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  • Elsevier  (304,574)
  • American Geophysical Union  (8,038)
  • American Physical Society (APS)
  • 2015-2019  (312,612)
  • 2019  (312,612)
  • 1
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Physics Letters B 294 (1992), S. 466-478 
    ISSN: 0370-2693
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Physics
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Physics Letters B 317 (1993), S. 474-484 
    ISSN: 0370-2693
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Physics
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  • 3
    Publication Date: 2020-11-23
    Description: Ground deformations are among the main volcanic phenomena occurring within the caldera system and pres- ently recorded at different volcanoes worldwide including the Campi Flegrei active caldera (southern Italy). A new stratigraphic, sedimentological and paleontological survey carried out in the central sector of the Campi Flegrei caldera both along the already known La Starza succession and through a new excavated tunnel provided new insights into the ground movement episodes occurred in the last 15 kyr. This study, which has also benefited of unpublished boreholes stratigraphic data, shows that the most uplifted sector of the Campi Flegrei caldera, presently marked by the morphological structure of the La Starza cliff close to the Pozzuoli coastline, was charac- terized by a complex sedimentary evolution. It results from different phases of alternating marine transgressions and regressions, the latter marked by both continental volcanic and/or palustrine/lacustrine sediments. These al- ternations result from the interplay between (i) subsidence and uplift episodes of the caldera floor and (ii) sea level variations during the Holocene. A rest period of volcanism accompanied by a sea level rise determined a sig- nificant submersion phase in about 3000 years between 8.59 and 5.5 ka. This phase was defined by a sea level with a maximum water depth value of 60–80 m and a late stage recording significant episodes of ground move- ments. Subsequently, between 5.5 and 3.5 ka, a ground uplift of about 100 m occurred, with short subsidence around 4.5 ka following the Plinian Agnano-Monte Spina eruption. The net vertical displacement represents the recorded deformation linked with a volcanism period in which ~2.5 km3 of magma were erupted by different vents within the caldera. It is worth to note as the general trend of ground movement through the time indicates a similarity in the pattern, beyond its scale.
    Description: Published
    Description: 143-158
    Description: 1V. Storia eruttiva
    Description: JCR Journal
    Keywords: Ground deformation ; Campi Flegrei ; Paleoenvironment ; Coastal marine sediments ; Volcanism ; Unrest
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 4
    Publication Date: 2021-06-15
    Description: Extreme and inaccessible environments are a new frontier that unmanned and remotely operated ve-hicles can today safely access and monitor. The Lusi mud eruption (NE Java Island, Indonesia) representsone of these harsh environments that are totally unreachable with traditional techniques. Here boilingmud is constantly spewed tens of meters in height and tall gas clouds surround the 100 m wide activecrater. The crater is surrounded by a ~600 m diameter circular zone of hot mud that prevents anyapproach to investigate and sample the eruption site. In order to access this active crater we designedand assembled a multipurpose drone.The Lusi drone is equipped with numerous airborne devices suitable for use on board of other mul-ticopters. During the missions, three cameras can complete 1) video survey, 2) high resolution photo-grammetry of desired and preselected polygons, and 3) thermal photogrammetry surveys with infra-redcamera to locate hotfluids seepage areas or faulted zones. Crater sampling and monitoring operationscan be pre-planned with aflight software, and the pilot is required only for take-off and landing. A winchallows the deployment of gas, mud and water samplers and contact thermometers to be operated withno risk for the aircraft. During the winch operations (that can be performed automatically), the aircrafthovers at a safety height until the tasks controlled by the winch-embedded processor are completed. Thedrone is also equipped with GPS-connected CO2and CH4sensors. Gridded surveys using these devicesallowed obtaining 2D maps of the concentration and distribution of various gasses over the area coveredby theflight path.The device is solid, stable even with significant wind, affordable, and easy to transport. The Lusi dronesuccessfully operated during several expeditions at the ongoing active Lusi eruption site and proved to bean excellent tool to study other harsh or unreachable sites, where operations with more conventionalmethods are too expensive, dangerous or simply impossible
    Description: LUSI LAB project, PI A. Mazzini; esearch Council of Norway through itsCenters of Excellence funding scheme, Project Number 223272; BPLS (Badan Penanggulangan Lumpur Sidoarjo, Sidoarjo Mudflow Management Agency)
    Description: Published
    Description: 26-37
    Description: 2IT. Laboratori sperimentali e analitici
    Description: JCR Journal
    Keywords: Lusi mud eruption ; Drone-UAV ; Multirotor ; Remote sampling ; Remote sensing ; Indonesia ; 05.04. Instrumentation and techniques of general interest
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 5
    Publication Date: 2021-06-15
    Description: An Mw 6.1, devastating earthquake, on April 6, 2009, struck the Middle Aterno Valley (Abruzzi Apennines, Italy) due to the activation of a poorly known normal fault system. Structural analysis of the fault population and investigation of the relationships with the Quaternary continental deposits through integrated field and laboratory techniques were conducted in order to reconstruct the long-term, tectono-sedimentary evolution of the basin and hypothesize the size of the fault segment. A polyphasic evolution of the Middle Aterno Valley is characterized by a conjugate, ∼E-W and ∼NS-striking fault system, during the early stage of basin development, and by a dip-slip, NW-striking fault system in a later phase. The old conjugate fault system controlled the generation of the largest sedimentary traps in the area and is responsible for the horst and graben structures within the basin. During the Early Pleistocene the E-W and NS system reactivated with dip-slip kinematics. This gave rise to intra-basin bedrock highs and a significant syn-tectonic deposition, causing variable thickness and hiatuses of the continental infill. Subsequently, since the end of the Early Pleistocene, with the inception of the NW-striking fault system, several NW-strands linked into longer splays and their activity migrated toward a leading segment affecting the Paganica-San Demetrio basin: the Paganica-San Demetrio fault alignment. The findings from this work constrain and are consistent with the subsurface basin geometry inferred from previous geophysical investigations. Notably, two major elements of the ∼E-W and ∼NS-striking faults likely act as transfer to the nearby stepping active fault systems or form the boundaries, as geometric complexities, that limit the Paganica-San Demetrio fault segment overall length to 19 ± 3 km. The resulting size of the leading fault segment is coherent with the extent of the 6 April 2009 L'Aquila earthquake causative fault. The positive match between the geologic long-term and coseismic images of the 2009 seismogenic fault highlights that the comprehensive reconstruction of the deformation history offers a unique contribution to the understanding faults seismic potential.
    Description: MIUR (Italian Ministry of Education, University and Research) project “FIRB Abruzzo - High-resolution analyses for assessing the seismic hazard and risk of the areas affected by the 6 April 2009 earthquake”, ref. RBAP10ZC8K_005 and RBAP10ZC8K_007, and by Agreement INGV-DPC 2012–2021
    Description: Published
    Description: 30-66
    Description: 2T. Deformazione crostale attiva
    Description: JCR Journal
    Keywords: Quaternary geology ; L'Aquila earthquake ; structural geology ; Middle Aterno Valley ; neotectonics ; active fault ; 04.04. Geology ; 04.07. Tectonophysics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 6
    Publication Date: 2021-06-30
    Description: Soil CO2 flux and 222Rn activity measurements may positively contribute to the geochemicalmonitoring of active volcanoes. The influence of several environmental parameters on the gas signals has been substantially demonstrated. Therefore, the implementation of tools capable of removing (or minimising) the contribution of the atmospheric effects from the acquired time series is a challenge in volcano surveillance. Here, we present 4 years-long continuousmonitoring (fromApril 2007 to September 2011) of radon activity and soil CO2 flux collected on the NE flank of Stromboli volcano. Both gases record higher emissions during fall–winter (up to 2700 Bq * m−3 for radon and 750 g m−2 day−1 for CO2) than during spring–summer seasons. Short-time variations on 222Rn activity aremodulated by changes in soil humidity (rainfall), and changes in soil CO2 flux that may be ascribed to variations in wind speed and direction. The spectral analyses reveal diurnal and semi-diurnal cycles on both gases, outlining that atmospheric variations are capable to modify the gas release rate fromthe soil. The long-termsoil CO2 flux shows a slow decreasing trend, not visible in 222Rn activity, suggesting a possible difference in the source depth of the of the gases, CO2 being deeper and likely related to degassing at depth of the magma batch involved in the February–April 2007 effusive eruption. To minimise the effect of the environmental parameters on the 222Rn concentrations and soil CO2 fluxes, two different statistical treatments were applied: the Multiple Linear Regression (MLR) and the Principal Component Regression (PCR). These approaches allow to quantify theweight of each environmental factor on the two gas species and showa strong influence of some parameters on the gas transfer processes through soils. The residual values of radon and CO2 flux, i.e. the values obtained after correction for the environmental influence, were then compared with the eruptive episodes that occurred at Stromboli during the analysed time span (2007–2011) but no clear correlations emerge between soil gas release and volcanic activity. This is probably due to i) the distal location of the monitoring stations with respect to the active craters and to ii) the fact that during the investigated period no major eruptive phenomena (paroxysmal explosion, flank eruption) occurred. Comparison of MLR and PCR methods in time-series analysis indicates thatMLR can bemore easily applied to real time data processing in monitoring of open conduit active volcanoes (like Stromboli) where the transition to an eruptive phase may occur in relatively short times.
    Description: This researchwas partly funded by ItalianMinistry of University and Research (MIUR) and by University of Torino-Fondazione Compagnia di San Paolo. Additional fundswere provided by the Italian “Presidenza del Consiglio dei Ministri–Dipartimento della Protezione Civile (DPC)” through the DEVnet Project (a cooperative program between the Departments of Earth Sciences of the University of Torino and the University of Florence) and through the “Potenziamento Monitoraggio Stromboli” project. Additional funds for improving our computing hardware were provided by Fondazione Cassa di Risparmio di Torino.
    Description: Published
    Description: 65-78
    Description: 4V. Processi pre-eruttivi
    Description: JCR Journal
    Keywords: Stromboli volcano ; Continuous geochemical monitoring ; Soil CO2 flux ; Radon activity ; Environmental parameters ; Time series analyses ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 7
    Publication Date: 2019-03-20
    Repository Name: EPIC Alfred Wegener Institut
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  • 8
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    Elsevier
    In:  EPIC3Molecular Phylogenetics and Evolution, Elsevier, 130, pp. 330-345, ISSN: 10557903
    Publication Date: 2021-06-19
    Description: Among the most derived calanoid copepod superfamily Clausocalanoidea about half of the genera belong to the so-called “Bradfordian” families that are defined by the presence of sensory setae at the maxilla and maxilliped. Many of these “Bradfordian” taxa are insufficiently well described, because their taxonomy is complicated and phylogenetic relationships are not completely resolved. We therefore aimed to unravel their phylogenetic relationships using molecular multi-gene analyses. We conducted molecular multi-gene analysis on 26 species from 15 genera representing all seven “Bradfordian” families using five gene fragments, the nuclear ribosomal 18S, 28S and internal transcribed spacer 2 DNA, and mitochondrial cytochrome c oxidase subunit I and cytochrome b. The monophyly of “Bradfordians” as one lineage in the superfamily Clausocalanoidea was supported by Maximum Likelihood and Bayesian Inference multi-gene analyses. Except for the support of species belonging to the same genus and specimens belonging to the same species, no phylogenetic relationships among genera and families were supported. The impossibility of resolving phylogenetic relationships among “Bradfordian” genera and families may be due to the young age or fast radiation of “Bradfordians” within the mostly derived calanoid superfamily Clausocalanoidea. Therefore, mutation rates might be not sufficient to track phylogenetic relationships. Evidence on phylogenetic relationships between genera and families remain unresolved after implementing integrated morphological and molecular taxonomic approaches.
    Repository Name: EPIC Alfred Wegener Institut
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  • 9
    Publication Date: 2018-11-28
    Description: Life cycle and reproduction of Calanus hyperboreus were studied during a year of record low ice cover in the southeastern Beaufort Sea. Stages CIV, adult females and CV dominated the overwintering population, suggesting a 2- to 3-year life cycle. Within two spring-summer months in the upper water column females filled their energy reserves before initiating their downward seasonal migration. From February to March, vigorous reproduction (20–65 eggs f−1 d−1) delivered numerous eggs (29 000 eggs m−2) at depth and nauplii N1-N3 (17 000 ind. m−2) in the water column. However, CI copepodite recruitment in May, coincident with the phytoplankton bloom, was modest in Amundsen Gulf compared to sites outside the gulf. Consequently, C. hyperboreus abundance and biomass stagnated throughout summer in Amundsen Gulf. As a mismatch between the first-feeding stages and food was unlikely under the favourable feeding conditions of April-May 2008, predation on the egg and larval stages in late winter presumably limited subsequent recruitment and population growth. Particularly abundant in Amundsen Gulf, the copepods Metridia longa and C. glacialis were likely important consumers of C. hyperboreus eggs and nauplii. With the ongoing climate-driven lengthening of the ice-free season, intensification of top-down control of C. hyperboreus recruitment by thriving populations of mesopelagic omnivores and carnivores like M. longa may counteract the potential benefits of increased primary production over the Arctic shelves margins for this key prey of pelagic fish, seabirds and the bowhead whale.
    Repository Name: EPIC Alfred Wegener Institut
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  • 10
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    Elsevier
    In:  EPIC3Computers and Geosciences, Elsevier, (123), pp. 65-72, ISSN: 0098-3004
    Publication Date: 2020-10-20
    Description: Time series derived from paleoclimate archives are often irregularly sampled in time and thus not analysable using standard statistical methods such as correlation analyses. Although measures for the similarity between time series have been proposed for irregular time series, they do not account for the time scale dependency of the relationship. Stochastically distributed temporal sampling irregularities act qualitatively as a low-pass filter reducing the influence of fast variations from frequencies higher than about 0.5 (Δtmax) − 1, where Δtmax is the maximum time interval between observations. This may lead to overestimated correlations if the true correlation increases with time scale. Typically, correlations are underestimated due to a non-simultaneous sampling of time series. Here, we investigated different techniques to estimate time scale dependent correlations of weakly irregularly sampled time series, with a particular focus on different resampling methods and filters of varying complexity. The methods were tested on ensembles of synthetic time series that mimic the characteristics of Holocene marine sediment temperature proxy records. We found that a linear interpolation of the irregular time series onto a regular grid, followed by a simple Gaussian filter was the best approach to deal with the irregularity and account for the time scale dependence. This approach had both, minimal filter artefacts, particularly on short time scales, and a minimal loss of information due to filter length.
    Repository Name: EPIC Alfred Wegener Institut
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  • 11
    Publication Date: 2019-01-29
    Description: Rapid declines in Arctic sea ice have captured attention and pose significant challenges to a variety of stakeholders. There is a rising demand for Arctic sea ice prediction at daily to seasonal time scales, which is partly a sea ice initial condition problem. Thus, a multivariate data assimilation that integrates sea ice observations to generate realistic and skillful model initialization is needed to improve predictive skill of Arctic sea ice. Sea ice data assimilation is a relatively new research area. In this review paper, we focus on two challenges for implementing multivariate data assimilation systems for sea ice forecast. First, to address the challenge of limited spatiotemporal coverage and large uncertainties of observations, we discuss sea ice parameters derived from satellite remote sensing that (1) have been utilized for improved model initialization, including concentration, thickness and drift, and (2) are currently under development with the potential for enhancing the predictability of Arctic sea ice, including melt ponds and sea ice leads. Second, to strive to generate the “best” estimate of sea ice initial conditions by combining model simulations/forecasts and observations, we review capabilities and limitations of different data assimilation techniques that have been developed and used to assimilate observed sea ice parameters in dynamical models.
    Repository Name: EPIC Alfred Wegener Institut
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  • 12
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    Elsevier
    In:  EPIC3Earth and Planetary Science Letters, Elsevier, 514, pp. 130-142, ISSN: 0012821X
    Publication Date: 2019-03-26
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  • 13
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    Elsevier
    In:  EPIC3Earth-Science Reviews, Elsevier, 197, pp. 102893, ISSN: 00128252
    Publication Date: 2019-08-15
    Repository Name: EPIC Alfred Wegener Institut
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  • 14
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    Elsevier
    In:  EPIC3Advances in Marine Biology Vol. 82, Advances in Marine Biology, Elsevier, 42 p., pp. 51-92, ISBN: 978-0-08-102914-5
    Publication Date: 2020-02-01
    Description: Hyperiid amphipods are predatory pelagic crustaceans that are particularly prevalent in high-latitude oceans. Many species are likely to have co-evolved with soft-bodied zooplankton groups such as salps and medusae, using them as substrate, for food, shelter or reproduction. Compared to other pelagic groups, such as fish, euphausiids and soft-bodied zooplankton, hyperiid amphipods are poorly studied especially in terms of their distribution and ecology. Hyperiids of the genus Themisto, comprising seven distinct species, are key players in temperate and cold-water pelagic ecosystems where they reach enormous levels of biomass. In these areas, they are important components of marine food webs, and they are major prey for many commercially important fish and squid stocks. In northern parts of the Southern Ocean, Themisto are so prevalent that they are considered to take on the role that Antarctic krill play further south. Nevertheless, although they are around the same size as krill, and may also occur in swarms, their feeding behaviour and mode of reproduction are completely different, hence their respective impacts on ecosystem structure differ. Themisto are major predators of meso- and macrozooplankton in several major oceanic regions covering shelves to open ocean from the polar regions to the subtropics. Based on a combination of published and unpublished occurrence data, we plot out the distributions of the seven species of Themisto. Further, we consider the different predators that rely on Themisto for a large fraction of their diet, demonstrating their major importance for higher trophic levels such as fish, seabirds and mammals. For instance, T. gaudichaudii in the Southern Ocean comprises a major part of the diets of around 80 different species of squid, fish, seabirds and marine mammals, while T. libellula in the Bering Sea and Greenland waters is a main prey item for commercially exploited fish species. We also consider the ongoing and predicted range expansions of Themisto species in light of environmental changes. In northern high latitudes, sub-Arctic Themisto species are replacing truly Arctic, ice-bound, species. In the Southern Ocean, a range expansion of T. gaudichaudii is expected as water masses warm, impacting higher trophic levels and biogeochemical cycles. We identify the many knowlegde gaps that must be filled in order to evaluate, monitor and predict the ecological shifts that will result from the changing patterns of distribution and abundance of this important pelagic group.
    Repository Name: EPIC Alfred Wegener Institut
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  • 15
    Publication Date: 2019-09-17
    Description: Ostracods are small-sized crustaceans, which inhabit all aquatic ecosystems and, because they have a comprehensive fossil record, are important environmental and paleoenvironmental indicators. However several aspects of the ecology of modern species (the basis for the paleontological investigations) are still controversial. Previous authors have raised the hypothesis that benthic ostracods, because of their calcified carapaces, are unable to survive below the Carbonate Compensation Depth (CCD). Herein we test this hypothesis based on (1) ostracods newly collected from the Kuril-Kamchatka Trench at depths far below the CCD during the KuramBio II expedition; and (2) a compilation of all previously published records of (geologically) Recent deep-sea Ostracoda in regions deeper than 3500 m. The KuramBio II expedition provided hundreds of living, hadal ostracods from at least 30 species and 21 genera from thousands of meters deeper than the CCD in the Kuril-Kamchatka Trench region. Additionally, the KuramBio II expedition provided the deepest record (9307 m) of a living ostracod with calcified carapaces: specimens of the genus Krithe. Finally, the compilation of all published information on living ostracods show that a highly diverse assemblage both at high and low taxonomic levels (2 subclasses, 4 suborders, 25 families, 89 genera and at least 206 species) occur below 3500 m. Therefore, we conclude that contrary to previous beliefs, the new data from the Kuril-Kamchatka Trench and the compilation of the literature show that ostracods do live and are even sometimes abundant below the CCD.
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  • 16
    Publication Date: 2019-10-01
    Repository Name: EPIC Alfred Wegener Institut
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  • 17
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    American Geophysical Union
    In:  EPIC3Earth's Future, American Geophysical Union, 7(12), pp. 1296-1306, ISSN: 2328-4277
    Publication Date: 2021-02-15
    Description: To counteract global warming, a geoengineering approach that aims at intervening in the Arctic ice‐albedo feedback has been proposed. A large number of wind‐driven pumps shall spread seawater on the surface in winter to enhance ice growth, allowing more ice to survive the summer melt. We test this idea with a coupled climate model by modifying the surface exchange processes such that the physical effect of the pumps is simulated. Based on experiments with RCP 8.5 scenario forcing, we find that it is possible to keep the late‐summer sea ice cover at the current extent for the next ∼60 years. The increased ice extent is accompanied by significant Arctic late‐summer cooling by ∼1.3 K on average north of the polar circle (2021–2060). However, this cooling is not conveyed to lower latitudes. Moreover, the Arctic experiences substantial winter warming in regions with active pumps. The global annual‐mean near‐surface air temperature is reduced by only 0.02 K (2021–2060). Our results cast doubt on the potential of sea ice targeted geoengineering to mitigate climate change.
    Repository Name: EPIC Alfred Wegener Institut
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  • 18
    Publication Date: 2019-12-19
    Description: Enrichment of the oceans with CO2 may be beneficial for some marine phytoplankton, including harmful algae. Numerous laboratory experiments provided valuable insights into the effects of elevated pCO2 on the growth and physiology of harmful algal species, including the production of phycotoxins. Experiments close to natural conditions are the next step to improve predictions, as they consider the complex interplay between biotic and abiotic factors that can confound the direct effects of ocean acidification. We therefore investigated the effect of ocean acidification on the occurrence and abundance of phycotoxins in bulk plankton samples during a long-term mesocosm experiment in the Gullmar Fjord, Sweden, an area frequently experiencing harmful algal blooms. During the experimental period, a total of seven phycotoxin-producing harmful algal genera were identified in the fjord, and in accordance, six toxin classes were detected. However, within the mesocosms, only domoic acid and the corresponding producer Pseudo-nitzschia spp. was observed. Despite high variation within treatments, significantly higher particulate domoic acid contents were measured in the mesocosms with elevated pCO2. Higher particulate domoic acid contents were additionally associated with macronutrient limitation. The risks associated with potentially higher phycotoxin levels in the future ocean warrants attention and should be considered in prospective monitoring strategies for coastal marine waters.
