ALBERT

Description: Climate change and urban development threaten health, undermine coping and deepen existing social and environmental inequities. A changing global environment requires transformative social responses: new partnerships, deep engagement with local communities, and innovations to strengthen individual and collective assets. The chapters of this proposed edited volume will be contributed mainly by established and emerging scholars from individuals, representing social work, sociology, development studies, law, government, social anthropology, urbanism, The chapters of this proposed edited volume will be contributed mainly by established and emerging scholars from individuals representing social work, sociology, development studies, public policy, and other social sciences This book is to be used for academics, policy makers, social work students, lecturers and other stakeholders to promote advocacy for vulnerable client groups affected by Climate Change. It gives some measure of hope and make the invisible visible to change.

Description: Despite the importance of surface energy budgets (SEBs) for land-climate interactions in the Arctic, uncertainties in their prediction persist. In situ observational data of SEB components - useful for research and model validation - are collected at relatively few sites across the terrestrial Arctic, and not all available datasets are readily interoperable. Furthermore, the terrestrial Arctic consists of a diversity of vegetation types, which are generally not well represented in land surface schemes of current Earth system models. This dataset describes the data generated in a literature synthesis, covering 358 study sites on vegetation or glacier (〉=60°N latitude), which contained surface energy budget observations. The literature synthesis comprised 148 publications searched on the ISI Web of Science Core Collection.

Description: Organic carbon (OC) stored in Arctic permafrost represents one of Earth's largest and most vulnerable terrestrial carbon pools. Amplified climate warming across the Arctic results in widespread permafrost thaw. Permafrost deposits exposed at river cliffs and coasts are particularly susceptible to thawing processes. Accelerating erosion of terrestrial permafrost along shorelines leads to increased transfer of organic matter (OM) to nearshore waters. However, the amount of terrestrial permafrost carbon and nitrogen as well as the OM quality in these deposits are still poorly quantified. Here, we characterise the sources and the quality of OM supplied to the Lena River at a rapidly eroding permafrost river shoreline cliff in the eastern part of the delta (Sobo-Sise Island). Our multi-proxy approach captures bulk elemental, molecular geochemical and carbon isotopic analyses of late Pleistocene Yedoma permafrost and Holocene cover deposits, discontinuously spanning the last ~52 ka. We show that the ancient permafrost exposed in the Sobo-Sise cliff has a high organic carbon content (mean of about 5 wt%).We found that the OM quality, which we define as the intrinsic potential to further transformation, decomposition, and mineralization, is also high as inferred by the lipid biomarker inventory. The oldest sediments stem from Marine Isotope Stage (MIS) 3 interstadial deposits (dated to 52 to 28 cal kyr BP) and is overlaid by Last Glacial MIS 2 (dated to 28 to 15 cal ka BP) and Holocene MIS 1 (dated to 7–0 cal ka BP) deposits. The relatively high average chain length (ACL) index of n-alkanes along the cliff profile indicates a predominant contribution of vascular plants to the OM composition. The elevated ratio of iso and anteiso-branched FAs relative to long chain (C ≥ 20) n-FAs in the interstadial MIS 3 and the interglacial MIS 1 deposits, suggests stronger microbial activity and consequently higher input of bacterial biomass during these climatically warmer periods. The overall high carbon preference index (CPI) and higher plant fatty acid (HPFA) values as well as high C / N ratios point to a good quality of the preserved OM and thus to a high potential of the OM for decomposition upon thaw. A decrease of HPFA values downwards along the profile probably indicates a relatively stronger OM decomposition in the oldest (MIS 3) deposits of the cliff.

Description: Lake Towuti is a tectonic basin, surrounded by ultramafic rocks. Lateritic soils form through weathering and deliver abundant iron (oxy)hydroxides but very little sulfate to the lake and its sediment. To characterize the sediment biogeochemistry, we collected cores at three sites with increasing water depth and decreasing bottom water oxygen concentrations. Microbial cell densities were highest at the shallow site - a feature we attribute to the availability of labile organic matter and the higher abundance of electron acceptors due to oxic bottom water conditions. At the two other sites, OM degradation and reduction processes below the oxycline led to partial electron acceptor depletion. Genetic information preserved in the sediment as extracellular DNA provides information on aerobic and anaerobic heterotrophs related to Actinobacteria, Nitrospirae, Chloroflexi and Thermoplasmatales. These taxa apparently played a significant role in the degradation of sinking organic matter. However, extracellular DNA concentrations rapidly decrease with core depth. Despite very low sulfate concentrations, sulfate-reducing bacteria were present and viable in sediments at all three sites, as confirmed by measurement of potential sulfate reduction rates. Microbial community fingerprinting supported the presence of taxa related to Deltaproteobacteria and Firmicutes with demonstrated capacity for iron and sulfate reduction. Concomitantly, sequences of Ruminococcaceae, Clostridiales and Methanomicrobiales indicated potential for fermentative hydrogen and methane production. Such first insights into ferruginous sediments show that microbial populations perform successive metabolisms related to sulfur, iron and methane. In theory, iron reduction could reoxidize reduced sulfur compounds and desorb OM from iron minerals to allow remineralization to methane. Overall, we found that biogeochemical processes in the sediments can be linked to redox differences in the bottom waters of the three sites, like oxidant concentrations and the supply of labile OM. At the scale of the lacustrine record, our geomicrobiological study should provide a means to link the extant subsurface biosphere to past environments.

Description: Pore water geochemistry and bulk sediment measurements of downcore profiles covering the upper 100 m-long sequence from site 1A, Lake Towuti, Indonesia

Description: The airborne laser scanning (ALS) datasets were acquired at the Arctic tundra site of Trail Valley Creek (TVC), Northwest Territories, Canada, which is underlain by continuous permafrost. Basic processing and filtering steps were applied to the ALS point cloud. Based on a classification into ground and vegetation points, a Digital Terrain Model (DTM) and rasters of mean and maximum vegetation heights are derived. Detailed metadata are included.

Description: A major uncertainty in determining the mass balance of the Antarctic ice sheet from measurements of satellite gravimetry, and to a lesser extent satellite altimetry, is the poorly known correction for the ongoing deformation of the solid Earth caused by glacial isostatic adjustment (GIA). In the past decade, much progress has been made in consistently modelling the ice sheet and solid Earth interactions; however, forward-modelling solutions of GIA in Antarctica remain uncertain due to the sparsity of constraints on the ice sheet evolution, as well as the Earth's rheological properties. An alternative approach towards estimating GIA is the joint inversion of multiple satellite data - namely, satellite gravimetry, satellite altimetry and GPS, which reflect, with different sensitivities, trends of recent glacial changes and GIA. Crucial to the success of this approach is the accuracy of the space-geodetic data sets. Here, we present reprocessed rates of surface-ice elevation change (Envisat/ICESat; 2003-2009), gravity field change (GRACE; 2003-2009) and bedrock uplift (GPS; 1995-2013). The data analysis is complemented by the forward-modelling of viscoelastic response functions to disc load forcing, allowing us to relate GIA-induced surface displacements with gravity changes for different rheological parameters of the solid Earth. The data and modelling results presented here form the basis for the joint inversion estimate of present-day ice-mass change and GIA in Antarctica. This paper presents the first of two contributions summarizing the work carried out within a European Space Agency funded study, REGINA.

Description: Surface air temperature measurements obtained from different sensors are used to construct a unique time series with one minute time-interval. Apart from differences in design and environmental exposition, periods of missing data also exist in the data series of each sensor. A primary data set was selected in terms of quality and temporal extension. A combination of two different techniques is applied to complete this data set: one is based on the autocorrelation of the series and the other on measurements taken from other sensors. The resulting values constitute a complete series of surface air temperature at AGGO.

Description: The rewetting of peatlands is a promising measure to mitigate greenhouse gas (GHG) emissions by preventing the further mineralization of the peat soil through aeration. In coastal peatland, the rewetting with brackish water can increase the GHG mitigation potential by the introduction of sulfate, a terminal electron acceptor (TEA). Sulfate is known to lower the CH4 production and thus, its emission by favoring the growth of sulfate-reducers, which outcompete methanogens for substrate. The data contain porewater variables such as pH, electrical conductivity (EC) and sulfate, chloride, dissolved CO2 and CH4 concentrations, as well as absolute abundances of methane- and sulfate-cycling microbial communities. The data were collected in spring and autumn 2019 after a storm surge with brackish water inflow in January 2019. Field sampling was conducted in the nature reserve Heiligensee and Hütelmoor in North-East Germany, close to the Southern Baltic Sea coast. We took peat cores using a Russian peat corer in addition to pore water diffusion samplers and plastic liners (length: 60cm; inner diameter 10 cm) at four locations along a transect from further inland towards the Baltic Sea. We wanted to compare the soil and pore water geochemistry as well as the microbial communities after the brackish water inflow to the common freshwater rewetting state. Pore water was extracted using pore water suction samplers in the lab and environmental variables were quantified with an ICP. Microbial samples were sampled from the peat core using sterile equipment. We used quantitative polymerase chain reaction (qPCR) to characterize pools of DNA and cDNA targeting total and putatively active bacteria and archaea. qPCR was performed on key functional genes of methane production (mcrA), aerobic methane oxidation (pmoA) and sulfate reduction (dsrB) in addition to the 16S rRNA gene for the absolute abundance of total prokaryotes. Furthermore, we retrieved soil plugs to determine the concentrations and isotopic signatures of dissolved trace gases (CO2/DIC and CH4) in the pore water.

Description: This dataset provides annually resolved microfacies data from ICDP core 5017-1-A, retrieved from the deep northern Dead Sea basin in 2010/11, for the last glacial-interglacial transition (ca. 14-13 ka BP). Sediments of the Lisan Formation were investigated between ~94.7 and 91.8 m sediment depth below lake floor (lithozone C2) by continuous thin section microscopy. Thin sections were prepared following the standard procedure by Brauer and Casanova (2001) that was adjusted for salty sediments. Thin section analyses were performed on overlapping large-scale thin sections using a Zeiss Axiolab pol microscope at magnifications of 50-400x. Microfacies analyses included varve counting and measurements of varve and sublayer thickness. The amount of varves in erosional gaps was interpolated and the position of mass flow deposits (MFD) is marked.

Description: We present sea ice temperature and salinity data from first-year ice (FYI) and second-year ice (SYI) relevant to the temporal development of sea ice permeability and brine drainage efficiency from the early growth phase in October 2019 to the onset of spring warming in May 2020. Our dataset was collected in the central Arctic Ocean during the Multidisciplinary drifting Observatory for the Study of Arctic Climate (MOSAiC) Expedition in 2019 to 2020. MOSAiC was an international transpolar drift expedition in which the German icebreaker RV Polarstern anchored into an ice floe to gain new insights into Arctic climate over a full annual cycle. In October 2019, RV Polarstern moored to an ice floe in the Siberian sector of the Arctic at 85 degrees north and 137 degrees east to begin the drift towards the North Pole and the Fram Strait via the Transpolar Drift Stream. The data presented here were collected during the first three legs of the expedition, so all the coring activities took place on the same floe. The end dates of legs 1, 2, and 3 were 13 December, 24 February, and 4 June, respectively. The dataset contributed to a baseline study entitled, Deciphering the properties of different Arctic ice types during the growth phase of the MOSAiC floes: Implications for future studies. The study highlights downward directed gas pathways in FYI and SYI by inferring sea ice permeability and potential brine release from several time series of temperature and salinity measurements. The physical properties presented in this paper lay the foundation for subsequent analyses on actual gas contents measured in the ice cores, as well as air-ice and ice-ocean gas fluxes. Sea ice cores were collected with a Kovacs Mark II 9 cm diameter corer. To measure ice temperatures, about 4.5 cm deep holes were drilled into the core (intervals varied by site and leg) . The temperatures were measured by a digital thermometer within minutes after the cores were retrieved. The ice cores were placed into pre-labelled plastic sleeves sealed at the bottom end. The ice cores were transported to RV Polarstern and stored in a -20 degrees Celsius freezer. Each of the cores was sub-sampled, melted at room temperature, and processed for salinity within one or two days. The practical salinity was estimated by measuring the electrical conductivity and temperature of the melted samples using a WTW Cond 3151 salinometer equipped with a Tetra-Con 325 four-electrode conductivity cell. The practical salinity represents the the salinity estimated from the electrical conductivity of the solution. The dataset also contains derived variables, including sea ice density, brine volume fraction, and the Rayleigh number.

