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  • Articles  (1,278,719)
  • Other Sources  (313)
  • American Chemical Society  (720,763)
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  • Articles  (1,278,719)
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  • 1
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    Advances in understanding large-scale responses of the water cycle to climate change (2020)
    Wiley
    Details
    Publication Date: 2020-12-22
    Description: Globally, thermodynamics explains an increase in atmospheric water vapor with warming of around 7%/°C near to the surface. In contrast, global precipitation and evaporation are constrained by the Earth's energy balance to increase at ∼2-3%/°C. However, this rate of increase is suppressed by rapid atmospheric adjustments in response to greenhouse gases and absorbing aerosols that directly alter the atmospheric energy budget. Rapid adjustments to forcings, cooling effects from scattering aerosol, and observational uncertainty can explain why observed global precipitation responses are currently difficult to detect but are expected to emerge and accelerate as warming increases and aerosol forcing diminishes. Precipitation increases with warming are expected to be smaller over land than ocean due to limitations on moisture convergence, exacerbated by feedbacks and affected by rapid adjustments. Thermodynamic increases in atmospheric moisture fluxes amplify wet and dry events, driving an intensification of precipitation extremes. The rate of intensification can deviate from a simple thermodynamic response due to in-storm and larger-scale feedback processes, while changes in large-scale dynamics and catchment characteristics further modulate the frequency of flooding in response to precipitation increases. Changes in atmospheric circulation in response to radiative forcing and evolving surface temperature patterns are capable of dominating water cycle changes in some regions. Moreover, the direct impact of human activities on the water cycle through water abstraction, irrigation, and land use change is already a significant component of regional water cycle change and is expected to further increase in importance as water demand grows with global population.
    Description: Published
    Description: 49-75
    Description: 4A. Oceanografia e clima
    Description: JCR Journal
    Keywords: climate change; land surface; precipitation; radiative forcing; water cycle
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 2
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    Physical and geochemical record of an early Eocene carbon‐cycle perturbation on a turbiditic continental margin (2021)
    Wiley
    Details
    Publication Date: 2021-01-20
    Description: Multivariate analysis of the elemental composition of hemipelagic sedimentary successions has provided invaluable information about palaeoenvironmental evolution, including records of short-lived Eocene hyperthermal events. However, few studies have analyzed the sedimentary record of these climatic events in turbidite-rich continental margin successions. In order to test the usefulness of multivariate statistical techniques (factor and cluster analysis) in palaeonvironmental and palaeoclimatic research on turbiditic successions, the lowermost Eocene Solondota section, which accumulated on the North Iberian continental margin, was studied. A prominent negative carbon isotope excursion from Solondota was correlated with the Ypresian (early Eocene) hyperthermal event J, also known as C24n.2rH1. High-resolution sedimentological, geochemical (stable isotopes, major and trace elements) and mineralogical (bulk and clay mineralogy) data show that multivariate statistical analysis helps to manage large-sized quantitative datasets objectively, avoiding arbitrary choice of representative elements and identifying environmental factors (virtual variables) that may not be evident otherwise. Variations in major and minor elements from hemipelagic carbonates across the Solondota carbon isotope excursion suggest a temporarily more humid continental climate, which caused increased terrigenous material input into the marine environment. The finer grained fraction boosted hemipelagic carbonate dilution, whereas the coarser grained sediment was transported by temporarily more frequent and voluminous turbidity currents. Thus, the results from the Solondota carbon isotope excursion revealed similarities with deep marine records of other early Eocene minor hyperthermal events. This demonstrates the validity of deep-marine turbiditic successions for providing reliable sedimentological, mineralogical and geochemical records of global palaeoclimatic significance, complementing the information obtained from other sedimentary environments. Furthermore, the generally expanded nature of turbiditic successions can potentially provide palaeoclimatic information at very high resolution, enriching, and perhaps improving, the commonly condensed and sometimes discontinuous record of hemipelagic- only successions.
    Description: Published
    Description: 881-904
    Description: 1A. Geomagnetismo e Paleomagnetismo
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 3
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    A minimum time control problem for aerobic degradation processes in biocell composting plants (2021)
    Wiley
    Details
    Publication Date: 2021-05-12
    Description: We introduce a mathematical model for the composting process in biocells. The model includes several phenomena, like the aerobic biodegradation of the soluble substrate by means of a bacterial population, the hydrolysis of insoluble substrate, and the biomass decay. We investigate the best strategies to reduce substrate components in minimal time by controlling the effects of cell oxygen concentration on the degradation phenomenon. It is shown that singular controls are not optimal for this model and the optimal control time profiles are of bang or bang-bang type. The occurrence of switching curves is discussed. In the case of a bang-bang control we prove that optimal control profiles have a unique switching time and the corresponding switching curve is determined.
    Description: Published
    Description: 1251-1266
    Description: 7A. Geofisica per il monitoraggio ambientale
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 4
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    Empirical H/V spectral ratios estimated in two deep sedimentary basins using microseisms recorded by short-period seismometers (2009)
    Wiley-Blackwell
    Details
    Publication Date: 2021-06-22
    Description: In this work, we analyse continuous measurements of microseisms to assess the reliability of the fundamental resonance frequency estimated by means of the horizontal-to-vertical (H/V) spectral ratio within the 0.1–1 Hz frequency range, using short-period sensors (natural period of 1 s). We apply the H/V technique to recordings of stations installed in two alluvial basins with different sedimentary cover thicknesses—the Lower Rhine Embayment (Germany) and the Gubbio Plain (Central Italy). The spectral ratios are estimated over the time–frequency domain, and we discuss the reliability of the results considering both the variability of the microseism activity and the amplitude of the instrumental noise. We show that microseisms measured by short period sensors allow the retrieval of fundamental resonance frequencies greater than about 0.1–0.2 Hz, with this lower frequency bound depending on the relative amplitude of themicroseism signal and the self-noise of the instruments. In particular,we show an examplewhere the considered short-period sensor is connected to instruments characterized by an instrumental noise level which allows detecting only fundamental frequencies greater than about 0.4 Hz. Since the frequency at which the peak of the H/V spectral ratio is biased depends upon the seismic signal-to-instrument noise ratio, the power spectral amplitude of instrumental self-noise should be always considered when interpreting the frequency of the peak as the fundamental resonance frequency of the investigated site.
    Description: Published
    Description: 175-184
    Description: 4.1. Metodologie sismologiche per l'ingegneria sismica
    Description: JCR Journal
    Description: open
    Keywords: site effects ; fourier analysis ; 04. Solid Earth::04.06. Seismology::04.06.01. Earthquake faults: properties and evolution
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 5
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    Integrated use of unmanned aerial vehicle photogrammetry and terrestrial laser scanning to support archaeological analysis: The Acropolis of Selinunte case (Sicily, Italy) (2021)
    Wiley
    Details
    Publication Date: 2021-06-14
    Description: Southwestern Sicily is an area of infrequent seismic activity; however, some studies carried out in the archaeological Selinunte site suggest that, between the fourth century BC and the early Middle Ages, probably at least two earthquakes strucked this area with enough energy to damage and cause the collapse and kinematics of much of the architecture of Selinunte. Take into account that, in 2008, a noninvasive archaeological prospection and traditional data gathering methods along the Acropolis north fortifications were carried out. Following these first studies, after about 10 years, a new geophysical campaign was carried out. This second campaign benefited from the application of modern technologies for the acquisition and processing of the point cloud data on the northern part of the Acropolis, like terrestrial laser scanning and unmanned aerial vehicle photogrammetry. In this paper, we present the application of these techniques and a strategy for their integration for the 3D modelling of buildings and cultural heritages. We show how the integration of data acquired independently by these two techniques is an added value able to overcome the intrinsic limits of the individual techniques. The application to Selinunte's Acropolis allowed it to highlight and measure with high accuracy fractures, dislocation, inclinations of walls, depressions of some areas and other interesting observations, which may be important starting points for future investigations.
    Description: Published
    Description: 153-165
    Description: 2IT. Laboratori analitici e sperimentali
    Description: JCR Journal
    Keywords: 3D reconstruction ; archaeological survey ; digital elevation model ; Selinunte Archaeological Park ; terrestrial laser scanning ; unmanned aerial vehicle photogrammetry ; 05.04. Instrumentation and techniques of general interest ; 04.02. Exploration geophysics ; 05.02. Data dissemination ; 05.06. Methods
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 6
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    Empirical nonergodic shaking scenarios based on spatial correlation models: An application to central Italy (2021)
    Wiley
    Details
    Publication Date: 2021-01-18
    Description: This paper provides a new methodological framework to generate empirical ground shaking scenarios, designed for engineering applications and civil protection planning. The methodology is useful both to reconstruct the ground motion pattern of past events and to generate future shaking scenarios, in regions where strong-motion datasets from multiple events and multiple stations are available. The proposed methodology combines (1) an ad-hoc nonergodic ground motion model (GMM) with (2) a spatial correlation model for the source region-, site-, and path-systematic residual terms, and (3) a model of the remaining aleatory error to take into account for directivity effects. The associated variability is a function of the type of scenario generated (bedrock or site, past or future event) and it is minimal for source areas where several events have occurred and for sites where recordings are available. In order to develop the region-specific fully nonergodic GMM and to compute robust estimation of the residual terms, the approach is calibrated on a highly dense dataset compiled for the area of central Italy. Example tests demonstrate the validity of the approach, which allows to simulate acceleration response spectra at unsampled sites, as well as to capture peculiar physical features of ground motion patterns in the region. The proposed approach could be usefully adopted for data-driven simulations of ground shaking maps, as alternative or complementary tool to physic-based and stochastic-based approaches.
    Description: Published
    Description: 60-80
    Description: 5T. Sismologia, geofisica e geologia per l'ingegneria sismica
    Description: JCR Journal
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  • 7
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    Geolithological and anthropogenic controls on the hydrochemistry of the Volturno river (Southern Italy) (2021)
    Wiley
    Details
    Publication Date: 2021-03-03
    Description: The present work aims to study the main chemical and physical water parameters in the upper and middle Volturno river catchment (southern Italy), between the Capo Volturno springs and the confluence with the Calore river. This study makes use of morphology, geolithology, tectonic, land use, and physico‐chemical (pH, electrical conductivity, redox potential, temperature, major ions, and 222Rn) data for the identification of the main sources of surface and groundwaters in the Volturno catchment and of their evolution and mixing both in base flow and peak flow conditions. The study was also performed to assess whether the alteration due to potential anthropogenic contamination may hamper the identification of natural “primitive” sources of surface waters, especially in the populated and farmed plains far from the river headwaters. Our data suggest that water chemistry of this stretch of the Volturno river is dominated mainly by lithology and, only marginally, by the intense exogenous activities and that this trend is appreciable in both base flow and peak flow conditions. The proposed simple geochemical approach based on easy‐to‐sample matrices and on cost‐effective standard methods is a valuable tool to address catchment functionality especially in upland areas, where complex geologic and structural settings, heterogeneous groundwater flow, and logistical issues are the rule rather than the exception. Because the upper and middle Volturno catchment is comparable with numerous valleys of the Mediterranean area, this study could be a reference for analogous applications.
    Description: Published
    Description: 627–638
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
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  • 8
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    Hydrogeochemical dynamics affecting steam-heated pools at El Chichón Crater (Chiapas - Mexico) (2021)
    Wiley
    Details
    Publication Date: 2021-03-02
    Description: El Chichon is an active volcano located in the north-western Chiapas, southern Mexico. The crater hosts a lake, a spring, named Soap Pool, emerging from the underlying volcanic aquifer and several mud pools/hot springs on the internal flanks of the crater which strongly interact with the current fumarolic system (steam-heated pools). Some of these pools, the crater lake and a cold spring emerging from the 1982 pumice deposits, have been sampled and analysed. Water–volcanic gas interactions determine the heating (43–99°C) and acidification (pH 2–4) of the springs, mainly by H2S oxidation. Significantly, in the study area, a significant NH3 partial pressure has been also detected. Such a geochemically aggressive environment enhances alteration of the rock in situ and strongly increases the mineralization of the waters (and therefore their electrical conductivity). Two different mineralization systems were detected for the crater waters: the soap pool-lake (Na+/Cl = 0.4, Na/Mg〉10) and the crater mud pools (Na+/Cl 〉 10, Na/Mg 〈 4). A deep boiling, Na+-K+-Cl -rich water reservoir generally influences the Soap Pool-lake, while the mud pool is mainly dominated by water-gas–rock interactions. In the latter case, conductivity of sampled water is directly proportional to the presence of reactive gases in solution. Therefore, chemical evolution proceeds through neutralization due to both rock alteration and bacterial oxidation of ammonium to nitrate. The chemical compositions show that El Chichon aqueous fluids, within the crater, interact with gases fed by a geothermal reservoir, without clear additions of deep magmatic fluids. This new geochemical dataset, together with previously published data, can be used as a base line with which to follow-up the activity of this deadly volcano.
    Description: Published
    Description: 331–343
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
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  • 9
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    New Applications in Gas Geochemistry (2021)
    Wiley
    Details
    Publication Date: 2021-02-03
    Description: Gases present in the Earth crust are important in various branches of human activities. Hydrocarbons are a significant energy resource, helium is applied in many high-tech instruments, and studies of crustal gas dynamics provide insight in the geodynamic processes and help monitor seismic and volcanic hazards. Quantitative analysis of methane and CO2 migration is important for climate change studies. Some of them are toxic (H2S, CO2, CO); radon is responsible for the major part of human radiation dose. The development of analytical techniques in gas geochemistry creates opportunities of applying this science in numerous fields. Noble gases, hydrocarbons, CO2, N2, H2, CO, and Hg vapor are measured by advanced methods in various environments and matrices including fluid inclusions. Following the “Geochemical Applications of Noble Gases”(2009), “Frontiers in Gas Geochemistry” (2013), and “Progress in the Application of Gas Geochemistry to Geothermal, Tectonic and Magmatic Studies” (2017) published as special issues of Chemical Geology and “Gas geochemistry: From conventional to unconventional domains” (2018) published as a special issue of Marine and Petroleum Geology, this volume continues the tradition of publishing papers reflecting the diversity in scope and application of gas geochemistry.
    Description: Published
    Description: 976190
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Keywords: geochemistry ; Atmosphere ; 03. Hydrosphere ; 04. Solid Earth
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  • 10
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    Sediment dynamics on the Northwest African continental margin (1982)
    Wiley
    In:  EPIC3The Ocean Floor : Bruce Heezen commemorative volume, (A Wiley-Interscience publication), Chichester, Wiley, pp. 147-163, ISBN: 0-471-10091-9
    Details
    Publication Date: 2014-05-12
    Description: The sedimentation regime off Northwest Africa is shaped by: (1) structur~al factors. which result in generallv low relief on land. shelf widths between 40 and more than 120 km. and av-erage sfope inclinations between 10 30' and 30; (2) land climates. which contral the delivery of terrigenous particles to the margin: (3) water movements including boundary currents and upwelling; and (4) the post- Pleistocene sea level rise. This chapter combines published and new results arising from research into the sedimentation processes off Northwest Africa. and emphasizes particularly the activities of the Kiel marine geological group during the past few years. Reviews of cruise activities and results were given in Closs et al. (1969) (Meteor cruise 8. 1967. off Morocco) . Seibold (1972) (Meteor cmise 25 . 1971. off Sahara to Central Senegal). Seibold and Hinz (1976) (Meteor cmise 39,1975 . and Valdivia cruise 10. 1975, from Morocco to South Senegal), and Waiden et al. (1974) (Meteor cmise 30, 1973, off Sierra Leone). Some of these cmises were used for pre- or post-site surveys for the Deep-Sea Drilling Project, or to add undisturbed Quaternary cores to the Glomar Challenger cores (leg 41, ] 975; Lancelot, et al .• 1978); leg 47 A, Arthur er al .• 1979; Lutze et al., 1979). We have concentrated our geological investigations on a number of standard profiles from the shelf to the upper continental rise as given in Figure 1. The manuscript was finished May 1979.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Inbook , peerRev
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  • 11
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    North Pacific halocline and cold climate induced by Panamanian Gateway closure in a coupled ocean-atmosphere GCM (2005)
    Wiley
    In:  EPIC3Geophysical Research Letters, Wiley, 32(L10618), ISSN: 0094-8276
    Details
    Publication Date: 2018-12-07
    Repository Name: EPIC Alfred Wegener Institut
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  • 12
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    Arctic Sea Ice in CMIP6 (2020)
    Wiley
    In:  EPIC3Geophysical Research Letters, Wiley, ISSN: 0094-8276
    Details
    Publication Date: 2020-05-04
    Description: We examine CMIP6 simulations of Arctic sea‐ice area and volume. We find that CMIP6 models produce a wide spread of mean Arctic sea‐ice area, capturing the observational estimate within the multi‐model ensemble spread. The CMIP6 multi‐model ensemble mean provides a more realistic estimate of the sensitivity of September Arctic sea‐ice area to a given amount of anthropogenic CO2 emissions and to a given amount of global warming, compared with earlier CMIP experiments. Still, most CMIP6 models fail to simulate at the same time a plausible evolution of sea‐ice area and of global mean surface temperature. In the vast majority of the available CMIP6 simulations, the Arctic Ocean becomes practically sea‐ice free (sea‐ice area 〈 1 million km2) in September for the first time before the year 2050 in each of the four emission scenarios SSP1‐1.9, SSP1‐2.6, SSP2‐4.5 and SSP5‐8.5 examined here.
