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  • Analytical Chemistry and Spectroscopy  (5.640)
  • 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics
  • Carbon cycle
  • Numerical modeling
  • Wiley-Blackwell  (5.648)
  • American Geophysical Union  (35)
  • Birkhauser  (1)
  • American Institute of Physics (AIP)
  • 2010-2014  (44)
  • 1985-1989  (5.640)
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  • 1
    Publikationsdatum: 2017-04-04
    Beschreibung: From December 2005 to January 2006, an anomalous degassing episode was observed at Mount Etna, well-correlated with an increase in volcanic tremor, and in the almost complete absence of eruptive activity. In the same period, more than 10,000 very long period (VLP) events were detected. Through moment tensor inversion analyses of the VLP pulses, we obtained quantitative estimates of the volumetric variations associated with these events. This allowed a quantitative investigation of the relationship between VLP seismic activity, volcanic tremor, and gas emission rate at Mount Etna. We found a statistically significant positive correlation between SO2 gas flux and volcanic tremor, suggesting that tremor amplitude can be used as a first-order proxy for the background degassing activity of the volcano. VLP volumetric changes and SO2 gas flux are correlated only for the last part of our observations, following a slight change in the VLP source depth. We calculate that the gas associated with VLP signal genesis contributed less than 5% of the total gas emission. The existence of a linear correlation between VLP and degassing activities indicates a general relationship between these two processes. The effectiveness of such coupling appears to depend upon the particular location of the VLP source, suggesting that conduit geometry might play a significant role in the VLP-generating process. These results are the first report on Mount Etna of a quantitative relationship between the amounts of gas emissions directly estimated through instrumental flux measurements and the quantities of gas mass inferred in the VLP source inversion.
    Beschreibung: Published
    Beschreibung: 4910-4921
    Beschreibung: 2V. Dinamiche di unrest e scenari pre-eruttivi
    Beschreibung: JCR Journal
    Beschreibung: restricted
    Schlagwort(e): Very Long Period seismicity ; UV scanners network ; Etna Volcano ; volcano monitoring ; 04. Solid Earth::04.02. Exploration geophysics::04.02.06. Seismic methods ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
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  • 2
    Publikationsdatum: 2021-11-25
    Beschreibung: Here we inverted the GPS data to infer the coseismic slip of the Tohoku-Oki earthquake and the time-dependent afterslip distribution in the 4 months following the main shock. The Tohoku-Oki earthquake showed an unexpected magnitude and a characteristic depth-dependent differentiation of seismic energy radiation. In this context the estimation and comparison of the distribution of the fault portions that slip coseismically and post-seismically contribute to a better understanding of the variation of frictional characteristics of the plate interface. The inferred coseismic slip extends in a relatively compact region located updip from the hypocentre and reaches its highest value (about 60 m) near the trench. Afterslip occurs mostly outside the coseismic rupture and is distributed in two main modal centres. It reaches its largest values in an area located downdip of the coseismic slip and extends to a depth of 80 km. In the depth range between 30 and 50 km afterslip overlaps the portion of the fault that experienced historical moderate earthquakes, high-frequency seismic radiation and thrust-type aftershocks. The behaviour of this area can be explained by a rheologically heterogeneous region made of a ductile fault matrix interspersed with compact brittle asperities. On the contrary, the region beneath 50–60 km depth is probably characterized by a fully velocity strengthening behaviour. Southern afterslip, located off-Chiba Prefecture, is probably related to the Mw 7.9 Ibaraki-Oki aftershock. The northward extension of the afterslip stops at a latitude of about 40◦ N, just south of the off-Aomori region. This may be related to three large events occurred in this area during the last century and the consequent strong coupling or complete depletion of the accumulated strain that characterize this region.
    Beschreibung: Published
    Beschreibung: 580-596
    Beschreibung: 2T. Tettonica attiva
    Beschreibung: JCR Journal
    Beschreibung: restricted
    Schlagwort(e): Satellite geodesy; Seismic cycle; Earthquake source observations; Subduction zone processes ; 04. Solid Earth::04.06. Seismology::04.06.01. Earthquake faults: properties and evolution ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.04. Plate boundaries, motion, and tectonics ; 04. Solid Earth::04.07. Tectonophysics::04.07.06. Subduction related processes
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
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  • 3
    Publikationsdatum: 2017-04-04
    Beschreibung: We used the SBAS DInSAR analysis technique to estimate the interseismic deformation along the western part of the Doruneh fault system (DFS), northeastern Iran. We processed 90 ENVISAT images from four different frames from ascending and descending orbits. Three of the ground velocity maps show a significant interseismic signal. Using a simple dislocation approach we model 2-D velocity profiles concerning three InSAR data set relative to the western part of the DFS, obtaining a good fit to the observations. The resulting model indicates that a slip rate of ∼5mmyr−1 accumulates on the fault below 10 km depth, and that in its western sector the Doruneh fault is not purely strike-slip (left-lateral) as in its central part, but shows a significant thrust component. Based on published geological observations, and assuming that all interseismic deformation is recovered with a single event, we can estimate a characteristic recurrence interval between 630 and 1400 yr.
    Beschreibung: Published
    Beschreibung: 622-628
    Beschreibung: 1.10. TTC - Telerilevamento
    Beschreibung: 3.2. Tettonica attiva
    Beschreibung: JCR Journal
    Beschreibung: restricted
    Schlagwort(e): Image processing; Satellite geodesy; Seismic cycle; Radar interferometry; Seismicity and tectonics; Continental tectonics: strike-slip and transform. ; 04. Solid Earth::04.03. Geodesy::04.03.01. Crustal deformations ; 04. Solid Earth::04.03. Geodesy::04.03.06. Measurements and monitoring ; 04. Solid Earth::04.03. Geodesy::04.03.07. Satellite geodesy ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
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  • 4
    Publikationsdatum: 2017-04-04
    Beschreibung: The peculiar source characteristics of long-period seismic events (time persistency of the source, low-frequency peaks in the source spectrum, absence of high-frequency radiation) prevent the formation of a definite high-frequency coda in the seismograms. In contrast, this is well formed in volcano–tectonic quakes. For this reason, the widely used duration magnitude scale that is based on the proportionality between the energy and the coda duration cannot be used for long-period estimation. In observatory practice, the long-period magnitude is sometimes estimated using the same duration magnitude scale, leading to confusing results. In this report, we show a new method to estimate the magnitude of long-period events that generally occur for volcanoes, with some application examples from data for Mt Etna (Italy), Colima Volcano (Mexico) and Campi Flegrei (Italy).
    Beschreibung: Published
    Beschreibung: 911-919
    Beschreibung: 3.1. Fisica dei terremoti
    Beschreibung: JCR Journal
    Beschreibung: restricted
    Schlagwort(e): Earthquake source observations; ; Volcano monitoring ; Volcano seismology ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 04. Solid Earth::04.06. Seismology::04.06.09. Waves and wave analysis
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
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  • 5
    Publikationsdatum: 2017-04-04
    Beschreibung: For decades, many authors have attempted to define the location, geometry and kinematics of the causative fault for the 1908 December 28, M 7.1 earthquake that struck the Messina Straits between Sicily and Calabria (southern Italy). The coseismic displacement caused a predominant downwarping of the Straits and small land uplift away from it, which were documented by levelling surveys performed 1 yr before and immediately after the earthquake. Most of the source models based on inversion of levelling data suggested that the earthquake was caused by a low angle, east-dipping blind normal fault, whose upper projection intersects the Earth surface on the Sicilian (west) side of the Messina Straits.An alternative interpretation holds that the causative fault is one of the high-angle, west-dipping faults located in southern Calabria, on the eastern side of the Straits, and may in large part coincide with the mapped Armo Fault. Here, we critically review the levelling data with the aim of defining both their usefulness and limits in modelling the seismogenic fault. We demonstrate that the levelling data alone are not capable of discriminating between the two oppositely dipping fault models, and thus their role as a keystone for modellers is untenable. However, new morphotectonic and geodetic data indicate that the Armo Fault has very recent activity and is accumulating strain. The surface observations, together with appraisal ofmacroseismic intensity distribution, available seismic tomography and marine geophysical evidence, lends credit to the hypothesis that the Armo and possibly the S. Eufemia faults are part of a major crustal structure that slipped during the 1908 earthquake.
    Beschreibung: Published
    Beschreibung: 1025-1041
    Beschreibung: JCR Journal
    Beschreibung: restricted
    Schlagwort(e): Earthquake source ; Messina Straits ; 04. Solid Earth::04.03. Geodesy::04.03.01. Crustal deformations ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 05. General::05.01. Computational geophysics::05.01.03. Inverse methods ; 05. General::05.01. Computational geophysics::05.01.04. Statistical analysis
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
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  • 6
    Publikationsdatum: 2022-05-24
    Beschreibung: The broad availability of geodetic measurements for the Mw 6.3 April 6th 2009 L’Aquila earthquake allowed an unprecedented description of the co- and post-seismic ground deformations, leading to the definition of the Paganica fault geometry and kinematics. Through DInSAR, we found, in a wide area of 20 kilometres on the Paganica hangingwall, a further displacement up to 7 cm, which might have occurred in the earthquake proximity. In this study, we explore the possibility of the co-, post- and pre-seismic alternative scenarios. Although our data are not sufficient to undoubtedly prove that this signal occurred before the main event, this seems to be the most likely hypothesis based on tectonics constraints and image acquisition times. The nature of this deformation remains unclear, but we speculate that deep fluids played a role. These results can drive ad hoc requirements for future space-based missions and design of the GPS network.
    Beschreibung: Published
    Beschreibung: 343–351
    Beschreibung: 1.10. TTC - Telerilevamento
    Beschreibung: JCR Journal
    Beschreibung: restricted
    Schlagwort(e): InSAR ; L'Aquila earthquake ; GPS ; Anomalous signature ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
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  • 7
    facet.materialart.
    Unbekannt
    American Geophysical Union
    Publikationsdatum: 2017-04-03
    Beschreibung: The weakening mechanisms occurring during an earthquake failure are of prominent importance in determining the resulting energy release and the seismic waves excitation. In this paper we consider the fully dynamic response of a seismogenic structure where lubrication processes take place. In particular, we numerically model the spontaneous propagation of a 3-D rupture in a fault zone where the frictional resistance is controlled by the properties of a low viscosity slurry, formed by gouge particles and fluids. This model allows for the description of the fault motion in the extreme case of vanishing effective normal stress, by considering a viscous fault response and therefore without the need to invoke, in the framework of Coulomb friction, the generation of the tensile mode of fracture. We explore the effects of the parameters controlling the resulting governing law for such a lubricated fault; the viscosity of the slurry, the roughness of the fault surfaces and the thickness of the slurry film. Our results indicate that lubricated faults produce a nearly complete stress drop (i.e., a very low residual friction coefficient; mu ~ 0.01), a high fracture energy density (E_G ~ few 10s of MJ/m^2) and significant slip velocities (vpeak ~ few 10s of m/s). The resulting values of the equivalent characteristic slip-weakening distance (d_0_eq = 0.1–0.8 m, depending on the adopted parameters) are compatible with the seismological inferences. Moreover, in the framework of our model we found that supershear ruptures are highly favored. In the case of enlarging gap height we can have the healing of slip or even the inhibition of the rupture. Quantitative comparisons with different weakening mechanisms previously proposed in the literature, such as the exponential weakening and the frictional melting, are also discussed.
    Beschreibung: Published
    Beschreibung: B05304
    Beschreibung: 3.1. Fisica dei terremoti
    Beschreibung: JCR Journal
    Beschreibung: restricted
    Schlagwort(e): governing models ; theoretical seismology ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
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  • 8
    Publikationsdatum: 2020-03-16
    Beschreibung: Post-seismic relaxation is known to occur after large or moderate earthquakes, on time scales ranging from days to years or even decades. In general, long-term deformation following seismic events has been detected by means of standard geodetic measurements, although seismic instruments are only used to estimate short timescale transient processes. Albeit inertial seismic sensors are also sensitive to rotation around their sensitive axes, the recording of very slow inclination of the ground surface at their standard output channels is practically impossible, because of their design characteristics. However, modern force-balance, broad- band seismometers provide the possibility to detect and measure slow surface inclination, through the analysis of the mass position signal. This output channel represents the integral of the broad-band velocity and is generally considered only for state-of-health diagnostics. In fact, the analysis of mass position data recorded at the time of the 2009 April 6, L’Aquila (MW = 6.3) earthquake, by a closely located STS-2 seismometer, evidenced the occurrence of a very low frequency signal, starting right at the time of the seismic event. This waveform is only visible on the horizontal components and is not related to the usual drift coupled with the temperature changes. This analysis suggests that the observed signal is to be ascribed to slowly developing ground inclination at the station site, caused by post-seismic relaxation following the main shock. The observed tilt reached 1.7 × 10−5 rad in about 2 months. This estimate is in very good agreement with the geodetic observations, giving comparable tilt magnitude and direction at the same site. This study represents the first seismic analysis ever for the mass position signal, suggesting useful applications for usually neglected data.
    Beschreibung: Published
    Beschreibung: 1717-1724
    Beschreibung: 3.1. Fisica dei terremoti
    Beschreibung: JCR Journal
    Beschreibung: restricted
    Schlagwort(e): Seismic cycle ; Earthquake source observations ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
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  • 9
    Publikationsdatum: 2017-04-04
    Beschreibung: One hundred twenty-nine long-period (LP) events, divided into two families of similar events, were recorded by the 50 stations deployed on Mount Etna in the second half of June 2008. During this period lava was flowing from a lateral fracture after a summit Strombolian eruption. In order to understand the mechanisms of these events, we perform moment tensor inversions. Inversions are initially kept unconstrained to estimate the most likely mechanism. Numerical tests show that unconstrained inversion leads to reliable moment tensor solutions because of the close proximity of numerous stations to the source positions. However, single forces cannot be accurately determined as they are very sensitive to uncertainties in the velocity model. Constrained inversions for a crack, a pipe or an explosion then allow us to accurately determine the structural orientations of the source mechanisms. Both numerical tests and LP event inversions emphasise the importance of using stations located as close as possible to the source. Inversions for both families show mechanisms with a strong volumetric component. These events are most likely generated by cracks striking SW–NE for both families and dipping 70° SE (family 1) and 50° NW (family 2). For family 1 events, the crack geometry is nearly orthogonal to the dikelike structure along which events are located, while for family 2 the location gave two pipelike bodies that belong to the same plane as the crack mechanism. The orientations of the cracks are consistent with local tectonics, which shows a SW–NE weakness direction. The LP events appear to be a response to the lava fountain occurring on 10 May 2008 as opposed to the flank lava flow.
