ALBERT

Notes: The abundance and morphology of microdiamond in dolomite marble from Kumdy-kol in the Kokchetav Massif, are unusual; a previous study estimated the maximum content of diamonds in dolomite marble to be about 2700 carat ton−1. Microdiamond is included primarily in garnet, and occasionally in diopside and phlogopite pseudomorphs after garnet. They are classified into three types on the basis of their morphology: (1) S-type: star-shaped diamond consisting of translucent cores and transparent subhedral to euhedral very fine-grained outer parts; (2) R-type: translucent crystals with rugged surfaces; and (3) T-type: transparent, very fine-grained crystals. The S-type is the most abundant.Micro-Laue diffraction using a 1.6-µm X-ray beam-size demonstrated that the cores of the star-shaped microdiamond represent single crystals. In contrast, the most fine-grained outer parts usually have different orientations compared to the core. Laser–Raman studies indicate that the FWHM (Full Width at Half Maximum) of the Raman band of the core of the S-type diamond is slightly larger than that for the outer parts. Differences in morphology, crystal orientations, and in the FWHM of the Raman band between the core and the fine-grained outer-parts of S-type microdiamond suggest that the star-shaped microdiamond was formed discontinuously in two distinct stages.

Notes: Oscillatory zoning in low δ18O skarn garnet from the Willsboro wollastonite deposit, NE Adirondack Mts, NY, USA, preserves a record of the temporal evolution of mixing hydrothermal fluids from different sources. Garnet with oscillatory zoning are large (1–3 cm diameter) euhedral crystals that grew in formerly fluid filled cavities. They contain millimetre-scale oscillatory zoning of varying grossular–andradite composition (XAdr = 0.13–0.36). The δ18O values of the garnet zones vary from 0.80 to 6.26‰ VSMOW and correlate with XAdr. The shape, pattern and number of garnet zones varies from crystal to crystal, as does the magnitude of the correlated chemistry changes, suggesting fluid system variability, temporal and/or spatial, over the time of garnet growth. The zones of correlated Fe content and δ18O indicate that a high Fe3+/Al, high δ18O fluid mixed with a lower Fe3+/Al and δ18O fluid. The high δ18O, Fe enriched fluids were likely magmatic fluids expelled from crystallizing anorthosite. The low δ18O fluids were meteoric in origin.These are the first skarn garnet with oscillatory zoning reported from granulite facies rocks. Geochronologic, stable isotope, petrologic and field evidence indicates that the Adirondacks are a polymetamorphic terrane, where localized contact metamorphism around shallowly intruded anorthosite was followed by a regional granulite facies overprint. The growth of these garnet in equilibrium with meteoric and magmatic fluids indicates an origin in the shallow contact aureole of the anorthosite prior to regional metamorphism. The zoning was preserved due to the slow diffusion of oxygen and cations in the large garnet and protection from deformation and recrystallization in zones of low strain in thick, rigid, garnetite layers. The garnet provide new information about the hydrothermal system adjacent to the shallowly intruded massif anorthosite that predates regional metamorphism in this geologically complex, polymetamorphic terrane.

Notes: The blueschist and greenschist units on the island of Sifnos, Cyclades were affected by Eocene high-pressure (HP) metamorphism. Using conventional geothermobarometry, the HP peak metamorphic stage was determined at 550–600 °C and 20 kbar, close to the blueschist and the eclogite facies transition. The retrograde P–T paths are inferred with phase diagrams. Pseudosections based on a quantitative petrogenetic grid in the model system Na2O–CaO–FeO–MgO–Al2O3–SiO2–H2O reveal coeval decompression and cooling for both the blueschist and the greenschist unit. The conditions of the metamorphic peak and those of the retrograde stages conform to a similar metamorphic gradient of 10–12 °C km−1 for both units. The retrograde overprint can be assigned to low-pressure blueschist to HP greenschist facies conditions. This result cannot be reconciled with the (prograde) Barrovian-type event, which affected parts of the Cyclades during the Oligocene to Miocene. Instead, the retrograde overprint is interpreted in terms of exhumation, directly after the HP stage, without a separate metamorphic event. Constraints on the exhumation mechanism are given by decompression-cooling paths, which can be explained by exhumation in a fore-arc setting during on-going subduction and associated crustal shortening. Back-arc extension is only responsible for the final stage of exhumation of the HP units.

Notes: Metabasic rocks from the Adula Nappe in the Central Alps record a regional high-pressure metamorphic event during the Eocene, and display a regional variation in high-pressure mineral assemblages from barroisite, or glaucophane, bearing garnet amphibolites in the north to kyanite eclogites in the central part of the nappe. High-pressure rocks from all parts of the nappe show the same metamorphic evolution of assemblages consistent with prograde blueschist, high-pressure amphibolite or eclogite facies conditions followed by peak-pressure eclogite facies conditions and decompression to the greenschist or amphibolite facies. Average PT calculations (using thermocalc) quantitatively establish nested, clockwise P–T paths for different parts of the Adula Nappe that are displaced to higher pressure and temperature from north to south. Metamorphic conditions at peak pressure increase from about 17 kbar, 640 °C in the north to 22 kbar, 750 °C in the centre and 25 kbar, 750 °C in the south. The northern and central Adula Nappe behaved as a coherent tectonic unit at peak pressures and during decompression, and thermobarometric results are interpreted in terms of a metamorphic field gradient of 9.6 ± 2.0 °C km−1 and 0.20 ± 0.05 kbar km−1. These results constrain the peak-pressure position and orientation of the nappe to a depth of 55–75 km, dipping at an angle of approximately 45° towards the south. Results from the southern Adula Nappe are not consistent with the metamorphic field gradient determined for the northern and central parts, which suggests that the southern Adula Nappe may have been separated from central and northern parts at peak pressure.

Notes: The Priest pluton contact aureole in the Manzano Mountains, central New Mexico preserves evidence for upper amphibolite contact metamorphism and localized retrograde hydrothermal alteration associated with intrusion of the 1.42 Ga Priest pluton. Quartz–garnet and quartz–sillimanite oxygen isotope fractionations in pelitic schist document an increase in the temperatures of metamorphism from 540 °C, at a distance of 1 km from the pluton, to 690 °C at the contact with the pluton. Comparison of calculated temperature estimates with one-dimensional thermal modelling suggests that background temperatures between 300 and 350 °C existed at the time of intrusion of the Priest pluton. Fibrolite is found within 300 m of the Priest pluton in pelitic and aluminous schist metamorphosed at temperatures 〉580 °C. Coexisting fibrolite and garnet in pelitic schist are in oxygen isotope equilibrium, suggesting these minerals were stable reaction products during peak metamorphism. The fibrolite-in isograd is coincident with the staurolite-out isograd in pelitic schist, and K-feldspar is not observed with the first occurrence of fibrolite. This suggests that the breakdown of staurolite and not the second sillimanite reaction controls fibrolite growth in staurolite-bearing pelitic schist. Muscovite-rich aluminous schist locally preserves the Al2SiO5 polymorph triple-point assemblage – kyanite, andalusite and fibrolite. Andalusite and fibrolite, but not kyanite, are in isotopic equilibrium in the aluminous schist. Co-nucleation of fibrolite and andalusite at 580 °C in the presence of muscovite and absence of K-feldspar suggests that univariant growth of andalusite and fibrolite occurred. Kyanite growth occurred during an earlier regional metamorphic event at a temperature nearly 80 °C lower than andalusite and fibrolite growth. Quartz–muscovite fractionations in hydrothermally altered pelitic schist and quartzite are small or negative, suggesting that late isotopic exchange between externally derived fluids and muscovite, but not quartz, occurred after peak contact metamorphism and that hydrothermal alteration in pelitic schist and quartzite occurred below the closure temperature of oxygen self diffusion in quartz (〈500 °C).

Notes: Abstract Concordant U–Pb ages of c. 530–510 Ma and c. 470–420 Ma on titanite from calcsilicate, orthogneiss and amphibolite rocks constrain the age of high-T metamorphism in the Early Palaeozoic mobile belt at the western margin of Proterozoic Gondwana (Argentina, 26–29°S). The U–Pb ages document the time of titanite formation at high-T conditions according to the stable mineral paragenesis and occurrence of titanite in the metamorphic fabric. The presence of migmatite at all sample sites indicates temperatures were 〉 c. 650 °C. Titanite formed at similar metamorphic conditions at different times on the regional and on the outcrop scale. The titanite crystals preserved their U–Pb isotopic signatures and chemical composition under ongoing upper amphibolite to granulite facies temperatures. Different thermal peaks or deformations are only detected by the different U–Pb ages and not by changes in the mineral paragenesis or metamorphic fabric of the samples. The range of U–Pb ages, e.g. in the Ordovician and Silurian (c. 470, 460, 440, 430, 420 Ma), is interpreted as the effect polyphase deformation with deformation-enhanced recrystallization of titanite and/or different thermal peaks during a long-standing, geographically fixed, high-T regime in the mid-crust of a continental magmatic arc. A clear correlation of the different ages with distinct tectonic events, e.g. collision of terranes, is not possible based on the present knowledge of the region.

Notes: Abstract The garnet blueschists from the Ile de Groix (Armorican Massif, France) contain millimetre- to centimetre-sized pseudomorphs consisting of an aggregate of chlorite, epidote and paragonite. The pseudomorphed phase developed at a late stage of the deformation history, because it overgrows a glaucophane–epidote–titanite foliation. Garnet growth occurred earlier than the beginning of the ductile deformation, and thus garnet is also included in the pseudomorphs. Microprobe analyses show that garnet is strongly zoned, with decreasing spessartine and increasing almandine and pyrope contents from core to rim. Grossular content is higher in garnet cores (about 35 mole%) compared to garnet rims (about 30 mole%). Blue amphibole has glaucophane compositions with a low Fe3+ content and become more magnesian when inclusions in garnet (XMg = 0.62–0.65) are compared with matrix grains (XMg = 0.67–0.70). Matrix epidote has a pistacite content of about 50 mole%. On the basis of their shape and the nature of the breakdown products, the pseudomorphs are attributed to lawsonite. A numerical model (using Thermocalc) has been developed in order to understand the reactions controlling both the growth and the breakdown of lawsonite. Lawsonite growth could have taken place through the continuous hydration reaction Chl + Ep + Pg + Qtz + Vap = Gln + Lws, followed by the fluid-absent reaction Chl + Ep + Pg = Grt + Gln + Lws. Peak P–T conditions are estimated at about 18–20 kbar, 450 °C. This indicates that lawsonite growth took place at increasing P and T, hence can be used as a geobarometer in the buffering assemblage garnet–glaucophane–epidote. The final part of the history is recorded by lawsonite breakdown, after cessation of the ductile deformation, and recording the earliest stages of the exhumation.

Notes: Previous models of hydrodynamics in contact metamorphic aureoles assumed flow of aqueous fluids, whereas CO2 and other species are also common fluid components in contact metamorphic aureoles. We investigated flow of mixed CO2–H2O fluid and kinetically controlled progress of calc-silicate reactions using a two-dimensional, finite-element model constrained by the geological relations in the Notch Peak aureole, Utah. Results show that CO2 strongly affects fluid-flow patterns in contact aureoles. Infiltration of magmatic water into a homogeneous aureole containing CO2–H2O sedimentary fluid facilitates upward, thermally driven flow in the inner aureole and causes downward flow of the relatively dense CO2-poor fluid in the outer aureole. Metamorphic CO2-rich fluid tends to promote upward flow in the inner aureole and the progress of devolatilization reactions causes local fluid expulsion at reacting fronts. We also tracked the temporal evolution of P-T-XCO2conditions of calc-silicate reactions. The progress of low- to medium-grade (phlogopite- to diopside-forming) reactions is mainly driven by heat as the CO2 concentration and fluid pressure and temperature increase simultaneously. In contrast, the progress of the high-grade wollastonite-forming reaction is mainly driven by infiltration of chemically out-of-equilibrium, CO2-poor fluid during late-stage heating and early cooling of the inner aureole and thus it is significantly enhanced when magmatic water is involved. CO2-rich fluid dominates in the inner aureole during early heating, whereas CO2-poor fluid prevails at or after peak temperature is reached. Low-grade metamorphic rocks are predicted to record the presence of CO2-rich fluid, and high-grade rocks reflect the presence of CO2-poor fluid, consistent with geological observations in many calc-silicate aureoles. The distribution of mineral assemblages predicted by our model matches those observed in the Notch Peak aureole.

Notes: The Swakane Gneiss and the overlying Napeequa Complex in the North Cascade range, Washington, were metamorphosed and deformed during development of a Cretaceous-Paleogene continental arc, and are among the structurally deepest exposed rocks within the Cordilleran arcs of North America. Peak metamorphic conditions in both the Swakane Gneiss and Napeequa Complex were c. 640–750 °C, 9–12 kbar. Clockwise paths and widespread evidence for high-P metamorphism in meta-supracrustal rocks (burial to 〉40 km) document major vertical tectonic motion during arc construction and unroofing.These and other moderately high-pressure rocks in the North Cascades-Coast Mountains experienced a dramatically different tectonometamorphic history than metamorphic rocks within other Cordilleran arcs. The exhumed arc complexes of the Sierra Nevada and Peninsular Ranges are dominated by relatively low-P metamorphic and plutonic rocks (typically 〈6 kbar). There is no evidence that the northern Cordillera was thickened to a greater degree than these other belts, suggesting that the greater magnitude of vertical motion in the Cascades may have been related to exhumation mechanisms: Eocene extension in the northern Cordillera vs. erosional unroofing in the central and southern Cordillera.

Notes: High-pressure (HP) granulites and eclogitized metagabbro are exposed along an orogen-parallel high-P belt that was developed at c. 1050–1020 Ma in the NE Grenville Province. Among these rocks, mafic granulites derived from a Labradorian anorthosite suite of the Lelukuau terrane contain garnet, Al-Na diopside, and, depending on bulk composition, plagioclase and kyanite. Moreover, the distribution of phases is influenced by the original igneous texture. For instance, in high XMgO leucocratic varieties, garnet porphyroblasts nucleated together with kyanite in An-rich cores of plagioclase domains whereas in low XMgO rocks garnet occurs together with clinopyroxene within formerly igneous ferromagnesian domains and kyanite is missing. In contrast, garnet pseudomorphs after igneous plagioclase in melanocratic varieties display evidence of earlier corona development. Metamorphic textures are consistent with a two stage evolution: (a) development of garnet and Al-Na-diopside (Cpx1) under high-P metamorphic conditions, concomitant with elimination of plagioclase in the mesocratic to melanocratic varieties; and (b) partial loss of Al-Na from Cpx1 resulting in production of new andesitic plagioclase, and growth of new clinopyroxene (Cpx2) after garnet and quartz in leucocratic to mesocratic rocks consistent with decompression. Widespread equilibrium textures between garnet-Pl2-Cpx2 and/or reset Cpx1 are consistent with development at the thermal peak. Estimated P–T conditions for the presumed thermal peak fall in the range 1500–1800 MPa and 800–900 °C and are comparable to those recorded by eclogitized gabbros from other parts of the high-P belt of the NE Grenville province. Low jadeite content of clinopyroxene from the HP granulites is attributed to the low bulk Na2O/(Na2O + CaO) of these rocks relative to common basaltic compositions. Scarcity of apparent retrograde textural overprint in both the HP granulites and the eclogites suggests fast subsequent cooling, consistent with extrusion of the high-P belt towards the foreland shortly after the metamorphic peak.

