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  • Elsevier  (24,792)
  • American Chemical Society  (20,626)
  • 2020-2024  (22,851)
  • 1935-1939
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  • 101
    facet.materialart.
    Unknown
    Elsevier
    In:  Spiess, R., Langone, A., Caggianelli, A., Stuart, F.M., Zucchi, M., Bianco, C., et al., 2021. Unveiling ductile deformation during fast exhumation of a granitic pluton in a transfer zone. J. Struct. Geol. 147, 104326.
    Publication Date: 2023-02-27
    Description: In their paper, Spiess et al. (2021) published structural, geochronological, and EBSD data on one of the monzogranite apophyses (Capo Bianco) of the buried Porto Azzurro Pluton (island of Elba, Northern Apennines, Italy), a pluton emplaced in the upper crust (P 〈 0.2 GPa; e.g. Papeschi et al., 2019). The authors published a new U/Pb age of 6.4 ± 0.4 Ma, associated with the thermal peak, and a U-Th/He apatite age of 5.0 ± 0.6 Ma, indicating cooling below 60 ◦C. Spiess et al. (2021) use these ages to model the exhumation of the pluton controlled, in their model, by the Zuccale Fault, a subhorizontal fault with 6 km of eastward displacement (ZF; Keller & Coward, 1996). Their structural dataset from the macro to the microscale and EBSD analyses relies on a small section (about 100 m wide) in the NE part of the Calamita Peninsula. Based on their documentation of (1) vertical dykes in the monzogranite, (2) vertical to low-angle top-to-the-E extensional faults, and (3) later NWstriking oblique faults, they interpret the Porto Azzurro Pluton as emplaced in an extensional to transcurrent tectonic setting, extrapolating their findings to the entire Eastern Elba.
    Description: Published
    Description: 104499
    Description: 1T. Struttura della Terra
    Description: JCR Journal
    Keywords: Upper crustal deformation ; Magmatic intrusion ; 04.04. Geology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 102
    Publication Date: 2023-02-27
    Description: Crystal zoning plays a fundamental role in modern volcanology as a key to unravel the geometry and the dynamics of plumbing systems. In this study, a detailed textural and compositional study of clinopyroxene crystals entrained in intrusive, hypabyssal and effusive products from Cima Pape (Dolomites) is coupled with thermobarometric-hygrometricmodels to reconstruct the geometry and evolution of the feeding systembeneath Middle Triassic volcanic edifices. Whole-rock major, trace element distribution and Sr-Nd isotopic signature (87Sr/86Sri = 0.7045–0.7050; 143Nd/144Ndi = 0.51223–0.51228) show that the rocks from Cima Pape are SiO2- saturated and have shoshonitic affinity, and likely belong to the acme of the Mid-Triassic magmatismthat shaped the Southern Alps between 239 and 237.6Ma. Highly porphyritic trachybasaltic to basaltic trachyandesitic volcanic rocks contain a large number of concentric-zoned clinopyroxene crystals. Here, high-Mg# and -Cr2O3, REEdepleted bands (Mg# 80–91; Cr2O3 up to 1.2 wt%) with variable thickness grew between relatively low-Mg# and -Cr2O3 (Mg# 70–77; Cr2O3 〈 0.1 wt%) augitic cores and rims. In contrast, the gabbroic to monzodioritic 50- to 300-m-thick sill cropping out belowthe volcanic sequences, though to represent a relic of the shallowest portion of the plumbing system, is mostly made up of unzoned clinopyroxene crystals. Thermobarometric and hygrometric models allowed us to define that a small “mush-type” batchwas located beneath the Cima Pape volcano at depths between 7 and 14 km. Here, augitic clinopyroxene formed in equilibrium with a slightly evolved (basaltic trachyandesitic), H2O-rich melt (Mg# = 43–45; T = 1035–1075 °C; H2O = 2.6–3.8 wt%). Periodic replenishments of the magma batch by primitive (Mg# = 65–70), hotter and relatively H2O-poor (T = 1130–1150 °C; H2O = 2.1–2.8 wt%) basaltic magmas led to the formation of diopsidic bands mantling the already formed augitic cores. Later on, re-equilibration of clinopyroxene with the mixed melt resulted in the formation of low-Mg#, LILE- and LREE-enriched rims. The most Mg-poor micro-phenocrystic clinopyroxene in the volcanic rocks and in the sill records the ultimate and shallowest conditions of crystallization, occurring at T of 975–1010 °C and P comprised between 50 and 150 MPa. Based on the presence of similar zoning in clinopyroxene phenocrysts, a comparison between the Mid-Triassic Cima Pape and active volcanoes was put forward to highlight the potential of studying ancient, entirely exposed volcanic systems for interpreting the feeding systemprocesses acting beneath active volcanoes. At a regional scale, this approach represents a new, powerful tool for investigating the evolution of the Mid-Triassic magmatism in the Southern Alps and shedding light on the interactions between mantle-derived melts and differentiated batches ponding in the crust.
    Description: Published
    Description: 107459
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 103
    Publication Date: 2023-02-28
    Description: A new decomposition method for nonstationary signals, named Adaptive Local Iterative Filtering (ALIF), has been recently proposed in the literature. Given its similarity with the Empirical Mode Decomposition (EMD) and its more rigorous mathematical structure, which makes feasible to study its convergence compared to EMD, ALIF has really good potentiality to become a reference method in the analysis of signals containing strong nonstationary components, like chirps, multipaths and whistles, in many applications, like Physics, Engineering, Medicine and Finance, to name a few. In [11], the authors analyzed the spectral properties of the matrices produced by the ALIF method, in order to study its stability. Various results are achieved in that work through the use of Generalized Locally Toeplitz (GLT) sequences theory, a powerful tool originally designed to extract information on the asymptotic behavior of the spectra for PDE discretization matrices. In this manuscript we focus on answering some of the open questions contained in [11], and in doing so, we also develop new theory and results for the GLT sequences.
    Description: Published
    Description: 127-152
    Description: 2A. Fisica dell'alta atmosfera
    Description: JCR Journal
    Keywords: Mathematics - Numerical Analysis; Mathematics - Numerical Analysis; Computer Science - Numerical Analysis
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 104
    Publication Date: 2023-02-28
    Description: This study aims to explore the reliability of flood warning forecasts based on deep learning models, in particular Long-Short Term Memory (LSTM) architecture. We also wish to verify the applicability of flood event predictions for a river with flood events lasting only a few hours, with the aid of hydrometric control stations. This methodology allows for the creation of a system able to identify flood events with acceptable errors within several hours' notice. In terms of errors, the results obtained in this study can be compared to those obtained by using physics-based models for the same study area. These kinds of models use few types of data, unlike physical models that require the estimation of several parameters. However, the deep learning models are data-driven and for this reason they can influence the results obtained. Therefore, we tested the stability of the models by simulating the missing or wrong input data of the model, and this allowed us to achieve excellent results. Indeed, the models were stable even if several data were missing. This method makes it possible to lay the foundations for the future application of these techniques when there is an absence of geological-hydrogeological information preventing physical modeling of the run-off process or in cases of relatively small basins, where the complex system and the unsatisfactory modeling of the phenomenon do not allow a correct application of physical-based models. The forecast of flood events is fundamental for correct and adequate territory management, in particular when significant climatic changes occur. The study area is that of the Arno River (in Tuscany, Italy), which crosses some of the most important cities of central Italy, in terms of population, cultural heritage, and socio-economic activities.
    Description: Published
    Description: 151885
    Description: 3IT. Calcolo scientifico
    Description: JCR Journal
    Keywords: Arno River; Deep learning; Fast catchment basin; Flood forecasting; Hydraulic models; LSTM
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 105
    Publication Date: 2023-02-28
    Description: Current global warming causes a change in atmospheric dynamics, with consequent variations in the rainfall regimes. Understanding the relationship between global climate patterns, global warming, and rainfall regimes is crucial for the creation of future scenarios and for the relative modification of water management. The aim of this study is to improve knowledge of the relationship between North Atlantic Oscillation (NAO), East Atlantic (EA), and Western Mediterranean Oscillation (WeMO) with the seasonal rainfalls in Tuscany, Italy. The study area occupies a strategic position since it lies in a transition zone between the wet area of northern Europe and the dry area of the northern coast of Africa. This research, based on a statistical correlation method and on linear models, is designed to understand the relationship between seasonal rainfalls and climate patterns. The results of this study demonstrate that the use of linear models can yield more information than traditional statistical corre- lations. The results show a decrease in rainfall in the warm period of the year, namely in the summer, when its expression is most visible. This phenomenon is ascribable to current global warming, which causes an increase in sea-surface temperatures. An increase in the Northern Atlantic Sea Surface Temperature and in the Mediterra- nean Sea Surface Temperature causes a reduction of the Iceland Low, with an extension of the Azores High. Moreover, an increase in the Genoa Gulf SST
    Description: Published
    Description: 128233
    Description: 4A. Oceanografia e clima
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 106
    Publication Date: 2023-02-28
    Description: New composite materials are always subjected to non-destructive evaluation (NDE) prior to being placed on the market. This is to fully understand the reactions (i.e., development of defects) at the interface between two subsequent layers. Active infrared thermography (aIRT) can help in this regard, especially if anticipated by a simulation of the heat transfer from the exterior (lamp) to the interior (multilayer). Comsol Multiphysics® was used in this work as a tool by developing an innovative approach, which is designed – on the one hand – to minimize the computational cost and – on the other hand – to optimize the radiation to be delivered. The innovation produced by our work also concerns the pre-processing step of the thermal images; in fact, the 2D Fast Iterative Filtering (FIF2) is here introduced, discussing its benefits in comparison to previously developed techniques. Pre-processed data were further analyzed during the post-processing step demonstrating the reliability of FIF2 in enhancing thermal imprints, which leads to an improved detection of subsurface features. In particular, enhanced thermal imprints highlight the shape of the grid of glass fibres present beneath an external coating of hemp fibres (and, in general, added to the whole specimen along the x-y vectors). This grid of glass fibres was recently introduced as an insulation material for buildings. A brief review of the use of the pre-processing step in aIRT allows the reader to better understand the decisive step forward provided by FIF2 combined with a clever numerical simulation in the applied thermal engineering field. Qualitative and quantitative IRT results are shown and discussed thoroughly. Finally, a validation among numerical and experimental (thermographic) data is provided thanks to the Parker (laser flash) method.
    Description: Published
    Description: 107553
    Description: 5T. Sismologia, geofisica e geologia per l'ingegneria sismica
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 107
    Publication Date: 2023-02-28
    Description: Retrieving object phase from the optical fringe pattern is a critical task in quantitative phase imaging and often requires appropriate image preprocessing (background and noise minimization), especially when retrieving phase from the single-shot fringe pattern image. In this article, for the first time, we propose to adapt the 2D Fast Iterative Filtering (FIF) method for fringe pattern decomposition and develop a novel version of FIF called the 2D fringe pattern Fast Iterative Filtering (fpFIF2), that is tailored for fringe pattern preprocessing. We show the positive influence of fpFIF2 onto fringe pattern filtering comparing to the previous 2D FIF implementation regarding processing speed, quality, and usage comfortability. We also compare the fpFIF2 with other state-of-the-art fringe pattern filtering methods in terms of aiding the Hilbert spiral transform method in phase retrieval. Employing numerical simulations and experimental fringe analysis, we prove that fpFIF2 outperforms reference methods, especially in terms of low-fringe-contrast phase reconstruction quality and decomposition time.
    Description: Published
    Description: 107069
    Description: 2A. Fisica dell'alta atmosfera
    Description: JCR Journal
    Keywords: Physics - Optics; Physics - Optics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 108
    Publication Date: 2023-02-21
    Description: Intra-oceanic arcs are typically associated with intermediate (andesitic) cone volcanoes. However, caldera volcanoes may also form in these settings from very large eruptions, resulting in sudden changes to the magma reservoir. These reservoirs can then produce either semi-continuous or intermittent low-intensity volcanism between major caldera-producing or caldera-deepening eruptions, providing insights into the post-caldera evolution of the system. Hunga volcano (Kingdom of Tonga, Southwest Pacific) is a large mainly submarine edifice that produced a series of caldera-forming eruptions ~900 years ago. Since then, numerous smaller-scale subaerial and submarine eruptions occurred, the most recent forming new islands in 2009 and 2014/15. Pyroclastic deposits associated with these latest eruptions have identical (range ~ 0.1 wt% of all major oxides) andesitic composition that overlap with the primitive end of the slightly wider compositional range of the caldera-forming episodes. Texturally simple plagioclase, clinopyroxene and orthopyroxene phenocrysts in pre-, syn- and post-caldera pyroclasts point to a single shallow storage reservoir at 5–8 km depth. Lack of complex zonation indicates that this reservoir is constantly resupplied by low-flux inputs of basaltic andesite magma and is large enough that convective mixing rapidly homogenises new inputs. The reservoir feeds intermittent, low-intensity, post-caldera volcanism with constant andesite composition, driven possibly by magmatic overpressure and “leakage” of gas-rich magma pockets around the edges of the caldera. More primitive and compositionally variable basaltic andesites formed a lava-dominated edifice prior to the caldera-forming event. This suggests a causal link between magma supply dynamics and caldera priming relating to the maturing of the plumbing system and formation of a sustained subvolcanic andesite magma reservoir.
    Description: This research was funded by the Faculty Research Development Fund, The University of Auckland to MB and SJC. We are grateful for financial and logistic support from ICON Films, Bristol, UK. We are especially grateful for the help and company of Lucy Meadows and Alex Holden, ICON Films, UK, during the field studies.
    Description: Published
    Description: 106614
    Description: 1V. Storia eruttiva
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: 4V. Processi pre-eruttivi
    Description: JCR Journal
    Keywords: Andesite caldera, mafic ignimbrite ; Lava Explosive volcanism ; Hunga Tonga Arc volcanism ; South Pacific volcanism ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 109
    Publication Date: 2023-02-21
    Description: Many vertical seismic velocity anomalies observed below different parts of the Eurasian plate are rooted in the transition zone between the upper and lower mantle (410–660 km), forming so-called secondary plumes. These anomalies are interpreted as the result of thermal effects of large-scale thermal upwelling (primary plume) in the lower mantle or deep dehydration of fluid-rich subducting oceanic plates. We present the results of thermo-mechanical numerical modelling to investigate the dynamics of such small-scale thermal and chemical (hydrous) anomalies rising from the lower part of the Earth’s upper mantle. Our objective is to determine the conditions that allow thermo-chemical secondary plumes of moderate size (initial radius of 50 km) to penetrate the continental lithosphere, as often detected in seismo-tomographic studies. To this end, we examine the effect of the following parameters: (1) the compositional deficit of the plume density due to the presence of water and hydrous silicate melts, (2) the width of the weak zone in the overlying lithosphere formed because of plume-induced magmatic weakening and/or previous tectonic events, and (3) a tectonic regime varied from neutral to extensional. In our models, secondary plumes of purely thermal origin do not penetrate the overlying plate, but flatten at its base, forming “mushroom”-shaped structures at the level of the lithosphere-asthenosphere boundary. On the contrary, plumes with enhanced density contrast due to a chemical (hydrous) component are shown to be able to pass upwards through the lithospheric mantle to shallow depths near the Moho when (1) the compositional density contrast is ≥ 100 kg m−3 and (2) the width of the lithospheric weakness zone above the plume is ≥ 100 km. An extensional tectonic regime facilitates plume penetration into the lithosphere but is not mandatory. Our findings can explain observations that have long remained enigmatic, such as the “arrow”-shaped zone of low seismic velocities below the Tengchong volcano in south-western China and the columnar (“finger”-shaped) anomaly within the lithospheric mantle discovered more than two decades ago beneath the Eifel volcanic fields in north-western Germany. It appears that a chemical component is a characteristic feature not only of conventional hydrous plumes located over presently downgoing oceanic slabs, but also of upper mantle plumes in other tectonic settings.
    Description: Published
    Description: 117819
    Description: 1T. Struttura della Terra
    Description: JCR Journal
    Keywords: plume-lithosphere interaction ; secondary plumes ; hydrous plumes ; lithosphere rheology ; mantle transition zone ; numerical modelling
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 110
    Publication Date: 2023-02-21
    Description: Continental ultramafic rock systems, through the process of serpentinization, provide chemical and biochemical pathways that lead to the production of methane. The extent to which rock-water-gas reactions and organisms supply methane in these systems is a matter of considerable discussion and debate. Deciphering the interplay of abiotic and microbial methane observed at the surface requires several lines of reasoning as well as a variety of analyses. Despite using multiple models and interpretative tools, conclusions for the origin of methane at a particular site may vary or diverge from regional or global observations. Here, we critically address how possible conclusions of microbial versus abiotic methane in continental serpentinization systems may be interpreted and reinterpreted. We review fundamental concepts, advantages and limits, for three major methane origin models: (a) abiotic CO2 hydrogenation supplying gas reservoirs, (b) derivation from fluid inclusions in olivine-rich rocks, and (c) microbialgenesis in aquifers. We use the case of methane in the Samail ophiolite of Oman as an emblematic example of multiple interpretations; we identify ambiguous information offered by methane clumped isotopes and molecular gas compositions (e.g., the meaning of gaseous hydrocarbons heavier than methane), and suggest key tools, such as radiocarbon (14C) in methane, which may solve interpretative issues. The major constraint in any model of methane origin is the capability to sustain continuous gas flows, in terms of methane emission intensity, longevity and spatial extension, such as in natural gas sedimentary systems. Overall, this review suggests that any site interpretation can benefit from a holistic approach, integrating geochemical, geological and biological data with gas flow dynamics, as well as including regional and global contextualization.
    Description: Published
    Description: 105373
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 111
    Publication Date: 2023-02-21
    Description: Sector-zoned clinopyroxene records kinetic effects imposed by variable degrees of magma undercooling, ΔT, and can be utilised to track the dynamics of magmatic systems. The partitioning of trace elements into sectors grown in different crystallographic orientations can be used as a proxy for ΔT. However, an experimental assessment of the relationship between trace element zoning and ΔT has been lacking to date. Here we present trace element data from a series of undercooling crystallisation experiments on a primitive trachybasalt from Mt. Etna (Italy), at conditions of crustal storage (400 MPa, NNO + 2), and ΔT ranging from 23 to 173 °C. Changes in ΔT were modulated by varying both resting and liquidus temperatures, the latter via the melt-H2O content of the experiments. The resting temperature was retained for 24 h to ensure the attainment of near-equilibrium conditions. High-resolution elemental mapping reveals the distribution of trace elements in individual clinopyroxene zones. Increasing ΔT drives a shift from polyhedral morphologies with Al-rich prism and Al-poor hourglass sectors (ΔT = 23–25 °C), to skeletal (ΔT = 75–123 °C) and dendritic (ΔT = 132–173 °C) crystals with Al-rich skeletons and Al-poor overgrowths. Aluminium-rich zones have higher concentrations of rare earth elements (REE) and high field strength elements (HFSE) than Al-poor zones across all investigated ΔT conditions, and overall, Al, REE and HFSE contents increase with ΔT. This indicates that tetrahedral aluminium (TAl) and associated charge-balancing mechanisms govern the incorporation of REE and HFSE within clinopyroxene. Lattice strain parameters for REE in the M2 site indicate the incorporation of light relative to heavy REE in clinopyroxene is controlled by competing effects between the strain-free partition coefficient, D0, and the optimum cation radius, r0. Critically, the middle and heavy REE switch from incompatible to compatible with increasing ΔT. Used to model fractional crystallisation, our data demonstrate that fractionation of clinopyroxene at low ΔT controls pre-eruptive melt evolution. Importantly, this indicates crystallisation of clinopyroxene in the deep portions of Mt. Etna’s plumbing system is not rapid and is unlikely to result in the early formation of dendrites. We develop a parameterisation of ΔT based on REE partitioning between experimental clinopyroxene and coexisting melt, which can be applied to sector-zoned augite crystallising from mafic alkaline magmas, to reconstruct dynamic processes and thermal pathways during magma transport and storage. Applied to sector-zoned clinopyroxene microphenocrysts and groundmass microcrysts from the 1974 eccentric eruption at Mt. Etna, our parameterisation tracks an increase in ΔT with magma ascent and eruption, following recharge of Cr-rich mafic magma at depth. Sector-zoned clinopyroxene can track ΔT variations leading to volcanism at Mt. Etna and could be applied to quantify magma dynamics in other active volcanoes.
    Description: This work was supported by a Foundation Research Excellence Award from The University of Queensland (UQ-FREA RM2019001828, T.U.), the Advance Queensland Women’s Research Assistance Program from the Queensland Government (WRAP109-2019RD1 RM2020002371, T.U.) and the HP-HT laboratory of Experimental Geophysics and Volcanology (INGV, Rome). A.M. was supported by the Australian Government Research Training Program (RTP). S.M, M.M. and A.P. were supported by the MIUR project “Time scales of solidification in magmas: Applications to Volcanic Eruptions, Silicate Melts, Glasses, Glass- Ceramics” (PRIN 2017J277S9).
