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  • Wiley-Blackwell
  • 2010-2014  (18)
  • 1980-1984  (8,161)
  • 1925-1929
  • 2014  (18)
  • 1980  (8,161)
Collection
Years
  • 2010-2014  (18)
  • 1980-1984  (8,161)
  • 1925-1929
Year
  • 1
    Publication Date: 2020-12-15
    Description: We present a time-independent gridded earthquake rate forecast for the European region including Turkey. The spatial component of our model is based on kernel density estimation techniques, which we applied to both past earthquake locations and fault moment release on mapped crustal faults and subduction zone interfaces with assigned slip rates. Our forecast relies on the assumption that the locations of past seismicity is a good guide to future seismicity, and that future large-magnitude events occur more likely in the vicinity of known faults. We show that the optimal weighted sum of the corresponding two spatial densities depends on the magnitude range considered. The kernel bandwidths and density weighting function are optimized using retrospective likelihood-based forecast experiments. We computed earthquake activity rates (a- and b-value) of the truncated Gutenberg–Richter distribution separately for crustal and subduction seismicity based on a maximum likelihood approach that considers the spatial and temporal completeness history of the catalogue. The final annual rate of our forecast is purely driven by the maximum likelihood fit of activity rates to the catalogue data, whereas its spatial component incorporates contributions from both earthquake and fault moment-rate densities. Our model constitutes one branch of the earthquake source model logic tree of the 2013 European seismic hazard model released by the EU-FP7 project ‘Seismic HAzard haRmonization in Europe’ (SHARE) and contributes to the assessment of epistemic uncertainties in earthquake activity rates. We performed retrospective and pseudo-prospective likelihood consistency tests to underline the reliability of our model and SHARE’s area source model (ASM) using the testing algorithms applied in the collaboratory for the study of earthquake predictability (CSEP). We comparatively tested our model’s forecasting skill against the ASM and find a statistically significant better performance for testing periods of 10–20 yr. The testing results suggest that our model is a viable candidate model to serve for long-term forecasting on timescales of years to decades for the European region.
    Description: EC-Research FP7-projects, SHARE, under grant agreement No. 226967 and NERA, under grant agreement No. 262330
    Description: Published
    Description: 1159-1172
    Description: 2T. Tettonica attiva
    Description: 3T. Pericolosità sismica e contributo alla definizione del rischio
    Description: JCR Journal
    Description: restricted
    Keywords: Probabilistic forecasting ; Statistical seismology ; Europe ; 04. Solid Earth::04.06. Seismology::04.06.02. Earthquake interactions and probability ; 04. Solid Earth::04.06. Seismology::04.06.11. Seismic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 2
    Publication Date: 2021-06-07
    Description: Episodic gas seepage occurs at the seafloor in the Gulf of Izmit (Sea of Marmara, NW Turkey) along the submerged segment of the North Anatolian Fault (NAF), which ruptured during the 1999 Mw7.4 Izmit earthquake, and caused tectonic loading of the fault segment in front of the Istanbul metropolitan area. In order to study gas seepage and seismic energy release along the NAF, a multiparametric benthic observatory (SN-4) was deployed in the gulf at the western end of the 1999 Izmit earthquake rupture, and operated for about 1 yr at 166 m water depth. The SN-4 payload included a three-component broad-band seismometer, as well as gas and oceanographic sensors. We analysed data collected continuously for 161 d in the first part of the experiment, from 2009 October to 2010 March. The main objective of our work was to verify whether tectonic deformation along the NAF could trigger methane seepage. For this reason, we considered only local seismicity, that is, within 100 km from the station. No significant (ML ≥ 3.6) local earthquakes occurred during this period; on the other hand, the seismometer recorded high-frequency SDEs (short duration events), which are not related to seismicity but to abrupt increases of dissolved methane concentration in the sea water that we called MPEs (methane peak events). Acquisition of current velocity, dissolved oxygen, turbidity, temperature and salinity, allowed us to analyse the local oceanographic setting during each event, and correlate SDEs to episodic gas discharges from the seabed. We noted that MPEs are the result of such gas releases, but are detected only under favourable oceanographic conditions. This stresses the importance of collecting long-term multiparametric time-series to address complex phenomena such as gas and seismic energy release at the seafloor. Results from the SN-4 experiment in the Sea of Marmara suggest that neither low-magnitude local seismicity, nor regional events affect intensity and frequency of gas flows from the seafloor.
    Description: Published
    Description: 850-866
    Description: 1T. Geodinamica e interno della Terra
    Description: 3A. Ambiente Marino
    Description: 7A. Geofisica di esplorazione
    Description: JCR Journal
    Description: restricted
    Keywords: Time-series analysis ; Seismicity and tectonics ; Broad-band seismometers ; multiparametric seafloor observatory ; Izmit Gulf ; Sea of Marmara ; gas seepage ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 04. Solid Earth::04.04. Geology::04.04.04. Marine geology ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 3
    Publication Date: 2017-04-04
    Description: This paper describes an application of artificial neural networks for the recognition of volcanic lava flow hot spots using remote sensing data. Satellite remote sensing is a very effective and safe way to monitor volcanic eruptions in order to safeguard the environment and the people affected by such natural hazards. Neural networks are an effective and well-established technique for the classification of satellite images. In addition, once well trained, they prove to be very fast in the application stage. In our study a back propagation neural network was used for the recognition of thermal anomalies affecting hot lava pixels. The network was trained using the three thermal channels of the Advanced Very High Resolution Radiometer (AVHRR) sensor as inputs and the corre- sponding values of heat flux, estimated using a two thermal component model, as reference outputs. As a case study the volcano Etna (Eastern Sicily, Italy) was chosen, and in particular the effusive eruption which took place during the month of 2006 July. The neural network was trained with a time-series of 15 images (12 nighttime images and 3 daytime images) and validated on three independent data sets of AVHRR images of the same eruption and on two relative to an eruption occurred the following month. While for both nighttime and daytime validation images the neural network identified the image pixels affected by hot lava with a 100 per cent success rate, for the daytime images also adjacent pixels were included, apparently not interested by lava flow. Despite these performance differences under different illumination conditions, the proposed method can be considered effective both in terms of classification accuracy and generalization capability. In particular our approach proved to be robust in the rejection of false positives, often corresponding to noisy or cloudy pixels, whose presence in multispectral images can often undermine the performance of traditional classification algorithms. Future work shall address application of the proposed method to data acquired with a high temporal resolution, such as those provided by the spinning enhanced visible and infrared imager sensor on board the Meteosat second generation geostationary satellite.