Notes: The upper deck of the East Athabasca mylonite triangle (EAmt), northern Saskatchewan, Canada, contains mafic granulites that have undergone high P–T metamorphism at conditions ranging from 1.3 to 1.9 GPa, 890–960 °C. Coronitic textures in these mafic granulites indicate a near-isothermal decompression path to 0.9 GPa, 800 °C. The Godfrey granite occurs to the north adjacent to the upper deck high P–T domain. Well-preserved corona textures in the Godfrey granite constrain igneous crystallization and early metamorphism in the intermediate-pressure granulite field (Opx + Pl) at 1.0 GPa, 775 °C followed by metamorphism in the high pressure granulite field (Grt + Cpx + Pl) at 1.2 GPa, 860 °C. U–Pb geochronology of zircon in upper deck mafic granulite yields evidence for events at both c. 2.5 Ga and c. 1.9 Ga. The oldest zircon dates are interpreted to constrain a minimum age for crystallization or early metamorphism of the protolith. A population of 1.9 Ga zircon in one mafic granulite is interpreted to constrain the timing of high P–T metamorphism. Titanite from the mafic granulites yields dates ranging from 1900 to 1894 Ma, and is interpreted to have grown along the decompression path, but still above its closure temperature, indicating cooling following the high P–T metamorphism from c. 960–650 °C in 4–10 Myr. Zircon dates from the Godfrey granite indicate a minimum crystallization age of 2.61 Ga, without any evidence for 1.9 Ga overgrowths. The data indicate that an early granulite facies event occurred at c. 2.55–2.52 Ga in the lower crust (c. 1.0 GPa), but at 1.9 Ga the upper deck underwent high P–T metamorphism, then decompressed to 0.9–1.0 GPa. Juxtaposition of the upper deck and Godfrey granite would have occurred after or been related to this decompression. In this model, the high P–T rocks are exhumed quickly following the high pressure metamorphism. This type of metamorphism is typically associated with collisional orogenesis, which has important implications for the Snowbird tectonic zone as a fundamental boundary in the Canadian Shield.

Notes: Orthopyroxene-free garnet + clinopyroxene + plagioclase ± quartz-bearing mineral assemblages represent the paragenetic link between plagioclase-free eclogite facies metabasites and orthopyroxene-bearing granulite facies metabasites. Although these assemblages are most commonly developed under P–T conditions consistent with high pressure granulite facies, they sometimes occur at lower grade in the amphibolite facies. Thus, these assemblages are characteristic but not definitive of high pressure granulite facies. Compositional factors favouring their development at amphibolite grade include Fe-rich mineral compositions, Ca-rich garnet and plagioclase, and Ti-poor hornblende. The generalized reaction that accounts for the prograde development of garnet + clinopyroxene + plagioclase ± quartz from a hornblende + plagioclase + quartz-bearing (amphibolite) precursor is Hbl + Pl + Qtz=Grt + Cpx + liquid or vapour, depending on whether the reaction occurs above or below the solidus. There are significant discrepancies between experimental and natural constraints on the P–T conditions of orthopyroxene-free garnet + clinopyroxene + plagioclase ± quartz-bearing mineral assemblages and therefore on the P–T position of this reaction. Semi-quantitative thermodynamic modelling of this reaction is hampered by the lack of a melt model and gives results that are only moderately successful in rationalizing the natural and experimental data.

Notes: Schlieren are trains of platy or blocky minerals, typically the ferromagnesian minerals and accessory phases, that occur in granites and melt-rich migmatites, such as diatexites. They have been considered as: (1) unmelted residue from xenoliths or the source region; (2) mineral accumulations formed during magma flow; (3) compositional layering; and (4) sites of melt loss. In order to help identify schlieren-forming processes in the diatexites at St Malo, differences in the size, shape, orientation, distribution and composition of the biotite from schlieren and from their hosts have been investigated.Small biotite grains are much less abundant in the schlieren than in their hosts. Schlieren biotite grains are generally larger, have greater aspect ratios and have, except in hosts with low (〈 10%) biotite contents, a much stronger shape preferred orientation than host biotite. The compositional ranges of host and schlieren biotite are similar, but schlieren biotite defines tighter, sharper peaks on composition-frequency plots. Hosts show magmatic textures such as imbricated (tiled), unstrained plagioclase. Some schlieren show only magmatic textures (tiled biotite, no crystal-plastic strain features), but many have textures indicating submagmatic and subsolidus deformation (e.g. kinked grains) and these schlieren show the most extensive evidence for recrystallization.Magmas at St Malo initially contained a significant fraction of residual biotite and plagioclase crystals; smaller biotite grains were separated from the larger plagioclase crystals during magma flow. Since plagioclase was also the major, early crystallizing phase, the plagioclase-rich domains developed rapidly and reached the rigid percolation threshold first, forcing further magma flow to be concentrated into narrowing melt-rich zones where the biotite had accumulated, hence increasing shear strain and the degree of shape preferred orientation in these domains. Schlieren formed in these domains as a result of grain contacts and tiling in the grain inertia-regime. Final amalgamation of the biotite aggregates into schlieren involved volume loss as melt trapped between grains was expelled after the rigid percolation threshold was reached in the biotite-rich layers.

Notes: The eclogite type locality in the Eastern Alps (the Koralpe and Saualpe region) is the largest region in the Eastern Alps that preserves high-pressure metamorphic rocks from the Eo-Alpine orogenic event of the Cretaceous age. Thermobarometric data from the metapelitic gneisses in the region indicate that a metamorphic field gradient across the region can be divided into three parts. The northern part shows continuously increasing P–T from 10 ± 1.5 to 14 ± 1.5 kbar and 500 ± 68 to 700 ± 68 °C over a distance of 40 km. The continuous increase in P–T indicates that no major tectonic boundaries were active in this part during the Eo-Alpine orogeny. Small discontinuities in the pressure gradient of the northern part can be correlated with more localized deformation. The central part exposes amphibolite–eclogite facies rocks with 15 ± 1.5 kbar and 700 ± 68 °C over about 20 km length. The southern part shows decreasing P–T conditions from 15 ± 1.5 to 10 ± 1.5 kbar and 700 ± 68 to 600 ± 63 °C over a distance of 10 km beyond which conditions remain roughly constant for the remainder of the profile.Overall, the field gradient is characterized by: (i) an increase in age with decreasing metamorphic grade and (ii) a T/P ratio that is lower than common metamorphic geotherms. The age–grade relationship is consistent with the timing relationship along piezothermal arrays predicted by simple models for regional metamorphism. However, the T/P ratio of the field gradient is inconsistent with such an interpretation. These inconsistencies indicate that the profile is not simply an obliquely exposed crustal section. We suggest that the exhumation of the transect is best explained with a two dimensional model of an extruding wedge, as has recently been suggested as a typical scenario for other large scale compressional orogens.

Notes: A largely undocumented region of eclogite associated with a thick blueschist unit occurs in the Kotsu area of the Sanbagawa belt. The composition of coexisting garnet and omphacite suggests that the Kotsu eclogite formed at peak temperatures of around 600 °C synchronous with a penetrative deformation (D1). There are local significant differences in oxygen fugacity of the eclogite reflected in mineral chemistries. The peak pressure is constrained to lie between 14 and 25 kbar by microstructural evidence for the stability of paragonite throughout the history recorded by the eclogite, and the composition of omphacite in associated eclogite facies pelitic schist. Application of garnet-phengite-omphacite geobarometry gives metamorphic pressures around 20 kbar. Retrograde metamorphism associated with penetrative deformation (D2) is in the greenschist facies. The composition of syn-D2 amphibole in hematite-bearing basic schist and the nature of the calcium carbonate phase suggest that the retrograde P–T path was not associated with a significant increase or decrease in the ratio of P–T conditions following the peak of metamorphism. This P–T path contrasts with the open clockwise path derived from eclogite of the Besshi area. The development of distinct P–T paths in different parts of the Sanbagawa belt shows the shape of the P–T path is not primarily controlled by tectonic setting, but by internal factors such as geometry of metamorphic units and exhumation rates.

Notes: Previous studies suggest that the metamorphic evolution of the ultrahigh-pressure garnet peridotite from Alpe Arami was characterized by rapid subduction to a depth of c. 180 km with partial chemical equilibration at c. 5.9 Gpa/1180 °C and an initial stage of near-isothermal decompression followed by enhanced cooling. In this study, average cooling rates were constrained by diffusion modelling on retrograde Fe–Mg zonation profiles across garnet porphyroclasts. Considering the effects of temperature, pressure and garnet bulk composition on the Fe–Mg interdiffusion coefficient, cooling rates of 380–1600 °C Myr−1 for the interval from 1180 to 800 °C were obtained. Similar or even higher average cooling rates resulted from thermal modelling, whereby the characteristics of the calculated temperature-time path depend on the shape and size of the hot peridotite body and the boundary conditions of the cooling process. The very high cooling rates obtained from both geospeedometry and thermal modelling imply extremely fast exhumation rates of c. 15 mm yr−1 or more. These results agree with the range of exhumation rates (16–50 mm yr−1) deduced from geochronological results. It is suggested that the Alpe Arami peridotite passively returned towards the surface as part of a buoyant sliver, caused as a consequence of slab breakoff.

Notes: We report SHRIMP U–Th–Pb monazite, conventional U–Pb titanite, Sm–Nd garnet and Rb–Sr muscovite and biotite ages for metamorphic rocks from the Danba Domal Metamorphic Terrane in the eastern Songpan-Garzê Orogenic Belt (eastern Tibet Plateau). These ages are used to determine the timing of polyphase metamorphic events and the subsequent cooling history. The oldest U–Th–Pb monazite and Sm–Nd garnet ages constrain an early Barrovian metamorphism (M1) in the interval c. 204–190 Ma, coincident with extensive Indosinian granitic magmatism throughout the Songpan-Garzê Orogenic Belt. A second, higher-grade sillimanite-grade metamorphic event (M2), recorded only in the northern part of the Danba terrane, was dated at c. 168–158 Ma by a combination of U–Th–Pb monazite and titanite and Sm–Nd garnet ages. It is suggested that M1 was a thermal event that affected the entire orogenic belt while M2 may represent a local thermal perturbation. Rb–Sr muscovite ages range from c. 138–100 Ma, whereas Rb–Sr biotite ages cluster at c. 34–24 Ma. These ages document regional cooling at rates of c. 2–3 °C Myr−1 following the M1 peak for most of the terrane. However, those parts of the terrane affected by the higher-temperature M2 event (e.g. the migmatite zone) experienced initially more rapid (c. 8 °C Myr−1) cooling after peak M2 before joining the regional slow cooling path defined by the rest of the terrane at c. 138 Ma. Regional slow cooling between c. 138 and c. 30 Ma is thought to be the result of post-tectonic isostatic uplift after extensive crustal thickening caused by collision of the South and North China Blocks. The clustering of biotite Rb–Sr ages marks the onset of rapid uplift across the entire terrane commencing at c. 30–20 Ma. This cooling history is shared with many other regions of the Tibet Plateau, suggesting that uplift of the Tibet Plateau (including the Songpan-Garzê Orogenic Belt) occurred predominantly in the last c. 30 Myr as a response to the continuing northwards collision of India with Eurasia.

Notes: Recent studies have used the relative rotation axis of sigmoidal and spiral-shaped inclusion trails, known as Foliation Inflexion/Intersection Axis (FIA), to investigate geological processes such as fold mechanisms and porphyroblast growth. The geological usefulness of this method depends upon the accurate measurement of FIA orientations and correct correlation of temporally related FIAs. This paper uses new data from the Canton Schist to assess the variation in FIA orientations within and between samples, and evaluates criteria for correlating FIAs. For the first time, an entire data set of FIA measurements is published, and data are presented in a way that reflects the variation in FIA orientations within individual samples and provides an indication of the reliability of the data. Analysis of 61 FIA trends determined from the Canton Schist indicate a minimum intrasample range in FIA orientations of 30°. Three competing models are presented for correlation of these FIAs, and each of the models employ different correlation criteria. Correlation of FIAs in Model 1 is based on relative timing and textural criteria, while Model 2 uses relative timing, orientation and patterns of changing FIA orientations, and Model 3 uses relative timing and FIA orientation as correlation criteria. Importantly, the three models differ in the spread of FIA orientations within individual sets, and the number of sets distinguished in the data. Relative timing is the most reliable criterion for correlation, followed by textural criteria and patterns of changing FIA orientations from core to rim of porphyroblasts. It is proposed that within a set of temporally related FIAs, the typical spread of orientations involves clustering of data in a 60° range, but outliers occur at other orientations including near-normal to the peak distribution. Consequently, in populations of FIA data that contain a wide range of orientations, correlation on the basis of orientation is unreliable in the absence of additional criteria. The results of this study suggest that FIAs are best used as semiquantitative indicators of bulk trends rather than an exact measurement for the purpose of quantitative analyses.

Notes: Documentation of pressure–temperature (P–T) histories across an epidote-amphibolite facies culmination provides new insight into the tectono-thermal evolution of the Brooks Range collisional orogen. Thermobarometry reveals that the highest grade rocks formed at peak temperatures of 560–600 °C and at pressures of 8–9.5 kbar. The thermal culmination coincides with the apex of a structural dome defined by oppositely dipping S2 crenulation cleavages suggesting post-metamorphic doming. South of the thermal culmination, greenschist facies and lowermost epidote-amphibolite facies rocks preserve widespread evidence for an early blueschist facies metamorphism. In contrast, no evidence for an early blueschist facies metamorphism was found in similar grade rocks of the northern flank, indicating that the southern flank underwent initial deeper burial during southward underthrusting of the continental margin. Thus, while the dome shows a symmetric distribution of peak temperatures, the P–T paths followed by the two flanks must have varied. This variation suggests that final thermal re-equilibration to greenschist and epidote–amphibolite facies conditions did not result from a simple process of southward underthrusting followed by thermal re-equilibration from the bottom upward. The new data are inconsistent with a previous model that invokes such re-equilibration, along with northward thrusting of epidote–amphibolite facies rocks over lower grade rocks presently on the southern flank of the culmination, to produce an inverted metamorphic field gradient. Instead, it is suggested that following blueschist facies metamorphism, rocks of the southern and northern flanks were juxtaposed, during which time the more deeply buried south flank was partially emplaced above rocks to the north, where they escaped Albian epidote–amphibolite facies overprinting. Porphyroblast growth, which post-dates the main fabric on the north flank of the culmination may be the result of Albian thermal re-equilibration following this deformation. Post-metamorphic doming resulted from a combination of Albian-Cenomanian extension and Tertiary deformation.

