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  • Articles  (104)
  • diatoms  (62)
  • Geochemistry  (42)
  • Springer  (104)
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  • 1995-1999  (104)
  • Geosciences  (104)
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  • Springer  (104)
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  • 1
    Electronic Resource
    Electronic Resource
    Crystal retention, fractionation and crustal assimilation in a convecting magma chamber, Nisyros Volcano, Greece (1995)
    Springer
    Bulletin of volcanology 56 (1995), S. 601-620 
    Details
    ISSN: 1432-0819
    Keywords: Calc-alkaline volcanism ; Geochemistry ; Isotopic study ; Petrology ; Magmatic evolution ; Aegean Arc ; Nisyros volcano
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract Nisyros island is a calc-alkaline volcano, built up during the last 100 ka. The first cycle of its subaerial history includes the cone-building activity with three phases, each characterized by a similar sequence: (1) effusive and explosive activity fed by basaltic andesitic and andesitic magmas; and (2) effusive andextrusive activity fed by dacitic and rhyolitic magmas. The second eruptive cycle includes the caldera-forming explosive activity with two phases, each consisting of the sequence: (1) rhyolitic phreatomagmatic eruptions triggering a central caldera collapse; and (2) extrusion of dacitic-rhyolitic domes and lava flows. The rocks of this cycle are characteized by the presence of mafic enclaves with different petrographic and chemical features which testify to mixing-mingling processes between variously evolved magmas. Jumps in the degree of evolution are present in the stratigraphic series, accompanied by changes in the porphyritic index. This index ranges from 60% to about 5% and correlates with several teochemical parameters, including a negative correlation with Sr isotope ratios (0.703384–0.705120). The latter increase from basaltic andesites to intermediate rocks, but then slightly decrease in the most evolved volcanic rocks. The petrographic, geochemical and isotopic characteristics can be largely explained by processes occurring in a convecting, crystallizing and assimilating magma chamber, where crystal sorting, retention, resorption and accumulation take place. A group of crystal-rich basaltic andesites with high Sr and compatible element contents and low incompatible elements and Sr isotope ratios probably resulted from the accumulation of plagioclase and pyroxene in an andesitic liquid. Re-entrainment of plagioclase crystals in the crystallizing magma may have been responsible for the lower 87Sr/86Sr in the most evolved rocks. The gaps in the degree of evolution with time are interpreted as due to liquid segregation from a crystal mush once critical crystallinity was reached. At that stage convection halted, and a less dense, less porphyritic, more evolved magma separated from a denser crystal-rich magma portion. The differences in incompatible element enrichment of pre-and post-caldera dacites and the chemical variation in the post-caldera dome sequence are the result of hybridization of post-caldera dome magmas with more mafic magmas, as represented by the enclave compositions. The occurrence of the quenched, more mafic magmas in the two post-caldera units suggests that renewed intrusion of mafic magma took place after each collapse event.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00301465
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  • 2
    Electronic Resource
    Electronic Resource
    Correlation of rhyolitic pyroclastic eruptive units from the Taupo volcanic zone by Fe–Ti oxide compositional data (1998)
    Springer
    Bulletin of volcanology 60 (1998), S. 224-238 
    Details
    ISSN: 1432-0819
    Keywords: Key words Fe ; Ti oxides ; Tephrostratigraphy ; Geochemistry ; Geothermometry ; Taupo volcanic zone
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract Grain-specific analyses of Fe–Ti oxides and estimates of eruption temperature (T) and oxygen fugacity (fO2) have been used to fingerprint rhyolitic fall and flow deposits that are important for tephrostratigraphic studies in and around the Taupo volcanic zone of North Island, New Zealand. The analysed Fe–Ti oxides commonly occur in the rims of orthopyroxene crystals and appear to reflect equilibrium immediately prior to eruption because of geochemical correlation with the co-existing glass phase. The composition of the spinel phase is particularly diagnostic of eruptive centre for post-65 ka events and can be used to distinguish many tephra beds from the same volcano. The 29 different units examined were erupted over a wide range in T (690–990°C) and Δ log fO2 (–0.1 to 2.0). These parameters are closely related to the mafic mineral assemblage, with hydrous mineral-bearing units displaying higher fO2. Such trends are superimposed on larger differences in fO2 that are related to eruptive centre. At any given temperature, all post-65 ka Okataina centre tephra have higher fO2 values than post-65 ka Taupo centre tephra. This provides a useful criterion for identifying the volcanic source. There are no temporal T and fO2 trends in the tephra record; over intervals 〉20 ka, however, tephra sequences from Taupo centre form characteristic T-fO2 buffer trends mirroring the glass chemistry. Individual eruptive events display uniform spinel and rhombohedral phase compositions and thus narrow ranges in T (± 〈20°C) and log fO2 (± 〈0.5), allowing these features to identify individual magma batches. These criteria can help distinguish tephra deposits of similar bulk or glass composition that originated from the same volcano. Distal fall deposits record the same T-fO2 conditions as the proximal ignimbrite and enable distal–proximal correlation. Lateral and vertical compositional and T-fO2 variability displayed in large volume (〉100 km3) ignimbrites, such as the Oruanui, Rotoiti and Ongatiti, is similar to that found in a single pumice clast and thus mainly reflects analytical error; however, thermal gradients of ca. 50°C may occur in some units.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/s004450050229
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  • 3
    Electronic Resource
    Electronic Resource
    Garnet pyroxenite and eclogite in the Bohemian Massif: geochemical evidence for Variscan recycling of subducted lithosphere (1995)
    Springer
    International journal of earth sciences 84 (1995), S. 489-505 
    Details
    ISSN: 1437-3262
    Keywords: Bohemian Massif ; Variscan ; Geochemistry ; Garnet pyroxenite ; Eclogite ; Lithosphere
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract High-temperature, high-pressure eclogite and garnet pyroxenite occur as lenses in garnet peridotite bodies of the Gföhl nappe in the Bohemian Massif. The high-pressure assemblages formed in the mantle and are important for allowing investigations of mantle compositions and processes. Eclogite is distinguished from garnet pyroxenite on the basis of elemental composition, with mg number 〈80, Na2O 〉 0.75 wt.%, Cr2O3 〈 0.15 wt.% and Ni 〈 400 ppm. Considerable scatter in two-element variation diagrams and the common modal layering of some eclogite bodies indicate the importance of crystal accumulation in eclogite and garnet pyroxenite petrogenesis. A wide range in isotopic composition of clinopyroxene separates [εNd, +5.4 to −6.0; (87Sr/86Sr)i, 0.70314–0.71445; δ18OSMOW, 3.8–5.8%o] requires that subducted oceanic crust is a component in some melts from which eclogite and garnet pyroxenite crystallized. Variscan Sm-Nd ages were obtained for garnet-clinopyroxene pairs from Dobešovice eclogite (338 Ma), Úhrov eclogite (344 Ma) and Nové Dvory garnet pyroxenite (343 Ma). Gföhl eclogite and garnet pyroxenite formed by high-pressure crystal accumulation (±trapped melt) from transient melts in the lithosphere, and the source of such melts was subducted, hydrothermally altered oceanic crust, including subducted sediments. Much of the chemical variation in the eclogites can be explained by simple fractional crystallization, whereas variation in the pyroxenites indicates fractional crystallization accompanied by some assimilation of the peridotite host.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00284516
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  • 4
    Electronic Resource
    Electronic Resource
    Puncoviscana folded belt in northwestern Argentina: testimony of Late Proterozoic Rodinia fragmentation and pre-Gondwana collisional episodes (1999)
    Springer
    International journal of earth sciences 88 (1999), S. 76-97 
    Details
    ISSN: 1437-3262
    Keywords: Key words Plate tectonics ; Geochemistry ; Trace fossils ; Late Precambrian ; Eocambrian stratigraphy and magmatism ; Gravity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract  Stratigraphic correlations and tectonic analysis suggest that the Puncoviscana fold belt of northwestern Argentina was an intracontinental basin with bimodal igneous suites that formed in connection with the breakup of the Rodinia supercontinent (at ∼800 Ma). Several lines of evidences point to an initial lithosphere rupture, possibly induced by a rising mantle plume. The earliest synrift igneous products are represented by ultra-potassic dykes and alkaline lava flows of high LREE/HREE and low Zr/Nb–Y/Nb ratios. The dyke emplacements and the initiation of rifting were probably synchronous. They pass laterally and upwards (middle part of the Puncoviscana succession) into basalts of alkaline transitional character (OIB-like source). The distinctive chemical feature of these lavas are very similar to the source of oceanic island basalts; thus, they are thought to represent a magmatism associated with the rift and rift-drift transition stage. During this stage of rifting probably true oceanic crust was formed. The upper part of the Puncoviscana sequence, Late Precambrian/Lower Cambrian in age, comprises a thick and monotonous sequence of pillow lavas, massive basaltic flows and minor volcanic breccias and hyaloclastites. These lavas exhibit MORB trace element characteristics with high FeOt and TiO2, low K2O and P2O5, flat light REE spectra, little or no depletion in Nb and Ta. This volcanism consists of the major and latest effusive episode from the Puncoviscana basin which was slightly modified by subduction processes. The geodynamical model proposed for the generation of these volcanic rocks could have been developed in two stages. In the first stage the volcanic event is compatible with a progressive opening of a continental rift leading to formation of a mature oceanic basin. In contrast, the second stage shows the effects of a completed Wilson cycle including a primitive volcanic arc which continued until the accreted Cuyania-Arequipa-Belen-Antofalla (CABA) terrane against the proto-Gondwana western borderland of the Amazonian shield (∼535 Ma).
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/s005310050247
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  • 5
    Electronic Resource
    Electronic Resource
    Granitic rocks as a source of granite: The Gösta and Sundsta Granites, south-west Sweden (1995)
    Springer
    International journal of earth sciences 84 (1995), S. 164-174 
    Details
    ISSN: 1437-3262
    Keywords: Geochemistry ; Granite ; source material South-west Sweden ; Eutectic melting
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract Granites, among them three generations of microline-rich granites, intruded repeatedly between 1600 and 900 Ma in the South-western Swedish Gneiss Complex. The deformed and metamorphosed Gösta and Sundsta granites are medium-grained, pale greyish red rocks belonging to the oldest generation of microclinerich granites. Biotite dominates over hornblende. Allanite, titanite, apatite and zircon are important accessory minerals. The granites are metaluminous and syeno- to monzogranitic in composition. SiO2 varies between 70.4 and 78.7% and K2O/Na2O between 0.86 and 2.32. Na and K are poorly correlated with the other major elements. The rocks are low in MgO (〈 0.9%) and FeO (〈 3.6%). They are characterized by high Rb/Sr, Ba/Sr and Ba/Rb ratios. The ratio Nb/Ta is almost constant (≈ 12) and the ratio Al/Ga decreases slightly with increasing SiO2 content. The Gösta granite has small, negative Eu anomalies, differentiated light and almost flat heavy rare earth element patterns. It intruded into continental crust approximately 1560 Ma ago. It is argued that the granites formed from continental rocks by pseudoeutectic partial melting at a fairly shallow depth. The source is older than the dominant country rock.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00192248
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  • 6
    Electronic Resource
    Electronic Resource
    Sedimentological proof and dating of the Early Holocene volcanic eruption of Ulmener Maar (Vulkaneifel, Germany) (1995)
    Springer
    International journal of earth sciences 84 (1995), S. 213-219 
    Details
    ISSN: 1437-3262
    Keywords: Sediments ; Varves ; Tephra layers ; Radiocarbon dating ; Geochemistry ; Palaeomagnetics Volcanism ; Holocene ; Westeifel (Germany)
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract A minerogeniclayer occurs in early postglacial organic sediments from five maar lakes (West Eifel Volcanic Field, Germany). The mineralogy and stratigraphic position of this tephra suggests that it is related to the youngest German volcano, Ulmener Maar, nearby. Radiocarbon dating of wood from the base of the Ulmener Maar Tephra at two locations provide ages in agreement with an accelerator mass spectrometer 14C date for the minerogenic layer from sediments of Lake Holzmaar situated 13 km south-west of Ulmener Maar. The mean radiocarbon age is 9 560 years BP. Dating by varve chronology provides an age of 10017 years VT (varve time in years before 1950) or 10 895 years corrected VT. Based on palynology the Ulmener Maar Tephra was deposited at the end of the Preboreal. High values of natural remnant magnetization intensity, typical of pyroclastic material, confirm that this minerogenic layer differs in composition from other clastic deposits of the sedimentary record. Geochemical analyses reveal increased values of total trace elements for the Laacher See Tephra and Ulmener Maar Tephra. An isopach map based on thickness variations of the Ulmener Maar Tephra at five investigated maar lakes indicates that the tephra was mainly transported to the south west.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00192252
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  • 7
    Electronic Resource
    Electronic Resource
    Geochemistry of early Palaeozoic amphibolites from the Orlica-Śnieżnik dome, Bohemian massif: petrogenesis and palaeotectonic aspects (1996)
    Springer
    International journal of earth sciences 85 (1996), S. 225-238 
    Details
    ISSN: 1437-3262
    Keywords: L. Palaeozoic volcanics ; Amphibolites ; Geochemistry ; Petrogenesis ; Crustal contamination ; Palaeotectonic environment ; Orlica-Śnieżnik dome, Bohemian massif
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract Orthoamphibolites within and marginal to the Orlica-Śnieżnik dome in the eastern Bohemian massif are associated with a series of Proterozoic-Lower Palaeozoic supracrustal meta-sediments of the Stronie, Nové Město and Staré Město formations. Massive and variably foliated amphibolites range from common epidote-plagioclase-blue-green/green hornblende varieties to assemblages with diopside, garnet and brown amphibole. All the amphibolites have a basaltic composition and are divided into three main chemical groups which are intimately associated in the field: main series tholeiites, low-Ti tholeiites and alkali basalts. All groups exhibit a common enrichment in LIL elements+Nb+Ta (relative to high-field-strength elements) which reflects contamination by upper continental crust and/or pelagic sediment compositions. The gross chemistry of the tholeiitesapproaches that for MORB, although the geological environment and nature of crustal contamination suggests that the basaltic precursors were probably emplaced in a rifted ensialic basinal environment. If the amphibolites are representative of an early phase of the Lower Palaeozoic fragmentation of Gondwanaland, then rifting did not fully develop ocean crust. The wider significance of the chemical interpretation implies that some of the variation from Variscan Proterozoic-Palaeozoic metabasite suites that is ascribed to a complex of different eruptive settings could be accounted for by variable contamination and/or source composition.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02422230
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  • 8
    Electronic Resource
    Electronic Resource
    Granitoids in the Rozvadov Pluton, Western Bohemia and Oberpfalz (1995)
    Springer
    International journal of earth sciences 84 (1995), S. 506-519 
    Details
    ISSN: 1437-3262
    Keywords: Peraluminous granite ; Rare-metal granite ; Western Bohemia ; Oberpfalz ; Geochemistry ; Cordierite
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract The Rozvadov Pluton is a complex of mainly Variscan granitoid rocks situated near the Bohemian-Bavarian border between Bärnau, Tachov, Rozvadov and Waidhaus, 25 km ESE of the KTB site. Five mappable units can be distinguished, which intruded as folows: (1) slightly deformed leucocratic meta-aplite/metapegmatite dykes with garnet and tourmaline; (2) a complex of cordierite-bearing granitoids, which have been divided into three facies (a) biotite granite with cordierite (at the margin of the complex), (b) biotite-cordierite granite and (c) cordierite tonalite (in the centre of the complex; (3) fine-grained biotite granite of the Rozvadov type with associated pegmatite bodies; (4) two-mica Bärnau granite; and (5) geochemically specialized albite-zinnwaldite-topaz granite (Krížový kámen/Kreuzstein granite) with indications of Sn-Nb-Ta mineralization and associated phosphorus-rich pegmatite cupolas. Rare earth element data suggest that meta-aplite/pegmatite dykes are the result of a batch partial melting process, whereas the compositional variation of the other rock types was mainly controlled by fractional crystallization. The genesis of the cordierite granitoid suite is best explained in terms of a batch melting of metapelitic source followed by crystallization of a cordierite-rich cumulate and K-feldspar enriched melt. The leucocratic pluton constituents — the meta-aplites and the Bärnau and Křížový kámen granites are rich in phosphorus (0.5–0.8%). The main carriers of phosphorus are alkali feldspars, especially K-feldspar (up to 0.8% P2O5). The presence of P-rich leucocratic granites is one of the features distinguishing the Variscan granitoids within the Moldanubian zone from the nearly contemporaneous granitoids in the Saxothuringian zone.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00284517
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  • 9
    Electronic Resource
    Electronic Resource
    Detrital chromites in metasediments of the East-Arabian continental margin in the Saih Hatat area: constraints for the palaeogeographic setting of the Hawasina and Semail basins (Oman Mountains) (1999)
    Springer
    International journal of earth sciences 88 (1999), S. 13-25 
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    ISSN: 1437-3262
    Keywords: Key words Oman ; Chromite ; Paleogeography ; Geochemistry
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract  In Oman, the convergence between Arabia and Eurasia resulted in the Late Cretaceous overthrusting of oceanic crust and mantle lithosphere onto the Arabian continental margin. During this compressional event, a part of the continental plate was subducted to a depth of more than 60 km (0.5 GPa, 250–350  °C to more than 2.0 GPa, 550  °C) resulting in progressive metamorphism of the continental margin sediments, well exposed in the Saih Hatat tectonic window, northeastern Oman Mountains. We attempt to constrain the possibility of one continuous history of extension (starting along the east Arabian continental margin in the Permian) that was followed by one continuous history of convergence starting at 90 Ma near a dead oceanic ridge. This compression resulted in the observed progressive metamorphism by ophiolite overthrusting onto the continental margin. Constraining arguments are the palaeogeographic setting before ophiolite obduction of the As Sifah units and the Hawasina Complex near Ghurba. Detrital chromites in the Triassic–Cretaceous metasediments of the Hawasina Complex are compared with magmatic Semail chromites, and the whole-rock chemistry of these metasediments and associated metabasites are investigated. In contrast to former hypotheses, differences in the chemical composition between detrital and magmatic chromites, and the probable origin of all detrital chromites in the Hawasina Basin from Permian age oceanic rocks, suggest that the high-pressure metamorphic sediments of As Sifah can be considered as part of the basal deposits of the Hawasina Basin.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/s005310050242
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  • 10
    Electronic Resource
    Electronic Resource
    Siliceous microfossil distribution in the surficial sediments of Lake Baikal (1995)
    Springer
    Journal of paleolimnology 14 (1995), S. 69-82 
    Details
    ISSN: 1573-0417
    Keywords: Russia ; Lake Baikal ; paleolimnology ; diatoms ; stomatocysts
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract Examination of surficial sediments at 16 stations shows minor, but consistent differences in the numbers and kinds of siliceous microfossils deposited in different regions of Lake Baikal. There is a general north-south decreasing trend in total microfossil abundance on a weight basis. Endemic plankton diatom species are the most abundant component of assemblages at all stations. Chrysophyte cysts are present at all stations, but most forms are more abundant at northern stations. Non-endemic plankton diatom species are most abundant at southern stations. Small numbers of benthic diatoms and sponge spicules are found in all samples. Although low numbers are present in offshore sediments, the benthic diatom flora is very diverse. Principal components analysis confirms primary north-south abundance trends and suggests further differentiation by station location and depth.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00682594
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  • 11
    Electronic Resource
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    The representation of diatom communities by fossil assemblages in a small acid lake (1995)
    Springer
    Journal of paleolimnology 14 (1995), S. 185-223 
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    ISSN: 1573-0417
    Keywords: taphonomy ; representativity ; diatoms ; acidification ; liming ; sediment traps
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract The representative quality of fossil diatom assemblages in the recent sediment of a lake is compared with its contemporary diatom flora. In April 1986 experimental liming of the catchment of a small acidified lake, Loch Fleet (Galloway, U.K.), produced immediate changes in water quality. Lakewater pH rose from a mean of approximately 4.5 to 6.5, and in the two year period following liming a consistently higher pH was maintained. The marked response of diatom species to changing water quality provided a means of tracing events from living communities to the fossil assemblages. Diatom periphyton and plankton were sampled during a 20 month period and archived material was used to characterise earlier diatom communities. A comparison is made between living diatom communities and diatom assemblages collected by sediment traps and from sediment cores taken during the same period. Following liming, the diatom communities were found to respond within days or weeks to the changes in water quality. There is an initial change from acidobiontic communities, dominated byTabellaria quadriseptata, to dominance by the acidophilous speciesEunotia incisa andPeronia fibula. However, in the epipsammic community the acidobiontic speciesTabellaria binalis fo.elliptica remains abundant after liming. Approximately one year after liming the abundances of species such asAchnanthes minutissima andBrachysira vitrea increase in the epilithon, epiphyton and epibryon, whilst in the epipsammonT. binalis fo.elliptica is replaced by smallEunotia spp. andAchnanthes altaica. During the latter part of 1987 and in 1988, despite a stable pH, fluctuating patterns of species abundances are seen in the epilithon, epiphyton and epibryon whilst the species composition of the epipsammon remains relatively stable. Spring blooms of the planktonic speciesSynedra acus andAsterionella formosa occur during 1988 and 1989 respectively. Sediment trapping, which began in April 1987, records shifts in species composition corresponding with those seen in the epilithon, epiphyton and epibryon and with the blooms of planktonic species. The signal from the smaller, and probably less easily transportable, epipsammic community is not so clearly discernible. Although the fundamental record of the sediment traps is one from living diatom communities, the appearance of taxa ‘extinct’ during the post-liming period reflects a low, but significant level of sediment resuspension. In contrast to the rapid response of living communities and their record in sediment traps, sediment cores do not begin to reflect changes in diatom composition until about 14 months after the initial liming. The first appearance of circumneutral taxa in significant abundance occurs only approximately 17 months after liming. The delayed reaction of sediment assemblages cannot be attributed principally to a slow rate of transport from the littoral to the profundal zone. Time-averaging processes within the sediment appear to be the main cause of the lag in core response. In contrast, blooms of planktonic species are quickly reflected in the stratigraphy of cores, but indicate that a considerable degree of downward mixing occurs. Comparison of the time trajectories of whole species assemblages in living communities, sediment traps and core surface sediments shows that the direction of change is similar in all three, but that the magnitude of change is attenuated in sediment assemblages.
