ALBERT

Description: The decadal-scale variability in the tropical Pacific has been analyzed herein by means of observations and numerical model simulations. The two leading modes of the sea surface temperature (SST) variability in the central western Pacific are a decadal mode with a period of about 10 yr and the ENSO mode with a dominant period of about 4 yr. The SST anomaly pattern of the decadal mode is ENSO like. The decadal mode, however, explains most variance in the western equatorial Pacific and off the equator. A simulation with an ocean general circulation model (OGCM) forced by reanalysis data is used to explore the origin of the decadal mode. It is found that the variability of the shallow subtropical–tropical overturning cells is an important factor in driving the decadal mode. This is supported by results from a multicentury integration with a coupled ocean–atmosphere general circulation model (CGCM) that realistically simulates tropical Pacific decadal variability. Finally, the sensitivity of the shallow subtropical–tropical overturning cells to greenhouse warming is discussed by analyzing the results of a scenario integration with the same CGCM.

Description: We report measurements made with an ocean bottom array which was operated for 10 days on the Mid-Atlantic Ridge just south of the 5°S transform fault/fracture zone. A total of 148 locatable earthquakes with magnitudes ∼0.5–2.8 were recorded; seismic activity appears to be concentrated within the western half of the median valley. The median valley seismic zone is bounded in along-axis direction by the transform fault to the north and the tip of the axial volcanic ridge to the south. A few scattered events occurred within the inside corner high, on the transform fault, and in the western sidewall close to the segment center. Earthquakes reach a maximum depth of 8 km below the median valley floor and appear to be predominantly in the mantle, although a few crustal earthquakes also occurred. The presence of earthquakes in the mantle indicates that it is not strongly serpentinized. We infer the median valley seismic activity to primarily arise from normal faulting.

Description: The current system east of the Grand Banks was intensely observed by World Ocean Circulation Experiment (WOCE) array ACM-6 during 1993–95 with eight moorings, reaching about 500 km out from the shelf edge and covering the water column from about 400-m depth to the bottom. More recently, a reduced array by the Institut für Meerskunde (IfM) at Kiel, Germany, of four moorings was deployed during 1999–2001, focusing on the deep-water flow near the western continental slope. Both sets of moored time series, each about 22 months long, are combined here for a mean current boundary section, and both arrays are analyzed for the variability of currents and transports. A mean hydrographic section is derived from seven ship surveys and is used for geostrophic upper-layer extrapolation and isopycnal subdivision of the mean transports into deep-water classes. The offshore part of the combined section is dominated by the deep-reaching North Atlantic Current (NAC) with currents still at 10 cm s−1 near the bottom and a total northward transport of about 140 Sv (Sv ≡ 106 m3 s−1), with the details depending on the method of surface extrapolation used. The mean flow along the western boundary was southward with the section-mean North Atlantic Deep Water outflow determined to be 12 Sv below the σθ = 27.74 kg m−3 isopycnal. However, east of the deep western boundary current (DWBC), the deep NAC carries a transport of 51 Sv northward below σθ = 27.74 kg m−3, resulting in a large net northward flow in the western part of the basin. From watermass signatures it is concluded that the deep NAC is not a direct recirculation of DWBC water masses. Transport time series for the DWBC variability are derived for both arrays. The variance is concentrated in the period range from 2 weeks to 2 months, but there are also variations at interannual and longer periods, with much of the DWBC variability being related to fluctuations and meandering of the NAC. A significant annual cycle is not recognizable in the combined current and transport time series of both arrays. The moored array results are compared with other evidence on deep outflow and recirculation, including recent models of different types and complexity.

Description: [1] A new model is developed and applied to simulate the Phanerozoic evolution of seawater composition (dissolved Ca, Sr, dissolved inorganic carbon, alkalinity, pH, δ18O), marine carbonates (Sr/Ca, 87Sr/86Sr, δ13C, δ18O), atmospheric CO2 and surface temperature. The marine carbonate records (Sr/Ca, 87Sr/86Sr, δ13C) are used to reconstruct changes in volcanic/tectonic activity and organic carbon burial over the Phanerozoic. Seawater pH is calculated assuming saturation with respect to calcite and considering the changing concentration of dissolved Ca documented by brine inclusion data. The depth of calcite saturation is allowed to vary through time and the effects of changing temperature and pressure on the stability constants of the carbonate system are considered. Surface temperatures are calculated using the GEOCARB III approach considering also the changing flux of galactic cosmic radiation (GCR). It is assumed that GCR cools the surface of the Earth via enhanced cloud formation at low altitudes. The δ18O of marine carbonates is calculated considering the changing isotopic composition of seawater, the prevailing surface temperatures and seawater pH. Repeated model runs showed that the trends observed in the marine δ18O record can only be reproduced by the model if GCR is allowed to have a strong effect on surface temperature. The climate evolution predicted by the model is consistent with the geological record. Warm periods (Cambrian, Devonian, Triassic, Cretaceous) are characterized by low GCR levels. Cold periods during the late Carboniferous to early Permian and the late Cenozoic are marked by high GCR fluxes and low pCO2 values. The major glaciations occurring during these periods are the result of carbon cycling processes causing a draw-down of atmospheric CO2 and a coevally prevailing dense cloud cover at low-altitudes induced by strong GCR fluxes. The two moderately cool periods during the Ordovician - Silurian and Jurassic - early Cretaceous are characterized by both high pCO2 and GCR levels so that greenhouse warming compensated for the cooling effect of low-altitude clouds. The very high Jurassic δ18O values observed in the geological record are caused by low pH values in surface waters rather than cold surface conditions.

Description: High-resolution sediment cores from the Vøring Plateau, the North Iceland shelf, and the East Greenland shelf have been studied to investigate the stability of major surface currents in the Nordic Seas during the Holocene. Results from diatom assemblages and reconstructed sea-surface temperatures (SSTs) indicate a division of the Holocene into three periods: the Holocene Climate Optimum (9500–6500 calendar (cal) years BP), the Holocene Transition Period (6500–3000 cal years BP) and the Cool Late Holocene Period (3000–0 cal years BP). The overall climate development is in step with the decreasing insolation on the Northern Hemisphere, but regional differences occur regarding both timing and magnitude of SST changes. Sites under the direct influence of the Norwegian Atlantic Current and the Irminger Current indicate SST cooling of 4–5°C from early Holocene to present, compared to 2°C recorded under the East Greenland Current. Superimposed on the general Holocene cooling trend, there is a high-frequency SST variability, which is in the order of 1–1.5°C for the Vøring Plateau and the East Greenland shelf and 2.5–3°C on the North Iceland shelf.

Description: In our analysis [Rahmstorf et al., 2004], we arrived at two main conclusions: the data of Shaviv and Veizer [2003] do not show a significant correlation of cosmic ray flux (CRF) and climate, and the authors' estimate of climate sensitivity to CO2 based on a simple regression analysis is questionable. After careful consideration of Shaviv and Veizer's comment, we want to uphold and reaffirm these conclusions. Concerning the question of correlation, we pointed out that a correlation arose only after several adjustments to the data, including shifting one of the four CRF peaks and stretching the time scale. To calculate statistical significance, we first need to compute the number of independent data points in the CRF and temperature curves being correlated, accounting for their autocorrelation. A standard estimate [Quenouille, 1952] of the number of effective data points is urn:x-wiley:00963941:media:eost14930:eost14930-math-0001 where N is the total number of data points and r1, r2 are the autocorrelations of the two series. For the curves of Shaviv and Veizer [2003], the result is NEFF = 4.8. This is consistent with the fact that these are smooth curves with four humps, and with the fact that for CRF the position of the four peaks is determined by four spiral arm crossings or four meteorite clusters, respectively; that is, by four independent data points. The number of points that enter the calculation of statistical significance of a linear correlation is (NEFF− 2), since any curves based on only two points show perfect correlation; at least three independent points are needed for a meaningful result.

Description: The physical, chemical/biological processes that control the methane dynamics in the Weddell Sea are revealed by the distributions of methane (CH4), its stable carbon isotope ratio, δ13C-CH4, and the conservative transient tracer, chlorofluorocarbon-11 (CFC-11, CCl3F). In general, a nearly linear correlation between CH4 and CFC-11 concentrations was observed. Air-sea exchange is the major source of methane to this region, and the distribution of methane is controlled mainly by mixing between surface water and methane-poor Warm Deep Water. A significant influence of methane oxidation over the predominant two end-member mixing was only found in the Weddell Sea Bottom Water (WSBW) of the deep central Weddell Basin, where the turnover time of methane appears to be about 20 years. Mixing also controls most of the δ13C-CH4 distribution, but lighter than expected carbon isotopic ratios occur in the deep WSBW of the basin. From box model simulations, it appears that this “anomaly” is due to methane oxidation with a low kinetic isotope fractionation of about 1.004. The surface waters in the Weddell Sea and the Antarctic Circumpolar Current showed a general methane undersaturation of 6 to 25% with respect to the atmospheric mixing ratio. From this undersaturation and model-derived air-sea exchange rates, we estimate a net uptake of CH4 of roughly −0.5 μmol m−2 d−1 during austral autumn.

Description: The application of radiogenic isotopes to the study of Cenozoic circulation patterns in the South Pacific Ocean has been hampered by the fact that records from only equatorial Pacific deep water have been available. We present new Pb and Nd isotope time series for two ferromanganese crusts that grew from equatorial Pacific bottom water (D137-01, “Nova,” 7219 m water depth) and southwest Pacific deep water (63KD, “Tasman,” 1700 m water depth). The crusts were dated using 10Be/9Be ratios combined with constant Co-flux dating and yield time series for the past 38 and 23 Myr, respectively. The surface Nd and Pb isotope distributions are consistent with the present-day circulation pattern, and therefore the new records are considered suitable to reconstruct Eocene through Miocene paleoceanography for the South Pacific. The isotope time series of crusts Nova and Tasman suggest that equatorial Pacific deep water and waters from the Southern Ocean supplied the dissolved trace metals to both sites over the past 38 Myr. Changes in the isotopic composition of crust Nova are interpreted to reflect development of the Antarctic Circumpolar Current and changes in Pacific deep water circulation caused by the build up of the East Antarctic Ice Sheet. The Nd isotopic composition of the shallower water site in the southwest Pacific appears to have been more sensitive to circulation changes resulting from closure of the Indonesian seaway.

Description: Oceanic bromoform (CHBr3) is the major source of organic Br to the atmosphere and may be significant for ozone depletion through the contribution of reactive bromine to the upper troposphere and lower stratosphere of the midlatitudes and tropics. We report the first analyses of boundary layer air, surface and deep ocean waters from the tropical Atlantic. The data provide evidence of a source of CHBr3 throughout the tropical open ocean associated with the deep chlorophyll maximum within the tropical thermocline. Equatorial upwelling carries the CHBr3 to the surface, adding to increased concentrations in the equatorial mixed layer and driving oceanic emissions that support locally elevated atmospheric concentrations. In air masses that had crossed the coastal upwelling region off NW Africa even higher atmospheric mixing ratios were measured. The observations suggest a link between climate, wind-driven upwelling, and the supply of Br to the upper atmosphere of the tropics.

Description: Simulations and seasonal forecasts of tropical Pacific SST and subsurface fields that are based on the global Consortium for Estimating the Circulation and Climate of the Ocean (ECCO) ocean-state estimation procedure are investigated. As compared to similar results from a traditional ENSO simulation and forecast procedure, the hindcast of the constrained ocean state is significantly closer to observed surface and subsurface conditions. The skill of the 12-month lead SST forecast in the equatorial Pacific is comparable in both approaches. The optimization appears to have better skill in the SST anomaly correlations, suggesting that the initial ocean conditions and forcing corrections calculated by the ocean-state estimation do have a positive impact on the predictive skill. However, the optimized forecast skill is currently limited by the low quality of the statistical atmosphere. Progress is expected from optimizing a coupled model over a longer time interval with the coupling statistics being part of the control vector.