    Description: Published
    Description: 1525-1535
    Description: 5V. Sorveglianza vulcanica ed emergenze
    Description: JCR Journal
    Description: restricted
    Keywords: Image processing ; Neural networks ; fuzzy logic ; Remote sensing of volcanoes ; Hot-spot detection ; Mt. Etna ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 4
    Publication Date: 2017-04-04
    Description: We present a systematic study on the influence of pressure (0.1–600 MPa), temperature (750– 1200 ◦C), carbon dioxide fugacity (logfCO2 = −4.41 to 3.60) and time (2–12 hr) on the chemical and physical properties of carbonate rock. Our experiments aim to reproduce the conditions at the periphery of magma chamber where carbonate host rock is influenced by, but not readily assimilated by, magma. This permits the investigation of the natural conditions at which circulating fluids/gases promote infiltration reactions typical of metasomatic skarns that can involve large volumes of subvolcanic carbonate basements. Results show that, providing that carbon dioxide is retained in the pore space, decarbonation does not proceed at any magmatic pressure and temperature. However, when the carbon dioxide is free to escape, decarbonation can occur rapidly and is not hindered by a low initial porosity or permeability. Together with carbon dioxide and lime, portlandite, a mineral commonly found in voluminous metasomatic skarns, readily forms during carbonate decomposition. Post-experimental analyses highlight that thermal microcracking, a result of the highly anisotropic thermal expansion of calcite, exerts a greater influence on rock physical properties (porosity, ultrasonic wave velocities and elastic moduli) than decarbonation. Our data suggest that this will be especially true at the margins of dykes or magma bodies, where temperatures can reach up to 1200 ◦C. However, rock compressive strength is significantly reduced by both thermal cracking and decarbonation, explained by the relative weakness of lime + portlandite compared to calcite, and an increase in grain size with increasing temperature. Metasomatic skarns, whose petrogenetic reactions may involve a few tens of cubic kilometres, could therefore represent an important source of volcanic instability.
    Description: Published
    Description: 369-380
    Description: 2R. Laboratori sperimentali e analitici
    Description: JCR Journal
    Description: restricted
    Keywords: Volcanic hazards and risks ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 5
    Publication Date: 2017-04-04
    Description: Interactions of conduit geometry with gas–liquid flows control volcanic activity, implying that the evaluation of volcanic hazards requires quantitative understanding of the inner structure of the volcano. The more established geophysical imaging techniques suffer from inherent ambiguity, may require spatially dense measurements in active areas and may not provide sufficient spatial resolution in the uppermost part of the conduit system. It is thus desirable to develop new imaging techniques allowing a better spatial resolution of a volcano's upper feeding system, with reduced ambiguity and a low level of risk for operators. Muon particles can be utilized to image the internal density distribution of volcanic structures. The principle of muon radiography is essentially the same as X-ray radiography, except for substituting penetrating particles in place of photons. Muons are more attenuated by higher density parts inside the target and thus information about its inner structure are obtained from the differential muon absorption. We report on a muon-imaging experiment that was conducted at Mt Etna in 2010. The target structure was one of the summit craters of the volcano. This experiment was performed using a muon telescope suitably designed to withstand the harsh conditions in the summit zone of a high volcano. We found a marked difference between synthetic and observed attenuation of muons through the target. This discrepancy is likely due to the bias on the observed flux, arising from false muon tracks. They are caused by low-energy particles that, by chance, hit simultaneously the two matrixes of the telescope, leading to detection of a false positive. We separated the useful from the unwanted signal through a first-order model of the background noise. The resulting signal is compared with the corresponding synthetic flux. Eventually, we found regions of higher- and lower-than-expected muon flux, that are possibly related to inner features of the target crater.
    Description: Published
    Description: 633-643
    Description: 2V. Dinamiche di unrest e scenari pre-eruttivi
    Description: JCR Journal
    Description: restricted
    Keywords: Tomography; Volcano monitoring; Volcanic hazards and risks ; 04. Solid Earth::04.03. Geodesy::04.03.06. Measurements and monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 6
    Publication Date: 2017-04-04
    Description: The identification of a source model for the catastrophic 1908 December 28 Messina earth- quake (Mw = 7.2) has been the subject of many papers in the last decades. Several authors proposed different models on the basis of seismological, macroseismic and geodetic data sets; among these models, remarkable differences exist with regard to almost all parameters. We selected a subset of six models among those most cited in literature and used them to model the post-seismic sea level variation recorded at the tide gauge station of Messina (until 1923), to attempt an independent discrimination among them. For each model, we assumed a simple rheological structure and carried out a direct-search inversion of upper crust thickness and lower crust viscosity to fit the post-seismic sea level signal. This approach enabled us to iden- tify a class of fault geometries which is consistent with the post-seismic signal at the Messina tide gauge and with the known structural and rheological features of the Messina strait
    Description: Published
    Description: 611-622
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: JCR Journal
    Description: open
    Keywords: Sea level change ; Earthquake source observations ; Rheology: crust and lithosphere ; 04. Solid Earth::04.07. Tectonophysics::04.07.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 7
    Publication Date: 2017-04-04
    Description: When remote sensing users are asked to define their requirements for a new sensor, the big question that always arises is: will the technical specifications meet the scientific requirements? Herein, we discuss quantitative relationships between instrumental spectral and radiometric characteristics and data exploitable for lava flow subpixel temperature analysis. This study was funded within the framework of ESA activities for the IR GMES (Global Monitoring for Environment and Security) element mission requirements in 2005. Subpixel temperature retrieval from satellite infrared data is a well-established method that is well documented in the remote sensing literature. However there is little attention paid to the error analysis on estimated parameters due to atmospheric correction and radiometric accuracy of the sensor. In this study, we suggest the best spectral bands combination to estimate subpixel temperature parameters. We also demonstrate that poor atmospheric corrections may vanish the effectiveness of the most radiometrically accurate instrument.