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    URL: http://dx.doi.org/10.1007/BF00735481
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  • 12
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    Late Holocene lake-level and lake development signals in Lower Herring Lake, Michigan (1996)
    Springer
    Journal of paleolimnology 15 (1996), S. 19-45 
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    ISSN: 1573-0417
    Keywords: diatoms ; grain-size analysis ; lake-level changes ; Lake Michigan ; paleolimnology
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract Paleolimnological investigations of a marginal lake in the Lake Michigan basin revealed signals of long-term lake-level changes primarily controlled by climatic forces. Multiple analyses identified concurrent signals in sediment chemistry, grain size, and the microfossil record. Coarse-grained sediments, benthic diatoms, and nutrient response species increased as lake levels rose or fell. Finer sediments and higher percentages of taxa associated with stable thermocline conditions occurred during high-lake periods. Sedimentary evidence revealed corresponding strong high-lake signals c. 2500–2200, 1800–1500, 1170–730, and 500–280 BP. Low-lake periods occurred c. 1500–1170 and 700–500 B.P. An additional signal of lake-level decline was apparent beginning c. 280 BP but was interrupted by anthropogenic effects. Evidence of extreme low-lake levels (c. 1400–1300 BP), and signals for a medieval warming period (1030–910 BP) and the Maunder minimum (370–325 BP) indicate occurrence of short-lived dry climatic conditions.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00176988
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  • 13
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    Changes in diatom assemblages in Lake C2 (Ellesmere Island, Arctic Canada): response to basin isolation from the sea and to other environmental changes (1996)
    Springer
    Journal of paleolimnology 16 (1996), S. 217-226 
    Details
    ISSN: 1573-0417
    Keywords: diatoms ; high arctic ; Ellesmere Island ; laminated sediments ; rheophilous ; river input ; marine isolation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract Diatoms preserved in the sediments of Lake C2 (82°50′ N, 76°00′ W), a high arctic meromictic lake, track changes in the lake's salinity which have occurred as the basin was isolated from the sea. An assemblage dominated by marine taxa, such as Chaetoceros species, Nitzschia cylindrus and Diploneis spp., was replaced by a Cyclotella kuetzingiana var. planetophora dominated freshwater flora. A brief brackish period separates the two assemblages. Relatively little floristic change occurred within either the marine or freshwater periods, indicating rather stable environmental conditions, except that rheophilous diatoms fluctuated in relative abundance during the lacustrine phase, perhaps tracking past changes in discharge from inflowing streams. These may reflect periods of warmer, wetter environmental conditions.
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    URL: http://dx.doi.org/10.1007/BF00176937
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  • 14
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    The paleolimnology of North Pond: watershed-lake interactions (1996)
    Springer
    Journal of paleolimnology 16 (1996), S. 323-354 
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    ISSN: 1573-0417
    Keywords: diatoms ; chrysophytes ; pollen ; charcoal ; hemlock decline ; Holocene ; Massachusetts
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract We examined the stratigraphic record of North Pond, a small, oligotrophic lake in western Massachusetts, U.S.A. to describe late and post-glacial watershed-lake interactions. In particular we investigated the effects of two similar vegetation changes in the watershed on lake biogeochemistry. There was a transient (about 100 years) decline in hemlock ca. 7500 yr B.P. that has not been recorded in other pollen stratigraphies in the northeast. The second event was the classical hemlock decline that occurred ca. 4800 yr B.P. and lasted about 2000 years. This decline occurred throughout the range of hemlock and is thought to have been caused by a pathogen. As the climate began to warm ca. 10 000 yr B.P., a spruce dominated boreal woodland was established in the watershed. Sediment chemistry data showed that as soils became more acidic, the lake also acidified as evidenced by diatom-inferred (DI) pH. Hemlock was established in the watershed by about 8000 yr B.P. This was accompanied by a slight decrease in DI pH. The transient hemlock decline ca. 7500 yr B.P. was associated with an increase in sedimentary charcoal particles, that suggested fire was responsible for its demise. The diatom stratigraphy indicated a brief, slight, increase in productivity and alkalinity and a brief decrease in lakewater dissolved organic carbon concentrations. Aquatic microfossil data indicated a decrease in the area of the littoral zone ca. 7500 yr B.P. Following the transient decline the lake became more acidic. There were only brief, subtle changes associated with the classical hemlock decline, including a slight decline in DI pH. Although the two disturbances involved a similar vegetation shift, the timing and mechanisms of the disturbances had a greater impact on lake biogeochemistry.
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    Colonization and evolution of lakes on the central Norwegian coast following deglaciation and land uplift 9500 to 7800 years B.P. (1997)
    Springer
    Journal of paleolimnology 18 (1997), S. 269-281 
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    ISSN: 1573-0417
    Keywords: colonization ; evolution ; lakes ; Norway ; deglaciation ; land uplift ; invertebrates ; Chironomidae ; Porifera ; Bryozoa ; diatoms ; Charophyta ; tsunami
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract Invertebrate colonization of lakes following the uplift of land from the sea was studied in four lakes, currently situated between 39 and 24 m a.s.l., on the central Norwegian coast. The lakes were isolated from the sea between 9500 and 7700 years B.P. Animal and algal remains picked from core samples showed that the first colonizers preserved as fossils were usually members of the Chironomidae, Daphnidae/Chydoridae, Acarina, Porifera (Ephydatia mülleri and Spongilla lacustris), Bryozoa (Cristatella mucedo and Plumatella spp.) and Charophyta (Chara sp.). Of the chironomids, the genus Chironomus was present in the oldest lacustrine layers of all four lakes, but other genera recorded at the marine/lacustrine boundary were Dicrotendipes, Procladius (?), Einfeldia, Microtendipes, and Glyptotendipes. Remains of the caddis fly family Limnephilidae were also present in the earliest lacustrine sediments in Kvennavatnet and Kvernavatnet. The oldest invertebrate fauna is typical for mesotrophic lakes. However, chironomids and mites have been present in this area from at least about 10 500 years B.P. A diverse chironomid community was established between 300 and 800 years after isolation from the sea at Kvernavatnet on the island of Hitra, while only between 80 and 120 years passed before a comparably diverse community developed at Kvennavatnet on the mainland coast. A similar development of the invertebrate fauna occurred in Kvennavatnet, Kvernavatnet and Storkuvatnet. However, Litjvatnet deviates greatly from the ‘normal’ pattern because a tsunami disturbed the bottom sediments and fauna. The tsunami, a gigantic sea wave, was caused by a submarine slide from the Norwegian continental slope. It reached Litjvatnet, today located 24 m a.s.l., but was not traced in Storkuvatnet at 30 m a.s.l. This event happened about 7200 years B.P.
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    A preliminary investigation of siliceous microfossil succession in late Quaternary sediments from Lake Baikal, Siberia (1997)
    Springer
    Journal of paleolimnology 18 (1997), S. 189-206 
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    ISSN: 1573-0417
    Keywords: Lake Baikal ; Russia ; paleolimnology ; diatoms ; chrysophyte cysts ; climate change
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract Siliceous microfossil assemblage succession was analyzed in a 100 m sediment core from Lake Baikal, Siberia. The core was recovered from the lake's central basin at a water depth of 365 m. Microfossil abundance varied greatly within the intervals sampled, ranging from samples devoid of siliceous microfossils to samples with up to 3.49 × 1011 microfossils g-1 sediment. Fluctuations in abundance appear to reflect trends in the marine δ18O record, with peak microfossil levels generally representing climate optima. Microfossil taxa present in sampled intervals changed considerably with core depth. Within each sample a small number of endemic diatom species dominated the assemblage. Changes in dominant endemic taxa between sampled intervals ranged from extirpation of some taxa, to shifts in quantitative abundance. Differences in microfossil composition and the association of variations in abundance with climate fluctuations suggest rapid speciation in response to major climatic excursions.
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    A record of accelerated erosion in the recent sediments of Blelham Tarn in the English Lake district (1997)
    Springer
    Journal of paleolimnology 18 (1997), S. 103-120 
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    ISSN: 1573-0417
    Keywords: magnetism ; diatoms ; radioisotopes ; erosion ; laminae ; chronology
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract Two frozen cores from Blelham Tarn were subsampled and measured using mineral magnetic, loss-on-ignition (LOI), radiometric, granulometric and diatom analyses. A detailed chronology was established using varves, radioisotopes and diatoms. This has enabled an accurately dated reconstruction of sedimentation over the past forty years. Despite a large increase in lake productivity, evidence suggests that the observed exponential increase in sedimentation rates can be attributed to erosion within the catchment. The predominant sediment source has been identified as surface soil. A comparison between the trend of accelerated sedimentation and the record of increased sheep stocking density for the area within which the most of the catchment lies, as well as observations of contemporary surface processes within the catchment, both suggest that much of the recent erosion is a direct response to increased pressure from sheep grazing.
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    URL: http://dx.doi.org/10.1023/A:1007922129794
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  • 18
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    On diatom concentrations in lake sediments: results from an inter-laboratory comparison and other tests performed on a uniform sample (1997)
    Springer
    Journal of paleolimnology 18 (1997), S. 261-268 
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    ISSN: 1573-0417
    Keywords: diatoms ; microfossil concentrations ; methods ; paleolimnology ; West Okoboji Lake ; Iowa
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract The diatom concentration of a uniform lake sediment sample was estimated in 15 laboratories. Whilst 21 of 35 estimates were between 13 and 19 × 107 valves g-1, values ranged from 8.2 × 106 to 2.0 × 109 valves g-1. However, counts from replicate sediment digestions, replicate slide preparations from a single digested slurry, and multiple counts from an individual slide all yielded internally consistent results, with acceptably low coefficients of variation (±4.5–6.3%). Without greater efforts towards harmonization, for example by calibrating techniques to a standard of known concentration, reported diatom concentration values, as well as derived data such as diatom accumulation rates, are not directly comparable between most laboratories. This sharply contrasts the strong reproducibility of diatom relative frequency data. A calibration exercise, using the Eucalyptus pollen spike technique to estimate a known concentration of Lycopodium spores, demonstrates that this method performs best when approximately equal proportions of microfossils and introduced markers are counted.
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    The palaeolimnology of Lake Fidler, a meromictic lake in south-west Tasmania and the significance of recent human impact (1997)
    Springer
    Journal of paleolimnology 18 (1997), S. 313-333 
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    ISSN: 1573-0417
    Keywords: palaeolimnology ; diatoms ; meromixis ; lakeontogeny ; human disturbance
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract Three meromictic lakes in the World Heritage Area of south-west Tasmania possess unusual microbiological communities. Their meromixis is maintained by periodic incursions of brackish water from the nearby Gordon River which, in its lower reaches, is a salt-wedge estuary. In 1977 the construction of a dam in the middle reaches of the river restricted penetration of the salt-wedge and meromixis rapidly declined in all three lakes. A palaeolimnological study was carried out on one of the lakes, Lake Fidler, firstly to determine the history of meromixis and its associated microbiological communities, and secondly to assess whether the recent and rapid decline of meromixis is inconsistent with natural rates of development of the Gordon River meromictic lakes. One part of this study included the analysis of the stratigraphy of fossil diatoms from a 17-metre sediment core dating back 8000 yrs. Detrended Correspondence Analysis and Analog Matching were used to compare diatom species assemblages in core samples with diatom samples from a reference dataset consisting of a selection of lake and river sites in the lower Gordon River valley. Five distinct stratigraphic zones were identified in the core. These zones indicated specific stages in the development of the Gordon River lakes from river backwaters to ectogenically-maintained meromictic lakes which will, finally, become terrestrialised by encroaching rainforest. The onset of a stratified water column was identified by the emergence of a dominant freshwater algal flora which suggested that the lake had developed a mixolimnion and become meromictic ca. 2070 ± 50 14C yrs ago. In the context of this long history of meromixis, the rapid demise in meromictic stability following construction of the dam is judged to be inconsistent with natural rates of development. The palaeolimnological studies, of which this paper is one part, prompt recommendations for a management strategy to prevent the further decay of these meromictic lakes in the World Heritage Area.
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    A diatom-based reconstruction of drought intensity, duration, and frequency from Moon Lake, North Dakota: a sub-decadal record of the last 2300 years (1998)
    Springer
    Journal of paleolimnology 19 (1998), S. 161-179 
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    ISSN: 1573-0417
    Keywords: drought ; diatoms ; paleoclimate ; Northern Great Plains ; paleosalinity ; Medieval Warm Period ; Little Ice Age
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract Diatom assemblages preserved in sediment cores from closed-basin lakes can provide high-resolution records of past hydrologic and climatic conditions, including long-term patterns in the intensity, duration, and frequency of droughts. At Moon Lake, a closed-basin lake in eastern North Dakota, a comparison of diatom-inferred salinity and the precipitation-based Bhalme-Mooley Drought Index (BMDI) over the last 100 years was highly significant, suggesting that the diatom record contains a sensitive archive of past climatic conditions. A sub-decadal record of inferred salinity for the past 2300 years indicates that extreme droughts of greater intensity than those during the 1930s 'Dust Bowl' were more frequent prior to A.D. 1200. This high frequency of extreme droughts persisted for centuries and was most pronounced from A.D. 200–370, A.D. 700–850 and A.D. 1000–1200. A pronounced shift to generally wetter conditions with less severe droughts of shorter duration occured at A.D. 1200. This abrupt change coincided with the end of the 'Medieval Warm Period' (A.D. 1000–1200) and the onset of the 'Little Ice Age' (A.D. 1300–1850).
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    A summary of past and recent plankton of Lake Winnipeg, Canada using algal fossil remains (1998)
    Springer
    Journal of paleolimnology 19 (1998), S. 297-307 
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    ISSN: 1573-0417
    Keywords: eutrophication ; algae ; bluegreen akinetes ; non-siliceousmicro fossils ; diatoms ; paleolimnology
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract Although the phytoplankton and protozoan assemblages of Lake Winnipeg are quite variable both, spatial and temporally, knowledge of their current distribution and ecology enables them to be used as indicators providing unique information concerning past and recent ecosystem conditions. Many of the main taxa have been similar throughout history although there have been dramatic changes in their abundance. Lake Winnipeg is currently very responsive to the climatic conditions in its drainage basin and it appears, historically, to have been a diatom-bluegreen algal lake with Tintinnids and thecate amoeba forming significant components of the protozoan community. A wide variety of microfossil remains have been used to infer past conditions in this large prairie lake. Microfossils reported from the long core 103 (8 m) taken from the north basin of LakeWinnipeg and short core Namao 7a taken from the south basin of the lake in August 1994 indicate that the lake has experienced several changes over its history. Diatom assemblages, low throughout the core 103 below 50 cm, except for a peak around 300–400 cm are virtually absent below 690–800 cm (Lake Agassiz). Stephanodiscus and Aulacoseira are the two major pelagic diatom genera represented throughout the lake's history. Species changes occur near the top of the core indicate increased anthropogenic eutrophication. Shallow water littoral taxa were never abundant at either coring sites. The presence of planktic cyanoprokaryote (cyanophyte, cyanobacteria, bluegreen algae) remains (akinetes) from 600 cm depth and the progressive increase in abundance from 400 cm to through the top 100 cm of the core indicates increasing phosphorus levels, warming summer temperatures and increasing summer nitrogen limitation in the lake. Nitrogen fixing bluegreens (especially Anabaena and Aphanizomenon akinetes) and the diatoms (Aulacoseira ambigua, A. granulata, A. islandica, S. binderanus, and S. niagarae) were abundant in the upper sediments and changes after 100 cm can be interpreted as the effects of human impact. These taxa indicative of increase eutrophication, in addition to S. agassizensis, Melosira varians and Cyclostephanos dubius, are representative of present day plankton. The short core Namao 7a was dated by Pb210 and the fossil remains also show a rise in the Aulacoseira (particularly A. granulata and A. ambigua) and bluegreen akinetes in the last 40 years as was seen in the upper sediments of the 103 core. There was an interesting peak in chrysophyte cysts during the 1930's which corresponds nicely with climatic conditions during this period. The fires accompaning the hot dry period in the mid 70's can be seen in the dramatic rise in charcoal during this period. Multiple types of micro fossils remains provides several useful tools for interpreting past lacustrine conditions.
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    A diatom-conductivity transfer function for Spanish salt lakes (1998)
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    Journal of paleolimnology 19 (1998), S. 399-416 
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    ISSN: 1573-0417
    Keywords: saline lakes ; paleolimnology ; paleoclimate ; diatoms ; transfer functions ; Spain ; CCA
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract Diatom-salinity transfer functions for interpretation of palaeosalinity and palaeoclimate change have been developed successfully for parts of North America and North and East Africa, but there is a need for data-sets in other saline lake regions of the world. A data-set of 74 modern diatom samples and associated water chemistry data is described from Spain. The influence of conductivity and other environmental variables on diatom distribution is explored using canonical correspondence analysis (CCA) and partial CCAs. A transfer function is derived for conductivity (70 samples) whose apparent predictive ability is high (apparent r2 = 0.91). Performance under jackknifing is poor due to the heterogeneous nature of the data-set and poor coverage of the freshwater end of the salinity gradient. There is a lack of suitable low-salinity sites in Spain, and the accuracy of estimated salinity optima and tolerance ranges may be improved by merging this data-set with those of other regions. The Spanish transfer function has strong affinities with the African data-set and contributes important ecological data for diatom taxa which are absent or poorly represented in the modern flora of African lakes, and for which, in fossil material, there were previously no good modern analogues.
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    Late Quaternary diatom response to vegetation and climate change in a subalpine lake in Banff National Park, Alberta (1998)
    Springer
    Journal of paleolimnology 20 (1998), S. 253-265 
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    ISSN: 1573-0417
    Keywords: Late Quaternary ; diatoms ; climate change ; vegetation change ; shallow ; subalpine ; Crowfoot Lake ; Alberta ; paleolimnology
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract The late Quaternary diatom record from subalpine Crowfoot Lake, Banff National Park, Alberta (lat. 51° 61′N; long. 116° 31′W) has been analyzed. Results are related to independently inferred vegetation and climate changes. No diatoms were found in the basal diamict that predates 11330 14C yr BP. Very few occur until ca. 10 10014 C yr BP probably due to the short time between de-glaciation and an advance of the Crowfoot Glacier during the ‘Younger Dryas Chron’. Initial pioneering species were characteristic of alkaline water and calcareous organic sediments. They appeared as sediments became organic and laminated suggesting increasing water clarity, and as the Pinus-dominated forest expanded and the climate warmed. After ca. 9060 14C yr BP diatom numbers increased rapidly, reaching a maximum prior to the Mazama tephra; they remained high until ca. 3500 14C yr BP. The period between ca. 9060 and 3500 14C yr saw timberline elevation increase and the dominance of xerophytic taxa. These are consistent with early to mid-Holocene warmth and aridity. Diatom productivity reflects the warm climate and presumably longer ice-free season, a stable catchment and transparent water. Decreases in diatom productivity coincide with a vegetation change with reduction of xerophytic taxa and the appearance of a closed Picea-Abies forest, hence a cooler, wetter climate at ca. 4100 to 3500 14C yr BP. The diatom numbers during the Neoglacial were of the same magnitude as prior to ca. 9060 14C yr BP. Small species of Fragilaria (overwhelmingly Fragilaria construens v. venter) became extremely dominant during the period of high diatom productivity, and remained so thereafter. Recovery of the lake appears to have been rapid after deposition of the Mazama tephra. Maximum occurrence of Cyclotella radiosa occurred ca. 8000 14C yr BP during the warm early Holocene and may reflect this warmer climate, a longer ice-free season than presently, perhaps less turbid water, or it may reflect a subtly higher nutrient status of the lake water. The diatom record of Crowfoot Lake has responded with sensitivity, particularly in terms of productivity, to the Holocene vegetation and climate changes.
