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  • Chemistry  (8,282)
  • Humans  (7,470)
  • Electronic structure and strongly correlated systems  (4,181)
  • Waves
  • 2010-2014  (11,682)
  • 1935-1939  (8,273)
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  • 1
    Publication Date: 2021-05-19
    Description: Daily topical application of the aqueous ethanolic extract of the marine sea grass, Thalassia testudinum, on mice skin exposed to UVB radiation resulted in a dose dependent recovery of the skin macroscopic alterations over a 6-day period. Maximal effect (90%) occurred at a dose of 240 μg/cm2, with no additional effects at higher doses. Bioassay-guided fractionation of the plant extract resulted in the isolation of thalassiolin B (1). Topical application of 1 (240 μg/cm2) markedly reduces skin UVB-induced damage. In addition, thalassiolin B scavenged 2,2-diphenyl-2-picrylhydrazyl radical with an EC50=100 μg/ml. These results suggest that thalassiolin B is responsible for the skin regenerating effects of the crude extract of T. testudinum
    Description: Published
    Description: Flavonoids, Thalassiolin B, DPPH scavenged, antioxidant activity, Skin regenerating activity, Thalassia testudinum
    Keywords: Chemistry ; Pharmacology ; Chemistry ; Pharmacology
    Repository Name: AquaDocs
    Type: Journal Contribution
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  • 2
    Publication Date: 2021-05-19
    Description: Bioguided fractionation of Agelas cerebrum crude extract resulted in isolation of four bromopyrrole and four bromopyrrole aminoimidazole alkaloids, identified as 5-bromopyrrole-2-carboxylic acid (1), 4-bromopyrrole-2-carboxylic acid (2), 3,4-bromopyrrole-2-carboxylic acid (3), 4,5-bromopyrrole-2-carboxylic acid (4), oroidin (5), bromoageliferin (6), dibromoageliferin (7) and dibromosceptrin (8) on the basis of spectroscopic data analyses (UV, IR, HRMS, 1D and 2D NMR) and comparison with literature data. This is the first report of compounds 2 and 3 in a marine sponge belonging to the Agelas genus and the first evidence of the presence of 1 from a natural source.
    Description: Published
    Description: Agelas cerebrum, bromopyrrole alkaloids, antitumoral, antiprotozoal activity
    Keywords: Chemistry ; Alkaloids ; Sponges ; Alkaloids ; Sponges ; Chemistry
    Repository Name: AquaDocs
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  • 3
    Publication Date: 2021-05-19
    Description: La velocidad de descomposición de tres fenólicos, el p-hidroxibenzoico, el protocatecúico y el gálico, los cuales se diferencian en el número de grupos OH, fue investigada en el suelo. Con el aumento de grupos OH aumenta también la velocidad de descomposición microbial. El ácido gálico se descompone más rápido que el protocatecúico y este a su vez más rápido que el phidroxibenzoico.
    Description: The rate of decomposition of the three phenolics, p-hydroxybenzoic acid, protocatechuic acid and gallic acid, whose difference is the amount of OH-groups, was investigated in the soil. With the increase in OH-groups increases the rate of microbial decomposition. Gallic acid decomposes faster than protocatecuic acid and this again faster than p-hydroxybenzoic acid.
    Description: Published
    Keywords: Chemical decomposition ; OH Groups ; Microbes ; Phenols ; Chemistry ; Phenols ; Chemistry
    Repository Name: AquaDocs
    Type: Journal Contribution
    Format: pp.141-143
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  • 4
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2004. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 109 (2004): C01027, doi:10.1029/2003JC001877.
    Description: Vertical flow structure and turbulent dissipation in the swash zone are estimated using cross-shore fluid velocities observed on a low-sloped, fine-grained sandy beach [Raubenheimer, 2002] with two stacks of three current meters located about 2, 5, and 8 cm above the bed. The observations are consistent with an approximately logarithmic vertical decay of wave orbital velocities within 5 cm of the bed. The associated friction coefficients are similar in both the uprush and downrush, as in previous laboratory results. Turbulent dissipation rates estimated from velocity spectra increase with decreasing water depth from O(400 cm2/s3) in the inner surf zone to O(1000 cm2/s3) in the swash zone. Friction coefficients in the swash interior estimated with the logarithmic model and independently estimated by assuming that turbulent dissipation is balanced by production from vertical shear of the local mean flow and from wave breaking are between 0.02 and 0.06. These values are similar to the range of friction coefficients (0.02–0.05) recently estimated on impermeable, rough, nonerodible laboratory beaches and to the range of friction coefficients (0.01–0.03) previously estimated from field observations of the motion of the shoreward edge of the swash (run-up).
    Description: This research was supported by ONR and NSF.
    Keywords: Beach ; Swash ; Waves
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 5
    Publication Date: 2022-05-25
    Description: Author Posting. © American Meteorological Society, 2010. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 40 (2010): 2605–2623, doi:10.1175/2010JPO4132.1.
