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  • 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions  (26)
  • 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry  (24)
  • Mt. Etna  (20)
  • 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology  (16)
  • Elsevier  (52)
  • Springer  (11)
  • Elsevier Science Limited  (7)
  • Springer-Verlag  (4)
  • Blackwell Publishing Ltd
  • ELSEVIER
  • Essen : Verl. Glückauf
  • Krefeld : Geologischer Dienst Nordhein-Westfalen
  • 2010-2014  (6)
  • 2005-2009  (69)
  • 2014  (6)
  • 2008  (37)
  • 2005  (32)
Collection
Publisher
Years
  • 2010-2014  (6)
  • 2005-2009  (69)
Year
  • 1
    Publication Date: 2020-10-14
    Description: In the last decades, the increasing availability of comprehensive geodetic datasets has allowed for more detailed constraints on subsurface magma storage and conduits at several active volcanoes worldwide. Here, by using a large dataset of geodetic measurements collected between early January 2001 and August 2001, we identified at least six different deformation stages that allow us to quantify the surface deformation patterns before, during and after the 2001 Mt. Etna volcanic eruption. Our results are largely in agreement with previous works (e.g. the presence of a deep inflating source and a shallow dike located beneath the north-western and upper southern flanks of the volcano, respectively). However, we provide (1) finer resolution of the temporal activity of these magmatic sources, leading to (2) new evidence related to the evolution of the magmatic system and the mechanical response of the western flank, in particular during the pre-eruptive phase. Results and analysis show a clear change in the ground deformation pattern of the volcano in response to the 20–24 April 2001 seismic swarm that occurred beneath the western flank, evolving from a volcano-wide inflation to a slight deflation of the summit area. We suggest that the source responsible for the volcano-wide inflation, beginning in the fall of 2000, experienced a drastic reduction in the inflation rate in response to this seismic swarm. Moreover, we provide evidence for the presence of a new inflating source located beneath the upper southern flank at a depth of ~ 7.0 km bsl that triggered both the occurrence of the 20–24 April 2001 seismic swarm and led to the rapid ascent of magma upward to the surface after 12 July (the Lower Vents system was fed by fresh magma rising from this source). The presence of this inflating source is inferred by (1) seismological and volcanological observations coming from the 2001 eruption and (2) seismological constraints coming from a previous similar episode that occurred at Etna during the 1993–1998 period. Furthermore, both shallow deflations observed after the 20–24 April 2001 seismic swarm and during the first day of the eruption also could be due to the deflation of two adjacent portions of the same shallow (~ 2 km bsl) reservoir. Such reservoirs would feed the activity that occurred at the South-East Crater after January 2001 and the activity of the Upper Vents system during the July–August eruption, in agreement with petrochemical observations. Through an updated revision of the available data, we shed some light on the relevance of pre-eruptive activity patterns, an important element for an effective volcano monitoring.
    Description: Published
    Description: 108-121
    Description: 2V. Dinamiche di unrest e scenari pre-eruttivi
    Description: JCR Journal
    Description: restricted
    Keywords: Mt. Etna eruption ; GPS ; InSAR ; Modelling ; Atmospheric correction ; Coulomb stress changes ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Publication Date: 2021-06-15
    Description: We investigated the geochemical features of the fluids circulating over the Amik Basin (SE Turkey–Syria border), which is crossed by the Northern extension of theDSF (Dead Sea Fault) and represents the boundary area of three tectonic plates (Anatolian, Arabian and African plates). We collected 34 water samples (thermal and cold from natural springs and boreholes) as well as 8 gas samples (bubbling and gas seepage) besides the gases dissolved in the sampled waters. The results show that the dissolved gas phase is a mixture of shallow (atmospheric) and deep components either of mantle and crustal origin. Coherently the sampled waters are variable mixtures of shallow and deep ground waters, the latter being characterised by higher salinity and longer residence times. The deep groundwaters (fromboreholes deeper than 1000 m)have a CH4-dominated dissolved gas phase related to the presence of hydrocarbon reservoirs. The very unique tectonic setting of the area includes the presence of an ophiolitic block outcropping in the westernmost area on the African Plate, as well as basalts located to the North and East on the Arabic Plate. The diffuse presence of CO2-enriched gases, although diluted by the huge groundwater circulation, testifies a regional degassing activity. Fluids circulating over the ophiolitic block are marked by H2-dominated gases with abiogenic methane and high-pH waters. The measured 3He/4He isotopic ratios display contributions from both crustal and mantle-derived sources over both sides of the DSF. Although the serpentinization process is generally independent from mantle-type contribution, the recorded helium isotopic ratios highlight variable contents of mantle-derived fluids. Due to the absence of recent volcanism over the western side of the basin (African Plate), we argue that CO2-rich volatiles carrying mantle-type helium and enriched in heavy carbon, are degassed by deep-rooted regional faults rather than from volcanic sources.
    Description: Published
    Description: 23–39
    Description: 2T. Tettonica attiva
    Description: JCR Journal
    Description: restricted
    Keywords: Dead Sea Fault ; Hydrogeochemistry ; Gas geochemistry ; He isotopes ; C isotopes ; Ophiolites ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.02. Carbon cycling ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 3
    Publication Date: 2017-04-04
    Description: In this work we show that the main springs of the central Apennine transport a total amount of heat of ∼2.2 109 J s−1. Most of this heat (57%) is the result of geothermal warming while the remaining 43% is due to gravitational potential energy dissipation. This result indicates that a large area of the central Apennines is very hot with heat flux values 4300 mWm−2. These values are higher than those measured in the magmatic and famously geothermal provinces of Tuscany and Latium and about 1/3 of the total heat discharged at Yellowstone. This finding is surprising because the central Apennines have been thought to be a relatively cold area. Translated by CO2 rich fluids, this heat anomaly suggests the existence of a thermal source such as a large magmatic intrusion at depth. Recent tomographic images of the area support the presence of such an intrusion visible as a broad negative velocity anomaly in seismic waves. Our results indicate that the thermal regime of tectonically active areas of the Earth, where meteoric waters infiltrate and deeply circulate, should be revised on the basis of mass and energy balances of the groundwater systems.
    Description: Published
    Description: 65–74
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: heat flux ; CO2 Earth degassing ; central Apennine ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 4
    Publication Date: 2022-06-10
    Description: Between January 2011 and April 2012, Santorini volcano (Greece) experienced a period of unrest characterised by the onset of detectable seismicity and caldera-wide uplift. This episode of inflation represented the first sizeable intrusion of magma beneath Santorini in the past 50 years. We employ a new approach using 222 Rn– δ 13 C systematics to identify and quantify the source of diffuse degassing at Santorini during the period of renewed activity. Soil CO 2 flux measurements were made across a network of sites on Nea Kameni between September 2010 and January 2012. Gas samples were collected in April and September 2011 for isotopic analysis of CO 2 ( δ 13 C), and radon detectors were deployed during September 2011 to measure ( 222 Rn). Our results reveal a change in the pattern of degassing from the summit of the volcano (Nea Kameni) and suggest an increase in diffuse CO 2 emissions between September 2010 and January 2012. High-CO 2 -flux soil gas samples have δ 13 C ∼ 0 .Using this value and other evidence from the literature we conclude that these CO 2 emissions from Santorini were a mixture between CO 2 sourced from magma, and CO 2 released by the thermal or metamorphic breakdown of crustal limestone. We suggest that this mixing of magmatic and crustal carbonate sources may account more broadly for the typical range of δ 13 CvaluesofCO 2 (from ∼− 4 to ∼+ 1 )in diffuse volcanic and fumarole gas emissions around the Mediterranean, without the need to invoke unusual mantle source compositions. At Santorini a mixing model involving magmatic CO 2 (with δ 13 C of − 3 ± 2 and elevated ( 222 Rn)/CO 2 ratios ∼ 10 5 –10 6 Bqkg − 1 )andCO 2 released from decarbonation of crustal limestone (with ( 222 Rn)/CO 2 ∼ 30–300 Bqkg − 1 ,and δ 13 Cof + 5 ) can account for the δ 13 C and ( 222 Rn)/CO 2 characteristics of the ‘high flux’ gas source. This model suggests ∼ 60% of the carbon in the high flux deep CO 2 end member is of magmatic origin. This combination of δ 13 Cand( 222 Rn) measurements has potential to quantify magmatic and crustal contributions to the diffuse outgassing of CO 2 in volcanic areas, especially those where breakdown of crustal limestone is likely to contribute significantly to the CO 2 flux
    Description: Published
    Description: 180-190
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: volcanic unrest ; soil gas measurements ; carbon isotopic analysis ; magmatic degassing ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 5
    Publication Date: 2024-05-09
    Description: Copahue volcano is part of the Caviahue–Copahue Volcanic Complex (CCVC),which is located in the southwestern sector of the Caviahue volcano-tectonic depression (Argentina–Chile). This depression is a pull-apart basin accommodating stresses between the southern Liquiñe–Ofqui strike slip and the northern Copahue–Antiñir compressive fault systems, in a back-arc setting with respect to the Southern Andean Volcanic Zone. In this study, we present chemical (inorganic and organic) and isotope compositions (δ13C-CO2, δ15N, 3He/4He, 40Ar/36Ar, δ13C-CH4, δD-CH4, and δD-H2O and δ18O-H2O) of fumaroles and bubbling gases of thermal springs located at the foot of Copahue volcano sampled in 2006, 2007 and 2012. Helium isotope ratios, the highest observed for a Southern American volcano (R/Ra up to 7.94), indicate a non-classic arc-like setting, but rather an extensional regime subdued to asthenospheric thinning. δ13C-CO2 values (from −8.8‰ to −6.8‰ vs. V-PDB), δ15N values (+5.3‰ to +5.5‰ vs. Air) and CO2/3He ratios (from 1.4 to 8.8 × 109) suggest that the magmatic source is significantly affected by contamination of subducted sediments. Gases discharged from the northern sector of the CCVC show contribution of 3He-poor fluids likely permeating through local fault systems. Despite the clear mantle isotope signature in the CCVC gases, the acidic gas species have suffered scrubbing processes by a hydrothermal system mainly recharged by meteoric water. Gas geothermometry in the H2O-CO2-CH4-CO-H2 system suggests that CO and H2 re-equilibrate in a separated vapor phase at 200°–220 °C. On the contrary, rock–fluid interactions controlling CO2, CH4 production from Sabatier reaction and C3H8 dehydrogenation seem to occur within the hydrothermal reservoir at temperatures ranging from 250° to 300 °C. Fumarole gases sampled in 2006–2007 show relatively low N2/He and N2/Ar ratios and high R/Ra values with respect to those measured in 2012. Such compositional and isotope variations were likely related to injection of mafic magma that likely triggered the 2000 eruption. Therefore, changes affecting the magmatic systemhad a delayed effect on the chemistry of the CCVC gases due to the presence of the hydrothermal reservoir. However, geochemical monitoring activities mainly focused on the behavior of inert gas compounds (N2 and He), should be increased to investigate the mechanism at the origin of the unrest started in 2011.
    Description: Published
    Description: 44–56
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: Fluid geochemistry ; Copahue volcano ; Fumarolic fluid ; Hydrothermal reservoir ; Volcanic unrest ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 6
    Publication Date: 2024-05-09
    Description: Measurements of soil fluxes of hydrothermal gases, with special emphasis on C6H6, as well as chemical composition of mono-aromatic compounds in fumaroles and air, were carried out in April 2012 at the Solfatara crater (Campi Flegrei, Southern Italy) to investigate the distribution and behavior of these species as they migrate through the soil from their deep source to the atmosphere. Soil fluxes of CO2, CH4 and C6H6 exhibit good spatial correlation, suggesting that diffuse degassing is mainly controlled by local fractures. The calculated total output of diffuse C6H6 from Solfatara is 0.10 kg day 1, whereas fluxes of CO2 and CH4 are 79 103 and 1.04 kg day 1, respectively. A comparison between soil gas fluxes and fumarole composition reveals that within the crater soil CH4 is significantly affected by oxidation processes, which are more efficient for low gas fluxes, being dependent on the residence time of the uprising hydrothermal gases at shallow depth. Benzene degradation, mainly proceeding through oxidation via benzoate, seems to be strongly controlled by the presence of a shallow SO2 4 -rich aquifer located in the central and southwestern sectors of the crater, suggesting that the process is particularly efficient when SO2 4 acts as terminal electron acceptor (SO4 reduction). Relatively high C6H6/C7H8 ratios, typical of hydrothermal fluids, were measured in air close to the main fumarolic field of Solfatara crater. Here, C6H6 concentrations, whose detection limit is 0.1 lgm 3, are more than one order of magnitude higher than the limit value for ambient air (5 lgm 3). This suggests that hydrothermal fluids have a strong impact on air quality in the immediate surroundings of the fumarolic vents. Significant concentrations of endogenous mono-aromatics were also detected in air samples collected from the northern and western sides of the crater, where these gas compounds are mostly fed by diffuse degassing through the crater bottom soil.
    Description: Published
    Description: 142–153
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: hydrothermal gases ; Solfatara crater ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 7
    Publication Date: 2020-11-26
    Description: During the July^August 2001 eruption of Mt. Etna development of extensional fractures/faults and grabens accompanied magma intrusion and subsequent volcanic activity. During the first days of the eruption, we performed an analysis of attitude, displacement and propagation of fractures and faults exposed on the ground surface in two sites, Torre del Filosofo and Valle del Leone, located along the same fracture system in the region surrounding the Valle del Bove depression on the eastern flank of Mt. Etna. Fractures and faults formed as the consequence of a shallow intruding dyke system that fed the several volcanic centres developed along the fracture system. The investigated sites differ in slope attitude and in geometrical relationships between fractures and slopes. In particular, the fracture system propagated parallel to the gentle slope (67‡ dip) in the Torre del Filosofo area, and perpendicular to the steep slope (V25‡ dip) in the Valle del Leone area. In the Torre del Filosofo area, slight graben subsidence and horizontal extension of the ground surface by about 3 m were recorded. In the Valle del Leone area, extensional faulting forming a larger and deeper graben with horizontal extension of the ground surface by about 10 m was recorded. For the Valle del Leone area, we assessed a downhill dip of 14‡ for the graben master fault at the structural level beneath the graben where the fault dip shallows. These results suggest that dyke intrusion at Mount Etna, and particularly in the region surrounding the Valle del Bove depression, may be at the origin of slope failure and subsequent slumps where boundary conditions, i.e. geometry of dyke, slope dip and initial shear stress, amongst others, favour incipient failures.
    Description: Published
    Description: 281-294
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 3.2. Tettonica attiva
    Description: 3.5. Geologia e storia dei sistemi vulcanici
    Description: 3.6. Fisica del vulcanismo
    Description: JCR Journal
    Description: reserved
    Keywords: dykes ; extensional fractures ; grabens ; slope failures ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.05. Stress ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 8
    Publication Date: 2021-01-07
    Description: The CO2 degassing process from a large area on the Tyrrhenian side of central Italy, probably related to the input into the upper crust of mantle fluids, was investigated in detail through the geochemical study of gas emissions and groundwater. Mass-balance calculations and carbon isotopes show that over 50% of the inorganic carbon in regional groundwater is derived from a deep source highlighting gas−liquid separation processes at depth. The deep carbonate−evaporite regional aquifer acts as the main CO2 reservoir and when total pressure of the reservoir fluid exceeds hydrostatic pressure, a free gas phase separates from the parent liquid and escapes toward the surface generating gas emissions which characterise the study area. The distribution of the CO2 flux anomalies and the location of high PCO2 springs and gas emissions suggest that the storage and the expulsion of the CO2 toward the atmosphere are controlled by the geological and structural setting of the shallow crust. The average CO2 flux and the total amount of CO2 discharged by the study area were computed using surface heat flow, enthalpy and CO2 molality of the liquid phase circulating in the deep carbonate−evaporite aquifer. The results show that the CO2 flux varies from 1×104 mol y−1 km−2 to 5×107 mol y−1 km−2, with an average value of 4.8×106 mol y−1 km−2, about five times higher than the value of 1×106 mol y−1 derived by Kerrick et al. [Kerrick, D.M., McKibben, M.A., Seward, T.M., Caldeira, K., 1995. Convective hydrothermal CO2 emission from high heat flow regions. Chem. Geol. 121, 285–293] as baseline for terrestrial CO2 emissions. The total CO2 discharged from the study area is 0.9×1011 mol y−1, confirming that Earth degassing from Tyrrhenian central Italy is a globally relevant carbon source
    Description: Published
    Description: 89–102
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Degassamento naturale
    Description: JCR Journal
    Description: reserved
    Keywords: Earth degassing ; carbon dioxide ; CO2 flux ; groundwater ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 9
    Publication Date: 2020-11-17
    Description: Mt. Etna in Sicily (Italy) is one of the best monitored basaltic volcanoes in the world due to the frequent eruptions from its summit and flanks. Routine monitoring carried out by the Istituto Nazionale di Geofisica e Vulcanologia, Sezione di Catania, for surveillance purposes permits following the evolution of volcanic events. In this paper, a description of the ash monitoring system as occurred during the August-December 2006 summit eruption at the Southeast Crater (SEC) is shown. This eruption was characterized by lava flow effusions and vigorous Strombolian activity. Eighteen paroxysmal episodes occurred up to the end of November, forming weak ash plumes accompanied by moderate tephra fallout over Etna’s slopes. During these events, we applied a multidisciplinary approach to promptly monitor the paroxysmal activity and the associated tephra fallout, through analysis from seismic tremor and observation from live-cameras, sampling operations, mapping and analysis of the deposit. During the most significant episodes, we carried out textural and grain-size analysis on tephra samples and evaluated the whole grain-size deposit and the erupted volume, while numerical simulations of tephra dispersal allowed better understanding eruptive dynamics. An example of this methodology is applied to the 16 November episode, during which seismic tremor furnished important constraints on the chronology. This paroxysmal eruption produced light fallout on the north-east sector of the volcano for about ten hours and a number of debris-avalanches over the slopes of the SEC cone. The erupted deposit was composed for the most part of lithic components and characterized by a whole grain-size distribution centered on 2.2 , while its total mass was evaluated 7 x 106 kg. On the whole, such integrated studies help to obtain information on magma fragmentation and eruptive mechanisms, to characterize the explosive styles shown by Etna and finally, to better approach the monitoring of imminent eruptions.