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    The Holocene development of Kushu Lake on Rebun Island in Hokkaido, Japan (1998)
    Springer
    Journal of paleolimnology 20 (1998), S. 57-69 
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    ISSN: 1573-0417
    Keywords: Kushu Lake ; diatoms ; sulfur ; threshold ; sea-level change ; salinity ; coastal paleoenvironments ; Japan
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract Diatom assemblages and sulfur content in sediments were analyzed to clarify changes in the sedimentary environment of Kushu Lake, a coastal lake on Rebun Island in Hokkaido, Japan. Salinity variations were assessed by means of a diatom-based index of paleosalinity and the sedimentary sulfur content. This paper discusses the Holocene development of the lake, in relation to Holocene relative sea-level change. For paleoenvironmental interpretation of the lake development, the rationale of the threshold method (Anundsen et al., 1994) was applied. At ca. 8000 yr BP, a coastal embayment (paleo-Kushu Bay) resulted from marine ingression. The threshold elevation at the mouth of the paleo-Kushu Bay kept pace with the rising sea-level, resulting in its enclosure at the culmination of Holocene marine transgression (ca. 6500–5000 yr BP). From predicted relative sea-level at ca. 6000 yr BP for Rebun Island (Nakada et al., 1991), the threshold may have been at least above –3 to –5 m altitude. A freshwater lake environment with strongly anoxic bottom conditions may have occurred from ca. 5500 to 5100 yr BP. After an important episode of marine ingression, the lake was isolated completely from the open sea at ca. 4900 yr BP. The diatom record suggests that the maximum lacustrine extent occurred at ca. 4900–3100 yr BP. Thereafter, water depth decreased at the lake margins. In Kushu Lake, the threshold elevation, due to a build-up of a coastal barrier, prevents us from determining the amplitude of sea-level changes, even though the age of isolation contacts corresponds to periods of regression and climatic deterioration. In spite of isostatic subsidence, the effective protection provided by the well-developed barrier did not allow registration of any relative sea-level fluctuations since its isolation.
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    Paleolimnology and recent environmental change in Lake Baikal: an introduction and overview of interrelated concurrent studies (1998)
    Springer
    Journal of paleolimnology 20 (1998), S. 107-117 
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    ISSN: 1573-0417
    Keywords: Lake Baikal ; pollution history ; trace metals ; carbonaceous particles ; magnetic minerals ; diatoms ; turbidites
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract Recent environmental change research in Lake Baikal is introduced together with an overview of several interrelated papers published concurrently in this issue of Journal of Paleolimnology. Five themes are tackled by analysis of recent Baikal sediment cores, dating, geochemistry, particulate pollutants, magnetism and diatoms. The concurrent papers focus on the first four themes in some detail and summary results of diatom analysis (from Mackay et al., 1998) are given here. Taken together these studies provide a time-space framework for recent environmental change in Lake Baikal not previously available. There are significant shifts in species composition of the endemic planktonic diatom assemblages in uppermost sediments collected from throughout the lake. However, these changes usually precede the sediment record of low level but widespread contamination by industrial products. The most clear sign of industrial contamination is the presence of particles from fossil fuel combustion in sediment post dating the 1930s. Although evidence for widespread biostratigraphic changes by pollution is lacking, radionuclide, diatom, lithostratigraphic and magnetic stratigraphies indicate two main features, (i) it is possible to make stratigraphic correlations within and between basins using recent sediment cores, (ii) that turbidite deposits, from several to tens of cm thick, are frequently encountered in recent sediments. Turbidite deposits occur in 210Pb dated and pre-210Pb sediment core sections and are undoubtedly a major macro-disturbance feature in many deep water locations in Lake Baikal. If profiles are to be used as direct proxy records of climate variability, then screening of cores for turbidites is a pre-requisite for quality assurance in future paleoenvironmental studies. On-going international research including Swiss, Russian and British joint paleoenvironmental studies on the distribution and biological formation of recent sediments will hopefully lead to better interpretation of Holocene and pre-Holocene sediment records in Lake Baikal.
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    Paleolimnological significance of observed distribution patterns of chrysophyte cysts in arctic pond environments (1995)
    Springer
    Journal of paleolimnology 13 (1995), S. 79-83 
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    ISSN: 1573-0417
    Keywords: chrysophytes ; cysts ; Stomatocysts ; diatoms ; periphyton ; Arctic ; Ellesmere Island ; Paleolimnology
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract In a survey of 35 high arctic ponds, chrysophycean cysts were relatively more common in moss periphyton and epilithon habitats, than in surface sediment samples. The highest percentages of cysts relative to diatoms were found in the semi-aquatic mosses. Although chrysophytes are generally considered to be planktonic, periphytic taxa may be common in high latitudes. The ratio of diatom frustules to chrysophyte cysts in arctic sediment cores may be tracking different environmental variables than paleolimnologists may intuitively expect based on observations from more temperate regions.
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    An expanded weighted-averaging model for inferring past total phosphorus concentrations from diatom assemblages in eutrophic British Columbia (Canada) lakes (1995)
    Springer
    Journal of paleolimnology 14 (1995), S. 49-67 
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    ISSN: 1573-0417
    Keywords: diatoms ; eutrophication ; lake management ; paleolimnology ; British Columbia ; lakes ; phosphorus ; training sets
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract Eighteen lakes were added to a published training set of 46 British Columbia (BC) lakes in order to expand the original range of total phosphorus (TP) concentrations. Canonical correspondence analysis (CCA) was used to analyze the relationship between diatom assemblages and environmental variables. Specific conductivity and [TP] each explained significant (P≤0.05) directions of variance in the distribution of the diatoms. The relationship between diatom assemblages and [TP] was sufficiently strong to warrant the development of a weighted-averaging (WA) regression and calibration model that can be used to infer past trophic status from fossil diatom assemblages. The relationship between observed and inferred [TP] was not improved by the addition of more eutrophic lakes, however the [TP] range and the number of taxa used in the transfer function are now superior to the original model. Diatom species assemblages changed very little in lakes with TP concentrations greater than 85 µg 1−1, so we document the development of a model containing lakes with TP≤85 µg 1−1. The updated model uses 59 training lakes and covers a range of species optima from 6 to 41.9 µg 1−1 TP, and a total of 150 diatom taxa. The updated inference model provided a more realistic reconstruction of the anthropogenic history of a highly eutrophic BC lake. The model can now be used to infer past nutrient conditions in other BC lakes in order to assess changes in trophic status.
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    Late-glacial pollen and diatom changes in response to two different environmental perturbations: volcanic eruption and Younger Dryas cooling (1995)
    Springer
    Journal of paleolimnology 14 (1995), S. 23-47 
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    ISSN: 1573-0417
    Keywords: Younger Dryas ; pollen ; diatoms ; varves ; laminated sediment ; Laacher See Tephra ; Holzmaar ; rates of change ; sequence splitting ; variance partitioning ; redundancy analysis
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract A high-resolution pollen and diatom stratigraphy has been studied from late-glacial annually laminated sediments of Holzmaar (425 m a.s.l., Germany). The sediment sequence studied comprises 475 varves and includes two environmental perturbations of different type and duration: the short, abrupt deposition of the late Allerød tephra layer of the Laacher See volcano (LST, 11 000 yr B.P.), and the more gradual onset of the 'Younger Dryas climatic cooling. Numerical analyses involving (partial) redundancy analyses in connection with Monte Carlo permutation tests suggest that the deposition of 78 mm of Laacher See Tephra had a statistically significant effect on the pollen stratigraphy (percentage and accumulation rates), most probably because of the proximity of the site to the volcano. The diatom accumulation rates also show a statistically significant change, whereas the diatom percentage data do not change significantly. The between-sample rates-of-change in both biostratigraphies are higher at and just after the LST event than at the transition to the Younger Dryas biozone. Sequence splitting of pollen and diatom accumulation rate data also shows a clustering of significant splits at the LST event. A close correlation between changes in the pollen and diatom percentage data for the investigated time-interval suggests a common underlying climatic signal, whereas the accumulation rates of both biostratigraphies behave more individualistically and show more short-term variability due, in part, to the inherent noise in the two data sets. Variance partitioning shows that the local pollen and diatom assemblage zones explain much of the variance in the data-sets. Statistical modelling using redundancy analysis shows that the changes in the diatom assemblages are best predicted by the Younger Dryas biozone and the main changes in the pollen stratigraphy (as represented by the first PCA axis of the pollen data). The results suggest that the biostratigraphies studied at Holzmaar reflect generally stable systems which were disturbed by the deposition of the Laacher See Tephra. After a phase of recovery both systems again reached a new phase of stability prior to the long-term Younger Dryas climatic deterioration that perturbed the assemblages again. The very close and statistically significant parallelism between the major stratigraphical patterns in the pollen and diatom percentage data highlights the responses of the two biological systems to environmental perturbations at different temporal scales.
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    An assessment of recent trophic changes in Windermere South Basin (England) based on diatom remains and fossil pigments (1995)
    Springer
    Journal of paleolimnology 14 (1995), S. 151-163 
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    ISSN: 1573-0417
    Keywords: chlorophyll ; diatoms ; myxoxanthophyll ; oscillaxanthin ; sediments ; eutrophication ; England ; paleolimnology
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract Cyanobacterial carotenoids and diatom remains have been analyzed in recent sediments from the Windermere South Basin (WSB) to study the trophic evolution experienced by the lake. Dates in the top 30 cm were specifically established through radionuclide (210Pb and137Cs) analyses. Diatom stratigraphy shows dominance of the centric diatomsCyclotella comensis andC. radiosa and several benthic taxa in the early postglacial. This indicates oligotrophy in the WSB during that period. This assemblage was replaced by another dominated by the diatomAsterionella formosa in the 1870's, as has been established from the210Pb dating. From that date onwards, the lake underwent a progression towards eutrophy, indicated by the progressive increase inAulacoseira subarctica (c. 1930's),Fragilaria crotonensis (c. 1943), and more recently, of the centricsStephanodiscus parvus (c. 1971) andCyclotella meneghiniana (1988). Carotenoid stratigraphy reveals the differences between different sections of the core. Oscillaxanthin and myxoxanthophyll had very low records in the early and medium parts of the core, but increased fromc. 1950's, showing peaks atc. 1967, 1979 and 1987. Some of these peaks indicated a differential abundance ofOscillatoria, and are matched to those observed directly during the ongoing monitoring of the phytoplankton of the lake. The coincidence between the historic appearance of diatoms associated with nutrient-rich waters and the enhanced carotenoid occurrence suggest a common response to phosphorus enrichment, and that the progressive change towards eutrophy has been accentuated during the last twenty-five years.
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    Assessment of freshwater diatoms as quantitative indicators of past climatic change in the Yukon and Northwest Territories, Canada (1995)
    Springer
    Journal of paleolimnology 13 (1995), S. 21-49 
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    ISSN: 1573-0417
    Keywords: diatoms ; temperature ; climatic change ; paleoclimate proxies ; canonical correspondence analysis ; weighted-averaging ; Yukon ; Northwest Territories
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract We identified, enumerated, and interpreted the diatom assemblages preserved in the surface sediments of 59 lakes located between Whitehorse in the Yukon and Tuktoyaktuk in the Northwest Territories (Canada). The lakes are distributed along a latitudinal gradient that includes several ecoclimatic zones. It also spans large gradients in limnological variables. Thus, the study lakes are ideal for environmental calibration of modern diatom assemblages. Canonical correspondence analysis, with forward selection and Monte Carlo permutation tests, showed that maximum lake depth and summer surface-water temperature were the two environmental variables that accounted for most of the variance in the diatom data. The concentrations of sodium and calcium were also important explanatory variables. Using weighted-averaging regression and calibration techniques, we developed a predictive statistical model to infer lake surface-water temperature, and we evaluated the feasibility of using diatoms as paleoclimate proxies. This model may be used to derive paleotemperature inferences from fossil diatom assemblages at appropriate sites in the western Canadian Arctic.
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    URL: http://dx.doi.org/10.1007/BF00678109
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    Climate change at the monsoon/Westerly boundary in Northern Mexico (1997)
    Springer
    Journal of paleolimnology 17 (1997), S. 155-171 
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    ISSN: 1573-0417
    Keywords: Mexico ; palaeoclimate ; sediments ; diatoms ; pollen
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract Northern Mexico lies close to the present day boundary between mid-latitude (Westerly) and tropical (monsoonal) sources of moisture. Studies from the adjacent southwest USA have shown major changes in lake levels and vegetation distributions over the late Quaternary which have been interpreted in terms of significant variations in the relative strengths and positions of these climate systems. Palaeoclimatic data from this area have, however, left a number of unresolved questions which can only be answered by extending work into northern Mexico, closer to the major source of summer (monsoonal) rain, the Gulf of Mexico. Studies of palaeolake sediments from a series of hydrologically closed lake basins across a range of altitudes (1280 to 2200 m a.s.l.) in northern Chihuahua are in progress using geochemical, mineral magnetic, diatom and plant microfossil analyses. Preliminary results are presented from the Alta Babícora and Encinillas basins. The sites provide records of lacustrine deposition between 〉11 000 and about 2500 yr BP. The diatom record from Babíora provides clear evidence for a deep water lake in this basin in the late glacial which persisted into the early Holocene. A dry episode coinciding with the timing of the Younger Dryas is recorded in Alta Babícora. Conditions wetter than present are indicated up to at least 7000 yr BP.
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    Changes in the importance of lotic and littoral diatoms in a high arctic lake over the last 191 years (1996)
    Springer
    Journal of paleolimnology 16 (1996), S. 187-204 
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    ISSN: 1573-0417
    Keywords: diatoms ; lotic diatoms ; varves ; paleolimnology ; turbidities ; high arctic
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract Both habitat preferences and community associations for some of the most prominent pennate taxa in our profile were established using samples from the modern lake and its watershed. Habitat preferences were used to establish a simple indicator for the relative contribution of lotic communities in this lake (Lotic Index) and indicator taxa for both littoral (Achnanthes spp. and Cymbella spp.) and lotic (Hannaea arcus and Meridion circulare) communities. When profiled, the Lotic Index showed a clear positive relationship to sedimentation rate as recorded in the varves, while profiles of littoral indicator taxa show the opposite trends. It seems likely that the patterns we observed in the Lotic Index are related to changes in runoff. Apparently, there was a period of declining runoff beginning ca. two centuries ago and ending in the late 1800's. This was followed by increasing runoff lasting until the middle of the 20th century. A brief minimum occurred in ca. 1970 followed by a recovery by ca. 1980. A strong positive relationship was also found between the dates of major turbidites, exceptionally thick varves and the concentration of valves in the sediment. It is possible that many of the thicker varves in the profiles contain littoral material transported to the site of deposition by turbid interflows and underflows. For this reason, the concentration of valves in the sediment in our cores appears to be a proxy for sediment deposition from turbidity currents.
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    A high resolution proxy-climate record from an arctic lake with annually-laminated sediments on Devon Island, Nunavut, Canada (1997)
    Springer
    Journal of paleolimnology 17 (1997), S. 215-225 
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    ISSN: 1573-0417
    Keywords: arctic ; lake sediments ; varves ; Devon Island ; bacteria ; diatoms ; paleoclimate
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract Sediments from a 3 ha lake (75 °34.34′N, 89 °18.55′W) from the coastal region of northern Devon Island, Nunavut, Canada, contain discrete laminations in the deepest part of the basin. The laminations are varves as indicated by the correspondence between counts and thickness measurements of the couplets and 210Pb dating. A 14 cm core representing 150 years of sedimentation contained laminated couplets consisting of a lighter inorganic layer with a higher percentage of calcium and magnesium, alternating with fine darker bands, typically more cohesive, and comprising higher proportions of silica and carbon. A reddish oxidation zone with higher iron and aluminum frequently separates the laminations. The dark layer represents a biogenic component deposited in summer and is made cohesive by bacterial filaments among the other particles. The light inorganic layer represents clastic deposition from allochthonous sources. Deposition rates were relatively consistent through the core with an increase in varve thickness in the 1950s. Diatom concentrations in the sediments increased by two orders of magnitude in this century, with major increases in the 1920s and 1950s. The increase in varve thickness and diatom abundance coincides with an increase in summer melt percentage in an ice core from the Devon Island Ice Cap (Koerner, 1977). The relatively high sedimentation rate (0.15 cm yr-1) coupled with the consistency of deposition makes this lake a significant indicator for recent climate changes of the Canadian Arctic Archipelago.
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    Distribution of diatoms among intermittent ponds on the Atlantic Coastal Plain: development of a model to preduct drought periodicity from surface-sediment assemblages (1998)
    Springer
    Journal of paleolimnology 20 (1998), S. 71-90 
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    ISSN: 1573-0417
    Keywords: diatoms ; Carolina bays ; paleolimnology ; calibration set ; non-metric multidimensional scaling ; weighted averaging
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract Inferences of past climate from the fossil record in lakes rely on the accurate quantification of a relationship of fossilizing organisms to their environment. Whereas the relationship of diatoms to water chemistry parameters has been modeled in many systems, few studies adequately address the relationship of diatoms to physical properties, such as water depth or hydrology, that may be more directly tied to climate. We examined the composition of modern diatoms in surface sediments of 75 isolated ponds (mostly Carolina bays) of the Atlantic Coastal Plain to: (1) assess the influence of physical and chemical variables on the distribution of diatoms among ponds of the region, and (2) develop a model that predicts hydroperiod (a measure of pond permanence) from diatom assemblages. We constructed two hydroperiod calibration models: the first infers hydroperiod from the weighted-average optima and tolerances of taxa along the hydroperiod gradient, the second bases inferences on the hydroperiod estimates of compositionally similar samples. Both approaches incorporate a-priori and post-hoc tests of assumptions often inherent in the construction of transfer functions. Diatom assemblage composition had strong, approximately linear relationships to hydroperiod, water depth, and calcium concentration in non-metric multidimensional ordination space; effects of other variables, including pH, were non-linear or ambiguous. Overall, the assemblages reflected the dilute, acidic chemical characteristics of bays. The assemblages contained differing abundances of euterrestrial, benthic and planktonic taxa, depending on a pond's susceptibility to drying. A weighted-averaging regression model based on taxon-specific hydroperiod optima generated adequate, unbiased hydroperiod inferences from diatom species composition (r2 = 0.81). This model may be used to infer past drought episodes from fossil diatom assemblages at appropriate sites on the Atlantic Coastal Plain.
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    Variability of diatom-inferred phosphorus profiles in a small lake basin and its implications for histories of lake eutrophication (1998)
    Springer
    Journal of paleolimnology 20 (1998), S. 47-55 
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    ISSN: 1573-0417
    Keywords: diatoms ; spatial variability ; canonical correspondence analysis ; lake eutrophication ; transfer functions ; phosphorus
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract Diatom analyses were undertaken of sediment cores covering a range of water depths in a small eutrophic lake (Lough Augher, Co. Tyrone, N. Ireland). The significance of between-core variability in diatom relative frequency stratigraphy was assessed by Canonical Correspondence Analysis (CCA) where the ordination axes were constrained to external environmental variables (sediment depth, core location coordinates, water depth, effective fetch, distance-from-shore and distance-from-inflow). After the removal of the effect of sediment age by partialling it out, the resultant first two axes from the partial-CCA were significantly correlated with water depth and distance-from-shore, indicating non-uniform diatom stratigraphies across the lake. Despite this variability, all cores show the same succession of species and, therefore, record the eutrophication of the lake. Diatom-inferred total phosphorus (DI-TP) was inferred for six cores using weighted averaging regression and calibration. Apart from considerable differences of DI-TP in surficial sediment samples, there was good between-core repeatability of DI-TP profiles. These data support the use of DI-TP for establishing background nutrient concentrations for lakes, and associated implications for lake restoration schemes using single cores. Comparisons of DI-TP profiles and total diatom accumulation rate data for the individual cores indicate that diatom production peaked prior to the maximum TP concentrations in the lake.
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    Mineral magnetic and physical properties of surficial sediments and onshore samples from the southern basin of Lake Baikal, Siberia (1998)
    Springer
    Journal of paleolimnology 20 (1998), S. 175-186 
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    ISSN: 1573-0417
    Keywords: Lake Baikal ; pollution history ; trace metals ; carbonaceous particles ; magnetic minerals ; diatoms ; turbidites
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract Results of lithostratigraphic and mineral magnetic analysis of two surficial sediment cores (21 cm and 45 cm in length) collected from the Southern basin of Lake Baikal at a water depth of 1390 m, are presented. The sediments have been measured for a wide range of mineral magnetic parameters in order to assess their value in the identification of turbidite layers. Particle size and geochemical data are also presented and these explain some of the down core variations in magnetic mineralogy. It is suggested that changes in the particle size frequency distributions down core may be related to fossil diatom shells. One of the cores has been dated using 210Pb. The sediment cores were cross-correlated using low frequency magnetic susceptibility (χf) and these cores can also be correlated with a nearby core collected earlier in 1992. Changes in the magnetic parameters of χlf, IRMs and HIRM210 suggest that there are significant changes in the concentration of ferrimagnetic minerals in the sediment cores, indicating changing sediment sources and/or increasing concentrations of spheroidal carbonaceous particles and the dissolution of minerals through reduction below the oxidised layer within the sediment core.