    Description: Published
    Description: 112-125
    Description: 3V. Dinamiche e scenari eruttivi
    Description: JCR Journal
    Description: restricted
    Keywords: Remote sensing, error analysis, IR sensors, sub-pixel temperature, Numerical solutions; Non-linear differential equations; Effusive volcanism; Eruption mechanisms and flow emplacement; Remote sensing of volcanoes; Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 8
    Publication Date: 2021-11-25
    Description: Here we inverted the GPS data to infer the coseismic slip of the Tohoku-Oki earthquake and the time-dependent afterslip distribution in the 4 months following the main shock. The Tohoku-Oki earthquake showed an unexpected magnitude and a characteristic depth-dependent differentiation of seismic energy radiation. In this context the estimation and comparison of the distribution of the fault portions that slip coseismically and post-seismically contribute to a better understanding of the variation of frictional characteristics of the plate interface. The inferred coseismic slip extends in a relatively compact region located updip from the hypocentre and reaches its highest value (about 60 m) near the trench. Afterslip occurs mostly outside the coseismic rupture and is distributed in two main modal centres. It reaches its largest values in an area located downdip of the coseismic slip and extends to a depth of 80 km. In the depth range between 30 and 50 km afterslip overlaps the portion of the fault that experienced historical moderate earthquakes, high-frequency seismic radiation and thrust-type aftershocks. The behaviour of this area can be explained by a rheologically heterogeneous region made of a ductile fault matrix interspersed with compact brittle asperities. On the contrary, the region beneath 50–60 km depth is probably characterized by a fully velocity strengthening behaviour. Southern afterslip, located off-Chiba Prefecture, is probably related to the Mw 7.9 Ibaraki-Oki aftershock. The northward extension of the afterslip stops at a latitude of about 40◦ N, just south of the off-Aomori region. This may be related to three large events occurred in this area during the last century and the consequent strong coupling or complete depletion of the accumulated strain that characterize this region.
    Description: Published
    Description: 580-596
    Description: 2T. Tettonica attiva
    Description: JCR Journal
    Description: restricted
    Keywords: Satellite geodesy; Seismic cycle; Earthquake source observations; Subduction zone processes ; 04. Solid Earth::04.06. Seismology::04.06.01. Earthquake faults: properties and evolution ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.04. Plate boundaries, motion, and tectonics ; 04. Solid Earth::04.07. Tectonophysics::04.07.06. Subduction related processes
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 9
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    Wiley-Blackwell
    In:  EPIC3Functional Ecology, Wiley-Blackwell, 28, pp. 1482-1493, ISSN: 0269-8463
    Publication Date: 2023-09-15
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
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  • 10
    Electronic Resource
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 26 (1980), S. 152-154 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Ill.
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  • 11
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 7 Ill.
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  • 12
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 26 (1980), S. 148-150 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Ill.
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  • 13
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 26 (1980), S. 174-174 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 14
    Electronic Resource
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 26 (1980), S. 175-176 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 15
    Electronic Resource
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 26 (1980), S. 177-201 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: This article reviews the major developments in the engineering and design of three-phase slurry catalytic reactors. A general theoretical analysis for predicting the overall rate of reaction in a slurry reactor for various kinetics is presented, incorporating all the transport effects. Modeling of semi-batch reactors is discussed and design procedures are indicated. Some major correlations and methods for determining gas-liquid and liquid-solid mass transfer coefficients and effective diffusivity in liquid filled pores are reviewed. Slurry reactors are compared with other three-phase reactors, such as trickle bed or packed bed reactors, and relative merits are pointed out.
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  • 16
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    AIChE Journal 26 (1980), S. 201-212 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Intraparticle mass transfer in coal pyrolysis is described by ternary diffusion and viscous flow, in conjunction with a simple pore model to predict concentration profiles for gases and tar. At low pressures, product yields depend on particle size only, while at high pressures they depend on pressure and particle size. Limited experimental data from a subbituminous coal confirm these trends. Data from a bituminous coal show different trends, as expected from the drastic changes the pore structure undergoes during pyrolysis.
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  • 17
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: When primary control objectives cannot be measured directly, secondary measurements have to be selected and used in conjunction with estimators to infer the value of the unmeasurable variables. Unmeasured process disturbances (state excitation noise) are assumed to be of major importance, dominating the errors caused by measurement noise. Since the white noise assumption is generally insufficient for the persistent disturbances commonly occuring in the Chemical Engineering, environment, a nonstationary noise model has been employed, and is shown to yield superior estimations under these circumstances. New necessary and sufficient conditions have been developed for the observability of the dynamic system augmented to include the noise model.A variety of new measurement selection criteria is presented here, with the goal of minimizing estimation error. One class of criteria aims at minimizing the transient estimation error when a static estimator is used. The other class minimizes the measurement error caused by the unobservable subspace. The design of state reconstruction procedures (which are able to handle persistent unmeasured process disturbances) is explained in a stochastic and a deterministic framework. Finally, the synthesis of reduced order control schemes is discussed. The power of the selection criteria and the superiority of a Kalman filter design employing a nonstationary noise model is demonstrated in many examples.
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  • 18
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    AIChE Journal 26 (1980), S. 274-281 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A three-parameter model of axial and radial dispersion in a packed tubular reactor is proposed as an alternative to the Fickian dispersion model. Though it is formulated in terms of differential equations, it requires no exit boundary condition, so it is mathematically more convenient than the Fickian model. Examples of its application to chemical reactors are given.
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  • 19
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    AIChE Journal 26 (1980), S. 287-288 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 20
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    AIChE Journal 26 (1980), S. 308-310 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 21
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    AIChE Journal 26 (1980), S. 314-317 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 22
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    AIChE Journal 26 (1980), S. 317-319 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 23
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    AIChE Journal 26 (1980), S. 325-327 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 24
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    AIChE Journal 26 (1980), S. 1-9 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: This article describes a novel approach to the systematic synthesis of heat exchanger networks. For a given synthesis problem, this approach leads to a complete listing of all solutions which exist, using a prescribed degree of energy recovery, the minimum number of exchangers, heaters and coolers, and no split streams. The approach is combinatorial, with a variety of thermodynamic criteria used to minimize the problem size by preventing infeasible solutions being generated. Two examples (5SPI and 6SPI) are discussed to illustrate complete solution by hand.