    Description: Published
    Description: 249-268
    Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Description: 4V. Processi pre-eruttivi
    Description: JCR Journal
    Keywords: Clinopyroxene ; Sector Zoning ; Trace element partitioning ; Undercooling ; Dendritic crystals ; Rare earth elements ; LA ICP-MS Mapping ; Mt. Etna ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 112
    Publication Date: 2023-02-21
    Description: We compute a high-resolution topographic model of the Moho beneath the fault system activated during the 2016–2017 Central Italy seismic sequence, using Receiver Function (RF) analyses. We document that Ps conversions recorded in RF data-set varies abruptly at very short distance across the crustal lineament called Ancona-Anzio Line (AAL). Moho depth varies from about 25-30 km in the Tyrrhenian domain on the West to 35- 40 km in the Adriatic domain in the East. Where the two domains are juxtaposed along the AAL, Moho depth values cluster around 50 km depth, in a stripe-like area 20 km wide. Such unique feature marks the deformation zone in the lithosphere and testifies the abrupt change in delamination style in the two sectors of the Apennines. Intermittent large normal faulting earthquakes driven by across-belt extension break through such inherited strong structural changes, conditioned by localized barriers to fluids migration and overpressuring.
    Description: Published
    Description: 229237
    Description: 1T. Struttura della Terra
    Description: 4T. Sismicità dell'Italia
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 113
    Publication Date: 2023-02-23
    Description: Trace metals and Rare Earth Element (REE) are amply discharged by submarine hydrothermal vents, sometimes leading to the formation of ore deposits of economic interest. We report on first data on the geochemical processes involving REE and trace metals, at the solid-liquid interface, in the hydrothermal area of Levante Bay at Vulcano Island (Aeolian Archipelago, Italy). Samples were collected from several submarine springs and seeps, a mud pool and one thermal well, and analyzed for Al, Si, Ti, V, Cr, Mn, Fe, Co, As, Rb, Sr, Cs, Ba, U and REE, besides major ions. Within the bay, hydrothermal fluids contaminate seawater and promote the leaching of metals from sediments through the dissolution of CO2 and H2S, while the particulate matter removes several elements from the water. The leaching of the bottom sediments and the contribution of steam-heated water produce an enrichment of some metals and REE in the Levante Bay with respect to the concentrations expected in the ambient seawater. An enrichment up to one order of magnitude is measured for Fe, Al, Ba, Cs and Rb, and up to two orders of magnitude for Mn in the submarine samples. Other transition metals (Ti, V, Co, Cr), U, As and Sr have concentrations similar or slightly lower than the ambient seawater. REE are in concentrations higher than in ambient seawater up to two orders of magnitude. Despite being significantly higher than uncontaminated seawater, the concentrations of some metals (namely Fe, Al, Ti, Cr, V, Co, U) and REE in most samples are lower than expected by the mixing between seawater and the steam-heated water, discharging from submarine springs. Indeed, equilibrium and reaction path modeling indicate the likely precipitation of Fe-oxyhydroxides, able to remove minor elements, such as Ti, Cr, Co, V and As, and REE. The last ones are significantly removed by newly-forming solid phases, due to the presence of a large amount of Fe released by the acidic fluids through the leaching of sediments. The low pH limits the formation of solution complexes of REE with carbonate ions (the main complexing agent for REE in seawater), whereas the sorption onto particles is still effective, even at close distance from the submarine springs and seeps. This study brings new insights on the geochemical processes occurring in submarine hydrothermal systems, in particular, those in subduction-related context.
    Description: Fondo Sociale Europeo (PO FSE 2014-2020)
    Description: Published
    Description: 120756
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Keywords: REE ; Trace metals ; Hydrothermal system ; Seawater ; 03.02. Hydrology ; 03.04. Chemical and biological ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 114
    Publication Date: 2023-02-23
    Description: Hydrogeological resources in the semiarid regions of Mexico support the economy and essential domestic activities of around 17 million people. However, adverse climatic conditions and overexploitation of aquifers affect the quantity and quality of the resource, added to problems of anthropogenic pollution and the salinity of water bodies. The Region Carbonífera aquifer represents the primary hydrogeological system in the most important coal-mining region in Mexico, located in the state of Coahuila. In this work, we present a complete dataset of 157 samples from surface and groundwaters sites have been used to characterizethe physicochemical and isotopic processes responsible for the composition of circulating waters, clarifying their origin, and to evaluate the water quality in terms of human consumption and irrigation use. The aquifer is mostly represented by Ca2+-Mg2+-SO42- and Ca2+-Mg2+-Cl- type waters, that supports salinization problems in 76% of the samples as well as sulfate excess. The origin of this chemical behavior seems to be the result of three main processes: 1) dissolution of soluble salts (gypsum, anhydrite and halite), 2) high surface evaporation under semiarid climate conditions, and 3) ionic and reverse ionic exchange. Processes 1 and 2 are also supported by the enrichment trends in the δ18O and δD signatures. For human consumption, 21% of the samples show high concentrations above the maximum permissible limits of the Official Mexican Standard (NOM-127-SSA1-1994) in total dissolved solids, Cl−, Na+, and SO42−. Additionally, 80% of the waters have some irrigation limitations due to excess sodicity or salinity. The worst quality waters for human or irrigation uses are located south of the aquifer in the municipalities of Juárez and Progreso. This study exhibits the complex hydric situation of the aquifer, raising awareness of the need to seek alternative sources, rational exploitation of resources, the use of crops that better adapt to these semiarid conditions, and intensifying hydrochemical monitoring in the region.
    Description: Published
    Description: 105307
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
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  • 115
    Publication Date: 2023-03-15
    Description: The Environmental Seismic Intensity scale (ESI-07), published 15 years ago under the umbrella of INQUA (In- ternational Union for Quaternary Research), is solely based on earthquake effects on the natural environment. ESI-07 provides complementary information with respect to other macroseismic scales, in particular those stemming from the original Mercalli scale, which are mainly based on effects on manmade structures. We collect information on 157 earthquakes, occurred between 300 AD and 2020, that have been studied using the ESI-07 scale. The ESI-07 epicentral intensity can be assigned based on linear or areal features (e.g., length of surface rupture, area affected by environmental effects); this value is generally in good agreement, or slightly larger, than estimates provided using other macroseismic scales. Higher discrepancies are found for earthquakes with ESI-07 epicentral intensity above X, where other scales tend to saturate, as expected based on the original definition of the Mercalli-family intensity scales. We develop scaling relations among ESI-07 epicentral intensity and moment magnitude, surface rupture length and affected area. After critically evaluating the scientific literature, we argue that the ESI-07 reached its original goals and proved to be particularly useful for the documentation of earthquake damage i) in remote regions, ii) in the case of strong events, where other scales saturate, and iii) in the region closer to the epicenter. Finally, we identify gaps where to focus future efforts, such as the integration of remote sensed datasets in ESI-07 assignment and the refinement of empirical regressions.
    Description: Published
    Description: 107-119
    Description: 6T. Studi di pericolosità sismica e da maremoto
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 116
    Publication Date: 2023-03-15
    Description: Volcanoes are currently to be regarded as natural sources of air pollutants. Climatic and environmental forcing of large volcanic eruptions are well known, although gases emitted through passive degassing during periods of quiescence or hydrothermal activity can also be highly dangerous for the environment and public health. Based on compositional and isotopic data, a survey on the spatial distribution in air of the main volatile compounds of carbon (CO2 and CH4) and sulfur (H2S and SO2) emitted from the fumarolic field of Pisciarelli (Campi Flegrei, Pozzuoli, Naples), a hydrothermal area where degassing activity has visibly increased since 2009, was carried out. The main goals of this study were (i) to evaluate the impact on air quality of these natural manifestations and (ii) inquire into the behavior of the selected chemical species once released in air, and their possible use as tracers to distinguish natural and anthropogenic sources. Keeling plot analysis of CO2 and CH4 isotopes revealed that the hydrothermal area acts as a net source of CO2 in air, whilst CH4 originated mainly from anthropogenic sources. Approaching the urban area, anthropogenic sources of CO2 increased and, at distances greater than 800 m from the Pisciarelli field, they prevailed over the hydrothermal signal. While hydrothermal CO2 simply mixed with that in the atmospheric background, H2S was possibly affected by oxidation processes. Therefore, SO2 measured in the air near the hydrothermal emissions had a secondary origin, i.e. generated by oxidation of hydrothermal H2S. Anthropogenic SO2 was recognized only in the furthest measurement site from Pisciarelli. Finally, in the proximity of a geothermal well, whose drilling was in progress during our field campaign, the H2S concentrations have reached values up to 3 orders of magnitude higher than the urban background, claiming the attention of the local authorities.
    Description: Published
    Description: 4V. Processi pre-eruttivi
    Description: JCR Journal
    Keywords: Air quality; Carbon and sulfur volatile compounds; Carbon isotopes; Hydrothermal systems; Natural sources of pollutants. ; 04.08. Volcanology ; 01.01. Atmosphere
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 117
    Publication Date: 2023-03-15
    Description: The exploitation of a geothermal field can be accompanied by both natural and induced seismicity. Hence the installation of a seismic network suitable for locating also low magnitude earthquakes is of great interest for geothermal development, especially for monitoring the activity related to the injection or production. Here we propose an improvement of the D-OPTIMAL algorithm (Tramelli et al., 2013) that tries and find optimal station positions minimizing the volume of the error ellipsoid of the event location using the D-criterion. In this version, we introduced the possibility to account for several prior information that is generally available when instrumenting a monitoring site permanently or temporarily. The a priori parameters introduced are: i) three-dimensional seismic velocity models, ii) seismic noise levels, iii) topographic gradient, and iv) H/V ratio values. The last three parameters are introduced in the station position 24 selection using aweighting system. We applied the methodology to the Acoculco geothermal field (Mexico) where an injection test was planned and executed in 2021. The comparison between the network defined usingthe standard approach and this updated version shows the importance of introducing a prioriinformation during the selection of the network. Installation sites resulted better distributed on the region, resulting in an overall increase of the sensitivity, and in a decreasing of the error location estimation in the target region. The methodology presented here is easy to apply to other study cases such as active volcanoes, anthropogenic activities, or whatever other study at local scale.
    Description: Published
    Description: 103995
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: JCR Journal
    Keywords: Network optimization ; Geothermal areas ; 04. Solid Earth
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 118
    Publication Date: 2023-03-15
    Description: This study analyses the geological reasons that supported the relocation of the Cavallerizzo village (Calabria, southern Italy) to a new area after the landslide event in 2005 to examine whether the institutional ordinance of displacing the entire village was the right choice. This study is based on new geological and geomorphological field investigations, on a new reading of the existing borehole data and new data collected by multi-temporal synthetic aperture radar interferometry. The results obtained reveal that only the areas bordering the Cavallerizzo village are affected by active landslides, whereas, in the historical centre, geomorphological evidence for an active landslide capable of involving the entire settlement is not found. Nowadays, 17 years after the 2005 landslide event, more than 85% of the Cavallerizzo village is completely intact, lacking evidence of instability or important damage to ancient buildings. Furthermore, in the historical urban area, very low ground displacements by InSAR investigation are observed, highlighting that the instability conditions of Cavallerizzo are less severe than those recognised in nearby villages. This evidence along with the strong negative economic and socio-cultural impacts that the village settlement had on the community involved led to the reconsideration of the adequacy of the relocation ordinance issued by the National Civil Protection. These findings can contribute to useful advice and best practices to state-run organisations and stakeholders for disaster management planning in urban sites, such as Cavallerizzo, subject to hydrogeological hazards.
    Description: This work was supported by the MIUR. Italy-ex 60% Project (Responsibility of Fabio Ietto). Copernicus Sentinel-1 IW SAR data were provided via and processed in ESA’s Geohazards Exploitation Platform (GEP), in the framework of the GEP Early Adopters Programme 2015–2020 and the Geohazards Lab initiative, the latter developed under the CEOS Working Group on Disasters. Data processing was carried out with the Snapping (Surface motioN mAPPING) service developed and integrated by Aristotle University of Thessaloniky in the GEP.
    Description: Published
    Description: 103267
    Description: 2T. Deformazione crostale attiva
    Description: JCR Journal
    Keywords: Geognostic survey ; Landslides ; MT-InSAR ; Village resettlement ; Calabria
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 119
    Publication Date: 2023-03-17
    Description: Spectral analyses of high-resolution records from the upper Eocene-lower Oligocene from the Massignano section, GSSP for the Eocene/Oligocene (E/O) boundary, and the nearby Massicore reveal orbitally controlled fluctuations in the percent concentration of calcium carbonate (wt% CaCO3) and magnetic susceptibility. Extraction of orbital components provides a consistent cyclochronology for the two sites that straddles the E/O boundary. Detection of longer-term modulation in the short eccentricity enabled tuning to the astronomical solution and development of a robust astrochronology for the E/O boundary transition in the GSSP section. Correlation with astrochronologically dated records allowed us to identify the local sedimentary response to the global paleoclimatic and palaeoceanographic events that characterize the greenhouse-icehouse transition during the late Eocene-early Oligocene.
    Description: Published
    Description: 110958
    Description: 4A. Oceanografia e clima
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 120
    Publication Date: 2023-03-22
    Description: Volcanic plume aerosol following the paroxysmal event of Mount Etna (Italy) in February 21st - 26th, 2021 was detected in Naples area (Italy), together with transport of Saharan dust aerosol, combining lidar, sunphotometer and satellite observations with back-trajectories and dispersion models simulations. Lidar data allowed to clearly distinguish the two main aerosol components, to investigate the spectral dependence of the aerosol optical properties and to retrieve their microphysical properties, essential for a detailed aerosol characterization. A new Monte Carlo algorithm, capable of retrieving the particle size distribution from lidar measurements, was applied. Lidar results are in good agreement with columnar integrated sunphotometer data. This combination of novel lidar observations of the vertically-resolved aerosol microphysics, column observations and modelling allows for a more complete description of multi-layered aerosol conditions.
    Description: Published
    Description: 106099
    Description: 5V. Processi eruttivi e post-eruttivi
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 121
    Publication Date: 2023-03-22
    Description: Quantification of the subsurface geothermal potential primarily relies on the assessment of the thermal and mechanical configuration of the lithosphere. Such investigations require a detailed knowledge of the geological and tectonic forcing on the regional thermal, stress and hydraulic regimes and their counter feedback mechanisms. This approach becomes even more relevant in complex and active tectonic settings. In this regard, the Sicily region, which is located in the Central-Western Mediterranean, is an exceptional case study due to its almost unexplored geothermal potential hosted in a complex geodynamic setting. The present-day geological configuration resulted from the collision between the African and European plates, which led to the coexistence of compressional phases, beginning with the Oligocene-Miocene clockwise rotation of Corsica-Sardinia and alternated extensional phases in the Tyrrhenian basin due to the southward progression of the Sicilian- Maghrebian chain towards areas of the internal foreland (Hyblean domain). In this study, we attempt a reconstruction of the present-day lithospheric state of Sicily to quantify its thermal regime at shallow and intermediate depths. We have carried out a 3D lithospheric-scale gravity modelling in order to define the main geological units and their lithology-dependent rock properties, then integrated into a 3D geological model consistent with available borehole and seismic datasets. We have used the constructed geological model with its lithologydependent density, thermal conductivity, and radiogenic heat production to derive the present-day conductive thermal field as a whole and for individual tectonic or geological units, thereby considering different boundary conditions. We have finally validated results of the modelling against a shallow temperature dataset derived from hydrocarbon explorations. Our results indicate that the thermal field at depths shallower than 10 km is largely controlled by variability in sedimentary thickness in the foreland and the orogen, while deeper temperatures are primarily controlled by the distribution of the heat transferred from the mantle together with the radiogenic contribution of the shallow crystalline basement rocks and deeper crustal layers. The thermal modelling portrays a rather heterogenous Moho heat flow, locally higher than 80 mW/m2, revealing a particular geodynamic setting with specific areas characterized by high-to-medium enthalpy geothermal potential. As such, our modelling provides new perspectives for the exploration of geothermal resources in Sicily and helps to better constrain the thermal structure of the complex Sicilian collisional setting.
    Description: Published
    Description: 103976
    Description: 1TR. Georisorse
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 122
    Publication Date: 2023-03-20
    Description: Published in https://www.sciencedirect.com/science/article/pii/S0012821X22004617
    Description: Earthquake forecasting and prediction have long and in some cases sordid histories but recent work has rekindled interest based on advances in early warning, hazard assessment for induced seismicity and successful prediction of laboratory earthquakes. In the lab, frictional stick-slip events provide an analog for earthquakes and the seismic cycle. Labquakes are ideal targets for machine learning (ML) because they can be produced in long sequences under controlled conditions. Recent works show that ML can predict several aspects of labquakes using fault zone acoustic emissions. Here, we generalize these results and explore deep learning (DL) methods for labquake prediction and autoregressive (AR) forecasting. DL improves existing ML methods of labquake prediction. AR methods allow forecasting at future horizons via iterative predictions. We demonstrate that DL models based on Long-Short Term Memory (LSTM) and Convolution Neural Networks predict labquakes under several conditions, and that fault zone stress can be predicted with fidelity, confirming that acoustic energy is a fingerprint of fault zone stress. We predict also time to start of failure (TTsF) and time to the end of Failure (TTeF) for labquakes. Interestingly, TTeF is successfully predicted in all seismic cycles, while the TTsF prediction varies with the amount of preseismic fault creep. We report AR methods to forecast the evolution of fault stress using three sequence modeling frameworks: LSTM, Temporal Convolution Network and Transformer Network. AR forecasting is distinct from existing predictive models, which predict only a target variable at a specific time. The results for forecasting beyond a single seismic cycle are limited but encouraging. Our ML/DL models outperform the state-of-the-art and our autoregressive model represents a novel framework that could enhance current methods of earthquake forecasting.
    Description: Published
    Description: 117825
    Description: 3T. Fisica dei terremoti e Sorgente Sismica
    Description: JCR Journal
    Keywords: Physics - Geophysics; Physics - Geophysics; Computer Science - Computer Vision and Pattern Recognition
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 123
    Publication Date: 2023-03-20
    Description: The footwall of the surface rupturing Paganica normal fault, the source of the 2009 L’Aquila earthquake (Mw 6.1) in the Central Apennines (Italy), was investigated using integrated geological and geomorphological approaches. The aim was to constrain the active tectonics by studying the Raiale River that orthogonally crosscuts the fault trace, where it provides a useful geomorphological marker of long-term fluvial incision and footwall uplift. Using morphostratigraphy and paleomagnetic analysis, the Plio–Pleistocene morphotectonic evolution of the area was reconstructed, comprising an ancient continental basin and paleolandforms that predate the footwall incision. Starting from the Late Early Pleistocene–Middle Pleistocene, fluvial dissection was mainly due to marked river downcutting triggered by significant activity of the Paganica Fault, which caused progressive base-level lowering. The Raiale River downcutting formed five Middle–Late Pleistocene fluvial terraces, that, along with absolute Optically Stimulated Luminescence (OSL) dating, allowed the identification of paleolongitudinal profiles with a diverging downstream configuration. Terrace dating yielded a minimum incision rate of 0.25 ± 0.02 mm/a, which only partially compensates the footwall uplift and can thus be considered as a minimum value for the Paganica Fault throw rate, which could reach up to ~0.45 mm/a. In parallel, using terrestrial cosmogenic nuclides, a denudation rate of 0.02–0.04 mm/a was measured on the summit of the footwall block. This denudation is in keeping with the drainage incision, suggesting a non-steady state for the fault footwall topography and a dominance of relief growth. Last, the analysis of the modern Raiale River longitudinal profile denoted an ungraded status, with two main knickzones that we interpret as transient forms due to tectonic perturbations, likely triggered by activity of the Paganica Fault during the end Early Pleistocene and the Late Pleistocene. Considering the 2009 L’Aquila earthquake coseismic rupture, we observe that the younger transience on the Raiale River longitudinal profile, if it is of tectonic origin, could have only been produced by much larger seismic events (i.e., Mw 〉 6.5) than those documented in the area by paleoseismological investigations. The collective results confirmed that in the Central Apennines, conditions of dynamic equilibrium are often not met, and that the persistence of transient perturbations induced by tectonics should be accounted for.
    Description: The work was financially supported by the MIUR (Italian Ministry of Education, University and Research) project “FIRB Abruzzo - High-resolution analyses for assessing the seismic hazard and risk of the areas affected by the 6 April 2009 earthquake”, ref. RBAP10ZC8K_005 and RBAP10ZC8K_007, and by Agreement INGV-DPC 2012-2021. The airborne LiDAR survey performedby the Civil Protection of Friuli Venezia Giulia (Italy) was kindly released by Italian Civil Protection Department Special thanks to Simone Atzori, who provided the InSAR data.
