of carbon annually from the upper ocean into the deep sea, due in part to processes known as the biological carbon pump. Once carbon moves below roughly 1000 meters depth in the ocean, it can remain out of the atmosphere for centuries to millennia. Without the benefits of the biological carbon pump, the atmospheric CO 2 concentration would increase by approximately 200 ppm 1 which would significantly amplify the negative effects of climate change that the world is currently trying to curtail and reverse. Unfortunately, existing scientific knowledge about this vast zone of the ocean, such as how chemical elements flow through its living systems and the physical environment, is extremely limited, jeopardizing the efforts to improve climate predictions and to inform fisheries management and ocean policy development.
    Description: Funding is: The Audacious Project housed at TED
    Keywords: Climate ; Mesopelagic ; Twilight Zone ; Fisheries ; Carbon Dioxide Removal ; Ocean ; Biological Carbon Pump ; Solubility Pump ; Carbon ; Marine Snow
    Repository Name: Woods Hole Open Access Server
    Type: Other
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  • 6
    Publication Date: 2022-10-26
    Description: © The Author(s), 2021. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Kourantidou, M., Hoagland, P., Dale, A., & Bailey, M. Equitable allocations in northern fisheries: bridging the divide for Labrador Inuit. Frontiers in Marine Science, 8, (2021): 590213, https://doi.org/10.3389/fmars.2021.590213.
    Description: Canada has undertaken commitments to recognize the rights of Indigenous Peoples in fisheries through policies and agreements, including Integrated Fishery Management Plans, the Reconciliation Strategy, and Land Claim Agreements (LCAs). In addition to recognizing rights, these commitments were intended to respect geographic adjacency principles, to enhance the economic viability of Indigenous communities, and to be reflective of community dependence on marine resources. We examined the determinants of quota allocations in commercial fisheries involving Nunatsiavut, Northern Labrador, the first self-governing region for the Inuit peoples in Canada. It has been argued that current fishery allocations for Nunatsiavut Inuit have not satisfied federal commitments to recognize Indigenous rights. Indicators that measure equity in commercial allocations for the turbot or Greenland halibut (Reinhardtius hippoglossoides) and northern shrimp (Pandalus borealis) fisheries were identified and assessed. In these two cases, historical allocations continue to predominate for allocations based upon equity or other social or economic considerations. We illustrate equity-enhancing changes in the quota distribution under scenarios of different levels of inequality aversion, and we make qualitative assessments of the effects of these allocations to Nunatsiavut for socioeconomic welfare. This approach could benefit fisheries governance in Northern Labrador, where federal commitments to equity objectives continue to be endorsed but have not yet been integrated fully into quota allocations.
    Description: This research was undertaken with funding from the Canada First Research Excellence Fund through the Ocean Frontier Institute (MK and MB) and the Johnson Endowment of the Woods Hole Oceanographic Institution’s (WHOI) Marine Policy Center (PH).
    Keywords: Fisheries ; Allocations ; Equity ; Indigenous rights ; Access
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 7
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    In:  aqdchief@seafdec.org.ph | http://aquaticcommons.org/id/eprint/18569 | 2002 | 2015-11-15 16:06:30 | 18569 | Southeast Asian Fisheries Development Center, Aquaculture Department
    Publication Date: 2022-08-02
    Description: This paper summarizes the results of the experiments on the induced breeding and larval rearing of milkfish (Chanos chanos) during the 1979 season. Milkfish larvae could be reared successfully without the use of trochophore larvae of oysters as feed during the first few days. In order to induce the ovulation of wild adult milkfish a higher dose of human chorionic gonadotropin hormone is required.
    Keywords: Fisheries ; Chanos chanos ; ISEW ; Philippines ; marine environment ; Brood stocks ; Fish culture ; Fish larvae ; Food organisms ; Induced breeding ; Larval development ; Sex hormones
    Repository Name: AquaDocs
    Type: article
    Format: application/pdf
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    Format: 1-3
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  • 8
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    In:  library@seafdec.org.ph | http://aquaticcommons.org/id/eprint/20100 | 17342 | 2016-02-24 22:18:26 | 20100 | Southeast Asian Fisheries Development Center, Aquaculture Department
    Publication Date: 2022-08-02
    Description: An outline is given of aquaculture and fisheries in Asia, providing information of use to students whose work can influence laws, rules, policy and regulations on aquaculture and fisheries, with the view in mind to sustainable aquaculture. In this issue, the following countries are examined: China, Indonesia, and Bangladesh.
    Keywords: Aquaculture ; Fisheries ; Fishery management ; Aquaculture development ; Aquaculture regulations ; Marine aquaculture ; Freshwater aquaculture ; Fishery industry ; Asia ; Bangladesh ; China
    Repository Name: AquaDocs
    Type: article
    Format: application/pdf
    Format: application/pdf
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  • 9
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    In:  library@seafdec.org.ph | http://aquaticcommons.org/id/eprint/20067 | 2002 | 2016-03-04 15:16:24 | 20067 | Southeast Asian Fisheries Development Center, Aquaculture Department
    Publication Date: 2022-08-02
    Keywords: Fisheries ; Aquaculture ; Vietnam ; Sri Lanka ; Sri Lanka ; Vietnam ; brackishwater environment ; freshwater environment ; marine environment ; Aquaculture ; Aquaculture techniques ; Brackishwater aquaculture ; Feed ; Fish culture ; Fish diseases ; Fisheries ; Fishery data ; Food organisms ; Freshwater aquaculture ; Marine aquaculture ; Marine fisheries ; Mollusc culture ; Pond culture ; Seaweed culture ; Shrimp culture
    Repository Name: AquaDocs
    Type: article
    Format: application/pdf
    Format: application/pdf
    Format: pp.9-10, 27
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  • 10
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    In:  library@seafdec.org.ph | http://aquaticcommons.org/id/eprint/20055 | 2002 | 2016-03-03 11:33:32 | 20055 | Southeast Asian Fisheries Development Center, Aquaculture Department
    Publication Date: 2022-08-02
    Keywords: Fisheries ; Aquaculture ; Asia ; Cambodia ; India ; Asia ; Cambodia ; India ; Myanmar ; Myanmar ; brackishwater environment ; freshwater environment ; marine environment ; Aquaculture ; Aquaculture development ; Aquaculture economics ; Aquaculture techniques ; Brackishwater aquaculture ; Catching methods ; Culture effects ; Environmental impact ; Fish culture ; Fisheries ; Fishery development ; Fishery resources ; Fishery statistics ; Freshwater aquaculture ; Marine aquaculture ; Shrimp culture ; Sustainability ; Trade
    Repository Name: AquaDocs
    Type: article
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    Format: application/pdf
    Format: pp.9-10, 29
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  • 11
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    Marine Fisheries Research Department, Southeast Asian Fisheries Development Center | Singapore
    In:  http://aquaticcommons.org/id/eprint/26291 | 23782 | 2019-04-08 09:42:05 | 26291 | Southeast Asian Fisheries Development Center, Marine Fisheries Research Department
    Publication Date: 2022-08-02
    Keywords: Fisheries ; Pollution ; Indonesia ; Heavy metals ; Chemical pollution ; Pollution monitoring
    Repository Name: AquaDocs
    Type: book_section
    Format: application/pdf
    Format: application/pdf
    Format: 10-19
    Format: 10
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  • 12
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    Marine Fisheries Research Department, Southeast Asian Fisheries Development Center | Singapore
    In:  http://aquaticcommons.org/id/eprint/26293 | 23782 | 2019-03-22 03:49:21 | 26293 | Southeast Asian Fisheries Development Center, Marine Fisheries Research Department
    Publication Date: 2022-08-02
    Keywords: Fisheries ; Myanmar ; Heavy metals ; Cadmium ; Lead ; Mercury ; Biological sampling ; Fish ; Fishery products ; Seafood
    Repository Name: AquaDocs
    Type: book_section
    Format: application/pdf
    Format: application/pdf
    Format: 38-46
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  • 13
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    Secretariat, Southeast Asian Fisheries Development Center | Bangkok, Thailand
    In:  http://aquaticcommons.org/id/eprint/26259 | 2002 | 2019-03-01 05:56:06 | 26259 | Southeast Asian Fisheries Development Center, Secretariat
    Publication Date: 2022-08-02
    Description: Round scad exploration by purse seine in the waters of western Philippines was conducted from April 22 to May 7, 1998 for a period of five (5) fishing days with a total catch of 7.3 tons and an average of 1.5 tons per setting. Dominant species caught were Decapterus spp. having 70.09% of the total catch, followed by Selar spp. at 12.66% and Rastrelliger spp. 10.70%. Among the Decapterus spp. caught, D. macrosoma attained the highest total catch composition by species having 68.81% followed by D. kurroides and D.russelli with 0.31% and 1.14% respectively. The round scad fishery stock was composed mainly of juvenile fish (less than 13 cm) and Age group II (13 cm to 14 cm). Few large round scad at Age group IV and V (20 cm to 28 cm) stayed at the fishery. Other fishes caught were: Auxis rochei (0.85%), A. thazard (0.12%), Caranx spp. (0.45%), Emmilichthys nitidus (0.58%), Euthynnus affinis (0.42%), Leiognathus ruconius (0.58%), Loligo sp. (0.31%), Megalaspis cordyla (0.09%), Rastrelliger spp. (10.70%), Sardinella longiceps (0.03%), Scomberoides lysan (0.24%), Selar spp. (12.66%), Sphyraena spp. (0.90%), Thunnus albacares (0.96%) and others (1.02%). Tuna and tuna like fishes such as yellowfin tuna, eastern little tuna, bullet tuna, frigate tuna and oceanic squid are distributed in the upper latitudes of the survey area. On the other hand, round scads, big-eyed scads and Indian mackerels are dominantly present in the lower latitudes of the survey area.