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  • 25
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    AIChE Journal 26 (1980), S. 24-30 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: For moving-bed solids flow in an inclined pipe leading into a fluidized bed, the pressure drop across the pipe is a retarding force while the gas leakage rate alters the flow properties of the solids. The pressure drop has been related to the pipe exit pressure, which, in turn, can be calculated by integrating the solids bulk density over the bed depth. A correlation for the rate of gas leakage in terms of the geometric features and operating conditions of the system is developed. The correlation agrees with experimental data to within ± 25%. Part II of this paper will deal with solids flow.
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  • 26
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    AIChE Journal 26 (1980), S. 43-51 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Diffusion in concentrated, non-ideal liquid solutions may take place not only through motion of single molecules but also through movement of groups of molecules, or “clusters.” Analyzing this cluster diffusion leads to predictions that the diffusion coefficient can vary with the square root of the usual activity corrections to diffusion. These predictions seem consistent with experiments, particularly in highly non-ideal solutions.
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  • 27
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    AIChE Journal 26 (1980), S. 60-67 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A reactor of fiour crossflow nomolithic blocks is used to approximate a cocurrent and a countercurrent reactor-heat excanger. Essentailly isothermal reaction pass profiles are produced by flowing the coolant and reactant streams cocurrent to each other according to the criteria set down in Part I of this paper. A multiplicy of steady states is shown to exist for the autothermal countercurrent mode, but not for the autothermal cocurrent mode, under identical conditions.
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  • 28
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: There are several ways to remove minral matter from coal-derived liquids: antisolvent agglomeration and subsequent sedimentation is one. Adding antisolvent to coal liquids causes asphaltenes and/or preasphaltenes in the oil to precipitate. The precipitated asphaltenes then agglomerate the paraticles, increasing the sedimentation rate. The magnitude of this increase depend no the mixing conditions used to dispers the antisolvent in the oil.This article discuss the results of sedimentation experiments performed onthe antisolvent addition to coal liquids, using an x-ray detection system. The system has the capacity of high temperature (up to 315°C) and high pressure (up to 2.75 7 × 106 Pa). The important parameters are the mixing time, the impeller speed, and the antisolvent addition rate. These are studied in detail for the antisolvent Soltrol.
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    AIChE Journal 26 (1980), S. 132-134 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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    AIChE Journal 26 (1980), S. 136-139 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: NO Abstract.
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    AIChE Journal 26 (1980), S. 144-148 
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    Keywords: Chemistry ; Chemical Engineering
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    Notes: Slugging experiments were performed in a semicircular Plexiglas column 5.6 m in height to study the effect of an expanded section on slugging. The bottom section of the column (3.05 m long) is 28.6 cm in inside diameter and the expanded section 40.6 cm. Both the bed height and the fluidizing velocity were varied during the study, and the results were successfully correlated with a theoretically derived equation. The implications in designing a bed with an expanded section to reduce the slugging effectively are also discussed.
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    AIChE Journal 26 (1980), S. 154-157 
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    Keywords: Chemistry ; Chemical Engineering
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    AIChE Journal 26 (1980), S. 507-510 
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    Keywords: Chemistry ; Chemical Engineering
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    AIChE Journal 26 (1980), S. 510-513 
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    Notes: Ruthven (1976) published thermodynamic and kinetic data on the adsorption of five gases in zeolites over a wide range of temperatures and concentrations. We have described zeolite diffusivities with a model based on the discrete structure of zeolite crystals and a statistic-thermodynamic evaluation of equilibrium measurements (Fiedler and Celbin 1978). Prof. Ruthven has kindly sent us tables of results for all systems in his paper, which we analyze below.
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    AIChE Journal 26 (1980), S. 526-526 
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    AIChE Journal 26 (1980) 
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    AIChE Journal 26 (1980), S. 517-521 
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    AIChE Journal 26 (1980), S. 526-526 
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    AIChE Journal 26 (1980), S. 527-528 
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    AIChE Journal 26 (1980), S. 529-536 
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    Notes: Models of the role of the interstitial fluid for dispersion in a fixed bed for very high Reynolds numbers are examined in detail to determine how well they fit the physical requirements of finite speed of signal propagation, no backmixing, conservation and correct asymptotic form. It is concluded that no linear continuous partial differential equation of finite order can satisfy all of these requirements as well as the cell model, although all models for sufficiently large axial space and time variables are very good approximations to the cell model. Some new hyperbolic models are presented and their solutions obtained and compared with the standard solutions. In present day design it appears that no model has an outstanding advantage over any other.
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    Notes: The simultaneous solution of all the equations for a general system of interlinked, multistaged separators is considered. The interlinks may be simple streams or reciprocal streams, and a particular separator may have bypassing streams (for example, pumparounds). Algorithms are developed that automatically arrange the linearized equations so that for a Newton-Raphson type of solution procedure using, for example, the Naphtali-Sandholm technique, a minimum or nearly minimum number of nonzero blocks occur outside the tridiagonal band so that computational memory and time requirements are minimized. The nonzero and nonidentity blocks are stored in a single vector of variable dimension.
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    AIChE Journal 26 (1980), S. 602-610 
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    Notes: Measurements were made of the steady state flux of sulfur dioxide through films of water and solutions of neutral and alkaline sodium salts (0.1 to 2.0 M sodium chloride, 10-3 to 3.0M sodium hydroxide, NaHSO3 or sodium sulfite) with sulfur dioxide partial pressures between 10 and 100Pa. In agreement with equilibrium theory (Part I), data from water and sodium chloride solutions show that HSO3- is responsible for 83 to 95% of the flux (facilitation factor F between 5 and 19). In alkaline solutions, HSO3- and other sulfur containing species cause F to be as large as 1 370. Equilibrium theory, however, overpredicts F by up to a factor of 7. The NEBLA (Part I) accounts for this deviation.
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    AIChE Journal 26 (1980), S. 635-641 
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    Notes: There are many industrially important reactions in which the chemical kinetics and external diffusion govern the observed reaction rate, and the observed kinetics differ drastically from the true kinetics. This study shows that the forward stagnation flow region of a circular cylinder can be a convenient system for studying the true kinetics of a solid catalyzed reaction owing to its unique property of uniform accessibility.
