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  • 1
    Publication Date: 2023-06-27
    Keywords: Age, 14C AMS; Age, 14C calibrated; Age, dated; Age, dated material; Age, dated standard error; AWI_Paleo; Biomarker; Calendar age; Calendar age, maximum/old; Calendar age, minimum/young; DEPTH, sediment/rock; Japan Sea; Laboratory code/label; Last Glacial; LV53-19-1; North Pacific; Paleoenvironmental Reconstructions from Marine Sediments @ AWI; paleo-oceanography; PC; Piston corer; sea-level; SST; TEX86; UK'37; upper ocean
    Type: Dataset
    Format: text/tab-separated-values, 49 data points
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  • 2
    Publication Date: 2023-06-27
    Keywords: AGE; AWI_Paleo; Biomarker; DEPTH, sediment/rock; Globigerina bulloides, δ18O; Japan Sea; Last Glacial; LV53-19-1; North Pacific; Paleoenvironmental Reconstructions from Marine Sediments @ AWI; paleo-oceanography; PC; Piston corer; sea-level; SST; TEX86; UK'37; upper ocean
    Type: Dataset
    Format: text/tab-separated-values, 33 data points
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  • 3
    Publication Date: 2023-06-27
    Description: Paleoceanographic evidence commonly indicates that Last Glacial Maximum surface temperatures in the Japan Sea were comparable to modern conditions, in striking difference to colder neighboring regions. Here, based on a core from the central Japan Sea, our results show similar UK′37- and TEXL86-derived temperatures between 24.7-16.3 ka BP, followed by an abrupt divergence at ~16.3 ka BP and a weakening of divergence after ~ 8.7 ka BP. We attribute this process to a highly stratified glacial upper ocean controlled by the East Asian Summer Monsoon, increasing thermal gradient between surface and subsurface layers during the deglaciation and the intrusion of Tsushima Warm Current since the mid Holocene, respectively. Therefore, we suggest threshold-like changes in upper-ocean temperatures linked to sea-level rise and monsoon dynamics, rather than just sea surface temperatures, play a critical role in shaping the thermal and ventilation history of this NW Pacific marginal sea.
    Keywords: AWI_Paleo; Biomarker; Japan Sea; Last Glacial; LV53-19-1; North Pacific; Paleoenvironmental Reconstructions from Marine Sediments @ AWI; paleo-oceanography; PC; Piston corer; sea-level; SST; TEX86; UK'37; upper ocean
    Type: Dataset
    Format: application/zip, 3 datasets
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  • 4
    Publication Date: 2023-12-18
    Keywords: Acyclic glycerol dialkyl glycerol tetraether; AGE; Alkenone, C37:2; Alkenone, C37:2+C37:3; Alkenone, C37:3; Alkenone, unsaturation index UK'37; AWI_Paleo; Biomarker; Branched and isoprenoid tetraether index; Branched glycerol dialkyl glycerol tetraether, Ia; Branched glycerol dialkyl glycerol tetraether, Ib; Branched glycerol dialkyl glycerol tetraether, Ic; Branched glycerol dialkyl glycerol tetraether, IIa; Branched glycerol dialkyl glycerol tetraether, IIb; Branched glycerol dialkyl glycerol tetraether, IIc; Branched glycerol dialkyl glycerol tetraether, IIIa; Branched glycerol dialkyl glycerol tetraether, IIIb; Branched glycerol dialkyl glycerol tetraether, IIIc; Calculated from TEX86H (Kim et al., 2010); Calculated from TEX86L (Kim et al., 2010); Calculated from UK'37 (Müller et al, 1998); Crenarchaeol; Crenarchaeol regio-isomer; DEPTH, sediment/rock; Dicyclic glycerol dialkyl glycerol tetraether; Isoprenoidal glycerol dialkyl glycerol tetraethers; Japan Sea; Last Glacial; LV53-19-1; Monocyclic glycerol dialkyl glycerol tetraether; North Pacific; Paleoenvironmental Reconstructions from Marine Sediments @ AWI; paleo-oceanography; PC; Piston corer; Ratio; Ring index; sea-level; Sea surface temperature; Sea surface temperature, annual mean; SST; Temperature, difference; Tetraether index of 86 carbon atoms, high-temperature region; Tetraether index of 86 carbon atoms, low-temperature region; TEX86; Tricyclic glycerol dialkyl glycerol tetraether; UK'37; upper ocean
    Type: Dataset
    Format: text/tab-separated-values, 645 data points
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  • 5
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The new monomer, α-(trityloxymethyl)acrylonitrile (2), was prepared. It can be polymerized anionically with optically active initiator systems to yield an insoluble polymer showing strong optical activity. In contrast to trityl methacrylate optically active polymers are obtained from 2 in toluene as well as in tetrahydrofuran. After removal of the trityl groups the optical activity is completely lost in the resulting poly[α-(hydroxymethyl)acrylonitrile]. It is therefore concluded that an atropisomeric helical arrangement is present in poly[α-(trityloxymethyl)acrylonitrile]. Compared to trityl methacrylate and its polymer the new monomer 2 and the corresponding polymer show higher stability against splitting off of the trityl groups.
    Additional Material: 9 Tab.