Description: Organic carbon (OC) stored in Arctic permafrost represents one of Earth’s largest and most vulnerable terrestrial carbon pools. Amplified climate warming across the Arctic results in widespread permafrost thaw. Permafrost deposits exposed at river cliffs and coasts are particularly susceptible to thawing processes. Accelerating erosion of terrestrial permafrost along shorelines leads to increased transfer of organic matter (OM) to nearshore waters. However, the amount of terrestrial permafrost carbon and nitrogen as well as the OM quality in these deposits are still poorly quantified. Here, we characterise the sources and the quality of OM supplied to the Lena River at a rapidly eroding permafrost river shoreline cliff in the eastern part of the delta (Sobo-Sise Island). Our multi-proxy approach captures bulk elemental, molecular geochemical and carbon isotopic analyses of late Pleistocene Yedoma permafrost and Holocene cover deposits, discontinuously spanning the last ~52 ka. We show that the ancient permafrost exposed in the Sobo-Sise cliff has a high organic carbon content (mean of about 5 wt%).We found that the OM quality, which we define as the intrinsic potential to further transformation, decomposition, and mineralization, is also high as inferred by the lipid biomarker inventory. The oldest sediments stem from Marine Isotope Stage (MIS) 3 interstadial deposits (dated to 52 to 28 cal kyr BP) and is overlaid by Last Glacial MIS 2 (dated to 28 to 15 cal ka BP) and Holocene MIS 1 (dated to 7–0 cal ka BP) deposits. The relatively high average chain length (ACL) index of n-alkanes along the cliff profile indicates a predominant contribution of vascular plants to the OM composition. The elevated ratio of iso and anteiso-branched FAs relative to long chain (C ≥ 20) n-FAs in the interstadial MIS 3 and the interglacial MIS 1 deposits, suggests stronger microbial activity and consequently higher input of bacterial biomass during these climatically warmer periods. The overall high carbon preference index (CPI) and higher plant fatty acid (HPFA) values as well as high C / N ratios point to a good quality of the preserved OM and thus to a high potential of the OM for decomposition upon thaw. A decrease of HPFA values downwards along the profile probably indicates a relatively stronger OM decomposition in the oldest (MIS 3) deposits of the cliff.

Description: We present sea ice temperature and salinity data from first-year ice (FYI) and second-year ice (SYI) relevant to the temporal development of sea ice permeability and brine drainage efficiency from the early growth phase in October 2019 to the onset of spring warming in May 2020. Our dataset was collected in the central Arctic Ocean during the Multidisciplinary drifting Observatory for the Study of Arctic Climate (MOSAiC) Expedition in 2019 to 2020. MOSAiC was an international transpolar drift expedition in which the German icebreaker RV Polarstern anchored into an ice floe to gain new insights into Arctic climate over a full annual cycle. In October 2019, RV Polarstern moored to an ice floe in the Siberian sector of the Arctic at 85 degrees north and 137 degrees east to begin the drift towards the North Pole and the Fram Strait via the Transpolar Drift Stream. The data presented here were collected during the first three legs of the expedition, so all the coring activities took place on the same floe. The end dates of legs 1, 2, and 3 were 13 December, 24 February, and 4 June, respectively. The dataset contributed to a baseline study entitled, Deciphering the properties of different Arctic ice types during the growth phase of the MOSAiC floes: Implications for future studies. The study highlights downward directed gas pathways in FYI and SYI by inferring sea ice permeability and potential brine release from several time series of temperature and salinity measurements. The physical properties presented in this paper lay the foundation for subsequent analyses on actual gas contents measured in the ice cores, as well as air-ice and ice-ocean gas fluxes. Sea ice cores were collected with a Kovacs Mark II 9 cm diameter corer. To measure ice temperatures, about 4.5 cm deep holes were drilled into the core (intervals varied by site and leg) . The temperatures were measured by a digital thermometer within minutes after the cores were retrieved. The ice cores were placed into pre-labelled plastic sleeves sealed at the bottom end. The ice cores were transported to RV Polarstern and stored in a -20 degrees Celsius freezer. Each of the cores was sub-sampled, melted at room temperature, and processed for salinity within one or two days. The practical salinity was estimated by measuring the electrical conductivity and temperature of the melted samples using a WTW Cond 3151 salinometer equipped with a Tetra-Con 325 four-electrode conductivity cell. The practical salinity represents the the salinity estimated from the electrical conductivity of the solution. The dataset also contains derived variables, including sea ice density, brine volume fraction, and the Rayleigh number.

Description: These datasets describe sediment samples taken from the Batagay megaslump, located in Yana Uplands in northeastern Siberia. Most sediment samples were taken from the slump headwall (B19-P1) by rapelling down on a rope from the slump surface and taking samples with a hole saw (diameter 55 mm, 40 mm deep) mounted on a handheld power drill. A second profile (B19-02) of the lowest part of the slump headwall was sampled (~100 m south) using a hammer and axe from the slump floor. Two permafrost sediment blocks (B19-03 and B19-04) at the slump bottom that had fallen from the headwall were sampled using a chainsaw. Finally, a baidzherakh (thermokarst mound; B19-05) in the north of the slump was sampled using a hammer and axe. The samples cover 5 stratigraphical units: 1. lower ice complex, 2. lower sand unit, 3. woody layer, 4. upper ice complex, 5. Holocene cover.

Description: Organic carbon (OC) stored in Arctic permafrost represents one of Earth’s largest and most vulnerable terrestrial carbon pools. Amplified climate warming across the Arctic results in widespread permafrost thaw. Permafrost deposits exposed at river cliffs and coasts are particularly susceptible to thawing processes. Accelerating erosion of terrestrial permafrost along shorelines leads to increased transfer of organic matter (OM) to nearshore waters. However, the amount of terrestrial permafrost carbon and nitrogen as well as the OM quality in these deposits are still poorly quantified. Here, we characterise the sources and the quality of OM supplied to the Lena River at a rapidly eroding permafrost river shoreline cliff in the eastern part of the delta (Sobo-Sise Island). Our multi-proxy approach captures bulk elemental, molecular geochemical and carbon isotopic analyses of late Pleistocene Yedoma permafrost and Holocene cover deposits, discontinuously spanning the last ~52 ka. We show that the ancient permafrost exposed in the Sobo-Sise cliff has a high organic carbon content (mean of about 5 wt%).We found that the OM quality, which we define as the intrinsic potential to further transformation, decomposition, and mineralization, is also high as inferred by the lipid biomarker inventory. The oldest sediments stem from Marine Isotope Stage (MIS) 3 interstadial deposits (dated to 52 to 28 cal kyr BP) and is overlaid by Last Glacial MIS 2 (dated to 28 to 15 cal ka BP) and Holocene MIS 1 (dated to 7–0 cal ka BP) deposits. The relatively high average chain length (ACL) index of n-alkanes along the cliff profile indicates a predominant contribution of vascular plants to the OM composition. The elevated ratio of iso and anteiso-branched FAs relative to long chain (C ≥ 20) n-FAs in the interstadial MIS 3 and the interglacial MIS 1 deposits, suggests stronger microbial activity and consequently higher input of bacterial biomass during these climatically warmer periods. The overall high carbon preference index (CPI) and higher plant fatty acid (HPFA) values as well as high C / N ratios point to a good quality of the preserved OM and thus to a high potential of the OM for decomposition upon thaw. A decrease of HPFA values downwards along the profile probably indicates a relatively stronger OM decomposition in the oldest (MIS 3) deposits of the cliff.

Description: We present sea ice temperature and salinity data from first-year ice (FYI) and second-year ice (SYI) relevant to the temporal development of sea ice permeability and brine drainage efficiency from the early growth phase in October 2019 to the onset of spring warming in May 2020. Our dataset was collected in the central Arctic Ocean during the Multidisciplinary drifting Observatory for the Study of Arctic Climate (MOSAiC) Expedition in 2019 to 2020. MOSAiC was an international transpolar drift expedition in which the German icebreaker RV Polarstern anchored into an ice floe to gain new insights into Arctic climate over a full annual cycle. In October 2019, RV Polarstern moored to an ice floe in the Siberian sector of the Arctic at 85 degrees north and 137 degrees east to begin the drift towards the North Pole and the Fram Strait via the Transpolar Drift Stream. The data presented here were collected during the first three legs of the expedition, so all the coring activities took place on the same floe. The end dates of legs 1, 2, and 3 were 13 December, 24 February, and 4 June, respectively. The dataset contributed to a baseline study entitled, Deciphering the properties of different Arctic ice types during the growth phase of the MOSAiC floes: Implications for future studies. The study highlights downward directed gas pathways in FYI and SYI by inferring sea ice permeability and potential brine release from several time series of temperature and salinity measurements. The physical properties presented in this paper lay the foundation for subsequent analyses on actual gas contents measured in the ice cores, as well as air-ice and ice-ocean gas fluxes. Sea ice cores were collected with a Kovacs Mark II 9 cm diameter corer. To measure ice temperatures, about 4.5 cm deep holes were drilled into the core (intervals varied by site and leg) . The temperatures were measured by a digital thermometer within minutes after the cores were retrieved. The ice cores were placed into pre-labelled plastic sleeves sealed at the bottom end. The ice cores were transported to RV Polarstern and stored in a -20 degrees Celsius freezer. Each of the cores was sub-sampled, melted at room temperature, and processed for salinity within one or two days. The practical salinity was estimated by measuring the electrical conductivity and temperature of the melted samples using a WTW Cond 3151 salinometer equipped with a Tetra-Con 325 four-electrode conductivity cell. The practical salinity represents the the salinity estimated from the electrical conductivity of the solution. The dataset also contains derived variables, including sea ice density, brine volume fraction, and the Rayleigh number.

Description: Rock magnetic and paleomagnetic results covering the past 30 ka were constructed from two sediment cores MSM33_856-1 (MSM33-55-1) and MSM33_855-1 (54-3) from the Black Sea. After the Mediterranean Sea water ingression, finely laminated organic-rich sapropelic sediments and coccolith oozes were deposited in the Black Sea since about 8.3 ka. Relict magnetic minerals in the Black Sea sarpoples are ferrous hemoilmenite, Fe-Mn and Fe-Cr spinels, and magnetite inclusions. In sediments deposited between about 14 and 8 ka, greigite and pyrite were formed in sediments because of the seawater penetration from overlying sediments after the seawater ingression. Before ~14 ka, the Black Sea sediments are dominated by detrital (titano-)magnetite minerals and the sporadically formed greigite which has SIRM/kLF ratios 〉 10 kAm-2. By comparison with detrital (titano-)magnetite samples between 20-30 ka, we found that relict magnetic mineral samples between 0-8.3 ka have similar behavior in recording the geomagnetic field. Moreover, the geomagnetic field variations reconstructed from the Black Sea sapropels are comparable with other validated regional datasets for the past 8.3 ka. The natural remanent magnetization (NRM) and the anhysteretic remanent magnetization (ARM) were measured with a 2G Enterprises 755 SRM (cryogenic) long-core magnetometer equipped with a sample holder for eight discrete samples at a separation of 20 cm. The magnetometer's in-line tri-axial alternating field (AF) demagnetizer was used to demagnetize the NRM and ARM of the samples. The NRM was measured after application of AF peak amplitudes of 0, 5, 10, 15, 20, 30, 40, 50, 65, 80, and 100 mT. Directions of the characteristic remanent magnetization (ChRM) were determined by principle component analysis (PCA) according to Kirschvink (1980). The error range of the ChRM is given as the maximum angular deviation (MAD). The ARM was imparted along the samples' z-axis with a static field of 0.05 mT and an AF field of 100 mT. Demagnetization then was performed in steps of 0, 10, 20, 30, 40, 50, 65, and 80 mT. The median destructive field of the ARM (MDFARM) was determined to estimate the coercivity of the sediments. The slope of NRM versus ARM of common demagnetization steps was used to determine the relative paleointensity (RPI). In most cases, demagnetization steps from 20 to 65 mT were used to determine the RPI.

