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  • Inorganic Chemistry  (1,032)
  • Aircraft Design, Testing and Performance
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  • 1
    Publication Date: 2019-06-06
    Description: The NASA Design and Analysis of Rotorcraft (NDARC) software is an aircraft system analysis tool that supports both conceptual design efforts and technology impact assessments. The principal tasks are to design (or size) a rotorcraft to meet specified requirements, including vertical takeoff and landing (VTOL) operation, and then analyze the performance of the aircraft for a set of conditions. For broad and lasting utility, it is important that the code have the capability to model general rotorcraft configurations, and estimate the performance and weights of advanced rotor concepts. The architecture of the NDARC code accommodates configuration flexibility, a hierarchy of models, and ultimately multidisciplinary design, analysis, and optimization. Initially the software is implemented with low-fidelity models, typically appropriate for the conceptual design environment. An NDARC job consists of one or more cases, each case optionally performing design and analysis tasks. The design task involves sizing the rotorcraft to satisfy specified design conditions and missions. The analysis tasks can include off-design mission performance calculation, flight performance calculation for point operating conditions, and generation of subsystem or component performance maps. For analysis tasks, the aircraft description can come from the sizing task, from a previous case or a previous NDARC job, or be independently generated (typically the description of an existing aircraft). The aircraft consists of a set of components, including fuselage, rotors, wings, tails, and propulsion. For each component, attributes such as performance, drag, and weight can be calculated; and the aircraft attributes are obtained from the sum of the component attributes. Description and analysis of conventional rotorcraft configurations is facilitated, while retaining the capability to model novel and advanced concepts. Specific rotorcraft configurations considered are single-main-rotor and tail-rotor helicopter, tandem helicopter, coaxial helicopter, and tiltrotor. The architecture of the code accommodates addition of new or higher-fidelity attribute models for a component, as well as addition of new components.
    Keywords: Aircraft Design, Testing and Performance
    Type: NASA/TP–2015-218751 , ARC-E-DAA-TN67537
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  • 2
    facet.materialart.
    Unknown
    In:  CASI
    Publication Date: 2019-06-04
    Description: NASA Ames Research Center (ARC) Aeromechanics Branch hosted more than 60 interns this summer and focused their energies on studying the future of vertical flight. This is the second of two reports from this past years summer interns.
    Keywords: Aircraft Design, Testing and Performance
    Type: ARC-E-DAA-TN61467 , Vertiflite Magazine (ISSN 0042-4455); 14-15
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  • 3
    Publication Date: 2019-05-31
    Description: No abstract available
    Keywords: Aircraft Design, Testing and Performance
    Type: ARC-E-DAA-TN41644
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  • 4
    Publication Date: 2019-07-20
    Description: Vacuum airships fueled by renewable energy would reduce reliance on fossil fuel-based modes of transport, lessen the need for limited and non-renewable lifting gases, and can be achieved using novel manufacturing techniques for ultra-light, discrete lattice material systems.The Discrete Lattice Material Vacuum Airships (DLMVA) system combines novel material science and manufacturing technologies for new modes of mass transportation, resulting in a disruptive approach to reduce national resource consumption and emissions. Through the use of high performance building block elements, modular, scalable and extensible aircraft can be rapidly assembled into positive net-buoyancy systems utilizing a vacuum instead of a lifting gas. By using architected lattice material principles, show that lattice materials can overcome stability limitations of previous vacuum balloon designs. Additionally, we show that lattice vacuum balloons are strength limited, rather than stability limited. As a result,airborne infrastructure can be developed to support the proliferation of modern systems such as e-commerce and distributed communications, while simultaneously reducing dependence on finite, non-renewable, emission-heavy resources.
    Keywords: Aircraft Design, Testing and Performance
    Type: ARC-E-DAA-TN64902 , AIAA Science and Technology Forum and Exposition; Jan 07, 2019 - Jan 11, 2019; San Diego, CA; United States
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  • 5
    Publication Date: 2019-07-25
    Description: NASA's Unmanned Aircraft Systems Integration into the National Airspace System (UAS in the NAS) project examines the technical barriers associated with the operation of UAS in civil airspace. For UAS, the removal of the pilot from onboard the aircraft has eliminated the ability of the ground-based pilot in command (PIC) to use out-the-window visual information to make judgements about a potential threat of a loss of well clear with another aircraft. NASA's Phase 1 research supported the development of a Detect and Avoid (DAA) system that supports the ground-based pilot's ability to detect potential traffic conflicts and determine a resolution maneuver, but existing display/alerting requirements did not account for multiple UAS control (1:N). Demands for increased scalability of UAS in the NAS operations are expected to create a need for simultaneous control of UAs, and thus, a new DAA HMI design will likely be necessary. Previous research, however, has found performance degradations as the number of vehicles under operator control has increased. The purpose of the current human-in-the-loop (HITL) simulation was to examine the viability of 1:N operations with the Phase 1 DAA alerting and guidance. Sixteen UAS pilots flew three scenarios with varying number of UAs under their control (1:1, 1:3, 1:5). In addition to their supervisory and sensor mission responsibilities, pilots were to utilize the DAA system to remain DAA well clear (DWC) during scripted conflicts of mixed severity. Measured response times, separation performance, mission task data, and subjective feedback were collected to assess how the multi-UAS control configuration impacted pilots' ability to maintain DAA well clear and perform the mission tasks. Overall, the DAA system proved surprisingly adaptive to multi-UAS control for preventing losses of DAA well clear (LoDWC). The findings suggest that, while multi-UAS operators are able to maintain safe separation (DWC) from other traffic, their ability to efficiently perform missions drastically decreases with their number of controlled vehicles. Pilot feedback indicated that, for this context, the use of automation support tools for completing and managing mission tasks would be appropriate and desired, especially for ensuring efficient use of assets. Finally, human-machine interface (HMI) design considerations for multi-UAS operations are discussed.
    Keywords: Aircraft Design, Testing and Performance
    Type: ARC-E-DAA-TN69010 , AIAA Aviation Forum 2019; Jun 17, 2019 - Jun 21, 2019; Dallas, TX; United States
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  • 6
    Publication Date: 2019-07-20
    Description: A computational framework to support the quantification of system uncertainties and sensitivities for rotorcraft applications is presented using the NASA Design and Analysis of Rotorcraft (NDARC) conceptual sizing tool. A 90 passenger conceptual tiltrotor configuration was used for case demonstration in the modeling of uncertainties in NDARCs emission module. A non-intrusive forward propagation uncertainty quantification approach was applied to ensemble simulations using a Monte Carlo methodology with stratified Latin hypercube sampling. An off-the-shelf software, DAKOTA, which supports trade studies and design space exploration, including optimization, surrogate modeling and uncertainty analysis was used to address the research goals. A toolsuite was further developed incorporating DAKOTA with automated design processes and methods using function wrappers to execute program routines including support for data post-processing. Uncertainties in rotorcraft emissions modeling using the Average Temperature Response metric for a set mission profile were studied. It was shown that for the current study, using the base-line best estimate modeling parameters for the Average Temperature Response metric, NDARC under-estimates the effects of emissions when compared with results from Monte Carlo simulations. A global sensitivity analysis was further undertaken to quantify the contribution of the various emission species on output sensitivity, hence uncertainty. The work demonstrates that the developed toolsuite is robust and will support the quantification of system uncertainties and sensitivities in future rotorcraft design efforts.
    Keywords: Aircraft Design, Testing and Performance
    Type: ARC-E-DAA-TN64160 , 2019 AIAA SciTech Forum; Jan 07, 2019 - Jan 11, 2019; San Diego, CA; United States
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  • 7
    Publication Date: 2019-07-20
    Description: This presentation is an overview of research being conducted by NASA and the AFRL, including recent successes and failures.
    Keywords: Aircraft Design, Testing and Performance
    Type: AFRC-E-DAA-TN67259 , AIAA Region VI Student Conference; Apr 04, 2019; San Luis Obispo, CA; United States
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  • 8
    Publication Date: 2019-07-19
    Description: The UAS in the NAS project Flight Test 6 (FT6) campaign scheduled for FY19Q3 will evaluate the proficiency of a Honeywell DAPA-Lite Radar installed on a Tiger Shark unmanned vehicle to detect the presence of air traffic operating in its vicinity. A 3D printed radome will be manufactured for the front of the Tiger Shark to enclose the radar during FT6 operations. The DAPA-Lite radar operates in the 24.5 GHz frequency band. Material properties of 3D printer filaments are widely available for the mechanical and thermal properties, but limited knowledge exists on the electrical properties for radome applications and no data was found to correspond at the 24.5 Ghz frequency band. To minimize project risk associated with the radome performance, transmissivity and reflectivity measurements were conducted on two candidate 3D printed dielectric material filaments (Ultem 1010 Natural and Ultem 9085 Black) and two thicknesses of a solid laminate (Ultem 1000) material. The 3D printed Ultem coupons were tested shortly after being printed and again 8 months later to examine ageing effects of the open cell structure. This paper presents the transmissivity and reflectivity measurement results collected on the Ultem coupons and concludes the 3D printed 1010 Natural coupon is a suitable candidate filament for radome applications at 24.5 GHz. The design of the structures open cell matrix has a significant impact on the materials surface reflectivity.