Description: The Galápagos Islands provide a topographic barrier for the Southern Equatorial Current (SEC) and the Equatorial Undercurrent (EUC). An island wake effect can be diagnosed from the difference of an ocean general circulation model simulation which includes the Galápagos Islands and one which ignores their presence. Cold thermocline water upwells on the western side of the islands, and only during boreal winter season these cold waters can linger around the Islands at a depth of about 80 m and affect the far eastern equatorial Pacific surface waters. This effect is partly offset by the westward transport of cold surface waters by the SEC which creates a wake on the western side of the Islands. It is furthermore shown that changes in horizontal current shear, induced by the presence of the Galápagos Islands modify the generation of tropical instability waves and lead to a basin scale SST anomaly pattern.

Description: In the eastern South Pacific Ocean, at a depth of about 200 m, a salinity minimum is found. This minimum is associated with a particular water mass, the “Shallow Salinity Minimum Water” (SSMW). SSMW outcrops in a fresh tongue (Smin) centered at about 45°S. The Smin appears to emanate from the eastern boundary, against the mean flow. The watermass transformation that creates SSMW and Smin is investigated here. The Smin and SSMW are transformed from saltier and warmer waters originating from the western South Pacific. The freshening and cooling occur when the water is advected eastward at the poleward side of the subtropical gyre. Sources of freshening and cooling are air–sea exchange and advection of water from south of the subtropical gyre. A freshwater and heat budget for the mixed layer reveals that both sources equally contribute to the watermass transformation in the mixed layer. The freshened and cooled mixed layer water is subducted into the gyre interior along the southern rim of the subtropical gyre. Subduction into the zonal flow restricts the transformation of interior properties to diffusion only. A simple advection/diffusion balance reveals diffusion coefficients of order 2000 m2 s−1. The tongue shape of the Smin is explained from a dynamical viewpoint because no relation to a positive precipitation–evaporation balance was found. Freshest Smin values are found to coincide with slowest eastward mixed layer flow that accumulates the largest amounts of freshwater in the mixed layer and creates the fresh tongue at the sea surface. Although the SSMW is the densest and freshest mode of water subducted along the South American coast, the freshening and cooling in the South Pacific affect a whole range of densities (25.0–26.8 kg m−3). The transformed water turns northward with the gyre circulation and contributes to the hydrographic structure of the gyre farther north. Because the South Pacific provides most of the source waters that upwell along the equatorial Pacific, variability in South Pacific hydrography may influence equatorial Pacific hydrography. Because one-half of the transformation is found to be controlled through Ekman transport, variability in wind forcing at the southern rim of the subtropical gyre may be a source for variability of the equatorial Pacific.

Description: An analytical model is developed to study the tidally induced mean circulation in the frontal zone. Four distinct forcing mechanisms are identified, which result in the generation of the counterclockwise Bernoulli cell, the clockwise Ekman cell, the clockwise frontal cell, and the Stokes drift (facing in the direction with the shallow water to the left). The decomposition of the cross-frontal circulation provides a dynamical framework for interpreting and understanding its complex structure. To illustrate the underlying physics, three model configurations are considered pertaining to a homogenous ocean and winter and summer fronts. For a homogeneous ocean, the circulation is dominated by three cells; for the winter front, the offshore Bernoulli cell is strengthened; and for the summer front, two counterrotating cells are found in the vertical direction, associated with the two branches of the front. The dependence of the cell structure on the Ekman, Burger, and other dimensionless numbers is examined.

Description: A multi-model ensemble-based system for seasonal-to-interannual prediction has been developed in a joint European project known as DEMETER (Development of a European Multimodel Ensemble Prediction System for Seasonal to Interannual Prediction). The DEMETER system comprises seven global atmosphere–ocean coupled models, each running from an ensemble of initial conditions. Comprehensive hindcast evaluation demonstrates the enhanced reliability and skill of the multimodel ensemble over a more conventional single-model ensemble approach. In addition, innovative examples of the application of seasonal ensemble forecasts in malaria and crop yield prediction are discussed. The strategy followed in DEMETER deals with important problems such as communication across disciplines, downscaling of climate simulations, and use of probabilistic forecast information in the applications sector, illustrating the economic value of seasonal-to-interannual prediction for society as a whole.

Description: The contribution of the marine biota to air-sea fluxes of CO2 and O2 is often described in terms of biological production concepts, such as new production, export production, and net community production. We evaluate these three quantities using a basin-scale ecosystem-circulation model of the North Atlantic Ocean based on Redfield stoichiometry into which we introduce an artificial tracer which records the biotic contribution to air-sea exchange of gases like O2 and CO2. It is found that on average the biological production rates overestimate the biotically effected air-sea flux by some 20% and, in some regions, even predict the wrong direction. With primary production restricted to the euphotic zone, but respiration extending to farther below, the discrepancy can largely be attributed to the different integration depths used in the different concepts (euphotic zone, surface mixed layer), and on annual and longer timescales, all rates converge when using the base of the winter mixed layer rather than that of the euphotic zone as the reference depth. For the surface carbon budget, which ultimately controls air-sea exchange of CO2, it is irrelevant whether carbon atoms cross this boundary in organic or inorganic speciation. Hence the transports of biotically generated surpluses or deficits of dissolved inorganic matter must also be accounted for. While their contribution amounts to only a few percent on the basin scale, the subduction of newly remineralized inorganic matter can locally account for about half of the biotically effected air-sea flux, for example, in regions of mode-water formation.

Description: New seismic and geodetic data from Costa Rica provide insight into seismogenic zone processes in Central America, where the Cocos and Caribbean plates converge. Seismic data are from combined land and ocean bottom deployments in the Nicoya peninsula in northern Costa Rica and near the Osa peninsula in southern Costa Rica. In Nicoya, inversion of GPS data suggests two locked patches centered at 14 ± 2 and 39 ± 6 km depth. Interplate microseismicity is concentrated in the more freely slipping intermediate zone, suggesting that small interseismic earthquakes may not accurately outline the updip limit of the seismogenic zone, the rupture zone for future large earthquakes, at least over the short (∼1 year) observation period. We also estimate northwest motion of a coastal “sliver block” at 8 ± 3 mm/yr, probably related to oblique convergence. In the Osa region to the south, convergence is orthogonal to the trench. Cocos-Caribbean relative motion is partitioned here, with ∼8 cm/yr on the Cocos-Panama block boundary (including a component of permanent shortening across the Fila Costeña fold and thrust belt) and ∼1 cm/yr on the Panama block–Caribbean boundary. The GPS data suggest that the Cocos plate–Panama block boundary is completely locked from ∼10–50 km depth. This large locked zone, as well as associated forearc and back-arc deformation, may be related to subduction of the shallow Cocos Ridge and/or younger lithosphere compared to Nicoya, with consequent higher coupling and compressive stress in the direction of plate convergence.

Description: This study focuses on an important aspect of air–sea interaction in models, namely, large-scale, spurious heat fluxes due to false pathways of the Gulf Stream and North Atlantic Current (NAC) in the “storm formation region” south and east of Newfoundland. Although high-resolution eddy-resolving models show some improvement in this respect, results are sensitive to poorly understood, subgrid-scale processes for which there is currently no complete, physically based parameterization. A simple method to correct an ocean general circulation model (OGCM), acting as a practical substitute for a physically based parameterization, is explored: the recently proposed “semiprognostic method,” a technique for adiabatically adjusting flow properties of a hydrostatic OGCM. The authors show that application of the method to an eddy-permitting model of the North Atlantic Ocean yields more realistic flow patterns and watermass characteristics in the Gulf Stream and NAC regions; in particular, spurious surface heat fluxes are reduced. Four simple modifications to the method are proposed, and their benefits are demonstrated. The modifications successfully account for three drawbacks of the original method: reduced geostrophic wave speeds, damped mesoscale eddy activity, and spurious interaction with topography. It is argued that use of a corrected (eddy permitting) OGCM in a coupled modeling system for simulating present climate (as now becomes possible because of increasing computer power) should lead to a more realistic simulation in regions of strong air–sea interaction as compared with that obtained with an uncorrected model. The method is also well suited for the simulation of the uptake and transport of passive tracers, such as anthropogenic carbon dioxide or components of ecosystem models.

Description: An 8 million year record of subtropical and midlatitude shelf-sea temperatures, derived from oxygen isotopes of well-preserved brachiopods from a variety of European sections, demonstrates a long-term Cenomanian temperature rise (16–20°C, midlatitudes) that reached its maximum early in the late Turonian (23°C, midlatitudes). Superimposed on the long-term trend, shelf-sea temperatures vary at shorter timescales in relation to global carbon cycle perturbations. In the mid-Cenomanian and the late Turonian, two minor shelf-sea cooling events (2–3°C) coincide with carbon cycle perturbations and times of high-amplitude sea level falls. Although this evidence supports the hypothesis of potential glacioeustatic effects on Cretaceous sea level, the occurrence of minimum shelf-sea temperatures within transgressive beds argues for regional changes in shelf-sea circulation as the most plausible mechanism. The major carbon cycle event in the latest Cenomanian (oceanic anoxic event 2) is accompanied by a substantial increase in shelf-sea temperatures (4–5°C) that occurred ∼150 kyr after the commencement of the δ13C excursion and is related to the spread of oceanic conditions in western European shelf-sea basins. Our oxygen isotope record and published δ18O data of pristinely preserved foraminifera allow the consideration of North Atlantic surface water properties in the Cenomanian along a transect from the tropics to the midlatitudes. On the basis of fossil-derived δ18O, estimated δw ranges, and modeled salinities, temperature-salinity-density ranges were estimated for tropical, subtropical, and midlatitude surface waters. Accordingly, the Cenomanian temperate shelf-seas waters have potentially the highest surface water density and could have contributed to North Atlantic intermediate to deep waters in the preopening stage of the equatorial Atlantic gateway.

Description: The consistency of long-term yearly precipitation and runoff trends over the largest Arctic watersheds (Ob, Yenisei and Lena Rivers) is examined. Three gridded precipitation datasets (Climatic Research Unit, University of Delaware, NCEP) are used for comparative analyses with runoff data collected at basin outlets. The results generally demonstrate inconsistency in long-term changes of basin precipitation and runoff. The Yenisei River runoff increases significantly, while precipitation data show mostly negative trends. The Ob River does not show any significant trend either in precipitation or runoff. Positive trend in the Lena River runoff is accompanied by a weak precipitation increase; however, the precipitation increase is not strong enough to support the observed runoff change. The inconsistency identified in basin precipitation and runoff trends suggests uncertainty in both the quality of basin precipitation and runoff datasets, as well as the perceived hydrologic factors impacting runoff change.

Description: Log and core data document gas saturations as high as 90% in a coarse-grained turbidite sequence beneath the gas hydrate stability zone (GHSZ) at south Hydrate Ridge, in the Cascadia accretionary complex. The geometry of this gas-saturated bed is defined by a strong, negative-polarity reflection in 3D seismic data. Because of the gas buoyancy, gas pressure equals or exceeds the overburden stress immediately beneath the GHSZ at the summit. We conclude that gas is focused into the coarse-grained sequence from a large volume of the accretionary complex and is trapped until high gas pressure forces the gas to migrate through the GHSZ to seafloor vents. This focused flow provides methane to the GHSZ in excess of its proportion in gas hydrate, thus providing a mechanism to explain the observed coexistence of massive gas hydrate, saline pore water and free gas near the summit.

Description: Two major water masses dominate the deep layers in the Mariana and Caroline Basins: the Lower Circumpolar Water (LCPW), arriving from the Southern Ocean along the slopes north of the Marshall Islands, and the North Pacific Deep Water (NPDW) reaching the region from the northeastern Pacific Ocean. Hydrographic and moored observations and multibeam echosounding were performed in the East Mariana and the East Caroline Basins to detail watermass distributions and flow paths in the area. The LCPW enters the East Mariana Basin from the east. At about 13°N, however, in the southern part of the basin, a part of this water mass arrives in a southward western boundary flow along the Izu–Ogasawara–Mariana Ridge. Both hydrographic observations and moored current measurements lead to the conclusion that this water not only continues westward to the West Mariana Basin as suggested before, but also provides bottom water to the East Caroline Basin. The critical throughflow regions were identified by multibeam echosounding at the Yap Mariana Junction between the East and West Mariana Basins and at the Caroline Ridge between the East Mariana and East Caroline Basins. The throughflow is steady between the East and West Mariana Basins, whereas more variability is found at the Caroline Ridge. At both locations, throughflow fluctuations are correlated with watermass property variations suggesting layer-thickness changes. The total transport to the two neighboring basins is only about 1 Sverdrup (1Sv ≡ 106 m3 s−1) but has considerable impact on the watermass structure in these basins. Estimates are given for the diapycnal mixing that is required to balance the inflow into the East Caroline Basin. Farther above in the water column, the high-silica tongue of NPDW extends from the east to the far southwestern corner of the East Mariana Basin, with transports being mostly southward across the basin.