    Repository Name: EPIC Alfred Wegener Institut
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  • 13
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    Circulation and Thermohaline Variability of the Hanna Shoal Region on the Northeastern Chukchi Sea Shelf (2020)
    Wiley
    In:  EPIC3Journal of Geophysical Research: Oceans, Wiley
    Details
    Publication Date: 2020-07-07
    Description: We analyzed velocity and hydrographic data from 23 moorings in the northeast Chukchi Sea from 2011 to 2014. In most years the eastern side of Hanna Shoal was strongly stratified year-round, while weakly stratified regions prevailed on the shelf south and west of the Shoal. Stratification differences cause differential vertical mixing rates, which in conjunction with advection of different bottom water properties resulted in seasonally-varying along-isobath density gradients. In agreement with numerical models, we find that bottom waters flow anticyclonically around the Shoal. Whereas most of the shelf responded barotropically to wind-forcing, there was a strong baroclinic component to the flow field northeast of Hanna Shoal, resulting in no net vertically-integrated transport on average. In contrast there is a net eastward transport from west of the Shoal, which implies convergence north of the Shoal. Convergence and along-isobath density gradients may foster cross-shelf exchange north of Hanna Shoal. Modal analyses indicate that the shelf south of the Shoal and Barrow Canyon responded coherently to local and remote winds, whereas the wind-current response around Hanna Shoal was less coherent. Barotropic topographic waves, of ~3-day period, were generated episodically northeast of the Shoal and propagate clockwise around Hanna Shoal, but are blocked from entering Barrow Canyon and are possibly scattered by the horizontally sheared flow and converging isobaths on the western side of the Shoal. Analysis of water properties on the western side of Hanna Shoal suggests that these include contributions from the western and southern portions of the Chukchi Sea.
    Repository Name: EPIC Alfred Wegener Institut
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  • 14
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    Limited Retreat of the Wilkes Basin Ice Sheet during the Last Interglacial (2020)
    Wiley
    In:  EPIC3Geophysical Research Letters, Wiley, 47(13), ISSN: 0094-8276
    Details
    Publication Date: 2020-07-20
    Description: The response of the East Antarctic Ice Sheet to global warming represents a major source of uncertainty in sea level projections. Thinning of the East Antarctic George V and Sabrina Coast ice‐cover is currently taking place, and regional ice‐sheet instability episodes might have been triggered in past warm climates. However, the magnitude of ice retreat in the past can not yet be quantitatively derived from paleo‐proxy records alone. We propose that a runaway retreat of the George V coast grounding line and subsequent instability of the Wilkes Basin ice‐sheet would either leave a clear imprint on the water isotope composition in the Talos Dome region or prohibit a Talos Dome ice‐core record from the Last Interglacial altogether. Testing this hypothesis our ice sheet model simulations suggest, that Wilkes Basin ice‐sheet retreat remained relatively limited during the Last Interglacial and provide a constraint on Last Interglacial East Antarctic grounding line stability.
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  • 15
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    Extent and cessation of the mid-Cretaceous Hikurangi Plateau underthrusting: Impact on global plate tectonics and the submarine Chatham Rise (2020)
    Wiley
    In:  EPIC3Journal of Geophysical Research-Solid Earth, Wiley, 125, ISSN: 0148-0227
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    Publication Date: 2020-08-21
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  • 16
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    Evolution of the Upper Ocean Stratification in the Japan Sea Since the Last Glacial (2020)
    Wiley
    In:  EPIC3Geophysical Research Letters, Wiley, 47(16), pp. e2020GL088255, ISSN: 0094-8276
    Details
    Publication Date: 2021-08-05
    Description: Paleoceanographic evidence commonly indicates that Last Glacial Maximum surface temperatures in the Japan Sea were comparable to modern conditions, in striking difference to colder neighboring regions. Here, based on a core from the central Japan Sea, our results show similar UK′37‐ and TEXL86‐derived temperatures between 24.7 and 16.3 ka BP, followed by an abrupt divergence at ~16.3 ka BP and a weakening of divergence after ~8.7 ka BP. We attribute this process to a highly stratified glacial upper ocean controlled by the East Asian Summer Monsoon, increasing thermal gradient between surface and subsurface layers during the deglaciation and the intrusion of Tsushima Warm Current since the mid‐Holocene, respectively. Therefore, we suggest that threshold‐like changes in upper‐ocean temperatures linked to sea level rise and monsoon dynamics, rather than just sea surface temperatures, play a critical role in shaping the thermal and ventilation history of this NW Pacific marginal sea.
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  • 17
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    AMOC recovery in a multi-centennial scenario using a coupled atmosphere-ocean-ice sheet model (2020)
    Wiley
    In:  EPIC3Geophysical Research Letters, Wiley, 47(16), pp. e2019GL086810, ISSN: 0094-8276
    Details
    Publication Date: 2020-09-14
    Description: We simulate the two Coupled Model Intercomparison Project scenarios RCP4.5 and RCP8.5, to assess the effects of melt‐induced fresh water on the Atlantic meridional overturning circulation (AMOC). We use a newly developed climate model with high resolution at the coasts, resolving the complex ocean dynamics. Our results show an AMOC recovery in simulations run with and without an included ice sheet model. We find that the ice sheet adds a strong decadal variability on the freshwater release, resulting in intervals in which it reduces the surface runoff by high accumulation rates. This compensating effect is missing in climate models without dynamic ice sheets. Therefore, we argue to assess those freshwater hosing experiments critically, which aim to parameterize Greenland's freshwater release. We assume the increasing net evaporation over the Atlantic and the resulting increase in ocean salinity, to be the main driver of the AMOC recovery.
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  • 18
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    Ocean Circulation and Variability Beneath Nioghalvfjerdsbræ (79 North Glacier) Ice Tongue (2020)
    Wiley
    In:  EPIC3Journal of Geophysical Research-Oceans, Wiley, 125(8), ISSN: 0148-0227
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    Publication Date: 2020-11-30
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  • 19
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    Spatial and Temporal variability of iodine in aerosol (2021)
    Wiley
    In:  EPIC3Journal of Geophysical Research-Atmospheres, Wiley, 126, pp. e2020JD034410, ISSN: 0148-0227
    Details
    Publication Date: 2021-05-10
    Description: In this work we describe the compilation and homogenization of an extensive dataset of aerosol iodine field observations in the period between 1963 and 2018 and we discuss the spatial and temporal dependences of total iodine in bulk aerosol by comparing the observations with CAM-Chem model imulations. Total iodine in aerosol shows a distinct latitudinal dependence, with an enhancement towards the northern hemisphere (NH) tropics and lower values towards the poles. This behavior, which has been predicted by atmospheric models to depend on the global distribution of the main ceanic iodine source (which in turn depends on the reaction of surface ozone with aqueous iodide on he sea water-air interface, generating gas-phase I2 and HOI), is confirmed here by field observations for the first time. Longitudinally, there is some indication of a wave-one profile in the Tropics, which peaks in the Atlantic and shows a minimum in the Pacific, following the wave-one longitudinal variation of tropical tropospheric ozone. New data from Antarctica show that the south polar seasonal variation of iodine in aerosol mirrors that observed previously in the Arctic, with two equinoctial maxima and the dominant maximum occurring in spring. While no clear seasonal variability is observed in NH middle latitudes, there is an indication of different seasonal cycles in the NH tropical Atlantic and Pacific. A weak positive long-term trend is observed in the tropical annual averages, which is consistent with an enhancement of the anthropogenic ozone-driven global oceanic source of iodine over the last 50 years.
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  • 20
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    Nonmonotonic Change of the Arctic Ocean Freshwater Storage Capability in a Warming Climate (2021)
    Wiley
    In:  EPIC3Geophysical Research Letters, Wiley, 48(10), pp. e2020GL090951, ISSN: 0094-8276
    Details
    Publication Date: 2021-07-01
    Description: Freshwater in the Arctic Ocean is one of the key climate components. It is not well understood how the capability of the Arctic Ocean to store freshwater will develop when freshwater supplies increase in a warming climate. By using numerical experiments, we find that this capability varies with the Arctic sea ice decline nonmonotonically, with the largest capability at intermediate strength of sea ice decline. Through enhancing the ocean surface stress, sea ice decline not only accumulates freshwater toward the Amerasian Basin but also tends to reduce the amount of freshwater in both the Eurasian and Amerasian basins by increasing the occupation of Atlantic-origin water in the upper ocean. An increase in river runoff modulates the counterbalance of the two competing effects, leading to the nonmonotonic changes of the Arctic freshwater storage capability in a warming climate.
    Repository Name: EPIC Alfred Wegener Institut
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    On the Cause of the Mid‐Pleistocene Transition (2021)
    Wiley
    In:  EPIC3Reviews of Geophysics, Wiley, 59(2), pp. e2020RG000727, ISSN: 8755-1209
    Details
    Publication Date: 2021-06-17
    Description: The Mid-Pleistocene Transition (MPT), where the Pleistocene glacial cycles changed from 41 to ∼100 kyr periodicity, is one of the most intriguing unsolved issues in the field of paleoclimatology. Over the course of over four decades of research, several different physical mechanisms have been proposed to explain the MPT, involving non-linear feedbacks between ice sheets and the global climate, the solid Earth, ocean circulation, and the carbon cycle. Here, we review these different mechanisms, comparing how each of them relates to the others, and to the currently available observational evidence. Based on this discussion, we identify the most important gaps in our current understanding of the MPT. We discuss how new model experiments, which focus on the quantitative differences between the different physical mechanisms, could help fill these gaps. The results of those experiments could help interpret available proxy evidence, as well as new evidence that is expected to become available.
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    Dynamics of the African Plate 75 Ma: From Plate Kinematic Reconstructions to Intraplate Paleo-Stresses (2021)
    Wiley
    In:  EPIC3Tectonics, Wiley, 40(7), ISSN: 0278-7407
    Details
    Publication Date: 2021-07-26
    Description: Plate reconstruction studies show that the Neotethys Ocean was closing due to the convergence of Africa and Eurasia toward the end of the Cretaceous. The period around 75 Ma reflects the onset of continental collision between the two plates as convergence continued to be taken up mostly by subduction of the Neotethys slab beneath Eurasia. The Owen transform plate boundary in the northeast accommodated the fast northward motion of the Indian plate relative to the African plate. The rest of the plate was surrounded by mid-ocean ridges. Africa was experiencing continent-wide rifting related to northeast-southwest extension. We aim to quantify the forces and paleostresses that may have driven this continental extension. We use the latest plate kinematic reconstructions in a grid search to estimate horizontal gravitational stresses (HGSs), plate boundary forces, and the plate's interaction with the asthenosphere. The contribution of dynamic topography to HGSs is based on recent mantle convection studies. We model intraplate stresses and compare them with the strain observations. The fit to observations favors models where dynamic topography amplitudes are smaller than 300 m. The results also indicate that the net pull transmitted from slab to the surface African plate was low. To put this into context, we notice that available tectonic reconstructions show fragmented subduction zones and various colliding micro-continents along the northern margin of the African plate around this time. We therefore interpret a low net pull as resulting from either a small average slab length or from the micro-continents' resistance to subduction.
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    Global River Discharge and Floods in the Warmer Climate of the Last Interglacial (2020)
    Wiley
    In:  EPIC3Geophysical Research Letters, Wiley, 47(e2020G), ISSN: 0094-8276
    Details
    Publication Date: 2020-09-18
    Description: We investigate hydrology during a past climate slightly warmer than the present: the Last Interglacial (LIG). With daily output of pre‐industrial and LIG simulations from eight new climate models we force hydrological model PCR‐GLOBWB, and in turn hydrodynamic model CaMa‐Flood. Compared to pre‐industrial, annual mean LIG runoff, discharge, and 100‐year flood volume are considerably larger in the Northern Hemisphere, by 14%, 25% and 82%, respectively. Anomalies are negative in the Southern Hemisphere. In some boreal regions, LIG runoff and discharge are lower despite higher precipitation, due the higher temperatures and evaporation. LIG discharge is much higher for the Niger, Congo, Nile, Ganges, Irrawaddy, Pearl, and lower for the Mississippi, Saint Lawrence, Amazon, Paraná, Orange, Zambesi, Danube, Ob. Discharge is seasonally postponed in tropical rivers affected by monsoon changes. Results agree with published proxies on the sign of discharge anomaly in 15 of 23 sites where comparison is possible.
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    Travel Time and Source Variation Explain the Molecular Transformation of Dissolved Organic Matter in an Alpine Stream Network (2020)
    Wiley-Blackwell
    In:  EPIC3JGR Biogeosciences, Wiley-Blackwell, ISSN: 2169-8961
    Details
    Publication Date: 2020-09-21
    Description: Streams and rivers are important components of the carbon cycle as they transport and transform dissolved organic matter (DOM). Using high‐resolution Fourier‐transform ion cyclotron resonance mass spectrometry, we studied the spatial distribution of DOM at the molecular level at more than 100 sites across a stream network during summer and winter baseflow. We developed a model approximating the time DOM spent in the fluvial network, a key constraint on the biogeochemical processing of DOM. Discharge‐weighted travel time explained the compositional changes of DOM, which differed markedly in summer and winter. We attribute these seasonal differences to variation in source material, putatively reflecting the dynamics of freshly produced DOM in summer and DOM with an imprint of leaf litter in winter. Hydrological mixing was an important driver of the spatial dynamics of DOM. From the convergence rate of DOM compound intensities to the network‐wide average, we inferred the spatial distribution of sources within the catchment. Finally, we estimated network‐wide apparent mass transfer coefficients (vf app) of individual DOM compounds, which describe the vertical velocity at which DOM compounds are removed by biotic and abiotic processes. We identified the oxidative state of carbon as an important factor explaining vf app, which we consequently attribute to biological uptake of thermodynamically favorable DOM compounds. This work contributes to our understanding of the spatial processes, temporal constraints, and chemical properties of DOM that regulate the transformation and diagenesis of DOM at the fluvial network scale.
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    Necessary Conditions for Warm Inflow Toward the Filchner Ice Shelf, Weddell Sea (2020)
    Wiley
    In:  EPIC3Geophysical Research Letters, Wiley, 47(22), pp. 1-11, ISSN: 0094-8276
    Details
    Publication Date: 2020-11-18
    Description: Understanding changes in Antarctic ice shelf basal melting is a major challenge for predicting future sea level. Currently, warm Circumpolar Deep Water surrounding Antarctica has limited access to the Weddell Sea continental shelf; consequently, melt rates at Filchner‐Ronne Ice Shelf are low. However, large‐scale model projections suggest that changes to the Antarctic Slope Front and the coastal circulation may enhance warm inflows within this century. We use a regional high‐resolution ice shelf cavity and ocean circulation model to explore forcing changes that may trigger this regime shift. Our results suggest two necessary conditions for supporting a sustained warm inflow into the Filchner Ice Shelf cavity: (i) an extreme relaxation of the Antarctic Slope Front density gradient and (ii) substantial freshening of the dense shelf water. We also find that the on‐shelf transport over the western Weddell Sea shelf is sensitive to the Filchner Trough overflow characteristics.
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    A changing Arctic Ocean: How measured and modeled 129129I distributions indicate fundamental shifts in circulation between 1994 and 2015 (2021)
    Wiley
    In:  EPIC3Journal of Geophysical Research-Oceans, Wiley, 126(3), ISSN: 0148-0227
    Details
    Publication Date: 2021-03-11
    Description: 129I measurements on samples collected during GEOTRACES oceanographic missions in the Arctic Ocean in 2015 have provided the first detailed, synoptic 129I sections across the Eurasian, Canada and Makarov Basins. During the 1990s, increased discharges of 129I from European nuclear fuel reprocessing plants produced a large, tracer spike whose passage through the Arctic Ocean has been followed by 129I time series measurements over the past 25 years. Elevated 129I levels measured over the Lomonosov and Alpha-Mendeleyev Ridges in 2015 were associated with tracer labeled, Atlantic-origin water bathymetrically steered by the ridge systems through the central Arctic while lower 129I levels were evident in the more poorly ventilated basin interiors. 129I levels of 200-400 x 107 at/l measured in intermediate waters in 2015 had increased by a factor of 10 compared to results from the same locations in 1994-1996 owing to the circulation of the 1990s, 129I input spike mainly associated with enhanced discharges from the La Hague nuclear fuel reprocessing plant. Comparisons of the patterns of 129I distributions between the mid-1990s and 2015 delineate large scale circulation changes that occurred during the shift from a positive Arctic Oscillation and a cyclonic circulation regime in the mid-1990s to anticyclonic circulation in 2015. The latter is characterized by a broadened Beaufort Gyre in the upper ocean, a weakened boundary current and partial mid-depth, AW flow reversal in the southern Canada Basin. Tracer 129I simulations using the applied circulation model, NAOSIM agree with both historical 129I results and recent GEOTRACES data sets, thereby lending context and credibility to the interpretation of large scale changes in arctic circulation and their relationship to shifts in climate indices revealed by tracer 129I distributions. This paper reports measurements and simulation results for 129I for the 1990s and 2015, and interprets them in the context of ocean circulation responses to changing atmospheric forcing regimes.