    Keywords: Aircraft Design, Testing and Performance
    Type: NF1676L-33377 , NASA/TM-2019-220287 , L-21031
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  • 9
    Publication Date: 2019-07-20
    Description: The first years effort identified sampling and interviewing as the principal risks to assessment of prompt reactions to overflights producing low-amplitude sonic booms. It also 1) established the utility of geo-information system-based route planning for LBFD flight missions, 2) developed and demonstrated a prototype of a geographically-distributed, Internet-enabled instrumentation system capable of wide-area tracking of LBFD aircraft in near-real time. The latter system permits synchronizing the conduct of interviews in multiple overflown communities with arrival times of shock waves at interviewing sites; and of measuring, archiving, and processing their acoustic signatures. Means were also recommended for constructing representative, telephone-based samples of eligible respondents living in households within carpet boom corridors adjacent to LBFD flight tracks, and for conducting interviews with cross-sectional (independent) samples of such respondents about their prompt reactions to exposure to low-amplitude sonic booms. A detailed study design was prepared and accepted by NASA for a set of single-contact attempt telephone interviews with a nationally representative sample of households. The study design focused on testing automated and live agent interview completion rates obtainable without callbacks. A minimal (two monitoring station) version of the aircraft tracking system was built and installed near a civil airport in a successful demonstration of the systems ability to detect and track aircraft movements. The field exercise also demonstrated the ability of the system to capture the acoustic emissions of departing aircraft, and to serve aircraft position and sound level information to remote, geographically-distributed analysts in near-real time. Upon approval of OMB and IRB of the detailed study plan, a stratified, nationally representative sample of landline and wireless telephone-subscribing households was constructed. A total of 12,734 telephone interview contact attempts of the sort required by a straightforward cross-sectional study design were then made. These contact attempts demonstrated the impracticality of conducting a time-critical, cross-sectional study of prompt community response to low-amplitude sonic booms by means of independent (single contact attempt per respondent for each LBFD flight mission) telephone samples of respondents. The observed interview completion rates for these single telephone contact attempts were so low (~ 1% to 3% for automated and live agent interviews, respectively) that: 1) the representativeness of collected opinions would be susceptible to intuitive challenge as inadequate, even absent conclusive evidence of non-representativeness. Refuting challenges to representativeness would have to demonstrate that the composition of the actual sample did not differ from that of the target population, a task that is tantamount to proving a negative; 2) the information required to refute allegations of non-representativeness would require a questionnaire considerably lengthier than that required simply to determine the prevalence of boom-induced startle and annoyance. Such a questionnaire would have to inquire about potentially sensitive and intrusive matters, including respondents age, gender, education, employment, home ownership, income, ethnicity, family size, and other demographic factors; and 3) unreasonable numbers of attempts would be required to re-contact households with unsuccessful initial contact attempts, given the limited time available for doing so. For example, if about 500 completed interviews were desired in a supersonically overflown community, approximately 50,000 automated interview attempts would have to be made within ten to fifteen minutes of each LBFD overflight. Such large numbers of contact attempts could well exceed the numbers of households available for interview in areas of similar boom exposure levels in some communities near LBFD flight tracks. Such large numbers of interviews could be cost-effectively undertaken only by means of automated (i.e., outgoing interactive voice response) interviewing, a data collection method ill-suited for complex and sensitive questionnaire items. The infeasibility of independent sampling for evaluating prompt responses to LBFD overflights in a cross-sectional study is due in large part to simple non-response: that is, potential respondents particularly those contacted on wireless telephones refusing to answer calls with unfamiliar caller IDs. It is also due in part, however, to 1) the lack of time to attempt to contact the same respondent more than once within a few minutes after the arrival of a shock wave at the respondents location; and 2) the need to place calls during weekday/daytime hours, when response rates are notably lower than during evenings and weekends. Despite the poor interview completion rates achieved under the above constraints, cross sectional assessments of delayed reactions to LBFD overflights could still be feasible, if multiple attempts could be made to contact respondents during evening and weekend time periods, over extended time periods. Detailed plans for a longitudinal (panel) sample were developed as an alternative to a cross sectional sample design.
    Keywords: Aircraft Design, Testing and Performance
    Type: NASA/CR-2019-22057 , NF1676L-32312
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  • 10
    Publication Date: 2019-07-20
    Description: A full-scale isolated proprotor test was recently conducted in the USAF National Full-Scale Aerodynamics Complex (NFAC) 40- by 80-Foot Wind Tunnel at NASA Ames. The test article was a 3-bladed research rotor derived from the right-hand rotor of the AW609. For this test, the NASA Tiltrotor Test Rig (TTR) and rotor were installed in the 40- by 80-Foot Wind Tunnel. This paper covers the analyses and testing done to prepare for a safe entry. Included are brief descriptions of the following: NASTRAN models of the TTR, ground vibration tests of the TTR (and resulting modal data), loads analyses, and stability predictions using the comprehensive analysis CAMRAD II. The evolution of these analyses from early in the TTR program until the initiation of actual testing is also discussed. The intent is to show how all of these efforts were integrated to ensure a successful test. This paper includes stability predictions based on NASTRAN modal data and worst-case damping test data. The stability predictions covered all test conditions: hover, cruise (airplane mode), conversion, and helicopter mode. The predictions showed that the TTR and rotor are stable within the test envelope.
    Keywords: Aircraft Design, Testing and Performance
    Type: ARC-E-DAA-TN63432 , AIAA Science and Technology Forum and Exposition; Jan 07, 2019 - Jan 11, 2019; San Diego, CA; United States
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  • 11
    Publication Date: 2019-07-13
    Description: After testing grooved over-the-rotor acoustic casing treatments on a turbofan rotor, a follow-on study was performed to investigate the effect of flow on grooved acoustic liners. The experiment was performed to understand the scaling of acoustic liner absorption with grazing flow and investigate a potential noise source from grooved acoustic liners. Acoustic liner absorption and reflection characteristics were quantified by examining the reduction in amplitude of a plane wave traveling over 2 inch liners with grazing flow. For all liners tested, as the grazing flow Mach number is increased, the absorption curves broadened and the frequency of peak absorption decreased. Grazing flow over a series of grooves was found to generate resonances up to 152 dB sound pressure level. Adding acoustic treatment to the bottom of these grooves was found to reduce the magnitude of this resonance by up to 10 dB sound pressure level and increase its frequency by up to 10%. The quantification of the grazing flow effect and identification of a mechanism behind the noise penalty from the prior turbofan rotor experiment will aid in the design of future over-the-rotor treatments.
    Keywords: Aircraft Design, Testing and Performance
    Type: GRC-E-DAA-TN67974 , AIAA/CEAS Aeroacoustics Conference; May 20, 2019 - May 23, 2019; Delft; Netherlands
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  • 12
    Publication Date: 2019-07-13
    Description: This presentation covers recent process improvements regarding environmental parameters, w.r.t convection, and future plans for thermal models.
    Keywords: Aircraft Design, Testing and Performance
    Type: GSFC-E-DAA-TN68948 , 2019 Scientific Ballooning Technologies Workshop; May 14, 2019 - May 16, 2019; Minneapolis, MN; United States
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  • 13
    Publication Date: 2019-07-13
    Description: Presentation will cover new high level requirement changes for gondolas launched by Columbia Scientific Balloon Facility (CSBF), and discuss recommendations for the design and design process.
    Keywords: Aircraft Design, Testing and Performance
    Type: GSFC-E-DAA-TN68680 , 2019 Scientific Ballooning Technologies Workshop; May 14, 2019 - May 16, 2019; Minneapolis, MN; United States
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  • 14
    Publication Date: 2019-07-27
    Description: This paper describes an aero-structural modeling method for the Transonic Truss-Braced Wing (TTBW) aircraft using VSPAERO. A vortex-lattice model of the TTBW aircraft is developed, and a transonic and viscous flow correction method is implemented in the VSPAERO models to account for transonic and viscous flow effects. A correction method for the wing-strut interference aerodynamics is developed and applied to the VSPAERO solver. Also, a structural dynamic finite-element model of the TTBW aircraft is developed. This finite-element model includes the geometric nonlinear effect due to the tension in the struts which cause a deflection dependent nonlinear stiffness. The VSPAERO models are coupled to the finite-element model to provide a rapid capability for aero-structural modeling and flutter analysis. A flight-optimized jig twist model is being developed and will be applied for the purpose of generating a full flight dynamic model of the TTBW aircraft.
    Keywords: Aircraft Design, Testing and Performance
    Type: ARC-E-DAA-TN69149 , Aviation Forum; Jun 17, 2019 - Jun 21, 2019; Dallas, TX; United States
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  • 15
    facet.materialart.
    Unknown
    In:  CASI
    Publication Date: 2019-08-17
    Description: This student poster describes their experiences during the current intern period.
    Keywords: Aircraft Design, Testing and Performance
    Type: AFRC-E-DAA-TN71270
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  • 16
    Publication Date: 2019-08-27
    Description: NASA's all-electric X-57 airplane will utilize 14 electric motors, of which 12 are exclusively for lift augmentation during takeoff and landing. This report covers the design and development process taken to create an open reference model representative of the 12 lift augmenting motors. A combined worst case scenario was used as the design point, which represents the simultaneously occurring worst case aspects of thermal, static stress, electromagnetic, and rotor dynamic conditions. This work also highlights the tightly coupled nature of aerospace electric motor design, requiring constant iteration between all disciplines involved. Further adding to the uniqueness is the cooling method, which is limited to nacelle skin forced convection cooling only, no internal air flow is permitted. The stator outer diameter limit of 156.45 mm greatly impacts the degree of coupling between the electromagnetic design with the thermal analysis. The permanent magnet synchronous motor developed here operates between 385 V and 538 V, at a peak current of 50 A. Detailed electromagnetic, thermal, static load, and rotordynamic analysis was completed for this electric motor; all of which are required for a full design. The rotordynamic analysis took into consideration the motor housing which is designed specifically for this motor. The final electric motor has a mass of 2.34 kg, produces 24.1 Nm of torque with a specific power of 5.56 kW/kg, and has an efficiency of 96.61% at the combined worst case design point.
    Keywords: Aircraft Design, Testing and Performance
    Type: GRC-E-DAA-TN71034 , AIAA/IEEE Electric Aircraft Technologies Symposium; Aug 22, 2019 - Aug 24, 2019; Indianapolis, IN; United States
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  • 17
    facet.materialart.
    Unknown
    In:  CASI
    Publication Date: 2019-08-28
    Description: Adding an ACTE II (Adaptive Compliant Trailing Edge II) closeout summary to the ACTE II TechPort page.
    Keywords: Aircraft Design, Testing and Performance
    Type: HQ-E-DAA-TN68391
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  • 18
    facet.materialart.