Notes: Spiral inclusion trails in garnet porphyroblasts are likely to have formed due to simultaneous growth and rotation of the crystals, during syn-metamorphic deformation. Thus, they contain information on the strain rate of the rock. Strain rates may be interpreted from such inclusion trails if two functions are known: (1) The relationship between rotation rate and shear strain rate; (2) the growth rate of the crystal. We have investigated details of both functions using a garnetiferous mica schist from the eastern European Alps as an example. The rotation rate of garnet porphyroblasts was determined using finite element modelling of the geometrical arrangement of the crystals in the rock. The growth rate of the porphyroblasts was determined by using the major and trace element distributions in garnet crystals, thermodynamic pseudosections and information on the grain size distribution. For the largest porphyroblast size fraction (size L=12 mm) we constrain a growth interval between 540 and 590 °C during the prograde evolution of the rock. Assuming a reasonable heating rate and using the angular geometry of the spiral inclusion trails we are able to suggest that the mean strain rate during crystal growth was of the order of 〈inlineGraphic alt="inline image" href="urn:x-wiley:02634929:JMG441:JMG_441_mu1" location="equation/JMG_441_mu1.gif"/〉=6.6 × 10−14 s−1. These estimates are consistent with independent estimates for the strain rates during the evolution of this part of the Alpine orogen.

Notes: Mineral textures in metapelitic granulites from the northern Prince Charles Mountains, coupled with thermodynamic modelling in the K2O–FeO–MgO–Al2O3–SiO2–H2O–TiO2–Fe2O3 (KFMASHTO) model system, point to pressure increasing with increasing temperature on the prograde metamorphic path, followed by retrograde cooling (i.e. an anticlockwise P–T path). Textural evidence for the increasing temperature part of the path is given by the breakdown of garnet and biotite to form orthopyroxene and cordierite in sillimanite-absent rocks, and through the break-down of biotite and sillimanite to form spinel, cordierite and garnet in more aluminous assemblages. This is equated to the advective addition of heat from the regional emplacement of granitic and charnockitic magmas dated at c. 980 Ma. A subsequent increase in pressure, inferred from the break-down of spinel and quartz to sillimanite, cordierite and garnet in aluminous rocks, is attributed to crustal thickening related to upright folding dated at 940–910 Ma. The terrane attained peak metamorphic temperatures of c. 880 °C at pressures of c. 6.0–6.5 kbar during this event. Subsequent cooling is inferred from the localised breakdown of cordierite and garnet to form biotite and sillimanite that developed in the latter stages of the same event. The textural observations described are interpreted via the application of P–T and P–T–X pseudosections. The latter show that most rock compositions preserve only fragments of the overall P–T path; a result of different rock compositions undergoing mineral assemblage changes, or changes in mineral modal abundance, on different sections of the P–T path. The results also suggest that partial melting during granulite facies metamorphism, coupled with melt loss and dehydration, initiated a switch from pervasive ductile, to discrete ductile/brittle deformation, during retrograde cooling.

Notes: Fluid flow at greenschist facies conditions during exhumation of the western Alps occurred in several penecontemporaneous systems, including shear zones at lithological contacts, deformed contacts between serpentinite bodies and metabasalts, albite veins within metabasalts, and calcite + quartz veins within calcareous schists. Fluid flow in shear zones that juxtapose metasediments and ophiolitic rocks within the Piemonte Unit reset O and H isotope ratios. δ18O values are buffered by the wall rocks; however, calculated fluid δ2H values are similar within all the shear zones suggesting that they formed an interconnected network. The similarity of δ2H values of the sheared rocks and those of unsheared calcareous schists suggests that the fluids were derived from, or had equilibrated with, the schists that envelop the ophiolite rocks. Time-integrated fluid fluxes at the sheared contacts estimated from changes in Si in metabasalts were up to 105 m3 m−2, with the fluid flowing up temperature driven either by topography or seismic pumping. Individual shear zones were active for c. 2–3 Myr, implying average fluid fluxes of up to 10−9 m3 m−2 s−1. Rocks in shear zones within the ophiolite away from contacts with the metasediments show much less marked isotopic and geochemical changes, implying that fluid volumes decreased into the ophiolite unit, consistent with the source of fluids being the metasediments. Fluids were generated by dehydration reactions that were intersected during exhumation and, while many rocks show the affects of fluid–rock interaction, large-scale fluid flow between major units was not common.

Notes: Eclogites from the south Tianshan, NW China are grouped into two types: glaucophane and hornblende eclogites, composed, respectively, of garnet + omphacite + glaucophane + paragonite + epidote + quartz and garnet + omphacite + hornblende (sensu lato) + paragonite + epidote + quartz, plus accessory rutile and ilmenite. These eclogites are diverse both in mineral composition and texture not only between the two types but also among the different selected samples within the glaucophane eclogite. Using thermocalc 3.1 and recent models of activity–composition relation for minerals, a P–T projection and a series of P–T pseudosections for specific samples of eclogite have been calculated in the system Na2O–CaO–FeO–MgO–Al2O3–SiO2–H2O (NCFMASH) with quartz and water taken to be in excess. On the basis of these phase diagrams, the phase relations and P–T conditions are well delineated. The three selected samples of glaucophane eclogite AK05, AK11 and AK17 are estimated to have peak P–T conditions, respectively, of 540–550 °C at c. 16 kbar, c. 560 °C at 15–17 kbar and c. 580 °C at 15–19 kbar, and two samples of hornblende eclogite AK10 and AK30 of 610–630 °C and 17–18 kbar. Together with H2O-content contours in the related P–T pseudosections and textural relations, both types of eclogite are inferred to show clockwise P–T paths, with the hornblende eclogite being transformed from the glaucophane eclogite assemblage dominantly through increasing temperature.

Notes: This study uses field, petrographic and geochemical methods to estimate how much granitic melt was formed and extracted from a granulite facies terrane, and to determine what the grain- and outcrop-scale melt-flow paths were during the melt segregation process. The Ashuanipi subprovince, located in the north-eastern Superior Province of Quebec, is a large (90 000 km2) metasedimentary terrane, in which 〉 85% of the metasediments are of metagreywacke composition, that was metamorphosed at mid-crustal conditions (820–900 °C and 6–7 kbar) in a late Archean dextral, transpressive orogen. Decrease in modal biotite and quartz as orthopyroxene and plagioclase contents increase, together with preserved former melt textures indicate that anatexis was by the biotite dehydration reaction: biotite + quartz + plagioclase = melt + orthopyroxene + oxides. Using melt/orthopyroxene ratios for this reaction derived from experimental studies, the modal orthopyroxene contents indicate that the metagreywacke rocks underwent an average of 31 vol% partial melting.The metagreywackes are enriched in MgO, CaO and FeOt and depleted in SiO2, K2O, Rb, Cs, and U, have lower Rb/Sr, higher Rb/Cs and Th/U ratios and positive Eu anomalies compared to their likely protolith. These compositions are modelled by the extraction of between 20 and 40 wt %, granitic melt from typical Archean low-grade metagreywackes. A simple mass balance indicates that about 640 000 km3 of granitic melt was extracted from the depleted granulites.The distribution of relict melt at thin section- and outcrop-scales indicates that in layers without leucosomes melt extraction occurred by a pervasive grain boundary (porous) flow from the site of melting, across the layers and into bedding planes between adjacent layers. In other rocks pervasive grain boundary flow of melt occurred along the layers for a few, to tens of centimetres followed by channelled flow of melt in a network of short interconnected and structurally controlled conduits, visible as the net-like array of leucosomes in some outcrops. The leucosomes contain very little residual material (〈 5% biotite + orthopyroxene) indicating that the melt fraction was well separated from the residuum left in situ as melt-depleted granulite. Only 1–3 vol percentage melt remained in the melt-depleted granulites, hence, the extraction of melt generated by biotite dehydration melting in these granulites, was virtually complete under conditions of natural melting and strain rates in a contractional orogen.

Notes: Zircon from a lower crustal metapelitic granulite (Val Malenco, N-Italy) display inherited cores, and three metamorphic overgrowths with ages of 281 ± 2, 269 ± 3 and 258 ± 4 Ma. Using mineral inclusions in zircon and garnet and their rare earth element characteristics it is possible to relate the ages to distinct stages of granulite facies metamorphism. The first zircon overgrowth formed during prograde fluid-absent partial melting of muscovite and biotite apparently caused by the intrusion of a Permian gabbro complex. The second metamorphic zircon grew after formation of peak garnet, during cooling from 850 °C to c. 700 °C. It crystallized from partial melts that were depleted in heavy rare earth elements because of previous, extensive garnet crystallization. A second stage of partial melting is documented in new growth of garnet and produced the third metamorphic zircon. The ages obtained indicate that the granulite facies metamorphism lasted for about 20 Myr and was related to two phases of partial melting producing strongly restitic metapelites.Monazite records three metamorphic stages at 279 ± 5, 270 ± 5 and 257 ± 4 Ma, indicating that formation ages can be obtained in monazite that underwent even granulite facies conditions. However, monazite displays less clear relationships between growth zones and mineral inclusions than zircon, hampering the correlation of age to metamorphism. To overcome this problem garnet–monazite trace element partitioning was determined for the first time, which can be used in future studies to relate monazite formation to garnet growth.

Notes: A suite of spinel–cordierite granulites from Viziangram, Eastern Ghats Belt, India preserve mineral assemblages and reaction textures indicative of peak metamorphic conditions of 〉1000 °C, 〉8〈10 kbar, followed successively by near isobaric cooling (down to 750–800 °C), near isothermal decompression (to 4–5 kbar), and late hydration. P–T conditions of each stage are evaluated through a combination of petrogenetic grid approach and thermobarometry. Sapphirine is developed in sillimanite-bearing acid pegmatite veins that intruded the spinel–cordierite granulite close to peak metamorphic conditions, and also in the host rock in immediate contact with the pegmatite. Both sillimanite and sapphirine in the pegmatite are considered to be magmatic phases. Field observations and textural characteristics suggest that Al-metasomatism of the spinel–cordierite granulite due to the intrusion of pegmatite was responsible for sapphirine formation in the spinel granulite.

Notes: Whereas geologists have known for three-quarters of a century that there was significant crustal thickening in the central East Greenland Caledonides, the crucial role of extensional faulting during Caledonian orogenesis has only been recognized during the past decade. In this paper, new petrographic and thermobarometric observations are presented from migmatitic metasedimentary gneisses of the Forsblad Fjord region (c. 72.5°N). Samples of the Krummedal Sequence, collected from the footwall of the upper of two significant splays of the main extensional fault system in the region—the Fjord Region Detachment (FRD)—enable us to establish a relative sequence of metamorphism. Our pressure (P)–temperature (T) results imply a clockwise loop in P–T space. As recorded by mineral assemblages in the Krummedal gneisses, prograde metamorphism involved a net increase of c. 4 kbar and 250 °C, with peak conditions of c. 10.5 kbar at 785 °C. Early burial and heating was followed by near-isothermal decompression of 4.5 kbar, a process which is attributed to roughly 18 km of tectonostratigraphic throw on the upper splay of the FRD. Combining data reported here with the published data, it is estimated that the approximate tectonostratigraphic throw along the lower splay of the FRD was c. 16 km. In situ U–Th–Pb-monazite electron microprobe dating suggests that the earliest phase of metamorphism recorded in the Krummedal Sequence gneisses of Forsblad Fjord occurred during the Caledonian orogeny. Furthermore, the combination of our new data with existing conventional TIMS U-Pb and 40Ar/39Ar data imply that: (1) movement along the uppermost splay of the FRD (c. 425–423 Ma) occurred at maximum time-averaged slip-rates equivalent to c. 9 mm of vertical displacement per year; and (2) that the final stages of metamorphism occurred prior to c. 411 Ma, although part of this denudation was likely accommodated on overlying extensional structures that may have been active more recently. There is close agreement between our data and results from the Krummedal Sequence north of the field area (72.5°−74°N), and rocks of the Smallefjord Sequence (75°−76°N) that are suggested to correlate with the Krummedal Sequence. This leads us to infer that the events recorded in the Forsblad Fjord region are of orogen-scale significance.

Notes: New data on the metamorphic petrology and zircon geochronology of high-grade rocks in the central Mozambique Belt (MB) of Tanzania show that this part of the orogen consists of Archean and Palaeoproterozoic material that was structurally reworked during the Pan-African event. The metamorphic rocks are characterized by a clockwise P–T path, followed by strong decompression, and the time of peak granulite facies metamorphism is similar to other granulite terranes in Tanzania. The predominant rock types are mafic to intermediate granulites, migmatites, granitoid orthogneisses and kyanite/sillimanite-bearing metapelites. The meta-granitoid rocks are of calc-alkaline composition, range in age from late Archean to Neoproterozoic, and their protoliths were probably derived from magmatic arcs during collisional processes. Mafic to intermediate granulites consist of the mineral assemblage garnet–clinopyroxene–plagioclase–quartz–biotite–amphibole ± K-feldspar ± orthopyroxene ± oxides. Metapelites are composed of garnet-biotite-plagioclase ± K-feldspar ± kyanite/sillimanite ± oxides. Estimated values for peak granulite facies metamorphism are 12–13 kbar and 750–800 °C. Pressures of 5–8 kbar and temperatures of 550–700 °C characterize subsequent retrogression to amphibolite facies conditions. Evidence for a clockwise P–T path is provided by late growth of sillimanite after kyanite in metapelites. Zircon ages indicate that most of the central part of the MB in Tanzania consists of reworked ancient crust as shown by Archean (c. 2970–2500 Ma) and Palaeoproterozoic (c. 2124–1837 Ma) protolith ages. Metamorphic zircon from metapelites and granitoid orthogneisses yielded ages of c. 640 Ma which are considered to date peak regional granulite facies metamorphism during the Pan-African orogenic event. However, the available zircon ages for the entire MB in East Africa and Madagascar also document that peak metamorphic conditions were reached at different times in different places. Large parts of the MB in central Tanzania consist of Archean and Palaeoproterozoic material that was reworked during the Pan-African event and that may have been part of the Tanzania Craton and Usagaran domain farther to the west.

Notes: Abstract An analytical electron microscope study of almandine garnet from a metamorphosed Al–Fe-rich rock revealed detailed composition profiles and defect microstructures of resorption zoning along fluid-infiltrated veins and even into the garnet/ilmenite (inclusion) interface. This indicates a limited volume diffusion for the cations in substitution (mainly Ca and Fe) and an interface-controlled partition for the extension of a composition-invariant margin. A corrugated interface between the Ca-rich margin/zone and the almandine garnet core is characterized by dislocation arrays and recovery texture further suggesting a resorption process facilitated by diffusion-induced recrystallization, diffusion-induced dislocation migration and diffusion–induced grain boundary migration. Integrated microstructural and chemical studies are essential for understanding the underlying mechanisms of processes such as garnet zoning and its modification. Without this understanding, it will not be possible to reliably use garnet compositions for thermobarometry and other applications that rely on garnet chemical information.