    Description: Steady scale-invariant solutions of a kinetic equation describing the statistics of oceanic internal gravity waves based on wave turbulence theory are investigated. It is shown in the nonrotating scale-invariant limit that the collision integral in the kinetic equation diverges for almost all spectral power-law exponents. These divergences come from resonant interactions with the smallest horizontal wavenumbers and/or the largest horizontal wavenumbers with extreme scale separations. A small domain is identified in which the scale-invariant collision integral converges and numerically find a convergent power-law solution. This numerical solution is close to the Garrett–Munk spectrum. Power-law exponents that potentially permit a balance between the infrared and ultraviolet divergences are investigated. The balanced exponents are generalizations of an exact solution of the scale-invariant kinetic equation, the Pelinovsky–Raevsky spectrum. A small but finite Coriolis parameter representing the effects of rotation is introduced into the kinetic equation to determine solutions over the divergent part of the domain using rigorous asymptotic arguments. This gives rise to the induced diffusion regime. The derivation of the kinetic equation is based on an assumption of weak nonlinearity. Dominance of the nonlocal interactions puts the self-consistency of the kinetic equation at risk. However, these weakly nonlinear stationary states are consistent with much of the observational evidence.
    Description: This research is supported by NSF CMG Grants 0417724, 0417732 and 0417466. YL is also supported by NSF DMS Grant 0807871 and ONR Award N00014-09-1-0515.
    Keywords: Waves ; Oceanic ; Internal waves ; Spectral analysis
    Repository Name: Woods Hole Open Access Server
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  • 6
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    Massachusetts Institute of Technology and Woods Hole Oceanographic Institution
    Publication Date: 2022-05-25
    Description: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution May 1993
    Description: Breaking waves charge the surface layer of the ocean with small air bubbles which play an important role in air-sea gas transfer and in underwater acoustics near the ocean surface. This work reports on a series of laboratory and field experiments on the measurement on air entrainment by breaking waves. The first part of this thesis addresses the measurement of high volumetric concentrations of air (0.3% to 100% void-fraction) found immediately beneath breaking waves. Instrumentation based on the change of electrical impedance of the bubbly mixture with change in void-fraction is developed. Laboratory measurements are conducted in a wave channel and in a large three-dimensional wave basin. Maps of the evolution of the void-fraction distribution in bubble plumes generated by various size breaking waves are presented. Moments of the void-fraction field are shown to scale with the initially enclosed air volume at breaking and the energy dissipated by breaking. A significant fraction (30 to 50%) of the energy dissipated by breaking is found to be expanded in entraining bubbles against their buoyancy. The results reveal that the bubble plumes experience rapid transformations within the first wave period after the onset of breaking. In particular, the plumes loose 95% of the initially entrained air volume during the fust wave period. Predictions of the low-frequency resonant oscillations of the bubble plumes from measurements of the void-fraction compare well with acoustic measurements. Measurements near the ocean surface show high void-fractions up to 24% immediately beneath breaking waves. These are several orders of magnitude greater than previously reported time-averaged measurements. The second part addresses the measurement of very low void-fractions. Instrumentation based on the propagation velocity of low-frequency acoustic pulses is developed. Simultaneous measurements of the sound-speed (and thus the void-fraction) at several depths are conducted during two field experiments. Time-series of sound-speed and attenuation show dramatic fluctuations over time periods on the order of minutes or less. These are attributed to the formation of bubble plumes or passage of bubble clouds. Frequent occurences of sound-speed anomalies greater than 1 OOrnls and attenuation greater than 30dB/m are observed for moderate wind conditions (8m/s). The signals at various depths are highly correlated and mostly coherent at frequencies below 0.05Hz. The time-averaged (20min) sound-speed profile is found to be significantly more pronounced and shallower than previously reported. Simultaneous measurements at several acoustic frequencies show that the sound-speed is non-dispersive below 20kHz for moderate wind conditions. Bubble size distributions are inferred from the soundspeed and attenuation measurements.
    Description: This research was funded by the Office of Naval Research (Ocean Acoustics and Oceanography) and the National Science Foundation.
    Keywords: Acoustic surface waves ; Air ; Waves
    Repository Name: Woods Hole Open Access Server
    Type: Thesis
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  • 7
    Publication Date: 2022-05-25
    Description: Author Posting. © American Meteorological Society, 2013. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 43 (2013): 2132–2141, doi:10.1175/JPO-D-12-0182.1.
    Description: Repeated occupations of two hydrographic sections in the southwest Pacific basin from the 1990s to 2000s track property changes of Antarctic Bottom Water (AABW). The largest property changes—warming, freshening, increase in total carbon, and decrease in oxygen—are found near the basin’s deep western boundary between 50° and 20°S. The magnitude of the property changes decreases with increasing distance from the western boundary. At the deep western boundary, analysis of the relative importance of AABW (γn 〉 28.1 kg m−3) freshening, heating, or isopycnal heave suggests that the deep ocean stratification change is the result of both warming and freshening processes. The consistent deep ocean changes near the western boundary of the southwest Pacific basin dispel the notion that the deep ocean is quiescent. High-latitude climate variability is being directly transmitted into the deep southwest Pacific basin and the global deep ocean through dynamic deep western boundary currents.
    Description: BMS, SEW, and BT were supported by the Australian Climate Change Science Program, funded jointly by the Department of Climate Change and Energy Efficiency and CSIRO. Funding for AM was provided through NOAA GrantNA110AR4310063.
    Description: 2014-04-01
    Keywords: Circulation/ Dynamics ; Waves ; Oceanic
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 8
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2006. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 111 (2006): C03016, doi:10.1029/2005JC003004.