    Repository Name: EPIC Alfred Wegener Institut
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  • 19
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    American Geophysical Union
    In:  EPIC3AGU Fall meeting, San Francisco, CA, 2019-12-09-2019-12-13USA, American Geophysical Union
    Publication Date: 2019-12-17
    Description: During the last decade the Arctic has experienced increasing human development while many native communities continue to live a subsistence lifestyle. Off-road winter tundra travel for resource exploration is most cost effective and least environmentally damaging during winter when the tundra is frozen and snow covered. Climate warming, which is occurring at an amplified rate in the Arctic, likely changes the period when access to the off-road tundra travel is possible. There currently exists, however, large uncertainty as to how climate change will impact the low-cost winter travel access across the tundra. Here we defined safe tundra access when soil temperatures are below a soil type dependent freezing temperature and snow cover is at least 20 cm. Our analysis is based on the simulated soil temperatures and snow depths of Land Surface Models (LSMs) contributing to “The Inter-Sectoral Impact Model Intercomparison Project” (ISIMIP). ISIMIP simulations are based on a common protocol, the same input data, the same spatial (0.5°) and temporal resolution (daily modeling output), and span over the period 1861-2100. The LSMs are forced by four different bias-corrected global circulation models (IPSL-CM5A-LR, GFDL-ESM2M, MIROC5, HadGEM2-ES) and three different future conditions (represented via representative concentration pathways (RCP) 2.6, 6.0, 8.5). The simulation results of our model ensemble (60 model combinations) show consistent permafrost warming and changing snow cover patterns at 60°N. Annual off-road tundra travel is considerably reduced (〉50%) under future climate change scenarios, especially under the RCP8.5. The main reduction can be observed in the spring and autumn (〉30%). The results of the multi-model ensemble differ in magnitude, however, their overall trend is consistent. Our results suggest a high vulnerability and substantial changes to the (subsistence) livelihoods of native communities and increasing costs for off-road resource exploration.
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  • 20
    Publication Date: 2021-01-26
    Description: Essential Biodiversity Variables (EBV) are fundamental variables that can be used for assessing biodiversity change over time, for determining adherence to biodiversity policy, for monitoring progress towards sustainable development goals, and for tracking biodiversity responses to disturbances and management interventions. Data from observations or models that provide measured or estimated EBV values, which we refer to as EBV data products, can help to capture the above processes and trends and can serve as a coherent framework for documenting trends in biodiversity. Using primary biodiversity records and other raw data as sources to produce EBV data products depends on cooperation and interoperability among multiple stakeholders, including those collecting and mobilising data for EBVs and those producing, publishing and preserving EBV data products. Here, we encapsulate ten principles for the current best practice in EBV-focused biodiversity informatics as ‘The Bari Manifesto’, serving as implementation guidelines for data and research infrastructure providers to support the emerging EBV operational framework based on trans-national and cross-infrastructure scientific workflows. The principles provide guidance on how to contribute towards the production of EBV data products that are globally oriented, while remaining appropriate to the producer's own mission, vision and goals. These ten principles cover: data management planning; data structure; metadata; services; data quality; workflows; provenance; ontologies/vocabularies; data preservation; and accessibility. For each principle, desired outcomes and goals have been formulated. Some specific actions related to fulfilling the Bari Manifesto principles are highlighted in the context of each of four groups of organizations contributing to enabling data interoperability - data standards bodies, research data infrastructures, the pertinent research communities, and funders. The Bari Manifesto provides a roadmap enabling support for routine generation of EBV data products, and increases the likelihood of success for a global EBV framework.
    Repository Name: EPIC Alfred Wegener Institut
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  • 21
    Publication Date: 2020-02-12
    Description: Climate change and sustainable use of natural capital demand increased collaboration across the sciences. The first steps for effective collaboration often focus on improving interoperability between observation and analyses methodologies. This is traditionally done through a combination of standards and best practices. The ocean observation community and observing infrastructures - with regionally diverse members working in physics, chemistry, biology and engineering - is looking toward a dynamic consensus-building approach to match the rapid pace of technological evolution. This is an essential part of the long-term cooperation among ocean observing infrastructures. In the last 12 months, the ocean observing community has implemented an Ocean Best Practices System (OBPS). This System was recently adopted by the Intergovernmental Ocean Commission as an international project under GOOS and IODE. The System consists of a permanent OBPS repository hosted by IODE with state-of-the-art semantic discovery and metadata indexing for improved access to best practices and, eventually, to the data associated with them. There have been discussions to understand how to deal with differing best practices and standards on the same observation or analyses objective and other issues that arise from a comprehensive ocean best practices system. A recent survey, to be described, offers options on alternative approaches. Further, we have created a forum, in “Frontiers in Marine Science” for discussion of best practices and their applications. This presentation will cover options for evolving and sustaining ocean best practices across infrastructures. The recommendations build upon the community survey, the OGC experience, the outcomes of the OceanObs’19 conference as well as inputs from the Decade for Ocean Sciences community meetings. The extension of this work to other communities will also be examined.
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  • 22
    Publication Date: 2020-05-14
    Description: IODP Exp. 383 recovered two Pleistocene sedimentary sequences from the upper continental slope along the southernmost Chilean margin that are well positioned to monitor changes in the Antarctic Circumpolar Current (ACC) upstream of the Drake Passage and the history of Patagonian glaciation. These sites are characterized by high sedimentation rates and a complex distribution of siliciclastic sediments with infrequent decimeter-scale beds of calcareous biogenic sediments. Unravelling ocean circulation and climate history from these sites requires a primary understanding of sedimentary provenance and transport mechanisms derived from a complete lithological characterization of the sequence. Here, we integrate downcore shipboard physical properties with sedimentological observations to fully characterize the sequences, evaluate potential for correlation and constrain regional depositional processes. Site U1542 (52°S; 1101 m water depth) consists of a 249 m spliced sedimentary sequence containing Middle Pleistocene to Holocene sediments. It mainly consists of clayey silt that is often interbedded with thin (~75 cm) beds of calcareous sand-bearing clayey to sandy silt with foraminifera and nannofossils or foraminifera-rich nannofossil ooze. Site U1544 (55°S; 2090 m water depth) consists of a 98 m sedimentary sequence obtained from a single hole. Sediments are also dominated by silty clay, but exhibit slightly thicker beds of calcareous ooze and a significantly higher proportion of cm- to dm-scale sand beds that are interpreted as turbidites. Based on the lithology of the recovered sediments and proximity to a glaciated continental margin, terrigenous sediment is likely delivered to these locations by a combination of ice rafting, glacial meltwater plumes, episodic downslope transport from the outer continental shelf and fine-grained sediments transported by the Cape Horn Current entering the Drake Passage as the northern branch of the ACC.
    Repository Name: EPIC Alfred Wegener Institut
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  • 23
    Publication Date: 2019-11-01
    Description: Multiple toxic and bioactive compounds produced by Alexandrium spp. cause adverse effects on bivalves, but these effects are frequently difficult to attribute to a single compound class. To disentangle the effect of neurotoxic vs lytic secondary metabolites, we exposed blue mussels to either a paralytic shellfish toxin (PST) producing Alexandrium spp. strain, or to an exclusively lytic compound (LC) producing strain, or a strain containing both compound classes, to evaluate the time dependent effects after 3 and 7 days of feeding. Tested parameters comprised signs of paralysis, feeding activity, and immune cell integrity (hemocyte numbers and viability; lysosomal membrane destabilization) and function (ROS production). Both compound classes caused paralysis and immune impairment. The only effect attributable exclusively to PST was increased phagocytic activity after 3 days and impaired feeding activity after 7 days, which curtailed toxin accumulation in digestive glands. Paralysis signals and lysosomal membrane destabilization were more closely, but not exclusively, matched with LC exposure. Effects on circulating hemocyte integrity and immune related functions were mostly transient or remain stable within 7 days; except for increased lysosomal labialization and decreased extracellular ROS production when mussels were exposed to the toxin combination. M. edulis displays adaptive fitness traits to survive and maintain immune capacity upon prolonged exposure to environmentally relevant concentrations of PST and/or LC producing Alexandrium strains.
    Repository Name: EPIC Alfred Wegener Institut
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  • 24
    Publication Date: 2018-11-08
    Repository Name: EPIC Alfred Wegener Institut
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  • 25
    Publication Date: 2019-08-19
    Description: The term “Dimension Stone” refers to natural stone that has been quarried, selected and processed into specific sizes or shapes, with or without one or more mechanically dressed or finished surfaces, for use as building facing, curbing, paving stone, monuments and memorials, and various industrial products. The dimension stone industry is currently increasing the volume of its activities: based on a prudent medium-term development forecast, the net product could reach one hundred million tons in 2020. For this reason, geoscientists and stakeholders need to reason about methods and technologies in the dimension stone sector and how to operate responsibly and sustainably in accordance with the following geoethical values. After a definition of geoethics and an overview of the dimension stone industry, the paper focuses on fundamental values of geoethics as stated in the Cape Town Statement on Geoethics. More precisely, geoethical values have been referred to real and practical cases of dimension stone subsectors, by presenting some examples recorded in Sardinia (Italy). This region has a long history of production of ornamental stones. Finally, tips and suggestions on how geoscientists (in particular geologists and mining engineers) can help the dimension stone sector in a geoethical way, i.e., responsibly and sustainably are herein offered.
    Description: Published
    Description: 101468
    Description: 1TR. Georisorse
    Description: 7SR AMBIENTE – Servizi e ricerca per la società
    Description: 1TM. Formazione
    Description: 3TM. Comunicazione
    Description: JCR Journal
    Keywords: geoethics ; dimension stone ; quarrying ; natural resources ; sustainability ; geoheritage ; geo-education ; 04.04. Geology ; 05.03. Educational, History of Science, Public Issues ; 05.09. Miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 26
    Publication Date: 2019-03-15
    Description: We investigated the geochemical behaviour of major and Rare Earth Elements (REE), together with oxygen and deuterium isotopic composition in the aquifer of Vulcano, the southernmost island of the Aeolian archipelago (Italy). Studied wells, located at different distances from the crater, are characterised by different contributions of the rising volcanic fluids. In particular, those located in the proximity of La Fossa crater are affected by a strong interaction with volcanic-hydrothermal fluids and show REE behaviour similar to that of fresh rocks, suggesting a congruent dissolution of the solid matrix. Samples from the other wells, located in an area where the volcanic deposits are hydrothermally altered as an “advanced argillic facies”, are enriched in HREE and mirror the corresponding depletion observed in the altered rocks. Moreover, the different grade of interaction with hydrothermal fluids determines the main ligand that complexes the REE. The main ligand is CO3 2– in the wells that are more directly affected by hydrothermal circulation, whereas SO4 2− dominates in those located at greater distances from La Fossa crater. This information provides further clues to the complex groundwater circulation model of Vulcano Island, which is regulated by the variable mixing and interacting of rising volcano-hydrothermal fluids, meteoric infiltration and seawater, differently interacting with fresh and altered rocks.
    Description: Published
    Description: 121-129
    Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 27
    Publication Date: 2019-03-29
    Description: At present, the urban population has to cope with the effects caused from Urban Heat Island (UHI), poor air quality and increased frequency and/or intensity of extreme weather and climate events. The expected increase of these extremes in areas of the planet and the way to adapt to them has emphasized the need to investigate in detail the climate of the cities. Local vulnerability and risk assessments, supported by using regional climate models at very high resolution, are key to support development and implementation of effective local adaptation measures to make well-adapted and climate-resilient cities, i.e. more sustainable ones. This study aims to provide some quantitative information on the effectiveness of main local adaptation measures to reduce the magnitude of UHI, in terms of temperature and energy fluxes. The investigation was conducted by adopting the TEB 1D model for the Toulouse city case-study. Different urban configurations and adaptation measures have been considered in the model set up. The results confirm that different adaptation measures may reduce the temperature on the town elements during the daylight hours; among the different measures, the green roof prevent the radiative cooling, increasing the roof night temperature and contributing to the night UHI.
    Description: Published
    Description: 662-673
    Description: 4A. Oceanografia e clima
    Description: JCR Journal
    Keywords: Urban Heat Island ; Adaptation measures
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 28
    Publication Date: 2019-03-29
    Description: Pore Pressure Pulse Drove the 2012 Emilia (Italy)Series of EarthquakesGiuseppe Pezzo1, Pasquale De Gori1, Francesco Pio Lucente1, and Claudio Chiarabba11Istituto Nazionale di Geofisica e Vulcanologia, Rome, ItalyAbstractThe 2012 Emilia earthquakes sequence is thefirst debated case in Italy of destructive eventpossibly induced by anthropic activity. During this sequence, two main earthquakes occurred separated by9 days on contiguous thrust faults. Scientific commissions engaged by the Italian government reportedcomplementary scenarios on the potential trigger mechanism ascribable to exploitation of a nearby oilfield.In this study, we combine a refined geodetic source model constrained by precise aftershock locationsand an improved tomographic model of the area to define the geometrical relation between the activatedfaults and investigate possible triggering mechanisms. An aftershock decay rate that deviates from theclassical Omori-like pattern andVp/Vschanges along the fault system suggests that natural pore pressurepulse drove the space-time evolution of seismicity and the activation of the second main shock
    Description: Published
    Description: 682-690
    Description: 4T. Sismicità dell'Italia
    Description: JCR Journal
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  • 29
    Publication Date: 2019-03-29
    Description: Near-fault ground motion records often present impulsive signals, characterized by a largeamplitude in the velocity wavefield and by the energy concentrated in a short time window as comparedto the total earthquake duration. Thispulse-likebehavior is ascribed to the directivity of the seismic rupture,and it requires a stronger demand to the buildings not predicted by the classical design spectra. In this workwe investigate the pulse occurrence and duration in near-fault synthetic seismograms generated from anensemble ofk 2source models. We exploited the fault geometry of theMw= 6.3, 2009 L’Aquila earthquake,which represents a typical example of normal-fault earthquake for which several records in the fault vicinityare available for comparison with synthetics. We show that impulsive records are sensitive to the rupturevelocity, to the hypocenter depth, and to the station location, whether it is on the hanging wall or on thefootwall. The pulse duration was also shown to be proportional to the risetime, and it scales with thesource-receiver distance and inversely with the rupture velocity. We model these results as an effectof the coupled along-strike and updip directivity
    Description: Published
    Description: 7707-7721
    Description: 6T. Studi di pericolosità sismica e da maremoto
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 30
    Publication Date: 2019-12-12
    Description: The Great Burma earthquake (MsGR 8.0; Ms 7.6–7.7) occurred on May 23rd, 1912, and was one of the most remarkable early 1900's seismic events in Asia as described by Gutenberg and Richter (1954). The earthquake, focused near Maymyo, struck the Northern Shan State in eastern Myanmar. Contemporary evaluation of damage distribution and oral accounts led to a correlation between the earthquake and the topographically prominent Kyaukkyan Fault near the western margin of the Shan Plateau, although direct evidence has never been reported. This study aims to find evidence of paleoseismic activity, and to better understand the relationship between the 1912 earthquake and the Kyaukkyan Fault. Paleoseismic trenching along the Kyaukkyan Fault revealed evidence of several surface rupturing events. The northernmost trench exposes at least two visible rupture events since 4660 ± 30 BP: an older rupture stratigraphically constrained by AMS 14C dating to between 4660 ± 30 BP and 1270 ± 30 BP, and a younger rupture formed after 1270 ± 30 BP. The presence of pottery, bricks and cookingrelated charcoal in the younger faulted stratigraphy demonstrates Kyaukkyan Fault activity within human times, and a possible correlation between the younger rupture and the 1912 Maymyo earthquake is not excluded. The southern paleoseismic trench, within a broad transtensional basin far from bounding faults, exposes two (undated) surface ruptures. Further study is required to correlate those ruptures to the events dated in the north. These preliminary paleoseismological results constitute the first quantitative evidence of paleoseismic activity along the northern ~160 km of the Kyaukkyan Fault, and support existing evidence that the Kyaukkyan Fault is an active but slow-slipping structure with a long interseismic period.
    Description: Published
    Description: 75-86
    Description: 2T. Deformazione crostale attiva
    Description: JCR Journal
    Keywords: Paleoseismology ; active tectonics ; Myanmar ; 1912 earthquake ; strike-slip faulting ; 04.04. Geology ; 04.07. Tectonophysics
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  • 31
    Publication Date: 2019-12-05
    Description: This study reports the complex textural and chemical features of K-feldspar megacrysts (up to 5 cm long) hosted in trachydacitic lava flows, lava domes, and coulées from Mt. Amiata volcano (Tuscan Magmatic Province, Central Italy). Backscattering and cathodoluminescence imaging, coupled with core to rim major and trace elements patterns, reveal a complex zoning, and resorption surfaces associated with sharp chemical variations (e.g., Sr and Ba). These zoning patterns originated by disequilibrium and re-equilibration events, related to the repetitive influx of mafic magmas or convective motions in the trachydacitic magma reservoir. Multiple mafic magma refilling events are also supported by the field occurrence of abundant microgranular magmatic enclaves in the studied products. Our results highlight that the abnormal dimension of the studied K-feldspars originates by the interplay between petrological and kinetic processes involving: (i) extensive dissolution; (ii) heterogeneous nucleation; (iii) alternation of spasmodic growth events in disequilibrium and near-equilibrium crystallization. Repetitive influx of hotter magmas and reheating can determine the thermal condition to the growth of few, large K-felspar megacrysts. Also, the strong textural and chemical similarities observed in the K-feldspar megacrysts from Mt. Amiata volcanic rocks and Mt. Capanne monzogranite (Elba Island, Central Italy) support the hypothesis of a phenocrystic origin of intrusive K-feldspar megacrysts.
    Description: Tuscan regional authority (Regione Toscana) in the framework of the LAMMA-CNR Project “Monografia vulcanologica del Monte Amiata”
    Description: Published
    Description: 569-583
    Description: 4V. Processi pre-eruttivi
    Description: JCR Journal
    Keywords: K-feldspar megacrysts ; feldspar microtexture ; chemical zoning ; trace elements ; magma mixing ; dissolution/recrystallization ; Mount Amiata ; Textural and chemical zoning of K-feldspar megacrysts from Mt. Amiata Volcano
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 32
    Publication Date: 2020-07-24
    Description: The thermal state of polar continental crust plays a crucial role for understanding the stability and thickness of large ice sheets, the visco-elastic response of the solid Earth due to unloading when large ice caps melt and, in turn, the accuracy of future sea-level rise prediction. Various studies demonstrate the need for precise measurements and estimation of geothermal heat flow (GHF) in Antarctica for better constrained boundary conditions to enhance the ice sheet model performance. This study provides ground-truth for regional indirect GHF estimates in the Amundsen Sea Embayment, which is part of the West Antarctic Rift System, by presenting in situ temperature measurements in continental shelf sediments. Our results show regionally elevated and heterogeneous GHF (mean of 65 mWm−2) in the Amundsen Sea Embayment. Considering thermal blanketing effects, induced by inflow of warmer water and sedimentary processes, the estimated GHF ranges between 65 mWm−2and 95 mWm−2.
    Repository Name: EPIC Alfred Wegener Institut
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  • 33
    Publication Date: 2019-03-04
    Description: The interaction between ocean warming, hypoxia and hypercapnia, suggested by climate projections, may push an organism earlier to the limits of its thermal tolerance window. In a previous study on juveniles of green abalone (Haliotis fulgens), combined exposure to hypoxia and hypercapnia during heat stress induced a lowered critical thermal maximum (CTmax), indicated by constrained oxygen consumption, muscular spams and loss of attachment. Thus, the present study investigated the cell physiology in foot muscle of H. fulgens juveniles exposed to acute warming (18 °C to 32 °C at +3 °C day−1) under hypoxia (50% air saturation) and hypercapnia (~1000 μatm PCO2), alone and in combination, to decipher the mechanisms leading to functional loss in this tissue. Under exposure to either hypoxia or hypercapnia, citrate synthase (CS) activity decreased with initial warming, in line with thermal compensation, but returned to control levels at 32 °C. The anaerobic enzymes lactate and tauropine dehydrogenase increased only under hypoxia at 32 °C. Under the combined treatment, CS overcame thermal compensation and remained stable overall, indicating active mitochondrial regulation under these conditions. Limited accumulation of anaerobic metabolites indicates unchanged mode of energy production. In all treatments, upregulation of Hsp70 mRNA was observed already at 30 °C. However, lack of evidence for Hsp70 protein accumulation provides only limited support to thermal denaturation of proteins. We conclude that under combined hypoxia and hypercapnia, metabolic depression allowed the H. fulgens musculature to retain an aerobic mode of metabolism in response to warming but may have contributed to functional loss. Keywords: 1H NMR spectroscopy; Citrate synthase; CTmax; Hsp70; Lactate dehydrogenase; Tauropine; Tauropine dehydrogenase
    Repository Name: EPIC Alfred Wegener Institut
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  • 34
    Publication Date: 2019-03-26
    Repository Name: EPIC Alfred Wegener Institut
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  • 35
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    Elsevier
    In:  EPIC3Encyclopedia of Ocean Sciences, Encyclopedia of Ocean Sciences, Third Edition, Vol 1, Elsevier, 10 p., pp. 235-244, ISBN: 978-0-12-813081-0
    Publication Date: 2019-05-20
    Repository Name: EPIC Alfred Wegener Institut
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  • 36
    Publication Date: 2019-10-04
    Description: The region of the Filchner Outflow System (FOS) in the southeastern Weddell Sea is characterized by intensive and complex interactions of different water masses. Dense Ice Shelf Water (ISW) emerging from beneath the ice shelf cavities on the continental shelf, meets Modified Warm Deep Water (MWDW) originating from the Antarctic Circumpolar Current at the sill of the Filchner Trough. These hydrographic features convert the FOS into an oceanographic key region, which may also show enhanced biological productivity and corresponding aggregations of marine top predators. In this context, six adult Weddell seals (Leptonychotes weddellii) were instrumented with CTD-combined satellite relay data loggers in austral summer 2014. By means of these long-term data loggers we aimed at investigating the influence of environmental conditions on the seals’ foraging behaviour throughout seasons, focussing on the local oceanographic features. Weddell seals performed pelagic and demersal dives, mainly on the continental shelf, where they presumably exploited the abundant bentho-pelagic fish fauna. Diurnal and seasonal variations in light availability affected foraging activities. MWDW was associated with increased foraging effort. However, we observed differences in movements and habitat use between two different groups of Weddell seals. Seals tagged in the pack ice of the FOS focussed their foraging activities to the western and, partly, eastern flank of the Filchner Trough, which coincides with inflow pathways of MWDW. In contrast, Weddell seals tagged on the coastal fast ice exhibited typical central-place foraging and utilized resources close to their colony. High foraging effort in MWDW and high utilization of areas associated with an inflow of MWDW raise questions on the underlying biological features. This emphasizes the importance of further interdisciplinary ecological investigations in the near future, as the FOS may soon be impacted by predicted climatic changes.
    Repository Name: EPIC Alfred Wegener Institut
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  • 37
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    Elsevier
    In:  EPIC3Sub-Seasonal to Seasonal Prediction: The Gap Between Weather and Climate Forecasting, Sub-Seasonal to Seasonal Prediction: The Gap Between Weather and Climate Forecasting, Elsevier, 21 p., pp. 201-221
    Publication Date: 2018-12-03
    Description: The chapter presents a review of sea ice properties in relation to sub-seasonal to seasonal (S2S) predictions in the Arctic and the Antarctic. After a concise presentation of the main processes governing sea ice physics, the spatial distribution, seasonal cycle, and variability of sea ice in both poles are described. Using a variety of observations and model reconstructions of the four recent decades, the memory of the main descriptors of the sea ice state is quantified. In both the Arctic and the Antarctic, persistence of the sea ice areal properties emerges as the primarily source of sea ice sub-seasonal predictability, with strong dependence on season. Further memory can be obtained from reemergence mechanisms, implying processes internal to sea ice and coupling with the atmosphere and the ocean. In addition, lessons from modeling studies are addressed in terms of potential sea ice predictability and actual predictive skill. Finally, the chapter provides an overview of our understanding of the possible role of sea ice as a source of S2S atmospheric predictability, both in the polar regions and beyond.