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    AIChE Journal 26 (1980), S. 663-669 
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    Notes: A five plate distillation column, 100 mm in diameter, has been used to study both fluid mixing and the mass transfer separations of mixtures of methylcyclohexane and n-heptane under periodically cycled conditions. Both the fluid mixing and mass transfer could be successfully analyzed using the (2S) model to describe the liquid movement in the column. Previously reported results by McWhirter and Lloyd could not be reproduced. Only moderate improvements in separating ability can be obtained with sieve plates and packed sieve plate columns operated in the cycled mode.
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    AIChE Journal 26 (1980) 
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  • 47
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    Notes: In an earlier article, a Corresponding States Method was presented for predicting the saturated liquid densities of both pure components and mixtures. The method is based on the known saturated liquid densities of two reference fluids and requires the critical properties and acentric factors of the pure components as input parameters. We use the method here to calculate the swelling factors of CO2-crude oil mixtures using CO2 and n-dodecane as the reference fluids. The critical properties and acentric factors of the crude oils were estimated from their API gravities and Watson K-factors. Using only one adjustable coefficient to characterize each CO2-crude oil system, swelling factors were calculated to within 0.5% of their experimental values. The single, adjustable coefficient is linearly related to the boiling point of the crude.
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    AIChE Journal 26 (1980), S. 372-378 
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    Notes: A cubic perturbed, hard sphere equation of state which combines the hard sphere expression of Scott and the empirical attractive term of Redlich and Kwong with two temperature dependent parameters has been successfully applied to the calculation of pure component properties and vapor-liquid equilibrium values.
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    AIChE Journal 26 (1980), S. 390-398 
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    Notes: Trajectories of bubbles and entrained particles in the rotating fluidized bed were obtained from equations expressing a balance among inertial, centrifugal, Coriolis, gravity and drag forces. The solutions led to information on the behavior of isolated bubbles, bubbles swarms and the elutriation characteristics of the rotating fluidized bed.
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    AIChE Journal 26 (1980), S. 411-419 
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    Notes: We identify dispersion approximations to the transverse average of the solution of the convective diffusion equation on exacting equality of a finite number of axial Hermite moments. The method unifies the dispersion of chemically active and passive solutes and generalizes dispersion theory to arbitrary transverse averages. We emphasize the importance of the scalar results via their application to the dispersion of a system of chemical isomers.
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    AIChE Journal 26 (1980), S. 443-454 
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    Notes: When an aerocolloidal suspension flows through a fibrous filter, particles deposit on the fibers and form dendrites. Similar phenomena are observed with collectors other than fibers, provided that the characteristic dimension of the collector does not exceed that of the particles by more than one to two orders of magnitude. This deposition pattern leads to marked increases in capture efficiency and pressure drop, as particles accumulate within the filter. In previous publications, theoretical models of this process were developed for the cases of deposition by interception alone and of deposition by combined inertial impaction and interception. Consequently, those works apply to aerosol particles with diameters of 1 μm or larger. Here we extend the model to the case of submicron particles, where the main transport mechanism is Brownian diffusion. To keep things specific, we consider fine fibers as collectors, but the model can be easily converted to other geometries. We present solutions for the cases of nonslip flow around the fiber and nonslip, slip and free molecular flow around particles. Unlike deposition by inertial impaction and/or interception, convective Brownian diffusion forms dendrites over the entire fiber surface.
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    AIChE Journal 26 (1980), S. 471-477 
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    Notes: The performances of cylindrical and conical thickeners are compared by means of calculations, using published data on the properties of a suspension. Experimental data on the operation of cylindrical thickeners indicate that sludge funneling at the bottom of such thickeners has a large effect and is a possible cause of observed discrepancies between theory and experiment.
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    AIChE Journal 26 (1980), S. 487-496 
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    Notes: A model is developed for the gasification of a single-char particle in an environment of water, hydrogen, carbon dioxide, carbon monoxide and methane, existing in the gasification zone of a reactor. The model, consisting of the mass and energy conservation equations, together with the Stefan-Maxwell relations includes the intraparticle effects and the change in internal surface area. It is found that the intraparticle effects and the surface area effects are significant and hence cannot be neglected, and the situation becomes more acute with increasing particle size and high temperatures. Comparisons with other models and existing empirical relations show that the model agrees well when diffusional effects are minimal, but at higher temperature and large pariticle size there is a significant difference. The model may be used to discriminate among various idealized models such as the homogeneous and the shrinking core model. The conyective terms in the Stefan-Maxwell relations have negligible influence. The analysis can be directly used in the modeling studies of gasification reactors and will be so applied in a later paper.
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    AIChE Journal 26 (1980), S. 496-504 
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    Notes: A study of the identification of the dynamics of a pilot scale absorption-desorption system and the subsequent design of a multivariable control scheme are reported. A multivariable transfer function model was obtained from experimental input-output data in which the inputs (steam supply and liquid circulation rate) were perturbed simultaneously using uncorrelated pseudo random sequences. A two-step, least-squares estimator was employed for the identification of the model.A multivariable controller was then designed on the basis of the direct Nyquist array method. The implementation of the controller design indicated the utility of the design procedure as compared to independent single input, single output control loops; there is, however, some scope for additional tuning.
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    AIChE Journal 26 (1980), S. 513-517 
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    AIChE Journal 26 (1980), S. 828-832 
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    Notes: A new numerical method is proposed for the one-dimensional melting problem. Unlike many of the existing numerical techniques which either immobilize the moving interface by a suitable coordinate transformation or search for the moving interface under a fixed grid, fixed-time-step finite-difference formulation, the present method was a fixed grid, variable time-step approach. Each time step in the computation is determined iteratively by requiring that the interface be located at a mesh point, one grid space from the previous interface location.Results of two sample calculations show that the present method is superior to the conventional finite-difference method both in its accuracy and computational efficiency. The formulation is mathematically simple and can be applied with no difficulty to problems with nonplanar geometry and initial subcooling. The present method is applied to the analysis of the melting of a finite slab subjected to a constant heat flux boundary condition. Some interesting effects of initial subcooling on the physics of melting are illustrated and discussed.