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    New Magnetostratigraphic Insights From Iceberg Alley on the Rhythms of Antarctic Climate During the Plio-Pleistocene (2021)
    Wiley
    In:  EPIC3Paleoceanography and Paleoclimatology, Wiley, 36(2), pp. 1-27, ISSN: 0883-8305
    Details
    Publication Date: 2021-02-25
    Description: International Ocean Discovery Program (IODP) Expedition 382 in the Scotia Sea’s Iceberg Alley recovered among the most continuous and highest resolution stratigraphic records in the Southern Ocean near Antarctica spanning the last 3.3 Myr. Sites drilled in Dove Basin (U1536/U1537) have well‐resolved magnetostratigraphy and a strong imprint of orbital forcing in their lithostratigraphy. All magnetic reversals of the last 3.3 Myr are identified, providing a robust age model independent of orbital tuning. During the Pleistocene, alternation of terrigenous versus diatomaceous facies shows power in the eccentricity and obliquity frequencies comparable to the amplitude modulation of benthic δ18O records. This suggests that variations in Dove Basin lithostratigraphy during the Pleistocene reflect a similar history as globally integrated ice volume at these frequencies. However, power in the precession frequencies over the entire ∼3.3 Myr record does not match the amplitude modulation of benthic δ18O records, suggesting Dove Basin contains a unique record at these frequencies. Comparing the position of magnetic reversals relative to local facies changes in Dove Basin and the same magnetic reversals relative to benthic δ18O at North Atlantic IODP Site U1308, we demonstrate Dove Basin facies change at different times than benthic δ18O during intervals between ∼3 and 1 Ma. These differences are consistent with precession phase shifts and suggest climate signals with a Southern Hemisphere summer insolation phase were recorded around Antarctica. If Dove Basin lithology reflects local Antarctic ice volume changes, these signals could represent ice sheet precession‐paced variations not captured in benthic δ18O during the 41‐kyr world.
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    Rapid Identification and Quantification of Microplastics in the Environment by Quantum Cascade Laser-Based Hyperspectral Infrared Chemical Imaging (2020)
    American Chemical Society
    In:  EPIC3Environmental Science & Technology, American Chemical Society, 54(24), pp. 15893-15903, ISSN: 0013-936X
    Details
    Publication Date: 2021-04-08
    Repository Name: EPIC Alfred Wegener Institut
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    Climatically modulated dust inputs from New Zealand to the Southwest Pacific sector of the Southern Ocean over the last 410 kyr (2021)
    Wiley
    In:  EPIC3Paleoceanography and Paleoclimatology, Wiley, pp. e2020PA003949
    Details
    Publication Date: 2021-04-01
    Description: Eolian mineral dust is an active agent in the global climate system. It affects planetary albedo and can influence marine biological productivity and ocean‐atmosphere carbon dynamics. This makes understanding of the global dust cycle crucial for constraining the dust/climate relationship, which requires long‐term dust emission records for all major dust sources. Despite their importance, the sources of atmospheric dust deposited in the Southern Ocean remain poorly constrained. Eolian dust in the Pacific sector of the Southern Ocean is generally assumed to originate from Australia, with minor contributions from New Zealand. Here we present a high‐resolution elemental record of terrestrial inputs for the past ∼410 kyr from marine sediment core PS75/100‐4 recovered from east of South Island, New Zealand. Sediment grain size is slightly finer than that of loess deposits from South Island, New Zealand, and is coarser than that of marine sediments in the Tasman Sea to the west of New Zealand, which indicates that the dust originated mainly from New Zealand and not only from Australia. Core PS75/100‐4 records lithogenic mass accumulation rates ranging from ∼0.01 to 0.69 g/cm2/kyr (∼0.20 g/cm2/kyr average), with variations over a factor of ∼3‐4 over glacial versus interglacial timescales for the past 410 kyr. Our geochemical data correlate well with Southern Ocean and Antarctic eolian dust records and suggest a westerly wind‐supplied dust signal from New Zealand. Our findings, therefore, suggest that New Zealand should be considered an important long‐term regional dust source in global dust cycle models.
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    Evidence for a highly dynamic West Antarctic Ice Sheet during the Pliocene (2021)
    Wiley
    In:  EPIC3Geophysical Research Letters, Wiley, 48, ISSN: 0094-8276
    Details
    Publication Date: 2021-07-20
    Repository Name: EPIC Alfred Wegener Institut
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    Detailed Seismic Bathymetry Beneath Ekström Ice Shelf, Antarctica: Implications for Glacial History and Ice‐Ocean Interaction (2020)
    Wiley
    In:  EPIC3Geophysical Research Letters, Wiley, 47, pp. e2019G, ISSN: 0094-8276
    Details
    Publication Date: 2020-08-03
    Description: The shape of ice shelf cavities are a major source of uncertainty in understanding ice‐ocean interactions. This limits assessments of the response of the Antarctic ice sheets to climate change. Here we use vibroseis seismic reflection surveys to map the bathymetry beneath the Ekström Ice Shelf, Dronning Maud Land. The new bathymetry reveals an inland‐sloping trough, reaching depths of 1,100 m below sea level, near the current grounding line, which we attribute to erosion by palaeo‐ice streams. The trough does not cross‐cut the outer parts of the continental shelf. Conductivity‐temperature‐depth profiles within the ice shelf cavity reveal the presence of cold water at shallower depths and tidal mixing at the ice shelf margins. It is unknown if warm water can access the trough. The new bathymetry is thought to be representative of many ice shelves in Dronning Maud Land, which together regulate the ice loss from a substantial area of East Antarctica.
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    Wintertime Airborne Measurements of Ice Nucleating Particles in the High Arctic: A Hint to a Marine, Biogenic Source for Ice Nucleating Particles (2020)
    Wiley
    In:  EPIC3Geophysical Research Letters, Wiley, 47, pp. 1-11, ISSN: 0094-8276
    Details
    Publication Date: 2020-09-14
    Description: Ice nucleating particles (INPs) affect the radiative properties of cold clouds. Knowledge concerning their concentration above ground level and their potential sources is scarce. Here we present the first highly temperature resolved ice nucleation spectra of airborne samples from an aircraft campaign during late winter in 2018. Most INP spectra featured low concentration levels (〈3 · 10−4 L−1 at −15°C). −2 −1 However, we also found INP concentrations of up to 1.8·10 L at −15°C and freezing onsets as high as −7.5°C for samples mainly from the marine boundary layer. Shape and onset temperature of the ice nucleation spectra of those samples as well as heat sensitivity hint at biogenic INP. Colocated measurements additionally indicate a local marine influence rather than long‐range transport. Our results suggest that even in late winter above 80°N a local marine source for biogenic INP, which can efficiently nucleate ice at high temperatures, is present. Clouds are a key factor in the energy budget of the Arctic atmosphere. Ice nucleating particles (INPs) can modify the radiation properties and lifetime of clouds by affecting the relative abundance of liquid and frozen droplets in a cloud. Despite this important ability, knowledge about the INP concentration above ground level is limited as airborne INP measurements are very scarce in the Arctic. Here we present results from an aircraft campaign, which took place during the late winter of 2018 in latitudes above 80°N. We found INP concentrations at above −15°C, which are similar to those found in midlatitudes. These INPs also initiate freezing already at high temperatures. We found indications that the INPs are biogenic and originate from a local, marine source, rather than being transported from midlatitudes into the Arctic. Due to the presence of numerous cracks, open leads and polynyas in the sea ice in the investigation area, the ocean may provide a source for these biogenic INP in an environment, where sources on land are still shrouded in snow and ice. However, in a warming Arctic contributions from different sources might change, making the characterization of the current state important.
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    Deposition history and paleo-current activity on the southeastern Lomonosov Ridge and its Eurasian flank based on seismic data (2020)
    Wiley
    In:  EPIC3Geochemistry, Geophysics, Geosystems, Wiley, 21, pp. #e2020GC009133
    Details
    Publication Date: 2020-11-01
    Description: A regional seismic survey on the southeastern Lomonosov Ridge and adjacent basins provides constraints on the coupled evolution of ocean circulations, depositional regime and tectonic processes. First, Mesozoic strata on the Lomonosov Ridge, its faulted flanks and the initial Amundsen Basin were covered with syn-rift sediments of Paleocene to early Eocene age. Numerous vertical faults indicate differential compaction of possibly anoxic sediments deposited in the young, still isolated Eurasian Basin. The second stage, as indicated by a prominent high-amplitude-reflector sequence (HARS) covering the ridge, was a time of widespread changes in deposition conditions, likely controlled by the ongoing subsidence of the Lomonosov Ridge and gradual opening of the Fram Strait. Episodic incursions of water masses from the North Atlantic probably were the consequences, and led to the deposition of thin sedimentary layers of different lithology. The third stage is marked by continuous deposition since the early Miocene (20 Ma). At that time, the ridge no longer posed an obstacle between the Amerasia and Eurasia Basins and pelagic sedimentation was established. Drift bodies, sediment waves, and erosional structures indicate the onset of circulation. Faulting on the ridge slope has led to a series of terraces where sediment drifts have accumulated since the early Miocene. It is suggested that ongoing sagging of the ridge and currents may have shaped the steep sediment free flanks of the terraces. Lastly, a sequence of high-amplitude reflectors marks the transition to the early Pliocene large-scale Northern Hemisphere glaciations.
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    Amplified Arctic Surface Warming and Sea Ice Loss Due to Phytoplankton and Colored Dissolved Material (2020)
    Wiley
    In:  EPIC3Geophysical Research Letters, Wiley, 47, pp. e2020GL088795, ISSN: 0094-8276
    Details
    Publication Date: 2020-11-16
    Description: Optically active water constituents attenuate solar radiation and hence affect the vertical distribution of energy in the upper ocean. To understand their implications, we operate an ocean biogeochemical model coupled to a general circulation model with sea ice. Incorporating the effect of phytoplankton and colored dissolved organic matter (CDOM) on light attenuation in the model increases the sea surface temperature in summer and decreases sea ice concentration in the Arctic Ocean. Locally, the sea ice season is reduced by up to one month. CDOM drives a significant part of these changes, suggesting that an increase of this material will amplify the observed Arctic surface warming through its direct thermal effect. Indirectly, changing advective processes in the Nordic Seas may further intensify this effect. Our results emphasize the phytoplankton and CDOM feedbacks on the Arctic ocean and sea ice system and underline the need to consider these effects in future modeling studies to enhance their plausibility.
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    COVID-19 crisis reduces free tropospheric ozone across the northern hemisphere (2021)
    Wiley
    In:  EPIC3Geophysical Research Letters, Wiley, 48(5), ISSN: 0094-8276
    Details
    Publication Date: 2021-03-04
    Description: Throughout spring and summer 2020, ozone stations in the northern extratropics recorded unusually low ozone in the free troposphere. From April to August, and from 1 to 8 kilometers altitude, ozone was on average 7% (≈4 nmol/mol) below the 2000 to 2020 climatological mean. Such low ozone, over several months, and at so many stations, has not been observed in any previous year since at least 2000. Atmospheric composition analyses from the Copernicus Atmosphere Monitoring Service and simulations from the NASA GMI model indicate that the large 2020 springtime ozone depletion in the Arctic stratosphere contributed less than one quarter of the observed tropospheric anomaly. The observed anomaly is consistent with recent chemistry-climate model simulations, which assume emissions reductions similar to those caused by the COVID-19 crisis. COVID-19 related emissions reductions appear to be the major cause for the observed reduced free tropospheric ozone in 2020.
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    Evolution of (Bio-)geochemical Processes and Diagenetic Alteration of Sediments Along the Tectonic Migration of Ocean Floor in the Shikoku Basin off Japan (2021)
    Wiley
    In:  EPIC3Geochemistry, Geophysics, Geosystems, Wiley
    Details
    Publication Date: 2021-06-30
    Description: Biogeochemical processes in subseafloor sediments are closely coupled to global element cycles. To improve the understanding of changes in biogeochemical conditions on geological timescales, we investigate sediment cores from a 1180 m deep hole in the Nankai Trough offshore Japan (Site C0023) drilled during International Ocean Discovery Program Expedition 370. During its tectonic migration from the Shikoku Basin to the Nankai Trough over the past 15 Ma, Site C0023 has experienced significant changes in depositional, thermal, and geochemical conditions. By combining pore-water, solid-phase, and rock magnetic data, we demonstrate that a transition from organic carbon-starved conditions with predominantly aerobic respiration to an elevated carbon burial environment with increased sedimentation occurred at ∼2.5 Ma. Higher rates of organic carbon burial in consequence of increased nutrient supply and productivity likely stimulated the onset of anaerobic electron-accepting processes during organic carbon degradation. A significant temperature increase by ∼50°C across the sediment column associated with trench-style sedimentation since ∼0.5 Ma could increase the bioavailability of organic matter and enhance biogenic methanogenesis. The resulting shifts in reaction fronts led to diagenetic transformation of iron (oxyhydr)oxides into pyrite in the organic carbon-starved sediments several millions of years after burial. We also show that high amounts of reducible iron(III) which can serve as electron acceptor for microbial iron(III) reduction are preserved and still available as phyllosilicate-bound Fe. This is the first study that shows the evolution of long-term variations of (bio-)geochemical processes along tectonic migration of ocean floor, thereby altering the primary sediment composition long after deposition.
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    Bathymetry beneath ice shelves of western Dronning Maud Land, East Antarctica, and implications on ice shelf stability (2020)
    Wiley
    In:  EPIC3Geophysical Research Letters, Wiley, 47(12), pp. e2019GL086724, ISSN: 0094-8276
    Details
    Publication Date: 2020-09-06
    Description: Antarctica's ice shelves play a key role in stabilizing the ice streams that feed them. Since basal melting largely depends on ice‐ocean interactions, it is vital to attain consistent bathymetry models to estimate water and heat exchange beneath ice shelves. We have constructed bathymetry models beneath the ice shelves of western Dronning Maud Land by inverting airborne gravity data, and incorporating seismic, multibeam and radar depth references. Our models reveal deep glacial troughs beneath the ice shelves and terminal moraines close to the continental shelf breaks, which currently limit the entry of Warm Deep Water from the Southern Ocean. The ice shelves buttress a catchment that comprises an ice volume equivalent to nearly 1 meter of eustatic sea level rise, partly susceptible to ocean forcing. Changes in water temperature and thermocline depth may accelerate marine based ice sheet drainage and constitute an underestimated contribution to future global sea level rise.
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    Antarctic Sea Ice Area in CMIP6 (2020)
    Wiley
    In:  EPIC3Geophysical Research Letters, Wiley, 47(9), ISSN: 0094-8276
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    Publication Date: 2020-06-02
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    Regionally coupled atmosphere - ocean - marine biogeochemistry model ROM: 2. Studying the climate change signal in the North Atlantic and Europe (2020)
    Wiley
    In:  EPIC3Journal of Advances in Modeling Earth Systems, Wiley, n/a(n/a), pp. e2019MS001646, ISSN: 1942-2466
    Details
    Publication Date: 2020-07-06
    Description: Climate simulations for the North Atlantic and Europe for recent and future conditions simulated with the regionally coupled ROM model are analyzed and compared to the results from the MPI‐ESM. The ROM simulations also include a biogeochemistry and ocean tides. For recent climate conditions, ROM generally improves the simulations compared to the driving model MPI‐ESM. Reduced oceanic biases in the Northern Atlantic are found, as well as a better simulation of the atmospheric circulation, notably storm tracks and blocking. Regarding future climate projections for the 21st century following the RCP 4.5 and 8.5 scenarios, MPI‐ESM and ROM largely agree qualitatively on the climate change signal over Europe. However, many important differences are identified. For example, ROM shows an SST cooling in the Subpolar Gyre which is not present in MPI‐ESM. Under the RCP8.5 scenario, ROM Arctic sea ice cover is thinner and reaches the seasonally ice‐free state by 2055, well before MPI‐ESM. This shows the decisive importance of higher ocean resolution and regional coupling for determining the regional responses to global warming trends. Regarding biogeochemistry, both ROM and MPI‐ESM simulate a widespread decline in winter nutrient concentration in the North Atlantic of up to ~35%. On the other hand, the phytoplankton spring bloom in the Arctic and in the North‐Western Atlantic starts earlier and the yearly primary production is enhanced in the Arctic in the late 21st century. These results clearly demonstrate the added value of ROM to determine more detailed and more reliable climate projections at the regional scale.