    Description: FIRB Italian project “Sviluppo Nuove Tecnologie per la Protezione e Difesa del Territorio dai Rischi Naturali” funded by Italian Minister of University and Research
    Description: Published
    Description: 123-134
    Description: 5V. Processi eruttivi e post-eruttivi
    Description: JCR Journal
    Description: open
    Keywords: Mt. Etna ; volcanic ash monitoring ; tephra deposit ; 2006 eruption ; 04. Solid Earth::04.06. Seismology::04.06.06. Surveys, measurements, and monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 10
    Publication Date: 2021-05-17
    Description: Papandayan is a stratovolcano situated in West Java, Indonesia. Since the last magmatic eruption in 1772,only few hydrothermal explosions have occurred. An explosive eruption occurred in November 2002 and ejected ash and altered rocks. The altered rocks show that an advanced argillic alteration took place in the hydrothermal system by interaction between acid fluids and rocks. Four zones of alteration have been defined and are limited in extension and shape along faults or across permeable structures at different levels beneath the active crater of the volcano. At the present time, the activity is centered in the northeast crater with discharge of low temperature fumaroles and acid hot springs. Two types of acid fluids are emitted in the crater of Papandayan volcano: (1) acid sulfate-chloride waters with pH between 1.6 and 4.6 and (2) acid sulfate waters with pH between 1.2 and 2.5. The water samples collected after the eruption on January 2003 reveal an increase in the SO4/Cl and Mg/Cl ratios. This evolution is likely explained by an increase in the neutralization of acid fluids and tends to show that water–rock interactions were more significant after the eruption. The evolution in the chemistry observed since 2003 is the consequence of the opening of new fractures at depth where unaltered (or less altered) volcanic rocks were in contact with the ascending acid waters. The high δ34S values (9–17‰) observed in acid sulfatechloride waters before the November 2002 eruption suggest that a significant fraction of dissolved sulfates was formed by the disproportionation of magmatic SO2. On the other hand, the low δ34S (−0.3–7‰) observed in hot spring waters sampled after the eruption suggest that the hydrothermal contribution (i.e. the surficial oxidation of hydrogen sulfide) has increased.
    Description: Published
    Description: 276-286
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: JCR Journal
    Description: reserved
    Keywords: Papandayan volcano ; Indonesia ; phreatic eruption ; hydrothermal system ; fluid geochemistry ; advanced argillic alteration ; gas geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 11
    Publication Date: 2017-04-04
    Description: The October 17 to November 5, 1999, eruption of Mount Etna’s Bocca Nuova crater emplaced a V15U106 m3 flow field. The eruption was characterized by 11 paroxysmal events during which intense Strombolian and lava fountain activity fed vigorous channelized PaPa flows at eruption rates of up to 120 m3 s31. Each paroxysm lasted between 75 and 450 min, and was separated by periods of less intense Strombolian activity and less vigorous (610 m3 s31) effusion. Ground-based, satellite- and model-derived volumetric data show that the eruption was characterized by two periods during which eruption rates and cumulative volume showed exponential decay. This is consistent with a scenario whereby the system was depressurized during the first eruptive period (October 17^23), repressurized during an October 24 pause, and then depressurized again during the second period (October 25^28). The imbalance between the erupted and supplied volumes mean that the two periods involved the collection of 1.5^5.7U106 m3 and 1.2^ 3.6U106 m3, respectively, or an increase in the time-averaged supply to 11.6^13.6 m3 s31 and 12.5^14.9 m3 s31. Two models are consistent with the observed episodic fountaining, derived volumetric trends and calculated volume imbalance: a magma collection model and a pulsed supply model. In the former case, depressurization of a shallow reservoir cause the observed volumetric trends and foam collapse at the reservoir roof powers fountaining. In the pulsing case, variations in magma flux account for pressurization^depressurization and supply the excess volume. Increases in rise rate and volatile flux, coupled with rapid exsolution during ascent, trigger fountaining. Limiting equations that define critical foam layer volumes and magma rise rates necessary for Hawaiian-style fountaining favor the latter model.
    Description: Published
    Description: 79-95
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 3.5. Geologia e storia dei sistemi vulcanici
    Description: 3.6. Fisica del vulcanismo
    Description: 4.3. TTC - Scenari di pericolosità vulcanica
    Description: JCR Journal
    Description: reserved
    Keywords: Etna ; lava fountaining ; eruption rates ; lava channel ; foam layers ; rise rates ; 04. Solid Earth::04.01. Earth Interior::04.01.99. General or miscellaneous ; 04. Solid Earth::04.01. Earth Interior::04.01.05. Rheology ; 04. Solid Earth::04.02. Exploration geophysics::04.02.99. General or miscellaneous ; 04. Solid Earth::04.02. Exploration geophysics::04.02.05. Downhole, radioactivity, remote sensing, and other methods ; 04. Solid Earth::04.02. Exploration geophysics::04.02.07. Instruments and techniques ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.11. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.02. Experimental volcanism ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.04. Thermodynamics ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 12
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    Springer-Verlag
    Publication Date: 2017-04-04
    Description: The July-August 2001 eruption of Mt. Etna stimulated widespread public and media interest, caused significant damage to tourist facilities, and for several days threatened the town of Nicolosi on the S flank of the volcano. Seven eruptive fissures were active, five on the S flank between 3050 and 2100 m altitude, and two on the NE flank between 3080 and 2600 m elevation. All produced lava flows over various periods during the eruption, the most voluminous of which reached a length of 6.9 km. Mineralogically the 2001 lavas fall into two distinct groups, indicating that magma was supplied through two different and largely independent pathways, one extending laterally from the central conduit system through radial fissures, the other being a vertically ascending eccentric dike. Furthermore one of the eccentric vents, at 2570 m elevation, was the site of vigorous phreatomagmatic activity as the dike cut through a shallow aquifer, both during the intial and closing stages of the eruption. For six days the magma column feeding this vent was more or less effectively sealed from the aquifer, permitting powerful explosive and effusive magmatic activity. While the eruption was characterized by a highly dynamic evolution, complex interactions between some of the eruptive fissures, and changing eruptive styles, its total volume (~25 x 106 m3 of lava and 5-10 x 106 m3 of pyroclastics) was relatively small in comparison with other recent eruptions of Etna. Effusion rates were calculated on a daily basis and reached peaks of 14-16 m3 s-1 while the average effusion rate at all fissures was about 11 m3 s-1, which is not exceptionally high. The eruption showed a number of peculiar features, but none of these (except the contemporaneous lateral and eccentric activity) represented a significant deviation from Etna's eruptive behavior in the long term. However, the 2001 eruption could be but the first in a series of flank eruptions, some of which might be more voluminous and hazardous. Placed in a long-term context, the eruption confirms a distinct trend, initiated during the past 50 years, toward higher production rates and more frequent eruptions, which might bring Etna back to similar levels of activity as during the early to mid 17th century.
    Description: Published
    Description: 461-476
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 3.5. Geologia e storia dei sistemi vulcanici
    Description: 3.6. Fisica del vulcanismo
    Description: 4.3. TTC - Scenari di pericolosità vulcanica
    Description: JCR Journal
    Description: reserved
    Keywords: Mt. Etna ; 2001 eruption ; Lava flow-field evolution ; Central-lateral vs. eccentric activity ; Phreatomagmatism ; Eruption dynamics ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.07. Tectonophysics::04.07.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 13
    Publication Date: 2017-04-04
    Description: Six hundred and sixty-seven water samples were collected from public drinking water supplies in Sicily and analysed for electric conductivity and for their Cl-, Br- and F- contents. The samples were, as far as possible, collected evenly over the entire territory with an average sampling density of about one sample for every 7600 inhabitants. The contents of Cl- and Br-, ranging between 5.53 and 1302 mg/l and between 〈 0.025 and 4.76 mg/l respectively, correlated well with the electric conductivity, a parameter used as a proxy for water salinity. The highest values were found both along the NW and SE coasts, which we attributed to seawater contamination, and in the central part of Sicily, which we attributed to evaporitic rock dissolution. The fluoride concentrations ranged from 0.023 to 3.28 mg/l, while the highest values (only 3 exceeding the maximum admissible concentration of 1.5 mg/l) generally correlated either with the presence in the area of crystalline (volcanic or metamorphic) or evaporitic rocks or with contamination from hydrothermal activity. Apart from these limited cases of exceeding F- levels, the waters of public drinking water supplies in Sicily can be considered safe for human consumption for the analysed parameters. Some limited concern could arise from the intake of bromide-rich waters (about 3% exceeding 1 mg/l) because of the potential formation of dangerous disinfection by-products.
    Description: Published
    Description: 303-313
    Description: 4.4. Scenari e mitigazione del rischio ambientale
    Description: JCR Journal
    Description: reserved
    Keywords: drinking water quality ; fluoride ; bromide ; chloride ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 14
    Publication Date: 2017-04-04
    Description: El Chichón volcano (Chiapas, Mexico) erupted violently in March–April 1982, breaching through the former volcano–hydrothermal system. Since then, the 1982 crater has hosted a shallow (1–3.3 m, acidic (pH ∼ 2.2) and warm (∼ 30 °C) crater lake with a strongly varying chemistry (Cl/SO4=0–79 molar ratio). The changes in crater lake chemistry and volume are not systematically related to the seasonal variation of rainfall, but rather to the activity of near-neutral geyser-like springs in the crater (Soap Pool). These Soap Pool springs are the only sources of Cl for the lake. Their geyser-like behaviour with a long-term (months to years) periodicity is due to a specific geometry of the shallow boiling aquifer beneath the lake, which is the remnant of the 1983 Cl-rich (24,000 mg/l) crater lake water. The Soap Pool springs decreased in Cl content over time. The zero-time extrapolation (1982, year of the eruption) approaches the Cl content in the initial crater lake,meanwhile the extrapolation towards the future indicates a zero-Cl content by 2009±1. This particular situation offers the opportunity to calculate mass balance and Cl budget to quantify the lake–spring system in the El Chichón crater. These calculations show that the water balance without the input of SP springs is negative, implying that the lake should disappear during the dry season. The isotopic composition of lake waters (δD and δ18O) coincide with this crater lake-SP dynamics, reflecting evaporation processes and mixing with SP geyser and meteoric water. Future dome growth, not observed yet in the post-1982 El Chichón crater, may be anticipated by changes in lake chemistry and dynamics.
    Description: Published
    Description: 237–248
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: JCR Journal
    Description: reserved
    Keywords: El Chichón volcano ; crater lake–Spring dynamics ; fluid geochemistry ; stable isotopes ; monitoring ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 15
    Publication Date: 2017-04-04
    Description: El Chichón crater lake appeared immediately after the 1982 catastrophic eruption in a newly formed, 1-km wide, explosive crater. During the first 2 years after the eruption the lake transformed from hot and ultraacidic caused by dissolution of magmatic gases, to a warm and less acidic lake due to a rapid “magmatic-tohydrothermal transition” — input of hydrothermal fluids and oxidation of H2S to sulfate. Chemical composition of the lake water and other thermal fluids discharging in the crater, stable isotope composition (δD and δ18O) of lake water, gas condensates and thermal waters collected in 1995–2006 were used for the mass-balance calculations (Cl, SO4 and isotopic composition) of the thermal flux from the crater floor. The calculated fluxes of thermal fluid by different mass-balance approaches become of the same order of magnitude as those derived from the energy-budget model if values of 1.9 and 2 mmol/mol are taken for the catchment coefficient and the average H2S concentration in the hydrothermal vapors, respectively. The total heat power from the crater is estimated to be between 35 and 60 MW and the CO2 flux is not higher than 150 t/day or ~200 gm−2 day−1.
    Description: Published
    Description: 472-481
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: JCR Journal
    Description: reserved
    Keywords: El Chichón ; crater lake ; mass-energy budget ; CO2 flux ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.02. Data dissemination::05.02.04. Hydrogeological data
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 16
    Publication Date: 2017-04-04
    Description: Historical sources have recorded earthquake shocks, their effects and difficulties that local inhabitants experienced before the AD 79 Pompeii eruption. Archaeological studies pointed out the effects of such seismicity, and have also evidenced that several water crises were occurring at Pompeii in that period. Indeed numerous sources show that, at the time of eruption, and probably some time before, the civic aqueduct, having ceased to be supplied by the regional one, was out of order and that a new one was being built. Since Roman aqueducts were usually built with a recommended minimum mean slope of 20 cm/km and Pompeii's aqueduct sloped from the nearby Apennines toward the town, this slope could have been easily cancelled by uplift that occurred in the area even if this was only moderate. For the crustal deformations a volcanic origin is proposed and a point source model is used to explain the observations. Simple analysis of the available data suggests that the ground deformations were caused by a b2 km3 volumetric change at a depth of ∼8 km that happened over the course of several decades.
    Description: Published
    Description: 959–970
    Description: 5.1. TTC - Banche dati e metodi macrosismici
    Description: JCR Journal
    Description: reserved
    Keywords: Vesuvius ; ground deformation ; seismicity ; stress changes ; 04. Solid Earth::04.03. Geodesy::04.03.06. Measurements and monitoring ; 04. Solid Earth::04.06. Seismology::04.06.05. Historical seismology ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 17
    Publication Date: 2017-04-04
    Description: In a geothermal area, a detailed knowledge of the three-dimensional velocity structures aids the managementof the field and the further development of the geothermal source. Here,we present a high-resolution study of the three-dimensional S-wave velocity structures from microearthquake travel times for the Larderello-Travale geothermal field, Italy.We have also deduced the Vp/Vs and Vp ×Vs parameters for this area toemphasize the deep variations in the physical rock properties due to fluid content and porosity. Furthermore, effective porousmedium modelling has been performed for site-relevant lithologies, to improve our interpretation of the results in terms of rock physics signatures. This has allowed us to estimate the variation range of the seismological parameters investigated, as well as their sensitivity for suitable rock under specific physical conditions. LowVp/Vs anomalies, arising froma lower Vp compared to Vs, dominate the geothermal field of Larderello-Travale. These have been interpreted as due to steam-bearing formations. On the contrary, analysis of Vp ×Vs images provides information on the relative changes in rock porosity at depth. Comparison of tomographic section images with previously interpreted seismic lines suggests that the reflective ‘K-horizon’ delineates a transition between zones that have different porosities or crack gatherings. The ‘K-horizon’ also lies on low Vp/Vs anomalies, which suggests a steam saturation zone, despite the reduced porosity at this depth.
    Description: In press
    Description: 1.4. TTC - Sorveglianza sismologica delle aree vulcaniche attive
    Description: JCR Journal
    Description: open
    Keywords: P- and S-wave velocity ; Seismic tomography images ; Geothermal field ; Rock properties ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 18
    Publication Date: 2017-04-04
    Description: Mount Etna is an open conduit volcano, characterised by persistent activity, consisting of degassing and explosive phenomena at summit craters, frequent flank eruptions, and more rarely, eccentric eruptions. All eruption typologies can give rise to lava flows, which represent the greatest hazard by the volcano to the inhabited areas. Historical documents and scientific papers related to the 20th century effusive activity have been examined in detail, and volcanological parameters have been compiled in a database. The cumulative curve of emitted lava volume highlights the presence of two main eruptive periods: (a) the 1900–1971 interval, characterised by a moderate slope of the curve, amounting to 436 · 106 m3 of lava with average effusion rate of 0.2 m3/s and (b) the 1971–1999 period, in which a significant increase in eruption frequency is associated with a large issued lava volume (767 · 106 m3) and a higher effusion rate (0.8 m3/s). The collected data have been plotted to highlight different eruptive behaviour as a function of eruptive periods and summit vs. flank eruptions. The latter have been further subdivided into two categories: eruptions characterised by high effusion rates and short duration, and eruptions dominated by low effusion rate, long duration and larger volume of erupted lava. Circular zones around the summit area have been drawn for summit eruptions based on the maximum lava flow length; flank eruptions have been considered by taking into account the eruptive fracture elevation and combining them with lava flow lengths of 4 and 6 km. This work highlights that the greatest lava flow hazard at Etna is on the south and east sectors of the volcano. This should be properly considered in future land-use planning by local authorities.