    Beschreibung: Published
    Beschreibung: B01304
    Beschreibung: 1.4. TTC - Sorveglianza sismologica delle aree vulcaniche attive
    Beschreibung: 3.1. Fisica dei terremoti
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): Etna Volcano ; long-period events ; source mechanism ; location ; plumbing systems ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
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  • 10
    Publikationsdatum: 2017-04-04
    Beschreibung: Near-fault strong-ground motions (0.1–10 Hz) recorded during the Mw 6.3 2009 L’Aquila earthquake exhibit great spatial variability. Modeling the observed seismograms allows linking distinct features of the observed wavefield to particular source and propagation effects and provides insights on strong motion complexity from this moderate magnitude event. We utilize a hybrid integral-composite approach based on a k-square kinematic rupture model, combining low-frequency coherent and high-frequency incoherent source radiation and providing omega-squared source spectral decay. Several source model features, proven to be stable by means of an uncertainty analysis in the preceding low-frequency (〈0.2 Hz) multiple finite-extent source inversion (Paper 1), were constrained. Synthetic Green’s functions are calculated in a 1D-layered crustal model including 1D soil profiles to account for site-specific response (where available). The results show that although the local site effects improve the modeling, the spatial broadband ground-motion variability is to large extent controlled by the rupture kinematics. The modeling thus confirms and further constraints the source model features, including the position and slip amount of the two main asperities, the largest asperity time delay and the rupture velocity distribution on the fault. Furthermore, we demonstrate that the crossover frequency dividing the coherent and incoherent wavefield, often considered independent on the station position, has to be variable in order to adequately reproduce both near and far station recordings. This suggests that the incoherency of the radiated wavefield is controlled by the wave-propagation phenomena and/or the initial updip rupture propagation was very smooth (coherent) up to relatively high frequencies (〉2 Hz)
    Beschreibung: Published
    Beschreibung: B0438
    Beschreibung: 4.1. Metodologie sismologiche per l'ingegneria sismica
    Beschreibung: JCR Journal
    Beschreibung: restricted
    Schlagwort(e): broad band modeling, source complexity, aquila earthquake ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
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  • 11
    Publikationsdatum: 2022-05-25
    Beschreibung: Author Posting. © American Geophysical Union, 2011. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 116 (2011): C12020, doi:10.1029/2011JC006998.
    Beschreibung: A three dimensional model of Arctic Ocean circulation and mixing, with a horizontal resolution of 18 km, is overlain by a biogeochemical model resolving the physical, chemical and biological transport and transformations of phosphorus, alkalinity, oxygen and carbon, including the air-sea exchange of dissolved gases and the riverine delivery of dissolved organic carbon. The model qualitatively captures the observed regional and seasonal trends in surface ocean PO4, dissolved inorganic carbon, total alkalinity, and pCO2. Integrated annually, over the basin, the model suggests a net annual uptake of 59 Tg C a−1, within the range of published estimates based on the extrapolation of local observations (20–199 Tg C a−1). This flux is attributable to the cooling (increasing solubility) of waters moving into the basin, mainly from the subpolar North Atlantic. The air-sea flux is regulated seasonally and regionally by sea-ice cover, which modulates both air-sea gas transfer and the photosynthetic production of organic matter, and by the delivery of riverine dissolved organic carbon (RDOC), which drive the regional contrasts in pCO2 between Eurasian and North American coastal waters. Integrated over the basin, the delivery and remineralization of RDOC reduces the net oceanic CO2 uptake by ~10%.
    Beschreibung: This study has been carried out as part of ECCO2 and SASS (Synthesis of the Arctic System Science) projects funded by NASA and NSF, respectively. MM and MJF are grateful for support from the National Science Foundation (ARC-0531119 and ARC-0806229) for financial support. MM also acknowledges NASA for providing computer time, the use of the computing facilities at NAS center and also the Scripps post-doctoral program for further financial support that helped to complete the manuscript. RMK also acknowledges NOAA for support (NA08OAR4310820 and NA08OAR4320752).
    Beschreibung: 2012-06-15
    Schlagwort(e): Air-sea gas exchange ; Biogeochemical cycles ; Land-ocean coupling ; Numerical modeling ; Ocean carbon cycle ; Polar oceans
    Repository-Name: Woods Hole Open Access Server
    Materialart: Article
    Format: application/pdf
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  • 12
    Publikationsdatum: 2022-05-25
    Beschreibung: Author Posting. © American Geophysical Union, 2012. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Paleoceanography 27 (2012): PA3225, doi:10.1029/2011PA002273.
    Beschreibung: The midpoint of the Last Termination occurred 4,000 years earlier in the deep Atlantic than the deep Pacific according to a pair of benthic foraminiferal δ18O records, seemingly implying an internal circulation shift because the lag is much longer than the deep radiocarbon age. Here a scenario where the lag is instead caused by regional surface boundary condition changes, delays due to oceanic transit timescales, and the interplay between temperature and seawater δ18O (δ18Ow) is quantified with a tracer transport model of the modern-day ocean circulation. Using an inverse method with individual Green functions for 2,806 surface sources, a time history of surface temperature and δ18Ow is reconstructed for the last 30,000 years that is consistent with the foraminiferal oxygen-isotope data, Mg/Ca-derived deep temperature, and glacial pore water records. Thus, in the case that the ocean circulation was relatively unchanged between glacial and modern times, the interbasin lag could be explained by the relatively late local glacial maximum around Antarctica where surface δ18Ow continues to rise even after the North Atlantic δ18Ow falls. The arrival of the signal of the Termination is delayed at the Pacific core site due to the destructive interference of the still-rising Antarctic signal and the falling North Atlantic signal. This scenario is only possible because the ocean is not a single conveyor belt where all waters at the Pacific core site previously passed the Atlantic core site, but instead the Pacific core site is bathed more prominently by waters with a direct Antarctic source.
    Beschreibung: G.G. is supported by NSF grant OIA-1124880 and the WHOI Arctic Research Initiative.
    Beschreibung: 2013-03-06
    Schlagwort(e): Deglaciation ; Foraminiferal data ; Inverse methods ; Numerical modeling ; Oxygen-18 ; Tracers
    Repository-Name: Woods Hole Open Access Server
    Materialart: Article
    Format: application/pdf
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  • 13
    facet.materialart.
    Unbekannt
    American Geophysical Union
    Publikationsdatum: 2022-05-25
    Beschreibung: Author Posting. © American Geophysical Union, 2012. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 39 (2012): L19703, doi:10.1029/2012GL052883.
    Beschreibung: Carbon cycling studies focusing on transport and transformation of terrigenous carbon sources toward marine sedimentary sinks necessitate separation of particulate organic carbon (OC) derived from many different sources and integrated by river systems. Much progress has been made on isolating and characterizing young biologically-formed OC that is still chemically intact, however quantification and characterization of old, refractory rock-bound OC has remained troublesome. Quantification of both endmembers of riverine OC is important to constrain exchanges linking biologic and geologic carbon cycles and regulating atmospheric CO2 and O2. Here, we constrain petrogenic OC proportions in suspended sediment from the headwaters of the Ganges River in Nepal through direct measurement using ramped pyrolysis radiocarbon analysis. The unique results apportion the biospheric and petrogenic fractions of bulk particulate OC and characterize biospheric OC residence time. Compared to the same treatment of POC from the lower Mississippi-Atchafalaya River system, contrast in age spectra of the Ganges tributary samples illustrates the difference between small mountainous river systems and large integrative ones in terms of the global carbon cycle.
    Beschreibung: This work was partially supported by U.S. National Science Foundation (NSF) Cooperative Agreement OCE-228996 to NOSAMS and NSF grants OCE-0851015 & OCE-0928582 to VG.
    Beschreibung: 2013-04-03
    Schlagwort(e): Ganges ; Himalaya ; Mississippi ; POC ; Carbon cycle ; Radiocarbon
    Repository-Name: Woods Hole Open Access Server
    Materialart: Article
    Format: application/pdf
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  • 14
    Publikationsdatum: 2024-05-09
    Beschreibung: In this paper, we propose a new model of the crustal structure and seismotectonics for central Sicily (southern Italy) through the analysis of the depth distribution and kinematics of the instrumental seismicity, occurring during the period from 1983 to 2010, and its comparison with individual geological structures that may be active in the area. The analysed data set consists of 392 earthquakes with local magnitudes ranging from 1.0 to 4.7. We defined a new, detailed 1-D velocity model to relocate the earthquakes that occurred in central Sicily, and we calculated a Moho depth of 37 km and a mean VP/VS ratio of 1.73. The relocated seismic events are clustered mainly in the area north of Caltanissetta (e.g. Mainland Sicily) and in the northeastern sector (Madonie Mountains) of the study area; only minor and greatly dispersed seismicity is located in the western sector, near Belice, and along the southern coast, between Gela and Sciacca. The relocated hypocentral distribution depicts a bimodal pattern: 50 per cent of the events occur within the upper crust at depths less than ~16 km, 40 per cent of the events occur within the middle and depth crust, at depths between 16 and 32 km, and the remaining 10 per cent occur at subcrustal depths. The energy release pattern shows a similar depth distribution. On the basis of the kinematic analysis of 38 newly computed focal plane solutions, two major geographically distinct seismotectonic domains are distinguished: the Madonie Mountain domain, with prevalent extensional and extensional-oblique kinematics associated with upper crust Late Pliocene–Quaternary faulting, and the Mainland Sicily domain, with prevalent compressional and compressional-oblique kinematics associated with thrust faulting, at mid to deep crust depth, along the north-dipping Sicilian Basal Thrust (SBT). The stress inversion of the Mainland Sicily focal solutions integrated with neighbouring mechanisms available in the literature highlights a regional homogeneous compressional tensor, with a subhorizontal NNW–SSE-striking σ1 axis. In addition, on the basis of geodetic data, the Mainland Sicily domain may be attributed to the SSE-ward thrusting of the Mainland Sicily block along the SBT plane. Seismogenic shearing along the SBT at mid-crustal depths was responsible for the unexpected Belice 1968 earthquake (Mw 6.1), with evident implications in terms of hazard assessment.
    Beschreibung: Published
    Beschreibung: 1237-2252
    Beschreibung: 1.1. TTC - Monitoraggio sismico del territorio nazionale
    Beschreibung: 3.2. Tettonica attiva
    Beschreibung: 3.3. Geodinamica e struttura dell'interno della Terra
    Beschreibung: 5.2. TTC - Banche dati di sismologia strumentale
    Beschreibung: JCR Journal
    Beschreibung: restricted
    Schlagwort(e): Seismicity and tectonics ; Continental tectonics: compressional ; Dynamics: seismotectonics ; Crustal structure ; Europe ; 04. Solid Earth::04.06. Seismology::04.06.99. General or miscellaneous ; 04. Solid Earth::04.06. Seismology::04.06.01. Earthquake faults: properties and evolution ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.99. General or miscellaneous ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.04. Plate boundaries, motion, and tectonics
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 15
    Publikationsdatum: 2017-04-04
    Beschreibung: Intermediate-focus seismicity (50〈H〈100km) related to the underplating zone of the South Shetland plate have been recorded at a small aperture seismic array set up in Deception Island, Antarctica.
    Beschreibung: Published
    Beschreibung: 531-534
    Beschreibung: 3.1. Fisica dei terremoti
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): Deep earthquakes ; Antarctica ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 16
    Publikationsdatum: 2017-04-04
    Beschreibung: The 2009 April 6, Mw= 6.3 L’Aquila earthquake occurred within a complex system of NW–SE trending normal faults in the Abruzzi Central Apennines (Italy). We analyse the coseismic deformation as measured by 〉70 global positioning system (GPS) stations, both from continuous and survey-mode networks, providing unprecedented details for a moderate normal faulting earthquake in Italy from GPS measurements. We use rectangular, uniform-slip, dislocations embedded in an elastic, homogeneous and isotropic half-space and a constrained, non-linear optimization algorithm, to solve for the best-fitting rectangular dislocation geometry and coseismic-slip distribution. We use a bootstrap approach to investigate uncertainties in the model parameters and define confidence bounds for all the inverted parameters. The rupture occurred on a N129°E striking and 50° southwestward dipping normal fault, in agreement with geological observations of surface breaks along the Paganica fault. Our distributed slip model exhibits a zone of relatively higher slip (〉60 cm) between ∼1.5 and ∼11 km depth, along a roughly downdip, NW–SE elongated patch, confined within the fault plane inverted assuming uniform-slip. The highest slip, of the order of ∼1 m, occurred on a ∼16 km2 area located at ∼5 km depth, SE of the mainshock epicentre. The analysis of model resolution suggests that slip at depth below ∼5 km can be resolved only at a spatial scale larger than 2 km, so a finer discretization of different asperities within the main patch of coseismic-slip is not allowed by GPS data. We compute the coseismic Coulomb stress changes in the crustal volume affected by the major aftershocks, and compare the results obtained from the uniform-slip and the heterogeneous-slip models. We find that most of the large aftershocks occurred in areas of Coulomb stress increase of 0.2–13 bar and that a deepening of the slip distribution down to a depth greater than 6 km in the SE part of the fault plane, in agreement with the inverted slip model, can explain the deepest, April 7, Mw 5.3 aftershock.
    Beschreibung: Published
    Beschreibung: 473-489
    Beschreibung: 1.9. Rete GPS nazionale
    Beschreibung: 3.2. Tettonica attiva
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): Satellite geodesy ; Space geodetic surveys ; Earthquake ground motions ; Earthquake source observations ; Earthquake interaction, forecasting, and prediction ; 04. Solid Earth::04.03. Geodesy::04.03.01. Crustal deformations ; 04. Solid Earth::04.03. Geodesy::04.03.07. Satellite geodesy ; 04. Solid Earth::04.06. Seismology::04.06.01. Earthquake faults: properties and evolution ; 04. Solid Earth::04.06. Seismology::04.06.02. Earthquake interactions and probability ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics ; 04. Solid Earth::04.06. Seismology::04.06.06. Surveys, measurements, and monitoring
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 17
    Publikationsdatum: 2017-04-04
    Beschreibung: 129 Long Period (LP) events, divided in two families were recorded by 50 stations deployed on Mount Etna within an eruptive context in the second half of June 2008. In order to understand the mechanisms of these events, we perform moment tensor inversion. Numerical tests show that unconstrained inversion leads to reliable moment tensor solutions because of the close proximity of numerous stations to the source positions. However, single forces cannot be accurately determined as they are very sensitive to uncertainities in the velocity model. These tests emphasize the importance of using stations located as close as possible to the source in the inversion of LP events. Inversion of LP signals is initially unconstrained, in order to estimate the most likely mechanism. Constrained inversions then allow us to accurately determine the structural orientations of the mechanisms. Inversions for both families show mechanisms with strong volumetric components. These events are generated by cracks striking SW-NE for both families and dipping 70± SE (fam. 1) and 50± NW (fam. 2). The geometries of the cracks are different from the structures obtained by the location of these events. The orientation of the cracks is consistent with the local tectonic context on Mount Etna. The LP events seem to be a response to the lava fountain occuring on the 10th of May, 2008.