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    Eddy Kinetic Energy in the Arctic Ocean From a Global Simulation With a 1‐km Arctic (2020)
    Wiley
    In:  EPIC3Geophysical Research Letters, Wiley, 47(14), ISSN: 0094-8276
    Details
    Publication Date: 2020-07-28
    Description: Simulating Arctic Ocean mesoscale eddies in ocean circulation models presents a great challenge because of their small size. This study employs an unstructured‐mesh ocean‐sea ice model to conduct a decadal‐scale global simulation with a 1‐km Arctic. It provides a basinwide overview of Arctic eddy energetics. Increasing model resolution from 4 to 1 km increases Arctic eddy kinetic energy (EKE) and total kinetic energy (TKE) by about 40% and 15%, respectively. EKE is the highest along main currents over topography slopes, where strong conversion from available potential energy to EKE takes place. It is high in halocline with a maximum typically centered in the depth range of 70–110 m, and in the Atlantic Water layer of the Eurasian Basin as well. The seasonal variability of EKE along the continental slopes of southern Canada and eastern Eurasian basins is similar, stronger in fall and weaker in spring.
    Repository Name: EPIC Alfred Wegener Institut
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  • 41
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    Meta-analysis of multiple driver effects on marine phytoplankton highlights modulating role of pCO2 (2020)
    Wiley
    In:  EPIC3Global Change Biology, Wiley, 26(12), pp. 6787-6804
    Details
    Publication Date: 2020-11-23
    Description: Responses of marine primary production to a changing climate are determined by a concert of multiple environmental changes, for example in temperature, light, pCO2, nutrients, and grazing. To make robust projections of future global marine primary production, it is crucial to understand multiple driver effects on phytoplankton. This meta-analysis quantifies individual and interactive effects of dual driver combinations on marine phytoplankton growth rates. Almost 50% of the single-species laboratory studies were excluded because central data and metadata (growth rates, carbonate system, experimental treatments) were insufficiently reported. The remaining data (42 studies) allowed for the analysis of interactions of pCO2 with temperature, light, and nutrients, respectively. Growth rates mostly respond non-additively, whereby the interaction with increased pCO2 profusely dampens growth-enhancing effects of high temperature and high light. Multiple and single driver effects on coccolithophores differ from other phytoplankton groups, especially in their high sensitivity to increasing pCO2. Polar species decrease their growth rate in response to high pCO2, while temperate and tropical species benefit under these conditions. Based on the observed interactions and projected changes, we anticipate primary productivity to: (a) first increase but eventually decrease in the Arctic Ocean once nutrient limitation outweighs the benefits of higher light availability; (b) decrease in the tropics and mid-latitudes due to intensifying nutrient limitation, possibly amplified by elevated pCO2; and (c) increase in the Southern Ocean in view of higher nutrient availability and synergistic interaction with increasing pCO2. Growth-enhancing effect of high light and warming to coccolithophores, mainly Emiliania huxleyi, might increase their relative abundance as long as not offset by acidification. Dinoflagellates are expected to increase their relative abundance due to their positive growth response to increasing pCO2 and light levels. Our analysis reveals gaps in the knowledge on multiple driver responses and provides recommendations for future work on phytoplankton.
    Repository Name: EPIC Alfred Wegener Institut
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  • 42
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    Dropstones in the Mar del Plata Canyon Area (SW Atlantic): Evidence for Provenance, Transport, Distribution, and Oceanographic Implications (2020)
    Wiley
    In:  EPIC3Geochemistry Geophysics Geosystems, Wiley, 22, ISSN: 1525-2027
    Details
    Publication Date: 2021-01-28
    Repository Name: EPIC Alfred Wegener Institut
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  • 43
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    Ammonium in Antarctic aerosol: Marine biological activity versus long-range transport of biomass burning (2021)
    Wiley
    In:  EPIC3Geophysical Research Letters, Wiley, 48, pp. e2021GL092826, ISSN: 0094-8276
    Details
    Publication Date: 2021-06-14
    Description: Year-round records of the ionic composition of Antarctic aerosol were obtained at the inland Dome C (DC) and coastal Neumayer (NM) sites, with additional observations of black carbon at NM. Discussions focus on the origin of ammonium in Antarctica. This first Antarctic atmospheric study of several species emitted by biomass burning indicates that black carbon, oxalate, and fine potassium reach a maximum in October in relation to biomass burning activity in the southern hemisphere. Ammonium reaches a maximum two months later, suggesting that biomass burning remains a minor ammonium source there. The ammonium maximum in December coincides with the occurrence of diatom blooms in the austral ocean, suggesting that oceanic ammonia emissions are the main source of ammonium in Antarctica. The ammonium to sulfur-derived biogenic species molar ratio of 0.15 in summer suggests far lower ammonia emissions from the Antarctic oceans than mid-latitude southern oceans.
    Repository Name: EPIC Alfred Wegener Institut
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  • 44
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    Seasonality in Saharan Dust Across the Atlantic Ocean: From Atmospheric Transport to Seafloor Deposition (2021)
    Wiley
    In:  EPIC3Journal of Geophysical Research-Atmospheres, Wiley, 126, ISSN: 0148-0227
    Details
    Publication Date: 2021-06-25
    Description: Saharan dust is transported in great quantities from the North African continent every year, most of which is deposited across the North Atlantic Ocean. This dust impacts regional and global climate by affecting the atmospheric radiation balance and altering ocean carbon budgets. However, little research has been carried out on time series of Saharan dust collected in situ across the open Atlantic. Here, we present a unique three-year time series of Saharan dust along a trans-Atlantic transect, sampled by moored surface buoys and subsurface sediment traps. Results show a good correlation between the particle-size distributions of atmospheric dust and the lithogenic particles settling to the deep ocean floor, confirming the aeolian origin of the lithogenic particles intercepted by the subsurface sediment traps, even in the distal western part of the Atlantic Ocean. Dust from both dry and wet deposition as collected by the sediment traps, shows increased deposition fluxes and coarser grain size in summer and/or autumn that coincides with increased precipitation at the sampling sites as derived from satellite data. In contrast, both buoys that sampled dust during transport at sea level show little seasonal variation in both concentration and particle size, as the large amounts of dust transported in summer and early autumn at high altitudes are far above their sampling range. This implies that wet deposition in summer and autumn defines the typical seasonal trends of both the dust deposition flux and its particle-size distribution observed in the sediment traps.
    Repository Name: EPIC Alfred Wegener Institut
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  • 45
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    Production of giant marine diatoms and their export at oceanic frontal zones: Implications for Si and C flux from stratified oceans (2006)
    Wiley
    In:  EPIC3Global Biogeochemical Cycles, Wiley, 20(4), ISSN: 0886-6236
    Details
    Publication Date: 2016-01-18
    Description: From a synthesis of recent oceanic observations and paleo-data it is evident that certain species of giant diatoms including Rhizosolenia spp. Thalassiothrix spp. and Ethmodiscus rex may become concentrated at oceanic frontal zones and subsequently form episodes of mass flux to the sediment. Within the nutrient bearing waters advecting towards frontal boundaries, these species are generally not dominant, but they appear selectively segregated at fronts, and thus may dominate the export flux. Ancient Thalassiothrix diatom mat deposits in the eastern equatorial Pacific and beneath the Polar Front in the Southern Ocean record the highest open ocean sedimentation rates ever documented and represent vast sinks of silica and carbon. Several of the species involved are adapted to a stratified water column and may thrive in Deep Chlorophyll Maxima. Thus in oceanic regions and/or at times prone to enhanced surface water stratification (e.g., during meltwater pulses) they provide a mechanism for generating substantial biomass at depth and its subsequent export with concomitant implications for Si export and C drawdown. This ecology has important implications for ocean biogeochemical models suggesting that more than one diatom “functional type” should be used. In spite of the importance of these giant diatoms for biogeochemical cycling, their large size coupled with the constraints of conventional oceanographic survey schemes and techniques means that they are undersampled. An improved insight into these key species will be an important prerequisite for enhancing our understanding of marine biogeochemical cycling and for assessing the impacts of climate change on ocean export production.
    Repository Name: EPIC Alfred Wegener Institut
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  • 46
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    Blackening of Pompeian Cinnabar paintings: X-ray micro-spectroscopy analysis (2007)
    American Chemical Society
    Details
    Publication Date: 2017-04-04
    Description: Red Pompeian paintings, very famous for their deep intensity, are currently suffering from darkening. The origins of this darkening degradation are not clearly identified yet and remain a major issue for curators. In the specific case of cinnabar (HgS)-based red pigment, a photoinduced conversion into black metacinnabar is usually suspected. This work is focused on the blackening of red cinnabar paintings coated on a sparry calcite mortar. Different samples exhibiting different levels of degradation were selected upon visual observations and analyzed by synchrotron-based microanalytical techniques. Atomic and molecular compositions of the different debased regions revealed two possible degradation mechanisms. On one hand, micro X-ray fluorescence elemental maps show peculiar distributions of chlorine and sulfur. On the other hand, X-ray absorption spectroscopy performed at both Cl and S K-edges confirms the presence of characteristic degradation products: (i) Hg- Cl compounds (e.g., corderoite, calomel, and terlinguaite), which may result from the reaction with exogenous NaCl, in gray areas; (ii) gypsum, produced by the calcite sulfation, in black coatings. Metacinnabar is never detected. Finally, a cross section was analyzed to map the in-depth alteration gradient. Reduced and oxidized sulfur distributions reveal that the sulfated black coating consists of a 5-ím-thick layer covering intact cinnabar.
    Description: Published
    Description: 7484-7492
    Description: reserved
    Keywords: Microspectroscopy Analysis ; 05. General::05.09. Miscellaneous::05.09.99. General or miscellaneous
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  • 47
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    Evidence of seismic deformation of the paved floor of the decumanus at Tindari (NE, Sicily) (2008)
    Blackwell Publishing Ltd
    Details
    Publication Date: 2017-04-04
    Description: Most of the ancient town of Tindari (NE, Sicily) was settled on a plateau the most surficial layer of which was made of unconsolidated material. Ongoing excavations at the archaeological site at Tindari uncovered a large portion of the decumanus which suffered deformations preliminarily assigned to coseismic effects. An analysis of the local dynamic response through the simulation of strong seismic shaking to the bedrock and modelling of spectral ratios of the bedrock-soft soil was carried out to verify the susceptibility of superficial terrains of the promontory to coseismic deformations. To perform this simulation the finite element method (FEM) was used. Four accelerometric recordings of three earthquakes of medium-high magnitude, recorded on rocky sites, were chosen to simulate the seismic shaking, using a constitutive law for the materials composing the promontory layers both of linear-elastic type and of elastoplastic type. The analysis of the linear-elastic field allowed the definition of the frequencies for which the spectral ratios of the accelerations recorded the highest amplifications; in particular the frequency range 31.5–37.2 Hz can be combined with deformation of the paved floor of the decumanus. The analysis in the elastoplastic field highlighted the zones of promontory more susceptible to suffer plasticization process. The results show that the topmost layer of the decumanus is the most susceptible to suffer plasticization. Therefore, the performed analysis lends greater support to the hypothesis that the deformations were produced by seismic shaking.
    Description: Published
    Description: 213-222
    Description: 3.10. Sismologia storica e archeosismologia
    Description: JCR Journal
    Description: reserved
    Keywords: Fourier analysis ; Elasticity and anelasticity ; Earthquake ground motions ; Site effects ; Computational seismology ; 04. Solid Earth::04.06. Seismology::04.06.99. General or miscellaneous ; 04. Solid Earth::04.06. Seismology::04.06.05. Historical seismology
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  • 48
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    Tectonic features of the Lipari–Vulcano complex (Aeolian archipelago, Italy) from 10 years (1996–2006) of GPS data (2008)
    Blackwell Publishing Ltd
    Details
    Publication Date: 2017-04-04
    Description: The tectonic deformation of the Lipari-Vulcano complex, one of the most important active volcanic areas of Mediterranean region, is studied here through the analysis of ten years (1996-2006) of GPS data from both 3 permanent and 13 non-permanent stations. This area can be considered crucial for the understanding of the Eurasia-Africa plates interaction in the Mediterranean area, and, in general, this work emphasize a methodological approach, already applied in other areas worldwide (e.g. Shen et al., 1996, El-Fiki and Kato, 1999) where geodetic data and strain parameters maps of critical areas can help to improve our understanding of their geodynamical aspects. In this framework, this study is aimed at providing a kinematic deformation model on the basis of the dense geodetically estimated velocities of the Lipari-Vulcano complex. In particular, the observed deformation pattern can be described by a mix between 1) the main N-S regional compression and 2) a NNE-SSW compression with a small right-lateral strike slip component acting along a tectonic structure N°40W trending located between the two islands. This pattern was inspected through a simplified synthetic model.
    Description: This research has benefited from funding provided by the Italian Presidenza del Consiglio dei Ministri – Dipartimento della Protezione Civile (DPC).
    Description: Published
    Description: 370–377
    Description: 1.9. TTC - Rete GPS nazionale
    Description: JCR Journal
    Description: reserved
    Keywords: GPS ; Aeolian Islands ; strain ; modelling ; 04. Solid Earth::04.03. Geodesy::04.03.01. Crustal deformations
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 49
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    Gas hazard assessment at the Monticchio Mt. Vulture, a volcano in Southern Italy (2009)
    Wiley-Blackwell
    Details
    Publication Date: 2017-04-04
    Description: Geochemical investigations have shown that there is a considerable inflow of gas into both crater lakes of Monticchio, Southern Italy. These lakes are located in two maars that formed 140 000 years ago during Mt. Vulture volcano s last eruptive activity. Isotopic analyses suggest that CO2 and helium are of magmatic origin; the latter displays 3He ⁄ 4He isotope ratios similar to those measured in olivines of the maar ejecta. In spite of the fact that the amount of dissolved gases in the water is less than that found in Lake Nyos (Cameroon), both the results obtained and the historical reports studied indicate that these crater lakes could be highly hazardous sites, even though they are located in a region currently considered inactive. This could be of special significance in very popular tourist areas such as the Monticchio lakes, which are visited by about 30 000 people throughout the summer, for the most part on Sundays.
    Description: Published
    Description: 83-87
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: JCR Journal
    Description: reserved
    Keywords: volcanic gases ; gas hazard ; crater lakes ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
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  • 50
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    Seismic moment tensors of the April 2009, L’Aquila (Central Italy), (2009)
    Wiley-Blackwell
    Details
    Publication Date: 2017-04-04
    Description: On 2009 April 6, the Central Apennines were hit by an Mw = 6.3 earthquake. The region had been shaken since 2008 October by seismic activity that culminated in two foreshocks with Mw 〉 4, 1 week and a few hours before the main shock. We computed seismic moment tensors for 26 events with Mw between 3.9 and 6.3, using the Regional Centroid Moment Tensor (RCMT) scheme. Most of these source parameters have been computed within 1 hr after the earthquake and rapidly revised successively. The focal mechanisms are all extensional, with a variable and sometimes significant strike-slip component. This geometry agrees with the NE–SW extensional deformation of the Apennines, known from previous seismic and geodetic observations. Events group into three clusters. Those located in the southern area have larger centroid depths and a wider distribution of T-axis directions. These differences suggest that towards south a different fault systemwas activated with respect to the SW-dipping normal faults beneath L’Aquila and more to the north.
    Description: In press
    Description: 1.1. TTC - Monitoraggio sismico del territorio nazionale
    Description: JCR Journal
    Description: open
    Keywords: moment tensor ; seismotectonics ; L'Aquila ; 04. Solid Earth::04.07. Tectonophysics::04.07.04. Plate boundaries, motion, and tectonics
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  • 51
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    P-wave propagation heterogeneity and earthquake location in the Mediterranean region (2008)
    Blackwell Publishing Ltd
    Details
    Publication Date: 2012-02-03
    Description: We analyse P-wave traveltimes for the Mediterranean area, using both teleseismic and regional arrivals for shallow earthquakes reported in the Bulletins of the International Seismological Centre. We model delays between pairs of 0.5° × 0.5° cells, obtaining a detailed representation of the P traveltime heterogeneities. Examination of these anomalies shows the clear presence of geographically coherent patterns—consistent with known geological features—due to significant structure in the upper mantle. We present a scheme, based on an empirical heterogeneity correction (EHC) to P-wave traveltimes, to improve earthquake location. This method provides similar benefits to those of a location procedure based on ray tracing in a 3-D model, but it is simpler and computationally more efficient. The definition of the traveltime heterogeneity model, being based on a statistical procedure, bypasses most of the critical points and possible instabilities involved in model inversion. EHC relocation, applied to Mediterranean earthquakes, allows one to predict about 70 per cent of the estimated signal due to heterogeneity and produces epicentral and origin time-shifts of, respectively, 4.22 km and 0.35 s (rms). From a synthetic experiment, in which we use the proposed algorithm to retrieve known source locations, we estimate that the rms improvement achieved by the EHC relocation over a simpler, standard, 1-D location is more than 20 per cent for both epicentral mislocation and origin time-shifts.