    Description: Published
    Description: 407–443
    Description: 4.3. TTC - Scenari di pericolosità vulcanica
    Description: JCR Journal
    Description: reserved
    Keywords: Mt. Etna ; effusive activity ; database ; lava flow length ; eruptive fractures ; vent elevation ; hazard zonation ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 19
    Publication Date: 2017-04-04
    Description: The 2001 eruption represents one of the most studied events both from volcanological and geophysical point of view on Mt. Etna. This eruption was a crucial event in the recent dynamic of the volcano, marking the passage from a period (March 1993 – June 2001) of moderate stability with slow, continuous flank sliding and contemporaneous summit eruptions, to a period (July 2001 to present) of dramatically increased flank deformations and flank eruptions. We show new GPS data and high precision relocation of seismicity in order to demonstrate the role of the 2001 intrusive phase in this change of the dynamic regime of the volcano. GPS data consist of two kinematic surveys carried out on 12 July, a few hours before the beginning of the seismic swarm, and on 17 July, just after the onset of eruptive activity. A picture of the spatial distribution of the sin-eruptive seismicity has been obtained using the HypoDD relocation algorithm based on the double-difference (DD) technique. Modeling of GPS measurements reveal a southward motion of the upper southern part of the volcano, driven by a NNW-SSE structure showing mainly left-lateral kinematics. Precise hypocenter location evidences an aseismic zone at about sea level, where the magma upraise was characterized by a much higher velocity and an abrupt westward shift, revealing the existence of a weakened or ductile zone. These results reveal how an intrusion of a dike can severely modify the shallow stress field, triggering significant flank failure. In 2001, the intrusion was driven by a weakened surface, which might correspond to a decollement plane of the portion of the volcano affected by flank instability, inducing an additional stress testified by GPS measurements and seismic data, which led to an acceleration of the sliding flanks.
    Description: In press
    Description: 1.1. TTC - Monitoraggio sismico del territorio nazionale
    Description: 1.3. TTC - Sorveglianza geodetica delle aree vulcaniche attive
    Description: 1.4. TTC - Sorveglianza sismologica delle aree vulcaniche attive
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 3.2. Tettonica attiva
    Description: 3.5. Geologia e storia dei sistemi vulcanici
    Description: 3.6. Fisica del vulcanismo
    Description: 4.2. TTC - Scenari e mappe di pericolosità sismica
    Description: 4.3. TTC - Scenari di pericolosità vulcanica
    Description: 4.4. Scenari e mitigazione del rischio ambientale
    Description: JCR Journal
    Description: reserved
    Keywords: Stress release ; Dike ; Volcano-tectonics ; Flank instability ; Mount Etna ; Instrumental monitoring ; 04. Solid Earth::04.01. Earth Interior::04.01.99. General or miscellaneous ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes ; 04. Solid Earth::04.02. Exploration geophysics::04.02.99. General or miscellaneous ; 04. Solid Earth::04.03. Geodesy::04.03.99. General or miscellaneous ; 04. Solid Earth::04.03. Geodesy::04.03.06. Measurements and monitoring ; 04. Solid Earth::04.03. Geodesy::04.03.07. Satellite geodesy ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.01. Earthquake geology and paleoseismology ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.06. Seismology::04.06.99. General or miscellaneous ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics ; 04. Solid Earth::04.06. Seismology::04.06.04. Ground motion ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 04. Solid Earth::04.07. Tectonophysics::04.07.99. General or miscellaneous ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.05. Stress ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
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  • 20
    Publication Date: 2017-04-04
    Description: Most flank eruptions within a central stratovolcano are triggered by lateral draining of magma from its central conduit, and only few eruptions appear to be independent of the central conduit. In order to better highlight the dynamics of flank eruptions in a central stratovolcano, we review the eruptive history of Etna over the last 100 years. In particular, we take into consideration the Mount Etna eruption in 2001, which showed both summit activity and a flank eruption interpreted to be independent from the summit system. The eruption started with the emplacement of a ~N-S trending peripheral dike, responsible for the extrusion of 75% of the total volume of the erupted products. The rest of the magma was extruded through the summit conduit system (SE crater), feeding two radial dikes. The distribution of the seismicity and structures related to the propagation of the peripheral dike and volumetric considerations on the erupted magmas exclude a shallow connection between the summit and the peripheral magmatic systems during the eruption. Even though the summit and the peripheral magmatic systems were independent at shallow depths (〈3 km b.s.l.), petro-chemical data suggest that a common magma rising from depth fed the two systems. This deep connection resulted in the extrusion of residual magma from the summit system and of new magma from the peripheral system. Gravitational stresses predominate at the surface, controlling the emplacement of the dikes radiating from the summit; conversely, regional tectonics, possibly related to N-S trending structures, remains the most likely factor to have controlled at depth the rise of magma feeding the peripheral eruption.
    Description: Published
    Description: 517-529
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 3.2. Tettonica attiva
    Description: 3.5. Geologia e storia dei sistemi vulcanici
    Description: 3.6. Fisica del vulcanismo
    Description: 4.3. TTC - Scenari di pericolosità vulcanica
    Description: JCR Journal
    Description: reserved
    Keywords: Central volcanoes ; Summit and flank eruptions ; Dikes ; Tectonics ; Volcano load ; Mount Etna ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.07. Tectonophysics::04.07.05. Stress ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
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  • 21
    Publication Date: 2017-04-04
    Description: During an eruption at the Bocca Nuova, one of the summit craters of Mt. Etna, in October-November 1999 a part of the crater floor near its WNW rim was uplifted to form a dome-shaped feature that consisted of older lava and pyroclastics filling the crater. This endogenous dome grew rapidly over the crater rim, thus being perched precariously over the steep outer slope of the Bocca Nuova, and near-continuous collapse of its steep flanks generated swiftly moving pyroclastic avalanches over a period of several hours. These avalanches advanced at speeds of 10-20 m s-1 and extended up to 0.7 km from their source on top of lavas emplaced immediately before. Their deposits were subsequently covered by lava flows that issued from vents below the front of the dome and from the Bocca Nuova itself. Growth of the dome was caused by the vertical intrusion of magma in the marginal W part of the crater, which deformed and uplifted previously emplaced, still hot and plastically deformable eruptive products filling the crater. The resulting avalanches had all characteristics of pyroclastic flows spawned by collapse of unstable flanks of lava domes, but in this case the magma involved was of mafic (hawaiitic) composition and would have, under normal circumstances, produced fluid lava flows. The formation of the dome and the generation of the pyroclastic avalanches owe their occurrence to the rheological properties of the eruptive products filling the crater, which were transformed into the dome, and to the morphological configuration of the Bocca Nuova and its surroundings. The density contrast between successive erupted products may also have played a role. Although events of this type are to be considered exceptional at Etna, their recurrence might represent a serious hazard to visitors to the summit area.
    Description: Published
    Description: 115-128
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: JCR Journal
    Description: reserved
    Keywords: Mt. Etna ; Bocca Nuova ; endogenous lava dome ; pyroclastic avalanches ; magma ascent ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions ; 05. General::05.08. Risk::05.08.99. General or miscellaneous
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  • 22
    Publication Date: 2017-04-04
    Description: Four groups of thermal springs with temperatures from 50 to 80 °C are located on the S–SW–W slopes of El Chichón volcano, a composite dome-tephra edifice, which exploded in 1982 with a 1 km wide, 160 m deep crater left. Very dynamic thermal activity inside the crater (variations in chemistry and migration of pools and fumaroles, drastic changes in the crater lake volume and chemistry) contrasts with the stable behavior of the flank hot springs during the time of observations (1974–2005). All known groups of hot springs are located on the contact of the basement and volcanic edifice, and only on the W–SW–S slopes of the volcano at almost same elevations 600–650 m asl and less than 3 km of direct distance from the crater. Three groups of near-neutral (pH≈6) springs at SW–S slopes have the total thermal water outflow rate higher than 300 l/s and are similar in composition. The fourth and farthest group on the western slope discharges acidic (pH≈2) saline (10 g/kg of Cl) water with a much lower outflow rate (b10 l/s). Water–rock interaction modeling of main types of the El Chichón thermal waters using regular log Q/K graphs (saturation indices vs temperature) showed maximum equilibrium temperature slightly higher than 200 °C. Acidic waters are equilibrated with some clay minerals at about 120 °C. Three main sources of the salinity of thermal water are suggested on the basis of mixing plots and isotopic data: a magmatic source for CO2, boron, sulfur and a limited part of Cl; volcanic rock source for the major cations and trace elements; the oil-bearing evaporitic basement source (oil-field brine?) for NaCl, Br, a part of Ca and some trace elements. All flank thermal springs end up in the river Rio Magdalena that has a variable seasonal flow rates from 4 to 20 m3/s. Any changes in the chemistry of springs must notably change the composition of the streams draining hot springs and eventually, Rio Magdalena. A monthly geochemical monitoring of Rio Magdalena and streams draining main hot springs would be a useful tool for surveying the activity of the volcano.
    Description: Published
    Description: 224–236
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: JCR Journal
    Description: reserved
    Keywords: volcano–hydrothermal system ; crater lake ; acidic water ; trace elements ; thermochemical modeling ; El Chichón volcano ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
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  • 23
    Publication Date: 2017-04-04
    Description: During 1999, the volcanic activity at Mt. Etna was both explosive and effusive at the summit craters: Strombolian activity, lava fountains and lava flows affected different areas of the volcano, involving three of the four summit craters. Results from analysis of the 1999 volcanic tremor features are shown at two different time scales. First, the long-term time variation of the features of the volcanic tremor (including spectral and polarization parameters), during the entire year, was compared with the evolution of the eruptive activity. This approach demonstrated the good agreement between tremor data and observed eruptive activity; the activation of different tremor sources was suggested. Then, a more refined analysis of the volcanic tremor, recorded during 14 lava fountain eruptions, was performed. In particular, a shift of the dominant frequencies towards lower values was noted which corresponds with increasing explosive activity. Similar behaviour in the frequency content has already been observed in other explosive eruptions at Mt. Etna as well as on other volcanoes. This behaviour has been explained in terms of either an increase in the tremor source dimension or a decrease in the sound speed in the magma within the conduit. These results confirm that the volcanic tremor is a powerful tool for better understanding the physical processes controlling explosive eruptions at Mt. Etna volcano.
    Description: Published
    Description: 19-31
    Description: 1.4. TTC - Sorveglianza sismologica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: Mt. Etna ; volcanic tremor ; spectral and polarization analysis ; effusive and explosive activity ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 24
    Publication Date: 2017-04-04
    Description: The 1631 Vesuvius eruption is one of its best known and most studied of its type. However, the historical approach performed within the framework of the Exploris project highlighted new evidence from previously unused or unknown historical sources. These consist of three treatises that were contemporary to the event; although written in Latin, they have been fully translated and analysed. To guarantee systematic use and open access to the large amount of information they contain, they have been provided as a small database. These treatises have provided new information on phenomena that preceded and accompanied the eruption of 1631, making possible the formation of a complex chronological profile, starting from around 6 months before the eruption. The anthropic impact is also outlined. The method applied has produced a chronology of “cold data”, which are not interpreted from the volcanological standpoint, but only derived directly from the analysed history and sequence of the texts. The analysis of the three treatises has not, however, solved all of the problems connected with the detailed knowledge of the event in 1631. Indeed, problems of two kinds persist: a) linguistic correspondence between the volcanological terms of today and those used in the texts; b) the lack of precision of the measures indicated. Here, the main results obtained from this analysis method are presented, along with a discussion of their limitations and some new perspectives.
    Description: Published
    Description: 347-358
    Description: 3.10. Sismologia storica e archeosismologia
    Description: JCR Journal
    Description: reserved
    Keywords: historical volcanology ; Vesuvius ; 1631 eruption chronology ; precursors ; treatises ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
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  • 25
    Publication Date: 2017-04-04
    Description: Eruptions are often fed by dikes; therefore, better knowledge of dike propagation is necessary to improve our understanding of how magma is transferred and extruded at volcanoes. This study presents an overview of dike patterns and the factors controlling dike propagation within volcanic edifices. Largely based on published data, three main types of dikes (regional, circumferential and radial) are illustrated and discussed. Dike pattern data from 25 volcanic edifices in different settings are compared to derive semi-quantitative relationships between the topography (relief, shape, height, and presence of sector collapses) of the volcano, tectonic setting (presence of a regional stress field), and mean composition (SiO2 content). The overview demonstrates how dike propagation in a volcano is not a random process; rather, it depends from the following factors (listed in order of importance): the presence of relief, the shape of the edifice and regional tectonic control. We find that taller volcanoes develop longer radial dikes, whose (mainly lateral) propagation is independent of the composition of magma or the aspect ratio of the edifice. Future research, starting from these preliminary evaluations, should be devoted to identifying dike propagation paths and likely locations of vent formation at specific volcanoes, to better aid hazards assessment.
    Description: In press
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 3.2. Tettonica attiva
    Description: 3.5. Geologia e storia dei sistemi vulcanici
    Description: 3.6. Fisica del vulcanismo
    Description: 4.3. TTC - Scenari di pericolosità vulcanica
    Description: JCR Journal
    Description: open
    Keywords: dikes ; volcanoes ; topography ; tectonic setting ; eruptions ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.07. Tectonophysics::04.07.99. General or miscellaneous ; 04. Solid Earth::04.07. Tectonophysics::04.07.05. Stress ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 26
    Publication Date: 2017-04-04
    Description: An extensive geochemical survey of the fluids released by the volcanic/geothermal system of Methana was undertaken. Gases were characterized based on the chemical and isotopic [helium (He) and carbon (C)] analysis of 27 samples. Carbon dioxide soil gas concentration and fluxes were measured at 179 sampling sites throughout the peninsula. Forty samples of thermal and cold groundwaters were also sampled and analysed to characterize the geochemistry of the aquifers. Gases of hydrothermal origin gave a preliminary geothermometric estimate of about 210 °C. The He-isotope composition indicated mantle contributions of up to 40%, and the C-isotope composition of CO2 indicated that it predominantly (〉90%) originated from limestone decomposition. The groundwater composition was suggestive of mixing between meteoric and hydrothermally modified sea-water endmembers and water–rock interaction processes limited to simple rock dissolution driven by an increased endogenous CO2 content. All of the thermal manifestations and anomalous degassing areas, although of limited extent, were spatially correlated with the main active tectonic system of the area. The total CO2 output of the volcanic system has been preliminary estimated to be less than 0.05 kg s–1. Although this value is very low compared to those of other volcanic systems, anomalous CO2 degassing at Methana – which is currently restricted to limited areas and at present is the only volcanic risk of the peninsula – is a potential gas hazard that warrants further assessment in future studies.
    Description: Published
    Description: 818-828
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: Methana ; south Aegean volcanic arc ; fluids geochemistry ; soil gases ; groundwaters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
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  • 27
    Publication Date: 2017-04-04
    Description: This study presents baseline data for future geochemical monitoring of the active Tacaná volcano–hydrothermal system (Mexico–Guatemala). Seven groups of thermal springs, related to a NW/SE-oriented fault scarp cutting the summit area (4,100m a.s.l.), discharge at the northwest foot of the volcano (1,500–2,000m a.s.l.); another one on the southern ends of Tacaná (La Calera). The near-neutral (pH from 5.8 to 6.9) thermal (T from 25.7°C to 63.0°C) HCO3–SO4 waters are thought to have formed by the absorption of a H2S/SO2–CO2-enriched steam into a Cl-rich geothermal aquifer, afterwards mixed by Na/HCO3-enriched meteoric waters originating from the higher elevations of the volcano as stated by the isotopic composition (δD and δ18O) of meteoric and spring waters. Boiling temperature fumaroles (89°C at~3,600m a.s.l. NW of the summit), formed after the May 1986 phreatic explosion, emit isotopically light vapour (δD and δ18O as low as −128 and −19.9‰, respectively) resulting from steam separation from the summit aquifer. Fumarolic as well as bubbling gases at five springs are CO2-dominated. The δ13CCO2 for all gases show typical magmatic values of −3.6 ± 1.3‰ vs V-PDB. The large range in 3He/4He ratios for bubbling, dissolved and fumarolic gases [from 1.3 to 6.9 atmospheric 3He/4He ratio (RA)] is ascribed to a different degree of near-surface boiling processes inside a heterogeneous aquifer at the contact between the volcanic edifice and the crystalline basement (4He source). Tacaná volcano offers a unique opportunity to give insight into shallow hydrothermal and deep magmatic processes affecting the CO2/3He ratio of gases: bubbling springs with lower gas/water ratios show higher 3He/4He ratios and consequently lower CO2/3He ratios (e.g. Zarco spring). Typical Central American CO2/3He and 3He/4He ratios are found for the fumarolic Agua Caliente and Zarco gases (3.1 ± 1.6 × 1010 and 6.0 ± 0.9 RA, respectively). The L/S (5.9 ± 0.5)and (L + S)/M ratios (9.2 ± 0.7) for the same gases are almost identical to the ones calculated for gases in El Salvador, suggesting an enhanced slab contribution as far as the northern extreme of the Central American Volcanic Arc,Tacana
    Description: In press
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: JCR Journal
    Description: reserved
    Keywords: Tacaná volcano ; Fluid geochemistry ; Volcano–hydrothermal system ; Bubbling gases ; Fumaroles ; Isotopes ; Volcanic surveillance ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
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  • 28
    Publication Date: 2017-04-04
    Description: The 1224 Mt. Etna eruption is a significant event both in terms of the mass of erupted materials and because it involved the lower eastern slope of the volcano, reaching down to the sea. Nevertheless, it is unknown to current historical catalogues. According to the historical sources, only two other lava flows actually reached as far as the sea: in 396 BC, just north of the present-day inhabited area of Acireale, according to the geological data alone, and in 1669, when the lava covered the south-eastern flank of Mt. Etna and damaged Catania. We present and discuss the two medieval sources that attest to the eruption of 1224 and make available the original texts. Furthermore, through the close analysis of the historical and topographic context of the Etna area, taking account of the roads and ports in the early 13th century, we have tried to single out the possible area of the lava's outlet into the sea in 1224 on historical grounds. A repeat of an eruption similar to that of 1224 would have a serious impact to day as the coast is densely populated.