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    AIChE Journal 26 (1980), S. 850-852 
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    AIChE Journal 26 (1980), S. 869-872 
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    Notes: Goodman's integral heat and mass balance method is applied to the problem of a moving boundary in a spherical particle. The moving boundary was fixed by a suitable transformation for ease in solution. The mean value theorem was used to treat the nonlinearities when they occurred. Relations for the heat and mass boundary positions are obtained for the most general conditions. These expressions reduce in their limiting cases to known results.
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    AIChE Journal 26 (1980), S. 876-876 
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    Keywords: Chemistry ; Chemical Engineering
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    AIChE Journal 26 (1980), S. 876-876 
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    Keywords: Chemistry ; Chemical Engineering
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    AIChE Journal 26 (1980), S. 891-901 
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    Keywords: Chemistry ; Chemical Engineering
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    Notes: Multistage permeation cascades have been designed for the removal of radioactive krypton and xenon from nuclear reactor atmospheres. These cascades could serve for the decontamination of the atmosphere within a reactor containment dome following a nuclear accident and for other applications of interest to the nuclear industry. The stages of the cascades are assumed to consist of permeator modules using silicone rubber capillaries as separation membranes. All stages are to be operated in a countercurrent mode with shell-side feed.It is shown that it is possible to design an ideal cascade for the separation of multicomponent mixtures by matching the concentrations of a suitable key component in interstage streams that are mixed. This procedure minimizes the cascade volume and power requirement. It is also possible to design a cascade with constant stage cuts in its enriching and stripping sections that approximates the performance of an ideal cascade. The krypton and xenon content of a feed mixture containing about 1 × 10-3 mol% Kr and 1 × 10-2 mol% Xe in air can be lowered by factors of 103 and 108 respectively in a 27-stage permeation cascade. Methods of reducing the number of stages and the effects of irradiation on the membrane performance are also discussed.
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    AIChE Journal 26 (1980), S. 881-890 
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    Notes: The objective of this investigation was to study the separation of krypton and xenon from nuclear reactor atmospheres by selective permeation through silicone rubber capillaries. Effective permeability coefficients for pure krypton xenon, nitrogen, and oxygen were determined between 0 and 40°C and at pressure differences across the capillary walls (Δp) of up to 3.45 × 105 N/m2 (50 psi). The silicone rubber capillaries had an O.D. of 635 μm (0.025 in.) and an I.D. of 305 μm (0.012 in.), and were pressurized externally. The effective permeability coefficients decreased with increasing Δp, due to the elastic deformation of the capillaries, in general agreement with a deformation analysis of thick-walled elastic tubes.Gas separation studies were made with a Kr-Xe-N2-O2 mixture in a permeator containing a bundle of silicone rubber capillaries. The permeator had an effective permeation area of 0.480 m2 (5.165 ft2) at a packing density of 4132 m2m3 permeator volume (1260 ft2/ft3), and was operated in a countercurrent mode. The separation studies were conducted at -10 and 20°C and at three Δp values. The separation achieved in the permeator at Δp's of 1.38 × 105 N/m2 (20 Ib/in.2) and 2.07 × 105 N/m2 (30 Ib/in.2) was in good agreement with that predicted from a theoretical model of a permeation stage with countercurrent flow. At 3.45 × 105 N/m2 (50 Ib/in.2), the separation approached that predicted from a “perfect mixing” model. This behavior probably was due to local collapses of the capillaries at weak spots in their walls, as was evidenced also by a sharp increase in the axial pressure drop inside the capillaries.
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    AIChE Journal 26 (1980), S. 916-928 
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    Keywords: Chemistry ; Chemical Engineering
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    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Due to rising energy costs, there is an increasing need to include the goal of energy conservation as an integral part of process synthesis. This paper discusses the problem of finding the optimum sequence of distillation columns for separating a multicomponent mixture, when heat exchange is permitted between the columns. The major difficulties are associated with the nonserial nature of the problem, the large combinatorial variety and the size of the optimization task. The synthesis strategy presented here overcomes these problems by the use of a bounding technique together with the Lagrangian theory from nonlinear programming. Accurate lower bounds on the optimal costs permit the elimination of nonoptimal sequences with minimal computational effort.
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    Notes: Numerical bifurcation techniques are used to predict multiple steady states for a nonadiabatic, premixed hydrogen flame stabilized on a flat-flame burner. It is found that predicted conditions for burnout and ignition vary remarkably as rival chemical niodels are selected, while conditions for a well-stabilized flame are much less sensitive to chemical and kinetic assumptions. It is concluded that multiplicity theory can help define the chemical behavior of realistic, complex reaction-diffusion systems.
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    Notes: An experimental investigation of an impinging water jet freezing on a melting solid surface has been carried out. Attention was focused on the stagnation region of an axisymmetric jet. In the experiment, a water jet was directed upward against the lower end of a meltable rod, having a diameter about twice that of the jet orifice. Solid octane (m.p. - 56.5°C) and solid mercury (m.p. - 38.9°C) served as the meltable materials. A laminar-axisymmetric flow model was developed to describe melting heat transfer in the presence of jet solidification within the impingement region. Measurements of the melting rate and conditions for the onset of jet solidification were found to agree quite well with the values predicted with this model.
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    AIChE Journal 26 (1980), S. 779-787 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An analytical solution is obtained to the extended Graetz problem with prescribed wall flux, based on a selfadjoint formalism resulting from a decomposition of the convective diffusion equation into a pair of first-order partial differential equations. The solution obtained is simple, computationally efficient and in striking contrast with incomplete numerical efforts in the past.
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    AIChE Journal 26 (1980), S. 802-816 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Structural relationships between the numbers of the various types of steady states exhibited by a mixed culture of microorganisms growing in a chemostat have been obtained. The analysis is based on the degree theory and utilizes Hopf's index theorem. Useful information concerning the culture growth and general conclusions pertaining to the nature of the possible steady states are obtained from these relationships. An alternate method of stability analysis, based on the above results, has also been developed and applications to several cases of growth of indirectly interacting populations which demonstrate the efficiency of the method are presented.
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    AIChE Journal 26 (1980), S. 832-839 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
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    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: For gas absorption accompanied by two consecutive second-order reactions, the reaction factors of the film and penetration theories were solved by the orthogonal collocation method. For equivalent definition of the other physico-chemical parameters, the reaction factors from the two theories differ only slightly. In film theory, it is shown that the film-bulk boundary condition is of importance only for small values of M. It is also shown that the difference between the point yields of the film and penetration theories is generally small, although it is larger than the difference in reaction factors for the two theories.