    Beschreibung: In press
    Beschreibung: (38)
    Beschreibung: 1.4. TTC - Sorveglianza sismologica delle aree vulcaniche attive
    Beschreibung: 3.1. Fisica dei terremoti
    Beschreibung: JCR Journal
    Beschreibung: open
    Schlagwort(e): Long-Period events ; earthquake source mechanism ; Etna Volcano ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
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  • 18
    Publikationsdatum: 2017-04-04
    Beschreibung: We (re)analyzed the source of the 26 December 2004 Sumatra-Andaman earthquake and tsunami through a nonlinear joint inversion of an inhomogeneous data set made up of tide gauges, satellite altimetry, and far-field GPS recordings. The purpose is twofold: (1) the retrieval of the main kinematics rupture parameters (slip, rake, and rupture velocity) and (2) the inference of the rigidity of the source zone. We independently estimate the slip from tsunami data and the seismic moment from geodetic data to derive the rigidity. Our results confirm that the source of the 2004 Sumatra-Andaman earthquake has a complex geometry, constituted by three main slip patches, with slip peaking at ~30 m in the southern part of the source. The rake direction rotates counterclockwise at the northern part of the source, according to the direction of convergence along the trench. The rupture velocity is higher in the deeper than in the shallower part of the source, consistent with the expected increase of rigidity with depth. It is also lower in the northern part, consistent with known variations of the incoming plate properties and shear velocity. Our model features a rigidity (20–30 GPa) that is lower than the preliminary reference Earth model (PREM) average for the seismogenic volume. The source rigidity is one of the factors controlling the tsunami genesis: for a given seismic moment, the lower the rigidity, the higher the induced seafloor displacement. The general consistence between our source model and previous studies supports the effectiveness of our approach to the joint inversion of geodetic and tsunami data for the rigidity estimation.
    Beschreibung: Published
    Beschreibung: B02304
    Beschreibung: 3.1. Fisica dei terremoti
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): Source process ; Sumatra ; Tsunami ; Joint Inversion ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 19
    Publikationsdatum: 2022-05-25
    Beschreibung: Author Posting. © American Geophysical Union, 2011. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 38 (2011): L09804, doi:10.1029/2011GL047238.
    Beschreibung: Atmospheric mixing ratios of CO2 are strongly seasonal in the Arctic due to mid-latitude transport. Here we analyze the seasonal influence of moist synoptic storms by diagnosing CO2 transport from a global model on moist isentropes (to represent parcel trajectories through stormtracks) and parsing transport into eddy and mean components. During winter when northern plants respire, warm moist air, high in CO2, is swept poleward into the polar vortex, while cold dry air, low in CO2, that had been transported into the polar vortex earlier in the year is swept equatorward. Eddies reduce seasonality in mid-latitudes by ∼50% of NEE (∼100% of fossil fuel) while amplifying seasonality at high latitudes. Transport along stormtracks is correlated with rising, moist, cloudy air, which systematically hides this CO2 transport from satellites. We recommend that (1) regional inversions carefully account for meridional transport and (2) inversion models represent moist and frontal processes with high fidelity.
    Beschreibung: This research is supported by the National Aeronautics and Space Administration contracts NNX08AT77G, NNX06AC75G, and NNX08AM56G.
    Schlagwort(e): Atmospheric transport ; Carbon cycle ; Inversion ; Isentropic coordinates ; Synoptic weather ; Tracer modeling
    Repository-Name: Woods Hole Open Access Server
    Materialart: Article
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  • 20
    Publikationsdatum: 2022-05-25
    Beschreibung: Author Posting. © American Geophysical Union, 2011. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Global Biogeochemical Cycles 25 (2011): GB3018, doi:10.1029/2010GB003813.
    Beschreibung: Studies indicate that, historically, terrestrial ecosystems of the northern high-latitude region may have been responsible for up to 60% of the global net land-based sink for atmospheric CO2. However, these regions have recently experienced remarkable modification of the major driving forces of the carbon cycle, including surface air temperature warming that is significantly greater than the global average and associated increases in the frequency and severity of disturbances. Whether Arctic tundra and boreal forest ecosystems will continue to sequester atmospheric CO2 in the face of these dramatic changes is unknown. Here we show the results of model simulations that estimate a 41 Tg C yr−1 sink in the boreal land regions from 1997 to 2006, which represents a 73% reduction in the strength of the sink estimated for previous decades in the late 20th century. Our results suggest that CO2 uptake by the region in previous decades may not be as strong as previously estimated. The recent decline in sink strength is the combined result of (1) weakening sinks due to warming-induced increases in soil organic matter decomposition and (2) strengthening sources from pyrogenic CO2 emissions as a result of the substantial area of boreal forest burned in wildfires across the region in recent years. Such changes create positive feedbacks to the climate system that accelerate global warming, putting further pressure on emission reductions to achieve atmospheric stabilization targets.
    Beschreibung: This study was supported through grants provided as part of the Arctic System Science Program (NSF OPP‐ 0531047), the North American Carbon Program (NASA NNG05GD25G), and the Bonanza Creek Long‐Term Ecological Program (funded jointly by NSF grant DEB‐0423442 and USDA Forest Service, Pacific Northwest Research Station grant PNW01‐JV11261952‐231).
    Schlagwort(e): Carbon cycle ; High-latitude ecosystems ; Modeling
    Repository-Name: Woods Hole Open Access Server
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  • 21
    Publikationsdatum: 2022-05-25
    Beschreibung: Author Posting. © American Geophysical Union, 2011. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Global Biogeochemical Cycles 25 (2011): GB3022, doi:10.1029/2010GB003892.
    Beschreibung: The North Atlantic Ocean accounts for about 25% of the global oceanic anthropogenic carbon sink. This basin experiences significant interannual variability primarily driven by the North Atlantic Oscillation (NAO). A suite of biogeochemical model simulations is used to analyze the impact of interannual variability on the uptake and storage of contemporary and anthropogenic carbon (Canthro) in the North Atlantic Ocean. Greater winter mixing during positive NAO years results in increased mode water formation and subsequent increases in subtropical and subpolar Canthro inventories. Our analysis suggests that changes in mode water Canthro inventories are primarily due to changes in water mass volumes driven by variations in water mass transformation rates rather than local air-sea CO2 exchange. This suggests that a significant portion of anthropogenic carbon found in the ocean interior may be derived from surface waters advected into water formation regions rather than from local gas exchange. Therefore, changes in climate modes, such as the NAO, may alter the residence time of anthropogenic carbon in the ocean by altering the rate of water mass transformation. In addition, interannual variability in Canthro storage increases the difficulty of Canthro detection and attribution through hydrographic observations, which are limited by sparse sampling of subsurface waters in time and space.
    Beschreibung: We would like to acknowledge funding from the NOAA Climate Program under the Office of Climate Observations and Global Carbon Cycle Program (NOAA‐NA07OAR4310098), NSF (OCE‐0623034), NCAR, the WHOI Ocean Climate Institute, a National Defense Science and Engineering Graduate Fellowship and an Environmental Protection Agency STAR graduate fellowship. NCAR is sponsored by the National Science Foundation.
    Schlagwort(e): North Atlantic Oscillation ; Anthropogenic carbon ; Carbon cycle ; Climate change ; Global climate model ; Mode waters
    Repository-Name: Woods Hole Open Access Server
    Materialart: Article
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  • 22
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    American Geophysical Union
    Publikationsdatum: 2022-05-25
    Beschreibung: Author Posting. © American Geophysical Union, 2011. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 38 (2011): L13405, doi:10.1029/2011GL047630.
    Beschreibung: Wave-influenced deltas, with large-scale arcuate shapes and demarcated beach ridge complexes, often display an asymmetrical form about their river channel. Here, we use a numerical model to demonstrate that the angles from which waves approach a delta can have a first-order influence upon its plan-view morphologic evolution and sedimentary architecture. The directional spread of incoming waves plays a dominant role over fluvial sediment discharge in controlling the width of an active delta lobe, which in turn affects the characteristic rates of delta progradation. Oblique wave approach (and a consequent net alongshore sediment transport) can lead to the development of morphologic asymmetry about the river in a delta's plan-view form. This plan-form asymmetry can include the development of discrete breaks in shoreline orientation and the appearance of self-organized features arising from shoreline instability along the downdrift delta flank, such as spits and migrating shoreline sand waves—features observed on natural deltas. Somewhat surprisingly, waves approaching preferentially from one direction tend to increase sediment deposition updrift of the river. This ‘morphodynamic groin effect’ occurs when the delta's plan-form aspect ratio is sufficiently large such that the orientation of the shoreline on the downdrift flank is rotated past the angle of maximum alongshore sediment transport, resulting in preferential redirection of fluvial sediment updrift of the river mouth.
    Beschreibung: This research was supported by NSF grants EAR‐0952146 and OCE‐0623766, the Exxon‐Mobil Upstream Research Company, and the WHOI‐USGS postdoctoral fellowship.
    Schlagwort(e): Depositional asymmetry ; Large-scale coastal evolution ; Numerical modeling ; Plan-view delta evolution
    Repository-Name: Woods Hole Open Access Server
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  • 23
    Publikationsdatum: 2022-05-25
    Beschreibung: Author Posting. © American Geophysical Union, 2011. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 116 (2011): C11019, doi:10.1029/2010JC006509.
    Beschreibung: The advance and retreat of sea ice produces seasonal convection and stratification, dampens surface waves and creates a separation between the ocean and atmosphere. These are all phenomena that can affect the air-sea gas transfer velocity (k660), and therefore it is not straightforward to determine how sea ice cover modulates air-sea flux. In this study we use field estimates k660 to examine how sea ice affects the net gas flux between the ocean and atmosphere. An inventory of salinity, 3He, and CFC-11 in the mixed layer is used to infer k660 during the drift of Ice Station Weddell in 1992. The average of k660 is 0.11 m d−1 across nearly 100% ice cover. In comparison, the only prior field estimates of k660 are disproportionately larger, with average values of 2.4 m d−1 across 90% sea ice cover, and 3.2 m d−1 across approximately 70% sea ice cover. We use these values to formulate two scenarios for the modulation of k660 by the fraction of sea ice cover in a 1-D transport model for the Southern Ocean seasonal ice zone. Results show the net CO2 flux through sea ice cover represents 14–46% of the net annual air-sea flux, depending on the relationship between sea ice cover and k660. The model also indicates that as much as 68% of net annual CO2 flux in the sea ice zone occurs in the springtime marginal ice zone, which demonstrates the need for accurate parameterizations of gas flux and primary productivity under partially ice-covered conditions.
    Beschreibung: Support for this work was provided by the Climate Center at the Lamont‐Doherty Earth Observatory, an NSF IGERT Fellowship and a NOAA Climate and Global Change Postdoctoral Fellowship to BL, and NSF grant OPP 01‐25523/ANT 04‐40825 (PS).
    Beschreibung: 2012-05-15
    Schlagwort(e): CO2 ; Southern Ocean ; Carbon cycle ; Gas exchange ; Sea ice
    Repository-Name: Woods Hole Open Access Server
    Materialart: Article
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  • 24
    Publikationsdatum: 2022-05-25
    Beschreibung: Author Posting. © American Geophysical Union, 2011. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 116 (2011): C10036, doi:10.1029/2011JC007035.
    Beschreibung: Inner-shelf circulation is governed by the interaction between tides, baroclinic forcing, winds, waves, and frictional losses; the mean circulation ultimately governs exchange between the coast and ocean. In some cases, oscillatory tidal currents interact with bathymetric features to generate a tidally rectified flow. Recent observational and modeling efforts in an overlapping domain centered on the Martha's Vineyard Coastal Observatory (MVCO) provided an opportunity to investigate the spatial and temporal complexity of circulation on the inner shelf. ADCP and surface radar observations revealed a mean circulation pattern that was highly variable in the alongshore and cross-shore directions. Nested modeling incrementally improved representation of the mean circulation as grid resolution increased and indicated tidal rectification as the generation mechanism of a counter-clockwise gyre near the MVCO. The loss of model skill with decreasing resolution is attributed to insufficient representation of the bathymetric gradients (Δh/h), which is important for representing nonlinear interactions between currents and bathymetry. The modeled momentum balance was characterized by large spatial variability of the pressure gradient and horizontal advection terms over short distances, suggesting that observed inner-shelf momentum balances may be confounded. Given the available observational and modeling data, this work defines the spatially variable mean circulation and its formation mechanism—tidal rectification—and illustrates the importance of model resolution for resolving circulation and constituent exchange near the coast. The results of this study have implications for future observational and modeling studies near the MVCO and other inner-shelf locations with alongshore bathymetric variability.
    Beschreibung: Funding was provided through the Office of Naval Research Ripples DRI, U.S. Geological Survey Coastal and Marine Geology Program, and National Science Foundation.
    Schlagwort(e): Coastal and nearshore circulation ; Grid resolution ; Nesting ; Numerical modeling ; Tidal rectification
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  • 25
    Publikationsdatum: 2017-04-04
    Beschreibung: We (re)analyzed the source of the 26 December 2004 Sumatra-Andaman earthquake and tsunami through a nonlinear joint inversion of an in-homogeneous dataset made up of tide-gages, satellite altimetry, and far-field GPS recordings. The purpose is two-fold: (1) the retrieval of the main kinematics rupture parameters (slip, rake, rupture velocity); (2) the inference of the rigidity of the source zone. We independently estimate the slip from tsunami data and the seismic moment from geodetic data, so to derive the rigidity. Our results confirm that the source of the 2004 Sumatra-Andaman earthquake has a complex geometry, constituted by three main slip patches, with slip peaking at ~30 meters in the Southern part of the source. The rake direction rotates counter-clockwise at North, according to the direction of convergence along the trench. The rupture velocity is higher in the deeper than in the shallower part of the source, consistently with the expected increase of rigidity with depth. It is also lower in the Northern part, consistently with known variations of the incoming plate properties and shear velocity. Our model features a rigidity (20-30 GPa), that is lower than PREM average for the seismogenic volume [Dziewonski and Anderson, 1981]. The source rigidity is one of the factors controlling the tsunamigenesis: for a given seismic moment, the lower the rigidity, the higher the induced seafloor displacement. The general consistence between our source model and previous studies supports the effectiveness of our approach to the joint inversion of geodetic and tsunami data for the rigidity estimation.
    Beschreibung: In press
    Beschreibung: 3.1. Fisica dei terremoti
    Beschreibung: JCR Journal
    Beschreibung: open
    Schlagwort(e): Source process ; Sumatra ; Tsunami ; joint inversion ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 26
    Publikationsdatum: 2017-04-04
    Beschreibung: In a recent work on the problem of sliding surfaces under the presence of frictional melt (applying in particular to earthquake fault dynamics), we derived from first principles an expression for the steady state friction compatible with experimental observations. Building on the expressions of heat and mass balance obtained in the above study for this particular case of Stefan problem (phase transition with a migrating boundary) we propose here an extension providing the full time-dependent solution (including the weakening transient after pervasive melting has started, the effect of eventual steps in velocity and the final decelerating phase). A system of coupled equations is derived and solved numerically. The resulting transient friction and wear evolution yield a satisfactory fit (1) with experiments performed under variable sliding velocities (0.9-2 m/s) and different normal stresses (0.5-20 MPa) for various rock types and (2) with estimates of slip weakening obtained from observations on ancient seismogenic faults that host pseudotachylite (solidified melt). The model allows to extrapolate the experimentally observed frictional behavior to large normal stresses representative of the seismogenic Earth crust (up to 200 MPa), high slip rates (up to 9 m/s) and cases where melt extrusion is negligible. Though weakening distance and peak stress vary widely, the net breakdown energy appears to be essentially independent of either slip velocity and normal stress. In addition, the response to earthquake-like slip can be simulated, showing a rapid friction recovery when slip rate drops. We discuss the properties of energy dissipation, transient duration, velocity weakening, restrengthening in the decelerating final slip phase and the implications for earthquake source dynamics.
    Beschreibung: S.N. and G.D.T. were supported by a European Research Council Starting Grant Project (acronym USEMS) and by a Progetti di Eccellenza Fondazione Cassa di Risparmio di Padova e Rovigo. We are grateful to Nick Beeler (and to an anonymous referee) for their constructive reviews and their help to improve the clarity of the manuscript.