    Description: Published
    Description: 693-700
    Description: 3.10. Sismologia storica e archeosismologia
    Description: JCR Journal
    Description: open
    Keywords: historical volcanology ; Etna ; medieval eruptions ; historical catalogues ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 29
    Publication Date: 2017-04-04
    Description: Research article
    Description: Quantifying the contribution of volcanism to global mercury (Hg) emissions is important to understand the pathways and the mechanisms of Hg cycling through the Earth's geochemical reservoirs and to assess its environmental impacts. While previous studies have suggested that degassing volcanoes might contribute importantly to the atmospheric budget of mercury, little is known about the amount and behaviour of Hg in volcanic aquifers. Here we report on detailed investigations of both the content and the speciation of mercury in aquifers of active volcanoes in Italy and Guadeloupe Island (Lesser Antilles). In the studied groundwaters, total Hg (THg) concentrations range from 10 to 500 ng/l and are lower than the 1000 ng/l threshold value for human health protection fixed by the World Health Organization [WHO (1993): WHO Guidelines for Drinking Water Quality- http://www.who.int/water_sanitation_health/GDWQ/index.htlm]. Positive co-variations of (THg) with sulphate indicate that Hg-SO4-rich acid groundwaters receive a direct input of magmatic/hydrothermal gases carrying mercury as Hg0 (gas). Increasing THg in a volcanic aquifer could thus be a sensitive tracer of magmatic gas input prior to an eruption. Since the complex behaviour and toxicity of mercury in waters depend on its chemical speciation, we carefully determined the different aqueous forms of this element in our samples.We find that dissolved elemental Hg0 (aq) and particulate-bound Hg (HgP) widely prevail in volcanic aquifers, in proportions that highlight the efficiency of Hg adsorption onto colloidal particles. Moreover, we observe that dissolved Hg0 aq and Hg(II) forms coexist in comparable amount in most of the waters, in stark contrast to the results of thermodynamic equilibrium modelling. Therefore, chemical equilibrium between dissolved mercury species in volcanic waters is either prevented by natural kinetic effects or not preserved in collected waters due to sampling/storage artefacts. Finally, we provide a first quantitative comparison of the relative intensity of aqueous transport and atmospheric emissions of mercury at Mount Etna, a very active basaltic volcano.
    Description: In press
    Description: 4.5. Degassamento naturale
    Description: JCR Journal
    Description: open
    Keywords: Fluid geochemistry ; volcanic mercury ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 30
    Publication Date: 2017-04-04
    Description: no abstract
    Description: Published
    Description: V–VII
    Description: 3.5. Geologia e storia dei sistemi vulcanici
    Description: JCR Journal
    Description: reserved
    Keywords: Explosive volcanism ; distal archives ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
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  • 31
    Publication Date: 2017-04-04
    Description: Kostrov's (1974) algorithm for seismic-strain tensor computations, in the version implemented by Wyss et al. (1992a) for error estimates, has been applied to shear-type earthquakes occurring beneath the Etna volcano during 1990-1996. Space-time variations of strain orientations and amplitudes have been examined jointly with ground-deformation and gravimetric data collected in the same period and reported in the literature. Taking also into account the information available from volcanological observations and structural geology, we propose a model assuming that hydraulic pressure by magma emplaced in nearly north-south vertical structures produces the E-W orientation of the maximum compressive strain found in the upper 10 km beneath the crater area. In contrast, regional tectonics deriving from the slow, north-south convergence between the African and European plates appear to play a dominant role in the generation of stress and strain fields at crustal depths deeper than 10 km below the volcano. According to our interpretation, the progressive ascent of magma through the upper crust prior to eruption produces the observed gravity changes, cone inflation and unusual seismic strain rate in the upper 10 km associated with a more sharply defined seismic deformation regime (i.e. very small confidence limits of the epsilon 1 orientation). In agreement with this model, deflation revealed by ground-deformation data during the course of the major 1991-1993 eruption was accompanied by a practically nil level of shallow seismicity.
    Description: Published
    Description: 318-330
    Description: JCR Journal
    Description: open
    Keywords: Mt. Etna ; Italy ; Earthquakes ; Seismic strain ; Stress inversion ; Volcanic processes ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 32
    Publication Date: 2017-04-04
    Description: Between December 2004 and August 2005, more than 50,000 long-period events (LP) accompanied by very-long period pulses (VLP) were recorded at Mt. Etna, encompassing the effusive eruption which started in September 2004. The observed activity can be explained by the injection of a gas slug formed within the magmatic column into an overlying cavity filled by either magmatic or hydrothermal fluids, thus triggering cavity resonance. Although a large number of LP events exhibit similar waveforms before the eruption, they change significantly during and after the eruption. We study the temporal evolution of the LP-VLP activity in terms of the source movement, change of the waveforms, temporal evolution of the dominant resonance frequencies and the source Q factor and changes in the polarization of the signal. The LP source locations before and after the eruption, respectively, do not move significantly, while a slight movement of the VLP source is found. The intensity of the LP events increases after the eruption as well as their dominant frequency and Q factor, while the polarization of the signals changes from predominantly transversal to pure radial motion. Although in previous studies a link between the observed LP activity and the eruption was not found, these observations suggest that such a link was established at the latter end of the eruptive sequence, most likely as a consequence of a reestablishment of the pressure balance in the plumbing system, after it was undermined due to the discharge of large amounts of resident magma during the eruption. Based on the polarization properties of the signal and geological setting of the area, a fluid-filled crack is proposed as the most likely source geometry. The spectral analysis based on the autoregressive-models (SOMPI) is applied to the signals in order to analyse the resonance frequencies and the source Q-factors. The results suggest water and basalt at low gas volume fraction as the most likely fluids involved in the source process. Using theoretical relations for the “slow waves” radiated from the fluid-filled crack, we also estimate the crack size for both fluids, respectively.
    Description: Published
    Description: 205-220
    Description: 1.4. TTC - Sorveglianza sismologica delle aree vulcaniche attive
    Description: 3.6. Fisica del vulcanismo
    Description: JCR Journal
    Description: reserved
    Keywords: volcano seismology ; long-period seismicity ; Etna volcano ; volcano monitoring ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology
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  • 33
    Publication Date: 2017-04-04
    Description: Fluorine is one of the many environmental harmful elements released by volcanic activity. The content of total, oxalate extractable and water extractable fluorine was determined in 96 topsoils of three active volcanic systems of southern Italy (Mt. Etna, Stromboli and Vulcano). Total fluorine content (FTOT) ranges from 112 to 7430 mg kg-1, F extracted with oxalate (FOX) ranges from 16 to 2320 mg kg-1 (2 – 93 % of FTOT) and F extracted with distilled water (FH2O) ranges from 1.7 to 159 mg kg-1 (0.2 – 40 % of FTOT). Fluorine in the sampled topsoils derives both from the weathering of volcanic rocks and ashes and from enhanced deposition due to volcanic gas emissions either from open-conduit passive degassing (Mt. Etna and Stromboli) or from a fumarolic field (Vulcano). Fluorine accumulation in the studied soils does generally not present particular environmental issues except for a few anomalous sites at Vulcano where measured contents could be dangerous both for vegetation and for grazing animals.
    Description: Published
    Description: 413-423
    Description: 4.5. Degassamento naturale
    Description: JCR Journal
    Description: reserved
    Keywords: soil fluorine ; oxalate extractable F ; water extractable F ; environmental impact of volcanic F ; Sicily ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
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  • 34
    Publication Date: 2017-04-04
    Description: The tectonic escarpments locally known as ‘Timpe’ cut a large sector of the eastern flank of Etna, and allow an ancient volcanic succession dating back to 225 ka to be exposed. Geological and volcanological investigations carried out on this succession have allowed us to recognize relevant angular unconformities and volcanic features which are the remnants of eruptive fissures, as well as important changes in the nature, composition and magmatic affinity of the exposed volcanics. In particular, the recognition in the lower part of the succession of important and unequivocal evidence of ancient eruptive fissures led us to propose a local origin for these volcanics and to revise previous interpretations which attributed their westward-dipping to the progressive tectonic tilting of strata. These elements led us to reinterpret the main features of the volcanic activity occurring since 250 ka BP and their relationship with tectonic structures active in the eastern flank of Etna. We propose a complex paleo-environmental and volcanotectonic evolution of the southeastern flank of Mt. Etna, in which the Timpe fault system played the role of the crustal structure that allowed the rise and eruption of magmas in the above considered time span.
    Description: Published
    Description: 289-306
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 3.5. Geologia e storia dei sistemi vulcanici
    Description: 3.6. Fisica del vulcanismo
    Description: JCR Journal
    Description: reserved
    Keywords: Mount Etna ; tectonics ; fisssure eruptions ; columnar basalt ; fault escarpment ; xenoliths ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.03. Geomorphology ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology ; 04. Solid Earth::04.04. Geology::04.04.06. Rheology, friction, and structure of fault zones ; 04. Solid Earth::04.04. Geology::04.04.07. Rock geochemistry ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.04. Geology::04.04.10. Stratigraphy ; 04. Solid Earth::04.04. Geology::04.04.11. Instruments and techniques ; 04. Solid Earth::04.07. Tectonophysics::04.07.99. General or miscellaneous ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.04. Plate boundaries, motion, and tectonics ; 04. Solid Earth::04.07. Tectonophysics::04.07.05. Stress ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
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  • 35
    Publication Date: 2017-04-04
    Description: We present a detailed analysis of the source properties of Long-Period (LP) signals recorded at Campi Flegrei Caldera (Italy) during the last (2005–2006) mini-uplift episode. Moment Tensor inversion via full-waveform modelling of broad-band seismograms indicates a crack-like source with a significant volumetric component. From auto-regressive modelling of the signal's tail we evaluate the dominant frequency and the attenuation factor of the oscillating source. Considering the acoustic properties of a fluid-filled crack, these values are consistent with the resonant oscillations of a crack filled by a water–gas mixture at variable gas–volume fraction. For these fluids, the crack size would be on the order of 40–420 m, a size range which is consistent with the spatial spreading of LP hypocenters. Analysis of temporally-correlated time series of seismological and geochemical data indicates that climaxing of LP activity was preceded by swarms of volcano-tectonic (VT) events and rapidly followed by a consistent increase of both thermal emissions and gas fluxes recorded at the surface (1 month — 2/3 days, respectively). Following these observations, we propose a conceptual model where VT activity increases permeability of the medium, thus favouring fluid mobility. As a consequence, the hydrothermal system experiences pressure perturbations able to trigger its resonant, LP oscillations.
    Description: Published
    Description: 1035–1044
    Description: 1.4. TTC - Sorveglianza sismologica delle aree vulcaniche attive
    Description: 3.6. Fisica del vulcanismo
    Description: JCR Journal
    Description: reserved
    Keywords: Campi Flegrei caldera ; Long-Period earthquakes ; crack model ; Sompi method ; gas composition ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology
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  • 36
    Publication Date: 2017-04-04
    Description: In the present paper we describe the results of a seismic field survey carried out at Copahue Volcano, Southern Andes, Argentina, using a small-aperture, dense seismic antenna. Copahue Volcano is an active volcano that exhibited a few phreatic eruptions in the last 20 years. The aim of this experiment was to record and classify the background seismic activity of this volcanic area, and locate the sources of local earthquakes and volcanic tremor. Data consist of several volcano-tectonic (VT) earthquakes, and many samples of back-ground seismic noise. We use both ordinary spectral, and multi-spectral techniques to measure the spectral content, and an array technique [Zero Lag Cross Correlation technique] to measure the back-azimuth and apparent slowness of the signals propagating across the array.We locate VT earthquakes using a procedure based on the estimate of slowness vector components and S–P time. VT events are located mainly along the border of the Caviahue caldera lake, positioned at the South-East of Copahue volcano, in a depth interval of 1–3 kmbelow the surface. The background noise shows the presence of many transients with high correlation among the array stations in the frequency band centered at 2.5 Hz. These transients are superimposed to an uncorrelated background seismic signal. Array solutions for these transients show a predominant slowness vector pointing to the exploited geothermal field of “Las Maquinitas” and “Copahue Village”, located about 6 km north of the array site. We interpret this coherent signal as a tremor generated by the activity of the geothermal field.
    Description: Published
    Description: 284–294
    Description: 3.1. Fisica dei terremoti
    Description: JCR Journal
    Description: reserved
    Keywords: volcanic seismicity ; volcanic tremor ; seismic array ; volcano tectonic earthquakes ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology
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  • 37
    Publication Date: 2017-04-04
    Description: A new method combining measurements of soil CO2 flux and determinations of the carbon isotopic composition of soil CO2 efflux was developed in order to qualitatively and quantitatively characterise the CO2 source feeding the soil CO2 diffuse degassing. The method was tested in March 2007 at the Solfatara of Pozzuoli volcano degassing area (Naples, Italy) where more than 300 measurements of soil CO2 flux and determinations of the carbon isotopic composition of soil CO2 efflux were performed, surveying Solfatara crater and its surroundings. The wide range of CO2 flux and CO2 isotopic composition values (from 8.4 g m−2 d−1 to 28,834 g m−2 d−1, and from 0.73‰ to −33.54‰, respectively), together with their statistical distributions suggests the occurrence of multiple CO2 sources feeding soil degassing. The combined interpretation of flux and isotopic data allows us to identify and characterise two distinct gas sources: a hydrothermal and a biogenic source. The soil CO2 from the hydrothermal source is characterised by a mean δ13CCO2 of −2.3‰±0.9‰, hence close to the isotopic composition of the fumarolic CO2 (δ13CCO2=−1.48‰± 0.22‰) and by a mean CO2 flux of 2875 g m−2 d−1. The CO2 from the biogenic source is characterised by a mean δ13CCO2 of −19.4‰±2.1‰, and by a mean CO2 flux of 26 g m−2 d−1, which are both in the range of the typical values for biologic CO2 soil degassing. This reliable characterisation of the biogenic CO2 flux would not have been possible by solely applying a statistical analysis of the CO2 flux values, which is commonly applied in volcanological studies for the partitioning between background fluxes and anomalous CO2 fluxes. A map of the Solfatara diffuse degassing structure was derived from the estimated threshold for the biogenic CO2 flux, highlighting that soil degassing of hydrothermal CO2 mixed in different proportion with biogenic CO2 occurs over a large area (~0.8 km2), which extends over the inner part of the Solfatara crater as well as the eastern periphery, corresponding with a NW–SE fault system. The presented method and data analysis are important means of surveillance of the volcanic activity.
    Description: Published
    Description: 372–379
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Degassamento naturale
    Description: JCR Journal
    Description: reserved
    Keywords: CO2 soil degassing ; CO2 flux ; carbon dioxide ; carbon isotopes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
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  • 38
    Publication Date: 2017-04-04
    Description: Lake Averno is situated in the homonymous crater in the northwestern sector of the Campi Flegrei active volcanic system in Campania region, Italy. In February 2005 a fish kill event was observed in the lake, prompting a geochemical survey to ascertain the possible cause. In February 2005 a geochemical survey revealed that the lake water was unstratified chemically and isotopically, presumably, as a result of lake overturn. This fish kill phenomenon was recorded at least two other times in the past. In contrast to the February 2005 results, data collected in October 2005, shows the Lake Averno to be stratified, with an oxic epilimnion (surface to 6 m) and an anoxic hypolimnion (6 m to lake bottom at about 33 m). Chemical and isotopic compositions of Lake Averno waters suggest an origin by mixing of shallow waters with a Na–Cl hydrothermal component coupled with an active evaporation process. The isotopic composition of Dissolved Inorganic Carbon, as well as the composition of the non-reactive dissolved gas species again supports the occurrence of this mixing process. Decreasing levels of SO4 and increasing levels of H2S and CH4 contents in lake water with depth, strongly suggests anaerobic bacterial processes are occurring through decomposition of organic matter under anoxic conditions in the sediment and in the water column. Sulfate reduction and methanogenesis processes coexist and play a pivotal role in the anaerobic environment of the Lake Averno. The sulfate reducing bacterial activity has been estimated in the range of 14–22 μmol m−2 day−1. Total gas pressure of dissolved gases ranges between 800 and 1400 mbar, well below the hydrostatic pressure throughout the water column, excluding the possibility, at least at the survey time, of a limnic eruption. Vertical changes in the density of lake waters indicate that overturn may be triggered by cooling of epilimnetic waters below 7 °C. This is a possible phenomenon in winter periods if atmospheric temperatures remain frosty for enough time, as occurred in February 2005. The bulk of these results strongly support the hypothesis that fish kill was caused by a series of events that began with the cooling of the epilimnetic waters with breaking of the thermal stratification, followed by lake overturn and the rise of toxic levels of H2S from the reduced waters near the lake bottom.