Description: This dataset provides data for four third-degree tidal constituents used in the publication of Sulzbach et al (2022). The tidal constituents provided are the 3M1, 3M3, 3N2 and 3L2 for 134 globally distributed stations. The tide information, such as the nodal modulations of these tides, are taken from Table 1 and Table S2 of Ray (2020). These tidal constants are estimated using the GESLA dataset (Woodworth et al 2014) following the approach presented in Piccioni et al (2019). This record is an add-on to the full TICON dataset (https://doi.org/10.1594/PANGAEA.896587), using exactly the same data format and pre-processing. These steps include using tide gauge data that contains at least ten years of continuous data. Further, the dataset is restricted to only contain open ocean tide gauges by limiting it to a mean surrounding depth of tide gauges to be deeper than 500 meters in a 2-degree radius and excluding stations not native to the ocean domain of the employed tidal model TiME. Duplicate and closely neighbouring tide gauges, found within a 0.2-degree radius, are also removed from the dataset. This resulted in the availability of the four tidal constants for 134 tide gauges. The results are stored in one tab-separated text/ASCII file with 13 columns: 1. Latitude of the tide gauge station 2. Longitude of the tide gauge station 3. Constituent name 4. Amplitude (in cm) 5. Phase (in degrees) 6. Standard deviation of the amplitude (in cm) 7. Standard deviation of the phase (in degrees) 8. Percentage of missing observations 9. Total number of observations analyzed 10. Length of the maximum temporal gap found in the time series in days 11. Date of the first observation 12. Date of the last observation 13. Code that corresponds to the original source of the record TICON is a useful and easy-to-handle data set for tide model validation and allows the users to select the records according to the different criteria most suitable for their purposes. The options span from the choice of a geographical region to the use of single constituents or time periods.

Description: These datasets provide sedimentological data partly at annual resolution and an age model for the lateglacial part of (1) the ICDP sediment core 5017-1-A retrieved from the deep northern Dead Sea basin in 2010/11, and (2) for the Masada outcrop located at the southwestern shore of the Dead Sea sampled in 2018. The here investigated two sediment sections cover the last glacial-interglacial transition (ca. 17-11.5 ka BP) in the hydroclimatically sensitive Levant, when the water level of Lake Lisan – the precursor of the Dead Sea – dropped dramatically from its glacial high-stand to the Holocene low levels. Here, we analyze the interval between the last two gypsum units – the Upper Gypsum Unit (UGU) and the Additional Gypsum Unit (AGU) – which were also used to correlate the two sites. In the ICDP core this section is located between ~101 and 88.5 m sediment depth below lake floor and at Masada it encompasses the uppermost ~3.8 m sediments of the Lisan Formation, which form the terminal deposit at this site. Due to the lake level decline, the complete transition into the Holocene is only recorded in the ICDP core, while sedimentation at Masada terminates earlier. The microfacies was investigated by continuous thin section microscopy, while additional macroscopic information is provided from over- and underlying sediment sections. A revised chronology using age modelling in OxCal (Ramsey 2008; Ramsey 2009; Ramsey and Lee 2013) was developed for the ICDP core and a floating varve chronology was constructed at Masada. Using these new microfacies data from marginal (Masada) and deep-water (ICDP core) sediments, the hydroclimatic variability during the final stage of Lake Lisan can be reconstructed, which could provide important insights into the development of human sedentism in the region at this time.

Description: We present sea ice temperature and salinity data from first-year ice (FYI) and second-year ice (SYI) relevant to the temporal development of sea ice permeability and brine drainage efficiency from the early growth phase in October 2019 to the onset of spring warming in May 2020. Our dataset was collected in the central Arctic Ocean during the Multidisciplinary drifting Observatory for the Study of Arctic Climate (MOSAiC) Expedition in 2019 to 2020. MOSAiC was an international transpolar drift expedition in which the German icebreaker RV Polarstern anchored into an ice floe to gain new insights into Arctic climate over a full annual cycle. In October 2019, RV Polarstern moored to an ice floe in the Siberian sector of the Arctic at 85 degrees north and 137 degrees east to begin the drift towards the North Pole and the Fram Strait via the Transpolar Drift Stream. The data presented here were collected during the first three legs of the expedition, so all the coring activities took place on the same floe. The end dates of legs 1, 2, and 3 were 13 December, 24 February, and 4 June, respectively. The dataset contributed to a baseline study entitled, Deciphering the properties of different Arctic ice types during the growth phase of the MOSAiC floes: Implications for future studies. The study highlights downward directed gas pathways in FYI and SYI by inferring sea ice permeability and potential brine release from several time series of temperature and salinity measurements. The physical properties presented in this paper lay the foundation for subsequent analyses on actual gas contents measured in the ice cores, as well as air-ice and ice-ocean gas fluxes. Sea ice cores were collected with a Kovacs Mark II 9 cm diameter corer. To measure ice temperatures, about 4.5 cm deep holes were drilled into the core (intervals varied by site and leg) . The temperatures were measured by a digital thermometer within minutes after the cores were retrieved. The ice cores were placed into pre-labelled plastic sleeves sealed at the bottom end. The ice cores were transported to RV Polarstern and stored in a -20 degrees Celsius freezer. Each of the cores was sub-sampled, melted at room temperature, and processed for salinity within one or two days. The practical salinity was estimated by measuring the electrical conductivity and temperature of the melted samples using a WTW Cond 3151 salinometer equipped with a Tetra-Con 325 four-electrode conductivity cell. The practical salinity represents the the salinity estimated from the electrical conductivity of the solution. The dataset also contains derived variables, including sea ice density, brine volume fraction, and the Rayleigh number.

Description: This dataset provides annually resolved microfacies data from ICDP core 5017-1-A, retrieved from the deep northern Dead Sea basin in 2010/11, for the last glacial-interglacial transition (ca. 17-11.5 ka BP). Sediments of the Lisan Formation were investigated between ~101 and 88.5 m sediment depth below lake floor by continuous thin section microscopy, while additional macroscopic information is provided from core catchers, as well as from over- and underlying sediment sections. Thin sections were prepared following the standard procedure by Brauer and Casanova (2001) that was adjusted for salty sediments. Thin section analyses were performed on overlapping large-scale thin sections using a Zeiss Axiolab pol microscope at magnifications of 50-400x. Microfacies analyses included varve counting and measurements of varve and sublayer thickness.

Description: Despite the importance of surface energy budgets (SEBs) for land-climate interactions in the Arctic, uncertainties in their prediction persist. In situ observational data of SEB components - useful for research and model validation - are collected at relatively few sites across the terrestrial Arctic, and not all available datasets are readily interoperable. Furthermore, the terrestrial Arctic consists of a diversity of vegetation types, which are generally not well represented in land surface schemes of current Earth system models. This dataset contains metadata information about surface energy budget components measured at 64 tundra and glacier sites 〉60° N across the Arctic. This information was taken from the open-access repositories FLUXNET, Ameriflux, AON, GC-Net and PROMICE. The contained datasets are associated with the publication vegetation type as an important predictor of the Arctic Summer Land Surface Energy Budget by Oehri et al. 2022, and intended to support research of surface energy budgets and their relationship with environmental conditions, in particular vegetation characteristics across the terrestrial Arctic.

Description: This dataset provides the results from Bayesian age depth modelling in OxCal for ICDP core 5017-1-A, retrieved from the deep northern Dead Sea basin in 2010/11, for the last glacial-interglacial transition between ~101 and 88.5 m sediment depth below lake floor (ca. 17-11.5 ka BP). The model was performed in OxCal v.4.4 using a P_Sequence (1,1,C(-2,2)) (Ramsey 2008; Ramsey 2009; Ramsey and Lee 2013) and includes three tephrochronological ages from Neugebauer et al. (2021) and three radiocarbon ages from Kitagawa et al. (2017).

Description: Despite the importance of surface energy budgets (SEBs) for land-climate interactions in the Arctic, uncertainties in their prediction persist. In situ observational data of SEB components - useful for research and model validation - are collected at relatively few sites across the terrestrial Arctic, and not all available datasets are readily interoperable. Furthermore, the terrestrial Arctic consists of a diversity of vegetation types, which are generally not well represented in land surface schemes of current Earth system models. This dataset comprises harmonized, standardized and aggregated in-situ observations of surface energy budget components measured at 64 sites on vegetated and glaciated sites north of 60° latitude, in the time period from 1994 till 2021. The surface energy budget components include net radiation, sensible heat flux, latent heat flux, ground heat flux, net shortwave radiation, net longwave radiation, surface temperature and albedo, which were aggregated to daily mean, minimum and maximum values from hourly and half-hourly measurements. Data were retrieved from the monitoring networks FLUXNET, AmeriFlux, AON, GC-Net and PROMICE.

Description: We present sea ice temperature and salinity data from first-year ice (FYI) and second-year ice (SYI) relevant to the temporal development of sea ice permeability and brine drainage efficiency from the early growth phase in October 2019 to the onset of spring warming in May 2020. Our dataset was collected in the central Arctic Ocean during the Multidisciplinary drifting Observatory for the Study of Arctic Climate (MOSAiC) Expedition in 2019 to 2020. MOSAiC was an international transpolar drift expedition in which the German icebreaker RV Polarstern anchored into an ice floe to gain new insights into Arctic climate over a full annual cycle. In October 2019, RV Polarstern moored to an ice floe in the Siberian sector of the Arctic at 85 degrees north and 137 degrees east to begin the drift towards the North Pole and the Fram Strait via the Transpolar Drift Stream. The data presented here were collected during the first three legs of the expedition, so all the coring activities took place on the same floe. The end dates of legs 1, 2, and 3 were 13 December, 24 February, and 4 June, respectively. The dataset contributed to a baseline study entitled, Deciphering the properties of different Arctic ice types during the growth phase of the MOSAiC floes: Implications for future studies. The study highlights downward directed gas pathways in FYI and SYI by inferring sea ice permeability and potential brine release from several time series of temperature and salinity measurements. The physical properties presented in this paper lay the foundation for subsequent analyses on actual gas contents measured in the ice cores, as well as air-ice and ice-ocean gas fluxes. Sea ice cores were collected with a Kovacs Mark II 9 cm diameter corer. To measure ice temperatures, about 4.5 cm deep holes were drilled into the core (intervals varied by site and leg) . The temperatures were measured by a digital thermometer within minutes after the cores were retrieved. The ice cores were placed into pre-labelled plastic sleeves sealed at the bottom end. The ice cores were transported to RV Polarstern and stored in a -20 degrees Celsius freezer. Each of the cores was sub-sampled, melted at room temperature, and processed for salinity within one or two days. The practical salinity was estimated by measuring the electrical conductivity and temperature of the melted samples using a WTW Cond 3151 salinometer equipped with a Tetra-Con 325 four-electrode conductivity cell. The practical salinity represents the the salinity estimated from the electrical conductivity of the solution. The dataset also contains derived variables, including sea ice density, brine volume fraction, and the Rayleigh number.

Description: We present sea ice temperature and salinity data from first-year ice (FYI) and second-year ice (SYI) relevant to the temporal development of sea ice permeability and brine drainage efficiency from the early growth phase in October 2019 to the onset of spring warming in May 2020. Our dataset was collected in the central Arctic Ocean during the Multidisciplinary drifting Observatory for the Study of Arctic Climate (MOSAiC) Expedition in 2019 to 2020. MOSAiC was an international transpolar drift expedition in which the German icebreaker RV Polarstern anchored into an ice floe to gain new insights into Arctic climate over a full annual cycle. In October 2019, RV Polarstern moored to an ice floe in the Siberian sector of the Arctic at 85 degrees north and 137 degrees east to begin the drift towards the North Pole and the Fram Strait via the Transpolar Drift Stream. The data presented here were collected during the first three legs of the expedition, so all the coring activities took place on the same floe. The end dates of legs 1, 2, and 3 were 13 December, 24 February, and 4 June, respectively. The dataset contributed to a baseline study entitled, Deciphering the properties of different Arctic ice types during the growth phase of the MOSAiC floes: Implications for future studies. The study highlights downward directed gas pathways in FYI and SYI by inferring sea ice permeability and potential brine release from several time series of temperature and salinity measurements. The physical properties presented in this paper lay the foundation for subsequent analyses on actual gas contents measured in the ice cores, as well as air-ice and ice-ocean gas fluxes. Sea ice cores were collected with a Kovacs Mark II 9 cm diameter corer. To measure ice temperatures, about 4.5 cm deep holes were drilled into the core (intervals varied by site and leg) . The temperatures were measured by a digital thermometer within minutes after the cores were retrieved. The ice cores were placed into pre-labelled plastic sleeves sealed at the bottom end. The ice cores were transported to RV Polarstern and stored in a -20 degrees Celsius freezer. Each of the cores was sub-sampled, melted at room temperature, and processed for salinity within one or two days. The practical salinity was estimated by measuring the electrical conductivity and temperature of the melted samples using a WTW Cond 3151 salinometer equipped with a Tetra-Con 325 four-electrode conductivity cell. The practical salinity represents the the salinity estimated from the electrical conductivity of the solution. The dataset also contains derived variables, including sea ice density, brine volume fraction, and the Rayleigh number.