    Description: Published
    Description: 232-254
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: JCR Journal
    Description: reserved
    Keywords: earthquake location ; Mediterranean ; P waves ; traveltime ; upper mantle ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics
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  • 52
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    New results of 40Ar/39Ar dating constrain the timing of transition from fissure-type to central volcanism at Mount Etna (Italy) (2008)
    Blackwell Publishing Ltd
    Details
    Publication Date: 2017-04-04
    Description: Recent geological studies performed at Etna allow reassessing the stratigraphic frame of the volcano where distinct evolutionary phases are defined. This stratigraphic reconstruction was chronologically constrained on the basis of a limited number of U–Th and K–Ar age determinations whose uncertainty margins are sometimes too wide. For this reason, we successfully adopted at Etna the 40Ar/39Ar technique that allowed obtaining more precise age determinations. The incremental heating technique also gives information on sample homogeneity, and potential problems of trapped argon. Five samples were collected from stratigraphically well-controlled volcanic units in order to chronologically define the transition between the fissure-type volcanism of the Timpe phase to the central volcanism of the Valle del Bove Centers. Isotopic ages with an uncertainty margin of 2–4% have been obtained emphasizing that this transition occurred (130– 126 ka) without significant temporal hiatus.
    Description: University of Catania grants (COFIN- 2002, resp. F. Lentini); CNR-IDPA and INGV-Sezione di Catania grants.
    Description: Published
    Description: 292-298
    Description: 3.5. Geologia e storia dei sistemi vulcanici
    Description: JCR Journal
    Description: reserved
    Keywords: 40Ar/39Ar dating ; Etna ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous
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  • 53
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    Methane seepage in an urban development area (Bacau, Romania): origin, extent, and hazard (2008)
    Blackwell Publishing Ltd
    Details
    Publication Date: 2017-04-04
    Description: The paper describes a case of a natural emission of methane from soil in an urban development area, generating a significant risk for the local population and buildings, due to gas explosiveness and asphyxiation potential. The site is located on the south-western margin of the East-European Platform in eastern Romania, in a hydrocarbon-prone area crossed by the Pericarpathian lineament and regional faults. Molecular composition of gas and stable isotopic analyses of methane (CH4〉90%, δ to the power of 13 C1: -49.4‰, δD1: -173.4‰) indicate a dominant thermogenic origin, with significant amounts of C2-C5 alkanes (~5%), likely migrating through faults from a deep reservoir. Possible candidates are the Saucesti and Secuieni gas fields, located in the same petroleum system. Two surface geochemical surveys, based on closed-chamber flux measurements, were performed to assess the degassing intensity and the extent of the affected area. Methane fluxes from soil reach orders of 10 to the power of 4 mg m to the power of -2 day to the power of -1. Gas seepage mainly occurs in one zone 30 000 m2 wide, and it is likely controlled by channeling along a fault and gas accumulation in permeable sediments and shallow subsoil. The estimated total CH4 emission is about 40 t year to the power of -1 CH4, of which 8–9 t year to the power of -1 are naturally released from soil and 30–35 t year to the power of -1 are emitted from shallow boreholes. These wells have likely channeled the gas accumulated in shallow alluvial sediment but gas flux from soil is still high and mitigation measures are needed to reduce the risk for humans and buildings.
    Description: Published
    Description: 311-320
    Description: 3.8. Geofisica per l'ambiente
    Description: JCR Journal
    Description: reserved
    Keywords: gas hazard ; methane seepage ; soil degassing ; thermogenic gas ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases
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  • 54
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    New evidence for a mixed inorganic and organic origin of the Olympic Chimaera fire (Turkey): a large onshore seepage of abiogenic gas (2008)
    Blackwell Publishing Ltd
    Details
    Publication Date: 2017-04-04
    Description: The Chimaera gas seep, near Antalya (SW Turkey), has been continuously active for thousands of years and it is known to be the source of the first Olympic fire in the Hellenistic period. New and thorough molecular and isotopic analyses including methane (approximately 87% v/v; δ to the power of 13 C1 from -7.9‰ to -12.3‰; δ to the power of 13 D1 from -119‰ to -124‰), light alkanes (C2 + C3 + C4 + C5 = 0.5%; C6+: 0.07%; δ to the power of 13 C2 from -24.2‰ to -26.5‰; δ to the power of 13 C3 from -25.5‰ to -27‰), hydrogen (7.5–11%), carbon dioxide (0.01–0.07%; δ to the power of 13 CCO2: -15‰), helium (approximately 80 ppmv; R/Ra: 0.41) and nitrogen (2–4.9%; δ to the power of 15 N from -2‰ to -2.8‰) converge to indicate that the seep releases a mixture of organic thermogenic gas, related to mature type III kerogen occurring in Palaeozoic and Mesozoic organic-rich sedimentary rocks, and abiogenic gas produced by low-temperature serpentinization in the Tekirova ophiolitic unit. Methane is not related to mantle or magma degassing. The abiogenic fraction accounts for about half of the total gas released, which is estimated to be well beyond 50 ton year to the power of -1. Ophiolites and limestones are in contact along a tectonic dislocation leading to gas mixing and migration to the Earth’s surface. Chimaera represents the biggest emission of abiogenic methane on land discovered so far. Deep and pressurized gas accumulations are necessary to sustain the Chimaera gas flow for thousands of years and are likely to have been charged by an active inorganic source.
    Description: Published
    Description: 263-273
    Description: 3.8. Geofisica per l'ambiente
    Description: JCR Journal
    Description: reserved
    Keywords: abiogenic methane ; isotopic composition ; ophiolites ; seep ; serpentinization ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases
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  • 55
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    Multiple hydro-fracturing by boron-rich fluids in the Late Miocene contact aureole of eastern Elba Island (Tuscany, Italy) (2008)
    Blackwell Publishing Ltd
    Details
    Publication Date: 2017-04-04
    Description: In eastern Elba Island (Tuscany, Italy), a shallow crustal level felsic, tourmaline-bearing, dyke-sill swarm of Late Miocene age is associated with abundant tourmaline-quartz hydrothermal veins and metasomatic masses. Development of these veins and masses in the host rocks demonstrates multiple hydro-fracturing by magmatic, boron-rich saline fluid. Tourmalines in felsic dykes are schorl, whereas in veins and metasomatic masses, tourmaline composition ranges from schorl-dravite through dravite to uvite. This compositional shift is evidence for an increasing contribution to the magmatic boron-rich fluids by a Mg-Ca-Ti-rich external component represented by biotite-rich and amphibolite host rocks. This system can be envisaged as an exposed proxy of the high temperature hydrothermal system presently active in the deepest part of the Larderello-Travale geothermal field (Tuscany).
    Description: Published
    Description: 318-326
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: 3.5. Geologia e storia dei sistemi vulcanici
    Description: JCR Journal
    Description: reserved
    Keywords: Hydro-fractures ; geothermal systems ; Magmatism ; southern Tuscany ; 04. Solid Earth::04.01. Earth Interior::04.01.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology
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  • 56
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    The Mw 6.3, 2009 L’Aquila earthquake: source, path and site effects from spectral analysis of strong motion data (2009)
    Wiley-Blackwell
    Details
    Publication Date: 2017-04-04
    Description: The strong motion data of 2009 April 6 L’Aquila (Central Italy) earthquake (Mw = 6.3) and of 12 aftershocks (4.1 ≤ Mw ≤ 5.6) recorded by 56 stations of the Italian strong motion network are spectrally analysed to estimate the source parameters, the seismic attenuation, and the site amplification effects. The obtained source spectra for S wave have stress drop values ranging from 2.4 to 16.8 MPa, being the stress drop of the main shock equal to 9.2 MPa. The spectral curves describing the attenuation with distance show the presence of shoulders and bumps, mainly around 50 and 150 km, as consequence of significant reflected and refracted arrivals from crustal interfaces. The attenuation in the first 50 km is well described by a quality factor equal to Q( f ) = 59 f 0.56 obtained by fixing the geometrical spreading exponent to 1. Finally, the horizontal-to-vertical spectral ratio provides unreliable estimates of local site effects for those stations showing large amplifications over the vertical component of motion.
    Description: Published
    Description: 1573–1579
    Description: 4.1. Metodologie sismologiche per l'ingegneria sismica
    Description: JCR Journal
    Description: open
    Keywords: Generalized inversion ; strong-motion ; 04. Solid Earth::04.06. Seismology::04.06.04. Ground motion
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  • 57
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    New Developments in the PuffinPlot Paleomagnetic Data Analysis Program (2020)
    Wiley
    Details
    Publication Date: 2020-03-06
    Description: PuffinPlot is a program for paleomagnetic data analysis and plotting, first released in 2012 and under continuous development since then. It is free, cross‐platform software and provides both a graphical desktop interface for interactive use and an application‐programmer interface for scripting. We present a major new release of the program, describe significant new features added since the first release, and demonstrate their application to real‐world data. New features include automatic magnetic declination realignment, relative paleointensity calculation, virtual geomagnetic pole determination, calculation of inclination‐only statistics, support for reproducible research via the export of self‐contained data bundles, and support for reading a number of popular paleomagnetic file formats. We also discuss the application of unit tests in ensuring PuffinPlot's long‐term reliability and outline directions for future development of the software.
    Description: Published
    Description: 5578-5587
    Description: 1A. Geomagnetismo e Paleomagnetismo
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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    Fine‐Scale Structure of the 2016–2017 Central Italy Seismic Sequence From Data Recorded at the Italian National Network (2020)
    Wiley
    Details
    Publication Date: 2020-05-25
    Description: We explore the three‐dimensional structure of the 2016–2017 Central Italy sequence using ~34,000 ML ≥ 1.5 earthquakes that occurred between August 2016 and January 2018. We applied cross‐correlation and double‐difference location methods to waveform and parametric data routinely produced at the Italian National Institute of Geophysics and Volcanology. The sequence activated an 80 km long system of normal faults and near‐horizontal detachment faults through the MW 6.0 Amatrice, the MW 5.9 Visso, and the MW 6.5 Norcia mainshocks and aftershocks. The system has an average strike of N155°E and dips 38°–55° southwestward and is segmented into 15–30 km long faults individually activated by the cascade of MW ≥ 5.0 shocks. The two main normal fault segments, Mt. Vettore‐Mt. Bove to the North and Mt. della Laga to the South, are separated by an NNE‐SSW‐trending lateral ramp of the Sibillini thrust, a regional structure inherited from the previous compressional tectonic phase putting into contact diverse lithologies with different seismicity patterns. Space‐time reconstruction of the fault system supports a composite rupture scenario previously proposed for the MW 6.5 Norcia earthquake, where the rupture possibly propagated also along an oblique portion of the Sibillini thrust. This dissected set of normal fault segments is bounded at 8–10 km depth by a continuous 2 km thick seismicity layer of extensional nature slightly dipping eastward and interpreted as a shear zone. All three mainshocks in the sequence nucleated along the high‐angle planes at significant distance from the shear zone, thus complicating the interpretation of the mechanisms driving strain partitioning between these structures.
    Description: Published
    Description: e2019JB018440
    Description: 3T. Sorgente sismica
    Description: JCR Journal
    Keywords: normal fault ; shear zone ; fault segmentation ; apennines ; 04.06. Seismology
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    Active Extension in a Foreland Trapped Between Two Contractional Chains: The South Apulia Fault System (SAFS) (2020)
    Wiley
    Details
    Publication Date: 2020-07-08
    Description: The response of continental forelands to subduction and collision is a widely investigated topic in geodynamics. The deformation occurring within a foreland shared by two opposite‐verging chains, however, is uncommon and poorly understood. The Apulia Swell in the southern end of the Adria microplate (Africa‐Europe plate boundary, central Mediterranean Sea) represents one of these cases, as it is the common foreland of the SW verging Albanides‐Hellenides and the NE verging Southern Apennines merging into the SSE verging Calabrian Arc. We investigated the internal deformation of the Apulia Swell using multiscale geophysical data: multichannel seismic profiles recording up to 12‐s two‐way time (TWT) for a consistent image of the upper crust; high‐resolution multichannel seismic profiles, high‐resolution multibeam bathymetry, and CHIRP profiles acquired by R/V OGS Explora to constrain the Quaternary geological record. The results of our analyses characterize the geometry of the South Apulia Fault System (SAFS), a 100‐km‐long and 12‐km‐wide structure attesting an extensional (and possibly transtensional) response of the foreland to the two contractional fronts. The SAFS consists of two NW‐SE right‐stepping master faults and several secondary structures. The SAFS activity spans from the Early Pleistocene through the Holocene, as testified by the bathymetric and high‐resolution seismic data, with long‐term slip rates in the range of 0.2–0.4 mm/yr. Considering the position within an area with few or none other active faults in the surroundings, the dimension, and the activity rates, the SAFS can be a candidate causative fault of the 20 February 1743, M 6.7, earthquake.
    Description: Italian Ministry for Education, University, and Research (MIUR), Premiale 2014 D. M. 291 03/05/2016.
    Description: Published
    Description: e2020TC006116
    Description: 2T. Deformazione crostale attiva
    Description: 2TR. Ricostruzione e modellazione della struttura crostale
    Description: JCR Journal
    Keywords: active tectonics ; apulia ; south apulia fault system ; 1743 earthquake ; marine geology ; stable continental region ; ionian sea ; active faults ; subsurface geology ; seismic interpretation ; 04.04. Geology ; 04.07. Tectonophysics ; 04.02. Exploration geophysics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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    Evaluating learning spaces in flood risk management in Germany: Lessons for governance research (2021)
    Blackwell Publishing Ltd | Oxford, UK
    Details
    Publication Date: 2021-06-28
    Description: Efforts to collaboratively manage the risk of flooding are ultimately based on individuals learning about risks, the decision process, and the effectiveness of decisions made in prior situations. This article argues that much can be learned about a governance setting by explicitly evaluating the relationships through which influential individuals and their immediate contacts receive and send information to one another. We define these individuals as “brokers,” and the networks that emerge from their interactions as “learning spaces.” The aim of this article is to develop strategies to identify and evaluate the properties of a broker's learning space that are indicative of a collaborative flood risk management arrangement. The first part of this article introduces a set of indicators, and presents strategies to employ this list so as to systematically identify brokers, and compare their learning spaces. The second part outlines the lessons from an evaluation that explored cases in two distinct flood risk management settings in Germany. The results show differences in the observed brokers' learning spaces. The contacts and interactions of the broker in Baden‐Württemberg imply a collaborative setting. In contrast, learning space of the broker in North Rhine‐Westphalia lacks the same level of diversity and polycentricity.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: MWK Baden‐Württemberg
    Keywords: 333.91 ; brokerage ; collaborative water governance ; comanagement ; comparative analysis ; social networks
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    Synthetic resampling strategies and machine learning for digital soil mapping in Iran (2021)
    Blackwell Publishing Ltd | Oxford, UK
    Details
    Publication Date: 2021-07-04
    Description: Most common machine learning (ML) algorithms usually work well on balanced training sets, that is, datasets in which all classes are approximately represented equally. Otherwise, the accuracy estimates may be unreliable and classes with only a few values are often misclassified or neglected. This is known as a class imbalance problem in machine learning and datasets that do not meet this criterion are referred to as imbalanced data. Most datasets of soil classes are, therefore, imbalanced data. One of our main objectives is to compare eight resampling strategies that have been developed to counteract the imbalanced data problem. We compared the performance of five of the most common ML algorithms with the resampling approaches. The highest increase in prediction accuracy was achieved with SMOTE (the synthetic minority oversampling technique). In comparison to the baseline prediction on the original dataset, we achieved an increase of about 10, 20 and 10% in the overall accuracy, kappa index and F‐score, respectively. Regarding the ML approaches, random forest (RF) showed the best performance with an overall accuracy, kappa index and F‐score of 66, 60 and 57%, respectively. Moreover, the combination of RF and SMOTE improved the accuracy of the individual soil classes, compared to RF trained on the original dataset and allowed better prediction of soil classes with a low number of samples in the corresponding soil profile database, in our case for Chernozems. Our results show that balancing existing soil legacy data using synthetic sampling strategies can significantly improve the prediction accuracy in digital soil mapping (DSM). Highlights Spatial distribution of soil classes in Iran can be predicted using machine learning (ML) algorithms. The synthetic minority oversampling technique overcomes the drawback of imbalanced and highly biased soil legacy data. When combining a random forest model with synthetic sampling strategies the prediction accuracy of the soil model improves significantly. The resulting new soil map of Iran has a much higher spatial resolution compared to existing maps and displays new soil classes that have not yet been mapped in Iran.