Notes: Abstract Granulite facies metapelites of the Mather and Filla Paragneisses within the Rauer Group, east Antarctica, possess markedly different compositions. The metamorphic evolution of the two metapelite types has been interpreted as temporally distinct, with the Rauer Group preserving at least two distinct granulite facies tectonothermal episodes. Calculated P–T pseudosections and orthopyroxene Al content indicate the revised maximum-preserved P–T conditions within the Mather Paragneiss to lie in the vicinity of 950–975 °C and 10–10.6 kbar, less extreme than previous estimates. The range of possible P–T paths for the Mather Paragneiss consistent with mineral textural relationships and pseudosections contoured for mineral proportion are significantly shallower (dP/dT) than previous estimates. A near-isothermal decompression P–T path, and extreme peak metamorphic conditions, are not necessary to explain the development of preserved mineral reaction textures. The Filla Paragneiss contains pelitic assemblages less amenable to rigorous quantitative analysis. Nevertheless, possibilities for the shared or otherwise metamorphic evolution of the Mather and Filla Paragneisses may be postulated on the basis of calculated pseudosections in the context of existing geochronology for the Rauer Group and preserved microstructures. A shared evolution, most likely during Pan-African granulite facies metamorphism, is plausible and consistent with mineral assemblage development, geochronology and microstructures. A revised interpretation of the Rauer Group's preserved metamorphic evolution may warrant the revision of existing tectonic models, applicable also to the remainder of Prydz Bay. More generally, the employed approach may incite a revision of peak P–T and P–T paths in other granulite facies terranes.

Notes: The solid-state reaction magnesite (MgCO3) + calcite (aragonite) (CaCO3) = dolomite (CaMg(CO3)2) has been identified in metapelites from western Tianshan, China. Petrological studies show that two metamorphic stages are recorded in the metapelites: (1) the peak mineral assemblage of magnesite and calcite pseudomorphs after aragonite which is only preserved as inclusions within dolomite; and (2) the retrograde glaucophane-chloritoid facies mineral assemblage of glaucophane, chloritoid, dolomite, garnet, paragonite, chlorite and quartz. The peak metamorphic temperatures and pressures are calculated to be 560–600 °C, 4.95–5.07 GPa based on the calcite–dolomite geothermometer and the equilibrium calculation of the reaction dolomite = magnesite + aragonite, respectively. These give direct evidence in UHP metamorphic rocks from Tianshan, China, that carbonate sediments were subducted to greater than 150 km depth. This UHP metamorphism represents a geotherm lower than any previously estimated for subduction metamorphism (〈 3.7 °C km−1) and is within what was previously considered a ‘forbidden’ condition within Earth. In terms of the carbon cycle, this demonstrates that carbonate sediments can be subducted to at least 150 km depth without releasing significant CO2 to the overlying mantle wedge.

Notes: Field data define two lithologically distinct basement-cover sequences within the ultrahigh-pressure metamorphic (UHPM) unit of the Dabie Shan, eastern China. One of the cover units, the Changpu unit, comprises calc-arenitic metasediments in stratigraphic contact with a basement consisting of gneisses of the Yangtze craton. The second cover unit, the Ganghe unit, consists of felsic-intermediate metavolcanics and clastic metasediments. Basement exposure of the Ganghe unit is not known. Fold axes in the Ganghe unit are oblique to those of the Changpu unit, which are parallel to those of the Yangtze gneisses. Preservation of primary textures in some volcanic rocks, and tectonic separation from the Yangtze gneisses by a greenschist facies mylonite, support an interpretation of the Ganghe unit as a low-strain domain. Protolith associations in the Ganghe and Changpu units are compatible with deposition in a rift setting and along a passive continental margin, respectively. A U–Pb single zircon age of 761 ± 33 Ma for volcanoclastic rocks of the Ganghe unit demonstrates a Neoproterozoic deposition age, concordant with inferred rifting at that time. Eclogite facies parageneses in the gneisses and both cover units, along with P–T data demonstrate regional UHPM in the Dabie Shan.

Notes: The Xugou garnet peridotite body of the southern Sulu ultrahigh-pressure (UHP) terrane is enclosed in felsic gneiss, bounded by faults, and consists of harzburgite and lenses of garnet clinopyroxenite and eclogite. The peridotite is composed of variable amounts of olivine (Fo91), enstatite (En92−93), garnet (Alm20−23Prp53−58Knr6−9Grs12−18), diopside and rare chromite. The ultramafic protolith has a depleted residual mantle composition, indicated by a high-Mg number, very low CaO, Al2O3 and total REE contents compared to primary mantle and other Sulu peridotites. Most garnet (Prp44−58) clinopyroxenites are foliated. Except for rare kyanite-bearing eclogitic bands, most eclogites contain a simple assemblage of garnet (Alm29−34Prp32−50Grs15−39) + omphacite (Jd24−36) + minor rutile. Clinopyroxenite and eclogite exhibit LREE-depleted and LREE-enriched patterns, respectively, but both have flat HREE patterns. Normalized La, Sm and Yb contents indicate that both eclogite and garnet clinopyroxenite formed by high-pressure crystal accumulation (+ variable trapped melt) from melts resulting from two-stage partial melting of a mantle source.Recrystallized textures and P–T estimates of 780–870 °C, 5–7 GPa and a metamorphic age of 231 ± 11 Ma indicate that both mafic and ultramafic protoliths experienced Triassic UHP metamorphism in the P–T forbidden zone with an extremely low thermal gradient (〈 5 °C km−1), and multistage retrograde recrystallization during exhumation. Develop of prehnite veins in clinopyroxenite, eclogite, felsic blocks and country rock gneiss, and replacements of eclogitic minerals by prehnite, albite, white mica, and K-feldspar indicate low-temperature metasomatism.

Notes: This paper provides further evidence for the ongoing discussion as to whether the Dabie UHPM belt formed in Triassic or Palaeozoic time, and whether the Sulu UHPM belt formed in Triassic or Neoproterozoic time. Combined use of laser Raman spectrometer (LR), cathodoluminescence imaging (CL), and ion probe U–Pb in-situ dating (SHRIMP) provided accurate ages of UHPM from rocks collected from Weihai, NE Sulu UHPM belt. LR was used to identify coesite and other UHP minerals as inclusions in zircon separates from an amphibolized peridotite and an eclogite. CL was used to examine the zoning structure of these zircon, and SHRIMP dating was performed on specific spots on zircon to obtain ages of different geological events. An age of 221 ± 12 Ma was obtained for coesite-bearing zircon from the amphibolized peridotite; an age of 228 ± 29 Ma for eclogite was obtained from the lower intercept of a concordia plot. These ages are interpreted as the time of UHPM in the Weihai region. Ultramafic rocks to the east of Weihai yield a magmatic age at 581 ± 44 Ma. The zircon in the ultramafic rocks possibly also records a thermal event at c. 400 Ma, but no independent geological evidence for this event has been found. The eclogite protolith formed in the Middle Proterozoic (1821 ± 19 Ma), which is similar to the age of country rock gneisses of 1847–1744 Ma. The new geochronological data confirm that UHPM occurred in the Triassic in the Sulu area when subduction took the ultramafic body and the eclogite protolith, together with the adjacent supracrustal rocks, to mantle depths.

Notes: Oxygen isotopic compositions of silicates in eclogites and whiteschists from the Kokchetav massif were analyzed by whole-grain CO2-laser fluorination methods. Systematic analyses yield extremely low δ18O for eclogites, as low as −3.9‰ for garnet; these values are comparable with those reported for the Dabie-Sulu UHP eclogites. Oxygen isotopic compositions are heterogeneous in samples of eclogite, even on an outcrop scale. Schists have rather uniform oxygen isotope values compared to eclogites, and low δ18O is not observed. Isotope thermometry indicates that both eclogites and schists achieved high-temperature isotopic equilibration at 500–800 °C. This implies that retrograde metamorphic recrystallization barely modified the peak-metamorphic oxygen isotopic signatures. A possible geological environment to account for the low-δ18O basaltic protolith is a continental rift, most likely subjected to the conditions of a cold climate. After the basalt interacted with low δ18O meteoric water, it was tectonically inserted into the surrounding sedimentary units prior to, or during subduction and UHP metamorphism.

Notes: A combined oxygen-isotope and fluid-inclusion study has been carried out on high- and ultrahigh-pressure metamorphic (HP/UHPM) eclogites and garnet clinopyroxenite from the Dabie-Sulu terranes in eastern China. Coesite-bearing eclogites/garnet clinopyroxenite and quartz eclogites have a wide range in whole-rock δ18OVSMOW, from 0 to 11‰. The high-T oxygen-isotope fractionations preserved between quartz and garnet preclude significant retrograde isotope exchange during exhumation, and the wide range in whole-rock oxygen-isotope composition is thought to be a presubduction signature of the precursors. Aqueous fluids with variable salinities and gas species (N2-, CO2-, or CH4-rich), are trapped as primary inclusions in garnet, omphacite and epidote, and in quartz blebs enclosed within eclogitic minerals. In high-δ18O HP/UHPM rocks from Hujialin and Shima, high-salinity brine and/or N2 inclusions occur in garnet porphyroblasts, which also contain inclusions of coesite, Cl-rich blue amphibole and dolomite. In contrast, in low-δ18O eclogites from Qinglongshan and Huangzhen, the Cl concentrations in amphibole are very low, 〈 0.2 wt.%, and low-salinity aqueous inclusions occur in quartz inclusions in epidote porphyroblasts and in epidote cores. These low-salinity fluid inclusions are believed to be remnants of meteoric water, although the fluid composition was modified during pre- and syn-peak HP/UHPM. Eclogites at Houshuichegou and Hetang contain CH4-rich fluid inclusions, coexisting with high-salinity brine inclusions. Methane was probably formed under the influence of CO2-rich aqueous fluids during serpentinisation of mantle-derived peridotites prior to or during plate subduction. Remnants of premetamorphic low- to high-salinity aqueous fluid with minor N2 and/or other gas species preserved in the Dabie-Sulu HP/UHPM eclogites and garnet clinopyroxenite indicate a great diversity of initial fluid composition in the precursors, implying very limited fluid–rock interaction during syn- and post-peak HP/UHPM.

Notes: Coesite relics were discovered as inclusions in clinopyroxene in eclogite and as inclusions in zircon in felsic and pelitic gneisses from Higher Himalayan Crystalline rocks in the upper Kaghan Valley, north-west Himalaya. The metamorphic peak conditions of the coesite-bearing eclogites are estimated to be 27–32 kbar and 700–770 °C, using garnet–pyroxene–phengite geobarometry and garnet–pyroxene geothermometry, respectively. Cathodoluminescence (CL) and backscattered electron (BSE) imaging distinguished three different domains in zircon: inner detrital core, widely spaced euhedral oscillatory zones, and thin, broadly zoned outermost rims. Each zircon domain contains a characteristic suite of micrometre-sized mineral inclusions which were identified by in situ laser Raman microspectroscopy. Core and mantle domains contain quartz, apatite, plagioclase, muscovite and rutile. In contrast, the rim domains contain coesite and minor muscovite. Quartz inclusions were identified in all coesite-bearing zircon grains, but not coexisting with coesite in the same growth domain (rim domain). 206Pb/238U zircon ages reveal that the quartz-bearing mantle domains and the coesite-bearing rim were formed at c. 50 Ma and 46.2 ± 0.7 Ma, respectively. These facts demonstrate that the continental materials were buried to 100 km within 7–9 Myr after initiation of the India–Asia collision (palaeomagnetic data from the Indian oceanic floor supports an initial India-Asia contact at 55–53 Ma). Combination of the sinking rate of 1.1–1.4 cm year−1 with Indian plate velocity of 4.5 cm year−1 suggests that the Indian continent subducted to about 100 km depth at an average subduction angle of 14–19°.

Notes: The Solund–Hyllestad–Lavik area affords an excellent opportunity to understand the ultrahigh-pressure Scandian orogeny because it contains a near-complete record of ophiolite emplacement, high-pressure metamorphism and large-scale extension. In this area, the Upper Allochthon was intruded by thec. 434 Ma Sogneskollen granodiorite and thrust eastward over the Middle/Lower Allochthon, probably in the Wenlockian. The Middle/Lower Allochthon was subducted to c. 50 km depth and the structurally lower Western Gneiss Complex was subducted to eclogite facies conditions at c. 80 km depth by c. 410–400 Ma. Within 〈 5–10 Myr, all these units were exhumed by the Nordfjord–Sogn detachment zone, producing shear strains 〉 100. Exhumation to upper crustal levels was complete by c. 403 Ma. The Solund fault produced the last few km of tectonic exhumation, bringing the near-ultrahigh-pressure rocks to within c. 3 km vertical distance from the low-grade Solund Conglomerate.

Notes: New petrographic evidence and a review of the latest radiometric age data are taken to indicate that formation of the ultra-high pressure (UHP) eclogites within the Western Gneiss Region of Norway probably occurred within the 400–410 Ma time frame. Thus, this event took place significantly later than the previous, widely accepted age of c. 425 Ma for the timing of the high pressure metamorphism in this part of the Scandinavian Caledonides. Garnet growth under UHP (coesite-stable) conditions is recognised as a discrete, younger event following on from earlier garnet formed under firstly amphibolite facies then quartz-stable, eclogite facies conditions. Currently, the best constrained and most precise age, specifically for UHP mineral growth, is the 402 ± 2 Ma U–Pb age for metamorphic zircon (some of which retain coesite inclusions) from the Hareidland eclogite. Exhumation must have followed shortly thereafter and, based on synoptic pressure–temperature and depth–time curves, must have been very fast. Our data and those of others indicate an initial fast exhumation to about 35 km depth by about 395 Ma at a mean rate of about 10 mm a−1. This rapid exhumation rate may have been driven by the appreciable residual buoyancy of the deeply subducted continental crustal slab due to incomplete eclogitization of the dominant Proterozoic orthogneisses during the short-lived UHP event. Subsequent exhumation to 8–10 km depth by about 375 Ma occurred at a much slower mean rate of about 1.3 mm a−1 with the late-stage extensional collapse of the Caledonian orogen playing an increasingly important role, especially in the final unroofing of the Western Gneiss Region with some remarkably preserved UHP rocks.

