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  • Cell & Developmental Biology  (7,775)
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  • 1
    facet.materialart.
    Unknown
    In:  CASI
    Publication Date: 2018-06-09
    Description: A NASA report detailing a wind tunnel investigation of a variable camber and twist could effectively reduce drag, thus improving performance. The resulting VooDoo fin is made of composite materials, has a rigid internal spar and a flexible polymer exterior coating. It is computer-designed and exceptionally durable.
    Keywords: Aerodynamics
    Type: Spinoff 1994; 79; NASA-NP-214
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  • 2
    Publication Date: 2019-06-28
    Description: Any aircraft preliminary design study requires a structural model of the proposed configuration. The model must be capable of estimating the structural weight of a given configuration, and of predicting the deflections which will result from foreseen flight and ground loads. The present work develops such a model for the proposed Oblique All Wing airplane. The model is based on preliminary structural work done by Jack Williams and Peter Rudolph at Mdng, and is encoded in a FORTRAN program. As a stand-alone application, the program can calculate the weight CG location, and several types of structural deflections; used in conjunction with an aerodynamics model, the program can be used for mission analysis or sizing studies.
    Keywords: Aerodynamics
    Type: NASA-CR-202164 , NAS 1.26:202164
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  • 3
    Publication Date: 2019-06-28
    Description: The purpose of this investigation is to provide a comprehensive data base for the validation of numerical simulations. The objective of the present paper is to provide a tabulation of the experimental data. The data were obtained in the two-dimensional, transonic flowfield surrounding a supercritical airfoil. A variety of flows were studied in which the boundary layer at the trailing edge of the model was either attached or separated. Unsteady flows were avoided by controlling the Mach number and angle of attack. Surface pressures were measured on both the model and wind tunnel walls, and the flowfield surrounding the model was documented using a laser Doppler velocimeter (LDV). Although wall interference could not be completely eliminated, its effect was minimized by employing the following techniques. Sidewall boundary layers were reduced by aspiration, and upper and lower walls were contoured to accommodate the flow around the model and the boundary-layer growth on the tunnel walls. A data base with minimal interference from a tunnel with solid walls provides an ideal basis for evaluating the development of codes for the transonic speed range because the codes can include the wall boundary conditions more precisely than interference connections can be made to the data sets.
    Keywords: Aerodynamics
    Type: OTN-035236 , OTN-BIBL-AGARD-AR-303-Vol-2
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  • 4
    Publication Date: 2019-06-28
    Description: Hybrid grids, composed of structured and unstructured grids, combines the best features of both. The chimera method is a major stepstone toward a hybrid grid from which the present approach is evolved. The chimera grid composes a set of overlapped structured grids which are independently generated and body-fitted, yielding a high quality grid readily accessible for efficient solution schemes. The chimera method has been shown to be efficient to generate a grid about complex geometries and has been demonstrated to deliver accurate aerodynamic prediction of complex flows. While its geometrical flexibility is attractive, interpolation of data in the overlapped regions - which in today's practice in 3D is done in a nonconservative fashion, is not. In the present paper we propose a hybrid grid scheme that maximizes the advantages of the chimera scheme and adapts the strengths of the unstructured grid while at the same time keeps its weaknesses minimal. Like the chimera method, we first divide up the physical domain by a set of structured body-fitted grids which are separately generated and overlaid throughout a complex configuration. To eliminate any pure data manipulation which does not necessarily follow governing equations, we use non-structured grids only to directly replace the region of the arbitrarily overlapped grids. This new adaptation to the chimera thinking is coined the DRAGON grid. The nonstructured grid region sandwiched between the structured grids is limited in size, resulting in only a small increase in memory and computational effort. The DRAGON method has three important advantages: (1) preserving strengths of the chimera grid; (2) eliminating difficulties sometimes encountered in the chimera scheme, such as the orphan points and bad quality of interpolation stencils; and (3) making grid communication in a fully conservative and consistent manner insofar as the governing equations are concerned. To demonstrate its use, the governing equations are discretized using the newly proposed flux scheme, AUSM+, which will be briefly described herein. Numerical tests on representative 2D inviscid flows are given for demonstration. Finally, extension to 3D is underway, only paced by the availability of the 3D unstructured grid generator.
    Keywords: Aerodynamics
    Type: NASA-TM-106709 , NAS 1.15:106709 , ICOMP-94-19 , E-9071
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  • 5
    Publication Date: 2019-06-28
    Description: A three-dimensional computational fluid dynamics code, RPLUS3D, which was developed for the reactive propulsive flows of ramjets and scramjets, was validated for glancing shock wave-boundary layer interactions. Both laminar and turbulent flows were studied. A supersonic flow over a wedge mounted on a flat plate was numerically simulated. For the laminar case, the static pressure distribution, velocity vectors, and particle traces on the flat plate were obtained. For turbulent flow, both the Baldwin-Lomax and Chien two-equation turbulent models were used. The static pressure distributions, pitot pressure, and yaw angle profiles were computed. In addition, the velocity vectors and particle traces on the flat plate were also obtained from the computed solution. Overall, the computed results for both laminar and turbulent cases compared very well with the experimentally obtained data.
    Keywords: Aerodynamics
    Type: NASA-TM-106579 , E-8839 , NAS 1.15:106579
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  • 6
    Publication Date: 2019-06-28
    Description: An experimental investigation of the aerodynamic characteristics of thin, moderately swept fighter wings has been conducted to evaluate the effect of camber and twist on the effectiveness of leading- and trailing-edge flaps at supersonic speeds in the Langley Unitary Plan Wind Tunnel. The study geometry consisted of a generic fuselage with camber typical of advanced fighter designs without inlets, canopy, or vertical tail. The model was tested with two wing configurations an uncambered (flat) wing and a cambered and twisted wing. Each wing had an identical clipped delta planform with an inboard leading edge swept back 65 deg and an outboard leading edge swept back 50 deg. The trailing edge was swept forward 25 deg. The leading-edge flaps were deflected 4 deg to 15 deg, and the trailing-edge flaps were deflected from -30 deg to 10 deg. Longitudinal force and moment data were obtained at Mach numbers of 1.60, 1.80, 2.00, and 2.16 for an angle-of-attack range 4 deg to 20 deg at a Reynolds number of 2.16 x 10(exp 6) per foot and for an angle-of-attack range 4 deg to 20 deg at a Reynolds number of 2.0 x 10(exp 6) per foot. Vapor screen, tuft, and oil flow visualization data are also included.
    Keywords: Aerodynamics
    Type: NASA-TM-4542 , L-17272 , NAS 1.15:4542
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  • 7
    Publication Date: 2019-06-28
    Description: The NASA Langley 8-Foot Transonic Pressure Tunnel is a continuous-flow, variable-pressure wind tunnel with control capability to independently vary Mach number, stagnation pressure, stagnation temperature, and humidity. The top and bottom walls of the test section are axially slotted to permit continuous variation of the test section Mach number from 0.2 to 1.2, the slot-width contour provides a gradient-free test section 50 in. long for Mach numbers equal to or greater than 1.0 and 100 in. long for Mach numbers less than 1.0. The stagnation pressure may be varied from 0.25 to 2.0 atm. The tunnel test section has been recalibrated to determine the relationship between the free-stream Mach number and the test chamber reference Mach number. The hardware was the same as that of an earlier calibration in 1972 but the pressure measurement instrumentation available for the recalibration was about an order of magnitude more precise. The principal result of the recalibration was a slightly different schedule of reentry flap settings for Mach numbers from 0.80 to 1.05 than that determined during the 1972 calibration. Detailed tunnel contraction geometry, test section geometry, and limited test section wall boundary layer data are presented.
    Keywords: Aerodynamics
    Type: NASA-TP-3437 , L-17322 , NAS 1.60:3437
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  • 8
    Publication Date: 2019-07-17
    Description: A numerical investigation is carried out to determine the magnitude of wake radiation for a proposed Venus composition probe. One of the scientific goals of the mission is to determine the atmospheric composition of Venus by examining the intensity of scattered sunlight through the wake of the vehicle during planetary entry. In the wake of the vehicle, excited particles generated in the bow shock and boundary layers absorb and emit radiation. Thus, the purpose of this study is to determine if the radiation sensor will be able to sense the incoming solar radiative flux relative to the radiative flux generated in the wake. During portions of the entry trajectory the incident surface heat flux will be high enough to produce significant ablation. Ablation products such as CN are known to be strong radiators. Also, the ablation will be driven by strong radiation emanating from the bow shock. Thus, radiation and ablation will be coupled into the Navier-Stokes flow solutions.
    Keywords: Aerodynamics
    Type: AIAA 29th Thermophysics Conference; Jun 19, 1995 - Jun 22, 1995; San Diego, CA; United States
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  • 9
    facet.materialart.
    Unknown
    In:  Other Sources
    Publication Date: 2019-07-17
    Description: The ability to control the extent of laminar flow on swept wings at supersonic speeds may be a critical element in developing the enabling technology for a High Speed Civil Transport (HSCT). Laminar boundary layers are less resistive to forward flight than their turbulent counterparts, thus the farther downstream that transition from laminar to turbulent flow in the wing boundary layer is extended can be of significant economic impact. Due to the complex processes involved experimental studies of boundary layer stability and transition are needed, and these are performed in "quiet" wind tunnels capable of simulating the low-disturbance environment of free flight. At Ames, a wind tunnel has been built to operate at flow conditions which match those of the HSCT laminar flow flight demonstration 'aircraft, the F-16XL, i.e. at a Mach number of 1.6 and a Reynolds number range of 1 to 3 million per foot. This will allow detailed studies of the attachment line and crossflow on the leading edge area of the highly swept wing. Also, use of suction as a means of control of transition due to crossflow and attachment line instabilities can be studied. Topics covered include: test operating conditions required; design requirements to efficiently make use of the existing infrastructure; development of an injector drive system using a small pilot facility; plenum chamber design; use of computational tools for tunnel and model design; and early operational results.
    Keywords: Aerodynamics
    Type: Aerospace Ground Test Facilities and Flight Testing XXIX Short Course; Apr 25, 1994 - May 05, 1994; Tullahoma, TN; United States
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  • 10
    Publication Date: 2019-07-17
    Description: NASA Ames Research Center is pursuing the development of SOFIA, the Stratospheric Observatory For Infrared Astronomy. SOFIA will consist of a 2.5 meter telescope mounted aft of the wing of a Boeing 747 aircraft. Since a large portion of the infrared spectrum is not visible at ground level due to absorption by water vapor in the atmosphere below 40,000 feet, it is highly desirable to make observations above this altitude. SOFIA will provide the opportunity for astronomers to conduct high-altitude research for extended periods of time. Current study is focused on wind tunnel testing for the open cavity. If not controlled, air would create resonance and damage the telescope. For this reason, SOFIA will design a boundary layer control device to achieve laminar flow over the cavity. This also provides a clearer flow for seeing, thus improving resolution on infrared sources. Other effects being tested in the wind tunnel are aerodynamic torque loads on the telescope, and flutter loads on the tail.