    Description: Alexander von Humboldt‐Stiftung http://dx.doi.org/10.13039/100005156
    Description: German Research Foundation http://dx.doi.org/10.13039/501100001659
    Description: Soil and Water Research Institute, Agricultural Research, Education and Extension Organization, Karaj, Iran
    Keywords: 631.4 ; covariates ; imbalanced data ; machine learning ; random forest ; soil legacy data
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    Impact of biochar on nutrient supply, crop yield and microbial respiration on sandy soils of northern Germany (2021)
    Blackwell Publishing Ltd | Oxford, UK
    Details
    Publication Date: 2021-06-16
    Description: The application of biochar to agricultural soils to increase nutrient availability, crop production and carbon sequestration has gained increasing interest but data from field experiments on temperate, marginal soils are still under‐represented. In the current study, biochar, produced from organic residues (digestates) from a biogas plant, was applied with and without digestates at low (3.4 t ha−1) and intermediate (17.1 t ha−1) rates to two acidic and sandy soils in northern Germany that are used for corn (Zea mays L.) production. Soil nutrient availability, crop yields, microbial biomass and carbon dioxide (CO2) emissions from heterotrophic respiration were measured over two consecutive years. The effects of biochar application depended on the intrinsic properties of the two tested soils and the biochar application rates. Although the soils at the fallow site, with initially low nutrient concentrations, showed a significant increase in pH, soil nutrients and crop yield after low biochar application rates, a similar response was found at the cornfield site only after application of substantially larger amounts of biochar. The effect of a single dose of biochar at the beginning of the experiment diminished over time but was still detectable after 2 years. Whereas plant available nutrient concentrations increased after biochar application, the availability of potentially phytotoxic trace elements (Zn, Pb, Cd, Cr) decreased significantly, and although slight increases in microbial biomass carbon and heterotrophic CO2 fluxes were observed after biochar application, they were mostly not significant. The results indicate that the application of relatively small amounts of biochar could have positive effects on plant available nutrients and crop yields of marginal arable soils and may decrease the need for mineral fertilizers while simultaneously increasing the sequestration of soil organic carbon. Highlights A low rate of biochar increased plant available nutrients and crop yield on marginal soils. Biochar application reduced the availability of potentially harmful trace elements. Heterotrophic respiration showed no clear response to biochar application. Biochar application may reduce fertilizer need and increase carbon sequestration on marginal soils.
    Description: German Academic Exchange Service http://dx.doi.org/10.13039/501100001655
    Description: Institute Strategic Programme grants, “Soils to Nutrition”
    Keywords: 631.4 ; black carbon ; carbon sequestration ; corn ; digestate ; heterotrophic respiration ; marginal soils ; microbial biomass
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    Self‐stated recovery from flooding: Empirical results from a survey in Central Vietnam (2021)
    Blackwell Publishing Ltd | Oxford, UK
    Details
    Publication Date: 2021-06-27
    Description: Social inequalities lead to flood resilience inequalities across social groups, a topic that requires improved documentation and understanding. The objective of this paper is to attend to these differences by investigating self‐stated flood recovery across genders in Vietnam as a conceptual replication of earlier results from Germany. This study employs a regression‐based analysis of 1,010 respondents divided between a rural coastal and an urban community in Thua Thien‐Hue province. The results highlight an important set of recovery process‐related variables. The set of relevant variables is similar across genders in terms of inclusion and influence, and includes age, social capital, internal and external support after a flood, perceived severity of previous flood impacts, and the perception of stress‐resilience. However, women were affected more heavily by flooding in terms of longer recovery times, which should be accounted for in risk management. Overall, the studied variables perform similarly in Vietnam and Germany. This study, therefore, conceptually replicates previous results suggesting that women display slightly slower recovery levels as well as that psychological variables influence recovery rates more than adverse flood impacts. This provides an indication of the results' potentially robust nature due to the different socio‐environmental contexts in Germany and Vietnam.
    Keywords: 333.7 ; flood recovery ; resilience ; societal equity ; vulnerability
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    The potential of ryegrass as cover crop to reduce soil N2O emissions and increase the population size of denitrifying bacteria (2021)
    Blackwell Publishing Ltd | Oxford, UK
    Details
    Publication Date: 2021-07-05
    Description: Nitrogen (N) fertilization is the major contributor to nitrous oxide (N2O) emissions from agricultural soil, especially in post‐harvest seasons. This study was carried out to investigate whether ryegrass serving as cover crop affects soil N2O emissions and denitrifier community size. A microcosm experiment was conducted with soil planted with perennial ryegrass (Lolium perenne L.) and bare soil, each with four levels of N fertilizer (0, 5, 10 and 20 g N m−2; applied as calcium ammonium nitrate). The closed‐chamber approach was used to measure soil N2O fluxes. Real‐time PCR was used to estimate the biomass of bacteria and fungi and the abundance of genes involved in denitrification in soil. The results showed that the presence of ryegrass decreased the nitrate content in soil. Cumulative N2O emissions of soil with grass were lower than in bare soil at 5 and 10 g N m−2. Fertilization levels did not affect the abundance of soil bacteria and fungi. Soil with grass showed greater abundances of bacteria and fungi, as well as microorganisms carrying narG, napA, nirK, nirS and nosZ clade I genes. It is concluded that ryegrass serving as a cover crop holds the potential to mitigate soil N2O emissions in soils with moderate or high NO3− concentrations. This highlights the importance of cover crops for the reduction of N2O emissions from soil, particularly following N fertilization. Future research should explore the full potential of ryegrass to reduce soil N2O emissions under field conditions as well as in different soils. Highlights This study was to investigate whether ryegrass serving as cover crop affects soil N2O emissions and denitrifier community size; Plant reduced soil N substrates on one side, but their root exudates stimulated denitrification on the other side; N2O emissions were lower in soil with grass than bare soil at medium fertilizer levels, and growing grass stimulated the proliferation of almost all the denitrifying bacteria except nosZ clade II; Ryegrass serving as a cover crop holds the potential to mitigate soil N2O emissions.
    Description: China Scholarship Council http://dx.doi.org/10.13039/501100004543
    Description: The National Science Project for University of Anhui Province
    Keywords: 551.9 ; 631.4 ; denitrification ; perennial ryegrass (Lolium perenne L.) ; soil bacteria ; soil CO2 emissions ; soil N2O emissions
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    Reservoir Structure and Hydraulic Properties of the Campi Flegrei Geothermal System Inferred by Audiomagnetotelluric, Geochemical, and Seismicity Study (2020)
    Wiley
    Details
    Publication Date: 2020-01-23
    Description: The Campi Flegrei caldera is a large volcanic complex lying in the Campanian Plain, Southern Italy. During its history the caldera experienced episodes of bradyseism and intense swarm seismicity. The mechanism leading to unrest episodes is still debated, and great efforts are ongoing to improve the knowledge of this structure and its evolution due to the high volcanic risk in such a densely populated area. Here we present a resistivity model from a two‐dimensional inversion of audiomagnetotelluric data acquired along an approximately 5.6‐km long profile crosscutting the Solfatara‐Pisciarelli district and the Agnano plain. The resistivity model shows (1) very low resistivity values confined in the first 500 m of depth both in correspondence of the Solfatara‐Pisciarelli districts and the Agnano depression; (2) a resistive plume that extends underneath the Solfatara crater down to 2,000‐ to 3,000‐m depth, and (3) an adjoining relative conductive unit eastward. We discuss the resistivity structures in a multidisciplinary framework integrating inedited geochemical and seismological observations with existing surface geology and subsurface information. The Solfatara‐Pisciarelli district and the Agnano plain, both being expression of intense hydrothermal activity, show different characteristics. Below the Solfatara‐Pisciarelli area, the shallow conductive zone is interpreted as a faulted clay cap that overlies a highly active vapor‐dominated reservoir characterized by a convective mechanism. Conversely, below the Agnano plain, a liquid phase seems to prevail in the reservoir. The spatiotemporal variations of seismicity imply a combined action of preexisting tectonic lineaments and fluid interaction between the gas/steam reservoir and the outflow zone.
    Description: Published
    Description: 5336-5356
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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    Insight Into Campi Flegrei Caldera Unrest Through Seismic Tremor Measurements at Pisciarelli Fumarolic Field (2020)
    Wiley
    Details
    Publication Date: 2020-01-23
    Description: Within a general volcanic unrest in the densely urbanized area of Campi Flegrei caldera (Italy) an increase in the activity of Pisciarelli hydrothermal area is occurring. The seismic amplitude of Pisciarelli fumarolic tremor is a proxy for the fluid emission rate of the entire Solfatara‐Pisciarelli hydrothermal system. The long‐term analysis indicates a significant increase, by a factor of ~3 of the fumarolic tremor amplitude since May 2017. This increment matches with the trend of geochemical and seismic parameters observed in Campi Flegrei, therefore highlighting that Pisciarelli is a key site to monitor the volcanic unrest underway in this high‐risk caldera. The analysis of data from three closely spaced seismic stations provided new clues about the source mechanism of the tremor. Analyzing the fumarolic tremor amplitude we could also identify an episode of enlargement of the emission area close to the main fumarole of Pisciarelli. We propose a monitoring system based on the fumarolic tremor analysis, which provides real‐time information on the Pisciarelli hydrothermal activity and therefore on the current unrest in Campi Flegrei caldera.
    Description: Published
    Description: 5544-5555
    Description: 4V. Processi pre-eruttivi
    Description: JCR Journal
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    Water Availability and Deformation Processes in Smectite‐Rich Gouges During Seismic Slip (2020)
    Wiley
    Details
    Publication Date: 2020-02-10
    Description: Smectite clays occur in subduction zone fault cores at shallow depth (approximately 1 km; e.g., Japan Trench) and landslide décollements (e.g., Vajont, Italy, 1963). The availability of pore fluids affects the likelihood that seismic slip propagates from deeper to shallow fault depths or that a landslide accelerates to its final collapse. To investigate the deformation processes active during seismic faulting we performed friction experiments with a rotary machine on 2‐mm‐thick smectite‐rich gouge layers (70/30 wt % Ca‐montmorillonite/opal) sheared at 5‐MPa normal stress, at slip rates of 0.001, 0.01, 0.1, and 1.3 m/s, and total displacement of 3 m. Experiments were performed on predried gouges under vacuum, under room humidity and under partly saturated conditions. The fault shear strength measured in the experiments was included in a one‐dimensional numerical model incorporating frictional heating, thermal, and thermochemical pressurization. Quantitative X‐ray powder diffraction and scanning electron microscopy investigations were performed on pristine and deformed smectite‐rich gouges. Under dry conditions, cataclasis and amorphization dominated at slip rates of 0.001–0.1 m/s, whereas grain size sensitive flow and, under vacuum, frictional melting occurred at fast slip rates (1.3 m/s). Under partly saturated conditions, frictional slip in a smectite foliation occurred in combination with pressurization of water by shear‐enhanced compaction and, for V = 0.01–1.3 m/s, with thermal pressurization. Pseudotachylytes, the only reliable microstructural markers for seismic slip, formed only with large frictional power (〉2 MW/m2), which could be achieved at shallow depth with high slip rates, or, at depth, with high shear stress in dehydrated smectites.
    Description: Published
    Description: 10855-10876
    Description: 3T. Sorgente sismica
    Description: JCR Journal
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    Visual stratigraphy of the North Greenland Ice Core Project (NorthGRIP) ice core during the last glacial period (2005)
    Wiley
    In:  EPIC3Jourmal of Geophysical Research: Atmospheres, Wiley, 110(D2), pp. D02108, ISSN: 2169-8996
    Details
    Publication Date: 2019-07-17
    Description: A continuous high-resolution record of digital images has been obtained from the North Greenland Ice Core Project (NorthGRIP) ice core (75.1N, 42.3W) in the depth interval from 1330 m to the bedrock at 3085 m. The ice core stratigraphy is clearly visible throughout the glacial period with the most frequent and brightest visible layers appearing during the coldest events. Down to a depth of 2600 m the horizontal layeringis very regular; below this depth, small irregularities in the layering start to appear, and below 2800 m the visual stratigraphy becomes more uncertain, perhaps because of penetration into climatically warmer ice. Comparison of the visual stratigraphy with high-resolution continuous records of chemical impurities and dust reveals a high degree of correlation, which indicates that the visible layers are caused by these impurities. Anew approach is used to automatically determine annual layer thicknesses from the visual stratigraphy record by carrying out a frequency analysis of the most prominent visible layers in the profile. The result gives strong support for the NorthGRIP timescale model.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
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    ogs5py: A Python‐API for the OpenGeoSys 5 Scientific Modeling Package (2021)
    Blackwell Publishing Ltd | Malden, US
    Details
    Publication Date: 2021-07-04
    Description: High‐performance numerical codes are an indispensable tool for hydrogeologists when modeling subsurface flow and transport systems. But as they are written in compiled languages, like C/C++ or Fortran, established software packages are rarely user‐friendly, limiting a wider adoption of such tools. OpenGeoSys (OGS), an open‐source, finite‐element solver for thermo‐hydro‐mechanical–chemical processes in porous and fractured media, is no exception. Graphical user interfaces may increase usability, but do so at a dramatic reduction of flexibility and are difficult or impossible to integrate into a larger workflow. Python offers an optimal trade‐off between these goals by providing a highly flexible, yet comparatively user‐friendly environment for software applications. Hence, we introduce ogs5py, a Python‐API for the OpenGeoSys 5 scientific modeling package. It provides a fully Python‐based representation of an OGS project, a large array of convenience functions for users to interact with OGS and connects OGS to the scientific and computational environment of Python.
    Description: German Federal Environmental Foundation http://dx.doi.org/10.13039/100007636
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Keywords: 551.49 ; hydrogeology ; subsurface flow ; modeling ; software
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    High‐Resolution Integrated Transport Model for Studying Surface Water–Groundwater Interaction (2021)
    Blackwell Publishing Ltd | Malden, US
    Details
    Publication Date: 2021-06-27
    Description: Transport processes that lead to exchange of mass between surface water and groundwater play a significant role for the ecological functioning of aquatic systems, for hydrological processes and for biogeochemical transformations. In this study, we present a novel integral modeling approach for flow and transport at the sediment–water interface. The model allows us to simultaneously simulate turbulent surface and subsurface flow and transport with the same conceptual approach. For this purpose, a conservative transport equation was implemented to an existing approach that uses an extended version of the Navier–Stokes equations. Based on previous flume studies which investigated the spreading of a dye tracer under neutral, losing and gaining flow conditions the new solver is validated. Tracer distributions of the experiments are in close agreement with the simulations. The simulated flow paths are significantly affected by in‐ and outflowing groundwater flow. The highest velocities within the sediment are found for losing condition, which leads to shorter residence times compared to neutral and gaining conditions. The largest extent of the hyporheic exchange flow is observed under neutral condition. The new solver can be used for further examinations of cases that are not suitable for the conventional coupled models, for example, if Reynolds numbers are larger than 10. Moreover, results gained with the integral solver provide high‐resolution information on pressure and velocity distributions at the rippled streambed, which can be used to improve flow predictions. This includes the extent of hyporheic exchange under varying ambient groundwater flow conditions.
    Description: Technische Universität Berlin, Germany
    Description: German Research Foundation http://dx.doi.org/10.13039/501100001659
    Keywords: 551.4 ; aquatic systems ; sediment-water interface ; transport model
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    Iron isotope fractionation in soil and graminaceous crops after 100 years of liming in the long‐term agricultural experimental site at Berlin‐Dahlem, Germany (2021)
    Blackwell Publishing Ltd | Oxford, UK
    Details
    Publication Date: 2021-07-05
    Description: Sustainable arable cropping relies on repeated liming. Yet, the associated increase in soil pH can reduce the availability of iron (Fe) to plants. We hypothesized that repeated liming, but not pedogenic processes such as lessivage (i.e., translocation of clay particles), alters the Fe cycle in Luvisol soil, thereby affecting Fe isotope composition in soils and crops. Hence, we analysed Fe concentrations and isotope compositions in soil profiles and winter rye from the long‐term agricultural experimental site in Berlin‐Dahlem, Germany, where a controlled liming trial with three field replicates per treatment has been conducted on Albic Luvisols since 1923. Heterogeneity in subsoil was observed at this site for Fe concentration but not for Fe isotope composition. Lessivage had not affected Fe isotope composition in the soil profiles. The results also showed that almost 100 years of liming lowered the concentration of the HCl‐extractable Fe that was potentially available for plant uptake in the surface soil (0–15 cm) from 1.03 (standard error (SE) 0.03) to 0.94 (SE 0.01) g kg−1. This HCl‐extractable Fe pool contained isotopically lighter Fe (δ56Fe = −0.05 to −0.29‰) than the bulk soil (δ56Fe = −0.08 to 0.08‰). However, its Fe isotope composition was not altered by the long‐term lime application. Liming resulted in relatively lower Fe concentrations in the roots of winter rye. In addition, liming led to a heavier Fe isotope composition of the whole plants compared with those grown in the non‐limed plots (δ56FeWholePlant_ + Lime = −0.12‰, SE 0.03 vs. δ56FeWholePlant_‐Lime = −0.21‰, SE 0.01). This suggests that the elevated soil pH (increased by one unit due to liming) promoted the Fe uptake strategy through complexation of Fe(III) from the rhizosphere, which favoured heavier Fe isotopes. Overall, the present study showed that liming and a related increase in pH did not affect the Fe isotope compositions of the soil, but may influence the Fe isotope composition of plants grown in the soil if they alter their Fe uptake strategy upon the change of Fe availability. Highlights Fe concentrations and stocks, but not Fe isotope compositions, were more heterogeneous in subsoil than in topsoil. Translocation of clay minerals did not result in Fe isotope fractionation in the soil profile of a Luvisol. Liming decreased Fe availability in topsoil, but did not affect its δ56Fe values. Uptake of heavier Fe isotopes by graminaceous crops was more pronounced at elevated pH.