    Keywords: Fisheries ; Exploratory fishing ; Purse seining ; Age composition ; Catch composition ; Fishery surveys ; Carangid fisheries ; South China Sea ; Philippines ; Rastrelliger ; Decapterus
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  • 14
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    Training Department, Southeast Asian Fisheries Development Center | Samut Prakarn, Thailand
    In:  http://aquaticcommons.org/id/eprint/26215 | 17342 | 2019-02-08 06:25:54 | 26215 | Southeast Asian Fisheries Development Center, Training Department
    Publication Date: 2022-08-02
    Description: Presented in this paper is the status of the fishery industry in Brunei Darussalam. Specifically, it discussed the following topics: fishery management strategies, zonation scheme, licencing, the use of poisons and explosives, the minimum cod-end mesh size for trawlers, closed areas, enhancement of fishing grounds, and the enforcement activities.
    Keywords: Fisheries ; Fishery resources ; Fishery management ; Fisheries ; Ecological zonation ; Licensing ; Fish poisoning ; Catching methods ; Illegal fishing ; Explosive fishing ; Fishing gear ; Season regulations ; Fishing grounds
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  • 15
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    Marine Fisheries Research Department, Southeast Asian Fisheries Development Center | Singapore
    In:  http://aquaticcommons.org/id/eprint/26295 | 23782 | 2019-03-22 08:39:12 | 26295 | Southeast Asian Fisheries Development Center, Marine Fisheries Research Department
    Publication Date: 2022-08-02
    Keywords: Fisheries ; Thailand ; Cadmium ; Lead ; Mercury ; Biological sampling ; Fish ; Fishery products ; Seafood
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    Type: book_section
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  • 16
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    Marine Fisheries Research Department, Southeast Asian Fisheries Development Center | Singapore
    In:  http://aquaticcommons.org/id/eprint/26292 | 23782 | 2019-03-22 03:43:09 | 26292 | Southeast Asian Fisheries Development Center, Marine Fisheries Research Department
    Publication Date: 2022-08-02
    Keywords: Fisheries ; Malaysia ; Cadmium ; Lead ; Mercury ; Biological sampling ; Fish ; Fishery products ; Seafood
    Repository Name: AquaDocs
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    Format: application/pdf
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  • 17
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    Secretariat, Southeast Asian Fisheries Development Center | Bangkok, Thailand
    In:  http://aquaticcommons.org/id/eprint/26258 | 2002 | 2019-03-01 06:00:19 | 26258 | Southeast Asian Fisheries Development Center, Secretariat
    Publication Date: 2022-08-02
    Description: An exploratory tuna longline fishing survey was conducted using the research and training vessels of the Southeast Asian Fisheries Development Center, the 1,178 GT MV SEAFDEC and the Bureau of Fisheries and Aquatic Resources, the 165 GT MV MAYA-MAYA in the South China Sea Waters, West of the Philippines from April to May, 1998. A total of 3,796 hooks was set in sixteen (16) fishing stations. There were no tuna caught during the entire survey but only minor and irrelevant species like the Pacific lancetfish, sharks and an opah species, Lampris guttatus. The important fishing and oceanographic factors during the survey and other research results on longline are described and analyzed. Additional longline studies within and near the Philippines territorial waters are also presented to substantiate the research results of the joint SEAFDEC/BFAR resource exploratory.
    Keywords: Fisheries ; Exploratory fishing ; Catch composition ; Fishery surveys ; Longlining ; Tuna fisheries ; South China Sea ; Philippines
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  • 18
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    Marine Fisheries Research Department, Southeast Asian Fisheries Development Center | Singapore
    In:  http://aquaticcommons.org/id/eprint/26299 | 23782 | 2019-03-27 06:00:01 | 26299 | Southeast Asian Fisheries Development Center, Marine Fisheries Research Department
    Publication Date: 2022-08-02
    Keywords: Chemistry ; Fisheries ; Malaysia ; Pesticides ; Biological sampling ; Fish ; Fishery products ; Biochemical analysis ; Lethal limits
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  • 19
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    Marine Fisheries Research Department, Southeast Asian Fisheries Development Center | Singapore
    In:  http://aquaticcommons.org/id/eprint/26300 | 23782 | 2019-03-27 05:58:36 | 26300 | Southeast Asian Fisheries Development Center, Marine Fisheries Research Department
    Publication Date: 2022-08-02
    Keywords: Aquaculture ; Chemistry ; Fisheries ; Myanmar ; Pesticides ; Biological sampling ; Fish ; Fishery products ; Lethal limits
    Repository Name: AquaDocs
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    Marine Fisheries Research Department, Southeast Asian Fisheries Development Center | Singapore
    In:  http://aquaticcommons.org/id/eprint/26307 | 23782 | 2019-03-27 03:35:56 | 26307 | Southeast Asian Fisheries Development Center, Marine Fisheries Research Department
    Publication Date: 2022-08-02
    Keywords: Fisheries ; Indonesia ; Histamines ; Biological sampling ; Fish ; Fishery products ; Quality control
    Repository Name: AquaDocs
    Type: book_section
    Format: application/pdf
    Format: application/pdf
    Format: 116-123
    Format: 8
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  • 21
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    Marine Fisheries Research Department, Southeast Asian Fisheries Development Center | Singapore
    In:  http://aquaticcommons.org/id/eprint/26303 | 23782 | 2019-03-27 05:51:15 | 26303 | Southeast Asian Fisheries Development Center, Marine Fisheries Research Department
    Publication Date: 2022-08-02
    Keywords: Chemistry ; Fisheries ; Thailand ; Pesticides ; Biological sampling ; Fish ; Fishery products ; Dried products ; Lethal limits
    Repository Name: AquaDocs
    Type: book_section
    Format: application/pdf
    Format: application/pdf
    Format: 100-105
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  • 22
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    Marine Fisheries Research Department, Southeast Asian Fisheries Development Center | Singapore
    In:  http://aquaticcommons.org/id/eprint/26309 | 23782 | 2019-03-27 03:49:31 | 26309 | Southeast Asian Fisheries Development Center, Marine Fisheries Research Department
    Publication Date: 2022-08-02
    Keywords: Fisheries ; Myanmar ; Histamines ; Biological sampling ; Biochemical analysis ; Fish ; Fishery products
    Repository Name: AquaDocs
    Type: book_section
    Format: application/pdf
    Format: application/pdf
    Format: 129-133
    Format: 5
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  • 23
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    Marine Fisheries Research Department, Southeast Asian Fisheries Development Center | Singapore
    In:  http://aquaticcommons.org/id/eprint/26826 | 23782 | 2019-11-21 00:56:12 | 26826 | Southeast Asian Fisheries Development Center, Marine Fisheries Research Department
    Publication Date: 2022-08-02
    Description: Presented in the paper is the standard procedure in the determination of K value which is an index to measure the enzymatic freshness of fish and squid. Specifically, reagents, apparatus and the analytical procedures needed and the calculations are presented.