Description: The 1.5-km-high, obliquely subducting Nazca Ridge and its collision zone with the Peruvian margin have been imaged by wide-angle and reflection seismic profiles, swath bathymetry, and gravity surveying. These data reveal that the crust of the ridge at its northeastern tip is 17 km thick and exhibits seismic velocities and densities similar to layers 2 and 3 of typical oceanic crust. The lowermost layer contributes 10–12 km to the total crustal thickness of the ridge. The sedimentary cover is 300–400 m thick on most parts of the ridge but less than 100 m thick on seamounts and small volcanic ridges. At the collision zone of ridge and margin, the following observations indicate intense tectonic erosion related to the passage of the ridge. The thin sediment layer on the ridge is completely subducted. The lower continental slope is steep, dipping at ∼9°, and the continental wedge has a high taper of 18°. Tentative correlation of model layers with stratigraphy derived from Ocean Drilling Program Leg 112 cores suggests the presence of Eocene shelf deposits near the trench. Continental basement is located 〈15 km landward of the trench. Normal faults on the upper slope and shelf indicate extension. A comparison with the Peruvian and northern Chilean forearc systems, currently not affected by ridge subduction, suggests that the passage of the Nazca Ridge along the continental margin induces a temporarily limited phase of enhanced tectonic erosion superposed on a long-term erosive regime.

Description: A marine sediment core from the leeward margin of Great Bahama Bank (GBB) was subjected to a multiproxy study. The aragonite dominated core MD992201 comprises the past 7230 years in a decadal time resolution and shows sedimentation rates of up to 13.8 m/kyr. Aragonite mass accumulation rates, age differences between planktonic foraminifera and aragonite sediments, and temperature distribution are used to deduce changes in aragonite production rates and paleocurrent strengths. Aragonite precipitation rates on GBB are controlled by exchange of carbonate ions and CO2 loss due to temperature-salinity conditions and biological activity, and these are dependent on the current strength. Paleocurrent strengths on GBB show high current velocities during the periods 6000–5100 years BP, 3500–2700 years BP, and 1600–700 years BP; lower current speeds existed during the time intervals 5100–3500 years BP, 2700–1600 years BP, and 700–100 years BP. Bahamian surface currents are directly linked to the North Atlantic atmospheric circulation, and thus periods with high (low) current speeds are proposed to be phases of strong (weak) atmospheric circulation.

Description: Sea surface temperature (SST) observations in the North Atlantic indicate the existence of strong multidecadal variability with a unique spatial structure. It is shown by means of a new global climate model, which does not employ flux adjustments, that the multidecadal SST variability is closely related to variations in the North Atlantic thermohaline circulation (THC). The close correspondence between the North Atlantic SST and THC variabilities allows, in conjunction with the dynamical inertia of the THC, for the prediction of the slowly varying component of the North Atlantic climate system. It is shown additionally that past variations of the North Atlantic THC can be reconstructed from a simple North Atlantic SST index and that future, anthropogenically forced changes in the THC can be easily monitored by observing SSTs. The latter is confirmed by another state-of-the-art global climate model. Finally, the strong multidecadal variability may mask an anthropogenic signal in the North Atlantic for some decades.

Description: [1] Volcanic glasses contained in distal fallout tephras from the Izu arc volcanic front (Izu VF) provide unique perspectives on general problems of arc volcanism. Unlike cogenetic lavas, these glasses are liquid compositions where element concentrations as well as ratios have significance. Isotopic evidence and previous work show that there is no sediment melt contribution to the sources of the Izu VF tephras, and hence their trace element characteristics permit determination of the trace element contents of slab fluids. The slab fluid is a composite of metasediment (∼5% of total fluid) and metabasalt (∼95%) component fluids, and carries large ion lithophile elements (LILE) with high LILE/Th and LILE/U, and low Th and U relative to source. Except for Sr and K, the metabasalt fluid is much less enriched than the metasediment fluid, but its large relative proportions make it an important carrier of many trace elements. The metabasalt fluid has the characteristics of the arc trace element signature, obviating the need for ubiquitous involvement of sediment in arc magma genesis. The fluid component in the tephras is remarkably constant in composition over fifteen million years, and hence appears to be a robust composition that may be applicable to other convergent margins. Assuming that the metabasalt fluid is a common component, and that distribution coefficients between sediment and fluid are similar from one arc to another, composite fluid compositions can be estimated for other arcs. Differences from this composition then would likely result from a sediment melt component. Comparison to arcs with sediment melt components in their source (Marianas, eastern Aleutians) shows that partial sediment melts may be so enriched, that they can completely mask the signature of the comingling slab fluids. Hence sediment melts can easily dominate the trace element and isotopic signature of many convergent margins. Since sediment melts inherit the LILE/LILE ratios of the trench sediment, Earth's surface processes must eventually influence the compositional diversity of arcs.

Description: A systematic modular approach to investigate the respective roles of the ocean and atmosphere in setting El Niño characteristics in coupled general circulation models is presented. Several state-of-the-art coupled models sharing either the same atmosphere or the same ocean are compared. Major results include 1) the dominant role of the atmosphere model in setting El Niño characteristics (periodicity and base amplitude) and errors (regularity) and 2) the considerable improvement of simulated El Niño power spectratoward lower frequencywhen the atmosphere resolution is significantly increased. Likely reasons for such behavior are briefly discussed. It is argued that this new modular strategy represents a generic approach to identifying the source of both coupled mechanisms and model error and will provide a methodology for guiding model improvement.

Description: The O'Higgins Seamount Group is a cluster of volcanic domes located 120 km west of the central Chilean Trench on the crest of the Juan Fernández Ridge. This aseismic hot spot track is subducting under South America triggering a belt of intraslab earthquake hypocenters extending about 700 km inland. The Juan Fernández Ridge marks the southern boundary of a shallow subduction segment. Subduction of oceanic basement relief has been suggested as a cause for the “flat” slab segments characterizing the Andean trench system. The Juan Fernández Ridge, however, shows only moderate crustal thickening, inadequate to cause significant buoyancy. In 2001, wide-angle seismic data were collected along two perpendicular profiles crossing the O'Higgins Group. We present tomographic images of the volcanic edifices and adjacent outer rise-trench environment, which indicate a magmatic origin of the seamounts dominated by extrusive processes. High-resolution bathymetric data yield a detailed image of a network of syngenetic structures reactivated in the outer rise setting. A pervasive fault pattern restricted to the hot spot modified lithosphere coincides with anomalous low upper mantle velocities gained from a tomographic inversion of seismic mantle phases. Reduced uppermost mantle velocities are solely found underneath the Juan Fernández Ridge and may indicate mineral alterations. Enhanced buoyancy due to crustal and upper mantle hydration may contribute an additional mechanism for shallow subduction, which prevails to the north after the southward migration of the Juan Fernández Ridge.

Description: On the basis of two sedimentary records from the central Sea of Okhotsk, we reconstruct the closely coupled glacial/interglacial changes in terrigenous flux, marine productivity, and sea ice coverage over the past 1.1 Myr. The correspondance of our sedimentary records to the China loess grain size record (China loess particle timescale, CHILOPARTS) suggests that environmental changes in both the Sea of Okhotsk area and in SE Asia were closely related via the Siberian atmospheric high-pressure cell. During full glacial times our records point to a strong Siberian High causing northerly wind directions, the extension of the sea ice cover, and a reduced Amur River discharge. Deglacial maxima of terrigenous flux were succeeded by or synchronous to high-productivity events. Marine productivity was strengthened during glacial terminations because of an effective nutrient utilization at times of enhanced water column stratification and high nutrient supply from fluvial runoff and sea ice thawing. During interglacials, SE monsoonal winds prevailed, analogous to today's summer situation of a pronounced Mongolian Heat Low and a strong Hawaiian High. Strong freshwater discharge induced by high precipitation rates in the Amur drainage area and a seasonally reduced and mobile sea ice cover favored marine productivity (although being considerably lower than during the terminations) and a lowered flux of ice-rafted detritus.

Description: The Indonesian Throughflow (ITF) spreading pathways and time scales in the Indian Ocean are investigated using both observational data and two numerical tracer experiments, one being a three-dimensional Lagrangian trajectory experiment and the other a transit-time probability density function (PDF) tracer experiment, in an ocean general circulation model. The model climatology is in agreement with observations and other model results except that speeds of boundary currents are lower. Upon reaching the western boundary within the South Equatorial Current (SEC), the trajectories of the ITF tracers within the thermocline exhibit bifurcation. The Lagrangian trajectory experiment shows that at the western boundary about 38%±5% thermocline ITF water flows southward to join the Agulhas Current, consequently exiting the Indian Ocean, and the rest, about 62%±5%, flows northward to the north of SEC. In boreal summer, ITF water penetrates into the Northern Hemisphere within the Somali Current. The primary spreading pathway of the thermocline ITF water north of SEC is upwelling to the surface layer with subsequent advection southward within the surface Ekman layer toward the southern Indian Ocean subtropics. There it is subducted and advected northward in the upper thermocline to rejoin the SEC. Both the observations and the trajectory experiment suggest that the upwelling occurs mainly along the coast of Somalia during boreal summer and in the open ocean within a cyclonic gyre in the Tropics south of the equator throughout the year. All the ITF water eventually exits the Indian Ocean along the western boundary within the Mozambique Channel and the east coast of Madagascar and, farther south, the Agulhas Current region. The advective spreading time scales, represented by the elapsed time corresponding to the maximum of transit- time PDF, show that in the upper thermocline the ITF crosses the Indian Ocean, from the Makassar Strait to the east coast of the African continent, on a time scale of about 10 yr and reaches the Arabian Sea on a time scale of over 20 yr.

Description: We have developed a new 163-year bimonthly coral δ18O record from La Réunion (55°E, 21°S). Interannual variations in coral δ18O are coherent with the Southern Oscillation Index but not with regional sea surface temperature (SST). Correlations with the global SST field suggest more negative seawater δ18O (δ18Osw) during La Niña years. We propose that the signal results from changes in the strength of the South Equatorial Current and the Indonesian throughflow, which carry low salinity water. Multidecadal variations in coral δ18O are coherent with regional SST, but the sign is of opposite sense as expected from the coral δ18O-temperature relationship. This requires multidecadal changes in salinity large enough to overprint the SST contribution in the coral δ18O record. Our results suggest that multidecadal salinity variations result from modulations in the transport of the South Equatorial Current, which varies in response to the surface wind field and/or the Indonesian throughflow.

Description: The results of 1 year of automated pCO2 measurements in 2002/2003 onboard the car carrier M/V Falstaff are presented and analyzed with regard to the driving forces that change the seawater pCO2 in the midlatitude North Atlantic Ocean. The pCO2 in surface seawater is controlled by thermodynamics, biology, air-sea gas exchange, and physical mixing. Here we estimate the effects on the annual cycle of pCO2 and relate this property to parameters like SST, nitrate, and chlorophyll. On the basis of the amplitude in seawater pCO2 for all 4° × 5° grid boxes, this region can be separated into an eastern and western basin. The annual pCO2 cycle in the eastern basin (10°W–35°W) is less variable, which can be related to the two counteracting effects of temperature and biology; air-sea gas exchange plays a minor role when using climatological MLD. In the western basin (36°W–70°W) the pCO2 amplitude is more variable and strongly follows the thermodynamic forcing, since the biological forcing (as derived from nitrate concentrations) is decreased. Biology and air-sea exchange strongly depend on the MLD and therefore also include physical mixing effects. The pCO2 data of the analyzed region between 34°N and 52°N compare well to the Takahashi et al. [2002] climatology except for regions north of 45°N during the wintertime where the bias is significant.