    Description: Published
    Description: 108411
    Description: 2T. Deformazione crostale attiva
    Description: JCR Journal
    Keywords: Earthquake geology ; Active faults ; L'Aquila earthquake ; Morphotectonics ; active faulting
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 124
    Publication Date: 2023-03-20
    Description: In seismically active regions with variable dominant focal mechanisms, there is considerable tsunami inundation height uncertainty. Basic earthquake source parameters such as dip, strike, and rake affect significantly the tsunamigenic potential and the tsunami directivity. Tsunami inundation is also sensitive to other properties such as bottom friction. Despite their importance, sensitivity to these basic parameters is surprisingly sparsely studied in literature. We perform suites of systematic parameter searches to investigate the sensitivity of inundation at the towns of Catania and Siracusa on Sicily to changes both in the earthquake source parameters and the Manning friction. The inundation is modelled using the Tsunami-HySEA shallow water code on a system of nested topo-bathymetric grids with a finest spatial resolution of 10 m. This GPU-based model, with significant HPC resources, allows us to perform large numbers of high- resolution tsunami simulations. We analyze the variability of different hydrodynamic parameters due to large earthquakes with uniform slip at different locations, focal depth, and different source parameters. We consider sources both near the coastline, in which significant near-shore co-seismic deformation occurs, and offshore, where near- shore co-seismic deformation is negligible. For distant offshore earthquake sources, we see systematic and intuitive changes in the inundation with changes in strike, dip, rake, and depth. For near-shore sources, the dependency is far more complicated and co- determined by both the source mechanisms and the coastal morphology. The sensitivity studies provide directions on how to resolve the source discretization to optimize the number of sources in Probabilistic Tsunami Hazard Analysis, and they demonstrate a need for a far finer discretization of local sources than for more distant sources. For a small number of earthquake sources, we study systematically the inundation as a function of the Manning coefficient. The sensitivity of the inundation to this parameter varies greatly for different earthquake sources and topo-bathymetry at the coastline of interest. The friction greatly affects the velocities and momentum flux and to a lesser but still significant extent the inundation distance from the coastline. An understanding of all these dependencies is needed to better quantify the hazard when source complexity increases.
    Description: Published
    Description: 757618
    Description: 6T. Studi di pericolosità sismica e da maremoto
    Description: 8T. Sismologia in tempo reale e Early Warning Sismico e da Tsunami
    Description: 1SR TERREMOTI - Sorveglianza Sismica e Allerta Tsunami
    Description: 3IT. Calcolo scientifico
    Description: JCR Journal
    Keywords: tsunami ; inundation ; HPC ; earthquakes ; numerical simulations
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 125
    Publication Date: 2023-03-20
    Description: The present investigation provides measurements of radon (222Rn) concentration levels in 20 thermal waters at the Campi Flegrei volcanic caldera, an important geothermal system with hydrothermal manifestations in the Neapolitan area (Southern Italy). We used a RAD7® Radon-in-air detector equipped with Big Bottle RAD H2O and DRYSTIK accessories (Durridge Co. Inc.). Water samples with different chemical and/or physical conditions, not used as drink waters, are taken from continental thermal groundwaters, springs, lakes, pools and one sub merged thermal spring. The waters are mostly chlorine to bicarbonate, except of a few sulphate types sampled at the hydrothermal discharge areas of Solfatara and Pisciarelli, central in the caldera. Water temperature and pH values range from 18.1 to 91.3 ◦C and from 2 to 8, respectively. Sampling and measurement of radon in groundwater are complicated by the high volatility of the gas; a method is here proposed. In some of the 20 sites double or triple samples were collected by using different volume polyethylene terephthalate (PET) bottles, diluting sample with blank water, and modifying flow of pumped wells. We suggest that dilution can be considered when water is i) not enough to fill in the PET, resulting in large head space in the sampler, ii) too hot determining damage of the PET or iii) too saline to clog the Big Bottle System. Dissolved radon concentrations vary from 0.1 ± 0.1 to 1146 ± 57 Bq/L with an average value of 152 Bq/L, using the CAPTURE program, the default RAD7 data acquisition program. Similar values in radon concentration are obtained using the method proposed in De Simone et al. (2015) ranging between 0.1 ± 5.8 and 1286 ± 98 Bq/L with an average value of 167 Bq/L. The hottest and most acidic sulphate waters refer to a small boiling pool at Pisciarelli hydrothermal discharge area and have nearly zero 222Rn content. 222Rn concentrations from this study are mostly below the reference level of 1000 Bq/L recommended for human health protection by the European Commission and the most adopted in the scientific community (Catao ˜et al., 2022). No correlation has been observed between temperature, pH, major anions and radon content values, nor between rock composition since it is almost homogeneous trachyte at the study sites. 222Rn levels therefore appear to reflect the local sedimentological, structural or hydrogeological conditions. The levels of 222Rn here presented are an important background for the scientific community that will intend to define the natural fluctuations of dissolved 222Rn in relation with seasons, environment, hydrogeology or volcanic dynamics at the geohazardous Campi Flegrei area.
    Description: Published
    Description: 107641
    Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Description: 6V. Pericolosità vulcanica e contributi alla stima del rischio
    Description: 6SR VULCANI – Servizi e ricerca per la società
    Description: JCR Journal
    Keywords: 222Rn ; Campi Flegrei ; RAD7 ; Big Bottle RAD H2O ; DRYSTIK ; Dissolved radon
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 126
    Publication Date: 2023-03-20
    Description: The δ18O and δ2H of rivers and springs were investigated in order to characterize the groundwater recharge sources around Nyiragongo and Nyamulagira volcanoes, in the Democratic Republic of the Congo and Rwanda. Water samples were collected monthly between November 2013 and October 2014 from 5 major rivers, 3 major cold springs, 3 tepid springs and 1 hot spring. The temperatures of each spring were nearly constant over the sampling period attesting for their groundwater character, while the temperatures of the rivers were much more variable. The rivers monthly δ2H and δ18O range from 􀀀 6.8‰ to 1.9‰ and 􀀀 3.1‰ to 1.6‰, respectively, while springs showed depleted values that span from 􀀀 10.2 to 􀀀 1.1‰ for δ2H and 􀀀 3.6 to 􀀀 1.9‰ for δ18O. Catchment morphology (formed of depression, upper footslope and medium to high gradient-mountains) and the local tectonic discontinuity (fissures and faults) regulate the surface runoff and subsurface flow, control the precipitation infiltration zones and hence the aquifers recharge areas. Chemical and isotopic (δ18O and δ2H) compositions of springs and rivers reveal the presence of shallow and deep aquifers, with some waters having intermediate isotope composition. Three different recharge zones characterized by different altitudes were identified: the first is found at low altitude ranging from ~1800 m to ~2150 m, the second and intermediate recharge zone in the altitude range from ~2180 m to ~2500 m at the upper footslope area, while the third and highest recharge area is located in the altitudes range from ~2620 to ~3220 m. The two upper recharge areas are the most fractured and fissured zones allowing rapid infiltration of depleted precipitations which recharge deep aquifers found in the tepid and hot springs. Based on their chemical and isotopic composition, waters from the shallow and deep aquifers have been considered representative of mixing end members. During their ascent to the surface, water from the deep aquifer mixes with that of shallow aquifer yielding the tepid springs of intermediate chemical and isotopic composition, while the other keep their original fingerprint corresponding to the isotopically depleted hot spring.
    Description: Published
    Description: 120778
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
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  • 127
    Publication Date: 2023-03-20
    Description: Implicit integration of the viscous term can significantly improve performance in computational fluid dynamics for highly viscous fluids such as lava. We show improvements over our previous proposal for semi-implicit viscous integration in Smoothed Particle Hydrodynamics, extending it to support a wider range of boundary models. Due to the resulting loss of matrix symmetry, a key advancement is a more robust version of the biconjugate gradient stabilized method to solve the linear systems, that is also better suited for parallelization in both shared-memory and distributed-memory systems. The advantages of the new solver are demostrated in applications with both Newtonian and non-Newtonian fluids, covering both the numerical aspect (improved convergence thanks to the possibility to use more accurate boundary model) and the computing aspect (with excellent strong scaling and satisfactory weak scaling).
    Description: Published
    Description: 111413
    Description: 3IT. Calcolo scientifico
    Description: JCR Journal
    Keywords: SPH ; Low Reynods number ; Implicit integration ; BiCGSTAB ; GPU ; 05.01. Computational geophysics
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  • 128
    Publication Date: 2023-03-20
    Description: The evolution of High-Performance Computing (HPC) platforms enables the design and execution of progressively larger and more complex workflow applications in these systems. The complexity comes not only from the number of elements that compose the workflows but also from the type of computations they perform. While traditional HPC workflows target simulations and modelling of physical phenomena, current needs require in addition data analytics (DA) and artificial intelligence (AI) tasks. However, the development of these workflows is hampered by the lack of proper programming models and environments that support the integration of HPC, DA, and AI, as well as the lack of tools to easily deploy and execute the workflows in HPC systems. To progress in this direction, this paper presents use cases where complex workflows are required and investigates the main issues to be addressed for the HPC/DA/AI convergence. Based on this study, the paper identifies the challenges of a new workflow platform to manage complex workflows. Finally, it proposes a development approach for such a workflow platform addressing these challenges in two directions: first, by defining a software stack that provides the functionalities to manage these complex workflows; and second, by proposing the HPC Workflow as a Service (HPCWaaS) paradigm, which leverages the software stack to facilitate the reusability of complex workflows in federated HPC infrastructures. Proposals presented in this work are subject to study and development as part of the EuroHPC eFlows4HPC project.
    Description: Published
    Description: 414-429
    Description: 6T. Studi di pericolosità sismica e da maremoto
    Description: 8T. Sismologia in tempo reale e Early Warning Sismico e da Tsunami
    Description: 4V. Processi pre-eruttivi
    Description: 6V. Pericolosità vulcanica e contributi alla stima del rischio
    Description: 3IT. Calcolo scientifico
    Description: JCR Journal
    Keywords: High performance computing ; Distributed computing ; Parallel programming ; HPC-DA-AI convergence ; Workflow development ; Workflow orchestration
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 129
    Publication Date: 2023-03-23
    Description: Aquaculture represents an important source of food and it plays an important role in terms of contribution to economic development. Offshore farming offers considerable advantages, especially in terms of production costs (lower than those of onshore facilities) and of farmed product quality. Suitable areas for aquaculture activities are still available in Italy but are increasingly limited and the demand for new farms is high. The lack of coastal areas allocated to aquaculture and the complex regulatory and legal framework constitutes the major constraints for further development of the sector. Zoning is the process that can allow to sustainably identify and allocate suitable areas for aquaculture. Several aspects, such as effective legal framework and procedures, collection of bio-geochemical, physical and socio-economical information, are crucial for a correct aquaculture zoning process in order to identify the Allocated Zones for Aquaculture (AZAs). In the present work, a spatial multi-criteria decision analysis (SMCDA) was applied for the individuation of potentially suitable marine areas for fish farming across the southern Tyrrhenian coast of Tuscany (Italy). The spatial model was developed by collecting and processing Earth Observation (EO) data, oceanography in situ measurements, and infrastructural and environmental constraints. Excluding areas of constrains, obtained results highlight that 96% of the total investigated area is characterised by medium (62%) and high (34%) suitability. In particular, the highest suitability areas occur in the Talamone gulf and offhore the Argentario promontory at water depth between 15-30 m and 30 50m, respectively. Other high suitability areas occur northern of Piombino town between 30-100 m depth. Environmental data at higher spatial resolution are needed to improve aquaculture zoning and further process of site selection in order to ensure the sustainability of fish farming in the study area.
    Description: Published
    Description: 106261
    Description: 3A. Geofisica marina e osservazioni multiparametriche a fondo mare
    Description: JCR Journal
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  • 130
    Publication Date: 2023-01-16
    Description: The uptake ability toward arsenic(V), chromium(VI), and boron(III) ions of ad hoc functionalized magnetic nanostructured devices has been investigated. To this purpose, ligands based on meglumine have been synthesized and used to coat magnetite nanoparticles (Fe3O4) obtained by the co-precipitation methodology. The as-prepared hybrid material was characterized by infrared spectroscopy (IR), X-ray diffraction, thermogravimetric analysis, and scanning electron microscopy combined with energy-dispersive X-ray analysis. Moreover, its magnetic hysteresis properties were measured to evaluate its magnetic properties, and the adsorption kinetics and isothermal models were applied to discern between the different adsorption phenomena. Specifically, the better fitting was observed by the Langmuir isotherm model for all metal ions tested, highlighting a higher uptake in arsenic (28.2 mg/g), chromium (12.3 mg/g), and boron (23.7 mg/g) sorption values if compared with other magnetic nanostructured materials. After adsorption, an external magnetic stimulus can be used to efficiently remove nanomaterials from the water. Finally the nanomaterial can be reused up to five cycles and regenerated for another three cycles.
    Description: Published
    Description: 10775–10788
    Description: 1A. Geomagnetismo e Paleomagnetismo
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 131
    Publication Date: 2023-01-16
    Description: Open-vent volcanic activity is typically sustained by ascent and degassing of shallow magma, in which the rate of magma supply to the upper feeding system largely exceeds the rate of magma eruption. Such unbalance between supplied (input) and erupted (output) magma rates is thought to result from steady, degassing-driven, convective magma overturning in a shallow conduit/feeding dyke. Here, we characterize shallow magma circulation at Stromboli volcano by combining independent observations of heat (Volcanic Radiative Power; via satellite images) and gas (SO2 , via UV camera) output in a temporal interval (from August 1, 2018 to April 30, 2020) encompassing the summer 2019 effusive eruption and two paroxysmal explosions (on July 3 and August 28, 2019). We show that, during the phase of ordinary strombolian explosive activity that preceded the 2019 effusive eruption, the average magma input rate (0.1-0.2 m3 /s) exceeds the magma eruption rate (0.001-0.01 m3 /s) by ∼2 orders of magnitude. Conversely, magma input and output rates converge to an average of ∼0.4 m3 /s during the summer 2019 summit effusion, implying an overall suppression of magma recycling back into the feeding system, and hence of excess degassing. We find that, during the effusive eruption, the peak in SO2 emissions lags behind the thermal emission peak by ∼27 days, suggesting that magma output, feeding the lava flow field, initially dominates over magma input in the conduit. We propose that this conduit mass unloading, produced by this initial phase of the effusive eruption, leads to an overall decompression (of up to 30 Pa/s) of the shallow plumbing system, ultimately causing ascent of less-dense, volatile-rich magma batch(es) from depth, enhanced explosive activity, and elevated SO2 fluxes culminating into a paroxysmal explosion on August 28. Our results demonstrate that combined analysis of thermal and SO2 flux time-series paves the way to improved understanding of shallow magmatic system dynamics at open-vent volcanoes, and of the transition from explosive to effusive activity regimes.
    Description: Published
    Description: 117726
    Description: 5V. Processi eruttivi e post-eruttivi
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 132
    Publication Date: 2023-01-16
    Description: The geodetic dataset used in the research article entitled "Multi-technique geodetic detection of onshore and offshore subsidence along the Upper Adriatic Sea coasts"[1] is presented here. It consists of the outcomes of three different techniques, i.e. Synthetic Aperture Radar Interferometry (InSAR), Global Navigation Satellite System (GNSS) and topographic Levelling surveys. This dataset has been used for the estimation of onshore and offshore deformation in a mineral concession area located along the Upper Adriatic Sea coastal area (Italy), South-East of Ravenna city. InSAR data covers the period from 2002 to 2018, GNSS data from 1998 to 2018 and levelling data from 2002 to 2017.The different measurements have been cross-validated and referred to a common local reference system fixed in the urban area of Ravenna. This data collection will be very useful for deepening the analysis of any type of deformation in the Ravenna coastal area.
    Description: Published
    Description: 108342
    Description: 5IT. Osservazioni satellitari
    Description: JCR Journal
    Keywords: GNSS; Geodetic data; Levelling; Ravenna coastal area; Remote sensing; SAR Interferometry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 133
    Publication Date: 2023-01-16
    Description: In the middle of the Mediterranean, the partly still active Apennines subduction system has been usually defined using tomographic images and available shear wave splitting measurements. In this paper we describe the new seismic anisotropy dataset for Central Italy, the region where the transition between Northern and Southern Apennines occurs. The new measurements show NW-SE fast polarisation directions beneath the belt, due to the retreat of the slab, NNE-SSW orientations from proper Adriatic mantle sources, and E-W directed anisotropy, attributed to mantle convection flow at the Thyrranian side. Additionally, the new data suggest the presence of a toroidal mantle flow through a tear in the Apenninic slab, from the Adria to the Tyrrhenian side. However, mantle circulation and flows, identified by the pattern of shear wave splitting results, seem different from what was proposed in previous geodynamic models. Indeed, our results support the presence of a vertical slab tear with limited dimension. In the geodynamic model we propose, the tear acts to accommodate a differential slab retreat. The slab partitioning results in a different pattern and strength of seismic anisotropy traced from the Central Apennines with respect to the adjacent Northern and Southern Apennines.
    Description: Published
    Description: 229549
    Description: 1T. Struttura della Terra
    Description: JCR Journal
    Keywords: Seismic anisotropy Mantle flows Geodynamic model Apennines Central Mediterranean ; seismic anisotropy
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 134
    Publication Date: 2023-01-13
    Description: We demonstrate a synchronous correlation technique to determine the chronology of Quaternary palaeoshorelines to test proposed relationships between tectonics, climate and sea-level change. The elevations of marine palaeoshorelines in Calabria around the active Vibo normal fault have been measured from TIN DEM 10 m data and fieldwork and correlated with global sea-level curves. A synchronous correlation method and new U/Th dates are used to ascertain how the slip-rate on the fault relates to uplift rates across the region. Regional uplift, possibly associated with subduction along the Calabrian trench or due to the cumulative effect of closely-spaced active normal faults, is rapid enough to uplift even the hangingwall of the Vibo normal fault; the actual value for the rate of background uplift can only be ascertained once the rate of slip on the Vibo fault is subtracted. Synchronous correlation of multiple palaeoshorelines sampled along 29 elevation profiles with global sea-levels shows that the resultant uplift rate (background uplift minus local hangingwall subsidence) is constant through time from 0 to 340 ka, and not fluctuating by a factor of 4 as previously suggested. The uplift rate increases from 0.4 mm/yr at the centre of the hangingwall of the fault to 1.75 mm/yr in the hangingwall in the vicinity of the fault tip. Palaeoshorelines can be traced from the hangingwall to the footwall around the fault tip and hence correlated across the fault. The throw-rate on the fault averaged over 340 ka decreases from a maximum at the centre of the fault (1 mm/yr) to zero at the tip. This gradient in throw-rate explains the spatial variation in resultant uplift rates along the fault. We interpret the 1.75 mm/yr resultant uplift rate at and beyond the fault tip as the signature of a regional uplift, presumably related to subduction, although we cannot exclude the possibility that other local faults influence this uplift; the lower uplift rates in the hangingwall of the fault are due to interaction between “regional” uplift and subsidence associated with the local active normal faulting. We discuss (a) how our synchronous correlation technique should trigger a re-appraisal of palaeoshoreline chronologies worldwide, and (b) the implications for the tectonics and seismic hazard of Calabria, suggesting that perturbations in the uplift-rate field are a key criterion to map the locations of active faults, their deformation rates, and hence seismic hazard above subduction zones.
    Description: Published
    Description: 169-187
    Description: 2T. Deformazione crostale attiva
    Description: JCR Journal
    Keywords: Active faults; Palaeoshorelines; Quaternary sea-level; Tectonics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 135
    Publication Date: 2023-01-13
    Description: The Cotentin Peninsula (Normandy, France) displays sequences of marine terraces and rasas, the latter being wide Late Cenozoic coastal erosion surfaces, that are typical of Western European coasts in Portugal, Spain, France and southern England. Remote sensing imagery and field mapping enabled reappraisal of the Cotentin coastal sequences. From bottom to top, the N Cotentin sequence includes four previously recognized Pleistocene marine terraces (T1 to T4) at elevations 〈 40 m as well as four higher and older rasas (R1 to R4) reaching 200 ± 5 m in elevation. Low-standing marine terraces are not observed in the central part of the Peninsula and a limited number of terraces are described to the south. The high-standing rasas are widespread all over the peninsula. Such strandline distributions reveal major changes during the Late Cenozoic. Progressive uplift of an irregular sea-floor led to subaerial exposure of bathymetric highs that were carved into rocky platforms, rasas and marine terraces. Eventually, five main islands coalesced and connected to the mainland to the south to form the Cotentin Peninsula. On the basis of previous dating of the last interglacial maximum terrace (i.e. Marine Isotopic Stage, MIS 5e), sequential morphostratigraphy and modelling, we have reappraised uplift rates and derived: (i) mean Upper Pleistocene (i.e. since MIS 5e ~ 122 +/− 6 ka, i.e. kilo annum) apparent uplift rates of 0.04 ± 0.01 mm/yr, (ii) mean Middle Pleistocene eustasy-corrected uplift rates of 0.09 ± 0.03 mm/yr, and (iii) low mean Pleistocene uplift rates of 0.01 mm/yr. Extrapolations of these slow rates combined with geological evidence implies that the formation of the sequences from the Cotentin Peninsula occurred between 3 Ma (Pliocene) and 15 Ma (Miocene), which cannot be narrowed down further without additional research. Along the coasts of Western Europe, sequences of marine terraces and rasas are widespread (169 preserve the MIS 5e benchmark). In Spain, Portugal, S England and other parts of western France, the sequences morphostratigraphy is very similar to that of Cotentin. The onset of such Western European sequences occurred during the Miocene (e.g. Spain) or Pliocene (e.g. Portugal). We interpret this Neogene-Quaternary coastal uplift as a symptom of the increasing lithospheric compression that accompanies Cenozoic orogenies.