    Keywords: Aerodynamics
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  • 11
    Publication Date: 2019-07-17
    Description: Experimental results for a two-dimensional separated turbulent boundary layer behind a backward facing step for five different Reynolds numbers are reported. Results are presented in the form of tables, graphs and a floppy disk for an easy access of the data. Reynolds number based on the step height was varied by changing the reference velocity upstream of the step, U(sub o), and the step height, h. Hot-wire measurement techniques were used to measure three Reynolds stresses and four triple-velocity correlations. In addition, surface pressure and skin friction coefficients were measured. All hot-wire measurements were acquired in a measuring domain which excluded recirculating flow region due to the directional insensitivity of hot-wires. The downstream extent of the domain from the step was 51 h for the largest and I 14h for the smallest step height. This significant downstream length permitted extensive study of the flow recovery. Prediction of perturbed flows and their recovery is particularly attractive for popular turbulence models since variations of turbulence length and time scales and flow interactions in different regions are generally inadequately predicted. The data indicate that the flow in the free shear layer region behaves like the plane mixing layer up to about 2/3 of the mean reattachment length when the flow interaction with the wall commences the flow recovery to that of an ordinary turbulent boundary layer structure. These changes of the flow do not occur abruptly with the change of boundary conditions. A reattachment region represents a transitional region where the flow undergoes the most dramatic adjustments to the new boundary conditions. Large eddies, created in the upstream free-shear layer region, are being torn, recirculated, reentrained back into the main stream interacting with the incoming flow structure. It is foreseeable that it is quite difficult to describe the physics of this region in a rational and quantitative manner other than statistical. Downstream of the reattachment point the flow recovers at different rates near the wall, in the newly developing internal boundary layer, and in the outer part of the flow. It appears that Reynolds stresses do not fully recover up to the longest recovery length of 114 h.
    Keywords: Aerodynamics
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  • 12
    Publication Date: 2019-07-17
    Description: Tail buffet studies were conducted on a full-scale, production, F/A-18 fighter aircraft in the 80- by 120-Foot Wind Tunnel of the National Full-Scale Aerodynamic Complex at NASA Ames Research Center at Moffett Field, California. Tail buffet data were acquired over an angle-of-attack range of +20 deg to +40 deg, a side-slip range of -16 deg to + 16 deg, and at wind speeds up to 100 knots. The maximum speed corresponds to a Reynolds number of l2.3 x l0(exp 6) based on mean aerodynamic chord and a Mach number of 0. 15. The port, vertical tail fin was instrumented with ninety-six surface-pressure transducers, arranged in six by eight arrays, on each side of the fin. ne aircraft was also equipped with a removable Leading-Edge Extension (LEX) fence whose purpose is to reduce tail-buffet loads. Current analysis methods for the unsteady aerodynamic pressures and loads are described. Only results for the zero side-slip condition are to be presented, both with and without the LEX fence. Results of the time-averaged, power-spectral analysis are presented for the tail fin bending moments which are derived from the integrated pressure field. Local wave velocities on the tail surfaces are calculated from pressure correlations. It was found that the LEX fence significantly reduces the magnitude of the root-mean-square pressures and bending moments. Scaling and repeatability issues are addressed by comparing the present full scale results for pressures at the 60%-span and 45%-chord location with previous full-scale F/A-18 tail-buffet test in the 80- by 120- Foot Wind Tunnel, and with several small-scale tests. The comparisons show that the tail buffet frequency scales very well with tail chord and free-stream velocity, and that there is good agreement with the previous full-scale test. Root-mean-square pressures and power spectra do not scale as well as the frequency results. Addition of a LEX fence caused tail-buffet loads to be reduced at all model scales.
    Keywords: Aerodynamics
    Type: SAE Aerospace Atlantic Conference; Apr 18, 1994 - Apr 22, 1994; Dayton, OH; United States
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  • 13
    Publication Date: 2019-07-17
    Description: The recent resurgence of interest in utilizing laminar flow on aircraft surfaces for reduction in skin friction drag has generated a considerable amount of research in natural laminar flow (NLF) and hybrid laminar flow control (HLFC) on transonic aircraft wings. This research has focused primarily on airfoil design and understanding transition behavior with little concern for the surface imperfections and manufacturing variations inherent to most production aircraft. In order for laminar flow to find wide-spread use on production aircraft, techniques for constructing the wings must be found such that the large surface imperfections present in the leading edge region of current aircraft do not occur. Toward this end, a modification to existing leading edge construction techniques was devised such that the resulting surface did not contain large gaps and steps as are common on current production aircraft of this class. A lowspeed experiment was first conducted on a simulation of the surface that would result from this construction technique. Preston tube measurements of the boundary layer downstream of the simulated joint and flow visualization using sublimation chemicals validated the literature on the effects of steps on a laminar boundary layer. These results also indicated that the construction technique was indeed compatible with laminar flow. In order to fully validate the compatibility of this construction technique with laminar flow, thus proving that it is possible to build wings that are smooth enough to be used on business jets and light transports in a manner compatible with laminar flow, a flight experiment is being conducted. In this experiment Mach number and Reynolds number will be matched in a real flight environment. The experiment is being conducted using the NASA Dryden F-104 Flight Test Fixture (FTF). The FTF is a low aspect ratio ventral fin mounted beneath an F-104G research aircraft. A new nose shape was designed and constructed for this experiment. This nose shape provides an accelerating pressure gradient in the leading edge region. By flying the aircraft at appropriate Mach numbers and altitudes, this nose shape simulates the leading edge region of a laminar flow wing for a business jet or light transport. Manufactured into the nose shape is a spanwise slot located approximately four inches downstream of the leading edge. The slot, which is an inch wide and one-eighth of an inch deep allows the simulation of surface imperfections, such as gaps and steps at skin joints, which will occur on aircraft using this new construction technique. By placing strips of aluminum of various sizes and shapes in the slot, the effect on the boundary layer of different sizes and shapes of steps and gaps will be examined. It is planned to use five different configurations, differing primarily in the size and number of gaps. Downstream of the slot, the state of the boundary layer is determined using hot film gages and Stanton gages. Agreement between these two very different techniques of measuring boundary layer properties is considered important to being able to state with confidence the effects on the boundary layer of the simulated manufacturing imperfections. To date, the aircraft has not flown. First flights of the aircraft are on schedule to begin October 4, 1993. Low-speed, preliminary experiments at matching Reynolds numbers have been completed.
    Keywords: Aerodynamics
    Type: AIAA 6th Biennial Flight Test Conference; Jun 20, 1994 - Jun 23, 1994; Colorado Springs, CO; United States
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  • 14
    Publication Date: 2019-07-13
    Description: Available redundancy among aircraft control surfaces allows for effective wing camber modifications. As shown in the past, this fact can be used to improve aircraft performance. To date, however, algorithm developments for in-flight camber optimization have been limited. This paper presents a perturbational approach for cruise optimization through in-flight camber adaptation. The method uses, as a performance index, an indirect measurement of the instantaneous net thrust. As such, the actual performance improvement comes from the integrated effects of airframe and engine. The algorithm, whose design and robustness properties are discussed, is demonstrated on the NASA Dryden B-720 flight simulator.
    Keywords: Aerodynamics
    Type: H-1998 , Automatic Control in Aerospace; 35-40|Aerospace Control; Sep 12, 1994 - Sep 16, 1994; Palo Alto, CA; United States
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  • 15
    Publication Date: 2019-07-18
    Description: A highly-instrumented UH-60A aircraft was tested at NASA-Ames Research Center from August 1993 to February 1994 obtaining an extensive data base for level flight, maneuvers, acoustics (both with respect to ground microphone arrays and inflight microphones), and flight dynamics. A majority of the data obtained are now in an electronic data base, however, only a small fraction of the data have been examined. The proposed paper will examine the issue of hovering steadiness in more detail. In particular, a single set of data obtained during ground acoustic testing may provide considerable insight as the wind speeds were measured at a hover height of 250 feet and the aircraft was positioned in 15 deg. steps in heading from 0 to 180 deg. Also, hover housekeeping data were obtained for many of the 31 flights and these will also allow a characterization of the unsteadiness. The variation in section lift will be examined in terms of the induced flow angle variation and this will be related to possible physical explanations.
    Keywords: Aerodynamics
    Type: AHS 51st Annual Forum and Technology Display; May 09, 1995 - May 11, 1995; Fort Worth, TX; United States
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  • 16
    Publication Date: 2019-07-18
    Description: Compressibility plays a significant role in the development of separation on airfoils experiencing unsteady motion, even at moderately compressible free-stream flow velocities. This effect can result in completely changed stall characteristics compared to those observed at incompressible speed, and can dramatically affect techniques used to control separation. There has been a significant effort in recent years directed toward better understanding; of this process, and its impact on possible techniques for control of separation in this complex environment. A review of existing research in this area will be presented, with emphasis on the physical mechanisms that play such an important role in the development of separation on airfoils. The increasing impact of compressibility on the stall process will be discussed as a function of free-stream Mach number, and an analysis of the changing flow physics will be presented. Examples of the effect of compressibility on dynamic stall will be selected from both recent and historical efforts by members of the aerospace community, as well as from the ongoing research program of the present authors. This will include a presentation of a sample of high speed filming of compressible dynamic stall which has recently been created using real-time interferometry.
    Keywords: Aerodynamics
    Type: 33rd AIAA Aerospace Sciences Meeting; Jan 09, 1995 - Jan 12, 1995; Reno, NV; United States
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  • 17
    Publication Date: 2019-07-17
    Description: This paper will describe the Airbreathing Hypersonic Research Program at NASA Ames Research Center. A main theme will be the "From Computation Through Flight" research effort. General research areas covered will include systems analysis, aerodynamics and aerothermodynamics, propulsion, materials, and flight research. Illustrative results from each discipline will be presented. The synergism between computational and experimental research will be demonstrated by examples. All examples given will have been published in the open literature.
    Keywords: Aerodynamics
    Type: AIAA Atmospheric Flight Mechanics Conference; Aug 01, 1994 - Aug 03, 1994; Scottsdale, AZ; United States
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  • 18
    Publication Date: 2019-07-17
    Description: A developed method has been applied to calculate accurately the viscous flow about airfoils normal to the free-stream flow. This method has special application to the analysis of tilt rotor aircraft in the evaluation of download. In particular, the flow about an XV-15 airfoil with and without deflected leading and trailing edge flaps at -90 degrees incidence is evaluated. The multi-element aspect of the method provides for the evaluation of slotted flap configurations which may lead to decreased drag. The method solves for turbulent flow at flight Reynolds numbers. The flow about the XV-15 airfoil with and without flap deflections has been calculated and compared with experimental data at a Reynolds number of one million. The comparison between the calculated and measured pressure distributions are very good, thereby, verifying the method. The aerodynamic evaluation of multielement airfoils will be conducted to determine airfoil/flap configurations for reduced airfoil drag. Comparisons between the calculated lift, drag and pitching moment on the airfoil and the airfoil surface pressure will also be presented.
