ALBERT

Description: Olivine major and trace element compositions from 12 basalts from the southern Payenia volcanic province in Argentina have been analyzed by electron microprobe and laser ablation inductively coupled plasma mass spectrometry. The olivines have high Fe/Mn and low Ca/Fe and many fall at the end of the global olivine array, indicating that they were formed from a pyroxene-rich source distinct from typical mantle peridotite. The olivines with the highest Fe/Mn have higher Zn/Fe, Zn and Co and lower Co/Fe than the olivines with lower Fe/Mn, also suggesting contributions from a pyroxene-rich source. Together with whole-rock radiogenic isotopes and elemental concentrations, the samples indicate mixing between two mantle sources: (1) a pyroxene-rich source with EM-1 ocean island basalt type trace element and isotope characteristics; (2) a peridotitic source with more radiogenic Pb that was metasomatized by subduction-zone fluids and/or melts. The increasing contributions from the pyroxene-rich source in the southern Payenia basalts are correlated with an increasing Fe-enrichment, which caused the olivines to have lower forsterite contents at a given Ni content. Al-in-olivine crystallization temperatures measured on olivine–spinel pairs are between 1155 and 1243°C and indicate that the magmas formed at normal upper mantle (asthenospheric) temperatures of ~1350°C. The pyroxene-rich material is interpreted to have been brought up from the deeper parts of the upper mantle by vigorous asthenospheric upwelling caused by break-off of the Nazca slab south of Payenia during the Pliocene and roll-back of the subducting slab beneath Payenia. The pyroxene-rich mantle mixed with peridotitic metasomatized South Atlantic mantle in the mantle wedge beneath Payenia.

Description: In contrast to the long narrow volcanic chains in the Pacific Ocean, Atlantic hotspot tracks, in particular in the South Atlantic (e.g., Tristan-Gough, Discovery, Shona, and Bouvet), are irregular and, in some cases, diffuse and discontinuous. An important question is whether this irregularity results from tectonic dismemberment of the tracks or if it represents differences in the size, structure, and strength of the melting anomalies. Here we present new age and geochemical data from volcanic samples from Richardson Seamount, Agulhas Ridge along the Agulhas-Falkland Fracture Zone (AFFZ), and Meteor Rise. Six samples yielded ages of 83–72 Ma and are 10–30 m.y. younger than the underlying seafloor, indicating that they are not on-axis seamounts associated with seafloor spreading. The incompatible element and Sr-Nd-Pb-Hf isotopic compositions range from compositions similar to those of the Gough domain of the nearby Tristan-Gough hotspot track to compositions similar to samples from the Shona bathymetric and geochemical anomaly along the southern Mid-Atlantic Ridge (49°–55°S), indicating the existence of a Shona hotspot as much as 84 m.y. ago and its derivation from a source region similar to that of the Tristan-Gough hotspot. Similar morphology, ages, and geochemistry indicate that the Richardson, Meteor, and Orcadas seamounts originally formed as a single volcano that was dissected and displaced 3500 km along the AFFZ, providing a dramatic example of how plate tectonics can dismantle and disseminate a hotspot track across an ocean basin.

Description: Little is known about the effects that subducting an oceanic large igneous province (LIP) has on the petrogenesis of submarine arc volcanoes and their geochemical composition. The southern Kermadec arc represents a rare example where an LIP—the Hikurangi Plateau—is currently subducting and where its effect on mantle composition, element recycling and arc volcanism can be studied. We present mineral chemistry and whole-rock major and trace element, and Sr–Nd–Pb isotope data from samples recovered from the southern Kermadec arc volcanoes Rumble II East and Rumble II West, together with shipboard gravity and magnetic measurements. The Rumble II volcanoes (including a volcanic cone ~10 km further west) form an ~23 km long arc–backarc transect located ~250 km north of New Zealand above the subducting Hikurangi Plateau. Although only a short distance apart, rocks from the two volcanoes have different mineral and whole-rock geochemical compositions. Lavas from Rumble II East are predominantly basaltic and contain primitive olivine phenocrysts (≤Fo 91 ), high-Mg# clinopyroxene (≤96) and anorthitic plagioclase (≤An 97 ). Geochemically these lavas are very diverse and cover a spectrum from low Th/Yb (〈0·15) at high Ba/Th (〉1014) to higher Th/Yb (〉0·15) at lower Ba/Th (〈844). This spectrum, together with 206 Pb/ 204 Pb and 143 Nd/ 144 Nd in the range of 18·74–18·83 and 0·51309–0·51298 respectively (at similar to slightly elevated 87 Sr/ 86 Sr), suggests a mantle wedge that has undergone previous melt extraction and significant fluid addition from the subducting Pacific Plate and that contains sediment and HIMU-type Hikurangi Plateau components. The geochemistry of the sediment–HIMU-type components is exemplified in an olivine pyroxenite (e.g. 206 Pb/ 204 Pb = 20·02; 87 Sr/ 86 Sr = 0·70516; 143 Nd/ 144 Nd = 0·5126). We propose that the olivine pyroxenite formed through melt or fluid–rock metasomatism and represents the first direct evidence of a near Moho arc mantle rock that shows the imprint from a subducting HIMU-type (Hikurangi) seamount. Conversely, lavas from Rumble II West and the cone ~10 km to the west are generally more silica rich than Rumble II East lavas and mainly contain plagioclase with less ortho- and clinopyroxene + olivine phenocrysts. The low Ba/Th (〈470) and 206 Pb/ 204 Pb (〈18·74), a range of 143 Nd/ 144 Nd (0·51297–0·51307) and elevated Th/Yb (0·13–0·39) in these lavas can best be explained by minor sediment input into a less depleted mantle wedge. In addition, the geochemical composition of the Rumble II West lavas does not require involvement of a Hikurangi component, placing a spatial limit on Hikurangi material influencing regional melt generation beneath the backarc. Supported by a gravity model requiring two distinct magma chambers, the different geochemical compositions of Rumble II East and West lavas are inconsistent with a shared magma plumbing system. The different geochemical compositions of lavas from the two Rumble II volcanoes furthermore demonstrate that across-arc geochemical heterogeneities can occur within a few kilometres and may originate from both a geochemically heterogeneous mantle wedge and Moho transition layer, recording inherited geochemical heterogeneities beneath the volcanoes.