    Repository Name: EPIC Alfred Wegener Institut
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  • 38
    Publication Date: 2018-11-19
    Description: The present study is based on a series of two-dimensional simple shear numerical simulations of two-phase non-linear viscous materials used to investigate the mechanical behaviour of two-phase aggregates representing partially molten rocks. These simulations couple viscoplastic deformation with dynamic recrystallisation (DRX). The aim of these simulations is to investigate the competition between deformation and recrystallisation, and how they affect the mechanical behaviour and resulting microstructures of the deforming material. We systematically vary the melt to solid rock ratio, the dihedral angle of melt and the ratio of DRX vs. deformation. The results show that the amount of DRX and the dihedral angle have a first-order impact on the bulk rheology and the melt distribution in the aggregate. The numerical results allow defining two regimes, depending on the relative contribution of deformation and DRX: (1) a deformation-dominated regime at high strain rates (i.e., with a low ratio of recrystallisation vs. viscoplastic deformation) and (2) a recrystallisation-dominated regime at low strain rates (i.e., with a high ratio of recrystallisation vs. viscoplastic deformation). The first case results in systems bearing large connected melt pockets whose viscous flow controls the deformation of the aggregate, while disconnected smaller melt pockets develop in models where dynamic recrystallisation dominates. The results of this study allow us to better understand the development of connected melt pockets, which may focus melt flow. The distribution of the melt phase plays a key role in the formation of larger-scale melt-enriched shear bands, which in turn has a direct influence on large-scale convective mantle flow.
    Repository Name: EPIC Alfred Wegener Institut
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  • 39
    Publication Date: 2019-08-12
    Description: Numerical models are important tools for understanding the processes and feedbacks in the Earth system, including those involving changes in atmospheric CO2 (CO2,atm) concentrations. Here, we compile 55 published model studies (consisting of 778 individual simulations) that assess the impact of six forcing mechanisms on millennial-scale CO2,atm variations: changes in freshwater supply to the North Atlantic and Southern Ocean, the strength and position of the southern-hemisphere westerlies, Antarctic sea ice extent, and aeolian dust fluxes. We generally find agreement on the direction of simulated CO2,atm change across simulations, but the amplitude of change is inconsistent, primarily due to the different complexities of the model representation of Earth system processes. When freshwater is added to the North Atlantic, a reduced Atlantic Meridional Overturning Circulation (AMOC) is generally accompanied by an increase in Southern Ocean- and Pacific overturning, reduced Antarctic sea ice extent, spatially varying export production, and changes in carbon storage in the Atlantic (rising), in other ocean basins (generally decreasing) and on land (more varied). Positive or negative CO2,atm changes are simulated during AMOC minima due to a spatially and temporally varying dominance of individual terrestrial and oceanic drivers (and compensating effects between them) across the different models. In contrast, AMOC recoveries are often accompanied by rising CO2,atm levels, which are mostly driven by ocean carbon release (albeit from different regions). The magnitude of simulated CO2,atm rise broadly scales with the duration of the AMOC perturbation (i.e., the stadial length). When freshwater is added to the Southern Ocean, reduced deep-ocean ventilation drives a CO2,atm drop via reduced carbon release from the Southern Ocean. Although the impacts of shifted southern-hemisphere westerlies are inconsistent across model simulations, their intensification raises CO2,atm via enhanced Southern Ocean Ekman pumping. Increased supply of aeolian dust to the ocean, and thus iron fertilisation of marine productivity, consistently lowers modelled CO2,atm concentrations via more efficient nutrient utilisation. The magni- tude of CO2,atm change in response to dust flux variations, however, largely depends on the complexity of models' marine ecosystem and iron cycle. This especially applies to simulations forced by Antarctic sea ice changes, in which the direction of simulated CO2,atm change varies greatly across model hierarchies. Our compilation highlights that no single (forcing) mechanism can explain observed past millennial-scale CO2,atm variability, and identifies important future needs in coupled carbon cycle-climate modelling to better understand the mechanisms governing CO2,atm changes in the past.
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  • 40
    Publication Date: 2019-03-12
    Description: © The Authors, 2019. This is the author's version of the work and is distributed under the terms of the Creative Commons Attribution-Noncommercial-Share Alike 4.0 International License. The definitive version was published in Marine Pollution Bulletin, 140, (2019):364-373, doi:10.1016/j.marpolbul.2018.12.047.
    Description: Estuaries provide significant cultural ecosystem services, including recreation and tourism. Disruptions of estuarine biogeochemical processes resulting from environmental degradation could interrupt the flow of these services, reducing benefits and diminishing the welfare of local communities. This study focused on recreational shellfishing in Buzzards Bay, Massachusetts (41.55°N, 70.80°W). Relationships among measures of recreational shellfishing, estuarine water quality, and local socioeconomic conditions were tested to understand how the benefits of cultural ecosystem services to local communities might be affected by declining water quality. Transferring estimated economic benefits from an analysis of nearby municipalities, the study finds that increases in Chl a during the 24-year period were associated with losses in recreational shellfishing benefits of $0.08–0.67 million per decade. The approach presented here suggests a more broadly applicable framework for assessing the impacts of changes in coastal ecosystem water quality on the welfare of local communities.
    Description: We would like to thank the Buzzards Bay Coalition, the Buzzards Bay National Estuary Program, and the Massachusetts Department of Marine Fisheries for providing data for this analysis. We thank the 1074 citizen volunteers of the Buzzards Bay Coalition who collected the water quality samples and Mark Rasmussen for his leadership in sustaining the Baywatchers Program. Support for this analysis was provided by the John D. and Catherine T. MacArthur Foundation (Grant no. 14-106159-000-CFP), MIT Sea Grant (subaward number 5710004045), the Johnson Endowment of the WHOI Marine Policy Center, and SCD acknowledges support from the University of Virginia.
    Keywords: Estuarine water quality ; Eutrophication ; Recreational shellfishing ; Cultural ecosystem services ; Economic benefits transfer
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  • 41
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    American Geophysical Union
    In:  EPIC3AGU Fall meeting 2019, San Francisco, CA, 2019-12-09-2019-12-13USA, American Geophysical Union
    Publication Date: 2021-08-16
    Description: Deciduous larch is a weak competitor when growing in mixed stands with evergreen taxa but is dominant in many boreal forest areas of Eastern Siberia. However, it is hypothesized that certain factors such as a shallow active layer thickness and high fire frequency favor larch dominance. Our aim is to understand how thermohydrological interactions between vegetation, permafrost, and atmosphere stabilize the larch forests and the underlying permafrost in Eastern Siberia. A tailored version of a one-dimensional land surface model (CryoGrid) is adapted for the application in vegetated areas and used to reproduce the energy transfer and thermal regime of permafrost ground in typical boreal larch stands. In order to simulate the responds of Arctic trees to local climate and permafrost conditions we have implemented a multilayer canopy parameterization originally developed for the Community Land Model (CLM-ml_v0). The coupled model is capable of calculating the full energy balance above, within and below the canopy including the radiation budget, the turbulent fluxes and the heat budget of the permafrost ground under several forcing scenarios. We will present first results of simulations performed for different study sites in larch-dominated forests of Eastern Siberia and Mongolia under current and future climate conditions. Model performance is thoroughly evaluated based on comprehensive in-situ soil temperature and radiation measurements at our study sites.
    Repository Name: EPIC Alfred Wegener Institut
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  • 42
    Publication Date: 2019-01-07
    Description: Author Posting. © American Geophysical Union, 2018. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Noble gases in deepwater oils of the U.S. Gulf of Mexico. Geochemistry, Geophysics, Geosystems , 19, 4218 – 4235.(2018): doi:10.1029/2018GC007654.
    Description: Hydrocarbon migration and emplacement processes remain underconstrained despite the vast potential economic value associated with oil and gas. Noble gases provide information about hydrocarbon generation, fluid migration pathways, reservoir conditions, and the relative volumes of oil versus water in the subsurface. Produced gas He-Ne-Ar-Kr-Xe data from two distinct oil fields in the Gulf of Mexico (Genesis and Hoover-Diana) are used to calibrate a model that takes into account both water-oil solubility exchange and subsequent gas cap formation. Reconstructed noble gas signatures in oils reflect simple (two-phase) oil-water exchange imparted during migration from the source rock to the trap, which are subsequently modified by gas cap formation at current reservoir conditions. Calculated, oil to water volume ratios (Vo/Vw) in Tertiary-sourced oils from the Hoover-Diana system are 2–3 times greater on average than those in the Jurassic sourced oils from the Genesis reservoirs. Higher Vo/Vw in Hoover-Diana versus Genesis can be interpreted in two ways: either (1) the Hoover reservoir interval has 2–3 times more oil than any of the individual Genesis reservoirs, which is consistent with independent estimates of oil in place for the respective reservoirs, or (2) Genesis oils have experienced longer migration pathways than Hoover-Diana oils and thus have interacted with more water. The ability to determine a robust Vo/Vw , despite gas cap formation and possible gas cap loss, is extremely powerful. For example, when volumetric hydrocarbon ratios are combined with independent estimates of hydrocarbon migration distance and/or formation fluid volumes, this technique has the potential to differentiate between large and small oil accumulations.
    Description: We thank ExxonMobil for funding and providing the samples. In addition, we thank James Scott and two anonymous reviewers for their comprehensive and constructive reviews, as well as Janne Blichert-Toft for editorial handling.
    Description: 2019-04-10
    Repository Name: Woods Hole Open Access Server
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  • 43
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2018. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research-Oceans 123(12), (2018): 8674-8687, doi:10.1002/2018JC013766.
    Description: A large collaborative program has studied the coupled air‐ice‐ocean‐wave processes occurring in the Arctic during the autumn ice advance. The program included a field campaign in the western Arctic during the autumn of 2015, with in situ data collection and both aerial and satellite remote sensing. Many of the analyses have focused on using and improving forecast models. Summarizing and synthesizing the results from a series of separate papers, the overall view is of an Arctic shifting to a more seasonal system. The dramatic increase in open water extent and duration in the autumn means that large surface waves and significant surface heat fluxes are now common. When refreezing finally does occur, it is a highly variable process in space and time. Wind and wave events drive episodic advances and retreats of the ice edge, with associated variations in sea ice formation types (e.g., pancakes, nilas). This variability becomes imprinted on the winter ice cover, which in turn affects the melt season the following year.
    Description: This program was supported by the Office of Naval Research, Code 32, under Program Managers Scott Harper and Martin Jeffries. The crew of R/V Sikuliaq provide outstanding support in collecting the field data, and the US National Ice Center, German Aerospace Center (DLR), and European Space Agency facilitated the remote sensing collections and daily analysis products. RADARSAT‐2 Data and Products are from MacDonald, Dettwiler, and Associates Ltd., courtesy of the U.S. National Ice Center. Data, supporting information, and a cruise report can be found at http://www.apl.uw.edu/arcticseastate
    Keywords: Arctic ; waves ; autumn ; sea ice ; Beaufort ; flux
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  • 44
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2018. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research-Oceans 123(12), (2018): 8887-8901, doi:10.1029/2018JC013797.
    Description: Sea ice is one of the determining parameters of the climate system. The presence of melt ponds on the surface of Arctic sea ice plays a critical role in the mass balance of sea ice. A total of nine cores was collected from multiyear ice refrozen melt ponds and adjacent hummocks during the 2015 Arctic Sea State research cruise. The depth profiles of water isotopes, salinity, and ice texture for these sea ice cores were examined to provide information about the development of refrozen melt ponds and water balance generation processes, which are otherwise difficult to acquire. The presence of meteoric water with low oxygen isotope values as relatively thin layers indicates melt pond water stability and little mixing during formation and refreezing. The hydrochemical characteristics of refrozen melt pond and seawater depth profiles indicate little snowmelt enters the upper ocean during melt pond refreezing. Due to the seasonal characters of deuterium excess for Arctic precipitation, water balance calculations utilizing two isotopic tracers (oxygen isotope and deuterium excess) suggest that besides the melt of snow cover, the precipitation input in the melt season may also play a role in the evolution of melt ponds. The dual‐isotope mixing model developed here may become more valuable in a future scenario of increasing Arctic precipitation. The layers of meteoric origin were found at different depths in the refrozen melt pond ice cores. Surface topography information collected at several core sites was examined for possible explanations of different structures of refrozen melt ponds.
    Description: The coauthors (S. F. A., S. S., T. M., and B. W.) wish to thank the other DRI participants and the Captain and crew of the Sikuliaq's October 2015 cruise for their assistance in the sample collections analyzed in the paper. Jim Thomson (Chief Scientist), Scott Harper (ONR Program Manager), and Martin Jeffries (ONR Program Manager) are particularly acknowledged for their unwavering assistance and leadership during the 5 years of the SeaState DRI. We thank Guy Williams for production of the aerial photo mosaic. Funding from the Office of Naval Research N00014‐13‐1‐0435 (S. F. A. and B. W.), N00014‐13‐1‐0434 (S. S.), and N00014‐13‐1‐0446 (T. M.) supported this research through grants to UTSA, UColorado, and WHOI, respectively. This project was also funded (in part) by the University of Texas at San Antonio, Office of the Vice President for Research (Y. G. and S. F. A.). Data for the stable isotope mixing models used in this study are shown in supporting information Tables S1–S3.
    Description: 2019-05-15
    Keywords: Arctic ; sea ice ; isotope tracer ; melt pond ; oxygen isotope ; deuterium excess
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  • 45
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2018. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Freymond, C. V., Lupker, M., Peterse, F., Haghipour, N., Wacker, L., Filip, F., et al. (2018). Constraining instantaneous fluxes and integrated compositions of fluvially discharged organic matter. Geochemistry, Geophysics, Geosystems, 19, 2453 2462. doi: 10.1029/2018GC007539.
    Description: Fluvial export of organic carbon (OC) and burial in ocean sediments comprises an important carbon sink, but fluxes remain poorly constrained, particularly for specific organic components. Here OC and lipid biomarker contents and isotopic characteristics of suspended matter determined in depth profiles across an active channel close to the terminus of the Danube River are used to constrain instantaneous OC and biomarker fluxes and integrated compositions during high to moderate discharges. During high (moderate) discharge, the total Danube exports 8 (7) kg/s OC, 7 (3) g/s higher plant‐derived long‐chain fatty acids (LCFA), 34 (21) g/s short‐chain fatty acids (SCFA), and 0.5 (0.2) g/s soil bacterial membrane lipids (brGDGTs). Integrated stable carbon isotopic compositions were TOC: −28.0 (−27.6)‰, LCFA: −33.5 (−32.8)‰ and Δ14C TOC: −129 (−38)‰, LCFA: −134 (−143)‰, respectively. Such estimates will aid in establishing quantitative links between production, export, and burial of OC from the terrestrial biosphere.
    Description: This project was funded by the Swiss National Science Foundation SNF. Grant Number: 200021_140850. F.P. acknowledges funding from NWO‐VENI grant 863.13.016. We thank the sampling crews from both field campaigns (Björn Buggle, James Saenz, Alissa Zuijdgeest, Marilu Tavagna, Stefan Eugen Filip, Silvia Lavinia Filip, Mihai, Clayton Magill, Thomas Blattmann, and Michael Albani), Daniel Montluçon for lab support and Hannah Gies for PCGC work. Figures, tables, and equations can be found in supporting information.
    Keywords: Danube River ; organic carbon ; biomarker ; radiocarbon ; ADCP
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  • 46
    Publication Date: 2022-05-25
    Description: Author Posting. © The Author(s), 2019. This is the author's version of the work. It is posted here by permission of Elsevier Ltd. for personal use, not for redistribution. The definitive version was published in Geochimica et Cosmochimica Acta 244 (2019): 216-228, doi:10.1016/j.gca.2018.10.012.
    Description: Mountain glaciers store dissolved organic carbon (DOC) that can be exported to river networks and subsequently respired to CO2. Despite this potential importance within the global carbon cycle, the seasonal variability and downstream transport of glacier-derived DOC in mountainous river basins remains largely unknown. To provide novel insight, here we present DOC concentrations and molecular-level dissolved organic matter (DOM) compositions from 22 nested, glaciated catchments (1.4 – 81.8 % glacier cover by area) in the Upper Ganges Basin, Western Himalaya over the course of the Indian summer monsoon (ISM) in 2014. Aliphatic and peptide-like compounds were abundant in glaciated headwaters but were overprinted by soil-derived phenolic, polyphenolic and condensed aromatic material as DOC concentrations increase moving downstream. Across the basin, DOC concentrations and soil-derived compound class contributions decreased sharply from pre- to post-ISM, implying increased relative contribution of glaciated headwater signals as the monsoon progresses. Incubation experiments further revealed a strong compositional control on the fraction of bioavailable DOC (BDOC), with glacier-derived DOC exhibiting the highest bioavailability. We hypothesize that short-term (i.e. in the coming decades) increases in glacier melt flux driven by climate change will further bias exported DOM toward an aliphatic-rich, bioavailable signal, especially during the ISM and post-ISM seasons. In contrast, eventual decreases in glacier melt flux due to mass loss will likely lead to more a soil-like DOM composition and lower bioavailability of exported DOC in the long term.
    Description: We thank Britta Voss (WHOI) for assisting with sample collection; Travis Drake (FSU), and Ekaterina Bulygina (Woods Hole Research Center) for laboratory assistance; and the NHMFL ICR user program (NSF-DMR-1157490) for aiding in data acquisition and analysis. This study was partly supported by NSF-DEB-1145932 to R.G.M.S. J.D.H. was partially supported by the NSF Graduate Research Fellowship Program under grant number 2012126152, with additional support in the form of travel grants awarded by the MIT Houghten Fund and NHMFL. All data used in this study are available in the Supporting Information Tables S1 and S2.
    Keywords: Dissolved organic matter ; Eco-hydrology ; Glaciers ; Himalaya ; Monsoon
    Repository Name: Woods Hole Open Access Server
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  • 47
    Publication Date: 2022-05-25
    Description: © The Author(s), 2019. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Fringer, O. B., Dawson, C. N., He, R., Ralston, D. K., & Zhang, Y. J. The future of coastal and estuarine modeling: findings from a workshop. Ocean Modelling, 143, (2019): 101458, doi:10.1016/j.ocemod.2019.101458.
    Description: This paper summarizes the findings of a workshop convened in the United States in 2018 to discuss methods in coastal and estuarine modeling and to propose key areas of research and development needed to improve their accuracy and reliability. The focus of this paper is on physical processes, and we provide an overview of the current state-of-the-art based on presentations and discussions at the meeting, which revolved around the four primary themes of parameterizations, numerical methods, in-situ and remote-sensing measurements, and high-performance computing. A primary outcome of the workshop was agreement on the need to reduce subjectivity and improve reproducibility in modeling of physical processes in the coastal ocean. Reduction of subjectivity can be accomplished through development of standards for benchmarks, grid generation, and validation, and reproducibility can be improved through development of standards for input/output, coupling and model nesting, and reporting. Subjectivity can also be reduced through more engagement with the applied mathematics and computer science communities to develop methods for robust parameter estimation and uncertainty quantification. Such engagement could be encouraged through more collaboration between the forward and inverse modeling communities and integration of more applied math and computer science into oceanography curricula. Another outcome of the workshop was agreement on the need to develop high-resolution models that scale on advanced HPC systems to resolve, rather than parameterize, processes with horizontal scales that range between the depth and the internal Rossby deformation scale. Unsurprisingly, more research is needed on parameterizations of processes at scales smaller than the depth, including parameterizations for drag (including bottom roughness, bedforms, vegetation and corals), wave breaking, and air–sea interactions under strong wind conditions. Other topics that require significantly more work to better parameterize include nearshore wave modeling, sediment transport modeling, and morphodynamics. Finally, it was agreed that coastal models should be considered as key infrastructure needed to support research, just like laboratory facilities, field instrumentation, and research vessels. This will require a shift in the way proposals related to coastal ocean modeling are reviewed and funded.
    Description: We thank Carmen Torres at Stanford University and Jennifer Warrillow at North Carolina State University for their assistance with workshop logistics. Helpful comments and suggestions were provided by two anonymous reviewers and Hans Burchard and John Warner. The workshop and preparation of this paper were funded by U.S. National Science Foundation Grant OCE-1749613.
    Keywords: Coastal ocean modeling ; Physical processes ; Model subjectivity ; Development of standards ; High-resolution modeling ; Parameter estimation
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  • 48
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2018. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research-Oceans, 123(11), (2018): 7877-7895. doi: 10.1029/2018JC014290.
    Description: A three‐dimensional, primitive‐equation, ocean circulation model coupled with a Lagrangian particle‐tracking algorithm is used to investigate the dispersal and settlement of planktonic larvae released from discrete hydrothermal habitats on the East Pacific Rise segment at 9–10°N. Model outputs show that mean circulation is anticyclonic around the ridge segment, which consists of a northward flow along the western flank and a southward flow along the eastern flank. Those flank jets are dispersal expressways for the along‐ridge larval transport and strongly affect its overall direction and spatial‐temporal variations. It is evident from model results that the transform faults bounding the ridge segment and off axis topography (the Lamont Seamount Chain) act as topographic barriers to larval dispersal in the along‐ridge direction. Furthermore, the presence of an overlapping spreading center and an adjacent local topographic high impedes the southward along‐ridge larval transport. The model results suggest that larval recolonization within ridge‐crest habitats is enhanced by the anticyclonic circulation around the ridge segment, and the overall recolonization rate is higher for larvae having a short precompetency period and an altitude above the bottom sufficient to avoid influence by the near‐bottom currents Surprisingly, for larvae having a long precompetency period (〉10 days), the prolonged travel time allowed some of those larvae to return to their natal vent clusters, which results in an unexpected increase in connectivity among natal and neighboring sites. Overall, model‐based predictions of connectivity are highly sensitive to the larval precompetency period and vertical position in the water column.
    Description: The sediment‐trap data presented in this paper are included in Table S1. The bathymetric data used in the model can be downloaded from the Global Multi‐Resolution Topography (GMRT) Synthesis of Marine Geoscience Data System (MGDS) (https://www.gmrt.org/GMRTMapTool). The ocean current time series data used in this work were acquired in 2006‐2007 by Andreas Thurnherr at the Earth Institute of Columbia University. Those data can be accessed in the supporting information. D.J. McGillicuddy gratefully acknowledges support from the National Science Foundation and the Holger W. Jannasch and Columbus O'Donnell Iselin Shared Chairs for Excellence in Oceanography. L.S. Mullineaux acknowledges with gratitude support from the National Science Foundation and the Woods Hole Oceanographic Institution (WHOI) Ocean life fellowship. We appreciate the operation support from the Captain and crew of R/V Atlantis and the Alvin submersible group. We are thankful to V.K. Kosnyrev for developing the coupling interface between the ocean‐circulation and particle‐tracking models. We are grateful to J.W. Lavelle for his intellectual support for the modeling work presented in this paper. We thank Houshuo Jiang for sponsoring our use of the cluster computer at WHOI.