    Type of Medium: Electronic Resource
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  • 6
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Trityl methacrylate possesses two different substituents at the olefinic double bond. The larger one containing the trityl group forms the outside sphere of the helix in the corresponding polymers. In this paper the role of the second, smaller substituent is discussed. For this purpose four new monomers, methyl α-(trityloxymethyl)acrylate (5), ethyl α-(trityloxymethyl)acrylate (6), α-(trityloxymethyl)styrene (7), and trityl α-ethylacrylate (3), were prepared. Polymerization experiments showed that this substituent should be of minimum size to obtain a stable helix. More extended substituents though do not fit into the helical arrangement and therefore neither anionic nor radical polymerization was achieved.
    Additional Material: 3 Tab.
    Type of Medium: Electronic Resource
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  • 7
    Publication Date: 2021-08-05
    Description: Paleoceanographic evidence commonly indicates that Last Glacial Maximum surface temperatures in the Japan Sea were comparable to modern conditions, in striking difference to colder neighboring regions. Here, based on a core from the central Japan Sea, our results show similar UK′37‐ and TEXL86‐derived temperatures between 24.7 and 16.3 ka BP, followed by an abrupt divergence at ~16.3 ka BP and a weakening of divergence after ~8.7 ka BP. We attribute this process to a highly stratified glacial upper ocean controlled by the East Asian Summer Monsoon, increasing thermal gradient between surface and subsurface layers during the deglaciation and the intrusion of Tsushima Warm Current since the mid‐Holocene, respectively. Therefore, we suggest that threshold‐like changes in upper‐ocean temperatures linked to sea level rise and monsoon dynamics, rather than just sea surface temperatures, play a critical role in shaping the thermal and ventilation history of this NW Pacific marginal sea.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
    Format: application/pdf
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  • 8
    Publication Date: 2021-05-16
    Description: Investigating the composition and distribution of pelagic marine sediments is fundamental in the field of marine sedimentology. The spatial distributions of surface sediment are unclear due to limited investigation along the Emperor Seamount Chain of the North Pacific. In this study, a suite of sedimentological and geochemical proxies were analyzed, including the sediment grain size, organic carbon, CaCO3, major and rare earth elements of 50 surface sediment samples from the Emperor Seamount Chain, spanning from ∼33°N to ∼52°N. On the basis of sedimentary components, we divide them into three Zones (I, II, and III) spatially with distinct features. Sediments in Zone I (∼33°N–44°N) and Zone III (49.8°N–53°N) are dominated by clayey silt, and mainly consist of sand and silty sand in Zone II. The mean grain size of the sortable silt shows that the hydrodynamic condition in the study area is significantly stronger than that of the abyssal plain, especially at the water depth of 1,000–2,500 m. The CaCO3 contents in sediments above 4,000 m range from 20 to 84% but decrease sharply to less than 1.5% below 4,000 m, confirming that the water depth of 4,000 m is the carbonate compensation depth of the study area. Strong positive correlations between Al2O3 and Fe2O3, TiO2, MgO, and K2O (R 〉 0.9) in the bulk sediments indicate pronounced contributions of terrigenous materials from surrounding continent mass to the study area. Furthermore, the eolian dust makes contributions to the composition of bulk sediments as confirmed by rare earth elements. There is no significant correlation between grain size and major and minor elements, which indicates that the sedimentary grain size does not exert important effects on terrigenous components. There is significant negative δCe and positive δEu anomalies at all stations. The negative Ce anomaly mainly exists in carbonate-rich sediments, inheriting the signal of seawater. The positive Eu anomaly indicates widespread volcanism contributions to the study area from active volcanic islands arcs around the North Pacific. The relative contributions of terrestrial, volcanic, and biogenic materials vary with latitude and water depth in the study area.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
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  • 9
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    ELSEVIER SCIENCE BV
    In:  EPIC3Palaeogeography Palaeoclimatology Palaeoecology, ELSEVIER SCIENCE BV, 479, pp. 61-70, ISSN: 0031-0182
    Publication Date: 2017-06-12
    Description: In this study, we investigate light and heavy minerals in sediment core OS03-1 located at the Academy of Sciences Rise of the southern Okhotsk Sea to determine their distributions and sources over the last 180 ka (thousand years). The sediment mainly consists of terrigenous and volcanic detritus. Ubiquitous drop-stones and volcanic detritus throughout the core and high detrital input suggest that sea ice, driven by wind and Kamchatka Current, was the main transport agent of detrital materials to the southern Okhotsk Sea. The ternary diagram of heavy minerals (hornblende-hypersthene-epidote) shows an expansion of detritus provenance from the eastern in cold periods to the northeastern in warm intervals of the Okhotsk Sea. It mainly relates to the shift of Aleutian Low. Combined with previous records, accumulation rates of quartz indicated a maximum extent but not perennial sea ice coverage during the glacial periods.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
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  • 10
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    European Geosciences Union
    In:  EPIC3EGU General Assembly - Sharing Geoscience Online, Virtual Online Meeting, 2020-05-04-2020-05-08European Geosciences Union
    Publication Date: 2020-05-14
    Repository Name: EPIC Alfred Wegener Institut
    Type: Conference , notRev
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