    Keywords: Aerodynamics
    Type: AIAA Aerospace Sciences; Jan 09, 1995 - Jan 12, 1995; Reno, NV; United States
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  • 19
    Publication Date: 2019-07-17
    Description: Steady and unsteady viscous, three-dimensional flowfields are calculated using a thin layer approximation of Navier-Stokes equations in conjunction with Chimera overset grids. The finite-difference numerical scheme uses structured grids and a pentadiagonal flow solver called "OVERFLOW". The configuration of Boeing 747-200 has been chosen as one of configurations to be used as a platform for the SOFIA (Stratospheric Observatory For Infrared Astronomy). Initially, the steady flowfield of the full aircraft is calculated for the clean configuration (without a cavity to house telescope). This solution is then used to start the unsteady flowfield of a configuration containing cavity housing the observation telescope and its peripheral units. Analysis of unsteady flowfield in the cavity and its influence on the tail empennage, as well as the noise due to turbulence and optical quality of the flow are the main focus of this study. For the configuration considered here, the telescope housing cavity is located slightly downstream of the portwing. The entire flow-field is carefully constructed using 45 overset grids and consists of nearly 4 million grid points. All the computations axe done at one freestream flow condition of M(sub infinity) = 0.85, alpha = 2.5deg, and a Reynolds of Re = 1.85x10deg
    Keywords: Aerodynamics
    Type: AIAA Aerspace Sciences; Jan 02, 1995 - Jan 12, 1995; Reno, NV; United States
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  • 20
    Publication Date: 2019-07-17
    Description: The proposed paper presents flow visualization performed during experiments conducted on a full-scale F/A-18 aircraft in the 80- by 120-Foot Wind-Tunnel at NASA Ames Research Center. This investigation used both surface and off-surface flow visualization techniques to examine the flow field on the forebody, canopy, leading edge extensions (LEXs), and wings. The various techniques used to visualize the flow field were fluorescent tufts, flow cones treated with reflective material, smoke in combination with a laser light sheet, and a video imaging system. The flow visualization experiments were conducted over an angle of attack range from 20deg to 45deg and over a sideslip range from -10deg to 10deg. The results show regions of attached and separated flow on the forebody, canopy, and wings. Additionally, the vortical flow is clearly visible over the leading-edge extensions, canopy, and wings.
    Keywords: Aerodynamics
    Type: SAE Aerospace Atlantic Conference; Apr 18, 1994 - Apr 22, 1994; Dayton, OH; United States
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  • 21
    facet.materialart.
    Unknown
    In:  Other Sources
    Publication Date: 2019-07-17
    Description: It is stated that the aerodynamic forces on the vehicle being aerocaptured are controlled by "altering the angle of attack" and thereby controlling the lift coefficient. Furthermore, the resulting variation of drag coefficient with angle of attack was ignored. The purpose of this Comment is to point out that an aerodynamic control method that is much more effective than the pitch modulation has been studied and utilized during entries for many years. During aerocapture, it is desirable to have a large range of lift coefficients available, while keeping the vehicle's ballistic coefficients constant. This is accomplished by modulating the vehicle's bank angle, i.e., by rolling the vehicle about its velocity vector. By this method, the angle of attack can be held constant (at the trim angle, if desired), and the C(sub D) and the ballistic coefficient remain constant. Furthermore, the vertical component of the normal force vector (essentially the lift) can be varied over its entire range, from maximum positive to maximum negative values. Reaction controls, rather than aerodynamic ones, are usually utilized to change the bank angle of the vehicle, thus requiring the use of fuel. However, the fuel expenditure that is required to change the bank angle is far less than the amount that would have to be used to continuously hold the vehicle at pitch angles that differ significantly from its trim angle of attack. Also, it has been shown that bank angle modulation to vary the lift can enlarge the entry corridor by increasing the entry angle for the undershoot boundary, where both the heating rate and deceleration reach a maximum. Finally, the crew's deceleration tolerance can be increased somewhat when the bank angle is varied, as opposed to the pitch angle. For bank modulation, the deceleration force vector can be kept at a constant angle with respect to the occupants whose tolerance to g loads is highest when the force is applied in a direction normal to the upper torso. The advantages of bank angle variation to modulate the lift vector were recognized long ago, and this method of control was used successfully on the Apollo command module during lunar return' and, more recently, for the Space Shuttle Orbiter.
    Keywords: Aerodynamics
    Type: Journal of Guidance, Control, and Dynamics; 17; 4; 878-878
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  • 22
    Publication Date: 2019-07-18
    Description: Study of sonic and supersonic jet plumes are relevant to understanding such phenomenon as jet-noise, plume signatures, and rocket base-heating and radiation. Jet plumes are simple to simulate and yet, have complex flow structures such as Mach disks, triple points, shear-layers, barrel shocks, shock-shear-layer interaction, etc. Experimental and computational simulation of sonic and supersonic jet plumes have been performed for under- and over-expanded, axisymmetric plume conditions. The computational simulation compare very well with the experimental observations of schlieren pictures. Experimental data such as temperature measurements with hot-wire probes are yet to be measured and will be compared with computed values. Extensive analysis of the computational simulations presents a clear picture of how the complex flow structure develops and the conditions under which self-similar flow structures evolve. From the computations, the plume structure can be further classified into many sub-groups. In the proposed paper, detail results from the experimental and computational simulations for single, axisymmetric, under- and over-expanded, sonic and supersonic plumes will be compared and the fluid dynamic aspects of flow structures will be discussed.
    Keywords: Aerodynamics
    Type: AIAA Atmospheric Flight Mechanics Conference; Aug 07, 1995 - Aug 09, 1995; Baltimore, MD; United States
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  • 23
    Publication Date: 2019-07-17
    Description: Three direct numerical simulations of time-evolving turbulent plane wakes with velocity deficit Reynolds numbers of about 2,000 have been simulated using a spectral numerical method with up to 600 x 260 x 160 modes. The initial conditions for the simulations are generated from direct numerical simulations of a turbulent boundary layer (momentum thickness Reynolds number of 670), and varying amounts of additional two- dimensional, forcing. In order to preserve the self-similar flow evolution, the forcing is implemented by multiplying all the two-dimensional modes in the initial condition by a constant factor. In the "natural" case no additional forcing is used; in the "forced" and "heavily forced" cases this factor is 5 and 20, respectively. The wake spreading rate Is increased by factors of 1.7 and 7.1 for the two forced cases. The Reynolds stresses are also increased by a similar or even larger factor. These results indicate that the plane wake is much more sensitive to initial forcing than the plane mixing layer. As in the plane mixing layer, two-dimensional forcing promotes more organized large-scale vortical flow structures and these structures axe sometimes separated by "braid regions" containing streamwise "rib" vortices, unlike in the unforced wake.
    Keywords: Aerodynamics
    Type: Forty-Seventh Annual Meeting of the American Physical Society; Nov 20, 1994 - Nov 22, 1994; Atlanta, GA; United States
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  • 24
    Publication Date: 2019-07-17
    Description: Large-eddy simulation of the incompressible Navier-Stokes equations has been used to examine the long-time development of initially isotropic turbulence subjected to solid-body rotation. The simulations were carried out using a pseudo-spectral method with 128 x 128 x 512 collocation points in a computational domain that is four times larger along the rotation axis than in the other directions; subgrid-scale motions were parameterized using a spectral eddy viscosity model modified for system rotation. Simulation results show that the correlation length along the rotation am's of velocities orthogonal to the rotation vector exhibits rapid growth while the integral length-scale of velocities aligned with the rotation axis is relatively unaffected by rotation. Examination of the energy spectrum of two-dimensional, two-component motions indicates the presence of an inverse cascade of energy. System rotation also causes an alignment of vorticity along the rotation axis with relatively stronger cyclonic vorticity than anticyclonic. The onset of anisotropic effects are well characterized by Rossby numbers defined in terms of both macroscopic and microscopic quantities.
    Keywords: Aerodynamics
    Type: Forty-Seventh Annual Meeting of the American Physical Society; Nov 20, 1994 - Nov 22, 1994; Atlanta, GA; United States
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  • 25
    Publication Date: 2019-07-17
    Description: This paper will review the advances made recently in the Navier-Stokes CFD methods to simulate aerodynamics and aeroacoustics of helicopter rotors and rotor-body flows. Although a complete flowfield simulation of full helicopter is currently not feasible with these methods, impressive gains have been made in analyzing individual components of this complex problem in a very detailed manner. The use of the state-of-the-art numerical algorithms in solution methods, in conjunction with powerful supercomputers, like the Cray-2, have enabled noticeable progress to be made in modeling viscous-inviscid interactions, blade-vortex interactions, tip-vortex: simulation and wake effects, as well as high speed impulsive noise in hover and forward flight for isolated rotor blades. This paper will critically evaluate the presently available Euler and Navier-Stokes methods, both finite-difference and finite volume methods using structured and unstructured grids for helicopter applications for accuracy, suitability, and computational efficiency. The review will also include the recent progress made using overset grids to model rotor-body flows. All the material for this review will be drawn from the published material shown below.
    Keywords: Aerodynamics
    Type: International Colloquium on Vortical Flows in the Aeronautics; Oct 12, 1994 - Oct 14, 1994; Aachan; Germany
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  • 26
    Publication Date: 2019-07-17
    Description: In recent years significant advances have been made for parallel computers in both hardware and software. Now parallel computers have become viable tools in computational mechanics. Many application codes developed on conventional computers have been modified to benefit from parallel computers. Significant speedups in some areas have been achieved by parallel computations. For single-discipline use of both fluid dynamics and structural dynamics, computations have been made on wing-body configurations using parallel computers. However, only a limited amount of work has been completed in combining these two disciplines for multidisciplinary applications. The prime reason is the increased level of complication associated with a multidisciplinary approach. In this work, procedures to compute aeroelasticity on parallel computers using direct coupling of fluid and structural equations will be investigated for wing-body configurations. The parallel computer selected for computations is an Intel iPSC/860 computer which is a distributed-memory, multiple-instruction, multiple data (MIMD) computer with 128 processors. In this study, the computational efficiency issues of parallel integration of both fluid and structural equations will be investigated in detail. The fluid and structural domains will be modeled using finite-difference and finite-element approaches, respectively. Results from the parallel computer will be compared with those from the conventional computers using a single processor. This study will provide an efficient computational tool for the aeroelastic analysis of wing-body structures on MIMD type parallel computers.
    Keywords: Aerodynamics
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  • 27
    Publication Date: 2019-08-13
    Description: The performance of a workstation cluster used for the solution of the Reynolds-averaged Navier-Stokes equations is compared with a conventional vector supercomputer architecture. The application simulation of the steady flowfield about a transonic transport was computed using an implicit diagonal scheme in an overset mesh framework. Static load balancing was used, while coarse grain decomposition was achieved by solution of a grid zone per processor. Price/performance ratios are estimated for several scenarios in which such clusters may be utilized.
    Keywords: Aerodynamics
    Type: OAI/NASA Symposium Application of Parallel and Distributed Computing; Apr 18, 1994 - Apr 19, 1994; Columbus, OH; United States
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  • 28
    Publication Date: 2019-07-13
    Description: The aim of the present investigation is to characterize the motion of dendrite fragments falling under the influence of gravity in a uniform liquid medium at low Reynolds number. In an earlier study, Zakhem, Weidman and de Groh (1992) reported on the settling speed of model equiaxed dendrite grains released along their axis of symmetry. In this follow-up study uniaxial model dendrite grains were released off-axis to observe and document their motion at different orientations. It was hypothesized that the dendrite models might rotate when released off-axis in which case an attempt would be made to document the ensuing unsteady motion. This latter event turned out to be in fact true: at the small but finite Reynolds numbers that existed, each uniaxial dendrite slowly rotated towards its equilibrium orientation while failing under the influence of gravity. In addition to completing the original goal, we have made use of a beads-on-a shell Stokes flow code to numerically determine the drag coefficient for capsules, i.e.. uniaxial dendrites without arms. The drag on horizontally and vertically falling capsules are reported and compared with measurements.