    Description: 2019-05-06
    Keywords: larva ; dispersal ; hydrothermal vent ; EPR ; connectivity ; supply
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  • 49
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2018. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research-Oceans, 123(11), (2018): 7983-8003. doi:10.1029/2018JC014298.
    Description: A melt pond (MP) distribution equation has been developed and incorporated into the Marginal Ice‐Zone Modeling and Assimilation System to simulate Arctic MPs and sea ice over 1979–2016. The equation differs from previous MP models and yet benefits from previous studies for MP parameterizations as well as a range of observations for model calibration. Model results show higher magnitude of MP volume per unit ice area and area fraction in most of the Canada Basin and the East Siberian Sea and lower magnitude in the central Arctic. This is consistent with Moderate Resolution Imaging Spectroradiometer observations, evaluated with Measurements of Earth Data for Environmental Analysis (MEDEA) data, and closely related to top ice melt per unit ice area. The model simulates a decrease in the total Arctic sea ice volume and area, owing to a strong increase in bottom and lateral ice melt. The sea ice decline leads to a strong decrease in the total MP volume and area. However, the Arctic‐averaged MP volume per unit ice area and area fraction show weak, statistically insignificant downward trends, which is linked to the fact that MP water drainage per unit ice area is increasing. It is also linked to the fact that MP volume and area decrease relatively faster than ice area. This suggests that overall the actual MP conditions on ice have changed little in the past decades as the ice cover is retreating in response to Arctic warming, thus consistent with the Moderate Resolution Imaging Spectroradiometer observations that show no clear trend in MP area fraction over 2000–2011.
    Description: We gratefully acknowledge the support of the NASA Cryosphere Program (grants NNX15AG68G, NNX17AD27G, and NNX14AH61G), the Office of Naval Research (N00014‐12‐1‐0112), the NSF Office of Polar Programs (PLR‐1416920, PLR‐1603259, PLR‐1602521, and ARC‐1203425), and the Department of Homeland Security (DHS, 2014‐ST‐061‐ML‐0002). The DHS grant is coordinated through the Arctic Domain Awareness Center (ADAC), a DHS Center of Excellence, which conducts maritime research and development for the Arctic region. The views and conclusions in this document are those of the authors and should not be interpreted as representing the official policies, either expressed or implied, of the DHS. MODIS‐derived MP area data are available at https://icdc.cen.uni‐hamburg.de/1/daten/cryosphere/arctic‐meltponds.html. MP area fraction statistics derived from MEDEA images are available from http://psc.apl.uw.edu/melt‐pond‐data/. Sea ice thickness and snow observations are available at http://psc.apl.washington.edu/sea_ice_cdr. CFS forcing data used to drive MIZMAS are available at https://www.ncdc.noaa.gov/data‐access/model‐data/model‐datasets/climate‐forecast‐system‐version2‐cfsv2.
    Description: 2019-04-18
    Keywords: Arctic Ocean ; sea ice ; melt ponds ; numerical modeling ; climate variability
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  • 50
    Publication Date: 2020-01-02
    Description: Localisation of ductile deformation in rocks is commonly found at all scales from crustal shear zones down to grain scale shear bands. Of the various mechanisms for localisation, mechanical anisotropy has received relatively little attention, especially in numerical modelling. Mechanical anisotropy can be due to dislocation creep of minerals (e.g. ice or mica) and/or layering in rocks (e.g. bedding, cleavage). We simulated simple-shear deformation of a locally anisotropic, single-phase power-law rheology material up to shear strain of five. Localisation of shear rate in narrow shear bands occurs, depending on the magnitude of anisotropy and the stress exponent. At high anisotropy values, strain-rate frequency distributions become approximately log-normal with heavy, exponential tails. Localisation due to anisotropy is scale-independent and thus provides a single mechanism for a self-organised hierarchy of shear bands and zones from mm-to km-scales. The numerical simulations are compared with the natural example of the Northern Shear Belt at Cap de Creus, NE Spain.
    Repository Name: EPIC Alfred Wegener Institut
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  • 51
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    American Geophysical Union
    In:  EPIC3Paleoceanography and Paleoclimatology, American Geophysical Union
    Publication Date: 2020-05-14
    Repository Name: EPIC Alfred Wegener Institut
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  • 52
    Publication Date: 2019-09-19
    Repository Name: EPIC Alfred Wegener Institut
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  • 53
    Publication Date: 2019-12-03
    Repository Name: EPIC Alfred Wegener Institut
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  • 54
    Publication Date: 2019-03-12
    Description: © The Authors, 2019. This article is distributed under the terms of the Creative Commons Attribution-Noncommercial-Share Alike 4.0 International License. The definitive version was published in Molecular Phylogenetics and Evolution (2019), doi:10.1016/j.ympev.2019.02.003.
    Description: The advent of massive parallel sequencing technologies has resulted in an increase of studies based upon complete mitochondrial genome DNA sequences that revisit the taxonomic status within and among species. Spatially distinct monophyly in such mitogenomic genealogies, i.e., the sharing of a recent common ancestor among con-specific samples collected in the same region has been viewed as evidence for subspecies. Several recent studies in cetaceans have employed this criterion to suggest subsequent intraspecific taxonomic revisions. We reason that employing intra-specific, spatially distinct monophyly at non-recombining, clonally inherited genomes is an unsatisfactory criterion for defining subspecies based upon theoretical (genetic drift) and practical (sampling effort) arguments. This point was illustrated by a re-analysis of a global mitogenomic assessment of fin whales, Balaenoptera physalus spp., published by Archer et al. (2013), which proposed to further subdivide the Northern Hemisphere fin whale subspecies, B. p. physalus. The proposed revision was based upon the detection of spatially distinct monophyly among North Atlantic and North Pacific fin whales in a genealogy based upon complete mitochondrial genome DNA sequences. The extended analysis conducted in this study (1,676 mitochondrial control region, 162 complete mitochondrial genome DNA sequences and 20 microsatellite loci genotyped in 358 samples) revealed that the apparent monophyly among North Atlantic fin whales reported by Archer et al. (2013) to be due to low sample sizes. In conclusion, defining sub-species from monophyly (i.e., the absence of para- or polyphyly) can lead to erroneous conclusions due to relatively “trivial” aspects, such as sampling. Basic population genetic processes (i.e., genetic drift and migration) also affect the time to the most recent common ancestor and hence the probability that individuals in a sample are monophyletic.
    Description: We are grateful to Hanne Jørgensen, Anna Sellas, Mary Beth Rew and Christina Færch-Jensen for technical assistance. We thank Drs. P. E. Rosel and K. D. Mullin (U.S. National Marine Fisheries Service Southeast Fisheries Science Center) and members of the U.S. Northeast and Southeast Region Marine Mammal Stranding Network and its response teams, including the International Fund for Animal Welfare, the Marine Mammal Stranding Center, Mystic Aquarium, the Riverhead Foundation for Marine Research and Preservation (K. Durham) and the Marine Mammal Stranding Program of the University of North Carolina Wilmington for access to fin whale samples from the western North Atlantic. We thank Gisli Vikingsson for providing samples. We are indebted to Dr. Eduardo Secchi for facilitating data sharing. Data collection in the Southern Ocean was conducted under research projects Baleias (CNPq grants 557064/2009-0 and 408096/2013-6), INTERBIOTA (CNPq 407889/2013-2) and INCT-APA (CNPq 574018/2008-5), of the Brazilian Antarctic Program and a contribution by the research consortium ‘Ecology and Conservation of Marine Megafauna – EcoMega-CNPq’. MAS was supported through a FCT Investigator contract funded by POPH, QREN European Social Fund, and Portuguese Ministry for Science and Education. Data collection in the Azores was funded by TRACE-PTDC/MAR/74071/2006 and MAPCET-M2.1.2/F/012/2011 [FEDER, COMPETE, QREN European Social Fund, and Proconvergencia Açores/EU Program]. Fin whale illustration herein is used with the permission of Frédérique Lucas. We acknowledge the Center for Information Technology of the University of Groningen for IT support and access to the Peregrine high performance-computing cluster.
    Keywords: fin whale ; Balaenoptera physalus ; North Atlantic Ocean ; subspecies ; mitochondrial genome
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  • 55
    Publication Date: 2022-03-25
    Description: The reconstruction of past environments by means of macrofossil and pollen analysis is commonly based on the modern ecological preferences of the taxa that may have produced these fossils. Here we present a modelling approach, in which we use modern vegetation–surface height relationships to quantify past surface heights in an Arctic ice-wedge polygon mire. Vegetation composition and ground surface height (GSH) were assessed in a polygon mire near Kytalyk (Northeastern Siberia). Cluster analysis revealed five plant communities, which are clearly separated with respect to ground surface height, frost surface height and coverages of open water and vegetation. Based on the composition of modern vegetation we constructed two sets of potential fossil types (plant macrofossils and pollen), an extensive one and a more restricted one to reflect different conditions of preservation and recognisability. We applied Canonical Correspondence Analysis to model the relationships between potential fossil types and measured GSH. Both models show a strong relationship between modelled and measured GSH values and a high accuracy in prediction. Finally, we used the models to predict GSH values for Holocene peat samples and found a fair correspondence with expert-based multi-proxy reconstruction of wetness conditions, even though only a minor part of the encountered fossils were represented in the GSH models, illustrating the robustness of the approach. Our approach can be used to reconstruct palaeoenvironmental conditions in a more objective way and can serve as a template for further palaeoecological studies.
    Repository Name: EPIC Alfred Wegener Institut
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  • 56
    Publication Date: 2021-11-09
    Description: The Punta delle Pietre Nere (Gargano, Southern Italy) igneous body is constituted by gabbroic and syenitic rocks with lamprophyric affinity of different age (58 and 62 Ma, respectively). The chemical composition of the minerals clearly indicates that there is no genetic relationship between the two lithotypes, in agreement with their significant age difference. The chemical (trace elements) and Sr-Nd-Pb-isotopic composition of these rocks highlights an “anorogenic” geochemical affinity derived from mixed DMM-HIMU-EM mantle reservoirs, similarly to other Paleogene-Oligocenemagmatic provinces in the Circum-Mediterranean Area. In past literature, these features were interpreted as evidences for enriched asthenospheric mantle plume upwelling from deep regions beneath the Western Europe. Here we suggest that the HIMU-like composition of Punta delle Pietre Nere rocks is related to a lithosphericmantle source bearing amphibole-rich veins, resulting from crystallization of melts within the amphibole stability field in presence of H2O, as shown by several experimental works. Our results suggests partial melting at 70–90 km depth, which corresponds to the spinel-garnet transition (2.5–3.5 GPa) close to the amphibole stability limit (~90–110 km and 2.5–3.5 GPa).
    Description: Published
    Description: 316-328
    Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Description: JCR Journal
    Keywords: Punta delle Pietre Nere Anorogenic magmatism Isotope geochemistry Mantle plume ; Anorogenic magmatism ; Mantle plume
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 57
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2019. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 46(3), (2019):1702-1708. doi:10.1029/2018GL081087.
    Description: After leaving the U.S. East Coast, the northward flowing Gulf Stream (GS) becomes a zonal jet and carries along its frontal characteristics of strong flow and sea surface temperature gradients into the North Atlantic at midlatitudes. The separation location where it leaves the coast is also an anchor point for the wintertime synoptic storm track across North America to continue to develop and head across the ocean. We examine the meridional variability of the separated GS path on interannual to decadal time scales as an agent for similar changes in the storm track and blocking variability at midtroposphere from 1979 to 2012. We find that periods of northerly (southerly) GS path are associated with increased (suppressed) excursions of the synoptic storm track to the northeast over the Labrador Sea and reduced (enhanced) Greenland blocking. In both instances, GS shifts lead those in the midtroposphere by a few months.
    Description: Our research has been conducted with the support of NSF (AGS‐1355339, OCE‐1419235, and OCE‐1242989), NASA (NNX13AM59G), and NOAA CPO Climate Variability and Predictability Program (NA13OAR4310139) grants to the Woods Hole Oceanographic Institution. We also thank three reviewers for their insightful comments on an earlier draft of this manuscript. Quarterly estimates of our Gulf Stream Index are available as a data file in the supporting information.
    Description: 2019-07-29
    Keywords: Gulf Stream path changes ; Wintertime atmospheric storm track ; Greenland blocking ; Intrerannual variability
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  • 58
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2019. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 46(5), (2019):2704-2714, doi:10.1029/2019GL081919.
    Description: Seismic images and glider sections of the Gulf Stream front along the U.S. eastern seaboard capture deep, lens‐shaped submesoscale features. These features have radii of 5–20 km, thicknesses of 150–300 m, and are located at depths greater than 500 m. These are typical signatures of anticyclonic submesoscale coherent vortices. A submesoscale‐resolving realistic simulation, which reproduces submesoscale coherent vortices with the same characteristics, is used to analyze their generation mechanism. Submesoscale coherent vortices are primarily generated where the Gulf Stream meets the Charleston Bump, a deep topographic feature, due to the frictional effects and intense mixing in the wake of the topography. These submesoscale coherent vortices can transport waters from the Charleston Bump's thick bottom mixed layer over long distances and spread them within the subtropical gyre. Their net effect on heat and salt distribution remains to be quantified.
    Description: J. G. gratefully acknowledges support from the French government, managed by the French National Agency for Research (ANR), through programs ISblue (ANR‐17‐EURE‐0015) and LabexMER (ANR‐10‐LABX‐19) and from LEFE/IMAGO through the project AO2017‐994457‐RADII. Simulations were performed using HPC resources from GENCI‐TGCC (grant 2017‐A0010107638). Simulations output is available upon request. Seismic data were processed using the Echos software package by Paradigm, Matlab, and Generic Mapping Tools. The Eastern North America Margin Community Seismic Experiment was funded by the National Science Foundation under grant OCE‐1347498 and UNOLS; cruise data are freely available via the Marine Geoscience Data System Academic Seismic Portal at Lamont‐Doherty Earth Observatory (http://www.marine-geo.org/portals/seismic/). Spray glider observations in the Gulf Stream are available from http://spraydata.ucsd.edu and should be cited using the following DOI (10.21238/S8SPRAY2675; Todd & Owens, 2016). Spray glider operations were funded by the National Science Foundation (OCE‐1633911) and the Office of Naval Research (N000141713040).
    Description: 2019-08-27
    Keywords: Submesoscale coherent vortices ; Glider ; Seismic observations ; Gulf Stream ; Topographic interactions ; Charleston Bump
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  • 59
    Publication Date: 2022-10-26
    Description: A© The Author(s), 2019. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Cedarholm, E. R., Rypina, I. I., Macdonald, A. M., & Yoshida, S. Investigating subsurface pathways of Fukushima cesium in the Northwest Pacific. Geophysical Research Letters, 46(12), (2019): 6821-6829, doi:10.1029/2019GL082500.
    Description: Advective pathways for Fukushima Daiichi Nuclear Power Plant (FDNPP)‐derived cesium observed in 2013 at 166°E south of the Kuroshio Extension (KE) at 〉500 m on the 26.5σθ isopycnal are investigated. Attention is paid to the KE's role in shaping these pathways. Using a high‐resolution model, particle trajectories were simulated backward and forward in time on 26.5σθ between the 2013 observations and the 2011 source. A large fraction of backtracked trajectories interacted with the mixed layer just offshore of the FDNPP. The likeliest pathway reaching the deepest 2013 observed cesium location runs along the KE out to ~165°E, where it turns sharply southward. Forward trajectory statistics suggest that for 26.5σθ waters originating north of the KE, this current acted as a permeable barrier west of 155–160°E. The deepest 2011 model mixed layers suggest that FDNPP‐derived radionuclides may have been present at 30°N in 2013 at greater depths and densities (700 m; 26.8σθ).
    Description: We would like to thank our two anonymous reviewers for their insightful suggestions that improved this paper. Work by Cedarholm on this project was supported by the WHOI Summer Student Fellowship program and was her UNH senior Capstone project. Rypina, Macdonald, and Yoshida acknowledge salary and project support from the National Science Foundation (NSF) grant OCE‐1356630. Additionally, Rypina would like to acknowledge support from NSF grant OCE‐1558806. CLIVAR PO2 and P10 observations, data sets 318M20130321 and 49NZ2012011, were obtained from the CCHDO (https://cchdo.ucsd.edu/) and the HYCOM output, data set GLBa0.08 expt_90.0v, from https://www.hycom.org/. Argo profiles were obtained from http://www.argodatamgt.org, the ISAS‐15 0.5°gridded Argo‐data‐alone product from https://www.seanoe.org, and delayed‐time allsat AVISO gridded surface velocity estimates from http://marine.copernicus.eu. Extended acknowledgements in Text S4.
    Keywords: Fukushima tracer ; Transport across Kuroshio Extension current ; Subsurface pathways and barriers ; Mode waters ; Particle tracking
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  • 60
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2019. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research-Oceans 124(6), (2019): 3987-4002, doi:10.1029/2019JC015134.
    Description: Mooring data from September 2011 to July 2013 on the Iceland slope north of Denmark Strait are analyzed to better understand the structure and variability of the North Icelandic Jet (NIJ). Three basic configurations of the flow were identified: (1) a strong separated East Greenland Current (EGC) on the mid‐Iceland slope coincident with a weak NIJ on the upper slope, (2) a merged separated EGC and NIJ, and (3) a strong NIJ located at its climatological mean position, coincident with a weak signature of the separated EGC at the base of the Iceland slope. Our study reveals that the NIJ‐dominant scenario was present during different times of the year for the two successive mooring deployments—appearing mainly from September to February the first year and from January to July the second year. Furthermore, when this scenario was active it varied on short timescales. An energetics analysis demonstrates that the high‐frequency variability is driven by mean‐to‐eddy baroclinic conversion at the shoreward edge of the NIJ, consistent with previous modeling work. The seasonal timing of the NIJ dominant scenario is investigated in relation to the atmospheric forcing upstream of Denmark Strait. The resulting lagged correlations imply that strong turbulent heat fluxes in a localized region on the continental slope of Iceland, south of the Spar Fracture zone, lead to a stronger NIJ dominant state with a two‐month lag. This can be explained dynamically in terms of previous modeling work addressing the circulation response to dense water formation near an island.
    Description: The authors thank the crew members of the R/V Knorr, RRS James Clark Ross, and R/V Bjarni Sæmundsson for the deployment and recovery of the moorings. D. Torres and F. Bahr processed the second year of mooring data. We thank K. Våge, B. Harden, Z. Song, J. Li, and M. Li for helpful discussions regarding the work. Funding was provided by the National Science Foundation under grants OCE‐1558742 (J. H., R. P., P. L., and M. S.) and OCE‐1534618 (M. S.). The mooring data are available at http://kogur.whoi.edu/php/index.php.
    Description: 2019-12-04
    Keywords: North Icelandic Jet ; Denmark Strait Overflow Water ; Baroclinic instability ; Island flow
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  • 61
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2019. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Earth and Space Science, 6(7), (2019): 1220-1233, doi:10.1029/2018EA000436.
    Description: Ocean evaporative fluxes are a critical component of the Earth's energy and water cycle, but their estimation remains uncertain. Near‐surface humidity is a required input to bulk flux algorithms that relate mean surface values to the turbulent fluxes. Several satellite‐derived turbulent flux products have been developed over the last decade that utilize passive microwave imager observations to estimate the surface humidity. It is known, however, that these estimates tend to diverge from one another and from in situ observations. Analysis of current state‐of‐the‐art satellite estimates provided herein reveals that regional‐scale biases in these products remain significant. Investigations reveal a link between the spatial coherency of the observed biases to atmospheric dynamical controls of water vapor vertical stratification, cloud liquid water, and sea surface temperature. This information is used to develop a simple state‐dependent bias correction that results in more consistent ocean surface humidity estimates. A principal conclusion is that further improvements to ocean near‐surface humidity estimation using microwave radiometers requires incorporation of prior information on water vapor stratification and sea surface temperature.
    Description: Data products used in this study are made publicly available via multiple repositories hosted by individual data product producers. JOFUROv2 and JOFUROv3 data are available online (https://j‐ofuro.scc.u‐tokai.ac.jp/en/). IFREMERv4 and NOCS surface data are available through the OceanHeatFlux project (https://www.ifremer.fr/oceanheatflux/Data). GSSTFv3 (doi:10.5067/MEASURES/GSSTF/DATA301) and MERRA‐2 data are obtained from the Goddard Earth Sciences Data and Information Services Center. HOAPSv3.2 data are available from Satellite Application Facility on Climate Monitoring (https://doi.org/10.5676/EUM_SAF_CM/HOAPS/V001). SEAFLUXv2 data are accessed through the National Centers for Environmental Information (http://doi.org/10.7289/V59K4885). Daily surface observations were provided by David Berry and Elizabeth Kent. This work is supported under the NASA Physical Oceanography Program Grant NNX14AK48A.
    Keywords: Humidity ; Passive microwave ; Ocean ; Turbulent fluxes ; Evaporation ; Remote sensing
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  • 62
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 20XX. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 46(12), (2019): 6435-6442, doi:10.1029/2019GL082523.
    Description: Acoustic Doppler current profiler and conductivity‐temperature‐depth data acquired in Yellowstone Lake reveal the presence of a buoyant plume above the “Deep Hole” hydrothermal system, located southeast of Stevenson Island. Distributed venting in the ~200 × 200‐m hydrothermal field creates a plume with vertical velocities of ~10 cm/s in the mid‐water column. Salinity profiles indicate that during the period of strong summer stratification the plume rises to a neutral buoyancy horizon at ~45‐m depth, corresponding to a ~70‐m rise height, where it generates an anomaly of ~5% (−0.0014 psu) relative to background lake water. We simulate the plume with a numerical model and find that a heat flux of 28 MW reproduces the salinity and vertical velocity observations, corresponding to a mass flux of 1.4 × 103 kg/s. When observational uncertainties are considered, the heat flux could range between 20 to 50 MW.
    Description: The authors thank Yellowstone National Park Fisheries and Aquatic Sciences, The Global Foundation for Ocean Exploration, and Paul Fucile for logistical support. This research was supported by the National Science Foundation grants EAR‐1516361 to R. S., EAR‐1514865 to K. L., and EAR‐1515283 to R. H. and J. F. All work in Yellowstone National Park was completed under an authorized Yellowstone research permit (YELL‐2018‐SCI‐7018). CTD and ADCP profiles reported in this paper are available through the Marine Geoscience Data System (doi:10.1594/IEDA/324713 and doi:10.1594/IEDA/324712, accessed last on 17 April 2019, respectively).
    Description: 2019-11-09
    Keywords: Hydrothermal plume
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  • 63
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2019. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Global Biogeochemical Cycles 32(12), (2019): 1759-1775, doi:10.1029/2018GB006026.