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    AIChE Journal 26 (1980), S. 858-862 
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    Keywords: Chemistry ; Chemical Engineering
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    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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    AIChE Journal 26 (1980), S. 865-868 
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    Keywords: Chemistry ; Chemical Engineering
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    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Diametrically different influences of small moisture contents upon strength are often measured in beds of different kinds of particles. Here we explain such opposing trends in terms of capillary forces exerted by condensed liquid rings at the points of particle contact. The effects of such rings are opposite for different particle shapes at the point of contact, namely, at spherical or at sharp angular contact points. In addition to the theoretical development, data are given for two different illustrative types of particles.
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    AIChE Journal 26 (1980), S. 876-876 
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    AIChE Journal 26 (1980), S. 876-879 
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    Keywords: Chemistry ; Chemical Engineering
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    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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    AIChE Journal 26 (1980) 
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    AIChE Journal 26 (1980), S. 910-916 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
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    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A number of approaches to the optimal selection of sensor locations are presented, and some of these are applied to determine optimal thermocouple positions in a packed bed tubular reactor. As expected, the optimal locations were found to be those surrounding the hot spot location. The theory also revealed that for good state estimation and for goodlinear quadratic control of the reactor, only one or two well located temperature measurements are necessary rather than the entire temperature profile.
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    AIChE Journal 26 (1980), S. 935-943 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A detailed mathematical model of a single catalyst pellet has been developed to describe its behavior under transient conditions encountered during the warmup period of automobile exhaust catalytic converters. In contrast to the converter models previously reported in the literature, this model is capable of describing the time-dependent behavior of a composite catalyst pellet, and thus provides a convenient means of examining the effects of poison penetration and various noble metal impregnation strategies in the activity-time (rather than activity-temperature) domain.Extensive calculations were carried out to investigate the effects of various catalyst design parameters and converter operating conditions on the lightoff behavior of a spherical, platinum-alumina catalyst pellet. Due to the complex kinetics of the CO and hydrocarbon oxidation reactions, catalyst lightoff was found to exhibit interesting behavior with respect to variations of the system's design parameters and operating conditions. Graphs are presented to illustrate the parameteric sensitivity of these effects.
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    AIChE Journal 26 (1980), S. 954-964 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
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    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: We have obtained values for interaction second viral coefficients of the helium-carbon dioxide system in the range 230 ≤ T/K ≤ 300. Our experimental technique is essentially the Burnett mixing method described by Hall and Eubank (1973, 1974). We have modified the analysis to account for higher-order effects and to detect significant systematic errors. We also report virial coefficients for the pure components: helium in the range 100 ≤ T/K ≤ 300 and carbon dioxide at 300 K.
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    Notes: The design of the steady-state optimizing control for a single unit is formulated within the framework of the nonlinear mathematical programming theory. Alternative implementational strategies are developed and a multilevel screening procedure is proposed to arrive at the best optimizing control configuration. Numerical examples on a fluid catalytic cracking unit and a distillation column demonstrate the systematic design and the synthesis of the most promising optimizing control structures for these systems.
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    AIChE Journal 26 (1980), S. 1013-1019 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
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    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A time lag method is described for use with a membrane-covered, rotated disc electrode that allows determination of the partitioning and diffusivity of small molecules in hydrophilic gel membranes and membrane permeability from a single measurement. This new technique takes into account the concentration boundary layer in the solution adjacent to the membrane and reaction at the electrode surface of solutes that are diffusion- or kinetic-limited. Examples are given of the use of this method for characterizing mass transfer in a commercial cellulosic membrane with oxygen, hydroquinone, ferrocyanide, and glucose as solutes.
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    AIChE Journal 26 (1980) 
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    AIChE Journal 26 (1980), S. 16-23 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A mathematical model is developed to describe non-isothermal sorption kinetics and used to interpret experimental uptake curves for CO2 in 4A zeolite and for CO2 and in C5H12 in 5A zeolite. The model assumes that the dominant mass transfer resistance is intracrystalline diffusion while the major resistance to heat transfer is the external heat transfer between the adsorbent sample and the surroundings. It gives a good representation of the kinetic behavior over a wide range of conditions. Both the extreme cases of isothermal diffusion and complete heat transfer control are demonstrated experimentally. Intermediate situations, in which the uptake rate is controlled by the combined effects of diffusion and heat transfer, are demonstrated as well. The parameters derived from the model are consistent, reproducible, and agree well with a priori estimates. The model provides a useful theoretical basis for the analysis of rapid sorption processes for which the non-isothermal approximation is invalid.
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    AIChE Journal 26 (1980), S. 68-76 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
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    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A new Isotherm equation for pure gas adsorption is developed and tseted. In the new method, the adsorption equilibrium is treated as an osmotic equilibrium between two “vacancy” slutions having different compsoitions. One solutions represents the gas phase and the other the adsorbed phase. The vacancy solution is composed fo adsorbates and vacancies. the latter is an imaginary entity defined as the vacuum space which acts as the solvent for the system. Thermodynamic equations governignt he euilibrium of this system are used to derive the equation of state for the adsorbed phase. The non-ideality of the adsorbed solution is accounted for in terms of an activity coefficent whose compsotion dependence is decribed by the Wilson equation. The equation of state, together the Gibbs adsorption equation, is then used in the derivaion of the adsorption isotherm equation. The developed correlation has been evalued with the adsorption isotherm data of O2, N2, and CO on zeolite 10X at 144.3 K, 172.0 K, 227.6 K and 273.2 K, and that of CH4, C2H2, C2H4, C2H6, C3H8, nC4H10, and CO2 on Nuxit-AL activated carbon at 293.2 K, 313.2K, 333.2 K and 363.2 K. For both adsorbents, the correlations are better than those obtained by any other adsorption model which has been extended to gas mixtures. The parametes obtained from the pure component data can be use to predict a priori, gas-mixture equilibria.