    Keywords: Chemistry ; Fisheries ; Manuals ; Culture media ; Analysis ; Analytical techniques ; Methodology ; Chemical analysis ; Fishery products ; Fish inspection ; Fishery industry ; Food technology ; Standards ; Specifications
    Repository Name: AquaDocs
    Type: book_section
    Format: application/pdf
    Format: application/pdf
    Format: B-6.1-B-6.7
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  • 24
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    Marine Fisheries Research Department, Southeast Asian Fisheries Development Center | Singapore
    In:  http://aquaticcommons.org/id/eprint/26825 | 23782 | 2019-11-21 00:52:35 | 26825 | Southeast Asian Fisheries Development Center, Marine Fisheries Research Department
    Publication Date: 2022-08-02
    Description: Presented in the paper is the standard procedure in measuring K value in fish meat by means of the freshness testing paper technique.
    Keywords: Chemistry ; Fisheries ; Manuals ; Culture media ; Analysis ; Analytical techniques ; Methodology ; Chemical analysis ; Fishery products ; Fish inspection ; Fishery industry ; Food technology ; Standards ; Specifications
    Repository Name: AquaDocs
    Type: book_section
    Format: application/pdf
    Format: application/pdf
    Format: B-7.1-B-7.2
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  • 25
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    Marine Fisheries Research Department, Southeast Asian Fisheries Development Center | Singapore
    In:  http://aquaticcommons.org/id/eprint/26802 | 23782 | 2019-11-12 05:28:20 | 26802 | Southeast Asian Fisheries Development Center, Marine Fisheries Research Department
    Publication Date: 2022-08-02
    Description: Presented in the paper is the standard procedure in the measurement of pH in the fresh fish meat. Specifically, the procedures in sampling and sample preparation, apparatus and reagents required, and the analytical procedures are presented.
    Keywords: Chemistry ; Fisheries ; Manuals ; Culture media ; Analysis ; Analytical techniques ; Methodology ; Chemical analysis ; Microbiological analysis ; Fishery products ; Processed fishery products ; Fish inspection ; Fishery industry ; Food additives ; Food technology ; Standards ; Specifications ; pH
    Repository Name: AquaDocs
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    Format: application/pdf
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    Format: A-3.1-A-3.2
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  • 26
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    Marine Fisheries Research Department, Southeast Asian Fisheries Development Center | Singapore
    In:  http://aquaticcommons.org/id/eprint/26842 | 23782 | 2019-11-15 07:54:48 | 26842 | Southeast Asian Fisheries Development Center, Marine Fisheries Research Department
    Publication Date: 2022-08-02
    Description: Starch is commonly used in the production of fish jelly products as an extender and as binding agent. The paper provides the methodology in the determination of starch in fish jelly products. Instructions for sample preparation and the reagents needed are presented. Detailed procedures in the determination of the starch in a sample are provided.
    Keywords: Chemistry ; Fisheries ; Manuals ; Culture media ; Analysis ; Analytical techniques ; Methodology ; Chemical analysis ; Fishery products ; Fishery industry ; Food technology ; Standards ; Specifications ; Starch ; Additives ; Food additives
    Repository Name: AquaDocs
    Type: book_section
    Format: application/pdf
    Format: application/pdf
    Format: D-4.1-D-4.4
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  • 27
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    Marine Fisheries Research Department, Southeast Asian Fisheries Development Center | Singapore
    In:  http://aquaticcommons.org/id/eprint/26881 | 23782 | 2019-11-05 02:46:02 | 26881 | Southeast Asian Fisheries Development Center, Marine Fisheries Research Department
    Publication Date: 2022-08-02
    Description: Monitoring and investigative work undertaken in the Philippines regarding dinoflagellate blooms are described. Chronological observations of the occurrence of red tides, aerial surveys, spatial distribution of the dinoflagellate and the physical environment are discussed. Fishing and the examination of gut content of fish and mussels and bioassay tests are detailed. Incidents of paralytic shellfish poisoning in the Philippines are considered briefly.
    Keywords: Fisheries ; Health ; Environmental monitoring ; Red tides ; Public health ; Medicine ; Dangerous organisms ; Philippines
    Repository Name: AquaDocs
    Type: book_section
    Format: application/pdf
    Format: application/pdf
    Format: 52-79
    Format: 28
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  • 28
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    Marine Fisheries Research Department, Southeast Asian Fisheries Development Center | Singapore
    In:  http://aquaticcommons.org/id/eprint/26885 | 23782 | 2019-11-05 02:23:34 | 26885 | Southeast Asian Fisheries Development Center, Marine Fisheries Research Department
    Publication Date: 2022-08-02
    Description: A report is made of the first incidence occurring of paralytic shellfish poisoning in Thailand in May 1983, following an extensive bloom of Trichodesmium erythraeum. Investigations undertaken regarding the source of the toxicity are outlined.
    Keywords: Fisheries ; Health ; Biological poisons ; Public health ; Red tides ; Shellfish ; Dangerous organisms ; Thailand
    Repository Name: AquaDocs
    Type: book_section
    Format: application/pdf
    Format: application/pdf
    Format: 90-91
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  • 29
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    Marine Fisheries Research Department, Southeast Asian Fisheries Development Center | Singapore
    In:  http://aquaticcommons.org/id/eprint/26879 | 23782 | 2019-11-05 02:54:38 | 26879 | Southeast Asian Fisheries Development Center, Marine Fisheries Research Department
    Publication Date: 2022-08-02
    Description: A brief account is given of recent cases of paralytic shellfish poisoning in Sabah, Malaysia, and toxicological studies undertaken. Hydrography surveys, underwater observations after the occurrence of the red tides and plankton studies and monitoring of red tides are discussed.
    Keywords: Fisheries ; Health ; Shellfish ; Toxicity tests ; Red tides ; Public health ; Dangerous organisms ; Malaysia
    Repository Name: AquaDocs
    Type: book_section
    Format: application/pdf
    Format: application/pdf
    Format: 35-42
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  • 30
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    Marine Fisheries Research Department, Southeast Asian Fisheries Development Center | Singapore
    In:  http://aquaticcommons.org/id/eprint/26852 | 23782 | 2019-11-15 07:36:44 | 26852 | Southeast Asian Fisheries Development Center, Marine Fisheries Research Department
    Publication Date: 2022-08-02
    Description: Cholera is an acute specific infection caused by the organism, Vibrio cholera. Diagnosis may be confirmed by the presence of large numbers of the comma-shaped bacilli on direct microscopic examination of a fecal or vomitus smear, and by the isolation of the organism on culture. Fish and shellfish have been identified as vehicles of cholera. Large numbers of V. cholera must usually be ingested to cause cholera. Thus problems often occur when poor handling and inadequate refrigeration have allowed the organism to multiply. Presented in the paper is the methodology of determining the presence of Vibrio cholera in fish and fishery products.
    Keywords: Chemistry ; Fisheries ; Manuals ; Culture media ; Analysis ; Analytical techniques ; Methodology ; Fishery products ; Fishery industry ; Food technology ; Standards ; Specifications ; Aerobic bacteria ; Microbiological analysis ; Microorganisms ; Pathogenic bacteria ; Pathogens ; Health and safety ; Public health ; Microbial contamination ; Vibrio cholerae
    Repository Name: AquaDocs
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    Format: E-7.1-E-7.5
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    Secretariat, Southeast Asian Fisheries Development Center | Bangkok, Thailand
    In:  http://aquaticcommons.org/id/eprint/26890 | 23782 | 2019-11-14 01:01:29 | 26890 | Southeast Asian Fisheries Development Center, Secretariat
    Publication Date: 2022-08-02
    Description: Fishery statistics in Brunei Darussalam have been collected by the Department of Fisheries since the 1940s. In the early 1980s, a number of statistics were collected, such as catch and effort data of artisanal fishermen, aquaculture statistics, processing statistics as well as data from major wet markets focusing on the amount, prices of marketed fish either from the local fishermen or imported. In 1984, the collection of statistics on commercial fishing was started. The statistics have been used in the formulation of fishery management and development policies as well as for sectoral development. Following a brief account of the responsibility and statistic collections of the Department of Fisheries, an examination is made of employment in the fishery sector, fisheries production, fish marketed and the GDP for the fishery industry. Fisheries in Brunei Darussalam is a very healthy industry, where production is well below the maximum allowable harvestable limit of 20,000 tons at 30%. The Department is embarking to increase production from the capture fishery to reduce the country's dependence on imported fish; the same applies for aquaculture, in order to complement production from the capture fisheries. The processing sector is also increasing in importance, especially with the increase in the number of capture fishery licenses, and the demand for quality and value-added products.