    Description: Karst subterranean estuaries (KSEs) extend into carbonate platforms along 12% of all coastlines. A recent study has shown that microbial methane (CH4) consumption is an important component of the carbon cycle and food web dynamics within flooded caves that permeate KSEs. In this study, we obtained high‐resolution (~2.5‐day) temporal records of dissolved methane concentrations and its stable isotopic content (δ13C) to evaluate how regional meteorology and hydrology control methane dynamics in KSEs. Our records show that less methane was present in the anoxic fresh water during the wet season (4,361 ± 89 nM) than during the dry season (5,949 ± 132 nM), suggesting that the wet season hydrologic regime enhances mixing of methane and other constituents into the underlying brackish water. The δ13C of the methane (−38.1 ± 1.7‰) in the brackish water was consistently more 13C‐enriched than fresh water methane (−65.4 ± 0.4‰), implying persistent methane oxidation in the cave. Using a hydrologically based mass balance model, we calculate that methane consumption in the KSE was 21–28 mg CH4·m−2·year−1 during the 6‐month dry period, which equates to ~1.4 t of methane consumed within the 102‐ to 138‐km2 catchment basin for the cave. Unless wet season methane consumption is much greater, the magnitude of methane oxidized within KSEs is not likely to affect the global methane budget. However, our estimates constrain the contribution of a critical resource for this widely distributed subterranean ecosystem.
    Description: Funding for T. M. I. and D. B. was provided by TAMU‐CONACYT (project 2015‐049). D. B. was supported by the Research‐in‐Residence program (NSF award 1137336, Inter‐university Training in Continental‐scale Ecology), the Boost Fellowship (Texas A&M University at Galveston), and the Postdoctoral Scholar Program by Woods Hole Oceanographic Institution and U.S. Geological Survey. We thank Jacob Pohlman and István Brankovits for assistance with field expeditions. Special thanks to the late Bil Phillips (Speleotech) for the support and expertise provided us during field operations. We also thank Pete van Hengstum for productive discussions and guidance during the development of the manuscript. Michael Casso and Adrian Green helped with laboratory analyses. The manuscript was greatly improved by helpful comments from an anonymus reviewer, Jeff Chanton, and Meagan Gonneea. This work is contribution number UMCES 5541. Any use of trade names is for descriptive purposes and does not imply endorsement by the U.S. Government. The authors declare no competing financial interests. Archival data are available through the USGS ScienceBase‐Catalog at https://doi.org/10.5066/P9U0KRVM.
    Keywords: Subterranean estuary ; Coastal aquifer ; Carbon cycling ; Methane ; Hydrobiogeochemistry ; Anchialine ecosystem
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  • 64
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2019. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 46(7) (2019): 3927-3935, doi: 10.1029/2018GL081593.
    Description: Climate model simulations of the summer South Asian monsoon predict increased rainfall in response to anthropogenic warming. However, instrumental data show a decline in Indian rainfall in recent decades, underscoring the critical need for additional, independent records of past monsoon variability. Here, we present new reconstructions of annual summer South Asian Monsoon circulation over the past 250 years, based on the geochemical barium‐calcium signature of dust present in Red Sea corals. These records reveal how monsoon circulation has evolved with warming climate and indicate a significant multi‐century long monsoon intensification, with decreased multidecadal variance. Stronger monsoon circulation would have increased the moisture transport from the Arabian Sea and Bay of Bengal over the Indian subcontinent. If these trends continue, the monsoon circulation and associated moisture transport and precipitation will remain strong and stable for several decades.
    Description: We thank Editor Valerie Trouet and two anonymous reviewers for their constructive comments. We gratefully acknowledge Justin Ossolinski for assistance during core drilling; Maureen Auro, Laura Robinson, and Tom Marchitto for use of lab space and for technical advice; Margaret Sulanowska for providing XRD analysis of dust samples; and Sujata Murty and Ryan Davis for assistance in the lab. We thank Falmouth Hospital for use of X‐ray equipment. We acknowledge the use of the NSF‐supported WHOI ICP‐MS facility and thank Scot Birdwhistell for his assistance. This research was supported by grants to K. A. H. from NSF award OCE‐1031288 and KAUST award USA00002, and by a WHOI Postdoctoral Fellowship awarded to S. P. B. All data presented in this manuscript will be made publicly available online through the NOAA NCDC Paleoclimatology data archive (https://www.ncdc.noaa.gov/data‐access/paleoclimatology‐data/).
    Description: 2019-09-28
    Keywords: Paleoclimatology ; Climate variability ; Aerosols and particles ; Major and trace element geochemistry
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  • 65
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2019. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 46(6), (2019):3398-3407, doi:10.1029/2018GL080890.
    Description: The hazards posed by infrequent major floods to communities along the Susquehanna River and the ecological health of Chesapeake Bay remain largely unconstrained due to the short length of streamgage records. Here we develop a history of high‐flow events on the Susquehanna River during the late Holocene from flood deposits contained in MD99‐2209, a sediment core recovered in 26 m of water from Chesapeake Bay near Annapolis, Maryland, United States. We identify coarse‐grained deposits left by Hurricane Agnes (1972) and the Great Flood of 1936, as well as during three intervals that predate instrumental flood records (~1800–1500, 1300–1100, and 400–0 CE). Comparison to sedimentary proxy data (pollen and ostracode Mg/Ca ratios) from the same core site indicates that prehistoric flooding on the Susquehanna often accompanied cooler‐than‐usual winter/spring temperatures near Chesapeake Bay—typical of negative phases of the North Atlantic Oscillation and conditions thought to foster hurricane landfalls along the East Coast.
    Description: This work was supported by the USGS Land Change Science Program and Northeast Region. We appreciated the assistance of Brian Buczkowski, Andrew Zimmerman, and John Bratton in locating archived core materials and data sets. We thank John Jackson and Bryan Landacre for assistance with XRD and pollen analysis, respectively. We thank two anonymous reviewers, Lynn Wingard (USGS), and Rob Stamm (USGS) for their helpful feedback on earlier versions of this manuscript. Any use of trade, firm, or product names is for descriptive purposes only and does not imply endorsement by the U.S. Government. Data generated for this report can be found in the accompanying supporting information.
    Description: 2019-08-19
    Keywords: Hurricane ; Flood ; Holocene ; East coast ; River ; Chesapeake
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  • 66
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2019. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Global Biogeochemical Cycles 32(12), (2019): 1738-1758, doi:10.1029/2018GB005994.
    Description: Sinking particles strongly regulate the distribution of reactive chemical substances in the ocean, including particulate organic carbon and other elements (e.g., P, Cd, Mn, Cu, Co, Fe, Al, and 232Th). Yet, the sinking fluxes of trace elements have not been well described in the global ocean. The U.S. GEOTRACES campaign in the North Atlantic (GA03) offers the first data set in which the sinking flux of carbon and trace elements can be derived using four different radionuclide pairs (238U:234Th ;210Pb:210Po; 228Ra:228Th; and 234U:230Th) at stations co‐located with sediment trap fluxes for comparison. Particulate organic carbon, particulate P, and particulate Cd fluxes all decrease sharply with depth below the euphotic zone. Particulate Mn, Cu, and Co flux profiles display mixed behavior, some cases reflecting biotic remineralization, and other cases showing increased flux with depth. The latter may be related to either lateral input of lithogenic material or increased scavenging onto particles. Lastly, particulate Fe fluxes resemble fluxes of Al and 232Th, which all have increasing flux with depth, indicating a dominance of lithogenic flux at depth by resuspended sediment transported laterally to the study site. In comparing flux estimates derived using different isotope pairs, differences result from different timescales of integration and particle size fractionation effects. The range in flux estimates produced by different methods provides a robust constraint on the true removal fluxes, taking into consideration the independent uncertainties associated with each method. These estimates will be valuable targets for biogeochemical modeling and may also offer insight into particle sinking processes.
    Description: This study grew out of a synthesis workshop at the Lamont‐Doherty Earth Observatory of Columbia University in August 2016. This workshop was sponsored by the U.S. GEOTRACES Project Office (NSF 1536294) and the Ocean Carbon and Biogeochemistry (OCP) Project Office (NSF 1558412 and NASA NNX17AB17G). The U.S. National Science Foundation supported all of the analytical work on GA03. Kuanbo Zhou measured 228Th in the large size class particles (NSF 0925158 to WHOI). NSF 1061128 to Stony Brook University supported the BaRFlux project, for which Chistina Heilbrun is acknowledged for laboratory and field work. The lead author acknowledges support from a start‐up grant from the University of Southern Mississippi. Two anonymous reviewers are thanked for their constructive comments. All GEOTRACES GA03 data used in this study are accessible through the Biological and Chemical Oceanography Data Management Office (http://data.bco‐dmo.org/jg/dir/BCO/GEOTRACES/NorthAtlanticTransect/), and derived parameters are reported in the supporting information.
    Description: 2019-05-22
    Keywords: Biological carbon pump ; Trace metals ; North Atlantic ; Export ; GEOTRACES
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  • 67
    Publication Date: 2022-10-26
    Description: © The Author(s), 2019. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Bodini, N., Lundquist, J. K., & Kirincich, A. US East Coast lidar measurements show offshore wind turbines will encounter very low atmospheric turbulence. Geophysical Research Letters, 46(10), (2019):5582-5591, doi:10.1029/2019GL082636.
    Description: The rapid growth of offshore wind energy requires accurate modeling of the wind resource, which can be depleted by wind farm wakes. Turbulence dissipation rate (ϵ) governs the accuracy of model predictions of hub‐height wind speed and the development and erosion of wakes. Here we assess the variability of turbulence kinetic energy and ϵ using 13 months of observations from a profiling lidar deployed on a platform off the Massachusetts coast. Offshore, ϵ is 2 orders of magnitude smaller than onshore, with a subtle diurnal cycle. Wind direction influences the annual cycle of turbulence, with larger values in winter when the wind flows from the land, and smaller values in summer, when the wind flows from open ocean. Because of the weak turbulence, wind plant wakes will be stronger and persist farther downwind in summer.
    Description: Collection of the wind data was funded by the Massachusetts Clean Energy Center through agreements with WHOI and AWS Truepower. The authors appreciate the efforts of the MVCO/ASIT technicians and AWS staff who collected the data. This analysis was supported by the National Science Foundation CAREER Award (AGS‐1554055) to J. K. L. and N. B., and by internal funds from WHOI for A. K. This work was authored (in part) by the National Renewable Energy Laboratory, operated by Alliance for Sustainable Energy, LLC, for the U.S. Department of Energy (DOE) under Contract DE‐AC36‐08GO28308. Funding was provided by the U.S. Department of Energy Office of Energy Efficiency and Renewable Energy Wind Energy Technologies Office. The views expressed in the article do not necessarily represent the views of the DOE or the U.S. Government. The U.S. Government retains and the publisher, by accepting the article for publication, acknowledges that the U.S. Government retains a nonexclusive, paid‐up, irrevocable, worldwide license to publish or reproduce the published form of this work, or allow others to do so, for U.S. Government purposes. The lidar observations used here are described at https://www.masscec.com/masscec-metocean-data-initiative, and available at https://doi.org/10.26025/1912/24050. The postprocessed data and the scripts used for the Figures of the present paper can be found at https://github.com/nicolabodini/GRL_OffshoreTurbulence.
    Description: 2019-11-01
    Keywords: Turbulence ; Offshore wind energy ; Lidar ; Wakes
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  • 68
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2019. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research-Oceans 124(4), (2019):2750-2768, doi: 10.1029/2018JC014635.
    Description: The advances in the modern sea level observing system have allowed for a new level of knowledge of regional and global sea level in recent years. The combination of data from satellite altimeters, Gravity Recovery and Climate Experiment (GRACE) satellites, and Argo profiling floats has provided a clearer picture of the different contributors to sea level change, leading to an improved understanding of how sea level has changed in the present and, by extension, may change in the future. As the overlap between these records has recently extended past a decade in length, it is worth examining the extent to which internal variability on timescales from intraseasonal to decadal can be separated from long‐term trends that may be expected to continue into the future. To do so, a combined modal decomposition based on cyclostationary empirical orthogonal functions is performed simultaneously on the three data sets, and the dominant shared modes of variability are analyzed. Modes associated with the trend, seasonal signal, El Niño–Southern Oscillation, and Pacific decadal oscillation are extracted and discussed, and the relationship between regional patterns of sea level change and their associated global signature is highlighted.
    Description: The satellite altimetry grids are available from NASA JPL/PO.DAAC at the following location: https://podaac.jpl.nasa.gov/dataset. GRACE land water storage data are available at http://grace.jpl.nasa.gov, supported by the NASA MEaSUREs Program. The gridded fields based on Argo data used to compute the steric sea level data are available at http://www.argo.ucsd.edu/Gridded_fields.html. The gridded fields based on Argo data used to compute the steric sea level data are available at http://www.argo.ucsd.edu/Gridded_fields.html. The research was carried out at the Jet Propulsion Laboratory, California Institute of Technology, under a contract with the National Aeronautics and Space Administration. B. D. H., F. W. L., J. T. R., and P. R. T. acknowledge support from NASA grant 80NSSC17K0564 (NASA Sea Level Change Team). C. G. P. acknowledges support from NSF awards OCE‐1558966 and OCE‐1834739. K. Y. K. was partially supported for this research by the National Science Foundation of Korea under the grant NRF‐ 2017R1A2B4003930.
    Description: 2019-09-21
    Keywords: Sea level ; Regional ; Global ; Variability
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  • 69
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2019. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research-Oceans 124(4), (2019):2861-2875, doi: 10.1029/2018JC014175.
    Description: Strong variability in sea surface salinity (SSS) in the Eastern Tropical Pacific (ETPac) on intraseasonal to interannual timescales was studied using data from the Soil Moisture and Ocean Salinity, Soil Moisture Active Passive, and Aquarius satellite missions. A zonal wave number‐frequency spectral analysis of SSS reveals a dominant timescale of 50–180 days and spatial scale of 8°–20° of longitude with a distinct seasonal cycle and interannual variability. This intraseasonal SSS signal is detailed in the study of 19 individual ETPac eddies over 2010–2016 identified by their sea level anomalies, propagating westward at a speed of about 17 cm/s. ETPac eddies trap and advect water in their core westward up to 40° of longitude away from the coast. The SSS signatures of these eddies, with an average anomaly of 0.5‐pss magnitude difference from ambient values, enable the study of their dynamics and the mixing of their core waters with the surroundings. Three categories of eddies were identified according to the location where they were first tracked: (1) in the Gulf of Tehuantepec, (2) in the Gulf of Papagayo, and (3) in the open ocean near 100°W–12°N. They all traveled westward near 10°N latitude. Category 3 is of particular interest, as eddies seeded in the Gulf of Tehuantepec grew substantially in the vicinity of the Clipperton Fracture Zone rise and in a region where the mean zonal currents have anticyclonic shear. The evolution of the SSS signature associated with the eddies indicates the importance of mixing to their dissipation.
    Description: This research was carried out in part at the Jet Propulsion Laboratory (JPL), California Institute of Technology, under a contract with NASA and part at LOCEAN (Sorbonne Université, CNRS, IRD, MNHN) under a CNES Postdoctoral fellowship. This work is supported by NASA Grants NNX11AE83G and NNX14AH38G and is a contribution to the TOSCA/SMOS‐Ocean proposal supported by CNES. We thank the reviewers for their thoughtfully comments that lead to a much‐improved manuscript. We benefited from numerous data sets made freely available and are listed here: The SMOS debias_v2 SSS have been produced by LOCEAN laboratory and ACRI‐st company that participate to the Ocean Salinity Expertise Center (CEC‐OS) of Centre Aval de Traitement des Donnees SMOS (CATDS). of CATDS at IFREMER, Plouzane, France (http://www.catds.fr/Products, see documentation: http://www.catds.fr/Products/Available‐products‐from‐CEC‐OS/L3‐Debiased‐Locean‐v2); the Aquarius/SAC‐D and SMAP data was produced by Remote Sensing Systems and distributed by PODAAC (https://podaac.jpl.nasa.gov/dataset/AQUARIUS_L3_SSS_SMI_7DAY_V4; https://podaac.jpl.nasa.gov/dataset/SMAP_RSS_L3_SSS_SMI_8DAY‐RUNNINGMEAN_V2); the SLA product is processed and distributed by CMEMS (http://marine.copernicus.eu); the global atlas of eddies is produced by AVISO (https://www.aviso.altimetry.fr/en/data/products/value‐added‐products/global‐mesoscale‐eddy‐trajectory‐product.html); the GPCP precipitation data set (http://eagle1.umd.edu/GPCP_CDR/Monthly_Data) is described in the project technical report (http://eagle1.umd.edu/GPCP_ICDR/GPCPmonthlyV2.3.pdf); Woods Hole Oceanographic Institution OAFlux evaporation data set (ftp://ftp.whoi.edu/pub/science/oaflux/data_v3); UCAR high‐resolution terrain data set (High res terrain data set https://rda.ucar.edu/datasets/ds759.2/#!description); Chelton et al. (1998) Global Atlas of the First‐Baroclinic Rossby Radius of Deformation and Gravity‐Wave Phase Speed (http://www‐po.coas.oregonstate.edu/research/po/research/rossby_radius/).
    Description: 2019-09-28
    Keywords: Eddies ; Mesoscale ; Salinity ; Pacific
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  • 70
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2019. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters, 46(8), (2019):4346-4355, doi:10.1029/2018GL081577.
    Description: A yearlong record from moored current, temperature, conductivity, and four mixing meters (χpods) in the northernmost international waters of the Bay of Bengal quantifies upper‐ocean turbulent diffusivity of heat (Kt) and its response to the Indian monsoon. Data indicate (1) pronounced intermittency in turbulence at semidiurnal, diurnal, and near‐inertial timescales, (2) strong turbulence above 25‐m depth during the SW (summer) and NE (winter) monsoon relative to the transition periods (compare Kt 〉 10−4 m2/s to Kt  ∼ 10−5 m2/s, and (3) persistent suppression of turbulence (Kt 〈 10−5 m2/s) for 3 to 5 months in the latter half of the SW monsoon coincident with enhanced near‐surface stratification postarrival of low‐salinity water from the Brahmaputra‐Ganga‐Meghna delta and monsoonal precipitation. This suppression promotes maintenance of the low‐salinity surface waters within the interior of the bay preconditioning the upper northern Indian Ocean for the next year's monsoon.
    Description: This work was supported by the U.S. Office of Naval Research (ONR) Grants N00014‐14‐1‐0236 and N00014‐17‐1‐2472, and the Ocean Mixing and Monsoon program of the Indian Ministry of Earth Sciences. The deployment of the Woods Hole Oceanographic Institution mooring and RW and JTF were supported by ONR Grant N00014‐13‐1‐0453. The deployment and recovery of the mooring were carried out by RV Sagar Nidhi and RV Sagar Kanya, respectively, with the help of the crew and science parties. Thanks to National Institute of Ocean Technology (India) for buoy support. The authors acknowledge invaluable discussions with Johannes Becherer, Deepak Cherian, and Sally Warner at CEOAS, OSU, and Dipanjan Chaudhuri, J Sree Lekha, and Debasis Sengupta at CAOS, IISc. The authors thank two anonymous reviewers for their detailed reviews, which have helped sharpen many aspects of this paper. Data can be accessed as described in section S2.
    Description: 2019-10-08
    Keywords: Ocean turbulence ; Turbulence suppression ; Indian Monsoon ; Bay of Bengal ; Turbulent Mixing ; Chipod
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  • 71
    Publication Date: 2022-10-26
    Description: © The Author(s), 2019. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Baltar, F., Bayer, B., Bednarsek, N., Deppeler, S., Escribano, R., Gonzalez, C. E., Hansman, R. L., Mishra, R. K., Moran, M. A., Repeta, D. J., Robinson, C., Sintes, E., Tamburini, C., Valentin, L. E., & Herndl, G. J. Towards integrating evolution, metabolism, and climate change studies of marine ecosystems. Trends in Ecology and Evolution. 34(11), (2019): 1022-1033, doi: 10.1016/j.tree.2019.07.003.
    Description: Global environmental changes are challenging the structure and functioning of ecosystems. However, a mechanistic understanding of how global environmental changes will affect ecosystems is still lacking. The complex and interacting biological and physical processes spanning vast temporal and spatial scales that constitute an ecosystem make this a formidable problem. A unifying framework based on ecological theory, that considers fundamental and realized niches, combined with metabolic, evolutionary, and climate change studies, is needed to provide the mechanistic understanding required to evaluate and forecast the future of marine communities, ecosystems, and their services.
    Description: This work arose from the international workshop IMBIZO 5: Marine biosphere research for a sustainable ocean: Linking ecosystems, future states and resource management, organized by the IMBeR (Integrated Marine Biosphere Research) Program, and held at the Woods Hole Oceanographic Institution in October 2017. In particular, this work was generated from the working group from Workshop 2: Metabolic diversity and evolution in marine biogeochemical cycling and ocean ecosystem processes. The constructive criticism of three reviewers on a previous version of the manuscript is gratefully acknowledged. F.B. was supported by a Rutherford Discovery Fellowship by the Royal Society of New Zealand. G.J.H. was supported by the Austrian Science Fund (FWF) project ARTEMIS (P28781-B21).
    Keywords: Marine ecosystems ; Niche ; Evolution ; Metabolism ; Climate change
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  • 72
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2019. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research-Solid Earth 124(5), (2019): 4710-4727, doi:10.1029/2018JB017080.
    Description: The southernmost Mariana margin lacks a mature island arc and thus differs significantly from the central‐north Mariana and Izu‐Bonin margins. This paper presents a new P wave velocity model of the crust and uppermost mantle structure based on a 349‐km‐long profile of wide‐angle reflection/refraction data. The active source seismic experiment was conducted from the subducting Pacific plate to the overriding Philippine plate, passing through the Challenger Deep. The subducting plate has an average crustal thickness of ~6.0 km with Vp of 7.0 ± 0.2 km/s at the base of the crust and low values of only 5.5–6.9 km/s near the trench axis. The uppermost mantle of the subducting plate is characterized by low velocities of 7.0–7.3 km/s. The overriding plate has a maximum crustal thickness of ~18 km beneath the forearc with Vp of ~7.4 km/s at the crustal bottom and 7.5–7.8 km/s in the uppermost mantle. A zone of slight velocity reduction is imaged beneath the Southwest Mariana Rift that is undergoing active rifting. The observed significant velocity reduction in a near‐trench crustal zone of ~20–30 km in the subducting plate is interpreted as a result of faulting‐induced porosity changes and fracture‐filling fluids. The velocity reduction in the uppermost mantle of both subducting and overriding plates is interpreted as mantle serpentinization with fluid sources from dehydration of the subducting plate and/or fluid penetration along faults.