    Keywords: Aerodynamics
    Type: NASA/CR-94-207107 , NAS 1.26:207107
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  • 29
    Publication Date: 2019-07-13
    Description: Supersonic jet plumes were studied using a two-equation turbulence model employing corrections for compressible dissipation and pressure-dilatation. A space-marching procedure based on an upwind numerical scheme was used to solve the governing equations and turbulence transport equations. The computed results indicate that two-equation models employing corrections for compressible dissipation and pressure-dilatation yield improved agreement with the experimental data. In addition, the numerical study demonstrates that the computed results are sensitive to the effect of grid refinement and insensitive to the type of velocity profiles used at the inflow boundary for the cases considered in the present study.
    Keywords: Aerodynamics
    Type: NASA-TM-111555 , NAS 1.15:111555 , AIAA Paper 92-2604 , Applied Aerodynamics Conference; Jun 22, 1992 - Jun 24, 1992; Palo Alto, CA; United States
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  • 30
    Publication Date: 2019-07-13
    Description: Results are obtained for cylindrical leading edges of proposed transatmospheric vehicles by employing a two-dimensional viscous shock-layer code for nonequilibrium gas flows. The accuracy and efficiency of the planar code is verified through detailed comparisons with other predictions. This study includes results for 6-deg half-angle bodies with nose radii ranging from 0.01 to 2.0 ft for both cylindrically blunted wedges and spherically blunted cones (included for comparison). Some results are presented as a ratio of the noncatalytic to the corresponding fully catalytic heating value to illustrate the maximum potential for a heating reduction in dissociated nonequilibrium flows. Generally, this ratio and the individual heating rates are smaller for cylindrically blunted wedges with small nose radii as compared to the spherically blunted cones (for the same nose radius). Therefore, a larger potential exists for heating reduction in cylindrically blunted as compared with the spherically blunted surfaces. However, the results presented at higher altitudes (where the slip effects become important) show that the spherically, blunted nose gives lower stagnation-point heating due to stronger merged shock-layer effects as compared with a cylindrically blunted nose.
    Keywords: Aerodynamics
    Type: NASA-TM-111564 , NAS 1.15:111564 , AIAA Paper 93-2751 , Thermophysics Conference; Jul 06, 1993 - Jul 09, 1993; Orlando, FL; United States
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  • 31
    Publication Date: 2019-07-13
    Description: The three-dimensional Reynolds-averaged, Navier-Stokes (RANS) equations are used to numerically simulate nonsteady vortical flow about a 65 degree sweep delta wing at 30 degrees angle of attack. Two large-amplitude, high-rate, forced-roll motions and a damped free-to-roll motion are presented. The free-to-roll motion is computed by coupling the time-dependent RANS equations to the flight dynamic equation of motion. The computed results are compared with experimental forces, moments, and roll-angle time histories. The overall agreement is good. Vortex breakdown is present in each case, which causes significant time lags in the vortex breakdown motions relative to the body motions. This behavior strongly influences the dynamic forces and moments.
    Keywords: Aerodynamics
    Type: NASA-TM-111611 , NAS 1.15:111611 , AIAA Paper 94-1884 , AIAA Applied Aerodynamics Conference; Jun 20, 1994 - Jun 22, 1994; Colorado Springs, CO; United States
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  • 32
    Publication Date: 2019-07-13
    Description: A study is described that evaluates the accuracy of vortex-lattice methods when they are used to compute the loads induced on aircraft as they encounter lift-generated wakes. The evaluation is accomplished by use of measurements made in the 80- by 120-foot wind tunnel of the lift, rolling-moment, and downwash in the wake of three configurations of a model of a subsonic transport aircraft. The downwash measurements are used as input for a vortex-lattice code in order to compute the lift and rolling moment induced on wings that have a span of 0.186, 0.510, or 1.022 times the span of the wake-generating model. Comparison of the computed results with the measured lift and rolling moment distributions are used to determine the accuracy of the vortex-lattice code. It was found that the vortex-lattice method is very reliable as long as the span of the encountering of following wing is less than about 0.2 of the generator span. As the span of the following wing increases above 0.2, the vortex-lattice method continues to correctly predict the trends and nature of the induced loads, but it overpredicts the magnitude of the loads by increasing amounts. The increase in deviation of the computed from the measured loads with size of the following wing is attributed to the increase in distortion of the structure of the vortex wake as it approaches and passes the larger following wings.
    Keywords: Aerodynamics
    Type: NASA-TM-111610 , NAS 1.15:111610 , AIAA-94-1839 , AIAA Applied Aerodynamics Conference; Jun 20, 1994 - Jun 22, 1994; Colorado Springs, CO; United States
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  • 33
    Publication Date: 2019-07-13
    Description: The viscous flow field near the surface of a hovering rotor blade was studied for blade twist distributions typical of a till rotor blade and a conventional helicopter rotor blade. Three blade geometries were studied, including a tilt rotor blade twist distribution (baseline), conventional helicopter rotor blade twist distribution, and the baseline twist distribution with 2 deg of precone. The results give insight into the delayed stall phenomenon often observed for highly twisted rotors. Calculations were performed for a high thrust condition near stall using the thin-layer Navier-Stokes CFD code TURNS. Effects of built-in twist on section force coefficients, skin friction, velocities, surface pressures, and boundary layer shape factor are discussed. Although the rotor thrust coefficient was nominally the same for the cases using the two twist distributions, large differences were found in the section in-plane and normal force coefficients. These preliminary results imply that the blade outboard region, rather than the inboard region, provides the majority of the performance advantage of the baseline case over the low twist case. Skin friction, velocities near the blade, and surface pressures for the two twist distributions reveal significant differences in the blade outboard region.
    Keywords: Aerodynamics
    Type: NASA-TM-111741 , NAS 1.15:111741 , Aeromechanics Specialists; Jan 19, 1994 - Jan 21, 1994; San Fransisco, CA; United States
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  • 34
    Publication Date: 2019-07-13
    Description: A hybrid method for computing compressible viscous flows is presented. This method divides the computational domain into two zones. In the outer zone, the unsteady full-potential equation (FPE) is solved. In the inner zone, the Navier-Stokes equations are solved. The two zones are tightly coupled so that steady and unsteady flows may be efficiently solved. The resulting CPU times are less than 50 percent of the required for a full-blown Navier-Stokes analysis. Sample applications of the method to an unswept iced wing at 4 deg and 8 deg angle of attack are presented. Surface pressures are in good agreement with the measurements obtained by Bragg et al. at the University of Illinois.
    Keywords: Aerodynamics
    Type: NASA-CR-201432 , NAS 1.26:201432 , AIAA Paper 94-0489 , AIAA Aerospace Sciences Meeting and Exhibit; Jan 10, 1994 - Jan 13, 1994; Reno, NV; United States
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  • 35
    Publication Date: 2019-07-13
    Description: Strong interactions between flow about an aircraft wing and the wing structure can result in aeroelastic phenomena which significantly impact aircraft performance. Time-accurate methods for solving the unsteady Navier-Stokes equations have matured to the point where reliable results can be obtained with reasonable computational costs for complex non-linear flows with shock waves, vortices and separations. The ability to combine such a flow solver with a general finite element structural model is key to an aeroelastic analysis in these flows. Earlier work involved time-accurate integration of modal structural models based on plate elements. A finite element model was developed to handle three-dimensional wing boxes, and incorporated into the flow solver without the need for modal analysis. Static condensation is performed on the structural model to reduce the structural degrees of freedom for the aeroelastic analysis. Direct incorporation of the finite element wing-box structural model with the flow solver requires finding adequate methods for transferring aerodynamic pressures to the structural grid and returning deflections to the aerodynamic grid. Several schemes were explored for handling the grid-to-grid transfer of information. The complex, built-up nature of the wing-box complicated this transfer. Aeroelastic calculations for a sample wing in transonic flow comparing various simple transfer schemes are presented and discussed.
    Keywords: Aerodynamics
    Type: NASA-CR-201433 , NAS 1.26:201433 , AIAA Paper 94-1587 , AIAA/ASME/ASCE/AHS/ASC Structures, Structural Dynamics, and Materials Conference; Apr 18, 1994 - Apr 20, 1994; Hilton Head, SC; United States
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  • 36
    Publication Date: 2019-07-13
    Description: A model of the Shuttle Orbiter rarefied-flow aerodynamic force coefficients has been derived from the ratio of flight acceleration measurements. The in-situ, low-frequency (less than 1Hz), low-level (approximately 1 x 10(exp -6) g) acceleration measurements are made during atmospheric re-entry. The experiment equipment designed and used for this task is the High Resolution Accelerometer Package (HiRAP), one of the sensor packages in the Orbiter Experiments Program. To date, 12 HiRAP re-entry mission data sets spanning a period of about 10 years have been processed. The HiRAP-derived aerodynamics model is described in detail. The model includes normal and axial hypersonic continuum coefficient equations as function of angle of attack, body-flap deflection, and elevon deflection. Normal and axial free molecule flow coefficient equations as a function of angle of attack are also presented, along with flight-derived rarefied-flow transition bridging formulae. Comparisons are made between the aerodynamics model, data from the latest Orbiter Operational Aerodynamic Design Data Book, applicable computer simulations, and wind-tunnel data.
    Keywords: Aerodynamics
    Type: NASA-TM-111566 , NAS 1.15:111566 , AIAA Paper 93-3441 , Applied Aerodynamics Conference; Aug 09, 1993 - Aug 11, 1993; Monterey, CA; United States
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  • 37
    Publication Date: 2019-07-13
    Description: Generation of significant side forces and yawing moments on an F/A-18 fuselage through tangential slot blowing is analyzed using computational fluid dynamics. The effects of freestream Mach number, jet exit conditions, jet length, and jet location are studied. The effects of over- and under-blowing on force and moment production are analyzed. Non-time-accurate solutions are obtained to determine the steady-state side forces, yawing moments, and surface pressure distributions generated by tangential slot blowing. Time-accurate solutions are obtained to study the force onset time lag of tangential slot blowing. Comparison with available experimental data from full-scale wind tunnel and sub-scale wind tunnel tests are made. This computational analysis complements the experimental results and provides a detailed understanding of the effects of tangential slot blowing on the flow field about the isolated F/A-18 forebody. Additionally, it extends the slot-blowing database to transonic maneuvering Mach numbers.
    Keywords: Aerodynamics
    Type: NASA-TM-111696 , NAS 1.15:111696 , AIAA Paper 95-1831 , AIAA Applied Aerodynamics Conference; Jun 20, 1994 - Jun 23, 1994; Colorado Springs, CO; United States
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  • 38
    Publication Date: 2019-07-13
    Description: An experimental survey of supersonic wing tip vortices has been conducted at Mach 2.5 using small performed 2.25 chords down-stream of a semi-span rectangular wing at angle of attack of 5 and 10 degrees. The main objective of the experiments was to determine the Mach number, flow angularity and total pressure distribution in the core region of supersonic wing tip vortices. A secondary aim was to demonstrate the feasibility of using cone probes calibrated with a numerical flow solver to measure flow characteristics at supersonic speeds. Results showed that the numerically generated calibration curves can be used for 4-hole cone probes, but were not sufficiently accurate for conventional 5-hole probes due to nose bluntness effects. Combination of 4-hole cone probe measurements with independent pitot pressure measurements indicated a significant Mach number and total pressure deficit in the core regions of supersonic wing tip vortices, combined with an asymmetric 'Burger like' swirl distribution.
