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  • Articles  (55,623)
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  • 2020-2022
  • 2000-2004  (54,030)
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  • 1
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    International journal of consumer studies 28 (2004), S. 0 
    ISSN: 1470-6431
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Economics
    Notes: The aim of this paper is to offer regional evidence from Spain on alcohol abuse among adolescents. Specifically, we identify the determinants of the decision to abuse alcohol with respect to the five most important regions of Spain, as well as for the country as a whole. To this end, we estimate Probit specifications using data drawn from the Spanish Surveys on Drug Use in the School Population corresponding to 1994, 1996 and 1998. The results first reveal patterns that are qualitatively similar, but quantitatively different. Similarly, it would appear that economic policies aimed at reducing the access of adolescents to alcohol may have a positive effect on reducing abuse. Finally, the results suggest that encouragement be given to healthy habits among young people, as well as to the fight against education failure and the launching of information campaigns that accurately portray the current lifestyle of adolescents.
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  • 2
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    International journal of consumer studies 28 (2004), S. 0 
    ISSN: 1470-6431
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Economics
    Notes: The aim of this study was to determine the knowledge and acceptability of soymilk (defined as consumption pattern/usage and taste) by adult consumers, residing in different socio-economic areas (low vs. high) in Cape Town. The study population of 214 participants were selected using convenience sampling. A questionnaire was developed in order to obtain demographic data (four items); basic general knowledge of soymilk (four items); and acceptability of the tested products (consumption patterns and taste) (eight items). There was a significant difference between the two groups (P = 0.000) regarding basic knowledge of soymilk, with significantly more in the high socio-economic area (HSEA) having a score of at least 75%. Gender (P = 0.082) and age (P = 0.122) did not have a significant impact on the consumption patterns of soymilk. There was no significant difference between the two groups with respect to current usage (P = 0.228) and frequency of use (P = 0.213) of soymilk. However, a significantly smaller group (P = 0.000) of participants in the low socio-economic area had previously tasted soymilk compared with those in the HSEA (16.7% vs. 41.5%; P = 0.000). In conclusion, socio-economic status appeared to be associated with knowledge of soymilk. No significant differences with regard to gender, age or current usage in the two groups studied were noted.
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  • 3
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    International journal of consumer studies 28 (2004), S. 0 
    ISSN: 1470-6431
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Economics
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  • 4
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 87 (2004), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The changes in porosity and elastic moduli of YSZ-containing nickel-based anode materials for solid oxide fuel cells were studied as a function of the fraction of reduced NiO. Anode samples were reduced in a gas mixture of 4% hydrogen and 96% argon for different periods of time at 800°C and their Young's and shear moduli were determined afterward at room temperature using resonant ultrasound spectroscopy and impulse excitation. It was found that the magnitude of Young's and shear moduli decreased significantly with increasing fraction of reduced NiO and that the magnitude of the elastic moduli of a fully reduced Ni–YSZ anode was ∼45% lower than that of unreduced NiO–YSZ. Because the elastic moduli of NiO are close to those of Ni, the observed decrease in the magnitude of the elastic moduli was found to be caused mainly by the significant increase in the porosity of the sample as a result of NiO reduction. Expressions are presented for the amount of porosity and the magnitude of the elastic moduli as a function of the fraction of reduced NiO.
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  • 5
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 87 (2004), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Two- and three-dimensional SiCr/SiC composites have been prepared starting from Tyranno SA(tm) fiber preforms. Preform densification has been performed by a modified preceramic polymer impregnation and pyrolysis (PIP) process consisting of filling the preform large interbundle voids with SiC powder before the PIP process. This step was accomplished by low-pressure infiltration of a SiC powder dilute slurry through the preform thickness. Specimens were further processed with polymer impregnation and pyrolysis to determine the effects on structural, thermal, and mechanical properties of the obtained composites. High-temperature pyrolysis treatment, which promoted polymer derived SiC matrix crystallization, markedly increased thermal diffusivity.
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  • 6
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 87 (2004), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Carbon is commonly added to sulfate-fined silicate-glass batches to enhance the fining process. Reactions between carbon and Na2SO4 modify the SOx emissions from Na2SO4 decomposition. Fourier-transform infrared (FTIR) spectrometry is used to analyze the emission of air pollutants from the isothermal decomposition of Na2SO4 + C undertaken using thermogravimetric analysis (TGA). The FTIR spectrometer is calibrated using standard gas mixtures containing CO, CO2, SO2, NO, and NO2. The collected spectra are quantified using the classical least-squares (CLS) approximation. The TGA-FTIR system provides SOx, and COx, concentrations versus time data from the isothermal decomposition of Na2SO4, in the presence of a carbon black. Mass spectrometry (MS) complements FTIR by being able to detect SO(g).
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  • 7
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 87 (2004), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Different ratios of the precursor phases of SrFeO3–x (SFO) and SrMoO4 (SMO) were used to prepare Sr2FeMoO6 (SFMO) by a solid-state reaction. X-ray diffraction was used to identify the phases. A residual SMO was observed to exist in the sample with an SFO/SMO ratio of 0.9:1. The sample with a residual SMO phase had higher resistivity, lower magnetization, but higher low-field magnetoresistance (LFMR). High-resolution transmission electron microscopy was used to identify the compositions and phases. Nanometer-sized amorphous-like clusters of SMO phase were located inside the grains rather than at grain boundaries; however, some boundaries were rich in the strontium ion. The possible mechanisms for the conduction and the increase of LFMR of SFMO are discussed.
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  • 8
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 87 (2004), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Submicro- and nano-sized liquid-phase-sintered SiC ceramics were mechanically tested by nanoindentation in the peak load range 5–400 mN. The submicro-sized sample showed a marked indentation size effect which the nano-sized samples did not exhibit. The relevance of indentation depth with respect to the microstructural scale has been outlined. In the investigated grain-size range, the hardness dependence on the grain size could be described by a load-dependent inverse Hall–Petch relation. Young's modulus was less microstructure- and load-dependent. Because of the very fine microstructure, the nano-sized SiC materials gave lower elastic values than the submicro-sized SiC ceramic.
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  • 9
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 87 (2004), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Samples of composition Ba1−xLaxTi1−x/4O3, x= 0, 0.003, 0.03, and 0.10, were prepared by an alkoxide sol–gel route with final firing of ceramics at 1100°C, 2 h in air. All samples showed bulk insulating behavior with no evidence of semiconductivity caused by either direct donor doping or oxygen loss.
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  • 10
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 87 (2004), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 11
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 87 (2004), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: We have studied the rheological property evolution and hydration behavior of white and ordinary portland cement (type I) pastes and concentrated cement–polyelectrolyte suspensions. Cement composition had a marked effect on the elastic property evolution (G′(t)) and hydration behavior of these suspensions in the presence of poly(acrylic acid)/poly(ethylene oxide) copolymer (PAA/PEO), even though their affinity to adsorb such species was nearly identical. Both white and ordinary portland cement pastes exhibited G′0 values of ∼104 Pa and fully reversible G′(t) behavior until the onset of the acceleratory period (t= 2 h), where the pastes stiffened irreversibly. In contrast, cement–PAA/PEO suspensions exhibited G′0 values of ∼1 Pa and G′(t) behavior comprised of both reversible and irreversible features. Interestingly, ordinary portland cement–PAA/PEO suspensions experienced a gel-to-fluid transition on high shear mixing at short hydration times (〈1 h), and the particle network did not rebuild until ∼24 h of hydration. In sharp contrast, white portland cement–PAA/PEO suspensions remained weakly gelled throughout the initial stage of hydration even after high shear mixing. At longer hydration times (〉1 h), both cement–PAA/PEO suspensions exhibited G′i(t) ∼ exp(t/τc) with τc values of 5.6 and 1.3 h for ordinary and white portland cement, respectively. Our observations suggest that hydration phenomena impact interparticle forces during early stage hydration and, ultimately, lead to initial setting through the formation of solid bridges at the contact points between particles within the gelled network.
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  • 12
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 87 (2004), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A new ceramic freeze-casting technique capable of manufacturing near room temperature with a sublimable vehicle was accomplished. Fluid-concentrated slurries of Al2O3 powder in molten camphene (C10H16) were prepared at 55°C. These slurries were quickly solidified (frozen) at room temperature to yield rigid solid green bodies, followed by frozen camphene removal by sublimation (freeze-drying) with negligible shrinkage. Sintering without any special binder burnout process yielded sintered bodies with over 98% theoretical density. The proposed advantages include (1) elimination of extremely cold temperatures, (2) elimination of troublesome binder burnout process, and (3) fast manufacturing cycle due to quick solidification.
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  • 13
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 87 (2004), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Dense composites in the Ti-B-N system have been produced by reactive hot pressing of titanium and BN powders. The effect of the addition of a small amount of nickel (1–3 wt%) on the reaction kinetics and densification of TiN–TiB2 (40 vol%) composite has been studied. Composites of ∼99% of theoretical density have been produced at 1600°C under 40 MPa for 30 min with 1% nickel. The hardness and fracture toughness of these composites are 24.5 ± 0.97 GPa and 6.53 ± 0.27 MPa·m1/2, respectively. The microstructural studies on samples produced at lower temperatures indicate the formation of a transient liquid phase, which enhances the kinetics of the reaction and densification of the composite.
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  • 14
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 87 (2004), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: This paper presents new findings on ultrasonic spray pyrolysis of zirconium hydroxyl acetate precursor drops whose sizes were precisely measured using laser light diffraction technique. Precursor concentration plays a predominant role in determination of product particle size. At 0.01 wt% precursor concentration, conventional spray pyrolysis at 750°C using precursor drops 5–8 μm in diameter, generated by an ultrasonic nebulizer at 2.66 MHz, yielded uniform spherical yttria-stabilized zirconia (YSZ) particles 73 nm in diameter measured by scanning electron microscopy. The YSZ particle diameters were much smaller than those predicted by the one-particle-per-drop mechanism. Under similar reaction conditions, the high-throughput ultrasound-modulated two-fluid (UMTF) spray pyrolysis of larger precursor drops (28-μm peak diameter) also yielded spherical dense particles; they were significantly smaller in size than those produced by the low-throughput conventional ultrasonic spray pyrolysis of smaller drops (6.8-μm peak diameter).
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  • 15
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 87 (2004), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Thermoelectric elements consisting of the layered polycrystalline materials of Al-doped ZnO and NaCo2O4 were prepared using the pulse electric-current sintering (PECS) method at 900°C for 3 min. Direct contact between the polycrystalline Al-doped ZnO and the NaCo2O4 was obtained in a single-step process for the stacked powders. The electrical conductivities of the polycrystalline materials prepared by PECS were higher than those of materials prepared by conventional sintering, despite their porous structure. The thermoelectric voltage of the 1-mol%-Al-doped ZnO and NaCo2O4 polycrystalline element (measuring ∼6 mm × 3 mm × 15 mm) was 83 mV at dT= 500 K, when the junction of the elements was at 800°C.