Notes: Widespread evidence for ultrahigh-pressure (UHP) metamorphism is reported in the Dulan eclogite-bearing terrane, the North Qaidam–Altun HP–UHP belt, northern Tibet. This includes: (1) coesite and associated UHP mineral inclusions in zircon separates from paragneiss and eclogite (identified by laser Raman spectroscopy); (2) inclusions of quartz pseudomorphs after coesite and polycrystalline K-feldspar + quartz in eclogitic garnet and omphacite; and (3) densely oriented SiO2 lamellae in omphacitic clinopyroxene. These lines of evidence demonstrate that the Dulan region is a UHP metamorphic terrane. In the North Dulan Belt (NDB), eclogites are characterized by the peak assemblage Grt + Omp + Rt + Phn + Coe (pseudomorph) and retrograde symplectites of Cpx + Ab and Hbl + Pl. The peak conditions of the NDB eclogites are P = 2.9–3.2 GPa, and T = 631–687 °C; the eclogite shows a near-isothermal decompression P–T path suggesting a fast exhumation. In the South Dulan Belt (SDB), three metamorphic stages are recognized in eclogites: (1) a peak eclogite facies stage with the assemblage Grt + Omp + Ky + Rt + Phn at P = 2.9–3.3 GPa and T = 729–746 °C; (2) a high-pressure granulite facies stage with Grt + Cpx (Jd 〈 30) + Pl (An24–29) + Scp at P = 1.9–2.0 GPa, T = 873–948 °C; and (3) an amphibolite facies stage with the assemblage Hbl + Pl + Ep/Czo at P = 0.7–0.9 GPa and T = 660–695 °C. The clockwise P–T path of the SDB eclogites is different from the near-isothermal decompression P–T path from the NDB eclogites, which suggests that the SDB was exhumed to a stable crustal depth at a slower rate. In essence these two sub-belts formed in different tectonic settings; they both subducted to mantle depths of around 100 km, but were exhumed to the Earth's surface separately along different paths. This UHP terrane plays an important role in understanding continental collision in north-western China.

Notes: Mineral assemblages in Al2O3-rich, SiO2- and K2O-poor metapelitic rocks from the western Odenwald Crystalline Complex (Variscan Mid-German Crystalline Rise, southern Germany) include corundum, spinel, cordierite, sillimanite, garnet and staurolite. Quartz is absent from almost all samples. Therefore, the applicability of conventional geothermobarometry is very limited or even impossible. Detailed petrographic investigation on selected samples permits inference of the sequence of appearance and disappearance of several mineral assemblages. The recognition of such partial re-equilibration stages and their associated mineral assemblages, together with mineral stabilities predicted from KFMASH pseudosections, enables the determination of the pressure-temperature (P–T) trajectories experienced by these rocks during the Variscan metamorphism. The rocks were metamorphosed under low-P/high-T conditions and underwent an anti-clockwise P–T evolution. A pressure increase from about 2 kbar to 4 ± 0.5 kbar was accompanied by heating. Peak metamorphic conditions were reached at pressures of 4 ± 0.5 kbar and temperatures of at least 640 °C, probably even higher. The retrograde evolution is characterised by near-isobaric cooling from ≥ 640 °C to approximately 550 °C. The rocks underwent the anti-clockwise evolution in a subduction-related magmatic arc setting. The close spatial association of the low-P/high-T rocks with recently discovered metabasic eclogites in the eastern part of the Odenwald Crystalline Complex may indicate a fossil paired metamorphic belt in the Central European Variscides.

Notes: The influx of a H2O–CO2-dominated fluid into actinolite-bearing metabasic rocks during greenschist facies metamorphism in the Kalgoorlie area of Western Australia resulted in a zoned alteration halo around inferred fluid conduits that contain gold mineralisation. The alteration halo is divided into two outer zones, the chlorite zone and the carbonate zone, and an inner pyrite zone adjacent to the inferred fluid conduits. Reaction between the fluid and the protolith resulted in the breakdown of actinolite and the development of chlorite, dolomite, calcite and siderite. In addition, rocks in the pyrite zone developed muscovite-bearing assemblages as a consequence of the introduction of potassium by the fluid. Mineral equilibria calculations undertaken using the computer software thermocalc in the model system Na2O–CaO–K2O–FeO–MgO–Al2O3–SiO2–H2O–CO2 show that mineral assemblages in the outer zones of the alteration halo are consistent with equilibrium of the protoliths with a fluid of composition XCO2 = CO2/(CO2 + H2O) = 0.1–0.25 for temperatures of 315–320 °C. The inner zone of the alteration halo reflect equilibrium with a fluid of composition XCO2≈ 0.25. Fluid-rock buffering calculations show that the alteration halo is consistent with interaction with a single fluid composition and that the zoned structure of the halo reflects the volume of this fluid with which the rocks reacted. This fluid is likely to have also been the one responsible for the gold mineralisation at Kalgoorlie.

Notes: Nanometric solid inclusions in diamond incorporated in garnet and zircon from felsic gneiss of the Kokchetav massif, Kazakhstan, have been examined utilizing electron microscopy and focused ion beam techniques. Host garnet and zircon contain numerous pockets of multiple inclusions, which consist of 1–3 diamond crystals intergrown with quartz, phengite, phlogopite, albite, K-feldspar, rutile, apatite, titanite, biotite, chlorite and graphite in various combinations. Recalculation of the average chemical composition of the entrapped fluid represented by multiple inclusion pockets indicates that such fluid contained a low wt% of SiO2, suggesting a relatively low-temperature fluid rather than a melt. Transmission electron microscopy revealed that the diamond contains abundant nanocrystalline inclusions of oxides, rare carbonates and silicates. Within the 15 diamond crystals studied, abundant inclusions were found of SiO2, TiO2, FexOy, Cr2O3, ZrSiO4, and single grains of ThxOy, BaSO4, MgCO3, FeCr2O4 and a stoichiometric Fe-rich pyroxene. The diversity of trace elements within inclusions of essentially the same stoichiometry suggests that the Kokchetav diamond crystallized from a fluid containing variable amounts of Si, Fe, Ti, Cr, Zr, Ba, Mg and Th and other minor components such as K, Na, P, S, Pb, Zn, Nb, Al, Ca, Cl. Most of the components in crystals included in diamond appear to have their origin in the subducted metasediments, but some of them probably originate from the mantle. It is concluded that Kokchetav diamond most likely crystallized from a COH-rich multicomponent supercritical fluid at a relatively low temperature (hence the apparently low content of rock-forming elements), and that the diversity of major and minor components suggests interactions between subducted metasediments and mantle components.

Notes: A high-P granulite facies gneiss complex occurs in north-west Payer Land (74°28′−74°47′N) in the central part of the East Greenland Caledonian (Ordovician–Devonian) orogen. High-P metamorphism of the Payer Land gneiss complex resulted in formation of the assemblages Grt + Cpx + Amp + Qtz + Ru ± Pl in mafic rocks, and Grt + Ol + Cpx + Opx + Spl in rare ultramafic pods. Associated metapelites experienced anatexis in the kyanite stability field. Peak metamorphic assemblages formed around 800–850 °C at pressures of c. 1.4–1.7 GPa, corresponding to crustal depths of c. 50 km. Mafic granulites contain abundant reaction textures, including the replacement of garnet by symplectites of Opx + Spl + Pl, indicating that the high-P event was followed by decompression while the granulites remained at elevated temperatures. Charnockitic gneisses from Payer Land show evidence of late Archean (c. 2.8–2.4 Ga) crustal growth and subsequent Palaeoproterozoic (c. 1.85 Ga) metamorphism. The gneiss complex experienced intense reworking during the Caledonian continental collision. On the basis of Caledonian monazite ages recorded from the high-P anatectic metapelites, the clockwise P–T evolution and formation of the high-P granulite facies assemblages is related to Caledonian crustal thickening, which resulted in formation of eclogites approximately 300 km north of Payer Land. The Payer Land granulites comprise a metamorphic core complex, which is separated from the overlying low-grade supracrustal rocks (the Neoproterozoic Eleonore Bay Supergroup) by a late Caledonian extensional fault zone, the Payer Land Detachment. The steep, nearly isothermal, unloading P–T path recorded by the granulites can be explained by erosional and tectonic unroofing along the Payer Land Detachment.

Notes: High-pressure granulites are characterised by the key associations garnet-clinopyroxene-plagioclase-quartz (in basic rocks) and kyanite-K-feldspar (metapelites and felsic rocks) and are typically orthopyroxene-free in both basic and felsic bulk compositions. In regional metamorphic areas, two essential varieties exist: a high- to ultrahigh-temperature group and a group representing overprinted eclogites. The high- to ultrahigh-temperature type formerly contained high-temperature ternary feldspar (now mesoperthite) coexisting with kyanite, is associated with garnet peridotites, and formed at conditions above 900 °C and 1.5 GPa. Clinopyroxene in subordinate basic rocks is Al-rich and textural evidence points to a high-pressure–high-temperature melting history. The second variety contains symplectite-like or poikilitic clinopyroxene-plagioclase intergrowths indicating former plagioclase-free, i.e. eclogite facies assemblages. This type of rock formed at conditions straddling the high-pressure amphibolite/high-pressure granulite field at around 700–850 °C, 1.0–1.4 GPa. Importantly, in the majority of high-pressure granulites, orthopyroxene is secondary and is a product of reactions at pressures lower than the peak recorded pressure. In contrast to low- and medium-pressure granulites, which form at conditions attainable in the mid to lower levels of normal continental crust, high-pressure granulites (of nonxenolith origin) mostly represent rocks formed as a result of short-lived tectonic events that led to crustal thickening or subduction of the crust into the mantle. Short times at high-temperature conditions are reflected in the preservation of prograde zoning in garnet and pyroxene. High-pressure granulites of both regional types, although rare, are known from both old and young metamorphic terranes (e.g. c. 45 Ma, Namche Barwa, E Himalaya; 400–340 Ma, European Variscides; 1.8 Ga Hengshan, China; 1.9 Ga, Snowbird, Saskatchewan and 2.5 Ga Jianping, China). This spread of ages supports proposals suggesting that thermal and tectonic processes in the lithosphere have not changed significantly since at least the end of the Archean.

Notes: The Mollendo–Camana Block (MCB) is a 50 × 150 km Precambrian inlier of the Andean belt that outcrops along the Pacific coast of southern Peru. It consists of stromatic migmatites of Paleoproterozoic heritage intensely metamorphosed during the Grenville event (c. 1 Ga; U-Pb and U-Th-Pb ages on zircon and monazite). In the migmatites, aluminous mesosomes (FMAS) and quartzofeldspathic leucosomes (KFMASH), contain various amounts of K-feldspar (Kfs), orthopyroxene (XMg Opx = 0.86), plagioclase (Pl), sillimanite (Sil; exceptionally kyanite, Ky) ilmenite (Ilm), magnetite (Mag), quartz (Qtz), and minor amounts of garnet (XMg Grt = 0.60), sapphirine (XMg Spr = 0.87), cordierite (XMg Crd = 0.92) and biotite (XMg Bt = 0.83). The ubiquitous peak mineral assemblage is Opx-Sil-Kfs-Qtz-(± Grt) in most of the MCB, which, together with the high Al content of orthopyroxene (10% Al2O3) and the local coexistence of sapphirine-quartz, attest to regional UHT metamorphism (〉 900 °C) at pressures in excess of 1.0 GPa. Fluid-absent melting of biotite is responsible for the massive production of orthopyroxene that proceeded until exhaustion of biotite (and most of the garnet) in the southern part of the MCB (Mollendo-Cocachacra areas). In this area, a first stage of decompression from 1.1–1.2 to 0.8–0.9 GPa at temperatures in excess of 950 °C, is marked by the breakdown of Sil-Opx to Spr-Opx-Crd assemblages according to several bivariant FMAS reactions. High-T decompression is also shown by Mg-rich garnet being replaced by Crd-Spr- and Crd-Opx-bearing symplectites, and reacting with quartz to produce low-Al-Opx-Sil symplectites in quartz-rich migmatites. Neither osumilite nor spinel-quartz assemblages being formed, isobaric cooling at about 0.9 GPa probably followed the initial decompression and proceeded with massive precipitation of melts towards the (Os) invariant point, as demonstrated by Bt-Qtz-(± pl) symplectites in quartz-rich migmatites (melt + Opx + Sil = Bt + Grt + Kfs + Qtz). Finally, Opx rims around secondary biotite attest to late fluid-absent melting, compatible with a second stage of decompression below 900 °C. The two stages of decompression are interpreted as due to rapid tectonic denudation whereas the regional extent of UHT metamorphism in the area, probably results from large-scale penetration of hot asthenospheric mantle at the base of an over-thickened crust.

Notes: The Arthur River Complex is a suite of gabbroic to dioritic orthogneisses in northern Fiordland, New Zealand. The Arthur River Complex separates rocks of the Median Tectonic Zone, a Mesozoic island arc complex, from Palaeozoic rocks of the palaeo-Pacific Gondwana margin, and is itself intruded by the Western Fiordland Orthogneiss. New SHRIMP U/Pb single zircon data are presented for magmatic, metamorphic and deformation events in the Arthur River Complex and adjacent rocks from northern Fiordland. The Arthur River Complex orthogneisses and dykes are dominated by magmatic zircon dated at 136–129 Ma. A dioritic orthogneiss that occurs along the eastern margin of the Complex is dated at 154.4 ± 3.6 Ma and predates adjacent plutons of the Median Tectonic Zone. Rims on zircon cores from this sample record a thermal event at c. 120 Ma, attributed to the emplacement of the Western Fiordland Orthogneiss. Migmatitic Palaeozoic orthogneiss from the Arthur River Complex (346 ± 6 Ma) is interpreted as deformed wall rock. Very fine rims (5–20 µm) also indicate a metamorphic age of c. 120–110 Ma. A post-tectonic pegmatite (81.8 ± 1.8 Ma) may be related to phases of crustal extension associated with the opening of the Tasman Sea. The Arthur River Complex is interpreted as a batholith, emplaced at mid-crustal levels and then buried to deep crustal levels due to convergence of the Median Tectonic Zone arc and the continental margin.

Notes: Petrological data provide a good record of the thermal structure of deeply eroded orogens, and, in principle, might be used to relate the metamorphic structure of an orogen to its deformational history. In this paper, we present two-dimensional thermal modelling of various subduction models taking into account varying wedge geometry as well as variation of density and topography with metamorphic reactions.The models clearly show that rock type accreted in the wedge has important effects on the thermal regime of orogenic wedges. The thermal regime is dominated by radiogenic heat production. Material having high radioactive heat production, like the granodioritic upper crust, produces high temperature metamorphism (amphibolitic conditions). Material with low radioactive heat production results in low temperature metamorphism of greenschist or blueschist types depending on the thickness of the wedge.Application of this model to seemingly unrelated areas of the Central Alps (Lepontine Dome, Grisons) and Eastern Alps (Tauern Window) explains the coexistence and succession of distinct Barrovian and blueschist facies metamorphic conditions as the result of a single, continuous tectonic process in which the main difference is the composition of the incoming material in the orogenic wedge. Accretion of the European upper continental crust in the Lepontine and Tauern Domes produces Barrovian type metamorphism while accretion of oceanic sediments results in blueschist facies metamorphism in the Valaisan domain.