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    Recent diatom assemblage changes in subarctic Lake Saanajärvi, NW Finnish Lapland, and their paleoenvironmental implications (1998)
    Springer
    Journal of paleolimnology 20 (1998), S. 205-215 
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    ISSN: 1573-0417
    Keywords: subarctic lakes ; diatoms ; paleolimnology ; climate change ; Cyclotella ; Finnish Lapland
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract Diatoms were analysed from a 30-cm long sediment core obtained from remote subarctic Lake Saanaärvi (69°03′N, 20°52′E) in order to trace possible changes in the lake. Diatom assemblages were relatively constant throughout the core, except in the top 4–5 cm (approx 1850 A.D.) where relative frequencies of Aulacoseira italica subsp. subarctica, A. lirata var. biseriata, Cyclotella comensis and C. glomerata increased markedly. No significant trends were observed in the weighted averaging (WA) reconstructed pH values. Several hypotheses, including (i) airborne pollution, (ii) climatic change, and (iii) catchment disturbances have been put forth to explain the recent changes in diatom assemblages. The diatom change coincides with a marked increase in mean annual temperature that has been documented in the area since the termination of the Little Ice Age. Our evidence favours climate change as the main causative mechanism for the observed diatom compositional changes, although other explanations cannot be ruled out.
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    A diatom-inferred water depth reconstruction for an Upper Peninsula, Michigan, lake (1998)
    Springer
    Journal of paleolimnology 20 (1998), S. 267-276 
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    ISSN: 1573-0417
    Keywords: diatoms ; lake depth ; Sylvania Wilderness Area ; Upper Peninsula of Michigan ; hemlock ; mid-Holocene warm period
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract Transects of surface sediment samples were taken in 4 lakes from the Sylvania Wilderness Area, Upper Peninsula of Michigan. These surface samples were compared with diatom samples from a core taken in the Northwest basin of Crooked Lake, also from the Sylvania Wilderness Area. Weighted Averaging calibration was used to reconstruct lake depths in Crooked Lake using the diatom microfossils from the core and the surface samples to infer past lake depth. During the early Holocene the lake was dominated by planktonic species and diatom-inferred water depth was large – approx. 13 m. At about 6700 BP inferred water depth was 2 m and samples were dominated by Fragilaria construens var. venter – a species characteristic of shallow parts of the surface sample transects. From 6700 to 5000 BP reconstructed water level was at its shallowest. From 5000 to 3000 BP it increased. This rise in water level was marked by increasing abundances of Aulacoseira ambigua and occurred at the same time increasing percentages of hemlock pollen indicate increasing available moisture. Modern water depth was reached about 3000 BP. The water level changes at Crooked Lake are consistent with regional climate changes in the Upper Midwest during the Holocene. The lake was shallowest during the mid-Holocene warm period documented by other investigators. It deepened as the Midwestern climate became cooler and wetter during the late Holocene.
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    Paleoecological evidence for diatom response to metal pollution in Lake Orta (N. Italy) (1998)
    Springer
    Journal of paleolimnology 20 (1998), S. 333-345 
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    ISSN: 1573-0417
    Keywords: diatoms ; sediment cores ; industrial pollution ; copper ; teratology
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract Diatom remains were analysed in two short sediment cores from a subalpine Italian lake (Lake Orta), known for its major industrial pollution dating from the late 1920s, which has only recently been stopped. Copper was recognised as the main toxic agent for diatoms during the first 30 years of pollution (peak value: 100 μg l-1 in the late 1950s). A diatom community similar to other deep subalpine lakes existed in the past, and was disrupted by the pollution events. Acute and long-term effects of Cu contamination were tracked by changes in three distinct groups of species around the sharp boundary corresponding to the onset of the pollution. These groups were respectively composed of: (1) Species quickly extirpated by the discharge, mostly belonging to Fragilaria and Cyclotella and never reappearing; (2) Species apparently not affected, or not immediately affected, by the pollution, showing no definite trends with time. Synedra species, with various deformities, were conspicuous among these; (3) Species with accumulation rates increasing with time irrespective of pollution, mostly belonging to Achnanthes. Properties and tolerances of these groups (e.g. Synedra and Achnanthes) are discussed in detail.
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    The end of moai quarrying and its effect on Lake Rano Raraku, Easter Island (1998)
    Springer
    Journal of paleolimnology 20 (1998), S. 409-422 
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    ISSN: 1573-0417
    Keywords: Lake cores ; Easter Island culture ; South America ; diatoms ; cladocerans ; ostracods ; chrysophytes ; magnetic properties ; palaeopigments
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract We reconstruct aspects of the history of Easter Island over the last 4-5 centuries based on the study of a core from Rano Raraku Lake, situated in the crater that contains the quarry of the island's giant statues or moai. We use microfossils of plants and animals to identify five zones. The last three of these are separated by waves of immigration from South America and from the subantarctic. We argue that the first or South American wave, dated to the second half of the 14th century, may represent a visit by South American Indians. Magnetic information, pollen, diatoms, chrysophyte stomatocysts and fossil plant pigments reveal a synchronism between the South American contact and the cessation of moai quarrying. We therefore suggest that Amerindians contributed to the cultural collapse of the island. The second or subantarctic wave may reflect an early European visit to the island, possibly by Cpt. James Cook in 1774, or by Jacob Roggeveen in 1722.
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    Reconstructing past eutrophication trends from diatoms and biogenic silica in the sediment and the pelagic zone of Lake Constance, Germany (1999)
    Springer
    Journal of paleolimnology 21 (1999), S. 171-192 
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    ISSN: 1573-0417
    Keywords: diatoms ; biogenic silica ; pigments ; biomass ; trophic state changes ; eutrophication ; Lake Constance ; Germany
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract In Lake Constance, phosphorus concentrations and the seasonal development of phytoplankton communities in water samples from the pelagic zone were regularly recorded since the 1950's. Before the 1950's, there were occasional investigations of plankton communities since 1896. We compared these data with the sedimentary record in two sediment cores. Then, the eutrophication history of Lake Constance was inferred from diatoms. The record of biogenic silica in the cores is discussed with respect to diatom biomass increase. Diatom assemblages in the sediment cores precisely reflected the pelagic diatom development for the period 1971--1992. Both sediment cores and the water samples have a high interannual variability of diatom assemblages. Below a sediment depth of 27 cm (AD 1920), more than 50% of the diatoms were partly corroded, and we limited the reconstruction of trophic state changes to the interval of 1920--1993. Oligotrophic conditions of Lake Constance were indicated by the dominance of various Cyclotella taxa from 1920 to 1940. Since 1939/1940, increasing abundance of it Tabellaria fenestrata showed oligotrophic to mesotrophic conditions. Between 1953 and 1956, increasing Stephanodiscus hantzschii and disappearing Cyclotella indicated advanced eutrophication and total phosphorus values ranged between 8--10 mg m-3 during turnover in late winter. Further eutrophication was shown by disappearing T. fenestrata and increasing S. minutulus in 1963. Maximum TP concentrations of 87 mg m-3 occurred in 1979/80 and was accompanied by increasing abundances of Aulacoseira granulata. From 1986 to 1992, reoccurrence of Tabellaria fenestrata and Cyclotella indicate some recovery of Lake Constance. Biogenic silica and diatom abundances were similar among cores but indicate a 3--4 fold increase of diatom biomass only. This was far below the estimate of biomass increase from sedimentary pigment data (25 fold) and the estimate of phytoplankton data from the literature (70 fold).
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    Lake evolution in a semi-arid montane environment: response to catchment change and hydroclimatic variation (1999)
    Springer
    Journal of paleolimnology 21 (1999), S. 325-343 
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    ISSN: 1573-0417
    Keywords: pollen ; diatoms ; algae ; ostracods ; stable isotopes ; palaeolimnology ; Holocene ; Morocco
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract Pollen, geochemical and sedimentological data from Sidi Ali, a montane Moroccan lake, provide a 7000 yr record of changes in climate, catchment vegetation and soil erosion intensity. Diatoms, non-silicious algae, macrophyte fossils and ostracods from the same core record the dynamics of the lake ecosystem. Oxygen isotope and trace-element ratios of benthic ostracods appear to be relatively insensitive to climatic variation in this open lake with low water-residence time, but diatom plankton / periphyton (P/L) ratios show lake-level variations that are probably climate controlled. At least two superimposed processes are recorded, but at different timescales: catchment vegetation and soils show long-term changes due to climate and human impact, whereas P/L ratios suggest century-scale oscillations in lake depth. The timing of changes in algal and macrophyte productivity and carbon cycling within the lake broadly corresponds to changes in terrestrial vegetation, suggesting either that lake nutrient status is linked to catchment vegetation and soils, or that both were influenced by climate. The lack of a sensitive and independent (non-biological) climate proxy makes it more difficult to assess the lake's ecological response to short-term climate variation. Overall, the lake's evolution has been influenced both by catchment-mediated nutrient flux and by changes in water balance, thus having characteristics in common with both temperate and arid zone lakes.
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    Temporal and spatial trends of lake acidity in northern Sweden (1999)
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    Journal of paleolimnology 22 (1999), S. 1-15 
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    ISSN: 1573-0417
    Keywords: diatoms ; lake sediments ; acidification ; pH ; alkalinity ; colour ; regional estimates ; northern Sweden
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract Changes in lake-water pH, alkalinity and colour were inferred from diatoms in surface sediment samples and sediment samples from pre-industrial times from 118 northern Swedish lakes. This palaeolimnological study does not support the hypothesis that there is a large-scale modern acidification in the two northernmost counties of Sweden; pH had decreased significantly in eight lakes, while five had a significant increase. Partial least-squares regression of changes in water chemistry in relation to catchment characteristics was performed to evaluate the causes of the acidity status. Furthermore, temporal trends were assessed from long sediment cores from five acidic lakes. The results suggest that the presently acid lakes have faced a long-term acidification trend over several thousand years due to soil-forming processes and vegetation development. However, due to the acid sensitivity of the region, future acidification trends in northern Swedish lakes should be carefully observed and assessed.
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    The volume and paleobathymetry of glacial Lake Agassiz (1999)
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    Journal of paleolimnology 22 (1999), S. 71-80 
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    ISSN: 1573-0417
    Keywords: circulation model ; diatoms ; Baltic Sea ; shoreline displacement ; palaeosalinity ; laminated sediments ; palaeoproductivity ; anoxia
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract During the last retreat of the Laurentide Ice Sheet in North America, many proglacial lakes formed as continental drainage was impounded against the southern and western ice margin. Lake Agassiz was the largest of these lakes. The bathymetry of Lake Agassiz at the Herman and Upper Campbell beach levels – formed at about 11.5–11.0 ka and 9.9–9.5 ka, respectively – was computer modelled in this study by first collecting data for the isostatically-deformed paleowater planes of the two lake levels (derived from isobase lines constructed from beach elevations), and then subtracting these from the modern topography of the former lake floor. Pixels with dimensions of 1/30 × 1/30 of a degree were used in the model. Using these data, the area and volume of the lake were also calculated: at the Herman level these were ∼152 500 km2 and ∼13 100 km3 respectively; at the Upper Campbell level these were ∼350 400 km2 and ∼38 700 km3. Contour maps showing the paleobathymetry of both periods in the lake's history were also constructed. Determining the paleobathymetry and volume of Lake Agassiz is an important step in understanding the impact that the lake had on its surrounding environment and on the rivers, lakes, and oceans into which it flowed.
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    Diatom stratigraphy in five offshore sediment cores from the northwestern Baltic proper implying large scale circulation changes during the last 8500 years (1999)
    Springer
    Journal of paleolimnology 22 (1999), S. 53-69 
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    ISSN: 1573-0417
    Keywords: circulation model ; diatoms ; Baltic Sea ; shoreline displacement ; palaeosalinity ; laminated sediments ; palaeoproductivity ; anoxia
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract Five Holocene sediment cores from the northwestern Baltic proper were analysed for lithology, siliceous microfossil assemblages and geochemical parameters. The data indicate that surface water salinity and redox conditions below the halocline have changed drastically at least four times since the Baltic Sea changed from a fresh water lake (the Ancylus Lake) to a semi-enclosed brackish water sea (the Litorina Sea) c. 8500 yrs BP. These variations appear to be mainly effects of changes in water depth at the thresholds of inlet areas. Based on these changes, and earlier studies of the shoreline displacement in the inlet areas, we propose a tentative model for changes of large scale water circulation in the Baltic Sea during the last c. 8500 yrs. At the transition from fresh to brackish water 8500 14C yrs BP, upwelling of nutrient rich bottom water started to occur, causing a slight increase in primary production. Diatom assemblages in sediments indicate a slow rise in surface water salinity during this period. At 7000-6500 14C yrs BP, surface water salinity and primary production simultaneously increased, as anoxic bottom conditions were established at depth below the halocline. We suggest that high primary production was caused by increased input of oceanic water, leading to increased upwelling of nutrient rich bottom water. At the anoxic bottoms laminated sediments formed until 5000-4500 14C yrs BP. This period (c. 7000-4500 14C BP) was contemporaneous with the post-glacial transgression maximum in Öresund, and we suggest it represents the most saline phase of the Baltic Sea post-glacial history. Due to a regression in Öresund starting 4500 14C yrs BP, upwelling decreased and the halocline was lowered, resulting in decreased primary productivity and hence oxic deep water conditions. The diatom assemblages of the sediments indicate a lowering of salinity at the beginning of this period. We suggest that the second period of anoxic bottom conditions c. 2000-1500 14C yrs BP was caused by a change of dominating inflows from the Öresund to the Belt Sea. This resulted in decreased salinity of the inflowing water which did not penetrate to the deepest parts of the basin as frequently as before. The diatom record indicates both a second lowering of salinity and a change in the large scale water circulation at the beginning of this period.
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    Paleolimnological environment indicated by the diatom and pollen assemblages in an alpine lake in Taiwan (1999)
    Springer
    Journal of paleolimnology 22 (1999), S. 149-158 
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    ISSN: 1573-0417
    Keywords: acidity ; diatoms ; lake sediment ; paleolimnology ; pollen ; terrestrial vegetation ; Yuanyanf Lake ; Taiwan
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract Yuanyang Lake (24°35′N, 121°24′E), located at an altitude of 1,670 m within a nature preserve in northern Taiwan, is an acidic lake. Remains of diatoms and pollen from a 3.72-m sediment core were used to elucidate the relationships between the vegetation of the watershed and the paleolimnological environment. Past pH, saprobity level, and total P of the lake were inferred from the diatom assemblages and were analyzed with respect to changes in the terrestrial vegetation. The inferred pH values fluctuated only slightly, whereas the inferred saprobity level increased markedly towards the sediment surface. In the topmost sediment, a slight drop in the inferred pH was associated with a lowering in the saprobity index. This was interpreted as a possible result of recent anthropogenic acidification and changes in productivity related to changes in acidity. Based on pollen analyses, we conclude that Chamaecyparis persisted over at least the last four thousand years in the watershed. The vegetation in the watershed changed little during this period of time, which is consistent with the constancy of inferred pH values. A positive correlation between the inferred pH and δ13C values of the sediments was found.
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    Stable isotope (δ13C and δ15N) signatures of sedimented organic matter as indicators of historic lake trophic state (1999)
    Springer
    Journal of paleolimnology 22 (1999), S. 205-221 
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    ISSN: 1573-0417
    Keywords: carbon isotopes ; diatoms ; lake management ; nitrogen isotopes ; phosphorus ; radium-226 ; sediments ; trophic state
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract We explored the use of carbon and nitrogen isotopes (δ13C and δ15N) in sedimented organic matter (OM) as proxy indicators of trophic state change in Florida lakes. Stable isotope data from four 210Pb-dated sediment cores were compared stratigraphically with established proxies for historical trophic state (diatom-inferred limnetic total phosphorus, sediment C/N ratio) and indicators of cultural disturbance (sediment total P and 226Ra activity). Diatom-based limnetic total P inferences indicate a transition from oligo-mesotrophy to meso-eutrophy in Clear Lake, and from eutrophy to hypereutrophy in Lakes Parker, Hollingsworth and Griffin. In cores from all four lakes, the carbon isotopic signature of accumulated OM generally tracks trophic state inferences and cultural impact assessments based on other variables. Oldest sediments in the records yield lower diatom-inferred total limnetic P concentrations and display relatively low δ13C values. In the Clear, Hollingsworth and Parker records, diatom-inferred nutrient concentrations increase after ca. AD 1900, and are associated stratigraphically with higher δ13C values in sediment OM. In the Lake Griffin core, both proxies display slight increases before ~1900, but highest values occur over the last ~100 years. As Lakes Clear, Hollingsworth and Parker became increasingly nutrient-enriched over the past century, the δ15N of sedimented organic matter decreased. This reflects, in part, the increasing relative contribution of nitrogen-fixing cyanobacteria to sedimented organic matter as primary productivity increased in these waterbodies. The Lake Griffin core displays a narrow range of both δ13C and δ15N values. Despite the complexity of carbon and nitrogen cycles in lakes, stratigraphic agreement between diatom-inferred changes in limnetic total P and the stable isotope signatures of sedimented OM suggests that δ13C and δ15N reflect shifts in historic lake trophic state.
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    Cladoceran and diatom evidence of lake-level fluctuations from a Finnish lake and the effect of acquatic-moss layers on microfossil assemblages (1999)
    Springer
    Journal of paleolimnology 22 (1999), S. 277-290 
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    ISSN: 1573-0417
    Keywords: Lake-level changes ; acquatic-moss layers ; Cladocera ; diatoms ; pollen ; cladoceran planktonic/littoral ratio
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract We studied Holocene lake-level fluctuations from a small lake, Iso Lehmälampi, southern Finland, utilizing cladoceran and diatom analyses. We report data from a sediment core (A) taken from the deepest part of the lake (8.1 m) where two layers of moss, mixed with gyttja, were found. These layers were formed in situ during the early Holocene (1. ca. 8100-7900, 2. ca. 7300 BP). Lake-level fluctuations were inferred also from another core C, which did not have moss layers. According to the ratio of planktonic/littoral Cladocera, the water level was high around 9000 BP and started to fall before 8000 BP. The lowering continued until 7000 BP and the moss layers were formed during this lowering. Water level was high again ca. 6000 BP and lowered towards ca. 4000 BP. The late Holocene is characterized by several rapid fluctuations of lake-level. The ratio of planktonic/littoral Cladocera and the diatom species composition in core A showed drastic changes between the moss layers and the non-moss gyttja sections of the core. We suggest that they reflect changes in sedimentary facies between the local moss environment and the pelagic bottom. Thus, cores which contain moss layers may lead to erroneous interpretations of lake-level fluctuations.
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    Surface-sediment and epilithic diatom pH calibration sets for remote European mountain lakes (AL:PE Project) and their comparison with the Surface Waters Acidification Programme (SWAP) calibration set (1999)
    Springer
    Journal of paleolimnology 22 (1999), S. 291-317 
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    ISSN: 1573-0417
    Keywords: diatoms ; pH ; weighted average partial least squares ; Guassian regression ; high-altitude lakes ; DOC ; optima ; Europe
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract A modern diatom-pH calibration data-set consisting of surface-sediment diatom assemblages from 118 lakes and 530 taxa is presented. The AL:PE data-set is from high-altitude or high-latitude lakes in the Alps, Norway, Svalbard, Kola Peninsula, UK, Slovenia, Slovakia, Poland, Portugal, and Spain (pH range = 4.5-8.0; DOC range = 0.2-3.2 mg l-1). In addition, 92 epilithon samples from 22 high-altitude or high-latitude lakes comprise an AL:PE epilithon diatom-pH data-set. Weighted averaging partial least squares regression is used to develop pH-inference models. The AL:PE data-set has a root-mean-square-error of prediction (RMSEP) of 0.33 and a maximum bias of 0.36 pH units and r2 of 0.82, as assessed by leave-one-out cross-validation. The epilithon data-set has, after data-screening and the deletion of one very obvious outlier, a RMSEP of 0.23 and a maximum bias of 0.18 pH units and r2 of 0.88. The 167 sample SWAP diatom-pH data-set from lowland or upland lakes in the UK, Norway, and Sweden has a RMSEP of 0.29 and a maximum bias of 0.23 pH units and r2 of 0.86. The pH optima, as estimated by weighted averaging and Gaussian regression, are compared for the three data-sets (AL:PE, SWAP, AL:PE epilithon). There is a good correspondence between the AL:PE and the AL:PE epilithon optima, but a consistent bias between the AL:PE and SWAP optima, with the SWAP optima being lower than the AL:PE estimates. The predictive performances of the AL:PE and SWAP calibration data-sets are compared using independent test samples and six core sequences, all from high-altitude lakes, one in south-east Siberia and five in eastern Scotland. The results show the importance of using the AL:PE data-set for inferring lake-water pH from diatom assemblages in high-altitude or high latitude lakes with low DOC concentrations.