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  • 16
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    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 87 (2004), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Pb(Zr,Ti)O3–Pb(Mn1/3 Nb2/3)O3 (PZT–PMnN) system has been studied for high-power piezoelectric applications. This study investigates this system to find out the composition with high-power density piezoelectric characteristics and low tem-perature coefficient of resonance frequency (TCF). It was found that the composition 0.9PZT–0.1PMnN (Zr/Ti = 0.51/0.49) modified with 6 mol% Sr exhibits a TCF of −8 ppm/°C (−20 to +80°C). Further, the dielectric and piezoelectric properties of this composition are as follows: kp= 0.53; Qm= 800; d33= 274; ε33/ε0= 1290 and tan δ=1.1%, which shows the suitability of this composition for ultrasonic devices used under fluctuating thermal environment.
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  • 17
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    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 87 (2004), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Beam bending is an excellent method for measuring low permeabilities (≤10−18 m2) in homogeneous materials, because it is fast, requires no high pressure, and provides a concurrent measurement of the modulus of the material. The method was previously analyzed and substantiated for cylindrical or square beams. Recently, the analysis was extended to include isotropic and transversely isotropic rectangular beams. In this paper, the analysis is applied to measurements performed on cement paste, and it is shown that the solution for isotropic rectangular beams accounts for changes in the hydrodynamic behavior caused by changing the aspect ratio of the sample. The permeability and elastic modulus results are verified through comparison to previous measurements on cylindrical beams.
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  • 18
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The deformation behavior of boron- and carbon-doped β-silicon carbide (B,C-SiC) with an average grain size of 260 ± 18 nm containing 1 wt% boron was investigated by compression testing at elevated temperatures. Extensive grain growth during deformation was observed. The stress–strain curves were compensated for grain growth by assuming power-law type of dependence on grain size and strain rate. The stress exponent n was ∼1.3 and the grain size exponent p was ∼2.7 at temperatures ranging from 1593° to 1758°C. The apparent activation energy of deformation Qd was ∼760 kJ/mol, which was lower than the activation energy for lattice diffusion of silicon and carbon in SiC and higher than that for grain-boundary diffusion of carbon in SiC. These results suggest that the deformation mechanism of the fine-grained B,C-SiC is grain-boundary sliding accommodated by the grain-boundary diffusion.
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  • 19
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Chromium-containing stainless steel (SS) is a prospective material for use as an interconnect in solid oxide fuel cells (SOFCs). However, during operations at high temperatures, the growth of oxide scales causes the performance of the interconnect and SOFC as a whole to deteriorate. The coating of SS 446 with a conducting perovskite is a potential method of slowing the growth of oxide scale and, therefore, improving overall SOFC performance. In the present research, the structural characterization of a pure LaCrO3 thin film on the SS 446 substrates has been performed as a model material that can be used as a barrier coating for the metallic interconnect. The deposition of an amorphous La-Cr-O thin film on SS 446 was performed using radio-frequency (rf) magnetron sputtering. The deposited amorphous film was annealed in air to form the desired perovskite phase. The film underwent an amorphous to LaCrO4 phase transition during annealing at 500°C with further transformation to LaCrO3 orthorhombic phase during annealing at 700°C. A self-organized dendritic structure was reported as a result of the perovskite-phase formation. Although formation of various oxides, such as Fe2O3 and Fe3O4, was observed during the annealing of uncoated SS 446 in air, the coating of SS 446 surface with LaCrO3 film prevented formation of various oxide phases at the interconnect surface. The structural characterization of the films and SS 446 surfaces was accomplished using scanning electron microscopy with energy-dispersive X-ray analysis, X-ray diffractometry, micro-Raman spectroscopy, and nanoindentation.
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  • 20
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    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 87 (2004), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The density, surface tension, and viscosity of the melts from the PbO-B2O3-SiO2 system have been measured at temperatures in the range 1073–1473 K. The effect of composition on these properties was also investigated. The density of the melt was found to increase linearly with increasing PbO content. Molar volume was derived from the density data, and its deviation from the additivity of partial molar volumes was calculated. These deviations in molar volume from those obtained from additivity rules have been used along with the ratio of various coordination numbers of boron (as reported by Bray) to discuss the structure of the melts. The surface tension was found to decrease with decreasing SiO2/B2O3 ratio, and to increase in the range of the PbO content between 30 and 60 mol%, showing a maximum at ∼60 mol% PbO, and then decreased with further additions. This result suggested that the surface tension would be affected primarily by the B2O3 content in the range of the PbO content between 30–60 mol%, and mainly by the PbO content in the range of the PbO content 〉60 mol%, respectively. The viscosity of the melt was found to decrease linearly with increasing PbO content. The results obtained indicate that the increase in viscosity with B2O3 was half that of SiO2 (on a molar basis), and an empirical equation has been proposed for the viscosity as a function of mole fraction.
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  • 21
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    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 87 (2004), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Core/shell structures have been prepared via a mechanofusion system by employing several kinds of spherical polymers as a core material and Al2O3 powder or a mixture of Al2O3 and SiO2 powders as a shell material. The effect of the kind of core polymers on the quality of the resulting hollow alumina microspheres has been discussed on the basis of the thermal decomposition behavior of spherical polymers used as a core material. A large fraction of hollow alumina microspheres reflecting the shape and the particle size distribution of the core polymer could be fabricated after sintering at 1600°3C for 3 h, when highly cross-linked poly(methyl methacrylate) (PMMA) microspheres with a gel fraction of 99.03% were used as a core polymer, and abrupt firing at temperatures higher than 500°3C was adopted to remove the PMMA microspheres. The addition of 5 mass% SiO2 to the Al2O3 shell layer was found to be useful for maintaining the spherical shell structure during the firing process and for fabricating a large fraction of hollow alumina microspheres after the sintering.
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  • 22
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    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 87 (2004), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Well-defined and stoichiometric spherical particles of BaTiO3 of narrow size distribution were produced at 82° and 92°3C by precipitation from chloride solutions in a strong alkaline environment. The size of the particles can be tailored in the range from ≅103 to 70–80 nm by increasing the barium concentration from ≅0.07 to 0.7 mol/L. The particles are composed of tight aggregates resulting from the assembly of several nanocrystals. The size of the nanocrystals decreases from 200–300 to 30–40 nm by increasing reactant concentration. At low barium concentration (≤0.07 mol/L at 82°3C, ≤0.06 mol/L at 92°3C), formation of BaTiO3 is strongly slowed down and nonstoichiometric, Ti-rich powders are produced. Under these conditions, the particles have the tendency to develop a dendritic-like morphology.
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  • 23
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    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 87 (2004), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Crystals of δ-Y2Si2O7 (space group P121/c1) were examined using high-temperature powder X-ray diffractometry to determine their unit-cell dimensions from 296 to 1473 K. The lattice deformation induced by thermal expansion was investigated using matrix algebra analysis to determine the directions and magnitudes of the principal distortions (Λi, i= 1,2, and 3). The directions of Λ1 and Λ3 were defined by the acute angle Λ1c, which linearly decreased from 5(2)° to —5.5(3)° with increased temperature from 504 to 1473 K. The Λ2-axis invariably coincided with the crystallographic b-axis. The magnitudes of Λ1 and Λ2 steadily increased to, respectively, 1.0061(1) and 1.0068(1) during heating to 1473 K, while Λ3 remained almost constant for the entire temperature range. The mean principal distortion, Λm (= (Λ1+Λ2+Λ3)/3), steadily increased to 1.0044(1) with increased temperature to 1473 K. The coefficient of mean linear thermal expansion (α) was derived from the mean principal strain (Λm - 1) as α= (Λm - 1)/ΔT. The temperature dependence was determined to be α= 2.03 times 103+ 1.36(T - 296) (10-9 K-1). Provided that the rule-of-mixtures holds for the Y2Si2O7/Y2SiO5 composites as protective coating on SiC substrates, the volume fractions of 0.72-0.77 (70–75 mass%) would be necessary for the Y2Si2O7 component to match the α-values of both materials.
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  • 24
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    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 87 (2004), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Microcellular silicon oxycarbide open cell ceramic foams were fabricated from a silicone resin. Microcellular foams, with a cell size ranging from ∼1–80 μm, were fabricated using poly(methyl methacrylate) microbeads as sacrificial templates. The compression strength of the foams decreased with increasing cell size.
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  • 25
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    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 87 (2004), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Electroconductive zirconia-toughened mullite (TiN/ZTM) intragranular nanocomposite was fabricated by hot-pressing a powder mixture of nano-sized TiN, ZrO2(2Y), and mullite gel. The material showed a good sinterability and could be highly densified at a low temperature of 1300°3C. Sintering temperature strongly influenced the microstructure and electrical resistivity of the material. The electrical resistivity increased monotonously from 20 Ω-cm to 1.5 times 106°3Cm, as the sintering temperature was increased from 1300° to 1500°3C. TEM results indicated that such a phenomenon could be ascribed to the changes in the microstructure of the material, which led to a decrease in the connectivity of the TiN network in the sample as the sintering temperature was increased.
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    Journal of the American Ceramic Society 87 (2004), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Effects of fluids on material removal rate, chipping damage, and surface roughness in the simulated clinical-dental machining of a dental-type glass ceramic were investigated. Significant differences in removal rate were obtained among the fluids investigated, but only a 4 wt% boric acid solution gave a higher removal rate than conventionally used water. Chipping damage was substantially lower for the boric acid and an oil-emulsion coolant compared with other fluids tested. Surface roughness was independent of the fluids used. The results indicate that improvement can be achieved in both material removal rate and machining damage by the appropriate selection of coolant chemistry.