    Description: Data acquisition and sample collections were supported by the Mariana Trench Initiative of the Chinese Academy of Sciences (CAS). We are grateful to the science parties and crews of R/V Shiyan 3 of the South China Sea Institute of Oceanology, CAS, for contributions to data acquisition. Constructive reviews by Robert Stern, Martha Savage, and anonymous reviewers significantly improved the manuscript. We thank Gaohua Zhu, Fan Zhang, Chunfeng Li, Zhen Sun, Zhi Wang, and Minghui Zhao for helpful discussion. The bathymetric maps were plotted using GMT (Wessel & Smith, 1995). Digital files of the velocity models and selected raw data are deposited and accessible online (at https://pan.baidu.com/s/1AbDJOgLZhYn1C‐3sg7S9Xw). This work was supported by the Strategic Priority Program of CAS (XDA13010101), CAS (Y4SL021001, QYZDY‐SSW‐DQC005, and 133244KYSB20180029), Key Laboratory of Ocean and Marginal Sea Geology, CAS (OMG18‐03), National Natural Science Foundation of China (41890813, 41676042, U1701641, 91628301, 41576041, and U1606401), and HKSAR Research Grant Council grants (14313816).
    Description: 2019-10-05
    Keywords: Arc rifting ; Plate hydration ; Southernmost Mariana Trench ; Seismic tomography
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  • 73
    Publication Date: 2022-10-26
    Description: © The Author(s), 2019. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in DeGrandpre, M. D., Lai, C., Timmermans, M., Krishfield, R. A., Proshutinsky, A., & Torres, D. Inorganic carbon and pCO(2) variability during ice formation in the Beaufort Gyre of the Canada Basin. Journal of Geophysical Research-Oceans, 124(6), (2019): 4017-4028, doi:10.1029/2019JC015109.
    Description: Solute exclusion during sea ice formation is a potentially important contributor to the Arctic Ocean inorganic carbon cycle that could increase as ice cover diminishes. When ice forms, solutes are excluded from the ice matrix, creating a brine that includes dissolved inorganic carbon (DIC) and total alkalinity (AT). The brine sinks, potentially exporting DIC and AT to deeper water. This phenomenon has rarely been observed, however. In this manuscript, we examine a ~1 year pCO2 mooring time series where a ~35‐μatm increase in pCO2 was observed in the mixed layer during the ice formation period, corresponding to a simultaneous increase in salinity from 27.2 to 28.5. Using salinity and ice based mass balances, we show that most of the observed increases can be attributed to solute exclusion during ice formation. The resulting pCO2 is sensitive to the ratio of AT and DIC retained in the ice and the mixed layer depth, which controls dilution of the ice‐derived AT and DIC. In the Canada Basin, of the ~92 μmol/kg increase in DIC, 17 μmol/kg was taken up by biological production and the remainder was trapped between the halocline and the summer stratified surface layer. Although not observed before the mooring was recovered, this inorganic carbon was likely later entrained with surface water, increasing the pCO2 at the surface. It is probable that inorganic carbon exclusion during ice formation will have an increasingly important influence on DIC and pCO2 in the surface of the Arctic Ocean as seasonal ice production and wind‐driven mixing increase with diminishing ice cover.
    Description: Research Associate Cory Beatty (University of Montana) prepared the CO2 instruments and helped with the mooring deployments and data processing. Pierce Fix (undergraduate intern, University of Montana) helped with the mass balance modeling. The moorings were designed and deployed by personnel at Woods Hole Oceanographic Institution. Michiyo Yamamoto‐Kawai (University of Tokyo) and Marty Davelaar (Institute of Ocean Sciences; IOS) provided the alkalinity and dissolved inorganic carbon data. We thank the captain, officers, crew, and chief scientists (Bill Williams and Sarah Zimmerman, IOS) of the CCGS Louis S. St. Laurent. The data used in this study are available through the U.S. National Science Foundation (NSF) Arctic Data Center (https://arcticdata.io). This research was made possible by grants from the NSF Arctic Observing Network program (ARC‐1107346, PLR‐1302884, PLR‐1504410, and PLR‐1723308).
    Keywords: Sea ice ; Dissolved inorganic carbon ; Carbon cycle ; Solute exclusion ; Partial pressure of CO2 ; Arctic Ocean
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  • 74
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2019. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Paleoceanography and Paleoclimatology, 34(7), (2019): 1218-1233, doi:10.1029/2018PA003537.
    Description: The last deglaciation (~20–10 kyr BP) was characterized by a major shift in Earth's climate state, when the global mean surface temperature rose ~4 °C and the concentration of atmospheric CO2 increased ~80 ppmv. Model simulations suggest that the initial 30 ppmv rise in atmospheric CO2 may have been driven by reduced efficiency of the biological pump or enhanced upwelling of carbon‐rich waters from the abyssal ocean. Here we evaluate these hypotheses using benthic foraminiferal B/Ca (a proxy for deep water [CO32−]) from a core collected at 1,100‐m water depth in the Southwest Atlantic. Our results imply that [CO32−] increased by 22 ± 2 μmol/kg early in Heinrich Stadial 1, or a decrease in ΣCO2 of approximately 40 μmol/kg, assuming there were no significant changes in alkalinity. Our data imply that remineralized phosphate declined by approximately 0.3 μmol/kg during Heinrich Stadial 1, equivalent to 40% of the modern remineralized signal at this location. Because tracer inversion results indicate remineralized phosphate at the core site reflects the integrated effect of export production in the sub‐Antarctic, our results imply that biological productivity in the Atlantic sector of the Southern Ocean was reduced early in the deglaciation, contributing to the initial rise in atmospheric CO2.
    Description: We would like to thank Bärbel Hönisch at Lamont‐Doherty Earth Observatory of Columbia University for help with methods development and Sarah McCart for technical assistance with ICP‐MS analyses. We would also like to give special thanks to Anna lisa Mudahy, who was responsible for picking a substantial portion of the benthic foraminifera used in this study. We are grateful to the WHOI core lab for sample collection and archiving. This work was supported by NSF grant OCE‐1702231 to D. L.
    Description: 2020-01-24
    Keywords: B/Ca ; Last deglaciation ; Carbon cycling
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  • 75
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2019. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 46(12), (2019): 6745-6754, doi:10.1029/2019GL082867.
    Description: Although photochemical oxidation is an environmental process that drives organic carbon (OC) cycling, its quantitative detection remains analytically challenging. Here, we use samples from the Deepwater Horizon oil spill to test the hypothesis that the stable oxygen isotope composition of oil (δ18OOil) is a sensitive marker for photochemical oxidation. In less than one‐week, δ18OOil increased from −0.6 to 7.2‰, a shift representing ~25% of the δ18OOC dynamic range observed in nature. By accounting for different oxygen sources (H2O or O2) and kinetic isotopic fractionation of photochemically incorporated O2, which was −9‰ for a wide range of OC sources, a mass balance was established for the surface oil's elemental oxygen content and δ18O. This δ18O‐based approach provides novel insights into the sources and pathways of hydrocarbon photo‐oxidation, thereby improving our understanding of the fate and transport of petroleum hydrocarbons in sunlit waters, and our capacity to respond effectively to future spills.
    Description: We thank Robert Ricker and Greg Baker (NOAA) for helping secure the oil residues, James Payne (Payne Environmental Consultants, Inc.) for collecting many of the surface oil residues, Joy Matthews (UC Davis) for exceptional assistance in preparing and analyzing the oil residues for oxygen content and isotopes, Hank Levi and Art Gatenby at CSC Scientific Company for assistance with the water content measurements, Robyn Comny (US EPA) for providing the Alaska North Slope oil, and Rose Cory (UMich) for discussions about our findings. Special thanks to John Hayes who provided constructive feedback on a preliminary version of this dataset prior to his passing in February of 2017. We thank Alex Sessions (CalTech) for his constructive feedback during the review process. This work was supported, in part, by National Science Foundation grants RAPID OCE‐1043976 (CMR), OCE‐1333148 (CMR), OCE‐1333026 (CMS), OCE‐1333162 (DLV), OCE‐1841092 (CPW), NASA NESSF NNX15AR62H (KMS), the Gulf of Mexico Research Initiative grants ‐ 015, SA 16‐30, and DEEP‐C consortium, a fellowship through the Hansewissenschaftskolleg (Institute for Advanced Studies) to SDW, and assistant scientist salary support from the Frank and Lisina Hoch Endowed Fund (CPW).
    Description: 2019-11-30
    Keywords: Petroleum hydrocarbons ; Photochemical oxidation ; Deepwater Horizon ; Stable oxygen isotopes ; Organic carbon
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  • 76
    Publication Date: 2022-10-26
    Description: © The Author(s), 2019. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Selden, C. R., Mulholland, M. R., Bernhardt, P. W., Widner, B., Macias-Tapia, A., Ji, Q., & Jayakumar, A. Dinitrogen fixation across physico-chemical gradients of the Eastern Tropical North Pacific oxygen deficient zone. Global Biogeochemical Cycles, 33, (2019): 1187-1202, doi:10.1029/2019GB006242.
    Description: The Eastern Tropical North Pacific Ocean hosts one of the world's largest oceanic oxygen deficient zones (ODZs). Hot spots for reactive nitrogen (Nr) removal processes, ODZs generate conditions proposed to promote Nr inputs via dinitrogen (N2) fixation. In this study, we quantified N2 fixation rates by 15N tracer bioassay across oxygen, nutrient, and light gradients within and adjacent to the ODZ. Within subeuphotic oxygen‐deplete waters, N2 fixation was largely undetectable; however, addition of dissolved organic carbon stimulated N2 fixation in suboxic (〈20 μmol/kg O2) waters, suggesting that diazotroph communities are likely energy limited or carbon limited and able to fix N2 despite high ambient concentrations of dissolved inorganic nitrogen. Elevated rates (〉9 nmol N·L−1·day−1) were also observed in suboxic waters near volcanic islands where N2 fixation was quantifiable to 3,000 m. Within the overlying euphotic waters, N2 fixation rates were highest near the continent, exceeding 500 μmol N·m−2·day−1 at one third of inshore stations. These findings support the expansion of the known range of diazotrophs to deep, cold, and dissolved inorganic nitrogen‐replete waters. Additionally, this work bolsters calls for the reconsideration of ocean margins as important sources of Nr. Despite high rates at some inshore stations, regional N2 fixation appears insufficient to compensate for Nr loss locally as observed previously in the Eastern Tropical South Pacific ODZ.
    Description: We gratefully acknowledge the efforts of the captain and crew of the NOAA vessel Ronald H. Brown and the scientists who participated in the collection and analysis of the data presented here, particularly Shannon Cofield, Wei Yan, Nicole Travis, and Matt Forbes. We thank the Monterey Bay Aquatic Research Institute for the use of their pump profiling system and Margeurite Blum for her expertise in its use. Finally, we thank Bess Ward for the use of her facilities at Princeton University. This work was supported by the National Science Foundation Division of Ocean Sciences (NSF‐OCE) Grant OCE‐1356056 to M. R. M. and A. J. Data will be made available at the website (https://www.bco‐dmo.org/project/472492). The authors declare no conflicts of interest.
    Keywords: Nitrogen fixation ; Oxygen deficient zone ; Eastern tropical pacific ; Diazotroph ; Oxygen minimum zone ; Aphotic
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  • 77
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2019. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research-Solid Earth 124 (2019): 9980– 9998, doi:10.1029/2019JB017584.
    Description: Macrostructures preserved in deformed rocks are essential for the understanding of their evolution, especially when the deformation is weak and hard to discriminate in regional scale or purely through geophysical data. In order to resolve the inconsistency between NS trending fracture zones and NE oriented spreading fabrics of the South China Sea during the latest spreading stage, we analyzed macrostructures identifiable from the basalt and consolidated sediment samples of the Integrated Ocean Drilling Program (IODP) Sites U1431 and U1433. These two sites are close to the East and Southwest relict spreading ridges and provide critical information on the latest spreading stages. The structures in the basalt of both sites suggest two dominant orientations of NS and NE. At U1431, sediments show mainly WNW trending slickensides, different from that of basalt. At U1433, no structures were found in postspreading sediment. Thus, NE and NS trending structures in basalt are most possibly formed by seafloor spreading. Crosscutting relationship suggests that NE trending structures formed first, followed by NS and finally WNW trending structures. These observations are consistent with geophysical features. Magnetic anomalies and ocean bottom seismometer velocity suggest that the latest relict ridge of the East Subbasin coincides with the EW trending seamount chain. Located between the relict ridges of East and Southwest Subbasins, NS trending Zhongnan‐Liyue Fracture Zone had acted as the latest transform fault. Based on the above evidences, we proposed that the South China Sea may have experienced a short period of NS oriented spreading after earlier SE spreading. These results resolve the previous inconsistencies.
    Description: We appreciate Anne Replumaz and other anonymous reviewers for the constructive suggestions, which improve this paper to a great extent. This research was supported by Guangdong NSF research team project (2017A030312002), K. C. Wong Education Foundation (GJTD‐2018‐13), the IODP‐China Foundation, the NSFC Projects (91628301, 41376027, 41576070, 41576068, 41430962, 41674069, 91528302, and 20153410), U.S. National Science Foundation through Grant EAR‐1250444, the Guangdong Province Foundation (41576068), and the Joint Foundation of the Natural Science Foundation of China (NSFC) and Guangdong Province (U1301233). Fucheng Li is thanked for helping with the earthquake epicenter figure for the study area. All the sample photos can be accessed via web address (http://www.iodp.tamu.edu). The archive halves of samples are kept in the Kochi repository. The paleomag data will be published by Xixi Zhao separately. All the other geophysical data have been published; for example, the multichannel seismic could be referenced to Li et al. (2015a), and the gravity data and magnetic anomaly data are from Sandwell et al. (2014) and Ishihara and Kisimoto (1996).
    Description: 2020-02-29
    Keywords: Macrostructure analysis ; Marine gravity anomaly ; Marine magnetic anomaly ; Latest spreading history ; IODP Expedition 349 ; South China Sea
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  • 78
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2019. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 20(7), (2019): 3347-3374, doi:10.1029/2019GC008374.
    Description: Subduction is a key component of Earth's long‐term sulfur cycle; however, the mechanisms that drive sulfur from subducting slabs remain elusive. Isotopes are a sensitive indicator of the speciation of sulfur in fluids, sulfide dissolution‐precipitation reactions, and inferring fluid sources. To investigate these processes, we report δ34S values determined by secondary ion mass spectroscopy in sulfides from a global suite of exhumed high‐pressure rocks. Sulfides are classified into two petrogenetic groups: (1) metamorphic, which represent closed‐system (re)crystallization from protolith‐inherited sulfur, and (2) metasomatic, which formed during open system processes, such as an influx of oxidized sulfur. The δ34S values for metamorphic sulfides tend to reflect their precursor compositions: −4.3 ‰ to +13.5 ‰ for metabasic rocks, and −32.4 ‰ to −11.0 ‰ for metasediments. Metasomatic sulfides exhibit a range of δ34S from −21.7 ‰ to +13.9 ‰. We suggest that sluggish sulfur self‐diffusion prevents isotopic fractionation during sulfide breakdown and that slab fluids inherit the isotopic composition of their source. We estimate a composition of −11 ‰ to +8 ‰ for slab fluids, a significantly smaller range than observed for metasomatic sulfides. Large fractionations during metasomatic sulfide precipitation from sulfate‐bearing fluids, and an evolving fluid composition during reactive transport may account for the entire ~36 ‰ range of metasomatic sulfide compositions. Thus, we suggest that sulfates are likely the dominant sulfur species in slab‐derived fluids.
    Description: All isotopic data and analysis locations are detailed in the supporting information accompanying this article. The authors would like to thank B. Monteleone and M. Yates for assistance with SIMS and EPMA analyses, respectively. J. Selverstone is thanked for providing samples and D. Whitney for providing additional field context. The authors would also like to thank J. Alt, C. LaFlamme, and an anonymous reviewer for their thoughtful and thorough reviews, as well as careful editorial handling by J. Blichert‐Toft. This project was funded by National Science Foundation Grant EAR 1725301 awarded to A. M. C. and a Geological Society of America grant to J. B. W.
    Description: 2019-12-14
    Keywords: Sulfur isotopes ; Subduction ; Sulfur cycle ; Sulfur ; Volcanic arc ; Metamorphism
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  • 79
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2019. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 46(14), (2019): 8572-8581, doi: 10.1029/2019GL083039.
    Description: As Arctic temperatures rise at twice the global rate, sea ice is diminishing more quickly than models can predict. Processes that dictate Arctic cloud formation and impacts on the atmospheric energy budget are poorly understood, yet crucial for evaluating the rapidly changing Arctic. In parallel, warmer temperatures afford conditions favorable for productivity of microorganisms that can effectively serve as ice nucleating particles (INPs). Yet the sources of marine biologically derived INPs remain largely unknown due to limited observations. Here we show, for the first time, how biologically derived INPs were likely transported hundreds of kilometers from deep Bering Strait waters and upwelled to the Arctic Ocean surface to become airborne, a process dependent upon a summertime phytoplankton bloom, bacterial respiration, ocean dynamics, and wind‐driven mixing. Given projected enhancement in marine productivity, combined oceanic and atmospheric transport mechanisms may play a crucial role in provision of INPs from blooms to the Arctic atmosphere.
    Description: We sincerely thank the U.S. Coast Guard and crew of the Healy for assistance with equipment installation and guidance, operation of the underway and CTD systems, and general operation of the vessel during transit and at targeted sampling stations. We would also like to thank Allan Bertram, Meng Si, Victoria Irish, and Benjamin Murray for providing INP data from their previous studies. J. M. C., R. P., P. L., L. T., and E. B. were funded by the National Oceanic and Atmospheric Administration (NOAA)’s Arctic Research Program. J. C. was supported by the NOAA Experiential Research & Training Opportunities (NERTO) program. T. A. and N. C. were supported through the NOAA Earnest F. Hollings Scholarship program. A. P. was funded by the National Science Foundation under Grant PLR‐1303617. Russel C. Schnell and Michael Spall are acknowledged for insightful discussions during data analysis and interpretation. There are no financial conflicts of interest for any author. INP data are available in the supporting information, while remaining DBO‐NCIS data presented in the manuscript are available online (at https://www2.whoi.edu/site/dboncis/).
    Description: 2020-01-15
    Keywords: Arctic ; Ice nucleation ; Phytoplankton bloom ; Aerosol‐cloud interactions ; Arctic aerosol
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  • 80
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2019. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research-Oceans 124(8), (2019): 5723-5746, doi:10.1029/2018JC014453.
    Description: Estimates of the kinetic energy transfer from the wind to the ocean are often limited by the spatial and temporal resolution of surface currents and surface winds. Here we examine the wind work in a pair of global, very high‐resolution (1/48° and 1/24°) MIT general circulation model simulations in Latitude‐Longitude‐polar Cap (LLC) configuration that provide hourly output at spatial resolutions of a few kilometers and include tidal forcing. A cospectrum analysis of wind stress and ocean surface currents shows positive contribution at large scales (〉300 km) and near‐inertial frequency and negative contribution from mesoscales, tidal frequencies, and internal gravity waves. Larger surface kinetic energy fluxes are in the Kuroshio in winter at large scales (40 mW/m2) and mesoscales (−30 mW/m2). The Kerguelen region is dominated by large scale (∼20 mW/m2), followed by inertial oscillations in summer (13 mW/m2) and mesoscale in winter (−12 mW/m2). Kinetic energy fluxes from internal gravity waves (−0.1 to −9.9 mW/m2) are generally stronger in summer. Surface kinetic energy fluxes in the LLC simulations are 4.71 TW, which is 25–85% higher than previous global estimates from coarser (1/6–1/10°) general ocean circulation models; this is likely due to improved representation of wind variability (6‐hourly, 0.14°, operational European Center for Medium‐Range Weather Forecasts). However, the low wind power input to the near‐inertial frequency band obtained with LLC (0.16 TW) compared to global slab models suggests that wind variability on time scales less than 6 hr and spatial scales less than 15 km are critical to better representing the wind power input in ocean circulation models.
    Description: We thank three anonymous reviewers for their helpful comments that led to an improved manuscript. We are grateful to Jörn Callies and Laurie Padman for fruitful discussions. This work is funded by the National Aeronautics and Space Administration (NASA) through the project “Towards improved estimates of upper ocean energetics: Science motivation for the simultaneous measurement of ocean surface vector winds and currents” (Grant NNX15AG42G) and through NASA Grant NNX14AM71G and NNX16AH76G. Model output from global 1/48° and 1/24° ECCO2 MITgcm simulations is freely available to the community. For access of the full solutions, we recommend that users apply for an HEC account at NASA Ames. Data are provided online (∼dmenemen/llc/). Users without a NASA Ames account may explore what is available online (https://data.nas.nasa.gov/ecco/). This work was, in part, performed at the Jet Propulsion Laboratory, California Institute of Technology, under contract with the National Aeronautics and Space Administration. Color maps used in this contribution are from Thyng et al. (2016). To Teresa and Francesc, for their patience.
    Keywords: Surface fluxes ; Inertial oscillations ; Wind power ; Kinetic energy budget ; Global ocean model ; MITgcm
    Repository Name: Woods Hole Open Access Server
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  • 81
    Publication Date: 2022-10-21
    Description: Author Posting. © American Geophysical Union, 2019. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research-Oceans 124(7), (2019): 4605-4617, doi: 10.1029/2018JC014928.
    Description: We report the significant impact of near‐inertial waves (NIWs) on vertical mixing and air‐sea carbon dioxide (CO2) fluxes in the Southern Ocean using a biogeochemical model coupled to an eddy‐rich ocean circulation model. The effects of high‐frequency processes are quantified by comparing the fully coupled solution (ONLINE) to two offline simulations based on 5‐day‐averaged output of the ONLINE simulation: one that uses vertical mixing archived from the ONLINE model (CTRL) and another in which vertical mixing is recomputed from the 5‐day average hydrodynamic fields (5dAVG). In this latter simulation, processes with temporal variabilities of a few days including NIWs are excluded in the biogeochemical simulation. Suppression of these processes reduces vertical shear and vertical mixing in the upper ocean, leading to decreased supply of carbon‐rich water from below, less CO2 outgassing in austral winter, and more uptake in summer. The net change amounts up to one third of the seasonal variability in Southern Ocean CO2 flux. Our results clearly demonstrate the importance of resolving high‐frequency processes such as NIWs to better estimate the carbon cycle in numerical model simulations.
    Description: The MITgcm can be obtained from http://mitgcm.org website. Resources supporting this work were provided by the NASA High‐End Computing (HEC) Program through the NASA Advanced Supercomputing (NAS) Division at Ames Research Center with the Award SMD‐15‐5752. H. S., J. M., and D. J. M. were supported by the NSF MOBY project (OCE‐1048926 and OCE‐1048897). H. S. acknowledges the support by National Research Foundation of Korea (NRF) grant (NRF‐2019R1C1C1003663) and Yonsei University Research Fund of 2018‐22‐0053. D. J. M. also gratefully acknowledges NASA support.