    Description: Published
    Description: 338-356
    Description: 2T. Deformazione crostale attiva
    Description: JCR Journal
    Keywords: Cotentin and Western Europe; Marine terrace; Neogene and Quaternary coastal uplift; Rasa
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 136
    Publication Date: 2023-01-18
    Description: This work describes the development of an underwater anti-intrusion system based on a magnetometer self-informed network, whose purpose is to detect the presence of threats in the proximity of critical infrastructures (e.g, terrorist divers in harbours). In this context, the magnetic network fills the gaps of sonar systems at the critical boundaries of the water volume to be controlled (sea bed, docks, …), where acoustic performances deteriorate due to reflections and attenuations. The system operates in a port-protection scenario, characterized by a medium-high environmental magnetic noise that can hide the diver signal (a diver is a weak, quasi-point-like, moving source). The magnetometer network processes two inputs: the environmental magnetic noise and a signal including the target magnetic signal superimposed to the same noise; the frequencies of a diver signal lie within the noise band, hence frequency filtering proves inadequate for noise removal. The basic idea underlying the system is to measure and use the noise itself to filter the overall signal; measuring noise supports a background-subtraction process that allows to extract the target signal and therefore detect the threat presence. The effectiveness of the procedure depends on the positions of magnetometers: sensors must be close enough to one another to measure the common background noise, and, at the same time, should be distant enough from one another so that just one sensor can measure the target signal. To generate alarms when a threat is detected, a real-time software application processes data and activates a visual and acoustic alarm upon identification of a magnetic anomaly. Sea trials carried out in port areas provided extremely satisfactory results in the detection of intruders. The paper presents experimental results obtained during the method validation tests, when intruders were moving in the surrounding undersea environment.
    Description: Published
    Description: 104743
    Description: 1A. Geomagnetismo e Paleomagnetismo
    Description: 3A. Geofisica marina e osservazioni multiparametriche a fondo mare
    Description: 7SR AMBIENTE – Servizi e ricerca per la società
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 137
    Publication Date: 2023-01-18
    Description: The structure of a caldera may influence its activity, making its understanding crucial for hazard assessment. Here, we analysed high-resolution seismic profiles in the Campi Flegrei (southern Italy) offshore sector. We recognised two main fault systems, including those associated with the formation of the caldera and those affecting the resurgent dome. The former system comprises three broadly concentric fault zones (inner, medial and outer ring fault zones) depicting a nested caldera geometry. Considering the relations between faults and seismic units that represent the marine and volcaniclastic successions filling the caldera, all ring faults were formed during the Campanian Ignimbrite eruption (40 ka) and subsequently reactivated during the Neapolitan Yellow Tuff eruption (15 ka). In this last caldera-forming event, the inner and medial fault zones accommodated most of the collapse and were episodically reactivated during the younger volcano-tectonic activity. The second fault system occurs in the apical zone of the resurgent dome and comprises dominantly high-angle normal faults that are mainly related to the volcanotectonic collapse that followed the Agnano-Monte Spina Plinian eruption (4.55 ka). Finally, we provide a volcano-tectonic evolutionary model of the last 40 kyr, considering the interplay among ring and dome faults activity, volcaniclastic sedimentation, ground deformation and sea-level changes.
    Description: Published
    Description: 104723
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 138
    Publication Date: 2023-02-01
    Description: This work deals with a comprehensive multiparametric and multilayer approach to study earthquake-related processes that occur during the preparation phase of a large earthquake. As a case study, the paper investigates the M7.2 Kermadec Islands (New Zealand) large earthquake that occurred on June 15, 2019 as the result of shallow reverse faulting within the Tonga-Kermadec subduction zone. The analyses focused on seismic (earthquake catalogs), atmospheric (climatological archives) and ionospheric data from ground to space (mainly satellite) in order to disclose the possible Lithosphere-Atmosphere-Ionosphere Coupling (LAIC). The ionospheric investigations analysed and compared the Global Navigation Satellite System (GNSS) receiver network with insitu observations from space thanks to both the European Space Agency (ESA) Swarm constellation and the China National Space Administration (CNSA in partnership with Italian Space Agency, ASI) satellite dedicated to search for possible ionospheric disturbances before medium-large earthquakes, i.e. the China Seismo-Electromagnetic Satellite (CSES-01). An interesting comparison is made with another subsequent earthquake with comparable magnitude (M7.1) that occurred in Ridgecrest, California (USA) on 6 July of the same year but in a different tectonic context. Both earthquakes showed anomalies in several parameters (e.g. aerosol, skin temperature and some ionospheric quantities) that appeared at almost the same times before each earthquake occurrence, evidencing a chain of processes that collectively point to the moment of the corresponding mainshock. In both cases, it is demonstrated that a comprehensive multiparametric and multilayer analysis is fundamental to better understand the LAIC in the occasion of complex phenomena such as earthquakes.
    Description: Published
    Description: 113325
    Description: 7T. Variazioni delle caratteristiche crostali e "precursori"
    Description: 1A. Geomagnetismo e Paleomagnetismo
    Description: 2A. Fisica dell'alta atmosfera
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 139
    Publication Date: 2023-02-01
    Description: In this work, we document two distinct tsunami deposits on the coasts of Ios Island, Aegean Sea, Greece. The younger tsunami deposit, dated 1831–1368 cal. BCE, includes both marine sediments and pumices from the ∼1600 BCE Minoan eruption of Santorini volcano. This is the first evidence of the Minoan tsunami in the Cycladic Islands North of Santorini. Tsunami waves inundated the Manganari coastal plain, southern coast of Ios, over a distance 〉200 m (〉2 m a.s.l.). The second tsunami deposit reworks pumice from the 22 ka Cape Riva eruption mixed with marine sediment. We assume a Neolithic age for this major tsunami, with a wave runup 〉13 m a.s.l. on the southern and eastern coasts of Ios. The source of this tsunami - volcanic eruption, landslide, or earthquake - remains unknown. Additionally, we provide the first on-land evidence of Cape Riva deposits outside Santorini, thus questioning previous estimates on the magnitude of this eruption.
    Description: Published
    Description: 106908
    Description: 6T. Studi di pericolosità sismica e da maremoto
    Description: JCR Journal
    Keywords: tsunami deposits ; Aegean Sea ; 04.04. Geology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 140
    Publication Date: 2023-02-01
    Description: The mechanism governing the kinetic growth of olivine in dynamic volcanic settings has been the subject of considerable attention in recent years. Under variable cooling rate (CR) and undercooling (􀀀 ΔT) regimes, the textual maturation of olivine proceeds from skeletal/dendritic crystals to polyhedral morphologies by infilling of the crystal framework. Owing to the establishment of a diffusion-controlled growth regime, a sharp diffusive boundary layer develops in the melt next to the advancing olivine surface. In this context, we have quantified the apparent partitioning of Ti, Al, P, and Cr between olivine and a Hawaiian tholeiitic basaltic melt at P = 1 atm, fO2 = QFM-2 buffer, and CR = 4, 20, and 60 ◦C/h over a constant -ΔT = 85 ◦C. Differences in charge and/or size between the substituent minor cations and the major species in the olivine crystallographic site dominate the energetics of homovalent and heterovalent cation substitutions. While the entry of Ti in the olivine lattice site accounts for the simple exchange [TSi4+] ↔ [TTi4+], more complex charge-balancing coupled-substitution mechanisms have been determined for the incorporation of Al, P, and Cr, i.e., [MMg2+, TSi4+] ↔ [MAl3+, TAl3+], [2 TSi4+] ↔ [TP5+, TAl3+], and [MMg2+, TSi4+] ↔ [MCr3+, TAl3+], respectively. In order to maintain charge balance, the disequilibrium uptake of minor cations in rapidly growing crystals is controlled by the same substitution mechanisms observed under equilibrium crystallization. This finding is consistent with the achievement of a local interface equilibrium at the olivine-melt interface independently of the diffusive boundary in the melt. A statistical approach based on multivariate analysis of olivine/melt compositional parameters confirms that the control of melt structure on the partitioning of Ti, Al, P, and Cr is almost entirely embodied in the olivine structure and chemistry via charge compensation reactions. Therefore, the magnitude of minor element partition coefficients is weakly dependent on diffusion kinetics in the melt but rather strongly governed by olivine zoning patterns resulting from fast crystal growth rates.
    Description: Published
    Description: 120870
    Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 141
    Publication Date: 2023-02-01
    Description: The gradual temporal shift of the spectral lines of harmonic seismic and/or acoustic tremor, known as spectral gliding, has been largely documented at different volcanoes worldwide. Despite the clear advantage of the experimental approach in providing direct observation of degassing processes and related elastic radiation, experimental studies on gliding tremor are lacking. Therefore, we investigated different episodes of gliding of acoustic and seismic tremor observed during analogue degassing experiments performed under different conditions of magma viscosity (10-1,000 Pa s), gas flux (5-180×10−3 l/s) and conduit surface roughness (fractal dimension of 2-2.99). Gliding experimental harmonic seismic and acoustic tremor was observed at high gas flux rates and viscosities, mostly associated with an increasing trend and often preceding a major burst. Decreasing secondary sets of harmonic spectral lines were observed in a few cases. Results suggest that gliding episodes are mostly related to the progressive volume variation of shallow interconnected gas pockets. Spectral analyses performed on acoustic signals provided the theoretical length of the resonator that was compared against the temporal evolution of the gas pockets, quantified from video analyses. The similarities between the observed degassing regime and churn-annular flow in high viscous fluids encourage further studies on churn dynamics in volcanic environments.
    Description: Published
    Description: 117344
    Description: 5V. Processi eruttivi e post-eruttivi
    Description: JCR Journal
    Keywords: seismo-acoustic tremor; experimental volcanology ; 04.06. Seismology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 142
    Publication Date: 2023-02-01
    Description: We report on the characterization of a thick sequence of pyroclastic deposits exposed on the summit area and flanks of Mount Melbourne volcano, in northern Victoria Land, Antarctica related to eruptions during the Late Glacial period. We provide a complete characterization of tephra deposits including mineralogy, single shard major- and trace-element glass compositions, and an 40Ar-39Ar age of feldspar crystals extracted from the deposit. The pyroclastic deposits are trachybasaltic to trachytic in composition and are interpreted to have resulted from four Strombolian/Vulcanian to sub-Plinian/Plinian eruptions. The younger and more intense sub-Plinian/Plinian eruption (our eruption 2) yielded an 40Ar-39Ar age of 13.5 ± 4.3 ka (±2σ). The study of Mount Melbourne proximal deposits provides significant new data for the reconstruction of the volcano eruptive history and a better assessment of the volcanic risk connected to a possible future eruption. We also explore geochemical correlations between Mount Melbourne proximal deposits and distal tephra layers recognized in ice cores and blue ice fields of East Antarctica. A good geochemical match exists between the composition of products from the trachytic sub-Plinian/Plinian eruption 2 and some tephra layers from Talos Dome and shards in Siple Dome which is also compatible in age (c. 9.3 ka) with our 40Ar-39Ar age determination. Our new insights into the volcanic history of Mount Melbourne and the new high-quality electron microprobe and trace element composition data on its proximal products will help improve future correlations and synchronization of tephra archives in the region.
    Description: Published
    Description: 107457
    Description: 1V. Storia eruttiva
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 143
    Publication Date: 2023-03-08
    Description: © The Author(s), 2022. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Samuel, B., & Danny, H. MineralMate: a standalone MATLAB-based aide for the magnetic separation of minerals. Heliyon, 8(9), (2022): e10411, https://doi.org/10.1016/j.heliyon.2022.e10411.
    Description: MineralMate is a standalone MATLAB-based program designed to optimize the workflow associated with the magnetic separation of minerals. For nearly every bulk geochemical analysis some amount of mineral separation must occur, and the use of an electromagnetic separator is ubiquitous and considered as standard practice in many fields. Despite the commonality in which magnetic separation is used, there are considerable shortcomings. Electromagnet overheating and composite mineral grains are frequently encountered, as well as poorly constrained mineral behavior. These complications ultimately reduce the quality of downstream geochemical data. MineralMate is designed to alleviate these shortcomings by quickly and efficiently producing a magnetic separation workflow allowing the user to: (1) identify and compare optimal recovery ranges for different minerals from a bulk mineral assemblage, (2) identify the parameters on a conventional magnetic separator required to magnetically separate composite grains, (3) create/update user-specific magnetic susceptibility databases through empirical data collection, and (4) utilize an alternative magnetic separation equation.
    Description: This research did not receive any specific grant from funding agencies in the public, commercial, or not-for-profit sectors.
    Keywords: Frantz ; Geochemistry ; Geochronology ; MATLAB ; Magnetic separation ; Mineral separation
    Repository Name: Woods Hole Open Access Server
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  • 144
    Publication Date: 2023-03-10
    Description: The global climate has been gradually cooling over the Cenozoic and is punctuated by the intensification of Northern Hemisphere Glaciation (NHG) from the latest Pliocene to earliest Pleistocene (∼3.1–2.5 millions of years ago, Ma). A decline of atmospheric CO2 is supposed as a prerequisite for the NHG, but the associated carbon-cycle processes remain elusive. Here we combine foraminiferal records of neodymium isotope and boron-calcium ratio, and simulations of an Earth system model, to investigate changes in the water-mass composition and carbonate-ion concentration of the deep Pacific Ocean during the NHG. Our proxy records have revealed a significant expansion of southern-sourced waters with increased respired carbon storage into the deep Pacific during the NHG. These changes may be explained by strengthened deep-water formation and biological-pump efficiency in the Southern Ocean due to Antarctic sea-ice growth, as suggested by our model experiments and evidence from the Sub-Antarctic region. These results provide key clues for quantifying the role of the dissolved inorganic carbon content of deep Pacific waters in modulating atmospheric CO2 during the NHG.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
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  • 145
    Publication Date: 2023-03-13
    Description: Soon after the MW = 6.0 main event of May 20, 2012 that struck the central part of the Emilia-Romagna region (Italy), several geochemical surveys were carried out on groundwater within the epicentral area. A total of 20 water samples were periodically collected, from May 2012 to July 2014, from shallow (up to 6 m depth) to deep (down to 175 m depth) wells within both unconfined and confined aquifers and analyzed for major ions, trace elements, dissolved gases and stable isotopes (δ2H–H2O, δ18O–H2O and δ13C-TDIC). Geochemical data were compared with previous data collected and analyzed in 2006 in a phase of absence of significant seismic activity. Monitored waters showed concentration variations in post-earthquake sampling on a large number of geochemical parameters. Many of these variations were recorded during the co-seismic phase and were transient as the geochemical parameters returned towards pre-earthquake values over time. The most significant transient variations involved trace elements, which generally show high sensitivity even to small variations in the surrounding environment due to their usually low concentrations in groundwater. Physical-chemical parameters (water temperature, pH, TDS) and major ions provided less unambiguous indications, whereas among dissolved gases CH4 and CO2 showed a general post-seismic increase within the unconfined aquifer. Increased contents of such gas species in both aquifers (this study) and soils (previous studies) suggest that the seismic-induced overpressure on the ground had enhancing effects on soil permeability and porosity and triggered their co-seismic migration upwards from deeper reservoirs. Water isotopes showed the systematic post-seismic change in δ2H toward heavier compositions with no significant changes in the δ18O, which was interpreted as due to isotopic exchange between water and a H2-bearing gas phase (e.g., H2S, CH4, H2) entering the system. Calculated δ13C data of CO2 suggested a relatively shallow production from both plant-root respiration and microbial-driven degradation of organic matter while the almost pure crustal origin of He (R/Ra values = 0.04–0.16 from the bubbling gas phase emitted by one of the monitored wells) reasonably excludes any evidence of both primary mantle 3He degassing and ascent of heavier CO2 from deep (mantle, decarbonation) inorganic sources. Monitored waters which showed the most significant transient variations are aligned in the same E-W direction along which the seismicity and soil gas anomalies were distributed, at about 5 km S from the epicenter of the May 20th seismic event and along the main direction of the May 29th (MW = 5.8) event. This confirms that the transient variations have been activated by the seismic sequence in a sector of the crust where the presence of a fault/fracture system favors the intensification of processes affecting sediments and groundwater (variations of porosity/permeability of soils, the groundwater level, redox state, etc.) and which are able to explain the observed geochemical variations. Only one sample monitored, the one closest to the epicenter of the May 20th event, showed clear geochemical evidence suggesting the hypothesis of mixing between superimposed water bodies.
    Description: Published
    Description: 105624
    Description: 9T. Geochimica dei fluidi applicata allo studio e al monitoraggio di aree sismiche
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 146
    Publication Date: 2023-03-14
    Description: Mineralogy, fabric, and frictional properties are fundamental aspects of faults. Despite the extensive effort spent in the characterization of such fault properties, the description of fabric elements is not always univocal and nomenclatures such as the Y-B-P-R and the S-C-C′ are at times used interchangeably. This work presents a sys- tematic mineralogical, microstructural, and frictional characterization of natural gouges designed to constrain a criterion for the distinction between the Y-B-P-R and S-C-C′ fabric. For this purpose, we tested four representative natural mixtures of granular minerals (quartz) with increasing amount of phyllosilicates (muscovite). 24 fric- tional experiments were performed at constant normal stresses of 25, 50, 75 and 100 MPa, at both room dry and water saturated condition. We document that Y-B-P-R fabric typically develops in frictionally strong, granular- rich experimental faults. This fabric is associated to strain localization in narrow shear zones characterized by intense grain size reduction and dominant cataclastic processes. Conversely, S-C-C′ fabric is observed in phyllosilicate-rich experimental faults, which are characterized by distributed deformation and pervasive foli- ation. Deformation is mainly accommodated by frictional sliding along the well-oriented phyllosilicate foliae. The transition from Y-B-P-R to S-C-C′ is observed for phyllosilicates content 〉30% and is facilitated by secondary mechanical processes as networking of phyllosilicates and grain mantling. The evolution from Y-B-P-R to S-C-C′ fabric is also associated with a marked reduction in friction, in healing rate and changes in the rate and state friction parameters. Despite their geometrical similarities, we show that Y-B-P-R and S-C-C′ represent distinct fabrics reflecting the dichotomy that exists between frictionally strong, granular-rich, and frictionally weak, phyllosilicate-rich faults.
    Description: Published
    Description: 104743
    Description: 2T. Deformazione crostale attiva
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 147
    Publication Date: 2023-03-14
    Description: Seismic Probabilistic Tsunami Hazard Analysis (SPTHA) is aimed at estimating the annual rate of exceedance of an earthquake-induced tsunami wave of a certain location with reference to a predefined height threshold. The analysis relies on computationally demanding numerical sim ulations of seismic-induced tsunami wave generation and propagation. A large number of sce narios needs to be simulated to account for uncertainties. However, the exceedance of tsunami wave threshold height is a rare event so that most of the simulated scenarios bring little statistical contribution to the estimation of the annual rate yet increasing the computational burden. To efficiently address this issue, we propose a wrapper-based heuristic approach to select the set of most relevant features of the seismic model, for deciding a priori the seismic scenarios to be simulated. The proposed approach is based on a Multi-Objective Differential Evolution Algorithm (MODEA) and is developed with reference to a case study whose objective is calculating the annual rate of threshold exceedance of the height of tsunami waves caused by subduction earthquakes that might be generated on a section of the Hellenic Arc, and propagated to a set of target sites: Siracusa, on the eastern coast of Sicily, Crotone, on the southern coast of Calabria, and Santa Maria di Leuca, on the southern coast of Puglia. The results show that, in all cases, the proposed approach allows a reduction of 95% of the number of scenarios with half of the features to be considered, and with no appreciable loss of accuracy.
    Description: Published
    Description: 103112
    Description: 6T. Studi di pericolosità sismica e da maremoto
    Description: JCR Journal
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  • 148
    Publication Date: 2023-03-14
    Description: Probabilistic Seismic Hazard Assessment (PSHA) evaluates the probability of exceedance of a given earthquake intensity threshold like the Peak Ground Acceleration, at a target site for a given exposure time. The stochasticity of the occurrence of seismic events is modelled by stochastic processes and the propagation of the earthquake wave in the soil is typically evaluated by empirical relationships called Ground Motion Prediction Equations. The large uncertainty affecting PSHA is quantified by defining alternative model settings and/or model parametri zations. In this work, we propose a novel Bootstrapped Modularised Global Sensitivity Analysis (BMGSA) method for identifying the model parameters most important for the uncertainty in PSHA, that consists in generating alternative artificial datasets by bootstrapping an available input-output dataset and aggregating the individual rankings obtained with the modularized method from each of those. The proposed method is tested on a realistic PSHA case study in Italy. The results are compared with a standard variance-based Global Sensitivity Analysis (GSA) method of literature. The novelty and strength of the proposed BMGSA method are both in the fact that its application only requires input-output data and not the use of a PSHA code for repeated calculations.