Description: This dataset describes two 17 m long sediment cores taken from beneath two thermokarst lakes in the Yukechi Alas, Central Yakutia, Russia. The first core was taken from below an Alas thermokarst lake (YU-L7; 61.76397°N, 130.46442°E) and the second core below and Yedoma lake (YU-L15; 61.76086°N, 130.47466°E). The dataset presents biogeochemical and biomarker parameters of sediment cores YU-L7 and YU-L15. Biogeochemical analyses include total carbon (TC) content, total organic carbon (TOC) content, total nitrogen (TN) content. Biomarker parameters include the n-alkane concentration, average chain length (ACL), carbon preference index (CPI), brGDGT concentration, archaeol concentration and the isoGDGT-0 concentration. The n-alkanes were measured in the aliphatic fraction by gas chromatography-mass spectromety using a Trace GC Ultra coupled to a DSQ MS. The branched and isoprenoid glycerol dialkyl glycerol tetraethers, as well as the dialkyl glycerol diether lipid (archaeol) were measured in the NSO fraction using a Shimadzu LC-10AD high-performance liquid chromatograph coupled to a Finnigan TSQ 7000 mass spectrometer via an atmospheric pressure chemical ionization interface. The pH soil is the sediment pH which was assessed by adding 6.12 mL of 0.01 M CaCl~2~ to ~2.5 g dried sediment and measuring with a Multilab 540 (WTW) at 20°C.

Description: We present sea ice temperature and salinity data from first-year ice (FYI) and second-year ice (SYI) relevant to the temporal development of sea ice permeability and brine drainage efficiency from the early growth phase in October 2019 to the onset of spring warming in May 2020. Our dataset was collected in the central Arctic Ocean during the Multidisciplinary drifting Observatory for the Study of Arctic Climate (MOSAiC) Expedition in 2019 to 2020. MOSAiC was an international transpolar drift expedition in which the German icebreaker RV Polarstern anchored into an ice floe to gain new insights into Arctic climate over a full annual cycle. In October 2019, RV Polarstern moored to an ice floe in the Siberian sector of the Arctic at 85 degrees north and 137 degrees east to begin the drift towards the North Pole and the Fram Strait via the Transpolar Drift Stream. The data presented here were collected during the first three legs of the expedition, so all the coring activities took place on the same floe. The end dates of legs 1, 2, and 3 were 13 December, 24 February, and 4 June, respectively. The dataset contributed to a baseline study entitled, Deciphering the properties of different Arctic ice types during the growth phase of the MOSAiC floes: Implications for future studies. The study highlights downward directed gas pathways in FYI and SYI by inferring sea ice permeability and potential brine release from several time series of temperature and salinity measurements. The physical properties presented in this paper lay the foundation for subsequent analyses on actual gas contents measured in the ice cores, as well as air-ice and ice-ocean gas fluxes. Sea ice cores were collected with a Kovacs Mark II 9 cm diameter corer. To measure ice temperatures, about 4.5 cm deep holes were drilled into the core (intervals varied by site and leg) . The temperatures were measured by a digital thermometer within minutes after the cores were retrieved. The ice cores were placed into pre-labelled plastic sleeves sealed at the bottom end. The ice cores were transported to RV Polarstern and stored in a -20 degrees Celsius freezer. Each of the cores was sub-sampled, melted at room temperature, and processed for salinity within one or two days. The practical salinity was estimated by measuring the electrical conductivity and temperature of the melted samples using a WTW Cond 3151 salinometer equipped with a Tetra-Con 325 four-electrode conductivity cell. The practical salinity represents the the salinity estimated from the electrical conductivity of the solution. The dataset also contains derived variables, including sea ice density, brine volume fraction, and the Rayleigh number.

Description: Despite the importance of surface energy budgets (SEBs) for land-climate interactions in the Arctic, uncertainties in their prediction persist. In-situ observational data of SEB components - useful for research and model validation - are collected at relatively few sites across the terrestrial Arctic, and not all available datasets are readily interoperable. Furthermore, the terrestrial Arctic consists of a diversity of vegetation types, which are generally not well represented in land surface schemes of current Earth system models. Therefore, we here provide four datasets comprising: 1. Harmonized, standardized and aggregated in situ observations of SEB components at 64 vegetated and glaciated sites north of 60° latitude, in the time period 1994-2021 2. A description of all study sites and associated environmental conditions, including the vegetation types, which correspond to the classification of the Circumpolar Arctic Vegetation Map (CAVM, Raynolds et al. 2019). 3. Data generated in a literature synthesis from 358 study sites on vegetation or glacier (〉=60°N latitude) covered by 148 publications. 4. Metadata, including data contributor information and measurement heights of variables associated with Oehri et al. 2022.

Description: This dataset provides lithological data from ICDP core 5017-1-A, retrieved from the deep northern Dead Sea basin in 2010/11, for the last glacial-interglacial transition (ca. 17-11.5 ka BP). The microfacies of the Lisan Formation was investigated between ~101 and 88.5 m sediment depth below lake floor by continuous thin section microscopy, while additional macroscopic information is provided from core catchers, as well as from over- and underlying sediment sections. Thin sections were prepared following the standard procedure by Brauer and Casanova (2001) that was adjusted for salty sediments. Thin section analyses were performed on overlapping large-scale thin sections using a Zeiss Axiolab pol microscope at magnifications of 50-400x.

Description: This dataset contains observations of water discharge rates and concentrations of dissolved organic carbon (DOC) and dissolved inorganic carbon (DIC) from a polygonal tundra site in the Lena River Delta, Russia. This dataset also contains lateral carbon fluxes of DOC and DIC that were estimated from these observations. Additionally, this dataset contains vertical fluxes of carbon dioxide and methane from the same study site. All observations were recorded on Samoylov Island (N 72.377188, E 126.495144) in the summer of 2014. The abbreviations A1, A2 and B refer to three outflows on the island where the hydrological parameters were observed (A1: N 72.379991, E 126.480886; A2: N 72.380134, E 126.481433; B: N 72.381348, E 126.483482). All outflows were approximately 10 meters. More information can be found in https://doi.org/10.5194/bg-19-3863-2022.

Description: Despite the importance of surface energy budgets (SEBs) for land-climate interactions in the Arctic, uncertainties in their prediction persist. In situ observational data of SEB components - useful for research and model validation - are collected at relatively few sites across the terrestrial Arctic, and not all available datasets are readily interoperable. Furthermore, the terrestrial Arctic consists of a diversity of vegetation types, which are generally not well represented in land surface schemes of current Earth system models. This dataset describes the environmental conditions for 64 tundra and glacier sites (〉=60°N latitude) across the Arctic, for which in situ measurements of surface energy budget components were harmonized (see Oehri et al. 2022). These environmental conditions are (proxies of) potential drivers of SEB-components and could therefore be called SEB-drivers. The associated environmental conditions, include the vegetation types graminoid tundra, prostrate dwarf-shrub tundra, erect-shrub tundra, wetland complexes, barren complexes (≤ 40% horizontal plant cover), boreal peat bogs and glacier. These land surface types (apart from boreal peat bogs) correspond to the main classification units of the Circumpolar Arctic Vegetation Map (CAVM, Raynolds et al. 2019). For each site, additional climatic and biophysical variables are available, including cloud cover, snow cover duration, permafrost characteristics, climatic conditions and topographic conditions.

Description: This dataset contains over 30 marine Electrical Resistivity Tomography (ERT) profiles taken in September 2021 around Tuktoyaktuk Island (NWT / Beaufort Sea, Canada). The measurements were part of the “Mackenzie Delta Permafrost Field Campaign” (mCan2021) within the “Modular Observation solutions for Earth Systems” (MOSES) program. The collected profiles consist of numerous adjacent vertical soundings in a (quasi-symmetric) reciprocal Wenner-Schlumberger array, using a floating cable towed behind a boat. GPS records along the electrode streamer were taken, enabling the improvement of pre- processing by excluding measurements for which the cable was curved and electrode positions deviated too widely. The aim of the study was to determine the depth of the submarine permafrost. Cleaned data is provided in csv format.

Description: This collection contains permafrost related measurements in the Mackenzie Delta, NWT, Canada from the MOSES (Modular Observation Solutions for Earth Systems) field campaign in September 2021. The field campaign was focused on three subaquatic sites: a small thermokarst lake along the ITH just south of Trail Valley Creek, "Lake 3", an elongated lake with known methane occurence in the outer Mackenzie Delta, "Swiss Cheese Lake", and north and south of Tuktoyaktuk Island. At "Swiss Cheese Lake", we measured methane and CO2 concentrations in surface water and in the air above the lake, lake bed temperatures and detailed bathymetry. At "Lake 3" we measured active layer thickness on the lake banks, lake bed temperatures, and detailed bathymetry, as well as an ERT survey to estimate the talik depth below the lake. North and south of Tuktoyaktuk Island, we measured active layer thickness and sea bed temperatures and did an extensive ERT survey to obtain the depth of the subsea permafrost table. An additional passive seismic survey was carried out and the data is available at https://doi.org/10.5880/GIPP.202199.1.

Description: This dataset contains seven Electrical Resistivity Tomography (ERT) profiles taken in September 2021 at “Lake 3”, a thermokarst lake near the Inuvik-Tuktoyaktuk-Highway (ITH), about 50 km north of Inuvik (NWT, Canada). The measurements were part of the “Mackenzie Delta Permafrost Field Campaign” (mCan2021) within the “Modular Observation solutions for Earth Systems” (MOSES) program. The collected profiles consist of numerous adjacent vertical soundings in a (quasi-symmetric) reciprocal Wenner-Schlumberger array. In addition to surveys on the lake, using a floating cable towed behind a boat, two “amphibian” profiles were taken. Starting as purely terrestrial surveys using metal spike electrodes, the cable was then moved towards the lake with some of the electrodes floating on the water surface, and some still on land. The aim of the study was to determine permafrost properties on the land, to detect a possible talik beneath the lake and to especially be able to infer the transition between the two below the shoreline.

Description: Presented are analytical data from lacustrine sediment cores, retrieved from Lake Nam Co (Tibetan Plateau). The sediment core is a composite of one gravity core, taken with a Rumohr-Meischner gravity corer (63 mm diameter) and a piston core, retrieved using an uwitec piston coring system (http://www.uwitec.at; 90 mm diameter). The composite core labelled 〈NC 08/01〉 comprises a total length of 10.378 m. The cores were obtained at N 30.737417, E 090.790333 at a water depth of 93 m on 2008-09-15. The purpose of obtaining this sediment core was to establish a high-resolution record of climate (monsoonal) and environmental change using multiple proxy data. The dataset comprises analytical data based on sedimentological, inorganic geochemical, mineralogical and isotope-geochemical methods. Specifically: sediment water content & density; magnetic susceptibility; particel size data; quantitative inorganic geochemical data (ICP-OES aqua regia and HCL digestions); semi-quantitative XRF elemental data; carbon, nitrogen, sulfur contents; qualitative mineralogical data; bulk sediment stable carbon and oxygen isotope data.

Description: This data set is part of a larger data harmonization effort to make lake sediment core data machine readable and comparable. Here we standardized X-ray fluorescence line scanning (XRF)-based element data of sediment core EN18208, retrieved in 2018 from Lake Ilirney (Chukotka, Russia) at 10.76 m water depth. The glacial lake Ilirney is situated in the forest tundra mountain area and has one outflow, one main inflow and several smaller inflows. It lies at an elevation of ca. 428 m a.s.l. with a surface area of ca. 30 km2 and a maximum lake water depth of estimated 44 m. The 10.76 m sediment core was retrieved by a UWITEC piston corer during the RU-Land_2018_Chukotka expedition of the Alfred Wegener Institute Helmholtz Centre for Polar and Marine Research (AWI, Germany, Potsdam) in cooperation with the North Eastern Federal State University (NEFU, Russia, Yakutsk). The downcore elemental composition was measured using an AVAATECH x-ray fluorescence core scanner at Bundesanstalt für Geowissenschaften und Rohstoffe (BGR) in Berlin, Spandau.