    Description: 2019-12-17
    Keywords: Southern Ocean ; near‐inertial waves ; CO2 ; vertical mixing
    Repository Name: Woods Hole Open Access Server
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  • 82
    Publication Date: 2023-02-21
    Description: Author Posting. © American Geophysical Union, 2019. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research-Oceans 124(8), (2019): 5313-5335, doi:10.1029/2019JC015014.
    Description: The Lagrangian method—where current location and intensity are determined by tracking the movement of flow along its path—is the oldest technique for measuring the ocean circulation. For centuries, mariners used compilations of ship drift data to map out the location and intensity of surface currents along major shipping routes of the global ocean. In the mid‐20th century, technological advances in electronic navigation allowed oceanographers to continuously track freely drifting surface buoys throughout the ice‐free oceans and begin to construct basin‐scale, and eventually global‐scale, maps of the surface circulation. At about the same time, development of acoustic methods to track neutrally buoyant floats below the surface led to important new discoveries regarding the deep circulation. Since then, Lagrangian observing and modeling techniques have been used to explore the structure of the general circulation and its variability throughout the global ocean, but especially in the Atlantic Ocean. In this review, Lagrangian studies that focus on pathways of the upper and lower limbs of the Atlantic Meridional Overturning Circulation (AMOC), both observational and numerical, have been gathered together to illustrate aspects of the AMOC that are uniquely captured by this technique. These include the importance of horizontal recirculation gyres and interior (as opposed to boundary) pathways, the connectivity (or lack thereof) of the AMOC across latitudes, and the role of mesoscale eddies in some regions as the primary AMOC transport mechanism. There remain vast areas of the deep ocean where there are no direct observations of the pathways of the AMOC.
    Description: The authors extend their thanks to Xiaobiao Xu for valuable comments on the first draft of this manuscript. A. B. (WHOI), H. F., M. S. L., N. F., and K. D. were supported by Overturning in the Subpolar North Atlantic Program grants OCE‐1259618, OCE‐1259013, and OCE‐1259102 from the U.S. National Science Foundation. S. Z. was supported by the Climate Program Office of the National Oceanic and Atmospheric Administration under award NA16OAR4310168. M. L. was supported through the MOVE project, funded by NOAA's Global Ocean Monitoring and Observing Program under award NA15OAR4320071. A. B. (GEOMAR) and S. R. received funding from the Cluster of Excellence 80 “The Future Ocean” within the framework of the Excellence Initiative by the Deutsche Forschungsgemeinschaft (DFG) on behalf of the German federal and state governments (grant CP1412) and by the German Federal Ministry of Education and Research (BMBF) for the SPACES projects AGULHAS (grant 03F0750A) and CASISAC (grant 03F0796A). No new data are reported in this project. The data mentioned in the text may be found in repositories cited in each previously published paper cited in this review manuscript.
    Keywords: Floats ; Drifters ; Lagrangian methods ; AMOC ; Atlantic Ocean ; Numerical models
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  • 83
    Publication Date: 2022-07-04
    Description: Differentiating thermokarst basin sediments with respect to the involved processes and environmental conditions is an important tool to understand permafrost landscape dynamics and scenarios and future trajectories in a warming Arctic and Subarctic. Thermokarst basin deposits have complex sedimentary structures due to the variability of Yedoma source sediments, reworking during the Late Glacial to Holocene climate changes, and different stages of thermokarst history. Here we reconstruct the dynamic growth of thermokarst lakes and basins and related changes of depositional conditions preserved in sediment sequences using a combination of biogeochemical data and robust grain-size endmember analysis (rEMMA). This multi-proxy approach is used on 10 sediment cores (each 300–400 cm deep) from two key thermokarst sites to distinguish four time slices that describe the Holocene thermokarst (lake) basin evolution in Central Yakutia (CY). Biogeochemical proxies and rEMMA reveal fine-grained sedimentation with rather high lake levels and/or reducing conditions, and coarse-grained sedimentation with rather shallow lake levels and/or oxidizing (i.e. terrestrial) conditions in relation to distal and proximal depositional and post-sedimentary conditions. Statistical analysis suggests that the biogeochemical parameters are almost independent of thermokarst deposit sedimentology. Thus, the biogeochemical parameters are considered as signals of secondary (post-sedimentary) reworking. The rEMMA results are clearly reflecting grain-size variations and depositional conditions. This indicates small-scale varying depositional environments, frequently changing lake levels, and predominantly lateral expansion at the edges of rapidly growing small thermokarst lakes and basins. These small bodies finally coalesced, forming the large thermokarst basins we see today in CY. Considering previous paleoenvironmental reconstructions in Siberia, we show the initiation of thaw and subsidence during the Late Glacial to Holocene transition between about 11 and 9 cal kyrs BP, intensive and extensive thermokarst activity for the Holocene Thermal Maximum (HTM) at about 7 to 5 cal kyrs BP, severely fluctuating water levels and further lateral basin growth between 3.5 cal kyrs BP and 1.5 cal kyrs BP, and the cessation of thermokarst activity and extensive frost-induced processes (i.e. permafrost aggradation) after about 1.5 cal kyrs BP. However, gradual permafrost warming over recent decades, in addition to human impacts, has led to renewed high rates of subsidence and abrupt, rapid CY thermokarst processes.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , NonPeerReviewed , info:eu-repo/semantics/article
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  • 84
    Publication Date: 2022-08-31
    Description: Author Posting. © American Geophysical Union, 2018. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry, Geophysics, Geosystems 19(11), (2018): 4218-4235. doi: 10.1029/2018GC007654
    Description: Hydrocarbon migration and emplacement processes remain underconstrained despite the vast potential economic value associated with oil and gas. Noble gases provide information about hydrocarbon generation, fluid migration pathways, reservoir conditions, and the relative volumes of oil versus water in the subsurface. Produced gas He‐Ne‐Ar‐Kr‐Xe data from two distinct oil fields in the Gulf of Mexico (Genesis and Hoover‐Diana) are used to calibrate a model that takes into account both water‐oil solubility exchange and subsequent gas cap formation. Reconstructed noble gas signatures in oils reflect simple (two‐phase) oil‐water exchange imparted during migration from the source rock to the trap, which are subsequently modified by gas cap formation at current reservoir conditions. Calculated, oil to water volume ratios (Vo/Vw) in Tertiary‐sourced oils from the Hoover‐Diana system are 2–3 times greater on average than those in the Jurassic sourced oils from the Genesis reservoirs. Higher Vo/Vw in Hoover‐Diana versus Genesis can be interpreted in two ways: either (1) the Hoover reservoir interval has 2–3 times more oil than any of the individual Genesis reservoirs, which is consistent with independent estimates of oil in place for the respective reservoirs, or (2) Genesis oils have experienced longer migration pathways than Hoover‐Diana oils and thus have interacted with more water. The ability to determine a robust Vo/Vw, despite gas cap formation and possible gas cap loss, is extremely powerful. For example, when volumetric hydrocarbon ratios are combined with independent estimates of hydrocarbon migration distance and/or formation fluid volumes, this technique has the potential to differentiate between large and small oil accumulations.
    Description: We thank ExxonMobil for funding and providing the samples. In addition, we thank James Scott and two anonymous reviewers for their comprehensive and constructive reviews, as well as Janne Blichert‐Toft for editorial handling.
    Description: 2019-04-10
    Repository Name: Woods Hole Open Access Server
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  • 85
    Publication Date: 2022-10-27
    Description: Author Posting. © American Geophysical Union, 2019. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 20(5), (2019):2462-2472, doi:10.1029/2019GC008250.
    Description: Methane hydrate occurs naturally under pressure and temperature conditions that are not straightforward to replicate experimentally. Xenon has emerged as an attractive laboratory alternative to methane for studying hydrate formation and dissociation in multiphase systems, given that it forms hydrates under milder conditions. However, building reliable analogies between the two hydrates requires systematic comparisons, which are currently lacking. We address this gap by developing a theoretical and computational model of gas hydrates under equilibrium and nonequilibrium conditions. We first compare equilibrium phase behaviors of the Xe·H2O and CH4·H2O systems by calculating their isobaric phase diagram, and then study the nonequilibrium kinetics of interfacial hydrate growth using a phase field model. Our results show that Xe·H2O is a good experimental analog to CH4·H2O, but there are key differences to consider. In particular, the aqueous solubility of xenon is altered by the presence of hydrate, similar to what is observed for methane; but xenon is consistently less soluble than methane. Xenon hydrate has a wider nonstoichiometry region, which could lead to a thicker hydrate layer at the gas‐liquid interface when grown under similar kinetic forcing conditions. For both systems, our numerical calculations reveal that hydrate nonstoichiometry coupled with hydrate formation dynamics leads to a compositional gradient across the hydrate layer, where the stoichiometric ratio increases from the gas‐facing side to the liquid‐facing side. Our analysis suggests that accurate composition measurements could be used to infer the kinetic history of hydrate formation in natural settings where gas is abundant.
    Description: This work was funded in part by the U.S. Department of Energy, DOE [awards DE‐FE0013999 and DE‐SC0018357 (to R. J.) and DOE Interagency Agreement DE‐FE0023495 (to W. F. W.)]. X. F. acknowledges support by the Miller Research Fellowship at the University of California Berkeley. W. F. W. acknowledges support from the U.S. Geological Survey's Gas Hydrate Project and the Survey's Coastal, Marine Hazards and Resources Program. L. C. F. acknowledges funding from the Spanish Ministry of Economy and Competitiveness (grants RYC‐2012‐11704 and CTM2014‐54312‐P). L. C. F. and R. J. acknowledge funding from the MIT International Science and Technology Initiatives, through a Seed Fund grant. The simulation data are available on the UC Berkeley Dash repository at https://doi.org/10.6078/D1G67B.
    Description: 2019-11-06
    Keywords: Methane hydrates ; Xenon hydrates ; Phase behavior ; Growth kinetics ; Nonstoichiometry
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  • 86
    Publication Date: 2022-10-27
    Description: Author Posting. © American Geophysical Union, 2019. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research-Biogeosciences, 124(6), (2019): 1591-1603, doi:10.1029/2018JG004803.
    Description: Tropical dry forests in eastern and southern Africa cover 2.5 × 106 km2, support wildlife habitat and livelihoods of more than 150 million people, and face threats from land use and climate change. To inform conservation, we need better understanding of ecosystem processes like nutrient cycling that regulate forest productivity and biomass accumulation. Here we report on patterns in nitrogen (N) cycling across a 100‐year forest regrowth chronosequence in the Tanzanian Miombo woodlands. Soil and vegetation indicators showed that low ecosystem N availability for trees persisted across young to mature forests. Ammonium dominated soil mineral N pools from 0‐ to 15‐cm depth. Laboratory‐measured soil N mineralization rates across 3‐ to 40‐year regrowth sites showed no significant trends and were lower than mature forest rates. Aboveground tree N pools increased at 6 to 7 kg N·ha−1·yr−1, accounting for the majority of ecosystem N accumulation. Foliar δ15N 〈0‰ in an N‐fixing canopy tree across all sites suggested that N fixation may contribute to ecosystem N cycle recovery. These results contrast N cycling in wetter tropical and Neotropical dry forests, where indicators of N scarcity diminish after several decades of regrowth. Our findings suggest that minimizing woody biomass removal, litter layer, and topsoil disturbance may be important to promote N cycle recovery and natural regeneration in Miombo woodlands. Higher rates of N mineralization in the wet season indicated a potential that climate change‐altered rainfall leading to extended dry periods may lower N availability through soil moisture‐dependent N mineralization pathways, particularly for mature forests.
    Description: This study depended on the knowledge, insights, and cooperation of many people and institutions. We thank the Millennium Villages Project‐Mbola site for providing introductions to the landscape and village headmen in many regions. We thank the ARI‐Tumbi staff (now TARI‐Tumbi) in Tabora, Tanzania for providing invaluable logistical support in identifying forest regrowth sites and help with labwork in Tabora, Tanzania. We thank other key local organizations, including Tabora Development Foundation Trust (Dick Mlimuka, Oscar Kisanji) and Tanzania Forest Service (Bw. Relingo), for logistical support and transportation. We thank many village headmen and farmers for access to forest sites within their lands for sampling. Finally, we would like to thank the MBL Stable Isotope laboratory and Dr. Marshall Otter for his expertise with producing and interpreting soil and leaf C, N and stable isotope data. This study was funded in part by NSF PIRE Grant OISE 0968211, a Dissertation Support Grant to Marc Mayes from Brown University (2015–2016), and completed with permission and cooperation from the Tanzania Commission on Science and Technology (COSTECH permits 2013‐261‐NA‐2014‐199 and 2015‐183‐ER‐2014‐199). Data and code for analyses can be accessed at a Github repository: https://github.com/mtm17/MiomboN.git.
    Description: 2019-11-08
    Keywords: Nitrogen ; Africa ; Miombo ; Tropical dry forest ; Carbon ; Secondary forest regrowth
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  • 87
    Publication Date: 2022-05-26
    Description: The cumulative Greenland freshwater flux anomaly has exceeded 5,000 km3 since the 1990s. The volume of this surplus freshwater is expected to cause substantial freshening in the North Atlantic. Analysis of hydrographic observations in the subpolar seas reveals freshening signals in the 2010s. The sources of this freshening are yet to be determined. In this study, the relationship between the surplus Greenland freshwater flux and this freshening is tested by analyzing the propagation of the Greenland freshwater anomaly and its impact on salinity in the subpolar North Atlantic based on observational data and numerical experiments with and without the Greenland runoff. A passive tracer is continuously released during the simulations at freshwater sources along the coast of Greenland to track the Greenland freshwater anomaly. Tracer budget analysis shows that 44% of the volume of the Greenland freshwater anomaly is retained in the subpolar North Atlantic by the end of the simulation. This volume is sufficient to cause strong freshening in the subpolar seas if it stays in the upper 50–100 m. However, in the model the anomaly is mixed down to several hundred meters of the water column resulting in smaller magnitudes of freshening compared to the observations. Therefore, the simulations suggest that the accelerated Greenland melting would not be sufficient to cause the observed freshening in the subpolar seas and other sources of freshwater have contributed to the freshening. Impacts on salinity in the subpolar seas of the freshwater transport through Fram Strait and precipitation are discussed.
    Description: © The Author(s), 2019. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Dukhovskoy, D. S., Yashayaev, I., Proshutinsky, A., Bamber, J. L., Bashmachnikov, I. L., Chassignet, E. P., Lee, C. M., & Tedstone, A. J. Role of Greenland freshwater anomaly in the recent freshening of the subpolar North Atlantic. Journal of Geophysical Research-Oceans, 124(5), (2019): 3333-3360, doi:10.1029/2018JC014686.
    Keywords: Greenland ice sheet melting ; freshwater anomaly ; subpolar North Atlantic ; subpolar gyre ; passive tracer numerical experiment ; freshwater budget
    Repository Name: Woods Hole Open Access Server
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  • 88
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2019. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research-Oceans 124(7), (2019): 4416-4432, doi: 10.1029/2019JC015185.
    Description: Synoptic and historical shipboard data, spanning the period 1981–2017, are used to investigate the seasonal evolution of water masses on the northeastern Chukchi shelf and quantify the circulation patterns and their impact on nutrient distributions. We find that Alaskan coastal water extends to Barrow Canyon along the coastal pathway, with peak presence in September, while the Pacific Winter Water (WW) continually drains off the shelf through the summer. The depth‐averaged circulation under light winds is characterized by a strong Alaskan Coastal Current (ACC) and northward flow through Central Channel. A portion of the Central Channel flow recirculates anticyclonically to join the ACC, while the remainder progresses northeastward to Hanna Shoal where it bifurcates around both sides of the shoal. All of the branches converge southeast of the shoal and eventually join the ACC. The wind‐forced response has two regimes: In the coastal region the circulation depends on wind direction, while on the interior shelf the circulation is sensitive to wind stress curl. In the most common wind‐forced state—northeasterly winds and anticyclonic wind stress curl—the ACC reverses, the Central Channel flow penetrates farther north, and there is mass exchange between the interior and coastal regions. In September and October, the region southeast of Hanna Shoal is characterized by elevated amounts of WW, a shallower pycnocline, and higher concentrations of nitrate. Sustained late‐season phytoplankton growth spurred by this pooling of nutrients could result in enhanced vertical export of carbon to the seafloor, contributing to the maintenance of benthic hotspots in this region.
    Description: The authors acknowledge the hard work and dedication of the many crew members who sailed on the different cruises of the USCGC Healy and the R/V Palmer. This study would not have been possible without their ongoing efforts to carry out successful science operations. Seth Danielson performed the quality control of the Barrow wind data. Funding was provided by the following sources: National Oceanic and Atmospheric Administration (NOAA) Grant NA14‐OAR4320158 (P. L., R. P., and L. M.), National Science Foundation (NSF) Grants OPP‐1702371 and OPP‐1733564 (R. P. and F. B.) and PLR‐1303617 (R. P., K. A., and K. L.), NSF Graduate Research Fellowship Program DGE‐0645962 (K. L.), National Aeronautics and Space Administration award NNX10AF42G (R. P., K. A., and K. L.), and NOAA's Ocean Observing and Monitoring Division, Climate Program Office Fund 100007298 (C. M.). This publication is partially funded by the Joint Institute for the Study of the Atmosphere and Ocean (JISAO) under NOAA Cooperative Agreement NA15OAR4320063 and is contribution EcoFOCI‐0924 to the Ecosystems and Fisheries‐Oceanography Coordinated Investigations, 4944 to PMEL. The CTD and shipboard ADCP data of the eight cruises are available from http://www.rvdata.us/, and the nutrients data can be accessed from https://arcticdata.io/.
    Description: 2019-12-07
    Repository Name: Woods Hole Open Access Server
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  • 89
    Publication Date: 2022-10-27
    Description: Author Posting. © American Geophysical Union, 2019. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research-Oceans 124(6), (2019): 3490-3507, doi:10.1029/2018JC014675.
    Description: Offshore permafrost plays a role in the global climate system, but observations of permafrost thickness, state, and composition are limited to specific regions. The current global permafrost map shows potential offshore permafrost distribution based on bathymetry and global sea level rise. As a first‐order estimate, we employ a heat transfer model to calculate the subsurface temperature field. Our model uses dynamic upper boundary conditions that synthesize Earth System Model air temperature, ice mass distribution and thickness, and global sea level reconstruction and applies globally distributed geothermal heat flux as a lower boundary condition. Sea level reconstruction accounts for differences between marine and terrestrial sedimentation history. Sediment composition and pore water salinity are integrated in the model. Model runs for 450 ka for cross‐shelf transects were used to initialize the model for circumarctic modeling for the past 50 ka. Preindustrial submarine permafrost (i.e., cryotic sediment), modeled at 12.5‐km spatial resolution, lies beneath almost 2.5 ×106km2 of the Arctic shelf. Our simple modeling approach results in estimates of distribution of cryotic sediment that are similar to the current global map and recent seismically delineated permafrost distributions for the Beaufort and Kara seas, suggesting that sea level is a first‐order determinant for submarine permafrost distribution. Ice content and sediment thermal conductivity are also important for determining rates of permafrost thickness change. The model provides a consistent circumarctic approach to map submarine permafrost and to estimate the dynamics of permafrost in the past.
    Description: Boundary condition data are available online via the sources referenced in the manuscript. This work was partially funded by a Helmholtz Association of Research Centres (HGF) Joint Russian‐German Research Group (HGF JRG 100). This study is part of a project that has received funding from the European Unions Horizon 2020 research and innovation program under grant agreement 773421. Submarine permafrost studies in the Kara and Laptev Seas were supported by Russian Foundation for Basic Research (RFBR/RFFI) grants 18‐05‐60004 and 18‐05‐70091, respectively. The International Permafrost Association (IPA) and the Association for Polar Early Career Scientists (APECS) supported research coordination that led to this study. We acknowledge coordination support of the World Climate Research Programme (WCRP) through their core project on Climate and Cryosphere (CliC). Thanks to Martin Jakobsson for providing a digitized version of the preliminary IHO delineation of the Arctic seas and to Guy Masters for access to the observational geothermal database. Any use of trade, firm, or product names is for descriptive purposes only and does not imply endorsement by the U.S. Government.
    Description: 2019-10-17
    Keywords: Submarine permafrost ; Arctic ; Cryosphere ; Sea level
    Repository Name: Woods Hole Open Access Server
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  • 90
    Publication Date: 2022-10-27
    Description: Author Posting. © American Geophysical Union, 2019. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 46 (2019): 10484–10494, doi:10.1029/2019GL083719.
    Description: Tropical cyclones (hurricanes) generate intense surface ocean cooling and vertical mixing resulting in nutrient upwelling into the photic zone and episodic phytoplankton blooms. However, their influence on the deep ocean remains unknown. Here we present evidence that hurricanes also impact the ocean's biological pump by enhancing export of labile organic material to the deep ocean. In October 2016, Category 3 Hurricane Nicole passed over the Bermuda Time Series site in the oligotrophic NW Atlantic Ocean. Following Nicole's passage, particulate fluxes of lipids diagnostic of fresh phytodetritus, zooplankton, and microbial biomass increased by 30–300% at 1,500 m depth and 30–800% at 3,200 m depth. Mesopelagic suspended particles following Nicole were also enriched in phytodetrital material and in zooplankton and bacteria lipids, indicating particle disaggregation and a deepwater ecosystem response. Predicted climate‐induced increases in hurricane frequency and/or intensity may significantly alter ocean biogeochemical cycles by increasing the strength of the biological pump.
    Description: This work and the Oceanic Flux Program time series were supported by the National Science Foundation Chemical Oceanography Program Grant OCE 1536644. The Bermuda Atlantic Time Series and Hydrostation S time series were supported by NSF Grants OCE 1756105 and OCE 1633125, respectively. We acknowledge the contributions of BATS technicians with CTD and pigment analyses. We sincerely thank the officers and crew of R/V Atlantic Explorer (Bermuda Institute of Ocean Sciences) for their expert assistance on the cruises. The data used in this study are listed in the figures, tables, and references, and are also available in the NSF's Biological and Chemical Oceanography Data Management Office (BCO‐DMO, https://doi.org/10.1575/1912/bco‐dmo.775902.1).
    Description: 2020-02-16
    Keywords: Hurricanes ; Carbon cycle ; North Atlantic Ocean ; Deep ocean ; Particle fluxes ; Lipid biomarkers
    Repository Name: Woods Hole Open Access Server
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  • 91
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2019. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research-Oceans 124(5), (2019): 2943-2968, doi:10.1029/2019JC015071.