Description: The Denmark Strait plays an important role as a dense water gateway between the Arctic and the subpolar North Atlantic. Previous studies have shown that the volume transport over the sill is limited by hydraulic constraints. A regional ocean-circulation model (ROMS) with a horizontal resolution of ≈1/20° degree and 30 sigma layers in the vertical is applied to study the through flow characteristics for Last Glacial Maximum to Holocene conditions. The bathymetry of the gateway region is obtained from a geodynamic model that takes into account the differential ice loading of the adjacent continents. First, the upstream reservoir conditions are systematically changed to test hydraulic limitations for altered bathymetry. Generally, the through flow is less than the predicted maximal value from hydraulic theory by almost 50%. The results indicate that the reduction in gateway depth and aperture owing to glacial-isostatic processes alone lead to a considerable further reduction of the overflow, by approximately 33%, compared to the present day. Second, the through flow is modeled using average density profiles and wind stress from global model data. The reduction in the density-driven part of the overflow is partly compensated by an enhanced wind stress but is still reduced by a factor of 5. Owing to the narrowing of the strait during the glacial and the increased northerly wind, the North Icelandic Irminger Current was strongly reduced but still existent.

Description: We report on epibenthic foraminiferal δ18O and δ13C and percentage coarse fraction records from Caribbean Ocean Drilling Program (ODP) Site 999 (12°44′N, 78°44′W, water depth 2828 m) spanning the interval from 8.5 to 5.3 Ma. Low epibenthic δ13C values and low amounts of sand-sized particles (mostly foraminifer shells) indicate a poorly ventilated deep Caribbean throughout the late Miocene. At this time the deep Caribbean was dominated by a nutrient-rich and corrosive water mass. A generally constant δ13C gradient between the Caribbean and deep Atlantic records during the late Miocene suggests that the fluctuations in δ13C reflect global changes in δ13C of the dissolved inorganic carbon due to varying erosion of organic carbon from terrigenous soils and shelf sediments. The observed 100-kyr cyclicity of epibenthic δ13C is in good accordance with the variability of terrigenous input to the equatorial Atlantic as recorded by magnetic susceptibility records of the Ceara Rise. However, some short-term gradient changes between 7.0 and 4.5 Ma indicate a poorer ventilation of the deep Atlantic related to a reduced production of deep water in the Atlantic. The Messinian Salinity Crisis between 6.0 and 5.3 Ma did not affect the intermediate to deep water gradient between the Caribbean and the Atlantic. Comparison to the Bahama platform record of ODP Site 1006, however, indicates a poorer ventilation of the shallower northern Caribbean basins coincident with the isolation of the Mediterranean Sea.

Description: Oceanic plateaus and continental flood basalts, collectively referred to as large igneous provinces (LIPs), represent the most voluminous volcanic events on Earth. In contrast to continental LIPs, relatively little is known about the surface and internal structure, range in age and chemical composition, origin, and evolution of oceanic plateaus, which occur throughout the worlds oceans [e.g., Mahoney and Coffin, 1997]. One of the major goals of the R/V Sonne SO168 ZEALANDIA expedition (depart Wellington, 3 December 2002, return Christchurch, 15 January 2003) was to investigate the Hikurangi oceanic plateau off the east coast of New Zealand.

Description: This contribution aims to report the reflections we had with the scientific community during two international workshops on reference materials for stable isotopes in Davos (2002) and Nice (2003). After evaluating the isotopic homogeneity of some existing reference materials, based on either certificates, literature data or specific inter-laboratory rounds, we confirm these as primary reference materials or propose new ones relative to which stable isotope compositions should be reported. We propose DSM-3 for Mg, NIST SRM 915a for Ca, L-SVEC for Li and NBS28 for Si. Cadmium does not yet have a well identified delta zero material, although three commercial mono-elemental Cd solutions have yielded the same isotopic composition relative to one another. In order to scale the linearity of any mass spectrometer, some secondary reference materials are also proposed: Cambridge-1 solution for Mg, the “Münster-Cd” and JEPPIM Cd solutions for Cd and the “Big Batch” silicate for Si. The team from Nancy propose to prepare a mixed spike solution for Li isotopes. Well-characterised natural samples such as ocean or continental waters, diatoms, sponges, rocks and minerals are needed to validate the entire analytical procedure, particularly to take into account the effect of sample mineralisation and of chemical manipulations for elemental separation prior to analysis.

Description: [1] The role of sediment diagenesis in the marine cycles of Li and B is poorly understood. Because Li and B are easily mobilized during burial and are consumed in authigenic clay mineral formation, their abundance in marine pore waters varies considerably. Exchange with the overlying ocean through diffusive fluxes should thus be common. Nevertheless, only a minor Li sink associated with the low-temperature alteration of volcanic ash has been observed. We describe a low-temperature diagenetic environment in the Black Sea dominated by the alteration of detrital plagioclase feldspars. Fluids expelled from the Odessa mud volcano in the Sorokin Trough originate from shallow (≈100–400 m deep) sediments which are poor in volcanic materials but rich in anorthite. These fluids are depleted in Na+, K+, Li+, B, and 18O and enriched in Ca2+ and Sr2+, indicating that anorthite is dissolving and authigenic clays are forming. Using a simple chemical model, we calculate the pH and the partial pressure of CO2 (PCO2) in fluids associated with this alteration process. Our results show that the pH of these fluids is up to 1.5 pH units lower than in most deep marine sediments and that PCO2 levels are up to several hundred times higher than in the atmosphere. These conditions are similar to those which favor the weathering of silicate minerals in subaerial soil environments. We propose that in Black Sea sediments enhanced organic matter preservation favors CO2 production through methanogenesis and results in a low pore water pH, compared to most deep sea sediments. As a result, silicate mineral weathering, which is a sluggish process in most marine diagenetic environments, proceeds rapidly in Black Sea sediments. There is a potential for organic matter-rich continental shelf environments to host this type of diagenesis. Should such environments be widespread, this new Li and B sink could help balance the marine Li and Li isotope budgets but would imply an apparent imbalance in the B cycle.

Description: Aspects of the sea level changes in the western Mediterranean Sea are investigated using a numerical tidal model of the Strait of Gibraltar. As a prerequisite, the performance of this model, that is, a two-dimensional, nonlinear, two-layer, boundary-fitted coordinate numerical model based on the hydrostatic approximation on an f plane, is assessed in the simulation of mean and tidal circulation of the Strait of Gibraltar. The model is forced by imposing mean interface and surface displacements as well as M2, S2, O1, and K1 tidal components along the Atlantic and Mediterranean model open boundaries. Model results are compared with observations and with results obtained from a tidal inverse model for the eastern entrance of the Strait of Gibraltar. In general, good agreement is found. A sensitivity study performed by varying different model parameters shows that the model behaves reasonably well in the simulation of the averaged circulation. The model is then used to investigate the climatological sensitivity of the simulated dynamics in the Strait of Gibraltar to changes in the density difference between Atlantic and Mediterranean waters. For this purpose, given a certain density difference between Atlantic and Mediterranean waters, the authors iteratively searched for that sea level drop between the Atlantic and the Mediterranean that fulfills the mass balance of the Mediterranean. It is found that an increase of the density difference leads to an increase of the exchange flow and to an increase of the sea level drop between the two basins. A trend in the sea level drop of O(1 cm yr−1), such as the one observed between 1994 and 1997, is explained by the model as the result of a trend of O(10−4 yr−1) in the relative density difference between the Mediterranean and Atlantic waters. The observed north–south asymmetry in this trend is also captured by the model, and it is found to arise from changes in the along-strait velocity. Results suggest that the dynamics within the Strait of Gibraltar cannot be neglected when sea level changes in the western Mediterranean basin are investigated.

Description: There is increasing evidence indicating that syndepositional redistribution of sediment on the seafloor by bottom currents is common and can significantly affect sediment mass accumulation rates. Notwithstanding its common incidence, this process (generally referred to as sediment focusing) is often difficult to recognize. If redistribution is near synchronous to deposition, the stratigraphy of the sediment is not disturbed and sediment focusing can easily be overlooked. Ignoring it, however, can lead to serious misinterpretations of sedimentary fluxes, particularly when past changes in export flux from the overlying water are inferred. In many instances, this problem can be resolved, at least for sediments deposited during the late Quaternary, by normalizing to the flux of 230Th scavenged from seawater, which is nearly constant and equivalent to the known rate of production of 230Th from the decay of dissolved 234U. We review the principle, advantages and limitations of this method. Notwithstanding its limitations, it is clear that 230Th normalization does provide a means of achieving more accurate interpretations of sedimentary fluxes and eliminates the risk of serious misinterpretations of sediment mass accumulation rates.

Description: Sea level anomalies measured by the altimeters aboard the TOPEX/Poseidon and ERS satellites for the periods 1993–2001 and 1997–2001, respectively, are used to investigate the eddy field in the subpolar North Atlantic and in the Labrador Sea. A quadratic correction of the obtained eddy kinetic energy (EKE) with respect to significant wave height is applied that led to an increased correlation between moored and altimetric EKE in the central Labrador Sea. The mean EKE field shows higher levels associated with the main currents and a strong seasonality in the Labrador Sea. The annual cycle of the EKE shows a propagation of West Greenland Current (WGC) EKE into the central Labrador Sea with a mean southward propagation speed of about 3 cm s−1, while the EKE maximum in the Labrador Current is well separated from the interior by local EKE minima. The interannual variability of the EKE in the Labrador Sea shows distinct regional differences. In the WGC region, strong early winter maxima are found during 1993 and 1997–1999. In the central Labrador Sea, maxima are found during March/April 1993–1995 and 1997. Variations in the annual cycle of the WGC EKE are observed: While there is a weak annual cycle in the WGC region during 1994–1996 with more continuous EKE generation, during 1997–2000, there is a strong seasonal cycle with maximum EKE during January and particularly low EKE during summer. The propagation of WGC EKE into the central Labrador Sea is enhanced during 1997–2000, leading to a long persistence of EKE in the central Labrador Sea. During 1993–1995 and 1997 the central Labrador Sea EKE almost instantaneously increased during March/April, followed, in the earlier years, by a relatively fast destruction of the winterly generated EKE.

Description: H2O2 was measured in the upper water column (0–200 m) along a west-east transect through the Equatorial Atlantic as part of the German SOLAS (Surface Ocean Lower Atmosphere) cruise Meteor 55 (M55). Vertical profiles of H2O2 showed characteristic exponential decay consistent with light profiles and rainwater inputs. Integrated (0–100 m) water column H2O2 inventories ranged from 1.1–8.9 mmol m−2 with the highest values in the Amazon Plume. H2O2 inventories were also higher at the Equatorial Upwelling and after heavy rain showers in the region of the Inter Tropical Convergence Zone (ITCZ). Analysis of rain water samples collected during the cruise gave a volume weighted mean of 10.8 μmol L−1 (range 1.5–22.3 μmol L−1). This work highlights the importance of rainwater as a major source for H2O2 in the surface waters under the ITCZ.

Description: Rapid descent of dense Drygalski Trough (western Ross Sea, Antarctica) shelf water over the continental slope, within 100 to 250 m thick benthic plumes, is described. Speeds of up to 1.0 m/s are recorded flowing at an average angle of 35° to the isobaths, entraining ambient Lower Circumpolar Deep Water en route. This process is predominant in determining the concentration and placement of the shelf water injected into the deep sea as a precursor Antarctic Bottom Water. Nonetheless, a 4-hour duration pulse of undiluted shelf water was observed at depth (1407 m) directly north of the Drygalski Trough, moving at around 90 degrees to isobaths, and at a speed of 1.4 m/s. Thus the export of Ross Sea shelf water to the deep sea is accomplished within plumes descending at moderate angle to isobaths, punctuated by rapid downhill cascades.

Description: Ecological stoichiometry describes the biochemical constraints of trophic interactions emerging from the different nutrient content and nutrient demand of producers and consumers, respectively. Most research on this topic originates from well-mixed pelagic food webs, whereas the idea has received far less attention in spatially structured habitats. Here, we test how light as well as grazing and nutrient regeneration by consumers affects growth and biomass of benthic primary producers. In the first laboratory experiment, we manipulated grazer presence (two different snail species plus ungrazed control), in the second experiment we factorially combined manipulation of grazer presence and light intensity. We monitored snail and periphyton biomass as well as dissolved and particulate nutrients (nitrogen and phosphorus) over time. Grazers significantly reduced algal biomass in both experiments. Grazers affected periphyton nutrient content depending on the prevailing nutrient limitation and their own body stoichiometry. In the nitrogen (N-) limited first experiment, grazers increased N both in the periphyton and in the water column. The effect was stronger for grazers with lower N-content. In the phosphorus (P-) limited second experiment, grazers increased the P-content of the periphyton, but the grazer with lower N-content had additionally positive effects on algal N. Light reduction did not affect periphyton biomass, but increased chlorophyll-, N- and P-content of the periphyton. These experiments revealed that the indirect effects of grazers on periphyton were bound by stoichiometric constraints of nutrient incorporation and excretion.