Description: This data set is part of a larger data harmonization effort to make lake sediment core data machine readable and comparable. Here we standardized radiocarbon and OSL age data of sediment core EN18208, retrieved in 2018 from Lake Ilirney (Chukotka, Russia) at 10.76 m water depth. The glacial lake Ilirney is situated in the forest tundra mountain area and has one outflow, one main inflow and several smaller inflows. It lies at an elevation of ca. 428 m a.s.l. with a surface area of ca. 30 km2 and a maximum lake water depth of estimated 44 m. The 10.76 m sediment core was retrieved by a UWITEC piston corer during the RU-Land_2018_Chukotka expedition of the Alfred Wegener Institute Helmholtz Centre for Polar and Marine Research (AWI, Germany, Potsdam) in cooperation with the North Eastern Federal State University (NEFU, Russia, Yakutsk). Radiocarbon data have been analysed from bulk sediment samples in Bremerhaven at the MICADAS laboratory. Optically stimulated luminescence (OSL) dating was performed at the Royal Holloway Luminescence Laboratory using a Risø TL/OSL-DA-15 automated dating system.

Description: A 25-cm long predominantly aragonite stalagmite was collected November 2, 2005 from Dharamjali Cave (29.5°N, 80.2°E) in the central Himalayas. This dataset contains stable isotope, trace element, XRF, U/Th dating, and dripwater data. The age model spans 4.2 to 2.3 ka BP, and the dataset records seasonal shifts in hydroclimate from 4.2 to 3.1 ka BP. Using the DHAR-1A half of the speleothem, 750 samples were milled at 100–300 µm resolution for stable isotope analysis (δ18O and δ13C) and analyzed at GFZ Potsdam. Further high-resolution stable isotope analysis at the University of Cambridge included 876 samples from the bottom 4 cm of the mirroring slab DHAR-1B, covering c. 4.2–3.6 ka BP. The δ44/40Ca measurements were made on 60 aragonite samples of aragonite and 1 calcite sample milled between 4.2 and 2.8 ka BP. The elemental composition of DHAR-1B was determined first with an Avaatech XRF scanner at the University of Cambridge, and later using laser ablation inductively-coupled plasma mass spectrometry (LA-ICP-MS) at the University of Waikato. U-series dating was performed at Caltech on 22 samples. Twelve U-series ages (between 2.55 and 4.14 ka BP) were used to construct the age models, using ensembles of 2000 Monte Carlo simulations for each proxy using the MATLAB-based COPRA script (Breitenbach et al., 2012, https://doi.org/10.5194/cp-8-1765-2012).

Description: This data set is part of a larger data harmonization effort to make lake sediment core data machine readable and comparable. Here we standardized grain size element data of sediment core EN18208, retrieved in 2018 from Lake Ilirney (Chukotka, Russia) at 10.76 m water depth. The glacial lake Ilirney is situated in the forest tundra mountain area and has one outflow, one main inflow and several smaller inflows. It lies at an elevation of ca. 428 m a.s.l. with a surface area of ca. 30 km2 and a maximum lake water depth of estimated 44 m. The 10.76 m sediment core was retrieved by a UWITEC piston corer during the RU-Land_2018_Chukotka expedition of the Alfred Wegener Institute Helmholtz Centre for Polar and Marine Research (AWI, Germany, Potsdam) in cooperation with the North Eastern Federal State University (NEFU, Russia, Yakutsk). Grain-size was measured using a Malvern Mastersizer 3000 laser diffraction particle analyser.

Description: This data set is part of a larger data harmonization effort to make lake sediment core data machine readable and comparable. Here we standardized mineral data of sediment core EN18208, retrieved in 2018 from Lake Ilirney (Chukotka, Russia) at 10.76 m water depth. The glacial lake Ilirney is situated in the forest tundra mountain area and has one outflow, one main inflow and several smaller inflows. It lies at an elevation of ca. 428 m a.s.l. with a surface area of ca. 30 km2 and a maximum lake water depth of estimated 44 m. The 10.76 m sediment core was retrieved by a UWITEC piston corer during the RU-Land_2018_Chukotka expedition of the Alfred Wegener Institute Helmholtz Centre for Polar and Marine Research (AWI, Germany, Potsdam) in cooperation with the North Eastern Federal State University (NEFU, Russia, Yakutsk). Bulk mineralogy was analysed by (x-ray diffractometry (XRD) using a (PHILIPS, Netherlands) PW1820 goniometer.

Description: This data set is part of a larger data harmonization effort to make lake sediment core data machine readable and comparable. Here we standardized radiocarbon and OSL age data of sediment core EN18208, retrieved in 2018 from Lake Ilirney (Chukotka, Russia) at 10.76 m water depth. The glacial lake Ilirney is situated in the forest tundra mountain area and has one outflow, one main inflow and several smaller inflows. It lies at an elevation of ca. 428 m a.s.l. with a surface area of ca. 30 km2 and a maximum lake water depth of estimated 44 m. The 10.76 m sediment core was retrieved by a UWITEC piston corer during the RU-Land_2018_Chukotka expedition of the Alfred Wegener Institute Helmholtz Centre for Polar and Marine Research (AWI, Germany, Potsdam) in cooperation with the North Eastern Federal State University (NEFU, Russia, Yakutsk). Water content and organic matter was analysed at AWI Potsdam. Dried and milled samples were analysed using a Vario EL III carbon-nitrogen-sulphur analyser. Organic carbon content was determined using a Vario MAX C analyser.

Description: Surface air temperature measurements obtained from different sensors are used to construct a unique time series with one minute time-interval. Apart from differences in design and environmental exposition, periods of missing data also exist in the data series of each sensor. A primary data set was selected in terms of quality and temporal extension. A combination of two different techniques is applied to complete this data set: one is based on the autocorrelation of the series and the other on measurements taken from other sensors. The resulting values constitute a complete series of surface air temperature at AGGO.

Description: This dataset contain stable isotope values for water samples collected ~weekly from the Rio Bermejo at the Lavalle bridge (-25.6513, -60.1277) from March 2016 to February 2018. Water samples were filtered to 0.2 micron using a custom filtration device. We measured d2H and d18O on a Picarro L-2140i Cavity Ring-Down Spectrometer at the GFZ Potsdam. Measurements were made in duplicate, normalized to the Vienna Standard Mean Ocean Water (VSMOW), and analytical uncertainty is reported as one standard deviation from the mean. River discharge was measured at the El Colorado gauging station, which is ~100 km down slope from the sampling location.

Description: This dataset provides the geochemistry data for the Holocene sediment sequence retrieved from Lake Uddelermeer (The Netherlands) in 2012. Additionally, alkane concentrations for a set of modern leaf samples are provided. Concentrations of fossil alkanes, GDGTs as well as elemental (C, N, S, H) and compound-specific delta Deuterium measurements are presented against both depth (cm) and age (cal yr. BP). A total of 59 samples were analysed. Modern leaf alkane concentrations are presented as concentrations, 10 samples were analysed. The geochemical data provides information about regional vegetation change as well as changes in effective precipitation. It was produced to inform on the age and duration of major environmental transitions during the middle and late Holocene. Cores were retrieved from the lake using a 3-m long handheld piston corer deployed from a floating coring platform during field work in April and May 2012. Samples were obtained from splits of the core and processed in the laboratory of the University of Amsterdam (the Netherlands) using standard protocols (CNHS, alkane concentrations), the laboratory of Utrecht University (the Netherlands; GDGT concentrations) and at GFZ Potsdam (Germany; delta Deuterium). Name of the Campaign: UDD Event Label: UDD-E Method: Uwitec piston corer Latitude: 52.24652778 Longitude: 5.76097222 Elevation: 24m asl Date/Time of event: 2012-05-01T14:00:00 Further information about event: Lake sediment sequence retrieved using a 60 mm piston corer deployed from a floating platform.

Description: Water samples were filtered to 0.2 micron prior to measurement. Samples for cation analysis were acidified in the field to pH 〈 2 using 6N HNO3. Cation concentrations were measured with a Varian 720 inductively coupled plasma optical emission spectrometer (ICP-OES) at the GFZ Helmholtz Laboratory for the Geochemistry of the Earth Surface (HELGES), using SLRS-5 (Saint-Laurent River Surface, National Research Council - Conseil National de Recherches Canada) and USGS M212 and USGS T187 as external standards. We corrected for instrument drift by measuring an internal standard (GFZ-RW1) every 10 samples and we determined measurement uncertainty using calibration curve uncertainty. Anion concentrations were measured with a Dionex ICS1100 Ion Chromatograph, using USGS standards M206 and M212 as external standards for quality control, with uncertainty determined from triplicate analysis. We corrected cation concentrations for cyclic salt inputs following Bickle et al. (2005, doi:10.1016/j.gca.2004.11.019).

Description: This dataset reports measurements from a laboratory incubation of soils sourced from a boreal peatland and surrounding habitats (Siikaneva Bog, Finland). In August 2021, soil cores were collected from three habitat zones: a well-drained upland forest, an intermediate margin ecotone, and a Sphagnum moss bog. The cores from each habitat were taken from surface to approximately 50cm below surface using an Eijelkamp peat corer and subdivided by soil horizon. The samples were then incubated anaerobically for 140 days in three temperature treatment groups (0, 4, 20°C). Subsamples of the incubations headspace (250 µL) were measured on a gas chromatograph (7890A, Agilent Technologies, USA) with flame ionization detection (FID) for CO2 and CH4 concentrations. The rate of respiration from the samples were calculated per gram carbon and per gram soil as described in the method of Robertson., et al. (1999) and reported here, along with other relevant parameters.

Description: The upper air soundings are normally performed once a day to measure vertical profiles of air pressure, temperature, relative humidity and the wind vector. Helium filled balloons (TOTEX 600 g, 800 g) were used to carry Vaisala RS92-SGPW radiosondes. Whenever possible, the launches were performed about 10 UTC. Condensed measurements (TEMP Format FM-35) were transferred without delay into the Global Telecommunication System GTS were they contribute for the world wide weather forecasts. The profile data were taken every 5-10 seconds which result in a vertical profile resolution of about 25-50 meter. The profiles start at the helideck 10 m above sea level and terminate at the burst level of the balloons, normally at heights between 25 and 37 km.

Description: Due to its strong influence on heat and moisture exchange between the ocean and the atmosphere, sea ice is an essential component of the global climate system. In the context of its alarming decrease in terms of concentration, thickness and duration, understanding the processes controlling sea-ice variability and reconstructing paleo-sea-ice extent in polar regions have become of great interest for the scientific community. In this study, for the first time, IP25, a recently developed biomarker sea-ice proxy, was used for a high-resolution reconstruction of the sea-ice extent and its variability in the western North Pacific and western Bering Sea during the past 18,000 years. To identify mechanisms controlling the sea-ice variability, IP25 data were associated with published sea-surface temperature as well as diatom and biogenic opal data. The results indicate that a seasonal sea-ice cover existed during cold periods (Heinrich Stadial 1 and Younger Dryas), whereas during warmer intervals (Bølling-Allerød and Holocene) reduced sea ice or ice-free conditions prevailed in the study area. The variability in sea-ice extent seems to be linked to climate anomalies and sea-level changes controlling the oceanographic circulation between the subarctic Pacific and the Bering Sea, especially the Alaskan Stream injection though the Aleutian passes.

Description: FIL2013: Polar 6 conducted a systematic digital photographic aerial survey of the area of the Filchner Outflow System during two survey flights from Halley VI on 15 and 16 November 2013. The total survey distance covered 3,000 km each on 15 (eastern section) and 16 (western section) November 2013. Due to a low cloud ceiling on 15 November, the first flight operation was terminated prematurely and thus the westernmost track could not be flown. This track was flown on 16 November, and the total number of tracks numbered 11 instead of 12 as had been planned originally. FIL2014: Visual surveys of pack ice seals using helicopters were conducted from 4 January to 9 February 2014 from aboard RV Polarstern (PS82). For all seal related operations (including deployments of satellite transmitte rs and reconnaissance flights) a total of 30:13 hours during 20 flights were flown (MIN 0:11; MAX 3:13). The survey region was sampled by flying systematically spaced line transects (parallel lines approximately 10 nm apart) whenever ship position and weather conditions allowed, with out clustering transects in areas of easier access. When a full transect length could not be flown on a day, we attempted to complete (extend) the particular transect on a following day.

Description: The upper air soundings are normally performed once a day to measure vertical profiles of air pressure, temperature, relative humidity and the wind vector. Helium filled balloons (TOTEX 600 g, 800 g) were used to carry Vaisala RS92-SGPW radiosondes. Whenever possible, the launches were performed about 10 UTC. Condensed measurements (TEMP Format FM-35) were transferred without delay into the Global Telecommunication System GTS were they contribute for the world wide weather forecasts. The profile data were taken every 5-10 seconds which result in a vertical profile resolution of about 25-50 meter. The profiles start at the helideck 10 m above sea level and terminate at the burst level of the balloons, normally at heights between 25 and 37 km.