    Beschreibung: Published
    Beschreibung: B10301
    Beschreibung: 3.1. Fisica dei terremoti
    Beschreibung: JCR Journal
    Beschreibung: open
    Schlagwort(e): Friction ; Melt ; Earthquake dynamics ; fault mechanics ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 27
    Publikationsdatum: 2017-04-04
    Beschreibung: The amount of energy radiated from an earthquake can be measured using recent methods based on earthquake coda signals and spectral ratios. Such methods are not altered by either site or directivity effects, with the advantage of a greatly improved accuracy. Several studies of earthquake sequences based on the above measurements showed evidence of a breakdown in self-similarity in the moment to energy relation. Radiated energy can be also used as a gauge to estimate the average dynamic stress drop on the fault. Here we compute the dynamic stress drop, infer the co-seismic friction and estimate the co-seismic heating resulting from the frictional work during events from different main shock-aftershock earthquake sequences. We relate the dynamic friction to the maximum temperature rise estimated on the faults for each earthquake. Our results are strongly indicative that a thermally triggered dynamic frictional weakening is present, responsible for the breakdown in self-similarity. These observations from seismic data are compatible with recent laboratory evidence of thermal weakening in rock friction under seismic slip-rates, associated to various physical processes such as melting, decarbonation or dehydration.
    Beschreibung: Kevin Mayeda was supported under Weston Geophysical subcontract No. GC19762NGD and AFRL contract No. FA8718-06-C-0024. Work by L. Malagnini was performed under the auspices of the Dipartimento della Protezione Civile, under contract S3 – INGV-DPC (2007-2009), project: “Valutazione rapida dei parametri e degli effetti dei forti terremoti in Italia e nel Mediterraneo”.
    Beschreibung: Published
    Beschreibung: B06319
    Beschreibung: 3.1. Fisica dei terremoti
    Beschreibung: JCR Journal
    Beschreibung: open
    Schlagwort(e): earthquake radiation ; coda ; friction ; self-similarity ; dynamic weakening ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 28
    Publikationsdatum: 2012-02-03
    Beschreibung: An edited version of this paper was published by AGU. Copyright (2010) American Geophysical Union.
    Beschreibung: An eleven‐month deployment of 25 ocean bottom seismometers provides an unprecedented opportunity to study low‐magnitude local earthquakes in the complex transpressive plate boundary setting of the Gulf of Cadiz, known for the 1755 Lisbon earthquake and tsunami. 36 relocated earthquakes (ML 2.2 to 4.8) concentrate at 40– 60 km depth, near the base of the seismogenic layer in ∼140 Ma old oceanic mantle lithosphere, and roughly align along two perpendicular, NNE‐SSW and WNWESE striking structures. First motion focal mechanisms indicate compressive stress for the cluster close to the northern Horseshoe fault termination which trends perpendicular to plate convergence. Focal mechanisms for the second cluster near the southern termination of the Horseshoe fault indicate a strike‐slip regime, providing evidence for present‐day activity of a dextral shear zone proposed to represent the Eurasia‐Africa plate contact. We hypothesize that regional tectonics is characterized by slip partitioning.
    Beschreibung: Published
    Beschreibung: L18309
    Beschreibung: 3.1. Fisica dei terremoti
    Beschreibung: 3.2. Tettonica attiva
    Beschreibung: 3.3. Geodinamica e struttura dell'interno della Terra
    Beschreibung: JCR Journal
    Beschreibung: restricted
    Schlagwort(e): oceanic lithospheric mantle ; focal mechanisms ; stress tensor inversion ; Gulf of Cadiz ; ocean bottom seismometer ; 1755 Lisbon earthquake ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics ; 04. Solid Earth::04.06. Seismology::04.06.10. Instruments and techniques ; 04. Solid Earth::04.07. Tectonophysics::04.07.04. Plate boundaries, motion, and tectonics ; 04. Solid Earth::04.07. Tectonophysics::04.07.05. Stress
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 29
    Publikationsdatum: 2017-04-04
    Beschreibung: We have simulated several scenarios of dynamic rupture propagation for the 1994 Northridge, California, earthquake, using a three-dimensional finite-difference method. The simulations use a rate- and slip-weakening friction law, starting from a range of initial conditions of stress and frictional parameters. A critical balance between initial conditions and friction parameters must be met in order to obtain a moment as well as a final slip distribution in agreement with kinematic slip inversion results. We find that the rupture process is strongly controlled by the average stress and connectivity of high-stress patches on the fault. In particular, a strong connectivity of the high-stress patches is required in order to promote the rupture propagation from the initial nucleation to the remaining part of the fault. Moreover, we find that a small amount of rate-weakening is needed in order to obtain a level of inhomogeneity in the final slip, similar to that obtained in the kinematic inversion results. However, when the amount of rate-weakening is increased, the overall moment drops dramatically unless the average prestress is raised to unrealistic levels. A velocity-weakening parameter on the order of 10 cm per second is found to be adequate for an average prestress of about a hundred bars. The presence of the free surface and of the uppermost low-impedance layers in the model are found to have negligible influence on the rupture dynamics itself, because the top of the fault is at a depth of several kilometers. The 0.1–0.5 Hz radiated waves from the dynamic simulation provides a good fit to strong motion data at sites NWH and SSA. Underprediction of the recorded peak amplitude at JFP is likely due to omission of near-surface low velocity and 3-D basin effects in the simulations.
    Beschreibung: Published
    Beschreibung: 2029-2046
    Beschreibung: 3.1. Fisica dei terremoti
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): stress drop ; slip pulses ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 30
    Publikationsdatum: 2017-04-04
    Beschreibung: An edited version of this paper was published by AGU. Copyright (2010) American Geophysical Union.
    Beschreibung: Tectonic tremor has been recorded at many subduction zones, including the Nankai, Cascadia, Mexican, and Alaskan subduction zones. This study, the first to use small aperture seismic arrays to track tremor, deployed three small aperture seismic arrays along the Cascadia subduction zone during a tremor and slow slip episode in July 2004. The tremor was active during virtually all (up to 99%) minutes of the analyzed tremor episode using 5 min sample windows. Individual wave phases were tracked across the arrays and used to derive slowness vectors. These were compared with slowness vectors computed from a standard layered Earth model to derive tremor locations. Locations were stable within a volume roughly 250 km2 in epicenter and 20 km in depth for hours to days before moving to a new volume. The migration between volumes was not smooth, and the movement of the sources within the volume followed no specific pattern. Overall migration speeds along the strike of the subduction zone were between 5 and 15 km/d; smaller scale migration speeds between volumes reached speeds up to 2 km/min. Uncertainties in the best locations were 5 km in epicenter and 10 km in depth. For this data set and processing methodology, tremor does not locate predominately on the primary subduction interface. Our favored model for the generation of tectonic tremor signals is that the tremor is triggered by stress and fluid pressure changes caused by slow slip and is composed, at least in part, of low‐frequency earthquakes broadly distributed in location
    Beschreibung: Published
    Beschreibung: B00A24
    Beschreibung: 3.2. Tettonica attiva
    Beschreibung: 3.3. Geodinamica e struttura dell'interno della Terra
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): tremor migration ; Cascadia 2004 ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics ; 04. Solid Earth::04.06. Seismology::04.06.06. Surveys, measurements, and monitoring ; 04. Solid Earth::04.06. Seismology::04.06.09. Waves and wave analysis ; 04. Solid Earth::04.07. Tectonophysics::04.07.04. Plate boundaries, motion, and tectonics
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  • 31
    Publikationsdatum: 2022-05-25
    Beschreibung: Author Posting. © American Geophysical Union, 2009. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Global Biogeochemical Cycles 23 (2009): GB4028, doi:10.1029/2009GB003519.
    Beschreibung: Nitrogen cycle dynamics have the capacity to attenuate the magnitude of global terrestrial carbon sinks and sources driven by CO2 fertilization and changes in climate. In this study, two versions of the terrestrial carbon and nitrogen cycle components of the Integrated Science Assessment Model (ISAM) are used to evaluate how variation in nitrogen availability influences terrestrial carbon sinks and sources in response to changes over the 20th century in global environmental factors including atmospheric CO2 concentration, nitrogen inputs, temperature, precipitation and land use. The two versions of ISAM vary in their treatment of nitrogen availability: ISAM-NC has a terrestrial carbon cycle model coupled to a fully dynamic nitrogen cycle while ISAM-C has an identical carbon cycle model but nitrogen availability is always in sufficient supply. Overall, the two versions of the model estimate approximately the same amount of global mean carbon uptake over the 20th century. However, comparisons of results of ISAM-NC relative to ISAM-C reveal that nitrogen dynamics: (1) reduced the 1990s carbon sink associated with increasing atmospheric CO2 by 0.53 PgC yr−1 (1 Pg = 1015g), (2) reduced the 1990s carbon source associated with changes in temperature and precipitation of 0.34 PgC yr−1 in the 1990s, (3) an enhanced sink associated with nitrogen inputs by 0.26 PgC yr−1, and (4) enhanced the 1990s carbon source associated with changes in land use by 0.08 PgC yr−1 in the 1990s. These effects of nitrogen limitation influenced the spatial distribution of the estimated exchange of CO2 with greater sink activity in high latitudes associated with climate effects and a smaller sink of CO2 in the southeastern United States caused by N limitation associated with both CO2 fertilization and forest regrowth. These results indicate that the dynamics of nitrogen availability are important to consider in assessing the spatial distribution and temporal dynamics of terrestrial carbon sources and sinks.
    Beschreibung: We also acknowledge the financial support of the National Aeronautics and Space Administration Land Cover and Land Use Change Program (NNX08AK75G).
    Schlagwort(e): Nitrogen cycle ; Carbon cycle ; ISAM
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  • 32
    Publikationsdatum: 2022-05-25
    Beschreibung: Author Posting. © American Geophysical Union, 2008. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 9 (2008): Q08O10, doi:10.1029/2008GC001965.
    Beschreibung: We use 2-D numerical models to explore the thermal and mechanical effects of magma intrusion on fault initiation and growth at slow and intermediate spreading ridges. Magma intrusion is simulated by widening a vertical column of model elements located within the lithosphere at a rate equal to a fraction, M, of the total spreading rate (i.e., M = 1 for fully magmatic spreading). Heat is added in proportion to the rate of intrusion to simulate the thermal effects of magma crystallization and the injection of hot magma into the crust. We examine a range of intrusion rates and axial thermal structures by varying M, spreading rate, and the efficiency of crustal cooling by conduction and hydrothermal circulation. Fault development proceeds in a sequential manner, with deformation focused on a single active normal fault whose location alternates between the two sides of the ridge axis. Fault spacing and heave are primarily sensitive to M and secondarily sensitive to axial lithosphere thickness and the rate that the lithosphere thickens with distance from the axis. Contrary to what is often cited in the literature, but consistent with prior results of mechanical modeling, we find that thicker axial lithosphere tends to reduce fault spacing and heave. In addition, fault spacing and heave are predicted to increase with decreasing rates of off-axis lithospheric thickening. The combination of low M, particularly when M approaches 0.5, as well as a reduced rate of off-axis lithospheric thickening produces long-lived, large-offset faults, similar to oceanic core complexes. Such long-lived faults produce a highly asymmetric axial thermal structure, with thinner lithosphere on the side with the active fault. This across-axis variation in thermal structure may tend to stabilize the active fault for longer periods of time and could concentrate hydrothermal circulation in the footwall of oceanic core complexes.
    Beschreibung: Funding for this research was provided by NSF grants OCE-0327018 (M.D.B.), OCE-0548672 (M.D.B.), OCE- 0327051 (G.I.), and OCE-03-51234 (G.I.).
    Schlagwort(e): Mid-ocean ridges ; Faulting ; Magmatism ; Numerical modeling
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  • 33
    Publikationsdatum: 2022-05-25
    Beschreibung: Author Posting. © American Geophysical Union, 2007. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Global Biogeochemical Cycles 21 (2007): GB3007, doi:10.1029/2006GB002857.
    Beschreibung: Results are presented of export production, dissolved organic matter (DOM) and dissolved oxygen simulated by 12 global ocean models participating in the second phase of the Ocean Carbon-cycle Model Intercomparison Project. A common, simple biogeochemical model is utilized in different coarse-resolution ocean circulation models. The model mean (±1σ) downward flux of organic matter across 75 m depth is 17 ± 6 Pg C yr−1. Model means of globally averaged particle export, the fraction of total export in dissolved form, surface semilabile dissolved organic carbon (DOC), and seasonal net outgassing (SNO) of oxygen are in good agreement with observation-based estimates, but particle export and surface DOC are too high in the tropics. There is a high sensitivity of the results to circulation, as evidenced by (1) the correlation of surface DOC and export with circulation metrics, including chlorofluorocarbon inventory and deep-ocean radiocarbon, (2) very large intermodel differences in Southern Ocean export, and (3) greater export production, fraction of export as DOM, and SNO in models with explicit mixed layer physics. However, deep-ocean oxygen, which varies widely among the models, is poorly correlated with other model indices. Cross-model means of several biogeochemical metrics show better agreement with observation-based estimates when restricted to those models that best simulate deep-ocean radiocarbon. Overall, the results emphasize the importance of physical processes in marine biogeochemical modeling and suggest that the development of circulation models can be accelerated by evaluating them with marine biogeochemical metrics.
    Beschreibung: R. G. N. and J. L. S. acknowledge the support of NASA grants NAG5-6451 and NAG5-6591, respectively, as part of the JGOFS Synthesis and Modeling Program. G. K. P. and F. J. acknowledge support by the Swiss National Science Foundation. European contributions were supported by the EU GOSAC Project (ENV4-CT97- 0495).
    Schlagwort(e): Export production ; Numerical modeling ; Ocean circulation
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  • 34
    Publikationsdatum: 2022-05-25
    Beschreibung: Author Posting. © American Geophysical Union, 2007. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Global Biogeochemical Cycles 21 (2007): GB2026, doi:10.1029/2006GB002900.
    Beschreibung: We investigate the interannual variability in the flux of CO2 between the atmosphere and the Southern Ocean on the basis of hindcast simulations with a coupled physical-biogeochemical-ecological model with particular emphasis on the role of the Southern Annular Mode (SAM). The simulations are run under either pre-industrial or historical CO2 concentrations, permitting us to separately investigate natural, anthropogenic, and contemporary CO2 flux variability. We find large interannual variability (±0.19 PgC yr−1) in the contemporary air-sea CO2 flux from the Southern Ocean (〈35°S). Forty-three percent of the contemporary air-sea CO2 flux variance is coherent with SAM, mostly driven by variations in the flux of natural CO2, for which SAM explains 48%. Positive phases of the SAM are associated with anomalous outgassing of natural CO2 at a rate of 0.1 PgC yr−1 per standard deviation of the SAM. In contrast, we find an anomalous uptake of anthropogenic CO2 at a rate of 0.01 PgC yr−1 during positive phases of the SAM. This uptake of anthropogenic CO2 only slightly mitigates the outgassing of natural CO2, so that a positive SAM is associated with anomalous outgassing in contemporaneous times. The primary cause of the natural CO2 outgassing is anomalously high oceanic partial pressures of CO2 caused by elevated dissolved inorganic carbon (DIC) concentrations. These anomalies in DIC are primarily a result of the circulation changes associated with the southward shift and strengthening of the zonal winds during positive phases of the SAM. The secular, positive trend in the SAM has led to a reduction in the rate of increase of the uptake of CO2 by the Southern Ocean over the past 50 years.