Description: So far, general circulation model studies have not been able to capture the magnitude and characteristics of the observed 11-year solar signal in the stratosphere satisfactorily. Here results from model experiments with the Freie Universität Berlin Climate Middle Atmosphere Model are presented that are in considerable agreement with observations. The experiments used realistic spectral solar irradiance changes, ozone changes from a two-dimensional radiative-chemical-transport model, and a relaxation toward observed equatorial wind profiles throughout the stratosphere. During Northern Hemisphere winter a realistic poleward downward propagation of the polar night jet (PNJ) anomalies, significantly weaker planetary wave activity, and a weaker mean meridional circulation under solar maximum conditions are reproduced in the model. The observed interaction between the Sun and the Quasi-Biennial Oscillation (QBO) is captured and stratospheric warmings occur preferentially in the west phase of the QBO. Only the magnitude of the anomalies during the dynamically active season improves, whereas the summer signal and the signal at low latitudes are still too weak. The results emphasize the important role of equatorial winds in achieving a more realistic solar signal by producing a more realistic wind climatology. Furthermore, they confirm recent results that equatorial winds in the upper stratosphere, the region dominated by the Semiannual Oscillation, are an important factor in determining interannual variability of the PNJ.

Description: During 2002 and 2003 exceptional inflow events have been registered. In January 2003 a massive inflow of highly saline, cold and extremely oxygen‐rich water from the North Sea was recorded at Darss Sill. This event is considered to be the most important inflow since 1993. A coupled model system for the Baltic Sea region, called BALTIMOS, was developed in the frame of DEKLIM/BALTEX by linking existing model components for the atmosphere (model REMO), for the ocean including sea ice (model BSIOM), for the hydrology (model LARSIM) as well as for lakes. The model system consists of high resolution model components: 1/6° (∼18 km) with 20 vertical levels; ocean‐ice 5 km with 60 vertical levels, hydrology 1/6°. The model domain covers the whole drainage basin of the Baltic Sea as well as major parts of Europe. The exceptional inflow events have been simulated successfully with BALTIMOS. The simulation was initialized at 1st of February 2002 and the model has been run until October 2003. This period includes the exceptional warm water inflow in autumn 2002 and the major Baltic inflow in January 2003. Different inflow characteristics are presented and discussed. The simulated volume transport for the major inflow in January 2003 amounts to about 250 km3, half of which was of salinity 17 PSU which corresponds to a salt transport of 2.7 × 1012 kg.

Description: A coupled ecosystem-circulation model of the North Atlantic Ocean is used to investigate the impact of radiative heating by biotically induced absorption of solar radiation on the ocean's heat budget, on water column stability and circulation, and on biological production itself. For fixed atmospheric conditions, the local sensitivity of the nonsolar heat flux to changes in sea surface temperature leads to a net cooling of the ocean by the biota at a rate of about 1 W m−2. As a result, simulated winter mixed-layer depths are deeper by more than 100 m in parts of the subpolar gyre, whereas upper-ocean stratification is enhanced in the tropics and subtropics, and coastal upwelling and associated nutrient supply are reduced by about 10% compared to a model run with optical properties of clear seawater. Simulated chlorophyll concentrations increase, indicating a positive feedback, only in subpolar regions that exhibit a pronounced phytoplankton spring bloom. Here biotically induced trapping of heat closer to the sea surface leads to a faster shoaling of the mixed layer and a more intense spring bloom in the model. On the basin average, simulated surface chlorophyll concentrations, however, decrease by 3%, constituting a weak negative feedback of 0.03 W m−2, when heating by biotic absorption of solar radiation is accounted for. These findings are based on the approximation of the atmosphere as a passive heat buffer and will have to be tested against results from fully coupled atmosphere-ocean models with interactive marine biology.

Description: The bifurcation behavior of a conceptual heat–salt oscillator model is analyzed by means of numerical continuation methods. A global (homoclinic) bifurcation acts as an organizing center for the dynamics of the simplified convective model. It originates from a codimension-2 bifurcation in an extended parameter space. Comparison with earlier work by Cessi shows that the intriguing stochastic thermohaline excitability can be understood from the bifurcation structure of the model. It is argued that global bifurcations may play a crucial role in determining long-term variability of the thermohaline circulation.

Description: A method is presented to reconstruct decadal variations of the North Atlantic Oscillation (NAO). The spectral characteristics of the NAO on time scales of decades and longer are of particular interest for the understanding of North Atlantic ocean–atmosphere interactions. The reconstruction is based on a transfer model calibration that uses bandpass-filtered time series. The maximum overlap discrete wavelet transform (MODWT) is applied for decomposing the time series variance into different time scales. A total of 43 proxies, including Greenland ice cores and European tree-ring chronologies, are selected and regionally grouped providing four independent reconstructions for the period 1700–1978. The mean reconstruction agrees well with two recently published reconstructions during most of the time period. However, there are considerable differences in the earliest part before 1750. Running correlations between the reconstructions indicate that time-dependent relations exist among the different NAO reconstructions. The results suggest that the geographical distribution of proxies strongly affects the reconstruction and could explain some of the apparent discrepancies among the reconstructions recently published in literature. In the early eighteenth century, external forcing (solar, volcanic) seems to mask the NAO signature within the proxies

Description: The deep circulation and related transports of the southern Labrador Sea are determined from direct current observations from ship surveys and a moored current-meter array. The measurements covered a time span from summer 1997 to 1999 and show a well-defined deep boundary current extending approximately out to the 3300-m depth contour and weak reverse currents farther offshore. The flow has a strong barotropic component, and significant baroclinic flow is only found in the shallow Labrador Current at the shelf break and associated with a deep core of Denmark Strait Overflow Water. The total deep-water transport below σΘ = 27.74 kg m−3 was 26 ± 5 Sv (Sv ≡ 106 m3 s−1) comprising Labrador Sea Water (LSW), Gibbs Fracture Zone Water (GFZW), and Denmark Strait Overflow Water (DSOW). Intraseasonal variability of the flow and transport was high, ranging from 15 to 35 Sv, and the annual means differed by 17%. A seasonal cycle is confined to the shallow Labrador Current; in its deeper part, where the mean flow is still strong, no obvious seasonality could be detected. The transport of the interior anticyclonic recirculation was estimated from lowered acoustic Doppler current profiler stations and geostrophy, yielding about 9 Sv. Thus, the net deep-water outflow from the Labrador Sea was about 17 Sv. The baroclinic transport of GFZW and DSOW referenced to the depth of the isopycnal σΘ = 27.80 kg m−3 is only about one-third of the total transport in these layers. Longer-term variations of the total transports are not represented well by the baroclinic contribution.

Description: Ecosystem resistance to a single stressor relies on tolerant species that can compensate for sensitive competitors and maintain ecosystem processes, such as primary production. We hypothesize that resistance to additional stressors depends increasingly on species tolerances being positively correlated (i.e. positive species co-tolerance). Initial exposure to a stressor combined with positive species co-tolerance should reduce the impacts of other stressors, which we term stress-induced community tolerance. In contrast, negative species co-tolerance is expected to result in additional stressors having pronounced additive or synergistic impacts on biologically impoverished functional groups, which we term stress-induced community sensitivity. Therefore, the sign and strength of the correlation between species sensitivities to multiple stressors must be considered when predicting the impacts of global change on ecosystem functioning as mediated by changes in biodiversity.

Description: Nitrogen fixation supports new production in the oligotrophic oceans and removes dinitrogen and carbon dioxide from mixed layer waters. N‐fixation rates have been estimated in various ways but measurements are still too rare and factors limiting N‐fixation are not yet fully understood. Here we present data from a transect along 10°N through the tropical Atlantic on the Meteor Cruise 55 where N‐fixation rates between 3.7 and 255 μmol N*m−2*d−1 were recorded. The highest rates occurred off Africa in the eastern tropical North Atlantic (ETNA), and in the Amazon River plume in the West and contributed to 1–12.2% of the N‐demand of primary production. N‐fixation rates correlated with dissolved Fe concentrations, which were 20–280 times greater than the estimated demand. High atmospheric Fe inputs combined with the shallow nutricline make the ETNA a favourable environment for N‐fixers.

Description: Recent experiments, mainly in terrestrial environments, have provided evidence of the functional importance of biodiversity to ecosystem processes and properties. Compared to terrestrial systems, aquatic ecosystems are characterised by greater propagule and material exchange, often steeper physical and chemical gradients, more rapid biological processes and, in marine systems, higher metazoan phylogenetic diversity. These characteristics limit the potential to transfer conclusions derived from terrestrial experiments to aquatic ecosystems whilst at the same time provide opportunities for testing the general validity of hypotheses about effects of biodiversity on ecosystem functioning. Here, we focus on a number of unique features of aquatic experimental systems, propose an expansion to the scope of diversity facets to be considered when assessing the functional consequences of changes in biodiversity and outline a hierarchical classification scheme of ecosystem functions and their corresponding response variables. We then briefly highlight some recent controversial and newly emerging issues relating to biodiversity-ecosystem functioning relationships. Based on lessons learnt from previous experimental and theoretical work, we finally present four novel experimental designs to address largely unresolved questions about biodiversity-ecosystem functioning relationships. These include (1) investigating the effects of non-random species loss through the manipulation of the order and magnitude of such loss using dilution experiments; (2) combining factorial manipulation of diversity in interconnected habitat patches to test the additivity of ecosystem functioning between habitats; (3) disentangling the impact of local processes from the effect of ecosystem openness via factorial manipulation of the rate of recruitment and biodiversity within patches and within an available propagule pool; and (4) addressing how non-random species extinction following sequential exposure to different stressors may affect ecosystem functioning. Implementing these kinds of experimental designs in a variety of systems will, we believe, shift the focus of investigations from a species richness-centred approach to a broader consideration of the multifarious aspects of biodiversity that may well be critical to understanding effects of biodiversity changes on overall ecosystem functioning and to identifying some of the potential underlying mechanisms involved.

Description: A West ‐East crossing of the Tropical Atlantic during Meteor cruise 55 included measurements of organic species within the atmospheric marine boundary layer and the upper ocean. Acetone, methanol, acetonitrile and DMS were measured between 10–0°N and 35°W–5°E, on either side of the ITCZ. Methanol and acetone concentrations were higher in the northern hemisphere, both in surface seawater and the atmosphere whereas acetonitrile and DMS showed no significant interhemispheric gradient. Three depth profiles from 0–200 m for these species were measured. Acetone, methanol, DMS and acetonitrile generally decreased with depth with the sharpest decrease in concentration in all profiles being found at the bottom of the mixed layer. The average air mixing ratios and surface seawater concentrations for the whole dataset are respectively: acetone 0.53 nmol/mol and 17.6 nmol/L; acetonitrile 0.11 nmol/mol and 6.19 nmol/L; methanol 0.89 nmol/mol and 118.4 nmol/L; and DMS 0.05 nmol/mol and 1.66 nmol/L.

Description: This special section presents results from an interdisciplinary research cruise to the northern tropical Atlantic Ocean, which took place in October–November 2002. The cruise was planned as a pilot study for the international Surface Ocean – Lower Atmosphere Study (SOLAS) project. This introduction summarizes the goals as well as the hydrographic and atmospheric setting of the expedition. We also present a brief review of the findings published in this section and elsewhere concerning controls on trace gas fluxes and the biogeochemical significance of dust composition and deposition.