    Description: Published
    Description: 305–316
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Degassamento naturale
    Description: JCR Journal
    Description: reserved
    Keywords: lake Averno ; dissolved gases ; stable isotopes ; stable isotopes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 39
    Publication Date: 2017-04-04
    Description: We determine the three-dimensional distribution of P- and S-wave velocities for Central São Miguel Island (Azores, Portugal) by tomographic inversion of local earthquake arrival times. We use P- and S-phases from 289 earthquakes recorded by a network of 20 seismometers. The model shows good resolution in the shallowest 5–6 km, as illustrated by different resolution tests. There are several velocity anomalies, interpreted as pyroclastic deposits, intrusive bodies, geothermal fields, and the effects of tectonics. A low Vp zone marks Furnas caldera, probably evidencing volcaniclastic sediments with development of intense geothermal activity. Another low Vp zone extends in correspondence of the highly fractured area between Fogo and the north coast. Conversely, strong positive anomalies are found south of Fogo and northwest of Furnas. They are interpreted in terms of high-density deposits and remnants of a plutonic intrusion. These interpretations are supported by the distribution of Vp/Vs, and are consistent with previous geological, geochemical, and geophysical data.
    Description: Published
    Description: 8-18
    Description: 1.4. TTC - Sorveglianza sismologica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: Seismic tomography ; Volcano seismology ; Crustal structure ; Azores ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology
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  • 40
    Publication Date: 2017-04-03
    Description: Despite the recent recognition of Mount Etna as a periodically violently explosive volcano, the hazards from various types of pyroclastic density currents (PDCs) have until now received virtually no attention at this volcano. Large-scale pyroclastic flows last occurred during the caldera-forming Ellittico eruptions, 15–16 ka ago, and the risk of them occurring in the near future is negligible. However, minor PDCs can affect much of the summit area and portions of the upper flanks of the volcano. During the past ~ 20 years, small pyroclastic flows or base-surge-like vapor and ash clouds have occurred in at least 8 cases during summit eruptions of Etna. Four different mechanisms of PDC generation have been identified during these events: (1) collapse of pyroclastic fountains (as in 2000 and possibly in 1986); (2) phreatomagmatic explosions resulting from mixing of lava with wet rock (2006); (3) phreatomagmatic explosions resulting from mixing of lava with thick snow (2007); (4) disintegration of the unstable flanks of a lava dome-like structure growing over the rim of one of the summit craters (1999). All of these recent PDCs were of a rather minor extent (maximum runout lengths were about 1.5 km in November 2006 and March 2007) and thus they represented no threat for populated areas and human property around the volcano. Yet, events of this type pose a significant threat to the lives of people visiting the summit area of Etna, and areas in a radius of 2 km from the summit craters should be off-limits anytime an event capable of producing similar PDCs occurs. The most likely source of further PDCs in the near future is the Southeast Crater, the youngest, most active and most unstable of the four summit craters of Etna, where 6 of the 8 documented recent PDCs originated. It is likely that similar hazards exist in a number of volcanic settings elsewhere, especially at snow- or glacier-covered volcanoes and on volcano slopes strongly affected by hydrothermal alteration.
    Description: In press
    Description: 4.3. TTC - Scenari di pericolosità vulcanica
    Description: JCR Journal
    Description: reserved
    Keywords: Mt. Etna ; Pyroclastic density currents ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
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  • 41
    Publication Date: 2017-04-04
    Description: Mt. Etna, in Sicily (Italy), is one of the world’s most frequent emitters of volcanic plumes. During the last ten years, Etna has produced copious tephra emission and fallout that have damaged the inhabited and cultivated areas on its slopes and created serious hazards to air traffic. Recurrent closures of the Catania International airport have often been necessary, causing great losses to the local economy. Recently, frequent episodes of ash emission, lasting from a few hours to days, occurred from July to December 2006, necessitating a look at additional monitoring techniques, such as remote sensing. The combination of a ground monitoring system, with polar satellite data represents a novel approach to monitor Etna’s eruptive activity and makes Etna one of the few volcanoes for which this surveillance combination is routinely available. In this work, ash emission information derived from an integrated approach, based on comparing ground and NOAA-AVHRR polar satellite observations, is presented. This approach permits us to define the utility of real time satellite monitoring systems for both sporadic and continuous ash emissions. Using field data (visible observations, collection of tephra samples and accounts by local inhabitants), the duration and intensity of most of the tephra fallout events were evaluated in detail and, in some cases, the order of magnitude of the erupted volume was estimated. The ground data vs. satellite data comparison allowed us to define five different categories of Etna volcanic plumes according to their extension and length, while taking into account plume height and wind intensity. Using frequent and good quality satellite data in real time, this classification scheme could prove helpful for investigations into a possible correlation between eruptive intensity and the presence and concentration of ash in the volcanic plume. The development and improvement of this approach may constitute a powerful warning system for Civil Protection, thus preventing unnecessary airport closures.
    Description: FIRB B5 Italian project “Sviluppo Nuove Tecnologie per la Protezione e Difesa del Territorio dai Rischi Naturali” funded by MIUR
    Description: Published
    Description: 135–147
    Description: JCR Journal
    Description: open
    Keywords: volcanic ash ; Mt. Etna ; ground monitoring ; NOAA–AVHRR ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 42
    Publication Date: 2020-02-24
    Description: Tephra layers from archaeological sites in southern Italy and eastern Europe stratigraphically associated with cultural levels containing Early Upper Palaeolithic industry were analysed. The results confirm the occurrence of the Campanian Ignimbrite tephra (CI; ca. 40 cal ka BP) at Castelcivita Cave (southern Italy), Temnata Cave (Bulgaria) and in the Kostenki–Borshchevo area of the Russian Plain. This tephra, originated from the largest eruption of the Phlegrean Field caldera, represents the widest volcanic deposit and one of the most important temporal/stratigraphic markers of western Eurasia. At Paglicci Cave and lesser sites in the Apulia region we recognise a chemically and texturally different tephra, which lithologically, chronologically and chemically matches the physical and chemical characteristics of the Plinian eruption of Codola; a poorly known Late Pleistocene explosive event from the Neapolitan volcanoes, likely Somma–Vesuvius. For this latter, we propose a preliminary age estimate of ca. 33 cal ka BP and a correlation to the widespread C-10 marine tephra of the central Mediterranean. The stratigraphic position of both CI and Codola tephra layers at Castelcivita and Paglicci help date the first and the last documented appearance of Early Upper Palaeolithic industries of southern Italy to ca. 41–40 and 33 cal ka BP, respectively, or between two interstadial oscillations of the Monticchio pollen record – to which the CI and Codola tephras are physically correlated – corresponding to the Greenland interstadials 10–9 and 5. In eastern Europe, the stratigraphic and chronometric data seem to indicate an earlier appearance of the Early Upper Palaeolithic industries, which would predate of two millennia at least the overlying CI tephra. The tephrostratigraphic correlation indicates that in both regions the innovations connected with the so-called Early Upper Palaeolithic – encompassing subsistence strategy and stone tool technology – appeared and evolved during one of the most unstable climatic phases of the Last Glacial period. On this basis, the marked environmental unpredictability characterising this time-span is seen as a potential ecological factor involved in the cultural changes observed.
    Description: Published
    Description: 208–226
    Description: 3.5. Geologia e storia dei sistemi vulcanici
    Description: 3.6. Fisica del vulcanismo
    Description: 4.3. TTC - Scenari di pericolosità vulcanica
    Description: JCR Journal
    Description: reserved
    Keywords: Campanian Ignimbrite ; Early Upper Palaeolithic ; Codola Plinian eruption ; south-eastern Europe ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
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  • 43
    Publication Date: 2024-05-09
    Description: A geochemical survey of thermal waters collected from submarine vents at Panarea Island (Aeolian Islands, southern Italy) was carried out from December 2002 to March 2007, in order to investigate i) the geochemical processes controlling the chemical composition of the hydrothermal fluids and ii) the possible relations between the chemical features of the hydrothermal reservoir and the activity of the magmatic system. Compositional data of the thermal water samples were integrated in a hydrological conceptual model, which describes the formation of the vent fluid by mixing of seawater, seawater concentrated by boiling, and a deep, highly-saline end-member, whose composition is regulated by water-rock interactions at relatively high temperature and shows clear clues of magmatic-related inputs. The chemical composition of concentrated seawater was assumed to be represented by that of the water sample having the highest Mg content. The composition of the deep end-member was instead calculated by extrapolation assuming a zero-Mg end-member. The Na–K–Ca geothermometer, when applied to the thermal end-member composition, indicated an equilibrium temperature of approximately 300 °C, a temperature in agreement with the results obtained by gas-geothermometry.
    Description: Published
    Description: 246-254
    Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Description: JCR Journal
    Description: reserved
    Keywords: low-pH waters; shallow submarine hydrothermal springs; Panarea Island ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 44
    Publication Date: 2020-12-15
    Description: The eruptive events of the July–August 2001 and October 2002–January 2003 at Mt. Etna provide new insights for reconstructing the complex geometry of the feeding system and their relationship to regional tectonics. The 2001 eruption took place mainly on the upper southern sector of the volcano. The eruption was preceded by a large earthquake swarm for a few days before its onset and accompanied by ground deformation and fracturing. The development of surface cracking along with the seismic pattern has allowed us to recognize three distinct eruptive systems (the SW–NE, NNW–SSE and N–S systems) which have been simultaneously active. Such eruptive systems are only the upper portions of a complex feeding system that was fed at the same time by two distinct magmas. The SW–NE and NNW–SSE systems, connected with the SE crater conduit, were fed by magma coming from depth, whereas the N–S system served instead as an ascending pathway for an amphibole-bearing magma residing in a shallow reservoir. The eruptive activity started again on October 2002 on the NE Rift Zone, where about 20 eruptive vents were aligned between 2500 and 1900 m a.s.l., and on the southern flank, from the central crater to the Montagnola. The onset of eruptive activity was accompanied by a seismic swarm. As in the 2001 eruptive event, two independent feeding systems formed, characterized by distinct magmas. The SW–NE system controlled the feeding of the Northeast Rift and was accommodated by left-lateral displacement along the WNW–ESE trending Pernicana Fault. The N–S system fed the eruptions on the southern flank. Moreover, the associated crustal deformation triggered seismic reactivation of tectonic structures in the eastern flank of the volcano and offshore. These two last eruptions indicate that at Mt. Etna the ascent of magma, as well as the accommodation of deformation, is strongly dominated by local extensional structures that are connected to a regional tectonic regime.
    Description: Published
    Description: 211-233
    Description: partially_open
    Keywords: extensional tectonics ; volcanic activity ; seismicity ; Sicily ; Mt. Etna ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics
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  • 45
    Publication Date: 2020-10-29
    Description: We have performed a parametric study on the dynamics of trachytic (alkaline) versus rhyolitic (calc-alkaline) eruptions by employing a steady, isothermal, multiphase non-equilibrium model of conduit flow and fragmentation. The employed compositions correspond to a typical rhyolite and to trachytic liquids from Phlegrean Fields eruptions, for which detailed viscosity measurements have been performed. The investigated conditions include conduit diameters in the range 30–90 m and total water contents from 2 to 6 wt%, corresponding to mass flow rates in the range 106–108 kg/s. The numerical results show that rhyolites fragment deep in the conduit and at a gas volume fraction ranging from 0.64 to 0.76, while for trachytes fragmentation is found to occur at much shallower levels and higher vesicularities (0.81–0.85). An unexpected result is that low-viscosity trachytes can be associated with lower mass flow rates with respect to more viscous rhyolites. This is due to the non-linear combined effects of viscosity and water solubility affecting the whole eruption dynamics. The lower viscosity of trachytes, together with higher water solubility, results in delayed fragmentation, or in a longer bubbly flow region within the conduit where viscous forces are dominant. Therefore, the total dissipation due to viscous forces can be higher for the less viscous trachytic magma, depending on the specific conditions and trachytic composition employed. The fragmentation conditions determined through the simulations agree with measured vesicularities in natural pumice clasts of both magma compositions. In fact, vesicularities average 0.80 in pumice from alkaline eruptions at Phlegrean Fields, while they tend to be lower in most calc-alkaline pumices. The results of numerical simulations suggest that higher vesicularities in alkaline products are related to delayed fragmentation of magmas with this composition. Despite large differences in the distribution of flow variables which occur in the deep conduit region and at fragmentation, the flow dynamics of rhyolites and trachytes in the upper conduit and at the vent can be very similar, at equal conduit size and total water content. This is consistent with similar phenomenologies of eruptions associated with the two magma types.
    Description: Published
    Description: 93-108
    Description: partially_open
    Keywords: trachytic magma ; conduit flow ; eruption dynamics and numerical simulations ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
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  • 46
    Publication Date: 2020-12-17
    Description: The Neapolitan Yellow Tuff (NYT) is the product of the largest known trachytic phreatoplinian eruption. It covered an area larger than 1000 km2 with an estimated volume of about 40 km3 of erupted magma. During the course of the eruption a caldera collapsed within the previously formed Campanian Ignimbrite caldera. The resulting nested structure strongly influenced the following volcanic activity in the Campi Flegrei caldera. As previous dating of the NYT does not converge toward a unique result, a new set of 40Ar/39Ar age determinations has been carried out to better constrain the age of the eruption. Two variants of the 40Ar/39Ar dating method were applied to determine the age of the NYT eruption: (1) single-crystal total fusion (SCTF), on an individual phenocryst of feldspar, and (2) laser incremental heating (LIH), on bulk aliquots of feldspar phenocrysts. The results of the SCTF analyses show that the overall sample weighted mean age, derived from the conventional age calculation, is 15.6 ;0.8 ka. A weighted mean of the isochron age is 15.3 ;1.2 ka (2c), and has been assumed as the best indicator of age to be derived from the SCTF analyses. The LIH analyses results show that plateau ages vary from 15.4; 0.5 to 14.5; 0.5 ka. The overall weighted mean age of the isochron results is 14.9;0.4 ka (2c). This result has been assumed as the reference age for the NYT eruption, and agrees with the SCTF age. The new age obtained for the NYT deposits is of great relevance for the understanding of the evolution and the present state of the Campi Flegrei caldera and collocates the NYT in a crucial stratigraphical position to date the climatic oscillations that occurred between the Late Glacial and the Holocene.
    Description: Published
    Description: 157-170
    Description: partially_open
    Keywords: Neapolitan Yellow Tuff ; Campi Flegrei caldera ; 40Ar/39Ar dating method ; Geochronology ; Late Glacial ; Holocene ; 04. Solid Earth::04.04. Geology::04.04.02. Geochronology ; 04. Solid Earth::04.04. Geology::04.04.10. Stratigraphy ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
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  • 47
    Publication Date: 2017-04-04
    Description: Continuous monitoring of soil CO2 dynamic concentration (which is proportional to the CO2 flux through the soil) was carried out at a peripheral site of Mt. Etna during the period November 1997 - September 2000 using an automated station. The acquired data were compared with SO2 flux from the summit craters measured two to three times a week during the same period. The high frequency of data acquisition with both methods allowed us to analyze in detail the time variations of both parameters. Anomalous high values of soil CO2 dynamic concentration always preceded periods of increased flux of plume SO2, and these in turn were followed by periods of summit eruptions. The variations were modeled in terms of gas efflux increase due to magma ascent to shallow depth and its consequent depressurization and degassing. This model is supported by data from other geophysical and volcanological parameters. The rates of increase both of soil CO2 dynamic concentration and of plume SO2 flux are interpreted to be positively correlated both to the velocity of magma ascent within the volcano and to lava effusion rate once magma is erupted at the surface. Low rates of the increase were recorded before the nine-month-long 1999 subterminal eruption. Higher rates of increase were observed before the violent summit eruption of September-November 1999, and the highest rates were observed during shorter and very frequent spike-like anomalies that preceded the sequence of short-lived but very violent summit eruptions that started in late January 2000 and continued until late June of the same year. Furthermore, the time interval between the peaks of CO2 and SO2 in a single sequence of gas anomalies is likely to be controlled by magma ascent velocity.