    Keywords: Fisheries ; Marine fisheries ; Fishery statistics ; Aquaculture development ; Aquaculture statistics ; Fish catch statistics ; Marine aquaculture ; Freshwater aquaculture ; Fishery development ; Marine ; Brackish ; Freshwater
    Repository Name: AquaDocs
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    Format: application/pdf
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    Marine Fisheries Research Department, Southeast Asian Fisheries Development Center | Singapore
    In:  http://aquaticcommons.org/id/eprint/26843 | 23782 | 2019-11-15 07:52:55 | 26843 | Southeast Asian Fisheries Development Center, Marine Fisheries Research Department
    Publication Date: 2022-08-02
    Description: Sodium chloride is an important additive for the production of fish jelly products. It extracts the salt soluble protein to give the gel strength of the final product. The paper provides the methodology in the determination of the amount of sodium chloride in fish jelly products. Instructions for sample preparation and the reagents needed are presented. Detailed procedures in the determination of the salt in a sample are provided.
    Keywords: Chemistry ; Fisheries ; Manuals ; Culture media ; Analysis ; Analytical techniques ; Methodology ; Chemical analysis ; Fishery products ; Fishery industry ; Food technology ; Standards ; Specifications ; Additives ; Food additives ; Salts ; Sodium chloride
    Repository Name: AquaDocs
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    Format: D-5.1-D-5.2
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    Marine Fisheries Research Department, Southeast Asian Fisheries Development Center | Singapore
    In:  http://aquaticcommons.org/id/eprint/26851 | 23782 | 2019-11-14 01:29:31 | 26851 | Southeast Asian Fisheries Development Center, Marine Fisheries Research Department
    Publication Date: 2022-08-02
    Description: Food poisoning due to Vibrio parahaemolyticus is a food-borne infection resulting from the ingestion of a large number of this organism (about 106-109 viable cells). The major symptoms are diarrhea and abdominal pain with headache, fever, and vomiting also occurring. The organisms are excreted during the acute stage of the illness after which they decrease rapidly. The differentiation of V. parahaemolyticus from other pathogenic species of Vibrio is based mainly on salt tolerance, Voges-Proskauer reaction, fermentation of sucrose, and growth at 43°C. Presented in the paper is the methodology of determining the presence of Vibrio cholera in fish and fishery products.
    Keywords: Chemistry ; Fisheries ; Manuals ; Culture media ; Analysis ; Analytical techniques ; Methodology ; Fishery products ; Fishery industry ; Food technology ; Standards ; Specifications ; Aerobic bacteria ; Microbiological analysis ; Microorganisms ; Pathogenic bacteria ; Pathogens ; Health and safety ; Public health ; Microbial contamination ; Vibrio parahaemolyticus ; Vibrio cholerae
    Repository Name: AquaDocs
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    Format: E-8.1-E-8.6
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  • 34
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 87 (1954) 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 35
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Vitamin D2 konnte durch Behandlung mit Bortrifluorid-ätherat unter Verschiebung des gesamten Trien-Systems in ein neues Isomeres umgelagert werden, das als iso-Tachysterin bezeichnet wird.Weiterhin konnte ein iso-Vitamin D2 partialsynthetisch gewonnen werden, wobei der aus Vitamin D2 durch Abbau erhaltene C21-Aldehyd Verwendung fand.Durch Oxydation von iso-Tachysterin sowie durch Umlagerung und Oxydation von iso-Vitamin D2 wurden schließlich identische Trien-ketone erhalten. Die Konfiguration der beiden neuen Isomeren wird im Zusammenhang mit den Ultraviolett-Absorptionsspektren diskutiert.
    Additional Material: 3 Ill.
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  • 36
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 993-997 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Literaturangabe, nach der 1.2-Diphenyl-inden bei der Ozonisierung in anomaler Reaktion o-Benzoyl-benzoin liefert, hat sich als irrtümlich erwiesen; es bildet vielmehr das normale Ozonid.
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  • 37
    Electronic Resource
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    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 1007-1010 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Aus den Blättern von Sol. acaule wurde ein neues Glykoalkaloid, Solacaulin, isoliert. Solacaulin liefert bei der Hydrolyse 1 Mol. Solanidin, 1 Mol. d-Glucose und 2 Moll. d-Xylose.
    Additional Material: 1 Tab.
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  • 38
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 1011-1018 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wird eine Methode zur Darstellung der ersten Glieder von vinylenhomologen Pyrrolaldehyden beschrieben. Diese Verbindungen wurden u.a. charakterisiert durch ihre 2.4-Dinitro-phenylhydrazone. Außerdem konnten mit Hilfe dieser Aldehyde neue unsymmetrische Polymethinfarbstoffe dargestellt werden.
    Additional Material: 2 Tab.
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  • 39
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es werden unsymmetrische Methinfarbstoffe beschrieben, die durch Kondensation von α-Furyl-polyenalen mit Pyrrolen bzw. mit α-Phenyl-indol entstehen. Die Absorptionsspektren wurden qualitativ und z.Tl. quantitativ vermessen.
    Additional Material: 3 Ill.
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  • 40
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 1051-1056 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Neun bi-homologe Reihen, teilweise bis zu einer Alkylkettenlänge von zweimal 20 Kohlenstoff-Atomen, wurden synthetisiert. Der Verlauf der Schmelzpunktskurven dieser bihomologen Reihen wird besprochen.
    Additional Material: 7 Ill.
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  • 41
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die symmetrischen 1.3-Dioxy-3.3-dialkyl-propane wurden durch Reduktion der in der VIII. Mitteil. beschriebenen 3-Oxy-3.3-dialkyl-propionsäuren mit LiAlH4 dargestellt.
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  • 42
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 87 (1954) 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 43
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 1082-1083 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Aus den Samen von Lunaria biennis wird neben Lunarin, C25H31O4N3, ein mit diesem isomeres Alkaloid Lunaridin isoliert.
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  • 44
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 1093-1098 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Durch Reaktion von α-Amino-acyl-thiophenolen mit Schwefel-wasserstoff entstehen die den α-Aminosäuren analogen α-Amino-thiosäuren. Die kristallisierten Analogen des Glycins, Alanins, Valins, Isoleucins und Methionins sind Zwitterionen mit charakteristischen UV-Spektren. Die höheren α-Amino-thiosäuren vermögen mit ihren schwefelfreien Stammsubstanzen Mischkristalle zu bilden.
    Additional Material: 3 Ill.
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  • 45
    Electronic Resource
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    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 1119-1123 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Kondensation von o-Phenylendiamin-hydrochlorid mit Dimethyl-alloxan führt zum 1.3-Dimethyl-alloxazin. Bei der alkalischen Spaltung entsteht als Endprodukt die 3-Methylamino-chinoxalin-carbonsäure-(2).Die entsprechende neutrale Kondensation liefert 3-Oxy-chinoxalin carbonsäure (2) N-methyl-amid, aus dem mit Alkali die 3-Oxychinoxalin-carbonsäure-(2) hervorgeht.
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  • 46
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 1138-1141 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: In 4-Stellung substituierte N-Acetyl-glucosamine geben die Morgan-Elson-Reaktion nicht.
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  • 47
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 1162-1163 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Das Produkt der alkalischen Verseifung von Vinylacetat in Wasser unter 15°, C8H14O4, wird als Acetyl-aldoxan erkannt; bei entsprechender alkalischer Verseifung von Vinylpropionat entsteht Propicnyl-aldoxan.