    Unknown
    In:  CASI
    Publication Date: 2019-09-18
    Description: This project details the design and analysis of a structure to replace the interface of the P-3B nadir port with an optimized interface for science installations. A new nadir port plug has been designed to replace the OEM (Original Equipment Manufacturer) plug (Lockheed PN 910169) currently used in Nadir ports 1 and 2 on the NASA P-3B aircraft. The plug consists of a milled frame that can be outfitted with customizable flat plates to meet a broad range of science needs. The frame slides into place using the existing P-3B rail system using a lever and tie-rod assembly. The seal interface will contact the Fuselage skin of the aircraft and consists of a bulb E-seal that is riveted around the perimeter of the frame. The flat plate (20 inches x 31 inches) provides a large profile that can be outfitted based on science mission goals and requirements to attach multiple instruments. This is a significant increase to the aircraft capability. Previously, the OEM plug had to be modified to hold very small plates, windows, or instruments limiting the use of the ports.There were several challenges for this project that included a constrained schedule, lack of historical references, and reverse engineering. The unusually tight schedule for design, manufacture, and install limited potential approaches. In addition, design of a new interface to replace the existing plug, on an aircraft designed in the 1960's by Lockheed for the Navy with little to no documentation, required substantial reverse engineering. In order to accomplish this, a suitable method to determine interface requirements with the aircraft had to be solved. After several iterations, the solution was to implement laser scanning techniques to scan the aircraft and the OEM plug and generate a 3D model to capture the design envelope. The structure is designed to maintain a positive margin of safety when subjected to the inertial, pressure, and aerodynamic load requirements for an external installation on the P-3B, as described in the Wallops' P-3B Design Requirements 548-RQMT-0001 Rev. A . A finite element model is created in FEMAP (Finite Element Modeling And Postprocessing) and is run through NX Nastran solver to analyze the structure. After several iterations of analysis, the structure was enveloped to hold 115 pounds evenly distributed on the plate.
    Keywords: Aircraft Design, Testing and Performance
    Type: GSFC-E-DAA-TN72505 , NASA Early Career Forum: Structures, Loads, and Mechanical Systems (SLaMS 2019); Sep 10, 2019 - Sep 13, 2019; Palmdale, CA; United States
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  • 19
    Publication Date: 2019-11-28
    Description: This report characterizes the certification practices for electric propulsion systems by modeling changes to current engine and propeller certification practices (14 CFR 23, 33 and 35 and means of compliance in standards developed by ASTM Committee F39 and F44). Industry technology paths are varied, so this report focuses on insights from the NASA X-57 Maxwell Distributed Electric Propulsion flight demonstrator system technology project. There are 122 sections of the regulation reviewed, where 28 needed tailoring or revision. A second report will examine the regulations to the X-57 system development products. A final report will describe a general regulatory gaps method for new vehicle concepts.
    Keywords: Aircraft Design, Testing and Performance
    Type: NF1676L-34449 , NASA/CR−2019-220406
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  • 20
    Publication Date: 2019-10-12
    Description: This paper will address NASA activities to monitor and study Earth processes from long-duration unmanned aircraft systems (UAS). NASA is currently supporting both large and small UAS development and demonstration. In a follow-on to previous work, NASA Armstrong Flight Research Center is hosting test flights of a large AeroVironment solar-powered aircraft, while NASA Ames Research Center is supporting the demonstration of a light-weight solar powered aircraft by Swift Engineering. Both are designed for long duration, multi-day flight. NASA Earth Science and Aeronautics researchers have been involved in the development and use of High Altitude Long Endurance (HALE) UAS since the 1990's. The NASA Environmental Research Aircraft Sensor and Technology Program (ERAST) demonstrated the promise of HALE aircraft for providing observations while also proving the importance of triple-redundant avionics to improve system reliability for large unmanned aircraft. Early efforts to develop an operational HALE capability for earth observations languished for nearly two decades owing to insufficient solar panel efficiency, battery power density, and light-weight, yet strong, materials. During this time NASA researchers focused on using the Global Hawk to demonstrate the utility of providing diurnal measurements over severe storms (i.e. HS3) and to track stratospheric water vapor transport (ATTREX). Recent significant commercial investments are now leading to the realization of a long-held goal of week- to month-long sustained observations and measurements from the stratosphere. In addition to a historical review of NASA use and interest in HALE aircraft, this paper will present current concepts for exploiting current and planned HALE aircraft capabilities including in situ characterization of atmospheric composition and dynamics as well as imagery collection and internet connectivity. NASA researchers anticipate HALE will also provide a useful means to test smallsat instruments and components. Observations from HALE-based instruments might also provide useful gap-filler observations to flagship satellite missions where the repeat time doesn't allow for measurements of quickly changing phenomenon. HALE will likely also provide measurements and communications relay to facilitate other aircraft in multi-aircraft campaigns. We will also report on progress towards a NASA-supported flight tests solar electric vehicles planned for 2019. One is the Swift Engineering UAS designed to carry 7kg (15lbs) for 30 days at 20km altitude. The other is the AeroVironment Hawk 30, also designed for multi-day flight.
    Keywords: Aircraft Design, Testing and Performance
    Type: ARC-E-DAA-TN73765 , Pecora 21/ISRSE 38; Oct 06, 2019 - Oct 11, 2019; Baltimore, MD; United States
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  • 21
    Publication Date: 2019-11-23
    Description: No abstract available
    Keywords: Aircraft Design, Testing and Performance
    Type: NF1676L-31660 , AIAA Aviation Forum; Jan 17, 2019 - Jan 21, 2019; Dallas, TX; United States
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  • 22
    Publication Date: 2019-12-21
    Description: No abstract available
    Keywords: Aircraft Design, Testing and Performance
    Type: ARC-E-DAA-TN75498 , International Conference for High Performance Computing, Networking, Storage, and Analysis (SC19); Nov 17, 2019 - Nov 22, 2019; Denver, CO; United States
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  • 23
    Publication Date: 2020-01-21
    Description: New manufacturing methods are needed to obtain innovative electric motor designs that have much higher power densities and/or efficiencies compared to the current state-of-the-art. Additive manufacturing offers the potential to radically change motor designs so that they have compact designs, multi-material components, innovative cooling, and optimally designed and manufactured components. New component designs enabled by additive manufacturing technologies have been designed and were fabricated to include the housing, rotors, stator cooling ring, a direct printed stator, and a wire embedded stator. The new components were integrated into the motor and tested evaluate the performance gains in comparison to the baseline electric motor configuration. Partners on the sub-project include NASA GRC, NASA LaRC, NASA AFRC, LaunchPoint Technologies, and the University of Texas El Paso.
    Keywords: Aircraft Design, Testing and Performance
    Type: GRC-E-DAA-TN74521 , Convergent Aeronautics Solutions (CAS) Showcase ; Nov 13, 2019 - Nov 14, 2019; Orlando, FL; United States
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  • 24
    Publication Date: 2020-01-10
    Description: NASA Langley and Glenn Research Centers have collaborated on the usage of acoustic liners mounted very near or directly over the rotor of turbofan aircraft engines. This collaboration began over a decade ago with the investigation of a metallic foam liner. Similar to conventional acoustic liner applications, this liner was designed to absorb sound generated by the rotor-alone and rotor-stator interaction sources within the fan duct. Given its proximity to the rotor tips, the expectation was that the liner would also serve as a pressure release and thereby inhibit the amount of noise generated. Initial acoustic results were promising, but there was concern regarding potential aerodynamic penalties. Nevertheless, there were sufficient positive results to warrant further investigation. To that end, the current report presents results obtained in the NASA Langley Normal Incidence Tube for 20 acoustic liner candidates for the OTR application. The majority contain grooves at their surface, designed to minimize aerodynamic penalties caused by placing the liner in close proximity to the fan rotor tips. The intent is to assess the acoustic properties of each liner configuration, and in particular to assess the effects of including the grooves on the overall acoustic performance. An additional intent of this paper is to provide documentation regarding recent enhancements to the NASA Langley Normal Incidence Tube.
    Keywords: Aircraft Design, Testing and Performance
    Type: NF1676L-35060 , NASA/TM–2019–220430
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  • 25
    Publication Date: 2019-07-13
    Description: A streamlined Multi-Disciplinary Analysis and Optimization (MDAO) process is being developed to provide feedback on conceptual designs and early airspace modeling assessments of unconventional aircraft. This MDAO process has been demonstrated using a Low-Boom Flight Demonstrator (LBFD) like configuration by performing a trade study of various flap sizes. The results of this trade showed that shorter takeoff distances are achieved with increased flap chord and flap deflections. This trend is unlike conventional transport type aircraft which typically show increased required takeoff distances due to the increased drag during its take-off flap configurations. The LBFD like configuration results are attributed to its high engine thrust which overcomes the higher drag associated with these takeoff flap configurations.
    Keywords: Aircraft Design, Testing and Performance
    Type: NASA/TM—2019–220239 , ARC-E-DAA-TN59874
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  • 26
    Publication Date: 2019-07-13
    Description: NASAs Hypersonic Inflatable Aerodynamic Decelerator (HIAD) technology was selected for a Technology Demonstration Mission under the Space Technology Mission Directorate in 2017. HIAD is an enabling technology that can facilitate atmospheric entry of heavy payloads to planets such as Earth and Mars using a deployable aeroshell. The deployable nature of the HIAD technology allows it to avoid the size constraints imposed on current rigid aeroshell entry systems. This enables use of larger aeroshells resulting in increased entry system performance (e.g. higher pay-load mass and/or volume, higher landing altitude at Mars). The Low Earth Orbit Flight Test of an Inflatable Decelerator (LOFTID) is currently scheduled for late-2021. LOFTID will be launched out of Vandenberg Air Force Base as a secondary payload on an Atlas V rocket. The flight test features a 6m diameter, 70-deg sphere-cone aeroshell and will provide invaluable high-energy orbital re-entry flight data. This data will be essential in supporting the HIAD team to mature the technology to diameters of 10m and greater. Aeroshells of this scale are applicable to potential near-term commercial applications and future NASA missions. Currently the LOFTID project has completed fabrication of the engineering design unit (EDU) inflatable structure (IS) and the flexible thermal protection system (F-TPS). These two components along with the rigid nose and center body comprise the HIAD aeroshell system. This EDU aeroshell is the precursor to the LOFTID aeroshell that will be used for flight. The EDU was built to verify the design given the subtle differences between the LOFTID aeroshell and past aeroshell designs that have been fabricated under the NASA HIAD project. To characterize the structural performance of the LOFTID aeroshell design, three structural tests will be performed. The first test to be conducted is static load testing, which will induce a uniform load across the forward surface of the aeroshell to simulate the expected pressure forces during atmospheric entry. The IS integrated with the rigid center body will first be tested alone to provide data for analytical model correlation, and then the F-TPS will be integrated for a second series of static load testing of the full aeroshell system. Instrumentation will be employed during the test series to measure component loads during testing, and a laser scanner will be used to generate a 3D map of the aeroshell surface to verify that the shape of the structure is acceptable at the simulated flight loads. After static load testing, pack and deployment testing will be conducted multiple times on the integrated system to demonstrate the aeroshells ability to fit within the required packed volume for the LOFTID mission without experiencing significant damage. Finally, the aeroshell will undergo modal testing to characterize its structural response. This presentation will discuss the setup and execution of each of the three tests that the EDU aeroshell will undergo. In addition, initial results of the testing will be presented outlining key findings as LOFTID moves for-ward with fabrication of the flight aeroshell.