    Description: Waves have many effects on near-surface dynamics: Breaking waves enhance mixing, waves are associated with a Lagrangian mean drift (the Stokes drift), waves act on the mean flow by creating Langmuir circulations and a return flow opposite to the Stokes drift, and, last but not least, waves modify the atmospheric surface roughness. A realistic ocean model is proposed to embrace all these aspects, focusing on near-surface mixing and surface drift associated with the wind and generated waves. The model is based on the generalized Lagrangian mean that separates the momentum into a wave pseudomomentum and a quasi-Eulerian momentum. A wave spectrum with a reasonably high frequency range is used to compute the Stokes drift. A turbulent closure scheme based on a single evolution equation for the turbulent kinetic energy includes the mixing due to breaking wave effects and wave-turbulence interactions. The roughness length of the closure scheme is adjusted using observations of turbulent kinetic energy near the surface. The model is applied to unstratified and horizontally uniform conditions, showing good agreement with observations of strongly mixed quasi-Eulerian currents near the surface when waves are developed. Model results suggest that a strong surface shear persists in the drift current because of the Stokes drift contribution. In the present model the surface drift only reaches 1.5% of the wind speed. It is argued that stratification and the properties of drifting objects may lead to a supplementary drift as large as 1% of the wind speed.
    Keywords: Stokes drift ; Surface drift ; Waves
    Repository Name: Woods Hole Open Access Server
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  • 9
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    Massachusetts Institute of Technology and Woods Hole Oceanographic Institution
    Publication Date: 2022-05-25
    Description: Submitted in partial fulfillment of the requirements for the degree of Master of Science at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution September 1997
    Description: A series of numerical experiments is conducted in order to examine the role of topographic irregularities in generation of subinertial cross-channel barotropic currents and to obtain quantitative estimates of the offshore flow amplitude, its ratio to the magnitude of the alongshore currents and the alongshore correlation scale. A periodic (along the coast) channel with geometry representative of continental margins is considered. Topographic disturbances have multiple alongshore wavenumber contributions, kT, and the amplitude proportional to kT-2 (except one experiment). The motion is forced by spatially uniform and temporally varying alongshore wind stress, which drives the background current along the channel. The background current adjusts to topographic disturbances and, in particular, Barotropic Shelf Waves (BSW) result. That gives rise to the offshore currents. The amplitude of the cross-channel flow is shown to increase with kT in the long wave limit (order of 100 km in the model) and, in contrast, to decrease with kT in the short wave limit (less than 20 km in the model). As a rule, the strongest response is attained on the intermediate scales where lee waves form most efficiently. Hart's {1990} quasi-geostrophic solution provided quantitative parameters to explain the scale dependence and helped to interpret the results of simulations meant to examine sensitivity of the cross-channel flow characteristics to variation of the governing parameters. It is shown that the structure of the resonant wave is established by the combination of spatial properties of the bottom bumps, and by the period and amplitude of the fluctuating background current. On the basis of this analysis, it is demonstrated how the BSW dispersion diagram can be used for diagnostic purposes. The averaged (in time and along the channel) amplitude of subinertial cross-channel currents ranged from negligible values to about 5.5 cm/sec, indicating that, indeed, rather substantial offshore flow can be generated due to the effect of the topographic irregularities. The alongshore correlation scale was no smaller than about 5 km and in a few simulations (for instance, with lee-wave-favourable mean wind included) reached 30 - 50 km.
    Description: This work was supported by the Office of Naval Research, Coastal Science Program, Grant N00014-95-1-0580.
    Keywords: Upwelling ; Waves
    Repository Name: Woods Hole Open Access Server
    Type: Thesis
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  • 10
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    Massachusetts Institute of Technology and Woods Hole Oceanographic Institution
    Publication Date: 2022-05-25
    Description: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution May 1998
    Description: Planktonic protozoan grazers have the potential to significantly affect the chemistry of particle-associated trace metals. This is due both to the importance of protists as consumers of bacterial-sized particles, and to the unique low-pH, enzyme-rich microenvironment of the grazer food vacuole. This thesis examines the role of protozoan grazers in the marine geochemistry of strongly hydrolyzed, particle-reactive trace metals, in particular Th and Fe. A series of tracer experiments was carried out in model systems in order to determine the effect of grazer-mediated transformations on the chemical speciation and partitioning of radioisotopes C9Fe, 234Th, 51Cr) associated with prey cells. Results indicate that protozoan grazers are equally able to mobilize intracellular and extracellular trace metals. In some cases, protozoan regeneration of trace metals appears to lead to the formation of metal-organic complexes. Protozoan grazing may generate colloidal material that can scavenge trace metals and, via aggregation, lead to an increase in the metal/organic carbon ratio of aggregated particles. Model system experiments were also conducted in order to determine the effect of grazers on mineral phases, specifically colloidal iron oxide (ferrihydrite). Several independent techniques were employed, including size fractionation ors9Fe-labeled colloids, competitive ligand exchange, and iron-limited diatoms as "probes" for bioavailable Fe. Experimental evidence strongly suggests that protozoan grazing can affect the surface chemistry and increase the dissolution rate of iron oxide phases through phagotrophic ingestion. In further work on protozoan-mediated dissolution of colloidal Fe oxides, a novel tracer technique was developed based on the synthesis of colloidal ferrihydrite impregnated with 133Ba as an inert tracer. This technique was shown to be a sensitive, quantitative indicator for the extent of ferrihydrite dissolution/alteration by a variety of mechanisms, including photochemical reduction and ligand-mediated dissolution. In field experiments using this technique, grazing by naturally occuring protistan assemblages was shown to significantly enhance the dissolution rate of colloidal ferrihydrite over that in non-grazing controls. Laboratory and field results indicate that, when integrated temporally over the entire euphotic zone, protozoan grazing may equal or exceed photoreduction as a pathway for the dissolution of iron oxides.