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    AIChE Journal 26 (1980), S. 89-98 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
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    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The governing equations describing the flow of an unequal phase velocity, equal phase temperature (UVET) seriated two-phase continuum as derived by Solbrig and Hughes (1978) are solved in this article, in one space dimension. A simple implicit iterative solution procedure is developed to numerically evaluate the five non-linear coupled field equations. Analytical solutions are developed, against which the computer code results are compared. The prototype UVET code results are compared to the equivalent equal phase velocity, equal phase temperature (EVET) code results for the same problem. Major phenomena such as phase flow reversal, counter-current flow and flooding-like behavior are predicted.
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    AIChE Journal 26 (1980), S. 112-120 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The facilitated transport of carbon monoxide through thin, immobilized films of cuprous chloride solutions is investigated, using a tracer C14O technique. Steady-state tracer flux measurements are used to determine the second-order forward rate constant and equilibrium constant for the reversible reaction of CO with cuprous ion. The enchanced results at low CO partial pressures can be interpreted in terms of a consecutive reaction model. The cuprous ion is remarkably effective as a carrier for CO. The CO permeation rate in the presence of cuprous ion can be increased by two orders of magnitude over the nonfacilitated flux. As such, the cuprous ion is an attractive facilitating agent for use in a membrane separation system.
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    Notes: The theory of equilibrium staged parametric pumps with discrete fluid transfers has been presented in previous papers for total reflux. Here, it is extended to open, fractionating systems, operating in cyclic steady state. The cases of and enriching section, a stripping section, and a complete fractionating apparatus are successively considered. Providing adequate variables are defined, the result is a diagram which plays the same role as the McCabe-Thiele diagram in distillation. The optimal feed stage location, the minimum reflux, and the separation factor for given operating conditions are determined analytically and graphically in the case of linear equilibrium isotherms. The method is then generalized to non-linear equilibria, particularly of constant relative volatility type.
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    AIChE Journal 26 (1980), S. 174-174 
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    AIChE Journal 26 (1980), S. 295-297 
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    AIChE Journal 26 (1980), S. 301-303 
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    AIChE Journal 26 (1980), S. 331-331 
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    AIChE Journal 26 (1980), S. 331-331 
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    AIChE Journal 26 (1980), S. 332-332 
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    AIChE Journal 26 (1980), S. 337-341 
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    Keywords: Chemistry ; Chemical Engineering
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    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Presented here is a Corresponding States Method for predicting saturated liquid densities of both pure components and mixtures. The method is based on the known properties of two reference fluids and requires the critical properties and the acentric factor of the pure component(s) as input parameters. The method is tested for predicting the orthobaric densities of LNG mixtures using methane and n-butane as the reference fluids. Very accurate prediction (well within the accuracy of the experimental data) are obtained for such mixtures using, at most, only one adjustable coefficient to characterize each binary system. The method is extremely simple to use and is suitable for design applications.
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    AIChE Journal 26 (1980), S. 363-371 
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    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An analysis is made of centrifugal flow of compacted porous beds through channels against high gas backpressure. One-dimensional compressible gas flow solutions are presented for concurrent and countercurrent solids/gas motion through the variable area channels. The physical process analyzed represents the flow through a newly developed centrifugal pump for feeding dry pulverized material against a pressure barrier. The objective of the analysis is to gain a basic theoretical understanding of this type of device. Good agreement is found between analytical predictions and test data obtained with an experimental pump feeding coal.
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    AIChE Journal 26 (1980), S. 386-390 
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    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A corresponding states approach has been used successfully to correlate reduced self-diffusivity of pure liquids with reduced temperature and acentric factor. In addition, dimensional analysis techniques have been used to accurately relate viscosity, normal boiling point and temperature with self-diffusivity, as well as to relate the three transport properties.
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    AIChE Journal 26 (1980), S. 403-411 
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    Keywords: Chemistry ; Chemical Engineering
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    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A distributed parameter model has been developed to describe flow and dissolution of different minerals in porous media. Asymptotic solutions are obtained to give the separation of the different mineral reaction fronts and the time for the reaction front to move through the porous core. The experimental observations agree well with theoretical predictions.
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    AIChE Journal 26 (1980), S. 430-443 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A model is formulated in order to study the transient behavior of oil ganglion populations during immiscible displacement in oil recovery processes. The model is composed of three components: a suitable model for granular porous media; a stochastic simulation method capable of predicting the expected fate (mobilization, breakup, stranding) of solitary oil ganglia moving through granular porous media; and two coupled ganglion population balance equations, one applying to moving ganglia and the other to stranded ones. The porous medium model consists of a regular network of randomly sized unit cells of the constricted tube type. Based on this model and a mobilization-breakup criterion, computer aided simulations provide probabilistic information concerning the fate of solitary oil ganglia. Such information is required in the ganglion population balance equations, the solution of which delineates the conditions under which oil bank formation suceeds or fails. Successful oil bank formation depends on the outcome of the competition between the process of oil ganglion deterioration through breakup and stranding on one hand and the process of oil ganglion collision and coalescence on the other. The parameters entering the system of population balances are initial ganglion number concentration, average ganglion velocity, ganglion dispersion coefficients, ganglion stranding coefficient, ganglion breakup coefficient and probability of coalescence given a collision. These parameters are, in turn, functions of the porous medium geometry, capillary number, ganglion size distribution, flood velocity, oil saturation and flood composition.
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    AIChE Journal 26 (1980), S. 462-470 
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    Keywords: Chemistry ; Chemical Engineering
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    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Experimental results are reported for the solubility of methanol in compressed nitrogen, methane, ethane and carbon dioxide in the region -45° to +10°C and 17 to 62 bars.New and previously published experimental data are used to obtain (or estimate) second virial coefficients for all binary pairs in mixtures containing hydrogen, nitrogen, carbon monoxide, methane, ethane, propane, carbon dioxide, hydrogen sulfide and methanol. These coefficients, combined with experimental data for the vapor pressure of methanol and with Henry's constants, partial molar volumes and Margules coefficients for dissolved gases in methanol, yield a correlation for calculating solvent losses as a function of temperature, pressure and gas composition. For a large-scale natural-gas absorption process, these losses may represent a significant economic factor in plant design.
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    AIChE Journal 26 (1980), S. 505-507 
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    AIChE Journal 26 (1980), S. 162-165 
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    AIChE Journal 26 (1980), S. 173-174 
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