Description: Discovery of seafloor volcanism west of Buldir Volcano, the westernmost emergent volcano in the Aleutian arc, demonstrates that surface expression of active Aleutian volcanism falls below sea level just west of 175·9°E longitude, but is otherwise continuous from mainland Alaska to Kamchatka. Lavas dredged from newly discovered seafloor volcanoes up to 300 km west of Buldir have end-member geochemical characteristics that provide new insights into the role of subducted basalt as a source component in Aleutian magmas. Western Aleutian seafloor lavas define a highly calc-alkaline series with 50–70% SiO 2 . Most samples have Mg-numbers [Mg# = Mg/(Mg + Fe)] greater than 0·60, with higher MgO and lower FeO* compared with average Aleutian volcanic rocks at all silica contents. Common basalts and basaltic andesites in the series are primitive, with average Mg# values of 0·67 (±0·02, n = 99, 1SD), and have Sr concentrations (423 ± 29 ppm, n = 99) and La/Yb ratios (4·5 ± 0·4, n = 29) that are typical of island arc basaltic lavas. A smaller group of basaltic samples is more evolved and geochemically more enriched, with higher and more variable Sr and La/Yb (average Mg# = 0·61 ± 0·1, n = 31; Sr = 882 ± 333 ppm, n = 31; La/Yb = 9·1 ± 0·9, n = 16). None of the geochemically enriched basalts or basaltic andesites has low Y (〈15 ppm) or Yb (〈1·5 ppm), so none show the influence of residual or cumulate garnet. In contrast, most western seafloor andesites, dacites and rhyodacites have higher Sr (〉1000 ppm) and are adakitic, with strongly fractionated trace element patterns (Sr/Y = 50–350, La/Yb = 8–35, Dy/Yb = 2·0–3·5) with low relative abundances of Nb and Ta (La/Ta 〉 100), consistent with an enhanced role for residual or cumulate garnet + rutile. All western seafloor lavas have uniformly radiogenic Hf and Nd isotopes, with Nd = 9·1 ± 0·3 ( n = 31) and Hf = 14·5 ± 0·6 ( n = 27). Lead isotopes are variable and decrease with increasing SiO 2 from basalts with 206 Pb/ 204 Pb = 18·51 ± 0·05 ( n = 11) to dacites and rhyodacites with 206 Pb/ 204 Pb = 18·43 ± 0·04 ( n = 18). Western seafloor lavas form a steep trend in 207 Pb/ 204 Pb– 206 Pb/ 204 Pb space, and are collinear with lavas from emergent Aleutian volcanoes, which mostly have 206 Pb/ 204 Pb 〉 18·6 and 207 Pb/ 204 Pb 〉 15·52. High MgO and Mg# relative to silica, flat to decreasing abundances of incompatible elements, and decreasing Pb isotope ratios with increasing SiO 2 rule out an origin for the dacites and rhyodacites by fractional crystallization. The physical setting of some samples (erupted through Bering Sea oceanic lithosphere) rules out an origin for their garnet + rutile trace element signature by melting in the deep crust. Adakitic trace element patterns in the dacites and rhyodacites are therefore interpreted as the product of melting of mid-ocean ridge basalt (MORB) eclogite in the subducting oceanic crust. Western seafloor andesites, dacites and rhyodacites define a geochemical end-member that is isotopically like MORB, with strongly fractionated Ta/Hf, Ta/Nd, Ce/Pb, Yb/Nd and Sr/Y. This eclogite component appears to be present in lavas throughout the arc. Mass-balance modeling indicates that it may contribute 36–50% of the light rare earth elements and 18% of the Hf that is present in Aleutian volcanic rocks. Close juxtaposition of high-Mg# basalt, andesite and dacite implies widely variable temperatures in the western Aleutian mantle wedge. A conceptual model explaining this shows interaction of hydrous eclogite melts with mantle peridotite to produce buoyant diapirs of pyroxenite and pyroxenite melt. These diapirs reach the base of the crust and feed surface volcanism in the western Aleutians, but are diluted by extensive melting in a hotter mantle wedge in the eastern part of the arc.