    Description: This work was financially supported by a Department of Defense ONR-NDSEG Graduate Fellowship, Office ofNaval Research AASERT Award (N00014-94-1-0711), and the National Science Foundation EGB Program (OCE-9523910).
    Keywords: Protozoa ; Water chemistry ; Trace elements in water ; Marine zooplankton ; Chemistry
    Repository Name: Woods Hole Open Access Server
    Type: Thesis
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  • 11
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    Massachusetts Institute of Technology and Woods Hole Oceanographic Institution
    Publication Date: 2022-05-25
    Description: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution October 1987
    Description: A two-layer shallow water equation model is used to investigate the linear stability of a coastal upwelling front. The model features a surface front near a coastal boundary and bottom topography which is an arbitrary function of the cross-shelf coordinate. By combining the various conservation statements for the global properties of the system, a general stability theorem is established which allows the a priori determination of the stability of a coastal upwelling front. Unstable waves are found for the modelled coastal upwelling front. The unstable wave motions are frontally-trapped and dominant in the upper layer. The wave propagates phase in the direction of the basic state flow and the primary energy conversion is via baroclinic instability. The effect of varying the model parameters is presented. Moving the front closer than ~ 2 Rossby radii to the coastal boundary results in a decrease in the growth rate of the fastest growing wave. Increasing the overall vertical shear of the basic state flow, by either decreasing the lower layer depth or increasing the steepness of the interface, results in an increase in the growth of the fastest growing wave. A bottom sloping in the same sense as the interface results in a decrease of the growth rates and alongfront wavenumbers of the unstable waves in the system. Linearized bottom friction is included in the stability model and results in a decrease in the growth rates of the unstable waves by extracting energy from the system. Since the unstable mode is strongest in the upper layer, bottom friction will not stabilize the upwelling front. A comparison between the predictions from the simple two-layer model and observed alongfront variability for three areas of active upwelling is presented. Reasonable agreement is found, suggesting that observed alongfront variability can be interpreted in terms of the instability of a coastal upwelling front.
    Description: This study was supported by the National Science Foundation Grant OCE 84-08563 and the Office of Naval Research Coastal Ocean Sciences Program 10/1984.37.
    Keywords: Upwelling ; Waves
    Repository Name: Woods Hole Open Access Server
    Type: Thesis
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  • 12
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    Massachusetts Institute of Technology and Woods Hole Oceanographic Institution
    Publication Date: 2022-05-25
    Description: Submitted in partial fulfillment of the requirements for the degree of Ocean Engineer at the Massachusetts Institute of Technology and Woods Hole Oceanographic Institution September 1994
    Description: This paper presents a method for estimating the spectra of water wave disturbances on five of the six axes of a stationary, slender body underwater vehicle in an inertia dominated wave force regime, both in head seas and in beam seas. Inertia dominated wave forces are typical of those encountered by a 21 inch diameter, torpedo shaped underwater vehicle operating in coastal waters and sea state 2. Strip theory is used to develop transfer function phase and magnitude between surface water waves and the slender body pitch, heave, and surge forces and moment for the vehicle in head seas, and for pitch, heave, yaw, and sway forces and moments in beam seas. Experiments are conducted which verify this method of transfer function calculation, and demonstrate the effects of vehicle forward motion in the head seas case. Using known sea spectra and linear time invariant systems theory allows for estimation of the water wave disturbance spectra for these forces and moments. Application of sliding control techniques are then developed for the underwater vehicle longitudinal plane equations of motion. Computer simulations are used to demonstrate the dependence of underwater vehicle depth control upon the pitch control, and adaptive pitch control is shown to provide good performance in the presence of substantial parametric uncertainty. Pitch disturbance rejection properties of variations of the sliding controller are investigated. Both single frequency and stochastic disturbances are used, and the stochastic disturbance is developed using the results of the earlier investigation.
    Description: This research was sponsored in part by ONR Contract N00014-90-J-1912.
    Keywords: Submersibles ; Waves
    Repository Name: Woods Hole Open Access Server
    Type: Thesis
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  • 13
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2012. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 39 (2012): L24604, doi:10.1029/2012GL054034.
    Description: Eddies and vortices associated with breaking waves rapidly disperse pollution, nutrients, and terrestrial material along the coast. Although theory and numerical models suggest that vorticity is generated near the ends of a breaking wave crest, this hypothesis has not been tested in the field. Here we report the first observations of wave-generated vertical vorticity (e.g., horizontal eddies), and find that individual short-crested breaking waves generate significant vorticity [O(0.01 s−1)] in the surfzone. Left- and right-handed wave ends generate vorticity of opposite sign, consistent with theory. In contrast to theory, the observed vorticity also increases inside the breaking crest, possibly owing to onshore advection of vorticity generated at previous stages of breaking or from the shape of the breaking region. Short-crested breaking transferred energy from incident waves to lower frequency rotational motions that are a primary mechanism for dispersion near the shoreline.