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    Environmental Characteristics of Lake Tecocomulco, northern basin of Mexico, for the last 50,000 years (1999)
    Springer
    Journal of paleolimnology 22 (1999), S. 399-411 
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    ISSN: 1573-0417
    Keywords: quaternary ; paleolimnology ; diatoms ; pollen ; magnetic properties ; lacustrine sediments ; Mexico
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract Paleoenvironmental studies have documented the late Pleistocene to Holocene evolution of the lakes in the central and southern parts of the basin of Mexico (Texcoco and Chalco). No information was available, however, for the lakes in the north-eastern part of this basin. The north-eastern and the central and southern areas represent, at present, different environmental conditions: an important gradient exists between the dry north and the moister south. To investigate the late Pleistocene to Holocene characteristics of the north-eastern lakes in the basin of Mexico two parallel cores (TA and TB) were drilled at the SE shore of Lake Tecocomulco. Stratigraphy, magnetic properties, granulometry, diatom and pollen analyses performed on these sediments indicate that the lake experienced a series of changes between ca. 〉 42,000 yr BP and present. Chronological control is given by five radiocarbon determinations. The base of the record is represented by a thick, rhyolitic air-fall tephra that could be older than ca. 50,000 yr BP. After this Plininan event, and until ca. 42,000 yr BP, Lake Tecocomulco was a moderately deep, freshwater lake surrounded by extended pine forests that suggest the presence of cooler and moister conditions than present. Between ca. 42,000 and 37,000 yr BP, the lake became shallower but with important fluctuations and pollen suggests slightly warmer conditions. Between ca. 37,000 and 30,000 yr BP the lake experienced two relatively deep phases separated by a dry interval. A second Plinian eruption, represented in the sequence by a dacitic an air-fall tephra layer dated at 31,000 yr BP, occurred in the area by the end of this dry episode. Between ca. 30,000 and 25,7000 yr BP Tecocomulco was a fresh to slightly alkaline lake with a trend towards lower level. After ca. 25,700 yr BP very low lake levels are inferred, and after ca. 16,000 yr BP the data indicate the presence of a very dry environment that was persistent until the middle Holocene. After 3,500 yr BP lacustrine conditions were re-established and the vegetation cover shows a change towards higher percentages of herbaceous taxa.
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    Development of a diatom-based specific conductivity model for the glacio-isostatic lakes of Truelove Lowland: implications for paleoconductivity and paleoenvironmental reconstructions in Devon Island lakes, N.W.T., Canada (1999)
    Springer
    Journal of paleolimnology 22 (1999), S. 367-382 
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    ISSN: 1573-0417
    Keywords: paleolimnology ; arctic lakes ; diatoms ; specific conductivity ; Canonical Correspondence Analysis (CCA) ; Weighted Averaging (WA) ; paleoconductivity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract Diatoms are identified and enumerated from the surface sediments of 100 lakes of Truelove Lowland, Devon Island, N.W.T., Canada. These lakes range from large oligotrophic lakes, to small tundra ponds, to coastal marine lagoons which are diverse in terms of ionic concentration and composition. The relationship between diatoms and 15 limnological variables is examined using Canonical Correspondence Analysis (CCA). Specific conductivity is identified as the most important variable influencing the distribution of diatoms in the Truelove lakes. A Weighted Averaging (WA) calibration model is developed to predict diatom-inferred specific conductivity. The reliability of the model is tested by evaluating the correlation between observed and diatom-inferred values and determining the error of prediction by bootstrapping. The applicability of the predictive conductivity equation is demonstrated by reconstructing the paleoconductivity history of Fish Lake.
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    URL: http://dx.doi.org/10.1023/A:1008022501117
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    Calibration of diatoms along a nutrient gradient in Florida Everglades Water Conservation Area-2A, USA (1999)
    Springer
    Journal of paleolimnology 22 (1999), S. 413-437 
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    ISSN: 1573-0417
    Keywords: diatoms ; Everglades ; phosphorus ; wetland ; calibration ; multivariate ; Florida
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract The relationship between diatom taxa preserved in surface soils and environmental variables at 31 sites in Water Conservation Area 2A (WCA-2A) of the Florida Everglades was explored using multivariate analyses. Surface soils were collected along a phosphorus (P) gradient and analyzed for diatoms, total P, % nitrogen (N), %carbon (C), calcium (Ca), and biogenic silica (BSi). Phosphorus varied from 315-1781 μg g-1, and was not found to be correlated with the other geochemical variables. Canonical correspondence analysis (CCA) was used to examine which environmental variables correlated most closely with the distributions in diatom taxa. Canonical correspondence analysis with forward selection, constrained and partial CCA, and Monte Carlo permutation tests of significance show the most significant changes in diatom assemblages along the P gradient (p 〈 0.01), with additional species differences correlated with soil C, N, Ca, and BSi. Weighted-averaging (WA) regression and calibration models of diatom assemblages to P and BSi were developed. The diatom-based inference model for soil [P] had a high apparent r2 (0.86) with RMSEboot = 218 μg g-1. Indicator diatom species identified by assessing species WA optima and WA tolerance to [P], such as Nitzschia amphibia and N. palea for high [P] (~1300-1400 μ g-1) and Achnanthes minutissima var. scotica and Mastogloia smithii for low [P] (~400-600 μg g-1), may be useful as monitoring tools for eutrophication in WCA-2A as well as other areas of the Everglades. Diatom assemblages analyzed by cluster analysis were related to location within WCA-2A, and dominant taxa within clusters are discussed in relation to the geochemical variables measured as well as hydrology and pH. Diversity of diatom assemblages and a ‘Disturbance Index’ based on diatom data are discussed in relation to the historically P-limited Everglades ecosystem. Diatom assemblages should be very useful for reconstructions of [P] through time in the Florida Everglades, provided diatoms are well preserved in soil cores.
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    Diatom-derived palaeoconductivity estimates for Lake Awassa, Ethiopia: evidence for pulsed inflows of saline groundwater (1999)
    Springer
    Journal of paleolimnology 21 (1999), S. 409-422 
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    ISSN: 1573-0417
    Keywords: Africa ; climate change ; conductivity ; diatoms ; Ethiopia ; Holocene ; lake levels ; palaeolimnology ; Rift Valley
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract A 6,500-year diatom stratigraphy has been used to infer hydrochemical changes in Lake Awassa, a topographically closed oligosaline lake in the Ethiopian Rift Valley. Conductivity was high from ~6400-6200 BP, and from 5200-4000 BP, with two brief episodes of lower conductivity during the latter period. Although the timing of the conductivity changes is similar to the timing of lake-level change in the nearby Zwai-Shalla basin, their directions are the reverse of that expected from a climatic cause. Dissolution of the tephras which precede both phases of high conductivity cannot explain the increases in salinity, because rhyolitic tephras are only sparingly soluble. Instead, the pulsed input of groundwater made saline by the reaction of silicate minerals and volcanic glass with carbonic acid, formed from the solution of carbon dioxide degassed from magma under the Awassa Caldera, is suggested as a plausible mechanism for the observed change in lake chemistry. Diatom-inferred hydrochemistry cannot therefore be used to reconstruct climate change in Lake Awassa.
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    Differences in the eutrophication dynamics of Ammersee and Starnberger See (Southern Germany), reflected by the diatom succession in varve-dated sediments (1999)
    Springer
    Journal of paleolimnology 21 (1999), S. 395-407 
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    ISSN: 1573-0417
    Keywords: varves ; diatoms ; eutrophication dynamics ; Amersee ; Starnberger See
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract Diatom assemblages in the annually laminated sediments of two neighboring, pre-alpine lakes (Ammersee and Starnberger See, Southern Germany) were analyzed and compared year by year. Within both varve records of the last decades, the same 4-phase-succession of planktonic diatom species is preserved, consisting of 1. a dominance of Cyclotella species 2. assemblages of Fragilaria crotonensis, Asterionella formosa and Stephanodiscus minutulus 3. a mass bloom of Aulacoseira islandica, and 4. a dominance of Stephanodiscus species. This diatom sequence is considered as a model of a 'basic species sequence of eutrophication'. Time lags and differences in the duration of the phases between both lakes show evidence of an earlier start for nutrient loading in Starnberger See than in Ammersee, and a faster development to a higher trophic state level in the latter. The different reactions of the lakes are attributed to hydrological differences such as the existence or lack of a major tributary, the size of the catchment area, and the water residence time. The reconstruction of the eutrophication dynamics appears to be reliably hindcast by the inference of total phosphorus (TP) concentrations using weighted averaging regression and calibration techniques. Remarkable differences in the occurrence of some diatoms in both stratigraphies, which are not related to the general changes of the 'basic species sequence of eutrophication' model, may be due to the epilimnetic silica content (e.g. Fragilaria crotonensis) or competitive weaknesses (e.g. Tabellaria flocculosa).
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    Sedimentation patterns of diatoms in Lake Holzmaar, Germany - (on the transfer of climate signals to biogenic silica oxygen isotope proxies) (1999)
    Springer
    Journal of paleolimnology 21 (1999), S. 437-448 
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    ISSN: 1573-0417
    Keywords: diatoms ; temperature ; sediment traps ; seasonal succession ; resuspension ; Lake Holzmaar
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract The seasonal sedimentation pattern of diatom valves in Lake Holzmaar was investigated during 1995 by deploying sediment traps at three different lake depths. According to the sedimentation pattern, the major reproduction zone of diatoms was restricted to the upper 6 m of the water body. The population growth started late in April and blooms of Cyclotella cf. comensis Grun., which dominates the plankton diatoms, and Fragilaria crotonensis Kitton were collected in traps during June and September, and July, respectively. During summer, the seasonal sedimentation pattern of each taxon, as collected in the upper traps, was reflected in the concentrations in the lowest trap. However, in May and from September onwards, the community composition in the lowest trap and augmented trapping rates suggest both sediment focusing and resuspension of bottom sediments. The temperature signals as recorded by δ18O values of diatom valves should, therefore, reflect integrated temperatures between 0 and 6 m depth. However, temperatures during summer and autumn are expected to be accentuated in the sedimentary record since the isotopic signal is weighted by both the number and the weight-mass of the valves. During summer, the transfer of these signals by the sedimenting diatoms retains the information pattern recorded, while in spring and autumn/winter additional influxes caused by resuspension may somewhat alter those temperature informations. The proxy signals finally stored in the sediments, may, therefore, not precisely represent the successive temperatures currently recorded during 1995 within mid-lake.
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    Sediment indicators of meromixis: comparison of laminations, diatoms, and sediment chemistry in Brownie Lake, Minneapolis, USA (1996)
    Springer
    Journal of paleolimnology 15 (1996), S. 129-132 
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    ISSN: 1573-0417
    Keywords: meromixis ; diatoms ; laminations ; varves
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract Meromixis has several powerful effects on lakes, yet there is no single definitive sediment indicator of meromixis. In this study three sediment indicators of meromixis were compared in Brownie Lake, Minneapolis, Minnesota, a small eutrophic lake that became meromictic around 1925. The results show that in Brownie the onset of laminations and changes in the iron to manganese ratio most likely occurred before the development of permanently anoxic bottom water and that changes in the diatom assemblage occurred later, most likely only when meromixis was well developed.
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    Siliceous microfossil succession in the recent history of two basins in Lake Baikal, Siberia (1995)
    Springer
    Journal of paleolimnology 14 (1995), S. 165-184 
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    ISSN: 1573-0417
    Keywords: Lake Baikal ; Russia ; paleolimnology ; diatoms ; chrysophyte cysts ; Little Ice Age ; climate change
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract As part of the international cooperative Baikal Drilling Project, siliceous microfossil assemblage succession was analyzed in two short (∼ 30-cm) sediment cores from Lake Baikal. One core was recovered from the north basin (Core 324, 55°15′N, 109°30′E), a second from between the central and southern basins (Core 316, 52°28′N, 106°5′E). The northern core had higher amounts of biogenic silica (40 g SiO2 per 100 g dry weight sediment) compared to the southern core, and increased deposition in the more recent sediments. Weight percent biogenic silica was lower in the southern core, ranging from approximately 20–30 g SiO2 per 100 g dry weight sediment throughout the entire core. Trends in absolute microfossil abundance mirror those of biogenic silica, with generally greater abundance in the northern core (86–275×106 microfossils g−1 dry sediment) compared to the southern core (94–163×106 microfossils g−1 dry sediment). Cluster analyses using relative abundance of the dominant diatom and chrysophyte taxa revealed four zones of microfossil succession in each core. Microfossil assemblage succession in the north basin may be reflecting shifts in nutrient supply and cycling driven by climatic changes. The most recent sediments in the northern basin (Zone 1,c. 1890's–1991 A.D.) were characterized by an increased abundance ofAulacoseira baicalensis andAulacoseira ‘spore’. Zone 3 (c. 1630's–1830's A.D.) was dominated by the endemicCyclotella spp. and reduced abundance of theAulacoseira spp. Zone 3 corresponds approximately to the Little Ice Age, a cooler climatic period. The microfossil assemblages between Zones 1 and 3 (Zone 2,c. 1830's–1890's A.D.) and below Zone 3 (Zone 4,c. 830's–1430's A.D.) are similar to one another suggesting they represent transitional intervals between warm and cold periods. Southern basin sediments record similar changes in the endemic taxa. However, the increased abundance of non-endemic planktonic taxa (e.g.Stephanodiscus binderanus, Synedra acus, Cyclostephanos dubius) during two periods in recent history (post World War II and late 1700's) suggests evidence for anthropogenic induced changes in southern Lake Baikal.
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    The late Quaternary development of three ancient tarns on southwestern Cumberland Peninsula, Baffin Island, Arctic Canada: paleolimnological evidence from diatoms and sediment chemistry (1996)
    Springer
    Journal of paleolimnology 15 (1996), S. 1-18 
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    ISSN: 1573-0417
    Keywords: lake developmental history ; diatoms ; sediment chemistry ; glacial refugia ; Baffin Island ; Arctic Canada
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract Sediment diatom and chemical analyses of cores from three poorly buffered extra-glacial lakes on the northeastern margin of the Canadian Shield (Cumberland Peninsula, Baffin Island) record interactions between aquatic and terrestrial spheres that were influenced by late Quaternary climatic conditions. Although differences exist between each of the lakes, notably with regards to the intensity of pre-Holocene catchment erosion and the timing of the onset of organic sedimentation, an underlying pattern of lake ontogeny, common to all three lakes, is identified. Although intensified watershed erosion characterized the Late Wisconsinan and Neoglacial cold periods, the lakes nonetheless remained viable ecosystems at these times. Sudden catchment stabilization during the late-glacial to earliest Holocene is associated with incipient organic sedimentation. Lake-water pH increased at this time, likely in response both longer base cation residence times as lake flushing rates decreased, and enhanced alkalinity production from sediment biogeochemical reactions. Subsequently, as the catchments remained stable during the productive early Holocene (c.9–7 ka BP), then gradually received a renewed increase of minerogenic sedimentation, the breakdown of sources of lake alkalinity resulted in natural acidification. Burial of cation-rich mineral sediments and the loss of permanent sedimentary sinks for the products of microbial reduction likely impeded within-lake alkalinity production, and catchment-derived base cations appeared ineffective in curtailing pH declines. The general nature of the Holocene development of these lakes is similar to that observed elsewhere on crystalline terrains, following deglaciation. Our data therefore suggest that catchment glaciation is not a necessary precursor for models of lake development characterized by initial base cation enrichment and subsequent gradual acidification.
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    Hamilton Harbour, Ontario: 8300 years of limnological and environmental change inferred from microfossil and isotopic analyses (1996)
    Springer
    Journal of paleolimnology 15 (1996), S. 79-97 
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    ISSN: 1573-0417
    Keywords: Hamilton Harbour ; paleolimnology ; diatoms ; sediment isotopes ; palynology
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract Limnological changes in Hamilton Harbour, Lake Ontario, over the Holocene were investigated by using proxy evidence from diatoms and other siliceous microfossils in a radiometrically dated sediment core (HH26comp), together with environmental data derived from sediment pollen and oxygen and carbon isotope analyses. The evidence demonstrates that the site of Hamilton Harbour has changed over the past 8300 y from a shallow, separate waterbody, to a deep embayment of Lake Ontario. The earliest evidence, from 8300 BP to 7000 BP, is of a mesotrophic pond of moderate alkalinity, warmer than present, and probably with an extensive marginal wetland. An initial transitory connection with the rising water level of Lake Ontario was established at c. 7000 BP, possibly via a deep outlet channel. This connection is 2000 y earlier then previously estimated. Permanent confluence with Lake Ontario was established at c. 6200 BP, causing a decline in inferred trophic level and water temperatures. Microfossils reach a minimum at 4400 BP coincident with the Nipissing Flood. Decreased mixing of Lake Ontario water from about 4000 BP following the Nipissing Flood highstand is evidenced in isotopic and diatom data. Three isolated shifts in the diatom spectrum at c. 4900 BP, 4500 BP, and 3500 BP may be associated with extreme turbidity or storm deposit events. Between 3200 BP and 280 BP, Hamilton Harbour was evidently a moderately alkaline embayment of Lake Ontario, oligotrophic to mesotrophic, and relatively cooler than present. The final 280 y sedimentary record reveals the magnitude of anthropogenically induced changes to the harbour, including eutrophication and organic pollution.
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    URL: http://dx.doi.org/10.1007/BF00176991
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    Diatom-based water chemistry reconstructions from northern Sweden: a comparison of reconstruction techniques (1996)
    Springer
    Journal of paleolimnology 15 (1996), S. 65-77 
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    ISSN: 1573-0417
    Keywords: diatoms ; lake sediments ; pH ; alkalinity ; colour ; weighted averaging (WA) ; weighted averaging partial least squares (WA-PLS) ; calibration ; Northern Sweden
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract The diatom composition in surface sediments from 119 northern Swedish lakes was studied to examine the relationship with lake-water pH, alkalinity, and colour. Diatom-based predictive models, using weighted-averaging (WA) regression and calibration, partial least squares (PLS) regression and calibration, and weighted-averaging partial least squares (WA-PLS) regression and calibration, were developed for inferences of water chemistry conditions. The non-linear response between the diatom assemblages and pH and alkalinity was best modelled by weighted-averaging methods. The lowest prediction error for pH was obtained using weighted averaging, with or without tolerance downweighting. For alkalinity there was still some information in the residual structure after extracting the first weighted-averaging component, which resulted in a slight improvement of predictions when using a two component WA-PLS model. The best colour predictions were obtained using a two component PLS model. Principal component analysis (PCA) of the prediction errors, with some characteristics of the training set included as passive variables, was performed to compare the results for the different alkalinity predictive models. The results indicate that calibration techniques utilizing more than one component (PLS and WA-PLS) can improve the predictions for lakes with diatom taxa that have broad tolerances. Furthermore, we show that WA-PLS performs best compared with the other techniques for those lakes that have a high relative abundance of the most dominant taxa and a corresponding low sample heterogeneity.
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    The environmental history of a mountain lake (Lago Paione Superiore, Central Alps, Italy) for the last c. 100 years: a multidisciplinary, palaeolimnological study (1996)
    Springer
    Journal of paleolimnology 15 (1996), S. 245-264 
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    ISSN: 1573-0417
    Keywords: palaeolimnology ; acidification ; diatoms ; chrysophytes ; pigments ; chironomids ; temperature ; Alps ; Italy
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract A palaeoecological study of an oligotrophic alpine lake, Paione Superiore (Italy), provided a record of historical changes in water quality. Historical trends in lake acidification were reconstructed by means of calibration and regression equations from diatoms, chrysophycean scales and pigment ratios. The historical pH was inferred by using two different diatom calibration data sets, one specific to the alpine region. These pH trends, together with the record of sedimentary carbonaceous particles and chironomid remains, indicate a recent acidification of this low alkalinity lake. Concentration of total organic matter, organic carbon, nitrogen, biogenic silica (BSiO2), chlorophyll derivatives (CD), fucoxanthin, diatom cell concentration and number of chironomid head capsules increased during the last 2–3 decades. When expressed as accumulation rates, most of these parameters tended to decrease from the past century to c. 1950, then all except P increased to the present day. A marked increase in sedimentary nitrogen may be related to atmospheric pollution and to the general increases in output of N in Europe. High C/N ratios indicate a prevailing allochthonous source of organic matter. Finally, the increase in measured air temperature from the mid-1800's appeared to be related to lake water pH before industrialization: cold periods generally led to lower pH and vice-versa. The more recent phenomenon of anthropogenic acidification has apparently decoupled this climatic-water chemistry relationship.