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    Journal of the American Ceramic Society 87 (2004), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: This paper reviews the structures and properties of 10 binary, ternary, and quaternary crystals within the equilibrium phase diagram of the SiO2–Y2O3–Si3N4 system. They are binary compounds SiO2, Y2O3, Si3N4; ternary compounds Si2N2O, Y2Si2O7, and YSi2O5; and quaternary crystals Y2Si3N4O3 (M-melilite), Y4Si2O7N2, (N-YAM), YSiO2N (wallastonite), and Y10(SiO4)6N2 (N-apatite, N-APT). Although the binary compounds are well-known and extensively studied, the ternary and the quaternary crystals are not. Most of the ternary and the quaternary crystals simply have been referenced as secondary phases in the processing of nitrogen ceramics. Their crystal structures are complex and not precisely determined. In the quaternary crystals, there exists O/N disorder in that the exact atomic positions of the anions cannot be uniquely determined. It is envisioned that a variety of cation–anion bonding configurations exist in these complex crystals. The electronic structure and bonding in these crystals are, therefore, of great interest and are indispensable for a fundamental understanding of structural ceramics. We have used ab initio methods to study the structure and bonding properties of these 10 crystals. For crystals with unknown or incomplete structural information, we use an accurate total energy relaxation scheme to obtain the most likely atomic positions. Based on the theoretically modeled structures, the electronic structure and bonding in these crystals are investigated and related to various local cation–anion bonding configurations. These results are presented in the form of atom-resolved partial density of states, Mulliken effective charges, and bond order values. It is shown that Y–O and Y–N bonding are not negligible and should be a part of the discussion of the overall bonding schemes in these crystals. Spectroscopic properties in the form of complex, frequency-dependent dielectric functions, X-ray absorption near-edge structure (XANES), and the electron energy-loss near-edge structure (ELNES) spectra in these crystals also are calculated and compared. These results are discussed in the context of specific bonding configurations between cations (silicon and yttrium) and anions (oxygen and nitrogen) and their implications on intergranular thin films in polycrystalline Si3N4 containing rare-earth elements.
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    Journal of the American Ceramic Society 87 (2004), S. 0 
    ISSN: 1551-2916
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Simultaneous synthesis and sintering of hexagonal α-Ti1−x-Alx(N) (0 ≤x≤ 0.08) solid solutions, which contain a small amount of nitrogen, have been performed by a self-propagating high-temperature combustion method under a nitrogen pressure of 4 MPa. Dense materials (∼99% of theoretical) prepared directly from a mixture of elemental (Ti and Al) powders reveal homogeneous microstructure composed of fine grains (12–16 μm). α-Ti1−xAlx(N) (x= 0.02; Ti0.98Al0.02N0.26) exhibits a three-point bending strength σb of 390 MPa, a Vickers hardness Hv of 9.24 GPa, and a fracture toughness KIC of 4.89 MPa·m1/2; their mechanical properties are much improved by doping Al into α-Ti(N), in comparison with those (σb= 245 MPa, Hv= 9.02 GPa, and KIC= 3.77 MPa·m1/2) of α-Ti(N) fabricated under the same conditions.
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    Journal of the American Ceramic Society 87 (2004), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Electrophoretic deposition has been used to synthesize nickel–alumina, functionally graded materials from NiO and alumina suspensions in ethanol. Suspension stability and the kinetics of deposition were studied to determine optimum conditions. Deposition starts with an alumina suspension into which a stream of NiO suspension is injected at various flow rates to obtain the desired profiles. The latter were controlled by varying the deposition current density and component flow rate. The green bodies obtained were sintered in Ar/H2 atmosphere to reduce the NiO to nickel. Various gradation profiles were obtained illustrating the facility of EPD to synthesize continuously graded materials. NiO was used as the precursor for nickel to alleviate settling and rough columnar deposit problems.
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    Fiscal studies 25 (2004), S. 0 
    ISSN: 1475-5890
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Economics
    Notes: This paper reviews the normative welfare economic literature on income-based targeting and contrasts its assumptions with those underlying current policy discourse. One current policy debate concerns the potential role for Earned Income Tax Credit (EITC) income tests. In general, economic models within the standard (for economists) ‘welfarist’ approach provide little support for such policies. However, much policy discourse is explicitly non-welfarist, placing a negative social value on the leisure or home production of the poor. From this perspective, EITC or workfare-type programmes may be socially optimal. The normative foundations of this policy discourse, however, have yet to be subject to the rigorous analysis that underlies the welfarist approach.
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    Fiscal studies 25 (2004), S. 0 
    ISSN: 1475-5890
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    Topics: Economics
    Notes: This paper examines the application of price-cap regulation to the UK airport industry, with particular reference to the expansion of London-Stansted. This expansion is relevant to the debate concerning investment incentives inherent in the RPI–X approach and whether the UK style of regulation encourages the ‘sweating of assets’ at the expense of new investment. Stansted's expansion also suggests a willingness of the authorities to accept the leveraging of market power in pursuit of perceived public-interest goals; it provides an insight into the behaviour of economic agents when capital market disciplines are mute; and it illustrates some unintended consequences that can follow from market intervention.
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    Fiscal studies 25 (2004), S. 0 
    ISSN: 1475-5890
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    Topics: Economics
    Notes: This paper addresses two sets of issues relevant to current and prospective future E(M)U members: the consequences of the Stability & Growth Pact for fiscal-financial sustainability and macroeconomic stability, and some risks associated with operational independence of the central bank. To be effective as a lender of last resort or to stabilise demand when short nominal interest rates are close to their zero lower bound, the central bank must coordinate and cooperate with the fiscal authorities. Central bank independence is unlikely to survive if such coordination and cooperation are not forthcoming.
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    Fiscal studies 25 (2004), S. 0 
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    Topics: Economics
    Notes: The literature on public sector discounting has brought important insights, but there remain wide differences on some fundamental issues. This paper reviews the main conflicts and the reasons underlying them. It suggests practical procedures for discounting in government which are consistent with most of the literature but not with the ‘efficient market’ thesis that financial markets provide all the information needed to define these procedures.
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    Fiscal studies 25 (2004), S. 0 
    ISSN: 1475-5890
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    Topics: Economics
    Notes: Scotland has much higher public expenditure per head than England, but little work has been done to compare Scottish and English needs. We compare their needs for school education, and we show that if the Formula Spending Share approach that is used to estimate English local authorities' needs were applied in Scotland, then Scotland would be found to need about 3 per cent more per pupil than England; however, this English approach may slightly underestimate Scotland's needs. We also show that the Grant Aided Expenditure approach that is actually used to estimate Scottish local authorities' needs may be about 7 per cent more generous than the English approach. Finally, we find that the correlation between the relative education needs for different authorities as assessed by the Scottish approach and their relative needs as assessed by the English approach is only modest; this implies that there may be serious shortcomings in at least one approach.
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    Topics: Economics
    Notes: Non-take-up of means-tested benefits among pensioners is of long-standing concern. It has assumed increased importance from October 2003 with the introduction of the new means-tested pension credit to which about half of pensioners are expected to be entitled. We use Family Resources Survey data from April 1997 to March 2000 to investigate patterns of pensioner take-up of income support (IS) (subsequently renamed the minimum income guarantee and now subsumed in pension credit), housing benefit (HB) and council tax benefit (CTB). Although 36 per cent of pensioners in our sample failed to claim their entitlements to at least one of these benefits, only 16 per cent failed to claim amounts worth more than 10 per cent of their disposable income. Generally, take-up is high where entitlement is high. But there are exceptions which may reflect the claims process and/or a greater degree of social stigma associated with IS than with HB or CTB.
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    Fiscal studies 25 (2004), S. 0 
    ISSN: 1475-5890
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    Topics: Economics
    Notes: Between 1992 and 1995, the Italian pension system was deeply reformed, and it is now moving from an earnings-related to a contribution-based scheme. The pre-1992 system was generous and redistributive; however, often redistribution operated from the poor to the rich, notably because the benefit formula was based on the last years of earnings, thus benefiting workers with steep earnings profiles. The new contribution-based scheme may enhance equity by removing (some of) the inequities implicit in the previous system.Simulations calibrated on Italian male employees show that the contribution-based scheme reduces inequality among all groups considered, with the exception of college graduates employed in the private sector. When taking into account the average level of the benefit as well as its distribution, the analysis shows mixed results depending on the worker's number of years of contribution and on their retirement age, as well as on the steepness of their earnings profile.
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    Topics: Economics
    Notes: We analyse a puzzle in the UK corporation tax: by both historic and international standards, corporation tax revenues have been high while the statutory rate has been reduced. We consider explanations based on changes in the tax law and in economic factors. Changes in the tax law, such as base-broadening measures through reductions in capital allowances, can explain only part of the puzzle. Among the economic explanations, an increase in the size of the corporate sector, mainly caused by expansion of the service sector and improvements in profitability of the financial sector, seems the most likely. To the extent that higher profits, particularly financial sector profits, may have led to high revenues, there are doubts as to whether revenues will continue to be so strong.
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    Fiscal studies 25 (2004), S. 0 
    ISSN: 1475-5890
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    Topics: Economics
    Notes: During the last decade, the Italian system of intergovernmental fiscal relations has been involved in a radical process of reform that is still under way. The reform has assigned Regions new taxing powers and has introduced a new system of interregional transfers. This paper provides a review of the recent reform and offers some tentative answers to the issues still open, relying on a series of simulations and projections. A number of conclusions have been reached. First, when the long-run performance of the new financing systems is investigated, regional resources may no longer be adequate to meet future health needs. Second, the incentives for active tax policies seem either to prove too weak or even to cause undesirable results. Finally, the complete devolution to the Regions of some significant public expenditure functions risks strengthening the polarisation of financial flows between the Northern and Southern Regions in the long run.
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    Geophysical prospecting 52 (2004), S. 0 
    ISSN: 1365-2478
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences , Physics
    Notes: The total mean-square error (MSE) of the estimated model, defined as the sum of the standard model variance and the bias variance, is used to define the truncation level of the singular-value decomposition to give a reasonable balance between model resolution and model variance. This balance is determined largely by the data and no further assumptions are necessary except that the bias terms are estimated sufficiently well. This principle has been tested on the 1D magnetotelluric inverse problem with special emphasis on high-frequency radio magnetotelluric (RMT) data. Simulations clearly demonstrate that the method provides a good balance between resolution and variance. Starting from a homogeneous half-space, the best solution is sought for a fixed set of singular values. The model variance is estimated from the sum of the inverse eigenvalues squared, up to a certain threshold, and the bias variance is estimated from the model projections on the remaining eigenvectors. By varying the threshold, the minimum of the MSE is found for an increasing number of fixed singular values until the number of active singular values becomes greater than or equal to the estimated number. As a side-effect, the depth of penetration of a given set of measurements can be estimated very efficiently by simply noting at which depth the final model deviates little from the starting homogeneous half-space model. A suite of synthetic data is inverted and an example of inversion of one site is shown to illustrate how the truncation is carried out as the non-linear inversion process proceeds. A field example with a profile across a plume of contaminated groundwater in the Netherlands shows good agreement with the electrical resistivity obtained in a nearby borehole.