    Description: Published
    Description: 102312
    Description: 6T. Studi di pericolosità sismica e da maremoto
    Description: JCR Journal
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  • 149
    Publication Date: 2023-03-24
    Description: A multidisciplinary study of a sector of the Ionian coastal belt, southern Italy, mainly based on two new bore holes approximately 25 m (MSA) and 20 m (MSB) deep, was carried out in the frame of a wider geo archaeological project. Stratigraphic and Paleoecological data, together with geomorphological observations, have been used in order to define the Late Quaternary morpho-sedimentary evolution and its relationships with tectonic and climate forcing. The analyses of core sediments and geomorphic interpretations allowed us to reconstruct the changes in depositional setting and physical landscape starting from the MIS 5.5. To this scope, new data about sedimentary facies, benthic foraminifera and ostracod assemblages, and a set of 14C ages spanning from about 33 to 15 kyr BP are here presented. All these data revealed a strong modification of the depositional setting within the coastal plain, as inferred by the presence of marine, transitional, and continental deposits, and suggest an anomalous position of sea-level reference points. Such anomalies are clustered in two homogenous arrays that can be explained only admitting a significant tectonic uplift in recent times (i.e. about 4 mm/yr over the last 15,000 years).
    Description: Published
    Description: 84-110
    Description: 4A. Oceanografia e clima
    Description: 7SR AMBIENTE – Servizi e ricerca per la società
    Description: JCR Journal
    Keywords: Coastal evolution ; Paleoecology ; Chronostratigraphy ; Relative sea-level changes ; Tectonic uplift ; Southern Italy
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 150
    Publication Date: 2023-01-23
    Description: The 1928 CE volcanic activity on eastern Etna, Italy, produced wide surface deformation and high effusion rates along fissures, with excess volumes of about 50 million m3 of lavas. This, in conjunction with the low elevation of the main eruptive vents (1150 m a.s.l.), caused the destruction of the Mascali town. Our research focuses on a multidisciplinary study from field observations and Finite Element Method modelling through COMSOL Multiphysics ®, with the aim of reconstructing the geometry, kinematics and origin of the system of faults and fissures formed during the 1928 event. We collected quantitative measurements from 438 sites of azimuth values, opening direction and aperture amount of dry fissures, and attitude and vertical offsets of faults. From west to east, four volcanotectonic settings have been identified, related to dike propagation in the same direction: 1) a sequence of 8 eruptive vents, surrounded by a 385-m wide graben, 2) a 2.5-km long single eruptive fissure, 3) a half-graben as wide as 74 m and a symmetric, 39-m-wide graben without evidence of eruption, 4) alignment of lower vents along the pre-existing Ripe della Naca faults. Field data, along with historical aerial photos, became inputs to FEM numerical models. The latter allowed us to investigate the connection between diking and surface deformation during the 1928 event, subject to a range of overpressure values (1–20 MPa), host rock properties (1–30 GPa) and geometrical complexity (stratigraphic sequence, layer thickness). In addition, we studied the distribution of tensile and shear stresses above the dike tip and gained insights into dike-induced graben scenarios. Our multidisciplinary study reports that soft (e.g. tuff) layers can act as temporary stress barriers and control the surface deformation scenarios (dike-induced graben, single fracture or eruptive fissures) above a propagating dike by suppressing the distribution of shear stresses towards the surface.
    Description: Published
    Description: 229468
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: JCR Journal
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  • 151
    Publication Date: 2023-01-23
    Description: The Valle del Bove is a profound and wide scar on the east Etna flank witnessing the Holocene main volcanotectonic event of the volcano, frequently invaded by lava flows during the last centuries. The Valle del Bove slope failure produced the Milo debris avalanche deposit on the lower east flank that is partially covered by the Mongibello lavas and a pyroclastic succession. In this paper, we constrain for the first time the age of the Milo debris avalanche deposit and the overlying lava succession exposed at three quarries recently caved at the valley mouth through a multidisciplinary approach integrating stratigraphic and petrographic analyses, 14C, and paleomagnetic dating. In particular, 14C age determinations of the Milo debris avalanche deposit indicate that the initial stage of the catastrophic flank collapse of the Valle del Bove occurred at 7478–7134 BCE during the Mesolithic age. Conversely, the main portion of the lava succession filling the valley floor emplaced after the sub- Plinian picritic eruption occurred at 2579–2278 BCE (FS tephra layer) consistently with the increasing occurrence frequency of flank eruptions documented in the geological record of Etna during the past 4000 yrs. Paleomagnetic dating highlighted that in the study area the sub-Plinian eruption was followed by two quasicontemporaneous flank eruptions during the Late Copper age (2600–2400 BCE), whereas other two flank eruptions occurred during Greek-Roman and Medieval ages. These results have relevant implications on the stratigraphy and evolution of Etna, particularly on the Valle del Bove initial collapse and the relative emplacement of the Chiancone detritic-alluvial sequence.
    Description: Published
    Description: 107752
    Description: 1V. Storia eruttiva
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 152
    Publication Date: 2023-01-27
    Description: The main objective of this work is to provide two zonations of Italy useful to incorporate regional source and path effects in empirical Ground Motion Models (GMMs). To this end, we revise existing zonations developed for seismic and tsunami hazard studies, based on the results of a residual analysis between the observations of the ITACAext dataset and the predictions of ITA18, a GMM recently developed for Italy. The analysis consists in the decomposition of the residuals into repeatable terms, according to the well-established approach used for the calibration of non-ergodic models. Based on the spatial trend of the interpolated residuals, and geological and seismological considerations, the zonations are proposed and discussed, in the perspective of supporting regionalization of a future generation of GMMs for Italy.
    Description: Published
    Description: 107775
    Description: 4T. Sismicità dell'Italia
    Description: 5T. Sismologia, geofisica e geologia per l'ingegneria sismica
    Description: 6T. Studi di pericolosità sismica e da maremoto
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 153
    Publication Date: 2023-01-27
    Description: The architecture of the magma storage system underneath Fogo Volcano (Cape Verde Archipelago) is characterised using novel fluid inclusion results from fifteen basanites, spanning the last 120 thousand years of volcanic activity, and encompassing a major flank collapse event at ~73 ka. Fluid inclusions, hosted in olivine and clinopyroxene, are made of pure CO2, and based on their textural characteristics, are distinguished in early (Type I) and late (Type II) stage. Inclusions homogenize to a liquid phase in the 2.8 to 30.8 ◦C temperature range. Densities values, recalculated assuming an original 10% H2O content at the time of trapping, range from 543 to 952 kg⋅m3, and correspond to entrapment or re-equilibration pressure ranges of 500–595 MPa, 700–740 MPa, and 245–610 MPa respectively for pre-collapse, early post-collapse, and Holocene/historical eruptions. These entrapment pressures are interpreted as reflecting the existence of two main magma accumulation zones at ~25 km and ~ 13–21 km depth, and a zone of fluid inclusion re-equilibration at 9–12 km depth. There is evidence of a complex temporal evolution of the magma system. Historical eruptions, and especially the three most recent ones (occurred in 1951, 1995 and 2014–25), bring fluid inclusion evidence for transient, pre-eruptive shallow (9–17 km depth) magma ponding. Early post-collapse (60 ka) volcanics, in contrast, document fast magma transport from ~25 km, and suggest a reconfiguration of the magma system after the Monte Amarelo collapse event.
    Description: Published
    Description: 107730
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: JCR Journal
    Keywords: Oceanic island volcanism ; Magma ascent path ; 04.08. Volcanology ; petrology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 154
    Publication Date: 2023-01-27
    Description: The complex sequential compositional zoning of clinopyroxene crystals erupted 〈5 ka during the Agnano-Monte Spina (A-MS) eruption, which is considered to be the reference event for a future large-scale explosive eruption at Campi Flegrei caldera (Italy), has been characterized in detail. Concentration profiles (20–800 μm long, spacing 2.5–10 μm) of major (Si, Ti, Al, Fe, Mg and Ca) and minor (Mn, Na, Ni and Cr) elements were measured along different directions in the clinopyroxene crystals. The zoning patterns of Fe–Mg and selected elements (e.g., Al, Ti) often consist of two or more compositional plateaus with both sharp and/or slightly diffuse boundaries between the plateaus. Each compositional population results from a growth stage in a distinct Magmatic Environment (ME), which is identified as a defined set of intensive thermodynamic variables (pressure, temperature, bulk composition and fugacity of fluids including oxygen). The large range of chemical compositions of clinopyroxenes reveals the existence of at least four MEs that are characterized by different compositional populations; two of these are dominant. The variation in zoning pattern from one plateau composition to another fingerprints the transfer of the crystal from one ME to another. In combination with Sr isotopic data and thermobarometric estimates, our systematic characterization of clinopyroxene zoning patterns suggests recharge by deep mafic magmas (ME0: Mg# = 85–92) of an evolved shallow reservoir (ME2: Mg# = 70–78). Such a process also led to the formation of a compositionally intermediate environment (ME1: Mg# = 84–80), that is detected in the clinopyroxene zoning pattern. A new method has been developed in this work to evaluate the effective diffusive modifications that affect the concentration profiles of zoned crystals. The application of different diffusion modeling methods indicates that deep and shallow reservoirs beneath the Campi Flegrei caldera were connected to each other over several tens of years until the amount of mafic recharge increased during the last 10–15 years before the A-MS eruption. This study highlights the complex relationships between events of magma recharge and the onset of eruption. Our results provide a contribution to the knowledge of timescales of magmatic processes that have recently occurred beneath the Campi Flegrei caldera, which is useful for risk assessment.
    Description: Published
    Description: 185-206
    Description: 4V. Processi pre-eruttivi
    Description: JCR Journal
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  • 155
    Publication Date: 2023-01-27
    Description: Seismic coupling helps define how large the earthquake potential of a region is, as well as the presence of asperities along plate zones. This work seeks to provide an improved picture of the seismic coupling for the Aegean-Anatolian region by taking advantage of extensive seismic and geodetic datasets. To estimate coupling, we compiled a series of by-products that are specific ingredients also for seismic hazard studies. With these by-products, we found that the seismogenic thickness is thinner (10–15 km) or thicker (20 to 30 km) to the east and to the west, respectively and even deeper along the Hellenic subduction zone. The b-value ranges between 0.9 and 1.1 for the entire area with high values concentrated at locations of Late Miocene to -recent volcanism whereas low b-values (〈0.8) concentrate along most of the Northern Anatolian fault zone that may suggests stress accumulation. Seismic coupling is low (〈35%) or intermediate (35% - 70%) in most of the area, while the Karliova triple junction, on a N-S-oriented belt along the boundary between western and central Anatolia, and the southeastern Peloponnese are fully coupled, suggesting a full seismic release of the entire deformation budget. An intermediate value of seismic coupling is observed for the eastern and central segments of the Northern and Eastern Anatolian Fault zones, for part of the Hellenic volcanic arc, the Kefalonia Transform Fault and the Corinth gulf active faults. Considering historical earthquake data, these intermediate coupling values indicate either aseismic deformation or catalog incompleteness. Furthermore, the time period since large magnitude earthquakes clearly raises the possibility of impending earthquakes on the Northern and Eastern Anatolian Fault zones. A broad seismic gap is evidenced along the Hellenic subduction zone, because of the reduced coupling and the absence of ~M8 earthquakes in the last 700 years, at least. We conclude that in most of the central Aegean Sea aseismic deformation prevails as suggested by the small value of coupling and the modest seismic release over the last millennium.
    Description: Published
    Description: 103993
    Description: 2T. Deformazione crostale attiva
    Description: JCR Journal
    Keywords: GNSS ; crustal deformation ; seismic coupling ; b-value ; 04. Solid Earth
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 156
    Publication Date: 2023-01-27
    Description: This work proposes a novel approach to the calibration of region- alized regression models, with particular reference to ground- motion models (GMMs), which are key for probabilistic seismic hazard analysis and earthquake engineering applications. A novel methodology, named multi-source geographically-weighted re- gression (MS-GWR), is developed, allowing one to (i) estimate regionalized regression models depending on multiple sources of non-stationarity (such as site- and event-dependent non- stationarities in GMMs), and (ii) make inference on the sig- nificance and stationarity of the regression coefficients. Unlike previous approaches to the problem, the proposed framework is non-parametric – in the sense of the distribution of the errors – the inference being based on a permutation scheme. MS-GWR is here used to calibrate a new regionalized ground-motion model for predicting peak ground acceleration in Italy, based on a large scale database of waveforms and metadata made available by the Italian Institute for Geophysics and Vulcanology (INGV).
    Description: Published
    Description: 100610
    Description: 5T. Sismologia, geofisica e geologia per l'ingegneria sismica
    Description: JCR Journal
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  • 157
    Publication Date: 2023-02-06
    Description: The Cisuralian–Guadalupian (early–middle Permian) was a period of climate transition between the Carboniferous icehouse conditions to the latest Permian–Early Triassic hothouse. The landmasses had coalesced in the supercontinent Pangaea and the climate was progressively becoming more arid, especially in a belt over the palaeoequator. The deposits of present-day Mallorca (Balearic Islands, western Mediterranean) were located in those low palaeolatitudes, in the western margin of the Tethys Sea, and correspond to alluvial systems with meandering rivers. The present study divides the stratigraphic succession into three main units, formally described herein as the Bec de s’Àguila Formation, Port des Canonge Formation and Pedra de s’Ase Formation. Based on an exhaustive review of the literature and new magneto- and biostratigraphic data, the sequence has been dated between the early and middle Permian (Artinskian–Wordian). Moreover, the detailed study of the fossils has provided a complete account of the denizens of those ecosystems. Tetrapod tracks occur abundantly in the Port des Canonge Formation, with morphotypes attributed to moradisaurine captorhinid eureptiles, araeoscelidian diapsids/non-varanodontine varanopids, possible pareiasauromorph parareptiles, “pelycosaur”-grade synapsids and indeterminate synapsids. Spores and pollen grains from the Pedra de s’Ase Formation indicate an overall dominance of conifers, accompanied by sphenophytes, ferns and seed ferns. Overall, apart from providing the first detailed interpretation of the ecosystems of the Permian of Mallorca, these new data have made it possible to improve the characterisation of the Permian–Triassic tectonosedimentary cycle in the Balearic Islands, which contribute to the understanding of the evolution of the western peri-Tethys ecosystems.
    Description: Published
    Description: 103948
    Description: 1A. Geomagnetismo e Paleomagnetismo
    Description: JCR Journal
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  • 158
    Publication Date: 2023-02-07
    Description: Fault zone architecture and its internal structural variability play a pivotal role in earthquake mechanics, by controlling, for instance, the nucleation, propagation and arrest of individual seismic ruptures and the evolution in space and time of foreshock and aftershock seismic sequences. Nevertheless, the along-strike architectural variability of crustal-scale seismogenic sources over regional distances is still poorly investigated. Here, we describe the architectural variability of the 〉40-km-long exhumed, seismogenic Bolfin Fault Zone (BFZ) of the intra-arc Atacama Fault System (Northern Chile). The BFZ cuts through plutonic rocks of the Mesozoic Coastal Cordillera and was seismically active at 5–7 km depth and ≤ 300 °C in a fluid-rich environment. The BFZ includes multiple altered fault core strands, consisting of chlorite-rich cataclasites-ultracataclasites and pseudotachylytes, surrounded by chlorite-rich protobreccias to protocataclasites over a zone up to 60-m-thick. These fault rocks are embedded within a low-strain damage zone, up to 150-m-thick, which includes strongly altered volumes of dilatational hydrothermal breccias and clusters of epidote-rich fault-vein networks at the linkage of the BFZ with subsidiary faults. The strong hydrothermal alteration of rocks along both the fault core and the damage zone attests to an extensive percolation of fluids across all the elements of the structural network during the activity of the entire fault zone. In particular, we interpret the epidote-rich fault-vein networks and associated breccias as an exhumed example of upper-crustal fluid-driven earthquake swarms, similar to the presently active intra-arc Liquiñe-Ofqui Fault System (Southern Andean Volcanic Zone, Chile).
    Description: European Research Council Consolidator Grant Project (NOFEAR) No 614705
    Description: Published
    Description: 104745
    Description: 3T. Fisica dei terremoti e Sorgente Sismica
    Description: JCR Journal
    Keywords: Atacama fault system ; Earthquakes ; Fault structure ; Fault zone rocks ; Fluid-driven seismicity ; Seismogenic faults ; 04. Solid Earth
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  • 159
    Publication Date: 2023-02-09
    Description: The density, colour and texture, plus mineral and chemical features of 18 ceramic-like CDW samples from the Abruzzo region (Central Italy) were characterised. The concretes, natural stones, tiles, roof-tiles, bricks and perforated bricks are either aphanitic to porphyric. Concretes and natural stones are grey to white and tend to be 〉 2.0 g/cm3; the masonries are brown to reddish and close to 〈 2.0 g/cm3. Concrete and natural stone are rich or even exclusively made up of calcite, with high amounts of CaO (〉40 wt%) and LOI (volatiles, CO2 + H2O). The masonries are instead calcite-, CaO- (〈25 wt%) and LOI-poor (〈8 wt%) but enriched in SiO2 (45 to 70 wt%) stabilised as quartz and/or cristobalite, with significant amount of Al2O3 (12 to 20 wt%). S and Cl contents are similar among concrete, bricks and perforated bricks. The petrography of CDW concretes is similar among geographical areas with abundance of limestones used as aggregates. However, in limestone-poor areas CDW are SiO2- and Al2O3-rich, reflecting the prevalent use of masonry and/or silicate-rich construction materials, implying that each geographical area is characterised by peculiar CDW composition. Therefore, the knowledge of mesoscopic, physical and petrographic aspects has to be known for planning adequate sorting methods, promoting upcycling reusing applications. Some of the studied CDW samples are susceptible to release relative high Cr and As content.
    Description: Published
    Description: 61-71
    Description: 6SR VULCANI – Servizi e ricerca per la società
    Description: JCR Journal
    Keywords: Abruzzo region (Italy); CDW (construction and demolition waste); Recycling; XRF; XRPD
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 160
    Publication Date: 2023-02-09
    Description: By leveraging monitoring data for the Gran Sasso carbonate aquifer during two significant seismic sequences that hit central Italy in recent years, this study investigates the possibility of using memory-enabled deep learning algorithms as meaningful tools for an enhanced modelling of the hydrological response of karst aquifers subject to earthquake phenomena. Meteorological, hydrological and seismic data are used to train and validate long short-term memory networks (LSTM) in one- and multiple-day ahead flow forecasting exercises, aimed at assessing model sensitivities to input variables and modelling choices (training data and parameters of the models). Results indicate that the models fairly reproduce the flow patterns for the considered spring in the Gran Sasso aquifer, thus supporting the potential use of these models for hydrological applications in similar areas, provided that sufficient data are available for the training of the network.
    Description: Published
    Description: 129002
    Description: 9T. Geochimica dei fluidi applicata allo studio e al monitoraggio di aree sismiche
    Description: JCR Journal
    Keywords: Earthquake hydrology ; Seismic sequences ; Karst aquifer ; Deep learning LSTM ; Central Italy ; LSTM
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  • 161
    Publication Date: 2023-02-02
    Description: The continental margin of the Ross Sea has been consistently sensitive to the advance and retreat of the Ross Ice Sheet (RIS) between the interglacial and glacial periods. This study examines changes of the glaciomarine sedimentation on the continental slope and rise to the eastern side of Hillary Canyon in the central Ross Sea, using three gravity cores collected at increasing water depths. Besides older AMS 14C ages of bulk sediments, based on the analytical results, sediment lithology was divided into units A, B1, and B2, representing Holocene, deglacial, and glacial periods, respectively. The sedimentation rate decreased as the water depth increased, with a higher sedimentation rate in the deglacial period (unit B1) than the Holocene (unit A). Biological productivity proxies were significantly higher in glacial unit B2 than in interglacial unit A, with transitional values observed in deglacial unit B1. Biological productivity generally decreased in the Antarctic continental margin during the glacial period because of extensive sea ice coverage. The higher biogenic contents in unit B2 are primarily attributed to the increased transport of eroded and reworked shelf sediments that contained abundant biogenic components to the continental slope and rise beneath the advancing RIS. Thus, glacial sedimentation on the continental slope and rise of the central Ross Sea was generally governed by the activity of the RIS, which generated melt-water plumes and debris flows at the front of the grounding line, although the continental rise might have experienced seasonally open conditions and lateral effects due to the bottom current.