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    A land-use and water-quality history of White Rock Lake reservoir, Dallas, Texas, based on paleolimnological analyses (1997)
    Springer
    Journal of paleolimnology 17 (1997), S. 227-227 
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    ISSN: 1573-0417
    Keywords: diatoms ; pollen ; sediment ; reservoir limnology ; land-use change ; Texas
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract White Rock Lake reservoir in Dallas, Texas contains a 150-cm sediment record of silty clay that documents land-use changes since its construction in 1912. Pollen analysis corroborates historical evidence that between 1912 and 1950 the watershed was primarily agricultural. Land disturbance by plowing coupled with strong and variable spring precipitation caused large amounts of sediment to enter the lake during this period. Diatoms were not preserved at this time probably because of low productivity compared to diatom dissolution by warm, alkaline water prior to burial in the sediments. After 1956, the watershed became progressively urbanized. Erosion decreased, land stabilized, and pollen of riparian trees increased as the lake water became somewhat less turbid. By 1986 the sediment record indicates that diatom productivity had increased beyond rates of diatom destruction. Neither increased nutrients nor reduced pesticides can account for increased diatom productivity, but grain size studies imply that before 1986 diatoms were light limited by high levels of turbidity. This study documents how reservoirs may relate to land-use practices and how watershed management could extend reservoir life and improve water quality.
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    Diatom-based interpretation of sediment banding in an urbanized lake (1997)
    Springer
    Journal of paleolimnology 17 (1997), S. 437-449 
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    ISSN: 1573-0417
    Keywords: diatoms ; laminated sediments ; storm events ; urbanized lake
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract Sediment stratigraphy and diatom succession were studied in an 80.5-cm core taken from the deepest part of Third Sister Lake, a small kettle hole in a recently urbanized landscape of southeastern Michigan. Alternating light clay and dark organic bands documented sporadic inputs of clay from outside the basin during rain events, rather than annual laminations. Urban construction activity also disrupted the inflow stream bed and facilitated transport of clay into the lake to generate non-rhythmic banding in the lake's deep hole. Diatom analysis revealed dramatic changes in predominant taxa with sediment depth verifying the non-annual nature of the sediment bands. Observation of halophilic diatom taxa also documented effects of human activity such as road salting on this small, urban lake.
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    URL: http://dx.doi.org/10.1023/A:1007910732353
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    A Holocene paleosalinity diatom record from southwestern Saskatchewan, Canada: Harris Lake revisited (1997)
    Springer
    Journal of paleolimnology 17 (1997), S. 23-31 
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    ISSN: 1573-0417
    Keywords: diatoms ; salinity ; climatic change ; Holocene ; CypressHills ; Saskatchewan
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract Fossil diatoms were analysed from a 10.3 m core from Harris Lake, Cypress Hills, Saskatchewan, and a diatom-salinity transfer function was used to construct a history of Holocene salinity changes for the lake. The diatom paleosalinity record indicates that Harris Lake remained fresh 〈0.5 g l-1 throughout the Holocene, with only slight increases in salinity between approximately 6500 and 5200 years BP. This interval corresponds to the only period in the lake's history when planktonic diatoms were abundant; benthic Fragilaria taxa, mainly F. pinnata, F. construens and F. brevistriata were dominant throughout most of the Holocene. The shift from a benthic to a planktonic diatom flora between 6500 and 5200 years BP may be an indirect response to a warmer climate that reduced forest cover in the watershed and allowed greater rates of inorganic sedimentation. The small salinity increase that accompanies the floristic change is probably not the result of lower lake levels; in fact the lake was probably deeper at this point than in the later Holocene. This paleosalinity record indicates that Harris Lake did not experience episodes of hypersalinity during the mid-Holocene, as suggested by a previous study, and that the lake may have been fresh during the early Holocene as well.
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    URL: http://dx.doi.org/10.1023/A:1007956808240
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    Recent environmental changes in a naturally acidic rocky lake in southern Finland, as reflected in its sediment geochemistry and biostratigraphy (1997)
    Springer
    Journal of paleolimnology 17 (1997), S. 191-213 
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    ISSN: 1573-0417
    Keywords: acidification ; geochemistry ; atmospheric loading ; diatoms ; in situ alkalinity ; forest fires
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract Paleolimnological methods are combined with statistical multivariate analyses (PCA and CCA) to study the effects of local environmental disturbances and changes in loading of atmospheric origin on water acidity and the physiochemical properties of the sediment in a small, naturally acidic rocky lake in southern Finland. The pH of the lake as calculated from the diatom flora increased by 0.9 pH units as a consequence of a forest fire in the catchment area at the turn of the last century, and the changes in the diatom assemblages point to an increase in dys(eu)trophy and turbulence. In terms of element influx (in µg cm-2 yr-1), the effects of the fire are seen in a slight increase in the accumulation of lithophilous elements. Diatom-inferred pH values decline upwards in the sediment, but do not regain the level recorded before the fire. This is attributed to reactions between Fe3+ and S, which has partly accumulated from the air as SO2-, producing internal alkalinity. Accumulation rates of many elements increase markedly after the 1960s, an effect for Al, Mg, Na, P and Zn may be connected mainly with the enhanced accumulation of dry matter, whereas the accumulation of K, Ni, Pb, Ti and V in surface sediment are obviously related to atmospheric loading. Measured accumulation rates of Cd and Cu are lower than the calculated values especially in the surface sediment, possibly because of diagenetic changes. Accumulation of Ca and Mn decreases towards the surface on account of acidification of anthropogenic origin.
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    Diatom assemblages from Costa Rican lakes: an initial ecological assessment (1997)
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    Journal of paleolimnology 17 (1997), S. 263-274 
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    ISSN: 1573-0417
    Keywords: diatoms ; tropics ; lakes ; limnology ; canonical correspondence analysis
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract We compared the distributions of 59 diatom species in surface sediments of 25 Costa Rican lakes with 21 environmental variables using canonical correspondence analysis (CCA). The distribution of taxa was related to the chemical and physical characteristics of the lakes. The most influential chemical variables were cation concentrations (especially magnesium) and related variables such as water hardness, pH, and temperature. Lake area and lake depth were among the most important physical variables. A number of taxa were identified as potential environmental indicators. The diatoms Brachysira serians var. brachysira and Frustulia rhomboides seem to be associated with low values of alkalinity, hardness, Ca, Mg, and SiO2. Cymbella minuta var. silesiaca is associated with low to moderate values of alkalinity, hardness, Ca, and Mg. Nitzschia cf. amphibia may be an indicator of moderate-to-high concentrations of Mg. Pinnularia braunii var. amphicephala seems to prefer low values of hardness, Ca, Mg, and SiO2. In many closed lakes, these environmental variables (Mg/Ca/hardness/alkalinity) increase with effective evaporation. Consequently, these diatoms may be indirectly tracking P:E ratios. Results from this initial, small data set indicate the potential of diatoms for inferring lake paleochemistry, and perhaps P:E ratios, in Costa Rica.
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    Diatoms in sediments of perennially ice-covered Lake Hoare, and implications for interpreting lake history in the McMurdo Dry Valleys of Antarctica (1997)
    Springer
    Journal of paleolimnology 17 (1997), S. 403-420 
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    ISSN: 1573-0417
    Keywords: McMurdo Dry Valleys ; Antarctica ; diatoms ; ice-covered lakes ; closed-basin lakes ; amictic lakes
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract Diatom assemblages in surficial sediments, sediment cores, sediment traps, and inflowing streams of perennially ice-covered Lake Hoare, South Victorialand, Antarctica were examined to determine the distribution of diatom taxa, and to ascertain if diatom species composition has changed over time. Lake Hoare is a closed-basin lake with an area of 1.8 km2, maximum depth of 34 m, and mean depth of 14 m, although lake level has been rising at a rate of 0.09 m yr-1 in recent decades. The lake has an unusual regime of sediment deposition: coarse grained sediments accumulate on the ice surface and are deposited episodically on the lake bottom. Benthic microbial mats are covered in situ by the coarse episodic deposits, and the new surfaces are recolonized. Ice cover prevents wind-induced mixing, creating the unique depositional environment in which sediment cores record the history of a particular site, rather than a lake-wide integration. Shallow-water (〈1 m) diatom assemblages (Stauroneis anceps, Navicula molesta, Diadesmis contenta var. parallela, Navicula peraustralis) were distinct from mid-depth (4–16 m) assemblages (Diadesmis contenta, Luticola muticopsis fo. reducta, Stauroneis anceps, Diadesmis contenta var. parallela, Luticola murrayi) and deep-water (26–31 m) assemblages (Luticola murrayi, Luticola muticopsis fo. reducta, Navicula molesta). Analysis of a sediment core (30 cm long, from 11 m water depth) from Lake Hoare revealed two abrupt changes in diatom assemblages. The upper section of the sediment core contained the greatest biomass of benthic microbial mat, as well as the greatest total abundance and diversity of diatoms. Relative abundances of diatoms in this section are similar to the surficial samples from mid-depths. An intermediate zone contained less organic material and lower densities of diatoms. The bottom section of core contained the least amount of microbial mat and organic material, and the lowest density of diatoms. The dominant process influencing species composition and abundance of diatom assemblages in the benthic microbial mats is episodic deposition of coarse sediment from the ice surface.
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    Diatom preservation in the recent sediment record of Spanish saline lakes: implications for palaeoclimate study (1998)
    Springer
    Journal of paleolimnology 19 (1998), S. 129-137 
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    ISSN: 1573-0417
    Keywords: saline lakes ; paleolimnology ; paleoclimate ; diatoms ; taphonomy ; preservation ; Spain
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract In palaeoclimate research, fossil diatoms from saline lakes can be excellent indicators of past salinity, a proxy for climate change, although they are sometimes poorly preserved in sediment cores. Spain has numerous salt lakes but the potential of diatoms for studies of climate change has never been investigated. A comprehensive survey of diatom preservation is described based on modern and fossil diatoms from short cores (〈50 cm depth) in a representative data-set of 59 sites, and the main factors affecting preservation are investigated using principal components analysis (PCA). Most lakes do not preserve a diatom record; four sites in southern Spain are identified which both contain diatoms and have suitable limnological characteristics for a climate study. Many lakes are ephemeral and the physical effects of desiccation, coupled with other factors such as turbidity and high salinity, are the main factors enhancing diatom dissolution or their failure to be incorporated into the sediment record.
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    URL: http://dx.doi.org/10.1023/A:1007948600780
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    A paleolimnological study of eutrophied Lake Arendsee (Germany) (1998)
    Springer
    Journal of paleolimnology 19 (1998), S. 41-54 
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    ISSN: 1573-0417
    Keywords: Lake Arendsee (Germany) ; paleolimnology ; nutrients ; eutrophication ; diatoms
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract To study the algal microfossil assemblages of eutrophic Lake Arendsee (Germany) prior to the beginning of a restoration project, a 47-cm long freeze core, dating back to ca 1800, was taken from the deepest area of the lake. Based on the CRS modeled 210Pb and 137Cs profiles from the core, 1948 is around 15 cm and the sedimentation rate has increased from ∼ 21.2 mg cm-2 yr-1 in 1900 to ∼ 56.6 mg cm-2 yr-1 in 1986. The sediments were dominated by three centric diatoms. Stephanodiscus binatus, a species associated with eutrophic environments, dominated the upper 19 cm of the core. Cyclotella rossii, a species commonly found in less productive freshwater systems, was found to dominate the lower portion of the core and was absent above 16 cm. S. agassizensis was found throughout the core. In addition to the centric diatoms, three penate diatoms were found to be abundant. Fragilaria crotonensis was found throughout the core, but was most abundant from 19 cm to 16 cm. Asterionella formosa was prevalent below 15 cm, while Diatoma elongatum was found to be common from 17 cm to the surface. The abundances of algal remains of cyanobacteria, chlorophytes, cryptophytes and dinoflagellates decrease dramatically below 25 cm. Zooplankton remains were most abundant around 20 cm, with copepod spermatophores, fecal pellets and protozoa remains most common in the lower portion of the core. The major species shifts observed in the core from Lake Arendsee occur in a transition zone between 20 cm and 15 cm (1920–1940), a time when agricultural production was being increase with the use of inorganic fertilizer.
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    Modern diatom, cladocera, chironomid, and chrysophyte cyst assemblages as quantitative indicators for the reconstruction of past environmental conditions in the Alps. II. Nutrients (1998)
    Springer
    Journal of paleolimnology 19 (1998), S. 443-463 
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    ISSN: 1573-0417
    Keywords: transfer functions ; WA-PLS ; total phosphorus ; trophic state ; eutrophication ; surface sediments ; Switzerland ; diatoms ; cladocera ; chironomids ; chrysophytes
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract Surface sediments from 68 small lakes in the Alps and 9 well-dated sediment core samples that cover a gradient of total phosphorus (TP) concentrations of 6 to 520 μg TP l-1 were studied for diatom, chrysophyte cyst, cladocera, and chironomid assemblages. Inference models for mean circulation log10 TP were developed for diatoms, chironomids, and benthic cladocera using weighted-averaging partial least squares. After screening for outliers, the final transfer functions have coefficients of determination (r2, as assessed by cross-validation, of 0.79 (diatoms), 0.68 (chironomids), and 0.49 (benthic cladocera). Planktonic cladocera and chrysophytes show very weak relationships to TP and no TP inference models were developed for these biota. Diatoms showed the best relationship with TP, whereas the other biota all have large secondary gradients, suggesting that variables other than TP have a strong influence on their composition and abundance. Comparison with other diatom – TP inference models shows that our model has high predictive power and a low root mean squared error of prediction, as assessed by cross-validation.
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    Stable-isotopes of groundwaters from the Albuquerque, New Mexico, basin: one decade later (1997)
    Springer
    Environmental geology 31 (1997), S. 199-204 
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    ISSN: 1432-0495
    Keywords: Key words Groundwater ; Geochemistry ; Stable-isotopes ; Resources
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract  In the spring of 1995, 24 samples were collected from a widely distributed system of municipal water wells in Albuquerque, N.M., and analyzed for hydrogen (δD) and oxygen (δ18O) isotopic compositions. δD values for 15 of these samples are largely similar to those reported by Yapp in 1985, but have locally become more negative by as much as 5 per mil (ö). δD–δ18O data define two endmembers that are well aligned along the familiar meteoric water line (MWL): (1) the eastern domain (mountain precipitation runoff), having δD〉–86ö (similar to the criteria of Yapp) and δ18O〉–12.1ö (this work); and (2) a central basin domain, which may be in part derived from water seepage from the Rio Grande, having δD〈–95ö and δ18O〈–13.2ö. Only a few wells across the basin have δD values near the "baseline" value of the Rio Grande, defined by Yapp as –92ö. The proximity of these wells to the Rio Grande is consistent with recharge by seepage from the river bed under baseline conditions. Extensive pumping in the eastern domain and West Mesa areas may be partly responsible for an apparent expansion of the central-basin regime of water more depleted in δD, much as a plume migrating in response to transient perturbations in original hydraulic gradients. Vertically stacked groundwater occurrences having limited interconnection are inferred from the significant differences in isotopic compositions of samples from two wells screened at multiple depths. The central and western parts of the basin are little influenced by contributions from the eastern domain. Some groundwaters from the western part of the basin plot below the MWL and clearly cannot be mixtures solely of the eastern domain and central basin endmembers. The origins of these western groundwaters and the most depleted central basin groundwaters are as yet unknown, but we speculate they may have received recharge under climatic conditions different from the present.
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    Distribution of heavy metals in the Piscinas beach sediments (SW Sardinia, Italy) (1999)
    Springer
    Environmental geology 38 (1999), S. 91-100 
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    ISSN: 1432-0495
    Keywords: Key words Sediments ; Mineralogy ; Geochemistry ; Heavy metals ; Biogeochemistry
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract We have studied sediments of the Piscinas beach (SW Sardinia, Italy), which is supplied by two streams that wash mine dumps of abandoned lead and zinc mines at Montevecchio and Ingurtosu, situated inland from the supply basin of the beach itself. A study of the texture, mineralogy and geochemistry of the sediments was conducted for the purpose of assessing the possible influence of the mine waste on the composition of the sediments, looking for any anomalous enrichments in heavy metals. Furthermore, to evaluate and quantify metal release into the sea, samples of Posidonia oceanica, a bioaccumulator marine plant, were also examined. The results indicate that the distribution of heavy metals in the foreshore sediments is particularly affected by the contribution of the streams, while in the shoreface the distribution is affected by the currents that disperse the sediments both out to sea and southwards. The metal contents of the Posidonia oceanica are correlated with the different stages of activity of the mines.
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    Radon emanation from giant landslides of Koefels (Tyrol, Austria) and Langtang Himal (Nepal) (1995)
    Springer
    Environmental geology 26 (1995), S. 32-38 
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    ISSN: 1432-0495
    Keywords: Radon ; Geochemistry ; Landslides ; Brittle deformation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract The identification of extremely high indoor radon concentrations in the village Umhausen (Tyrol, Austria) initiated a scientific program to get information about the source and distribution of this noble gas. The high concentrations can not be related to U anomalies or large-scale fault zones. The nearby giant landslide of Koefels, with its highly fractured and crushed orthogneisses, are the only possible source of radon, despite the fact that the U and Ra content of the rocks is by no means exceptional. The reasons for the high emanation rates from the landslide are discussed and compared to results gained from a similar examination of the giant landslide of Langtang Himal (Nepal). The exceptional geologic situation in both cases, as well as the spatial distribution of different concentration levels, indicate that both landslides must be considered as the production sites of radon. Independent of the U and Ra contents of the rocks, the most important factors producing high emanation rates are the production of a high active surface area and circulation pathways for Rn-enriched soil air by brittle deformation due to the impact of the landslidemass.
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    Texture and geochemistry of the sediments of a tropical mangrove ecosystem, southwest coast of India (1996)
    Springer
    Environmental geology 27 (1996), S. 164-169 
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    ISSN: 1432-0495
    Keywords: Sedimentation ; Geochemistry ; Mangrove environment
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract The textural and geochemical aspects of the sediments of a tropical mangrove ecosystem have been studied and discussed. The sediments are characterized by the abundance of silt and sand with minor amounts of clay. The mean size of the sediment ranges from 0.205 mm to 0.098 mm (fine to very fine grained sand). The sediments are very poorly sorted, negatively to very negatively skewed, and platy to extremely leptokurtic in nature. The organic carbon content of the sediments ranges from 0,33% to 4.93%, which is controlled by the particle size of the sediments. The CaCO3 content is five times the enrichment of organic carbon. This enhanced CaCO3 content of the mangrove sediments might be a result of the abundance of shell fragments in the sediments. The shell mining activities in the estuarine bed adjoining the Kumarakam mangroves also contribute a substantial amount of lime muds to the mangrove area, which in turn add CaCO3 to the sediments. The relative concentrations of heavy metals are Fe 〉 Mn 〉 Cr 〉 Zn 〉 Ni 〉 Cu. All heavy metals other than Fe show an increase in concentration compared to the other parts of the estuarine bed. Cluster analysis indicates that the contents of organic C, Fe and Mn have a marked bearing on the Cr, Zn, Ni, and Cu levels of the mangrove sediments.
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    URL: http://dx.doi.org/10.1007/BF00770428
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    Natural and anthropogenic influences on the geochemistry of Quaternary lake sediments from Holzmaar, Germany (1997)
    Springer
    Environmental geology 31 (1997), S. 236-247 
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    ISSN: 1432-0495
    Keywords: Key words Lake sediments ; Heavy metals ; Geochemistry ; Element fluxes
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract  The accumulation of heavy metals and trace elements has been investigated in a well laminated sequence of Holocene and late Pleistocene lake sediments composed of diatomaceous gyttja, tuff and silt and clay sediments. Varve chronology of the annually deposited gyttja yielded a continuous high-resolution time sequence and allowed the absolute age dating of the sediment. Fluxes of elements remained largely uniform from the late Pleistocene into the Holocene (12 867–2 364 VT years ago; VT: varve time, years before 1950). Higher trace element and heavy metal fluxes occur from 2 322 to 862 VT years ago and reached their maxima in the uppermost sediments (〈845 VT years ago). These increasing element fluxes correlate with increasing inputs of clastic material. The changing accumulation rates are the result of elevated soil erosion in the lake catchment caused by human settlement, deforestation and agricultural activities. Thus disturbances of the natural geochemical cycles of the Holzmaar region have occurred since the beginning of the Iron Age and especially since the beginning of the Middle Ages.