    Keywords: Aircraft Design, Testing and Performance
    Type: ARC-E-DAA-TN66439 , International Planetary Probe Workshop; Jul 08, 2019 - Jul 12, 2019; Oxford; United Kingdom
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  • 27
    Publication Date: 2019-12-17
    Description: Heat flux characterization of high-enthalpy boundary layer flows is key to optimize the performance and design of Thermal Protection System of next generation aerospace vehicles [1]. At atmospheric entry hypersonic speeds, ablation as well as surface catalycity impact boundary layer aeroheating. Out-gassing occurring from an ablative surface in planetary entry environment introduces a rich set of problems in thermodynamic, fluid dynamic, and material pyrolysis. Ablation leads to out-gassing and surface roughness, both of which are known to affect surface heating in hypersonic chemically reacting boundary layers via three main routes: gas blowing into the boundary layer from the wall, changing the surface heat transfer due to wall-flow chemical reactions, and modifying surface roughness via ablative processes.
    Keywords: Aircraft Design, Testing and Performance
    Type: ARC-E-DAA-TN76132 , American Physical Society's Division of Fluid Dynamics Annual Meeting; Nov 23, 2019 - Nov 26, 2019; Seattle, WA; United States
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  • 28
    Publication Date: 2019-11-28
    Description: Innovative technology has to prove itself in the context of legacy regulations. The knowledgeable technologist must engage standards process and regulating authorities to understand their roles and to advise the effect of new technology, and with manufacturers to demonstrate technology benefit. A model for Innovative Technology Environment relating NASA to industry, standards and regulation is described. The needs of the standards community of the X-57 are identified, and a NASA standards structure is described. No NASA project works with standards and regulatory organizations like the X-57.
    Keywords: Aircraft Design, Testing and Performance
    Type: NF1676L-34451 , NASA/CR−2019-220408
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  • 29
    Publication Date: 2019-11-28
    Description: This report describes a generic method for addressing any new technology to its associated set of regulations and certification criteria. The result is a framework under which a detailed assessment can be conducted. Using just such a framework, the report maps the detailed updated regulations and evolving ASTM standards to the particular technology planning and tests. As a result, a roadmap of NASA technology is documented that shows clear transfer of technology data to industry (standards developers, as well as technology developers) and the FAA regulatory policy and certification staff upon whom certification and policy will be data-driven. A clear description of benefits and gaps are identified, as well.
    Keywords: Aircraft Design, Testing and Performance
    Type: NF1676L-34450
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  • 30
    Publication Date: 2019-07-13
    Description: Wing design optimization has been studied extensively and is of continued interest as optimization tools are developed and become more accessible. In each of these studies, certain assumptions and simplifications are made to make the design problem tractable. However, it is difficult to find systematic studies in which several considerations are added or removed one at a time to study how much impact they have. In this work, we examine how certain physical considerations (viscous drag, wave drag, thrust loads, and inertial relief from structural, fuel, and engine masses), impact the aerostructural optimization results for three distinct aircraft wings. The goal is to help develop a rough idea of how important these physical considerations are. We do this using gradient-based optimization and a multidisciplinary design optimization framework, OpenMDAO. We use the open-source tool OpenAeroStruct that couples a vortex lattice method to a finite element method. We establish a baseline aerostructural design optimization problem then perform a series of optimizations, each with one physical consideration removed from the baseline case. We find that depending on the size of the aircraft and flight conditions, the importance of some of these physical considerations varies considerably whereas the importance of others do not. Specifically, the optimal designs change radically without proper viscous and wave drag considerations and smaller aircraft with more distributed propulsion are more affected by the inclusion of engine loads.
    Keywords: Aircraft Design, Testing and Performance
    Type: GRC-E-DAA-TN68633 , GRC-E-DAA-TN68641 , AIAA Aviation and Aeronautics Forum (Aviation 2019); Jun 17, 2019 - Jun 21, 2019; Dallas, TX; United States
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  • 31
    Publication Date: 2019-07-13
    Description: The accurate prediction of turbulent mixing in high-pressure turbines that incorporate various airfoil surface-cooling strategies is becoming increasing critical to the design of modern gas turbine engines where the quest for improved efficiency is driving compressor overall pressure ratios and turbine inlet temperatures to much higher levels than ever before. In the present paper, a recently developed computational capability for accurate and efficient scaleresolving simulations of turbomachinery is extended to study the turbulent mixing mechanism of a simplified abstraction of an airfoil trailing-edge cooling slot - a plane wall jet with finite lip thickness discharging into an ambient flow. The computational capability is based on an entropy stable, discontinuousGalerkin approach that extends to arbitrarily high orders of spatial and temporal accuracy. The numerical results show that the present simulations capture the trends observed in the experiments. Discrepancies between the simulations and experiments are believed to be due to differences in the inflow profiles and tunnel sidewall effects. The thick lip configuration leads to a thicker wake and higher unsteadiness in the wall jet compared to the thin lip. A detailed comparison of the turbulent flowfields is presented to highlight differences arising due to lip thickness variations.
    Keywords: Aircraft Design, Testing and Performance
    Type: ARC-E-DAA-TN63837 , ASME Turbomachinery Technical Conference & Exposition; Jun 17, 2019 - Jun 21, 2019; Phoenix, AZ; United States
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  • 32
    Publication Date: 2019-07-13
    Description: The Tiltrotor Test Rig (TTR) was tested in the National Full-Scale Aerodynamics Complex (NFAC) 40- by 80-Foot Wind Tunnel from 2017 to 2018. The rotor system can be configured in airplane mode, with the rotor plane perpendicular to the wind flow, and in helicopter mode, with the rotor plane parallel to the wind flow. Four microphones were placed around the TTR: two on the wind tunnel floor and two on struts. The primary goal of the test was to understand the operational capabilities of the TTR, while also acquiring research data as available. Limited measurements of the blade vortex interaction (BVI) noise of the TTR rotor were taken to not only understand the acoustic testing capabilities of the TTR in the NFAC 40- by 80-Foot Wind Tunnel, but to also compare to previous tests and to be used for future validation studies. In particular, data will be compared to measurements of an XV-15 rotor previously acquired in the NFAC 80- by 120-Foot Wind Tunnel.
    Keywords: Aircraft Design, Testing and Performance
    Type: ARC-E-DAA-TN62155 , Vertical Flight Society''s Annual Forum and Technology Display; May 13, 2019 - May 16, 2019; Philadelphia, PA; United States
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  • 33
    Publication Date: 2019-07-13
    Description: Supersonic aircraft are challenging to optimally design due to the widely varying constraints and flight conditions they experience. Additionally, a large number of disciplinary subsystems must be considered due to highly complex design requirements. One subsystem that has a major effect on overall performance is the engine. In this work, we construct a supersonic mixed-flow variable cycle engine and perform multipoint gradient-based optimization using this model. We see that the operational variables allow the optimizer to tailor performance at each individual flight condition, leading to better overall performance. To simulate airframe integration constraints, we run successive optimizations with increasingly restrictive inlet areas and see decreases in engine performance. This work is part of a larger effort to incorporate engine design into aero-thermal-mission optimization of a supersonic aircraft.
    Keywords: Aircraft Design, Testing and Performance
    Type: GRC-E-DAA-TN63727 , AIAA 2019-0172 , AIAA SciTech Forum 2019; Jan 07, 2019 - Jan 11, 2019; San Diego, CA; United States
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  • 34
    Publication Date: 2019-07-13
    Description: Many of the aircraft concepts of the future are exploring the use of hybrid-, turbo- or all-electric propulsion systems to improve performance and decrease environmental impacts. These aircraft concepts range from small rotorcraft for urban air mobility to conventional commercial transports to large blended wing body designs. Developing the conceptual design for these vehicles presents a challenge, however, as traditional aircraft design tools often were not developed to handle these unique propulsion system architectures. Previous studies on these vehicles have therefore relied on relatively simple models of the electrical transmission and distribution system. This paper presents the development of a hybrid AC-DC load flow (or power flow) analysis capability to enhance the conceptual design of these concept vehicles. Specifically, the desire was to create a load flow analysis capability within the OpenMDAO framework that is also being used to develop a set of compatible tools for rapid optimization of conceptual designs. This load flow analysis capability is unique in its flexible object-oriented structure and implementation of analytic derivatives to facilitate the use of solvers and gradient based optimization in the design process. The developed hybrid load flow analysis capability is first verified against a published 13-bus example then used to model the electrical distribution system for a turbo-electric tiltwing aircraft.
    Keywords: Aircraft Design, Testing and Performance
    Type: GRC-E-DAA-TN63675 , AIAA Science and Technology Forum and Exposition (SciTech); Jan 07, 2019 - Jan 11, 2019; San Diego, CA; United States
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  • 35
    Publication Date: 2019-07-13
    Description: Urban Air Mobility vehicles are intended to operate near or within large cities, where a significant portion of the public will be exposed to the noise they create. If these vehicles are to become acceptable to the public, designers must be able to manage the amount of noise they generate, and understand the relationship between traditional performance metrics (thrust, efficiency, etc.) and noise. As a first step to addressing this need, this work combines a blade element momentum theory tool (OpenBEMT) with an acoustic prediction tool (ANOPP2) to optimize a propeller subject to both aerodynamic and acoustic constraints. These tools are developed within a optimization framework (OpenMDAO) that allows analytic derivatives to be propagated through the models and passed to a gradient-based optimizer. This tool chain is exercised on the cruise propellers from the X-57 Maxwell, and yields propeller designs that reduced the overall sound pressure level by about 5 dB for a cost of 1% propeller efficiency.