    Beschreibung: This work was supported by NASA headquarters under the Earth System Science Fellowship Grant NNG05GP78H to N. S. L. and grants NAG5-12528 and NNG04GH53G to N. G. Both S. C. D. and I. D. L. were supported by NSF/ONR NOPP (N000140210370) and NASA (NNG05GG30G).
    Schlagwort(e): Southern Ocean ; Carbon cycle ; Southern Annular Mode
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  • 35
    Publikationsdatum: 2022-05-25
    Beschreibung: Author Posting. © American Geophysical Union, 2007. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 112 (2007): F03016, doi:10.1029/2006JF000666.
    Beschreibung: We employ a numerical model to study the development of sorted bed forms under a variety of hydrodynamic and sedimentary conditions. Results indicate that increased variability in wave height decreases the growth rate of the features and can potentially give rise to complicated, a priori unpredictable, behavior. This happens because the system responds to a change in wave characteristics by attempting to self-organize into a patterned seabed of different geometry and spacing. The new wavelength might not have enough time to emerge before a new change in wave characteristics occurs, leading to less regular seabed configurations. The new seabed configuration is also highly dependent on the preexisting morphology, which further limits the possibility of predicting future behavior. For the same reasons, variability in the mean current magnitude and direction slows down the growth of features and causes patterns to develop that differ from classical sorted bed forms. Spatial variability in grain size distribution and different types of net sediment aggradation/degradation can also result in the development of sorted bed forms characterized by a less regular shape. Numerical simulations qualitatively agree with observed geometry (spacing and height) of sorted bed forms. Also in agreement with observations is that at shallower depths, sorted bed forms are more likely to be affected by changes in the forcing conditions, which might also explain why, in shallow waters, sorted bed forms are described as ephemeral features. Finally, simulations indicate that the different sorted bed form shapes and patterns observed in the field might not necessarily be related to diverse physical mechanisms. Instead, variations in sorted bed form characteristics may result from variations in local hydrodynamic and/or sedimentary conditions.
    Beschreibung: G.C., M.O.G., and T.M.H. acknowledge funding from the (New Zealand) Foundation for Research, Science and Technology (contract C01X0401). The National Science Foundation (OCE0452178) supported A.B.M.
    Schlagwort(e): Self-organization ; Sorted bed forms ; Numerical modeling
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  • 36
    Publikationsdatum: 2022-05-25
    Beschreibung: Author Posting. © American Geophysical Union, 2007. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 112 (2007): C04S15, doi:10.1029/2006JC003728.
    Beschreibung: The summer circulations and hydrographic fields of the Kara Sea are reconstructed for mean, positive and negative Arctic Oscillation regimes employing a variational data assimilation technique which provides the best fit of reconstructed fields to climatological data and satisfies dynamical and kinematic constraints of a quasi-stationary primitive equation ocean circulation model. The reconstructed circulations agree well with the measurements and are characterized by inflow of 0.63, 0.8, 0.51 Sv through Kara Gate and 1.18, 1.1, 1.12 Sv between Novaya Zemlya and Franz Josef Land, for mean climatologic conditions, positive and negative AO indexes, respectively. The major regions of water outflow for these regimes are the St. Anna Trough (1.17, 1.21, 1.34 Sv) and Vilkitsky/Shokalsky Straits (0.52, 0.7, 0.51 Sv). The optimized velocity pattern for the mean climatological summer reveals a strong anticyclonic circulation in the central part of the Kara Sea (Region of Fresh Water Inflow, ROFI zone) and is confirmed by ADCP surveys and laboratory modeling. This circulation is well pronounced for both high and low AO phases, but in the positive AO phase it is shifted approximately 200 km west relatively to its climatological center. During the negative AO phase the ROFI locaion is close to its climatological position. The results of the variational data assimilation approach were compared with the simulated data from the Hamburg Shelf Ocean Model (HAMSOM) and Naval Postgraduate School 18 km resolution (NPS-18) model to validate these models.
    Beschreibung: This research is supported by the Frontier Research System for Global Change, through JAMSTEC, Japan, and by the National Science Foundation Office of Polar Programs (under cooperative agreements OPP-0002239 and OPP-0327664 with the International Arctic Research Center, University of Alaska Fairbanks). The development of the data assimilation system, utilized in this study, was also supported by NSF grant OCE-0118200.
    Schlagwort(e): Kara Sea ; Variational approach ; Numerical modeling
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  • 37
    Publikationsdatum: 2022-05-25
    Beschreibung: Author Posting. © American Geophysical Union, 2010. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 115 (2010): C11015, doi:10.1029/2010JC006152.
    Beschreibung: The concentration of inert gases and their isotopes in the deep ocean are useful as tracers of air-sea gas exchange during deepwater formation. ΔKr/Ar, ΔN2/Ar, and δ40Ar were measured in deep profiles of samples collected in the northwest Pacific, subtropical North Pacific and tropical Atlantic oceans. For the ocean below 2000 m, we determined a mean ΔKr/Ar composition of −0.96% ± 0.16%, a mean ΔN2/Ar of 1.29% ± 0.21% relative to equilibrium saturation, and for δ40Ar a value of 1.188‰ ± 0.055‰ relative to air. These data are used to constrain high-latitude ventilation processes in the framework of three-box and seven-box ocean models. For the three-box model tracer data, we constrain the appropriate surface area of the high-latitude region in both models to be 3.6% (+2.5%, −1.7%) of ocean surface area and the bubble air injection rate to be 22.7 (+8.8, −7.3) mol air m−2 yr−1. Results for the seven-box model were similar, with a high-latitude area of 3.3% (+2.2%, −1.3%). Our results provide geochemical support for suggestions that the effective area of high-latitude ventilation is much smaller than the region of elevated preformed nutrients and demonstrate that noble gases strongly constrain the ocean solubility pump. Reducing high-latitude surface area weakens the CO2 solubility pump in the box models and limits communication between the atmosphere and deep ocean. These tracers should be useful constraints on high-latitude ventilation and the strength of the solubility pump in more complex ocean general circulation models.
    Beschreibung: Funding was provided by NSF‐OCE‐0647979.
    Schlagwort(e): Noble gases ; Ventilation ; Carbon cycle ; Solubility pump ; Gas exchange
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  • 38
    Publikationsdatum: 2022-05-25
    Beschreibung: Author Posting. © American Geophysical Union, 2008. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 113 (2008): F01006, doi:10.1029/2007JF000885.
    Schlagwort(e): Coastline evolution ; Morphodynamic instabilities ; Numerical modeling
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  • 39
    Publikationsdatum: 2022-05-25
    Beschreibung: Author Posting. © American Geophysical Union, 2006. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 111 (2006): F04011, doi:10.1029/2005JF000422.
    Beschreibung: Contrary to traditional findings, the deepwater angle of wave approach strongly affects plan view coastal evolution, giving rise to an antidiffusional “high wave angle” instability for sufficiently oblique deepwater waves (with angles between wave crests and the shoreline trend larger than the value that maximizes alongshore sediment transport, ∼45°). A one-contour-line numerical model shows that a predominance of high-angle waves can cause a shoreline to self-organize into regular, quasiperiodic shapes similar to those found along many natural coasts at scales ranging from kilometers to hundreds of kilometers. The numerical model has been updated from a previous version to include a formulation for the widening of an overly thin barrier by the process of barrier overwash, which is assumed to maintain a minimum barrier width. Systematic analysis shows that the wave climate determines the form of coastal response. For nearly symmetric wave climates (small net alongshore sediment transport), cuspate coasts develop that exhibit increasing relative cross-shore amplitude and pointier tips as the proportion of high-angle waves is increased. For asymmetrical wave climates, shoreline features migrate in the downdrift direction, either as subtle alongshore sand waves or as offshore-extending “flying spits,” depending on the proportion of high-angle waves. Numerical analyses further show that the rate that the alongshore scale of model features increases through merging follows a diffusional temporal scale over several orders of magnitude, a rate that is insensitive to the proportion of high-angle waves. The proportion of high-angle waves determines the offshore versus alongshore aspect ratio of self-organized shoreline undulations.
    Beschreibung: This research was funded by the Andrew W. Mellon Foundation and NSF grants DEB-05-07987 and EAR-04-44792.
    Schlagwort(e): Coastline evolution ; Morphodynamic instabilities ; Numerical modeling
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  • 40
    Publikationsdatum: 2022-05-25
    Beschreibung: Author Posting. © American Geophysical Union, 2008. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 113 (2008): C07040, doi:10.1029/2007JC004602.
    Beschreibung: A coupled physical/biological modeling system was used to hindcast a massive Alexandrium fundyense bloom that occurred in the western Gulf of Maine in 2005 and to investigate the relative importance of factors governing the bloom's initiation and development. The coupled system consists of a state-of-the-art, free-surface primitive equation Regional Ocean Modeling System (ROMS) tailored for the Gulf of Maine (GOM) using a multinested configuration, and a population dynamics model for A. fundyense. The system was forced by realistic momentum and buoyancy fluxes, tides, river runoff, observed A. fundyense benthic cyst abundance, and climatological nutrient fields. Extensive comparisons were made between simulated (both physical and biological) fields and in situ observations, revealing that the hindcast model is capable of reproducing the temporal evolution and spatial distribution of the 2005 bloom. Sensitivity experiments were then performed to distinguish the roles of three major factors hypothesized to contribute to the bloom: (1) the high abundance of cysts in western GOM sediments; (2) strong ‘northeaster' storms with prevailing downwelling-favorable winds; and (3) a large amount of fresh water input due to abundant rainfall and heavy snowmelt. Model results suggest the following. (1) The high abundance of cysts in western GOM was the primary factor of the 2005 bloom. (2) Wind-forcing was an important regulator, as episodic bursts of northeast winds caused onshore advection of offshore populations. These downwelling favorable winds accelerated the alongshore flow, resulting in transport of high cell concentrations into Massachusetts Bay. A large regional bloom would still have happened, however, even with normal or typical winds for that period. (3) Anomalously high river runoff in 2005 resulted in stronger buoyant plumes/currents, which facilitated the transport of cell population to the western GOM. While affecting nearshore cell abundance in Massachusetts Bay, the buoyant plumes were confined near to the coast, and had limited impact on the gulf-wide bloom distribution.
    Beschreibung: Research support was provided through the Woods Hole Center for Oceans and Human Health, National Science Foundation (NSF) grant OCE-0430723 and National Institute of Environmental Health Science (NIEHS) grant 1-P50-ES012742-01, ECOHAB program through NSF grant OCE-9808173 and NOAA grant NA96OP0099, and GOMTOX program through NOAA grant NA06NOS4780245.
    Schlagwort(e): Gulf of Maine ; Harmful algal bloom ; Numerical modeling
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  • 41
    Publikationsdatum: 2022-05-26
    Beschreibung: Author Posting. © American Geophysical Union, 2006. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 111 (2006): C08002, doi:10.1029/2005JC003254.
    Beschreibung: A high-resolution hybrid data assimilative (DA) modeling system is used to study barotropic tides and tidal dynamics on the southeast New England shelf. In situ observations include tidal harmonics of 5 major tidal constituents [M2, S2, N2, O1, and K1] analyzed from coastal sea level and bottom pressure gauges. The DA system consists of both forward and inverse models. The former is the three-dimensional, finite difference, nonlinear Regional Ocean Modeling System (ROMS). The latter is a three-dimensional linearized, frequency domain, finite element model TRUXTON. The DA system assimilates in situ observations via the inversion for the barotropic tidal open boundary conditions (OBCs). Model skill is evaluated by comparing the misfits between the observed and modeled tidal harmonics. The assimilation scheme is found effective and efficient in correcting the tidal OBCs, which in turn improve ROMS tidal solutions. Up to 50% decreases of model/data misfits are achieved after inverse data assimilation. Co-amplitude and co-phase maps and tidal current ellipses for each of 5 tidal constituents are generated, revealing complex tidal variability in this transition region between the tidally amplified Gulf of Maine in the northeast and the tidally much less energetic Middle Atlantic Bight in the southwest. Detailed examinations on the residual circulation, energetics, and momentum balances of the M2 tide reveal the key roles of the unique bottom bathymetry of Nantucket Shoals and the complex coastal geometry in affecting the regional tidal dynamics.
    Beschreibung: This work was supported by WHOI Coastal Ocean Institute Research Award. J.W. acknowledges support of the Office of Naval Research.
    Schlagwort(e): Continental shelf ; Barotropic tides ; Numerical modeling ; Data assimilation
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  • 42
    Publikationsdatum: 2022-05-26
    Beschreibung: Author Posting. © American Geophysical Union, 2008. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 113 (2008): C07032, doi:10.1029/2007JC004598.
    Beschreibung: This paper examines the sensitivity of atmospheric pCO2 to changes in ocean biology that result in drawdown of nutrients at the ocean surface. We show that the global inventory of preformed nutrients is the key determinant of atmospheric pCO2 and the oceanic carbon storage due to the soft-tissue pump (OCS soft ). We develop a new theory showing that under conditions of perfect equilibrium between atmosphere and ocean, atmospheric pCO2 can be written as a sum of exponential functions of OCS soft . The theory also demonstrates how the sensitivity of atmospheric pCO2 to changes in the soft-tissue pump depends on the preformed nutrient inventory and on surface buffer chemistry. We validate our theory against simulations of nutrient depletion in a suite of realistic general circulation models (GCMs). The decrease in atmospheric pCO2 following surface nutrient depletion depends on the oceanic circulation in the models. Increasing deep ocean ventilation by increasing vertical mixing or Southern Ocean winds increases the atmospheric pCO2 sensitivity to surface nutrient forcing. Conversely, stratifying the Southern Ocean decreases the atmospheric CO2 sensitivity to surface nutrient depletion. Surface CO2 disequilibrium due to the slow gas exchange with the atmosphere acts to make atmospheric pCO2 more sensitive to nutrient depletion in high-ventilation models and less sensitive to nutrient depletion in low-ventilation models. Our findings have potentially important implications for both past and future climates.
    Beschreibung: While at MIT, I.M. was supported by the NOAA Postdoctoral Program in Climate and Global Change, administered by the University Corporation for Atmospheric Research.
    Schlagwort(e): Carbon cycle ; Preformed nutrient ; Nutrient depletion
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  • 43
    Publikationsdatum: 2022-05-26
    Beschreibung: Author Posting. © American Geophysical Union, 2006. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Global Biogeochemical Cycles 20 (2006): GB2002, doi:10.1029/2005GB002530.