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    Geophysical prospecting 52 (2004), S. 0 
    ISSN: 1365-2478
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    Topics: Geosciences , Physics
    Notes: Faithful recording of the elastic wavefield at the sea-bed is required for quantitative applications of 4C seismic. The accuracy of the recorded vectorial wavefield depends on factors that vary from deployment to deployment. This paper focuses on one such factor: the interaction of the acquisition system with the sea-bed, which is referred to here as coupling. We show, using multi-azimuth data recorded with a cable-based sea-bed acquisition system, whose sensor housing is cylindrically shaped and with the in-line geophone fixed to the cable, that coupling depends on the propagation direction and wave type (P- or S-waves) of the incident wavefield. We show that coupling is more critical for S-waves than for P-waves. Detection of inconsistent coupling using both P- and S-waves is therefore mandatory. A data-driven processing method to compensate for the frequency-dependent coupling response of the cross-line geophone is derived. Its application to field data verifies the effectiveness of the method.
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    Geophysical prospecting 52 (2004), S. 0 
    ISSN: 1365-2478
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences , Physics
    Notes: The combined use of time-lapse PP and PS seismic data is analysed for optimal discrimination between pressure and saturation changes. The theory is based on a combination of the well-known Gassmann model and the geomechanical grain model derived by Hertz and Mindlin. A key parameter in the discrimination process is the opening angle between curves representing constant changes in PP and PS reflectivity plotted against pressure and saturation changes. The optimal discrimination angle in the pressure–saturation space is 90° and this is used to determine optimal offset ranges for both PP and PS data. For typical production scenarios, we find an optimal offset range corresponding to an angle of incidence of 25–30°, for both PP and PS data. For gas we find slightly different results. This means that conventional survey parameters used in marine multicomponent acquisition should be sufficient for the purpose of estimating pressure and fluid saturation changes during production.
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    Geophysical prospecting 52 (2004), S. 0 
    ISSN: 1365-2478
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    Topics: Geosciences , Physics
    Notes: Cross-hole anisotropic electrical and seismic tomograms of fractured metamorphic rock have been obtained at a test site where extensive hydrological data were available. A strong correlation between electrical resistivity anisotropy and seismic compressional-wave velocity anisotropy has been observed. Analysis of core samples from the site reveal that the shale-rich rocks have fabric-related average velocity anisotropy of between 10% and 30%. The cross-hole seismic data are consistent with these values, indicating that observed anisotropy might be principally due to the inherent rock fabric rather than to the aligned sets of open fractures. One region with velocity anisotropy greater than 30% has been modelled as aligned open fractures within an anisotropic rock matrix and this model is consistent with available fracture density and hydraulic transmissivity data from the boreholes and the cross-hole resistivity tomography data. However, in general the study highlights the uncertainties that can arise, due to the relative influence of rock fabric and fluid-filled fractures, when using geophysical techniques for hydrological investigations.
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    Geophysical prospecting 52 (2004), S. 0 
    ISSN: 1365-2478
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    Topics: Geosciences , Physics
    Notes: Shear-wave polarization and time delay are attributes commonly used for fracture detection and characterization. In time-lapse analysis these parameters can be used as indicators of changes in the fracture orientation and density. Indeed, changes in fracture characteristics provide key information for increased reservoir characterization and exploitation. However, relative to the data uncertainty, is the comparison of these parameters over time statistically meaningful? We present the uncertainty in shear-wave polarization and time delay as a function of acquisition uncertainties, such as receiver and source misorientation, miscoupling and band-limited random noise. This study is applied to a time-lapse borehole seismic survey, recorded in Vacuum Field, New Mexico. From the estimated uncertainties for each survey, the uncertainty in the difference between the two surveys is 31° for the shear-wave polarization angle and 4 ms for the shear-wave time delay. Any changes in these parameters greater than these error estimates can be interpreted with confidence. This analysis can be applied to any time-lapse measurement to provide an interval of confidence in the interpretation of shear-wave polarization angles and time splitting.
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    Geophysical prospecting 52 (2004), S. 0 
    ISSN: 1365-2478
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences , Physics
    Notes: A series of downhole magnetometric resistivity (DHMMR) and downhole electromagnetic (DHEM) surveys were conducted near Broken Hill, New South Wales, Australia, and at Zinkgruvan, Sweden, to determine how probe and receiver equipment choices affect the amount of noise visible in borehole MMR and EM data. Noise analyses performed on the data, using the standard deviation to gauge the relative noise levels between different probes and receiver systems, indicate that high noise levels in MMR data result primarily from the use of a three-component EM probe, which has a reduced effective area and hence a higher noise floor compared with a single-component EM probe. High noise, attributable to cultural sources such as nearby power lines, in either MMR or EM data can be reduced through the use of full-waveform, multipurpose receiver systems. These systems allow for the use of tapered stacking, which is a more effective method of eliminating coherent noise associated with power-line transients than the boxcar-stacking method used by traditional receiver systems.
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    Geophysical prospecting 52 (2004), S. 0 
    ISSN: 1365-2478
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    Topics: Geosciences , Physics
    Notes: Interlayer slipping breccia-type gold deposit – a new type of gold deposit, defined recently in the northern margin of the Jiaolai Basin, Shandong Province, China – occurs in interlayer slip faults distributed along the basin margin. It has the features of large orebody thickness (ranging from 14 m to 46 m, with an average thickness of 30 m), shallow embedding (0–50 m thickness of cover), low tenor of gold ore (ranging from 3 g/t to 5 g/t), easy mining and ore dressing. This type of gold deposit has promising metallogenic forecasting and potential for economic exploitation.A ground gamma-ray survey in the Pengjiakuang gold-ore district indicates that the potassium/thorium ratio is closely related to the mineralization intensity, i.e. the larger the potassium/thorium ratio, the higher the mineralization. The gold mineralized alteration zone was defined by a potassium/thorium ratio of 0.35. A seismic survey confirms the location of the top and bottom boundaries and images various features within the Pengjiakuang gold mineralization belt. The gold-bearing shovel slipped belt dips to the south at an angle of 50–55° at the surface and 15–20° at depth. The seismic profile is interpreted in terms of a structural band on the seismic section characterized by a three-layered model. The upper layer is represented by weakly discontinuous reflections that represent the overlying conglomerates. A zone of stronger reflections representing the interlayer slip fault (gold-bearing mineralized zone) is imaged within the middle of the section, while the strongest reflections are in the lower part of the section and represent metamorphic rocks at depth. At the same time, the seismic reflection survey confirms the existence of a granite body at depth, indicating that ore-forming fluids may be related to the granite. A CSAMT survey showed that the gold-bearing mineralized zone is a conductive layer and contains a low-resistivity anomaly ranging from 2 Ωm to 200 Ωm.
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    Geophysical prospecting 52 (2004), S. 0 
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    Topics: Geosciences , Physics
    Notes: The elastic properties and anisotropy of shales are strongly influenced by the degree of alignment of the grain scale texture. In general, an orientation distribution function (ODF) can be used to describe this alignment, which, in practice, can be characterized by two Legendre coefficients. We discuss various statistical ODFs that define the alignment by spreading from a mean value; in particular, the Gaussian, Fisher and Bingham distributions. We compare the statistical models with an ODF resulting from pure vertical compaction (no shear strain) of a sediment. The compaction ODF may be used to estimate how the elastic properties and anisotropy evolve due to burial of clayey sediments.Our study shows that the three statistical ODFs produce almost identical correspondence between the two Legendre coefficients as a function of the spreading parameter, so that the spreading parameter of one ODF can be converted to the spreading parameter of another ODF. In most cases it is then sufficient to apply the spreading parameter for the ODF instead of the two Legendre coefficients. The effect of compaction on the ODF gives a slightly different correspondence between the two Legendre coefficients from that for the other models. In principle, this opens up the possibility of distinguishing anisotropy effects due to compaction from those due to other processes.We also study reflection amplitudes versus angle of incidence (AVA) for all wave modes, where shales having various ODFs overlie an isotropic medium. The AVA responses are modelled using both exact and approximation formulae, and their intercepts and gradients are compared. The modelling shows that the S-wave velocity is sensitive to any perturbation in the spreading parameter, while the P-wave velocity becomes increasingly sensitive to a perturbation of a less ordered system. Similar observations are found for the AVA of the P-P and P-SV waves. Modelling indicates that a combined use of the amplitude versus offset of P-P and P-SV reflected waves may reveal certain grain scale alignment properties of shale-like rocks.
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    Geophysical prospecting 52 (2004), S. 0 
    ISSN: 1365-2478
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences , Physics
    Notes: Although it is believed that natural fracture sets predominantly have near-vertical orientation, oblique stresses and some other mechanisms may tilt fractures away from the vertical. Here, we examine an effective medium produced by a single system of obliquely dipping rotationally invariant fractures embedded in a transversely isotropic with a vertical symmetry axis (VTI) background rock. This model is monoclinic with a vertical symmetry plane that coincides with the dip plane of the fractures.Multicomponent seismic data acquired over such a medium possess several distinct features that make it possible to estimate the fracture orientation. For example, the vertically propagating fast shear wave (and the fast converted PS-wave) is typically polarized in the direction of the fracture strike. The normal-moveout (NMO) ellipses of horizontal reflection events are co-orientated with the dip and strike directions of the fractures, which provides an independent estimate of the fracture azimuth. However, the polarization vector of the slow shear wave at vertical incidence does not lie in the horizontal plane – an unusual phenomenon that can be used to evaluate fracture dip. Also, for oblique fractures the shear-wave splitting coefficient at vertical incidence becomes dependent on fracture infill (saturation).A complete medium-characterization procedure includes estimating the fracture compliances and orientation (dip and azimuth), as well as the Thomsen parameters of the VTI background. We demonstrate that both the fracture and background parameters can be obtained from multicomponent wide-azimuth data using the vertical velocities and NMO ellipses of PP-waves and two split SS-waves (or the traveltimes of PS-waves) reflected from horizontal interfaces. Numerical tests corroborate the accuracy and stability of the inversion algorithm based on the exact expressions for the vertical and NMO velocities.
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    Geophysical prospecting 52 (2004), S. 0 
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    Topics: Geosciences , Physics
    Notes: The azimuth moveout (AMO) operator in homogeneous transversely isotropic media with a vertical symmetry axis (VTI), as in isotropic media, has an overall skewed saddle shape. However, the AMO operator in anisotropic media is complicated; it includes, among other things, triplications at low angles. Even in weaker anisotropies, with the anisotropy parameter η= 0.1 (10% anisotropy), the AMO operator is considerably different from the isotropic operator, although free of triplications. The structure of the operator in VTI media (positive η) is stretched (has a wider aperture) compared with operators in isotropic media, with the amount of stretch being dependent on the strength of anisotropy. If the medium is both vertically inhomogeneous, i.e. the vertical velocity is a function of depth (v(z)), and anisotropic, which is a common combination in practical problems, the shape of the operator again differs from that for isotropic media. However, the difference in the AMO operator between the homogeneous and the v(z) cases, even for anisotropic media, is small. Stated simply, anisotropy influences the shape and aperture of the AMO operator far more than vertical inhomogeneity does.