    Description: In the Southern Ocean, polynyas exhibit enhanced rates of primary productivity and represent large seasonal sinks for atmospheric CO2. Three contrasting east Antarctic polynyas were visited in late December to early January 2017: the Dalton, Mertz, and Ninnis polynyas. In the Mertz and Ninnis polynyas, phytoplankton biomass (average of 322 and 354 mg chlorophyll a (Chl a)/m2, respectively) and net community production (5.3 and 4.6 mol C/m2, respectively) were approximately 3 times those measured in the Dalton polynya (average of 122 mg Chl a/m2 and 1.8 mol C/m2). Phytoplankton communities also differed between the polynyas. Diatoms were thriving in the Mertz and Ninnis polynyas but not in the Dalton polynya, where Phaeocystis antarctica dominated. These strong regional differences were explored using physiological, biological, and physical parameters. The most likely drivers of the observed higher productivity in the Mertz and Ninnis were the relatively shallow inflow of iron‐rich modified Circumpolar Deep Water onto the shelf as well as a very large sea ice meltwater contribution. The productivity contrast between the three polynyas could not be explained by (1) the input of glacial meltwater, (2) the presence of Ice Shelf Water, or (3) stratification of the mixed layer. Our results show that physical drivers regulate the productivity of polynyas, suggesting that the response of biological productivity and carbon export to future change will vary among polynyas.
    Description: This work was cofunded by the Australian Antarctic Division research projects AAS 4131 and 4291. This project was also supported by the Australian Government Cooperative Research Centres Programme through the Antarctic Climate & Ecosystems (ACE CRC). S. Moreau and C. Genovese were supported by the Australian Research Council's Special Research Initiative for Antarctic Gateway Partnership (project ID SR140300001). V. Puigcorbé and M. Roca‐Martí are grateful for the support from Pere Masque and Edith Cowan University. M.C. Arroyo was supported by the Dickhut Fellowship, administered by the Virginia Institute of Marine Science. The authors would like to thank the officers and crew of the R/V Aurora Australis for their logistic support, the CSIRO hydrochemists for their analyses of nutrient concentrations, and E. J. Yang for her microscope analysis of phytoplankton species. We also want to thank two anonymous reviewers for their very good comments on this study. The data presented in this paper are available on the Australian Antarctic Division (AAD) Data Centre at https://data.aad.gov.au/aadc/metadata/metadata_by_parameter.cfm.
    Description: 2019-09-28
    Keywords: Polynyas ; Primary productivity ; Phytoplankton biomass ; Ice shelves ; Sea ice ; Iron
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  • 92
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2019. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research-Oceans 124(3), (2019): 1778-1794, doi:10.1029/2018JC014775.
    Description: Abyssal ocean warming contributed substantially to anthropogenic ocean heat uptake and global sea level rise between 1990 and 2010. In the 2010s, several hydrographic sections crossing the South Pacific Ocean were occupied for a third or fourth time since the 1990s, allowing for an assessment of the decadal variability in the local abyssal ocean properties among the 1990s, 2000s, and 2010s. These observations from three decades reveal steady to accelerated bottom water warming since the 1990s. Strong abyssal (z 〉 4,000 m) warming of 3.5 (±1.4) m°C/year (m°C = 10−3 °C) is observed in the Ross Sea, directly downstream from bottom water formation sites, with warming rates of 2.5 (±0.4) m°C/year to the east in the Amundsen‐Bellingshausen Basin and 1.3 (±0.2) m°C/year to the north in the Southwest Pacific Basin, all associated with a bottom‐intensified descent of the deepest isotherms. Warming is consistently found across all sections and their occupations within each basin, demonstrating that the abyssal warming is monotonic, basin‐wide, and multidecadal. In addition, bottom water freshening was strongest in the Ross Sea, with smaller amplitude in the Amundsen‐Bellingshausen Basin in the 2000s, but is discernible in portions of the Southwest Pacific Basin by the 2010s. These results indicate that bottom water freshening, stemming from strong freshening of Ross Shelf Waters, is being advected along deep isopycnals and mixed into deep basins, albeit on longer timescales than the dynamically driven, wave‐propagated warming signal. We quantify the contribution of the warming to local sea level and heat budgets.
    Description: S. G. P. was supported by a U.S. GO‐SHIP postdoctoral fellowship through NSF grant OCE‐1437015, which also supported L. D. T. and S. M. and collection of U.S. GO‐SHIP data since 2014 on P06, S4P, P16, and P18. G. C. J. is supported by the Global Ocean Monitoring and Observation Program, National Oceanic and Atmospheric Administration (NOAA), U.S. Department of Commerce and NOAA Research. B. M. S and S. E. W. were supported by the Australian Government Department of the Environment and CSIRO through the Australian Climate Change Science Programme and by the National Environmental Science Program. We are grateful for the hard work of the science parties, officers, and crew of all the research cruises on which these CTD data were collected. We also thank the two anonymous reviewers for their helpful comments that improve the manuscript. This is PMEL contribution 4870. All CTD data sets used in this analysis are publicly available at the website (https://cchdo.ucsd.edu).
    Description: 2019-08-20
    Keywords: Abyssal warming ; Pacific deep circulation ; Deep steric sea level ; Deep warming variability ; Antarctic Bottom Water
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  • 93
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2019. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research-Oceans 124(3), (2019): 2088-2109, doi:10.1029/2018JC014583.
    Description: As observations and models improve their resolution of oceanic motions at ever finer horizontal scales, interest has grown in characterizing the transition from the geostrophically balanced flows that dominate at large‐scale to submesoscale turbulence and waves that dominate at small scales. In this study we examine the mesoscale‐to‐submesoscale (100 to 10 km) transition in an eastern boundary current, the southern California Current System (CCS), using repeated acoustic Doppler current profiler transects, sea surface height from high‐resolution nadir altimetry and output from a (1/48)° global model simulation. In the CCS, the submesoscale is as energetic as in western boundary current regions, but the mesoscale is much weaker, and as a result the transition lacks the change in kinetic energy (KE) spectral slope observed for western boundary currents. Helmholtz and vortex‐wave decompositions of the KE spectra are used to identify balanced and unbalanced contributions. At horizontal scales greater than 70 km, we find that observed KE is dominated by balanced geostrophic motions. At scales from 40 to 10 km, unbalanced contributions such as inertia‐gravity waves contribute as much as balanced motions. The model KE transition occurs at longer scales, around 125 km. The altimeter spectra are consistent with acoustic Doppler current profiler/model spectra at scales longer than 70/125 km, respectively. Observed seasonality is weak. Taken together, our results suggest that geostrophic velocities can be diagnosed from sea surface height on scales larger than about 70 km in the southern CCS.
    Description: This research was funded by NASA (NNX13AE44G, NNX13AE85G, NNX16AH67G, NNX16AO5OH, and NNX17AH53G). We thank Sung Yong Kim for providing the high‐frequency radar spectral estimates and the two anonymous reviewers for providing useful comments and suggestions that greatly improved the manuscript. High‐frequency ALES data for Jason‐1 and Jason‐2 altimeters are available upon request (https://openadb.dgfi.tum.de/en/contact/ALES). Both AltiKa and Sentinel‐3 altimeter products were produced and distributed by the Copernicus Marine and Environment Monitoring Service (CMEMS; http://www.marine.copernicus.eu). D. M. worked on the modeling component of this study at the Jet Propulsion Laboratory (JPL), California Institute of Technology, under a contract with the National Aeronautics and Space Administration (NASA). High‐end computing resources were provided by the NASA Advanced Supercomputing (NAS) Division of the Ames Research Center. The LLC output can be obtained from the ECCO project (ftp://ecco.jpl.nasa.gov/ECCO2/LLC4320/). The ADCP data are available at the Joint Archive for Shipboard ADCP data (JASADCP; http://ilikai.soest.hawaii.edu/sadcp).
    Description: 2019-08-21
    Keywords: Mesoscale ; Submesoscale ; Internal gravity waves
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  • 94
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2019. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 20(3), (2019): 1485-1507, doi:10.1029/2018GC007985.
    Description: In 2015 a geothermal exploration well was drilled on the island of Tutuila, American Samoa. The sample suite from the drill core provides 645 m of volcanic stratigraphy from a Samoan volcano, spanning 1.45 million years of volcanic history. In the Tutuila drill core, shield lavas with an EM2 (enriched mantle 2) signature are observed at depth, spanning 1.46 to 1.44 Ma. These are overlain by younger (1.35 to 1.17 Ma) shield lavas with a primordial “common” (focus zone) component interlayered with lavas that sample a depleted mantle component. Following ~1.15 Myr of volcanic quiescence, rejuvenated volcanism initiated at 24.3 ka and samples an EM1 (enriched mantle 1) component. The timing of the initiation of rejuvenated volcanism on Tutuila suggests that rejuvenated volcanism may be tectonically driven, as Samoan hotspot volcanoes approach the northern terminus of the Tonga Trench. This is consistent with a model where the timing of rejuvenated volcanism at Tutuila and at other Samoan volcanoes relates to their distance from the Tonga Trench. Notably, the Samoan rejuvenated lavas have EM1 isotopic compositions distinct from shield lavas that are geochemically similar to “petit spot” lavas erupted outboard of the Japan Trench and late stage lavas erupted at Christmas Island located outboard of the Sunda Trench. Therefore, like the Samoan rejuvenated lavas, petit spot volcanism in general appears to be related to tectonic uplift outboard of subduction zones, and existing geochemical data suggest that petit spots share similar EM1 isotopic signatures.
    Description: Reviews from Kaj Hoernle and three anonymous reviewers are gratefully acknowledged. M. G. J. acknowledges support from the American Samoa Power Authority and National Science Foundation grants OCE‐1736984 and EAR‐1624840. The Tutuila drill core was the brainchild of Tim Bodell, without whom we would still have no stratigraphic record of Tutuila volcanism. The support of Utu Abe Malae and Matamua Katrina Mariner was instrumental to the project's success. We dedicate this paper to the memory of Abe Malae and his efforts to support science and education in American Samoa. Images of the entire drill core are available online (escholarship.org/uc/item/6gg6p61w). All data presented are either part of this study or previously published and are referenced in text.
    Description: 2019-08-13
    Keywords: Samoa ; Mantle geochemistry ; Petit spot ; EM1 ; Rejuvenated volcanism
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  • 95
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2019. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research-Oceans 124(7), (2019): 4618-4630, doi: 10.1029/2019JC014940.
    Description: The Arctic Ocean mixed layer interacts with the ice cover above and warmer, nutrient‐rich waters below. Ice‐Tethered Profiler observations in the Canada Basin of the Arctic Ocean over 2006–2017 are used to investigate changes in mixed layer properties. In contrast to decades of shoaling since at least the 1980s, the mixed layer deepened by 9 m from 2006–2012 to 2013–2017. Deepening resulted from an increase in mixed layer salinity that also weakened stratification at the base of the mixed layer. Vertical mixing alone can explain less than half of the observed change in mixed layer salinity, and so the observed increase in salinity is inferred to result from changes in freshwater accumulation via changes to ice‐ocean circulation or ice melt/growth and river runoff. Even though salinity increased, the shallowest density surfaces deepened by 5 m on average suggesting that Ekman pumping over this time period remained downward. A deeper mixed layer with weaker stratification has implications for the accessibility of heat and nutrients stored in the upper halocline. The extent to which the mixed layer will continue to deepen appears to depend primarily on the complex set of processes influencing freshwater accumulation.
    Description: We gratefully acknowledge J. Toole for helpful conversations. S. Cole was supported by the National Science Foundation under grant PLR‐1602926 and J. Stadler by the Woods Hole Oceanographic Institution Summer Student Fellowship program. Profile data are available via the Ice‐Tethered Profiler program website: http://whoi.edu/itp. SSM/I ice concentration data were downloaded from the National Snow and Ice Data Center.
    Description: 2019-12-22
    Keywords: Arctic Ocean ; Mixed layer ; Freshwater
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  • 96
    Publication Date: 2022-10-26
    Description: © The Author(s), 2019. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Druffel, E. R. M., Griffin, S., Wang, N., Garcia, N. G., McNichol, A. P., Key, R. M., & Walker, B. D. Dissolved organic radiocarbon in the central Pacific Ocean. Geophysical Research Letters, 46(10), (2019):5396-5403, doi:10.1029/2019GL083149.
    Description: We report marine dissolved organic carbon (DOC) concentrations, and DOC ∆14C and δ13C values in seawater collected from the central Pacific. Surface ∆14C values are low in equatorial and polar regions where upwelling occurs and high in subtropical regions dominated by downwelling. A core feature of these data is that 14C aging of DOC (682 ± 86 14C years) and dissolved inorganic carbon (643 ± 40 14C years) in Antarctic Bottom Water between 54.0°S and 53.5°N are similar. These estimates of aging are minimum values due to mixing with deep waters. We also observe minimum ∆14C values (−550‰ to −570‰) between the depths of 2,000 and 3,500 m in the North Pacific, though the source of the low values cannot be determined at this time.
    Description: We thank Jennifer Walker, Xiaomei Xu, and Dachun Zhang for their help with the stable carbon isotope measurements; John Southon and staff of the Keck Carbon Cycle AMS Laboratory for their assistance and advice; the support of chief scientists Samantha Siedlecki, Molly Baringer, Alison Macdonald, and Sabine Mecking; the guidance of Jim Swift and Dennis Hansell for shared ship time; and Sarah Bercovici for collecting water on the GoA cruise. We appreciate the comments of Christian Lewis and Niels Hauksson on this manuscript. This work was supported by NSF (OCE‐141458941 to E. R. M. D. and OCE‐0824864, OCE‐1558654, and Cooperative Agreement OCE1239667 to R. M. K. and A. P. M.), the Fred Kavli Foundation, the Keck Carbon Cycle AMS Laboratory, and the NSF/NOAA‐funded GO‐SHIP Program. This research was undertaken, in part, thanks to funding from the Canada Research Chairs program (to B. D. W.) and an American Chemical Society Petroleum Research Fund New Directions grant (55430‐ND2 to E. R. M. D. and B. D. W.). Data from the P16N cruises are available in Table S2 in the Supporting Information and at the Repeat Hydrography Data Center at the CCHDO website (http://cdiac.esd.ornl.gov/oceans/index.html) using the expo codes 3RO20150329, 3RO20150410, and 3RO20150525. There are no real or perceived financial conflicts of interests for any author.
    Description: 2019-11-02
    Keywords: Dissolved organic carbon ; Radiocarbon ; Pacific Ocean ; Dissolved inorganic carbon ; Deep ocean circulation ; AABW
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  • 97
    Publication Date: 2022-10-19
    Description: Author Posting. © American Geophysical Union, 2018. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research-Oceans, 123(11), (2018): 7795-7818. doi: 10.1029/2018JC013794.
    Description: This work studies the subduction of the shelf water along the onshore edge of a warm‐core ring that impinges on the edge of the Mid‐Atlantic Bight continental shelf. The dynamical analysis is based on observations by satellites and from the Ocean Observatories Initiative Pioneer Array observatory as well as idealized numerical model simulations. They together show that frontogenesis‐induced submesoscale frontal subduction with order‐one Rossby and Froude numbers occurs on the onshore edge of the ring. The subduction flow results from the onshore migration of the warm‐core ring that intensifies the density front on the interface of the ring and shelf waters. The subduction is a part of the cross‐front secondary circulation trying to relax the intensifying density front. The dramatically different physical and biogeochemical properties of the ring and shelf waters provide a great opportunity to visualize the subduction phenomenon. Entrained by the ring‐edge current, the subducted shelf water is subsequently transported offshore below a surface layer of ring water and alongside of the surface‐visible shelf‐water streamer. It explains the historical observations of isolated subsurface packets of shelf water along the ring periphery in the slope sea. Model‐based estimate suggests that this type of subduction‐associated subsurface cross‐shelfbreak transport of the shelf water could be substantial relative to other major forms of shelfbreak water exchange. This study also proposes that outward spreading of the ring‐edge front by the frontal subduction may facilitate entrainment of the shelf water by the ring‐edge current and enhances the shelf‐water streamer transport at the shelf edge.
    Description: W. G. Z. was supported by the National Science Foundation under grants OCE‐1657853, OCE‐1657803, and OCE 1634965. JP is grateful for the support of the Woods Hole Oceanographic Institution Summer Student Fellow Program in 2016 and 2017. W. G. Z. thanks Kenneth Brink, Glen Gawarkiewicz, Rocky Geyer, Steven Lentz, Dennis McGillicuddy, Robert Todd, and John Trowbridge for helpful discussions during the course of the study or useful comments on earlier versions of the manuscript. The satellite sea surface temperature data were obtained from the University of Delaware Ocean Exploration, Remote Sensing, Biogeography Lab (led by Matthew Oliver), through the Mid‐Atlantic Coastal Ocean Observing System (MARACOOS) data server (http://tds.maracoos.org/thredds/catalog.html). The OOI Pioneer Array mooring and glider data presented in this paper were downloaded from the National Science Foundation OOI data portal (http://ooinet.oceanobservatories.org) in July–August 2016.
    Description: 2019-04-15
    Keywords: Frontal subduction ; Warm‐core ring ; Mid‐Atlantic Bight ; Shelf‐water streamer ; Cross‐shelf exchange ; OOI Pioneer Array
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  • 98
    Publication Date: 2022-10-20
    Description: Author Posting. © American Geophysical Union, 2018. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 1123(11), (2018): 8568-8580. doi: 10.1029/2018JC014352.
    Description: In the past decades, in the context of a changing ocean submitted to an increasing human activity, a progressive decrease in the frequencies (pitch) of blue whale vocalizations has been observed worldwide. Its causes, of natural or anthropogenic nature, are still unclear. Based on 7 years of continuous acoustic recordings at widespread sites in the southern Indian Ocean, we show that this observation stands for five populations of large whales. The frequency of selected units of vocalizations of fin, Antarctic, and pygmy blue whales has steadily decreased at a rate of a few tenths of hertz per year since 2002. In addition to this interannual frequency decrease, blue whale vocalizations display seasonal frequency shifts. We show that these intra‐annual shifts correlate with seasonal changes in the ambient noise near their call frequency. This ambient noise level, in turn, shows a strong correlation with the seasonal presence of icebergs, which are one of the main sources of oceanic noise in the Southern Hemisphere. Although cause‐and‐effect relationships are difficult to ascertain, wide‐ranging changes in the acoustic environment seem to have a strong impact on the vocal behavior of large baleen whales. Seasonal frequency shifts may be due to short‐term changes in the ambient noise, and the interannual frequency decline to long‐term changes in the acoustic properties of the ocean and/or in postwhaling changes in whale abundances.
    Description: The authors wish to thank the Captains and crews of RV Marion Dufresne for the successful deployments and recoveries of the hydrophones of the DEFLOHYDRO (Royer, 2008) and OHASISBIO (Royer, 2009) experiments. French cruises were funded by the French Polar Institute (IPEV) with additional support from INSU‐CNRS. NOAA/PMEL also contributed to the DEFLOHYDRO project. E. C. L. was supported by a PhD fellowship from the University of Brest and from the Regional Council of Brittany (Conseil Régional de Bretagne). The contribution of Mickael Beauverger at LGO to the logistics and deployment of the OHASISBIO cruises is greatly appreciated. The data underlying this analysis (weekly averaged frequencies of Antarctic blue whales, pygmy blue whales, and fin whales and daily averaged noise levels at each site) are accessible at http://doi.org/10.17882/51007.
    Description: 2019-05-27
    Keywords: Large baleen whales ; Blue whale calls ; Frequency decrease ; Bioacoustics ; Frequency shifts ; Ambient noise
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  • 99
    Publication Date: 2022-10-20
    Description: Author Posting. © American Geophysical Union, 2018. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Oceans 123(11), (2018): 8411-8429, doi: 10.1029/2018JC014178.
    Description: A method for estimating gross primary production (GPP) is presented and validated against a numerical model of Chesapeake Bay that includes realistic physical and biological forcing. The method statistically fits a photosynthesis‐irradiance response curve using the observed near‐surface time rate of change of dissolved oxygen and the incoming solar radiation, yielding estimates of the light‐saturated photosynthetic rate and the initial slope of the photosynthesis‐irradiance response curve. This allows estimation of GPP with 15‐day temporal resolution. The method is applied to the output from a numerical model that has high skill at reproducing both surface and near‐bottom dissolved oxygen variations observed in Chesapeake Bay in 2013. The rate of GPP predicted by the numerical model is known, as are the contributions from physical processes, allowing the proposed diel method to be rigorously assessed. At locations throughout the main stem of the Bay, the method accurately extracts the underlying rate of GPP, including pronounced seasonal variability and spatial variability. Errors associated with the method are primarily the result of contributions by the divergence in turbulent oxygen flux, which changes sign over the surface mixed layer. As a result, there is an optimal vertical location with minimal bias where application of the method is most accurate.
    Description: This paper is the result of research funded in part by NOAA's U.S. Integrated Ocean Observing System (IOOS) Program Office as a subcontract to the Woods Hole Oceanographic Institution under award NA13NOS120139 to the Southeastern University Research Association. All of the model output, as well as both the CBIBS data (2010–2016) and the bottom oxygen data of Scully (2016b), are publicly available through the THREDDS server associated with the IOOS Coastal Modeling Testbed site: https://comt.ioos.us/projects/cb_hypoxia.
    Description: 2019-05-24
    Keywords: Gross primary production ; Vertical mixing ; Numerical model ; Chesapeake Bay
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  • 100
    Publication Date: 2022-10-20
    Description: Author Posting. © American Geophysical Union, 2018. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Theoretical considerations on factors confounding the interpretation of the oceanic carbon export ratio. Global Biogeochemical Cycles, 32(11), (2018); 1644-1658, doi:10.1029/2018GB006003.
    Description: The fraction of primary production exported out of the surface ocean, known as the export ratio (ef ratio), is often used to assess how various factors, including temperature, primary production, phytoplankton size, and community structure, affect the export efficiency of an ecosystem. To investigate possible causes for reported discrepancies in the dominant factors influencing the export efficiency, we develop a metabolism‐based mechanistic model of the ef ratio. Consistent with earlier studies, we find based on theoretical considerations that the ef ratio is a negative function of temperature. We show that the ef ratio depends on the optical depth, defined as the physical depth times the light attenuation coefficient. As a result, varying light attenuation may confound the interpretation of ef ratio when measured at a fixed depth (e.g., 100 m) or at the base of the mixed layer. Finally, we decompose the contribution of individual factors on the seasonality of the ef ratio. Our results show that at high latitudes, the ef ratio at the base of mixed layer is strongly influenced by mixed layer depth and surface irradiation on seasonal time scales. Future studies should report the ef ratio at the base of the euphotic layer or account for the effect of varying light attenuation if measured at a different depth. Overall, our modeling study highlights the large number of factors confounding the interpretation of field observations of the ef ratio.
    Description: Z. L was supported by a NASA Earth and Space Science Fellowship (Grant NNX13AN85H) and the Postdoctoral Scholarship Program at Woods Hole Oceanographic Institution. N. C. was supported by NASA Grant 5109296. Satellite data, nutrient concentration, and monthly MLD climatology are downloaded from NASA ocean color (http://oceancolor.gsfc.nasa.gov/cms/), World Ocean Atlas (https://www.nodc.noaa.gov/OC5/woa13/), and http://www.ifremer.fr/cerweb/deboyer/mld/home.php, respectively.
    Description: 2019-04-13
    Keywords: Oceanic carbon export ratio ; Net community production ; Export production ; Net primary production
    Repository Name: Woods Hole Open Access Server
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