    Beschreibung: Regional air-sea fluxes of anthropogenic CO2 are estimated using a Green's function inversion method that combines data-based estimates of anthropogenic CO2 in the ocean with information about ocean transport and mixing from a suite of Ocean General Circulation Models (OGCMs). In order to quantify the uncertainty associated with the estimated fluxes owing to modeled transport and errors in the data, we employ 10 OGCMs and three scenarios representing biases in the data-based anthropogenic CO2 estimates. On the basis of the prescribed anthropogenic CO2 storage, we find a global uptake of 2.2 ± 0.25 Pg C yr−1, scaled to 1995. This error estimate represents the standard deviation of the models weighted by a CFC-based model skill score, which reduces the error range and emphasizes those models that have been shown to reproduce observed tracer concentrations most accurately. The greatest anthropogenic CO2 uptake occurs in the Southern Ocean and in the tropics. The flux estimates imply vigorous northward transport in the Southern Hemisphere, northward cross-equatorial transport, and equatorward transport at high northern latitudes. Compared with forward simulations, we find substantially more uptake in the Southern Ocean, less uptake in the Pacific Ocean, and less global uptake. The large-scale spatial pattern of the estimated flux is generally insensitive to possible biases in the data and the models employed. However, the global uptake scales approximately linearly with changes in the global anthropogenic CO2 inventory. Considerable uncertainties remain in some regions, particularly the Southern Ocean.
    Beschreibung: This research was financially supported by the National Aeronautics and Space Administration under grant NAG5- 12528. N. G. also acknowledges support by the National Science Foundation (OCE-0137274). Climate and Environmental Physics, Bern acknowledges support by the European Union through the Integrated Project CarboOcean and the Swiss National Science Foundation.
    Schlagwort(e): Anthropogenic CO2 ; Carbon cycle ; Inverse modeling
    Repository-Name: Woods Hole Open Access Server
    Materialart: Article
    Format: application/pdf
    Format: text/plain
    Format: application/postscript
    Format: application/x-tex
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  • 44
    Publikationsdatum: 2022-05-26
    Beschreibung: Author Posting. © American Geophysical Union, 2008. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Global Biogeochemical Cycles 22 (2008): GB3025, doi:10.1029/2007GB003082.
    Beschreibung: Interannually varying net carbon exchange fluxes from the TransCom 3 Level 2 Atmospheric Inversion Intercomparison Experiment are presented for the 1980 to 2005 time period. The fluxes represent the model mean, net carbon exchange for 11 land and 11 ocean regions after subtraction of fossil fuel CO2 emissions. Both aggregated regional totals and the individual regional estimates are accompanied by a model uncertainty and model spread. We find that interannual variability is larger on the land than the ocean, with total land exchange correlated to the timing of both El Niño/Southern Oscillation (ENSO) as well as the eruption of Mt. Pinatubo. The post-Pinatubo negative flux anomaly is evident across much of the tropical and northern extratropical land regions. In the oceans, the tropics tend to exhibit the greatest level of interannual variability, while on land, the interannual variability is slightly greater in the tropics and northern extratropics. The interannual variation in carbon flux estimates aggregated by land and ocean across latitudinal bands remains consistent across eight different CO2 observing networks. The interannual variation in carbon flux estimates for individual flux regions remains mostly consistent across the individual observing networks. At all scales, there is considerable consistency in the interannual variations among the 13 participating model groups. Finally, consistent with other studies using different techniques, we find a considerable positive net carbon flux anomaly in the tropical land during the period of the large ENSO in 1997/1998 which is evident in the Tropical Asia, Temperate Asia, Northern African, and Southern Africa land regions. Negative anomalies are estimated for the East Pacific Ocean and South Pacific Ocean regions. Earlier ENSO events of the 1980s are most evident in southern land positive flux anomalies.
    Schlagwort(e): Carbon cycle ; Atmospheric inversion ; Interannual variability
    Repository-Name: Woods Hole Open Access Server
    Materialart: Article
    Format: application/pdf
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  • 45
    Digitale Medien
    Digitale Medien
    New York, NY : Wiley-Blackwell
    Journal of Chemometrics 3 (1989), S. 601-608 
    ISSN: 0886-9383
    Schlagwort(e): Gas phase flow injection analysis ; Membrane-differentiated analysis ; Multicomponent determinations ; Successive linear regression ; Successive regression in fiduciary region ; Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: A membrane-discriminated gas phase analyzer is proposed for multicomponent determinations. Nitrogen gas flows countercurrent through outer and inner channels in a tube-in-tube arrangement. The only communication between the two channels occurs through a 500 μm aperture covered by a porous PTFE membrane. A mixture of organic compounds (up to four components) is injected into the inner channel by a heated backflushed injector and the sample components diffusing into the outer channel are monitored by a flame ionization detector (FID). A calibration set, consisting of pure components, binary, ternary and quaternary mixtures (a total of 64 samples), provides the known data base: temporal profiles of the FID output as a function of sample composition. Although the overall response behavior is not a linearly additive function of individual analyte concentrations, the use of successive inverse multiple linear regression (while continually altering the choice of the calibration samples considered for the forward regression, on the basis of the most recent values of the predicted unknown sample composition) is shown to yield analytical results for unknown samples that are in good agreement with their true values.
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
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  • 46
    Digitale Medien
    Digitale Medien
    New York, NY : Wiley-Blackwell
    Journal of Chemometrics 3 (1989), S. 609-609 
    ISSN: 0886-9383
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Materialart: Digitale Medien
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  • 47
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 18 (1989), S. 174-176 
    ISSN: 0887-6134
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Plasma levels and urinary excretion of mevalonate were reported to be correlated with cholesterol biosynthesis. Evaluation of mevalonate concentration in plasma and urine represents therefore a non-invasive method for studying the modifications of cholesterol synthesis. A method is described here by wich mevalonate in plasma and urine is determined by the selected ion monitoring technique after extraction as mevalonolactone and conversion into the trimethylsilyl ether. Linear responses were obtained in the evaluation of mevalonate added to plasma in the 10-100 ng/ml (r 〉 0.995) and to urine in the 50-1000 ng/ml concentration ranges, respectively. Identity of mevalonate in plasma and urine was confirmed by high-resolution mass spectrometry.
    Zusätzliches Material: 2 Tab.
    Materialart: Digitale Medien
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  • 48
    ISSN: 0887-6134
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Fast atom bombardment (FAB) mass spectrometry was used to characterize the pyochelin complexes of iron and zinc. Ferripyochelin readily forms the [M + H]+ and [2M + H]+ ions in a glycerol matrix. The molecular ion was 2.5 fold more abundant when acetic acid was present. Iron was shown to be present in the iron-pyochelin complex as the ferric ion by wet chemical methods. Differentiation between ferric and ferrous ions by FAB was not successful owing to the FAB reducing environment. Ferric ions were reduced by FAB to ferrous ions in the following model salts - ferric chloride, ferric nitrate and ferric sulfate - when dissolved in either glycerol, thioglycerol or the magic bullet matrix. Ferric and ferrous chloride salts gave virtually identical spectra with a glycerol/acetic acid matrix. Zinc-pyochelin readily forms the [M + H]+ and [2M + H]+ ions, but only when acetic acid was present in the glycerol matrix. The FAB mass spectrum of zinc-pyochelin exhibited various fragmentations which can be used in structural analysis. Linked-scan at constant B/E and accurate mass data were used to characterize the fragmentations of the zinc-pyochelin complex. Metastable analysis allowed the fragmentation pathway of zinc-pyochelin to be determined.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
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  • 49
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 18 (1989), S. 207-217 
    ISSN: 0887-6134
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The electron impact (EI) mass spectra of 2,6-di-tert-butyl-4-methylphenol (BHT) and certain of its alteration products are described in detail. Accurate mass measurements confirm the elemental compositions of important fragment ions in the EI spectra. Collisionally activated mass spectra are also used to study fragmentation and suggest common ion structures. The reference spectra provide the basis for identifying various alteration products of BHT by capillary gas chromatography/mass spectrometry (GC/MS) without the necessity of isolating individual components. Application of GC/MS is made to three studies: (i) pyrolysis of hydroperoxy-BHT as a potential pathway to alteration products in food; (ii) GC/MS pyrolysis of hydroperoxy-BHT as a model study; and (iii) alteration of BHT in ethanol/water as a food-simulating solvent.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
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  • 50
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 18 (1989), S. 363-372 
    ISSN: 0887-6134
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The MI and CA spectra of selected positive and negative ions generated by fast atom bombardment (FAB) of the stereoisomeric aldohexoses can be used to differentiate among these isomers, without prior derivatization or addition of other substances. The main fragmentation routes were traced and compared to those of some 2- and 6-deoxyaldohexoses, which appeared to be suitable model compounds. In both positive and negative ion FAB mass spectrometry, the OH group at the C-2 position plays an important role in the fragmentation reactions of the pseudomolecular [M + glycerol + H]+ and [M - H]- ions.
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
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  • 51
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 18 (1989), S. 387-393 
    ISSN: 0887-6134
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Chicken intestinal calbindin-D28k is an intracellular protein which is believed to have a fundamental role in vitamin D-mediated transport of calcium. A mapping approach based on 252Cf plasma desorption mass spectrometry (PD mapping) was used to screen the DNA-deduced sequence of calbindin-D28k for sequence changes and posttranslational modifications. In the PD mapping experiment, purified calbindin-D28k was cleaved with cyanogen bromide and the resulting peptides were subjected to PD mass spectrometric analysis either as a mixture or as high-performance liquid chromatography isolated fractions. The DNA-derived primary structure of calbindin-D28k was confirmed by rapid PD mass spectral identification of the CNBr peptide fragments, and the nature of the N-terminal blocking group was readily determined to be an acetyl group. The relatively non-destructive nature of the PD mass spectrometric analysis allowed the mapping of the N-terminal peptide through an additional in situ V8 protease enzymatic reaction.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
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  • 52
    ISSN: 0887-6134
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: A current limitation in the use of fast atom bombardment (FAB) mass spectrometric mapping of peptide mixtures, derived from enzymic digestion of proteins, is that most of the hydrophilic peptides are not observed. However, it has been demonstrated from previous work that esterification of the peptide mixture results in the detection of almost all peptides in FAB mass spectrometry. This strategy of FAB mapping was applied to the protein actinidin, isolated from an Italian variety of Actinidia chinensis. Two of the 12 tryptic peptides in FAB mass spectrometry did not exhibit molecular ions predicted from the known sequence of actinidin isolated from the New Zealand variety of A. chinensis. The two peptides were isolated by high-performance liquid chromatography, subjected to Staphylococcus aureus V8 protease digestion and sequenced by gas-phase microsequencing. Nine changes in amino acid composition were detected using the rapid and powerful combination of FAB mass spectrometric mapping and gas-phase microsequencing.
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
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  • 53
    ISSN: 0887-6134
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The metabolism of 17α-methyl-17β-hydroxy-2-oxa-5α-androstan-3-one (oxandrolone) in man has been investigated by gas chromatography/mass spectrometry. After oral administration of a 10 mg dose to man, five metabolites were detected in the free fraction of the urinary samples. Oxandrolone, the major compound excreted in urine, was detected within 72 h after administration. During this period 35.8 and 8.4% of the administered dose was excreted as unchanged oxandrolone and 17-epioxandrolone, respectively. In addition, minute amounts of 16α- and 16β- hydroxyoxandrolone and a δ-hydroxy acid resulting from the hydrolysis of the lactone group of oxandrolone were detected in the urine samples 8-60 h after administration. Furthermore, the susceptibility of oxandrolone to hydrolysis was investigated under several pH conditions. Extraction and fractionation of steroidal metabolites was achieved by using C18 and silica Sep Pak™ chromatography. The mass spectra of the metabolites are presented and major fragmentation pathways discussed.
    Zusätzliches Material: 10 Ill.
    Materialart: Digitale Medien
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  • 54
    ISSN: 0887-6134
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: An increasing amount of evidence is accumulating to support the proposal that steroidogenesis can occur by a sesterterpene pathway as well as the cholesterol pathway. Key intermediates on the sesterterpene pathway are 23,24-dinor-5-cholen-3β-ol (guneribol) and some of its metabolites, e.g. 23,24-dinor-4-cholen-3-one (guneribone). It has been reported that these intermediates are biosynthesized and converted to steroid hormones by a range of endocrine tissues in vitro. Monitoring the pentafluorobenzyloxime derivatives by negative ion chemical ionization mass spectrometry in the electron capture mode provided evidence for the presence of guneribone in extracts of bovine testicular and human adrenal tumour tissue. Complementary evidence was obtained from gas chromatographic/tandem mass spectrometric data generated on a triple-quadrupole instrument by monitoring daughter ions (in the multiple ion detection, MID mode) of the molecular anion of derivatized guneribone in both standards and tissue extracts. The present findings that sesterterpene pathway intermediates are present as endogenous compounds in tissue extracts, together with the previously reported radiochemical data, give further support to the sesterterpene pathway hypothesis.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
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  • 55
    ISSN: 0887-6134
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: A gas chromatographic/mass spectrometric analytical procedure is described to determine glycols in plasma as cyclic butyl boronate esters. The method, involving a pre-deproteinization step, required only 0.25 ml of plasma and a short time (20 min) to react with the derivatizing agent (butyl boronic acid). The gas chromatographic separation on a CP Sil 8 CB silica capillary column coupled to a mass detector assured a complete identification of the compounds. The analytical recoveries (〉95%) with low coefficient of variation (4-11%) assured the feasibility of the method over a concentration range from 5 to 1000 μg ml-1 for each glycol. The lower detection limits, namely 1-5 μg ml-1, confirmed the sensitivity of the method.
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
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  • 56
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 18 (1989), S. 603-612 
    ISSN: 0887-6134
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The synthesis of tetradeuterated 10-methylundecanoic acid, dideuterated tetracos-2-enoic acid, (1-14C)pristanic acid and (1-14C)tetracos-2-enoic acid using the Favorsky rearrangement are described. They will be used for studies of long-chain fatty acid metabolism in patients. The positions of isotope labelling were determined by mass spectrometry.
    Zusätzliches Material: 12 Ill.
    Materialart: Digitale Medien
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  • 57
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 18 (1989), S. 617-619 
    ISSN: 0887-6134
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Negative ion fast atom bombardment mass spectrometry is used to verify the sequence of oligodeoxyribonucleotides containing a single modified nucleotide. Both the position in the sequence and the molecular weight of the modified nucleotide can be determined from the 3′ and 5′-phosphate sequence ions which are prominent in the mass spectrum.
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
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  • 58
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 18 (1989), S. 620-623 
    ISSN: 0887-6134
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: A number of sulphonyl hydrazones and derivatives have been synthesized and tested for biological activity as pesticides during the crop protection research programme at the Hatfield Polytechnic. A recent comparative ionization study of some of these compounds using electron impact (EI), fast atom bombardment (FAB) and various chemical ionization methods showed FAB mass spectrometry to be the optimum technique to use in terms of molecular weight information obtained. This study compares the FAB mass spectral data in positive and negative ion mode using an alternating positive and negative ion detection system.
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
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  • 59
    ISSN: 0887-6134
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The thermospray liquid chromatography/mass spectrometry (LC/MS) interface has had a major impact on the direct analysis of the metabolic fate of xenobiotics in complex biological media. This paper outlines the rapidity and power of the LC/MS approach, and shows how detailed structural information can be obtained without recourse to individual compound isolation. This provides a great saving in time and effort. The additional specificity of liquid chromatography/tandem mass spectrometry is highlighted in identifying the sites of metabolic transformation. The ability to handle biological samples with little or no clean-up using wide high-performance liquid chromatographic gradients is a key feature of the success of this methodology.
    Zusätzliches Material: 9 Ill.