    Keywords: Aerodynamics
    Type: NASA-CR-202591 , NAS 1.26:202591 , AIAA Paper 94-2576 , Aerospace Ground Testing; Jun 20, 1994 - Jun 23, 1994; Colorado Springs, CO; United States
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  • 39
    Publication Date: 2019-07-13
    Description: Digital flight records from reported clear-air turbulence incidents are used to determine winds and turbulence, to determine maneuver g loads, and to analyze control problems. Many cases of severe turbulence are found downwind of mountains and thunderstorms where sharp, sudden jolts are associated with vortices in atmospheric waves. Other cases of severe turbulence are round in strong updrafts above thunderstorm buildups that may be undetected by onboard weather radar. An important finding is that there are large maneuvering loads in over half of the reported clear-air turbulence incidents. Maneuvering loads are determined through an analysis of the short-term variations in elevator deflection and aircraft pitch angle. For altitude control in mountain waves the results indicate that small pitch angle changes with proper timing are sufficient to counter variations in vertical wind. For airspeed control in strong mountain waves, however, there is neither the available thrust nor the quickness in engine response necessary to counter the large variations in winds.
    Keywords: Aerodynamics
    Type: NASA-TM-111780 , NAS 1.15:111780 , AIAA Paper 92-4341 , Journal of Aircraft; 31; 4; 753-760|Atmospheric Flight Mechanics; Aug 10, 1992 - Aug 12, 1992; Hilton Head, SC; United States
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  • 40
    Publication Date: 2019-07-13
    Description: The effect of forebody tangential slot blowing on the flowfield about an F/A-18 aircraft is investigated numerically using solutions of the Navier-Stokes equations. Computed solutions are obtained for an aircraft geometry which includes the fuselage, a wing with deflected leading-edge flap, empennage, and a faired-over engine inlet. The computational slot geometry corresponds to that used in full-scale wind-tunnel tests. Solutions are computed using flight test conditions and jet mass flow ratios equivalent to wind-tunnel test conditions. The effect of slot location is analyzed by computing two nontime-accurate solutions with a 16-in. slot located 3 in. and 11 in. aft of the nose of the aircraft. These computations resolve the trends observed in the full-scale wind-tunnel test data. The flow aft of the leading-edge extension vortex burst is unsteady. A time-accurate solution is obtained to investigate the flow characteristics aft of the vortex burst, including the effect of blowing on tail buffet.
    Keywords: Aerodynamics
    Type: NASA-TM-111779 , NAS 1.15:111779 , AIAA Paper 93-2962 , Journal of Aircraft; 31; 4; 922-928|Fluid Dynamics, Plasmadynamics, and Lasers Conference; Jul 06, 1993 - Jul 09, 1993; Orlando, Fl; United States
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  • 41
    Publication Date: 2019-07-13
    Description: Floquet eigenanalysis requires a few dominant eigenvalues of the Floquet transition matrix (FTM). Although the QR method is used almost exclusively, it is expensive for such partial eigenanalysis; the operation counts and, thereby, the approximate machine-time grow cubically with the matrix order. Accordingly, for Floquet eigenanalysis, the Arnold-Saad method, a subspace iteration method, is investigated as an alternative to the QR method. The two methods are compared for machine-time efficiency and the residual errors of the corresponding eigenpairs. The Arnolds-Saad method takes much less machine-time than the QR method with comparable computational reliability and offers promise fpr large-scale Floquet eigenanalysis.
    Keywords: Aerodynamics
    Type: NASA-CR-203147 , NAS 1.26:203147 , Mathl. Comput. Modelling (ISSN 0895-7177); 19; 4-Mar; 69-73
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  • 42
    Publication Date: 2019-07-13
    Description: A 3-D compressible Navier-Stokes solver has been developed and applied to 3-D viscous flow over clean and iced wings. This method uses a third order accurate finite volume scheme with flux difference splitting to model the inviscid fluxes, and second order accurate symmetric differences to model the viscous terms. The effects of turbulence are modeled using a Kappa-epsilon model. In the vicinity of the sold walls the kappa and epsilon values are modeled using Gorski's algebraic model. Sampling results are presented for surface pressure distributions, for untapered swept clean and iced wings made of NACA 0012 airfoil sections. The leading edge of these sections is modified using a simulated ice shape. Comparisons with experimental data are given.
    Keywords: Aerodynamics
    Type: NASA-CR-202616 , NAS 1.26:202616 , AIAA Paper 94-0485 , Aerospace Sciences; Jan 10, 1994 - Jan 13, 1994; Reno, NV; United States
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  • 43
    Publication Date: 2019-07-13
    Description: The design of the high lift system has a major impact on the performance of an aircraft yet our understanding of the physics of this flow is still weak. Flow features include interactions between the wakes shed from the upstream elements and the pressure gradients and boundary layers of the downstream elements. Interaction of the turbulent wake of the main element and the flap can cause (1) separation of the flap boundary layer or (2) 'bursting' of the main airfoil wake. Although the first factor is at least partially understood, even the qualitative aspects of (2) remain to be determined. In order to study these phenomena at Reynolds numbers approaching those of flight, a thick high Reynolds number wake is created using a 24 foot flat plate in the long rectangular test section of a 4 ft. by 6 ft subsonic wind tunnel. The design and construction of this test section, plate, and accompanying flap is described. Results obtained in a quarter-scale model were used for design purposes and are also described. Construction of the full scale facility is complete and preliminary results are presented.
    Keywords: Aerodynamics
    Type: NASA-CR-203019 , NAS 1.26:203019 , AIAA Paper 94-2613 , Aerospace Ground Testing; Jun 20, 1994 - Jun 23, 1994; Colorado Springs, CO; United States
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  • 44
    Publication Date: 2019-07-13
    Description: Interest has increased recently in the thrust-producing capability of rotors at very high collective pitch angles. An early reference noted this behaviour in rotors and offered alternative models for section lift characteristics to explain it. The same phenomenon was coincidentally noted and used in a propeller code, resulting in very good correlation with static thrust data. The proposed paper will present experimental data demonstrating the pronounced persistence of thrust for propellers at increasing collective pitch angles. Comparisons with blade element/momentum theory will be made. These results are expected to point to the need to define (ultimately to explain) aerodynamic lift and drag behaviour in a rotating environment. Experimental measurements made by the U.S. Army Aeroflightdynamics Directorate at the Ames Research Center have shown that locally measured normal force coefficients along the span of a highly twisted rotor blade continue to increase at high values of collective pitch. In some cases these coefficients exceed expected values for the same type of airfoil tested under two dimensional conditions. To date no one to the authors' knowledge has defined the variation of C(n) with pitch for very high angles (to 45 deg) in a rotating environment and for a blade of reasonably high aspect ratio; however, total propeller thrust measurements support the idea that stalling does not occur in the same way as on a wing. This paper will present experimental data in the form of surface pressure distributions as well as flow visualization (microtufts) to explore the aerodynamic behavior of the rotating airfoil at high values of blade incidence. This paper also reviews experimental evidence and infers some high lift coefficient behavior from it. Comparisons between predicted thrust, utilizing modified airfoil characteristics and a blade element model, and measured thrust for both rotors and propellers that cover the extremes of collective pitch are shown and discussed.
    Keywords: Aerodynamics
    Type: AGARD Aerodynamic Conference; Oct 01, 1994; Berlin; Germany
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  • 45
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 34 (1994), S. 6-11 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A new class of materials based on a spirodilactam structure has been recently synthesized as part of research into new polymeric materials. Not only is the spirodilactam structure novel, but it was not even the intended product in the synthesis as originally designed. The polymerization process discovered by the reaction of 4-ketopimelic acid or its corresponding spirodilactone with primary amines opened a new field of polysprodilactam chemistry. This paper describes the chemistry leading to the discovery of spirodilactam-based polymers and initial applications in the area of thermoplastics and thermosets. Most recent developments to be covered include aromatic spirodilactams and isomeric spirodilactams.
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  • 46
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 34 (1994), S. 12-16 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Spirodilactam bisallylether is a new high temperature performance monomer. It melts at 154°C, and is thermally inactive in forming a homopolymer. However, it reacts readily with a bismaleimide via “ene” reaction. Therefore, it could be used as a comonomer and an effective toughening modifier for bismaleimide. The properties of the blends of spirodilactam bisallylether and 4,4'-bismaleimidodiphenyl-methane were studied. The cocured resins have high glass transition temperature, 〉 300°C. By adding 30 to 40 mole % of the bisallylether, the compact tension toughness of the bismaleimide was improved to 0.7 MPa-m1/2. Therefore, the resins have a combination of high glass transition temperature and toughness. They also showed good flexural properties. Despite the high water absorption, 5 to 7%, the resins retained high hot/wet flexural properties because of the high glass transition.
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  • 47
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 34 (1994), S. 59-68 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Four immiscible blend systems, styrene-maleic anhydride/styrene-acrylonitrile (SMA/SAN). styrene-maleic anhydride/acrylonitrile-butadiene-styrene (SMA/ABS), poly(vinylidene fluoride)/SAN (PVF2/SAN), and PVF2/ABS, were investigated. The effect of adding up to about 10 wt% of a third polymer that is miscible with each blend component, poly(methylmethacrylate) (PMMA), was determined. In every case, the addition of PMMA led to the improvement of properties such as tensile strength, tensile elongation, and notched impact strength. Furthermore, the addition of PMMA resulted in finer, more uniform dispersions of the primary blend components. The experimental results are interpreted in terms of interfacial activity of the common phase component, PMMA.
    Additional Material: 13 Ill.
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  • 48
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 34 (1994), S. 81-85 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Differential scanning calorimetry (DSC) was used to investigate the solid-state cure process of poly(phenylene sulfide)(PPS) resin. Virgin PPS resin in an open sample pan was cured in DSC cell. Either air or oxygen was used as a curing atmosphere. Cure temperatures were in the range of 200 and 250 °C, which are below the melting point of PPS resin. Cure temperature as well as atmospheric condition influenced the cure behavior of PPS in the solid state. Both the rate and the amount of cure increased with increasing cure temperature. On the other hand, the time to reach the maximum cure rate was independent of cure temperature. Changing the atmosphere from air to oxygen increased both the cure rate and the amount of cure. The size effect of PPS particles on the cure reaction was also discussed.
    Additional Material: 9 Ill.
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  • 49
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 34 (1994), S. 109-115 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Slow crack growth was measured in the perpendicular and parallel directions relative to the extrusion direction of the pipe. For five pipes from different manufacturers, the anisotropy factor, the lifetime to fracture in the perpendicular direction divided by lifetime in the parallel direction, varied from 1.2 to 4.7 for complete fracture and 1.4 to 4.0 for crack initiation. The degree of molecular orientation was determined by measuring the shrinkage that occured when a pipe specimen was heated near its melting point. The amount of shrinkage correlated with the anisotropy factor for slow crack growth. The shape change after shrinkage was related to the flow pattern of the resin during extrusion and the cooling rate after extrusion.