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    URL: http://dx.doi.org/10.1007/s002540050185
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    Pore water geochemistry near the sediment-water interface of a zoned, freshwater wetland in the southeastern United States (1998)
    Springer
    Environmental geology 33 (1998), S. 143-153 
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    ISSN: 1432-0495
    Keywords: Key Words Sediment ; Pore water ; Iron ; Geochemistry ; Redox
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract  Sediment and its associated pore water were collected from a zoned, freshwater, riparian wetland, located in the Talladega National Forest, northeastern Hale County, Alabama, to study the porewater chemistry and its spatial changes within and between the wetland ecological zones. Obvious changes in pH, Eh and element concentrations were observed between the different wetland ecological zones. Major cations (Ca, Mg, and Na) and trace elements (B, Ba, Sr, and Mn) have very good spatial correlation with Fe and Mn distributions, both in the pore water and the sediment, suggesting that adsorption on, and desorption from, iron and manganese oxyhydroxides are important processes controlling the distributions of these elements in the wetland sediment. However, an equilibrium adsorption model is not able to explain the distribution of trace elements between the pore water and sediment. A redox kinetic model gives similar vertical profiles for iron and the correlated elements as those measured in the field and thus suggests that the relative rates of ferrous iron oxidation and the reductive dissolution of ferric iron in the sediment are important variables determining the distributions of these elements in the wetland pore waters.
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    URL: http://dx.doi.org/10.1007/s002540050234
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    Geochemical characterization of a karst polje – an example from Sinjsko polje, Croatia (1998)
    Springer
    Environmental geology 33 (1998), S. 263-273 
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    ISSN: 1432-0495
    Keywords: Key words Karst poljes ; Geochemistry ; Trace elements ; Soil ; Factor analysis ; Dinaric Karst ; Sinjsko polje ; Croatia
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract  The poljes of the Adriatic Coast are rather special features whose like is not found anywhere else in the world. The delineation of this unique landform feature by its geochemical characteristics has been attempted by using examples from Sinjsko polje, which represents a typical karst polje in the Adriatic Coast, or the area of the Dinaric Karst. Factor analysis was performed on 96 samples collected in a regular grid of 1×1 km which covered the entire area of the Sinjsko polje valley. Another factor analysis was performed in a regular grid of 5×5 km that comprised 41 samples in the karstic environment. In this manner two factor models were created and closely inspected for possible differences due to the peculiar properties arising from two geochemically different environments. Within the polje itself it was possible to evaluate three factors, while four factors were identified to be significant for the explanation of the geochemical structure of data assessed in the regular 5×5-km grid. This grid includes the area of Sinjsko polje and its wider neighborhood. The Ba/Sr index reveals striking differences in drainage patterns between the polje itself and the surrounding area.
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    URL: http://dx.doi.org/10.1007/s002540050245
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    Heavy metal pollution of coastal river sediments, north-eastern New South Wales, Australia: lead isotope and chemical evidence (1998)
    Springer
    Environmental geology 36 (1998), S. 118-126 
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    ISSN: 1432-0495
    Keywords: Key words River sediments ; Heavy metals ; Lead isotopes ; Geochemistry
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract  Heavy metal and metalloid concentrations within stream-estuary sediments (〈180-μm size fraction) in north-eastern New South Wales largely represent natural background values. However, element concentrations (Ag, As, Cd, Cr, Cu, Hg, Ni, Pb, Sb, Zn) of Hunter River sediments within the heavily industrialized and urbanized Newcastle region exceed upstream background values by up to one order of magnitude. High element concentrations have been found within sediments of the Newcastle Harbour and Throsby Creek which drains into urbanized and light industry areas. Observed Pb enrichments and low 208Pb/204Pb, 207Pb/204Pb and 206Pb/204Pb ratios are likely caused by atmospheric deposition of Pb additives from petrol and subsequent Pb transport by road run-off waters into the local drainage system. Sediments of the Richmond River and lower Manning, Macleay, Clarence, Brunswick and Tweed River generally display no evidence for anthropogenic heavy metal and metalloid contamination (Ag, As, Cd, Cr, Cu, Hg, Ni, Pb, Sb, Zn). However, the rivers and their tributaries possess localized sedimentary traps with elevated heavy metal concentrations (Cu, Pb, Zn). Lead isotope data indicate that anthropogenic Pb provides a detectable contribution to investigated sediments. Such contributions are evident at sample sites close to sewage outlets and in the vicinity of the Pacific Highway. In addition, As concentrations of Richmond River sediments gradually increase downstream. This geochemical trend may be the result of As mobilization from numerous cattle-dip sites within the region into the drainage system and subsequent accumulation of As in downstream river and estuary sediments.
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    URL: http://dx.doi.org/10.1007/s002540050327
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    Spatial distribution of major and trace elements in shallow reservoir sediments: an example from Lake Waco, Texas (1998)
    Springer
    Environmental geology 36 (1998), S. 349-363 
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    ISSN: 1432-0495
    Keywords: Key words Trace elements ; Reservoir sediments ; Geochemistry ; Sediment source
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract  Sediment geochemistry of a shallow (6-m average) reservoir (Lake Waco) was evaluated for the spatial distribution of major and trace elements. Sixty bottom and core samples along a 21-km transect within the reservoir, 18 overbank sediment samples, and 8 rock types in the drainage area were collected and analyzed for major (Al, Ca, Fe) and trace elements (As, Ba, Cr, Cu, Hg, Mn, Ni, Pb, Sr, V, Zn). Elemental concentrations in the reservoir sediments closely correspond to concentrations in the regional rocks and represent a mixture of overbank sediment composition of the tributaries. Elemental concentrations were statistically regressed against Al concentrations in order to establish regional baseline levels and thereby distinguish natural from anthropogenic sources. Spatial geochemical trends, considered in terms of element-to-Al ratio versus V-to-Al ratio, relate to the natural and anthropogenic sources contributing to the elemental concentrations. The spatial elemental distribution in the reservoir, which receive sediments from two mineralogically contrasting basins, reflect textural and mineralogical transition within the reservoir and suggest a progressive mixing of sediment from the tributaries. The spatial elemental distribution and sediment texture suggest that the sediment-source, which determines the sediment-type, has a greater influence on the major- and trace-element distributions in shallow reservoir sediments than bathymetry.
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    Environmental geochemistry of the Pichavaram mangrove ecosystem (tropical), southeast coast of India (1999)
    Springer
    Environmental geology 37 (1999), S. 223-233 
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    ISSN: 1432-0495
    Keywords: Key words Mangrove ; Geochemistry ; Biological productivity ; Anthropogenic impacts ; Heavy metal sink
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract  Spatial and temporal geochemical variations of various parameters in the water and sediment of a relatively small mangrove situated on the southeast coast of India were examined in detail for the first time. The water quality generally reflects the impact of seawater and the Vellar estuary (mixing effect) aided by evaporation and in situ biological productivity. The depletion and fluctuation of dissolved silica are controlled by biological processes. Nitrate and phosphate are contributed by fertilizer input from adjoining agriculture fields. Total suspended matter (TSM) shows an erratic range and trend due to deforestation and resuspension processes. Sand and silt constitute 70–90% of the sediments. Statistical analysis of the sediments shows the prevalence of a moderately high-energy environment with very effective winnowing activity. Organic matter content is higher in the mangrove sediments in comparison to adjacent estuaries. Water and sediment show fluctuations in their chemical concentration, but no specific trends could be identified. Heavy metals are also enriched in the mangrove sediments, indicating their unique chemical behavior and the existence of trapping mechanisms. Factor analysis and correlation analysis of water and sediments show the complexity of the system and the multitude of contributing sources. The core sediment chemistry suggests the depletion of metal input due to the damming of the detrital inputs. The Pichavaram mangrove seems to be relatively unpolluted, since the anthropogenic signal observed is small and acts as a sink for heavy metals contributed from a multitude of sources without an adverse effect.
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    Geochemistry of Fe and Mn in surficial sediments of a tropical river and estuary, India—a granulometric approach (1995)
    Springer
    Environmental geology 25 (1995), S. 270-276 
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    ISSN: 1432-0495
    Keywords: Sedimentation ; Geochemistry ; Tropical river ; Physical fractionation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract Geochemical characteristics of Fe and Mn in sand, silt, and clay fractions as well as in bulk sediments of the tropical perennial Muvattupuzha river and the Central Vembanad estuary of the southwest coast of India have been studied and discussed. The results of a physical fractionation study of Fe and Mn indicated a substantial increase in the content of these metals in silt and clay fractions above that in sand. The riverine silt and clay fractions account for two to three times the enrichment of Fe and Mn than the corresponding sand fraction; the estuarine counterparts indicate four to eight times the enrichment. The observed enrichment of Fe and Mn towards the more finer size grades is mainly due to the increased surface area of the finer clastics, which in turn increase the absorptive ability. However, the mineralogical diversities of the three size fractions also influence the enrichment of Fe and Mn. The spatial distribution of Fe and Mn indicates a marked decrease in the content of the latter than the former towards the high saline zones of the river and the estuary. This variation could be due to the higher solubility of Mn towards the high saline zones of the aquatic environment where reducing condition prevails most of the year.
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    Texture and geochemistry of the sediments of a tropical mangrove ecosystem, southwest coast of India (1996)
    Springer
    Environmental geology 27 (1996), S. 164-169 
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    ISSN: 1432-0495
    Keywords: Key words Sedimentation ; Geochemistry ; Mangrove environment
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract The textural and geochemical aspects of the sediments of a tropical mangrove ecosystem have been studied and discussed. The sediments are characterized by the abundance of silt and sand with minoramounts of clay. The mean size of the sediment ranges from 0.205 mm to 0.098 mm (fine to very fine grained sand). The sediments are very poorly sorted, negatively to very negatively skewed, and platy to extremely leptokurtic in nature. The organic carbon content of the sediments ranges from 0.33% to 4.93%, which is controlled by the particle size of the sediments. The CaCO3 content is five times the enrichment of organic carbon. This enhanced CaCO3 content of the mangrove sediments might be a result of the abundance of shell fragments in the sediments. The shell mining activities in the estuarine bed adjoining the Kumarakam mangroves also contribute a substantial amount of lime muds to the mangrove area, which in turn add CaCO3 to the sediments. The relative concentrations of heavy metals are Fe〉Mn〉Cr〉Zn〉Ni〉Cu. All heavy metals other than Fe show an increase in concentration compared to the other parts of the estuarine bed. Cluster analysis indicates that the contents of organic C, Fe and Mn have a marked bearing on the Cr, Zn, Ni, and Cu levels of the mangrove sediments.
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    Geochemistry and stratigraphic correlation of basalt lavas beneath the Idaho Chemical Processing Plant, Idaho National Engineering Laboratory (1997)
    Springer
    Environmental geology 30 (1997), S. 108-118 
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    ISSN: 1432-0495
    Keywords: Key words Stratigraphy ; Basalt ; Geochemistry ; Snake River Plain aquifer ; Idaho National Engineering Laboratory
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract  Thirty-nine samples of basaltic core were collected from wells 121 and 123, located approximately 1.8 km apart north and south of the Idaho Chemical Processing Plant at the Idaho National Engineering Laboratory. Samples were collected from depths ranging from 15 to 221 m below land surface for the purpose of establishing stratigraphic correlations between these two wells. Elemental analyses indicate that the basalts consist of three principal chemical types. Two of these types are each represented by a single basalt flow in each well. The third chemical type is represented by many basalt flows and includes a broad range of chemical compositions that is distinguished from the other two types. Basalt flows within the third type were identified by hierarchical K-cluster analysis of 14 representative elements: Fe, Ca, K, Na, Sc, Co, La, Ce, Sm, Eu, Yb, Hf, Ta, and Th. Cluster analyses indicate correlations of basalt flows between wells 121 and 123 at depths of approximately 38–40 m, 125–128 m, 131–137 m, 149–158 m, and 183–198 m. Probable correlations also are indicated for at least seven other depth intervals. Basalt flows in several depth intervals do not correlate on the basis of chemical compositions, thus reflecting possible flow margins in the sequence between the wells. Multi-element chemical data provide a useful method for determining stratigraphic correlations of basalt in the upper 1–2 km of the eastern Snake River Plain.
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    Prediction method of sand-movement direction in water by geochemical elements (1995)
    Springer
    Environmental geology 25 (1995), S. 100-108 
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    ISSN: 1432-0495
    Keywords: Sand movement ; Geochemistry ; Fluorescent spectroscopy
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract The analysis of sand samples by x-ray fluorescent spectroscopy (XRF) gives the ratio of the geochemical elements to construct the sand samples. The x-ray analysis therefore shows the geochemical characteristics of sand in the sampled area. In this study, sand is sampled on coasts and rivers of the Noto Peninsula to determine the geochemical elements and to show the geological characteristics that occur, especially iron and calcium. The experiments show the effect of rivers and Kotogahama beach on iron and calcium, respectively. Applying the method of ratio matching to the measured data of the geochemical elements, the direction of movement of sand on the coast is determined by considering the correlation matrix and the ratio of geochemical elements between sand samples at two locations. The predominant longshore direction movement of sand offshore in the study area is from south to north. Sand in rivers is not directly transported to adjacent beaches; however, offshore sand is transported to beaches. The estimated direction of movement of sand longshore near coastal structures agrees with observations. The proposed method to predict the direction of movement of sand gives the correct one in comparison with the observed data in rivers.
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    Surface analysis of particles in mine tailings by time-of-flight laser-ionization mass spectrometry (TOF-LIMS) (1997)
    Springer
    Environmental geology 32 (1997), S. 107-113 
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    ISSN: 1432-0495
    Keywords: Key words Mine tailings ; TOF-LIMS ; Geochemistry ; Surface analysis ; Laser-ionization
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract   Time-of-flight laser-ionization mass spectrometry was applied to study the chemical composition of mineral particle surfaces in a sulphide-rich mine-tailings impoundment. This surface-sensitive technique provides chemical information from surfaces of irregularly shaped mineral particles (both conductive and insulators) less than 100 μm in diameter, which are considered to be representative of particle surface coatings in the tailings pile (after drying). In addition, depth profiles in the mineral particles were obtained. The combination of speed of analysis (1 min), small beam-diameter (2–4 μm), surface sensitivity (2–10 nm), trace-element sensitivity, and capability to analyze rough surfaces makes this method useful as a complement to studies of pore-water geochemistry and tailings mineralogy. As an example, the behavior of Pb and As in the Kidd Creek tailings dam near Timmins, Ontario, Canada, was studied, using a combination of surface analyses, and pore-water geochemical data.
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    Research on limestone decay in a polluting environment, I˙stanbul-Turkey (1999)
    Springer
    Environmental geology 38 (1999), S. 149-158 
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    ISSN: 1432-0495
    Keywords: Key words Limestone ; Weathering ; Historical buildings ; Petrographical characteristics ; Geochemistry ; Physical properties
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract  I˙stanbul, the capital of the east Roman, Byzantine and Ottoman Empires embraces two continents, one arm reaching out to Asia, the other to Europe. It is therefore, a rich city in terms of monuments and historical cites. Shell limestones of Upper Miocene age are used as building stone in the majority of the monuments in I˙stanbul because of their attractiveness, availability and workability. The durability characteristics of the limestones are examined, and those factors that are responsible for atmospheric weathering are discussed, in a humid and marine environment with important problems of urban pollution, specifically due to traffic. In the present study weathering of the building stones were first examined in situ by macroscopic observations. The weathering that developed as a result of environmental effects since this limestone was first used in historical monuments has been affected 0.1–1.5 cm deep from the surface. The weathered facing stone of Şehzade Mehmed Mosque in I˙stanbul is undergoing a program of progressive replacement. During this study, samples were taken from this monument where the shell limestone was used. The stone surface was principally examined by means of Scanning Electron Microscopy (SEM). Petrographical and mineralogical analyses were made by using optical microscopy and X-ray diffraction method. The physico-chemical properties of these rocks control their weathering behaviour and reactivity. Major and trace element analyses and the effect of deterioration on the physical properties of the limestones (unit weight, porosity and water absorption) have also been investigated. Studies on the samples implies that weathering on the stone surface caused important variations on the physical characteristics of the rock.
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    Crystal retention, fractionation and crustal assimilation in a convecting magma chamber, Nisyros Volcano, Greece (1995)
    Springer
    Bulletin of volcanology 56 (1995), S. 601-620 
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    ISSN: 1432-0819
    Keywords: Key words Calc-alkaline volcanism ; Geochemistry ; Isotopic study ; Petrology ; Magmatic evolution ; Aegean Arc ; Nisyros volcano
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract  Nisyros island is a calc-alkaline volcano, built up during the last 100 ka. The first cycle of its subaerial history includes the cone-building activity with three phases, each characterized by a similar sequence: (1) effusive and explosive activity fed by basaltic andesitic and andesitic magmas; and (2) effusive and extrusive activity fed by dacitic and rhyolitic magmas. The second eruptive cycle includes the caldera-forming explosive activity with two phases, each consisting of the sequence: (1) rhyolitic phreatomagmatic eruptions triggering a central caldera collapse; and (2) extrusion of dacitic–rhyolitic domes and lava flows. The rocks of this cycle are characterized by the presence of mafic enclaves with different petrographic and chemical features, which testify to mixing–mingling processes between variously evolved magmas. Jumps in the degree of evolution are present in the stratigraphic series, accompanied by changes in the porphyritic index. This index ranges from 60% to about 5% and correlates with several geochemical parameters, including a negative correlation with Sr isotope ratios (0.703384–0.705120). The latter increase from basaltic andesites to intermediate rocks, but then slightly decrease in the most evolved volcanic rocks. The petrographic, geochemical and isotopic characteristics can be largely explained by processes occurring in a convecting, crystallizing and assimilating magma chamber, where crystal sorting, retention, resorption and accumulation take place. A group of crystal-rich basaltic andesites with high Sr and compatible element contents and low incompatible elements and Sr isotope ratios probably resulted from the accumulation of plagioclase and pyroxene in an andesitic liquid. Re-entrainment of plagioclase crystals in the crystallizing magma may have been responsible for the lower 87Sr/86Sr in the most evolved rocks. The gaps in the degree of evolution with time are interpreted as due to liquid segregation from a crystal mush once critical crystallinity was reached. At that stage convection halted, and a less dense, less porphyritic, more evolved magma separated from a denser crystal-rich magma portion. The differences in incompatible element enrichment of pre- and post-caldera dacites and the chemical variation in the post-caldera dome sequence are the result of hybridization of post-caldera dome magmas with more mafic magmas, as represented by the enclave compositions. The occurrence of the quenched, more mafic magmas in the two post-caldera units suggests that renewed intrusion of mafic magma took place after each collapse event.
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    The character of long-term eruptions: inferences from episodes 50–53 of the Pu'u 'Ō'ō-Kūpaianaha eruption of Kīlauea Volcano (1998)
    Springer
    Bulletin of volcanology 59 (1998), S. 381-393 
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    ISSN: 1432-0819
    Keywords: Key words Kīlauea ; Pu'u 'Ō'ō-Kūpaianaha ; Basaltic eruption ; Lava shield ; Lava pond ; Geochemistry
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract  The Pu'u 'Ō'ō-Kūpaianaha eruption on the east rift zone of Kīlauea began in January 1983. The first 9 years of the eruption were divided between the Pu'u 'Ō'ō (1983–1986) and Kūpaianaha (1986–1992) vents, each characterized by regular, predictable patterns of activity that endured for years. In 1990 a series of pauses in the activity disturbed the equilibrium of the eruption, and in 1991, the output from Kūpaianaha steadily declined and a short-lived fissure eruption broke out between Kūpaianaha and Pu'u 'Ō'ō. In February 1992 the Kūpaianaha vent died, and, 10 days later, eruptive episode 50 began as a fissure opened on the uprift flank of the Pu'u 'Ō'ō cone. For the next year, the eruption was marked by instability as more vents opened on the flank of the cone and the activity was repeatedly interrupted by brief pauses in magma supply to the vents. Episodes 50–53 constructed a lava shield 60 m high and 1.3 km in diameter against the steep slope of the Pu'u 'Ō'ō cone. By 1993 the shield was pockmarked by collapse pits as vents and lava tubes downcut as much as 29 m through the thick deposit of scoria and spatter that veneered the cone. As the vents progressively lowered, the level of the Pu'u 'Ō'ō pond also dropped, demonstrating the hydraulic connection between the two. The downcutting helped to undermine the prominent Pu'u 'Ō'ō cone, which has diminished in size both by collapse, as a large pit crater formed over the conduit, and by burial of its flanks. Intervals of eruptive instability, such as that of 1991–1993, accelerate lateral expansion of the subaerial flow field both by producing widely spaced vents and by promoting surface flow activity as lava tubes collapse and become blocked during pauses.