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    Geophysical prospecting 52 (2004), S. 0 
    ISSN: 1365-2478
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences , Physics
    Notes: The attenuation of ground-penetrating radar (GPR) energy in the subsurface decreases and shifts the amplitude spectrum of the radar pulse to lower frequencies (absorption) with increasing traveltime and causes also a distortion of wavelet phase (dispersion). The attenuation is often expressed by the quality factor Q. For GPR studies, Q can be estimated from the ratio of the real part to the imaginary part of the dielectric permittivity.We consider a complex power function of frequency for the dielectric permittivity, and show that this dielectric response corresponds to a frequency-independent-Q or simply a constant-Q model. The phase velocity (dispersion relationship) and the absorption coefficient of electromagnetic waves also obey a frequency power law. This approach is easy to use in the frequency domain and the wave propagation can be described by two parameters only, for example Q and the phase velocity at an arbitrary reference frequency. This simplicity makes it practical for any inversion technique. Furthermore, by using the Hilbert transform relating the velocity and the absorption coefficient (which obeys a frequency power law), we find the same dispersion relationship for the phase velocity. Both approaches are valid for a constant value of Q over a restricted frequency-bandwidth, and are applicable in a material that is assumed to have no instantaneous dielectric response.Many GPR profiles acquired in a dry aeolian environment have shown a strong reflectivity inside dunes. Changes in water content are believed to be the origin of this reflectivity. We model the radar reflections from the bottom of a dry aeolian dune using the 1D wavelet modelling method. We discuss the choice of the reference wavelet in this modelling approach. A trial-and-error match of modelled and observed data was performed to estimate the optimum set of parameters characterizing the materials composing the site. Additionally, by combining the complex refractive index method (CRIM) and/or Topp equations for the bulk permittivity (dielectric constant) of moist sandy soils with a frequency power law for the dielectric response, we introduce them into the expression for the reflection coefficient. Using this method, we can estimate the water content and explain its effect on the reflection coefficient and on wavelet modelling.
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    Geophysical prospecting 52 (2004), S. 0 
    ISSN: 1365-2478
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences , Physics
    Notes: The forward computation of the gravitational and magnetic fields due to a 3D body with an arbitrary boundary and continually varying density or magnetization is an important problem in gravitational and magnetic prospecting. In order to solve the inverse problem for the arbitrary components of the gravitational and magnetic anomalies due to an arbitrary 3D body under complex conditions, including an uneven observation surface, the existence of background anomalies and very little or no a priori information, we used a spherical coordinate system to systematically investigate forward methods for such anomalies and developed a series of universal spherical harmonic expansions of gravitational and magnetic fields. For the case of a 3D body with an arbitrary boundary and continually varying magnetization, we have also given the surface integral expressions for the common spherical harmonic coefficients in the expansion of the magnetic field due to the body, and a very precise numerical integral algorithm to calculate them. Thus a simple and effective method of solving the forward problem for magnetic fields due to 3D bodies of this kind has been found, and in this way a foundation is laid for solving the inverse problem of these magnetic fields. In addition, by replacing the parameters and unit vectors in the spherical harmonic expansion of a magnetic field by gravitational parameters and a downward unit vector, we have also derived a forward method for the gravitational field (similar to that for the magnetic case) of a 3D body with an arbitrary boundary and continually varying density.
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    Geophysical prospecting 52 (2004), S. 0 
    ISSN: 1365-2478
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    Topics: Geosciences , Physics
    Notes: 2.5D modelling approximates 3D wave propagation in the dip-direction of a 2D geological model. Attention is restricted to raypaths for waves propagating in a plane. In this way, fast inversion or migration can be performed. For velocity analysis, this reduction of the problem is particularly useful.We review 2.5D modelling for Born volume scattering and Born–Helmholtz surface scattering. The amplitudes are corrected for 3D wave propagation, taking into account both in-plane and out-of-plane geometrical spreading. We also derive some new inversion/migration results. An AVA-compensated migration routine is presented that is simplified compared with earlier results. This formula can be used to create common-image gathers for use in velocity analysis by studying the residual moveout. We also give a migration formula for the energy-flux-normalized plane-wave reflection coefficient that models large contrast in the medium parameters not treated by the Born and the Born–Helmholtz equation results. All results are derived using the generalized Radon transform (GRT) directly in the natural coordinate system characterized by scattering angle and migration dip. Consequently, no Jacobians are needed in their calculation.Inversion and migration in an orthorhombic medium or a transversely isotropic (TI) medium with tilted symmetry axis are the lowest symmetries for practical purposes (symmetry axis is in the plane). We give an analysis, using derived methods, of the parameters for these two types of media used in velocity analysis, inversion and migration. The kinematics of the two media involve the same parameters, hence there is no distinction when carrying out velocity analysis. The in-plane scattering coefficient, used in the inversion and migration, also depends on the same parameters for both media. The out-of-plane geometrical spreading, necessary for amplitude-preserving computations, for the TI medium is dependent on the same parameters that govern in-plane kinematics. For orthorhombic media, information on additional parameters is required that is not needed for in-plane kinematics and the scattering coefficients.Resolution analysis of the scattering coefficient suggests that direct inversion by GRT yields unreliable parameter estimates. A more practical approach to inversion is amplitude-preserving migration followed by AVA analysis.SYMBOLS AND NOTATIONA list of symbols and notation is given in Appendix D.
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    ISSN: 1365-2478
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences , Physics
    Notes: A strategy for multiple removal consists of estimating a model of the multiples and then adaptively subtracting this model from the data by estimating shaping filters. A possible and efficient way of computing these filters is by minimizing the difference or misfit between the input data and the filtered multiples in a least-squares sense. Therefore, the signal is assumed to have minimum energy and to be orthogonal to the noise. Some problems arise when these conditions are not met. For instance, for strong primaries with weak multiples, we might fit the multiple model to the signal (primaries) and not to the noise (multiples). Consequently, when the signal does not exhibit minimum energy, we propose using the L1-norm, as opposed to the L2-norm, for the filter estimation step. This choice comes from the well-known fact that the L1-norm is robust to ‘large’ amplitude differences when measuring data misfit. The L1-norm is approximated by a hybrid L1/L2-norm minimized with an iteratively reweighted least-squares (IRLS) method. The hybrid norm is obtained by applying a simple weight to the data residual. This technique is an excellent approximation to the L1-norm. We illustrate our method with synthetic and field data where internal multiples are attenuated. We show that the L1-norm leads to much improved attenuation of the multiples when the minimum energy assumption is violated. In particular, the multiple model is fitted to the multiples in the data only, while preserving the primaries.
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    Geophysical prospecting 52 (2004), S. 0 
    ISSN: 1365-2478
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences , Physics
    Notes: Sonic techniques in geophysical prospecting involve elastic wave velocity measurements that are performed by placing acoustic transmitters and receivers in a fluid-filled borehole. The signals recorded at the receivers are processed to obtain compressional- and shear-wave velocities in the surrounding formation. These velocities are generally used in seismic surveys for the time-to-depth conversion and other formation parameters, such as porosity and lithology. Depending upon the type of transmitter used (e.g. monopole or dipole) and as a result of eccentering, it is possible to excite axisymmetric (n= 0), flexural (n= 1) and quadrupole (n= 2) families of modes propagating along the borehole. We present a study of various propagating and leaky modes that includes their dispersion and attenuation characteristics caused by radiation into the surrounding formation. A knowledge of propagation characteristics of borehole modes helps in a proper selection of transmitter bandwidth for suppressing unwanted modes that create problems in the inversion for the compressional- and shear-wave velocities from the dispersive arrivals. It also helps in the design of a transmitter for a preferential excitation of a given mode in order to reduce interference with drill-collar or drilling noise for sonic measurements-while-drilling. Computational results for the axisymmetric family of modes in a fast formation with a shear-wave velocity of 2032 m/s show the existence of Stoneley, pseudo-Rayleigh and anharmonic cut-off modes. In a slow formation with a shear-wave velocity of 508 m/s, we find the existence of the Stoneley mode and the first leaky compressional mode which cuts in at approximately the same normalized frequency ωa/VS= 2.5 (a is the borehole radius) as that of the fast formation. The corresponding modes among the flexural family include the lowest-order flexural and anharmonic cut-off modes. For both the fast and slow formations, the first anharmonic mode cuts in at a normalized frequency ωa/VS= 1.5 approximately. Cut-off frequencies of anharmonic modes are inversely proportional to the borehole radius in the absence of any tool. The borehole quadrupole mode can also be used for estimating formation shear slownesses. The radial depth of investigation with a quadrupole mode is marginally less than that of a flexural mode because of its higher frequency of excitation.
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    Geophysical prospecting 52 (2004), S. 0 
    ISSN: 1365-2478
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences , Physics
    Notes: A series of time-lapse seismic cross-well and single-well experiments were conducted in a diatomite reservoir to monitor the injection of CO2 into a hydrofracture zone, based on P- and S-wave data. A high-frequency piezo-electric P-wave source and an orbital-vibrator S-wave source were used to generate waves that were recorded by hydrophones as well as 3-component geophones. During the first phase the set of seismic experiments was conducted after the injection of water into the hydrofractured zone. The set of seismic experiments was repeated after a time period of seven months during which CO2 was injected into the hydrofractured zone. The questions to be answered ranged from the detectability of the geological structure in the diatomic reservoir to the detectability of CO2 within the hydrofracture. Furthermore, it was intended to determine which experiment (cross-well or single-well) is best suited to resolve these features.During the pre-injection experiment, the P-wave velocities exhibited relatively low values between 1700 and 1900 m/s, which decreased to 1600–1800 m/s during the post-injection phase (−5%). The analysis of the pre-injection S-wave data revealed slow S-wave velocities between 600 and 800 m/s, while the post-injection data revealed velocities between 500 and 700 m/s (−6%). These velocity estimates produced high Poisson's ratios between 0.36 and 0.46 for this highly porous (∼50%) material. Differencing post- and pre-injection data revealed an increase in Poisson's ratio of up to 5%. Both velocity and Poisson's ratio estimates indicate the dissolution of CO2 in the liquid phase of the reservoir accompanied by an increase in pore pressure.The single-well data supported the findings of the cross-well experiments. P- and S-wave velocities as well as Poisson's ratios were comparable to the estimates of the cross-well data.The cross-well experiment did not detect the presence of the hydrofracture but appeared to be sensitive to overall changes in the reservoir and possibly the presence of a fault. In contrast, the single-well reflection data revealed an arrival that could indicate the presence of the hydrofracture between the source and receiver wells, while it did not detect the presence of the fault, possibly due to out-of-plane reflections.