Description: This dataset was created via processing of raw position data acquired by the GPS sensor for scientific equipment on Polar 6/Polar 5 to receive a validated master track which is used as reference of further expedition data.

Description: This dataset was created via processing of raw position data acquired by the GPS sensor for scientific equipment on Polar 6/Polar 5 to receive a validated master track which is used as reference of further expedition data.

Description: This dataset was created via processing of raw position data acquired by the GPS sensor for scientific equipment on Polar 6/Polar 5 to receive a validated master track which is used as reference of further expedition data.

Description: This dataset was created via processing of raw position data acquired by the GPS sensor for scientific equipment on Polar 6/Polar 5 to receive a validated master track which is used as reference of further expedition data.

Description: Data underlying figures 1, 2, 3 and 5. Figure 1: Monthly mass changes of the Greenland Ice Sheet from GRACE/GRACE-FO and SMB-D (2003-2019) Figure 2: Biennial mass balance and its components from GRACE/GRACE-FO and SMB-D (2003-2018) for the Greenland Ice Sheet, along with regional estimates for 2017-2018 for East and West. Figure 3: Rate of mass change for year 2019 from GRACE/GRACE-FO and SMB-D Figure 5: Annual mass balance and its main components from SMB-D (1948-2019) and GRACE/GRACE-FO (2003-2019)

Description: The upper air soundings are normally performed once a day to measure vertical profiles of air pressure, temperature, relative humidity and the wind vector. Helium filled balloons (TOTEX 600 g, 800 g) were used to carry Vaisala RS92-SGPW radiosondes. Whenever possible, the launches were performed about 10 UTC. Condensed measurements (TEMP Format FM-35, BUFR) were transferred without delay into the Global Telecommunication System GTS were they contribute for the world wide weather forecasts. The profile data were taken every 5-10 seconds which result in a vertical profile resolution of about 25-50 meter. The profiles start at the helideck 10 m above sea level and terminate at the burst level of the balloons, normally at heights between 25 and 37 km.

Description: Coinciding with global warming, Arctic sea ice has rapidly decreased during the last four decades and climate scenarios suggest that sea ice may completely disappear during summer within the next about 50-100 years. Here we produce Arctic sea ice biomarker proxy records for the penultimate glacial (Marine Isotope Stage 6) and the subsequent last interglacial (Marine Isotope Stage 5e). The latter is a time interval when the high latitudes were significantly warmer than today. We document that even under such warmer climate conditions, sea ice existed in the central Arctic Ocean during summer, whereas sea ice was significantly reduced along the Barents Sea continental margin influenced by Atlantic Water inflow. Our proxy reconstruction of the last interglacial sea ice cover is supported by climate simulations, although some proxy data/model inconsistencies still exist. During late Marine Isotope Stage 6, polynya-type conditions occurred off the major ice sheets along the northern Barents and East Siberian continental margins, contradicting a giant Marine Isotope Stage 6 ice shelf that covered the entire Arctic Ocean.

Description: A combined year round assessment of selected oceanographic data and a macrobiotic community assessment was performed from October 2013 to November 2014 in the littoral zone of the polar fjord systems Kongsfjorden on the west coast of Svalbard (Norway). A state of the art remote controlled cabled underwater observatory technology was used for daily vertical profiles of temperature, salinity and turbidity together with a stereo-optical assessment of the macrobiotic community, including fish. The results reveal a distinct seasonal cycle in total species abundances with a significantly higher total abundance and species richness during the polar winter when no light is available under water compared to the summer months when 24-h light is available. During the winter months, a temporally highly segmented community was observed with respect to species occurrence with single species dominating the winter community for restricted times. In contrast, the summer community showed an overall lower total abundance, as well as a significantly lower number of species. The study clearly demonstrates the high potential of cable connected remote controlled digital sampling devices, especially in remote areas, such as the polar fjord systems, with harsh environmental conditions and limited accessibility. A smart combination of such new digital ?sampling? methods with classic sampling procedures can provide a possibility to significantly extend the sampling time and frequency especially in remote and difficult to access areas. This can help to provide a sufficient data density and therefore statistical power for a sound scientific analysis without increasing the invasive sampling pressure in ecologically sensitive environments.

Description: Here, we provide the raw pollen data archived in three Siberian lake sediment cores spanning the mid-Holocene to the present (7.6-0 cal ka BP), from northern typical tundra to southern open larch forest in the Omoloy region. There are three cores: 1. 14-OM-20B, Lat. / °: 70.53, Lon. / °: 132.91, Ele. / m a.s.l.: 52, Modern vegetation: open larch forest, Lake area / km2: 0.26, Maximal depth / m: 3.4 2. 14-OM-02B, Lat. / °: 70.72, Lon. / °: 132.67, Ele. / m a.s.l.: 58, Modern vegetation: forest tundra, Lake area / km2: 0.08, Maximal depth / m: 3.5 3. 14-OM-12A, Lat. / °: 70.96, Lon. / °: 132.57, Ele. / m a.s.l.: 60, Modern vegetation: tundra, Lake area / km2: 0.09, Maximal depth / m: 4.5 Three lake sediment cores, 14OM12A (33 cm long), 14OM02B (49.5 cm long) and 14OM20B (86 cm long), were recovered from three sites using a UWITEC gravity corer (6 cm internal diameter) equipped with a hammer tool in July 2014. From the three cores, 16 bulk organic carbon samples were selected because of the lack of macrofossil remains and radiocarbon dated using accelerator mass spectrometry (AMS) at Poznań radiocarbon laboratory of Adam Mickiewicz University, Poland. In addition, 30 freeze-dried samples per core at 0.25 or 0.5 cm intervals between 0 and 15 cm were analysed for 210Pb/137Cs at the Liverpool University Environmental Radioactivity Laboratory. In this project, we analyse pollen and sedaDNA (Liu et al., 2020; doi:10.5061/dryad.69p8cz900) from three lake sediment cores from the Omoloy region in north-eastern Siberia (northern Yakutia), which are currently surrounded by different vegetation types ranging from typical tundra to open larch forest. First, our aim is to compare sedaDNA with the pollen data to see whether both methods track the same pattern with respect to compositional changes and diversity changes across the northern Russian treeline zone or are complementary to each other. Second, we reconstruct the mid- to late-Holocene changes of vegetation composition along a north–south transect. Third, we use the sedaDNA data to reconstruct variations in species richness and relate this to vegetation and climate change.

Description: Increasing climate variability may pose an even greater risk to species than climate warming because temperature fluctuations can amplify adverse impacts of directional warming on fitness-related traits. Here, the influence of directional warming and increasing climate variability on marine stickleback fish (Gasterosteus aculeatus) offspring size variation was investigated by simulating changes to the mean and variance of ocean temperatures predicted under climate change. Reproductive traits of mothers and offspring size reaction norms across four climate scenarios were examined to assess the roles of standing genetic variation, transgenerational and within-generation plasticity in adaptive potential. Mothers acclimated to directional warming produced smaller eggs than mothers in constant, ambient temperatures, whereas mothers in a predictably variable environment (weekly change between temperatures) produced a range of egg sizes, possibly reflecting a diversified bet hedging strategy. Offspring size post-hatch was mostly influenced by genotype by environment interactions and not transgenerational effects. Offspring size reaction norms also differed depending on the type of environmental predictability (predictably variable vs. stochastic), with offspring reaching the largest sizes in the stochastic environment. Release of cryptic genetic variation for offspring size in the stochastic environment suggests hidden evolutionary potential in this wild population to respond to changes in environmental predictability.

Description: The isotopic composition of water in ice sheets is extensively used to infer past climate changes. In low-accumulation regions their interpretation is however challenged by poorly constrained effects that may influence the initial isotope signal during and after deposition of the snow. This is reflected in snow-pit isotope data from Kohnen Station, Antarctica, which exhibit a seasonal cycle but also strong inter-annual variations that contradict local temperature observations. These inconsistencies persist even after averaging many profiles and are thus not explained by local stratigraphic noise. Previous studies have suggested that post-depositional processes may significantly influence the isotopic composition of East Antarctic firn. Here, we investigate the importance of post-depositional processes within the open-porous firn (〉 10 cm depth) at Kohnen Station by separating spatial from temporal variability. To this end, we analyse 22 isotope profiles obtained from two snow trenches and examine the temporal isotope modifications by comparing the new with published trench data extracted 2 years earlier. The initial isotope profiles undergo changes over time due to downward-advection, firn diffusion and densification in magnitudes consistent with independent estimates. Beyond that, we find further modifications of the original isotope record to be unlikely, or small in magnitude (〈〈 1 per mil RMSD). These results show that the discrepancy between local temperatures and isotopes most likely originates from spatially coherent processes prior to or during deposition, such as precipitation intermittency or systematic isotope modifications acting on drifting or loose surface snow.

Description: Due to methodological challenges there are only a few studies that focus on macrophyte dynamics in large lakes despite their notable role in a lake's ecosystem functioning. This study investigates composition and productivity changes of the submerged vegetation of Lake Karakul, Pamir Mountains (Tajikistan), using sedimentary ancient DNA metabarcoding and elemental (C/N) and isotopic (d13C, d15N) measurements of Stuckenia cf. pamirica ((Baagøe) Z.Kaplan; Potamogetonaceae) leaf remains. No Stuckenia cf. pamirica leaf remains were found for 28.7 to 26.1 cal ka BP, when both Potamogetonaceae and Chara (L.) DNA sequences were recorded, suggesting sparse submerged vegetation at the coring site. This agrees with the inference of a deep lake reached using geochemical proxies. From 26.1 to 17.5 cal ka BP a few macrophyte remains and high numbers of Potamogetonaceae sequences were recovered: lake level was probably low, as suggested by other studies on the lake. Another phase of increased numbers of Chara sequences and the absence of Stuckenia cf. pamirica leaf remains was found between 17.5 and 12.2 cal ka BP, which coincides with a lake-level transgression at Lake Karakul as indicated by paleo-shoreline investigations. Analyses of macrophyte remains reveal intermediate paleo-productivity from 6.9 cal ka BP and high paleo-productivity from 2.2 cal ka BP onwards. From comparisons with other studies, we suggest that lake-level changes are the main driver for the submerged vegetation composition and productivity at the coring site in Lake Karakul and underline our conclusions by depicting the present-day distribution of Stuckenia cf. pamirica and Chara within the lake.

Description: Understanding the resilience of African savannas to global change requires quantitative information on long-term vegetation dynamics. Here we present a reconstruction of past vegetation cover of the northern Namibian savanna obtained after applying the REVEALS model to fossil pollen data from Lake Otjikoto. We also present modern pollen and vegetation data used to calculate pollen productivity estimates for the major Namibian savanna taxa Acacia (Senegalia, Vachellia), Combretaceae, Dichrostachys, Grewia and Poaceae. Data were collected at 10 sites along a rainfall gradient in north central Namibia. Modern pollen was extracted from soil samples collected from plots at the different sites. Vegetation data were extracted from satellite images covering a 1.5 km radius from the plots where pollen was collected. The mean cover of the studied taxa was calculated by 100 m rings.

Description: The Late Holocene is a substantial cultural and economic transition in the eastern Eurasian Steppe and Altai Region, but paleoclimate conditions during this time remain unclear. Therefore, we established a high-resolution paleoclimate record from Lake Khar Nuur in the Mongolian Altai, spanning the last 4200 years. Lake Khar Nuur is a high-altitude lake with a small catchment located at 2,486 m a.s.l. (48°37'22.9"N, 88°56'42.5"E). We recovered the sediment core (that we abbreviate KN18) from the deepest part of the lake (49.4 m) in July 2018 using an Uwitec gravity corer. Within the sediment core KN18, a wide array of lake sediment proxies was measured. While total organic carbon (TOC), total nitrogen, bulk δ^13^C~TOC~, δ^15^N and biogenic silica were measured in 2 cm resolution, the elemental composition (log (Ca/Ti) ratio) was measured in 0.5 cm resolution. Additionally, compound-specific hydrogen isotopic composition of _n_-alkanes was measured in 1 cm resolution.