    Description: Published
    Description: 106752
    Description: 1A. Geomagnetismo e Paleomagnetismo
    Description: JCR Journal
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  • 162
    Publication Date: 2023-02-02
    Description: We analyzed from meso-to microscale the chemical interaction (e.g., bleaching) between deep fluids and carbonate rocks in pelagic limestones exposed along the seismically active Gubbio normal fault (Northern Apennines), exhumed from ca. 2 km depth. Bleaching is enhanced by the exploitation of inherited stylolitic seams by fluids and is favored by the progressive leaching and mobilization of primary components (i.e., Ca, Fe, Pb, and Cu) and the precipitation of authigenic baryte due to temperature and/or redox potential contrast. Analysis of fluid inclusions trapped in calcite veins in the damage zone precipitated from a H2O–NaCl-bearing fluid(s), with low salinity (1.22–2.57 wt%NaCleq) and a range of trapping temperature between 107 ◦C and 185 ◦C, higher than the host rock peak T conditions. Analysis of fluid inclusions and noble gases from syn-kinematic calcite and mineralogy of altered rocks suggests a mixed contribution between crustal-derived fluids with diagenetic fluids containing sulphates and CO2. We speculate that bleaching is a by-product of the circulation of such aggressive fluids with mixed contributions, likely mobilized during seismic event(s) and injected into the damage zone at shallow depths. Such processes, affecting the chemical-physical properties of limestones, are generally underestimated and should be considered when modelling hydraulic connectivity in fractured carbonate reservoirs.
    Description: Published
    Description: 104668
    Description: 9T. Geochimica dei fluidi applicata allo studio e al monitoraggio di aree sismiche
    Description: JCR Journal
    Keywords: fluids ; eartquakes ; Gubbio Fault ; noble gases
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  • 163
    Publication Date: 2023-02-02
    Description: In this study, we explore the impact of using different Moho surfaces on the reconstruction of the upper mantle geophysical parameters. The study area is the subsurface of the Antarctica continent. Using the optimization program of Sequential Integrated Inversion (SII) and the gravity anomalies synthetized by a global Gravity Field Model (GFM), we reconstructed the upper mantle density and the related 3D distribution of the rho-v_SV couplings down to the depth of 400 km, with a lateral resolution of 0.5° × 0.5°. Here, we present the results obtained for four models, built with four different Moho surfaces. A correlation analysis showed that different Moho structures affect the optimization of the intensity of the anomalies and the rho-v_SV couplings. The possibility of having both a density model and a 3D distribution of the rho-v_SV couplings enables us to highlight several significant features for all models that are not disclosed by seismic tomography. Among them, a trend of positive, presumably compositional anomalies suggests the contribution of the Lambert Rift System (LRS) to the Gamburstev Mountains (GSM) uplift, which in turn may have influenced the formation of the Maud Subglacial Basin (MSB). A continuous low-density anomaly and positive rho-v_SV phase coupling anomaly, extending from the northwestern side of the Transantarctic Mountains (TAM) to Victoria Land, support the thermal buoyancy force as the causative element of the formation of the TAM. A circumscribed negative density anomaly extending up to depth of 365 km, which is associated to a negative variation in the angular coefficients of the rho-v_SV couplings, indicates the presence of an active magmatic system in the upper mantle or a Cenozoic mantle plume beneath the region of Mary Byrd Land (MBL).
    Description: PNRA project: “Risposta litosferica alla dinamica del mantello e della criosfera” (D.D. n. 2164–14/11/2013 – PdR 2013/B2.06) CINECA ISCRA Class C project (HP10CGC85K).
    Description: Published
    Description: 229724
    Description: 1T. Struttura della Terra
    Description: JCR Journal
    Keywords: Antarctic upper mantle ; Moho depths of Antarctica ; Integrated inversion of seismological and gravity data ; Satellite gravity field ; Upper mantle density of Antarctica ; Density-velocity relationship ; 0.4 Solid Earth
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 164
    Publication Date: 2023-02-02
    Description: One of the most dangerous aspects of explosive volcanism is the occurrence of dilute pyroclastic density currents that move at high velocities of tens to about a hundred of metres per second outwards from volcanic vents. Predicting the runout behaviour of these turbulent flows of hot particles and air is complicated by strong changes in the flow density resulting from entrainment of ambient air, sedimentation of particles, as well as heating and expansion of the gas phase. Current hazard models that are based on the behaviour of aqueous gravity currents cannot capture all aspects of the flow dynamics, and thus pyroclastic density current dynamics remain comparatively poorly understood. Here we interrogate the runout behaviour of dilute pyroclastic density currents in large-scale experiments using hot volcanic material and gas. We demonstrate that the flows transition through four dynamic regimes with distinct density and force characteristics. The first, inertial regime is characterized by strong deceleration under high density differences between the flow and ambient air where suspended particles carry a main proportion of the flows' momentum. When internal gravity waves start to propagate from the flow body into the advancing flow front, the currents transition into a second, inertia-buoyancy regime while flow density continues to decline. In this regime, subsequent arrivals of fast-moving internal gravity waves into the front replenish momentum and lead to sudden short-lived front accelerations. In the third regime, when the density ratio between flow and ambient air decreases closer to a value of unity, buoyancy forces become negligible, but pressure drag forces are large and constitute the main flow retarding force. In this inertia-pressure drag regime, internal gravity waves cease to reach the front. Finally, and with the density ratio decreasing below 1, the current transitions into a buoyantly rising thermal in regime 4. Unlike for aqueous gravity currents, the Froude number is not constant and viscous forces are negligible in these gas-particle gravity currents. We show that, in this situation, existing Boussinesq and non-Boussinesq gravity current models strongly underpredict the front velocity for most of the flow runout for at least half of the flow propagation. These results are not only important for hazard mitigation of pyroclastic density currents but are also relevant for other turbulent gas-particle gravity currents, such as powder snow avalanches and dust storms.
    Description: Published
    Description: 107697
    Description: 5V. Processi eruttivi e post-eruttivi
    Description: JCR Journal
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  • 165
    Publication Date: 2023-02-02
    Description: In complex plate-boundary settings, a reliable 3-D geophysical characterization of the deep tectonic structure is a fundamental starting point for a breakthrough in the analysis of processes controlling plate subduction and (U)HP rock exhumation. The Western Alps host one of the best-studied fossil subduction zones worldwide, with a well-defined deep structure in 2-D based on recent geophysical experiments. However, a full 3-D characterization of its deep tectonic structure is still lacking. Here we present a series of new receiver function cross-sections across the northern and southern Western Alps, validated and complemented by a S-wave velocity model from ambient-noise tomography that provides additional constraints between the profiles. We document a marked change in Moho attitude from the northern Western Alps, where the eastward-dipping European Moho reaches ∼45 km depth beneath the Gran Paradiso dome, to the southern Western Alps, where the European Moho reaches ∼70 km depth beneath the equivalent Dora-Maira dome. This change in Moho attitude takes place over a few tens of kilometers and was likely emphasized by deformation of the slab during subduction. The Western Alps subduction wedge is much thicker in the south than in the north, and the mantle-wedge rocks are deeply involved in orogeny exclusively in the south, where coesite is found in continental (U)HP rocks at several locations. Our detailed information on the 3-D structure of the subduction wedge provides first-order constraints for the next-generation of thermo-mechanical numerical models and may help explain the lateral variations in exhumation style revealed by the geologic record.
    Description: Published
    Description: 117843
    Description: 2T. Deformazione crostale attiva
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 166
    Publication Date: 2023-02-03
    Description: Abstract One of the key aspects of the approaching data-intensive science era is integration of data through interoperability of systems providing data products or visualization and processing services. Far from being simple, interoperability requires robust and scalable e-infrastructures capable of supporting it. In this work we present the case of EPOS, a plan for data integration in the field of Earth Sciences. We describe the design of its e-infrastructure and show its main characteristics. One of the main elements enabling the system to integrate data, data products and services is the metadata catalogue based on the \{CERIF\} metadata model. Such a model, modified to fit into the general e-infrastructure design, is part of a three-layer metadata architecture. \{CERIF\} guarantees a robust handling of metadata, which is in this case the key to the interoperability and to one of the feature of the \{EPOS\} system: the possibility of carrying on data intensive science orchestrating the distributed resources made available by \{EPOS\} data providers and stakeholders.
    Description: Published
    Description: 3-10
    Description: 4IT. Banche dati
    Description: N/A or not JCR
    Keywords: Research Infrastructure
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 167
    Publication Date: 2023-02-10
    Description: The phenomenon `earthquake swarm' is well known from numerous locations on Earth but its mechanism and trigger process are still an enigma. The influence of fluids on fluid-driven seismicity is generally well accepted but the temporal behaviour and the migration of activated phases is still an open question. We attempt to answer these open questions by combining the results of research on induced-seismicity with new reliable analyses of full moment tensors (FMTs) of the swarm earthquakes of 2008 to 2018 in Northwest-Bohemia, Czech Republic by Vavryˇcuk et al. (2017, 2021). The FMTs reveal evidence of compressive fracturing as the prevailing focal mechanism during the swarms. Our proposed hypotheses considered these earthquakes as the origin of subsequent pore pressure pulses in the respective active swarm phase. The diffusion of these pore pressure pulses, which could trigger the nearby earthquakes as well as the successive swarm phase in the vicinity after a respective diffusion process in space and time, are the target of this studies. Missing information regarding the real diffusion distances are compiled by a strict statistical approach of a one-to-one analysis of the swarm earthquakes. The analyses suggest that parts of the swarm earthquakes could be triggered by pore pressure diffusion with an estimated diffusivity range of approximately D = 0.01 to 3.0 m2/s. In exceptional cases, which make about 5% of all cases, we have to consider also diffusivities up to 15 m2/s. Examples of hydraulic diffusivities observed in our region of interest confirm this range. Such a process can also be assumed during further swarms in the years 2011 to 2018 because of the continuous and predominant occurrence of compressive fracturing as a focal mechanism beside pure shear and tensile fracturing. Our results could explain for the firsttime the missing link regarding the temporal and spatial migration of the subsequent swarm phases in ourstudied region at Nový Kostel (Northwest-Bohemia, Czech Republic).
    Description: Published
    Description: 106941
    Description: 3T. Fisica dei terremoti e Sorgente Sismica
    Description: JCR Journal
    Keywords: Induced seismicity ; Earthquake swarm ; Pore pressure diffusion ; NW-Bohemia ; 04.06. Seismology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 168
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    Unknown
    Elsevier
    In:  EPIC3Progress in Oceanography, Elsevier, 206, pp. 102851, ISSN: 00796611
    Publication Date: 2023-08-01
    Description: Harmful Algae Blooms pose an increasing threat to the public health and economic stability of Southern Chile, particularly to the aquaculture industries. This fieldwork performed during the PROFAN expedition from 12th to 22nd November 2019 extends the knowledge on the distribution of marine toxin-producing species in the difficult to access Última Esperanza Province in the Magallanes Region. Paralytic Shellfish Poisoning toxins with high relative abundances of saxitoxin and lipophilic toxins dominated by yessotoxins, pectenotoxins and domoic acid were detected at nearly each sampling station. The respective toxin-producing organisms are mainly from the genus Alexandrium and Dinophysis. Furthermore, the first detection of pinnatoxin-G (PnTx-G) in Chilean waters strongly indicates the presence of the dinoflagellate Vulcanodinium rugosum.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , NonPeerReviewed
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  • 169
    facet.materialart.
    Unknown
    Elsevier
    In:  EPIC3Heliyon, Elsevier, 9(7), pp. e18331-e18331, ISSN: 2405-7843
    Publication Date: 2023-08-31
    Description: Calcium carbonate minerals produced by marine organisms play a central role in the global carbon cycle and carbonate sedimentation, which influence the climate by regulating atmospheric CO2 levels. Foraminifera are important marine single-celled organisms that have produced calcite shells for over 300 million years. Here, we present new observations promoting our understanding for foraminiferal biocalcification by studying Amphistegina lessonii. We integrated in vivo confocal autofluorescence and dye fluorescence imaging with elemental analysis of the cell supporting the concept that the calcite shells of foraminifera are produced via deposition of intracellularly formed Mg-rich amorphous calcium carbonate (Mg-ACC) particles that transform into a stable mineral phase. This process is likely accompanied by the activity of endosymbiotic microalgae and seawater-derived endocytic vesicles that provide calcification substrates such as DIC, Ca2+, and Mg2+. The final transformation of semi-liquid amorphous nanoparticles into a crystalline shell was associated with Mg2+ liberation.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
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  • 170
    Publication Date: 2023-09-04
    Description: Cold-water corals (CWCs) are considered vulnerable to environmental changes. However, previous studies have focused on adult CWCs and mainly investigated the short-term effects of single stressors. So far, the effects of environmental changes on different CWC life stages are unknown, both for single and multiple stressors and over long time periods. Therefore, we conducted a six-month aquarium experiment with three life stages of Car- yophyllia huinayensis to study their physiological response (survival, somatic growth, calcification and respira- tion) to the interactive effects of aragonite saturation (0.8 and 2.5), temperature (11 and 15 ◦C) and food availability (8 and 87 μg C L−1). The response clearly differed between life stages and measured traits. Elevated temperature and reduced feeding had the greatest effects, pushing the corals to their physiological limits. Highest mortality was observed in adult corals, while calcification rates decreased the most in juveniles. We observed a three-month delay in response, presumably because energy reserves declined, suggesting that short-term ex- periments overestimate coral resilience. Elevated summer temperatures and reduced food supply are likely to have the greatest impact on live CWCs in the future, leading to reduced coral growth and population shifts due to delayed juvenile maturation and high adult mortality.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
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  • 171
    Publication Date: 2023-01-17
    Description: In this paper we present the ground response analyses (GRA) of a site where an industrial facility is planned. Because of its location on an active normal fault system known as a relevant seismic gap, the Mt. Morrone Fault system (MMF), and at the edge of a basin filled with slow velocity continental deposits, a inter-disciplinary and non-standard approach has been applied to assess the seismic input of the dynamic numerical analyses. It includes geological, seismological, geotechnical and engineering contributions. Two fault scenarios, MMF1 and MMF2, were considered and scenario-based (SSHA) and probabilistic (time-dependent, TD, and time-independent, TI) seismic hazard (PSHA) analyses were implemented. Comparison among the spectra corresponding to the 90th percentile of the SSHA statistical distribution and the PSHA average ones, shows that the MMF2 has values similar to the TD model. The SSHA 90th percentile distribution was selected as target spectra to retrieve the seismic input for GRA. Nonlinear numerical simulations of seismic wave propagation were implemented to derive surface ground motion parameters. GRA acceleration response spectra and their PGA are notably higher, and thus on the safety site, than those obtained following the Italian code approach for seismic resistant buildings. These results confirm that a scenario-based methodology can better capture the shaking effect in near-field conditions, avoiding possibly unconservative underestimations of the seismic actions and in view of a more robust performance-based approach used by engineers for either new design and/or assessment/retrofit purposes of the built environment.
    Description: Published
    Description: 106970
    Description: 5T. Sismologia, geofisica e geologia per l'ingegneria sismica
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 172
    Publication Date: 2023-01-17
    Description: Volcanic tremor and long period (LP) events are typical seismic signals recorded on active volcanoes and are characterized by different durations, longer than minutes and a few seconds - tens of seconds for the former and latter, respectively. As they share the same frequency content, they are often grouped together in the literature and referred to by the unique name of LP seismicity. The common spectral features, together with observations in some volcanoes of individual LP events merging to form volcanic tremor, led to hypotheses that LP events and volcanic tremor share the same source mechanism. However, it is still open to debate whether volcanic tremor can be considered a simple coalescence of LP events or not. In this work, to help answer such a question, we analysed volcanic tremor and LP events recorded at Mt. Etna during the period February 2019–June 2020, characterized by minor eruptive activity, varying from weak ash emission to explosive and effusive eruptions at all the summit craters. Results from spectral, amplitude and location analyses, as well as the different scaling laws explaining the distributions of the duration/number of events versus size, led us to infer that LP events and volcanic tremor at Mt. Etna are not due to a common source mechanism.
    Description: Published
    Description: 106850
    Description: 4V. Processi pre-eruttivi
    Description: 5V. Processi eruttivi e post-eruttivi
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 173
    Publication Date: 2023-01-17
    Description: To better constrain the deep structure and dynamics of the Western Alps, we studied the mantle transition zone (MTZ) structure using P-wave receiver functions (RFs). We obtained a total of 24904 RFs from 1182 events collected by 307 stations in the Western Alps. To illustrate the influence of the heterogeneity on the upper mantle velocity, we used both IASP91 and three-dimensional (3-D) velocity models to perform RF time-to-depth migration. We documented an MTZ thickening of about 40 km under the Western Alps and most of the Po Plain due to the uplift associated with the 410-km discontinuity and the depression associated with the 660-km discontinuity. Based upon the close spatial connection between the thickened MTZ and the location of the subducted slabs, we proposed that the thick MTZ was due to the subduction of the Alpine slab through the upper MTZ and the presence of remnants of subducted oceanic lithosphere in the MTZ. The uplift associated with the 410-km discontinuity provided independent evidence of the subduction depth of the Western Alps slab. In the Alpine foreland in eastern France, we observed localized arc-shaped thinning of the MTZ caused by a 12 km depression of the 410-km discontinuity, which has not been previously reported. This depression indicated a temperature increase of 120 K in the upper MTZ, and we proposed that it was caused by a small-scale mantle upwelling. Hardly any uplift of the 660 km discontinuity was observed, suggesting that the thermal anomaly was unlikely to be the result of a mantle plume. We observed that the thinning area of the MTZ corresponded to the area with the highest uplift rate in the Western Alps, which may have indicated that the temperature increase caused by the mantle upwelling contributed to the topographic uplift.
    Description: Published
    Description: 117267
    Description: 1T. Struttura della Terra
    Description: JCR Journal
    Keywords: receiver function, mantle transition, slab subduction ; Receiver function for the Western Alps ; 04.07. Tectonophysics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 174
    Publication Date: 2023-01-17
    Description: Explosive activity preceding the ~40 ka Campanian Ignimbrite (CI) eruption in the Neapolitan volcanic area, Southern Italy, has long been speculated based on the occurrences of widespread tephra layers, with a Campanian geochemical signature, such as the C-22, X-5, and X-6, preserved in Mediterranean Marine Isotope Stage (MIS) 5 sedimentary records. However, previous studies of pre-CI pyroclastic units occurring in close proximity of the Neapolitan volcanoes, including Campi Flegrei, Somma-Vesuvius, Ischia and Procida islands, did not allow a conclusive identification of the near-source equivalents of these tephra markers. Here we present a comprehensive characterization of four pyroclastic units from the Campanian Plain, comprising major and trace element glass compositions, Sr–Nd isotopes and 40Ar/39Ar dating. Our data allowed the identification of the medial equivalents of the MIS 5 tephra markers, including the widespread C-22, X-5, and X-6 tephra, and their assignment to previously undocumented Campi Flegrei activity between 109 and 92 ka. In addition to substantially extending Campi Flegrei explosive activity deeper in time, and thus providing the basis for a revaluation of its history, our findings provide new precise radioisotopic dating to better constrain the chronology of the millennial scale climatic oscillations of the MIS 5c-d in the Mediterranean area and possibly on a larger scale.
    Description: Published
    Description: 103785
    Description: 1V. Storia eruttiva
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 175
    Publication Date: 2023-01-19
    Description: Argnani (2021, hereinafter ARG2021) commented on the paper by Barreca et al. (2021, hereinafter BRC2021) titled: “The Strait of Messina: Seismotectonics and the source of the 1908 earthquake”, in which a new seismotectonic model and constraints on the possible source fault (the so-called W-Fault) for the 1908 disastrous seismic event were provided. Results from BRC2021 led to a revision of most of the previously published papers on the issue. ARG2021 commented both on the recent activity of the W-Fault and even about its existence in the offshore. In fact, according to the author's inferences: “it may belong to a fault system that is no longer active” and, contradictorily, “the offshore occurrence of the W-Fault is not supported by the data”. The comment is mostly based on a new tectonic interpretation that the author performed directly on the BRC2021 figures, where the offshore portion of the W-fault is illustrated. In this reply, we demonstrate that the interpretation provided by ARG2021 is affected by several oversights that led the author to erroneous conclusions about the issue. Accordingly, we strongly confirm both the occurrence of the W-Fault in the offshore and the present-day activity of this structure, the only active fault capable of producing large earthquakes in the Strait of Messina area.
    Description: Published
    Description: 103962
    Description: 3T. Fisica dei terremoti e Sorgente Sismica
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 176
    Publication Date: 2023-03-01
    Description: In this paper, we propose an innovative machine learning approach called NESTORE, which analyses seismic clusters to forecast strong earthquakes of magnitudes similar or greater to those of the mainshock. The method analyzes the seismicity in the first hours/days after the mainshock and provides the probability of having a strong subsequent earthquake. The analysis is conducted at various stages of time to simulate the increase in knowledge over time. We address the main problem of statistics and machine learning when applied to spatiotemporal variation of seismicity: the small datasets available, on the order of tens or fewer instances, need a more accurate analysis with respect to the classical testing procedures, where hundreds or thousands of data are available. In addition, we develop a more robust NESTORE method based on a jackknife approach (rNESTORE), and we successfully apply it to California seismicity.
    Description: Funded by a grant from the Italian Ministry of Foreign Affairs and International Cooperation.