Description: We use a global coupled atmosphere‐ocean sea‐ice model of intermediate complexity to demonstrate that wind‐forcing is a crucial element to sustain meridional overturning flow in the Atlantic. Neglecting wind‐stress in our multi‐century‐long simulations leads to a complete shutdown of the conveyor belt circulation. This result may have tremendous impacts for an assessment of the sensitivity of 2‐d climate models which typically do not capture wind‐driven gyres. It is argued that wind effects may be a key element in determining the fate and length of a collapsed THC state. Possible paleo implications will be discussed.

Description: Marine and fisheries scientists are increasingly using metapopulation concepts to better understand and model their focal systems. Consequently, they are considering what defines a metapopulation. One perspective on this question emphasizes the importance of extinction probability in local populations. This view probably stems from the focus on extinction in Levins' original metapopulation model, but places unnecessary emphasis on extinction–recolonization dynamics. Metapopulation models with more complex structure than Levins' patch-occupancy model and its variants allow a broader range of population phenomena to be examined, such as changes in population size, age structure and genetic structure. Analyses along these lines are critical in fisheries science, where presence–absence resolution is far too coarse to understand stock dynamics in a meaningful way. These more detailed investigations can, but need not, aim to assess extinction risk or deal with extinction-prone local populations. Therefore, we emphasize the coupling of spatial scales as the defining feature of metapopulations. It is the degree of demographic connectivity that characterizes metapopulations, with the dynamics of local populations strongly dependent upon local demographic processes, but also influenced by a nontrivial element of external replenishment. Therefore, estimating rates of interpopulation exchange must be a research priority. We contrast metapopulations with other spatially structured populations that differ in the degree of local closure of their component populations. We conclude with consideration of the implications of metapopulation structure for spatially explicit management, particularly the design of marine protected area networks.

Description: The Subtropical Cells (STCs) of the Pacific and Atlantic Oceans connect the subtropical subduction regions of both hemispheres to the eastern, equatorial upwelling regimes by equatorward thermocline and poleward surface flows. In the Indian Ocean, where equatorial upwelling is absent, a cross-equatorial cell (CEC) connects the southern-hemisphere subduction regime with upwelling regions north of the equator, and it is closed by southward, cross-equatorial Ekman/Sverdrup transport at the ocean surface. We review here the theory explaining the mean features of the STCs and CEC, the observational evidence for their various branches, and results of realistic model simulations. A topic of particular interest is the partition of the equatorward STC branch between interior and western-boundary pathways. Observational results are only now beginning to reveal the structure of the interior pathways, and model results of these flows vary with model type and the wind forcing applied. We also review studies of STC variability, which has been hypothesized to play a role in climate variability. Existing work indicates that wind-driven STC transport variations (v'f processes) are more important than advection of subducted temperature anomalies by the mean STC currents (the vr' processes) in generating equatorial sea-surface temperature anomalies and, hence, climate variability.

Description: A model of the North Atlantic Ocean is used to simulate the spreading of CFC‐12 from the Labrador Sea deep convection site. The standard version of the model fails to capture the local maximum in CFC‐12 concentration that is observed along the continental slope of the western boundary. Hydrographic data are used to apply a simple correction to the model's horizontal momentum equations. The corrected model is much more successful at capturing the nearslope maximum in CFC‐12 concentration than the uncorrected model and also exhibits a 50% increase of the deep southward export of CFC‐12 at 24°N. The difference between the two model runs is shown to be a consequence of the different paths taken by the Deep Western Boundary Current in the two model versions.

Description: We present a numerical eigenmode analysis of an intermediate El Nin˜o–Southern Oscillation (ENSO) model which is driven by present-day observed background conditions as well as by simulated background conditions for the Last Glacial Maximum (LGM) about 21,000 years ago. The background conditions are obtained from two LGM simulations which were performed with the National Center for Atmospheric Research climate system model (CSM1.4) and an Earth system model of intermediate complexity (ECBilt-CLIO). Our analysis clearly shows that the leading present-day unstable recharge-discharge mode changes its stability as well as its frequency during LGM conditions. Simulated LGM background conditions were favorable to support large-amplitude self-sustained interannual ENSO variations in the tropical Pacific. Our analysis indicates that off-equatorial climate conditions as well as a shoaling of the thermocline play a crucial role in amplifying the LGM ENSO mode.

Description: The annual cycle is one of the most important components of the global climate system Yet little attention has been paid to the response of the equatorial annual cycle to anthropogenic climate change. Here we present results from a global climate model with high tropical resolution that simulates a strong intensification of the annual cycle in the tropical Pacific in response to increased greenhouse gas concentrations. This sensitivity of the tropical annual cycle to greenhouse warming can be explained in terms of tropical ocean‐atmosphere feedbacks. A possible amplification of the tropical annual cycle is expected to have also profound ecological and societal impacts.

Description: On seasonal time scales, ENSO prediction has become feasible in an operational framework in recent years. On decadal to multidecadal time scales, the variability of the oceanic circulation is assumed to provide a potential for climate prediction. To investigate the decadal predictability of the coupled atmosphere–ocean general circulation model (AOGCM) European Centre-Hamburg model version 5/Max Planck Institute Ocean Model (ECHAM5/MPI-OM), a 500-yr-long control integration and “perfect model” predictability experiments are analyzed. The results show that the sea surface temperatures (SSTs) of the North Atlantic, Nordic Seas, and Southern Ocean exhibit predictability on multidecadal time scales. Over the ocean, the predictability of surface air temperature (SAT) is very similar to that of SST. Over land, there is little evidence of decadal predictability of SAT except for some small maritime-influenced regions of Europe. The AOGCM produces predictable signals in lower-tropospheric temperature and precipitation over the North Atlantic, but not in sea level pressure.

Description: A series of numerical experiments using a three-dimensional, coupled ecosystem-circulation model has been performed to evaluate the impact of variations on an “intraseasonal” daily to monthly timescale in surface fluxes of heat and momentum on simulated biological production in the Arabian Sea. The biological component is a four-compartment, nitrogen-based system; the physical component is a high-vertical-resolution z-level model that includes a mixed-layer model based on the turbulent energy equation and contrasts with layer models which often overestimate vertical mixing associated with intraseasonal mixed-layer retreat and formation. Experiments show that the intraseasonal variations in the forcing may have to be considered when comparing sparsely sampled data with results from a numerical model. The experiments provide, however, no evidence that there is any rectification impact on longer timescales. In particular, accounting for intraseasonal variations has essentially no effect on the simulated annual mean biological production.

Description: Nitrous oxide (N2O) was measured during the first German SOLAS (Surface Ocean – Lower Atmosphere Study) cruise in the tropical North Atlantic Ocean on board R/V Meteor during October/November 2002. About 900 atmospheric and dissolved N2O measurements were performed with a semi-continuous GC-ECD system equipped with a seawater-gas equilibrator. Surface waters along the main transect at 10°N showed no distinct longitudinal gradient. Instead, N2O saturations were highly variable ranging from 97% to 118% (in the Guinea Dome Area, 11°N, 24°W). When approaching the continental shelf of West Africa, N2O surface saturations went up to 113%. N2O saturations in the region of the equatorial upwelling (at 0–1.5°N, 23.5–26°W) were correlated with decreasing sea surface temperatures and showed saturations up to 109%. The overall mean N2O saturation was 104 ± 4% indicating that the tropical North Atlantic Ocean is a net source of atmospheric N2O.

Description: [1] Toward understanding of the subduction mass balance in the Izu-Bonin-Mariana (IBM) convergent margin, we present an inventory of N and C concentrations and isotopic compositions in sediments obtained on Ocean Drilling Program (ODP) Legs 129 and 185. Samples from Sites 1149, 800, 801, and 802 contain 5 to 661 ppm total N (organic, inorganic combined) with δ15NAir of −0.2 to +8.2‰ (all δ15N values 〈+2.5‰ from Site 800). At Site 1149, N content is higher in clay-rich layers and lower in chert and carbonate layers, and δ15N shows a distinct down-section decrease from 0 to 120 mbsf (near +8.0 at shallow levels to near +4.0‰). Reduced-C concentration ranges from 0.02 to 0.5 wt.%, with δ13CVPDB of −28.1 to −21.7‰. The down-section decreases in δ15N and N concentration (and variations in concentrations and δ13C of reduced C, and Creduced/N) at Site 1149 could help reconcile differences between δ15N values of modern deep-sea sediments from near the sediment-water interface and values for forearc metasedimentary rocks. At Site 1149, negative shifts in δ15N, from marine organic values (up to ∼+8‰) toward lower values approaching those for the metasedimentary rocks (+1 to +3‰), are most likely caused by complex diagenetic processes, conceivably with minor effects of changes in productivity and differing proportions of marine and terrestrial organic matter. However, the forearc metamorphic suites (e.g., Franciscan Complex) are known to have been deposited nearer continents, and their lower δ15N at least partly reflects larger proportions of lower-δ15N terrestrial organic matter. Subduction at the Izu-Bonin (IB) margin, of a sediment section like that at Site 1149, would deliver an approximate annual subduction flux of 2.5 × 106 g of N and 1.4 × 107 g of reduced C per linear kilometer of trench, with average δ15N of +5.0‰ and δ13C of −24‰. Incorporating the larger C flux of 9.2 × 108 g/yr/linear-km in carbonate-rich layers of 1149B (average δ13C = +2.3‰) provides a total C flux of 9.3 × 108 g/yr/linear-km (δ13C = +1.9‰). Once subducted, sediments are shifted to higher δ15N by N loss during devolatilization, with magnitudes of the shifts depending on the thermal evolution of the margin.

Description: Great earthquakes in subduction zones occur after stable slip in the proto-seismogenic zone transitions to the unstable slip that characterizes seismogenic zones. Subducted material input to seismogenic zones affects this transition. Material structure, lithology and physical properties change progressively during subduction, and according to current hypotheses, specific material transformations trigger the stable to unstable slip transition.Where accretion dominates a convergent margin, material input is trench sediment that is easily drill-sampled. However, where erosion dominates a margin, material input is unknown because it originates along the base of the upper plate and alters differently. The depth at which material is eroded lies beyond the sampling capabilities of past scientific ocean drilling, so the protoseismogenic zone transformed material has never been drill-sampled; nor does geophysics resolve its structure, lithology, and physical properties. The Japanese riser drill ship Chikyu in the Integrated Ocean Drilling Program (IODP) overcomes this difficulty. Preparing a site for deep drilling is a much greater task than preparing the shallower sites of past programs, so this is accomplished during workshops.

Description: Three simple fisheries indicators are presented: (i) percentage of mature fish in catch, with 100% as target; (ii) percent of specimens with optimum length in catch, with 100% as target; and (iii) percentage of ‘mega-spawners‘ in catch, with 0% as target, and 30–40% as representative of reasonable stock structure if no upper size limit exists. Application of these indicators to stocks of Gadus morhua, Sardinella aurita and Epinephelus aeneus demonstrate their usefulness. It is argued that such simple indicators have the potential to allow more stakeholders such as fishers, fish dealers, supermarket managers, consumers and politicians to participate in fisheries management and eventually hold and reverse the global pattern of convenience overfishing, which is defined here as deliberate overfishing sanctioned by official bodies who find it more convenient to risk eventual collapse of fish stocks than to risk social and political conflicts.

Description: The Cascadia convergent margin is a first-order research target to study the impact of rapid sedimentation processes on the mechanics of frontal subduction zone accretion. The near-trench part of the accretionary prism offshore Washington is affected by strongly increased glacial age sedimentation and fan formation that led to an outstanding Quaternary growth rate with landward vergent thrust faulting that is rarely observed elsewhere in accretionary wedges. Multichannel seismic reflection data acquired on the ORWELL project allows us to study the structure and dynamics of the atypical frontal accretion processes. We performed a kinematical and mechanical analysis of the frontal accretion structures, and developed a dynamic Coulomb-wedge model for the landward-verging backthrust formation. Backthrusting results from heterogeneous diffuse strain accumulation in the mechanically heterogeneous Cascadia basin sediment succession entering the subduction zone, and strain partitioning along a midlevel detachment that is activated by gravitational loading caused by rapid glacial age sedimentation. These complex deformation processes cause the passive “upward” delamination of the upper turbidite beds from the basal pelagic carbonate section similar to triangle-zone formation and passive backthrust wedging in foreland thrust belts caused by rapid burial beneath syntectonic sediment deposits. The deformation mechanism at the tectonic front of the Cascadia margin is an immediate response to the strongly increased late Pleistocene sediment flux rather than to atypical physical boundary conditions as generally thought.