Notes: The central part of the Carolina terrane in western South Carolina comprises a 30 to 40 km wide zone of high grade gneisses that are distinct from greenschist facies metavolcanic rocks of the Carolina slate belt (to the SE) and amphibolite facies metavolcanic and metaplutonic rocks of the Charlotte belt (to the NW). This region, termed the Silverstreet domain, is characterized by penetratively deformed felsic gneisses, granitic gneisses, and amphibolites. Mineral assemblages and textures suggest that these rocks formed under high-pressure metamorphic conditions, ranging from eclogite facies through high-P granulite to upper amphibolite facies.Mafic rocks occur as amphibolite dykes, as metre-scale blocks of coarse-grained garnet-clinopyroxene amphibolite in felsic gneiss, and as residual boulders in deeply weathered felsic gneiss. Inferred omphacite has been replaced by a vermicular symplectite of sodic plagioclase in diopside, consistent with decompression at moderate to high temperatures and a change from eclogite to granulite facies conditions. All samples have been partially or wholly retrograded to amphibolite assemblages. We infer the following P-T-t history: (1) eclogite facies P-T conditions at ≥ 1.4 GPa, 650–730 °C (2) high-P granulite facies P-T conditions at 1.2–1.5 GPa, 700–800 °C (3) retrograde amphibolite facies P-T conditions at 0.9–1.2 GPa and 720–660 °C. This metamorphic evolution must predate intrusion of the 415 Ma Newberry granite and must postdate formation of the Charlotte belt and Slate belt arcs (620 to 550 Ma).Comparison with other medium temperature eclogites and high pressure granulites suggests that these assemblages are most likely to form during collisional orogenesis. Eclogite and high-P granulite facies metamorphism in the Silverstreet domain may coincide with a ≈570–535 Ma event documented in the western Charlotte belt or to a late Ordovician-early Silurian event. The occurrence of these high-P assemblages within the Carolina terrane implies that, prior to this event, the western Carolina terrane (Charlotte belt) and the eastern Carolina terrane (Carolina Slate belt) formed separate terranes. The collisional event represented by these high-pressure assemblages implies amalgamation of these formerly separate terranes into a single composite terrane prior to its accretion to Laurentia.

Notes: Detailed 3-D analysis of inclusion trails in garnet porphyroblasts and matrix foliations preserved around a hand-sample scale, tight, upright fold has revealed a complex deformation history. The fold, dominated by interlayered quartz–mica schist and quartz-rich veins, preserves a crenulation cleavage that has a synthetic bulk shear sense to that of the macroscopic fold and transects the axis in mica-rich layers. Garnet porphyroblasts with asymmetric inclusion trails occur on both limbs of the fold and display two stages of growth shown by textural discontinuities. Garnet porphyroblast cores and rims pre-date the macroscopic fold and preserve successive foliation inflection/intersection axes (FIAs), which have the same trend but opposing plunges on each limb of the fold, and trend NNE–SSW and NE–SW, respectively. The FIAs are oblique to the main fold, which plunges gently to the WSW. Inclusion trail surfaces in the cores of idioblastic porphyroblasts within mica-rich layers define an apparent fold with an axis oblique to the macroscopic fold axis by 32°, whereas equivalent surfaces in tabular garnet adjacent to quartz-rich layers define a tighter apparent fold with an axis oblique to the main fold axis by 17°. This potentially could be explained by garnet porphyroblasts that grew over a pre-existing gentle fold and did not rotate during fold formation, but is more easily explained by rotation of the porphyroblasts during folding. Tabular porphyroblasts adjacent to quartz-rich layers rotated more relative to the fold axis than those within mica-rich layers due to less effective deformation partitioning around the porphyroblasts and through quartz-rich layers. This work highlights the importance of 3-D geometry and relative timing relationships in studies of inclusion trails in porphyroblasts and microstructures in the matrix.

Notes: Abstract P–T conditions, mineral isograds, the relation of the latter to foliation planes and kinematic indicators are used to elucidate the tectonic nature and evolution of a shear zone in an orogen exhumed from mid-crustal depths in western Turkey. Furthermore, we discuss whether simple monometamorphic fabrics of rock units from different nappes result from one single orogeny or are related to different orogenies. Metasedimentary rocks from the Çine and Selimiye nappes at the southern rim of the Anatolide belt of western Turkey record different metamorphic evolutions. The Eocene Selimiye shear zone separates both nappes. Metasedimentary rocks from the Çine nappe underneath the Selimiye shear zone record maximum P–T conditions of about 7 kbar and 〉550 °C. Metasedimentary rocks from the overlying Selimiye nappe have maximum P–T conditions of 4 kbar and c. 525 °C near the base of the nappe. Kinematic indicators in both nappes are related to movement on the Selimiye shear zone and consistently show a top-S shear sense. Metamorphic grade in the Selimiye nappe decreases structurally upwards as indicated by mineral isograds defining the garnet-chlorite zone at the base, the chloritoid-biotite zone and the biotite-chlorite zone at the top of the nappe. The mineral isograds in the Selimiye nappe run parallel to the regional SR foliation, parallel the Selimiye shear zone and indicate that the Selimiye shear zone formed during this prograde greenschist to lower amphibolite facies metamorphic event but remained active after the peak of metamorphism. 40Ar/39Ar mica ages and the tectonometamorphic relationship with the Eocene Cyclades–Menderes thrust, which occurs above the Selimiye nappe in the study area, suggests an Eocene age of metamorphism in the Selimiye nappe.Metasedimentary rocks of the Çine nappe 20–30 km north of the Selimiye shear zone record maximum P–T conditions of 8–11 kbar and 600–650  °C. An age of about 550 Ma is indicated for amphibolite facies metamorphism and associated top-N shear in the orthogneiss of the Çine nappe. Our study shows that simple monophase tectonometamorphic fabrics do not always indicate a simple orogenic development of a nappe stack. Preservation in some areas and complete overprinting of those fabrics in other areas apparently occur very heterogeneously.

Notes: Abstract The prograde metamorphism of eclogites is typically obscured by chemical equilibration at peak conditions and by partial requilibration during retrograde metamorphism. Eclogites from the Eastern Blue Ridge of North Carolina retain evidence of their prograde path in the form of inclusions preserved in garnet. These eclogites, from the vicinity of Bakersville, North Carolina, USA are primarily comprised of garnet–clinopyroxene–rutile–hornblende–plagioclase–quartz. Quartz, clinopyroxene, hornblende, rutile, epidote, titanite and biotite are found as inclusions in garnet cores. Included hornblende and clinopyroxene are chemically distinct from their matrix counterparts. Thermobarometry of inclusion sets from different garnets record different conditions. Inclusions of clinozoisite, titanite, rutile and quartz (clinozoisite + titanite = grossular + rutile + quartz + H2O) yield pressures (6–10 kbar, 400–600 °C and 8–12 kbar 450–680 °C) at or below the minimum peak conditions from matrix phases (10–13 kbar at 600–800 °C). Inclusions of hornblende, biotite and quartz give higher pressures (13–16 kbar and 630–660 °C). Early matrix pyroxene is partially or fully broken down to a diopside–plagioclase symplectite, and both garnet and pyroxene are rimmed with plagioclase and hornblende. Hypersthene is found as a minor phase in some diopside + plagioclase symplectites, which suggests retrogression through the granulite facies. Two-pyroxene thermometry of this assemblage gives a temperature of c. 750 °C. Pairing the most Mg-rich garnet composition with the assemblage plagioclase–diopside–hypersthene–quartz gives pressures of 14–16 kbar at this temperature. The hornblende–plagioclase–garnet rim–quartz assemblage yields 9–12 kbar and 500–550 °C. The combined P–T data show a clockwise loop from the amphibolite to eclogite to granulite facies, all of which are overprinted by a texturally late amphibolite facies assemblage. This loop provides an unusually complete P–T history of an eclogite, recording events during and following subduction and continental collision in the early Palaeozoic.

Notes: Static heating during intrusion of the Makhavinekh Lake Pluton (MLP) caused replacement of garnet in the adjacent country rocks (Tasiuyak Gneiss) by coronal assemblages of orthopyroxene + cordierite. Thermometry based on Al solubility in orthopyroxene, applied to relict garnet and neighbouring orthopyroxene, preserves a temperature gradient from 700 to 900 °C at distances between 5750 and 20 m from the intrusion, reaffirming the robustness of this thermometry technique. Intracrystalline and intergranular variations of Al zoning in orthopyroxene are well-preserved, suggesting that little diffusional modification of Al growth zoning occurred. Maximum Al2O3 in orthopyroxene ranges from c. 2.0 wt% at 5750 m from the intrusion to a maximum of 4.3 wt% at the contact. Individual orthopyroxene grains show decreasing Al from core to rim in samples 〈 500 m from the intrusion, while those at greater distances show an increase from core to rim. These features are interpreted with the aid of numerical models for conductive heat flow in the aureole. Coronas in samples close to the intrusion grew at high temperatures and along T-t paths dominated by cooling, so maximum Al content in orthopyroxene in these samples occurs in the cores of grains that grew during the earliest stages of garnet consumption. In contrast, the corona-forming reactions in rocks further from the contact proceeded along prograde heating paths, so maximum Al content in orthopyroxene occurs in the rims of grains that grew during the final stages of garnet consumption. These results document the ability of Al-in-orthopyroxene thermometry to preserve a detailed record of thermal histories in contact-metamorphic granulites; they suggest that similar intracrystalline and intergranular variations of Al zoning in orthopyroxene in regional granulites may also preserve portions of both the prograde and peak-T evolution.

Notes: Grain growth simulations using the microstructure simulation system Elle have been performed in materials with a pre-existing grain shape foliation. As might be expected, the foliation is destroyed by the end of the experiment, and grain areas have increased by a factor of seven. The area of material swept by the migrating grain boundaries was monitored, and it was found that at every stage, virtually all of the grains which survived the grain growth process contain one and only one core of ‘unswept’ material. Remarkably these remnant unswept cores preserve a useable record of the initial grain size and the orientation of the grain shape foliation. This work suggests that, even for samples where no equivalent protolith can be found, it may be possible to see past a grain growth episode to estimate the original grain shape and grain size of the rock, and perhaps even reconstruct the grain boundary kinematics. In addition the identification of unswept cores has the potential to help unravel the evolution of grain boundary chemistry in rocks during metamorphism.As an example of a natural system showing these microstructures, we describe a peridotite from Almklovdalen, Norway. This peridotite was infiltrated by aqueous fluids at several stages during late Caledonian exhumation and retrogressive metamorphism. Grain boundary migration associated with the last of these infiltration events swept off abundant intragranular fluid inclusions in the original chlorite-peridotite. At the grain scale, microstructural mapping of the fluid inclusion rich areas shows that, as with the numerical simulations, many of the grains retain exactly one core of unswept material. Examples of other natural systems discussed include dislocation density distributions and trace element zoning.

Notes: Granulite facies magnesian metapelites commonly preserve a wide array of mineral assemblages and reaction textures that are useful for deciphering the metamorphic evolution of a terrane. Quantitative pressure, temperature and bulk composition constraints on the development and preservation of characteristic peak granulite facies mineral assemblages such as orthopyroxene + sillimanite + quartz are assessed with reference to calculated phase diagrams. In NCKFMASH and its chemical subsystems, peak assemblages form mainly in high-variance fields, and most mineral assemblage changes reflect multivariant equilibria. The rarity of orthopyroxene–sillimanite–quartz-bearing assemblages in granulite facies rocks reflects the need for bulk rock XMg of greater than approximately 0.60–0.65, with pressures and temperatures exceeding c. 8 kbar and 850 °C, respectively. Cordierite coronas mantling peak minerals such as orthopyroxene, sillimanite and quartz have historically been used to infer isothermal decompression P–T paths in ultrahigh-temperature granulite facies terranes. However, a potentially wide range of P–T paths from a given peak metamorphic condition facilitate retrograde cordierite growth after orthopyroxene + sillimanite + quartz, indicating that an individual mineral reaction texture is unable to uniquely define a P–T vector. Therefore, the interpretation of P–T paths in high-grade rocks as isothermal decompression or isobaric cooling may be overly simplistic. Integration of quantitative data from different mineral reaction textures in rocks with varying bulk composition will provide the strongest constraints on a P–T path, and in turn on tectonic models derived from these paths.

Notes: A petrogenetic grid for metapelites in the system NKFMASH is presented. The P–T range is investigated in three sections: (1) The high- and ultrahigh-pressure range is discussed in the system NFMASH because phengite is the only stable potassic phase. (2) The transition region is characterised by four NKFMASH-invariant points that separate high-pressure glaucophane-bearing from medium-pressure biotite-bearing metapelites. (3) The medium-pressure range contains the fifth NKFMASH-invariant point. The univariant reactions of this point terminate the stability range of paragonite, which breaks down to form staurolite or kyanite and plagioclase during decompression and/or heating. As the growth of albitic plagioclase by decomposition of paragonite via continuous reactions may be conspicuous already before these staurolite- or kyanite-producing reactions are reached, such albite porphyroblast schists are typical indicators of a former high-pressure metamorphic history.Considering the preservation of high-pressure metapelitic assemblages, those crossing the NKFMASH-transition region during exhumation commonly dehydrate and preservation is unlikely. Three types of metapelites have a fairly good survival potential: (1) low-temperature metapelites (up to c. 540 °C) with an exhumation path back into the chlorite + albite stability field, (2) assemblages with chloritoid + glaucophane, and (3) the relatively high-temperature glaucophane + kyanite and jadeite + kyanite bearing parageneses, that are relatively dry at the onset of exhumation. A comparison with data from the literature shows that these rock types are the most abundant in nature.

Notes: Micaceous quartzites from a subvertical shear zone in the Tauern Window contain abundant quartz clasts derived from dismembered quartz-tourmaline veins. Bulk plane strain deformation affected these rocks at amphibolite facies conditions. Shape changes suggest net shortening of the clasts by 11–64%, with a mean value of 35%. Quartz within the clasts accommodated this strain largely via dislocation creep processes. On the high-stress flanks of the clasts, however, quartz was removed via solution mass transfer (pressure solution) processes; the resulting change in bulk composition allowed growth of porphyroblastic staurolite + chlorite ± kyanite on the clast flanks. Matrix SiO2 contents decrease from c. 83 wt% away from the clasts to 49–58% in the selvages on the clast flanks. The chemical changes are consistent with c. 70% volume loss in the high-stress zones. Calculated shortening values within the clast flanks are similar to the volume-loss estimates, and are greatly in excess of the shortening values calculated from the clasts themselves. Flow laws for dislocation creep versus pressure solution imply large strain-rate gradients and/or differential stress gradients between the matrix and the clast selvages. In a rock containing a large proportion of semirigid clasts, weakening within the clast flanks could dominate rock rheology. In our samples, however, weakening within the selvages was self limiting: (1) growth of strong staurolite porphyroblasts in the selvages protected remaining quartz from dissolution; and (2) overall flattening of the quartz clasts probably decreased the resolved shear stress on the flanks to values near those of the matrix, which would have reduced the driving force for solution-transfer creep. Extreme chemical changes nonetheless occurred over short distances. The necessity of maintaining strain compatibility may lead to significant localized dissolution in rocks containing rheologic heterogeneities, and overall weakening of the rocks may result. Solution-transfer creep may be a major process whereby weakening and strain localization occur during deep-crustal metamorphism of polymineralic rocks.