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  • 50
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    Polymer Engineering and Science 34 (1994), S. 135-140 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The complex Young's modulus, E*(ω), and the complex strain-optical coefficient, O*(ω), of poly(ether sulfone) (PES), polysulfone (PSF), and polyethermide (PEI), were measured over the frequency range 1 to 130 Hz. The data were analyzed with a modified stress-optical rule: The Young's modulus was decomposed into two complex functions, EG*(ω) and ER*(ω); the modified stress-optical coefficient, CR and CG, associated with the rubber (R) and glass (G) components, respectively, were determined. The results for six polymers, including polystyrene, poly(α-methyl styrene), and bisphenol A polycarbonate were compared with each other. One of the coefficients, CR, equivalent to the stress-optical coefficient in melts, mainly depended on the way in which phenyl groups were connected to the chain. The other, CG, was in the range of 20 to 40 Brewsters, and did not strongly depend on the details of polymer structure. The component function, EG*(ω), which was located in the glassy region and originated from the high glassy modulus, was almost the same in shape when plotted against ω with double logarithmic scales. The R component, ER*(ω), located at the long time end of the glass-to-rubber transition zone, was slightly sensitive to the molecular structure of polymers.
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    Polymer Engineering and Science 34 (1994), S. 159-165 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: While there is abundant evidence that the molecular weight distribution (MWD) of a linear polymer has an influence on the shape of the viscosity function, the ability to convert the viscosity function to an MWD has been questioned. Using strictly numerical techniques, we have shown that the viscosity function can be transformed to the MWD, but always with some distortion. However, distinct bimodality can be qualitatively preserved through both the MWD-viscosity and viscocity-MWD transforms.
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    Polymer Engineering and Science 34 (1994), S. 169-173 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: In microcellular plastics, an unfoamed skin that is integral with the foamed core can be created by allowing the nucleating gas to diffuse from the surfaces of a gas saturated specimen prior to foaming. In this paper, a semi-empirical model is proposed that predicts the skin thickness variation in microcellular foams as a function of gas desorption time. The model shows good agreement with experimental results on the polycarbonate-carbon dioxide system.
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    Polymer Engineering and Science 34 (1994), S. 174-189 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The present paper proposes “Deformation Characteristics” (DC) as a new deformation measure of screw extrusion processes, based on the Green deformation tensor. In contrast to previous strain measures heuristically proposed by Mohr, et al., Mckelvey, and Pinto and Tadmor, the new DC can naturally incorporate the demixing phenomena and systematically take into account the three-dimensional circulatory flow with the screw flight effect. Therefore, DC can be regarded as an improved strain measure. “Weighted Average Deformation characteristics” (WADC) is also proposed to indicate the overall deformation characteristics as a quantitative measure to the “goodness of mixing” of the extrusion process. The present paper includes discussion on delicate differences between DC and several other strain measures in case of the two-dimensional velocity approximation, and on the application of DC into a general three-dimensional velocity field obtained by a quasi-three-dimensional finite element analysis of extrusion processes. In determining WADC in the three-dimensional application, the residence time distribution function, including the three-dimensional circulatory flow effect, is used.
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    Polymer Engineering and Science 34 (1994), S. 229-237 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Non-isothermal flow is simulated in the screw and kneading disc elements in a modular co-rotating twin screw extruder. Methods of calculating mean temperature rises for individual elements are discussed and results are presented. The implications of non-isothermal operation for scale-up is discussed. A method is then described for making calculations in a modular co-rotating machine, that contains many different elements. Example calculations are given showing the tendency of larger machines to buildup greater temperatures when viscous heating is included.
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    Polymer Engineering and Science 34 (1994), S. 221-228 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A study of the influence of a compatibilizing agent on phase morphology development in a 75/25 polyethylene/polyamide-6 blend in a modular co-rotating twin screw extruder is presented. The development of phase morphology along the axis of the modular screw was observed by cooling the extruder and removing the polymer from the screw channels. Changes in phase morphology due to the addition of a compatibilizer have been investigated using scanning electron microscopy. Sufficient quantities of compatibilizing agent produce significant increases in the rate of mixing and also reduce the scale of the phase morphology. Much larger quantities (5%) than actually required for interface coverage are needed for rapid mixing. This seems to be due to the high viscosity of the matrix.
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    Polymer Engineering and Science 34 (1994), S. 251-251 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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    Polymer Engineering and Science 34 (1994) 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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    Polymer Engineering and Science 34 (1994), S. 260-265 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Penrose states that quantum effects can occur even in relatively large systems when energy differences remain small. This is just the situation with polymer materials. A quantum description by Penrose of the formation of quasi-crystals can be rewritten to apply to polymer crystallization. The implications of the need to take account of quantum effects are discussed. Another approach based on the quantization of energy levels in clusters of atoms offers a possible explanation of heat setting in nylon and polyester fibers. Finally some problems of the interpretation of quantum theory are discussed.
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  • 59
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A novel approach to a truly dynamic thermodynamics is proposed in which equilibrium is defined in terms of explicit time, distance, and acceptable error scales. This approach involves reformulating the second law of thermodynamics in terms of an excess energy that vanishes at equilibrium instead of an entropy that assumes some unknown maximum value. Excess energy is defined mathematically as the total Legendre transform of energy with respect to an independent set of extensive variables. Excess energy is effectively the free energy functional of a nonequilibrium system and is a function of the time, distance, and acceptable error scales. Elimination of entropy from thermodynamics requires recognizing temperature as a thermal stress, proportional to the antimetric component of the stress tensor that is neglected when one assumes the validity of Cauchy's second law of motion. The inclusion of temperature as part of the stress-strain couple completes the science of thermomechanics and opens the way for a practical unification of chemistry and physics in strictly mechanical terms.The last sentence of the abstract shows how high the goals that Lindem meyer set for himself were. I personally do not agree with the idea that mechanics is the queen of all sciences, and that given deep enough probing one could achieve “a practical unification of chemistxy and physics in strictly mechanical terms”; for instance, electromagnetism has full citizenship's rights in physics, and it is hard to conceive that it could be reduced to mechanics.
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  • 60
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    Keywords: Chemistry ; Chemical Engineering
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    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The interfacial strength of two paper-polypropylene-paper laminates used for electrical power transmission cable insulation has been measured using a peel test after a variety of conditionings that simulate the service thermal stress conditions. Immersion in dielectric oil at 23°C causes little decrease in peel strength, but heating in the oil at 90°C causes a rapid initial loss followed by a slow loss of strength. Cyclic and static heating show that cyclic fatigue is not a factor as the initial loss of strength occurs in a time comparable to the first two test cycles and further heating causes much less loss of strength. Tensile and compressive stresses resulting from cable winding have no effect on the loss of bond strength during heating in oil. Vacuum drying of the laminate and oil (as in cable manufacture) before heating results in less decrease in peel strength than heating without prior drying. Optical and electron microscopy show minimal wetting of the paper fibrils by the polypropylene with only a few having been either normal to or at a steep angle to the polypropylene surface. That is, the fibrils appear to be parallel to the interface and only partially immersed in the polypropylene. Micrographs show little, if any, differences between the interfaces on the two sides as well as little paper on the polypropylene after delamination and vice versa. It is suggested that the bonding mechanism is a combination of weak mechanical interlocking and secondary bonds. It is also suggested that swelling of the polypropylene relative to the paper by the dielectric oil at 90°C weakens the interfacial bond.
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    Polymer Engineering and Science 34 (1994), S. 290-300 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Variations of stress with temperature for stretched networks of trans-polyisoprene networks in the crystallization region are reported. Such profiles are characteristically U-shaped with the stress at lower temperatures often climbing to high levels. Valley widths of the profiles narrow as annealing temperature increases to about 50°C, then widen at yet higher temperatures. The degree of crystallization at 22°C is 37% and independent of deformation and annealing temperature. The β crystal form is overwhelmingly present with traces of other crystal forms appearing only at high deformations. The theory of stress-induced crystallization provides a good description of experimental results provided the nucleation parameter σ is dependent upon deformation. Therefore, the data provide good qualitative support for the theory in its current form.
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  • 62
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    Notes: Polyalkylenebenzoxazoles of high molecular weight (inherent viscosity values from 0.76 to 2.95) were prepared from 4,6-diaminoresorcinol dihydrochloride and aliphatic diacids in polyphosphoric acid by heating at 180 to 200°C for 3-5 h. Melting points of the polymers ranged from 148 to 423°C, depending on the length of the alkylene chain. Glass transition temperatures were relatively low, ranging from 50 to 100°C and did not show the pronounced odd/even effect noted for melting points. In all cases, rapid weight loss occurred above 400°C. No evidence for the formation of a molecular composite was observed in an attempt to prepare in situ a rod-like polybenzoxazole in a polyalkylenebenzoxazole.
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    Polymer Engineering and Science 34 (1994) 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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    Polymer Engineering and Science 34 (1994), S. 93-101 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Low levels of oligomer molecules are generally desirable in polymeric materials. It is known that several reactor variables can affect the oligomer distribution, and therefore it is useful to have predictive models for molecular weight distribution. The normal approach of a differential equation-based model is very complex to set up if it is applied rigorously to include all the non-Flory aspects of the step growth polycondensation and in particular the interfacial polycarbonate polymerization. In this paper, simple methods based on the Monte Carlo method and Stockmayer distribution are applied to simulate the effects of mass-transfer, unequal reactivity, and the starting stoichiometry of the polycondensing functional groups on the oligomer distribution. It is shown that these parameters can have a significant effect on the oligomer weight distribution and polydispersity of the final polymer.
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    Polymer Engineering and Science 34 (1994), S. 308-317 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The true crystallite modulus of polyoxymethylene (POM) was evaluated experimentally and thoeretically as a function of temperature. The mechanical deformation mechanism of POM was lattice-dynamically predicted and confirmed by measuring the stress-induced vibrational frequency shifts of the infrared and Raman spectra, which were interpreted on the basis of anharmonic potential field.
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    Polymer Engineering and Science 34 (1994), S. 141-152 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The ultra-high strength/modulus, extended chain polyethylene fiber (Spectra® fiber) composite has shown great potential as a lightweight armor material with its extraordinary capability of absorbing the kinetic energy of projectiles. But the relatively low melting point of this fiber (∼ 145°C) has caused concerns regarding the effect of temperature rise during the impact/penetration process on the performance as armor material. In this article, an analysis of temperature rise in projectile and the fiber composite during the impact/penetration process is described. Combining the simulation of impact deformation by finite element analysis and the simulation of temperature rise by a finite difference approximation of the related dynamic equations, the temperature rise caused by the projectile/composite interaction was estimated. Results show that there is a significant temperature rise at the projectile/composite interface due to the friction but that the short length of time involved in the process and the low thermal conductivity of Spectra fiber composite keep the temperature rise in a very small region (in the order of 0.001 cm) around the interface during the impact/penetration process. Consequently, the volume that is affected by the temperature rise is very small, in the order of total 0.001 cm3 around the projectile, and this is too small to generate any detectable effect on the armor performance. After the projectile is stopped, however, substantial heating of fiber composite can occur under specific conditions as the result of heat flow from the hot projectile embedded in the composite. This heating of fibers, however, is a postmortem effect and hence inconsequential to the ballistic performance of the composite armor.