    Keywords: Aircraft Design, Testing and Performance
    Type: GRC-E-DAA-TN63365 , SCITECH 2019 (AIAA); Jan 07, 2019 - Jan 11, 2019; San Diego, CA; United States
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  • 36
    Publication Date: 2019-10-12
    Description: No abstract available
    Keywords: Aircraft Design, Testing and Performance
    Type: ARC-E-DAA-TN71894 , U.S. National Congress on Computational Mechanics; Jul 28, 2019 - Aug 01, 2019; Austin, TX; United States
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  • 37
    Publication Date: 2019-10-01
    Description: The present paper details the design of the counter rotating fans for a Turboelectric Distributed Propulsion (TeDP) system. Sixteen propulsors installed in mail-slot-shape nacelles are embedded on an aerodynamically optimized hybrid wing-body configuration. The hybrid-wing/body (HWB) configuration which was previously designed to satisfy the conditions of trim, longitudinally static stability and specific cargo space is employed as the baseline configuration in pursuing an optimal distributed propulsion system. A set of distributed propulsors is conceptually designed and the collective performance is evaluated against the target thrust mandated by the mission requirements. The concept of the distributed propulsion allows the fan pressure ratio to be around 1.27~1.32 for the target thrust. In addition, further splitting of the fan pressure ratio by using the counter-rotating fans for each slot realizes the target pressure ratio with low tip speed. In the distributed propulsion system, the nature of the flow conditions and/or the thickness of the ingested boundary layer may differ and result in different propulsive reaction of each individual propulsor. The optimization is, thus, approached from both the propulsion system and individual propulsor perspectives. An optimal distribution of the thrust and power output is determined by how the system utilizes each passage's propulsive characteristics and its interaction with the airframe. These system level analysis and optimization are conducted using an actuator disk model to account for the propulsion-airframe integration numerically. With respect to the propulsor level, aerodynamic shape optimizations of the fan blades are performed in a sequential multi-objective optimization process for various design objectives, such as mass flow rate condition, fan pressure ratio, efficiency and the exit flow angle of the fan stage by using a genetic algorithm, NSGA-II. The radial chord distribution, and meanline distribution of the rotors are designed on the circumferentially averaged axi-symmetric inlet profiles and tested on the six inlet profiles from six divided sectors to reckon flow distortion. The performances of the counter rotating fans are, thus, evaluated accordingly for obtaining distortion tolerant fan. The performance of the distributed propulsion system is evaluated by two CFD tools, i.e., a multi-stage turbo-machinery CFD code and one propulsion-airframe integration flow solver coupled with a body-force model. The optimized boundary layer ingestion propulsion system of 16 distributed slots not only reaches the system target thrust, but also delivers a close to 20% fuel saving benefit against its counterpart 12 distributed clean inlet propulsion system.
    Keywords: Aircraft Design, Testing and Performance
    Type: GRC-E-DAA-TN72036 , The International Society for Air Breathing Engines (ISABE) Conference 2019; Sep 22, 2019 - Sep 27, 2019; Canberra; Australia
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  • 38
    Publication Date: 2019-10-01
    Description: Safe Unmanned Aerial Vehicle (UAV) operations near the ground require navigation methods that avoid fixed obstacles such as buildings, power lines and trees. Aerial lidar surveys of ground structures are available with the precision and accuracy to geolocate obstacles, but the high volume of raw survey data can exceed the compute power of onboard processors and the rendering ability of ground-based flight planning maps. Representing ground structures with bounding polyhedra instead of point clouds greatly reduces the data size and can enable effective obstacle avoidance, as long as the bounding geometry envelopes the structures with high spatial fidelity. This report describes in detail four methods to compute bounding geometries of ground obstacles from lidar point clouds. The four methods are: 1) 2.5D Maximum Elevation Box, 2) 2.5D Ground Map Extrusion, 3) 3D Bounding Cylinder, and 4) 3D Bounding Box. The methods are applied to five point cloud datasets from lidar surveys of UAV flight research sites in Georgia and Virginia with an average point spacing that ranges from 0.1m to 0.6m. The methods are assessed using survey areas with geometrically heterogeneous ground structures: buildings, vegetation, power lines, and sub-meter structures such as road signs and guy wires. The 2.5D Maximum Elevation Box method is useful for simple structures. The 2.5D Ground Map Extrusion method efficiently encloses vegetation, but requires handdrawn ground footprints. The 3D Bounding Cylinder method excels at enclosing linear structures such as power lines and fences. The 3D Bounding Box method excels at enclosing planar structures such as buildings. The methods are compared on the basis of data compression and boundary fidelity on selected areas. The 2.5D methods yield the highest data compression but the polyhedra produced by them enclose significant amounts of empty space. Boundary fidelity is superior for the 3D methods, though this fidelity comes at the cost of a roughly thirtyfold lower data compression ratio than the 2.5D Maximum Elevation Box method. A mix of these output geometries is proposed for autonomous UAV navigation with limited on-board computing. Both the accuracy and spatial detail of emerging satellite-based survey technology lower than that of aerial lidar scanning survey technology. Sub-meter structures and thin linear structures are not reliably mapped at present by satellite-based surveys.
    Keywords: Aircraft Design, Testing and Performance
    Type: NF1676L-34257 , NASA/TM–2019-22399
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  • 39
    Publication Date: 2019-10-01
    Description: The Airborne Spacing for Terminal Arrival Routes (ASTAR) Flight Test was conducted by the NASA Air Traffic Management Technology Demonstration 1 (ATD- 1) project to demonstrate the use of NASAs ASTAR algorithm beyond a simulated environment and assess the operational risks of performing a multi-aircraft flight test of Flight-deck Interval Management (FIM). Utilizing contemporary tools of the Federal Aviation Administrations Next Generation Air Transportation System (NextGen) such as ADS-B, the ASTAR algorithm calculated speeds that the flight crew flew to achieve a precise spacing interval behind another aircraft at the final approach fix. Airspeed commands issued by the algorithm were flown by the flight crew of the FIM-equipped aircraft to achieve or maintain an assigned spacing goal from a target vehicle. The ASTAR algorithm was integrated with the Boeing supplied B-787 ecoDemonstrator aircraft, and five flight trials were conducted as a joint effort between NASA and Boeing on December 12, 2014. Initial results indicated arrival times within several seconds of accuracy of the planned termination point between two aircraft performing FIM in a real world environment. This flight test opened the way for the much more expansive ATD-1 Avionics Phase II flight test which occurred in early 2017. The flight trials under Phase II preceded further testing by the community in preparation for inclusion of the Interval Management concept as a part of the NextGen environment.
    Keywords: Aircraft Design, Testing and Performance
    Type: NASA/TM–2019-220404 , L-20741 , NF1676L-25257
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  • 40
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    In:  CASI
    Publication Date: 2019-11-21
    Description: These slides are an overview of the FT6 Test and Evaluation program.
    Keywords: Aircraft Design, Testing and Performance
    Type: AFRC-E-DAA-TN75432 , UAS-NAS FT6 VIP Day at Edwards Airforce Base; Nov 12, 2019; Kern County, CA; United States
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  • 41
    Publication Date: 2019-11-20
    Description: A tool to give the public a window into Unmanned Aerial Systems (UAS) Traffic Management (UTM) operations was created from an existing data collection tool. The interface included a map and a table showing details about UAS operations that could be queried in a number of ways. Eleven participants attended the study, successfully completing a 19-item task set in about 30 minutes. They correctly found information for 87% of the non-subjective tasks at a rate of around a minute per task, and rated the usability of the tool at the end of the session above the industry benchmark. Participants gave favorable reviews of the "public portal tool", even reporting that they would be satisfied with less information that it presented. There were one or two elements of the display that users found distracting and some navigation functions that need improvement, but on balance, the public representatives liked the features they saw in, and had few criticisms of, the public portal tool. One important issue for the small Unmanned Aerial System community to resolve will be how much or how little information should be available about UTM operations to members of the public.
    Keywords: Aircraft Design, Testing and Performance
    Type: ARC-E-DAA-TN74749 , Human Factors and Ergonomics Society (HFES) 2019; Oct 28, 2019 - Nov 01, 2019; Seattle, WA; United States
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  • 42
    Publication Date: 2019-11-20
    Description: A tool to give the public a window into Unmanned Aerial Systems (UAS) Traffic Management (UTM) operations was created from an existing data collection tool. The interface included a map and a table showing details about UAS operations that could be queried in a number of ways. Eleven participants attended the study, successfully completing a 19-item task set in about 30 minutes. They correctly found information for 87% of the non-subjective tasks at a rate of around a minute per task, and rated the usability of the tool at the end of the session above the industry benchmark. Participants gave favorable reviews of the "public portal tool", even reporting that they would be satisfied with less information that it presented. There were one or two elements of the display that users found distracting and some navigation functions that need improvement, but on balance, the public representatives liked the features they saw in, and had few criticisms of, the public portal tool. One important issue for the small Unmanned Aerial System community to resolve will be how much or how little information should be available about UTM operations to members of the public.
    Keywords: Aircraft Design, Testing and Performance
    Type: ARC-E-DAA-TN66269 , Human Factors and Ergonomics Society (HFES) Annual Meeting 2019; Oct 28, 2019 - Nov 01, 2019; Seattle, WA; United States
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  • 43
    Publication Date: 2019-11-19
    Description: Overview of the projects in the Advanced Air Vehicle Program, Aeronautics Research Mission Directorate.
    Keywords: Aircraft Design, Testing and Performance
    Type: HQ-E-DAA-TN75332 , 2019 Transportation and Defense Policy Fly-In; Nov 12, 2019 - Nov 13, 2019; Washington, DC; United States
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  • 44
    Publication Date: 2020-01-22
    Description: No abstract available
    Keywords: Aircraft Design, Testing and Performance
    Type: GRC-E-DAA-TN74511 , Propulsion and Power Technical Meeting; Oct 29, 2019 - Oct 30, 2019; Hampton, VA; United States
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  • 45
    Publication Date: 2020-01-18
    Description: The paper describes a feedback controls design approach for a generic regional jet turbofan engine, which can be adapted to aero engines in general. To demonstrate this approach, linear models for control design are generated at different operating conditions from a full envelope nonlinear simulation created with the NASA Glenn Research Center-developed Toolbox for the Modeling and Analysis of Thermodynamic Systems. The primary objective is to design a single feedback controller that achieves good performance, without the need of developing scheduled control designs to cover the engine operating envelope. An additional objective is to progressively design more robust controllers that can perform under large variations in plant dynamics to also cover control for engine limits and potentially for some off nominal or even damaged conditions.