    Description: Funding was provided by a National Security Science and Engineering Faculty Fellowship, the Office of Naval Research, and a Woods Hole Oceanographic Institution Postdoctoral Fellowship.
    Description: 2013-06-21
    Keywords: Mixing ; Nearshore ; Turbulence ; Vorticity ; Waves
    Repository Name: Woods Hole Open Access Server
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  • 14
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    Massachusetts Institute of Technology and Woods Hole Oceanographic Institution
    Publication Date: 2022-05-25
    Description: Submitted in partial fulfillment of the requirements for the degree of Ocean Engineer at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution September 1991
    Description: A model is developed for the prediction of the seismo-acoustic noise spectrum in the microseism peak region (0.1 to 0.7 Hz). The model uses a theory developed by Cato [J. Acoust. Soc. Am., 89 , 1096-1112 (1991)] for an infinite depth ocean in which the surface orbital motion caused by gravity waves may produce acoustic waves at twice the gravity wave frequency. Using directional wave spectra as inputs, acoustic source levels are computed and incorporated into a more realistic environment consisting of a horizontally stratified ocean with an elastic bottom. Noise predictions are made using directional wave spectra obtained from the SWADE surface buoys moored off the coast of Virginia and the SAFARI sound propagation code, with a bottom model derived using wave speeds measured in the EDGE deep seismic reflection survey. The predictions are analyzed for noise level variations with frequency, wave height, wind direction, and receiver depth. These predictions are compared to noise measurements made in ECONOMEX using near-bottom receivers located close to the surface buoys. Good agreement is found between the predictions and observations under a variety of environmental conditions.
    Keywords: Underwater acoustics ; Waves
    Repository Name: Woods Hole Open Access Server
    Type: Thesis
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  • 15
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2013. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Oceans 118 (2013): 6319–6328, doi:10.1002/2013JC008939.
    Description: Strong and strategic collaborations among experts from academia, federal operational centers, and industry have been forged to create a U.S. IOOS Coastal and Ocean Modeling Testbed (COMT). The COMT mission is to accelerate the transition of scientific and technical advances from the coastal and ocean modeling research community to improved operational ocean products and services. This is achieved via the evaluation of existing technology or the development of new technology depending on the status of technology within the research community. The initial phase of the COMT has addressed three coastal and ocean prediction challenges of great societal importance: estuarine hypoxia, shelf hypoxia, and coastal inundation. A fourth effort concentrated on providing and refining the cyberinfrastructure and cyber tools to support the modeling work and to advance interoperability and community access to the COMT archive. This paper presents an overview of the initiation of the COMT, the findings of each team and a discussion of the role of the COMT in research to operations and its interface with the coastal and ocean modeling community in general. Detailed technical results are presented in the accompanying series of 16 technical papers in this special issue.
    Description: This project was supported by NOAA via the IOOS Office, award NA10NOS0120063 and NA11NOS0120141, and used the Extreme Science and Engineering Discovery Environment (XSEDE), which is supported by National Science Foundation grant OCI- 1053575.
    Keywords: Modeling ; Hypoxia ; Inundation ; Waves
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  • 16
    Publication Date: 2022-05-26
    Description: © The Authors, 2010. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Coral Reefs 30 (2011): 23-38, doi:10.1007/s00338-010-0705-3.
    Description: Sediment traps are commonly used as standard tools for monitoring “sedimentation” in coral reef environments. In much of the literature where sediment traps were used to measure the effects of “sedimentation” on corals, it is clear from deployment descriptions and interpretations of the resulting data that information derived from sediment traps has frequently been misinterpreted or misapplied. Despite their widespread use in this setting, sediment traps do not provide quantitative information about “sedimentation” on coral surfaces. Traps can provide useful information about the relative magnitude of sediment dynamics if trap deployment standards are used. This conclusion is based first on a brief review of the state of knowledge of sediment trap dynamics, which has primarily focused on traps deployed high above the seabed in relatively deep water, followed by our understanding of near-bed sediment dynamics in shallow-water environments that characterize coral reefs. This overview is followed by the first synthesis of near-bed sediment trap data collected with concurrent hydrodynamic information in coral reef environments. This collective information is utilized to develop nine protocols for using sediment traps in coral reef environments, which focus on trap parameters that researchers can control such as trap height (H), trap mouth diameter (D), the height of the trap mouth above the substrate (z o ), and the spacing between traps. The hydrodynamic behavior of sediment traps and the limitations of data derived from these traps should be forefront when interpreting sediment trap data to infer sediment transport processes in coral reef environments.