Description: According to a recent study, C:N ratios of sinking particulate organic matter (POM) in the ocean appear to be higher than Redfield (7.1 instead of 6.6) and depth dependent (increase +0.2/km). Here we investigate the effects of vertically variable C:N element ratios on marine carbon fluxes and the air-sea exchange of CO2 using a global ocean carbon cycle model (AAMOCC). For a steady-state ocean, the results show that models using the constant classical Redfield ratio underestimate both, total inventory and vertical gradients of dissolved inorganic carbon (DIC). While the amount of additional DIC (+150 Gt C) is negligible compared to the high marine carbon inventory, the C:N depth dependence can reduce the ambient atmospheric pCO2 by 20 ppm, permanently. Moreover, the simulation of a future scenario, estimating a possible effect of CO2-dependent C:N ratios of POM on the marine carbon cycle, has shown that even a moderate rise in the C:N element ratio of sinking POM, which is on the order of magnitude of natural variability, yields a considerably higher oceanic uptake of anthropogenic CO2 on timescales of decades to centuries. The assumption is based on a predicted increase in the production of highly carbon enriched transparent exopolymer particles (TEP) caused by rising atmospheric CO2 concentrations and enhanced nutrient limitation. However, counteracting a predicted decrease of the physical (solubility) CO2 pump as a consequence of global change, the effect in our scenario will alleviate further rising atmospheric CO2 concentrations rather than compensate a reduced physical uptake.

Description: During the 1990s, ocean sampling expeditions were carried out as part of the World Ocean Circulation Experiment (WOCE), the Joint Global Ocean Flux Study (JGOFS), and the Ocean Atmosphere Carbon Exchange Study (OACES). Subsequently, a group of U.S. scientists synthesized the data into easily usable and readily available products. This collaboration is known as the Global Ocean Data Analysis Project (GLODAP). Results were merged into a common format data set, segregated by ocean. For comparison purposes, each ocean data set includes a small number of high‐quality historical cruises. The data were subjected to rigorous quality control procedures to eliminate systematic data measurement biases. The calibrated 1990s data were used to estimate anthropogenic CO2, potential alkalinity, CFC watermass ages, CFC partial pressure, bomb‐produced radiocarbon, and natural radiocarbon. These quantities were merged into the measured data files. The data were used to produce objectively gridded property maps at a 1° resolution on 33 depth surfaces chosen to match existing climatologies for temperature, salinity, oxygen, and nutrients. The mapped fields are interpreted as an annual mean distribution in spite of the inaccuracy in that assumption. Both the calibrated data and the gridded products are available from the Carbon Dioxide Information Analysis Center. Here we describe the important details of the data treatment and the mapping procedure, and present summary quantities and integrals for the various parameters.

Description: The huge warming of the Arctic that started in the early 1920s and lasted for almost two decades is one of the most spectacular climate events of the twentieth century. During the peak period 1930–40, the annually averaged temperature anomaly for the area 60°–90°N amounted to some 1.7°C. Whether this event is an example of an internal climate mode or is externally forced, such as by enhanced solar effects, is presently under debate. This study suggests that natural variability is a likely cause, with reduced sea ice cover being crucial for the warming. A robust sea ice–air temperature relationship was demonstrated by a set of four simulations with the atmospheric ECHAM model forced with observed SST and sea ice concentrations. An analysis of the spatial characteristics of the observed early twentieth-century surface air temperature anomaly revealed that it was associated with similar sea ice variations. Further investigation of the variability of Arctic surface temperature and sea ice cover was performed by analyzing data from a coupled ocean–atmosphere model. By analyzing climate anomalies in the model that are similar to those that occurred in the early twentieth century, it was found that the simulated temperature increase in the Arctic was related to enhanced wind-driven oceanic inflow into the Barents Sea with an associated sea ice retreat. The magnitude of the inflow is linked to the strength of westerlies into the Barents Sea. This study proposes a mechanism sustaining the enhanced westerly winds by a cyclonic atmospheric circulation in the Barents Sea region created by a strong surface heat flux over the ice-free areas. Observational data suggest a similar series of events during the early twentieth-century Arctic warming, including increasing westerly winds between Spitsbergen and Norway, reduced sea ice, and enhanced cyclonic circulation over the Barents Sea. At the same time, the North Atlantic Oscillation was weakening.

Description: Measurements of dissolved (DFe) and total iron (TFe) in the upper water column are presented from the German SOLAS (Surface Ocean ‐ Lower Atmosphere Study) cruise (M55), along a west to east transect at 10°N, in the equatorial Atlantic in October/November 2002. Aerosol samples were collected simultaneously during this time and are used to estimate an iron flux to the surface waters. Resulting flux estimates combined with iron inventories in the near surface waters reveal extremely short fractional mean residence times (6–62 days) for total (dissolved and particulate) iron in waters directly under the path of Saharan dust plumes. These results suggest that individual dust storms can supply a significant amount of the present iron upper water column inventory which is subsequent rapidly removed by aggregation and sinking.

Description: Methane clathrate hydrate (structure I) is found to be very strong, based on laboratory triaxial deformation experiments we have carried out on samples of synthetic, high‐purity, polycrystalline material. Samples were deformed in compressional creep tests (i.e., constant applied stress, σ), at conditions of confining pressure P = 50 and 100 MPa, strain rate 4.5 × 10−8 ≤ equation image ≤ 4.3 × 10−4 s−1, temperature 260 ≤ T ≤ 287 K, and internal methane pressure 10 ≤ PCH4 ≤ 15 MPa. At steady state, typically reached in a few percent strain, methane hydrate exhibited strength that was far higher than expected on the basis of published work. In terms of the standard high‐temperature creep law, equation image = Aσne−(E*+PV*)/RT the rheology is described by the constants A = 108.55 MPa−n s−1, n = 2.2, E* = 90,000 J mol−1, and V* = 19 cm3 mol−1. For comparison, at temperatures just below the ice point, methane hydrate at a given strain rate is over 20 times stronger than ice, and the contrast increases at lower temperatures. The possible occurrence of syntectonic dissociation of methane hydrate to methane plus free water in these experiments suggests that the high strength measured here may be only a lower bound. On Earth, high strength in hydrate‐bearing formations implies higher energy release upon decomposition and subsequent failure. In the outer solar system, if Titan has a 100‐km‐thick near‐surface layer of high‐strength, low‐thermal conductivity methane hydrate as has been suggested, its interior is likely to be considerably warmer than previously expected.

Description: Most Central American volcanoes occur in an impressive volcanic front that trends parallel to the strike of the subducting Cocos Plate. The volcanic front is a chain, made of right-stepping, linear segments, 100 to 300 Km in length. Volcanoes cluster into centers, whose spacing is random but averages about 27 Km. These closely spaced, easily accessible volcanic centers allow mapping of geochemical variations along the volcanic front. Abundant back-arc volcanoes in southeast Guatemala and central Honduras allow two cross-arc transects. Several element and isotope ratios (e.g. BalLa, Uffh, B/La, IOBe/9Be, 87Sr/86Sr) that are thought to signal subducted marine sediments or altered MORB consistently define a chevron pattern along the arc, with its maximum in Nicaragua. BalLa, a particularly sensitive signal, is 130 at the maximum in Nicaragua but decreases out on the limbs to 40 in Guatemala and 20 in Costa Rica, which is just above the nominal mantle value of 15. This high amplitude regional variation, roughly symmetrical about Nicaragua, contrasts with the near constancy, or small gradient, in several plate tectonic parameters such as convergence rate, age of the subducting Cocos Plate, and thickness and type of subducted sediment. The large geochemical changes over relatively short distances make Central America an important margin for seeking the tectonic causes of geochemical variations; the regional variation has both a high amplitude and structure, including flat areas and gradients. The geochemical database continues to improve and is already adequate to compare to tectonic models with length scales of 100 Km or longer.

Description: Oceanic ecosystems altered by interdecadal climate variability may provide a feedback to the physical climate by phytoplankton affecting heat fluxes into the upper ocean and dimethylsulfide fluxes into the atmosphere

Description: Intrinsic oscillations of stable geophysical surface frontal currents of the unsteady, nonlinear, reduced-gravity shallow-water equations on an f plane are investigated analytically and numerically. For frictional (Rayleigh) currents characterized by linear horizontal velocity components and parabolic cross sections, the primitive equations are reduced to a set of coupled nonlinear ordinary differential equations. In the inviscid case, two periodic analytical solutions of the nonlinear problem describing 1) the inertially reversing horizontal displacement of a surface frontal current having a fixed parabolic cross section and 2) the cross-front pulsation of a coastal current emerging from a motionless surface frontal layer are presented. In a linear and in a weakly nonlinear context, analytical expressions for field oscillations and their frequency shift relative to the inertial frequency are presented. For the fully nonlinear problem, solutions referring to a surface frontal coastal current are obtained analytically and numerically. These solutions show that the currents oscillate always superinertially, the frequency and the amplitude of their oscillations depending on the magnitude of the initial disturbance and on the squared current Rossby number. In a linear framework, it is shown that disturbances superimposed on the surface frontal current are standing waves within the bounded region, the frequencies of which are inertial/superinertial for the first mode/higher modes. In the same frame, a zeroth mode, which could be interpreted as the superposition of an inertial wave on a background vorticity field, would formally yield subinertial frequencies. For surface frontal currents affected by Rayleigh friction, it is shown that the magnitude of the mean current decays according to a power law and that the oscillations decay faster, because this decay follows an exponential law. Implications of the intrinsic oscillations and of their rapid dissipation for the near-inertial motion in an active ambient ocean are discussed.

Description: The southern central Chilean margin at the site of the largest historically recorded earthquake in the Valdivia region, in 1960 (Mw = 9.5), is part of the 5000-km-long active subduction system whose geodynamic evolution is controversially debated and poorly understood. Covering the area between 36° and 40°S, the oceanic crust is segmented by prominent fracture zones. The offshore forearc and its onshore continuation show a complex image with segments of varying geophysical character, and several fault systems active during the past 24 m.y. In autumn 2001, the project SPOC was organized to study the Subduction Processes Off Chile, with a focus on the seismogenic coupling zone and the forearc. The acquired seismic data crossing the Chilean subduction system were gathered in a combined offshore-onshore survey and provide new insights into the lithospheric structure and evolution of active margins with insignificant frontal accretion.

Description: [1] Very rare, halogen-rich andesite melt inclusions (HRA) in bytownitic plagioclase phenocrysts (An89–90) from tephra fallout of the Izu arc volcanic front (Izu VF) provide new insights into the processes of fluid release from slab trenchward to the volcanic front in a cool subduction zone. These HRA are markedly enriched in Cl, F and Li - by factors of up to 8 (Cl, F) and 1.5 (Li) - but indistinguishable with respect to the fluid-mobile large-ion lithophile elements (LILE; K, Sr, Rb, Cs, Ba, Pb, U), rare earths (REE) or high field strength elements (HFSE) from the low-K tholeiitic magmas of the Izu VF. We suggest that the chemical signature of the HRA reflects the presence of a fluid in the mantle source that originated from the serpentinized mantle peridotite above the metacrust. This “wedge serpentinite” presumably formed by fluid infiltration beneath the forearc and was subsequently down-dragged with the slab to arc front depths. The combined evidence from the Izu VF (∼110 km above slab) and the outer forearc serpentinite seamounts (∼25 to 30 km above slab) suggests that the slab flux of B and Cl is highest beneath the forearc, and decreases with increasing slab depths. In contrast, the slab flux of Li is minor beneath the forearc, but increases with depth. Fluorine may behave similarly to Li, whereas the fluid-mobile LILE appear to be largely retained in the slab trenchward from the Izu VF. Consequently, the chemical signatures of both Izu trench sediments and basaltic rocks appear preserved until arc front depths.

