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  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Macromolecules 15 (1982), S. 1455-1460 
    ISSN: 1520-5835
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 31 (1993), S. 933-938 
    ISSN: 0887-6266
    Keywords: liquid-crystal copolyesters ; melt-spinning ; mechanical properties ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Melt-spinning and mechanical properties of fibers of a new class of semirigid thermotropic liquid-crystal polymers are presented. These copolyesters are synthesized from 4-4′-dihydroxybiphenyl (B), 4-hydroxybenzoic acid (H), and flexible units provided by aliphatic diacids. The flexible units depress the melting temperature without strongly depressing the mechanical properties. These liquid-crystal polymers can be easily spun at high draw ratios. Indeed, unlike rigid liquid-crystal polymers, relatively high draw ratios are needed to attain high mechanical strength. Tensile moduli of about 28 GPa and tensile strengths of about 350 MPa are obtained. © 1993 John Wiley & Sons, Inc.
    Additional Material: 10 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Acta Polymerica 30 (1979), S. 685-688 
    ISSN: 0323-7648
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: An ataktischem Polystyrol wurden Reckversuche im Temperaturbereich von 125 bis 180°C mit unterschiedlichen Dehungsgeschwindigkeiten und unterschiedlicher Einwirkungszeit der orientierenden Kraft durchgeführt. Die mechanischen Eigenschaften der orientierten Proben, wie Elastizitätsmodul, Fließdehnung, Fließspannung, Bruchlast und Bruchdehnung, werden als Funktion der Doppelbrechung dargestellt.
    Notes: Hot stretching experiments for an atactic polystyrene have been performed in the temperature range 125 to 180°C, at various elongation rates and with different times of application of the orienting field. Mechanical properties of the oriented samples, including Young's modulus, yield strain and stress, ultimate strength and elongation at break, are reported as a function of birefringence.
    Additional Material: 6 Ill.
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  • 4
    ISSN: 0323-7648
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Die Festigkeitseigenschaf ten und das Verhalten beim Kugelfalltest von coextrudiertcn Filmen aus LDPE und LLDPE wurden mit den entsprechenden Eigenschaften von aus Mischungen dieser Polymere hergestellten Filmen verglichen. Der Einfluß der Zusammensetzung, des Aufblasverhältnisses und des achsialen Reckverhältnisses auf die Filmeigeneigenschaften wurde untersucht. Die Ergebnisse zcigen, daß zumindest bei den hicr betrachteten semiverträglichen Systemen die Eigensehaften der durch Coextrusion bzw. aus dem Polymergemisch bergestellten Filme dicht beieinander liegen.
    Notes: Ultimate tensile properties and dart impact behaviour of coextruded films of LDPE and LLDPE were compared with those of films made from blends of the same resins. The effect of composition and of both blow up ratio and axial draw ratio of the blowing process on film properties was explored. The results indicate that, at least for semicompatible systems like that considered here, films made from blends and coextruded ones have mechanical properties very close to each other.
    Additional Material: 6 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Letters Edition 15 (1977), S. 323-327 
    ISSN: 0360-6384
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 2 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 25 (1980), S. 555-564 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Experimental transient results in the nonlinear region are reported for a commercial polyisobutylene subjected to sudden imposition of either a constant shear stress or a constant electric field. Some steady-state results, eventually obtained in different types of experiments, are also considered. In both cases, a model analysis is presented that accounts for the nonlinear effects through changes in the free volume depending upon the applied stress. The good comparison between theoretical predictions and experimental results seems to indicate that the phenomenological approach advanced here is very promising.
    Additional Material: 6 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 25 (1980), S. 2001-2006 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Nylon 6-LiCl systems of various concentrations were prepared by anionic polymerization of caprolactam in the presence of salt. A depression of both crystallization rate and melting temperature was evidenced through x-ray, density, and DSC analyses. Such a preliminary characterization allowed for choosing the proper conditions in order to obtain amorphous fibers from a spinning operation which was performed at a temperature lower than the pure polymer melting point. These results are of technological relevance, especially in view of obtaining, as in similar cases, large amorphous orientations through a spinning-drawing process and high-modulus fibers after subsequent crystallization. Also, the possibility of restoring some crystallinity in the material has been proven.
    Additional Material: 5 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 28 (1983), S. 3075-3080 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The effect of aluminum hydroxide upon the dielectric properties of an epoxy resin has been studied in a wide frequency and temperature range. An interfacial polarization effect, known as the Maxwell-Wagner-Sillars polarization is evidenced for the filled resin, which shows a higher permittivity, a higher dielectric loss, and a β transition with a larger relaxation time. The glass transition temperature is, on the contrary, mostly unaffected by the presence of the filler.
    Additional Material: 6 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 39 (1990), S. 865-873 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: An easy and cheap method to prepare functionalized polyethylene is reported in which polyethylene is photooxidized and then melt-blended with nylon. Structural, rheological, and mechanical modifications indicate that carbonyl, formed during photooxidation, and amine groups react giving rise to copolymers which stabilize the blends. Photooxidized polyethylene from waste could be very effective in preparing polyethylene/polyamide blends with improved properties. This new approach improves over current methods in which compatibilization of polyolefines and polyamides is mostly performed by reacting functionalized polyolefines with polyamides in molten state. The functionalization is achieved by chemical modification of the polyolefines chains. This step could be very expensive.
    Additional Material: 9 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 27 (1982), S. 1335-1341 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A polycaprolactam/3.7% w/w LiCl system, obtained by anionic polymerization of caprolactam directly in the presence of salt, has been employed for the production of highly oriented fibers. More particularly, an optimization of spinning, drawing, and annealing conditions has been performed, finally obtaining fibers which shows very satisfactory mechanical results. Namely, average moduli values up to 12 GPa and strength values up to 1 GPa when fracture is far from clamps, have been observed.
    Additional Material: 9 Ill.
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