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    Polymer Engineering and Science 34 (1994) 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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    Polymer Engineering and Science 34 (1994), S. 190-200 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A mathematical model of a polycondensation reactor that can be used in the final stage for poly(ethylene terephthalate) (PET) is established and compared with experimental data obtained from a laboratory scale reactor with film renewal. Detailed side reactions are considered along with the diffusional removal of the small molecules through thin film. Among several kinetic constants, the polycondensation reaction rate constant k1(= k8) and diester group degradation reaction rate constant k7 have an influence over the degree of polymerization. The values of k1(= k8) and k7 for 0.05 wt% Sb2O3 were obtained as curve-fit values: (1) k1(= k8) = 3.4 × 106 exp(- 18.500/RT′) (L/mol-min); (2) k7 = 1.3 × 1011 exp(- 37,800/RT′) (min-1). Effects of the film exposure time, reduced pressure of vacuum, temperature, the initial terephthalic acid (TPA)/ethylene glycol (EG) mole ratio, the initial degree of polymerization, and catalysts were well explained by the model.
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    Polymer Engineering and Science 34 (1994), S. 209-212 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Entrance pressure losses for the creeping flow of a power-law fluid are calculated for an abrupt contraction of ratio 2, 4, 8 and ∞ for both the axisymmetric and planar cases using P2P1 and P+2P1 finite elements. Contrary to some earlier findings in the literature, the entrance pressure loss obtained by using the two different types of finite elements, both of which satisfy the Babus̆ka-Brezzi condition, are found to converge to the same results. The present results also confirm that the variational method of Duda and Vrentas gives excellent upper bounds for both the axisymmetric and planar cases with infinite contraction ratio.
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    Polymer Engineering and Science 34 (1994), S. 405-413 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The curing of epoxy-amine polymer has been modeled by the reaction of functional groups, and the mole balance of these is governed by a set of six nonlinear differential equations. In this work, we have first developed a complete analytical solution for isothermal curing. For nonisothermal curing, we have divided the domain of hydroxyl group concentration β into small increments Δβ and adopted our analytical results for this domain. In addition, we solved the energy balance equation analytically and obtained the temperature rise for Δβ. We have compared our results with those obtained from the Runge Kutta numerical solutions. We have shown that our semianalytical technique is about a thousand times more efficient and faster.
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    Polymer Engineering and Science 34 (1994), S. 513-518 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A shear test is proposed as a complement to the tensile test in order to characterize the short time mechanical behavior of thermoplastic polymers. The proposed test geometry makes the test easy to perform and to evaluate and gives relevant information about anisotropy, plastic deformation, crack initiation, and propagation properties. Three different materials have been tested and the results are discussed.
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    Polymer Engineering and Science 34 (1994), S. 500-506 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Material property models for poly(etheretherketone) (PEEK) have been combined with a residual stress model to provide a means for investigating the effect of crystallization process on the residual stress development in semicrystalline materials. The analysis shows that crystallization causes an increase in the residual stress levels. This increase is affected through an increase in the resin modulus values and through the resin modulus build-up at higher temperatures. The shrinkage due to crystallization was found to have no effect on the residual stress development in neat PEEK.
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    Notes: Temperature sweeps of dynamic viscoelastic properties have shown that phydroxybenzoic acid (PHB)-based liquid crystalline polyesters, specifically in this case those copolymerized with poly(ethylene terephthalate) (PET), can be subjected to considerable supercooling if initial heating curves are compared to subsequent cooling curves, indicating that this type of material can be in quite different states even at the same temperature, depending on thermal history. Utilizing this supercooling behavior, viscoelastic properties of a 60 mol% PHB/40 mol% PET material produced by Unitika were monitored before and, particularly, after large-scale shear deformation to determine how potential structure changes induced by the shear are reflected in viscoelastic properties immediately, and with time. According to dynamic viscoelastic temperature sweep data four quite different initial states were employed including conditions with, as well as largely free of, crystallites. However, in all cases, post-shear monitoring showed decreased G′ and G″ values with almost no evidence of return towards initial values within approximately 25 min. These results, in addition to furthering somewhat the fundamental understanding of the flow and relaxation properties of liquid crystalline polymers, may be useful in polymer processing, where large-scale shear deformations employed in forming processes appear to be capable of changing considerably the subsequent behavior of such materials.
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    Polymer Engineering and Science 34 (1994), S. 507-512 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A thermodynamic model was proposed to correlate the phase behavior of a swelling polymeric gel (vinyl alcohol-sodium acrylate copolymer) and the volume phase transition in alcohol (methanol, ethanol or propanol)-water solutions. The model is based on the Flory-Huggins formula for polymer solution coupled with the osmotic pressure by rubber elasticity proposed by Flory. The volume change behavior and the equilibrium concentrations inside and outside the gel were successfully correlated using the present model.
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    Polymer Engineering and Science 34 (1994), S. 528-531 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Terpolymerization was investigated by dilatometry for zincacrylate (ZnA2), acrylonitrile (AN), and styrene (St), radically initiated by a As2S3-styrene complex (I) in dimethyl sulphoxide (DMSO), at 90 ± 0.1°C for 1 h under inert atmosphere. The system follows non-ideal kinetics, due to primary radical termination as well as a degradative chain transfer reaction. The kinetic expression for the system is Rpα(I)0.27 (St)0.31 (AN) 0.22[ZnA2]0.12. The value for the activation energy and kp2/kt are 55 kJ mol-1 and 1.87 × 10-7 1 mol-1 s-1 respectively. The terpolymer has been characterized by IR and NMR spectroscopy. The thermal stability and solubility of the terpolymer have also been studied.
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    Polymer Engineering and Science 34 (1994) 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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    Polymer Engineering and Science 34 (1994), S. 551-558 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The intermeshing counterrotating twin screw extruder is widely used for compounding, devolatilization, blending, and reactive extrusion. A fluid dynamics analysis package-FIDAP, using the finite element method, was implemented to simulate the 3-D flow patterns in the region of conveying elements and shearing discs of a Leistritz LSM30.34 twin screw extruder. The rheological behavior of the fluid was described by a power law model. The flow fields were characterized in terms of velocity profiles, pressure distributions, shear stresses generated, and a parameter λ quantifying the elongational flow components. The influence of screw rotational speed and axial pressure difference on the flow characteristics was also analyzed. A comparison between the flow characteristics in the shearing discs operated in a corotating or counterrotating mode was also presented.
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    Polymer Engineering and Science 34 (1994), S. 532-540 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A model for the phase distribution and evolution of the heterogeneous (suspension) polymerization of vinyl chloride is presented. Experimental information on pressure, temperature, and conversion has been obtained from a 34 liter bench reactor reproducing reaction conditions and product properties typical of industrial operation. A calculation procedure based on simple plant data is proposed for the description of the phase compositions and their evolution over the entire process. Results based on classical Flory-Huggins theory of solutions are presented and compared with existing data.
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    Polymer Engineering and Science 34 (1994), S. 559-569 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A mathematical model is presented for the computer simulation of multilayer flow of polymer melts in coexitrusion. The proposed model can handle an arbitrary number of layers. The viscosity of each layer is shear-rate and temperature dependent. Given the material properties, die dimensions, and process conditions, the model determines the flow field throughout the die gap. Computer simulations and experimental data are presented for a three-layer polyester/EVA/polyester film coextrusion, with emphasis on the interfacial instability and its effects on optical properties of the film. The rsults are discussed in the context of the critical interfacial shear stress criterion that has been proposed by Schrenk, et al. (1) for the onset of interfacial instability. It appears that elasticity differences between layers contribute to the interfacial instability. It is conjectured that minimizing interfacial shear stress and matching elasticities of adjacent layers is an appropriate criterion in coextrusion analysis.
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    Polymer Engineering and Science 34 (1994), S. 541-550 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A simple unified lubrication approach has been proposed to design a coat-hanger die that can deliver wide and uniform liquid sheets. This approach requires that the wall stress in the manifold be constant. With this constraint, any inelastic non-Newtonian fluid model can be used to describe the liquid motion inside the die. Fluid models that can represent the pseudoplastic or viscoplastic behavior of polymeric liquids have been selected for illustration. A general equation that can be solved to determine the effect of production variations on flow uniformity inside the die has also been derived.
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    Polymer Engineering and Science 34 (1994), S. 570-579 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: In this paper we address the aspects associated with shear modification of low density polyethylene by extrusion. By successive passes of the polymer through an extruder it can be shown that both the melt viscosity and melt elasticity are reduced by shear modification. These reversible variations are not accompanied by significant changes in molecular weight distribution. The major effects of extrusion are to decrease the amount of elastically effecitve material. Study of proton relaxation times at 150°C shows that the melt comprises regions of relatively ordered, entangled, and unentangled polymer. Shearing reduces the proportion of more ordered material. The elastically effective anchors that are reduced by shearing are regions with restricted segmental mobility rather than conventional entanglements or intermolecular knots. Successive extrusions produce a relatively small decrease in the number of such constraints to molecular motion. Repeated shearing has a diminishing effect on the proportion of more ordered material in the polyethlene melt. This parallels observations of the effects of repeated shear modification on the properties of polyethylene films and other extrudates.
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    Polymer Engineering and Science 34 (1994), S. 585-597 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: This paper presents the design and analysis of a process control strategy for a reactive extrusion polypropylene degradation process. The primary control objective is to continuously produce polypropylene with desired properties (viscosity) despite variations in the properties of the feed material. The viscosity of the polypropylene, measured using an In-line Wedge Rheometer, is controlled by manipulating the feed concentration of the peroxide which acts as the initiator for the degradation reaction. An empirical model of the reactive degradation process is developed which describes the process dynamics and the characteristic process disturbances. Minimum variance (MV), constrained minimum variance (CMV), and pole placement (PP) controllers are first evaluated and compared in simulation. Then, a pole placement controller is implemented on the actual reactive extrusion process, with results being presented for the response of the controlled process to load disturbances due to feed material changes.
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    Polymer Engineering and Science 34 (1994) 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 84
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    Polymer Engineering and Science 34 (1994), S. 580-584 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A sliding plate rheometer has been developed to measure the normal thrust of a molten plastic in large amplitude oscillatory shear. The normal thrust of a molten plastic in large amplitude oscillatory shear is a significant nonlinear effect that has previously been unobtainable. Normal thrust measurements may now be used to help understand and characterize nonlinear viscoelastic behavior inherent in most molten plastics. The new rhemoeter incorporates a piezoelectric pressure transducer in a very stiff plate that minimizes compliance. Normal thrust measurements with cone and plate rheometers are made by measuring the total force on the plate (or cone) and are subject to error due to edge effects. The new rheometer measures the local pressure in the sample and is therefore unaffected by sample size or edge effects. Normal thrust measurements in large amplitude oscillatory shear are reported for both molten Phillips TR480 high density polyethylene pipe resin which contains 2% by weight of carbon black filler and IUPAC LDPE X. Crosstalk due to shear stress on the active face of the pressure transducer causes signal error which for oscillatory shear is filtered out using a discrete Fourier transform.
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    Polymer Engineering and Science 34 (1994), S. 613-624 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: At 75/25 concentration ratio, bisphenol a polycarbonate (PC)/styreneacry-lonitrile copolymer (SAN) blend has poor impact resistance compared to PC/ABS. A rubber phase methacrylate-butadiene-styrene (MBS) of core/shell type was dispersed in PC/SAN blend. The morphology of the unmodified and modified blend was investigated. The influence of the acrylonitrile ratio in the SAN on the microstructure was studied. It clearly shows that core/shell resides at the interface between PC and SAN. It seems that core/shell particles enhance the adhesion between the different phases. Their presence influences the interface mobility; i.e., the coalescence of the dispersed phase observed in pure PC/SAN is considerably reduced when the MBS particles are added. The impact resistance of the samples was correlated with the morphology.