    Keywords: Aircraft Design, Testing and Performance
    Type: NASA/TM-2019-220361 , E-19750 , GRC-E-DAA-TN73199 , Propulsion and Energy Forum; Aug 19, 2019 - Aug 22, 2019; Indianapolis, IN; United States
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  • 46
    Publication Date: 2020-01-17
    Description: This project intends to update and redesign imperfections in the scanned 3D CAD model of the Viking 400 aircraft. This aircraft, similar to the Sierra-B UAS, will carry payloads of scientific instruments for research purposes. The goals of this project are to modify the current scanned model such that it better represents the physical qualities of the aircraft, as well as creating the features that are missing from the model. As the model was imported from a different software, many of the critical surfaces did not accurately reflect the actual aircraft. Those parts of the model were redesigned entirely so that they can be edited for future use, as well as correctly representing the aircraft as it is now. Additionally, parts of the aircraft that did not appear in the scanned model were designed and added to the new model. In order to prioritize ease of use for future missions, the model has been reorganized in a logical fashion that enables modification of specific parts of the aircraft. The organization of this model imitates the drawing tree of the Sierra-B, with the intention of maintaining a functional system of redesign, analysis, and implementation. Ultimately, this project will be a catalyst for making Viking 400 into a functional aircraft and increasing scientific research in airborne vehicles.
    Keywords: Aircraft Design, Testing and Performance
    Type: ARC-E-DAA-TN70779 , Ames Intern Poster Session; Aug 08, 2019; Moffett Field, CA; United States
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  • 47
    Publication Date: 2019-09-21
    Description: The Parallel Electric-Gas Architecture with Synergistic Utilization Scheme (PE- GASUS) vehicle is a regional aircraft concept that uses electric and hybrid-electric propulsors located strategically to obtain aerodynamic and mission benefits. Traditional aircraft analysis tools are not well suited to analyze the PEGASUS aircraft due to the different propulsor types used. This report summarizes a methodology that addresses some of the mission analysis challenges expected in modeling this vehicle concept. An initial baseline design is selected and sensitivity studies are performed to further understand the potential benefits of the concept.
    Keywords: Aircraft Design, Testing and Performance
    Type: NASA/TM–2019–220396 , L-21042 , NF1676-33672
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  • 48
    Publication Date: 2019-11-08
    Description: This work covers the refinement of thermal models from design estimates to actual fabricated performance. Matching the experimental data of the first fully electrified version of the X-57 Maxwell experimental vehicle requires high fidelity thermal analysis to sufficiently capture the electric motor and inverter temperature profiles. Qualification test data of the motors and inverters is used to validate finite element analysis models used to simulate thermal performance over mission transients. An additional thermal-hydraulic models is used to estimate flow characteristics through the propulsor nacelle and component heat sinks. After calibration of the higher order models, overall component sizing and peak temperature constraints can be distilled to reduced order models, to improve modelflexibility and utility.
    Keywords: Aircraft Design, Testing and Performance
    Type: GRC-E-DAA-TN56452 , AIAA Aviation Forum; Jun 17, 2019 - Jun 21, 2019; Dallas, TX; United States
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  • 49
    Publication Date: 2019-10-23
    Description: These slides describe the design and execution of the testing and integration of the X-59 life support system.
    Keywords: Aircraft Design, Testing and Performance
    Type: AFRC-E-DAA-TN73893 , Annual SAFE Symposium; Oct 14, 2019 - Oct 16, 2019; Reno, NV; United States
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  • 50
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1018-1027 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Bei nochmaliger Untersuchung der Umsetzung von CCl4 mit Si/Cu-Gemischen werden, wie bereits bekannt, SiCl4, C2Cl4 und Si2Cl6 gefunden. Darüber hinaus lief eine direkte Synthese. Sie führte wahrscheinlich zur Bildung des allerdings dabei nicht nachgewiesenen Cl3C·SiCl3. Dagegen wurde die nach der direkten Synthese entstandene Verbindung C(SiCl3)4 erstmalig aufgefunden.  -  Die Entstehung der ebenfalls nachgewiesenen Verbindungen Cl3SiC·C⋮CC·SiCl3 und Cl3SiC·(Cl)C:C(Cl)C·SiCl3 wird durch Dechlorierungen des Cl3CC·SiCl3 mit Kupfer erklärt.  -  Für die neuen Verbindungen wurden Strukturbeweise geführt. Es wurden C2Cl4 und Cl3CC·SiCl3 mit Si/Cu-Gemischen umgesetzt. Die letzte Umsetzung ergab dieselben Reaktionsprodukte wie das CCl4, so daß auch bei diesem eine direkte Synthese über das Cl3CC·SiCl3 glaubhaft gemacht ist.
    Additional Material: 2 Ill.
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  • 51
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1048-1055 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Eigenschaften von tert.-Butylthionitrit, Triphenylmethylthionitrit und tert.-Butylthionitrat werden Rückschlüsse auf die Elektronenstruktur der schwefelhaltigen Gruppe gezogen.
    Additional Material: 2 Tab.
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  • 52
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Als weiteres Beispiel für die präparative Überlegenheit der säurekatalysierten Aldolreaktionen des Formaldehyds gegenüber den OH⊖-katalysierten wird über die Synthese der bisher unbekannten Bisanhydro-ennea-heptose, die das Ringsystem des 3.7-Dioxa-bicyclo-[1.3.3]-nonans enthält, berichtet.  -  Bei der Untersuchung des Verhaltens der Bisanhydro-ennea-heptose gegen Alkalien machten sich in der Abspaltbarkeit der Hydroxymethylgruppen charakteristische Unterschiede geltend, deren Erklärung in den konstitutionell-konstellativen Gegebenheiten zu suchen ist.  -  Bei dem Versuch einer Ringerweiterung an der Anhydro-ennea-heptose mit Diazomethan bildet sich eine Verbindung C9H16O5, die wahrscheinlich kein Derivat des Oxa-cycloheptanons-(4), sondern ein Derivat des Tetrahydro-γ-pyrons ist.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1092-1101 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Substituierte Ammoniumsalze vom Typ I liefern mit Abkömmlingen des Phenylglyoxals in Methanol in glatter Reaktion Lactolid-Basen vom Typ II. Aus diesen lassen sich verschiedene Octa- bzw. Decahydroisochinolin-Derivate darstellen, die in 1-Stellung einen substituierten Benzylrest tragen.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1115-1117 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die jodometrische Bestimmung der Hydroperoxyde von Benzolkohlenwasserstoffen kann durch katalytische Wirkung von Kupferionen verbessert werden.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1135-1139 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Umsetzung von Tetraacetyl-α-D-glucopyranosylbromid und Tetraacetyl-6-trityl-β-D-glucopyranose mit Silberperchlorat oder Silberfluoroborat in Nitromethan liefert in guter Ausbeute Octaacetyl-β-gentiobiose. Die gleiche Umsetzung mit einem Überschuß an Tetraacetyl-α-D-glucopyranosylbromid und Silberperchlorat führt zur Octaacetyl-α-gentiobiose. Es wird eine Deutung des Reaktionsablaufs gegeben.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1126-1129 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Tachysterin2 wurde mit durch Glas gefiltertem Quecksilberdampflicht in Präcalciferol2 umgewandelt.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1152-1158 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Um eine Aussage über den Reaktionsmechanismus bei der Mercurierung des Ammonium-Ions in wäßrigen Lösungen machen zu können, wurde Quecksilber-(II)-diamminchlorid, Hg(NH3)2Cl2, mit wäßriger Ammoniumacetat-Lösung zum sog. „unschmelzbaren Präzipitat“, HgNH2Cl, umgesetzt. Die Lösung enthielt 1 Mol. 203Hg(CH3CO2)2 pro Mol. des Diammoniakates.Die beiden heterogenen Austauschreaktionen Hg(NH3)2Cl2/[203Hg(NH3)4]2⊕ und HgNH2Cl/[203Hg(NH3)4]2⊕ wurden in Abhängigkeit von der Temperatur untersucht.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1158-1163 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Von den sechs möglichen Isomeren des Decalindiols-(1.4) wurden zwei der Reihe des cis-Decalins und zwei der Reihe des trans-Decalins angehörende Diole durch Reduktion von cis- und trans-Decalindion-(1.4) sowie durch katalyt. Hydrierung von Naphthohydrochinon-(1.4) und ar-Tetralindiol-(5.8) mit Raney-Nickel im Autoklaven erhalten, eindeutig der cis- und trans-Reihe zugeordnet und durch Derivate charakterisiert.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1184-1188 
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Einwirkung von Aryldiazoniumsalzen auf verschiedene monoalkylierte Dihydroresorcine wurde untersucht. Dabei wurden im glatten Reaktionsverlauf δ-Keto-δ-arylhydrazono-carbonsäuren erhalten. Die gleiche Reaktion führte beim 2-Acetamino-dihydroresorcin infolge einer sekundär verlaufenden Wasserabspaltung zu einem Derivat des 1.2.4-Triazols, dessen Konstitution bewiesen wurde.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1206-1212 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Durch Umsetzung von Alkylhydroperoxyden oder Wasserstoffperoxyd mit Formaldehyd und sekundären Aminen werden nach Art der Mannich-Reaktion Aminoalkylperoxyde erhalten. In mineralsaurer Lösung gelingt auch die Umsetzung von Benzamid oder Harnstoff mit Formaldehyd und Alkylhydroperoxyden.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1216-1223 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Einführung der Carbonsäurechloridgruppe in 1- bzw. 3-Stellung des Azulensystems gelingt durch Substitution mittels Phosgens ohne Friedel-Crafts-Katalysatoren. Befindet sich in Nachbarstellung zur Carbonsäurechloridgruppe am 7-Ring kein Substituent, so lassen sich die Verbindungen zu den freien Carbonsäuren hydrolysieren, andernfalls tritt Decarboxylierung ein. Die Säurechloride lassen sich in Ester, Amide und Anilide überführen. Die spektralen Verschiebungen gegenüber den zugrunde liegenden Azulenen werden diskutiert.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1195-1205 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Hydrierung des Adrenalins mit Raney-Nickel liefert keine brauchbaren Ergebnisse. Das Hexahydro-adrenalin (Xb) wird deshalb synthetisch aus Tetrahydro-benzaldehyd in 5 Stufen in guter Ausbeute dargestellt. Es wird gezeigt, daß das synthetische Produkt eine sterisch weitgehend einheitliche Verbindung ist und die 3(trans).4(cis)-Konfiguration besitzt.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1212-1215 
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Aus cyclischen Ketonen und sekundären Aminen erhältliche α.β-ungesättigte Amine addieren Wasserstoffperoxyd an der Doppelbindung und geben kristalline Peroxyde.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1237-1237 
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    Keywords: Chemistry ; Inorganic Chemistry
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    Topics: Chemistry and Pharmacology
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1239-1246 
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Tetrahydroxy-p-benzochinon zeigt einige Eigenschaften, die es als „doppeltes aci-Redukton“ erscheinen lassen. So erleidet es „Diazo-Spaltung“ unter Bildung von Mesoxalsäure-bis-arylhydrazid. Diazomethan verwandelt es in den Tetramethyläther, der leicht, sogar durch den Ausgangsstoff, zum entspr. Hydrochinon reduziert wird. Es werden noch Acetyl- und Aminoderivate des Tetrahydroxy-p-benzochinons und seines Dimethyläthers beschrieben sowie die UV- und IR-Spektren diskutiert.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1276-1287 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Ausgehend von den in der ersten Veröffentlichung(1) beschriebenen Substanzen wurden Derivate der folgenden Peptide synthetisiert: Glycyl-L-glutaminsäure, Glycyl-glycyl-L-glutaminsäure, γ-L-Glutamyl-glycin, α- und γ-L-Glutamylglycyl-L-glutaminsäure, α- und γ-L-Glutamyl-α-L-glutamyl-glycin und α-L-Glutamyl-L-tyrosin. Auch einige freie Peptide konnten erhalten werden. Als interessante Nebenprodukte der Peptidsynthese über gemischte Anhydride mit Kohlensäure-halbestern wurden in zwei Fällen Diacylimide erhalten.