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  • 48
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Bei der Umsetzung von Acyl-aryl-acetonitrilen mit Guanidin bildeten sich nicht die erwarteten Pyrimidinderivate, sondern 1.3.5-Triazine. Auch wenn man die Anilinverbindung des α-Formyl-α-p-chlorphenyl-acetonitrils mit Guanidin reagieren lieβ, erhielt man ein Triazin; aus den Anilinderivaten der homologen Acyl-Verbindungen bildeten sich die entsprechenden Pyrimidine. Andere Reaktionsprodukte der Ketogruppe der Acyl-aryl-acetonitrile, wie das Oxim, das Semicarbazon und das Phenylhydrazon konnten nicht isoliert werden, weil sofort ein Ringschluß mit der Nitrilgruppe eintrat, wie durch die Aufnahme der UR-Spektren nachgewiesen wurde.Die Umsetzung der Nitrile mit Hydroxylamin führte zu den Amino-bzw. Imino-isoxazolen, die durch Säuren zu 5-Oxy-isoxazolen verseift wurden.
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  • 49
    Electronic Resource
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    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 1197-1200 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Ausgehend von der Furylvaleriansäure wurde über das Furocycloheptenon ein Oxy-furo-tropolon synthetisch gewonnen.
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  • 50
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 1201-1205 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Während Alkylhydroperoxyde bei der katalytischen Zersetzung mit CoII-Salzen symmetrische Dialkyl-peroxyde geben, setzen sie sich i. Ggw. von Cycloalkenen und Hydroaromaten bei der gleichen Behandlung zu gemischten Dialkyl-peroxyden um.
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  • 51
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 1219-1225 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Bei der Umsetzung von Acetylen-Kohlenwasserstoffen R-C≡C-R' mit Peressigsäure erfolgt neben der oxydativen Spaltung zu R-CO2H+R'-CO2H eine mit Oxydation verknüpfte Umlagerung des Kohlenstoff-Gerüstes zu disubstituierten Essigsäuren RR'CH·CO2H. Aus Di-acetylen-Verbindungen erhält man α,α'-di-substituierte Dicarbonsäuren. Diese Reaktion, die vermutlich über die Ketene RR'C=C=O verläuft und in ihrem Wesen der Schröterschen und der Buckleyschen Umlagerung verwandt erscheint, ist ein neuer Weg zur Darstellung α-verzweigter Fettsäuren.
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  • 52
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die bi-homologe Reihe der symmetrischen Phenyl-dialkyl-methanole wurde bis zum Phenyl-di-eikosyl-methanol durch Kondensation von Phenyl-magnesiumbromid mit symmetrischen Dialkyl-ketonen hergestellt.
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  • 53
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Kondensation von 3-Chlor-butanon-(2) bzw.α-Brom-propanal mit Thiosemicarbazid führt in schwach saurem Medium zu den entsprechenden Thiosemicarbazonen Ia und Ib, die sich in alkoholischer Lösung zum 2-Amino-5.6-dimethyl- (IIa) bzw. 2-Amino-6-methyl-1.3.4-thiodiazin (IIb) cyclisieren. Letztere lagern sich beim Erhitzen mit starker Salzsäure in das 3-Amino-4.5-dimethyl (IVa) bzw. 3-Amino-5-methyl-thiazolon-(2)-imid (IVb) um. Beide Verbindungen werden durch Salpetrige Säure desaminiert. Der Nachweis der hierbei gebildeten, substituierten 2-Amino-thiazole erfolgt durch Diazotierung und Kupplung zu Azofarbstoffen. Bei Einwirkung von Benzaldehyd gehen die beiden obengenannten Thiodiazine in die Benzalverbindungen des 4.5-Dimethyl- (Va) bzw. 5-Methyl-thiazolyl-(2)-hydrazins (Vb) über. Auch diese lagern sich unter dem Einfluß von H-Ionen in die entsprechenden Thiazolon-(2)-imide um.Zum Strukturbeweis der bei den einzelnen intramolekularen Umlagerungen auftretenden Endprodukte werden diese auf anderem Wege synthetisch dargestellt. Ferner wird eine Synthese des 5.5'-Dimethyl-azothiazols beschrieben.Als brauchbarer Nachweis für Thiazolyl-(2)-hydrazine hat sich deren Dehydrierung mit Quecksilberoxyd unter Bildung der entsprechenden Thiazolderivate erwiesen.
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  • 54
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 1179-1183 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wird ein technisch anwendbares Verfahren zur Darstellung von Chinolinaldehyden durch katalytische Oxydation der entsprechenden Methylchinoline beschrieben.
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  • 55
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 1184-1186 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Versuchsbedingungen für die Bildung der einzelnen bei der Einwirkung von Schwefelsäure auf 2-Acetylamino-thiophen entstehenden Sulfonsäuren wurden ausgearbeitet und diese in Form der freien Säuren isoliert. Aus 2-Amino-thiophen-disulfonsäure-(3.5) wurde über die Diazoverbindung Thiophen-disulfonsäure-(3.5), aus 2-Acetylamino-sulfonsäure-(5) die 2-Amino-thiophen-sulfonsäure-(5) dargestellt. Diese unterscheidet sich in ihren chemischen Eigenschaften deutlich von der Sulfanilsäure, dem entsprechenden Benzolderivat.
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  • 56
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Aus der 2-Acetylamino-thiophen-sulfonsäure-(5) wurde das Sulfonsäurechlorid dargestellt, aus dem das Sulfonamid, das Sulfanilid, das Sulfonamidopyridin-Derivat und der Sulfonsäure-äthylester erhalten wurden.
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  • 57
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 1449-1460 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Reine geminale Chlor-nitroso-Verbindungen sowie durch Radikal-Reaktionen erzeugte Gemische dieser Stoffe werden durch katalytische Hydrierung, Lithiumaluminiumhydrid, Natriumborhydrid oder durch rotes Licht mit zum Teil sehr guten Ausbeuten zu den entsprechenden Ketoximen reduziert.
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  • 58
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wurden die Additionsprodukte von Phenanthrenchinon an d-Xylal und an Cellobial hergestellt.
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  • 59
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 1511-1512 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Herstellung des Diphenylena mit verbesserter Ausbeute wird beschrieben.
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  • 60
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 1513-1540 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Enolisierbare β-Diketone zeigen, [amphotere Halochromie], d. h. das Absorptions-Maximum der Enolform wird sowohl in alkalischer Lösung wie auch in starker Schwefelsäure nach längeren Wellen verschoben (aci- bzw. Onium-Halochromie). Bei trans-fixierten β-Diketonen geben die Absorptionskurven im pH-Bereich zwischen etwa +15 und -10 durch einen mehr oder weniger ausgeprägten isosbestischen Punkt; bei offenkettigen und, [cis-fixierten] β-Diketonen überlagert das Keto-Enol-Gleichgewicht die amphoteren Neutralisierungs-Gleichgewichte. Durch Isolierung und Analyse kristalliner Perchlorate und Sulfate lieβ sich erweisen, daβ sich mit den genannten Säuren Enol-Oxonium-Salze bilden. Diese besitzen ein ähnliches mesomeres Chromophor-System wie die Enolate, was die Ähnlichkeit der Absorptions-Kurven erklärt.Die, Onium-[Halochromie] von enolisierbaren β-Benzoyl-ketonen führt zu einer größeren bathochromen Verschiebung und Intensitäts-Erhöhung des Absorptions-Maximums als die, aci-[Halochromie] der gleichen β-Diketone; als Grund dafür wird angesehen, daβ sich nur im ersten Falle die Phenylringe am Zustandekommen des neuen Chromophors beteiligen.Aus den optischen Daten in Schwefelsäuren verschiedener Konzentration wird die, [Basizität] der β-Diketone berechnet.Beim Stehenlassen der stark sauren Lösungen der β-Diketone treten Änderungen der Spektren ein, die auf einer Säure-Spaltung in je eine Molekel Mono-Keton und Carbonsäure beruhen.