    Description: Consiglio Nazionale delle Ricerche of Italy (C.N.R.)Gruppo Nazionale per la Vulcanologia.
    Description: Published
    Description: 80-89
    Description: partially_open
    Keywords: Mt. Etna ; Soil CO2 emissions ; Plume SO2 flux ; COSPEC ; Continuous geochemical monitoring ; Eruptive activity ; Degassing model ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
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  • 48
    Publication Date: 2017-04-04
    Description: The properties of volcanic tremor wavefield at Mt. Etna Volcano, Italy, are investigated using data from two dense, smallaperture arrays of short-period seismometers deployed on the North and South flank of the volcano. Spectral analysis shows that most of the seismic energy is associated to several, narrow spectral peaks spanning the 1–5 Hz frequency band. Analysis of simultaneous recordings evidences that most of these peaks are common to different sites, thus suggesting a source effect as the origin of this energy. Frequency-slowness analyses evidence a complex wavefield, where body- and surface-waves alternatively dominate depending on the frequency band and component of motion taken into account. Surface waves are found to dominate at frequencies below 1 Hz and above 3 Hz. Conversely, the 0.8–2.3 Hz vertical- and radial-component wavefields at both arrays exhibit a nondispersive nature, with apparent velocities spanning the 1–2 s/km range. Particle motion analysis suggests these arrivals are associated to both P- and SV-waves inciding at shallow angles. At the northern array, back-azimuths of these waves encompass the whole summit crater area. At the southern array, back-azimuths are instead clustered around a direction pointing about 500 m east of the SE crater. At frequency around 4 Hz, the dominant direction of wave propagation at the southern site shifts about 30jW, pointing to the Bocca-Nuova/Voragine craters, and concordance of location is found with the source imaged by the northern array. The 0.8–2.3 Hz transverse-component of motion depicts velocities of about 0.5 km/s, a value which is about three times lower than those associated to the vertical and radial components. Results from polarization analyses at the two array sites depict the dominance of horizontal, linear particle motion oriented transversally with respect to the source direction. Polarization ellipsoids at the stations of the sparse network all depict a quasi-horizontal setting. With two exceptions, the direction of particle motion is always oriented tangentially to the summit volcanic edifice. The origin of the large transverse motion observed at the two array sites is thus attributed to SH waves generated by free-surface interaction of waves impinging the concave topography. The correlation method is used to derive the dispersion properties of short-period (0.5–5 Hz) Rayleigh waves, from which the shallow shear-wave velocity structures are derived for beneath the two semicircular arrays. Using a probabilistic approach, we invert slowness data measured at the two dense arrays for retrieving source location and extent. The joint inversion of slowness data from the two arrays point to different sources. This observation is interpreted in terms of ray bending associated to lateral heterogeneity and/or strong topographic effects on wave propagation. Once the propagation effects are taken into account, the most probable source locations are associated to a shallow region encompassing the summit craters and the eruptive fissures active at the time of the experiment (September 1999).
    Description: Published
    Description: 223-245
    Description: partially_open
    Keywords: Mount Etna ; Volcanic tremor ; Volcanic seismicity ; Seismic monitoring ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology
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  • 49
    Publication Date: 2017-04-04
    Description: Analysis of the historical records of Etnas eruptive activity for the past three centuries shows that, after the large 1669 eruption, a period of about 60 years of low-level activity followed. Starting from 1727, explosive activity (strombolian, lava fountaining and subplinian) at the summit crater increased exponentially to the present day. Since 1763, the frequency of flank eruptions also increased and this value remained high until 1960; afterward it further increased sharply. In fact, the number of summit and flank eruptions between 1961 and 2003 was four times greater than that of the pre-1960 period. This long-term trend of escalating activity rules out a pattern of cyclic behaviour of the volcano. We propose instead that the 16702003 period most likely characterises a single eruptive cycle which began after the large 1669 eruption and which is still continuing. On the basis of the eruptive style, two distinct types of flank eruptions are recognised: Class A and Class B. Class A eruptions are mostly effusive with associated weak strombolian activity; Class B eruptions are characterised by effusive activity accompanied by intense, long-lasting, strombolian and lava fountaining activity that produces copious tephra fallouts, as during the 2001 and 20022003 eruptions. Over the past three centuries, seven Class B eruptions have taken place with vents located mainly on the south-eastern flank, indicating that this sector of the volcano is a preferential zone for the intrusion of volatile-rich magma rising from the deeper region of the Etna plumbing system.
    Description: Published
    Description: 732-742
    Description: partially_open
    Keywords: Etna ; Historical record ; Summit activity ; Flank eruptions ; Eruptive behaviour ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
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  • 50
    Publication Date: 2017-04-04
    Description: The Monte Nuovo eruption is the most recent event that occurred at Phlegrean Fields (Italy) and lasted from 29 September to 6 October 1538. It was characterized by 2 days of quasi-sustained phreatomagmatic activity generating pumice-bearing pyroclastic density currents and forming a 130-m-high tuff cone (Lower Member deposits). The activity resumed after a pause of 2 days with two discrete Vulcanian explosions that emplaced radially distributed, scoria-bearing pyroclastic flows (Upper Member deposits). The juvenile products of Lower and Upper Members are, respectively, phenocryst-poor, light-coloured pumice and dark scoria fragments with K-phonolitic bulk compositions, identical in terms of both major and trace elements. Groundmass is formed by variable proportions of K-feldspar and glass, along with minor sodalite and Fe-Ti oxide present in the most crystallized samples. Investigations of groundmass compositions and textures were performed to assess the mechanisms of magma ascent, degassing and fragmentation along the conduit and implications for the eruptive dynamics. In pumice of the Lower Member groundmass crystal content increases from 13 to 28 vol% from the base to the top of the sequence. Products of the Upper Member consist of clasts with a groundmass crystal content between 30 and 40 vol% and of totally crystallized fragments. Crystal size distributions of groundmass feldspars shift from a single population at the base of the Lower Member to a double population in the remaining part of the sequence. The average size of both populations regularly increases from the Lower to the Upper Member. Crystal number density increases by two orders of magnitude from the Lower to the Upper Member, suggesting that nucleation dominated during the second phase of the eruption. The overall morphological, compositional and textural data suggest that the juvenile components of the Monte Nuovo eruption are likely to record variations of the magma properties within the conduit. The different textures of pumice clasts from the Lower Member possibly reflect horizontal gradients of the physical properties (P, T) of the ascending magma column, while scoriae from the second phase are thought to result from the disruption of a slowly rising plug crystallizing in response to degassing. In particular, crystal size distribution data point to syn-eruptive degassing-induced crystallization as responsible for the transition in eruptive style from the first to the second phase of the eruption. This mechanism not only has been proved to profoundly affect the dynamics of dome-forming calc-alkaline eruptions, but may also have a strong influence in driving the eruption dynamics of alkaline magmas of intermediate to evolved compositions.
    Description: Published
    Description: 601-621
    Description: reserved
    Keywords: Phlegrean Fields ; Vulcanian explosion ; Degassing ; Groundmass crystallization ; Eruption dynamics ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.02. Experimental volcanism ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
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  • 51
    Publication Date: 2017-04-04
    Description: On October 9, 1999 an earthquake of ML =3.6 occurred about 3 km beneath the central cone of Mt. Vesuvius, near Naples, Italy. The event had the highest magnitude recorded for at least 25 years, and possibly since the last eruption of this volcano (1944), and was not accompanied by other geophysical or geochemical changes. The present paper essentially deals with the seismological data collected at Mt. Vesuvius for 29 years before the October 9 earthquake till the end of 2001, and describes the time pattern distribution of seismic slip release and the b-parameter of the Gutenberg^Richter distribution. The self-similarity of the source process is investigated through the scaling law of the seismic spectrum. Results indicate a two-fold pattern of stress release, with high values (up to 100 bar) for earthquakes occurring close to the top of the carbonate basement that underlies the volcano at 2^3 km of depth, and low values (down to 0.1 bar) for the shallow events occurring within the volcanic edifice. The scaling law of the seismic spectrum is non-self-similar, indicating that the source dimensions do not scale with the seismic moment. For this reason the low-magnitude events substantially contribute to the overall cumulative seismic slip release. The bparameter of the Gutenberg^Richter distribution shows a variation around 1980, and a substantial constancy in the other time periods. The presence of extended aquifers, with their tops at about 1 km beneath the crater, favors the hypothesis of the triggering of the shallowest events by water-level changes. This hypothesis is in agreement with the low values of the stress drop measured for the shallowest seismic events. The existence of a carbonate basement with its top at about 2.5 km beneath the crater and the higher stress drops for the deeper events make reasonable the hypothesis that the pre-fractured carbonate basement may be the site of tectonic stress release.
    Description: Published
    Description: 23-39
    Description: partially_open
    Keywords: Vesuvius ; Seismicity ; Seismic source ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology
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  • 52
    Publication Date: 2017-04-04
    Description: In this work we present seismological and ground deformation evidence for the phase preparing the July 18 to August 9, 2001 flank eruption at Etna. The analysis performed, through data from the permanent seismic and ground deformation networks, highlighted a strong relationship between seismic strain release at depth and surface deformation. This joint analysis provided strong constraints on the magma rising mechanisms. We show that in the last ten years, after the 1991–1993 eruption, an overall accumulation of tension has affected the volcano. Then we investigate the months preceding the 2001 eruption. In particular, we analyse the strong seismic swarm on April 20–24, 2001, comprising more than 200 events (Mmax = 3.6) with prevalent dextral shear fault mechanisms in the western flank. The swarm showed a ca. NE-SW earthquake alignment which, in agreement with previous cases, can be interpreted as the response of the medium to an intrusive process along the approximately NNW-SSE volcano-genetic trend. These mechanisms, leading to the July 18 to August 9, 2001 flank eruption, are analogous to ones observed some months before the 1991–1993 flank eruption and, more recently, in January 1998 before the February-November 1999 summit eruption.
    Description: Published
    Description: 1469-1487
    Description: partially_open
    Keywords: Ground deformation ; volcano seismology ; Mt. Etna Volcano ; intrusive mechanism ; 04. Solid Earth::04.03. Geodesy::04.03.01. Crustal deformations ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology
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  • 53
    Publication Date: 2017-04-04
    Description: While the eruptive record of Mount Etna is reasonably complete for the past 400 years, the activity of the early and late 1960s, which took place at the summit, is poorly documented in the scientific literature. From 1955 to 1971, the Central and Northeast Craters were the sites of long-lived mild Strombolian and effusive activity, and numerous brief episodes of vigorous eruptive activity, which led to repeated overflows of lava onto the external flanks of the volcano. A reconstruction of the sequence of the more important of these events based on research in largely obscure and nearly inaccessible sources permits a better understanding of the eruption dynamics and rough estimates of erupted volumes and of the changes to the morphology of the summit area. During the first half of 1964, the activity culminated in a series of highly dynamic events at the Central Crater including the opening of a fissure on the E flank of the central summit cone, lava fountains, voluminous tephra emission, prolonged strong activity with continuous lava overflows, and growth of large pyroclastic intracrater cones. Among the most notable processes during this eruption was the breaching of a section of the crater wall, which was caused by lateral pressure of lava ponding within the crater. Comparison with the apparently similar summit activity of 1999 allows us to state that (a) lava overflows from large pit craters at the summit are often accompanied by breaching of the crater walls, which represents a significant hazard to nearby observers, and that (b) eruptive activity in 1999 was much more complex and voluminous than in 1964. For 1960s standards however, the 1964 activity was the most important summit eruption in terms of intensity and output rates for about 100 years, causing profound changes to the summit morphology and obliterating definitively the former Central Crater.
    Description: Published
    Description: 203-218
    Description: partially_open
    Keywords: Mount Etna ; Summit eruption ; Crater morphology and Lava overflows ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
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  • 54
    Publication Date: 2017-04-04
    Description: On July 18, 2001, two main eruptive vents opened on the southern flank of Mount Etna volcano (Italy) at ~2100 m and ~2550 m a.s.l., respectively. The former vent fed mild strombolian activity and lava flows, while the latter represented the main explosive vent, producing strong phreato-magmatic explosions. Explosions at this latter vent, however, shifted to a strombolian style in the following days, before switching back to phreato-magmatic activity towards the end of the eruption, which ended on August 9, 2001. On August 3, a small seismoacoustic array was deployed close to the eruptive vents. The array was composed of three stations, which recorded seismic and infrasonic waves coming from both of the eruptive vents. A further seismoacoustic station, equipped with a thermal-infrared sensor, was also installed several kilometers north of the first array. Seismic signals relating to the strombolian activity at the 2100-m vent were characterized by a strong decompression at the source. Analysis of the time delays between seismic, infrasonic and infrared event onsets also revealed that ejection velocities during explosions from both vents were subsonic. Time delays between the onset of explosive events apparent in the infrared and infrasound data indicated that the explosion source at the 2550-m vent was located 220–250 m below the crater rim. In comparison, the depth of the seismic source was estimated to be between 230 and 335 m below the rim. This converts to 120–150 and 130–235 m below the preexisting ground surface. In addition, time delays between seismic and infrasonic signals recorded for the lower (2100 m) vent also revealed a seismic source that was no more than a few tens of meters deeper than the fragmentation surface.
    Description: Published
    Description: 219-230
    Description: partially_open
    Keywords: Mt. Etna ; explosive eruptions ; arrays ; seismic ; infrasonic and thermal data ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 04. Solid Earth::04.06. Seismology::04.06.10. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
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  • 55
    Publication Date: 2017-04-04
    Description: The strike-slip Pernicana fault system (PFS) was activated along the eastern flank of Mt. Etna during an earthquake in September 2002 and, one month later, during the eruption of the NE Rift. Structural and volcanological data suggest that the PFS was activated as a result of the slide of the NE flank of Etna. This activation produced surface fracturing on walls and on paved and unpaved roads. The segments of the PFS, arranged in a right stepping en échelon configuration, show (a) an inverse proportion between length and frequency; (b) fractal behavior over scales of 10−2 –101 m, between their length, overstep and overlap; (c) consistent strike with regard to their fault array; and (d) a progressive eastward decrease in the displacement, along the smallest faults. The consistent geometric and kinematic features of the PFS, related to the sector collapse of Etna, are similar to those of faults in strike-slip settings.
    Description: Published
    Description: 343-355
    Description: partially_open
    Keywords: Active faulting ; Strike-slip faults ; Fractal behavior ; Volcano collapse ; Mt. Etna ; Pernicana fault system ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology
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  • 56
    Publication Date: 2017-04-04
    Description: The 200203 Mt Etna flank eruption began on 26 October 2002 and finished on 28 January 2003, after three months of continuous explosive activity and discontinuous lava flow output. The eruption involved the opening of eruptive fissures on the NE and S flanks of the volcano, with lava flow output and fire fountaining until 5 November. After this date, the eruption continued exclusively on the S flank, with continuous explosive activity and lava flows active between 13 November and 28 January 2003. Multi-disciplinary data collected during the eruption (petrology, analyses of ash components, gas geochemistry, field surveys, thermal mapping and structural surveys) allowed us to analyse the dynamics of the eruption. The eruption was triggered either by (i) accumulation and eventual ascent of magma from depth or (ii) depressurisation of the edifice due to spreading of the eastern flank of the volcano. The extraordinary explosivity makes the 200203 eruption a unique event in the last 300 years, comparable only with La Montagnola 1763 and the 2001 Lower Vents eruptions. A notable feature of the eruption was also the simultaneous effusion of lavas with different composition and emplacement features. Magma erupted from the NE fissure represented the partially degassed magma fraction normally residing within the central conduits and the shallow plumbing system. The magma that erupted from the S fissure was the relatively undegassed, volatile-rich, buoyant fraction which drained the deep feeding system, bypassing the central conduits. This is typical of most Etnean eccentric eruptions. We believe that there is a high probability that Mount Etna has entered a new eruptive phase, with magma being supplied to a deep reservoir independent from the central conduit, that could periodically produce sufficient overpressure to propagate a dyke to the surface and generate further flank eruptions.