    Keywords: Sediment trap ; Coral reefs ; Sedimentation ; Waves ; Currents ; Shear stress
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  • 17
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    Massachusetts Institute of Technology and Woods Hole Oceanographic Institution
    Publication Date: 2022-05-26
    Description: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution November 1990
    Description: One and two layer models are used to study flow over axisymmetric isolated topography. Inviscid or nearly inviscid flow in which non-linear effects have order one importance is considered, and both the effects of β and finite topography are included. A one-layer quasi-geostrophic model is used to find the shape of Taylor columns on both the f-plane and the β-plane in the inviscid limit of the frictional problem. In this limit, the boundary of the Taylor column is a streamline, and the velocity in both directions vanishes on the boundary. The fluid within the Taylor column is stagnant, corresponding to the solution that Ingersoll (1969) found for flow over a right circular cylinder on the f-plane. In this case, the Taylor column is circular. An iterative boundary integral technique is used to find the solutions for flow over a cone on the f-plane. In this case the Taylor column has a tear drop shape. Solutions are also found for flow on the β-plane over a cylinder, and the Taylor column is approximately elliptical for westward flow with the major axis in the x direction, while it is slightly elongated in the y direction for eastward flow. The stagnation point of the Taylor column is located on the edge of the topography for all the solutions found. It was not possible to find solutions for smooth topographic shapes. Steady solutions for flow over a right circular cylinder of finite height are studied when the quasi-geostrophic approximation no longer applies. The solution consists of two parts, one which is similar to the quasi-geostrophic solution and is driven by the potential vorticity anomaly over the topography and the other which is similar to the solution of potential flow around an cylinder and is driven by the matching conditions on the edge of the topography. When the effect of β is large, the transport over the topography is enhanced as the streamlines follow lines of constant background potential vorticity. For eastward flow, the Rossby wave drag can be much larger than predicted from quasi-geostrophic theory. A two-layer model over finite topography using the quasi-geostrophic approximation is developed. The topography is a right circular cylinder which goes all of the way through the lower layer and an order Rossby number amount into the upper layer, so that the quasi-geostrophic approximation can be applied consistently. This geometry allows description of flow in which an isopycnal intersects the topography. The model is valid for a different regime than existing models of steady flow over finite topography in a continuously stratified fluid in which the bottom boundary is an isopycnal surface. The solutions contain the two components that are found in the the barotropic model of flow over finite topography. The model breaks down when the interface goes above the topography which occurs more easily when the stratification is weak. Closed streamlines occur more readily over the topography when the stratification is weak, whereas in traditional quasi-geostrophic theory they occur more readily when the stratification is strong. Near the topography, the interface is depressed to the right and raised to the left (looking downstream). A hierarchy of time-dependent models is used to examine the initial value problem of flow initiation over topography on the f-plane. A modified contour dynamics method is developed that extends the range of problems to which contour dynamics can be applied. The method allows boundary and matching conditions to be applied on a circular boundary. A one-layer quasi-geostrophic model is used to show that more fluid that originates over the topography remains there when the flow is turned on slowly than when it is turned on quickly. Flow over finite topography in a one-layer model shows a variety of different behaviors depending on the topographic height. When the topography has moderate height, two cyclonic eddies are created; when the topography fills up most of the water column, the fluid oscillates on and off the topography as it moves around the topography in a clockwise direction, and none of the fluid is shed downstream. Two quasi-geostrophic stratified models are considered, one in which the topography is small, and the other in which it is finite. In the small topography model, an eddy is shed which is cyclonic, warm-core, and bottom-trapped. In contrast, the shed eddy is cyclonic, cold-core, and surfaceintensified in the finite depth model using the geometry described above.
    Description: This study was supported by the Office of Naval Research Program N00014- 90-J-1839.
    Keywords: Waves ; Eddies
    Repository Name: Woods Hole Open Access Server
    Type: Thesis
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    Publication Date: 2022-05-26
    Description: © The Author(s), 2013. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Journal of Geophysical Research: Oceans 118 (2013): 5129–5172, doi:10.1002/jgrc.20376.
    Description: A Gulf of Mexico performance evaluation and comparison of coastal circulation and wave models was executed through harmonic analyses of tidal simulations, hindcasts of Hurricane Ike (2008) and Rita (2005), and a benchmarking study. Three unstructured coastal circulation models (ADCIRC, FVCOM, and SELFE) validated with similar skill on a new common Gulf scale mesh (ULLR) with identical frictional parameterization and forcing for the tidal validation and hurricane hindcasts. Coupled circulation and wave models, SWAN+ADCIRC and WWMII+SELFE, along with FVCOM loosely coupled with SWAN, also validated with similar skill. NOAA's official operational forecast storm surge model (SLOSH) was implemented on local and Gulf scale meshes with the same wind stress and pressure forcing used by the unstructured models for hindcasts of Ike and Rita. SLOSH's local meshes failed to capture regional processes such as Ike's forerunner and the results from the Gulf scale mesh further suggest shortcomings may be due to a combination of poor mesh resolution, missing internal physics such as tides and nonlinear advection, and SLOSH's internal frictional parameterization. In addition, these models were benchmarked to assess and compare execution speed and scalability for a prototypical operational simulation. It was apparent that a higher number of computational cores are needed for the unstructured models to meet similar operational implementation requirements to SLOSH, and that some of them could benefit from improved parallelization and faster execution speed.