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    Industrial relations journal 35 (2004), S. 0 
    ISSN: 1468-2338
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Economics
    Notes: This paper explores the apparent paradox that while unions exist to promote the interests and well-being of their members, UK survey evidence consistently shows that union members report lower levels of job satisfaction than non-union workers. A review and further analysis of the evidence confirms that this difference persists after controlling for other factors such as type of work. If union member dissatisfaction reflects a form of voice, then we might expect to see resulting gains. An analysis of data from the 1998 Workplace Employee Relations Survey indicates that any gains are modest. Evidence is presented to suggest that although management has become less hostile to trade unions, a degree of anti-union sentiment remains, sometimes leading to a muffling of the union voice, and this helps to account for some of the union member dissatisfaction.
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    Industrial relations journal 35 (2004), S. 0 
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    Topics: Economics
    Notes: There has been an increasing focus on the performance of workers through appraisal, performance-related pay and performance management and this emphasis on measuring performance has extended to the public sector—more specifically, to the teaching profession. This paper uses research commissioned by the DfES to investigate the operation of capability procedures introduced to deal with the perceived problem of incompetent teachers. It revealed that the procedures suffered from a number of defects both in modus operandi and style and there was little evidence that their application resulted in either improved performance or dismissal when satisfactory performance was not achieved.
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    Topics: Economics
    Notes: Unlike studies of women, studies of men in paid employment have tended to focus on them purely as workers, trade unionists and breadwinners, rather than on their roles beyond the workplace. This paper addresses this omission by exploring the relationship between paid work and aspects of family life amongst 69 male process workers from three manufacturing companies. It offers qualitative evidence to demonstrate that understanding men's wider domestic/familial roles and responsibilities is integral to analyses of their workplace behaviour. The conclusion from this study is that the boundary between home and work is selectively-permeable, and the workers took aspects of their domestic life into the workplace whilst seeking to prevent their paid work from intruding on family and domestic life.
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    Topics: Economics
    Notes: This article examines the workings of co-determination in the German finance industry through two case studies examining the introduction of working time accounts. It is shown that the accounts posed important new challenges for employees and works councillors that represented variants of long-existing negotiations around working time issues. The problems were clear and similar in both cases, giving rise to complaints to councillors, though not to managers. Councillors’ responses differed in the two companies. In one, they successfully re-negotiated the agreement under which the accounts had been introduced. In the other, they did not succeed in doing so. The differences between the two representative bodies are analysed to reflect on a theory of employee representative influence.
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    Industrial relations journal 35 (2004), S. 0 
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    Topics: Economics
    Notes: Books reviewed:Jill C. Humphrey. Towards a Politics of the RainbowBrendan Burchell, David Lapido and Frank Wilkinson (eds). Job Insecurity and Work IntensificationPeter Ackers and Adrian Wilkinson (eds). Understanding Work and Employment: Industrial Relations in Transition
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    Notes: The aim of this paper is to review the role that representative worker participation can play in contributing to better health and safety performance in small enterprises. The relevance of representative participation to health and safety in small enterprises is addressed and the challenges that the sector poses are discussed. Using a number of examples, including legislative approaches, trade union initiatives and joint trade union employer schemes in various countries, the paper explores some of the ways in which such challenges have been tackled.
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    Topics: Economics
    Notes: The impact of child rearing upon male and female participation rates and earnings within 130 dual career households is investigated. Female participation rates and earnings in households with children are significantly lower than both comparable males and females without children. No significant gender differences exist in pay in childless households.
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    Topics: Economics
    Notes: Most publications on German industrial relations tend to focus on works councils but miss trade union delegates and senior delegates. Seeking to address this lack of research, a case study of a large manufacturing plant is used to examine the role of union delegates and senior delegates and their relationship to works councils. The case study seeks to show why works councils are inextricably linked to the union movement, even though both are structurally separated. Research findings support the notion that both are in a mutually supportive relationship. Furthermore, the evidence also suggests that trade union shopfloor representation is of crucial importance for works councils, industrial democracy and trade unions in German industrial relations.
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    Notes: This paper examines the mutual expectations of employment agencies, the temporary workers who are placed by them and the client or host companies with whom they are placed. It considers the ambiguities and complexities inherent in the psychological contracts of agency temps, pointing to positive dimensions of the agency relationship with temps coupled with a tough transactional regime. In periods of uncertainty agency temping provided individuals with an illusion of freedom and control.
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    Topics: Economics
    Notes: This article assesses the impact of the profound changes that have taken place in the higher education sector on academic staff in the UK. The perceptions of staff about their work and employment are examined through evidence provided by a recent large-scale survey. The discussion draws on a labour process perspective. The article finds that the views of staff are far from homogeneous and not universally pessimistic. However, in general the morale and satisfaction of many teaching staff have been eroded by work intensification and that of research staff by the considerable insecurity created by casualised employment. Nonetheless resistance and resilience continues despite the commodifying pressures, and ‘traditional’ values remain strong.
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    Topics: Economics
    Notes: This article focuses on the struggle for a social Europe by examining social partnership developments in two western countries, Germany and Britain, and two eastern countries, Bulgaria and Poland. The resurgence of social partnership in the west, even in the weakest case (Britain), is paradoxically driven in part by neoliberal EU economic policies. In the east, post-communist tripartism helped preserve social peace with the coming of markets, while both international lending agencies and subsequent EU accession processes pushed domestic actors towards social dialogue. The coming or deepening of markets has therefore surprisingly promoted or reinforced relations of social partnership throughout Europe.
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    Notes: Book reviewed Dock Workers: International Explorations in Comparative Labour History 
 Sam Davis, Colin J. Davis, David de Vries, Lex Heerma van Voss, Lidewij Hesselink and Klaus Weinhauer (eds) 
 Ashgate, 2000, 863 pp., £75 (hardback, 2 volumes) Labored Relations: Law, Politics and the NLRB—A Memoir 
 William B. Gould IV 
 MIT Press, 2000, 474 pp., £27.50 Trade Unions and Global Governance. The Debate on a Social Clause 
 Gerda van Roozendal 
 Continuum, 2002, 260 pp., £75.00 (hardback), £25.00 (paperback) Organized Labour in the 21st Century 
 A.V. Jose (ed.) 
 International Institute for Labour Studies, 2002, xii + 406 pp., 120
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    International journal of selection and assessment 12 (2004), S. 0 
    ISSN: 1468-2389
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Economics
    Notes: This study addresses the determinants and outcomes of fairness perceptions in a real assessment procedure as performed by a selection agency. Fairness perceptions were investigated at three points in time: before the assessment, right after the assessment but before assessment feedback, and after assessment feedback. Using structural equation modeling, we tested how fairness perceptions develop throughout the assessment procedure. Applicants' openness to experiences affected their test beliefs before the actual test-taking. These beliefs remained powerful in the subsequent stages of the assessment procedure in that they influenced applicants' perceptions of performance, feedback and fairness. In the context of selection by an external selection agency, post-feedback fairness perceptions were not related to job attractiveness. Perceived feedback treatment and feedback content directly affected job attractiveness.
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    ISSN: 1468-2389
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    Topics: Economics
    Notes: Expectations, which are beliefs about a future state of affairs, constitute a basic psychological mechanism that underlies virtually all human behavior. Although expectations serve as a central component in many theories of organizational behavior, they have received limited attention in the organizational justice literature. The goal of this paper is to introduce the concept of justice expectations and explore its implications for understanding applicant perceptions. To conceptualize justice expectations, we draw on research on expectations conducted in multiple disciplines. We discuss the three sources of expectations – direct experience, indirect influences, and other beliefs – and use this typology to identify the likely antecedents of justice expectations in selection contexts. We also discuss the impact of expectations on attitudes, cognitions, and behaviors, focusing specifically on outcomes tied to selection environments. Finally, we explore the theoretical implications of incorporating expectations into research on applicant perceptions and discuss the practical significance of justice expectations in selection contexts.
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    Topics: Economics
    Notes: This article proposes a new theory called the Applicant Attribution-Reaction Theory (AART) to better understand attributional processes in the formation of applicant reactions. The theory proposes that applicants' affective, behavioral, and cognitive reactions, such as fairness, test perceptions, test performance, and motivation, are fundamentally driven by an attributional process. A key implication of the theory is that perceptions such as fairness and test attitudes carry little explanatory power; instead they are consequences of attributional processing. We provide a brief review of dominant applicant reactions frameworks, review the social psychological literature on attributions, and present the theory. We then contrast the theory to existing conceptualizations, and finally describe its potential for better understanding several key topics in applicant reactions, including the justice judgment process, test performance, and racial subgroup differences. The theory has the potential to integrate many diverse perspectives on applicant reactions, and provides numerous directions for future research and practice.
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    Topics: Economics
    Notes: This research contributes to the understanding of reactions to different selection screening methods. A sample of students (n=153) experienced one of three types of screening techniques, face-to-face interview screenings, telephone interview screenings, and interactive voice response (IVR) screenings, with identical content in a pre- to post-screening longitudinal study. We further examined the role of two important individual differences, cognitive ability and conscientiousness, in attitudes toward the screenings. IVR is a “non-interpersonal” screening method so it was not surprising that it was rated lower in terms of procedural justice factors such as interpersonal treatment, two–way communication, and openness but what is encouraging is that there were no differences between other labor intensive and costly technologies and IVR on the other procedural justice factors. Therefore, there do not appear to be any major negatives in terms of structural fairness among alternative screening devices implying that organizations can make choices between screening methods based on other factors such as recruitment strategy or cost.
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    Topics: Economics
    Notes: This paper examines the reactions to personnel selection methods in Spain and Portugal using a sample composed of 125 and 104 students, respectively. The results found are very similar in both countries. The best rated and most favorable methods are interviews, résumés and work sample tests, while contacts, integrity tests and graphology were the least favorable ones. With regard to the process dimensions used, face validity and opportunity to perform are the most important bases for considering personnel techniques favorably. The results show some similarities with the ones found by Steiner and Gilliland (1996) in French and American samples. The similarities among the countries are examined and directions for future research are discussed.
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    Growth and change 35 (2004), S. 0 
    ISSN: 1468-2257
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geography , Economics
    Notes:   Clusters now form a central element in many regional economic development policies. Location within a cluster of related industries is thought to increase a firm's competitive advantage resulting in higher output and productivity growth rates than in similar firms located beyond the cluster. This study focuses on owner-managers operating small firms within a traditional cluster of metalworking industries and empirically examines the relationship between growth-orientation and the extent and nature of cluster embeddedness. The results indicate only a limited number of differences in growth-orientation given variations in levels of cluster embeddedness. Contrary to conventional wisdom, many of the most growth-oriented entrepreneurs focus their activities outside the cluster, especially in terms of market-based linkages. However, those firms with more advanced process technologies do tend to show above average within cluster linkages.