Description: In order to interpret the paleoclimatic record stored in the air enclosed in polar ice cores, it is crucial to understand the fundamental lock-in process. Within the porous firn, bubbles are sealed continuously until the respective horizontal layer reaches a critical porosity. Present-day firn models use a postulated temperature dependence of this value as the only parameter to adjust to the surrounding conditions of individual sites. However, no direct measurements of the firn microstructure could confirm these assumptions. Here we show that the critical porosity is a universal constant by providing a statistically solid data set of µm-resolution 3D X-ray computer tomographic measurements for ice cores representing different extremes of the temperature and accumulation ranges. We demonstrate why indirect measurements yield misleading data and substantiate our observations by applying percolation theory as a theoretical framework for bubble trapping. Incorporation of our results does significantly influence the dating of trace gas records, changing gas age-ice age differences by up to more than 1000 years. This will help resolve inconsistencies, such as differences between East Antarctic d15N records (as a proxy for firn height) and model results. We expect our findings to be the basis for improved firn air and densification models, leading to lower dating uncertainties. The reduced coupling of proxies and surrounding conditions may allow for more sophisticated reinterpretations of trace gas records in terms of paleoclimatic changes and will foster the development of new proxies, such as the air content as a marker of local insolation.

Description: Abstract: We investigated the bacterial community structure in surface waters along a 2500 km transect in the eastern Indian Ocean. Using high throughput sequencing of the 16S rRNA gene we measured a significant latitudinal increase in bacterial richness from 800 to 1400 OTUs (42% increase; r2=0.65; p〈0.001) from the tropical Timor Sea to the colder temperate waters. Total dissolved inorganic nitrogen, chl a, phytoplankton community structure and primary productivity strongly correlated with bacterial richness (all p〈0.01). Our data suggest that primary productivity drives greater bacterial richness. Because, N2-fixation accounts for up to 50% of new production in this region we tested whether higher N2-fixation rates are linked to a greater nifH diversity. The nifH diversity was dominated by heterotrophic Alphaproteobacteria, Betaproteobacteria, and Gammaproteobacteria. We did not found any mechanistic links between nifH amplicon data, bacterial richness and primary productivity due to the overall low nifH evenness in this region. Scientific statement: Geographic gradients of marine microbial diversity is currently thought to be explained by two mechanisms, 1) diversity increases with increased productivity, and 2) it increases with increasing temperature. However, conclusive evidence for these mechanisms has been lacking from studies that span gradients in both, and it is unclear which organisms are responsible for the changes in diversity along these gradients. Here we present the first analysis of bacterial richness along the West Australian boundary current, the Leeuwin Current. Our analysis of bacterial richness along a latitudinal gradient in the eastern Indian Ocean shows support for the productivity mechanism rather than the temperature mechanism. Further, we show that bacterial richness increases towards the productive temperate waters are driven by productive eukaryotes (NO3- based) and heterotrophic N2-fixers.

Description: A shallow subtidal area in the northern Wadden Sea was monitored over 17 years for sediment parameters and macrobenthic fauna using stratified random sampling of a grid of 50 sampling positions. Samples were collected with a Reineck-type box-corer of 0.02 m² surface area, always during preceeded high tide. Granulometric sediment composition was analysed from a sub-sample of each box-core using a diffraction laser particle-size analyser. Macrobenthos (sieved through 1 mm square meshes and fixed in buffered formalin solution) was counted, identified to species level, and the size of hard-shelled individuals measured. The amount of shell detritus was quantified as wet-weight in the benthos samples. From 2003 to 2007 sampling was approximatively monthly and from 2008 to 2013 seasonally. When a new ship with larger drought was put into operation, the number of sampling sites needed to be reduced to 33 from 2014 onwards and sampling frequency was only once per year in autumn.

Description: Upper air soundings onboard Polarstern are normally performed once a day to measure vertical profiles of air pressure, temperature, relative humidity and the wind vector. Helium filled balloons (TOTEX 600 g) were used to carry Vaisala RS92-SGP radiosondes. Whenever possible, the launches were carried out shortly before 11 UTC, in order to reach 100 hPa at 12 UTC. Condensed measurements (TEMP Format FM-35, BUFR) were transferred without delay into the Global Telecommunication System GTS, were they contribute to the world wide weather forecast analysis. The profile data were taken every 5 seconds, which results in a vertical resolution of about 25 meter. The profiles start at the helideck 10 m above sea level and terminate at the burst level of the balloons, normally at heights between 25 and 37 km.

Description: The Yermak Plateau is located north of Svalbard at the entrance to the Arctic Ocean, i.e. in an area highly sensitive to climate change. A multi proxy approach was carried out on Core PS92/039-2 to study glacial-interglacial environmental changes at the northern Barents Sea margin during the last 160 ka. The main emphasis was on the reconstruction of sea ice cover, based on the sea ice proxy IP25 and the related phytoplankton - sea ice index PIP25. Sea ice was present most of the time but showed significant temporal variability decisively affected by movements of the Svalbard Barents Sea Ice Sheet. For the first time, we prove the occurrence of seasonal sea ice at the eastern Yermak Plateau during glacial intervals, probably steered by a major northward advance of the ice sheet and the formation of a coastal polynya in front of it. Maximum accumulation of terrigenous organic carbon, IP25 and the phytoplankton biomarkers (brassicasterol, dinosterol, HBI III) can be correlated to distinct deglaciation events. More severe, but variable sea ice cover prevailed at the Yermak Plateau during interglacials. The general proximity to the sea ice margin is further indicated by biomarker (GDGT) - based sea surface temperatures below 2.5 °C.

Description: Past sea ice conditions and open water phytoplankton production were reconstructed from a sediment core taken in Disko Bugt, West Greenland, using the sea ice biomarker IP~25~ and other specific phytoplankton biomarker (i.e., brassicasterol, dinosterol, HBI III) records. Our biomarker record indicates that Disko Bugt experienced a gradual expansion of seasonal sea ice during the last 2.2 kyr. Maximum sea ice extent was reached during the Little Ice Age around 0.2 kyr BP. Superimposed on this longer term trend, we find short-term oscillations in open water primary production and terrigenous input, which may be related to the Atlantic Multidecadal Oscillation and solar activity changes as potential climatic trigger mechanisms. A direct sample-to-sample multiproxy comparison of our new biomarker record with microfossil (i.e., benthic foraminifera, dinocysts, and diatoms) and other geochemical records (i.e., alkenone biomarkers) indicates that different proxies are influenced by the complex environmental system with pronounced seasonal changes and strong oceanographic gradients, e.g., freshwater inflow from the Greenland Ice Sheet. Differences in sea ice reconstructions may indicate that the IP~25~ record reflects only the relatively short sea ice season (spring), whereas other microfossil reconstructions may reflect a longer (spring–autumn) interval.

Description: Using a microprofiler and electrochemical oxygen sensors after Revsbech (1989) in situ oxygen profiles measurements were conducted with a spatial resolution if 100 µm and a temporal resolution of 30 seconds at three stations in Potter Cove in austral summer 2015.

Description: This is a dataset from an in situ experiment at station S2 from the LTER monitoring site HAUSGARTEN, performed in June-July 2013 during Maria S Merian expedition MSM29. The in situ responses of Arctic deep-sea benthos to input of phytodetritus of a diatom (Thalassiosira sp.) as opposed to a coccolithophorid (Emiliania huxleyi) were investigated in incubation chambers of benthic landers. Using 13C and 15N labelled phytodetritus harvested from cultures of these species, we traced the fate of the respective phytodetritus into different parts of the food web (respiration, assimilation by bacteria and infauna 〉250 µm), in a short (4d) and long (14d) term experiment. The benthic landers were lowered to the sea floor, where they enclosed ~ 20cm of sediment and ~10 cm of overlying water. During respectively 4d and 14d, the temperature and concentrations of O2, DIC, 13C-DIC, NHx, NOx, 15N-NH4, 15N-NOx were measured. Upon recovery of the landers, the sediment was retrieved and subsampled in vertical horizons to measure pigment, TOC and TN, 13C-POC and 15N-PN concentrations, pore water concentrations of DIC, 13C-DIC, NHx, NOx, 15N-NH4 and 15N-NOx and the assimilation of 13C in bacterial fatty acids (iC15:0 and aiC15:0) and in fauna 〉 250 µm

Description: We present the first field application of a N2O-based approach to correct for vertical mixing in the estimation of net community production (NCP) from mixed layer O2 measurements. Using new ship-based observations of N2O and biological oxygen saturation anomalies (DeltaO2/Ar) from the Subarctic Northeast Pacific, we provide refined mixed layer NCP estimates across contrasting hydrographic regimes and a comprehensive assessment of the methodological considerations and limitations of the approach. Increased vertical mixing coefficients at the base of the mixed layer, derived using N2O measurements, corresponded with periods of heightened wind speed and coastal upwelling. Corrections were most significant in coastal regions where the vertical supply of low-O2 water can otherwise falsely imply net heterotrophy from negative DeltaO2/Ar measurements. After correcting for the mixing flux, all coastal stations showed autotrophic signatures, with maximum NCP exceeding 100 mmol O2 m-2 day-1 in the spring and summer. Vertical fluxes were lower in off-shelf waters, but often contributed more than 50 % to corrected NCP. At some oceanic stations, however, the co-occurrence of N2O minima and O2 maxima resulted in biased (over-estimated) N2O corrections. Evaluating vertical fluxes in these regions remains a challenge for ship-based studies. Nonetheless, our refined NCP estimates show better coherence with surface chlorophyll, temperature, and mixed layer depth than uncorrected values. Potential mixed layer N2O production introduces some uncertainty in the approach, but errors are likely to be small. Ultimately, this work provides rationale for the adoption of the N2O correction to refine NCP estimates, particularly in coastal waters. Data in this submission include the ancillary components required to replicate all calculations, and conclusions made in the main manuscript.

Description: Arctic treelines are facing a strong temperature increase as a result of recent global warming, causing possible changes in forest extent, which will alter vegetation-climate feedbacks. However, the mode and strength of the response is rather unclear, as potential changes are happening in areas that are very remote and difficult to access, and empirical data are still largely lacking. Here, we assessed the current population structure and genetic differentiation of Larix Mill. tree stands within the northernmost latitudinal treeline reaching ~72° N in the southern lowlands of the Taymyr Peninsula (~100° E). We sampled 743 individuals belonging to different height classes (seedlings, saplings, trees) at eleven locations along a gradient from 'single tree' tundra over 'forest line' to 'dense forest' stands and conducted investigations applying eight highly polymorphic nuclear microsatellites. Results suggest a high diversity within subpopulations (HE=0.826-0.893), coupled, however, with heterozygote deficits in all subpopulations, but pronounced in 'forest line' stands. Overall, genetic differentiation of subpopulations is low (FST=0.005), indicating a region-wide high gene flow, although 'forest line' stands harbour few rare and private alleles, likely indicating greater local reproduction. 'Single tree' stands, located beyond the northern forest line, are currently not involved in treeline expansion, but show signs of a long-term refuge, namely asexual reproduction and change of growth-form from erect to creeping growth, possibly having persisted for thousands of years. The lack of differentiation between the subpopulations points to a sufficiently high dispersal potential, and thus a rapid northward migration of the Siberian arctic treeline under recent global warming seems potentially unconstrained, but observations show it to be unexpectedly slow.

Description: Ground-based spectroscopy measurements acquired systematically within the Toolik Vegetation Grid in the 2015 and 2016 growing seasons and within the Imnavait Vegetation Grid in the 2016 growing season. Data were collected in 68 distinct 1 x 1 m long-term monitoring plots representing five distinct vegetation communities. Spectral measurements were acquired two times throughout the season in 2015 representing peak and late season and three times in 2016 representing early, peak and late season. Data were acquired using a GER 1500 field spectrometer (350-1050 nm; 512 bands, spectral resolution 3 nm, spectral sampling 1.5 nm, and 8! field of view). Spectra were collected under clear weather conditions at the highest solar zenith angle between 10:00 and 14:00 local time. Data were collected at nadir approximately 1 m off the ground resulting in a Ground Instantaneous Field of View (GIFOV) of approximately 15 cm in diameter. Nine point measurements of upwelling radiance (Lup) were collected in 1 x 1 m plots representative of the five vegetation communities and averaged to characterize the spectral variability and to reduce noise. Downwelling radiance (Ldown) was measured as the reflectance from a white Spectralon© plate. Surface reflectance (R) was processed as Lup/Ldown x 100 (0-100%). Reflectance spectra were preprocessed with a Savitzky-Golay smoothing filter (n = 11) and subset to 400-985 nm to remove sensor noise at the edges of the radiometer detector.