    Description: This project was supported by NOAA via the U.S. IOOS Office (award: NA10NOS0120063 and NA11NOS0120141)
    Keywords: Storm surge ; Tides ; Waves ; Testbed ; Hurricane ; Inundation
    Repository Name: Woods Hole Open Access Server
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  • 19
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    Publication Date: 2022-05-26
    Description: Originally issued as Reference No. 60-20, series later renamed WHOI-.
    Description: Six years of field data plus the conclusions of eight published papers, plus two papers 11 in press", are included in this final report. Wherever possible the writer has attempted to sum up significant unpublished data by the use of illustrations, for example (Plates I through XII and Plates XIII to XVI). All other research, whether fruitful or not is summed up as concisely as possible. The format is outlined in the Contents. It may best be considered in three parts, an Introduction, description of the area and a discussion of technique, for one part. A second part wherein Beach and Coastal Regimen is the topic, this includes profile studies, aerial photography and coastal erosion studies; sediment distribution and wave dynamics is part 3. The studies have led to problems which are unsolved and in a sense the data bearing on these problems is more or less "hanging in air". For example, the most interesting conclusion we derived from the sediment sampling along offshore profiles was that deposition of sediment is confined to a thin strip of sand next to the coast and a mud zone far offshore. These sites of deposition are separated by a zone of erosion or non-deposition. We have carried these ideas rather far and have published a model to explain the mechanics of transport (Miller and Zeigler, in press). Yet, the field sampling is inadequate in spite of supplementary efforts made on two cruises, not a part of this contract, to get enough field data. Consequently, a formal discussion of this problem is in the future and surely that discussion will draw heavily on data which is now inadequate. A second example of a problem in progress, but unsolved concerns inlets. The data is included in this report, but it leads to no conclusions. In keeping with instructions for report requirements for Geography Branch contracts, conclusions of published reports are listed, details are not reported.
    Description: Geography Branch, Office of Naval Research Under Contract Nonr-1254 {00) (NR-388-018)
    Keywords: Sediment transport ; Waves ; Beaches
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    Helvetica Chimica Acta 19 (1936), S. 842-849 
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    Helvetica Chimica Acta 19 (1936), S. 858-879 
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    Notes: 1. Bei der Dehydrierung der Sesquiterpen-Fraktionen von 6 verschiedenen Ölen wurde Guajazulen erhalten; „Eucazulen“ aus Eucalyptusöl und „Gurjunazulen“ aus Gurjunbalsamöl sind gleichfalls mit Guajazulen identisch. Anscheinend gehören die meisten Sesquiterpen-Verbindungen, aus denen durch Dehydrierung ein Azulen erhalten worden ist, dem Guajazulen-Typus an.
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    Notes: Die Methode der Brechungsindex-Messung mit Licht von veränderlicher Wellenlänge wird zur Untersuchung der Lichtbrechung und der Dispersion von Fasern herangezogen. Es zeigt sich, dass der Faser kein genau definiertes Brechungsvermögen zukommt, sondern dass dieses von den verwendeten Messflüssigkeiten abhängig ist. Bei Imbibitionsversuchen mit Gemischen von Glycerin oder Benzylalkohol mit anderen Flüssigkeiten scheinen diese Alkohole, wie aus der Veränderung der Lichtbrechung geschlossen wird, im Laufe der Zeit in der Faser angereichert zu werden. Das Verfahren kann daher zur optischen Verfolgung von Adsorptionsvorgängen Dienste leisten.
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    Notes: Le système aldéhyde benzoïque-acide perbenzoïque (préparé à, partir du peroxyde de benzoyle) se transforme, dans Ies divers dissolvants, avec la même vitesse que le système obtenu par ozonation de l'aldéhyde benzoïque. On en conclut que le corps peroxydique, formé par action de l'oxygène sur l'aldéhyde et qui réagit ensuite sur cet aldéhyde, est le peracide.
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    Notes: 1. Die Bildungsenergie des Magnesiumoxyds wurde neu berechnet, wobei die mittlere spez. Wärme des flüssigen Metalls aus der Dampfdruck-Kurve berechnet wurde.
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    Notes: Nous avons déterminé les constantes diélectriques du maléate d'éthyle, du fumarate diéthyle et du méthyl-iso-eugénol et des ozonides de ces corps.
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    Notes: 1. Fructose wird durch die Hg-Liniengruppe bei 366 mμ des langwelligen Ultravioletts (Quarzlicht durch Glas) unter Kohlenmonoxyd-Bildung zersetzt.
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    Notes: Es wird gezeigt, dass die enzymatische Histamin-Spaltung ein oxydativer Vorgang ist, bei dem ein Äquivalent Stickstoff in Form von Ammoniak in Freiheit gesetzt wird. Die Frage, ob dieses Stickstoff-Atom aus dem Kern stammt, ist auf Grund der analogen Modellversuche mit Ascorbinsäure und Eisenkatalyse wahrscheinlich im positiven Sinn zu beantworten, muss aber erst endgültig bewiesen werden. Auf Grund dieses Verhaltens muss das Enzym höchstwahrscheinlich als ein sogenanntes Häminferment angesehen werden. Bei der Histaminspaltung bildet sich ein Pigment. Ausserdem ist es gelungen, ein Keton in Form eines wohlcharakterisierten Dinitro-phenylhydrazons zu isolieren, dessen Konstitutionsermittlung im Gange ist.