    Description: Published
    Description: 314-330
    Description: partially_open
    Keywords: Multi-disciplinary study ; Mount Etna ; 2002–03 eruption ; Eccentric eruptions ; Flank activity ; Etna feeding system ; Volcanic processes ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
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  • 57
    Publication Date: 2017-04-04
    Description: The northwestern flank of the Colli Albani, a Quaternary volcanic complex near Rome, is characterised by high CO2 values and Rn activities in the groundwater and by the presence of zones with strong emission of gas from the soil. The most significant of these zones is Cava dei Selci where many houses are located very near to the gas emission site. The emitted gas consists mainly of CO2 (up to 98 vol) with an appreciable content of H2S (0.8). The He and C isotopic composition indicates, as for all fluids associated with the Quaternary Roman and Tuscany volcanic provinces, the presence of an upper mantle component contaminated by crustal fluids associated with subducted sediments and carbonates. An advective CO2 flux of 37 tons/day has been estimated from the gas bubbles rising to the surface in a small drainage ditch and through a stagnant water pool, present in the rainy season in a topographically low central part of the area. A CO2 soil flux survey with an accumulation chamber, carried out in February-March 2000 over a 12 000 m2 surface with 242 measurement points, gave a total (mostly conductive) flux of 61 tons/day. CO2 soil flux values vary by four orders of magnitude over a 160-m distance and by one order of magnitude over several metres. A fixed network of 114 points over 6350 m2 has been installed in order to investigate temporal flux variations. Six surveys carried out from May 2000 to June 2001 have shown large variations of the total CO2 soil flux (8/25 tons/day). The strong emission of CO2 and H2S, which are gases denser than air, produces dangerous accumulations in low areas which have caused a series of lethal accidents to animals and one to a man. The gas hazard near the houses has been assessed by continuously monitoring the CO2 and H2S concentration in the air at 75 cm from the ground by means of two automatic stations. Certain environmental parameters (wind direction and speed; atm P, T, humidity and rainfall) were also continuously recorded. At both stations, H2S and CO2 exceeded by several times the recommended concentration thresholds. The highest CO2 and H2S values were recorded always with wind speeds less than 1.5 m/s, mostly in the night hours. Our results indicate that there is a severe gas hazard for people living near the gas emission site of Cava dei Selci, and appropriate precautionary and prevention measures have been recommended both to residents and local authorities.
    Description: - GNV funded research project Gas Hazard of Colli Albani
    Description: Published
    Description: 81^94
    Description: partially_open
    Keywords: Colli Albani ; CO2 flux ; H2S ; gas hazard ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes ; 04. Solid Earth::04.03. Geodesy::04.03.06. Measurements and monitoring ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.02. Experimental volcanism ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
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  • 58
    Publication Date: 2017-04-04
    Description: This study presents a detailed analysis and interpretation of the seismicity that occurred on July 2-7 and August 22, 2000, during a ground uplift episode which started on March 2000 at Solfatara crater, Campi Flegrei. Earthquakes are located using a probabilistic grid-search procedure acting on a 3-D heterogeneous earth structure. The mainshock of the July swarm depicts a spectrum characterized by a few narrow peaks spanning the 1^5-Hz frequency band. For this event, we hypothesize a direct involvement of magmatic fluids in the source process. Conversely, the spectra of the August events are typical of shear failure. For these latter events, we evaluate the source properties from P-and Swave displacement spectra. Results for the most energetic shocks (Md around 2) yield a source radius in the order of 100 m and stress drop around 10 bars, in agreement with most of the earthquakes that occurred during the 1982-1984 bradyseismic crises. For the August swarm we identify two clusters of similar earthquakes. Application of highresolution relative location techniques to these events allows for the recognition of two parallel alignments trending NE^SW. The relationship among source dimension and relative location evidences overlapping of sources. This may be interpreted in terms of either a heterogeneous stress field or a lubrication process acting over the fault surface. For a selected subset of the August events, we also analyze the splitting of the shear waves: results are indicative of wave propagation through a densely fractured medium characterized by a distribution of cracks oriented NE-SW. The pattern of faulting suggested by relative locations and shear-wave splitting is not consistent with the surface trace of NW^SE striking faults. However, a detailed mesostructural analysis carried out over the Solfatara area indicated the occurrence of two main crack systems striking NW-SE and NE-SW. This latter system shows a strike consistent with that derived from seismic evidence. Results from a stress analysis of the crack systems indicate that a fluid overpressure within the NW-SE-striking faults is able to form NE-SW cracks. We found that the pressure of fluids Pf required to activate the NW-SE faults is less than cHmin, while the Pf value required to open the NE-SW cracks is higher than cHmax. Our main conclusions are: (a) the Solfatara area is affected by two orthogonal fracture systems, and the fluid pathway during the 2000 crisis mainly occurred along the NNE-SSW/NE-SW-striking crack system; (b) the July seismicity is associated to the upward migration of a pressure front triggered by an excess of fluid pressure from a small-size magmatic intrusion; conversely, the August events are associated to the brittle readjustment of the inflated system occurring along some lubricated structures.
    Description: Published
    Description: 229-246
    Description: partially_open
    Keywords: Seismicity ; Hydrothermal fuids ; Fuid pressure ; Faults ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 04. Solid Earth::04.06. Seismology::04.06.09. Waves and wave analysis
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  • 59
    Publication Date: 2017-04-04
    Description: Basaltic volcanism is most typically thought to produce effusion of lava, with the most explosive manifestations ranging from mild Strombolian activity to more energetic fire fountain eruptions. However, some basaltic eruptions are now recognized as extremely violent, i.e., generating widespread phreatomagmatic, subplinian and Plinian fall deposits. We focus here on the influence of conduit processes, especially partial open-system degassing, in triggering abrupt changes in style and intensity that occurred during two examples of basaltic Plinian volcanism. We use the 1886 eruption of Tarawera, New Zealand, the youngest known basaltic Plinian eruption and the only one for which there are detailed written eyewitness accounts, and the well-documented 122 BC eruption of Mount Etna, Italy, and present new grain size and vesicularity data from the proximal deposits. These data show that even during extremely powerful basaltic eruptions, conduit processes play a critical role in modifying the form of the eruptions. Even with very high discharge, and presumably ascent, rates, partial open-system behaviour of basaltic melts becomes a critical factor that leads to development of domains of largely stagnant and outgassed melt that restricts the effective radius of the conduit. The exact path taken in the waning stages of the eruptions varied, in response to factors which included conduit geometry, efficiency and extent of outgassing and availability of ground water, but a relatively abrupt cessation to sustained high-intensity discharge was an inevitable consequence of the degassing processes.
    Description: Published
    Description: 1-14
    Description: partially_open
    Keywords: basaltic Plinian eruption ; Etna ; Tarawera and explosive volcanism ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
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  • 60
    Publication Date: 2017-04-03
    Description: Remarkable changes in the local magnetic field were associated with the onset of the 2002–2003 flank eruption at Mt. Etna. After differential magnetic field measurements were filtered from the external noise by using adaptive filters, we recognized two stages in the total intensity changes, which are closely related to different volcanic events: (a) rapid variations of about 4–5 nT associated with October 26 seismic swarm recorded beneath the summit craters; (b) step-like variations of 9–10 nT coincident with October 27 eruptive fissures opening up in the north flank. These observations are generally consistent with those calculated from simple magnetic models of these volcanic processes, in which the magnetic changes are generated by stress redistribution due to magmatic intrusions at different depth. The magnetic data not only allow the timing of the intrusive event to be described in greater detail but also, together with other volcanological and geophysical evidences, permit some constraints to be set on the characteristics of propagation of a shallow dike. Firstly, at around midnight on 26 October magma was rapidly injected to a depth of 3–4 km just below the summit craters. Secondly, after 1:00 on 27 October, continued intrusion magma occurred upward and culminated a few hundred meters below the free surface fractured along a N–E direction. Thirdly, at about 2:28, magma gave rise to an explosive fissural vent at the northern base of the NE crater near 3000 m a.s.l. Finally, at about 5:00, the first eruptive fissure became active along the eastern border of the NE rift at 2500 m a.s.l. The rate of growth of the magnetic anomalies, moreover, leads to the interpretation that the magmatic intrusion travelled northward from base of the NE crater to the NE rift at approximately 14 m/min.
    Description: Published
    Description: 1-14
    Description: partially_open
    Keywords: eruptions ; monitoring ; magnetic methods ; volcanomagnetic modeling ; Mt. Etna ; 04. Solid Earth::04.05. Geomagnetism::04.05.04. Magnetic anomalies ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 61
    Publication Date: 2017-04-04
    Description: Since the early 1970s enhanced eruptive activity of Mount Etna has been accompanied by selective geochemical changes in erupted lavas, among which a gradual increase of alkalis whose origin is still debated. Here we provide further insight into the origin of this recent evolution, based on a detailed study of the chemistry and dissolved volatile content of melt inclusions trapped in olivine crystals of unusual plagioclase-poor primitive basalt that was extruded during a highly explosive flank eruption in July–August 2001. Two types of lava were erupted simultaneously along a N–S fracture system. Trachybasalts from the upper vents (2950–2700 m) were simply drained out by fracturing of the central volcanic conduit. They are identical to summit crater lavas and contain Mg-poor olivines (Fo70–72) with evolved and volatile-poor melt inclusions that represent late-stage crystallisation during shallow open conduit degassing. In contrast, plagioclase-poor basalt (80% of total) extruded through the lower vents (2550–2100 m) derived from lateral dyke intrusion of a more primitive and volatile-rich magma across the sedimentary basement. This primitive melt is best preserved in rare Fo82.4–80.5 skeletal olivines present in lapilli deposits from the most powerful activities at the 2550 m vent. Its high dissolved contents of H2 O (3.4 wt.%), CO2 (0.11 to 0.41 wt.%), S (0.32 wt.%), Cl (0.16 wt.%) and F (0.094 wt.%) point to its closed system ascent from ∼400 to 250 MPa (∼12 to 6.5 km depth b.s.l.). However, the predominance of euhedral olivine phenocrysts with common reverse zoning (cores Fo76–78 and rims Fo78–80) and decrepited inclusions shows that most of the erupted basalt derived from a slightly more evolved, crystallizing body of the same magma that was invaded by the uprising primitive melt prior to erupting. The few preserved inclusions in these olivines indicate pre-eruptive storage of that magma body at about 5 km depth b.s.l., in coherence with seismic data. We propose that the 2001 flank eruption resulted from gradual overpressuring of Etna's shallow plumbing system due to the influx of volatile-rich primitive basalt that may have begun several months in advance. We find that this basalt is much richer in alkalis (2.0 wt.% K2 O) and has higher S/Cl (2.0) but lower Cl/K and Cl/F ratios than all pre-1970s Etnean lavas (1.4 wt.% K2 O, S/Cl=1.5), as further exemplified by melt inclusions in entrained olivine xenocrysts. Combining these new observations with previously published data, we argue that the 2001 basalt represents a new alkali-rich basic end-member feeding Mt. Etna, only few amount of which had previously been extruded during a 1974 peripheral eruption and, more recently, during brief paroxysmal summit events. Over the last three decades this new magma has progressively mixed with and replaced the former K-poorer trachybasalts filling the plumbing system, leading to extrusion of gradually more primitive and alkali-richer lavas. Its geochemical singularities cannot result from shallow crustal contaminations. Instead, they suggest the involvement of an alkali-richer but Cl-poorer arc-type component during recent magma genesis beneath Etna.
    Description: Published
    Description: 1-17
    Description: partially_open
    Keywords: Mt. Etna ; volatiles ; degassing ; eruptive mechanism ; magma geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
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  • 62
    Publication Date: 2017-04-04
    Description: Flank instability and collapse are observed at many volcanoes. Among these, Mt. Etna is characterized by the spreading of its eastern and southern flanks. The eastern spreading area is bordered to the north by the EW-trending Pernicana Fault System (PFS). During the 20022003 Etna eruption, ground fracturing along the PFS migrated eastward from the NE Rift, to as far as the 18 km distant coastline. The deformation consisted of dextral en-echelon segments, with sinistral and normal kinematics. Both of these components of displacement were one order of magnitude larger (~1 m) in the western, previously known, portion of the PFS with respect to the newly surveyed (~9 km long) eastern section (~0.1 m). This eastern section is located along a pre-existing, but previously unknown, fault, where displaced man-made structures give overall slip rates (11.9 cm/year), only slightly lower than those calculated for the western portion (1.42.3 cm/year). After an initial rapid motion during the first days of the 20022003 eruption, movement of the western portion of the PFS decreased dramatically, while parts of the eastern portion continued to move. These data suggest a model of spreading of the eastern flank of Etna along the PFS, characterized by eruptions along the NE Rift, instantaneous, short-lived, meter-scale displacements along the western PFS and more long-lived centimeter-scale displacements along the eastern PFS. The surface deformation then migrated southwards, reactivating, one after the other, the NNWSSE-trending Timpe and Trecastagni faults, with displacements of ~0.1 and ~0.04 m, respectively. These structures, along with the PFS, mark the boundaries of two adjacent blocks, moving at different times and rates. The new extent of the PFS and previous activity over its full length indicate that the sliding eastern flank extends well below the Ionian Sea. The clustering of seismic activity above 4 km b.s.l. during the eruption suggests a deep décollement for the moving mass. The collected data thus suggests a significant movement (volume 〉1,100 km3) of the eastern flank of Etna, both on-shore and off-shore.
    Description: Published
    Description: 417-430
    Description: partially_open
    Keywords: Volcano spreading ; Fracturing ; Mt. Etna ; Pernicana Fault System ; NE Rift ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
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  • 63
    Publication Date: 2017-04-04
    Description: We have characterized pumice products belonging to the climactic phase of the 800-year-b.p. Quilotoa eruption. Bulk rock compositions, petrography, mineral, and glass chemistry and textural investigations were performed on the three end-member pumice types, namely white, gray, and mingled pumices. All the investigated pumice clasts are dacites characterized by the same bulk rock composition and mineralogical assemblage, but glass compositions and bulk textures change according to different pumice types. White pumice has higher crystallinity (~48 wt%), abundant euhedral pheno/microphenocrysts, no groundmass microlites, the most evolved glass compositions (7478 wt% SiO2), and heterogeneous vesicle populations marked by deformed and highly coalesced vesicles with thin walls. Gray pumice exhibits lower crystallinity (2936 wt%), abundant broken and/or resorbed crystals, ubiquitous groundmass phenocryst fragments and microlites, the widest range of glass compositions (6978 wt% SiO2), and quite homogeneous poorly deformed and coalesced vesicles with thicker walls. Mingled pumices are characterized by the alternation of bands or patches with white and gray pumice compositional and textural characteristics. We attribute heterogeneities in glass compositions and crystal and vesicle textures to processes occurring within volcanic conduits as magma is ascending to the surface. In particular, the above observations and results are consistent with an origin of a gray magma by heating of the original white magma in a strongly sheared region of the conduit because of a mechanism of viscous dissipation and crystal grinding and resorption at the conduit walls. The less viscous gray magma, therefore, would enable the onset and preservation of a high mass flux of the eruption otherwise difficult to explain for highly viscous crystal-rich dacitic magmas.
    Description: Published
    Description: 307-321
    Description: partially_open
    Keywords: Plinian eruption ; Crystal-rich magma ; Crystal grinding ; Pumice types ; Viscous dissipation ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
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  • 64
    Publication Date: 2017-04-04
    Description: Chlorine- and sulphur-bearing compounds in fumarole discharges of the La Fossa crater at Vulcano Island (Italy) can be modelled by a mixing process between magmatic gases and vapour from a boiling hydrothermal system. This allows estimating the compounds in both endmembers. Magma degassing cannot explain the time variation of sulphur and HCl concentrations in the deep endmember, which are more probably linked to reactions of solid phases at depth, before mixing with the hydrothermal vapours. Based on the P^T conditions and speciation of the boiling hydrothermal system below La Fossa, the HCl and Stot contents in the hydrothermal vapours were used to compute the redox conditions and pH of the aqueous solution. The results suggest that the haematite magnetite buffer controls the hydrothermal fO2 values, while the pH has increased since the end of the 1970s. The main processes affecting pH values may be linked to Na^Ca exchanges between evolved seawater, feeding the boiling hydrothermal system, and local rocks. While Na is removed from water, calcium enters the solution, undergoes hydrolysis and produces HCl,lowering the pH of the water. The increasing water^rock ratio within the hydrothermal system lowers the Ca availability, so the aqueous solution becomes less acidic. Seawater flowing towards the boiling hydrothermal brine dissolves a large quantity of pyrite along its path. In the boiling hydrothermal system, dissolved sulphur precipitates as pyrite and anhydrite, and becomes partitioned in vapour phase as H2S and SO2. These results are in agreement with the paragenesis of hydrothermal alteration minerals recovered in drilled wells at Vulcano and are also in agreement with the isotopic composition of sulphur emitted by the crater fumaroles.
    Description: Published
    Description: 137-150
    Description: partially_open
    Keywords: chlorine ; sulphur ; hydrothermal system ; genetic processes ; Vulcano Island ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.04. Thermodynamics ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
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  • 65
    Publication Date: 2017-04-04
    Description: Mount Etna produced two significant eruptions in 2001 and 2002–2003, which we have analysed using geological, seismic and deformation data. These eruptions showed some similarities, such as the activating of two magmatic plumbing systems (central–lateral and eccentric), but they differed in their triggering mechanisms. While the 2001 eruption was largely the result of the emplacement of a N–S eccentric dike (independent from the central conduits) consistent with E–W regional extension, the 2002–2003 eruption occurred in response to a major flank slip on the eastern and southeastern sides of the volcano. This is demonstrated by the spatial and temporal distribution of seismicity and deformation preceding and accompanying the two eruptions. During the months prior to the 2001 eruption, most epicenters were concentrated on the southern flank, at depths of 5–15 km below sea level. During the 4 days before the eruption, earthquake hypocenters migrated to shallower levels (from 5 km bsl. upward) indicating the emplacement of the eccentric dike. This is confirmed by the patterns of ground fracturing observed in the field and deformation documented by electronic distance measurements (EDM). In contrast, the months before the 2002–2003 eruption were characterised by shallower seismicity, mainly concentrated along the active faults bordering the slipping flank sector. Flank slip accelerated in September 2002 and a second, more vigorous acceleration of flank slip occurred on 26–27 October 2002, accompanying the opening of eruptive vents. The very short (2 h) seismic crisis preceding the onset of eruptive activity stands in neat contrast with the 4 days of intense seismicity before the 2001 eruption. Subsequently, flank slip-deformation extended all over the eastern and southeastern flanks of the volcano, causing serious damage in this sector. The events of 2001–2003 can be seen as a continuous chain of intimately interacting processes including regional tectonics, magma accumulation and eruption, and flank instability. In this scenario the 2001 eruption led to increased flank instability that subsequently accelerated and culminated with the massive flank slip, which in turn facilitated the 2002–2003 eruption. This sequence of events points to a long-term feedback mechanism between magmatism and flank instability at Etna.