    Description: Bundesministerium für Bildung und Forschung http://dx.doi.org/10.13039/501100002347
    Keywords: 551.9 ; liming ; plant‐available Fe pool in soil ; winter rye ; δ56Fe
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    Sediment dynamics on the Northwest African continental margin (1982)
    Wiley
    In:  EPIC3The Ocean Floor, The Ocean Floor, Wiley, pp. 147-163
    Details
    Publication Date: 2016-03-17
    Repository Name: EPIC Alfred Wegener Institut
    Type: Inbook , peerRev
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    The evolving paleobathymetry of the circum-Antarctic Southern Ocean since 34 Ma – A key to understanding past cryosphere-ocean developments (2020)
    Wiley
    In:  EPIC3Geochemistry Geophysics Geosystems, Wiley, 21, ISSN: 1525-2027
    Details
    Publication Date: 2021-07-19
    Description: The Southern Ocean is a key player in the climate, ocean and atmospheric system. As the only direct connection between all three major oceans since the opening of the Southern Ocean gateways, the development of the Southern Ocean and its relationship with the Antarctic cryosphere has influenced the climate of the entire planet. Although the depths of the ocean floor have been recognized as an important factor in climate and paleoclimate models, appropriate paleobathymetric models including a detailed analysis of the sediment cover are not available. Here, we utilize more than 40 years of seismic reflection data acquisition along the margins of Antarctica and its conjugate margins, along with multiple drilling campaigns by the International Ocean Discovery Program (IODP) and its predecessor programs. We combine and update the seismic stratigraphy across the regions of the Southern Ocean and calculate ocean-wide paleobathymetry grids via a backstripping method. We present a suite of high-resolution paleobathymetric grids from the Eocene-Oligocene Boundary to modern times. The grids reveal the development of the Southern Ocean from isolated basins to an interconnected ocean affected by the onset and vigor of an Antarctic Circumpolar Current, as well as the glacial sedimentation and erosion of the Antarctic continent. The ocean-wide comparison through time exposes patterns of ice sheet development such as switching of glacial outlets and the change from wet-based to dry-based ice sheets. Ocean currents and bottom-water production interact with the sedimentation along the continental shelf and slope and profit from the opening of the ocean gateways.
    Repository Name: EPIC Alfred Wegener Institut
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    Assessing East African trade in seahorse species as a basis for conservation under international controls (2005)
    Wiley
    Details
    Publication Date: 2021-05-19
    Description: 1. Seahorses (Hippocampus spp.), many of which are listed as Vulnerable or Endangered on the IUCN Red List, are traded worldwide as souvenirs, aquarium fish and, primarily, for use in traditional medicines. Given concern over the sustainability of this trade, the genus was added to Appendix II of the Convention on International Trade in Endangered Species of Wild Fauna and Flora (CITES) in May 2004. 2. This paper reports findings of the first ever survey of seahorse trade in Africa, conducted in Kenya and Tanzania in May and June 2000. 3. Seahorse trade in Kenya was found to be negligible, with approximately 10 live seahorses exported as aquarium fish annually. Until 1998, however, Kenya may have imported somewhere from 1 to 2.3 t of dried seahorses annually from Tanzania for re-export to Asian medicine markets. Seahorse trade in Tanzania remained substantial, with at least 630–930 kg of dried seahorse exported directly to Asia each year. 4. Accounts of declines in seahorse availability and seahorse size, although few in number, could be early warning signs that wild populations are suffering, at least locally. Close monitoring of future developments in the trade will be essential to allow for timely conservation action as and when necessary, and would contribute to our understanding of the ecological and economical implications of small-scale, non-food fisheries. Copyright # 2004 John Wiley & Sons, Ltd.
    Description: Published
    Keywords: Hippocampus spp ; By catch ; Non-food fisheries ; Seahorse trade ; Endangered species ; Aquatic animals
    Repository Name: AquaDocs
    Type: Journal Contribution , Non-Refereed , Article
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    Role of carbon cycle observations and knowledge in carbon management (2005)
    Annual Reviews
    Details
    Publication Date: 2022-05-25
    Description: Author Posting. © Annual Reviews, 2003. This article is posted here by permission of Annual Reviews for personal use, not for redistribution. The definitive version was published in Annual Review of Environment and Resources 28 (2003): 521-558, doi:10.1146/annurev.energy.28.011503.163443.
    Description: Agriculture and industrial development have led to inadvertent changes in the natural carbon cycle. As a consequence, concentrations of carbon dioxide and other greenhouse gases have increased in the atmosphere and may lead to changes in climate. The current challenge facing society is to develop options for future management of the carbon cycle. A variety of approaches has been suggested: direct reduction of emissions, deliberate manipulation of the natural carbon cycle to enhance sequestration, and capture and isolation of carbon from fossil fuel use. Policy development to date has laid out some of the general principles to which carbon management should adhere. These are summarized as: how much carbon is stored, by what means, and for how long. To successfully manage carbon for climate purposes requires increased understanding of carbon cycle dynamics and improvement in the scientific capabilities available for measurement as well as for policy needs. The specific needs for scientific information to underpin carbon cycle management decisions are not yet broadly known. A stronger dialogue between decision makers and scientists must be developed to foster improved application of scientific knowledge to decisions. This review focuses on the current knowledge of the carbon cycle, carbon measurement capabilities (with an emphasis on the continental scale) and the relevance of carbon cycle science to carbon sequestration goals.
    Description: The National Center for Atmospheric Research is supported by the National Science Foundation.
    Keywords: Carbon sequestration ; Measurement techniques ; Climate ; Kyoto protocol
    Repository Name: Woods Hole Open Access Server
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    Long nonlinear internal waves (2006)
    Annual Reviews
    Details
    Publication Date: 2022-05-25
    Description: Author Posting. © Annual Reviews, 2006. This article is posted here by permission of Annual Reviews for personal use, not for redistribution. The definitive version was published in Annual Review of Fluid Mechanics 38 (2006): 395-425, doi:10.1146/annurev.fluid.38.050304.092129.
    Description: Over the past four decades, the combination of in situ and remote sensing observations has demonstrated that long nonlinear internal solitary-like waves are ubiquitous features of coastal oceans. The following provides an overview of the properties of steady internal solitary waves and the transient processes of wave generation and evolution, primarily from the point of view of weakly nonlinear theory, of which the Korteweg-de Vries equation is the most frequently used example. However, the oceanographically important processes of wave instability and breaking, generally inaccessible with these models, are also discussed. Furthermore, observations often show strongly nonlinear waves whose properties can only be explained with fully nonlinear models.
    Description: KRH acknowledges support from NSF and ONR and an Independent Study Award from the Woods Hole Oceanographic Institution. WKM acknowledges support from NSF and ONR, which has made his work in this area possible, in close collaboration with former graduate students at Scripps Institution of Oceanography and MIT.
    Keywords: Solitary waves ; Nonlinear waves ; Stratified flow ; Physical Oceanography
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    Design and function of superfast muscles : new insights into the physiology of skeletal muscle (2005)
    Annual Reviews
    Details
    Publication Date: 2022-05-25
    Description: First published online as a Review in Advance on October 24, 2005. (Some corrections may occur before final publication online and in print)
    Description: Author Posting. © Annual Reviews, 2005. This article is posted here by permission of Annual Reviews for personal use, not for redistribution. The definitive version was published in Annual Review of Physiology 68 (2006): 22.1-22.29, doi:10.1146/annurev.physiol.68.040104.105418.
    Description: Superfast muscles of vertebrates power sound production. The fastest, the swimbladder muscle of toadfish, generates mechanical power at frequencies in excess of 200 Hz. To operate at these frequencies, the speed of relaxation has had to increase approximately 50-fold. This increase is accomplished by modifications of three kinetic traits: (a) a fast calcium transient due to extremely high concentration of sarcoplasmic reticulum (SR)-Ca2+ pumps and parvalbumin, (b) fast off-rate of Ca2+ from troponin C due to an alteration in troponin, and (c) fast cross-bridge detachment rate constant (g, 50 times faster than that in rabbit fast-twitch muscle) due to an alteration in myosin. Although these three modifications permit swimbladder muscle to generate mechanical work at high frequencies (where locomotor muscles cannot), it comes with a cost: The high g causes a large reduction in attached force-generating cross-bridges, making the swimbladder incapable of powering low-frequency locomotory movements. Hence the locomotory and sound-producing muscles have mutually exclusive designs.
    Description: This work was made possible by support from NIH grants AR38404 and AR46125 as well as the University of Pennsylvania Research Foundation.
    Keywords: Parvalbumin ; Ca2+ release ; Ca2+ uptake ; Cross-bridges ; Adaptation ; Sound production ; Whitman Center
    Repository Name: Woods Hole Open Access Server
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    Plio‐Pleistocene variability of the East Pacific thermocline and atmospheric systems (2020)
    Wiley
    In:  EPIC3Paleoceanography, Wiley, 35, pp. 1-7, ISSN: 0883-8305
    Details
    Publication Date: 2020-03-13
    Description: The transition from the Pliocene to the Pleistocene was accompanied by major tectonic reorganizations of key oceanic gateways. In particular, the gradual closure of the Panama Gateway and the constriction of the Indonesian Gateway significantly affected the structure of the Pacific thermocline. In the East Pacific, the thermocline shoaled from an early Pliocene El Niño‐like depth to its modern state, which had significant implications for global climate. Here we use Mg/Ca temperature estimates from subsurface and thermocline dwelling foraminifera to reconstruct the meridional Plio‐Pleistocene evolution of the Southeast Pacific thermocline, in relation to atmospheric circulation changes. In combination with similar reconstructions from the north‐equatorial Pacific, our data indicate a change in the thermocline, responding to the northward displacement of the Intertropical Convergence Zone/South Pacific High system between ~3.8 and 3.5 Ma. After 3.5 Ma, we record a second major phase of thermocline shoaling, which points to the Intertropical Convergence Zone/South Pacific High‐system movement toward its modern position along with the gradual cooling of the Northern Hemisphere and its associated glaciation. These findings highlight that a warming globe may affect equatorial regions more intensively due to the potential temperature‐driven movement of the Intertropical Convergence Zone/South Pacific High and their associated oceanic systems.
    Repository Name: EPIC Alfred Wegener Institut
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    Radiocarbon evidence for the contribution of the Southern Indian Ocean to the evolution of atmospheric CO2 over the last 32,000 years (2020)
    Wiley
    In:  EPIC3Paleoceanography, Wiley, 35, pp. PA003733, ISSN: 0883-8305
    Details
    Publication Date: 2020-03-13
    Description: It is widely assumed that the ventilation of the Southern Ocean played a crucial role in driving glacial‐interglacial atmospheric CO2 levels. So far, however, ventilation records from the Indian sector of the Southern Ocean are widely missing. Here we present reconstructions of water residence times (depicted as ΔΔ14C and Δδ13C) for the last 32,000 years on sediment records from the Kerguelen Plateau and the Conrad Rise (~570‐ to 2,500‐m water depth), along with simulated changes in ocean stratification from a transient climate model experiment. Our data indicate that Circumpolar Deep Waters in the Indian Ocean were part of the glacial carbon pool. At our sites, close to or bathed by upwelling deep waters, we find two pulses of decreasing ΔΔ14C and δ13C values (~21–17 ka; ~15–12 ka). Both transient pulses precede a similar pattern in downstream intermediate waters in the tropical Indian Ocean as well as rising atmospheric CO2 values. These findings suggest that 14C‐depleted, CO2‐rich Circumpolar Deep Water from the Indian Ocean contributed to the rise in atmospheric CO2 during Heinrich Stadial 1 and also the Younger Dryas and that the southern Indian Ocean acted as a gateway for sequestered carbon to the atmosphere and tropical intermediate waters.
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    Intensification of the Atlantic Water Supply to the Arctic Ocean Through Fram Strait Induced by Arctic Sea Ice Decline (2020)
    Wiley
    In:  EPIC3Geophysical Research Letters, Wiley, 47(3), pp. e2019GL086682, ISSN: 0094-8276
    Details
    Publication Date: 2020-03-23
    Repository Name: EPIC Alfred Wegener Institut
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    Assessment of sea ice extent in CMIP6 with comparison to observations and CMIP5 (2020)
    Wiley
    In:  EPIC3Geophysical Research Letters, Wiley, 47(9), pp. e2020GL087965, ISSN: 0094-8276
    Details
    Publication Date: 2020-05-04
    Description: Both the Arctic and Antarctic sea ice extents (SIE) from 44 coupled models in the Coupled Model Intercomparison Project Phase 6 (CMIP6) are evaluated by comparing them with observations and CMIP5 results. The CMIP6 multi‐model mean can adequately reproduce the seasonal cycles of both the Arctic and Antarctic SIE. The observed Arctic September SIE declining trend (−0.82±0.18 million km2/decade) between 1979 and 2014 is slightly underestimated in CMIP6 models (−0.70±0.06 million km2/decade). The observed weak but significant upward trend of the Antarctic SIE is not captured, which was an issue already in the CMIP5 phase. Compared with CMIP5 models, CMIP6 models have lower inter‐model spreads in SIE mean values and trends, although their SIE biases are relatively larger. The CMIP6 models did not reproduce the new summer tendencies after 2000, including the faster decline of Arctic SIE and the larger interannual variability in Antarctic SIE.
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    SoilTemp: a global database of near‐surface temperature (2020)
    Wiley
    In:  EPIC3Global Change Biology, Wiley, ISSN: 1354-1013
    Details
    Publication Date: 2020-04-22
    Description: Current analyses and predictions of spatially‐explicit patterns and processes in ecology most often rely on climate data interpolated from standardized weather stations. This interpolated climate data represents long‐term average thermal conditions at coarse spatial resolutions only. Hence, many climate‐forcing factors that operate at fine spatiotemporal resolutions are overlooked. This is particularly important in relation to effects of observation height (e.g. vegetation, snow and soil characteristics) and in habitats varying in their exposure to radiation, moisture and wind (e.g. topography, radiative forcing, or cold‐air pooling). Since organisms living close to the ground relate more strongly to these microclimatic conditions than to free‐air temperatures, microclimatic ground and near‐surface data are needed to provide realistic forecasts of the fate of such organisms under anthropogenic climate change, as well as of the functioning of the ecosystems they live in. To fill this critical gap, we highlight a call for temperature time series submissions to SoilTemp, a geospatial database initiative compiling soil and near‐surface temperature data from all over the world. Currently this database contains time series from 7538 temperature sensors from 51 countries across all key biomes. The database will pave the way towards an improved global understanding of microclimate and bridge the gap between the available climate data and the climate at fine spatiotemporal resolutions relevant to most organisms and ecosystem processes.
    Repository Name: EPIC Alfred Wegener Institut
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    Constraining the age and evolution of the Tuaheni Landslide Complex, Hikurangi Margin, New Zealand, using pore-water geochemistry and numerical modeling (2020)
    Wiley
    In:  EPIC3Geophysical Research Letters, Wiley, 47, ISSN: 0094-8276
    Details
    Publication Date: 2020-06-05
    Repository Name: EPIC Alfred Wegener Institut
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    Back-Arc Extension of the Central Bransfield Basin Induced by Ridge–Trench Collision: Implications From Ambient Noise Tomography and Stress Field Inversion (2021)
    Wiley
    In:  EPIC3Geophysical Research Letters, Wiley, 48(21), ISSN: 0094-8276
    Details
    Publication Date: 2021-11-02
    Description: The Bransfield Basin is a young (∼4 Ma) back-arc basin related to the remnant subduction of the Phoenix Plate that once existed along the entire Pacific margin of the Antarctic Peninsula. Based on a recently deployed amphibious seismic network, we use ambient noise tomography to obtain the S-wave velocity structure in the Central Bransfield Basin (CBB). Combining with the stress field inverted from focal mechanisms, our images reveal that the CBB suffers a significant extension in the northwest-southeast direction. The extension is strongest in the northeastern CBB with associated mantle exhumation and weakens to the southwest with decoupled deformations between the upper crust and lithospheric mantle. Such an along-strike variation of extension can be explained by slab window formation and forearc rotation, which are associated with the Phoenix Plate detachment during the ridge–trench collisions at the southwest of the Hero Fracture Zone.