    Description: Published
    Description: 106879
    Description: 6T. Studi di pericolosità sismica e da maremoto
    Description: 7T. Variazioni delle caratteristiche crostali e "precursori"
    Description: JCR Journal
    Keywords: Largest aftershocks ; Machine Learning ; 04.06. Seismology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 177
    Publication Date: 2023-03-01
    Description: The European Union (EU) has firmly positioned itself as a global leader in promoting and implementing nature-based solutions (NBS). The recently released EU Biodiversity Strategy for 2030, Strategy on Adaptation to Climate Change, and Forest Strategy - all representing key pillars of the ambitious European Green Deal (EGD) - rely on NBS to both preserve and restore ecosystem integrity and increase climate resilience. Although research and policy in Europe have advanced the conceptualization and operationalization of NBS, a much wider adoption is needed to reach the ambitious goals of the EGD and fulfil its vision of transforming into a sustainable, climate-neutral, climate resilient, fair, and prosperous EU by 2050. In this paper, we review recent EU-supported research, policy, and practices to identify critical dimensions that still need to be addressed for greater uptake of NBS. While recognising the multiple societal challenges NBS can target, we build on the key messages from the ‘5th European Climate Change Adaptation conference ECCA 2021′ and focus our analysis on NBS for climate change adaptation and disaster risk reduction. We screen a wide range of NBS cases across the EU and identify-three core challenges to implementation: the lack of a comprehensive evidence base on the effectiveness of NBS to address targeted challenges; the need for a greater involvement of the private sector in financing NBS; and opportunities for enhancing stakeholder engagement in the successful design and implementation of NBS. We take these challenges as the starting point for a broader reflection and critical discussion on the role of i) knowledge, i) finance, including investments in NBS and divestments from nature-negative projects, and iii) governance and policy frameworks to enable the uptake of NBS. We conclude by identifying options for the EU to foster the uptake of NBS in research, policy and practice.
    Description: Published
    Description: 100450
    Description: 4A. Oceanografia e clima
    Description: JCR Journal
    Keywords: Nature-based solutions ; European Union ; European Green Deal ; Climate change adaptation ; Disaster risk reduction ; 05.08. Risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 178
    Publication Date: 2023-03-02
    Description: © The Author(s), 2022. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Leistenschneider, C., Le Bohec, C., Eisen, O., Houstin, A., Neff, S., Primpke, S., Zitterbart, D., Burkhardt-Holm, P., & Gerdts, G. No evidence of microplastic ingestion in emperor penguin chicks (Aptenodytes forsteri) from the Atka Bay colony (Dronning Maud Land, Antarctica). Science of The Total Environment, (2022): 158314, https://doi.org/10.1016/j.scitotenv.2022.158314.
    Description: Microplastic (〈5 mm; MP) pollution has been an emerging threat for marine ecosystems around the globe with increasing evidence that even the world's most remote areas, including Antarctica, are no longer unaffected. Few studies however, have examined MP in Antarctic biota, and especially those from Antarctic regions with low human activity, meaning little is known about the extent to which biota are affected. The aim of this study was to investigate, for the first time, the occurrence of MP in the emperor penguin (Aptenodytes forsteri), the only penguin species breeding around Antarctica during the austral winter, and an endemic apex predator in the Southern Ocean. To assess MP ingestion, the gizzards of 41 emperor penguin chicks from Atka Bay colony (Dronning Maud Land, Antarctica), were dissected and analyzed for MP 〉500 μm using Attenuated Total Reflection Fourier-transform Infrared (ATR-FTIR) spectroscopy. A total of 85 putative particles, mostly in the shape of fibers (65.9 %), were sorted. However, none of the particles were identified as MP applying state-of-the-art methodology. Sorted fibers were further evidenced to originate from contamination during sample processing and analyses. We find that MP concentrations in the local food web of the Weddell Sea and Dronning Maud Land coastal and marginal sea-ice regions; the feeding grounds to chick-rearing emperor penguin adults, are currently at such low levels that no detectable biomagnification is occurring via trophic transfer. Being in contrast to MP studies on other Antarctic and sub-Antarctic penguin species, our comparative discussion including these studies, highlights the importance for standardized procedures for sampling, sample processing and analyses to obtain comparable results. We further discuss other stomach contents and their potential role for MP detection, as well as providing a baseline for the long-term monitoring of MP in apex predator species from this region.
    Description: This study was supported by the Alfred Wegner Institute (AWI; Germany), the Ricola Foundation (Switzerland), the Freiwillige Akademische Gesellschaft Basel (FAG; Switzerland), the CNRS-France and the RTPI-NUTRESS (CSM Monaco & CNRS University of Strasbourg France).
    Keywords: Aptenodytes forsteri ; Microplastics ; ATR-FTIR ; Stomach content ; Antarctica ; Weddell Sea & Dronning Maud Land
    Repository Name: Woods Hole Open Access Server
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  • 179
    Publication Date: 2023-03-02
    Description: This study analyses the morphological changes induced by eruptive activity at Stromboli volcano (Italy) during and after events occurring during July–August 2019. This period was characterized by intense eruptive activity (two paroxysmal explosions, a two-month-long lava emission, and more intense and frequent “ordinary” explosive activity) that produced significant changes within the region known as Sciara del Fuoco, located on the most unstable, north-western flank of the volcano. Since September 2019, the eruptive activity waned but remained intense, and erosive phenomena continued to contribute to the re-shaping of the Sciara del Fuoco. The morphological changes described here were documented by integrating topographic (PLÉIADES satellite tri-stereo Digital Elevation Models) and multibeam bathymetric data, acquired before, during, and after the paroxysmal events. This allowed the study of the cumulative effect of the different processes and the characterization of the different phases of accumulation/emplacement, erosion, remobilization and re-sedimentation of the volcaniclastic materials. Data acquired at several periods between September 2018 and April 2020, allowed a comparison of the subaerial and submarine effects of the 2019 events. We find evidence of localized, significant erosion following the two pyroclastic density currents triggered by the paroxysmal explosion of the 3 July 2019. We interpret this erosion as being caused by submarine and subaerial landslides triggered by the propagation of pyroclastic density currents down the Sciara del Fuoco slope. Immediately after the explosion, a lava field accumulated on the sub-aerial slope, produced by effusive activity which lasted about two months. Subsequently, the newly emplaced lava, and in particular its breccia, was eroded, with the transfer of material onto the submarine slope. This work demonstrates how repeated topo-bathymetric surveys allowed identification of the slope processes that were triggered in response to the rapid geomorphological variations due to the eruptive activity. The surveys also allowed distinction of whether estimated volumetric losses were the result of single mass-flows or gradual erosive processes, with implications on the related geohazard. Furthermore, this work highlights how submarine slope failures can be triggered by the entry into the water of pyroclastic density currents, even of modest size. These results are important for the development and improvement of an early warning system for tsunami-induced by mass flows, both in Stromboli and for island-based and coastal volcanoes elsewhere, where landslides and pyroclastic density currents can trigger significant, potentially destructive, tsunami waves.
    Description: Published
    Description: 108093
    Description: 5V. Processi eruttivi e post-eruttivi
    Description: JCR Journal
    Keywords: Digital Elevation Models ; PLÉIADES ; Repeated bathymetric surveys ; Volcano geomorphology ; Submarine morphology ; Stromboli ; Active volcano ; Aeolian Archipelago ; 04.08. Volcanology
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  • 180
    Publication Date: 2023-03-02
    Description: An innovative method of estimating the relative risk of buildings exposed to seismic and tsunami hazards in volcanic islands is applied to Stromboli (Italy), a well-known stratovolcano affected by moderate earthquakes and mass-flow-induced tsunamis. The method uses a pre-existing quali-quantitative analysis to assess the relative risk indices of buildings, which provide comparative results useful for prioritisation purposes, in combination with a historical-geographical settlement analysis consistent with the ‘territorialist’ approach to the urban and regional planning and design. The quali-quantitative analysis is based on a new proposed survey-sheet model, useful to collect building information necessary for the relative risk estimation, whereas the historical-geographical investigation is based on the multi-temporal comparison of aerial and satellite images. The proposal to combine two consolidated methods represents an innovation in estimating relative risk. Considering that Stromboli Island had never been subjected to similar analyses, the results of the relative seismic risk assessment are novel and moreover identify buildings with a fairly-low and spatially-uniform relative risk. The results of the relative tsunami risk assessment are consistent with results of similar past studies, identifying buildings with a higher relative risk index on the northern coast of the island. The combined use of a building-by-building survey with a multi-temporal analysis of settlements allows obtaining a higher detail than previously available for the region. If adequately modified, the proposed combination of methods allows assessing relative risk also considering other geo-environmental hazards and their cascading effects, in a multi-hazard risk assessment perspective.
    Description: Published
    Description: 103002
    Description: 6V. Pericolosità vulcanica e contributi alla stima del rischio
    Description: JCR Journal
    Keywords: Relative risk assessment ; Seismic risk ; Tsunami risk ; Volcanic islands ; Stromboli ; Aeolian archipelago ; 05.08. Risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 181
    Publication Date: 2023-03-02
    Description: The Fucino Pliocene-Quaternary extensional basin represents a puzzling tectonic structure in the central part of the Apennine chain (Italy). Bordered by seismogenetic faults responsible for strong earthquakes in the last millennium (Mw = 6–7), differently from other elongated intermontane basins in this area, it has a rounded shape and extends for 15–20 km both in the E-W and N-S directions. This structural peculiarity is also demonstrated by the very intense gravity low, with amplitude 〉30 mGal (e.g., Cella et al., 2021), associated with this basin. Available reflection seismic data in this area are often considered of low quality (e.g., Compagnia Mediterranea Idrocarburi, 1999), and no deep well (i.e., 〉200 m depth) is present in this basin, so that its structure at depth results poorly constrained. In a recent paper, Mancinelli et al. (2021; hereafter this paper will be referred to as MSPM), by forward modelling residual gravity data try to confirm a recent 2D seismic stratigraphic interpretation (Patruno and Scisciani, 2021) and the relative model of the Fucino basin structure. In this interpretation of seismic data, the Pliocene-Quaternary units infilling the basin overlies an older (Messinian) siliciclastic flysch, instead of a carbonate substrate as hypothesized in previous studies (e. g., Cavinato et al., 2002; Cella et al., 2021). The forward gravity modelling attempted in MSPM would confirm the presence of huge volumes of Miocene sediments, with a thickness up to 1000 m, and would support the hypothesis of the presence of a, rapidly filled, transient Messinian foredeep basin. However, we have concerns about the quality of the gravity modelling proposed in MSPM, and consequently we are doubtful about the geological conclusions that are drawn from it.
    Description: Published
    Description: 229540
    Description: 3T. Fisica dei terremoti e Sorgente Sismica
    Description: JCR Journal
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  • 182
    Publication Date: 2023-03-06
    Description: Nowadays, the coating industry offers a wide range of products to protect, decorate, and perform special functions on surfaces of objects such as automobiles, aerospace aircrafts, heavy industrial machines and structures, consumable toys, and many other products. The use of coatings as a corrosion protection agent is of great interest in the research and development industries, acting as a barrier between the material substrate and the corrosive elements. In the present work, we have tested the anti-corrosion performances of three types of protective coatings, derived from calcium-phosphate (CaP) minerals, ethyl silicate (TEOS) and polysilazanes. These coatings have been applied on different lapideous materials that belong to the groups of siliceous and carbonaceous rocks. CaP minerals and TEOS coatings are performed by the immersion of samples in baths of crafted solutions, whereas polysilazanes are applied on surfaces with techniques of spraying and brushing. Raw and coated samples have been analysed by SEM/EDX and FTIR to address their effective functionalization of the surfaces. The coated lapideous samples have been tested with corrosive agents to simulate decay processes in harsh acidic environments. The main results reveal that PHPS treated samples offers a considerable higher level of protection against acidic attack compared to the other protective coatings. Moreover, we highlighted a different behaviour among siliceous and carbonaceous surfaces treated with PHPS, as the former reveals a much longer survivability in acidic environments.
    Description: Published
    Description: 128507
    Description: 1TR. Georisorse
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 183
    Publication Date: 2023-03-06
    Description: The phenomenology of lava flow emplacement involves complex physical processes related to crystallization, eruption rate, temperature, crust solidification, and a variety of other factors. Changes in effusion rate are a natural part of lava flow emplacement and can complicate lava flow morphology and propagation. Analog experiments are a useful tool for investigating the role of changing effusion rates on flow propagation because they allow reasonably precise control of conditions and detailed documentation of resulting flows. Experimental datasets that investigate the impact of variable effusion rates on flow propagation can be used to enhance fundamental understanding of flow processes and to inform numerical models for hazards forecasts. In this study, we address the effects of decreasing and increasing eruption rates (Q) on four emplacement modes common to lava flows: resurfacing, marginal breakouts, inflation, and lava tubes. Laboratory analogue experiments using polyethylene glycol (PEG) 600 wax were used to derive Ψ, a dimensionless parameter that relates crust formation (ts) and lateral advection (ta) timescales of a viscous gravity current. We conducted 120 experiments using a peristaltic pump to inject dyed PEG wax into a chilled bath (∼ 0 °C) in a tank with a roughened base at a slope of 0°. The experiments were divided into two conditions: decreasing Q with time (condition 1) and increasing Q with time (condition 2). We controlled for volume of extruded wax, temperature, instantaneous eruption rate, Ψ, and duration of the decrease or increase in eruption rate. Results indicate that the duration of the pulsatory eruption rate, the experimental condition, initial Ψ, and the extruded volume influence the presence and strength of a crust (or lack thereof) which in turn influences the onset and extent of the four emplacement modes investigated. Prolonged increase in eruption rates favored resurfacing, widespread marginal breakouts and flow advancement, inflation, and some tube formation, while the specific morphology and area covered was controlled by an extensive, coherent crust, which in turn depended on initial Ψ and duration of the initial eruptive stage. Prolonged decreasing eruption rates promoted localized marginal breakouts, inflation, and tube formation. The duration of the pulse during the eruption rate change affected the likelihood and/or significance of the mode of emplacement. Similar observations were made on the early stages of the 2021 Fagradalsfjall eruption in Iceland to demonstrate the utility of the wax experiments in interpreting natural systems.
    Description: Published
    Description: 107674
    Description: 5V. Processi eruttivi e post-eruttivi
    Description: JCR Journal
    Keywords: Lava flows ; analogue experiments ; 04.08. Volcanology
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  • 184
    Publication Date: 2023-03-06
    Description: The Arabian Peninsula (AP), the largest peninsula in the world, contains hot spot’ areas for intensive dust storms. Dust sources outside the AP can also represent ‘hot spots’ that heavily impact the AP. This study explores the sourc and transport pathways of severe dust storm events over the AP over nine years (2010–2018) using MODIS Aqua and Terra satellites (0.25–0.5 km/pxl resolution) combined with the HYSPLIT model and synoptic meteorology. The study identified ten dust source ‘hot spots’ that affect the AP; two are local (within the AP) and eight are regional (outside the AP). The identified local dust sources were (1) the Empty Quarter and (2) the Mesopotamian flood plain in southern Iraq, while the regional dust sources were (3) the Syria-Iraq border, (4) Hamun-e Jaz Murian, (5) Coastal desert of Iran, (6) Seistan basin ephemeral lakes, (7) Hamun-e Mashkel, (8) Thar desert of Rajasthan, (9) Nile River basin, and (10) Wadi Langeb Tokar Delta. To the best of our knowledge, this is the first study to investigate the emission and transport of dust storms over the AP at the local and regional/subcontinental levels using medium-high resolution remote sensing. This study has important implications for the international community and the multilateral environmental agreements related to desert dust.
    Description: Published
    Description: 105932
    Description: 7SR AMBIENTE – Servizi e ricerca per la società
    Description: JCR Journal
    Keywords: Dust Storms ; MODIS ; Empty Quarter ; Mesopotamia ; Arabian Peninsula.
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 185
    Publication Date: 2023-03-06
    Description: Faults are characterized by a complex internal architecture. In carbonates, the geometry, attitude, and distribution of fault-related fractures and subsidiary faults can largely affect the petrophysical properties and hydraulic behavior of the fault zone. This work investigates the footwall damage zone of a seismic-scale normal fault (throw ∼ 300 m) from a structural, petrophysical and seismic point of view. The studied Venere Fault (VF) bounds the intra-mountain Fucino Basin (central Italy) and crosscuts Lower Cretaceous platform carbonates. A significant portion of the footwall VF damage zone (VF-DZ) is well exposed in the 400 × 200 m Santilli Quarry. There, we assess the amount of outcrop-scale fracture porosity and permeability by in-situ fracture analyses and permeability measurements. The results show a composite power-law decay of fracture intensity away from the main slip surfaces, strongly influenced by subsidiary faults. An outcrop-based, digital 2D model of the VF-DZ is constructed and populated with acoustic properties (Vp, Vs and density) derived from both the matrix and fracture porosities. This model is enlarged five times and used for seismic modelling to investigate the seismic signature of the VF-DZ under different but realistic geological and geophysical conditions. Seismic modelling suggests that within the modelled damage zone and for wave frequencies of 20–40 Hz, seismic impedance contrasts associated with subsidiary faults may be imaged, depending on the degree of fracture porosity, fracture aperture, and the illumination angle (a measure of the maximum dip that can be imaged), the last two parameters being controlled by overburden depth. These results have implications for the seismic interpretation and characterization of fault zones in carbonates, and hence for the evaluation of fluid migration through these structures.
    Description: Published
    Description: 104515
    Description: 2T. Deformazione crostale attiva
    Description: JCR Journal
    Keywords: Outcrop-scale fracture analysis and seismic modelling of a basin-bounding normal fault in platform carbonates, central Italy
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 186
    Publication Date: 2023-03-06
    Description: This study aims at evaluating the control exerted by fracture stratigraphy and diagenetic processes on oil first migration through an outcropping, mixed carbonate-siliciclastic succession. The present work included results of sedimentological, paleontological, mineralogical, petrographic, structural, and microstructural analyses carried out on organic-rich shales exposed at the Favignana Island of Sicily, Italy. The analyses focus on Upper Triassic yellowish siltstones and greyish laminated dolomitic limestones, which form a 10’s of m-thick succession exposed along the westernmost portion of the Sicilian fold-and-thrust belt. The studied succession deposited in a coastal lagoon associated to a wide carbonate platform, in which anoxic bottom conditions allowed the preservation of the organic matter forming catagenetic patches and veins/fractures infill. In fact, two orthogonal fracture sets perpendicular to bedding are pervaded by organic matter. They are hence interpreted as structural elements that affected the paleofluid circulation and oil migration within the Triassic source rock. These two orthogonal sets form the background fracture network predating the formation of three other sets infilled mainly with calcite cements. The latest fracture set also includes barite cements implying a hydrothermal origin (〈200 ◦C), as supported by the R1 and R3 mixed-layer Illite-Smectite (I–S) stacking. Data are consistent with a burial depth of the sedimentary succession of about 3 ± 0.5 km. In light of these considerations, the study area might represent an outcropping stratigraphic and structural analogue of the source rocks buried in the offshore of western Sicily and northern Tunisia.
    Description: Published
    Description: 105400
    Description: 2T. Deformazione crostale attiva
    Description: JCR Journal
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  • 187
    Publication Date: 2023-03-06
    Description: Fluid geochemistry in active fault zones has been proven to be sensitive to tectonic activity. The North China Craton (NCC) has attracted much attention because of its complex and intense tectonic activity. In this study, fluid geochemistry in the primary active fault zones in the NCC was investigated, including inference of its tectonic activity. Stronger degassing from soil and springs has been observed in the northeastern Tibetan Plateau (NETP) and the Zhang-Bo seismic zone (ZBSZ) than in the other seismic zones. Both geological soil gas and deepderived gas (crust- or mantle-derived gas) from springs were concentrated there. Also, a comprehensive analysis has indicated that the development of new fractures might have occurred widely beneath the NETP and ZBSZ because of the strong regional tectonic activity there. The 3He/4He and 4He/20Ne of gas from the springs in the ZBSZ suggest that the low-velocity zone 20– 40 km deep might be a magmatic intrusion derived from the mantle. However, crust-derived gas accompanied with a negligible mantle-derived component has been detected in the Diebu-Bailongjiang fault (DBF), the West Qinling fault (WQLF), and the Liupanshan fault (LPSF) in the NETP. There, the occurrence of more new fractures was probable, in accordance with the obvious δ18O shift of the water from the springs in the fault zones. This suggests that a channel flow, also depicted by the low-velocity zone 20– 40 km deep, could have formed within the crust and that the probable leading front reached the LPSF.
    Description: Published
    Description: 121048
    Description: 7T. Variazioni delle caratteristiche crostali e "precursori"
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 188
    Publication Date: 2023-02-22
    Description: The understanding of the Earth’s magnetic field variations over time on the African continent is fundamental for several reasons. For instance, the most important feature of the present geomagnetic field, the South Atlantic Anomaly (SAA) characterized by weaker geomagnetic strength values than those expected for their latitudes, may have emerged in South Africa at the beginning of the second millennium CE. Here, we first selected the available volcanic and archaeomagnetic data following a set of three criteria inspired by the FAIR principles. We then built a first regional geomagnetic model for Africa covering the last 4000 years, using a revised version of the spherical cap harmonic (SCH) analysis in 2 dimensions. The new regional model shows, at the Earth’s surface, the westward migration of the SAA from the Indian Ocean over Africa since 1100 CE. In addition, the regional model is tested as a paleomagnetic dating tool by re-dating previous archaeomagnetic data from Africa and thus can be used to date other African archeological sites and the numerous active and dormant volcanoes of the East African System.