Description: Asymmetrically zoned hotspot tracks in the Pacific Ocean are interpreted to have formed from zoned plumes originating from the large-scale, lower-mantle, low-seismic-velocity anomaly (superplume?) beneath the southern Pacific, providing direct information about lower-mantle compositional heterogeneity. New trace-element and Sr-Nd-Hf-Pb isotope data from the classic Tristan-Gough hotspot track in the South Atlantic also display a bilateral, asymmetric zonation with two distinct mantle source components, making it the first zoned plume to be recognized overlying the African superplume. The plume zonation can be traced for 70 m.y., four times longer than recognized for Pacific zoned hotspot tracks. These findings confirm that the proposed zonation of Pacific hotspots is not simply a geochemical oddity, but could be a major feature of plumes derived from lower-mantle superplumes. We propose that the enriched southern Gough subtrack source with elevated 207 Pb/ 204 Pb and 208 Pb/ 204 Pb at a given 206 Pb/ 204 Pb, but low 143 Nd/ 144 Nd and 176 Hf/ 177 Hf (DUPAL-like composition), may reflect the African superplume composition, whereas the more depleted northern Tristan subtrack source could represent a mixture of the superplume with the surrounding depleted mantle. Our results strengthen arguments that the enriched signature (DUPAL anomaly) in the South Atlantic could be derived from the lower mantle.

Description: A suite of 48 samples, including both historical and prehistoric lavas and some plutonic rocks, have been analysed from the Cumbre Vieja rift, La Palma, Canary Islands. Additionally, mineral–melt partition coefficients have been measured for clinopyroxene, plagioclase, amphibole, titanite and apatite in selected rocks. The lavas range from basanite to phonolite (SiO 2 = 41·2–57·5 wt % and MgO = 10–0·8 wt %) in composition and form coherent, curvilinear major and trace element arrays in variation diagrams, irrespective of eruption age. The mafic lavas have typical ocean island incompatible trace element patterns and Sr, Nd and Pb isotope compositions show little variation but have a HIMU-type character. Generation of the parental magmas is inferred to have involved ~4% dynamic melting of a garnet lherzolite source that may have previously been metasomatized by melts derived from a recycled mafic component containing residual phlogopite. The major process of differentiation to phonotephrite involved fractional crystallization of basanitic magmas that evolved along the same liquid line of descent under similar pressure–temperature conditions. Numerical simulations using the MELTS algorithm suggest that this occurred across a temperature interval from c. 1320 to 950°C at 400 MPa and an oxygen fugacity equivalent to quartz–fayalite–magnetite (QFM), with an initial H 2 O content of 0·3 wt %. The later stages of differentiation (〈5 wt % MgO) were dominated by mixing with partial melts of young syenites formed from earlier magma batches. All of the lavas are characterized by 230 Th and 226 Ra excesses and ( 230 Th/ 238 U) decreases with decreasing Nb/U and increasing SiO 2 , with no accompanying change in ( 226 Ra/ 230 Th). To explain the observations, we propose a model in which there was a significant role for amphibole, and more importantly accessory titanite, in decre'asing Nb/U, Ce/Pb and Th/U ratios and increasing or buffering ( 226 Ra/ 230 Th) ratios during the later stages of differentiation and magma mixing. These processes all occurred over a few millennia in small magma batches that were repeatedly emplaced within the mid-crust of the Cumbre Vieja rift system prior to rapid transport to the surface.

Description: The existence of an intrinsic depleted component in mantle plumes has previously been proposed for several hotspots in the Pacific, Atlantic, and Indian Oceans. However, formation of these depleted basalts is often associated with unusual tectonomagmatic processes such as plume-ridge interaction or multistage melting at plume initiation, where depleted basalts could reflect entrainment and melting of depleted upper mantle. Late Cretaceous to middle Eocene seamounts that accreted in Costa Rica and are part of the early Galapagos hotspot track provide new insights into the occurrence and nature of intrinsic depleted components. The Paleocene (ca. 62 Ma) seamounts include unusually depleted basalts that erupted on the Farallon plate far from a mid-ocean ridge. These basalts closely resemble Gorgona komatiites in terms of trace element and radiogenic isotope composition, suggesting formation from a similar, refractory mantle source. We suggest that this source may be common to plumes, but is only rarely sampled due to excessive extents of melting required to extract melts from the most refractory parts of a heterogeneous mantle plume.