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    Restoring shellfish reefs: Global guidelines for practitioners and scientists (2020)
    Wiley
    In:  EPIC3Conservation Science and Practice, Wiley, e198, pp. 1-11
    Details
    Publication Date: 2020-03-27
    Description: Widespread global declines in shellfish reefs (ecosystem-forming bivalves such as oysters and mussels) have led to growing interest in their restoration and protection. With restoration projects now occurring on four continents and in at least seven countries, global restoration guidelines for these ecosystems have been developed based on experience over the past two decades. The following key elements of the guidelines are outlined: (a) the case for shellfish reef resto- ration and securing financial resources; (b) planning, feasibility, and goal set- ting; (c) biosecurity and permitting; (d) restoration in practice; (e) scaling up from pilot to larger scale restoration, (f) monitoring, (g) restoration beyond oyster reefs (specifically mussels), and (h) successful communication for shell- fish reef restoration projects.
    Repository Name: EPIC Alfred Wegener Institut
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    Poleward shift of the major ocean gyres detected in a warming climate (2020)
    Wiley
    In:  EPIC3Geophysical Research Letters, Wiley, 47(5), pp. e2019GL085868, ISSN: 0094-8276
    Details
    Publication Date: 2020-09-17
    Description: Recent evidence shows that wind‐driven ocean currents, like the western boundary currents, are strongly affected by global warming. However, due to insufficient observations both on temporal and spatial scales, the impact of climate change on large‐scale ocean gyres is still not clear. Here, based on satellite observations of sea surface height and sea surface temperature, we find a consistent poleward shift of the major ocean gyres. Due to strong natural variability, most of the observed ocean gyre shifts are not statistically significant, implying that natural variations may contribute to the observed trends. However, climate model simulations forced with increasing greenhouse gases suggest that the observed shift is most likely to be a response of global warming. The displacement of ocean gyres, which is coupled with the poleward shift of extratropical atmospheric circulation, has broad impacts on ocean heat transport, regional sea level rise, and coastal ocean circulation.
    Repository Name: EPIC Alfred Wegener Institut
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    Statistical Uncertainty in Paleoclimate Proxy Reconstructions (2021)
    Wiley
    In:  EPIC3Geophysical Research Letters, Wiley, 48, pp. e2021GL092773, ISSN: 0094-8276
    Details
    Publication Date: 2021-08-23
    Description: A quantitative analysis of any environment older than the instrumental record relies on proxies. Uncertainties associated with proxy reconstructions are often underestimated, which can lead to artificial conflict between different proxies, and between data and models. In this paper, using ordinary least squares linear regression as a common example, we describe a simple, robust and generalizable method for quantifying uncertainty in proxy reconstructions. We highlight the primary controls on the magnitude of uncertainty, and compare this simple estimate to equivalent estimates from Bayesian, nonparametric and fiducial statistical frameworks. We discuss when it may be possible to reduce uncertainties, and conclude that the unexplained variance in the calibration must always feature in the uncertainty in the reconstruction. This directs future research toward explaining as much of the variance in the calibration data as possible. We also advocate for a “data-forward” approach, that clearly decouples the presentation of proxy data from plausible environmental inferences.
    Repository Name: EPIC Alfred Wegener Institut
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    Stable nitrogen isotope analysis of amino acids as a new tool to clarify complex parasite–host interactions within food webs (2021)
    Wiley
    In:  EPIC3Oikos, Wiley, ISSN: 0030-1299
    Details
    Publication Date: 2021-08-26
    Description: Traditional bulk isotopic analysis is a pivotal tool for mapping consumer–resource interactions in food webs but has largely failed to adequately describe parasite–host relationships. Thus, parasite–host interactions remain undescribed in food web frameworks despite these relationships increasing linkage density, connectance and ecosystem biomass. Compound-specific stable isotopes from amino acids provides a promising novel approach that may aid in mapping parasite–host relationships in food webs. Here we apply a combination of traditional bulk stable isotope analyses and compound-specific isotopic analysis of nitrogen in amino acids to examine resource use and trophic interactions of five parasites from three hosts from a marine coastal food web (Wadden Sea, European Atlantic). By comparing isotopic compositions of bulk and amino acid nitrogen, we aimed to characterize isotopic fractionation occurring between parasites and their hosts and to clarify parasite trophic positions. Our results indicate that parasitic trophic interactions were more accurately identified using compound-specific stable isotope analysis due to removal of underlying source isotopic variation for both parasites and hosts. The compound-specific method provided clearer trophic discrimination factors in comparison to bulk isotope methods. Amino acid compound specific isotope analysis has widely been applied to examine trophic position within food webs, but our analyses suggest that the method is particularly useful for clarifying the feeding strategies for parasitic species. Baseline isotopic information provided by source amino acids allows clear identification of the fractionation from parasite metabolism by integrating underlying isotopic variations from the host tissues. However, like for bulk isotope analysis, the application of a universal trophic discrimination factor to parasite–host relationships remains inappropriate for compound-specific stable isotope analysis. Despite this limitation, compound-specific stable isotope analysis is and will continue to be a valuable tool to increase our understanding of parasitic interactions in marine food webs.
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    The ‘Flood Resilience Rose’: A management tool to promote transformation towards flood resilience (2021)
    Blackwell Publishing Ltd | Oxford, UK
    Details
    Publication Date: 2021-09-29
    Description: Coping with the growing impacts of flooding in EU countries, a paradigm shift in flood management can be observed, moving from safety‐based towards risk‐based approaches and holistic perspectives. Flood resilience is a common denominator of most of the approaches. In this article, we present the ‘Flood Resilience Rose’ (FRR), a management tool to promote harmonised action towards flood resilience in European regions and beyond. The FRR is a result of a two‐step process. First, based on scientific concepts as well as analysis of relevant policy documents, we identified three ‘levels of operation’. The first level refers to the EU Floods Directive and an extended multi‐layer safety approach, comprising the four different layers of protection, prevention, preparedness and recovery, and related measures to be taken. This level is not independent but depends both on the institutional (second level) and the wider (third level) context. Second, we used surveys, semi‐structured interviews and group discussions during workshops with experts from Belgium, Denmark, Germany, the Netherlands and the United Kingdom to validate the definitions and the FRR's practical relevance. The presented FRR is thus the result of rigorous theoretical and practical consideration and provides a tool capable to strengthen flood risk management practice.
    Description: European Regional Development Fund http://dx.doi.org/10.13039/501100008530
    Keywords: 551.48 ; flood defence measures ; governance and institutions ; integrated flood risk management ; resilience
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    Seasonality of Mesoscale Phytoplankton Control in Eastern Fram Strait (2021)
    Wiley
    In:  EPIC3Journal of Geophysical Research: Oceans, Wiley, 126(10), ISSN: 2169-9275
    Details
    Publication Date: 2021-12-08
    Description: Globally, mesoscale processes create a rich and filamented pattern in biological productivity. Despite of remoteness and a harsh environment, observations likewise show an impact of mesoscale processes on phytoplankton growth in the Arctic. Observations of sufficiently high resolution are, however, difficult to carry out. Large-scale models are another way to gain knowledge about the system. In the current study, we use a global sea ice-ocean biogeochemical model, which is eddy resolving in Fram Strait, to show that the mesoscale dynamics has a strong effect on shaping phytoplankton growth. For the year 2009, we demonstrate that the growth season in the West Spitzbergen Current can be divided into two regimes; during Regime I, which takes place in May and June before and during the spring bloom, high chlorophyll concentrations are associated with areas of positive vorticity and a shallow mixed layer, pointing toward light limitation controlling growth. During Regime II, which occurs after the bloom from mid-July to late August, the highest chlorophyll concentration is found in areas of negative vorticity. Here, upwelling of nutrient-rich water occurs, through doming isopycnals, acting to raise the nutricline, may also play a role in alleviating nutrient limitation in the surface water. The study suggests that the mesoscale eddy environment locally modulates the seasonal cycle of light and nutrient limitation. Knowledge of the eddy field should be taken into consideration for making conclusions from point-wise measurements in Fram Strait.
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    Sensitivity to changes in the surface-layer turbulence parameterization for stable conditions in winter: A case study with a regional climate model over the Arctic (2021)
    Wiley
    In:  EPIC3Atmospheric Science Letters, Wiley, e1066, pp. 1-10
    Details
    Publication Date: 2021-12-16
    Description: The modeling of the atmospheric boundary layer over sea ice is still challenging because of the complex interaction between clouds, radiation and turbulence over the often inhomogeneous sea ice cover. There is still much uncertainty concerning sea ice roughness, near-surface thermal stability and related processes, and their accurate parameterization. Here, a regional Arctic climate model forced by ERA-interim data was used to test the sensitivity of climate simulations to a modified surface flux parameterization for wintertime conditions over the Arctic. The reference parameterization as well as the modified one is based on Monin–Obukhov similarity theory, but different roughness lengths were prescribed and the stability dependence of the transfer coefficients for momentum, heat and moisture differed from each other. The modified parameterization accounts for the most compre- hensive observations that are presently available over sea ice in the inner Arctic. Independent of the parameterization used, the model was able to reproduce the two observed dominant winter states with respect to cloud cover and longwave radiation. A stepwise use of the different parameterization assumptions showed that modifications of both surface roughness and stability dependence had a considerable impact on quantities such as air pressure, wind and near-surface turbulent fluxes. However, the reduction of surface roughness to values agreeing with those observed during t he Surface Heat Budget of the Arctic Ocean campaign led to an improvement in the western Arctic, while the modified stability parameteri- zation had only a minor impact. The latter could be traced back to the model's underestimation of the strength of stability over sea ice. Future work should concentrate on possible reasons for this underestimation and on the question of generality of the results for other climate models
    Repository Name: EPIC Alfred Wegener Institut
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    Bathymetric Control on Borchgrevink and Roi Baudouin Ice Shelves in East Antarctica (2021)
    Wiley
    In:  EPIC3Journal of Geophysical Research-Earth Surface, Wiley, 126(10), ISSN: 0148-0227
    Details
    Publication Date: 2021-10-18
    Description: The stability of ice shelves and drainage of ice sheets they buttress is largely determined by melting at their atmospheric and oceanic interfaces. Subglacial bathymetry can impact ice shelf stability because it influences the onset and the pattern of warm ocean water incursions into the cavities between them and the seafloor. Bathymetry is further important at pinning points, which significantly retard the flow of ice shelves. This effect can be lost instantaneously if basal and surface melting cause an ice sheet to thin and lift off its pinning points. With all this in mind, we have developed a model of bathymetry beneath the western Roi Baudouin and central and eastern Borchgrevink ice shelves in Dronning Maud Land based on inversion from gravity data and tied to available depth references offshore and subglacial topography inland of the grounding line. The model shows deep glacial troughs beneath the ice shelves and bathymetric sills close to the continental shelf. The central Borchgrevink Ice Shelf overhangs the continental slope by around 50km, exposing its northern parts to the open ocean and higher ocean temperatures. Continuous troughs traverse the central Borchgrevink and western Roi Baudouin ice shelves at depths greater than the offshore thermocline and thus present a risk of Warm Deep Water intrusions into their cavities under the current and future oceanographic regimes. Differing bathymetric characteristics might explain the ice shelves' contrasting dominant mass loss processes.
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    Evidence of Cascading Subglacial Water Flow at Jutulstraumen Glacier (Antarctica) Derived From Sentinel-1 and ICESat-2 Measurements (2021)
    Wiley
    In:  EPIC3Geophysical Research Letters, Wiley, 48(20), ISSN: 0094-8276
    Details
    Publication Date: 2021-10-22
    Description: Migration of subglacial water underneath thick Antarctic ice is difficult to observe directly but is known to influence ice flow dynamics. Here, we analyze a 6-year time series of displacement maps from differential Sentinel-1 SAR interferometry (DInSAR) in the upstream region of Jutulstraumen Glacier. Our results reveal short-term (between 12 days and 1 year) interconnected subsidence- and uplift events of the ice surface, which we interpret as a pressure response to the drainage and filling of subglacial lakes. This indicates an episodic cascade-like water transport with longer quiescent phases in a dynamically stable glacial setting. Abrupt events appear in the DInSAR time series and are confirmed by ICESat-2 altimetry. The events can be traced for a 1-year period along a urn:x-wiley:00948276:media:grl63164:grl63164-math-0001175 km flow path. We are able to observe the migration of subglacial water with unprecedented spatial and temporal resolution, providing a new observational baseline to further develop subglacial hydrological models.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
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  • 94
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    Unknown
    Influence of Early Low-Temperature and Later High-Temperature Diagenesis on Magnetic Mineral Assemblages in Marine Sediments from the Nankai Trough (2021)
    Wiley
    In:  EPIC3Geochemistry Geophysics Geosystems, Wiley, ISSN: 1525-2027
    Details
    Publication Date: 2021-10-21
    Description: Diagenesis can have a major impact on sedimentary mineralogy. Primary magnetic mineral assemblages can be modified significantly by dissolution or by formation of new magnetic minerals during early or late diagenesis. At International Ocean Discovery Program Site C0023, which was drilled in the protothrust zone of the Nankai Trough during Expedition 370, offshore of Shikoku Island, Japan, non-steady state conditions have produced a complex sequence of magnetic overprints. Detailed rock magnetic measurements, which characterize magnetic mineral assemblages in terms of abundance, grain size, and composition, were conducted to assess magnetic mineral alteration and diagenetic overprinting. Four magnetic zones (MZs) are identified down-core from ∼200 to 1100 meters below sea floor based on rock magnetic variations. MZ 1 is a high magnetic intensity zone that contains ferrimagnetic greigite, which formed at shallow depths and is preserved because of rapid sedimentation. MZs 2 and 4 are low magnetic intensity zones with fewer magnetic minerals, mainly coarse-grained (titano-)magnetite and hematite. This magnetic mineral assemblage is a remnant of a more complex assemblage that was altered diagenetically a few million years after deposition when the site entered the Nankai Trough. MZ 3 is a high magnetic intensity zone between MZs 2 and 4. It contains authigenic single-domain magnetic particles that probably formed from fluids that circulated through faults in the accretionary prism. Varying sediment supply and organic matter input through time, burial temperature, and tectonic fluid circulation are the primary drivers of magnetic mineral assemblage variations.
    Repository Name: EPIC Alfred Wegener Institut
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  • 95
    Electronic Resource
    Electronic Resource
    Bromide ion promoted .beta.-elimination in .alpha.-bromo ester substrates. Evidence for an intermediate in the E2C reaction (1983)
    s.l. : American Chemical Society
    The @journal of organic chemistry 48 (1983), S. 4502-4508 
    Details
    ISSN: 1520-6904
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1021/jo00172a012
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  • 96
    Electronic Resource
    Electronic Resource
    Aureolic acid antibiotics: a simple method for 2-deoxy-.beta.-glycosidation (1990)
    s.l. : American Chemical Society
    The @journal of organic chemistry 55 (1990), S. 5-7 
    Details
    ISSN: 1520-6904
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1021/jo00288a003
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  • 97
    Electronic Resource
    Electronic Resource
    Palladium-catalyzed alkenylation and alkynylation of polyhaloarenes (1990)
    s.l. : American Chemical Society
    The @journal of organic chemistry 55 (1990), S. 63-69 
    Details
    ISSN: 1520-6904
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1021/jo00288a013
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  • 98
    Electronic Resource
    Electronic Resource
    Stereoselective construction of the taxinine AB system through a novel tandem aldol-Payne rearrangement annulation (1990)
    s.l. : American Chemical Society
    The @journal of organic chemistry 55 (1990), S. 3-5 
    Details
    ISSN: 1520-6904
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1021/jo00288a002
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  • 99
    Electronic Resource
    Electronic Resource
    Theoretical evaluation of epimerization in Diels-Alder cycloadducts (1990)
    s.l. : American Chemical Society
    The @journal of organic chemistry 55 (1990), S. 28-33 
    Details
    ISSN: 1520-6904
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1021/jo00288a006
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  • 100
    Electronic Resource
    Electronic Resource
    A study of new bis(macrocyclic polyamine) ligands as inorganic and organic anion receptors (1990)
    s.l. : American Chemical Society
    The @journal of organic chemistry 55 (1990), S. 42-46 
    Details
    ISSN: 1520-6904
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1021/jo00288a009
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