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Bromessigester-Kondensation läβt sich mit 1.3-Dioxo-8.10-dimethyl-dekalin ähnlich wie mit Dimedon ausführen. Sie führt zu einer C-substituierten Diketo-dekalin-essigsäure, die der Santonin-Reihe nahesteht. Deren Reduktion zu der wichtigen Monoketosäure gelingt katalytisch über die Enol-Acetate. Weiter wird gefunden, daβ sich auch die Enol-Äther cyclischer 1.3-Diketone katalytisch zu Monoketonen reduzieren lassen.
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  • 62
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 1373-1377 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Durch Anlagerung von Chlorjod an 1.2-Dialkoxy-äthene werden 1.2-Dichlor-1.2-dialkoxy-äthane und elementares Jod erhalten. In Gegenwart von Pyridin bilden sich äquimolare Mengen N,N'-[1.2-Dialkoxy-äthylen]-bis-pyridiniumchloride und -bis-pyridiniumjodide.
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  • 63
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 1711-1713 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die in der Literatur als „Dinaphthol“ bezeichnete, durch Schmelzen von 2-Oxy-naphthaldehyd-(1) mit Kaliumhydroxyd bzw. durch Erhitzen von 1-Diazo-naphthol (2) mit methanolischer Kalilauge erhältliche Substanz ist in Wirklichkeit Bis-[2-oxy-naphthyl-(1)]-methan.
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  • 64
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Für die Enthalogenierung der vicinalen Dibromide mit Jodid-Ion wird ein kationischer Mechanismus vorgeschlagen. Die erhaltenen Versuchsergebnisse sprechen dafür, daß α,β-Dibrom-propyl-phenol-äther mit Jodid-Ionen unter Abspaltung des α-ständigen Brom-Atoms Carbenium-β-bromo-jodo-jodide ergeben, die z. Tl. intramolekular den Polyhaloid-Komplex abspalten und in die entsprechenden Olefine übergehen, z.Tl. sich aber einem Propenylphenoläther-Molekül unter Bildung von Dimeren anlagern. Das im letztgenannten Fall zuerst entstehende Verkettungsprodukt ergibt erst bei Berührung mit Wasser das entsprechende halogenfreie 2-Methyl-3-äthyl-1-phenyl-indan.
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  • 65
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Enthalogenierung der α,β-Dibrom-propylphenoläther mit Kupfer verläuft anscheinend über das Radikal Ar-CH-CHBr-CH3 und führt teils zu dem entsprechenden Propenylphenoläther, teils zu einem 3α-brom-substituierten Methronol.Aus dem α,β-Dibromid des Isoeugenol-benzyläthers wurde mit Kupfer 3α-Brom-diisoeugenol-dibenzyläther (Va) erhalten, aus wel-chem das trans-cis-Racemat des Diisoeugenols (VIIa) hergestellt wurde.
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 1752-1759 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wird gezeigt, daß in der aus Cyclopentadien-kalium (bzw. Cyclopentadienyl-magnesiumbromid) und Kohlendioxyd hergestellten Cyclopentadien-carbonsäure die Carboxygruppe nicht, wie bisher angenommen, in 5- sondern in 1-Stellung haftet.
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 1547-1552 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Durch katalytische Hydrierung von Lactosazon erhält man nebeneinander Lactosamin (2-Desoxy-2-amino-lactose) und Isolactosamin (1-Desoxy-1-amino-lactulose). Nach Peracetylierung und anschließender Ammonolyse wurden N-Acetyl-lactosamin (2-Acetamino-lactose) und N-Acetyl isolactosamin (1 Acetamino-lactulose) chromatographisch getrennt. Die so synthetisch gewonnene 2-Acetamino-lactose ist in allen Eigenschaften identisch mit dem durch partielle Hydrolyse von Blutgruppen-Substanzen erhaltener Disaccharid.
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 1600-1604 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Unter Verwendung von Methylanilino-magnesiumbromid als Kondensationsmittel wurde aus Korksäure-dinitril das 1-Cyan-cycloheptanon-(2) in 75-proz. Ausbeute gewonnen, das u. a. durch Hydrazinhydrat in 5-Amino-3.4-pentamethylen-pyrazol, durch Monobromaceton cyclisierend in 5-Methyl-2.3-pentamethylen-furan übergeführt wurde.
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 35-37 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Natriumverbindung anmethylierter Saccharose reagiert in ätherischer Lösung mit Dimethylsulfat schnell und vollständig unter Bildung von Oktamethyl-saccharose.
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    Keywords: Chemistry ; Inorganic Chemistry
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    Topics: Chemistry and Pharmacology
    Notes: Die bei der Reaktion von [Co(CO)4]2 mit Aminen und Alkoholen beobachtete Valenzdisproportionierung des Carbonylmetalls: \documentclass{article}\pagestyle{empty}\begin{document}$$ 3{\rm{Co}}^0 \to {\rm{Co}}^{ \oplus \oplus } + 2{\rm{Co}}^ \odot $$\end{document} tritt sinngemäß beim tetrameren Kobalt-tricarbonyl ein. Entsprechend: \documentclass{article}\pagestyle{empty}\begin{document}$$ 3\left[ {{\rm{Co}}\left( {{\rm{CO}}} \right)_3 } \right]_4 + 24{\rm{B}} \to 4\left[ {{\rm{CoB}}_6 } \right]\left[ {{\rm{Co}}\left( {{\rm{CO}}} \right)_4 } \right]_2 + 4{\rm{CO}}\left( {{\rm{B}} = {\rm{N - oder O - Base}}} \right) $$\end{document}Außer Aminen und Alkoholen sind andere N- und O-Basen, wie z. B. Nitrile, Säureamide, Ketone und cyclische Äther zu dieser Umsetzung befähigt. Zwischenstufen der Reaktion mit CO-haltigen Kationen konnten nicht nachgewiesen werden. Stärker basische Amine, wie z. B. Methylamin, Dimethylamin und Piperidin, werden durch das bei der Umsetzung entbundene CO carbonyliert.Der Chemismus der Reaktion wird mit der Struktur der mehrkernigen Carbonyle in Zusammenhang gebracht.
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 38-45 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: In der Tetramethyl-d-glucose und Tetramethyl-d-fructose konnte der Wasserstoff des Lactolhydroxyls durch Alkalimetall ersetzt werden. Konfiguration und Reaktionsfähigkeit der Alkalimetallverbindungen wurden durch Umsetzung mit Methyljodid und Dimethylsulfat, die zu den entsprechenden Glykosiden führte, ermittelt. Die Kalium-Verbindung der 2.3.4.6-Tetramethyl-d-glucose reagierte mit α-1-Tosyl-, α-1-Brom- und β-1-Chlor-2.3.4.6-Tetramethyl-d-glucose unter Bildung von Disacchariden des Trehalosetypus.
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  • 72
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wird eine allgemeine Methode zur Darstellung der 5-Amino-1.2.4-thiodiazole beschrieben, die sich auf die Umsetzung von N-Halogen-amidinen mit Rhodaniden gründet. Auf die Eigenschaften dieser Stoffe, einige Derivate - darunter die Sulfanilamide - und Abbaureaktionen wird näher eingegangen.
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  • 73
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Durch Umsetzung der 5-Amino-1.2.4-thiodiazole mit Methyljodid oder durch Ringschluß-Synthesen werden die im Kern methylierten Imino-thiodiazoline erhalten. Die exocyclisch methylierten Amine sind über die 5-Chlor-Verbindung zugänglich, gelegentlich auch durch Umlagerung aus dem entsprechenden Thiodiazolin. Beide Klassen, von deren Hauptvertretern eine Anzahl Substitutions- und Abbauprodukte hergestellt wurden, unterscheiden sich charakteristisch in ihren Basizitäten, UV-Spektren und Polarogrammen. Aus den Befunden wird geschlossen, daß die tautomeren 5-Amino-thiodiazole als Amine vorliegen.