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    Topics: Geography , Economics
    Notes:   The goal of this paper is twofold. The first goal is to incorporate spatial structure within shift-share analysis, to take into account interregional interaction in the decomposition analysis. Secondly, this paper develops a taxonomy of regional growth rate decompositions. A taxonomy of the spatial structure is presented; it comprises twenty alternative decomposition structures, including the original standard shift-share analysis as well as six alternative structures outlined in the taxonomy for non-spatial structures.
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    Topics: Geography , Economics
    Notes: Book reviewed: Internet, Economic Growth and Globalization: Perspective on the New Economy in Europe, Japan and the USA. Edited by Claude E. Barfield, Günter Heiduk, and Paul J.J. Welfens: Springer, 2003. 385pp. ISBN 3-540-00286-3.
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    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geography , Economics
    Notes:   This paper discusses various aspects of the economic analysis of commuting behavior. It starts with a review of two difficulties associated with urban economics models: the empirically falsified prediction of the relation between commuting time and income, and the presence of substantial excess commuting. Notwithstanding these anomalies, research that focuses directly on the value of travel time provides evidence that there is substantial resistance against commuting among large groups of workers. However, commuting costs are just one among many other explanatory variables for actual commuting behavior, and commuting itself has become much less onerous over time. This suggests that commuting costs play a much more limited role than has been assumed in the past. On the other hand, empirical evidence suggests that space is more important than one would be inclined to think on the basis of the considerations just given. These empirical regularities suggest that other space-related aspects of the functioning of urban labor and housing markets are more important than was previously thought.
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    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geography , Economics
    Notes:   Commuting is popularly viewed as a stressful, costly, time-wasting experience from the individual perspective, with the attendant congestion imposing major social costs as well. However, several authors have noted that commuting can also offer benefits to the individual, serving as a valued transition between the home and work realms of personal life. Using survey data collected from about 1,300 commuting workers in three San Francisco Bay Area neighborhoods, empirical models are developed for four key variables measured for commute travel, namely: Objective Mobility, Subjective Mobility, Travel Liking, and Relative Desired Mobility. Explanatory variables include measures of general travel-related attitudes, personality traits, lifestyle priorities, and sociodemographic characteristics. Both descriptive statistics and analytical models indicate that commuting is not the unmitigated burden that it is widely perceived to be. About half of the sample were relatively satisfied with the amount they commute, with a small segment actually wanting to increase that amount. Both the psychological impact of commuting, and the amounts people want to commute relative to what they are doing now, are strongly influenced by their liking for commuting. An implication for policy is that some people may be more resistant than expected toward approaches intended to induce reductions in commuting (including, for example, telecommuting). New creativity may be needed to devise policies that recognize the inherent positive utility of travel, while trying to find socially beneficial ways to fulfill desires to maintain or increase travel.
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    Growth and change 35 (2004), S. 0 
    ISSN: 1468-2257
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geography , Economics
    Notes:   Information and Communication Technology (ICT) has become an important tool to promote a variety of public goals and policies. In the past years much attention has been given to the expected social benefits from deploying ICTs in different urban fields (transportation, education, public participation in planning, etc.) and to its potential to mitigate various current or emerging urban problems. The growing importance of ICTs in daily life, business activities, and governance prompts the need to consider ICTs more explicitly in urban policies. Alongside the expectation that the private sector will play a major role in the ICT field, the expected benefits from ICTs also encourage urban authorities to formulate proper public ICT policies.Against this background, various intriguing research questions arise. What are the urban policy-makers’ expectations about ICTs? And how do they assess the future implications of ICTs for their city? A thorough analysis of these questions will provide a better understanding of the extent to which urban authorities are willing to invest in and to adopt a dedicated ICT policy.This study is focusing on the way urban decision-makers perceive the opportunities of ICT policy. After a sketch of recent development and policy issues, a conceptual model is developed to map out the driving forces of urban ICT policies in cities in Europe. Next, by highlighting the importance of understanding the decision-maker's “black box,” three crucial variables are identified within this box. In the remaining part of the paper these three variables will be operationalized by using a large survey comprising more than 200 European cities. By means of statistical multivariate methods (i.e., factor and cluster analysis), the decision-makers were able to be characterized according to the way they perceive their city (the concept of “imaginable city”), their opinion about ICT, and the way they assess the relevance of ICT policies to their city. Next, a solid explanatory framework will be offered by using a log-linear logit analysis to test the relationships between these three aspects.
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    Growth and change 35 (2004), S. 0 
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    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geography , Economics
    Notes: Books reviewedJohannes Brocker, Dirk Dohse, and Rudiger Soltwedel, Innovation Clustersand Interregional Competition.Norman Walzer, The American Midwest: Managing Changein Rural Transition.G.D. Hewings, M. Sonis, and D. Boyce, Trade, Networksand Hierarchies: Modeling Regionaland Interregional Economies.
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    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geography , Economics
    Notes:   Inter-industry employment shifts were largely responsible for changes in the income distribution in the Pittsburgh region during the 1980s. Kernel density estimators were used, together with decomposition techniques developed by DiNardo et al. (1996) to show that industry shifts were responsible for over 90 percent of the earnings reductions at some points on the earnings distribution. Most of the losses at the lower end of the distribution occurred in the early 1980s as the economy plunged into a deep recession. The recovery in the later part of the decade brought little improvement as earnings in the lower part of the distribution continued to fall with the increase in employment of part-time workers in the low-wage trade and service sectors.
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    Growth and change 35 (2004), S. 0 
    ISSN: 1468-2257
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geography , Economics
    Notes: Books reviewedJoel Greenberg, A Natural History Of The Chicago Region.James H. Carr and Zhong Yi Tong, Replicating Microfinance In The United States.
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    Growth and change 35 (2004), S. 0 
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    Topics: Geography , Economics
    Notes:   Linkages among changes in employment, earnings per worker, and pollution per square mile are estimated for 3,036 U.S. counties for the period 1987 to 1995 using a three-equation disequilibrium adjustment model. Counties with higher shares of African-Americans experienced higher earnings growth rates over the period 1987-1995, as did counties with proportionally more females. Counties in states with higher shares of unionized workers had higher earnings growth rates but generated fewer new jobs. Firm size had a significant and negative effect on earnings growth while higher costs of living were associated with higher earnings growth. Also, metro counties and counties in the Northeastern U.S. experienced higher earnings growth than their non-metro counterparts and counties in other geographic regions. Statistically, faster job growth was found to accelerate the rate of earnings growth per worker. The authors conclude that counties concerned with job growth should recruit or attempt to spawn the creation of larger firms, recognizing that for some firms such a strategy may come at the cost of more rapid increases in pollution. Counties concerned with increasing the rate of growth in per worker earnings should instead focus on the creation of smaller firms.
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    International journal of selection and assessment 12 (2004), S. 0 
    ISSN: 1468-2389
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Economics
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    International journal of selection and assessment 12 (2004), S. 0 
    ISSN: 1468-2389
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Economics
    Notes: The purpose of this paper is to examine the usefulness of the organizational justice approach to applicant reactions. We begin with an overview of the research relating the fairness of selection procedures (“selection fairness”) to individual and organizational outcomes. Next we propose boundary conditions defining when fairness should matter, the appropriate outcomes to examine in applicant reactions research, and methodological issues limiting the contribution of much of the current literature. We then consider a range of questions that remain to be addressed and new issues such as high-tech testing. Finally, we propose a series of applied questions and recommendations based on both theory and empirical research.
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    International journal of selection and assessment 12 (2004), S. 0 
    ISSN: 1468-2389
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Economics
    Notes: This study investigates the role of feedback in minimizing the psychological impact of a negative selection decision on job applicants. The method and findings of a laboratory experiment into subjects' reactions to rejection, combined with feedback on this decision as well as perceptions of procedural and distributive fairness, are discussed. Subjects participating in the experiment (N=119) were asked to complete two GMA tests and were told they had to belong to the 20% best performers to be invited for a selection interview. Upon completion, all subjects received a rejection message, supposedly based on their performance scores on the two tests. Subjects were randomly assigned to one of two feedback conditions: either a mere rejection message, or a rejection message including performance feedback. Analyses revealed that core self-evaluations and affective well-being of rejected subjects receiving performance feedback significantly decreased compared to that of subjects in the mere rejection message condition. Furthermore, it was found that procedural fairness perceptions interacted with feedback on subjects' core self-evaluations, while distributive fairness perceptions interacted with feedback on affective well-being. These findings raise the question whether performance feedback following a negative selection decision is as advantageous as generally assumed. Implications for giving feedback in rejection situations are discussed in the conclusion.
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    International journal of selection and assessment 12 (2004), S. 0 
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    Topics: Economics
    Notes: This article offers an agenda for future research on applicant reactions to selection procedures. Advocating a construct-oriented approach, we propose that future research focuses attention on fundamental issues subsumed under seven distinct although related areas namely: (1) dimensions of applicant reactions, (2) changes in applicant reactions over time, (3) determinants of applicant reactions, (4) applicant reactions and test constructs, (5) criterion outcomes of applicant reactions, (6) reactions to new technology in testing, and (7) methodological and data analysis issues.
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    International journal of selection and assessment 12 (2004), S. 0 
    ISSN: 1468-2389
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    Topics: Economics
    Notes: Research in industrial/organizational (I/O) psychology has generally focused on objective measures of employment discrimination and has virtually neglected individuals' subjective perceptions as to whether a selection or promotion process is discriminatory or not. This paper presents two theoretical models as organizing frameworks to explain candidates' likelihood of perceiving that discrimination has occurred in a certain selection or promotion situation. The prototype model stresses the importance of the prototypical victim-perpetrator combination, the perceived intention of the decision-maker, and the perceived harm caused as possible antecedents of perceived employment discrimination. In the organizational justice model, procedural, informational, interpersonal, and distributive fairness play a central role in determining candidates' perceptions of discrimination. The fairness heuristic helps to explain which type of fairness information dominates these perceptions. Applications and research propositions are discussed as well as the similarities and differences between the two models. We conclude by offering several factors that may determine which model is used in deciding whether or not discrimination has occurred.