    Description: Published
    Description: 106855
    Description: 1A. Geomagnetismo e Paleomagnetismo
    Description: JCR Journal
    Keywords: geomagnetic modeling ; Africa
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 189
    Publication Date: 2023-02-21
    Description: © The Author(s), 2022. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Lozier, M., Bower, A., Furey, H., Drouin, K., Xu, X., & Zou, S. Overflow Water pathways in the North Atlantic. Progress In Oceanography, (2022): 102874, https://doi.org/10.1016/j.pocean.2022.102874.
    Description: As part of the international Overturning in the Subpolar North Atlantic Program (OSNAP), 135 acoustically-tracked deep floats were deployed to track the spreading pathways of Iceland-Scotland Overflow Water (ISOW) and Denmark Strait Overflow Water (DSOW) from 2014 to 2018. These water masses, which originate in the Nordic Seas, are transported by the deepest branch of the Atlantic Meridional Overturning Circulation (AMOC). The OSNAP floats provide the first directly-observed, comprehensive Lagrangian view of ISOW and DSOW spreading pathways throughout the subpolar North Atlantic. The collection of OSNAP float trajectories, complemented by model simulations, reveals that their pathways are (a) not restricted to western boundary currents, and (b) remarkably different from each other in character. The spread of DSOW from the Irminger Sea is primarily via the swift deep boundary currents of the Irminger and Labrador Seas, whereas the spread of ISOW out of the Iceland Basin is slower and along multiple export pathways. The characterization of these Overflow Water pathways has important implications for our understanding of the AMOC and its variability. Finally, reconstructions of AMOC variability from proxy data, involving either the strength of boundary currents and/or the property variability of deep waters, should account for the myriad pathways of DSOW and ISOW, but particularly so for the latter.
    Description: MSL gratefully acknowledges the support from the Physical Oceanography Program of the U.S. National Science Foundation (Grant OCE-2017522). ASB, HHF and SZ gratefully acknowledge the support from the Physical Oceanography Program of the U.S. National Science Foundation (Grant OCE-1756361). KLD gratefully acknowledges the support from the Physical Oceanography Program of the U.S. National Science Foundation (Grant OCE-1851075). XX gratefully acknowledges the support from the Physical Oceanography Program of the U.S. National Science Foundation (Grant OCE-2038449). RAFOS float data can be accessed at Woods Hole Open Access Server (https://doi.org/10.26025/1912/24388).
    Repository Name: Woods Hole Open Access Server
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  • 190
    Publication Date: 2023-02-24
    Description: We use the tidal deformations of the Moon induced by the Earth and the Sun as a tool for studying the inner structure of our satellite. Based on measurements of the degree-two tidal Love numbers $k_2$ and $h_2$ and dissipation coefficients from the GRAIL mission, Lunar Laser Ranging and Laser Altimetry on board of the LRO spacecraft, we perform Monte Carlo samplings for 120,000 possible combinations of thicknesses and viscosities for two classes of the lunar models. The first one includes a uniform core, a low viscosity zone (LVZ) at the core-mantle boundary, a mantle and a crust. The second one has an additional inner core. All models are consistent with the lunar t otal mass as well as its moment of inertia. By comparing predicted and observed parameters for the tidal deformations we find that the existence of an inner core cannot be ruled out. Furthermore, by deducing temperature profiles for the LVZ and an Earth-like mantle, we obtain stringent constraints on the radius (500 $\pm$ 1) km, viscosity, $(4.5 \pm 0.8) \times10^{16}$ Pa$\cdot$s and the density (3400 $\pm$ 10) kg/m$^3$ of the LVZ. We also infer the first estimation for the outer core viscosity, (2.07 ± 1.03) × 10$^{17}$ Pa·s, for tw o different possible structures: a Moon with a 70 km thick outer core and large inner core (290 km radius with a density of 6000 kg/m$^{3}$), and a Moon with a thicker outer core (169 km thick) but a denser and smaller inner core (219 km radius for 8000 kg/m$^{3}$).
    Description: Published
    Description: 115426
    Description: 5IT. Osservazioni satellitari
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 191
    Publication Date: 2023-02-15
    Description: Tajogaite cone in the Cumbre Vieja ridge (La Palma, Canary Islands) erupted between 19 September and 13 December 2021. The tephra and lava sourced from the newly formed fissure rapidly built a pyroclastic cone. During the early days of eruption and after several small-scale landslides, the west flank of the edifice partially collapsed on 25 September, breaching the cone and emplacing a prominent raft-bearing lava flow. Our research combines direct observations, digital elevation models, thermal and visible imaging, and textural and compositional investigation of the explosive products to describe and characterize the edifice growth and collapse. The cone built over a steep slope (26◦) and its failure occurred after an intense phase of lava fountaining (up to 30 m3 s􀀀 1) that produced rapid pyroclastic accumulation. We suggest that an increased magma supply, to an ascent rate of 0.30 m s􀀀 1, led to the rapid growth of the cone (at 2.4 × 106 m3 day􀀀 1). Simultaneously, the SW lava flow reactivated and formed a lava ‘seep’ that undercut the flank of the cone, triggering a lateral collapse via rotational rockslide that moved at minimum speeds of 34–70 m h􀀀 1. The lateral collapse formed a ~ 200 m wide scar, involving 5.5 × 106 m3 of material, and covered 1.17 km2 with decametric edifice portions and raft-bearing lava. The collapse produced a modest change in the vent geometry, but did not affect eruptive activity long term. A short pause in the eruption after the collapse may have been favored by rapid emptying of the shallower magma system, reducing ascent rates and increasing crystallization times. These results reveal the complex chain of events related to the growth and destruction of newly formed volcanic cones and highlight hazards when situated close to inhabited areas.
    Description: Published
    Description: 107642
    Description: 5V. Processi eruttivi e post-eruttivi
    Description: JCR Journal
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  • 192
    Publication Date: 2023-02-14
    Description: A two-dimensional basin and petroleum system modeling approach was applied to the Burano-Bolognano petroleum system (Central Italy) to constrain some factors (position, lateral extension and maturity of the source rock, the role of fractures and faults in hydrocarbon migration) which influenced its structural evolution and the related migration pathways. The petroleum system extends from the Majella Mountain to the northern Cigno, Vallecupa, Bonanno oil fields, intensively explored during the past century. Some features, such as the location and extension of the source rock and its maturity, and hydrocarbon pathways, are still undefined. Thus, we developed a 3D geological static model of the Cenozoic carbonate succession and then, we performed basin modeling along a 2D geological section, integrating the petrophysical properties of rocks measured in laboratory. Our results prove that the Burano source rock reached a low-middle maturity, and the best representation of the actual hydrocarbon occurrences is reached when the source rock is at north of the Majella Mountain with a minimum extension of 3 km. For the BBPS a strong lateral migration and a gradual oil biodegradation towards the Majella area must be considered. Moreover, modeling results highlight a minor control of the faults on the migration in this area. This basin modeling is relevance for investigations in similar settings since carbonate-ramp reservoir studies are usually very challenging to be correctly modeled due to their high heterogeneities.
    Description: Published
    Description: 105436
    Description: 1TR. Georisorse
    Description: JCR Journal
    Keywords: Basin modeling ; Carbonate reservoir ; Geological modeling ; Hydrocarbon migration and accumulation ; 04.02. Exploration geophysics
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  • 193
    Publication Date: 2023-02-14
    Description: North-east Java is part of a large sedimentary basin containing hydrocarbon provinces that feature diffuse hydrothermal systems, mud volcanoes, and degassing sites. Seismic profiles acquired to explore the basin reveal a broad distribution of palaeo- and modern piercement structures. The Watukosek fault system links the volcanic arc, to the south, with the Sidoarjo province, to the north. Several piercement structures, including the Kalang Anyar mud volcano, are hosted along this left-lateral strike-slip system that favors the migration of crustal fluids in this part of the basin. Here, we present a multidisciplinary geological, geophysical and geochemical study conducted at Kalang Anyar where dozens of seepage sites are active in the crater area and intermittently emit bursts oil, gas, mud, and water. The emitted gasses are methane-dominated with smaller amounts of heavier hydrocarbons and CO2. Unlike most mud volcanoes, at Kalang Anyar the mixed-thermogenic origin of the methane is coupled with geothermal anomalies, as indicated by helium and CO2 isotopic values (δ13CCO2 as high as −4‰) that suggest the input of mantle-derived gas. Our gas flux measurements reveal that Kalang Anyar emits about 1.62 and 5.75 t yr−1 of CO2 and CH4, respectively. The intense bubbling gives rise to a typical drumbeat seismic signal characterized by dominant frequencies around of 3–4 Hz (and up to 15 Hz). We interpret the drumbeat as fluids rising and resonating through shallow plumbing system of Kalang Anyar. Erupted clasts with different lithologies and shells are scattered across the mud volcano area, while the edges of the crater zone include cubic meter-sized carbonate-cemented blocks and ridges that contain siliciclastic sediments and abundant chemosymbiotic bivalves. Carbon isotope analyses of the carbonate cement (δ13C as low as −48.8‰) identify the latter as methanogenic chemoherms. Radiocarbon (14C) dating of bivalves cemented in the blocks indicates an age of 1890-1488 BP. These results indicate that the activity of Kalang Anyar MV dates from when the area was below sea level and that the microbially-mediated precipitation of carbonates was ongoing during subaqueous methane seepage at the crater site. To the best of our knowledge, Kalang Anyar is the first example of a mud volcano that progressed from subaqueous to subaerial conditions during marine regression, displaying evidence of former marine activity (i.e. methanogenic carbonates) and current subaerial degassing at numerous seepage sites. Potentially eruptive phases represent a clear geohazard for the numerous settlements constructed inside the mud volcano. In light of this, it may be prudent to apply stricter rules for development activities, such as housing construction permits that consider the possibility of potentially catastrophic events, and apply steps to mitigate these hazards.
    Description: Published
    Description: 105970
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Keywords: mud volcano ; geochemistry ; 04.08. Volcanology
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  • 194
    Publication Date: 2023-02-14
    Description: In this study, we investigate the negative ionospheric response over the European sector during two storms that took place on 8 September 2017, primarily, by exploiting observations over ten European locations. The spatial and temporal variations of TEC, foF2 and hmF2 ionospheric characteristics are examined with the aim to explain the physical mechanisms underlying the strong negative ionospheric response. We detected very sharp electron density (in terms of foF2 and TEC) decrease during the main phases of the two storms and we attributed this phenomenon to the large displacement of the Midlatitude Ionospheric Trough (MIT). Our study also revealed that the two storms show different features caused by different processes. In addition, Large Scale Traveling Ionospheric Disturbances (LSTIDs) were observed during both storms, followed by enhanced Spread F conditions over Digisonde stations. The regional dependence of ionospheric storm effects was demonstrated, as the behavior of ionospheric effects over the northern part of Europe differed from that over the southern part.
    Description: Published
    Description: 1104-1120
    Description: 2A. Fisica dell'alta atmosfera
    Description: JCR Journal
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  • 195
    Publication Date: 2023-02-20
    Description: Ongoing studies conducted in northern polar regions reveal that permafrost stability plays a key role in the modern carbon cycle as it potentially stores considerable quantities of greenhouse gases. Rapid and recent warming of the Arctic permafrost is resulting in significant greenhouse gas emissions, both from physical and microbial processes. The potential impact of greenhouse gas release from the Antarctic region has not, to date, been investigated. In Antarctica, the McMurdo Dry Valleys comprise 10 % of the ice-free soil surface areas in Antarctica and like the northern polar regions are also warming albeit at a slower rate. The work presented herein examines a comprehensive sample suite of soil gas (e.g., CO2, CH4 and He) concentrations and CO2 flux measurements conducted in Taylor Valley during austral summer 2019/2020. Analytical results reveal the presence of significant concentrations of CO2, CH4 and He (up to 3.44 vol%, 18,447 ppmv and 6.49 ppmv, respectively) at the base of the active layer. When compared with the few previously obtained measurements, we observe increased CO2 flux rates (estimated CO2 emissions in the study area of 21.6 km2 ≈ 15 tons day-1). We suggest that the gas source is connected with the deep brines migrating from inland (potentially from beneath the Antarctic Ice Sheet) towards the coast beneath the permafrost layer. These data provide a baseline for future investigations aimed at monitoring the changing rate of greenhouse gas emissions from Antarctic permafrost, and the potential origin of gases, as the southern polar region warms.
    Description: Published
    Description: 161345
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Keywords: Antarctica; ; CO(2) output; ; McMurdo Dry Valleys; ; Permafrost; ; Soil gas survey ; 02.01. Permafrost
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  • 196
    Publication Date: 2023-02-20
    Description: Several regions around the globe are characterized by a seismically active lower crust, at depths where litho­logical and thermal conditions suggest stress release by ductile flow. The Gargano Promontory (GP, southern Italy) is an example where a recently installed seismic network has recorded an intense seismic activity at depths between 20 and 30 km, i.e. in the lower crust. The GP is located in proximity of the Gargano-Dubrovnik line­ament, a seismogenic zone separating the central and southern Adriatic basins. These two basins constitute sites of sediments accumulation since Tertiary times. Another important basin in the region is represented by the Apennine foredeep, that includes the Candelaro area. We analyze the possible mechanisms controlling the dis­tribution of seismicity in the GP to identify the factors that make the lower crust seismically active. To this aim, we construct a thermo-rheological model of a layered continental crust, calibrated on the basis of geometrical, lithological and thermal constraints. The model takes into account various crustal lithologies, the presence of fluids in the crystalline basement, lateral variations of geotherm and stress field. The numerical simulations show that the presence of fluids is a key factor controlling the cluster of seismicity in the lower crust. Moreover, the presence of water in the upper crystalline basement and sedimentary cover provides a plausible explanation for upper crustal seismicity in a zone of very high heat flow SW of the GP. The distribution of the seismicity is probably affected by the composition of the crystalline basement, with mafic bodies injected into the crust during the Paleocene magmatic phase that affected the Mediterranean region. In addition, fluid accumulation and overpressure may occur along detachment levels in the lower crust, leading to clustering of the earthquakes. Based on our findings, we hypothesize that the presence of hydrous diapiric upwelling(s) in the upper mantle can feed a deep fluid circulation system, inducing lower crustal seismicity.
    Description: Published
    Description: 103929
    Description: 4T. Sismicità dell'Italia
    Description: JCR Journal
    Keywords: Lower crust ; Rheology ; Seismology ; Geotherm ; Numerical modeling ; Gargano Promontory (southern Italy)
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 197
    Publication Date: 2023-02-20
    Description: The Qinling orogenic belt and surrounding areas are a junction zone in Central China that connects the North China craton, Yangtze craton and northeastern Tibetan plateau. This area is in a key position within the more general framework where there is eastward extrusion of the Tibetan plateau and westward subduction of the Pacific plate. There is an ongoing scientific debate on how these two main processes are driving the geodynamic evolution of the Qinling orogenic belt and surrounding areas. Specific mechanisms have been proposed, such as lower crustal flow, crustal shortening and big mantle wedge tectonics. Knowledge of the seismic velocity structure helps us understand how these two driving forces affect the tectonic blocks of the study area, as well as test how well the proposed mechanisms to fit the regional velocity structure. For this purpose, a high-resolution P-wave velocity model of the crust and uppermost mantle was obtained by inverting arrival times from local earthquakes that occurred in the Qinling and surrounding region. Our three-dimensional (3D) model suggests that crustal channel flow cannot exist in the whole Qinling orogenic belt, and the localized low-velocity zone generated by the horizontal compressive stress caused by the collision of the Indian and Eurasian plates, is a possible explanation for the growth of the northeastern Tibetan plateau. The contrast in seismic velocities found under the east-Qinling and the west-Qinling orogenic belts implies a different response of these two terranes to the eastward extrusion of the Tibetan plateau. Our velocity model points to relatively stable structural features in the east-Qinling and the Weihe graben, while a low-velocity anomaly in the uppermost mantle of the southernmost Ordos plateau suggests that the lithosphere of the southern Ordos plateau is undergoing destruction.
    Description: Published
    Description: 229619
    Description: 1T. Struttura della Terra
    Description: JCR Journal
    Keywords: Qinling orogenic belt ; Finite difference tomography P-wave velocity ; Crustal and uppermost mantle structure ; High-resolution P-wave velocity model that includes independent Moho data. ; Different response of west- and east-Qinling to the eastward extrusion of the TP. ; The southern Ordos plateau is likely undergoing destruction.
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 198
    Publication Date: 2023-03-07
    Description: In the present paper we introduce a numerical model for the representation of displacement, strain and stress due to single forces embedded in a layered elastic half-space. The code EFGRN/EFCMP (Elastic Forces GReeN functions/Elastic Forces CoMPutation) is able to represent the mechanical effects due to pre-assigned distributions of single forces. Even if internal deformation sources can be described by distributions of equivalent body forces with vanishing resultant and moment, single forces are employed in geophysics to represent hydraulic and/or lithostatic loads, effects of internal density anomalies, and even some kind of seismic events. A distribution of single forces is also used to describe the effects of an inelastic inclusion located inside an elastic medium. In fact, the recent literature shows that poro-elastic and thermo-elastic inclusions can be represented using single forces distributed on their boundaries. EFGRN/EFCMP shares the benefits of rapid and semi-analytical calculation offered by the parent code, EFGRN/EFCMP , which is instead suitable for the representation of extended dislocation sources, as seismic faults. The present code also provides an option for computing the effects of a distribution of single forces embedded in a homogeneous half-space, by using the analytical solutions of Mindlin. Accordingly, EFGRN/EFCMP can be a valid support both for the representation of forward models of deformation sources and for the procedures of inversion of geodetic data in a layered medium. We show some applications of the code and we provide several scripts in MATLAB language which help the user to quickly start using EFGRN/EFCMP
    Description: Published
    Description: 105136
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: JCR Journal
    Keywords: 04.08. Volcanology ; 05.01. Computational geophysics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 199
    Publication Date: 2023-03-13
    Description: The productive but highly exposed coastline of the southern Benguela eastern boundary upwelling system offers limited natural environment for aquaculture. Saldanha Bay located on the west coast of South Africa is one of the few embayments on the coastline that provides a productive and relatively sheltered environment suitable for the cultivation of shellfish. Consequently, bivalve culture in South Africa is centered in Saldanha Bay and is presently targeted for expansion. Pseudo-nitzschia blooms including toxin-producing species are shown to contribute significantly to the phytoplankton of Saldanha Bay specifically in spring and summer. Their dominance at this time of the year, when upwelling is strongest, fits the ecological profile of Pseudo-nitzschia occurring during periods of high turbulence and nutrients. Multiple Pseudo-nitzschia blooms were sampled under varying environmental conditions and the strength of the relationship between Pseudo-nitzschia cell abundance and particulate domoic acid (pDA) content, reflecting bloom toxicity, varied greatly. This variability is the result of the combined influence of species and strain composition of the Pseudo-nitzschia assemblage and the effect of environmental conditions on toxin production. Elevated levels of pDA were associated with higher concentrations of cells of the P. seriata complex differentiated by frustule width (〉3 µm). P. australis was identified as a toxin-producing species and a prominent member of the P. seriata complex. Low DA levels in shellfish in Saldanha Bay are considered a function of low cellular domoic acid (cDA). Silicate limitation has emerged as an important factor inducing DA production in Pseudo-nitzschia species. The high ratio of silicate to nitrate in Saldanha Bay provides a plausible explanation for the low toxin content of Pseudo-nitzschia blooms in the bay and the consequent low risk posed by these blooms to the aquaculture sector.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
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  • 200
    Publication Date: 2023-03-13
    Description: Goniodomin A (GDA, 1) is a phycotoxin produced by at least four species of Alexandrium dinoflagellates that are found globally in brackish estuaries and lagoons. It is a linear polyketide with six oxygen heterocyclic rings that is cyclized into a macrocyclic structure via lactone formation. Two of the oxygen heterocycles in 1 comprise a spiro-bis-pyran, whereas goniodomin B (GDB) contains a 2,7-dioxabicyclo[3.3.1]nonane ring system fused to a pyran. When H2O is present, 1 undergoes facile conversion to isomer GDB and to an α,β-unsaturated ketone, goniodomin C (GDC, 7). GDB and GDC can be formed from GDA by cleavage of the spiro-bis-pyran ring system. GDA, but not GDB or GDC, forms a crown ether-type complex with K+. Equilibration of GDA with GDB and GDC is observed in the presence of H+ and of Na+, but the equilibrated mixtures revert to GDA upon addition of K+. Structural differences have been found between the K+ and Na+ complexes. The association of GDA with K+ is strong, while that with Na+ is weak. The K+ complex has a compact, well-defined structure, whereas Na+ complexes are an ill-defined mixture of species. Analyses of in vitro A. monilatum and A. hiranoi cultures indicate that only GDA is present in the cells; GDB and GDC appear to be postharvest transformation products.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
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