Description: Our data, as part of the OISO (Ocean Indien Service d'Observation) campaign, contributes to a better understanding of the physical and biological factors controlling N2 fixation in the Southern Indian Ocean and the French Southern and Antarctic lands during Austral summer January and February 2017. We measured N2 and C fixation as well as NH4+ and NO3- assimilation in 3-6 replicates per station. Additionally, we measured diagnostic pigment concentrations to evaluate phtosynthetic community composition. For pigment analysis 4L water was filtered through 25mm Whatman GF/F filters (pressure drop 〈10kPa). Samples were stored at -80°C until analysis. Pigments were analysed using High Performance Liquid Chromatography (HPLC). Pigment concentration were calculated according to Kilias et al (2013, doi:10.1111/jpy.12109). N2 fixation experiments were carried out in three to six replicates for each station. Incubations were done in pre-acid washed polycarbonate bottles on deck with ambient light conditions. All polycarbonate incubation bottles were rinsed with deionized water, and seawater prior to incubation. We used the combination of the bubble approach (Montoya et al., 1996) and the dissolution method (Mohr et al., 2010, doi:10.1371/journal.pone.0012583) proposed by Klawonn et al. (2015, doi:10.3389/fmicb.2015.00769). Bottles were filled up to capacity to avoid air contamination. Incubations were initialized by adding a 10 ml 15-15N gas bubble. Bottles were gently rocked for 15 minutes. Finally, the remaining bubble was removed to avoid equilibration between gas and aqueous phase. after 24 hours a water subsample was taken to a 12 ml exetainer and preserved with 100 µl HgCl2 solution for later determination of exact 15N-15N concentration. Natural 15N2 was determined using Membrane Inlet Mass Spectrometry (MIMS; GAM200, IPI) for each station. Analysis of 15N2 incorporated was carried out by the Isotopic Laboratory at the UC Davis, California campus. We used stable isotope tracers (15N) to measure dissolved inorganic nitrogen (DIN) assimilation rates. Experiments were initiated by adding a known concentration of 0.05 of K15NO3 and 15NH4Cl for oligotrophic waters of the IO and 0.625 µmol L-1 for HNLC regions in the ACC and PF (Knap et al., 1994, Waite et al., 2007, doi:10.1016/j.dsr2.2006.12.010) to one litre polycarbonate bottles. For C assimilation experiments, we added 20 µmol L-1 of NaH13CO3 to one of each of N2 fixation, NH4+ and NO3- assimilation experiment bottles. For incubation, we followed the same procedure as for N2 fixation experiments. Findings reveal that N2 fixation occurs throughout the whole sampling area up to 55°S latitude. In addition, variations of N2 fiaxation rates between replicates were relatively high indicating a great heterogeneity of the French Southern and Antarctic waters. References: Montoya 1996: Montoya, Joseph P., et al. "A Simple, High-Precision, High-Sensitivity Tracer Assay for N (inf2) Fixation." Applied and environmental microbiology 62.3 (1996): 986-993. Knap et al 1994: Knap, A., Michaels, A., Close, A., Ducklow, H. & Dickson, A. 1994. Protocols for the Joint Global Ocean Flux Study (JGOFS) Core Measurements, JGOFS, Reprint of the IOC Manuals and Guides No. 29. UNESCO, 19, 1.

Description: Lithogenic material such as Saharan dust can be incorporated into organic aggregates and act as ballast, potentially enhancing the marine carbon export via increased sinking velocities of aggregates. We studied the ballasting effects of Saharan dust on the aggregate dynamics in the upwelling region off Cape Blanc (Mauritania). Aggregate formation from a natural plankton community exposed to Saharan dust deposition resulted in higher abundance of aggregates with higher sinking velocities compared to aggregate formation with low dust. This higher aggregate abundance and sinking velocities potentially increased the carbon export 10-fold when the aggregates were ballasted by Saharan dust. After aggregate formation in the surface waters, subsequent sinking through suspended Saharan dust minerals had no influence on aggregate sizes, abundance, and sinking velocities. We found that aggregates formed in the surface ocean off Mauritania were already heavily ballasted with lithogenic material and could therefore not scavenge any additional minerals during their descent. This suggests that carbon export to the deep ocean in regions with high dust deposition is strongly controlled by dust input to the surface ocean while suspended dust particles in deeper water layers do not significantly interact with sinking aggregates.

Description: Ground-based spectroscopy measurements acquired systematically within the Toolik Vegetation Grid in the 2016 growing season. All data were collected in a subset of 1 x 1 m long-term monitoring plots representing three distinct vegetation communities three times representing early, peak and late season. Spectral data were acquired using a GER 1500 field spectrometer (350-1050 nm; 512 bands, spectral resolution 3 nm, spectral sampling 1.5 nm, and 8! field of view). Spectra were collected under clear weather conditions at the highest solar zenith angle between 10:00 and 14:00 local time. Data were collected at nadir approximately 1 m off the ground resulting in a Ground Instantaneous Field of View (GIFOV) of approximately 15 cm in diameter. Nine point measurements of upwelling radiance (Lup) were collected in each plot and averaged to characterize the spectral variability and to reduce noise. Downwelling radiance (Ldown) was measured as the reflectance from a white Spectralon© plate. Surface reflectance (R) was processed as Lup/Ldown x 100 (0-100%). Reflectance spectra were preprocessed with a Savitzky-Golay smoothing filter (n = 11) and subset to 400-985 nm to remove sensor noise at the edges of the radiometer detector. Digital camera data were acquired using a consumer-grade camera (Panasonic DM3 LMX, Japan) approximately 1 m off the ground with a white frame for registration of off nadir images. For detailed definitions of the RGB indices see metadata.docx. Leaves and stems of the dominant vascular species in a subset of the sampled plots were collected at early, peak, and late season for chlorophyll and carotenoid analysis.Samples were placed in porous tea bags and preserved in a silica gel desiccant in an opaque container for up to 3 months until pigment extraction (Esteban et al. 2009, doi:10.1007/s11120-009-9468-5). Each sample was homogenized by grinding with a mortar and pestle. Approximately 1.00 mg (+/- 0.05 mg) of homogenized sample was placed into a vial with 2 ml of dimethylformamide (DMF). Vials were then wrapped in aluminum foil to eliminate any degradation of pigments due to UV light and stored in a fridge (4C) for 24 hrs. Samples were measured into a cuvette prior to spectrophotometric analysis. Bulk pigments concentrations were then estimated using a spectrophotometer measuring absorption at 646.8, 663.8 and 480 nm (Porra et al. 1989, doi:10.1016/S0005-2728(89)80347-0) . Absorbance (A) values at specific wavelengths were transformed into µg/mg concentrations of chlorophyll a, Chla, chlorophyll b, Chlb, total chlorophyll, Chl, carotenoids, Car (for equations see metadata.docx). Pigment concentration was calculated as the average concentration of the dominant species in each plot. mean_"pigment" represents the mean of all biomass from each vegetation community and sd_"pigment" represents the standard deviation of each vegetation community.

Description: Seasonal variations in fluxes of isoprenoid glycerol dialkyl glycerol tetraethers (GDGTs) and the estimated temperatures based on TEX86 are examined in sinking particles collected using moored sediment traps in the eastern Atlantic upwelling regions. In the equatorial Guinea Basin, GDGT fluxes show a correlation with opal fluxes, implying that GDGTs are mainly transported via aggregation with diatoms. The flux-weighted TEXH86 temperatures derived from particles collected both at 853 m and 3,921 m depth correspond to the water temperature (24.1 °C) of ca. 50 m depth, where nitrate concentration starts to increase, potentially as a consequence of nitrification by Thaumarchaeota. This suggests that nutrient concentrations may affect the depth habitat of Thaumarchaeota, and it determines at which water depth the TEXH86 temperature is recorded. In the coastal upwelling off Namibia, TEXH86 temperatures are similar to satellite-derived sea surface temperature (SST) during the warm season, but the record derived from the trap is delayed relative to the SST by approximately 26 days. Warm biases, however, occur during the cold season, similar to what has previously been observed in the filamentous upwelling region off Cape Blanc. In both coastal upwelling regions, oxygen minimum zones (OMZs) are a common feature, and higher TEX86 values have been found within the OMZs in the water column off Cape Blanc and elsewhere. Thus, contributions from GDGTs produced in OMZs might explain the warmer temperature estimates during the cold season in both regions. We thus conclude that in the eastern Atlantic upwelling system, TEXH86 temperature estimates are influenced by non-thermal factors such as nutrient depth distributions and GDGTs produced in the OMZ. In paleoenvironmental records of TEX86, non-thermal signals have to be considered on regional scales.

Description: Recently, Ponto-Caspian species (i.e. area of Azov, Black and Caspian Seas) have invaded brackish and freshwater habitats of the North and Baltic Seas and the Laurentian Great Lakes in much higher numbers than expected based on shipping frequency and environmental conditions among these regions. Therefore, it has been hypothesized that Ponto-Caspian species may have inherent advantages over other species in colonizing new habitats, or that they are of freshwater origin. To test these hypotheses, we conducted artificial selection experiment on Ponto-Caspian amphipod Pontogammarus maeoticus collected from 10 PSU to evaluate adaptation capacity of this species to different salinities. Our results indicated that selection to lower salinity than that of population's ambient salinity is possible. Though, generation time in lower salinity conditions took slightly longer. On the contrary, selection to higher salinity was unsuccessful. Taking into account the results from this and previous studies and the geological history of the Ponto-Caspian region, we suggest that majority of the Ponto-Caspian relict fauna might be of freshwater origin and lack necessary genetic background for adaptation to fully marine conditions. Further selection studies using more species and populations, as well as molecular techniques, should be conducted to confirm this hypothesis on a broader scale. Consequently, if Ponto-Caspian relict species are of freshwater origin, the perception that they are better colonizers than species from other regions might be inclined by the fact that areas with biggest introduction frequency of nonindigenous species (i.e., shipping ports) are environmentally variable habitats which often include freshwater conditions.

Description: The Kara Sea is an important area for paleo-climatic research since sea ice and brine formation take place on its shelf-two processes inducing supra-regional climatic implications and thereby connecting regional environmental variability with global climatic conditions. To gain information about past sea ice coverage and variations, three sediment cores distributed in the southern and central parts of the marginal Sea were investigated. By applying the sea ice biomarker IP25 and the PIP25 index [phytoplankton biomarker (dinosterol)-IP25 index] post-glacial sea ice variability could be detected in the central Kara Sea (Core BP00-36/4), with most intense sea ice cover between 12.4 and 11.8 ka coinciding with the Younger Dryas (12.9-11.6 ka), and reduced sea ice cover between 10 and 8 ka during the Holocene Thermal Maximum. During the last ~7 ka, increasing sea ice indicators might indicate a Holocene cooling trend, probably induced by declining summer insolation. Furthermore, temporal changes in the fast ice?polynya distribution in the southern Kara Sea were detected: expanding fast ice during the late Holocene and a cyclic short-term Holocene climate variability documented by abrupt changes in the sea ice coverage at the BP00-07/7 core site. Core BP99-04/7 from the Yenisei estuary recorded consistently seasonal sea ice cover since ~9.3 ka, apart from five short phases of fast ice expansion to the core site. The strong influence of river run-off as well as estuary processes might prevent the detection of (short-term) climatic signals at this study site.

Description: Extra-tropical circulation systems impede poleward moisture advection by the Indian Summer Monsoon. In this context, the Himalayan range is believed to insulate the south Asian circulation from extra-tropical influences and to delineate the northern extent of the Indian Summer Monsoon in central Asia. Paleoclimatic evidence, however, suggests increased moisture availability in the Early Holocene north of the Himalayan range which is attributed to an intensification of the Indian Summer Monsoon. Nevertheless, mechanisms leading to a surpassing of the Himalayan range and the northern maximum extent of summer monsoonal influence remain unknown. Here we show that the Kunlun barrier on the northern Tibetan Plateau [~36°N] delimits Indian Summer Monsoon precipitation during the Holocene. The presence of the barrier relocates the insulation effect 1,000 km further north, allowing a continental low intensity branch of the Indian Summer Monsoon which is persistent throughout the Holocene. Precipitation intensities at its northern extent seem to be driven by differentiated solar heating of the Northern Hemisphere indicating dependency on energy-gradients rather than absolute radiation intensities. The identified spatial constraints of monsoonal precipitation will facilitate the prediction of future monsoonal precipitation patterns in Central Asia under varying climatic conditions.