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    International journal of selection and assessment 12 (2004), S. 0 
    ISSN: 1468-2389
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Economics
    Notes: A type of selection measure is presented which combines the psychometric characteristics of an intelligence test with the surface and content validity characteristics of a work sample for clerical occupations. Consequently, this measure – AZUBI-BK – is more positively evaluated by participants than a conventional measure of general mental ability (N=1375). Preferences for the work sample-intelligence test hybrid applied for potential applicants from different school types, for job-experienced as well as for inexperienced subjects and for members of the ethnic majority as well as for ethnic minorities. AZUBI-BK showed high correlations with total scores (uncorrected r=.77 and .73) and corresponding factors of two intelligence tests, respectively. Criterion-related validity was equal to the reference measure in predicting theoretical examinations (uncorrected r=.61) and higher in predicting supervisory ratings (uncorrected r=.43). In the latter case, the new instrument shows incremental validity over an intelligence test but not vice versa; in a regression equation, AZUBI-BK can fully account for the variance in supervisory assessment. Adverse impact of AZUBI-BK for ethnic minorities is small which, however, was also true for a conventional intelligence test.
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    International journal of selection and assessment 12 (2004), S. 0 
    ISSN: 1468-2389
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Economics
    Notes: This study explored the relative importance attached to various perceived personnel selection fairness determinants (e.g., selection system content-based variables, features of selection system administration). We investigated how demographic variables (ethnicity and gender), individual differences characteristics (the Big Five and cognitive ability) and job characteristics (job complexity and domestic/expatriate assignment status) relate to the importance of ratings of perceived personnel selection system determinants. The results, especially for race/ethnicity analyses indicated that there might be differences across demographic groups in importance placed on different aspects of selection system characteristics. The magnitudes of the relationships were small to moderate for Asian–White and Hispanic–White comparisons. Asian–Hispanic and gender differences in importance assessments were small. Few individual differences variables (i.e., personality and cognitive ability) were associated with importance placed on various aspects of selection system characteristics. Notable exceptions were moderate positive relationships between general mental ability and importance of content-based selection system characteristics, and moderate negative relationships between emotional stability, conscientiousness and cognitive ability, and importance of selection system context variables. The complexity levels of the jobs held by respondents did not appreciably affect the importance placed on the different selection system characteristics. There were few notable differences between importance assessments for domestic versus expatriate positions. Implications for practice, especially managing cultural diversity in organizations, and for theory development are discussed.
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    Growth and change 35 (2004), S. 0 
    ISSN: 1468-2257
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geography , Economics
    Notes:   Both economic and demographic contexts influence aggregate migration streams at the regional scale. The influence of demographic and economic context on aggregate migration at the nonmetropolitan scale, however, remains unstudied. This paper presents analysis based on 1980 and 1990 Public Use Microdata Sample (PUMS) data related to age cohort effects on nonmetropolitan population change. The analysis provides enhanced understanding of how demographic factors like the baby boom might influence population movements into and out of nonmetropolitan regions. Using modified age-cohort decomposition techniques, the analysis demonstrates how the fluctuations in nonmetropolitan population growth between 1975 and 1990 are tied to the differential migration flows of the peak baby boom years (those born between 1955 and 1964). The analysis further demonstrates how fluctuations in nonmetropolitan population growth across regions are tied to migration flows of these baby boomers. Significant variation remains within regions.
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    Growth and change 35 (2004), S. 0 
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    Topics: Geography , Economics
    Notes:   This paper shows that in the Baltic countries, commuting reduces urban-rural wage and employment disparities and increases national output. To quantify the effect of commuting on wage differentials, two sets of earnings functions are estimated (based on Estonian, Latvian, and Lithuanian Labor Force Surveys) with location variables (capital city, rural, etc.) measured at the workplace and at the place of residence. We find that the ceteris paribus wage gap between capital city and rural areas, as well as between capital and other cities is significantly narrowed by commuting in some cases but remains almost unchanged in others. Different outcomes are explained by country-specific spatial patterns of commuting, educational and occupational composition of commuting flows, and presence or absence of wage discrimination against rural residents in urban markets. A treatment effects model is used to estimate individual wage gains to rural—urban or inter-city commuting; these gains are substantial in most but not all cases. Wage effects of commuting distance, as well as impact of education, gender, ethnicity, and local labor market conditions on the commuting decision are also explored.
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    Growth and change 35 (2004), S. 0 
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    Topics: Geography , Economics
    Notes:   Over the last two decades many European governments have pursued ambitious research and development (R&D) policies with the aim of fostering innovation and economic growth in peripheral regions of Europe. The question is whether these policies are paying off. Arguments such as the need to reach a minimum threshold of research, the existence of important distance decay effects in the diffusion of technological spillovers, the presence of increasing returns to scale in R&D investments, or the unavailability of the necessary socio-economic conditions in these regions to generate innovation seem to cast doubts about the possible returns of these sort of policies. This paper addresses this question. A two-step analysis is used in order to first identify the impact of R&D investment of the private, public, and higher education sectors on innovation (measured as the number of patent applications per million population). The influence of innovation and innovation growth on economic growth is then addressed. The results indicate that R&D investment, as a whole, and higher education R&D investment in peripheral regions of the EU, in particular, are positively associated with innovation. The existence and strength of this association are, however, contingent upon region-specific socio-economic characteristics, which affect the capacity of each region to transform R&D investment into innovation and, eventually, innovation into economic growth.
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    Growth and change 35 (2004), S. 0 
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    Topics: Geography , Economics
    Notes:   In the international business literature location behavior has traditionally been analyzed using Dunning's (1977) OLI framework, which focuses on the nature, role, and behavior of multinational enterprise (MNE). In this paper it is argued that this approach is now no longer appropriate for discussing the spatial behavior of MNEs, because of the fundamental changes which have taken place either in MNE organization or in the global and institutional environment for foreign direct investment (FDI). At the same time, the paper argues that current location theory from regional economics and economic geography is also largely unsuitable for discussing these issues, such that the spatial behavior of the MNE provides a set of difficult challenges to location analysts. There appears to have been some response to these issues from the international business and management literature, most notably the Porter literature on clusters. However, it is also argued here that this literature provides few, if any, real answers to the problems set by the geographical behavior of the MNE. It is concluded that a fusion of traditional economic geography approaches with a focus on the information and organizational aspects of the firm and the region under consideration may be a way forward for both theory and empirical analysis.
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    Growth and change 35 (2004), S. 0 
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    Topics: Geography , Economics
    Notes:   This paper documents the investigation of the impact of metropolitan structure on the commute behavior of urban residents in the Netherlands. Not only has the impact of monocentrism versus polycentrism been analyzed, but the influence of metropolitan density and size has also been considered, together with the ratio of employment to population and the growth of the population and employment. Furthermore, data are used at a variety of levels of analysis ranging from the individual worker to the metropolitan region rather than being drawn from aggregate level statistics alone. Multilevel regression modeling is applied to take account of the interdependencies among these levels of aggregation. With regard to mode choice, the results indicate that the probability of driving an auto to work is lower in employment-rich metropolitan regions, and rises as the number of jobs per resident has grown strongly. Furthermore, women in most polycentric regions are less likely to commute as an auto driver. All else being equal, commute distances and times for auto drivers are longer in most polycentric regions than in monocentric urban areas. In addition, commute time as an auto driver rises with metropolitan size, whereas commute distance depends on employment density and the growth of the number of jobs per resident. The investigation shows that metropolitan structure, although significantly influencing commute patterns, explains only a small part of the variation of individuals’ commute behavior.
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    Topics: Geography , Economics
    Notes:   Economic competitiveness now has less to do with new materials than with new ways of producing, utilizing, and combining diverse knowledges. It is branded as symptomatic of a “new” economy and is often juxtaposed against the “old” economy. As accelerating technological change has greatly increased the volume and quality of the information available to organizations, to firms, and to individual employees, it is asserted that the economy has become more “new” than “old.” But this is predicated on the assumption that there is a “new” economy and that it is somehow distinguishable from the “old.” This paper explores the basis for this dichotomy and whether it really adds anything to understanding contemporary economies and their ongoing development. It will be argued that it is more useful and constructive to examine the economy through a lens dominated by service industries that are now the key drivers of change (innovation, competition, employment) and development. The paper is concluded with a discussion of some items that could usefully be part of an agenda for further research by economic geographers on the evolving spatial and structural attributes of service work and organizations and their impact on cities or regions at different scales of analysis.
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    Topics: Geography , Economics
    Notes:   With the passage of the Telecommunications Act of 1996, Congress directed the Federal Communications Commission and all fifty U.S. states to encourage the deployment of advanced telecommunication capability in a reasonable and timely manner. Today, with the rollout of advanced data services such as digital subscriber lines (xDSL), cable modems, and fixed wireless technologies, broadband has become an important component of telecommunication service and competition. Unfortunately, the deployment of last-mile infrastructure enabling high-speed access has proceeded more slowly than anticipated and competition in many areas is relatively sparse. More importantly, there are significant differences in the availability of broadband services between urban and rural areas. This paper explores aspects of broadband access as a function of market demand and provider competition. Data collected from the Federal Communications Commission is analyzed using a geographic information system and spatial statistical techniques. Results suggest significant spatial variation in broadband Internet access as a function of provider competition in the United States.
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    Topics: Geography , Economics
    Notes:   This article reports on an attempt to duplicate the results of “Regime, Polity, and Economic Growth: The Latin American Experience,” published in the Winter 1995 issue of Growth and Change. The original article used the Parks method to analyze cross section time series data, and concluded that after controlling for other relevant variables military governments have lower rates of economic growth than their civilian counterparts. Using data provided by the original researcher, and using various regression techniques including the Parks method, we were not able to reproduce the original results. We attribute this to problems in both the original data and regression techniques.
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    Topics: Geography , Economics
    Notes:   This essay reevaluates “Regime, Polity, and Economic Growth: The Latin American Experience,” published in Growth and Change 26 (1995): 77-104. Particularly, it reexamines three issues: data, estimation, and research design. Furthermore, it retests the same model with the same data through alternative estimation methods. The new results from the panel corrected standard errors (PCSEs) estimators, which are more rigorous than the Parks estimation, support and confirm the original finding that a civilian government in the eleven Latin American countries during the period of 1982-1988 was able to generate a higher economic growth rate than their military or military-civilian counterparts.
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    Topics: Geography , Economics
    Notes:   Population, employment, and income changes in a region comprised of eighteen nonmetropolitan counties of Maine, New Hampshire, Vermont, and New York are described using Bureau of Economic Analysis data covering 1970 to 2000. Changes at the county level are examined as net differences using pooled cross-section time series analysis. The specific focus of the empirical analysis is the effect that environmental amenities have in population and economic change. Empirical results indicate that a county's relative endowment of environmental amenities has positive economic change effects, but only when the county is relatively accessible as well. Further, the environmental amenity effects vary in their temporal consistency, even when accessibility is taken into account. In general, however, the reported results support the proposition that even relatively moderate environmental amenities can hold positive effects for economic change.
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