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wird die Darstellung des 2-[d-gluco-Pentaoxy-pentyl]-4-phenyl-thiazols beschrieben.Aus der Literatur sind zahlreiche Verbindungen bekannt, bei denen der Einbau einer Zuckerkette in heterocyclische Ringsysteme in der Weise erfolgte, daß ein, zwei oder auch drei Kohlenstoffatome des Zuckermoleküls dem Heterocyclus angehören. Wir verweisen in diesem Zusammenhang auf das kürzlich erschienene Referat „Heterocyclische Verbindungen aus Zuckern“ von H. Vogel1). Danach und nach unserer Kenntnis ist es bisher nicht gelungen, einfache Zucker in den Thiazolkern einzubauen. Lediglich in einem Fall war es durch Kondensation von einfachen Zuckern mit Cystein möglich, zu Zuckerabkömmlingen der Thiazolidin-carbonsäure (4)2) zu kommen.Für die von uns geplanten Untersuchungen war die Arbeit von C. Neuberg und H. Wolff3) von Interesse, wonach bei der Einwirkung von Phenyl- bzw. Allyl-senföl auf d-Glucosamin in glatter Reaktion 1-Phenyl (bzw. Allyl)-2-mercapto-4-[d-arabo-tetraoxy-butyl]-imidazol entsteht. Als Zwischenprodukt bildet sich hierbei N-[Anilino-thioformyl]-[bzw. N-(Allylamino-thioformyl])-d-glucosamin, das anschließend unter Wasseraustritt in das Imidazolderivat übergeht. Demnach reagiert bei gleichzeitiger Anwesenheit einer Sulfhydryl- und einer sekundaren Aminogruppe bevorzugt die letztere. Würde sich die SH-Gruppe an der Wasserabspaltung beteiligen, so müßte ein Thiazolylzucker entstehen, in dem die C-Atome 1 und 2 des Glucosemoleküls dem Thiazolring angehören. Eine derartige Kondensation ließ sich bisher nicht realisieren. Ein weiteres Beispiel dafür, daß das lactolische Hydroxyl des Zuckers vornehmlich mit einer Aminogruppe reagiert, ist die Bildung des d-Glucose-thioharnstoffs4) aus der d-Glucose und Thioharnstoff in Gegenwart von Salzsäure.
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die drei stereoisomeren Dihydro-santene werden dargestellt und optisch untersucht. Ein durch katalytische Hydrierung von Santen erhaltenes Dihydro-santen erweist sich in bezug auf die Methylgruppen als endo-cis-Verbindung. Die Anlagerung von Wasserstoff erfolgt sterisch “von der Brücke her” und stellt einen weiteren Fall von “exo-Addition” vor.
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 179-186 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Während bisher ausschließlich die synthetisch schwer zugängliche 4-Nitro-salicylsäure als Ausgangsmaterial zur Herstellung von Dialkylaminoalkyl-estern der 4-Amino- und 4-Alkamino-2-alkoxybenzoesäuren diente, wird jetzt die Herstellung dieser Verbindungen ausgehend von der Stammsubstanz, der heute leicht erhältlichen 4-Amino-salicylsäure (PAS), beschrieben.
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Das noch nicht näher charakterisierte Proazulen der Schafgarbe (“M-Proazulen”) läßt sich durch alkalische Verseifung über eine Zwischenstufe in eine intensiv blaue, unbeständige Cham-Azulencarbonsäure überführen, die einen gut kristallsierenden, tiefblauen, stabilen Methylester gibt, dessen Analyse zeigte daß dem zugrundeliegenden Cham-Azulen - in Übereinstimmung mit einer kürzlich erschienen Arbeit von A. Meisels und A. Weizmann1) - die Formel C14H16 zukommt. Die Cham-Azulencarbonsäure geht unter den Bedingungen der Wasserdampfdestillation leicht in Cham-Azulen über.
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Durch Orthoesterbildung mit cis-Phloroglucit können Carboxygruppen vorübergehend gegen den Angriff von metallorganischen Verbindungen geschützt werden. Am Beispiel eines Halb-Orthoesters der Bernsteinsäure wird die präparative Bedeutung dieser Maskierung gezeigt.
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die p-Nitro-homohydratropasäure wird sowohl durch Umlagerung des 1-[p-Nitro-phenyl] -3-diazo-butanons-(2), als auch durch Verseifung und Decarboxylierung des α-[p-Nitro-benzyl]-α eyan-propion, säureesters, der durch Kondensation von p-Nitro-benzylchlorid mit Natrium-α-cyan-propionsäure-ester gut zugänglich ist, gewonnen. Für die m-Verbindung wird nur der zweite Weg beschrieben.
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 211-215 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 2.3.4.6-Tetraacetyl-β-d-glucose läßt sich nach der Trifluoressigsäure-anhydrid-Methode von Stacey mit Benzoesäure zu einem Gemisch von α- und β-2.3.4.6-Tetraacetyl-benzoyl-d-glucose benzoylieren. Das Verhältnis α:β-Verbindung hängt von den Versuchsbedingungen ab. Aus Benzyl-β-d-glucosid ist durch Umsetzung mit Trifluoressigsäure-anhydrid und Natriumtrifluoracetat das 2.3.4.6- Tetrakis-trifluoracetyl-benzyl-β-d-glucosid vomSchmp. 102° leicht darstellbar; die Benzyl-Gruppe konnte aber durch katalytische Hydrierung nicht entfernt werden. Falls dies gelänge, wäre es durch Veresterung mit Carbonsäuren in 1-Stellung nach Stacey und Umesterung durch Erwärmen mit Methanol möglich gewesen, in 1-Stellung beliebig veresterte Glucosen (und andere Zucker) herzustellen. Schließlich wird die Pentakis-trifluoracetyl-β-d-glucose beschrieben.
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  • 81
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 209-211 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Darstellung von 3.3-Dimethyl-1.5-diphenyl-pentan-dion-(1.5) aus β.β-Dimethyl-glutarsäure auf zwei verschiedenen Wegen wird beschrieben.
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  • 82
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wird die Spaltung der p-Nitro-hydratropasäure in die optischen Antipoden beschrieben. Weiter werden sowohl die racemischen als auch die optisch-aktiven p-Amino-, p-Oxy- und p-Chlor-hydratropasäuren gewonnen.
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  • 83
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 221-222 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Darstellung des α-[m-Nitro-phenyl]-äthylamins und seine Spaltung in optische Antipoden wird beschrieben. Die Rotationsdispersion des Hydrochlorids und der Acetylverbindung wird mitgeteilt.
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  • 84
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 232-233 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die katalytische Hydrierung des 1-Cyanäthyl-naphthols-(2) (I) führt zu 1.2.3.4-Tetrahydro-5.6-benzochinolin (III).
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  • 85
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Kondensation von 1-Phenyl-thiosemicarbazid mit α-Halogenketonen führt in Abhängigkeit von der Wasserstoffionenkonzentration zu 2-Phenylhydrazino-thiazolen bzw. deren benzidinartig umgelagerten Produkten oder zu 2-Amino-4-phenyl-1.3.4-thiodiazinen. Es wird über die Darstellung einiger 2-Amino-4-phenyl-1.3.4-thiodiazine und des 2-Phenylhydrazino-4.5-dimethyl-thiazols berichtet. Eine Umlagerung der 2-Phenylhydrazino-thiazole durch Salzsäure in die 2-Amino-4-phenyl-1.3.4-thiodiazine trat nicht ein.
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  • 86
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 228-231 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Ausgehend von m-Nitro-benzaldehyd, wird unter Verwendung der Japp-Klingemann-Reaktion und der Fischer-Cyclisierung die Synthese der Indol-diessigsäuren-(3.4) und -(3.6) beschrieben. Die Säuren lassen sich zu den entsprechenden Dimethylindolen decarboxylieren.
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  • 87
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 233-237 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Das Additionsprodukt von Phenanthrenchinon an Triacetyl-d-glucal wurde näher untersucht. Ausgehend von dieser Substanz wurde - als Modellversuch - Gentiobiose synthetisch dargestellt.
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  • 88
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 237-247 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Addition von Maleinsäure-anhydrid an α-Brom-styrol verläuft unter Abspaltung von Bromwasserstoff und führt in glatter Reaktion zur 1.2-Dihydro-naphthalin-dicarbonsäure-(1.2), die sich successive in die isomeren 1.4- und 3.4-Dihydro-säuren umlagern läßt. In der Literatur beschriebene und auf anderen Wegen gewonnene Präparate werden in ihrer Struktur bestätigt oder berichtigt.Durch Einwirkung von Acrylsäure auf α-Brom-styrol läßt sich auf die gleiche Weise die noch unbekannte 1.2 Dihydro-naphthoesäure-(1) darstellen.Versuche einer Addition von β-Brom-styrol, α.β-Dibrom-styrol und β.β-Dibrom-styrol an Maleinsäure-anhydrid werden beschrieben.