    Materialart: Digitale Medien
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  • 60
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 18 (1989), S. 629-636 
    ISSN: 0887-6134
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Several populations of Achillea species were collected from Hungarian localities. The characteristic composition cf the essential oils of almost 220 populations were determined by gas chromatography/mass spectrometry. The main component of Achillea asplenifolia, A. setacea and A. collina oils is chamazulene, with a molecular mass of 184. The composition of some A. setacea is different: instead of chamazulene it contains a significant amount of farnesene. Oils of A. distans, A. crithmifolia, A. nobilis, A. pannonica and A. ochroleuca contain some different and specific compounds instead of chamazulene. During the analysis of many essential oils, we found some very interesting differences within species originating from another geographical area.
    Zusätzliches Material: 13 Ill.
    Materialart: Digitale Medien
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  • 61
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 18 (1989), S. 652-656 
    ISSN: 0887-6134
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Deficiency of biotin at the tissue level can be assessed indirectly by measuring the urinary excretion of 3-hydroxyisovaleric acid. This paper describes the application of an improved method of quantifying urinary 3-hydroxyisovaleric acid using unlabeled and uniformly deuterated 3-hydroxyisovaleric acid. These compounds were synthesized by a modification of the lithioacetic acid method for generation of beta-hydroxy acids. Elemental analysis, nuclear magnetic resonance, gas chromatographic and gas chromatographic/mass spectrometric data demonstrated that the compounds are greater than 95% pure. Mass spectrometry confirmed the identity of the unlabeled compound, demonstrated that the deuterated compound is uniformly labeled, and offered insight into the pattern of mass fragmentation. The method for determination of the concentration of 3-hydroxyisovaleric acid in rat urine uses gas chromatographic/mass spectrometric quantification of the di-trimethylsilyl derivative with the deuterated compound as the internal standard. Results provide evidence that this method is more accurate than a previously published method that did not utilize the unlabeled and deuterated standards.
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
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  • 62
    ISSN: 0887-6134
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The metabolism of deutrated cortisol (9,12,12,-2H)cortisol, (2H3-F) was compared to that of radioactive cortisol (3H2-F) and natural cortisol, when these three compounds were administered simultaneously to an adrenalectomized piglet. The relative isotope dilution of tritium was determined from the specific activities of the main urinary neutral cortisol metabolites, tetrahydrocortisone (THE) and tetrahydrocortisol (THF), normalized to that of the cortisol mixture administered. To obtain a comparison of the isotope dilution of deuterium in the metabolites THE and THF to that in the cortisol mixture, the three steroids were converted to the common oxidation product 11-oxo-aetiocholanolone, and deivatized to the methoxime-tert-butyl-dimethylsilyl ether. The relative 2H-isotope dilution then was measured by gas chromatography/mass spectrometry. It was found that the specific activity of THE in the cumulative urine collections was similar to that of the cortisol mixture administered; the two-day value was, however, less. The specific activity of THF was slightly but significantly smaller than 1 (∼0.9) at all times. The relative 2H-isotope dilution in THE was slightly but significantly larger than one (∼1.1) at all times, whereas that in the THF was larger than 1.0 at 9 and 32 h or equal to 1.0 at 20 and 47 h of urine collection. When comparing the metabolism of the two tracer cortisol species the quotient of the 3H- and the 2H-isotope dilutions in THE and THF was smaller than 1.0. It can be concluded that (2H3)cortisol may be used for the determination of the cortisol production rate.
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
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  • 63
    ISSN: 0887-6134
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The characterization of the components of a surfactant mixture is a challenge, since we are dealing with substances inherently difficult to purify or separate by any available chromatographic methods. The results of the present work provide evidence that with fast atom bombardment mass spectrometry it is possible to identify the single constituents of the different clases of tensides - non-ionic, anionic, cationic and amphoteric - directly in the mixture and in detergent formulations (shampoos). The method, which is based on unambiguous molecular weight determination of the single components, allows the definition of the exact distribution of oligomers in the surfactant mixture, and distinction of subtle variations in the detergent composition in finished formulations. The results obtained indicate that this technique is a powerful analytical tool which can be used as a rapid screen test for quality control.
    Zusätzliches Material: 12 Ill.
    Materialart: Digitale Medien
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  • 64
    ISSN: 0887-6134
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The in vivo biliary and urinary metabolites of (±)-N-methyl-N-(1-methyl-3,3-diphenylpropyl) formamide (1) from male Wistar rats have been characterized by gas chromatography/mass spectrometry. In urine, non-conjugated metabolites included 1,1-diphenyl-3-butanone (4) and 3-methylamino-1,1, diphenylbutane (7). β-Glucuronidase liberated 4, 1,1-diphenyl-3-butanol (5), 1,1-diphenyl-3-butanone oxime (6), N-hydroxymethyl-N-(1-methyl-3, 3-diphenylpropyl) formamide (3), 1-(4-hydroxyphenyl)-1-phenyl-3-butanone (11), 1-(4-hydroxyphenyl)-1-phenyl-3-butanone oxime (12), N-methyl-N-(1-methyl-3-(4-hydroxyphenyl)-3-phenylpropyl) formamide (8), 1-(4-hydroxy-3-methoxyphenyl)-1-phenyl-3-butanone (16), 1-(4-hydroxy-3-methoxyphenyl)-1-phenyl-3-butanol (17), 1-(4-hydroxy-3-methoxyphenyl)-1-phenyl-3-butanone oxime (18), N-(1-methyl-3-(4-hydroxy-3-methoxyphenyl)-3-phenylpropyl) formamide (14) and N-methyl-N-(1-methyl-3-(4-hydroxy-3-methoxyphenyl)-3-phenylpropyl) formamide (13). Most of the carbinolamide (3) decomposed in the gas chromatograph inlet to N-(1-methyl-3,3-diphenylpropyl) formamide (2) unless stabilized as a trimethylsilyl (TMS) derivative. In bile, compounds 1, 2, 3, 5, 6, 11, 12 and 16 were present as non-conjugated metabolites. β-Glucuronidase also liberated N-(1-methyl-3-(4-hydroxyphenyl)-3-phenylpropyl) formamide (9), and all of the previously listed compounds except 7. Trimethylsilylation of the conjugated bile fraction revealed the presence of an additional two compunds: N-hydroxymethyl-N-(1-methyl-3-(4-hydroxyphenyl)-3-phenylpropyl) formamide (10) and N-hydroxymethyl-N-(1-methyl-3-(4-hydroxy-3-methoxyphenyl)-3-phenylpropyl) formamide (15). A stable carbinolamide metabolite standard was synthesized and the mass spectral fragmentations of its TMS derivative studied by tandem mass spectroscopy. This is the first report on stable carbinolamide metabolites of high-molecular-weight formamides.
    Zusätzliches Material: 6 Ill.
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  • 65
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 18 (1989), S. 713-718 
    ISSN: 0887-6134
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Advanced glycation products have been investigated by parent ion spectroscopy, employing B2/E = constant linked scans of furoyl ions obtained from hydrolysed glycated albumin and polylysine mixtures, without any extraction procedures. Using such an instrumental approach, together with exact mass measurements and collision spectroscopy, the identification of 2-(2-furoyl)-4-hydroxyl-1H-imidazole and 2-(2-furoyl)-4-carboxy-1H-imidazole among the advanced glycation products has been achieved.
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
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  • 66
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 18 (1989), S. 719-723 
    ISSN: 0887-6134
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Human cerumen was hydrolysed with base and the constituents were examined as trimethylsilyl (TMS), methyl ester/TMS, picolinyl/TMS and nicotinate/TMS derivatives by gas chromatography and gas chromatography/mass spectrometry. A sample was also reacted with osmium tetroxide for double bond location. The major constituents were cholesterol, squalene and several series of long-chain fatty acids and alcohols. These latter compounds had chain lengths of 12-26 carbon atoms and were predominantly either straight-chain saturated or straight-chain unsaturated compounds. Saturated branched-chain acids with methyl groups predominantly on even-numbered carbon atoms were present but were less abundant. Unsaturated, branched-chain acids were also present. The major unsaturated acids contained unsaturation at the delta-6-position or were derived from these acids by chain elongation. The compounds were similar to those found in vernix caseosa. The mass spectra of picolinyl esters were, for the first time, shown to be capable of determining both the position of unsaturation and methyl branching in the same molecule.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
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  • 67
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 18 (1989), S. 727-732 
    ISSN: 0887-6134
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Daughter ion mass spectral data of [M + H]+ ions of leucine enkephalin and physalaemin, which were formed by fast atom bombardment, were obtained using an instrument of EBQQ configuration. In the case of leucine enkephalin, experiments were carried out in which the collision energy was varied and the collision gas pressure kept constant and vice versa. The results show that conditions can be established under which seuqence-relevant ions above m/z 200 are formed, as well as under which mainly immonium and acylium type ions are generated. Of possible interest for characterization of unknown peptides, when using hybrid instruments, are the mid-chain cleavage ions, which, at a constant argon gas pressure of 5 × 10-6 mbat, were found to maximize at around 30 eV collision energy. Daughter ion mass spectral data are also presented for [M + H]+ ions of physalaemin (mol. wt 1264). Compared to data obtained for physalaemin on multisector instruments, our results indicate that the formation of mid-chain cleavage ions is clearly enhanced.
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
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  • 68
    ISSN: 0887-6134
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The supernatants of Vero cell cultures after infection with a herpes simplex virus or a poliomyelitis virus as well as a blank were analysed by pyrolysis/direct chemical ionization mass spectrometry (Py/DCI MS). Informative pyrogrammes were obtained and used for characterization of viral proteins by applying pattern recognition methods. Differentiation of viral proteins was evaluated by analysing ‘blind’ samples. Herpes viruses could be classified correctly but the observed differences between the blank and the polio virus supernatants were too small for reliable classification of the polio viruses. Purification of the samples seems to be a prerequisite for further studies. The potential value of Py/DCI MS as a rapid non-invasive diagnostic method for viral meningoencephalitis is stressed.
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
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  • 69
    ISSN: 0887-6134
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Experimental variables in fast atom bombardment combined with tandem mass spectrometry based on low-energy collision-induced dissociation have been systematically invetigated in order to optimize parameters for analysis of synthetic lipo-oligopeptides. The parameters studied were matrix, ion polarity, collision gas, collision gas pressure and collision energy. The optimal parameters recommended in this study have been applied to the N-terminal amino acid seuquence determination of lipopeptide obtained from Nocardia rubra cell wall skeleton. Daughter and parent ion experiments with negative ion fast atom bombardment combined with tandem mass spectrometry have proven to be very useful for structure elucidation of a complex mixture of lipo-oligopeptides.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
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  • 70
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 18 (1989), S. 775-779 
    ISSN: 0887-6134
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The technique of gas chromatography/tandem mass spectrometry is applied to the analysis of bis(chloromethyl) ether in laboratory and production environments. A selected reaction monitoring method is shown to yield superior sensitivity and selectivity to previous methods. A detection limit of ∼1 ppt is established even for chemically complex atmospheres which have proved intractable by previous techniques.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
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  • 71
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 18 (1989), S. 281-286 
    ISSN: 0887-6134
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Positive ion fast atom bombardment mass spectra of the opioid pentapeptides leucine enkephalin (1) (H-Tyr-Gly-Gly-Phe-Leu-OH or YGGFL), methionine enkephalin (2) (H-Tyr-Gly-Gly-Phe-Met-OH or YGGFM) and leucine enkephalin-2H2 (3) (H-Tyr-2Gly-2H2-Gly-Phe-Leu-OH or YGGFL-2H2) have been recorded in glycerol. The following experiments have been carried out: (i) dimer studies [2M + 1]+; (ii) decompositions of dimers: daughter ions from (YGGFL)2, (YGGFL-YGGFL-2H2) and (YGGFL-2H2)2 as well as (YGGFM-YGGFL) and (YGGFM)2 dimers; (iii) solvation site and pyridine collision-activated dissociation studies for dimer ions; (iv) mechanism of formation of [(2M + 1) - Gly4]+ ions.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
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  • 72
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 18 (1989), S. 321-327 
    ISSN: 0887-6134
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Increasingly widespread usage of stable isotope tracers to aid clinical diagnosis and support basic research has stemmed from both advances in mass spectrometry and the availability of competitively priced labelled compounds. Stable isotopes have been used generally to investigate normal and abnormal metabolic pathways, to estimate energy expenditure and body composition and to quantitate substrate flux and oxidation rates. Despite the fact that the underlying principles relating to the use of stable isotopes for in vivo studies are straightforward, careful consideration must be given to all aspects of human studies. This review highlights some of these, including choice of label and tracer molecule, mode of tracer administration and sampling site, analytical instrumentation, interpretation of data and ethical constraints.
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
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  • 73
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 18 (1989) 
    ISSN: 0887-6134
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 74
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 18 (1989), S. 358-358 
    ISSN: 0887-6134
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 75
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 18 (1989), S. 359-362 
    ISSN: 0887-6134
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The glucuronide of N-1-hydroxy-ethyl flurazepam has been analysed by a direct liquid inlet liquid chromatographic/mass spectrometric system using MeOH/H2O (70:30 v/v) as mobile phase, at a flow rate of 0.7 ml min-1. Urine samples were purified by amberlite XAD-2 chromatography; the glucuronide was quantified by highperformance liquid chromatography using a counterion (tetrabutyl ammonium nitrate in methanol). Chromatographic results were validated by an enzymatic method: treatment of the samples with β-glucuronidase and extraction of the parent drug with ethyl ether at pH 9. The biological application of this method was demonstrated by determination of this glucuronide in the urine of healthy human volunteers following a single intravenous administration of 50 mg of N-1-hydroxy-ethyl flurazepam.
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
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  • 76
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 18 (1989), S. 373-386 
    ISSN: 0887-6134
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Domoic acid is a naturally occurring amino acid, formerly available in limited amounts as a natural product of some algae of the family Rhodomelaceae. As the result of a recent incidence of toxicity in cultured blue mussels (Mytilus edulis) from a highly localized region of Atlantic Canada, useful amounts of this substance are likely to become available in the near future. Domoic acid is an important substance for fundamental studies in neurobiology as it possesses the highest affinity amongst known substances for the kainate receptors of the central nervous system. The present work describes fast atom bombardment (FAB) mass spectra of domoic acid, and of some of its isomers present in minor quantities in contaminated mussel extracts. These FAB spectra are subject to interferences from beam-inducced reduction reactions associated with matrices such as glycerol, but not with others such as 3-nitrobenzyl alcohol. Tandem mass spectrometry of the MH+ ions from these compounds is also reported. As a more feasible approach to quantitative analysis at trace levels, formation of the volatile tert-butyldimethylsilyl derivatives has been investigated and shown to be highly promising.
    Zusätzliches Material: 9 Ill.
    Materialart: Digitale Medien
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  • 77
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 18 (1989), S. 394-400 
    ISSN: 0887-6134
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Collisionally activated decomposition mass spectra of M-. ions of azo dyes are presented. The compounds are of general structure Ar(1)—N=N—Ar(2), where Ar(1) is substituted phenyl and Ar(2) is 2-naphthol. Characteristic fragment ions observed include m/z 157, which corresponds to the 2-naphthol substituent with cleavage of the —N=N— bond represented as [Ar(2) - N]-.. Ion of general structure [Ar(1)- NH]- are also observed. Parent ion scans of m/z 157 provide a potential screening technique for 2-naphthol-containing axo dyes. Specific results are reported for the chloroform extract of FD&C Red #8, and capillary gas chromatographic introduction is compared with direct exposure probe introduction for the identification of dyes.