Notes: Geothermometry and mineral assemblages show an increase of temperature structurally upwards across the Main Central Thrust (MCT); however, peak metamorphic pressures are similar across the boundary, and correspond to depths of 35–45 km. Garnet-bearing samples from the uppermost Lesser Himalayan sequence (LHS) yield metamorphic conditions of 650–675 °C and 9–13 kbar. Staurolite-kyanite schists, about 30 m above the MCT, yield P-T conditions near 650 °C, 8–10 kbar. Kyanite-bearing migmatites from the Greater Himalayan sequence (GHS) yield pressures of 10–14 kbar at 750–800 °C. Top-to-the-south shearing is synchronous with, and postdates peak metamorphic mineral growth.Metamorphic monazite from a deformed and metamorphosed Proterozoic gneiss within the upper LHS yield U/Pb ages of 20–18 Ma. Staurolite-kyanite schists within the GHS, a few metres above the MCT, yield monazite ages of c. 22 ± 1 Ma. We interpret these ages to reflect that prograde metamorphism and deformation within the Main Central Thrust Zone (MCTZ) was underway by c. 23 Ma. U/Pb crystallization ages of monazite and xenotime in a deformed kyanite-bearing leucogranite and kyanite-garnet migmatites about 2 km above the MCT suggest crystallization of partial melts at 18–16 Ma. Higher in the hanging wall, south-verging shear bands filled with leucogranite and pegmatite yield U/Pb crystallization ages for monazite and xenotime of 14–15 Ma, and a 1–2 km thick leucogranite sill is 13.4 ± 0.2 Ma. Thus, metamorphism, plutonism and deformation within the GHS continued until at least 13 Ma. P-T conditions at this time are estimated to be 500–600 °C and near 5 kbar. From these data we infer that the exhumation of the MCT zone from 35 to 45 km to around 18 km, occurred from 18 to 16 to c. 13 Ma, yielding an average exhumation rate of 3–9 mm year−1. This process of exhumation may reflect the ductile extrusion (by channel flow) of the MCTZ from between the overlying Tibetan Plateau and the underthrusting Indian plate, coupled with rapid erosion.

Notes: Book reviewed in this article: The Identification of Soils for Forest Management. By Fiona Kennedy.

Notes: Abstract. A no-tillage (NT) system was developed in semiarid Morocco to improve the soil fertility and stabilize yield through conservation of water. Results in two long-term trials (4 and 11 years) were able to show the effects of a no-tillage system in increasing total soil organic matter and total nitrogen. Over time, the quality of the NT soil surface was improved compared with that under conventional tillage (CT) with disc harrows. This effect was the result of an increase in soil organic carbon (SOC) and a slight decline in pH. However, over time, nitrogen decreased in both tillage practices, especially in the 0–25 mm layer (from 0.59 to 0.57 t ha−1 and from 0.44 to 0.42 t ha−1 under NT and CT, respectively). After 4 years of NT an extra 5.62 t ha−1 of SOC was sequestered in the 0–25 mm layer, and after 11 years the SOC increased further to 7.21 t ha−1.

Notes: Book reviewed in this article: Agriculture, Hydrology and Water Quality. By P.M. Haygarth and S.C. Jarvis (Editors).

Notes: Abstract. For an efficient abatement of diffuse N pollution from arable land, it is important to have practical and reliable tools that can quantify the effect of different management practices on leaching, and also analyse the effect of alternative management scenarios aimed at reducing leaching. We present here an application of soilndb, a management-oriented model for quantifying nitrate leaching from arable land. Simulations with soilndb were compared with measurements of pipe-drain discharge of nitrate taken in a 14-year field experiment on a sandy loam soil in south-west Sweden. Following adjustment of parameters connected to litter and faeces decomposition and mineralization, the model gave satisfactory predictions of nitrate leaching for all 10 treatments. The temporal pattern was generally well captured by the model, as was confirmed by high model efficiency values (average = 0.59). This application also supports the model's ability to simulate the long-term influence of different crops and catch crops as well as different manure strategies on leaching. However, further studies should be done to evaluate the model under additional agro-environmental conditions (e.g. soils, climates, and crops).

Notes: Abstract. The Phosphorus Indicators Tool provides a catchment-scale estimation of diffuse phosphorus (P) loss from agricultural land to surface waters using the most appropriate indicators of P loss. The Tool provides a framework that may be applied across the UK to estimate P loss, which is sensitive not only to land use and management but also to environmental factors such as climate, soil type and topography. The model complexity incorporated in the P Indicators Tool has been adapted to the level of detail in the available data and the need to reflect the impact of changes in agriculture. Currently, the Tool runs on an annual timestep and at a 1 km2 grid scale.We demonstrate that the P Indicators Tool works in principle and that its modular structure provides a means of accounting for P loss from one layer to the next, and ultimately to receiving waters. Trial runs of the Tool suggest that modelled P delivery to water approximates measured water quality records. The transparency of the structure of the P Indicators Tool means that identification of poorly performing coefficients is possible, and further refinements of the Tool can be made to ensure it is better calibrated and subsequently validated against empirical data, as it becomes available.

Notes: Abstract. We present a semi-quantitative visual and tactile method for assessing soil physical fertility in terms of soil structure, root growth and soil surface condition. A block of topsoil is dug out with a spade. Horizontal layers (usually 2–4) are then identified as they appear. A brief one-page description of the soil is produced. Using a key, structural and rooting scores are assigned to each soil layer from the appearance of the soil and from its response to tactile assessment. These scores are then combined across depths, with weighting appropriate for the depth of each layer. A separate score was made of soil surface condition. Thus, overall soil physical fertility is assessed as three scores for topsoil structure, rooting and surface condition. The usefulness and sensitivity of the procedure were tested in two ley-arable organic rotation experiments on sandy loams in northeast Scotland.

Notes: Abstract. Eleven precipitated phosphates were evaluated as sources of phosphorus (P) for plant growth by comparing their effectiveness with that of monocalcium phosphate, a source of water soluble P that is generally considered to be fully plant available. The precipitated phosphates comprised struvites recovered from waste water discharges (mainly magnesium ammonium phosphate), laboratory synthesised struvites, a synthetic iron phosphate and a recovered calcium phosphate. Precipitating phosphates in these forms could be a way for removing P from waste water before it is discharged to rivers, so reducing the risk of eutrophication. Application to agricultural land would be one potential use for such phosphates. Evaluation was by pot experiments with a sandy loam soil and with a sandy clay loam soil using perennial ryegrass (Lolium perenne) as the test crop. The soils differed in pH (6.6 and 7.1) and in Olsen P (28 and 11 mg L−1). Measured variables were grass dry matter (DM) yield and grass P concentration which were used to calculate offtake of P in the harvested grass. DM yields of ryegrass and P offtakes given by the synthetic and recovered struvites were not significantly different statistically either between themselves or to MCP applied at the same rate. On this basis these struvites could be used to recycle P to similar soils and the effect of the P on crop yield should be similar to that of MCP

Notes: Abstract. The main inputs, outputs and transfers of potassium (K) in soils and swards under typical south west England conditions were determined during 1999/00 and 2000/01 to establish soil and field gate K budgets under different fertilizer nitrogen (N) (0 and 280 kg ha−1 yr−1) and drainage (undrained and drained) treatments. Plots receiving fertilizer N also received farmyard manure (FYM). Potassium soil budgets ranged, on average for the two years, from −5 (+N, drained) to +9 (no N and undrained) kg K ha−1 yr−1 and field gate budgets from +23 (+N, drained) to +89 (+N, undrained). The main inputs and outputs to the soil K budgets were fertilizer application (65%) and plant uptake (93%). Animals had a minor effect on K export but a major impact on K recycling. Nitrogen fertilizer application and drainage increased K uptake by the grass and, with it, the efficiency of K used. It also depleted easily available soil K, which could be associated with smaller K losses by leaching.

Notes: Abstract. Crops on sandy soils (〈5% clay) are exposed to K deficiency due to the small release and high leaching losses of K. Reliable tools are needed to improve the K management in cropping systems with limited K input, such as organic farming where import of nutrients are restricted according to the EC regulations. We investigated K balances and exchangeable K (Kexch) changes in an organic crop rotation experiment. Potassium leaching decreased from 42 kg ha−1 in 1998/99 to 21 kg ha−1 in 2000/01 as an average of a crop rotation (spring barley, grass-clover, winter wheat and pea/barley) with manure application and without catch crops. In the same period, spring Kexch decreased from 5.0 to 3.0 mg K 100 g soil−1 (0–20 cm). The retention of the straw K left in the field after harvest increased with decreasing levels of Kexch. The cereal crops did not respond to K application but in the pea/barley mixture the pea yield increased by 46%. The concordance between measured K balances and changes in Kexch was weak. Exchangeable K is suitable as a tool for K management on a rotational basis, and a Kexch above 3 mg 100 g soil−1 in the autumn should be avoided to minimize K leaching.

Notes: Abstract. Diagnosis of soil salinity and its spatial variability is required to establish control measures in irrigated agriculture. This article shows the usefulness of electromagnetic (EM) and soil sampling techniques to map salinity. We analysed the salinity of a 1-ha plot of surface-irrigated olive plantation in Aragon, NE Spain, by measuring the electrical conductivity of the saturation extract (ECe) of soil samples taken at 22 points, and by reading the Geonics EM38 sensor at 141 points in the horizontal (EMH) and vertical (EMV) dipole positions. EMH and EMV values had asymmetrical bimodal distributions, with most readings in the non-saline range and a sharp transition to relatively high readings. Most salinity profiles were uniform (i.e. EMH=EMV), except in areas with high salinity and concurrent shallow water tables, where the profiles were inverted as shown by EMH 〉 EMV, and by ECe being greater in shallow than in deeper layers. The regressions of ECe on EM readings predicted ECe with R2 〉 84% for the 0–100 to 0–150 cm soil depths. We then produced salinity contour maps from the 141 ECe values estimated from the electromagnetic readings and the 22 measured values of ECe. Owing to the high soil sampling density, the maps were similar (i.e. mean surface-weighted ECe values between 3.9 dS m−1 and 4.2 dS m−1), although the electromagnetically estimated ECe improved the mapping of details. Whereas soil sampling is preferred for analysing the vertical distribution of soil salinity, the electromagnetic sensor is ideal for mapping the lateral variability of soil salinity.

Notes: Abstract. The effects of soil management on soil losses from olive plantations in southern Spain were evaluated using the Revised Universal Soil Loss Equation (RUSLE), a review of published experiments, and preliminary results of an on-going field trial. Experimental data were used to parameterize the RUSLE for olive orchards under various soil management regimes. The predictions agreed qualitatively with the data available, and the model provided a simple way to assess the effects of soil management on erosion. Our results showed that no-tillage caused the greatest soil loss, while cover crops showed the least. Tillage and planting following contours proved only partially effective and did not reduce soil erosion as much as protective crops. One scenario studied suggests that, on slight to moderate slopes, land transformed from row crops to olive orchards may remain below the maximum tolerable soil erosion limit, if a cover crop is included between the trees. A scenario for marginal olive orchards located on steep slopes suggests that effective erosion control could only be achieved with a cover crop system that would have the side-effect of reducing the yield of rain-fed olives. Quantifying the effects of soil management on soil erosion in olive orchards is uncertain because very few experimental results are available. Further research that monitors soil loss in carefully selected long-term experiments at different scales and follows the changes in key soil parameters is urgently required to develop effective erosion control policies.

Notes: Abstract. Rainfall simulation experiments on a laboratory soil flume were conducted to test the hypothesis that the incorporation of slurry into the soil would reduce bacterial transport in overland flow. Presumptive faecal coliform (PFCs) concentrations were higher in the runoff from the surface applied treatment than from the incorporated treatments. The transport of PFCs and organic sediment were strongly correlated, with values of r ranging from 0.72 to 0.91.

Notes: Abstract. Land evaluation is the prediction of land performance over time under specific uses, to guide strategic land use decisions. Modern land evaluation has a 30 year history, yet the results have often been disappointing. Land users and planners have been reported to ignore land evaluations, perhaps reflecting poor quality, low relevance, or poor communication. To test the success of a large land evaluation exercise undertaken as part of micro-catchment project in Santa Catarina State, southern Brazil, we queried agricultural extensionists, considered as the primary land evaluation clients. We used a questionnaire with both structured and open questions, to determine their experiences with, and attitudes to, the current land evaluation method. The soil resource inventory and associated land evaluation had some usefulness, but were not in general used for their intended purpose, namely farm planning. This was mainly because they did not contain crucial information necessary to such planning in the actual context of the farmer taking decisions. The primary deficiencies were identified as:〈list xml:id="l1" style="custom"〉1no estimate of environmental degradation risk;2no financial analysis;3no social analysis of decision-makers' attitudes and preferences;4no risk assessment for weather, yields, profits and market; and5insufficiently-specific alternative land uses.These deficiencies could have been avoided with a demand-driven approach, evaluating and reporting according to the true needs and opportunities of the decision-makers.

Notes: Abstract. The residual value of mineral N fertilizer applied in the spring was investigated in a field experiment where four cereals (winter wheat, winter barley, spring barley and spring oats) had been grown at reduced (0.7N), normal (1N) or high (1.3N) N fertilizer rates for 20 to 28 years. The effect of previous N fertilizer dressing was tested in two succeeding years by replacing the original N rate with five test N rates ranging from 0 to 240 kg N ha−1 for winter cereals and 0 to 200 kg N ha−1 for spring cereals. In the first test year, winter wheat grown on plots previously supplied with the high rate of mineral fertilizer (202 kg N ha−1 yr−1) yielded more grain and straw and had a higher total N uptake than wheat on plots previously supplied with the normal (174 kg N ha−1 yr−1) or reduced (124 kg N ha−1 yr−1) rate. The grain yield response and N uptake was not significantly affected by the N supply in the test year. The winter wheat grown in the second test year was unaffected by the previous N supply. Grain and straw yield response and total N uptake for spring barley, winter barley and oats, were almost identical irrespective of the previous N rate.After 20 to 28 years there were no significant differences in soil C and N (0 to 20 cm) between soil receiving three rates of N fertilizer. Soil from differently fertilized oat plots showed no significant differences in N mineralizing capacity. Nitrate leaching losses from the soils at the three N rates were estimated and the N balances for the 20 to 28 years experimental period calculated. The data indicated a reduction in overall loss of 189 to 466 kg N ha−1 at the normal and high N rates compared with the reduced N rate. We conclude that the N supplying capacity and soil organic matter content of this fertile sandy loam soil under continuous cereal cropping with straw removal was not significantly affected by differences in N fertilizer residues.