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    Notes: Beim Behandeln von N-Benzoyl-D-glucosamin (IV) mit chlorwasserstoffhaltigem Aceton entsteht das Acetonderivat VII eines Phenyloxazolins, welches Furanosestruktur besitzt. Dieses wird mit chlorwasserstoffhaltigem Methanol in das entsprechende Aceton-β-methylfuranosid IX und anschließend in das acetonfreie β-Methylfuranosid X umgewandelt.  -  Behandeln von O-Tetraacetyl-N-carbobenzoxy-D-glucosamin (XI) mit TiCl4 oder mit AlCl3/PCl5 führt unter Abspaltung von Benzylchlorid zur Bildung eines Oxazolonderivates (XIII).
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1313-1319 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Methylphenylhydrazone der Monobenzoyl-aldosen liegen im kristallisierten und gelösten Zustand nur als Schiffsche Basen vor, sie zeigen keine Mutarotation und lassen sich zu 5-Benzoyl-2.3.4-triacetyl-pentose- bzw. 6-Benzoyl-2.3.4.5-tetraacetyl-hexose-methylphenylhydrazonen acetylieren, deren Struktur durch Synthese bewiesen wird. Die aus Monobenzoyl-aldose-phenylhydrazonen mit Phenylhydrazin darstellbaren Monobenzoyl-aldose-phenylhydrazonen werden sehr leicht zu Aldose-phenylosazonen und Benzoesäure hydrolysiert.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1329-1335 
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Darstellung des Monobrom-, Monojod- und Trimethoxy-pivalophenons werden beschrieben. Die Halogenverbindungen erleiden bei der Einwirkung wäßriger Alkalien eine hydrolytische Spaltung. Die Methoxyverbindung ist gegen Alkalien stabil.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1363-1366 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: β-Aroyl-acrylsäuren reagieren mit Pyrrol, 1- und 2-Methyl-pyrrol nach dem Schema der substituierenden Addition.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1386-1397 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Durch Oxydation von Tetralol-(6) und Östradiol-17-monoacetat mit Bleitetraacetat werden Tetralin-p-chinolacetat und 17β-Acetoxy-östra-p-chinol-(10ζ)-acetat dargestellt. Aus den Chinolacetaten lassen sich die Chinole durch basenkatalysierte Umesterung in Freiheit setzen. Dem aufgezeigten Weg kommt allgemeine Bedeutung zur Darstellung von p-Chinolen zu.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1472-1477 
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: β-Phenyl-äthylamine lassen sich mit Cyclohexanon-(2)-essigsäure zu partiell hydrierten Oxindol-Derivaten kondensieren, die durch Ringschluß in Verbindungen der Erythrinan-Reihe übergeführt werden.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1478-1480 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Umsetzung von Chlorameisensäure-benzylester mit überschüssigem Hydrazinhydrat in absol. Chloroform ergibt Carbobenzoxy-hydrazin. In wäßrigem Medium entsteht vorwiegend N.N′-Dicarbobenzoxy-hydrazin (I), das von rauchender Salpetersäure leicht zu Azodicarbonsäure-dibenzylester (II) dehydriert wird.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1483-1500 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wurden 2 Tetraphenyl-äthylene, 2 Tetraphenyl-butatriene und 2 Tetraphenyl-hexapentaene mit je 2 meta- bzw. para-ständigen Nitrogruppen dargestellt. Es gelang, die beiden Äthylene durch Kristallisation und das Butatrien mit m-ständigen NO2-Gruppen durch Chromatographie in der cis- und in der trans-Form zu gewinnen. Damit ist bei einem zweiten Beispiel die von J. H. van't Hoff 1874 vorausgesagte Isomerie an einer Verbindung verwirklicht worden, in der 4 C-Atome durch 3 Doppelbindungen verknüpft sind.  -  Die Isomeren des Triens sind lichtempfindlich. Das Mengenverhältnis cis : trans im photochemischen Gleichgewicht entspricht der Zusammensetzung des Kumulens, wie es bei der Synthese anfällt. Die thermische cis-trans-Umlagerung der Butatriene läßt sich vorzüglich IR-spektroskopisch verfolgen. Die Zuordnung der mit A und B bezeichneten isomeren Butatriene zur cis- und trans-Formel wird diskutiert.  -  Von den beiden Hexapentaenen konnte dasjenige mit 2 p-ständigen Nitrogruppen in roten Kristallen, aber nicht in cis-trans-isomeren Formen gewonnen werden. Das entsprechende Hexapentaen mit 2 m-ständigen NO2-Gruppen war in Lösung beständig, es zersetzte sich aber teilweise bei Entfernung des Lösungsmittels.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1517-1523 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Umsetzung von 1.3.5-Trinitro-benzol mit Nitrophloroglucin sowie diejenige von Pikrinsäure mit Phloroglucin führt zu polycyclischen Verbindungen. Deren adamantanartige Konstitution wird auf Grund UV-spektroskopischer Vergleiche diskutiert.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1559-1563 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: α.α′-Alkandialdehyde wurden durch Abbau von α.α′-Dibrom-dicarbonsäuren nach Curtius erhalten. Aus α.α′-Dibrom-korksäure bzw. α.α′-Dibrom-azelainsäure entstanden unter geeigneten Bedingungen l-Formyl-cyclopenten-(1) bzw.-cyclohexen-(1).
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1573-1578 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Der durch Säuren katalysierte Isochinolin-Ringschluß ist unter bestimmten Bedingungen auch mit Substanzen durchführbar, die eine säureempfindliche Gruppe enthalten. Auf diese Weise lassen sich Enoläther bzw. Acetale des Decahydroisochinolons herstellen (XII bzw. XIII), die durch nachfolgende Hydrolyse das freie α.β-ungesättigte Ringketon (XVI) liefern, das man durch direkten Ringschluß nicht erhalten kann.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1594-1599 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Bei der Anlagerung von Ammoniak an Δ1-Tetrahydrobenzoesäure und Cyclopenten-(1)-carbonsäure-(1) entstehen ausschließlich die trans-β-Aminosäuren. Der Nachweis der Konfiguration erfolgt bei den entsprechenden cis-Aminosäuren, die durch Hofmannschen Abbau der cis-Hexahydrophthalamidsäure (V) und des cis-Cyclopentan-dicarbonsäure-(1.2)-monoamids erhalten werden. cis-und trans-2-Amino-cyclopentan-carbonsäure-(1) wurden erstmals dargestellt.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1618-1623 
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: D-Arabinose-mercaptale lassen sich mit p-Toluolsulfonsäure- und mit Methansulfonsäurechlorid in Pyridin bei tiefer Temperatur partiell zu 5-Tosyl- bzw. 5-Mesyl-D-arabinose-mercaptalen verestern. Diese werden mit Lithiumaluminiumhydrid zu 5-Desoxy-D-arabinose-mercaptalen reduziert. Daraus gewinnt man durch Abspalten von Mercaptan die 5-Desoxy-D-arabinose.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1550-1558 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die gleichzeitige Einwirkung von o-Phenylendiamin und Phenylhydrazin auf Dehydro-L-ascorbinsäure führt zum 2-Hydroxy-3-[1′-phenylhydrazono-L-threo-2′.3′4′-trihydroxy-butyl]-2.2′-anhydro-chinoxalin, dessen Natriumsalz beim Erhitzen in Wasser unter Ausbildung eines anellierten Pyrazolringes zum 1-Phenyl-3-[L-threo-trihydroxy-propyl]-flavazol kondensiert. Dagegen entsteht unter dem Einfluß von Hydroxylamin-hydrochlorid das 2-Hydroxy-3-[1′-phenyl-5′-hydroxymethyl-pyrazolyl-(3′)]-chinoxalin. Zu der gleichen Verbindung gelangt man auch durch alkalische Verseifung der Diacetylverbindung des Ausgangsstoffes.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1579-1586 
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wird der Nachweis erbracht, daß bei der Dieckmann-Kondensation des Esters IVc vorwiegend der Ketoester I entsteht. Hydrierung und Hydrolyse führt zu 3-Hydroxy-piperidin-carbonsäure-(2). Ozonspaltung und Hydrolyse ergibt Oxalsäure. Eine entsprechende Kondensation, ausgehend vom Ester IXc, ergibt den ungesättigten Piperidonester X.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1587-1593 
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Bei der Anlagerung von Ammoniak an Shikimisäure (I) entstehen vorwiegend zwei stereoisomere Aminosäuren der Konstitution III und IV.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1679-1694 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: o-Substituierte Benzole mit 1. aliphatischer Amino- und aromatischer Mercaptogruppe und 2. aliphatischer Mercapto- und aromatischer Aminogruppe wurden in wäßrig-alkoholischem Medium oxydiert. In der 1. Kategorie resultierten je nach pH Sulfenamid oder Disulfid; im geeigneten Fall trat weitere Dehydrierung zum 1.2-Benzisothiazol-Derivat ein. Es wurde ein pH-abhängiges Gleichgewicht Disulfid ⇌ Sulfenamid + Aminomercaptan festgestellt. In der 2. Kategorie lief die Bildung des Sulfenamids (2.1-Benzisothiazol) und des Disulfids nebeneinander in pH-abhängigen Mengenverhältnissen. Ein übergang Disulfid → Sulfenamid konnte nur unter bestimmten oxydativen Bedingungen erzielt werden. Es wurde an diesem Beispiel gezeigt, daß auch unter günstigen sterischen Verhältnissen die aromatische Aminogruppe nicht in der Lage ist, die aliphatische Disulfid-Gruppe zu spalten.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1710-1711 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 5.5-Diphenyl-glykocyamidin wird durch Methyljodid in 3-Stellung methyliert. Durch Ammonolyse (bzw. Aminolyse) von 1-Methyl-2-methylmercapto-4.4-diphenyl-imidazolon-(5) in Gegenwart von Ammoniumsalzen wurden weitere-3-substituierte Glykocyamidine dargestellt.