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    Notes: Pour les constantes diélectriques et les moments dipolaires des maléate et fumarate l'éthyle et des ozonides de ces deux corps, les valeurs trouvées sont: .
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    Notes: 1° Nous avons mesuré, par la méthode calorimétrique, les chaleurs de formation des mélanges binaires: .
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    Helvetica Chimica Acta 20 (1937), S. 779-782 
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    Notes: Description d'un appareillage pour la mesure précise et rapide de la pression de vapeur en équilibre avec une solution liquide on sous forme de gel. Cet appareil peut être utilisé avec des quantités de substances inférieures à 0,1 gr.
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    Helvetica Chimica Acta 20 (1937), S. 791-804 
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    Helvetica Chimica Acta 20 (1937), S. 817-827 
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    Helvetica Chimica Acta 20 (1937), S. 846-851 
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    Helvetica Chimica Acta 20 (1937), S. 852-852 
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    Helvetica Chimica Acta 20 (1937), S. 853-877 
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    Notes: 1. Es wird festgestellt, dass Farbstoffe vom Typus des Methylenblaus schwärzungsfähiges Zinksulfid desensibilieren.
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    Helvetica Chimica Acta 20 (1937), S. 892-894 
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    Helvetica Chimica Acta 20 (1937), S. 905-913 
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    Helvetica Chimica Acta 20 (1937), S. 913-918 
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    Helvetica Chimica Acta 20 (1937), S. 927-931 
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    Helvetica Chimica Acta 20 (1937), S. 936-949 
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    Notes: 1. Es wurde die Dampfdruckkurve von Vinylbromid in dem Temperaturbereich von - 80° bis + 50° bestimmt.
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    Helvetica Chimica Acta 18 (1935), S. 1030-1052 
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    Topics: Chemistry and Pharmacology
    Notes: Für den elektroskopischen Nachweis des gelben Phosphors wurde eine Versuchsanordnung beschrieben, wobei der Phosphor zunächst in einem Strom von reinem Stickstoff verdampft und dann erst im Ionisationsgefäss mit Luft verbrannt wird. Durch Verwendung eines Glasdochtes als Substanzträger und Verdampfung des Phosphors bis zu seiner Erschöpfung gelingt es, Phosphormengen bis zu ca. 1 mg quantitative zu bestimmen.
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    Notes: 1. Die Nitrierung des 2-Methyl-naphtalins wurde nach verschiedenen Methoden durchgeführt. Man erhält zur Hauptsache 1-Nitro-2-methyl-naphtalin.
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    Helvetica Chimica Acta 18 (1935), S. 1140-1143 
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    Helvetica Chimica Acta 18 (1935), S. 1147-1149 
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    Topics: Chemistry and Pharmacology
    Notes: 1. Jodostarin in Chloroform-Lösung erfährt bei Belichtung eine Zerlegung in Taririnsäure und Jod. Die Reaktion ist umkehrbar und folgt bei Raumtemperatur dem Massenwirkungsgesetz. Bei erhöhter Temperatur stellen sich gewisse Abweichungen von diesem Verhalten ein.
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    Helvetica Chimica Acta 18 (1935), S. 1157-1160 
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    Helvetica Chimica Acta 18 (1935), S. 1161-1171 
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    Notes: 1. Die Darstellung von P4S5 nach Boulouch (durch Belichten einer Lösung von P4S3 + S + Spur J2 in CS2) wurde nachgeprüft und bestätigt.
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    Helvetica Chimica Acta 18 (1935), S. 1190-1203 
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    Helvetica Chimica Acta 18 (1935), S. 1181-1189 
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    Topics: Chemistry and Pharmacology
    Notes: 1. Es wird gezeigt, dass die Kohleelektroden für die Spektral-analyse sehr wirksam gereinigt werden können, dadurch, dass man einen Flammbogen von ca. 12 Amp. während 2--3 Minuten zwischen denselben brennen lässt in einer Atmosphäre von Argon oder Stickstoff.
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    Helvetica Chimica Acta 18 (1935), S. 1204-1206 
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    Helvetica Chimica Acta 20 (1937), S. 1458-1461 
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    Notes: Bei der Chlorierung von trockenem Nitrobenzol mit trockenem Chlor in Gegenwart von wasserfreiem Eisen(III)chlorid bilden sich bei 40° m-Nitrochlorbenzol, 1,2-Nitrochlorbenzol, 1,4-Nitrochlorbenzol und 2,5-Dichlor-nitrobenzol. Geht man bei der Chlorierung auf höhere Temperaturen, so bilden sich beträchtliche Mengen an Hexachlorbenzol, welches aus dem Nitrobenzol entsteht und nicht aus Benzol.
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    Helvetica Chimica Acta 20 (1937), S. 1510-1523 
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    Topics: Chemistry and Pharmacology
    Notes: En vue d'augmenter le rendement de production de l'ozone par électrolyse, celle-ci a été opérée en réfrigérant énergiquement l'anolyte.
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    Helvetica Chimica Acta 20 (1937), S. 1537-1541 
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    Helvetica Chimica Acta 20 (1937), S. 224-232 
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    Topics: Chemistry and Pharmacology
    Notes: 1. Darstellung und Eigenschaften des Azulens, Bicyclo-[0,3,5]-decapentaen-(1,3,5,7,9), wurden beschrieben.
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