    Description: Published
    Description: 235-255
    Description: partially_open
    Keywords: eruption triggering ; central–lateral vs. eccentric eruptions ; flank instability and slip ; volcano-tectonics ; Mt. Etna ; instrumental monitoring ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
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  • 66
    Publication Date: 2017-04-04
    Description: This work addresses the study of fluid circulation of the Stromboli island using a dense coverage of self-potential (SP) and soil CO2 data. A marked difference exists between the northern flank and the other flanks of the island. The northern flank exhibits (1) a typical negative SP/altitude gradient not observed on the other flanks, and (2) higher levels of CO2. The general SP pattern suggests that the northern flank is composed of porous layers through which vadose water flows down to a basal water table, in contrast to the other flanks where impermeable layers impede the vertical flow of vadose water. In the Sciara del Fuoco and Rina Grande-Le Schicciole landslide complexes, breccias of shallow gliding planes may constitute such impermeable layers whereas elsewhere, poorly permeable, fine-grained pyroclastites or altered lava flows may be present. This general model of the flanks also explains the main CO2 patterns: concentration of CO2 at the surface is high on the porous north flank and lower on the other flanks where impermeable layers can block the upward CO2 flux. The active upper part of the island is underlain by a well-defined hydrothermal system bounded by short-wavelength negative SP anomalies and high peaks of CO2. These boundaries coincide with faults limiting ancient collapses of calderas, craters and flank landslides. The hydrothermal system is not homogeneous but composed of three main subsystems and of a fourth minor one and is not centered on the active craters. The latter are located near its border. This divergence between the location of the active craters and the extent of the hydrothermal system suggests that the internal heat sources may not be limited to sources below the active craters. If the heat source strictly corresponds to intrusions at depth around the active conduits, the geometry of the hydrothermal subsystems must be strongly controlled by heterogeneities within the edifice such as craters, caldera walls or gliding planes of flank collapse, as suggested by the correspondence between SP^CO2 anomalies and structural limits. The inner zone of the hydrothermal subsystems is characterized by positive SP anomalies, indicating upward movements of fluids, and by very low values of CO2 emanation. This pattern suggests that the hydrothermal zone becomes self-sealed at depth, thus creating a barrier to the CO2 flux. In this hypothesis, the observed hydrothermal system is a shallow one and it involves mostly convection of infiltrated meteoric water above the sealed zone. Finally, on the base of CO2 degassing measurements, we present evidence for the presence of two regional faults, oriented N41‡ and N64‡, and decoupled from the volcanic structures.
    Description: Published
    Description: 1^18
    Description: partially_open
    Keywords: Stromboli ; hydrothermal system ; self-potential ; soil gas ; carbon dioxide ; Aeolian islands ; 03. Hydrosphere::03.02. Hydrology::03.02.02. Hydrological processes: interaction, transport, dynamics ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
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  • 67
    Publication Date: 2017-04-04
    Description: Two strong flank eruptions occurred in July–August 2001 and from late October 2002 to late January 2003 at Mt. Etna volcano. The two eruptions mainly involved the upper southern flank of the volcano, a particularly active area during the last 30 years, damaging several tourist facilities and threatening some villages. The composite eruptive activity on the upper southern flank of Mt. Etna during 2001–2003 has confirmed “a posteriori” the results of a multidisciplinary study, started well before its occurrence by combining geological, seismic and geochemical data gathered in this part of the volcano. We were able, in fact, to highlight fractured zones likely to be re-activated in the near future in this area, where the largest majority of eruptive fissures in the recent past opened along N120° to N180° ranging directions. The spatial distribution of earthquake epicentres during the period June 30th 2000–June 30th 2001 showed the greatest frequency in a sector compatible with both the direction of the main fissures of the pre-2001 period and that of the 2001 and 2002 lateral eruptions. Soil CO2 and soil temperature surveys carried out in the studied area during the last 3 years have revealed anomalous release of magmatic fluids (mainly CO2 and water vapour) along some NNW–SSE-trending volcano-tectonic structures of the area even during inter-eruptive periods, indicating persistent convective hydrothermal systems at shallow depth connected with the main feeder conduits of Etna. The temporal changes in both seismic and geochemical data from June 30th, 2000 to June 30th, 2001 were compared with the evolution of volcanic activity. The comparison allowed to recognize at least two sequences of anomalous signals (August to December 2000 and April to June 2001), likely related to episodes of step-like magma ascent towards the surface, as indicated by the following eruptive episodes. The N120° to N180° structural directions are in accord with one of the main structural lines affecting eastern Sicily; they would be important pathways for magma uprise to the surface that will keep on feeding the eruptive activity of Etna in the near future. This study also pointed out the high instability of the southern slope of Etna, a sector where the potential hazard by lava flow invasion will remain high also in the near future.
    Description: Published
    Description: 20
    Description: partially_open
    Keywords: Mt. Etna ; fault detection ; soil gas ; historical eruptive fissures ; eruptive activity ; local seismicity ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas
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  • 68
    Publication Date: 2017-04-04
    Description: Data from two dense arrays of short-period seismometers are used to retrieve source locations of the explosion quakes at Stromboli volcano. Slowness vectors stimated at both arrays with the zero-lag cross-correlation technique constitute the experimental data set. A probabilistic approach based on a grid search spanning the volcano interior is used to calculate the probability of the source location. Results depict a shallow source, located beneath the crater area, at depths not greater than 500 m below the surface. Results are slightly different from, but comparable to, those obtained in a companion experiment carried out in the same time period using a broad-band seismometer network, which show a source shifted some hundreds of meters northwest of the crater area. The method is revealed to be effective and useful for future studies having the purpose of real-time tracking of the explosion quakes and tremor.
    Description: Published
    Description: 123-142
    Description: partially_open
    Keywords: Stromboli ; Array ; Explosion quake ; Source location ; 04. Solid Earth::04.02. Exploration geophysics::04.02.06. Seismic methods ; 04. Solid Earth::04.06. Seismology::04.06.06. Surveys, measurements, and monitoring ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 04. Solid Earth::04.06. Seismology::04.06.09. Waves and wave analysis ; 04. Solid Earth::04.06. Seismology::04.06.10. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 69
    Publication Date: 2017-04-04
    Description: Accurate and precisely located self-potential (SP), temperature (T) and CO2 measurements were carried out in the summit area of Stromboli along 72 straight profiles. SP data were acquired every metre and T data every 2.5 m. CO2 concentrations were acquired with the same density as T, but only along seven profiles. The high density of data and the diversity of the measured parameters allows us to study structures and phenomena at a scale rarely investigated. The shallow summit hydrothermal activity (Pizzoâ Fossa area) is indicated by large positive SP, T and CO2 anomalies. These anomalies are focused on crater faults, suggesting that the fracture zones are more permeable than surrounding rocks at Stromboli. The analysis of the distribution of these linear anomalies, coupled with the examination of the geologic, photographic and topographic data, has led us to propose a new structural interpretation of the summit of Stromboli. This newly defined structural framework comprises (1) a large Pizzo circular crater, about 350 m in diameter; (2) a complex of two concealed craters nested within the Pizzo crater (the Large and the Small Fossa craters), thought to have formed during the eruption of the Pizzo pyroclastites unit; the Small Fossa crater is filled with highly impermeable material that totally impedes the upward flow of hydrothermal fluids; and (3) The present complex of active craters. On the floor of the Fossa, short wavelength SP lows are organized in drainage-like networks diverging from the main thermal anomalies and converging toward the topographic low in the Fossa area, inside the Small Fossa crater. They are interpreted as the subsurface downhill flow of water condensed above the thermal anomalies. We suspect that water accumulates below the Small Fossa crater as a perched water body, representing a high threat of strong phreatic and phreatomagmatic paroxysms. T and CO2 anomalies are highly correlated. The two types of anomalies have very similar shapes, but the sensitivity of CO2 measurements seems higher for lowest hydrothermal flux. Above T anomalies, a pronounced high frequency SP signal is observed. Isotopic analyses of the fluids show similar compositions between the gases rising through the faults of the Pizzo and Large Fossa craters. This suggests a common origin for gases emerging along different structural paths within the summit of Stromboli. A site was found along the Large Fossa crater fault where high gas flux and low air contamination made gas monitoring possible near the active vents using the alkaline bottle sampling technique.
    Description: Published
    Description: 486â 504
    Description: partially_open
    Keywords: Carbon dioxide ; Hydrothermal system ; Soil gas ; Stromboli ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.03. Physical::03.03.01. Air/water/earth interactions ; 03. Hydrosphere::03.03. Physical::03.03.02. General circulation ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration ; 04. Solid Earth::04.02. Exploration geophysics::04.02.04. Magnetic and electrical methods ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.06. Seismology::04.06.06. Surveys, measurements, and monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
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  • 70
    Publication Date: 2017-04-04
    Description: The evolution of scaling characteristics of the local geomagnetic field and of the seismicity at Etna volcano is studied in relation to the strong eruptive activity occurred here from 2000 to 2002. Scaling laws are found in the hourly time variability of magnetic data and in the seismicity pattern. The scaling exponents suggest the presence of persistent temporal fluctuations. Clear links between the dynamics of the measured data and the eruptive volcanic episodes are revealed. Fractal dimensions of seismicity seem to be always correlated to the beginning of main eruptive events, while strong alterations of the dynamics of the local magnetic field take place only when the eruptive fractures opened very close to the magnetic sites.
    Description: Published
    Description: 96-106
    Description: partially_open
    Keywords: scaling characteristics ; volcanic eruptions ; geomagnetic field ; seismic activity ; Mt. Etna ; 04. Solid Earth::04.05. Geomagnetism::04.05.02. Geomagnetic field variations and reversals ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
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  • 71
    Publication Date: 2017-04-04
    Description: New geochemical data on dissolved major and minor constituents in 276 groundwater samples from Etna aquifers reveal the main processes responsible for their geochemical evolution and mineralisation. This topic is of particular interest in the light of the progressive depletion of water resources and groundwater quality in the area. Multivariate statistical analysis reveal 3 sources of solutes: (a) the leaching of the host basalt, driven by the dissolution of magmaderived CO2; (b) mixing processes with saline brines rising from the sedimentary basement below Etna; (c) contamination from agricultural and urban wastewaters. The last process, highlighted by increased concentrations of SO4,NO3, Ca, F and PO4, is more pronounced on the lower slopes of the volcanic edifice, associated with areas of high population and intensive agriculture. However, this study demonstrates that natural processes (a) and (b) are also very effective in producing highly mineralised waters, which in turn results in many constituents (B, V, Mg) exceeding maximum admissible concentrations for drinking water.
    Description: Published
    Description: 863–882
    Description: partially_open
    Keywords: Hydrogeochemistry ; water quality ; Mt. Etna ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring ; 03. Hydrosphere::03.02. Hydrology::03.02.06. Water resources ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters
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  • 72
    Publication Date: 2017-04-04
    Description: Geochemical research was carried out on cold and hot springs at Popocatepetl (Popo) volcano (Mexico) in 1999 to identify a possible relationship with magmatic activity. The chemical and isotopic composition of the fluids is compatible with strong gas–water interaction between deep and shallow fluids. In fact, the isotopic composition of He and dissolved carbon species is consistent with a magmatic origin. The presence of a geothermal system having a temperature of 80–1008 C was estimated on the basis of liquid geothermometers. A large amount of dissolved CO2 in the springs was also detected and associated with high CO2 degassing.
    Description: Published
    Description: 91– 108
    Description: partially_open
    Keywords: Popocatepetl volcano ; helium isotope composition ; carbon isotope composition ; dissolved gases ; gas–water interaction ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
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  • 73
    Publication Date: 2017-04-04
    Description: We have developed a quantitative model of CO2 and H2O isotopic mixing between magmatic and hydrothermal gases for the fumarolic emissions of the La Fossa crater (Vulcano Island, Italy). On the basis of isotope balance equations, the model takes into account the isotope equilibrium between H2O and CO2 and extends the recent model of chemical and energy two-end-member mixing by Nuccio et al. (1999). As a result,the H2O and CO2 content and the dD, d18O, and d13C isotope compositions for both magmatic and hydrothermal end-members have been assessed. Low contributions of meteoric steam, added at a shallow depth, have been also recognized and quantified in the fumaroles throughout the period from 1988 to 1998. Nonequilibrium oxygen isotope exchange also seems to be occurring between ascending gases and wall rocks along some fumarolic conduits. The d13CCO2 of the magmatic gases varies around -3 to 1‰ vs. Peedee belemnite (PDB), following a perfect synchronism with the variations of the CO2 concentration in the magmatic gases. This suggests a process of isotope fractionation because of vapor exsolution caused by magma depressurization. The hydrogen isotopes in the magmatic gases (-1 to -35‰ vs. standard mean ocean water [SMOW]), as well as the above d13CCO2 value, are coherent with a convergent tectonic setting of magma generation, where the local mantle is widely contaminated by fluids released from the subducted slab. Magma contamination in the crust probably amplifies this effect. The computed isotope composition of carbon and hydrogen in the hydrothermal vapors has been used to calculate the dD and d13C of the entire hydrothermal system, including mixed H2O-CO2 vapor, liquid water, and dissolved carbon. We have computed values of about 10‰ vs. SMOW for water and -2 to -6.5‰ vs. PDB for CO2. On these grounds, we think that Mediterranean marine water (dDH2O 10‰) feeds the hydrothermal system. It infiltrates at depth throughout the local rocks, reaching oxygen isotope equilibrium at high temperatures. Interaction processes between magmatic gases and the evolving seawater also seem to occur, causing the dissolution of isotopically fractionated aqueous CO2 and providing the source for hydrothermal carbon. These results have important implications concerning fluid circulation beneath Vulcano and address the more convenient routine of geochemical surveillance.
    Description: Published
    Description: 759–772
    Description: partially_open
    Keywords: isotope geochemistry ; volcanic gases ; mixing modeling ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
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  • 74
    Publication Date: 2017-04-04
    Description: The results of the 7 years (1994-2000) of monthly monitoring of spring water before and during eruptions show response to volcanic activity. Low salinity and temperature characterize most of the springs, which are located on the flanks of Popocatepetl Volcano. The pH ranges from 5.8 to 7.8 and temperature from 3 to 36 jC. Oxygen and hydrogen isotopic data show that the water is of meteoric origin, but SO4 2 , Cl , F , HCO3 , B, and SO4 2- /Cl- variations precede main eruptive activity, which is considered linked to influx of magmatic gases and acid fluids that react with sublimates and host rock and mix with the large water system. Na +, Ca2 + , SiO2 and Mg2 + concentrations in the water also increased before eruptive activity. The computed partial pressure of CO2 in equilibrium with spring waters shows values higher than air-saturated water (ASW), with the highest values up to 0.73 bar of pCO2. Boron is detected in the water only preceding the larger eruptions. When present, boron concentration is normally under health standard limits, but in two cases the concentration was slightly above. Other components are within health standard limits, except for F- in one spring.
    Description: Published
    Description: 207– 229
    Description: partially_open
    Keywords: Volcano monitoring ; Spring water chemistry ; Popocatepetl ; Mexico ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
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  • 75
    Publication Date: 2022-05-24
    Description: Many studies have assessed the strong influence of volcanic activity on the surrounding environment. This is particularly true for strong gas emitters such as Mt. Etna and Stromboli volcanoes. Among volcanic gases, fluorine compounds are potentially very harmful. Fluorine cycling through rainwater in the above volcanic areas was studied analysing more than 400 monthly bulk samples. Data indicate that only approximately 1% of fluorine emission through the plume is deposited on the two volcanic areas by meteoric precipitations. Although measured bulk rainwater fluorine fluxes are comparable to and sometimes higher than in heavily polluted areas, their influence on the surrounding vegetation is limited. Only annual crops, in fact, show some damage that could be an effect of fluorine deposition, indicating that long-living endemic plant species or varieties have developed some kind of resistance.
    Description: Published
    Description: 175–185
    Description: partially_open
    Keywords: Fluorine ; Rainwater chemistry ; Volcanic activity ; Mt. Etna ; Stromboli Island ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 03. Hydrosphere::03.03. Physical::03.03.01. Air/water/earth interactions ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.08. Risk::05.08.01. Environmental risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Format: 539 bytes
    Format: 1320202 bytes
    Format: text/html
    Format: application/pdf
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