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    Volcanology of the 2350 B.P. Eruption of Mount Meager Volcanic Complex, British Columbia, Canada: implications for Hazards from Eruptions in Topographically Complex Terrain (1999)
    Springer
    Bulletin of volcanology 60 (1999), S. 489-507 
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    ISSN: 1432-0819
    Keywords: Key words Mount Meager ; Volcanic stratigraphy ; Pyroclastic flow ; Lahar ; Avalanche ; Petrography ; Geochemistry
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract  The Pebble Creek Formation (previously known as the Bridge River Assemblage) comprises the eruptive products of a 2350 calendar year B.P. eruption of the Mount Meager volcanic complex and two rock avalanche deposits. Volcanic rocks of the Pebble Creek Formation are the youngest known volcanic rocks of this complex. They are dacitic in composition and contain phenocrysts of plagioclase, orthopyroxene, amphibole, biotite and minor oxides in a glassy groundmass. The eruption was episodic, and the formation comprises fallout pumice (Bridge River tephra), pyroclastic flows, lahars and a lava flow. It also includes a unique form of welded block and ash breccia derived from collapsing fronts of the lava flow. This Merapi-type breccia dammed the Lillooet River. Collapse of the dam triggered a flood that flowed down the Lillooet Valley. The flood had an estimated total volume of 109 m3 and inundated the Lillooet Valley to a depth of at least 30 m above the paleo-valley floor 5.5 km downstream of the blockage. Rock avalanches comprising mainly blocks of Plinth Assemblage volcanic rocks (an older formation making up part of the Mount Meager volcanic complex) underlie and overlie the primary volcanic units of the Formation. Both rock avalanches are unrelated to the 2350 B.P. eruption, although the post-eruption avalanche may have its origins in the over-steepened slopes created by the explosive phase of the eruption. Much of the stratigraphic complexity evident in the Pebble Creek Formation results from deposition in a narrow, steep-sided mountain valley containing a major river.
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    High-West and Low-East Distribution Patterns of Chlorophyll a, Primary Productivity and Diatoms in the Subarctic North Pacific Surface Waters, Midwinter 1996 (1999)
    Springer
    Journal of oceanography 55 (1999), S. 493-503 
    Details
    ISSN: 1573-868X
    Keywords: Chlorophyll a ; primary productivity ; diatoms ; Thalassiosira ; cast and west distribution pattern ; midwinter ; subarctic North Pacific ; naked ciliates ; copepods
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract We have determined chlorophyll a (Chla) concentration, primary productivity, cell density and species composition of diatoms, and the number of microzooplankton at the surface in the subarctic North Pacific in January 1996. The wet weight of copepods obtained by vertical tows from 150 m to the surface was also measured during the cruise. Chla concentration and primary productivity tended to be higher in the region west of 180°, the western subarctic North Pacific (WSNP), than east of 180°, the eastern subarctic North Pacific (ESNP). The same results were observed for the total diatom cell densities and for the genera Thalassiosira and Denticulopsis. Significant linear relationships were observed between the Thalassiosira cell density and Chla concentration and primary productivity, indicating that Thalassiosira contributes to the high-WSNP and low-ESNP distribution patterns of Chla concentration and primary productivity. Moreover, naked ciliate abundance tended to be lower in the WSNP than in the ESNP, whereas copepod biomass showed an inverse trend. Significantly negative Spearman rank correlations were found between the Thalassiosira cell density and the number of naked ciliates and between the number of naked ciliates and the wet weight of copepods. These results indicate that copepod grazing indirectly controls Thalassiosira cell density via predation on the naked ciliates. We conclude that the high copepod biomass in the WSNP is a factor controlling the high-WSNP and low-ESNP Thalassiosira abundance and hence Chla concentration and primary productivity patterns.
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    URL: http://dx.doi.org/10.1023/A:1007835306413
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    Geochemistry of early Palaeozoic amphibolites from the Orlica-Śnieżnik dome, Bohemian massif: petrogenesis and palaeotectonic aspects (1996)
    Springer
    Geologische Rundschau 85 (1996), S. 225-238 
    Details
    ISSN: 0016-7835
    Keywords: Key words L. Palaeozoic volcanics ; Amphibolites ; Geochemistry ; Petrogenesis ; Crustal contamination ; Palaeotectonic environment ; Orlica-Śnieżnik dome ; Bohemian massif
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract  Orthoamphibolites within and marginal to the Orlica-Śnieżnik dome in the eastern Bohemian massif are associated with a series of Proterozoic-Lower Palaeozoic supracrustal meta-sediments of the Stronie, Nové Město and Staré Město formations. Massive and variably foliated amphibolites range from common epidote–plagioclase–blue-green/green hornblende varieties to assemblages with diopside, garnet and brown amphibole. All the amphibolites have a basaltic composition and are divided into three main chemical groups which are intimately associated in the field: main series tholeiites, low-Ti tholeiites and alkali basalts. All groups exhibit a common enrichment in LIL elements+Nb+Ta (relative to high-field-strength elements) which reflects contamination by upper continental crust and/or pelagic sediment compositions. The gross chemistry of the tholeiites approaches that for MORB, although the geological environment and nature of crustal contamination suggests that the basaltic precursors were probably emplaced in a rifted ensialic basinal environment. If the amphibolites are representative of an early phase of the Lower Palaeozoic fragmentation of Gondwanaland, then rifting did not fully develop ocean crust. The wider significance of the chemical interpretation implies that some of the variation from Variscan Proterozoic-Palaeozoic metabasite suites that is ascribed to a complex of different eruptive settings could be accounted for by variable contamination and/or source composition.
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    URL: http://dx.doi.org/10.1007/s005310050070
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    Acidification of groundwater in water-filled gravel pits -- a new environmental and geomedical threat (1997)
    Springer
    Environmental geochemistry and health 19 (1997), S. 111-127 
    Details
    ISSN: 1573-2983
    Keywords: Geochemistry ; chemical weathering ; sulphide ; sulphuric acid ; jarosite ; groundwater ; geomedicine ; Finland
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Medicine
    Notes: Abstract Swimmers and users of motor boats frequenting old, water-filled gravel pits in Kiiminki, Northern Finland, found in August 1993 that they were suffering from painful irritation of the eyes and that their boats had developed a finely polished surface on their aluminium hulls, evidently due to the corrosive action of the water. Subsequent measurements carried out by the water authority showed that the pH of the water in some of the pits was extremely low, reaching a value of 3.4 at its lowest. To find out the causes of the abnormally low pH values, the present authors began systematic measurements of the pH and determination of the chemical composition (Si, Al, Ca, Mg, K, Na, Fe, Mn, Cu, Pb, Ni, Cd, Cl-, NO3 -, SO4 2-) of the water in 23 gravel pits. In addition, a series of laboratory experiments was carried out to examine the interaction of water with samples of the soil and bedrock of the area to evaluate the role of this process as a possible cause of the acidification. The results show that the reaction of water with the moderately to intensively weathered sulphide and jarosite-bearing black schists, typical of the bedrock of the area, can bring about aqueous solutions similar in pH and sulphate--nitrate ratios to those found naturally in the gravel pits. The contribution of other possible mechanisms, e.g. acidic precipitation as such or combined with enhanced evaporation, the possible use of the pits as dumping sites for acidic waste or the flow or seepage of acidic peat-bog waters into the pits from the surrounding wetlands, cannot be ruled out entirely, but their contribution seems to be of minor importance. Since the concentrations of several heavy metals (notably Pb, Cd, Ni, Fe and Mn) and of sulphate and aluminium has increased in the pit water as a result of the acidification process and exceed the norms laid down in the EU Drinking Water Directive, acidification of water in gravel pits due to the oxidation of sulphides must be regarded as a new, serious environmental and geomedical threat which has so far remained poorly known or unrecognised.
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    URL: http://dx.doi.org/10.1023/A:1018454622669
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    Granitoids in the Rozvadov Pluton, Western Bohemia and Oberpfalz (1995)
    Springer
    Geologische Rundschau 84 (1995), S. 506-519 
    Details
    ISSN: 0016-7835
    Keywords: Key words Peraluminous granite ; Rare-metal granite ; Western Bohemia ; Oberpfalz ; Geochemistry ; Cordierite
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract  The Rozvadov Pluton is a complex of mainly Variscan granitoid rocks situated near the Bohemian-Bavarian border between Bärnau, Tachov, Rozvadov and Waidhaus, 25 km ESE of the KTB site. Five mappable units can be distinguished, which intruded as follows: (1) slightly deformed leucocratic meta-aplite/metapegmatite dykes with garnet and tourmaline; (2) a complex of cordierite-bearing granitoids, which have been divided into three facies (a) biotite granite with cordierite (at the margin of the complex), (b) biotite–cordierite granite and (c) cordierite tonalite (in the centre of the complex; (3) fine-grained biotite granite of the Rozvadov type with associated pegmatite bodies; (4) two-mica Bärnau granite; and (5) geochemically specialized albite–zinnwaldite–topaz granite (Křížový kámen/Kreuzstein granite) with indications of Sn–Nb–Ta mineralization and associated phosphorus-rich pegmatite cupolas. Rare earth element data suggest that meta-aplite/pegmatite dykes are the result of a batch partial melting process, whereas the compositional variation of the other rock types was mainly controlled by fractional crystallization. The genesis of the cordierite granitoid suite is best explained in terms of a batch melting of metapelitic source followed by crystallization of a cordierite-rich cumulate and K-feldspar enriched melt. The leucocratic pluton constituents – the meta-aplites and the Bärnau and Křížový kámen granites – are rich in phosphorus (0.5–0.8%). The main carriers of phosphorus are alkali feldspars, especially K-feldspar (up to 0.8% P2O5). The presence of P-rich leucocratic granites is one of the features distinguishing the Variscan granitoids within the Moldanubian zone from the nearly contemporaneous granitoids in the Saxothuringian zone.
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    URL: http://dx.doi.org/10.1007/BF00284517
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    Garnet pyroxenite and eclogite in the Bohemian Massif: geochemical evidence for Variscan recycling of subducted lithosphere (1995)
    Springer
    Geologische Rundschau 84 (1995), S. 489-505 
    Details
    ISSN: 0016-7835
    Keywords: Key words Bohemian Massif ; Variscan ; Geochemistry ; Garnet pyroxenite ; Eclogite ; Lithosphere
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract  High-temperature, high-pressure eclogite and garnet pyroxenite occur as lenses in garnet peridotite bodies of the Gföhl nappe in the Bohemian Massif. The high-pressure assemblages formed in the mantle and are important for allowing investigations of mantle compositions and processes. Eclogite is distinguished from garnet pyroxenite on the basis of elemental composition, with mg number 〈80, Na2O〉0.75 wt.%, Cr2O3〈0.15 wt.% and Ni〈400 ppm. Considerable scatter in two-element variation diagrams and the common modal layering of some eclogite bodies indicate the importance of crystal accumulation in eclogite and garnet pyroxenite petrogenesis. A wide range in isotopic composition of clinopyroxene separates [εNd, +5.4 to –6.0; (87Sr/86Sr)i, 0.70314–0.71445;δ18OSMOW, 3.8–5.8ö] requires that subducted oceanic crust is a component in some melts from which eclogite and garnet pyroxenite crystallized. Variscan Sm-Nd ages were obtained for garnet-clinopyroxene pairs from Dobešovice eclogite (338 Ma), Úhrov eclogite (344 Ma) and Nové Dvory garnet pyroxenite (343 Ma). Gföhl eclogite and garnet pyroxenite formed by high-pressure crystal accumulation (±trapped melt) from transient melts in the lithosphere, and the source of such melts was subducted, hydrothermally altered oceanic crust, including subducted sediments. Much of the chemical variation in the eclogites can be explained by simple fractional crystallization, whereas variation in the pyroxenites indicates fractional crystallization accompanied by some assimilation of the peridotite host.
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    Petrology and geochemistry of post–kinematic mafic rocks from the Paleoproterozoic Ubendian belt, NE Katanga (Democratic Republic of Congo) (1998)
    Springer
    Geologische Rundschau 87 (1998), S. 345-362 
    Details
    ISSN: 0016-7835
    Keywords: Key words Ubendian ; Paleoproterozoic ; Post-orogenic ; Continental tholeiites ; Geochemistry ; Asthenosphere ; Lithosphere ; Subduction enrichment ; Congo
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract The Paleoproterozoic post-kinematic Ubendian mafic rocks from northeastern Katanga (Democratic Republic of Congo) are olivine-and-quartz tholeiites which in many respects resemble Phanerozoic continental tholeiites. The analogies are suggested by the petrographic features and the major element diagrams classically used to infer magmatic affinity. The clinopyroxene compositions straddle the boundary between clinopyroxenes from orogenic and extensional tectonic settings. In addition, the whole-rock compositions are mostly Ti- and P-poor as in low Ti–P continental flood basalts and in subduction-related mafic magmas. The same conclusion is sustained by the trace-element compositions (e.g., occurrence of mafic magmas with high Th/Ta and La/Ta values; low Sr/Ce ratios, etc). These geochemical features indicate involvement of a subduction component at the source of these extensional igneous rocks. Convective mixing of asthenospheric mantle with the overlying lithospheric mantle enriched during the Ubendian subduction or mixing of melts from both mantle components can account for the composition of the post-orogenic Ubendian mafic rocks.
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    URL: http://dx.doi.org/10.1007/s005310050214
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    Origin of giant stratabound deposits of magnesite and siderite in Riphean carbonate rocks of the Bashkir mega-anticline, western Urals (1999)
    Springer
    Geologische Rundschau 87 (1999), S. 589-602 
    Details
    ISSN: 0016-7835
    Keywords: Key words Sediment-hosted deposits ; Magnesite ; Siderite ; Bashkir mega-anticline ; Riphean ; Metasomatism ; Geochemistry
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract In the Bashkir mega-anticline (western Urals) stratabound magnesite, siderite, fluorite and base-metal deposits are hosted by a sequence of Riphean sediments with a thickness of more than 12 km. The giant deposits of siderite (Bakal) and sparry magnesite (Satka) belong to the largest known mineral deposits of this type on Earth but are still disputed with respect to their origin. Both the Fe- and Mg-carbonate ores are clearly characterized by mimetic preservation of sedimentary and diagenetic textures of the host carbonate sediments, giving evidence of epigenetic metasomatic replacement. In the stratiform magnesite deposits of Satka, O- and C-isotopes, REE pattern and the lithostratigraphic position of the ore, point to the reflux of early diagenetic Mg-rich brines being responsible for the selective replacement of brecciated dolomite. The Bakal siderite deposits are hosted by Lower Riphean carbonate rocks and are controlled by a Lower to Middle Riphean unconformity marked by deep erosion and subsequent transgression-related sedimentation of coarse clastics. Their independence of carbonate lithofacies and their trace element distribution are indicative of metasomatic processes. Fe-bearing fluids have probably been generated by low-grade metamorphic (catagenetic) devolatization from underlying argillites, causing the metasomatic formation of large siderite ore bodies in the Bakal carbonates due to the focusing of the fluid flow by the overlying Mid-Riphean coarse clastics.
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    URL: http://dx.doi.org/10.1007/s005310050233
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    Nd–Sr isotopic and trace element study of rocks and fluids from the continental deep drilling Project (KTB), Germany (1996)
    Springer
    Geologische Rundschau 85 (1996), S. 162-171 
    Details
    ISSN: 0016-7835
    Keywords: Key words KTB pilot hole ; Metabasites ; Geochemistry ; Sr ; Nd isotopes ; Fluid ; Lamprophyre
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract  Geochemical analyses were interpreted on the dominant lithological units and on a deep crustal fluid from the Continental Deep Drilling Project (KTB) Pilot Hole, situated at the western margin of the Variscan Bohemian Massif. The biotite gneiss (from 384 m depth) shows a rare earth element pattern very similar to the European shale composite with Nd model ages of 940 Ma (CHUR) and 1.4 Ga (DM). The lamprophyre dike in the upper profile (1549 m), a nepheline and olivine normative basalt, is geochemically and isotopically similar to rocks from the Tertiary Central European Volcanic Province. The lower metabasite sequence (3575–4000 m), with an intrusion age of approximately 500 Ma, is made up primarily of highly metamorphosed subalkalic olivine basalts. The geochemical characteristics of the metabasites are a (La/Yb)N of 5–10, an La concentration of 20–50 times chondrite as well as (87Sr/86Sr)i of 0.7035–0.7038 and εNd(T) of 4–6. These values suggest a depleted mantle source for the igneous precursors, evolving by assimilation-fractional crystallization processes with up to 25% of upper crust into the ultramafic, basaltic, and intermediate rock types of the metabasite sequence. The strong geochemical and chronological similarities between the KTB metabasites and rocks from the Münchberg Massif suggest that these units belong to the same lithological complex. The high salinity as well as the radiogenic 87Sr/86Sr ratio of 0.709413 in the KTB fluid from 4000 m depth might be the result of migrating fluids reacting with the regional Permo-Mesozoic evaporite deposits, followed by extensive Sr isotopic exchange with the upper crust.
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    URL: http://dx.doi.org/10.1007/BF00192074
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    Geochemistry and petrogenesis of Sikait leucogranite, Egypt: an example of S-type granite in a metapelitic sequence (1997)
    Springer
    Geologische Rundschau 86 (1997), S. 81-92 
    Details
    ISSN: 0016-7835
    Keywords: Key words Sikait leucogranite ; S-type ; Metapelites ; Geochemistry ; Egypt
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract  The Sikait leucogranite (SLG) is a body of porphyritic garnet granite intruded a metapelitic sequence and interlayered orthogneisses. Multiple deformation and low- to medium-grade metamorphism of the sequence was closely associated with pluton emplacement. Textural features of the SLG indicate that subsolidus plastic deformation was induced during the extensive thrusting. The granite is strongly peraluminous, alkali-rich and HFS (high field-strength) elements-depleted with low contents of REE, all facts that substantiate the geochemical characteristics of S-type granites. The geologic and geochemical features are consistent with a dehydration melting model of the hosted metapelites to generate the peraluminous SLG. However, geochemical modelling of trace elements and REEs suggest that the anatectic partial melt was subsequently affected by fractional crystallization of feldspars. This could explain much of the chemical attributes of SLG.
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    URL: http://dx.doi.org/10.1007/s005310050123
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    A Mid Cretaceous origin for the Galápagos hotspot: volcanological, petrological and geochemical evidence from Costa Rican oceanic crustal segments (1997)
    Springer
    Geologische Rundschau 86 (1997), S. 141-155 
    Details
    ISSN: 0016-7835
    Keywords: Key words Costa Rica ; Ophiolites ; Oceanic crust ; Hotspot ; Galápagos islands ; Volcanology ; Petrology ; Geochemistry ; Isotopes
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract  The Quepos, Nicoya and Herradura oceanic igneous terranes in Costa Rica are conspicuous features of a Mid to Late Cretaceous regional magmatic event that encompasses similar terranes in Central America, Colombia, Ecuador and the Caribbean. The Quepos terrane (66 Ma), which consists of ol-cpx phyric, tholeiitic pillow lavas overlain by highly vesicular hyaloclastites, breccias and conglomerates, is interpreted as an uplifted seamount/ocean island complex. The Nicoya (∼90 Ma) and Herradura terranes consist of fault-bounded sequences of sediments, tholeiitic volcanics (pillow lavas and massive sheet flows) and plutonic rocks. The volcanic rocks were emplaced at relatively high eruption rates in moderate to deep water, possibly forming part of an oceanic plateau. Major and trace element data from Nicoya/Herradura tholeiites indicate higher melting temperatures than inferred for normal mid-ocean-ridge basalts (MORB) and/or a different source composition. Sr–Nd–Pb isotopic ratios from all three terranes are distinct from MORB but resemble those from the Galápagos hotspot. The volcanological, petrological and geochemical data from Costa Rican volcanic terranes, combined with published age data, paleomagnetic results and plate tectonic reconstructions of this region, provide strong evidence for a Mid Cretaceous (∼90Ma) age for the Galápagos hotspot, making it one of the oldest known, active hotspots on Earth. Our results also support an origin of the Caribbean Plate through melting of the head of the Galápagos starting plume.
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    URL: http://dx.doi.org/10.1007/PL00009938
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    Geochemical evolution of high-pressure mafic granulites from the Bacariza formation (Cabo Ortegal complex, NW Spain): an example of a heterogeneous lower crust (1997)
    Springer
    Geologische Rundschau 86 (1997), S. 539-555 
    Details
    ISSN: 0016-7835
    Keywords: Key words Mafic granulites ; Eclogites ; Amphibolites ; Gneisses ; Hercynian belt ; Geochemistry
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract  The Cabo Ortegal complex (northwestern Iberian massif) is a klippen formed of several structural units stacked during the Hercynian collision. All these units include ultramafic rocks, metabasites and quartz-feldspathic gneisses affected by different metamorphic conditions. The Bacariza formation is heterogeneous showing a conspicuous layering mainly defined by alternate high-pressure ultrabasic-to-basic granulites, retrogressed garnet amphibolites of intermediate composition and rare acid rocks forming garnet trondhjemitic gneisses. This layering is inherited from a gabbroic protolith showing a composition rich in Fe and Ti. Major and trace elements of these rocks can be correlated to continental tholeiitic series of extensional settings. These high-pressure granulites are situated in normal contact between±serpentinised ultramafic rocks and other high-grade metabasites with lessevolved and more-depleted composition comparable to T-type and N-type MORB. It is suggested that the layered gabbro-type protolith was part of a continuous mafic crust. This crust was initially formed during Early Ordovician in a continental extensional setting and progressively evolved to oceanic spreading.
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    URL: http://dx.doi.org/10.1007/s005310050162
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