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
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  • 78
    ISSN: 0887-6134
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: In order to determine the fraction of an intravenous bolus dose of ketamine which is metabolized in vivo to the corresponding N-desmethyl compound, norketamine, a novel stable isotope technique was developed and applied to a study in rats. Co-injection of equimoiar amounts of deuterium-labeled ketamine and unlabeled norketamine to four animals, followed by gas chromatographic/mass spectrometric analysis of both the administered compounds and deuterium-labeled norketamine in plasma yielded pharmacokinetic data from which the fraction of the parent drug subjected to N-demethylation (fm) was calculated from AUC data to be 36.8 ± 2.4%. It is concluded that this stable isotope co-administration technique represents a powerful approach to the determination of fm, in that the pharmacokinetics of the metabolite of interest, given as the preformed compound and generated in vivo, are determined simultaneously. This experimental design thus obviates the influence of time-dependent changes in metabolite clearance which may complicate the interpretation of studies performed using the classical cross-over design.
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
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  • 79
    ISSN: 0887-6134
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Rats given 2-octynoic acid by intraperitoneal injection excrete elevated amounts of medium-chain dicarboxylic acids and other acidic metabolites usually associated with human medium-chain acyl-CoA dehydrogenase deficiency. Onset of this organic acid profile is immediate and lasts for approximately 24 h. The induced acidosis in this animal model closely, acutely and transiently resembles the human disorder. The 2-octynoate load is also extensively Ω- and Ψ-oxidized, and evidence is presented for the enzymic hydration of 2-octynoate to 3-ketooctanoic acid.
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
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  • 80
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 18 (1989), S. 445-449 
    ISSN: 0887-6134
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: A series of dyes belonging to different chemical classes have been analyzed by thermospray (TSP) ionization mass spectrometry using a modified source containing a wire-repeller. Detection limits were determined and found to be in the range 0.05-20 ng, which are lower by a factor of 10-400 than previously published results. Positive-ion TSP mass spectra of some sulfonated dyes could be recorded for the first time owing to the increased sensitivity. Losses of SO3Na and 2SO3Na as well as losses of Na and 2Na were observed. The losses of each one of these groups involved replacement by a hydrogen atom.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
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  • 81
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 18 (1989), S. 558-562 
    ISSN: 0887-6134
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: A specific and sensitive gas chromatographic/mass spectrometric method was developed and validated for the quantitative determination of the aromatase inhibitor CGS 16 949 in plasma and urine. A deuterium-labelled analogue of CGS 16 949 was used as internal standard. The analysis of spiked samples demonstrated the good accuracy and precision of the method. For both plasma and urine, the limit of quantification (LOQ: coefficient of variation (CV) = 10%) and the limit of detection (LOD: CV = 100%) were estimated to be 5 and 1 nmol l-1, respectively. The method was applied to the determination of unchanged CGS 16 949 in plasma and urine of a healthy volunteer orally dosed with 1 mg of CGS 16 949 A.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
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  • 82
    ISSN: 0887-6134
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The determination of pipecolic acid in serum or plasma by positive chemical ionization gas chromatography/mass spectrometry is assessed. This quantitative method involves stable isotope dilution and cation-exchange solid-phase extraction. Several derivatives of pipecolic acid and its octadeuterated analogue were investigated for their mass spectrometric characteristics. The beptafluorobutyric methyl ester derivatives afford optimal resolution on gas chromatography of biological extracts. Moreover, the derivatizing reagent (methanolic HCl) allows a combined elution and derivatization. Selected ion monitoring is performed on the [M + H]+ ions of both analyte and internal standard, at m/z 340 and 348, respectively. Serum or plasma samples from healthy subjects and patients suspected of peroxisomal diseases have been examined.
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
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  • 83
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 18 (1989), S. 581-591 
    ISSN: 0887-6134
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Laser microprobe mass spectrometry has been applied to a variety of organic polyfunctional molecules, covering a wide range of polarity and mass spectrometric behaviour. The technique apparently combines desorption under relatively soft conditions with extensive fragmentation and hence allows much structural information from intactly released thermolabiles to be obtained. The mass spectra appear unfamiliar in comparison to conventional techniques. Interpretation is attempted in a purely empirical way by means of the evidence from our database and tentative hypotheses to rationalize the desorption and ionization by laser microbeam irradiation of organic solids. Selected examples are presented to illustrate the potential and limitations of the method in the field of biomolecules, such as pyridoxine and pyridoxal phosphate, nucleosides, nucleotides and related analogues, drugs and the corresponding N-oxides.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
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  • 84
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 18 (1989) 
    ISSN: 0887-6134
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 85
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 18 (1989), S. 5-11 
    ISSN: 0887-6134
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The collision-induced dissociation mass spectrum, observed with a hybrid tandem instrument, of the ammonia chemical ionization protonated molecular ion of chloramphenicol was used for the detection of residues of the drug in biological samples. The extracted oil from fish was subjected to a rapid clean-up on a pre-packed silica gel cartridge prior to non-chromatographic tandem mass spectral analysis. Fat extracted from milk was analysed directly by on-line combined high-performance liquid chromatography/tandem mass spectrometry with rapid elution of chloramphenicol. Identification was on the basis of agreement of the daughter ion spectra obtained from sample extracts with that of the chloramphenicol standard. Detection was unambiguous at 0.5 mg kg-1. The sensitivity advantage normally expected with multiple reaction monitoring was not achieved owing to the effect of neutral noise phenomena.
    Zusätzliches Material: 9 Ill.
    Materialart: Digitale Medien
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  • 86
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 18 (1989), S. 48-56 
    ISSN: 0887-6134
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Metabolism of cyclosporin A (CsA) was studied in a model of isolated and perfused rabbit liver, and in man. After diethyl ether extraction, CsA metabolites were separated and successfully purified by a combination of two highperformance liquid chromatographic (HPLC) procedures. A normal-phase HPLC methodology was used to separate most of the metabolites, and further separation and purification were optimized with a reversed-phase HPLC method. 27 different CsA metabolites were separated, collected, and characterized by fast atom bombardment mass spectrometry. In addition to several metabolites already described (OL-1, OL-17, OL-18 and OL-21), new compounds (of original molecular weights 1236, 1222 and 1174, and numerous structural isomers of previously reported molecular weights) were isolated from rabbit and human bile. Mass spectral analysis of two of these new metabolites strongly suggests vicinal dihydrodiol (mol. wt 1236) and N-demethylated vicinal dihydrodiol (mol. wt 1222) structures. These two new metabolites most probably derive from an epoxide as a preliminary intermediate.
    Zusätzliches Material: 7 Ill.
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  • 87
    ISSN: 0887-6134
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Packed capillary liquid chromatography/mass spectrometry using a moving belt interface is a practical, versatile technique for the identification of unknowns. The low flow rates (1-2 μl min-1) improve the operation of the moving belt and allow direct deposition of eluates from reversed-phase liquid chromatographic columns containing large proportions of water. Column performance and durability is equivalent to that obtained with conventional or microbore liquid chromatographic columns. Techniques have been developed for analyzing dilute solutions with no loss in column performance and for the detection of radiolabeled metabolites. Applications to analyses of polar, thermally labile compounds and environmental samples are presented.
    Zusätzliches Material: 9 Ill.
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  • 88
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 18 (1989), S. 106-109 
    ISSN: 0887-6134
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Perfluorocarbons (PFCs) can be detected by thermospray liquid chromatography/mass spectrometry (LC/MS) only when the system is operated in the negative ion mode with filament on and some water entering the thermospray source. A new mechanism for PFC ionization is proposed, based on studies of LC/MS detection of the perfluorinated forms of cyclohexane, methyl and dimethyl cyclohexane, decalin, 1-methyl decalin and toluene. The ion evaporation mechanism of Dodd, involving pre-ionization of PFCs in the presence of aqueous NH4OAc, is not operative, nor is chemical ionization of PFCs by the reagent ions as in true thermospray LC/MS. Instead, PFC ionization is attributable to the negative ions formed from the water in the source; these ions undergo prompt charge-exchange reactions with the more electronegative PFCs to form structure-retaining PFC ions.
    Zusätzliches Material: 4 Ill.
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  • 89
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 18 (1989), S. 131-137 
    ISSN: 0887-6134
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Suppression effects observed in plasma desorption (PD) mass spectrometry have been studied and compared to those found in fast atom bombardment mass spectrometry. A basic difference in the mechanism of suppression in the two techniques is demonstrated. In positive ion mode PD mass spectrometry, peptides carrying net positive charges are preferentially detected when analysed together with peptides carrying net negative charges, and in negative ion mode PD mass spectrometry, the situation is generally reversed. Based on this complementarity, PD mapping carried out by enzymatic digestion of a nitrocellulose-bound sample can in many cases yield almost complete coverage of smaller proteins.
    Zusätzliches Material: 4 Ill.
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  • 90
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 18 (1989), S. 122-130 
    ISSN: 0887-6134
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Fast atom bombardment (FAB) mass spectrometry and FAB tandem mass spectrometry in negative mode can provide molecular weight and very useful structural prior information for C-glycosyl flavonoids without derivatization. Diethanolamine or thioglycerol matrix gave an abundant deprotonated molecular ion for all the studied compounds. Mass-analysed ion kinetic energy (MIKE) and collision-activated dissociation/MIKE spectra provide characteristic fragment ions which permit differentiation of the 6- and/or 8-location, and the position of O-glycosylation.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
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  • 91
    ISSN: 0887-6134
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The use of high-performance liquid chromatography and fast atom bombardment mass spectrometry are shown to be an efficient combination for investigating protease-mediated digestion of synthetic analogs of the peptide hormone ANF (atrial natriuretic factor). As examples of the reported methodology, rANF5-23-NH2 and rANF7-23-NH2 were digested with the endopeptidase thermolysin. These truncated analogs were selected to investigate metabolism within the disulfide-linked core of ANF, particularly at the Cys7—Phe8 bond. While this position was the site of initial hydrolysis for rANF5-23-NH2 (t1/2 = 0.5 min), the Cys7—Phe8 bond remained intact for all observed degradation products of rANF7-23-NH2 (t1/2 = 16 min). These findings suggest that improved stability towards endopeptidase-mediated core hydrolysis may be conferred to analogs of ANF by removal of the first six residues from the N-terminus.
    Zusätzliches Material: 8 Ill.
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  • 92
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 18 (1989), S. 265-277 
    ISSN: 0887-6134
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Laser ionization of guanosines containing methyl substitutions in the 1-, N2-, 3′-O-, O6- and 7- positions generated two characteristic negative ions: loss of hydrogen to generate [M - H]- and elimination of the sugar ring to form the nucleic base ion. The ions generated by elimination of the sugar ring provided the information necessary to determine whether the methyl group was on the nucleic base or sugar ring. Fourier transform mass spectrometry was used to isolate and collisionally dissociate selected negative ions from these nucleosides. The collisional dissociation spectra indicated daughter ions which were sufficient to differentiate all the isomers with methyl substitution of the nucleic bases. In addition, accurate mass measurement an dsequential collisional dissociation experiments were employed to investigate fragmentation mechanisms.
    Zusätzliches Material: 11 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 93
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 18 (1989), S. 301-307 
    ISSN: 0887-6134
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The mass spectra of many rifamycins cannot be obtained by electron ionization (EI) owing to their thermal decomposition. When a laser beam is used to vaporize the sample through an optic fibre inserted in a hollow probe which reaches the sample cup, decomposition is minimized and the EI spectra show abundant molecular ions and fragments of structurally high diagnostic value. These ionic species are easily observed owing to the lack of chemical noise often present in soft ionization methods, such as direct liquid chemical ionization and fast atom bombardment.
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 94
    ISSN: 0887-6134
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The conversion of oestrogens mixed derivatives comprising a phenolic silyl ether and one or more alcoholic perfluoroactyl ester(s) is described. They are easily formed in quantitative yield and have excellent gas chromatographic and mass spectrometric properties, making them suitable for analysis by selected ion monitoring. Reaction mechanisms are examined which propose explanations for the experimentally observed optimal reaction conditions. The 3-t-butyldimethylsilyl ether-16α 17β-bis(pentafluoropropionate) has been used for the quantitative determination of oestriol in plasma by gas chromatography/mass spectrometry using a stable isotope internal standard. Comparison with the pertrimethylsilyl ether of oestriol indicates higher specificity and better precision for low-level (〈0.5 ng ml-1) estimations.
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 95
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 18 (1989), S. 355-357 
    ISSN: 0887-6134
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 96
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 18 (1989), S. 1087-1095 
    ISSN: 0887-6134
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The utility of deuterium-labeled 3-nitrobenzyl alcohol (DNBA) as a fast atom bombardment (FAB) matrix for establishing the number of exchangeable hydrogens present in a molecule is illustrated by the analysis of five selected antitumor agents. A method for the simple preparation of this labeled matrix is described. The use of DNBA may be of value for samples which provide no FAB spectra when deuterium-labeled glycerol is used as a matrix.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 97
    ISSN: 0887-6134
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Like most dyes, Basic Yellow 2 (BY-2) fades upon prolonged exposure to light. Light-induced fading is a complex process that is also affected by heat and humidity. In order to better understand the photodegradation process and to identify the various photodegradation products of BY-2, fabric samples and solutions containing BY-2 were exposed to a variety of fading conditions. The analysis of faded BY-2 dyed fabric extracts by high-performance liquid chromatography/mass spectrometry (HPLC/MS) indicated the reduction and hydrolysis of the C=NH2+ group to form primarily benzophenone derivatives, as well as various demethylated products. Due to the absence of fragmentation in the thermospray spectra (only [M + H]+ ions were observed) the dye extracts were analyzed by gas chromatography/mass spectrometry (GC/MS) to confirm the identity of the degradation products. Many of the degradation products were sufficiently volatile for analysis by GC/MS. Mass spectra of the photodegradation products of BY-2 exhibited molecular ions and structurally important fragment ions to complement the thermospray data. The mass spectral data indicated that the most prevalent degradation product formed was ((CH3)2NC6H4)2C=0 (Michler's ketone). Hydrolysis of the C=NH2+ group to C=0 is the main color-destroying reaction in the fading of BY-2. Demethylation products which can alter the shades of color were also detected in the faded BY-2 samples.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 98
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 18 (1989), S. 1096-1098 
    ISSN: 0887-6134
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Methanesulfinic and methanesulfonic acids were shown to be present in urine from rats fed laboratory rat diet. The daily excretions of each acid were equivalent at 0.47 μmol day-1. The excretion of methanesulfinic acid increased about ninefold and that of methanesulfonic doubled when rats were dosed with 17 μmol of pentachlorothioanisole. The excretion of methanesulfinic acid above control levels in urine may be a method for detecting methylthio displacements that occur during the intermediary metabolism of xenobiotics.
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 99
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 18 (1989), S. 1105-1105 
    ISSN: 0887-6134
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 100
    Digitale Medien
    Digitale Medien
    New York, NY : Wiley-Blackwell
    Journal of Chemometrics 3 (1989), S. i 
    ISSN: 0886-9383
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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