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  • 85
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    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 92 (1959) 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 86
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1638-1643 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Durch Umsetzungen von Glucuron- und Galakturonsäure und einigen ihrer Derivate mit Trimethylchlorsilan werden Substanzen erhalten, die i. Vak. gut destillieren und aus denen sich die Ausgangsverbindungen durch Alkoholyse leicht zurückgewinnen lassen. Die Eigenschaften der Trimethylsilylverbindungen werden beschrieben.
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  • 87
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1654-1657 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: (±)-Corypalmin und (±)-Isocorypalmin wurden nach einer vereinfachten Methode zur Darstellung von Tetrahydro-protoberberinen synthetisiert.
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  • 88
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1828-1834 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Carbonsäuren, Carbonsäureester und Kohlensäureester lassen sich durch Umsetzung mit Antimonpentachlorid und Chlorwasserstoff in Acidiumsalze mit Wasserstoff am Oxonium-O-Atom überführen. Diese Acidiumsalze zeigen eine gewisse Chlorwasserstofftension und bilden mit einem zweiten Mol (bzw. bei den Carbonsäuren auch mehreren Molen) der zugehörigen Base H-Brücken-Addukte. Das Dimethyl-carbonatacidium-hexachloroantimonat konnte mittels Diazomethans zum Trimethyl-carbonatacidium-Salz methyliert werden.
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  • 89
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1858-1863 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Durch Umsetzung von Kobalt(II)-acetylacetonat, gelöst in Methylenchlorid oder in fester Form, mit gasförmigem Stickoxyd wird ein tiefblaues, kristallines Nitrosyl-kobalt-bis-acetylacetonat rein dargestellt. Dieses ist in Äthylenbromid und anderen organischen Lösungsmitteln monomer löslich. Auf Grund von Leitfähigkeitsmessungen erweist es sich als Nichtelektrolyt und somit als ein Komplex der Koordinationszahl 5. Die aus dem magnetischen Verhalten und dem IR-Spektrum sich ergebenden Bindungsverhältnisse werden diskutiert.
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  • 90
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1880-1903 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Aus einem Streptomyces-Stamm wurden drei kristallisierte, als ν-, ζ-und ∊-Pyrromycinon bezeichnete Farbstoffe isoliert. ν-Pyrromycinon ist ein 1.4.6-Trihydroxy-carbomethoxy-äthyl-tetracenchinon, ζ- und ∊-Pyrromycinon sind Derivate des 1.4.6-Trihydroxy-7.8.9.10-tetrahydro-tetracenchinons mit einer Carbomethoxygruppe, einer Äthylgruppe und einer bzw. zwei Hydroxygruppen. Durch Dehydrierung bzw. Wasserabspaltung lassen sie sich in ν-Pyrromycinon überführen. Für alle drei Pyrromycinone werden Konstitutionsformeln aufgestellt. Die Pyrromycinone stehen den Rhodomycinonen nahe, mit denen sie über das aus ν-Pyrromycinon dargestellte ν-Iso-pyrromycinon strukturell verknüpft werden konnten.
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  • 91
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1918-1920 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Umsetzung von Formamid mit Methyläthylketon über Aluminiumoxyd führt bei 350-360° zu α-Amino-methyläthylacetonitril, bei 250-260° zu N-[α-Amino-isovaleryl]-N′-[2-imino-5-methyl-3.5-diäthyl-pyrrolidinyl-(3)]-harnstoff.
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  • 92
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1944-1949 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: α-Halogen-ketone setzen sich mit Harnstoff, N-mono- und N.N-disubstituierten Harnstoffen in Dimethylformamid als Lösungsmittel zu 2-Amino-oxazolen um. Auf ihre Umwandlung in 2-Amino-imidazole wird hingewiesen.
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  • 93
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1950-1956 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Aus den drei isomeren Dichloräthylenen kann mit Methyl-lithium in Äther Lithium-chloracetylenid (I) dargestellt werden, während Äthylmagnesiumbromid praktisch unwirksam ist. Die metallorganischen Eigenschaften von I werden zur Synthese organischer Chloracetylen-Derivate ausgenützt.
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  • 94
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1982-1982 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 95
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1999-2013 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die bereits früher durchgeführten Umsetzungen von ortho-metalliertem Halogenbenzol mit tertiären Aminen, wie Triäthylamin, zu phenylierten tertiären Aminen lassen sich mit einem nucleophilen Angriff der Base auf Dehydrobenzol interpretieren. Zwingendere Argumente für ein intermediäres Auftreten von Dehydroaromaten liefert das Verhalten von orthometalliertem α- und β-Halogennaphthalin gegenüber Triäthylamin, da hierbei ein und dasselbe isomerenfreie β-Diäthylamino-naphthalin entsteht. Dafür spricht auch die Dien-Reaktion von Dehydronaphthalin mit Furan zum Endoxyd XII.  -  Orthometalliertes Halogenbenzol vermag auch mit elektrophilen Partnern wie Triäthylbor zu reagieren. Gleichzeitige Einwirkung von Triphenylbor und Triphenylphosphin führt zum Betain XV.
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  • 96
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 2022-2025 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Beim Erhitzen von Calciumhydrid mit Borsäure-trimethylester entsteht ein komplexes Hydrid, das Carbonylverbindungen sehr spezifisch zu den Alkoholen reduziert.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 2029-2032 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Aus l-Acetyl-3.3.5-trimethyl-5-benzyl-cyclohexen-(1)-ol-(2)-dion-(4.6) wird bei Hydrierung in Gegenwart von Palladium der Benzylrest als Toluol hydrogenolytisch glatt abgespalten. Analoga mit Allyl- bzw. γ.γ-Dimethyl-allyl-Gruppen anstelle des Benzylrestes werden normal hydriert zum n-Propyl- bzw. Isoamyl-Derivat.
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  • 98
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 2.4.6-Trisubstituierte Pyryliumsalze lassen sich mit geeigneten Carbanionen in aromatische Verbindungen überführen. In Analogie zu der früher beschriebenen Reaktion mit Metallsalzen des Nitromethans, wobei Derivate des Nitrobenzols entstehen, werden mit Benzyl-lithium Derivate des Biphenyls, mit Acetessigester substituierte Benzoesäureester, mit Acetylaceton substituierte Acetophenone und mit Cyanessigester substituierte aromatische Nitrile erhalten.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 2051-2056 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Darstellung einiger Phosphorsäure-monoarylester-dichloride und Phosphorsäure-diarylester-monochloride und eines Phosphonsäure-dichlorids wird beschrieben, ebenso die Kondensation einiger dieser Chloride mit einigen Phenolen zu polymeren Phosphorsäure-phenolestern.
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  • 100
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Umsetzungen des Eisenpentacarbonyls mit Derivaten der Pyridinreihe, z. B. Pyridin-aldehyd-(2) und koordinativ 2-zähligen Pyridin-aldehyd-(2)-imiden, wie dem Methyl- und Äthylimid, führen zu Octacarbonyldiferraten mit hexakoordiniertem Kation, z. B. [Fe(RN=CH—NC5H4)3][Fe2(CO)8]. Mitunter verläuft die Reaktion über eine tieffarbige Additionsverbindung des betr. Amins mit Pentacarbonyl, die beim Anil als 2 Fe(CO)5·C6H5N=CH—NC5H4 gefaßt wurde. Weiterhin entstehen im letzteren Fall mit Eisentetracarbonyl, wie auch mit Pyridin-aldehyd-(2)-p-tolil, ferner mit o-Phenylendiamin oder Bipyridyl-(2.2′) und Pentacarbonyl Hendecacarbonylrifterrate, während sich mit Isochinolin, Pyrrolidon und Methylpyrrolidon und Pentacarbonyl Tridecacarbonyltetraferrate bilden, z. B. die Verbindungen [Fe(RN=CH—NC5H4)3][Fe3(CO)11] oder [Fe(C4H6ON(CH3))4][Fe4(CO)13].  -  Die für die Carbonylferrate angenommene Struktur mit 2-, 3- und 4-kernigen Anionen wird schließlich durch IR-Absorptionsspektren gestützt. Insgesamt zeigen so die Ergebnisse den spezifischen Einfluß der betr. komplexbildenden Komponente auf den Reaktionstyp.
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