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    Polymer Engineering and Science 34 (1994), S. 598-612 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: This paper presents the development of a model for free radical initiated polypropylene degradation during reactive extrusion that combines a kinetic model of the polypropylene degradation reaction with a simplified model of the melting mechanism in the extruder. The free radical initiated degradation of polypropylene is characterized by a narrowing of the molecular weight distribution (MWD) and a decrease in the molecular weight averages. A high temperature SEC is used to determine MWD's for three different commercially available polypropylenes degraded at various initiator concentrations in a 1.5 inch single screw extruder (L/D = 24:1). The predictions of the kinetic model alone and the combined kinetic-melting model are compared with the experimentally determined MWD's and molecular weight averages for the degraded polypropylenes. The predictions of a modified kinetic model that includes the possibility of termination by combination are also examined. The kinetic-melting model is found to provide significantly improved predictions of the experimentally determined MWD's and molecular weight averages in comparison to the original kinetic model. A viscosity-molecular weight relationship is also developed, which is then used to determine the gain of the degradation process as a function of the initiator concentration from the molecular weight averages predicted by the kinetic-melting model. Earlier work has shown such prior knowledge of the process gain can be used to significantly improve the performance of process control schemes for the degradation process.
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    Polymer Engineering and Science 34 (1994), S. 625-631 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The curing and vitrification effect during the reaction of ATBN modified epoxy resin was studied through the dynamic differential scanning calorimetry method and a new reaction kinetic equation containing generalized WLF equation was developed to describe the reaction rate at both glassy and rubbery state. An autocatalytic mechanism was found to describe adequately the cure kinetics of the rubber modified epoxy resin and the overall order of reaction was assumed to be 2. The kinetic parameters were determined from the DSC data through the Marquardt's multivariable nonlinear regression method and Runge-Kutta integration technique. The presence of rubber indicated minor effect on the cure kinetics of epoxy resin. The Arrhenius type viscosity function was employed to establish a relationship between viscosity data measured by RMS and chemical conversion calculated from the reaction kinetic equation.
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    Polymer Engineering and Science 34 (1994), S. 642-649 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Polyurethane foam formation involves both polymerization and expansion processes. The dynamics of the water and R-11 blown foams depend on the rates of chemical and physical blowing processes, along with the rate of viscosity increase of the reacting mixture. Experiments were carried out to study the dynamics of free rising, water and R-11 blown rigid polyurethane foams. The density and temperature change during the foam formation were monitored. A theoretical model was developed to predict the density and temperature variation with time. In the model, the physical blowing agent (R-11) evaporation process is assumed to be heat generation-controlled and the carbon dioxide generation process to be controlled by the rate of the water-isocyanate reaction. The kinetic parameters of the reactions of isocyanate with polyol and water were obtained separately and were asssumed to be independent of each other. The water-isocyanate reaction appears to follow first-order kinetics with respect to concentration of water. The theoretical predictions of the model show good agreement with the experimental data for density variation with time. The model predictions for temperature rise also match experimental data, except at the later stages of foaming when it is found to be slower than the experimental measurements. However, this deviation does not affect the dynamics of density change since it occurs after the completion of the expansion process.
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    Polymer Engineering and Science 34 (1994), S. 657-664 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A good extrusion die must distribute the polymer melt in the flow channel such that the material exits from the die with a uniform velocity and temperature. Coathanger dies are commonly used for the extrusion of plastic sheets and films. The die is usually provided with a straining bar allowing a regulation of the flowrate in the case of a poor design. But this, in turn, can affect temperature uniformity. Therefore, the design of coathanger die is a complex task which is mainly accomplished by trial and error in industry. Analyses of the flow in coathanger dies have been reported in the literature. Analytical and numerical approaches are used to solve this problem. The first one involves many simplifying assumptions: the most important ones being the unidirectional and isothermal flow of the polymer. Most numerical methods deal with a 2-D geometry, but only a few of them have considered the non-isothermal flow. A new model has been developed using a modified FAN method (Flow Analysis Network introduced by Tadmor) for the calculation of the 2-D flow, coupled with a finite-difference scheme for the calculation of temperature. The overall model can run on a PC with only a few minutes of calculation. Good agreement was obtained between experimental data and simulations.
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    Polymer Engineering and Science 34 (1994), S. 650-656 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A new finite element model named Corrected Slice Method (CSM) has been developed to cope with three-dimensional vacuum cooling calibrator problems. Such problems appear whenever the cooling channel lay-out comprises transverse channels in the calibrator. The CSM is an extension of the 2D approach (8), which takes into account the axial heat fluxes within the calibrator. The proposed model was validated by comparing the numerical results obtained on a test problem with a rigorous finite element approach. Moreover, a real complex profile-calibrator system was simulated in order to illustrate the full performance of the porposed method.
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    Polymer Engineering and Science 34 (1994), S. 665-670 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The use of bend testers for the determination of critical strains in the study of environmental stress cracking has been assessed. Using the combination of polystyrene in ethanol, various factors affecting the measurement of critical strains were investigated, including the strain applied during the bend testing, the time of immersion in the liquid prior to straining, the surface finish, and the extent of physical aging. It was concluded that the best determination of critical strain is the strain at which a sample just shows signs of crazing, rather than the strain at the outer edge of a band of crazes. The measured value of critical strain increases with increased prior immersion time, decreased surface roughness, and decreased physical aging time. Reasons for these variations are discussed. It is concluded that although the use of bend testers is valuable for qualitative testing, careful testing methodologies need to be adopted for it to be a useful quantitative test.
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    Polymer Engineering and Science 34 (1994), S. 632-641 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The dynamics of R-11 blown polyurethane foam formation depend on the rates of viscosity increase of the reacting mixture and R-11 evaporation, and both are controlled by the polymerization process. Detailed experiments were carried out to study the dynamics of foaming and the measurements made included the cream and rise times, the density change of the expanding foam with time, and the temperature rise during reaction. Dynamic temperature measurements at different points in the foaming mixture were also made to study the spatial variation of the temperature in the foam. The experimental results showed the rate of foaming, the final density, and the maximum temperature decreased with increasing R-11 concentration. The heat losses from the foam were also found to be significant towards the later stages of foaming when density was low. Theoretical models were developed to predict the temperature and density change with time and spatial variation of temperature in the foam due to heat losses, by considering the foaming dynamics to be either heat generation controlled or heat and mass transfer controlled. In the former, the foam was assumed to be a pseudohomogeneous phase and the approach was similar to that of Rojas, et al. (5). New features accounted for in the model were dilution of the reactant concentration due to the presence of liquid blowing agent and heat loss from the foam due to radiation. While excellent agreement between theoretical predictions and experimental results was obtained for temperature variation with time at different locations in the foam, the model gave a much sharper reduction in density with time as compared to the experimental data. In the second model, the rate of foaming was assumed to be controlled by the rate of heat and mass transfer to a single bubble in the foam. Assuming a film model for heat and mass transfer, the theoretical predictions for both temperature and density were found to be in very good agreement with experimental data.
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    Polymer Engineering and Science 34 (1994), S. 821-826 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: When diffusion coefficients are measured with the cup method, the exposed area is often less than the area of the sample. Because of this masking effect the measured diffusion coefficient is overestimated. The present article presents simple formulas based on two-dimensional analytical solutions to correct for this in cylindrical cup samples. Different cases of anisotropical diffusion are dealt with. The error in the analytical solutions is determined by numerical computer simulations.
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    Polymer Engineering and Science 34 (1994), S. 815-820 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A comparative study of warpage, global shrinkage, and residual quench stresses developed in rotational molding is made for a series of thermoplastics including various polythylenes, polypropylene, polyamide-6, polycarbonate, and polystyrene. The influence of rate of quench on uniaxial stress strain and impact behavior of rotomolded parts was also studied. Generally, warpage, global shrinkage, and residual stresses increase with increasing quench rate for all the polymers. Further, the levels of warpage and global shrinkage increases with extent of crystallization, i.e., products from glassy polymers exhibit little warpage and those from highly crystalline polymers are highly warped. Increasing rate of quench tends to increase elongation to break and impact strength.
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    Polymer Engineering and Science 34 (1994), S. 799-803 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Measurements of melt strength and breaking stretching ratio of several blends of thermoplastic polymers with liquid crystalline polymers are presented. The melt strength behavior depends not only on the viscosity of the blends but also on the temperature dependence of the viscosity. In particular, even if the viscosities of the blends are, at the extrusion temperature, lower than that of the thermoplastic matrices, the melt strength can be larger than that of the pure thermoplastics if its viscosity-temperature curve exceeds that of the matrices far from the solidification temperature. This behavior allows one to spin or film blow these blends despite the low viscosity.
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    Polymer Engineering and Science 34 (1994), S. 804-814 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A mathematical model of the high pressure polymerization of ethylene in tubular reactors was tested with experimental data obtained from an industrial size tubular reactor. Series of experiments involving changes in operating conditions were carried out, and process data and polyethylene samples were collected. The collected samples were characterized for their molecular weight distributions and various rheological material functions involving shear and extensional flows. The findings of the model were compared against the generated process data and the molecular weight distributions of the samples. The determined rheological behavior exhibited strong dependence on the primary characteristics of the resins. Overall, this study should introduce a better understanding of the interactions between high pressure reaction conditions and the primary properties of polyethylene, including moments of molecular weight distribution and extent of branching on one hand and the interrelationships between primary properties and the rheological behavior of the high pressure polyethylene product on the other hand.
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    Polymer Engineering and Science 34 (1994), S. 827-834 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The Galerkin finite element method has been applied to study the three-dimensional flow field of power-law fluids inside an extrusion die. Two inlet designs, i.e., center-fed and end-fed, have been considered. The effects of inertial force as represented by the Reynolds number Re, inlet geometry, and the power-law index n on lateral flow uniformity and vortex formation in the entrance region have been examined. A flow visualization technique has been carried out to experimentally verify the theoretical prediction of the three-dimensional flow field inside a die. It has been found that increasing Re or decreasing n will deteriorate flow uniformity. Depending on the direction of the inlet jet stream, the inertial force may create a flow peak in the central region of a center-fed die, or the maximum flow rate will appear close to the end of the die for an end-fed die. For highly shear-thinning fluids, lower flow rates are always observed close to the end of the dies. It is concluded that creating a plug flow in the inlet tube of the extrusion die is advantageous for both center-fed and end-fed designs.
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    Polymer Engineering and Science 34 (1994), S. 835-846 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A two-phase model is presented for simulating the post-filling stage of injection molding of amorphous and semicrystalline materials. A finite-element scheme with quadratic shape function for the pressure is proposed. The melt is considered in terms of Hele-Shaw flow for a non-Newtonian fluid using a modified-Cross model with either an Arrhenius-type or WLF-type functional form to describe the viscosity under nonisothermal conditions; the compressible behavior of the polymer is assumed to obey either a double-domain Tait or single-domain Spencer Gilmore equation of state. The interfacial energy balance equation including the latent-heat effect for semicrystalline materials is coupled with the transient energy equation for the solid and melt phases in order to predict the solidified layer and temperature profile. Two well-characterized materials, namely a commercial-grade PP and PS, were used in the present work. Good agreement is obtained between the present simulation and experimental pressure traces from this study and from previous investigation in the literature. The effects of compressibility, viscosity model, and thermal properties upon the predicted pressure field are also considered.
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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