Description: Aspects of the dynamics of warm-core eddies evolving in a deep ocean are investigated using the results of laboratory experiments and numerical simulations. The vortices, produced experimentally in a system brought to solid body rotation by rapidly lifting a bottomless cylinder containing freshwater immersed in a salty ambient fluid, show clearly the presence of inertial oscillations: deepenings and contractions, shoalings and expansions, alternate during an exact inertial period. These pulsations, though predicted analytically and simulated numerically, had never been measured before for surface eddies having aspect ratios, as well as Rossby and Burger numbers, typical of geophysical warm-core eddies. The spatial structure of the vortex radial and tangential velocity components is analyzed using the experimental results and numerical simulations carried out by means of a layered, nonlinear, reduced-gravity frontal model. It is found that, while the dependence of the vortex radial velocity on the vortex radius evolves toward linearity as time elapses, different spatial structures seem to be possible for the vortex tangential velocity dependence. This behavior, which strongly differs from the “pulson” dynamics, is instead consistent with recently found analytical solutions of the nonlinear, reduced-gravity shallow-water equations describing the dynamics of warm-core eddies on an f plane.

Description: The convergent Sunda margin off Indonesia displays all geological features characteristic of an accretion-dominated subduction zone. A combined interpretation of prestack depth-migrated seismic reflection data and velocity information gained from refraction studies is supplemented by high-resolution bathymetric data and for the first time allows the exact mapping of backstop regimes. Initially, the outer high evolved as material was pushed against a static rigid arc framework backstop underlying a forearc basin. Increasing material strength of the outer high due to lithification formed a dynamic backstop, which controls accretion today. An out-of-sequence thrust marks the transition from the recent active frontal accretionary prism to the outer high and may be traced in the seismic and bathymetric data over the whole extent of the study area. The existence of a static as well as a dynamic backstop controls the forearc geometry and is associated with the segmentation of the forearc, which is observed in regimes of frontal as well as of oblique subduction. Mass balance calculations, which account for porosity changes and metamorphism, indicate a subduction history dominated by accretionary processes since the late Eocene. Accretion is associated with the low values of basal friction inferred for the Sunda margin. Structural investigations of conjugate fault planes indicate a very weak basal detachment. Effective stress analyses reveal that intrinsically weak material causes the high strength ratio of the detachment to the overlying sediments, whereas overpressuring within the frontal accretionary prism is negligible.

Description: Simplified representations of spatially inhomogeneous (three-dimensional (3-D)) clouds in radiative transfer models provide systematic errors when calculating solar broadband radiative fluxes. An example is the neglect of horizontal photon transports as it is the case for the independent column approximation (ICA). The present work tries to quantify and interpret these errors on the basis of a large set of 3-D mixed phase cloud scenarios with 3-D varying extinction coefficients, scattering phase functions, and single-scattering albedos. The cloud cases result from a mesoscale atmospheric circulation model with detailed cloud microphysics. Domain-averaged cloud radiative fluxes are calculated by means of a Monte Carlo radiative transfer model. Depending on cloud type and solar zenith angle (SZA) the differences between 3-D and ICA results range from +20 W m−2 to −30 W m−2 for the upward reflected fluxes and from +10 W m−2 to −7 W m−2 for the absorbed fluxes. The mean (averaged over all cloud realizations) errors of the ICA-based upward fluxes vary between 5 W m−2 overestimation at 15°SZA and 6 W m−2 underestimation at 75°SZA. The ICA underestimates the absorbed flux by ∼1–2 W m−2 for most SZA except for 75°. It is found that neglecting the horizontal variability of the absorption and scattering properties of the cloud hydrometeors leads to a general underestimation of solar broadband absorption by as much as 15 W m−2 with average values between 4 W m−2 at small SZA and 1 W m−2 at large SZA.

Description: Between 1996 and 1998, a concerted effort was made to study the deep open ocean convection in the Labrador Sea. Both in situ observations and numerical models were employed with close collaboration between the researchers in the fields of physical oceanography, boundary layer meteorology, and climate. A multitude of different methods were used to observe the state of ocean and atmosphere and determine the exchange between them over the experiment's period. The Labrador Sea Deep Convection Experiment data collection aims to assemble the observational data sets in order to facilitate the exchange and collaboration between the various projects and new projects for an overall synthesis. A common file format and a browsable inventory have been used so as to simplify the access to the data.

Description: Two large-scale free-drifting isobaric-floats experiments, “SOFARGOS”/Marine Science and Technology Programme, phase 2 (MAST2) and Mass Transfer and Ecosystem Response (MATER)/MAST3, undertaken in 1994–95 in the northwestern Mediterranean Sea and in 1997–98 in the Algerian Basin, respectively, have revealed for the first time that Western Mediterranean Deep Water, newly formed by deep convection in the Gulf of Lion (the so-called Medoc site), can be advected several hundreds of kilometers away from the formation area by anticyclonic submesoscale coherent vortices (SCVs). This behavior implies that SCVs participate actively in the large-scale thermohaline circulation and deep ventilation of the western Mediterranean Sea. These SCVs are characterized by small radius (5 km), very low potential vorticity, high aspect ratio (0.1), and extended lifetime (〉0.5 yr).

Description: Current hydrographic data can provide snapshots but no continuous timeseries of the meridional overturning circulation (MOC). Using output from two eddy-permitting numerical ocean models we test the feasibility of a monitoring system for the MOC in the North Atlantic. The results suggest that a relatively simple arrangement, using moorings placed across a longitude-depth section and the zonal wind stress, is able to capture most of the MOC strength and vertical structure as a function of time. Being closely related to the transport of energy to the North Atlantic, measuring the MOC would open the prospect of having continuous information about a key element of northern hemisphere climate.

Description: GLAMAP 2000 presents new reconstructions of the Atlantic's sea surface temperatures (SST) at the Last Glacial Maximum (LGM), defined at both 21,500–18,000 years B.P. (“Last Isotope Maximum”) and 23,000–19,000 years B.P. (maximum glacial sea level low stand and orbital minimum of solar insolation; EPILOG working group; see Mix et al. [2001]). These reconstructions use 275 sediment cores between the North Pole and 60°S with carefully defined chronostratigraphies. Four categories of core quality are distinguished. More than 100 core sections provide a glacial record with subcentennial- to multicentennial-scale resolution. SST estimates are based on a new set of almost 1000 reference samples of modern planktic foraminifera and on improved transfer-function techniques to deduce SST from census counts of microfossils, including radiolarians and diatoms. New proxies also serve to deduce sea ice boundaries. The GLAMAP 2000 SST patterns differ significantly in crucial regions from the CLIMAP [1981] reconstruction and thus are important in providing updated boundary conditions to initiate and validate computational models for climate prediction.

Description: This study has been motivated by reports of extraordinary change in the Arctic Ocean observed in recent decades. Most of these observations are based on synoptic measurements, while evaluation of anomalies requires an understanding of the underlying long-term variability. Historical climatologies give reference means, and while these datasets are a reliable source of the mean Atlantic Layer temperature, they significantly underestimate variability. Using historical data, we calculated statistical parameters for selected Arctic Ocean regions. They demonstrate a high level of Atlantic Layer temperature variability in the Nansen Basin and sea-surface salinity fluctuations on the Siberian shelf and the Amundsen Basin. These estimates suggest strong limitations on our ability to define amplitudes of anomalies by comparing recent synoptic measurements with climatologies, especially for regions characterized by strong variability.

Description: Bulk properties of the Denmark Strait overflow (DSO) plume observed in velocity and hydrography surveys undertaken in 1997 and 1998 are described. Despite the presence of considerable short-term variability, it is found that the pathway and evolution of the plume density anomaly are remarkably steady. Bottom stress measurements show that the pathway of the plume core matches well with a rate of descent controlled by friction. The estimated entrainment rate diagnosed from the rate of plume dilution with distance shows a marked increase in entrainment at approximately 125 km from the sill, leading to a net dilution consistent with previous reports of a doubling of overflow transport measured by current meter arrays. The entrainment rate increase is likely related to the increased topographic slopes in the region, compounded by a decrease in interface stratification as the plume is diluted and enters a denser background.

Description: A new shipboard current profiler, a 75-kHz ocean surveyor, was operationally used during two research cruises in the tropical Atlantic and the subpolar North Atlantic, respectively. Here, a report is presented on the first experience with this instrument in two very different current regimes, in the Tropics with large vertical shears, and in the subpolar regime with mainly barotropic flow. The ocean surveyor continuously measured currents in the upper ocean from near the surface to about 500–700-m depth. The measurement range showed a dependence on the regional and temporal variations of scattering particles and on the intensity of swell and wind waves. Statistical comparisons are performed with on-station lowered acoustic Doppler current profiler (LADCP) profiles and underway measurements by classic shipboard acoustic Doppler current profiler (ADCP) measurements. Accuracy estimates for hourly averaged ocean surveyor currents result in errors of about 1 cm s–1 for on-station data and of 2–4 cm s–1 for underway measurements, depending on the regional abundance of scatterers and on the weather conditions encountered.

Description: Conceptual models predict counteractive effects of herbivores and nutrient enrichment on plant diversity and reversed effects of grazers under different nutrient regimes. I tested these hypotheses in 11 field experiments with periphyton communities in three different aquatic habitats (a highly eutrophic lake, an meso-eutrophic lake, and an meso-eutrophic part of the Baltic Sea coast) and in different seasons. Grazer access and nutrient supply were manipulated in a factorial design. Species richness and evenness were chosen as response variables. Both manipulated factors had significant and contrasting effects on diversity, with variable effect strength between sites and seasons. From the two aspects of diversity, evenness well reflected the changes in community composition. Fertilization tended to increase the dominance of few species and thus to decrease evenness, whereas grazers counteracted these effects by removing dominant life forms. The response of species richness was not as expected, since grazers decreased richness throughout, whereas nutrients had weaker effects but tended to increase richness. Species richness rather reflected changes in periphyton architecture. Grazers reduced algal richness presumably by co-consumption of rare species in the tightly connected periphyton assemblages, whereas enrichment may increase richness by providing more structure via increased dominance of filamentous species. Although grazer and nutrient effects on richness and evenness were opposing, there was no change in the effect of one factor by manipulation of the other.

Description: [1] We report results of magnetic data from the Nazca Plate and of geochemical (major element and Sr-Nd-Pb-isotope) analyses of rocks dredged from the Galápagos hot spot tracks (Cocos, Carnegie, Malpelo and Coiba Ridges and adjacent seamounts) in the Central East Pacific. Magnetic anomalies indicate that the Malpelo and Carnegie Ridges were once attached and that seafloor spreading separated the two ridges between 14.5 Ma and 9.5 Ma. The variations in Sr-Nd-Pb isotopic composition show that three of the mantle components currently observed at the Galápagos (Central, Southern, and Eastern) existed in the hot spot for at least 20 m.y., whereas the Northern Galápagos mantle component has been present for at least ∼15 Ma. Our data are consistent with the existence of a compositionally zoned/striped Galápagos plume since ∼20 Ma. Combined constraints from the morphology of the hot spot tracks, the magnetic record, and the isotope geochemistry of the rock samples provide new insights into the hot spot-ridge geometry and interaction of the Galápagos hot spot with the Cocos-Nazca spreading center (CNS) over the past 20 m.y. At 19.5 Ma a ridge jump moved the spreading axis to the northern edge of the hot spot. Between 19.5 and 14.5 Ma, the spreading axis was located above the center of the hot spot. At 14.5 Ma, a new ridge jump moved the spreading axis to the south, splitting the paleo-Carnegie Ridge into the present Carnegie and Malpelo Ridges. The repeated ridge jumps reflect capture of the northwardly drifting spreading center by the Galápagos hot spot. At 11–12 Ma an offset of the spreading axis lay above the plume center. Spreading between the Carnegie and Malpelo Ridges continued until 9.5 Ma.

Description: A new mechanism is proposed that explains two key features of the observed El Niño–Southern Oscillation (ENSO) phenomenon—its irregularity and decadal amplitude changes. Using a low-order ENSO model, the authors show that the nonlinearities in the tropical heat budget can lead to bursting behavior characterized by decadal occurrences of strong El Niño events. La Niña events are not affected, a feature that is also seen in ENSO observations. One key result of this analysis is that decadal variability in the Tropics can be generated without invoking extratropical processes or stochastic forcing. The El Niño bursting behavior simulated by the low-order ENSO model can be understood in terms of the concept of homoclinic and heteroclinic connections. It is shown that this new model for ENSO amplitude modulations and irregularity, although difficult to prove, might explain some features of ENSO dynamics seen in more complex climate models and the observations.