Notes: Abstract. A field experiment was undertaken to assess the effectiveness of a combined treatment, involving addition of Aspergillus niger-treated sugar beet (SB) residue in the presence of rock phosphate and mycorrhizal inoculation of seedlings with Pisolithus tinctorius. The aim was to improve the physical, chemical, biochemical and biological properties of a degraded semiarid Mediterranean soil. Short-term effects of such improvements on the establishment of Cistus albidus L. seedlings were evaluated. Eight months after planting, macronutrients (NPK), total carbohydrates, water-soluble C, water-soluble carbohydrates, microbial biomass C and enzyme activities (dehydrogenase, urease, protease, acid phosphatase and β-glucosidase) measured in the rhizosphere soil of C. albidus were increased greatly by addition of fermented SB residue. Soil structural stability improved only with the fermented SB addition (about 79% higher in the amended soils than in the non-amended soils). The mycorrhizal inoculation was the most effective treatment in improving the growth of C. albidus plants, but only slightly improved soil quality. Growth of inoculated plants was about 33% greater than plants grown in the amended soil and about 131% greater than control plants. The combined benefit of mycorrhizal inoculation of seedlings and addition of fermented SB residue to soil on plant growth was similar to that of the treatments applied individually.

Notes: Abstract. Organic agriculture (OA) aims to identify a production regime that causes less environmental problems than conventional agriculture (CA). We examined whether the two systems differ in their susceptibility to soil erosion by water. To account for the large heterogeneity within the rotations practised on different farms, we chose a statistical evaluation which modelled erosion using the USLE method from the cropping statistics for 2056 districts in Bavaria (70 547 km2; 29.8% arable). Physical conditions of erosion were determined in a rectangular grid yielding 13 125 grid-cells of c. 5 km2 each. For validation, erosion was measured in 10 sub-watersheds on two neighbouring OA and CA farms over 8 years (287 erosive events). On average, about 15% less erosion on arable land was predicted for OA than for CA due to the larger area of leys, although OA occupies areas that are susceptible to erosion more often than CA. The same conclusions could be drawn from the validation data. These data also demonstrated that erosion could be reduced considerably below 1 t ha−1 yr−1 with best management practices under both farming systems. In contrast, at the countrywide scale, cropping did not change adequately with site conditions favouring erosion. The need for erosion control seems not to influence crop rotation decisions on erosion-prone sites.

Notes: Abstract. The effects of various fallow management systems and cropping intensities on water infiltration were measured on an Alfisol at Ibadan in southwestern Nigeria. The objective was to determine the influence of the land use systems (a combination of crop–fallow sequences and intercropping types) on soil hydraulic properties obtained by disc permeameter and double-ring infiltration measurements. The experiment was established in 1989 as a split-plot design with four replications. The main plots were natural fallow, planted Pueraria phaseoloides and planted Leucaena leucocephala. The subplots were 1 year of maize/cassava intercrop followed by 3-year fallow (25% cropping intensity), or 2-year fallow (33% cropping intensity), or 1-year fallow (50% cropping intensity), or no fallow period (100% cropping intensity). Water infiltration rates and sorptivities were measured under saturated and unsaturated flow. Irrespective of land use, infiltration rates at the soil surface (121–324 cm h−1) were greater than those measured at 30 cm depth (55–144 cm h−1). This indicated that fewer large pores were present below 30 cm depth compared with 0–30 cm depth. Despite some temporal variation, sorptivities with the highest mean value of 93.5 cm h−½ increased as the cropping intensity decreased, suggesting a more continuous macropore system under less intensive land use systems. This was most likely due to continuous biopores created by perennial vegetation under long fallow systems. Intercropped maize and cassava yields also increased as cropping intensity decreased. The weak relationship between crop yields and hydraulic conductivity/infiltration rates suggests that the rates were not limiting.

Notes: Abstract. Hierarchical crop growth models can contribute significantly to land quality research because the yield gap between the estimated optimum and the actual crop production has been identified as a major land quality indicator. This study describes a three-level, hierarchical crop production model, simulating radiation-thermal, water-limited and natural production potentials of annual crops. Input requirements have been kept low to ensure its applicability to developing regions, which often have access only to limited data. The simplicity of this model also has disadvantages: inconsistencies have been reported when applying this model in semiarid regions, which are characterized by very irregular rainfall patterns. Revision of the water balance, which simulates the availability of water, was required. The modified model was validated using the experimental yields of maize and sunflower in Guquka, a semiarid region of South Africa. Yields were estimated very well, possible improvements to crop production were identified and implications for land-use planning highlighted. Yield gap analysis revealed that radiation, sunshine and temperature are favourable for crop production, but the heavy dependence on rainfall makes the region very vulnerable to drought, with devastating impact on yields. The generally low chemical soil fertility further reduces crop performance.

Notes: Abstract. A potential technique for reducing overwinter leaching from high N containing crop residues is to immobilize the N released during decomposition by co-incorporating materials of a wider C : N ratio. This article describes the use of laboratory incubation experiments to investigate the effects of a wide range of such amendment materials on the mineralization of N from sugar beet and brassica leaf residues in a sandy loam and a silt loam. These materials were of varying quality, with C : N ratio ranging from 15 : 1 to 520 : 1, and cellulose content from 0 to 34%. Amendments were added at a fixed rate of 3.5 mg C g−1 of dry soil, equivalent to around 10 t ha−1 C (to 20 cm depth). The soils were then incubated at 15°C, and net mineral N derived from the leaves was measured at regular intervals over 168 days. Net mineralization of residue N was greatest with molasses (C : N ratio of 18 : 1), whereas paper waste (C : N ratio of 520 : 1) reduced N mineralized by up to 90% compared with a soil-only control. As the concentration of cellulose and lignin in the amendment materials increased, so the amounts of N mineralized decreased, with 62 and 54% of variance in N mineralized explained by cellulose and lignin content, respectively. Reduced levels of mineral N were associated with higher levels of biomass-N. The levels of N2O-N lost from sugar beet residues on day 14 were significantly reduced from 66 to 5 g ha−1 where compactor (cardboard) waste had been mixed into sandy loam, but this effect was not observed in the silt loam. These techniques could lead to greater efficiency of N use in rotations through reduction in N losses, and provide alternative routes for disposal of wastes when the EC Landfill Directive is implemented.

Notes: Abstract. The Olsen method is an indicator of plant-available phosphorus (P). The effect of time and temperature on residual phosphate in soils was measured using the Olsen method in a pot experiment. Four soils were investigated: two from Pakistan and one each from England (calcareous) and Colombia (acidic). Two levels of residual phosphate were developed in each soil after addition of phosphate by incubation at either 10 °C or 45 °C. The amount of phosphate added was based on the P maximum of each soil, calculated using the Langmuir equation. Ryegrass was used as the test crop. The pooled data for the four soils incubated at 10 °C showed good correlation between Olsen P and dry matter yield or P uptake (r2= 0.85 and 0.77, respectively), whereas at 45 °C, each soil had its own relationship and pooled data did not show correlation of Olsen P with dry matter yield or P uptake. When the data at both temperatures were pooled, Olsen P was a good indicator of yield and uptake for the English soil. For the Pakistani soils, Olsen P after 45 °C treatment was an underestimate relative to the 10 °C data and for the Colombian soil it was an overestimate. The reasons for these differences need to be explored further before high temperature incubation can be used to simulate long-term changes in the field.

Notes: Abstract. Nitrous oxide (N2O) from animal excreta in grazed pasture systems makes up a significant component (c. 10%) of New Zealand's total greenhouse gas inventory. We report an effective method to decrease N2O emissions from animal urine patches by treating the soil with the nitrification inhibitor dicyandiamide (DCD), in a simulated grazed dairy pasture system under spray irrigation. The soil was a free-draining Lismore stony silt loam (Udic Haplustept loamy skeletal) and the pasture was a mixture of perennial ryegrass (Lolium perenne) and white clover (Trifolium repens). By treating the soil with DCD, N2O emissions were decreased by 76% following urine application in the autumn, from 26.7 kg N2O-N ha−1 without DCD to an average of 6.4 kg N2O-N ha−1 with DCD over the 6-month experimental period. N2O flux was decreased by 78% following urine application in the spring, from 18 kg N2O-N ha−1 without DCD to 3.9 kg N2O-N ha−1 with the application of DCD over the 3-month period. A single application of DCD immediately after urine was sufficient to effectively mitigate N2O emissions from the urine. The results showed that repeated applications of DCD after urine application, or mixing DCD with urine, offered no advantage over a single application of DCD immediately after urine deposition.

Notes: Abstract. Pig slurry was applied by open-slot injection to experimental plots on a sandy loam site at ADAS Gleadthorpe, Nottinghamshire. Volume and distribution of over-winter drainage were adjusted through the use of rainfall exclusion covers or irrigation. The resultant slurry N leaching over the range of drainage values tested (up to 300 mm) could be satisfactorily described by curve-fitting, using a quadratic or exponential function. Initial simulations of slurry N leaching using the manure nitrogen decision support system manner (v. 3.0) compared poorly with the experimental data, predicting both earlier and greater amounts of nitrate leaching. However, the lack of fit could be explained by consideration of the likely ammonia emissions following slurry injection, the actual volumetric soil moisture capacity at the experimental site and the likely time delay for the nitrification of slurry N following application. Good agreement between modelled and observed data was achieved when these factors were taken into account. The manner model was used to simulate nitrate leaching beyond the range of drainage treatments tested in the experiments and the anticipated sigmoidal relationship between nitrate leaching and drainage was observed. The model was then used to study the effects of manure application timing and the likely impact on nitrate leaching, across the range of rainfall conditions found in Great Britain. Simulations for a range of manure types were undertaken, with manures applied at rates up to the limit of permitted N loading on freely draining sandy loams. Rainfall inputs for these simulations were based on long-term average climatic data. Results are presented for two contrasting manure types, cattle slurry and poultry manure, both of which are subject to controls in Nitrate Vulnerable Zones (NVZs) in Great Britain.

Notes: Abstract. As measures to reduce point source inputs of phosphorus (P) to water have been introduced, the effect of diffuse P has become more evident. Land drains can act as an effective conduit for transfer of sediment and sediment P from agricultural land to surface waters. This article describes the development of a national risk map, identifying areas of agricultural land in England and Wales that are most likely to be prone to such losses. The map is based on data obtained from a variety of sources, including field studies, laboratory-based rainfall simulation experiments and secondary sources. From these studies, eight factors relating to soil HOST class, rainfall, soil moisture deficit, land use and the type and condition of land drains were identified as influential in the process of sediment and sediment P transfer. Each factor was weighted to provide an estimate of risk and the combined total was used to plot a national risk estimate at a resolution of 25 km2. The exercise suggests that large areas of England and Wales may be at risk of subsurface sediment and sediment P transfer from agricultural land to rivers. The scale of the map is insufficient for planning at the farm level, but further work incorporating similar data and principles could make it more applicable to potential end-users on the ground.

Notes: Abstract. Detailed morphological, physical, chemical, mineralogical and micromorphological studies were carried out to identify properties that influence the yield of deep-rooted crops in 29 Vertisols of semiarid central India, since existing land evaluation methods are not adequate to explain the yield of cotton obtained by farmers. The studies indicated that among the soil parameters, CaCO3 in the clay fraction, the exchangeable Ca/Mg ratio, exchangeable sodium percentage (ESP) and saturated hydraulic conductivity (HC) were the yield-influencing factors. The pedogenetic relationships between the semiarid climate, formation of pedogenic calcium carbonate, exchangeable Ca/Mg, ESP and HC have been established. In view of the pedogenetic processes that ultimately impair the drainage of soils, evaluation of Vertisols for deep-rooted crops on the basis of HC alone may help in planning and management of soils, not only in the Indian semiarid tropics, but also in similar climatic areas elsewhere.

Notes: Abstract. Water retention properties of 219 horizons were measured in Cambisols, Luvisols and Fluvisols, mainly from the Paris basin. We derived class pedotransfer functions (class PTFs) based on texture alone and in a second stage class PTFs based on classes combining texture and clod bulk density. The performance of these two types of PTFs were discussed at −330 and −15000 hPa water potential on an independent set of 221 horizons. Results showed that PTFs based on sets grouped by texture and clod bulk density provide estimates with an accuracy that is (i) greater than with class PTFs based on texture alone, and (ii) similar to the estimation accuracy recorded with continuous PTFs. As a consequence, the lack of interest in class PTFs should be reconsidered to bridge the gap between the available basic soil data and hydraulic properties which are generally missing, particularly when pertinent soil characteristics can be derived from the data available in soil databases. The two types of class PTFs providing gravimetric water contents at seven water potentials ranging from −10 to −15 000 hPa were converted to volumetric water content using the soil bulk density. Finally, the parameters of van Genuchten's water retention curve model were computed for every class PTF.

Notes: Abstract. Soils can be used as a biospheric sink for carbon under Article 3.4 of the Kyoto Protocol and parties are able to use agricultural soil carbon sinks to contribute towards carbon emission reduction targets. This should be done ‘taking into account uncertainties, transparency in reporting, and verifiability’. Models are often tested against data sets of long-term changes in soil organic carbon (SOC), but most data sets have only mean SOC values available at each sample date, with no estimates of error about the mean. We show that when using data sets that do not include estimates of error about the mean, it is not possible to reduce the error (root mean squared error) between modelled and measured values below 6.8–8.5%, even with site-specific model calibration. Equivalent errors for model runs using regional default input values are 12–34%. Using error as an indicator of the certainty that can be attached to model projections, we show that a significant reduction in uncertainty is needed for Kyoto accounting. Uncertainties for modelling during the first Kyoto Commitment Period could be reduced by better replication of soil measurements at benchmark sites. This would allow model error to be separated from measurement error, which would allow more comprehensive model testing and, ultimately, more certainty to be attached to model predictions.

Notes: Abstract. Artificial urine containing 20.2 g N per patch of 0.2 m2 was applied in May and September to permanent grassland swards of a long-term experiment in the western uplands of Germany (location Rengen/Eifel), which were fertilized with 0, 120, 240, 360 kg N ha−1 yr−1 given as calcium ammonium nitrate. The effect on N2O fluxes measured regularly during a 357-day period with the closed-chamber technique were as follows. (1) N2O emission varied widely among the fertilized control areas without urine, and when a threshold water-filled pore space 〉60% was exceeded, the greater the topsoil nitrate content the greater the flux from the individual urine patches on the fertilized swards. (2) After urine application in May, 1.4–4.2% of the applied urine-N was lost as N2O from the fertilized swards; and after urine application in September, 0.3–0.9% of the applied urine-N was lost. The primary influence on N2O flux from urine patches was the date of simulated grazing, N-fertilization rate being a secondary influence. (3) The large differences in N2O emissions between unfertilized and fertilized swards after May-applied urine contrasted with only small differences after urine applied in September, indicating an interaction between time of urine application and N-fertilizer rate. (4) The estimated annual N2O emissions were in the range 0.6–1.6 kg N2O-N per livestock unit, or 1.4, 3.6, 4.1 and 5.1 kg N2O-N ha−1 from the 0–360 kg ha−1 of fertilizer-N. The study demonstrated that date of grazing and N-fertilizer application could influence the N2O emission from urine patches to such an extent that both factors should be considered in detailed large-scale estimations of N2O fluxes from grazed grassland.