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  • 89
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 248-256 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Aus aliphatischen Aminosäuren (Glykokoll und d, l-Alanin) bilden sich mit 2 Moll. Trifluoressigsäure-anhydrid gemischte Anhydride aus N-Trifluoracetyl-aminosäure und Trifluoressigsäure. Mit l-Alanin tritt hierbei Racemisierung ein. Diese gemischten Anhydride können in die symmetrischen N-Trifluoracetyl-aminosäure-anhydride über-geführt werden, die, wie die gemischten Anhydride, mit Anilin oder Glycinäthylester N-Triflucracetyl-aminosäure-anilide bzw. N-Trifluoracetyl-peptidester geben. Nach der Säurechlorid-Methode läßt sich aus N-Trifluoracetyl-l-alanin das N-Trifluoracetyl-l-alanyl-anilid herstellen. Von der Glutaminsäure ist das innere N-Trifluoracetyl-l-glutaminsäure-anhydrid ohne Racemisierung erhältlich. Aus p-Amino-benzoesäure werden über die 4-[N-Trifluoracetylamino]-benzoesäure und das Säurechlorid 4-[N-Trifluorcetylamino]-benzoesäure-peptide gewonnen mit Glycinäthylester, l-Glutaminsäure-diäthylester und p-Aminobenzoesäure-äthylester.Auf die ziemlich leicht erfolgende alkalische Verseifbarkeit von N-Trifluoracetyl-Verbindungen ist schon hingewiesen worden1).
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  • 90
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 262-266 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Durch Umsetzung von ω-Brom-acetophenon mit Zink und Crotonaldehyd wurde Sorbophenon, C6H5·CO·CH:CH·CH:CH·CH3, erhalten. Die analoge Reaktion mit Sorbinaldehyd führte zum 1-Phenyl-octatrienon-(1), C6H5·CO·CH:CH·CH:CH·CH:CH·CH3. Es handelt sich um eine Modifikation der Reformatsky-Synthese, die nun auch zur Darstellung von Ketonen Verwendung finden kann.
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  • 91
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 257-261 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Durch Reduktion von 4.8-Dimethyl-azulen-carbonsäure-(6)-äthylester mit Lithiumaluminiumhydrid werden 4.8-Dimethyl 6-oxy-methyl-azulen und hieraus 4.8-Dimethyl-azulen-aldehyd-(6) hergestellt. Die neuen Azulene werden durch Derivate und durch ihre Absorptionsspektren im Sichtbaren und im Ultrarot charakterisiert.
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  • 92
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 19-24 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Formamid und Formyl-guanidin kondensieren zu 2-Amino-1.3.5-triazin. Diese Reaktion ist jedoch nicht verallgemeinerungsfähig. Die verschiedenen anomalen Reaktionen des Aminotriazins und des 2-Amino-4.6-dimethyl-triazins führen zu dem Schluß, daß diese Verbindungen nicht die ihnen bisher zugeschriebene Struktur besitzen können, sondern als Imino-dihydro-triazine vorliegen müssen.
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  • 93
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 13-18 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Kojisäure-monomethyläther läßt sich durch Oxydation mit Salpetersäure oder Luftsauerstoff i. Ggw. eines Platin-Katalysators in Komensäure-methyläther überführen. Auf einem neuen Wege wird die 5-Stellung der Oxy-Gruppe in den aus Mekonsäure und Kojisäure erhaltenen Pyron- und Pyridonderivaten bestätigt und damit eine neuerdings vertretene abweichende Auffassung widerlegt.
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  • 94
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 922-934 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Dehydriert man unter geeigneten Bedingungen das 2.4.6-Tri-tert.-butyl-phenol, so erhält man eine tiefblaue Lösung, aus der sich das blaue, feste 2.4.6-Tri-tert.butyl-phenoxyl-(1) gewinnen läßt. Die Substanz ist paramagnetisch. Das chemische und physikalische Verhalten steht mit einer Formulierung als freies Radikal in Übereinstimmung.
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  • 95
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 971-977 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Der Arndt-Eistertsche Säureaufbau, ausgehend vom Diazomethyl-trichlorvinyl-keton und vom Diazomethyl-pentachloräthyl-keton, sowie die Umwandlung des letzteren in verschiedene halogenierte Methyl-pentachloräthyl-ketone werden beschrieben.Perchlorierte Diazoketone, bei denen das Silberoxydverfahren wegen der Alkaliempfindlichkeit oder wegen zu geringer Reaktionsfähigkeit versagt, lassen sich durch Zersetzung im UV-Licht nach Horner glatt in höhere Säuren bzw. Ester überführen.
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  • 96
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 985-990 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wird die Reduktion einiger mono- bzw. disubstituierter Cyanessigsäure-äthylester zu den entsprechenden Aminoalkoholen beschrieben und dargelegt, daβ auch die aliphatisch gebundene Carbäthoxy-Gruppe wie die Keto-Gruppe bei einigen der angeführten Derivate einer vollständigen Reduktion zu der Methyl- bzw. Methylen-Gruppe unter relativ einfachen Bedingungen unterliegen kann, und daβ bei der Reduktion aliphatischer Nitrile auch sekundäre Amine entstehen können.
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  • 97
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 997-1003 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Durch Diensynthese von Cyclopentadien und α-Methyl-acrylsäure entstehen 2 diastereomere 2-Methyl-bicyclo-[1.2.2]-hepten-(5)-carbonsäuren-(2), die durch Hydrierung und anschließenden Curtiusschen Abbau in 2 diastereomere Amine übergeführt werden. Letztere liefern beim Behandeln mit Salpetriger Säure ohne Umlagerung, aber in einem Falle unter Waldenscher Umkehrung, denselben tertiären Alkohol, 2-Methyl-bicyclo-[1.2.2]-heptanol-(2) (= 2-Methyl-norborneol). Dessen Diastereomeres wird durch Grignard-Umsetzung des Norcamphers erhalten.
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  • 98
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 1032-1036 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Auf chemischem Wege wurde nachgewiesen, daβ im Alkaloid Meteloidin, dem Tiglinsäureester des 3.6.7-Trioxy-tropans, der Säurerest am Kohlenstoffatom 3 des Alkamins haftet.
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  • 99
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Untersuchung der Umsetzung von Indol mit Dialkylaminoacetonitrilen läßt erkennen, daß zuerst eine Transaminomethylierung zwischen den beiden Reaktionspartnern unter Bildung von Dialkylamino-skatol und Blausäure stattfindet, worauf sich das Dialkylamino-skatol z. Tl. mit unverändert gebliebenem Indol zu β.β'-Diindolyl-methan, zu einem anderen Teil mit der entstandenen Blausäure zu β-Indolyl-acetonitril umsetzt. Mit Acylamino-malonestern reagieren die Dialkylamino-acetonitrile unter gleichen Bedingungen nicht; sie besitzen also keine cyanomethylierende Fähigkeit. Scheinbare Cyanomethylierungen können erfolgen, wenn durch Transaminomethylierung zwischen Dialkylamino-acetonitril und dem Kondensationspartner  -  wie im Falle des Indols  -  eine tertiäre Mannich-Base gebildet wird, welche auf die gleichzeitig entstehende Blausäure C-alkylierend wirkt.
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  • 100
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Elektrolyse von wasserfreien Fettsäuren und der Zerfall von Diacylperoxyden wurde in Pyridin (bzw. α-Methyl-pyridin) durchgeführt. Die durch Entladung der Anionen bzw. durch den thermischen Zerfall der Diacylperoxyde auftretenden Radikale reagieren mit Pyridin (bzw. Pyridinhomologen) unter Bildung von 2- und 4-Alkylpyridinen (bzw. 2.6-Dialkyl- und 2.4-Dialkyl-pyridinen). Der Peroxydzerfall in Pyridin ist zur präparativen Darstellung von Alkylpyridinen verwendbar.
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